SCIENTIFIC ABSTRACT MIKHANTYEV, B. I. - MIKHATSKIY, YU. V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001033920018-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 12, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Vir.@'Ilaticn @A ,c, tr m-,-
t
Ll
r
AJ UC IA ICI: Voronezh State University
A V,'- I LA:3 L'--'tL r"
1. Monoacetone-1--Glucose-Virylation
Card 21"

TM,'NS: Viikhantlyev 3 1 PIr akhina, E. A. 156
TIT LE The Synthesis of Ethyl, Isopropyl and n- '--ro I ly" -
-IC (
, -tal (.;intez etil-, izopropil- i n-nropil-1-metilallil-
ataetaley)
rl;.:: TODICAL - Nauchnyye doklady v.ysshey shkoly, Khimiya i
hn o I :,!Iiya, 1 13, pp. 5 5 0 - 'US SR
;.7@'T'RACT :-,ie authors invfm:@t iga ted the in terac t ion bpt-i@pn th,,,,l -
j@lcohol with vinylethyl-, vinylisoproryl- an,I vin. 1 -n-pro-
pyl esters in the Lresence of acils acting as catalysts,
inorropyl and n-propyl-a-methylallylacetal. are prolu7el in
a yield of 1,0-80 @;% The following synthese@ were rnrr,,PI
out: the synthegis of e-thyl-or-methylallylacetal with
ing point 59-41 C, d 20 = 0,8351, nD2o = 1,4G50, in a -;-ld
4
of 77,7 @',; the synthesis o" isoproi)vl-a-metli:;I~,11,iia,~-~'taI
with boiling, point 52-53 0C, d 20 @ 0,8315, nD 20 = 1.4067
in a yiel.,I of 100 '/,; the !rjnth si s Of n-prop@l -a-methylal 1 v!
0 0@' . O@ 0'
:icetal with a boilintr point at @@ -65 1 d F"5r-,g-,
20 )7,3 - 97,7 'P'-ie @,ydrat 1 )Y,.
nD 1,4096, in a *vielI of
,a r -1 1 2 ni' the acetal was calried out on a nickel skeleton catalll.@3T.

S07 156
lso@ro-jl ;@Pil n-.
"Iv? ,nthpsis ol" Ethy l Pro yl-a-Methyla 1-i a
i ch firo 3ov i e t
I Kafedra i v,,, ,2 o k orn o- e k @ i I v a rny oy
',ia i r for trke @f trli Compo@,r.,Iq
iioronezh @;tate Un;versity@
_.-OY 'MED: January 17, 1))8

AUTHORS: M-' . k han t I y ev, B. Pa V" I e -

TITLE: The Cyclic Acetals of the Isr-rrpric Hydrn Benz-irll
(.slkl,@-!@Pskiyc- a@setali izomernykh gidr@)benzoinov,
PERIODICAL: Nau@-Iinyye dc)k-*EiJy vysshey shKo-'@,. Khimiya -cnimicheska,-a
t. ek hn o - cg-,
ya, 195e, Nr 4, pp 157-758 @USSR'
ABSTRACT: In the in*eractior. of meso and rac-Ahydro benzoin with simple
viny" ester, cyc-:4-,-, acetals @mesothydro benzoin acetal and
rac. hydr, benzoin acetal) are formed. The syntheses of the
-in'tiq! pr3d-@ta of rac. hydro benz-ir. w@'th a yield of 45-50%
and me-3(-. hyd-D benzoin with a y"eld of 37.5% are described in
detail. The elementary analysis of the cyclic acetals was
carried out and the empirical formula was given. During
hydrolysis the acetals are converted into the initial hydro
benzoin. The cyclic acetal of the meso hydro benzoin was
prepared in a y-'s,'J of 70.8%. After a double cryntallization
from aicohol,cycli,: ace--.a'- was separated in the form of fine-
need"Led crystals. The crystals have *their melting Fjoint at
43-5-44, bc4ling point at 103-104oC and refractive index

Card 112 20 20
nD - 1.5',162, density dD _ 1.1021. The c@,mpo-,nd is easily

The Cyc'j- Acetals of the Isomeric Hydic Benzoins
SOVI/i 56-1.8-4-37//49
so @.@b -e ester and alcohol, insGluble in unstacle
in air. The preparation of the Cyclic acetal of the rac. h_,,-,Iro
benzoir, gave a yield of 22.8%1 it is colorless, scentleas and
liquid. The boiling point is at 1C'.)-106'-C FAnd the refractive
20 -and mixes wi-h ordinary organic
index
is @-D -570. The r@.@mpo
sclvents and decomprsqa r. u.r. There are 8 r,-ferences, 4 of
whlrh ar@-- 3-,v;et.
ASSOCIATION: Kafedra khimiJ vys.-k,mc@lekuyarnykY, soyedinen.y Voronezhskogo
gr,s-Aarst-,r,-nn"g-,, unversiteta "Chair )f Chkm-9try of the
Compo%inds .,f Higi, M-e-lar Weigh,. at the Voroneah State
TJ n --* .- e r s i t y )
SUBMITTED: i @i ra.;-, --Y 19:, 9
Card 212

AUTHORS: M--Kt,ar., lye. E.
TI -, LE The, r_ th, r,? A Car b c- n
A,.: - zi ar @ I -,'n t@ 1 n
ef-' -a RK r k L 'K S - V "F, nY e.
PERIODICA,,: N au - h n i i k a (4 yY b F, hk. @ie - . v . ir - v u kt-.,M,
'Y
Y@l 1 1 1"9-760 @usa
,kBSTRACT: By -,y a fa J' r @,mpr- @r 13 ny 1 e3ters of the arrilire-
- @18
a.- Ei ft r. 41 t " ' r @,.T P Y I d 3 W3:-P rrepared. Thr@
preparat . ,n *f,@ , ' 'I . r w as ar r - e d o.t ac,-@rlLng h e
method dpve - cped oy Faii,:,r-,K. -S-,riostELkuwsk-' \'Fa%crskiy-
Shostak,-vsk-y') at 1800 -Irder a press-@re --f zG atm-,spheres. Phe
yl@eld I a 24%. Thn ump,,-;rid y C t r,
Denzer,e, - rher organ: s-,jvc-r,*
me rg p3-n Qa, ',"
C ln-mp-et@- a@ylal -f hr d
n Y I esT@:- was @y-lloh-txane in th@ ref'-x
t " arr.ffj;j . r
. @ 11 - " . , :,t a Y ;I M Y @w , I!A -,v h tv; tint
t I , - .1 r@ @ - , % I . v, an J s 9 ar,d fip @mp,,,i w hpr, neat ed
The y ; --2 11 . s ' @1/6. T he e -m,@ r. i::.y anall y @, - gav f c - -jv I ng
Card 11 2 Ir : I Ir I -j : C 25 H - 0N. rr.,- 11,,j naS 'r- f-, @ -,,-x -r.aracter-

SOV 11 156-58-4-58/'49
The Prepara-lon of the Vinyl E3ter of the Acridine-@-CarbonJc Acid and
Their In,-omplete Acylals
20 20 Th e -coap I ete
istics: n 11.1,381 d 1.051 ME = 1C5.91@.
D 1 4
flcyial of th,3 nompoood vinyl oBtor of the acrildine-?-carbonic
acid witr, heptanol was prepared in a yie'-d of 50%. The acyla-'
is a light g--Pen liquid with a strarg odor. The empirical
formula is C, H O,N and has the following characteristics:
n20 = 1.2 23 27 .1 L;
D , " I 14@O - 0 - 7..) MR - 92.C. Ther@-- are 2 Scviet references.
ASSOCIATION: Kaf olra vysrkomc)'cki.,1yarn-.y kh,-mli Vorcnezhgkoge, gosudar9tvOrl-
nogr, (Chair -)f Chemistry of Highmoleculars at
t h P V State University)
SUBMITTED. hjgjr@-@. 2,-
Card 2112

A. U 7 11C R 'Ai khan-t_'-yevJ B. I., Dootor of Chemical 3ciences r,- fessor,
_Tn_@FvW@s i ty 'iec to r
TITLE: The Opinion of the University 7taff (Mneniye kollektiva uni-
versiteta;
PERT-@!CAL: Vestnik vysshey shkoly, 1Q59, 'Ir '11, pp 25 - 27
AB'ITRACT: 9aving discussed N.7). Yhriishchev's report to the TsV Yresi-
dium of t',e Kr73, the staff of the Voronezh University came
to the conclusion that a thorough reorganization of its
educational and scientific activit7 is necessary. in re-
cent years the number of st,idents -rith practical experience
is steadily increasing. In 1957, they comprised 40 @ of
those admitted to the University's regular day-time depart-
ment, and this year 6C V. Beginning with 1959, it will be
possible, and necessar ,7, to enroll into the Voronezh Uni-
versity only production workers. 7xceptions should be per-
mitted only in respect to outstandingly talented boys and
girls. The age of admittance is 2" to 35 years, and for
those coming direct from school - over 19 years. The eve-
ning and correspondence departments should adopt the same
principles. The 8-month preparatory courses for production
workers and demobilized soldiers are of considerable import-
Card 1/2 ance and should be somewhat enlarged so as to accomodate

