SCIENTIFIC ABSTRACT MALKIN, V.I. - MALKIN, YA.Z.

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• Collection: Scientific Abstracts
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• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

News in Brief
(terdd-Wireless Factory)
SOV/32-24-10-65/7N
Card 3/3

TOPIC TAGS: 16mi v6ltage ard, static characteristic Current vb tage, -ca odlei-
t2.wee, veAding taclhnology
S-BSTRACT: The effect oil' the individual are areas (c-athod-, anode and column)
the formation of its static charalete-Qtic 's virtua).1v unknow-P.. The authors
0 rl A
i.~ ~C,(] a rnchod lmhkh involveo oca I chanfro o~' the ourrent between the cathode
~jx!('A the anode -,%,hi-1K! the arc cu'lunna~ cur~-E-it %;,,~S 'T'he length of the basic':
~~Vc re.Ttaine-d Invariable, the assigmed rurrent vas stable v.,hatever the voltag-
~~ftaulges arLd the spo".-,; r in(Jirfct are -?iere combined on
he
The cathD(J-- n 1-1, -~-prl adc-.;-;si-ve influence on the forma.
r
~on of the istatic characteristic within the 0. 5 to 15 amp railge whiie the anode
d1ro) "hanoed negligilbly, its ef"fect being mipov. The aut-hors conclude that in

// i I", -Z,
DANILOV, V.I.; KAZIN, V. L
-
Experi;=a-I'verification of the cryatal growth theory. Probl.
metalloved. I fiz. met. no,2:25-30 151. (MIRA 11:4)
1. Ohlen-korrespondent 'a USSB~
(Crystallization) (Salol)

USSR/Crystals. B-5
Abs Jour Referat Zhur Khimiya, No 6, 1957, 18371
Aut'.or V. I. Malkin.
Title +Tro-~ ~el on Concerning The Dependence of '1he Crystal
Growth Shape on The Growth Speed.
Orig Pub Probl. metalloval. i fiz. metallov, sb.4, 1955, 113-120
Abstract The dependenc,; of the gro,~rth shape on the 6rowth speed v
of a salol crystal growing in a melt and the connection
between v and the structure in an ingot of Sli were stu-
died. The transition to an acicular grovth shape is ob-
servcd, when v of the crystal increases. When undercoo-
linZ is decreas-z-1, v decreases also, and the (6rowth of
crystals of acicular shape is replaced by the growth of
crystal of regialar shape. 'Me same transition to an aci-
cular structure with the increasu of v wao observed also
in an ingot of Sn. It is pointed out that, besides the
thermal and "geometrical" factors, an essential part in
Card 1/2 - 120 -

USSR/Crystals.
Abs Jour : Referat 7-hur - KhImilya, No 6, 1957, 183711
produc' % the acLcular L~,rovrLh shape belongs to the
grow'.1. "ILc'lanism. I-L is surmised that the crystal
eXow',h Irj wc-dimeniicnal nuclei is replaced with
the growth b~ dislod-ement in proportion to the
receding from the me!*,,-ing point.
B-5
Card 2/2 - 121 -

-~HVARTSMAR, A.; 14ALIKIN,V.1.
On O.A.Hein and P.V.Gelld's book: "Physical chemistry of pyro-
metallurgical processes." Part 2. Reviewed by L.A.Shvsrtsman,
V.I.Malkin. Zhur.fiz.khim.29 no.5:946-949 MY'55- (MLRA 8:12)
(Chemistry, Metallurgic) (Bein,O.A) (Gelld,P.V.)

HATSKIT,S.M., nauchnyy sotrudnik; SMIRNOV, V.P., nauchnyy sotrudnik;
SHVARTSKa, L.A., nauchnyy sotrudnik; MALKIN, V.I., nauchnyy
sotrudaik.
"Radioisotopes in machine-building.' P.E. Dliachenko, Reviewed
by S.K. Raiskii and others. Zav.lab. 22 no.6:758-759 156.
(MLBA 9:8)
1. Fizicheskly institut Akadsmii aauk SSSR (for Rayakiy, Smirnov);
2. TSentrallayy nauchno-isaledovatellskiy institut chernoy metal-
lurgii.
(Radioisotopes--Industrial applications) (Wiacheako, F.Z.)

:550 ~Inmffl
- -10
MALKIN., V. I.
"The Mobility of Cations in Silicate Melts,"
lecture given at the Fourth Conference on Steelmaking, A.A. Baikov Institute of
Metallurgy, Moscuw, Jul, 1-6, 1957
1

man" V. 1.
"Measurements of the Relative Mobility of Cations in -fixtureas of Fused
Oxides." V.I. Malkin, Shvarzman, L.A., Moscow, USSR
Paper submitted for presentati-on at the International Conference on
Radioisotopes in Scientific Research, Paris, 9-20 Sep 1957
Cent. Research Inst. of Iron Metallurgy, Moscow, USSR

V.
137-58-4-6566
Translation from: Referativnyy zhurnal, Metallurgiya. 1958, Nr 4, p 36 IUSSR)
AUTHORS; Malkin, V.I., Shvartsman, L.A.
TITLE, Measuring the Ion Transference (Hittorf) Number of the Ca 24
in Fused CaO-PZ05 (Izmereniye chisla perenosa iona Caz+ v
rasplave CaO-P205)
PERIODICAL: V sb- Fiz. -khim. osnovy proiz-va stali, Moscow AN
SSSR. 1957 pp 433-437. Diskus. pp 505-512
ABSTRACT: The following method was used to measure the ion trans-
ference numbers in oxide melts. A srnail corundum-coated
crucible, having a 1- 1 5 mrn aperture at its bottom, was
placed in a large-diameter crucible of the same materials
The slag (27% CaO, 73% P205) was charged into the cruc-
ibles and weighed. The slag contained Ca45. Graphite elec-
trodes were lowered into the melt on attainment of 10000C
temperature. After current had been passed through it, the
electrodes were removed and the crucible weighed with its
diaphragm and contents. The loss of weight in the course of
the experiment was determined in this way. Then the crucible
Ca rd 1/2 was broken, and the weights of the catholyte and anolyte were

137-58-4-6566
Measuring the Ion Transference (cont.
determined separately. The Hittorf number x, of the Ca ion througli iine
anodic space was calculated from the equation:
p. qf If qa
1 K - IE qj
where q, was the weight of the anolyte after the experiment, qa was the
weight loss of the anolyte during the experiment, Ii and If were the radio-
activities of the ano te before and after the experiment, p was the weight
percentage of the CalN ion before the experiment, K was the quantity of
electriciti in farads, and El was the numerical value of a gram-equivalent
of the Ca + ion. Here qa was computed from the equation qa- K (E14 E2~xi'
where E2 was the numerical value of a gram-equivalent of the 02- ion. Four
experiments yielded the following values of x1. 1.06, 1.04, 1.06. 1.02, These
data show that the conductivity of the melt is by a single cation.
L K.
1 Metallurgy 2 Melts--Applfcations 3 'Lon exchange--Measuremen,
Card 212

_z'
AUTHORi Malkin, V.I., Khokhlov, S.F., Shvartarrion, L.A. 76-11-16/35
TITLE: Determination of the Cation Transport Numbers in the Melt
Na20,K2O,4SiO2 (Izmereniye chisel perenosa kationov v rasplave
Na2O-K20-4SiO2)
PMIODICAL: Zhurnal Flzicheskoy Khimii, 1957, Vol. 31, Nr 11 , pp. 2485-2487
(USSR)
ABSTRACTi The relative m6bility of the cations Na* and K4* with a charge, the
radii of which differed noticeably from each other, was investigated
in a silicate melt, the composition of which corresponds to the
formula Na20 K 0 4S102- For the determination of the transmission
tiumbers for Ja~ and K+ the method CRef.2] described already
previously was applied by making use of the radio isotopes Na24 and
K42. The results of the experiments were somewhat surprising. They
showed that the mobilities of the Ne- and K+-ions are nearly
equal in the melt investigated here. There are I figure and 6 refe-
rences, 3 of which are Slavic
Card 1/2

76-ii-IC/35
Determinaticn of the Cation Transport Numbers in the Melt Na2o'K20-4-S'02
ASSOCIATICK: Institute for Metallurgy and Metal Physics. Central Scientific
Research Institute Of FerrQUS YetallurgY., Mosco~r (Institut
metallovedeniya i fiziki metallov. Tsentral'n_vy nauchno-
issledova.tel'skiy institut chernoy metallurgii, Moskva)
SUBMITTED- JulY 14, 1956
AVAILABLE: Library of Congress
Card 212

M ~ , 4,1, :7-7
KURDYUHOV, G.T.. otvetstvenrWy red.; SAMARIN. A.K., red.-, SHYARTSHAN, L.A..
red.; HALKIN, V.I., red.; GOLIKOV. V.H., red.; RABEZOVA, V.A..
red.; red.izd-va; SIMKINA. Yi3.fi., tekhn.red.;
KASHINA, P.S.: tekhn.red.
[Metallurgy and physical metallurgy proceedings of the Conference
on the Use of Radioactive and Stable Isotopes and Radiation in the
Rational Economy and in Science) Metallurgiia i metallovedents;
truAy Vaesoiamot riauchno-tekhricheakoi konferentaii po primeneniiu
radioaktivufth I stabillnykh Izotopov I izluchenii v narodnom
khoziaistve i nauke. Moskva, Izd-vo Akad. nauk SSSR. 1958- 518 P.
(MIRA 11:6)
1. Vaesoymnaya nauchno-tek.hnicheskaya konferentaiya po primeneniyu
radioaktivnykh i stabillrqkh izotopov i Uluchenti v narodnom
khozyaystvo i nauke. 1957.
(metallurgy) (Physical metallurgy)