The @-Jpinion of the University Staff 30V/@-58-11_9/36
300 students. Admittance should take place on recommenda-
tions from public organizations. 9tationary education at
the university will last 5 years. The author gives further
details, in respect to scholarships, practical training,
future employment, and payment of grants to all students of
the 5th and 6th course. He comments on evening and corre-
spondence edocation and on the necessity of a 3 year period
of actual work in @,is speciality, before the graduate pre-
pares his graduation thesis. The author suggests that at
the same time the student gets his marks on his academical
progress, his participation in social activity should also
be discussed.
ASSOCIATION: Voronezhskiy gosudarstvennyy universitet (Voronezh State
University)
Card 212

AUTHORS: 11.:ikhant I-J-ev, B. I., Pavlov, L. P. 7j-2-4),'64
TITLEt Vinjlization of HJarobenzoin. I(iinilirovaniye pidrooenzoi:.R.J.)
PLRIODICAL: Zhurnal Obsncaey Lhimii, 1958, Vol. 28, Nr 2, r-P.
ABS'."RACT: The major part of the more .9iui,-,lt: vinylether.i is obtained ac-
cording to A. Ye. Favorskiy and ;,I. F. Shostakovskiy (ref. 1).
The vinylization of fatty aromatic and aromatic alcohols with
some hydroxyles is less known. The present paper shows a syn-
thesis of mezo-u,al-divinyldioxydibenzyl from acetylene and
hjdrobenzoin hitherto not yet described in technical litcrature.
A direct vinylization was carried out in an autoclave, at a
maximum pressure of 6o atm. and a temperature of 130-1350C for
6 hours. The hydrolytic oxymation and the quantitative hydra-
tion of the product obtained indicated two vinyl group3.
Mezo-u-al-diethoxydibenzyl was obtained from the product by
hydration in the presence of nickel. There are 5 references,
of wnich are Slavic.
ASSOCIATIOII*: Voronezh State Unimraity (Voronezhakiy gosudart3tv'L!:.@','*y
aniversitet)
Card 112

82579
S/08l/6()/00,0/-@,-X/0C8/XjE
AC06/A00 1
15-- 3 YJ
Translation from: Referativnyj zhurnal, Mimiya, 1960, No. 6, p. 664, # 25205
AUTHORS: Mikhant-'yev, B.I., Sklyarov, V.A., Fedorov, Ye.I.
TITLE: On the Polymerization and Copolymerizatlon of Vinyl-n-Buty! Esterl
PERIODICAL: Tr. Voronezhsk. un-ta, 1958, vol. 4), pp. 41-44
TEXT: Polymerization of vinyl-n-butyl ester (:) under the effect of PeC13
at 80-900C and 50-700 mm Hg pressure (P) entails the formation of a polymer with
a molecular weight (M) of 14,200. 1 is easily polymerized in n-C4HcjOH and
(CpHr,)pO solutions under the effect of BF (temperatures (t) -30C, P 760 mm Hg,
M 6400). Copolymers of I with divinyl ( 2) were obtained under the effect of
BF (P 760 mm t -50C, m io,4oo). The copolymers are soluble in (C2H5)20,
%@ , benzine: CC14, CHC13 and are not soluble in (CH3)2CO, acetoacetic ester, and
dioxane. At 1800C they darken, harden and become insoluble in organic solvents.
Copolymerization of I and II under the effect of FeC13 and P205 does not take
place to a noticeable degree. R. Mllyutinskaya
Translator's note- This is the full translation of the original Russian abstract.
Card 1/1

5 (3)
AUTHORS: Mikhantlyev, B. I., Fedorov, Te. I. SOV/153-2-3-15/29
TITLE: Synthesis of Vinyl Pyridone and Some of Its Derivatives
PEnIODICAL: Izvestiya vysehikh uchebnykh zavedeniy. Khimiya I khimicheskuyu
tekhnologiya, 1959, Vol 2, Nr 3, pp 390-391 (USSR)
ABSTRAM By vinylation of 2-pyridone with acetylene the authors synthesized
N-vinyl-2-pyridone. This reaction was carried out under pre83ure
at 145 - 1500 in the autocluve.' Dioxane was used as solvent, the
duration of vinylation was 6 hours. The product obtained yields
N-ethyl-2-pyridone in the catalytic hydrogenation. The working
conditions In this ;gnthenis were the followings hydrogenation
during 2 hours at 1and 300 torr pressure with the use of a
nickel catalyst. N-1,2-dichloro ethyl-2-pyridone was obtained by
chlorination of N-vinyl-2-pyridone in carbon tetrachloride as
solvent. Moreover, the authors synthesized N-vinyl-5-Br-2-
pyridone by the action of acetylene on 5-Br-2-pyridone. Dioxane
was used as solvent, the reaction was carried out in the auto-
clave at 150-1600. These four syntheses are described in detail
in an experimental part. rields, compositions, and physical dats,
of the products obtained are given. There are 7. references,
4604-42 2 of which are Soviet.
Z4
Ld

S/ 138/59/ ooo/ o i o/ooVo ij
AOIIWA02@0
AUTHORS. Mikhant'yev, B.I.; Rayevskiy, A.B.
TITLE: The Divinyl-3tyrene W-Polymer
PERIODICAL. Kauchuk i Rezina, 1959, No. 10, pp. 24 - 27
TEXT-i The mechanism of&)-eolymerization Iwas studied. In this connection
the initiating stage is of particular interest. The reaction mechanIsm was Inves-
tigated at various ratios of divinyl to styrene in the absence of peroxides or
triggers and at various temperatures. The effect of different amounts of hydro-
gen peroxide and elementary oxygen on the W-polymerization was also studied The
experimental procedure is outlined in detail and the results of the investigation
are discussed. By making a comparative study of the W-polymerization rate with
and without trigger (Fig. 1), it was seen that the reaction in both cases takes
several hours, whereas the difference in the induction period is 240 hours- It
is concluded that the extent of the induction period depends mostly on the pro-
cesses which lead to the formation of the6)-polymer nucleus. As soon as the nu-
cleus appears in the system, the rate of the reaction progressively increases and
shortly after it almost all the monomers are converted to the(J-pol'ymer "@-Po'y-
Card 1/3

S/138/59/000/010/005/01')
The Divinyl-StyrenetJ-Polymer A051/AO29
mers are formed simultaneously in the system, which can be seen from the Increase
In viscosity and by the presence of benzene-soluble products in theei-polymer In
the experiments with triggers the induction period can be explained by the effect
of traces of oxygen, namely, If the polymerization is conducted in an atmosphere
of elementary oxygen the induction period becomes twice as long. The temperature
coefficient of the reaction rate was computed from the difference of these rates
at temperatures of 30P 50 and 700C. The formula
1/77
f _7_2
is derived, where Y is the temperature coefficient of the reaction rate, and Vi,
V2 are the rates of polymerization. Several conclusions could be drawn from the
experimental results: 1) The optimum ratio of divinyl to styrene for the W-poly-
merization at 500C in the absence of a trigger was found to be 0.17 mole/mole. 2)
The temperature coefficient of the(O-polymerization rate in the presence of a
trigger was found to be 1.70. 3) Molecular oxygen increases the induction period
of the W-polymerization by a factw of two, without affecting the rate. 4) Isoprt>-
pylbenzene hydrogen peroxide, at U.1 weight % quantity, does not noticeably af-
fect the W-polymerization. With a further Increase in the concentration, the rate
of polymerization decreases. There are 5 graphs, 2 tables and 14 references- 6
Card Z/3

The Divinyl-Styrene(A)-Polymer
Soviet, 6 English and 2 German.
S/138/59/000/010/005/010
ASSOCIATION: Voronezhskly zavod 81nteticheskogo kauchuka (Voronezh Plant of 3yn--
thetic Rubber)
Card 3/3

AUTHORS: M i @ t_m. !I. Pryrik@.'r.a, A.
TITLE: Syr. t)@ i F f a-. i
an -1 C A -
f

? SRI, Ll D1 " A y k N r
ABSTRACT: c f t" ra, hav
I
fa: H
ovt, i-,:
r + r ri",f Thp
he S., i :f a,@ 3
'h.-i-s ac,-cri,nE tr, %g
s r, F- 'T, -
H MCHCH
OH C
-
CHOR--'
H
H " OR
C H P
C
, C
CF1,-C5-- CHCH,
T
R C,B, 1 '.-C H s
' C H n c H an d s -C H,
7 49
T tp
P x Ke m say. '10% i 1 a-,
waq 9@ T i@, s3Tr p',
L ard -.i -1@r Y r Y ;@ a -eta
Card /2 ar@ r-@!_ j Th-