4,4~1 A / J
AUTHORS: iLallcin I~ and 3,F.
TITLE: 1,1easurement of ti-ic; Trans orl-, for Ca~~- ir '.',elts in
t1le C;3.O,',',---0--3iO- an d CaO-14c-O-Al 07,-Sio-.
2 2 1
(Izmereniye Er-nosa iona V-al'---iya v r'-- 3 va -.:-!I
sis-Lle:,, ckis' kal'tsiya
--o-kis1ma--niya---c,.cis'
P~,L'~IODICAL: Iz-vel,,tija Akadeaii NLiuk Otdc-1cc.,iyc Tc!l:h~nich.eszklikh
i7au',,, 1)58, Nr 1081--liO (U-;jl?)
ABSTRA~;T: Struct-ure studiec on :a,--1tic-on,,-)onent silic,--,z; :--lts are of
si-lbstantial intc~..est -,n Tne bel,-.vL~)ar of the
various con?-.,~-,nerits in ~a:,ich ar- can be
jud-(,d fr-)-,i the ionic da'~a are
riven by tra-nsport ni-L::ber m,~aL~ui~lments, Ti-,c 'bel-iaviour Df
oxides such as 1i'llsO and A1.0 in silicatc, is of inter-
s~ n.-
e s b e e r, 'L a i,-, , e d (. R e f 3 , 1
are amphoteric in melts i,-: thc, Crj.O-i~-O-Al C, jic),
U
In relation -o the ionic -J.iure of the sla,~, amono'cric
behavioar a-pears in the :actal beinr~- present Ln. --il-i3n form
C~
(in vtlii,:~h it has an ai-,T)r~-ial-,Ie -~C'biiity) c -'ex anion
.-nd in
form. (where the mobility io vc--ry --T-,a--,I), Trie authurs of this
Card 1/6 T)aper o-t:3z=ed an amphoteric beiiaviour -)f A-',,O- -n 'CaO-Al 0 -
2 3

2)4- 5;-- -3-13/33
ivleasure-ment of th- '2r-an_-I.,,_)-_,t for Cra -n-
CaO-'.,I,r-O-SiO 2 and -,aC)-'.',--,O-Al p0- -S-10--) 3ystl,~:ns,
_SiO 2 inel in their Df the
mobility of,(~-a'_' in tills- systein (Ref,~5). Tile relative mob-
ility of .'a ion in Pielts of the CaO.0-5-.i,70.0-5
Al 0 3 .2 50310, and ", a 0, 1 - 5Al,, 0 i . 1) i 0 (and n one of
2 31 2
siti -in ~"56W_ fr~-,, vla~: :~v_as t
,-ompo, ure d o
clucidate '611~~, beLuv-_',)L,r Df Al-0, aInd Tli,e of tliese
four-component mel~_3 diff._--rs from. t1bat ternary sy:3tei-
in tavin-, nar- of SiO, re-olaced by Do_ A :,-ic-thod ,Dre-
I:-, z! 9 45
viously described in ;-I-tail (Ref.4" w~iicn u~,d Ga was
employed, bu~: Fhe C. _45,V,
- a as found to be 11--st a~,- the temoerat-
(l ~, 0 C_C, -Ile ~-aE.,t'rrd had tc be chan ed somewhat.
ure used 550 C)~ 1 1,
The electrDly7is (sc-0. fi-ure) cons_'=ed of a lar,-e alun-
dum crucible conta-i two- 2mall --racibles One of ~-,~aese
hal a hole in it uild _-Dnstituted the an:-,Ide the
anode. beiro, insert-c-d! It, TIe -)1:1ic-~r .,ia!3 in-
serted in the -.-elL in Jie large cru,-ible. T~,(~ othor Small
U
,:.,rucible acted as a i-, tiad nc hc~le 1- Lt , bat viaG used
Card 2/6

aeasurement of the TransToort ~-:)r Ca'
a 0 0 - S 10 2 and CaO-~.,1,::O-Al,0,-3iO,-,
45
to determine 'k',,e Cat Loss fro.,:, t~-ie ~~han--e 'n -hr, :,c'--ivity
of the slag In It; tne activity c17 the Sid ir.
was used of the
Of ciurse, t1ne accuracy of tl4e tra7-.s.or~:
is therebj red.--ced, and the
B u - P v e n -,, a,
a s s o m e w ha t q u a t a -, -e , -j ita"-%, -,~03 C',
relative mobility .,ive lral-ja')Ie data in - 1~ _-i t t b e
~ e ~_a~ ! - f. 4-+
aviour of cations in .,.'Ielts. T~-,
h
was determined *Lr,-j,li the equatio,.-11
-Ca
--. - -. a )
9,,a k At
x Ca =
+
.Ca a )ALI B~- a
where -D I: t n ~2 frjct~or, b.7 viei;-ht cf' -a4
L
experiment, V" E 1b ? -i n;-r h c c -i a I n t, t s
~Ia -, ?At 0
of the alu:-~.inilx,.- 2: :11 ~-he ar-olyte
,,,jeighLt (g). Ic the charge )az,---,ed farada7s'), UT tho ar-olyte
Card 3/6 ~D a

21-5-13-13/ 38
i'leasurement of the TraEs~)~)r-~ for Ca + +. i ri I t ~-, I n t h,~
CaO-M--O-SiO and CaO-l; O-A-'-,o -Sio, Systems.
2 1- 3 1~
activity afte-r the exj~-rimc;nt, J tILe activity in the check
crucible and -x, the trans.)ort number of Ca`
q SuM4
~.(I), -whieL was dprivc~d (R;~I`,3) as Lnc-. a unipolar conduc-
E
tivity fo-, -aelts witL 'Iwc, ca~n he used here since
_~A,t and are- c-Lose u tier, Tatles 1-3 -,ive the
results; TC le 1 shows that in the Si02 melt tine
Ca +4- --;-- of -_-u~~h hi,-her mob4'~i-~.y than tne ME-:++ ; when part of
the IjIgO is re-i-ALaced by Al 0 -,hc-- tran_,:z-,)-,)rt number dro-)s
2
appreciably, as Tabls 2 shcws. Since there ar--- no suitable
radio isotc~nes of Al and i4g it cculd nct be decisively dettar-
mined vinich of the ions from th-ese metalE comDet,:~s ,,iith ~a
in conduct~n- the c,irrent, b-it tLe a~_itliors s-up-cse that
main one is Al'+~ The aD-.-.r-~,.~iable :icbility of Al+++ in
a CaO-Al O.-SiO, mel-~, indi3at~~s this: so doc-s the reduced
2
.,.IgO content of tl~e CaO~0,5!AgO.0-5A! 0 melt, relative
2 3'
to th-e ;~I-c_rnary syste(u, Sincp i r the ++ here retained the
'lard 4/6

Measurement of the Trp_ns-,=~- "I' x3be' rs fc Ir Ca i n, e i i - t e
CaO-M-O-SiO and CaO-',II-'O-A1.-O.1_S'.O-'
2 L , - C
same mobiiity as Oi.-~ one it-:-, trruis~-ort
number shouid be (,u c e d So, if the ",It +4- in
, T 4-
-Gate to compete with h ")e- if the
system is in no s t e ,,I
fall in the Ca+ trano-)ort number in tbe
L Id t~~ the ~,*i-+ viould br- nccessary
melt is to be at-ribute. - EI 4-
to suppose a very surprising increase tla.- tr_n~s -~,Drt nx,-Ib,-r
of the lattler, which is ri;7,hly ira-lrnbablc~. :es_~lts of
Table 3 indicate that when some of the in t_ie t=nary
system is replaced Ly AI,O-. the Ca+' trazisI~Dr~ ntLniber dro-.)s
s~,4_11 more ma_rkedii, 'J'a I~nlicate-_7 tLat t'ue 7~arrent i~_
partially carried by Al In cati,)n form; JiLL is doubtfui if
U I
it can be supposed tha-, the is of hi;-,-h niobili~cy in -this
melt.., since when the acid 3102 is reulaced by a_-i-~h,)teric A120 3
tde ',3cid' feati-ii-es of ions suc-q as '.!-++ si~io~_-Id 'be :,-,-Ire
and the mcbilit-y th!_~I--~Iorc. 1'educed. T'--e re-7ul~;s ~!ius lndicatk~
that Al. eXi3tS in catixi form in melto -in thc-
-Al,_)O -SiO,) syste-, a.-rd thr__~~ i7ii,-O ~ia_, acid so both
3
Al.,,J- and M.-7.0 -an I)e cg"Islaored nI!,._,A_)c-.1--ri- -.3 :i.: laese
Card 5/6 L ~