SOV, 29 -
f E,
Cr-- tyl A - t;@'
1 f. - 7
ASS@CIA7.'C'N. V
'J,-
S7BMiTTED: N.
Carl e,'2

50) SOV/79-29-4-41/77
AUTHORS; Mikhantlyev, B. I_ Pavlov, L. P.
TITLE: Synthesis of a-Vinyloxydibenzil (Sintez a-vinilokoldibenzila)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 4, pp 1230-1231 (USSR)
ABSTRACT: In the vinylation of hydroxy compounds of the diphenylethane
series with acetylene by the method. developed by A. Ye.
Favorskiy and M. F. Shostakovakiy (Ref 1) the authors obtained
the vinyl ether of a-oxydibenzil (of phenylbenzylcarbinol) (I).
It was found that the affiliation of acetylene in the presence
of cauo@ic potash takes place at a satisfactory velocity at
160-170 - As a by-reaction at this temperature the water splits
off from a-oxydibenzil, and stilbene is formed, as had already
been pointed out in previous publications (Ref 2). Vinyl ether
and the ethyl ether of a-oxydibenzil (II) obtained from vinyl
ether by hydrogenation over the skeleton nickel catalyst decom-
pose, like the initial alcohol, during normal distillation as
well as when heated with a 20-30% sulphuric acid solution. In
either case the stilbene yield is satisfactory (Refs 2-4)
Card 112

Synthesis of a-Vinyloxydibenzil
SOV/79-29-4-41/77
/_@_ - 2
CH CH CH - CH
D 1 2
OCH CH 2 OCH 2 - CH 3
The experiments carried out 80 far proved the capability of
a-vinyloxydibenzil of polymerizing under the influence of the
ether compound (CH 3)2 0 - BF 3 (---w denotes the semipolar bond)
into viscous and solid resins. Ethyl ether can be easily bromin-
ated. During this process hydrogen bromide is removed. Thus
a-vinyloxydibenzil was synthesized from acetylene and a-oxydi-
benzil, and a-ethoxydibenzil was obtained by hydrogenating the
former. There are 6 references, 1 of which is Soviet.
ASSOCIATION: Voronezhakiy gosudarstvennyy universitet (Voronezh State Uni-
versity)
SUBMITTEDt March 1, 1958
Card 2/2

5 (3)
AUTHORS: Mikhantlyev, B. I., Fedorov, Ye. I., SCV/719-23-t-'@/"
Kudherova--T.-T., Potapove.. V. P.
TITLE: N-A-Ilyl.-pyridone--2 and 2-Alloxy--pyridine and Their Hydrogena.
tion Products (N-Allilpirldon.-2 i 2-alloksipiridin i prndukty
1kh gidrirovaniya)
PERIODICAL: Zhurnal obahchey khimii, *?59 Vol 29, Nr 6, pp '874 -- '875
(USSR)
ABSTRACT; A. Ye. (Ref 1 ) synthesized the N-allyl quinolone-2
by reaction of the potassium salt of quinolone--2 with allyl
bromide and tried to synthesize the 2-alloxy-quinoline from 2-
chloro-quinoline and sodium allylate. The 2-alloxy-quinoline
however was transformed by distillation under normal pressure
into the N-allyl.-quinolone.-2. Considering the eimilarity of the
chemical properties of quinolone-2 and pyridone-2 the authors
tried the analogous synthesis Pa the basis of the 6odium salt
of pyridone--2 and obtained the N-.allyl-pyridone-2 (I). By re-
aotion of 2-chloro--pyridine wi*h %odium allylate the 2-alloxy-
-pyridine was formed (11). In order to avoid tht, isomerization
of com ound (II) into the N-allyl--pyridona-.2 the product was
Card 1/2 diatilfed from the r-@actior@ mixtire in the vacuum (-,5mm).

N-Allyl-pyridone-2 and 2-Al'L,-xy- -yridin@3 anl h-. .@-20 "2
Hydrogenation Products
The hydrog-@?natj on --f N-allyl pyridonp. 2 and ?loxy -pyr, dine
on the skeleton-nickal -atalya-l yielded the --orre5poiiding 11-n -
-propyl pyridone-2 (III) and 2-propoxy-pyr,.dine. @.IV).
0 @@)CH .-CH-rH Y' H -n
2
N --CH .,H-CH 11 11 -C R.- -n IN
2 2
W
There are 3 referen,@ea.
ASSOC IAT ION: Voronezhak.y gosudarstvannyy universitet Statp
University)
SUBMITTED: May '5- 1@9e-@
Card 2/2

MIKRANTOYEV, B.I.; WASOVA, A.V.; SKMAROV. V.A.; FMOROV. Ye.I.
Acetals. Report fio.2. Trudy VGU 57:177-187 159.
(KIR& 13*5)
(Acetals)

MIKHA, liT'TL'V-,-B".
Syntheses and some conversions of vinyl others and vin7l eatera.
Trudy VGU 57:18(@-201 '5 9. (KIRA 1):5)
(Ithers) (Estors)

MIKHASTI-MV. B.-I.
Part played by A.Z.Favorskii in the development of organic
chemistry. Trudy VGU 57:20)-209 '59. (14IRA 1): 5)
(7avorskii. Alel-nei Rvgrafovich 1860-1945)

PHASE I BOOK EXPLOITATION SOV/5225
Mikhantlyev Boris Iyanovich, Aaato]Ay Yakovlevich Shatalav,and Igort
---ur-n 164 -
Polimery - novyye korrozionno-stoykiye materialy (Polymers; New Corrosion-
Resistant Materials) Voronezh, Izd-vo Voronezhskogo univ., 1960. io6 p.
5,000 copies printed.
Scientific Ed.: I. Ya. Klinov, Doctor of Technical Sciences, Professor
Ed. of Publishing House: G.F. Biryukov, Tech. Ed.: M.V. Novikov.
PURPOSE: This book is intended for teachers in higher schools of education. It
may be used by chemical engineers and techniciann of plant laboratoriesv tech-
nologists and foremen, as well as workers who are interested in improving their
skills.
COVERAGE: The book reviews the causes and types of corrosive destruction to metals
and alloys exposed to external conditionsP and discusses methods and means of
replacing nonferrous metals and alloyed steels with new corrosion-resistant
Card 1/3

Polymers; New Corrosion-Resistant Materials SOV/5225
materials based on synthetic polymers and natural and synthetic resins. The
main poicochemical properties are given for the structural pl"tics which
have received wide practical application in.the national econany, and especially
in anticorrosion engineering. No personalities are mentioned. There are 68
Soviet references (including 2 translations).
TABLE OF CONTENTS:
Organic Synthesis in Oe Service of Metallurgy
Diseases of Metals and Methods for "Ibeir Prevention. How and Why
M--tals Corrode 8
Physicochemical Properties of High-Molecular Compounds and Methods of
Processing Them 18
Co--rosion Resistance of Polycondensed Plastics
32
Card 2/3

S/138/60/000/002/002/OOQ
A051/A02)
AUTHORS: Mikhantlyev, B.I., Rayevskiy, A.B.
TITLE: The InhibitJon of w -Polimerization\\
PERIODICAL: Kauchuk i Rezina, 1960, No. 2, pp. 3 6
TEXT: The nature of t-,-polymerization is little known The divinyi
V
styrene -polymer, which is formed in the production of rubber by the emul--
sion method, is harmful. since it clogs the apparatus and causes a break-
down in the equipment. It is stressed,therefore, that the development of a
method for the prevention of Lj -polymer formation is of great practica'
significance. The authors used 3ulfxir, polysulfide of sodium, n-ox@,aiph.n_
ylamine, quinone, hydroquinone and isopropyl benzene hydroperoxide as in
hibitors. It was found that hydroquinone inhibi"sLo-polymerization 2 to 4
times as effectively as quinone. Elemental sulfur in a 0.05% dosage in-
creases the induction period of the (--polymerization by a factor of 2 An
aqueous solution of polyBulfide of sodium, after dilution or processing
with air, is a good inhibitor of w -polymerization, N-oxydiphenylamine in
hibitB ci -polymerization well. The induction period increases 8 times with
Card 1/2

S/1@8/60/000/002/002/00j
AO5'/AO29
The Inhibition of w-Polymerization
a dosage of 0,01@4 of the latter. Since the porous polymer is formed in the
production apparatus in the presence of water or perhaps oxygen, the ex
periment was directed at a study of the inhibitors in the presence of these
latter components. The authors previously pointed out in Reterence 4, that
oxygen increases the induction period of the ,,-polymerization consideraoly
In the present work the behavior -,foxygen introduced into the system at the
end of the induction period was also investigated and it was noted that it
does not inhibit theLi-polymerization in this case As a result of the ex- J
periments the authors conclude that sulfur, sodium polysulfide and n oxy
diphenylamine can be recommended for use as inhibitors of ,J-polymt-ri7ation
in industry. There are 6 f ig,.i-r- tables and 4 ref erences 1 22 Soviet and
2 English.
ASSOCIATION: Voronezhakiy Gosudarstvennyy universitet 1 Voronezhskly zavod
sinteticheskogo kauchuka im. S M Kirova (Vor -onezh State Uni
versity and Voronezh Synthetic Rubber Plant imeni S M _,Kirov)
Card 2/2