Me as uremen t of tlie '-7ra-ns-. amber_~ f :)r C, a ~+ in
CaO--1.I,,--G-SiO and 0-,-Sio, .3'ystler2s~
2
-)Iysis
melts, Tile fi.-ure sliovis a sketch of Aectr, , ceil
for transoort riwa-ber measurem~_nts (-.c'Iif_--matic Table,; 1-~
:rive the mea_;ured re~ )111 ~31 1 S "a C D- -~D 1t e t r ~:_n 3
with the exception of tiae uubie:" and -Dine refer-_'nces). T-'qere
are 3 tables, 1 figure and' A- Soviet ref-r~~nces.
rr'c'TIIChI-
ASSOCIATIU11 : Insti ~I-ut Taeta_'Ic)vc.~I_enij'-k EIZI ~~i -.:ie tail.~-r I s~
~4 N
(Meta.1 iography and Metal Physics cf tne. r."sNIIChI]
SUBMITTIE'D. July ~, l')57 .
1. Metallurgr 2.
Card 6/6

MALKIN, V.I.; POKIDYSEERV. V.V.
,i
Change of the transference number of Ha 4' ion in 1A O.Ra 0.4SLO
2 2 2
melt. Zhur. neorg. khim. 3 no.9:2219-2220 S '58. C MIRA 11:10)
1.1natitut metallovedeniya i fiziki metallov TSentrallnogo nauchno-
iseledovatellskogo Institute, chernoy metallurgii.
(Ions) (Electrochemical analysis)

O'OV/24-58-5-25/31
AUTHORS: Malkin, V. I. and Pokidyshev, V. V. (Moscow)
..;TITLE-. Mea er of Ion Transfers in a Sodiam-
suring -the Numb
Cobalt Silicate Melt (Izmereniye chisel perenosa ionov
v rasplave natriy-kobal"tovogo silikata)
PERIODICAL: Izvestiya Akademii Nault SSSR, Otdeleniye Tekhnicheskikh
Nauk, 1958, Nr 5, pp 129-131 (USSR)
ABSTRACT: In earlier work of one of the authors and his team ~Ref 1),
a comparison was made of the mobility of Na+ and Ca +
ions in a silicate melt of the composition Na20-CaO-43iO2,
Although the two ions have almost equal radii, the
mobility of the single ch re ion Na + is over twice as
high as that of the ion C:T The authorf considered it
of interest to compare the inob4lity of Na with Co ++ ' the
radius of which is lower than the radius of the ion Na+,
For this purpose thTT measured the number of transfers of
the ions Na+ and Co in the melt 2Na20.Co0.6SiO2 for
which the O:Si ratio is the same as for the melt
Na20'CaO.4SiO2 but the molar concentration is twice as
large as the concentration of CoO. Measurement of the
Card 1/3 number of transfers was carried out by a method which was

SOV/24-58-5-25/31
Measuring the Number of Ion Transfers in a Sodium-Cobalt
Silicate Melt
described in detail in earlier work (Ref 2) of one of the
authors, which is based on measuring by means of radio-
active tracers the small changes in the cathion and
anion concentrations in the case of passing Qf small 60
quantities of electricity through the melt; Na-` and so
were used. The experiments were carried out at 1200 C
and the results are entered +in a table, p 130. The number
of transfef~ for the ion Na approaches unity, whilst for
the ion Co they are nearer to zero. Thus, in the
investigated melt the+ fatio of the mobility of the 19a+
ion to that of the Co + ion iF larger than the.ratio of
the mobility of the Na ion to that of the Ca++ ion in
the melt Na O-CaO-4SiO . This is explained by the
smaller val. fof the r2lus of the Co+ ion as compared
with the C~+ ion, which brings about a stronger link
between Co ion and the anion grid of the melt.
Card 2/3

SO~-"/24-58-5-25/31
Measuring the Number of Ion Transfers in a So%],i-a-Cobalt
Siiicate Melt
There are 1 table and 5 references, 4 of which are Soviet,
1 English.
ASSOCIATION: Institut metallovedenlya i fiziki metallov TsNIIChhi
(Institute of Met&Uography and Metal Physics
TsNIIChM)
SUBMITTED: October 1?, 1957
Card 3/3

4UTHORS: Malkin, V. I.,
TITLE: The Determ_ifilat~an
in the Melt of
ions. Na+ v rasplave
Pokidyshev, V. V. SOV/78-3-9-37/38
of the Transference Number of the Na+ Ion
Li 2 O.Na 20-4SiO2 (Izmereniye chisla perenosa
Li 2O.Na2O.4SiO2)
PERKODICAL: Zhurnal neorganicheskoy khimii, 1958, Vol 3, Nr 9, pp 2219-2220
(USSR)
ABSTRACT: The paper under review deals with the analysis of the relative
mobility of cations in the melt of Li 20-Ha2O-4SiO2' The in-
vestigations were carried out by using the radioactive isotope
Na 24. The results show that the sodium ion in the melt examined
is more mobile in comparison with lithium. The electric con-
ductivity of the melt Na 2O.Sio2 at 150-2300C is considerablr
higher than that of the glass melt with a composition of
Li 20.23i0 2' In the case of simultaneous presence of two cations
with equal anions the mobility of one cation depends on the
properties of the other.
Card 1/2 There are 1 table and 10 references, 5 of which are Soviet.

+SOV/78-3-9-37/38
The Determination of the Transference Number of the Na Ton in the Melt of
,Li 20.Na 20-4SiO2
ASSOCIATION: Institut metallovedeniya i fiziki metallov (Institute of
Metallography and Physics of Metuals) Tsentrallnogo nauchno-
issledovateliskogo instituta chernoy metallurgii 'of the Central
Scientific Research Institute of Ferrous Metallurgy)
SUBMITTED: March 18, 1958
Card 2/2

SHWARTSM, LA., doktor khim.nauk-. KALKIN, V.I.. kan&.tskhD.nauk;
1AQWLIH. I.A.,
A.H. Norozov's article x9odern, slag theory and the theory of
steel smelting processes." Izv., vys. ucheb. zav.; chern. met.
no.7:65-65 JI 158. (KRA 1l:10)
(Steel-143tallurgy)

AUTUOR: Malkin V 1 32-24-6-43/44
TITLE: Conference on the Use of Radioactive Isotopes in Iron Metallurg-Y
(Soveshchaniye po primeneniyu radioaktivnykh izotopov v chernoy
metallurgii)
PERIODICAL: Zavodskaya Laboratoriya, 1958, Vol 24, Nr 6,
PP. 783 - 784 (USSR)
ABSTRACT: From March 25 - 2a, 1958 a conference convened by the Central
Scientific Research Institute for Iron Metallurgy was held
in Moscow in order to discuss the above subject. It was attended
by the workers and the staff of the factories and scientific
research institutes. 2o metallurgical works and 3o scientific
research organizations took part in it, and 35 contributions
and reports were made. In the contributionsby P.L.Gruzina
(Central Scientific Research Institute for Iron Metallurgy),
I.G.Polovehenko (works imeni Dzerzhinskiy), Ya.S.Gorbaneva
("Azovstall 11 works), Yu.P.Belyayeva ("Illich" works), V,A.
Smolyak (Dnepropetrovsk metallurgical works) the problems
concerning the use of radioactive isotopes in blast furnace
industry were discussed, while the lecture by L.A.Shvartsman
Card 112 dealt with the use of isotopes in steel casting. Furthermore,

Conference on the Use of Radioactive Isotopes in 32-24-6-43/44
Iron'~etallurgy
the topics of the contributions by A.M.Skrebtsova, I~G.
Golldahteyn, V.K.Latyshev and V.S.Tokmakov, 0.14,.Ignat'YOV,
P.L.Gruzin, S.V.Zemskiy, A.Ya.Yampollskiy, N.G.Bogdanova,
O.I.Vallter, Ye.S.Shlyakhovetakiy, A.G.Vasillyev, L.K.
Strelkov, N.I.Volkova, N.G.Gusev, V.A.Korotkova and V,F.
Smirnov are mentioned and respective comments are made. At
this conference the decision was made that a further develop-
ment of the use of radioactive isotopes is necessary in order
to make it possible to solve problems in metallurgical science.
1. Iron--Metallurgy 2. Radioisotopes--Applications
Card 2/2

AUTHOR: Malkijn:,~I , ((Iijoscow) 74-27-3-1/7
TITLEs On the Mobility of Cations in Silicates (0 podvizhnosti
kationov v silikatakh)
PERIODICAL: Uspekhi YChimii, 1958, Vol. 27, Nr 3, PP. 306-315 (USSR)
ABSTRACT: At the beginning the author discusses the physical and
chemical properties of the silicates. Facts concerning
the mobility of the ions in simple systems: the basic
oxide is silicon dioxide, Due to the small ionic radius
and the great charge the silicon deforms the electron
cloud of oxygen. The binding between silicon and oxygen
is covalent to 50%. Moreover, the author discusses the
special polarizability of silicon dioxide. Two generally
known concepts exist on the structure of the silicate
glasses, The second is of interest because it is assumed
that the glass contains certain chemical compounds. It
is of interest that silicate glass consists of anion com=
plexes and metal cations and that it has short-range orders
This makes possible to utilize some rules which are charac.
Card 1/3 teristic of the crystalline state on the observation of the