5C I 1@ /BC
ALMIC RS: L V L
T 1 T LE: A I
PERICDICAL: ,,A-dur-y- Y!
6 V
T EXT: The a,Ath,rs rtq t-l
.he prc-rgr,--F- H-5-, mi@ -i
tw, a-
P: I
s,- a nd
a (71 f a I s T a wus i, r -Au - @d -1c h u at .r.
c) n - hil t Ft I h c r" m 1- @ nd
Tr i a -s,, - -.r 1-i
-n cf
rard 1/2

--n f M, r /o /xx
)ca Wilh All h ELr A
f -plF,
sir th-s f r -,n f r! y
o a 7 t- r.
r
r
a's f7173. '.ranspir- -
i . r
d s r t r o m . r. e w q 7 T r r- Ei t r@ 5 -rrl r . -rr
I as al u I at.ed anl t e - a g a r,. e s
ASS OC I AT I ON V - r -, n s i,. r J - T. rs d ra K h
Vy K ff K y k y I r@r. . V,@ S a 7'r
-,j @i r t
SUBMITTED; rl

.@fj

f I f
12. 7 0.02'st; .19 4fl,
7@ 1 7 111 1;11., m IMM
14.1 ti 7

r-
1.36,c
AUMORS: Mikhant'yev, B I - Ff--dur--)v, E. 1.
'789C
TITLE: Allylation cf Aminc and Bromoamlnopyr,.dines
PERIODICAI,: Zburnal obshchev kl,imi@, 1)6c, Vol 3- Nr C,
ABSTRACT: Aliyl chioride renc'Ls wi!-@. 22-sudilum lerllv@A-vt!s .1
5-bromo-aminopyridine, and 3,@-dlbromu-amlncpyrld'ie, fC'rTr-4r'g
ponding 2-allyi-aminopyridine (1), 5-bromo-2-al iy lam-,riopyrillne
and 215-dibromo-2-aily.Laminopyridine (III).
,Nr
Obtained product bp/mm pr mp n2G
D
d@"
Yle@l
56-58/1 1.56-(6 I.D2411 .2
50 -

3
,b2l)7 41, 1
Compounds 1, 11, and III were hydrogena,@ed over -seeieta. a*
temperature, at atmospheric pressure, and '@he
Card -12 aminopyri-dirie (IV),

Allylation of Arninc arid Br-omoamnupyrldlrips
we:-
Prc,pertips r-I Propylaminopyrid,.n(-
Nr Obtained product bp/mm pr mp n,60
4( 3-.+,
vi 95-96/2 b (--)9 0 1
There are 2 tables; and refereri--es, 2Soviet, .
ASSOCIATION- Voronezh State 'jr-.,vers,.t-j (Voronezhsxiv gusudal-, + :enr,,(-y
SITBMITrED- February 4, 1959
Card 212

w)k
AUTHORS i M@1,41q"L .,Yt;vj P-Yal,:: 1!@a,
TITLE i VtriylatL,-;r, )f' Ethyleno tliy-ul
PERIODICALi Zhurnal obahchey &Iml 1, 1,I)hO, V@ I @C, Nr
960 (ussR)
ABSTRACT: 1-3ynthcnLi )r a ly
radir-a'.9 ,,ia:i
It " It' 1116
11@ lift 113)
A
The J)taLri-d
g] yr-,-@ 1, me ta 1 1 "o Na (ad(lod at 50"), and :--;rre@,pjnd! ng
alkyl halides (acided wLth heating on water bath)i
monobutyl ether )f ethyleni, glycol (61%), bp
(22 rrim), (ill 00.8981, n20 1.4197;
4 - D CL-methylallyl ether
Card 112 of ethylene glycjl (17.61%), bp 68--(O'@' mm),

VinylatIon ol' Ethylene Glycol 7 8,'r-) 0
Monoethers 1-)OV/-1'9-30-3-44/6q
d20 0.914'(, n @? 01.4@.io; monocrotyl ether of' etl.ylene
4 D 0
glycol (27.6%), bu (21-22@- mm), d 14 7,
n20 1.4428. The following vinyl ethers --i-r- )btained
D
by vinylation of the ether:-, In autoclaves (ma:.-, pr 41@, atm)
at 150 0 with 10% KOH: vinyi b,ity.' el@her of etliylene
2C , -,0
glycol (70%), bp 70-7,`@' mm), II; A21
0
vinyl crotyl ether -)f' ethylen- @-,Ijcol (,-, r@-- -8G
(21-22 mm) d'' 0 0. B91- I
n."' v .1i iy'i Cj-!-,,--thylal11yl
D
ether of' f-,thyLene glyoul (Y4), bj@ '-'-74
-36 mm),
d20 0.8761, n 01 1 -4 3"0. There are ref'ererices, -1 U.S.,
4 D
3 Soviet. The U.S. reference is: W. H. Watanabe, L. E.
Conlon, J. Am. Chem. S@-c., (1957).
ASSOCIATION: Voronezh State Univer:3ity (Vor)re.,hskly gDsujarstvennyy
universitet)
SUBMITTEDt March 1951, 'lard

MIMANrIYEV, B.I.; IAPERKO, VA.
Vinylation of diacetone-,:P-galactoBe. Zhur.ob.khim. 31 no.6:1843-
1844 is 161. (KM 14:6)
le Voronezhskiy gosudarBtvennyy univerBitet.
(Galactose)

MIKHANTIYEV, B.I.1 FRYAKHIIA, E.A.
Synthesis of acetals based on vinyl ethers of n-butyl- and
crotyloxyethanols. Zhur.ob.khim. 31 no.8:2766-2768 Ag 161.
(MIRA 14:8)
1. Voronezhakiy gosudarstvennyy universitet.
(Acetals) (Ethanol)

57 -5 L4 a
27507
S/079/61/031/009/008/012
D215/D306
AUTHORS: Mikhant'yev, B.I., and Mikhant'yeV,iVxD.
TITLE: O-Aminophenylvinyl and p-aminophejy171nyl ethers
PERIODICAL; Zhurnal obahchey khimii, V. 31, no. 9, 1961,
3050 - 3051
TEXT: M.F. Shostakovski and I.A. Chekulayeva (Ref. 1: Izv. AN
SSSR Okh.N., 1954, 1111@ prepared vinyl ethers of ethanolamines
and decided that acetylene adds only to the hydroxyl groups of di-
ethanolamine. However, diarylamines and acridone have been found
to vinylate through the amino group. The presence of both groups
in aminophenols allows tiie addition of two vinyl groups thus pro -
ducing ortho- and paxe.,-aminophenylvinyl ethers. Both ethers are
prepared by reacting the corresponding aminophenol with acetylene
under pressure, in the presence of KOH and aqueous dioxon. The
ortho-ether boils at 87.5-88.50C/10 mm, and has the empirical for-
mula C R ON,
8 9
Card 1/2 A 114

27507
S/07 61/031/009/008/012
O-Aminophenylvinyl and D215YD306
*20 1.5706, d 20 _ 1.0975; the para-ether boils at 103-1040 C/lOmm,
D 4
*20 1.5788, d 20 _ 1.080. Both ethers polymerize in the presence
D 4
of boron trifluoride and copolymerize with vinylbutylether. Hydro-
genation of any of the ethers on skeletal nickel gives the corres-
:,.,.ponding aminophenylethyl ether. There are 4 references, 2 Soviet-
bloc and 2 non-Soviet-bloc.
ASSOCIATION: Voronezhskiy gosudarstvennyy universitet (State Uni-
versity of Voronezh)
SUBMITTED: October 7, 1960
Card 212

MIKHANTIYEV, B.I.; PAVLOV, L.P.
Acetals of hydrobenzoin ethers. Zhur. ob. k-him. 31 no. 1-1:3643-
3646 N 161. (MIRA 14:11)
1. Voronezhskiy gosudarstvennyy universitet.
(Hydrobenzoin) (Ethers)