On the Mobility of Cations in Silicates 74-27-3-4/7
migration process of the particles in the glasses. Accor=
ding to Frenkell(Reference lo) the translocation of the
particles in the crystal lattice is caused by the transi=
tion of these particles into the interstitial sites of the
lattice, In order to reach the interstitial site the ion
must overcome the potential barrier The ion gets the energy
necessary for it at the cost of the energy fluctuation of
the thermal oscillation. The experiment proved the assump=
tion that the cations are the most mobile particles in the
silicates It was demonstrated in the measuring of auto=
diffusion (with Ca and Si) in crystals of CaSiO 3 by means
of radioactive isotopes of Ca and Si that mobility of Si
is approximately by three orders of magnitude smaller than
that of Ca. Conductivity increases with the decrease of the
silicon content in the binary glass. In measuring the elec=
tric conductivity in binary silicate batches it was found
that conductivity increases with simultaneous decrease of
the silicon acid content, In this connection the intensity
of the Coulomb interaction between cation and anion plays
Card 2/3 an important rlo"le. The author discusges in detail the re-

On the Mobility of Cations in Silicates 74-27-3-11/7
lative mobility of the cations in the complex silicate
system. At the end it is stressed that at present a col=
lection of experimental data on the mobility of the par=
ticles in the silicate systems is very important in order
to make possible a future generalization on a wide basis.
There are 1 table and 36 references.. 14 of which are Soviet.
1. Silicates-Physi,-a-I properties
Card 3/3

AUTHOR: Malkin, V T 76-32-4-16/43
TITLE: Measurement of the Transport Numbers of Cations in the
K 2O-CaO-4SiO2 Melt (Izmereniye chisel perenosa kationov
v rasplave K O.CaO.4SiO )
2 21
PERIODICAL: Zhurnal Fizicheskoy Khimii,1958, Vol, 32, Nr 4,
PP- 638 - 640 (USSR)
ABSTRACT: From results of earlier investi7ations in thio field it can
be concluded that the mobility of cations in silicate melts
of this kind is essentially greater than that of anions. In
the present work the transport numbers of the ions K+ and
Ca +2 in the melt mentioned in the title were measured, with
the radioisotopes K42 and Ca 45 being used.The radioactivity
of K42 was measured with a E3 -2 counter and that of Ca45
with a BC~A-25 counters The equations for the calculation
of the transport numbers are mentioned just so well as a
Card 1/2 table with the results of seven examinations. It is noticed

76-A2-4-18/43
Measurement of the Transport Numbers of Cations in the K 2O.CaO.4SiO2 Melt
that the mobility of. e ions exceeds essentially that of Ca +2
ions, from which fact can be concluded that an interaction
of the cations is present also in sufficiently acidous sili-
cate melts. A comparison of the obtained results with those
of an earlier work with Na+ and Ca+2 ions shows that the
ratio Na + and K+ is not equal to that of Na+ and Ca +2 ; thus

we have here a proof-for the interaction of cations. The re-
lative mobility of the cations would have to be a function
of the cation radii as well as of the ratios in magnitude bet-
ween cation valence and radii., There are 1 table, 5 references,
4 of which are Soviet.
ASSOCIATION: Institut metallovedeniya i fiziki metallov TsNIICh11,'_'oskva
(Moscow Institute for Metallography and Metal Physics TsNI1ChM)
SUBMITTED: December 28, 1956
AVAILABLE: Library of Congress
1. Silicate ions--Motion 2. Potassium isotopes (Radioactive)--Appli-
Card 2/2 cations 3. Calcium isotopes (Radioactive)--Applications

J~ "I -~ '; -~ -~ ~F ,F, -):
18(o) PHASE I BOOK EXPLOITATION SOV/2125
Tsentrallnyy nauchno-issledovatellskiy institut chernoy metallurgii.
Institut Metallovedeniya I fiziki metallov
Problemy metallovedeniya i fiziki metallov (Problems in Physical
Metallurgy and Metallophysics) Moscow Metallurgizdat, 1959.
540 p. (Series: Its: Sbornik trudov, 9) Errata slip inserted.
3,600 copies printed.
Additional Sponsoring Agency: USSR. Gosudarstvennaya planova komissiya.
Ed. of Publishing House: Ye.N. Berlin; Tech. Ed.: P.G. Islentlyeva;
Editorial Board: D.S. KamenetskaVa, B.Ya. Lyubov (Resp. Ed.),
Ye.Z. Spektor, L.M. Utevskiy, L.A. Shvartsman, and V.I. Malkin.
PURPOSE: This book is intended for metallurgists, metallurgical
engineers, and specialists In the physics of metals.
COVERAGE: The papers in this collection present the results of
investigations conducted between 1954 and 1956. Subjects
Card 1/18

Problems in Physical Metallurgy (Cont.) SOV/2125
covered include crystallization of metals, physical methods of
influencing the processes of crystallization, problems in the
physical chemistry of metallurgical processes, development of
new methods_aQ4 equipment for investigating metals, and
production control. References follow each article.
TABLE OF CONTENTS:
PART 1. CRYSTALLIZATION OF METALS
Dukhin, A.I., Candidate of Physical and Mathematical Sciences.
Crystallization of Metals and Alloys in Small Volumes 9
Dukhin, A.I., and V.Ye. Neymark, Candidate of Physical and
Mathematical Sciences. Effect of Boron and Titanium on the
Supercooling of Steel 34
The results 6f measuring the supercooling of steels lead to
the conclus-ion that the energy of nucleation in-type-Khl8N9
austenitic steel is much greater than in type-Kh27 ferritic
steel. This explains the difficulty of refining the grain
of ingots of Khl8N9 steel by means of additions of titanium
and boron, as well as the ease of refining the gain of Kh27
Card 2/18

Problems in Physical Metallurgy (Cont.) SOV/2125
steel with the aid of seed crystals. It was shown that modifyin
additions of titanium and boron diminish the capacity of Yh23Nlg
steel for significant supercooling. Titanium and boron, at
concentrations which produce minimum supercooling of the melt,
refine the dendritic structure at rapid rates of solidification.
Neymark, V.Ye., and A.I. Dukh:Ln. Effect of Modifying Agents on the
Structuref Skin Deformation, and Solidification Rate of Steel
Ingots 39
Skin defects were revealed in ingots of four types of steel
(St. 3, Kh27, Kh23N18, and Khl8N9) by the vacuum-crystalli-
zation method. It was found that modifying agents (titanium,
zirconium, and boron) reduce skin deformation and accelerate
the skin-solifidication rate of these steels in varying
degrees. The results obtained suggest that it would be
advisable to investigate the possibility of using modifying
agents for lessening skin deformation and increasing the
skin-solidification rate in the continuous casting of steel.
Card 3/18

Problems in Physical Metallurgy (Cont.) SOV/2125
Kamenetskaya, D.S., Candidate of Physical and Mathematical
Sciences; E.P. Rakhmanova; Ye.Z. Spektor; and V.1. Shiryayev.
The Mechanism of the Effect of Aluminum on the Formation of
Crystallization Centers in Liquid Iron 63
Liquid primary iron (electrolytic and direct-reduction) con-
taining no active undissolved Impurities or surface-active
dissolved impurities can easily be supercooled 260-0-70c C,
below the melting point. Nonactivated particles of A120 have
little effect on the development of crystallization cQers
in iron. But the start of the crystallization process in iron
containing particles of A120~ has an activating effect on the
particles and results in a d crease in supercooling capacity.
The introduction of small quantities of aluminum into iron
sharpl~r reduces the supercooling capacity. The small degree
of supercooling in such cases is in accord with the fact
that additions of aluminum to steel act to refine the grain.
In view of the results of this investigation and others, this
effect may be explained by the fact that small additions of
aluminum decrease the energy of nucleation in liquid iron.
Because of the surface activity of alwiiinum, nucleation can
take place spontaneously with but slight supercooling, as a
result of which a fine-grained cast structure is obtained.
Card 4/18

Problems in Physical Metallurgy (Cont.) SOV/2125
Malkin,Vj., Candidate of Technical Sciences. Mechanism of the
G-ro,wtfi--of-dr~stalls From the Liquid Phase 76
Lyubov, B.Ya., Doctor of Physical and Mathematical Sciences, and
D.Ye Temkin. On the Theory of Crystallization in Large Volumes 84
Leontlyev, V.I. Effect of Ultrasonic Waves on the Crystallization
of Ingots
For effective passage of ultrasonic waves through molten metal
it is necessary to establish a definite limit of specific
ultrasonic power. The time necessary for action of the waves on
the molten metal must exceed a certain minimum, but at the
same time need not be as great as that required for complete
solidification. Better results are obtained with the use of
wider ingot molds and slower cooling. Ultrasonic waves Induce
intensive crystallization in all directions from numerous
nuclei, the formation of which is aided by the action of the
waves.
Card 5/18

Problems in Physical Metallurgy (Cont.) SOV/2125
Gurevich, Ya.B., Candidate of Technical Sciences; V.I. Leontlyev;
and I.I. Teumin, Candidate of Physical and Mathematical Sciences.
Effect of Elastic Vibrations During Crystallization on the
Structure, Mechanical Properties, and Deformability of Kh27
and Kh.25N20 Steel 117
The application of elastic vibrations during crystallization
results in a marked refinement of the grain. The linear
dimensions of the grains are 3-5 1-imes smaller than those of
ordinary grains. Columnar crystals are almost entirely
lacking. In addition, nonmetallic inclusions are relatively
small and uniformly distributed. The mechanical properties
of both types of steel are improved.
Neymark, V.Ye. Application of the Vacuum-Crystallization Method
for Producing Hollow High-alloy Steel Ingots for Rolling Into
Tubes 137
This method is recommended for the production of high-
quality thin-walled ingots (blanks). In cases where the
blanks are long and thich-walled, or short and thin-walled,
the centrifugal-casting method is preferred. The vacuum-
crystallization method is still in the experimental stage,
Card 6/18

Problems in Physical Metallurgy (Cont.) SOV/2125
but is already being used at several Soviet machine-building
plants for producing hollow cylindrical blanks from
nonferrous metals and alloys.
Yemyashev, A.V.;_.P~.M. Zubko, Candidate of Physical and Mathematical
Sciences; and V.Ye. Neymark. On the Effect of Vacuum Melting and
Teeming on Metal Properties and Ingot Quality 169
Zelenov, A.N., and D.S. Kamenetskaya. Effect of Inert Gas
Pressure in the Furnace on Gas Content in the Metal 187
The content of nitrogen and hydrogen in metal melted in an
atmosphere of argon at a pressure of 1-450 mm. Hg has little
relationship to the pressure of the argon and is considerably
lower than In the original charge. The inert gas must be
purified of oxygen if a pressure is used at which the partial
pressure of oxygen would exceed 0.01 mg. Hg. The same applies
to nitrogen contained in the inert gas, provided the nitrogen
reacts with the metal.
Card 7/18

Problems in Physical Metallurgy (Cont.) SOV/2125
Gorbatenko, A.K., and D.S. Kamenetskaya. On the Shape of
Equilibrium Curves of Binary Alloys 191
PART II. PHYSICAL CHEMISTRY OF METALLURGICAL PROCESSES
Tomilin, I.A., Candidate of Technical Sciences, and L.A. Shvarts-
man, Doctor of Chemical Sciences. Effect of Silica, Calcium
Oxide, and Sodium Oxide on the Distribution of Sulfur and
Phosphorus in Iron and Ferruginous Slag 199
It was found that the heat of transfer of sulfur from Iron
to slag in the system FeO-SiO2, saturated with silica, is
decreased by the addition of CaO to the slag. At a concen-
tration of about 20 percent CaO the heat of reaction amounts
to some 13,000 cal./g. atom, which coincides with the heat
of transfer of sulfur from iron to ferruginous slag. Further,
on increasing the content of CaO in the slag, a certain
increase in entropy takes place. An overall result of these
processes is a reduction in the value of the coefficients of
sulfur distribution In comparison with acid slag not containing
CaO. The introduction of Na2O into the slag causes the same
phenomenon to take place, but in a greater degree. These
Card 8/18

Problems in Physical Metallurgy (Cont.) SO-VI2125
facts may be explained by the specific interaction of ions In
the acid fusion. The free energy of solution of solid iron
sulfide in ferruginous and ferruginous-silicate slags was
calculated. It was shown that the heat of transfer of
phosphorus from iron to acid slag does not differ from the
corresponding figure in the case of ferruginous slag. The
coefficients of diffusion of phosphorus, however, are con-
siderably less in the first case than In the second. This can
be explained by the presence of a "structure" of silicate
polymers in the acid slag. Additions of CaO and Na2O to acid
slag increase the heat of reaction of dephosphorization, and
at the same time the values of the coefficients of distribution
rise.
Kozhevnikov, I.Yu., Candidate of Technical Sciences, and
L.A. Shvartsman. Effect of Oxides of Alkali Earth Metals on
the Equilibrium of the Dephosphorization Reaction of Iron 221
Card q/ 18

Problems in Physical Metallurgy (Cont.) SOV/2125
Petrova, Ye'.F., and L.A. Shvartsman. Effect of Alloying
.Elements on the Thermodynamic Activity of Carbon in Gamma Iron 259
It is shown that the activity of carbon in gawma iron con-
taining additions of Mn, Cr, V, and Ti Is considerably
higher than in non-alloyed auBtenite. This would indicate
that the bond strength of carbon dissolved in gamma iron
is substantially increased by the introduction of _,arbide-
forming elements.
Vintaykin, Ye.Z. Methods of Determining Vapor Pressure Over
Metals and A~loys 293
Malkin,, V.I. Measurement of Crystallization Rates in Slags of
the System CaO-Al ~O 3- S102 3o6
For '~wo slags of this system a determination was made of
the relationship between temperature and rate of crystalli-
zation in the temperature range of the vitreous state.
Within a narrow temperature range this relationship can be
described by a simple exponential law. Determinations were
also made of the energy of activation of the rate of
crystallization. The high value of the energy of activation
Card 10/18

Problems in Physical Metallurgy (Cont.) SOV/2125
for slag consisting of 23 percent CaO, 18 percent A120 . and
59 percent S102 (66,000 k cal./mol) as compared with Nat for
slag consisting of 23 percent CaO, 32 percent A1203, and
45 percent S102 indicates the presence of cationic aluminum
In these slags.
Malkin, V.I . and L.A. Shvartsman. Change in the Transport
Number of t~e Na+ Ion In Fused Sodium Silicate 311
Malkin, V.I., V.V. Pokidyshev, S.F. Khokhlov, and
L.A. Shvartsman. The Effect of an Electric Current Passed
Through the Slag-Metal Boundary in the Desulfurization Process
of Pig Iron 314
Osipov, A.I., L.A. Shvartsman, V.Ye. Iudin; and M.L. Sazonov.
On the Uniform Distribution of a Small Addit on in the Slag
During the Production of Steel in a 350-ton tOpen-hearthT
Furnace 318
Card 1l/'18

Problems in Physical Metallurgy (Cont.) SOV/2125
The distribution p ocess was studied with the use of a radio-
active isotope (CM). It was shown that the process of
diffusion of a substance in slag takes place at a consider-
ably slower rate than in metal.
Shvartsman, L.A., A.I. Osipov,, V.I. Alekseyev, V.F. Surov,
M.L. Sazonov, M.T., Bul'skiy, S.A. Telesov, A.M. Skrebtsov,
A.M. Ofengenden, L.G. Gol'dahteyn, and F.F. Sviridenko. An
Investigation of the Kinetics of Scrap Melting in the
Scrap-Ore Process
A method for determining the speed of melting scrap in
an open-hearth furnace in the scrap-ore process -was
developed on the basis of this investigation. The method
is based on "isotopic dilution" using radioactive cobalt.
It was shown that the melting speed depends on the duration
of the pig iron pouring process and carbon content in the
bath.
Stuparl, S.N. Investigation of the Transfer of Sulfur from
the Gas Phase to the Bath in the Basic Open-hearth Furnace
The transfer of sulfur from the gas phase to the bath
takes place most intensively during the loading of the
326
344
Card 12/18

Problems in ?hysical Metallurgy (Cont.) SOV/2125
metallic portion of the charge. The speed of sulfur absorption
during this period is 17-25 percent per hour, during pre-
heating 8-11 percent, and during final melting 3-7.5 percent.
Percentage is based on the sulfur content in the metal.
PART III. METHODS AND EQUIPMENT
Ferkas, M.D., Candidate of Technical Sciences. Determination of
the Depth of Decarburized and Carburized Layers by the X-ray
Method 363
The maximum carbon content In the specimen was found to be
not of the surface but at some depth (0.1-0.2 mm.) from
the surface.
Zubko, A.M., Candidate of Physical and Mathematical Sciences, and
Ye.Z. Spektor. A Quantitative Method for Determining the
Graphitization of Coke in the Blast Furnace 372
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Problems in Physical Metallurgy (Cont.) SOV/2125
Lyashchenko, B.G. On the Possibility of Localizing Carbon
Atoms in the Austenite Crystal Lattice by the Neutron
Diffraction Method 378
Litevskiy, -L.M., Candidate of Technical Sciences. Some Problems
Concerning the Semidirect Investigation of Multiphase Alloys
by the Electron Microscope Method 381
Zakharov, A.I. Determining the Integral Neutron Flux During
the Bombardment of Materials In a Nuclear Reactor 389
Felinger, A.K. Controlling the Output Current of a Photo-
electric Multiplier 391,
It is possible to control the output current and amplifi-
cation coefficient of an electric multiplier (FEU) by
varying the voltage of one of the diodes.
Afanaslyev, V.N. One Possible Method of Constructing a
Multichannel Amplitude Analyzer 397
Card 14/18