L 141-64 EPR/ZdP(J)/EPF(c)/EfiT(m)/BDS 4 Rjk'/,-,W/
a IF P. cd/-C@y
ACC:@S'10'.' ',M: ARNIC69U S/0 MMOIOA@A 9 MA Y
STOMME: RZh. Lhimiya, Abs. 10rhgg
AUTHOR: Mikhantlyev, B. I., Kretinin, S. A., Shatalov, V.,P.
TITLE: Study of the properties of divinyl-styrene rubbers filled in the
latex stage
CITED SOURCE: Tr. Labor. khimii vy*sokomolekul. soyedeneniy. Vorone?.hsk. un-t.-
vy*p. 1, 1962, 162-16
9
TOPIC TAGS: Divinyl-styrene rubber, latex stage, rubber
TRUNSIATION: A study was made of the conditions of filling @XS-300 with HAF
carbon bl ck, channel carbon black, Al sub 2 0 sub 3, PN-6 oil, auto scrap-18,
and mazut at the latex stage and on rollers. Carbon lifi`@k dispersions were
prepared with a rzgnatic striction vibrator with a frequency of 25 kilocycles
(concentration of carbon black of 15%, vibration time of 20 minutes). With
Card 1/2
IV

L 141-64
ACCESSION NR: AR3006942
the introduction of 0.2-0.5% leucanol the vibration time is lcrdered to 5-10
minutes. The combination of latex with the dispersion of carbon black and the
oil emulsion was also conducted through vibration for 3-5 minutes. The mixture
,,.,as coagulated by CaCl sub 2 -,dth H sub 2 SO sub h or CH sub 3 COOH. The
c;tpenditures per ton of commercial rubber with HAF carbon black were: CaCl
sub 2 -- 30 kg, CH sub 3 COOH -- 1.9 kg; with channel carbon black; CaCl sub 2
15.6 kg. CH sub 3 COOH -- 8 kg. The product which was obtained was dried at
80-90 degrees irith forced ventilation. Upon introducing the carbon black into
the latex a moro plastic mixture was obtained which yielded stronger and more
elastic vulcanized rubbers; the speed of vulcanization'was increased. Dis-
persions with leucanol yielded better rubbers than without it. A basic tech-
nological plan for the production of carbon black-butyric rubbers was proposed.
A 20@, aqueous solution of Al sub 2 0 sub 3 was prepared in a ball mill (30
rev/r.in) for 3 hours at about 20 degrees. The expenditure of CaCl sub 2 for
the coagulation of I ton of co=ercial rubber was 47 kg. There was no Ions @f
Al sub 2 0 sub 3 during the coagulation of the latex mixture. The introduction
of Al sub 2 0 sub 3 into the latex produced more plastic mixtures and stronger
vulcanized rubbers than when it was introduced on rollers. 0. Chasovahchiko4i
DATE ACQ: 01Ju263 SUB CODEs CH, MA ENCL: 00
Card 2/2

MDMANTIXEK,B.I.; PAVLOV, L.P.; IAPEITKO, V.L.
Halogenated ethers of hydrazybenzoin. Zhur.ob.khim. 32 no.6 1798-1801
Je 162. (141RA 15:6)
1. Voronezhakiy gosudarstverlnrj univeraitat.
(Benzoin) (Ethers)

KIKHAIiTIYEV,, B.I.; IAPENKO, V.L.; PAVIDV,, L.P.
Vinylation of mannitol and its aceto derivatives. Zhur.ob.khim.
32 no.8;2505-2508 Ag 162. (KM 15:9)
1. Voronezhokiy gosudarstvennyy universitet.
(Mamiitol) (Vinylation)

MIKHANTIYFV, H.I.; RADZHYUNAS, L.V.
Vinyl ethers of o-- and wj-hydrar(dipt@enylamlnes. Izv.vys.urheb.za,,r.;
khim.1 khim.t.okh. 6 no.4t697-698 '63. (MIRA 1712)
1. Voronezbskiy gosudarstvennyy universitet. Kafedra khimii wisokomo-
lekulyELrnykh soyedineniy.

MIKHANT'IEV, B.I.; FEDOROV, Ye.I.
Allylation of chloroaminopyridines. Zhur.ob.khim. 33
no.3:865-966 Mr 163. (MIRA 16:3)
1. Voronezhskiy gosudarstvennyy universitet.
(Pyridine)
(Allyl compourAs)

-35073@S5_-
Cciia 1/3

yffl,S-.ltlaCate6:.tJheLr GtrUotUM:LS:,cn&raCTsmzed by &C@
gher
'a a K ho" u's-'::A, si r W, Wu r a a al B a -8 a,

00

m

,

-a TiWT(m)/F.-fiR(j) M IBM
ALV- NK, JLTOW57,j5 SOURGE CODE: URJOOOO/631000 27
AUTHORSt MikhantI12YA Be I@ Radzhyunas, L. V.
ORG- Labora-IM- c#IM-Wei t, undo, Voronezh State
.9je a h kMM
-Univereity (Laboratoriya khimii vysokomolekulyarnykh soyedineniy Yoronezhakogo,
gosudarstvennogo univeraiteta)
TITLE: Vinylation of aminophenols
SOURCEs Voronezh* Universitat. Laboratoriya khimii vysokomolokulyarnykh
3oyedineniy. Trudy.# no. 2p 1963* Monomery, khimiya i takhnaloglya SK (Mononeras
chemistryl and technology of synthetic rubber), 24-27
TOPIC TAGS% organic nitrogen compound, organic synthetic process, aromatic ether,
aromatic hydrocarbon , phenol
ABSTRACTa This investigation is a continuation of work published by Be 1, Mikhantlym
and Ve Be Mikhantlyev 3050., 1961)o The aminophanylvivyl others,
at hip 21" Lr7laminelether were synthesized after
m-amin!gherq1vinyl - . 9 4L@2d@IPW _
the method of A. To, ME rakiy and Me F, ShostakovskiO- (ZhOKb,, 13s 10 1943)- The
reactions were carried out according to the schamast
Card

L ROD'
Acc mts AT60059351 ECH
VIP
%.Lkelelwu
Reaction yiel" I, Melting point&,, molwular weighte and elemntal CONPOsitlOft Of the'
"Uthesixed compounds a" presented* orig. art. hast 4 equations-
so GWES 07/ SUBM DATZI none/ ORM RW s 0031 ON HWI 003
ro @@t

AUTHORSt MikhantlyeyA Be It ; Radzhyunas, L. V.
ORG.- LaboratoEy for the Cheeistrv arn!@@ig@t Compounds. Voronezh
-;(@j eni
State University (Laboratoriya khimii vysokomolakulyarnykh -ea@ln-yTo-ronezhakogo
gosudarstvennogo universiteta)
TITLE: Vinylation of aminophenole containing a tertiary nitrogen atom
SOURCE: Voronezh, Universitot. Laboratoriya khimli vysokomolekulyornykh soyedinenlys
Trudy, no. 2. 1963- Monomery.. khimiya i tekhnologiya SK (monomers,, chemistryi and
technology of synthetic rubber)p 28-35
TOPIC TAGSt organic nitrogen compound, organic synthetic process., aromatic other,
aromatic hydrocarbon, monomer
ABSTRACTs This investigation is an extension of the works published by Be I.
Mikhantlyev and Vo Be Mikhantlyev MOD,, 34 3o5o,, 1961) and by Be I. mikhantlyev
and L. Be Radxhyunas (Isy, vyashikh uchaboyM zavedonly, Khis#a i khine tekh
6j, rip. 4j* 697@9 1963), In this study a-(H.H-diethyl)-aminophonylvin I other j'NW
1
dimethyl)-aminophenylvinyl ether, and p-oX.-Mmauquanuop y 0 -j were
synthesized after the method of A, Be Favorafty and He Fo Shostakovgkiy (ZbM#
l3v ls 1943)e Picrates of the vinyl and ethyl others were also synthesized. The
product yields, melting points.. boiling pointep refractive indices,, and molecular
Card

ACC NRs ATOW5M 13
composition of the derived compounds are tabulated. it was found that the yields of
monomers depended on the temperature and on KOH concentration of the reaction
mixture (see Fig. 1)e
Fig. I* Yield of
Vk monouter as a function
of.;XOH concentration
or@this solutione
Grig* art* Mat 4 tables and 2 grapbisl-
MBN DATM none/ ORIG RIWC 002/ UrH RW 1 006
SUB -CODEs, 07/
212Ad
Card

'ACC NRs ATOMW31 (A) UMMUS UUMS1 Ut(/WW/QJ/UUU/UUU/UU41/UU4Y
AUTHORS: Mikhant'Ley ..I. : Kretinin, S. A.; Shirokov" Yu. P. q1
' I== --- - ,. _j B -.. 15-11
I
ORG, Laboratory for the Chemist" of Histh-Molecular-Welaht Comnounds. Voronezh
go6udarstvennogo universitsta)
TITLE: Synthesis and polymerizationlof certain @itanoorganic compoundicontaining
-unsaturated radicals -
SOURCE: Voronezh. Universitet. Laboratoriya Ithimii Tysokowlekulyarnykh
soyedineniye Trudy# no* 2,, 1963, Monomerys khWKa i tekhnologiya SK (Manomersp
chemistryj, and technology of synthetic rubber)v 7-49
TOPIC TAGSt organamstallic compound, organatitanium compoundj, titanium compound#
organic synthetic process, titanium, polymerization
ABSTRAGTg The organotitanic compounds CHS
(Cm-CH-CH
Hs-CH-C-CM)eTi
.40
__0CH.&' 0CHs
Card JL2