Problems in Physical Metallurgy (Cont.) SOV/2125
Pliskin, Yu.S. Method of Designing Installations for Levitation
Melting of Metals.. 401
Methods of levitation melting of metals are compared, and a
simple method of designing an inductor sufficiently accurate
for practical purposes is proposed.
Teumin, I.I. Principles of Designing Magnetostrictive
Vibrators 412
Basic principles of designing magnitostrictive vibration
for untrasonic'industrial equipment are presented. Special
attention is given to the analysis of operating conditions
in machining crystallizing metals and alloys
Latyshev, V.K., and A.K. Felinger. Logarithmic Electron Con-
verter for Type MF-4 Microphoto-meter 453
Tatochenko, L.K., Yu-V. Moysh, V.V. Lyndin, and B.S. Tokmakov.
Magnetic Particle Inspection Method Used in Metallurgy 46o
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Problems in Physical Metallurgy (Cont.) SOV/2125
Zakharov., A.I. Proportional Neutron Counters Utilizing Boron
Trifluoride 466
The author states that, ordinarily, gas obtained from the
composition of a solt by heating is used in proportional
neutron -~_,znters. However, he further states, BF3 obtained
from glas,, containers Is also effective.
Kor-nev,Yu.V.,, Candidate of Physical and Mathematical Sciences.
A Simple Electronic Magnetic Spectrometer for Identifying
Radioactive Isotopes 481
A simple portable design of a beta-spectrometer based on
focusing electrons by means of a transverse uniform mag-
netic field is described.
Tatochenko, L.K., and V.V. Lyndin. Instrument for Rapid
Determination of the Curie Point 485
The 4nstrument described is successfully being used at
the TsNIIChM for investigating properties of ferromegnetic
alloys.
Card 16/ 18

Problems in Physical Metallurgy (Cont.) SOV/2125
At'anaslyev, V.N. Remote-control Radiometers for Radiometric
Investigation,of.Certain Blast Furnace Production Processes 492
Latyshe , V.K. Us of Radioactive Isotopes for Measuring
Levels rof liquidsT 499
Latyshev, V.K., Yu.S. Pliskin, and L.K. Tatoshenko. Automatic
Level Regulator for a Continuous Steel-castin,& Installation 512
Spasskiy, M.N., and L.M. Utevskiy. High-frequency Vacuum
Melting Furnace .. 520
Gurevich, Yu.V., and V.Ye. Neymark. Selection of Conditions for
Defo-- Mes &.530 and E1533 Steels in the Cast State 527
r e strecx,-h and plasticity of high-alloy steels, types
41533 and L 530, are sharply reduced with an increase in
-emperature Mechanical properties of these steels were
nvestigate. in order to determine the possibility of
_iproving '.ieir strength and plasticity at elevated tempera-
t-Lres by rr.-ans of alloy treating or by diffusion annealing.
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Problems in Physical Metallurgy (Cont.) SOV/2125
It was found that a substantial inerflq.se in plasticity
results from the addition of 0.1-0.2 percent. Al and
0.2-0.3 percent Ba-Al alloy. Addition of Titanium greatly
reduces the plasticity.
Tokmakov, V.S. Experience Gained in the Use of Gamma-ray Flaw-
detection Method in Metallurgy 537
Experience.gained in the use of radioactive isotopes for
the purpose of flaw detection has shown that it is possible
to use this method in checking castings and welded
structures.
AVAILABLE: Library of Congress
Card 18/18
GO/Jmr
9- -59

L4ALKDA,I-V.1,.; POKIMSHEV, V.V.
Svyazi mezhdu otnositelynoy podv-lzhnostyyu kationov v
silikatnykh rasplavakh i ikh zaryadami i radiusami.
report submitted for the 5th Physical Chemical Conference on
Steel Production.
-9

5(2) 05895
AUTHORSt Malkin, V. I., Pokidyshev, V. V. SOV/78-4-11-48/50
TITLE: Measurement of the Transference Number of Na +_ and Ba 2+-Ions in
the Melt Na2O.BaO.4SiO2
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 11,
pp 2645-2646 (USSR)
ABSTRACT: In order to determine the relative mobility of a bivalent ion
the radius of which is larger than that of C&2+, a malt was
prepared from Na 2CO 39 BaCO3and rock crystal, and the trans-
ference number was computed by means of the radioactive isotopes
Na 24 (5 experiments) and Bs.140 (3 experiments) according to the
equations derived in reference 4. As had been expected, the
transport of electricity in the melt Na 2O.BaO-4SiO2 takes place
only by cations (sum of transference numbers - 1). The fraction
Card 1/2

05895
Measurement of the Transference Number of SOV/78-4-11-48/50
Ha +- and Ba 2+- Ions in the Melt Na2O.BaO-4SiO2
of Ba in the transport is much smaller than that of Ca 2+ in the
Melt Na2O-C&O-4SiO2 which is assumed to be due to the lower
mobility of Ba 2+ caused by the larger radius. There are
I table and 7 references, 6 of which are Soviet.
ASSOCIATION: Institut metallovedeniya i fiziki metallov (Institute of
Metallography and bletal Physics) - Tsentraltnyy nauchno-
issiedovatellskiy institut chernoy metallurgii (Central
Soientif ic Research Institute cf FercouB Metallurgy)
SUBMITTED: February 25, 1959
Card 2/2

MMIN, "V.I., kand.takhn.nailk
Mechanism of crystal growth from malts. Probl.metallared.i fiz.
met. no,6:76-83 '59. (KIRA 12-8)
(Crystals--Growth) (Liquid metals)

MALKIN, V.I., kand.tekhn.nauk
h.
Measuring crystallization mtes in slags of the CaO - Al 203 - SIO2
system. Probl.rtetalloved.t fiz.met. no.6:3o6-310 '59-
(MIRA 12-*8)
(Cr7stallizati3n--Speed) (Slag-T3sting)

M&LKIN, V.I., kand.tekbn.nauk-; SHVARTSHAN, L.A., doL-tor khim.nauk
jci"~;
-
-~ -asuring the number of Ha+ ion transfer in sodium silicate
melts. Probl.metalloved.i flz.mat. no.6-.311--313 '59.
(MIRA 12:8)
(Ions) (Sodium silicates)

KALKIM, V.I., kand.tekbn.nau1q POKIDTSHEV. 7.T.; KHOKMV. S.F.;
--_-;__SHVAkTSMAN, L.A.. doktor lehia.nauk
Zffect of electric current paseed through a metal-slag baandar7
on the process of iron desulfuration. Probl.metallo7ed.i fis.
met. no.6:314-317 159. (MIRA 12:8)
(Cast Iron--F-lectrometallurgy)
(Des ulf ura t io a)

5(4)
A'OTHORS: Malkin, V. I., Pokidyshev, V. V. SOV120-127-6-30151
TITLE: Determination of the Relative Nobility of Alkali Metal
Ions in Silicate Melts
PERIODICAL: Boklady Akademii nauk SSSR, 1959, Vol 127, Nr 6, pp 1253-1255
(USS-R)
ABSTRACT: The present investigation was intended to explain the relation
between ionic radius and mobility for alkali cations. The ana-
1jel i was made by measurement of the Hittorf number in silicate
melts consisting of Me I O.Me II O-4SiO
2 2 2 (me - Li,ffa,K,Rb,Cs), and
the concentration change of the one cation was observed by
means of Us 24 , K42 , Rb 86 , or Cs 134 marking. The experiments
were performed at 12000 by using a corundum cell. Table 1
shows the measured Hittorf numbers, the radii as calculated
according to Pauling, and the coordination numbers. It was
discovered that with increasing radius of the cation there is
a tendency to raise the Hittorf number according to the les-
sened strength of the linkage of the cation to the anion of
Card 112 the melt. The raise of the Hittorf number does not proceed

Determination of the Relative Mobility of Alkali SOV/20-127-6-30/51
Metal Ions in Silicate Melts
monotonously. Not always does a great difference between two
radii of the cations correspond to a great difference of the
Hittorf numbers. The relative mobility of the cation is not
only influenced by the strength of the linkage to the anion
but mainly also by a geometric factor that is caused by re-
pulsive forces. This factor complicates the migration of a
big cation more than that of a small one. The interaction of
both these factors (strength of the linkage and repulsive
forces) causes a zigzag shape of the ionic mobility curve.
There are 1 figure, 1 table, and 12 references, 8 of which are
Soviet.
ASSOCIATION: Institut metallovedeniya i fiziki metallov Tsentrallnogo
nauchno-isaledovatellskogo instituta chernoy metallurgii
(Institute of Metallography and Metal Physics of the Central
Scientific Research Institute of Fe=cus Metallurgy)
PRESENTED: April 24, 1959, by G. V. Kurdyumov, Academician
SUBMITTED: April 22, 1959
Card 2/2

V.I.; POKIDYSM, V.V. (Moscow)
Mea4urement of cation transference numbers in N C-MgO-430, and
khim. 34 no 4. 05-808 Ap
"-SrO14SiC~ melts. Zhur. fiz N W.
(MIRA 14-5)~
1. Institut metaUovedeniya i fiziki metallov TSentrallnogo nauchno-
isoledavatellskogo instituta cherno7 inetallurgii.
(Ions-Migration and velociti)

MALKINg V.I.; MOGUTNOV, B.M.
Self-diffusion of alkali ions in silicate melts. Dokl..A-11
SSZOR 141 no..9:1127-1130 D 161. (MIRA 14:12)
1. TSentralinyy nauchno-issledovatellskiy institut chernoy
metallurgii im. I.P. Bardina. Predstavleno akademikom G.V.
'UrdyUmovyMjAlkali, metal silicates) (Diffusion)

MALKINp V.I. (Moscow)
Dependence of the relative ;aobility of cations on their
coordinate number ratios iii tbree-component silicate melts.
Zhur, fize khim, 35 no,2:336-341 F 161. (MIRA 16:7)
1e I'natitut zatallovedeniya i fiziki metallov TSentrallnogo
nauchno-issledovatel'skogo instituta chernoy metallurgii,
_(Silicates) (cations)

MAUINq V.I., kand.takhn.nauk
Mobility of ions and the acid-basic interaction in silicate melts.
Probl.metalloved.i fiz.met. no.7:522-532 162. (KIRA 15 --5)
(Silicates) (Ions-Mlaration and velocity)

RUUD, V.I.; MOGUTNOV, B.M.
Measurement of the transfer number of cations in a YiaD-~~
2 103
melt. Zhur.neorg.ldi~m. 7 no.9:2277-2278 S 162. (Y1IRA lrl,:9)
1. Institut metallovedeniyn. i fizi-k-if metallov i TSentralin-yy
nauchno-issledovatellskiy institut chernoy metallurgii Lmerd
I.P. Bardina.,
(Alkali metal borates)
(Ions-Migration and velocity)

3/032/62/028/003/004/017
B101/B138
AUTHORS. Malkin, V. I., and Mogutnov, B. M,
TITLE t Methods of measuring the diffusion coefficient in silicate
melts
PERIODICAL: Zavodskaya laboratoriya, v. 28, no, 3, 1962, 291 - 296
TEXTi This is a survey of methods published for determining the diffusion
coefficient in slags and other silicate melts. Tagging with radio-
isotopes and investigations of electrodic processes are mentioned. Equa-
tions are given for calculating the diffusion coefficient. The following
S;viet authors are mentionedt Han Chlih-yung, V, A, Grigoryan,
A, A. Zhukhovitskiy (Izvestiya Vyashikh uchebnykh zavedeniy, Chernaya L/
metallurgiya, 5, 5 (1961), 1~ A,. Novokhatskiy, 0, A. Yesin,
S., K. Chuchmarev (Doklady AN SSSR, 136 (4), 86a (1961), and Yu.P Nikitin,
O~ A.. Yesin, Ye. S. Vorontsov (Zhurnal fizicheskoy khimii, 32 (6), 1420
(1958). There are 1 figure and 59 referencest 20 Soviet and 19 non-
Soviet. The four most recent references to English-language publications
read as follows; T. Saitoi K. Maruya. Sci. Rep, Research Inst , T'ohoku
Card 1/2

S/032/62/028/00.z//O()4/017
Methods of measuring t'le- BIOI/B138
Univ , IOA (4)~ 306 (1958); T, B.
Temperature Processes. Reports
(1959); L- Yang a. M, T.- Simnad.
Temperature, Butterworth's Sci.
J- Henderson, L. Yang. Trans. of
(1961).
King a, P, J,
Df the Conference,
Physico-Chem,
Publications,
Metallurgical
Koros, Kinetics of high
New York, 80 - 61,
Measurements at High
London, 295 (1959);
Soc, of AIYF,, 221 (1), 56
Card 2/2

6M6 F.VIT(m)/EWP(t -TI IJOW JD/VV71/JW/1 VJ1JG
6bl3372* SOURCE CODEt UR/0370/661000/002/0166/0173,r~,
,.'--AUTHOR: ;:Malkln, V. 1. (MOSCOW)' Pokidyshav, V. V. (Moscow)
ORG; none
TITU: Determination of the thermodynamic activity of aluminum in N4-Al #,nd NI-AI-Cr
-alloys brtheclectromotive force method
SOURCE: AN SSSR. Izvestlya. Metally, no. 2, 1966, 166-173
TOPIC TAGS: nickel alloy, aluminum alloy, chromium containing alloy, free energy
ABSTFACT: In order to determine the Influence of chromium on the interaction of
nickel and aluminum, the emf method was used to determine the activity of aluminum
In alloys of the binary system Ni-Al in the concentration range from 0 to 25 at.% Al
and in the CL-Al section of the ternary system Ni-AI-Cr (8.38 at.% Cr, 91.62 at.%
Ni - 100 at.% Al) in the concentration range from 0 to 21 at.% Al. The experiments
were performed at 1045,'1090, 1135, and 11800K. A pronounced negative deviation from
ideality was observed in the alloys of both systems. The Work of formation of the
alloys and the magnitude of these deviations decrease as chromium is added to the
alloys of the binary eystem. The observed decrease In the Interaction of nickel and
aluminum In the presence of chromium may be due to the competition between aluminum
and chromium In giving up their electrons to nickel. The results obtained by the emf
1711

L 38968--66
ACC NRs AP6013372 kb
method are In good agreement with data on chromium vapor pressure measurements and
with the results of calorimetric measurements. Orig. art. bast 5 figures$ 3 tables,
and 10 formulas.
SUB CODE: il/ SU&4 VATEt '26Feb64/ ORIG REFt 004/ OTH REF: 003
Card

Lj 7 -1
ACC NR: AP6009427 SOURCE CODE: UR/0020/E,6/166/006/1390/1392
AUTHOR: Malkin, V. I.; Pokidyshev, V. V.
ORG: Central Sc;.entific Research I-nstitute of-Ferrous Metallu-rgy im. I.-P.--Bardin
Tsentj~`a-Vnyi__~_a ~_,chno -'1_S__S_i_~-d6v_aieiT!iFiy iiistlfu~ cyl~rnoyT
TITLE: Effect c,~C a third component added to nickel-aluminum alloys on the thermo-
dynamic propertie~,of the Y- and Y'-phases
SOURCE: AN SSSR. Doklady, v. 166, no. 6, 1966, 1390-1392
TOPIC TAGS: thermodynamic property, nickel alloy, high temperature alloy
jOSTRACT: The activity 4?f alumiy~niin the Y- and y'-phj~es of the Ni-Al ~)inary
system and the Ni-Al-Crl~,'Ni-Al-W I -Al-Cd'~nd Ni-Al-Fe ternary Systems 1-1,35 studied
by the errf metho- in the 10145-11800K temperature interval. The sum of emf of th,~
cobalt-aluminum reference electrode (containing 55-7007,) Al) and the test alloy char-
acterizes the work required for the transfer of aluminum from the alumin ...... melt into
this alloy. If -olid aluminum at the temperature of the experiment :'~; taken as the
standard state then the isobaric-isothermal potential of the dissolution of aluminum
in the alloy, where NA1 is the atomic fraction of aluminum, is defined by the
Card 1/3 UDC: 536.777

L 38224-66
ACC NR: AP6009427
expression
AZm = RT In am ~ RT In YA1 + RT In N,&, = -nEF - AS;a,(T - Tfi,), (IN
where n is the charge of aluminum ion, E is emf in volts, F = 23,060 (if AZA1 is eX-
pressed in calories), aAl is the activity of aluminum in the alloy, YAl :;-i the ac-
tivity coefficient of aluminum2 ASf is the entropy of the fusion of aluminum ? T9 is
the melting point of aluminum in OK, T is the temperature of the experiment in K.
In all of the systems investigated, extremely large negative deviations from the
ideal behavior were observed. These deviations decrease with an increase in temper-
ature, which indicates a strong interatomic interaction. This interaction is
greatest in the Ni-Al system, where the added third component increases the activity
of ---,luminum in the following order: Co, Fe, Cr, W. A similar sequence, character-
ized by the interatomic interaction in the _ystems upon the addition of the third
component, was also --Yserved in the partial ieats of solution of aluminum in alloys
of y- and y'-phases .'RThe effect of the third component an the thermodynamic activi-
ty of aluminum ~is related to the difference in the electronegativity of nickel and
of the added component. The greater this difference, the more effective is the
added third compnnent in increasing the activity of aluminum. &s the solubility-of
the third component decreases in the y'-phase the activity of aluminum in this phase
Card 2/3

L 38224-66
ACC NR-. AP6009427
increases. Orig. art. has:
Do
SUB CODE: 11,V/ SUBM DATE:
I
2 figures, 1 table.
OlJul65/ ORIG REF: 005/ OTH REF: 001
Card 3/3 &

SOV,1117-50 1-4928
Translation frc;m: Referativnyy zi-irnal. Metallurgiya, 195q, Nr _~, p 4 (USSR)
AUTHORS: Nosov, G. L., Malkin, V. M.
T IT LE: Heating a Two-layer Plate (Nagre,. dvukhsloynoy plas,inv)
PERIODICAL: Tr. Ural'skogo politekhn. in-ta, 1958, Nr 73, pp 198-~'06
ABSTRACT: The analytical solution of the heating of an unbounded plate (P)
consisting of two layers with different thermal characterisi1cs is
adducecl. The heat transfer onto one of the P surfaces proceeds
according to Newton's law. The ambient space has i constant tem-
perature. No heat is lost on the reverse side of the P (adiabatic
surface or plane of symmetry). The thermal charicteristics of the
layers and the heat transfer coefficient are assumed to be at their
medium values and independent of the temperature Cases are
examined when the temperatures of P are either eqUal at all points
at the initial moment or v,,ien each layer has its own L!-.ilia! tem-
perature.
G G.
Card 1/1