ACC NRs
0
were.synthesized to extend the work of Se V, Noginas R. Kh. Freydlina, and A. No
Nesmoyanoy (Isve AN SSSR# 0KhNs 3s 327j. 1950). The compounds were synthesized by
reacting TM4 # 8NH3 in dry benzene with 2_wthaxybuten-3-ol-l and with 2-mthoxy-2
methylbuten-3-ol-1 respectively* The intermediate products were synthesized after
the method of A. A. Petrov (ZhOKho Us 991p 1941; Zh0Khq 16s 162% 1946) and or A. 14.
Pudovnik and.S. Go Denislamova (ZhOKhp 27t 2363s 1957), Reaction yis;ds and the
characteristic physical constants for the synthesized compounds are tabulated* The
polymerization of the synthesized compounds was studied., Only thermopolymerisation
and polymrization induced by orthophosphoric acid yielded polymerso Metallic sodium
BF_3pFeGl.39 and bensoyl peroxide did not induce polymerizationo The polymers
obtained were ruby-red. in colorp brittle, and showed a poor-adhesion to glass* Orig.
arto hass 2 formlase
So CODES 07/ SUBM DATSt none/ ORIO REFS 007 OTH REFs 001

earb it hl Ajj
y pers *ns'Vere,.prepar
GOORi 6i@ i@etic. att Be:, a 0 20% ori
1, : n-a'ba I mill for-24 hrew in thi',Presenici of.44:parts b weight
-by -grind. ni s
Teultmnol and- 0.6'parts, by w#ight, luon (in'relativn to the carbon black) The. oil
emu a on: arigino luriog. the CoAgulation: of -mixtures from hekal.
the. best, resulti wire--produced-by CaCl 'an(VCH300OR; -in the case of latex
produce t 1ds,:,the_,.besk,res It
d irith@the-i6aosi of synthetic fat Y.-se u a 'were produced b
a -0 tur*e- I -phonylatex, NaCI.-and
tx @f C@d-29@ NSCl and CH-,COOH;.In-the cane of co a
@HZS04 gave'the best results, Duking'deformation of the initial rubber with 4500
raw mixtures of :rubbei,,1 IlIdd with. carbon'black and oil (SW rubber)..had a some-
d
what greatOr'plastic"ity and, less.reducibility than when carbon black wa's ad ad to
7.011-f 1llod.;:r4b,ber -on the- rollers. - --The strength- of the vulcanates'was 'somewhat
h lilai of Introduc ing the.: carbon black had -no a lgaLf icant
a
I-over have ftr@
effect-on t 9 proporties@of iu or- mixtures'and vulcanites, lnl@ noft rubber& The-
i,iii"df-i-dbb-e'r:-do--depetid-,,--howeveri~dii-ithii method of--coagulation, Theift-
propert
Btant4MOUi M rubber:-resulted fit sodewMt more
_d A
V
rigid' Uresvith bleteas -a istre.ngth ..aft,
.11@ixt d ecreased @re ative elongationa'.
S
cis
uva
M
21.@2

L 41JO@5-i@ __EMT-(-m-)/E'.VP(j-)/TI-j P @ c )RM
ACC NR, AR6021268 (A) SOURCE CODE: UR/0081/66/000/004/3030/3030
A,: OR Mikha@p@ykvj B. I Shatelov, G. V.
Polymerization of piperylene. Report 2. Polymerization'of
trans- a-nd cis-pi@er4enelin the presence of the dilsobutylaluminum
chloride and alcoholic cohaltous chloride complex catalytic system
SOURCE: Ref zh. Khim, Part II, Ab3- 4S188
REF SCTIMCE: Tr. Le.bor. khimli vysokomolokul. soyedineniy. YorDDAm"k-,
un-t. vyp. 3, 1964, 83-86
T011IC TAGS: catalytic polymerization, alkeno, polymerization catalyst,
tensile strength, elongation, fluid viscosity
.M-BSTRACT: Pure Isomers were separated from the emylone-piperylene
;fraction. Polymerization was carried out for 8-10 hours at 200 in dry
oxyCen-free argon in glass ampoules in 20-30% solution In absolute
benzene. Catelyst1was 3% diisobutyloluinintim chloride (I) and 0.01-0.02%,
:CoCl on t9Mweigbt of the monomer. Percentage of conversion wan 75-85@-
;The 2
polyrrer consists primarily of 1,4- and 1,2-cis groups. Decreasing
the amount of the alcoholic CoCl2 complex does not cause a change In the@
'polypiperylene structure but reduces @jl . Reducing the amount of I to
-Card 112

L 41103-66
ACC NRI AR6021268
2% and reducing reaction time leads to a decrease in polymer yield and
The liktter is also reduced by raising the temperature to 400. A
;carbon blackvyulcanizate of the polymer has a tensile atrengthJ35f 160
,arid 101 kg/cmI at 200 and 1000 and relative elongation of 7bO and 490%.
:res-Dectively. Report 1, see R. Zh. Khim.s 1964, 243175. 1. Gritakova.
lffr@nslation of abstr c3t.
a
SUB CODE: 07
11b

r, WT k if"
22 11c, W I * kI -I
ACC NR, AR6016783
SOURCE CODEt 1ffVoo8i/65/OO0/O23/SO26/S0,'6
AUTHOR: Shatalov, V. P.; Mi
anasov., F. khantlyev, B. 1.
TITLE: @,,.,,,ymerlza@Aon'of isoprene under the influence of a homogeneous "cobaltic"
system
SOURCE: i(ef. zh. Khimiya, Abe. 23SI66
REF 60UHGi:,: Tr. Labor. khi-ii vyookomolakul. soyedineniy. Voronezhok. un-t, vyp.
3, 1964, 87-89
TOPIC TAGS: isoprene, catalytic polymerization, aluminum compound
ABSTRACT: rho polymerization of isoprene (1) on an Al('so_G4 Hg)Sl (II) catalytic
system (2 to 4A), with a CoCl 2 alcohol complex (111) (0.01%) and an addition of
acryinitril at various ratios of the componentat (118t4, lsM and 1:1614) is
studied. The reaction was carried out without the presence Of 02 and moisture in an
absolute benzene solution at 20 to 400 and the following concentrationst (1) 20%,,
(11.) and (111) 2 to 4% and 0.01% (to I). The yield of the polymer is 49 to 80% of
mol. wt. 105 800 - 193 400# cia - 1.4 links content of 60 to 69%, 1.4-trane 29 to
38% and 3.4 about 2%. The polymer is practically entirely soluble In benzene. The
amount of gel-fraction amounts to only a few percent. V. Dudirin. F
SUB COM 07/ SUBM DAM none

L 42P75-66 Fe1T(_m)/SVP(J)/T we,I'/P'M
ACC NR& ,-'60?-4955 14 icuac--' 'J-.1/ooi~I/66/000/006/jO29/,-)029
A",':;:G,@: ':ikhant'yov, B.I.; 'ikhant'yev, V. a. Kal-,ykov, '1.
T
. 1-1 L@L :?olynorizationjand conol7nGrization of v-1Vl compounds at reiuccd pressure
SCU,-CE: RaC. zh. Khiriiya, Part H, 16s. 63192
-30'Ta"': Tr. Labor. khtmit v-
ysokomolokul. soyedinoniy. Voronnhikun--ts vy-- 3,
1964, 9;1@@5
?CPIC '.L'AGS: v-injl comound, copolymerization, other
A@T!@,ZT: In the Dolymerization (P.") of vinyl others of higher fatty alcohols in the
prasenco of forric chloride at the boilinv, noint of the initial other and at atmosnhor-
ic nressure, these eAhers nartly deco-nnoso at the boiling noint (150-2000), and the
nol"ers obtained are insufficiently viscous and are contardnated idth the alcohol and
riono.-ier. According to the T)roDosed method of P'@ and coDolymerization of high-bolling
vinyl compounds, the process is carried out In a vacuum (e. g., a residual pressure Rf
12-18 -n) and at a reeuced tomerature (a. i@., 40-'70*). The method makes it oossible
to obtain high-qu,Lity nroducts in P,5-901'@ Yield of theoretical, no depolymerization
takes place, and the polymers obtained are oure. Z:ca.-.1plo. The PA of vinyl hexyl
other@(100 g) is carried out in a flask connected to a straight condenser, which is
follo,jed by a c,ndensate receiver. The latter is connected to an aspirator; after the
latter has rz;sn connected, heating of the flask containing the reaction mixture is *
started (on a water bath). At the instant the ether begins to boi.1, Kt (2-4 drops of

L 42875-66
ACC N_Rs
jO@662W55
0
5@'O alcohol solution of ferric chloride) is introduced through a capilIary. The PIIII re-
action Droceeds quietly, and the partly unreacted monomer is driven off through the'-
straight condenser and collected in the receiver . E. Bukhina. [Translation of ab-'
stract]
3UB CODS: 07
C rd 212

T
ACC NR, AR6015910
(A) SOURCE CODE: UR/0081/65/000/022/5027/SC)27
AUTHOR, Fedorov,, Ye. I., M:Lkhant'yev, B. I.; Fursava, L. Ya.
TITLE: Emulsion copolymerizationlof 2-allylami=ldino'land N-vi , 1-2 id
with bivi and @no-
SOURCEt Ref. zh. Khimiya, Abs. 22S157
REF SOURCE: Tr. Labor. khimii vysokomolokul. soyedineniy. Voronezhak. un-t, vyp. 3,
1964, ioo-io4
TOPIC TAGS$ emulsion polymerization, copolymerization, pyridine, vinyl compound,
ABSTRACT: The copolymerization (CF) of N-vinyl-2-pyridone and 2-allylaminopyridine
with bivinyl and s one was carried out in an emulsion, the latex,obtained was
tested for bondingpcord with rubber, and the effect of ultrasoundl:6n the adhesive
properties of the latex were studied. The emulsion CP was carried out at 20* and a
ratio of the hydrocarbon phase (HP) to the aqueous phase of 100:150; the HP consisted
of 70% bivinyl and 30@ styrene (the pyridine derivatives were Introduced by decreasing
the amount of styrene); the aqueous phaso (in % of HP) consisted oft water 150,
synthetic fatty acid (C 10-C A6 ) 49KOH 0.9p hydroquinono 0 035'Na SO@ 0.2, trilon
B 0.025, cumene hydroperoxi e 0.25, IAmkanol 0.5, diproxi@ 0.2. Vho copolymers B, C,
I Card 1/2

ACC NR,
AR6015910
D contained 3.1, 5.53, and 4.1% of pyridine dorivativea reopectivoly. The Impregnant
for the cord was prepared from latex, resorcinol-fomaldehyde resin, and a carbon
black dispersion. It is shown that admixtures of pyridine derivatives do not appre-
ciably affect the bonding of the cord to the rubber; an Increase In the static
strength of the bond is observed only in latex B in the case of rubber based on syn-
thetio butadione rubber; irradiation with ultrasound does not affect the adhesive
properties of the latexes. A. Zak. [Translation of abstract)
SUB CODEs 07,11

i--rr(M)1,--;jP(J) LINO
ACC NR, R6
A 016972 SOURCE CODE: UR/0081/65/000/024/3077/3078'
:A'JTHOR-. Mikhantlyev,/B. I.; Gostev, M. M.; Kretinin S. A.
!TITLE: Carbon black-oil filled butadiene styrene rubber of low
@terrperature polymerization obtain-a-d-T-na system with a 'Trilon Rongalite
,activating group
SOURCE: Ref. zh, Khimiya, Abs. 24S547
RE,- SOURCE: Tr. Labor. khimii vysokomolakul. soyedineniy. Voronezhsk.
@un-t, VYP. 3, 1964, 186-19o
@T'OPIC TAGS: butadiene styrene rubber, filler, carbon black,
!polymerization catalyst, elasticity, tensile strength
1A3STRACT: The possibility of using channel and gas furnace blacks in
@reinforcemant in SKS-30 ARK @Iatex prepared with the Trilon Rongalite
iactivating group was investigated. The carbon blacks were introduced
iinto the latex as 20% dispersions stabilized with K-soaps of hydrated or.-
idisproportionated rosin. The following proportions of stabilizer were
'necessary to obtain stabilized dispersions: for channel black 4-5 p&rt4
:by weight, for furnace black 3.5 parts by weiyht, for their mixtures
c
(1:1) 5-6 parts by weight. Introduction of both carbon blacks and tbeir.
Card 112

L 40962--(3--
ACC NR1 AR6016972
mixtures to the latex gives vulcanizates with lower modulus and greater
!elasticity. The strength of vulcanizates with furnace black is higher
land with channel black it is lower than when the carbon black is added
,on the rolls. M. Ayzinson. ZTranslation of abstract7-
SUB CODE: 07, 11 1-kG
2111, e

MIKHANVY77, B.I.; LAPENKO, V.L.
Viriylation of acetone derivativm-9 of sorbitol dulcitol. Wir.ob.khim.
34 no.2-694-696 i 164. (@URA 17: 3)
1. 7oronezhskiy Rosi-idarstvenny-y universitet.

,--A U'KAYEV , L.P.; It-20AIII-I 'YEV, --,. 1. ; All I'KAYFVA Ye. A.
I,rGb.em r' intraro"ec-,lar donor-a@@ceptor in*,ra@'-,r.. rl'
.4 N 156 no - 5: 1109-1111 je '64.
1. Voronezliskiv gos,jcar,.itvOnnTf univer,91tet. Fretl3L;A,-,:-rir,

, Y@,-v , _@.. 1. ; '-;,:;: , :,. V .
V I ny I ethers tj,* s(.rr.,. ;-am: r. j; tenc, 13. im. 4 @ :
3 4,@ 4 - 3 4,' r, (' ' e,,. - 1. X " "A I " : i .
1. Voronezir,skly _ir,.Ivers.tpt.

L 42R75-66 SVT(m)
/@U-p Vr WVY@M
ACC NRj V.6024955 (A) SOURCE CGD-E: Ul/oo91/66/ooo/006/429/5029
AU7-'()R: :-:ikhant'-Yevj I.; :',Jkhant'yr)-.r,
Polynori ationjand conolynorization of vArV!l compounds at reduced pressure
Pv)f. -.h. Kliimiya, Part II, A?)s. 63192
@@E7 307,12C-7: Tr. labor. khimii v-jsokomolokul . soyedinaniy. VQronezhsk, _q_ @tvyo. 3,
1964, 94-95
TOPIC TAG3: vinyl compound, copolynerizationp ether
A@TaACT: In the rolymerization (R:) of vinyl athers of higher fatty alcohols in the
presenco of forric chloride at the boiling Doint of the initial ether and at atmospher-,
ic nressure, these eAhers partly deco-nnoso at the boiling noint (150-200*), and the
polyners obtained are insufficiently viscous and are contardnated t-rith the alcohol and
riono.ner. According to the -oroDosed method of PM and coDolymerization of hiFh-boilinEr
vinyl compounds, the process is carried out in a vacuumNe. g., a residual pressure qf
12-IS m) and at a recluced tennerature (a. @,., 40-701). ' The method makes ii possible"*
to obtain high-quality product s in 85-90;,' Yield of theoretical, no depolymerization
takes place, and the polymers obtained are r)ure. acxnplo. The PM of vinyl hexyl
ethe-A(100 g) is carried out in a flask connected to a straight condenser, which is
followed by a condensate receiver. The latter is connected to an aspirator; after t6-
latter has been connected, heating of the flask containing the reaction mixture is
started (on a water bath). At the instant the ether begins to boil, Kt (2-4 drops of
Card.

L 42875-66
ACC NR: !@"O 49-55
5@-; alcohol solution of ferric chloride) is introduced through a capillary. The PM re-
action Droceeds quietly, and the partly unreacted monomer is driven off through the
straight condenser and collected in the receiver . E. Bukhina. [Translation of ab-!
stract]
3UB CODS: 07
CO d Z/Z

MIKHANOVSKIT Vladimir Nei, vIch; SHUN, M.S., otv. red.;
NAZARENKO, LY., red,j TROFIMENKC, A.S., tekhn. red.
[Electromagnetic defectoscopy In constant and variable
fields) ElektromngnitnaiR defekto5koplia v postolannom
i peremennom pole Khar-kov, Izd-vo Goa,univ. 1963-
57 p (MIRA 16,11)
(@'agnetlc testing)
(Pipe mills-Quality control)

27507
S/07 61/031/009/008/012
D215YD306
AUTHORS: Mikhantlyev, B.I., and Mikhantlyev,
TITLE: O-Aminophenylvinyl and p-aminophery7lnyl ethers
PERIODICAL: Zhurnal obahchey khimii, v. 31, no. 9, 1961,
3050 - 3051
TEXT: M.F. Shostakovski and I.A. Chekulayeva (Ref. 1: Izv- AN
SSSR Okh.N., 1954, 11M prepared vinyl ethers of ethanolamines
and decided that acetylene adds only to the hydroxyl groups of di-
ethanclamine. However, diarylamines and acridone have been found
to vinylate through the amino group. The presence of both groups
in aminophenols allows tiie addition of two vinyl groups thus pro-
ducing ortho- and pero/-aminophenylvinyl ethers. Both ethers are
prepared by reacting the corresponding aminophenol with acetylene
under pressure, in the presence of KOH and aqueous dioxon. The
ortho-ether boils at 87.5-88-50C/10 mm, and has the empirical for-
mula C,H 9 ON,
Card 112