MALKIN, V.M., inzh.
Accurate and efficient shaping of grinding wheels on flat-surface
grinding machines. Vest.mash. 40 no.2:60-64 F 16o.
(MIRA 13:5)
(Grinding wheels)

-Tq-~j -"")
A-
tio 'T 'Y '69,
-M-a P- J.
~

j r,.rbri

Iv i,-tu .J;Fvz .."1 7- 1.-, -;% v 'Lgz

T,zrq v~

.99Z
-4v
P-

P- .01I.Tvv --14S

cq -- 0 a uo -. 0
-
1
:7
R
~
.01
.11M
-a
4l
0
rgz

-09Z
33FT-A -ivTivirw T-Tz;~iiFD 7.ta xxTH 'V
T-SMT~4-31 R ~UT57---ov
-e6a

wT.19 .611-~;=-Z T~oj--07~ xcTm -1 Lga
-Tq
voll-w J. m~4;o u.jjnT.S I-
c.T-l I=ol"
c.T;" -99a
'q,z ' ;Q
I-T*17 -'43 M --T.; -3 %--S 96 'uv I-r-ka -1 "Ke
wll-l-~-): jo owag.Q q%
jo u.7 I
-,z;Ta
'usm
P-lu .... 6. lj~d.g

,M ; TIMOFMVg V. N.; SHKL&~ F. R.
MALM, V
Tempdrature field of a plate during the ragenerative,beat
exchange process. Sbor. nauch. trud. MIMT no.8:5- 162.
(KM 16-- 1
(Beat-Transmission)
Ir

TIKOFEYFIR V. H.; MALKIN, V. M.; SHKLYAR, F. R.
Theory of regenerative heat exchanger design. Sbor. nauch.
trud. VNIIMT no.8:16-32 162. ZM--I-RA 16:1)
(Heat exchangers-Design and construction)

MALKINY V. M.; TIMOFEYEV, V. N.; SHKLYAR, F. R.
Developing wthods for the calculation of regenerative beat
excbangers.'Sbor. nauch. trud. VNIM no.8:4,1-67 162.
(MIRA 16:1)
(Heat-Transmission)
(Heat regenerators)

MUZIN V M,
Unstead~r heat exchan-ae in a fluid with laminar flow. Sbar. nauch.
trad. VNIIMT no.8:106-118 162. (MIRA 16: 1)
(Heat-Transmission) (lemi- flow) Ir

SERLYAR, F. R.; TIMOFMV, V. ff.; MALKIN, V. M.
Experimental inveattgation of beat exchange coefficients r',
during the regenerative heat exabangs proceeis, Sbore nauche
trud. VNIIMT no.8tl62-177 162. (MIRA 1611)
(Heat regenerators-Testing)
(Heat-Transmission)

SHKLYAR, F. R.; N v M
MLm-nL--L* 1-10
Galculations of a blast ftumce air prebeater with variable
air flow. Sbor. naueb. trud. VNIIMT no.8:178-196 162.
(MIRA 161l)
(Blast furnaces) (Air preheaters)

TIMOFXM# T. ff.; SHUZAR, F. R.; WHTANOVA, S. P.; KAMM. V. .
9
Methods of calculating heat regenerators for industrial
Aumces,, Sbora nauch, trude VNI3MT no.8tl97-228 162.
(KRA 16: 1)
(Heat regenerators)

SHKLYAR, F. R.; TIKOFET.EV, V. N.; M~~t- V. M.
Methods of calculating blast furnace air pmheaters. Sbor.
much. trud. VRW no.8:229-245 162. (MMA 16: 1)
(Blast furnaces) (Air preheaters)

)ULM V - SHRUAR, Fe Ra
2 . Hot
Simultaneous blowing operation of two air preheaters. Sbore
naueb. trud. MIMT no.86-259-277 162. (MIRA 16:1)
(Blast furnaces) (Air preheaters)

SHKLYARO F. R.; TIMOMEV# V. NO; MAWNP V.--M*
Se3actinC optima the I rates for air preheater operdtions.
Sbor. nauch. trud. VNIIMT no.82278-288 162. (MIRA 1691)
(Air preheaters)

--N,,,_SHKLYAR,, F. R.,
HATMN.,-L -
Temperature distribution in solids of rectangular shape 4
under linear boundary conditions and internal over-all
sources of heat. Sbor. nauch. trud. VNIrAT no.8:495- 4 162.
(MIRA 16:1
(Solids) (Heat-Conduction)

MLEIN, Ya.
r
Verifying range finders of cmaeras.
S t58.
(cameras)
Sav. foto 18 w.9-.44
(WRA 11:10)

137-58-4-6769
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 4, p 66 (USSR)
AUTHOR: Malkin, Ya. I.
TITLED Anniversary Note on the Personnel of the Chimkent Lead Works
(Rabotniki Chimkentskogo svintsovogo zavoda k yubileyu)
PERIODICAL: Byul. tsvetn. metallurgii, 1957, Nr 19-20, pp 61-62
ABSTRACT: The achievements scored by the personnel of !he plant on the
occasion of the anniversary are noted.
l.. Metallurgy--USSR 2 Personnel--CitaLicns
Card 1/1

INSTRUMENTATION: CLOUD CHA14BERS
"Method of Scanning and Measurin_- Cloud-Chamber Tracks", by Ya.P.
~Ikin, Tbilisi State University, Pribory i Tekhnika Ekspei~ yenta, 14)
3, Noveriber-December 1956, pp 42-43.
The advantaCe of the meLhod proposed in this artirle f,~ the p,c;ul-
bility of viewing a steroscopic ima;-e simultaneously by severai in-
vestigators, using three-dimensional proje-tion in polarized ILJlt.
kpparatus and a measurement procedure axe described and re~;_,I'Ls are
cited.
Card 1/-I

Z 4 ~:
i~
j~AIIM, A, T-nt,
ava za 8~-w'f
I'L

co lg!~ liW; I:" OIL

- --------- --
Aw

136-8-9/?l
AUTHORS :Malkin, YaZ.,_x Sergiyenko, V.Ya., Yudelevich, I.G.
TITLE: Production of High Purity Lead (Polucheniye svintsa vysokoy
chistoty)
PERIODICAL: Tsvetnye Metally, 1957, Nr 8, pp ,.44-51 (USSR)
AJ3STRACT: The authors describe a systematic investigation to
secure the industrial production of Ligh-purity lead in which
the concentration Rf 25 elements is controlled so as not to
exceed 10-4 to 10- %, the maximal concentration of silver,
copper and cadmium being 2 x 10-5, 10-4 and 10-4%, respect-
L
ively. They give analyses of lead after repeated e'ectro-
lysis in an industrial (Table 1) and a purified electrolyte
(Table 2), and describe t1ae scheme used for removing silver
and cop- (Fig.1). Changes in process conditions and im-
per
purities-co nc entrat ions during the refining of lead are shown
graphically (Fig.2) and impurity levels in lead obtained by
pyrometallurgical refining of cathodic lead with and without
repeat electrolysis are compared (Table 3). Rapid analyti-
cal methods developed for production control are described.
It was shown that by using pyrometallurgical refining of
Card 1/9

136-8-9/21
Production of High Purity Lead.
cathodic lead with and without repeat electrolysis , lead of
the required purity could be obtained in an industrial in-
st all at i o n. The expe riment s al s o s howed t hat f or remov ing
silver and copper it is better to use metallic zinc and
elementary sulphur simultaneously than separately. Sh.I.
Peyzulayev, A.T.Shamova, N.Y.Vovtuta and T.V.Dembnitskaya
articipated in the work.
K
ere are 2 figures, 4 tables and 5 references, 3 of which
are Slavic.
ASSOCIATION: Chimkent LeEd Works.
(Chimkentskiy Svintsovyy Zavod)
AVAILABLE: Library of Congress,
Card '31?

P,
136-10-1?/"13
AUTHORS:Malkin, Ya.Z., Sergiyenko. V".Ya., Bovtuta, lt.v,
-71-laelevich, I.G.
TITL21", Extraction of Tellurium from Some Lead-Industry Products
(Izvlecheni.ye tellura iz nekotorykh produkt3v svintsovogo
proizvodstva)
PERIODICAL: Tsvetnyye Metally, 1957, Nr 10, pp.80-87 (USSR)
ABSTRACT: The authors desaribe results of work caarried out at the
Chinkent lead wcrrks with the object of finding the concen-
tration of tellurium in various materials involved in lead
production and of determining methods for its recovery. The
concentrates received at the works have 0.005-0,70CK/a Te and
the distribution of the element in different products (Tables
1 and 2) showed that some contained increased-concentrations,
particularly alkali skimmings from the oxygen refining of
bismuth. A method for recovering elementary tellurium from
these is described; and it is shown that the element can also
be recovered from slag from the melting of sodium antimonate.
Details are given of two new spectroscopic methods developed
for determining tellurium in lead (1-0.006%), bismuth (1--
0.003%)r tin(1-0.01%) and antimony (1-0,005%) and also in
Card 1/2