27507
8/079/61/031/009/008/012
O-Aminophenylvinyl and D215/D306
n 20 _ 1.5706, d 20 _ 1.0975; the para-ether boils at 103-104 0C/10MM,
D 4
n 20 _ 1.5788, d 20 _ 1.080. Both ethers polymerize in the presence
D 4
of boron trifluoride and copolymerize with vinylbutylether. Hydro-
genation of any of the ethers on skeletal nickel gives the corres-
aminophenylethyl ether. There are 4 references, 2 Soviet-
bloc and 2 non-Soviet-bloc.
ASSOCIATION: Voronezhakiy gosudarstvennyy universitet (State Uni-
versity of Voronezh)
SUBMITTED: October 7, 1960
Card 212

I :A i 'ili"''J,
U, 1, U I D ZI,
(,, rige P. I ta r;i,. a r- t lafect. i r, r i ;; s .9 -T,
n i 3@i ty i e n t zLileriri@, !().,-(jki

GOROKHOVp I., 1nzh. (Zhdanov); GRANKOV, L., inah. (Wanov); RAKRMANOV, K.,
inzh.-mayor, Isobretatell; BASKAKOV, Yu. (Chernogorsk); PEMLIYEV,
N. (Moskva); GLINCHEVSKIY, V. (Penza); KORNEV, M., inah. (Kiyev);
@HARE@V, P., konstruktor (Orenburg*; DITACHKOV, M. (Irkutsk)
How interesting! Izobr.i rats. no.1:19 163. (MIRA 16:3)
1. Nachallnik Penzenskogo byuro po delam ratsionalizatsil
i isobrotatellstva (for GI-inchevskiy).
(Technological innovations)

HIMIAM V.A. agronom.
ffNevw methods for determining seeding rates for grain crops.
Zemledelis 4 no.7:122-124 ji 56. (Kw 9:9)
(Grain) (Soving)

USSR / Cultivated Plants. Grains. Legumes. Tropical M-1
Cereals.
Abs Jour :Ref Zhur - Biologlya, No 2, 1959, No. 6209
Author :@JllthaFev, V. A.
Inst :Chkalov__ I'C"u-ItUral, Institute
Title :The Sowing of Durum WhFat by Separate Seed
Fractions
OrIg Pub :Zemledeliye, 1957, No 3. 80-82
Abstract :The results of the study at the Chkalov agricul-
tural Institute (1954-1956) of the norms of
sowing of durum wheat (Melanopus 69 variety)
In relation to the size of seeds Is given in
this paper. Excessive density of sowings
(6-5 millions for small seeds, 5.5 M11. for
medium and large sizes on 1 ha) causes the
plants to become depressed. This phenomenon
Card 1/2
6

MIKHAREV, V. A. Cand Agr Sci -- "Certain problems of agriculturFil engineering
t
and prospects of development of the cultivation of durum wheat in Orenburgskays
Oblast." Omsk, 1961 (Author'si Jbstraots of Jissertations presented at Omsk
t'
Agr Inst im S. M. Kirov). (KL, 4-61. 205)

MXKHARSKIY, K.I., inzh.
Threading trapezoidal double screw threads by a vortex method
in one operation. Stroi.i dor.mash. 6 no.8:34-36 Ag 161.
(MIRA 14:8)
(Screw cutting)

I
@MITTAMXYJ YE, V'j
Agriculturp & Plant F, Animal Tndustry.
Increased mill, production. 3aratovskoe obl. gos. lzd-vo, 1950.
Monthl- List of Russian Accessions, Librar7 of Congress, April 1952 UNCLASSIFYED.

VOLKOV, Te.T.1
Z.M.Pankina, compiler of a complete bibliography of ftasian bookg
on the sea. Okeanologiia 2 no.5054-958 162. OCRA l5sU)
(Penkina, Zinaida Milrhokilovna, 1861-1887)

MIKHASEV, M.-I.
Dynamics of gas metabolism in circulatory insufficiency. Kardiologiia
1 no.6:7441 N-D 161. (MIRA 15:1)
1. Iz kafedry propedevtiki vnutrennikh bolesney (nachalfnik -
deystvitellnyy eblen AM SSSR prof. N.N.Savitskiy) Voyenno-haditsinakoy
ordena Lenina akademii imeni S.M.Kirova.
(RESPIRATION) (BLOOD-CIRCULATION, DISORDERS OF)

IUZMSOV Volop doteentl KUSHMVSXII, H.S.9 kand,med.nauk; KMMZVv W.I.
lls.ingrad)
Antihypertensive activity of cystamine. Klin.med. 39 no.1171-
76 A 161. (MM 1411)
1. Iz kafedry propedertiki vnutrermikh bole5ney (nach. - saslu-
zhemyy deyatell nauki deystritellnyy chlen AMR SSSR prof.
N.N. Savitskiy) Toyemo-meditainakoy ordena Lenina akademil
imeni S.M. Kirove.
(BLOOD PRESSURZ)
(THYImm)

MIKHASIK I podpolkovnik; NERETO, Ye., podpolkovnik;
=nn-@
- SUMOTIN, Ye., podpolkovnik
Recording of military and political training. Voen. vast.
41 no.5.69-73 My 161. (MIRA 14:8)
(Russia@Army--Personnel records)

j 1, '
MI @.iA . IVA, , ; P-C'. -- 'I If, @. : " (Y t I -:@V'
Le.-M,e - 't-,Arp of @1, ;, I -), t, , 1 @ L,:
- C- . - 1. @j;'
L, "IeE@Lfi @@ gra ris (Mi'll f hi L: 01'
Lecn I-st. (.r '-lr@o,i (KIL, ' , I @ )
.1
- t" I -

MIMTOVA, G.N.
............ Optimum for predefecation temperature. Sakh. prom. 32 nooB-.29-34
Ag 158. (MIRA 11:9)
l.Moskovskiy tekhnologicheekly institut pishchevoy promehlennosti.
(sugar manufacture)

. MIKHATUVA, G.N.
Product calculation in the combined processing of sugar beets and
raw cane sugar. Sakh.prom. 36 no.4:45--48 Ap 162. (KIRA 15:5)
1. Vaesoyuznyy zaochMy inatitut pishchevoy promyohlennooti.
(Sugar mwmfacturs)

BUGAYENKO, I.F.; MIKHATOVA G.N.
[High-mclecular floccultints In tr'-- s-ugar :.wustry: V@y3oko-
moleku-liarnye flukulianty v sakharnoi promyshlennosti.
Moskva, I'Sen'r. lr.-t riauchno-tekhri. lnforzratsli pishchevol
promyshl., 1964. 21 p. (MIRA 17:12)

KAGANOV, Isaak Natanovi7hi MIKHATUVA, Galina Nilk@.@irjrevna;
VOYKOVA, A.A., red.
[Chemical and technical ralculationn and acv.)unting In
sugar manufacture) Khlmiko-tekhnicheskie ra.,3choty I
uchet v sakharnom proizvodstve. Moskva. Pishcheval'a
promyshl9nnost', 1964. 330 @. IVI!.'IILA -12 4 ,

ACC NF4 AP6009065
E CODE: UR/0185/66/OU/003/0253/-0251
AUMR: Kozak, 0 Y ff. A. Pasichnyk
oil
Pasechniko L. L.
ORG: institute or Physics, M URSHy nev (Instytut rizyky m uRsR)
.2 0, '4 4
The measurement of electron temperature in helim plasm by the Intensity
ratio of the spectral lae-s
Ukrayinalkiy fizychnyy zhurnal, v. 11, no. 3. 1966, 253-257
TOPIC TOWS: electron temperature, helium plasm, spectral line
A&MAPT: This paper presents some calculations linking the Intensity ratio of the
spectral lines with the electron temperature in helium plasms. The calculations
are @arried out for different singlet (k - 50471, A = 50161, A w 49221) and triplet
(A - 4713A*, X - 44721) combinations. The excitation function for He-lines and cross-
section data in maxima applied here represent an average of results obtained by other
authors. The electron temperature values obtained by the Intensity ratio of the
-helium spectral lines in the plasm or a positive discharge column with a hot cathode
.are compared with the results obtained by means of probe techniques. The experi-
mental,data ShOWLth&t Intensity ratlo.bf some spectral lines depends on the helium
pressure when the letter is over 10-3 mak9g. The use of spectral lines for deter-
mining the electron teaperature or piag Orig. art. has: 4 figures, 2 tables
i.forwils tBased on authors' iLbstracti.,
@1:8= =0 ?0
V SMM DAns %.1"5/ CRM MWs 062/ OTR MWS006t

MIKHATSKIY, A.G. (Nezhin)
Concerning one draw.ng. Piz. v shkole 22 no.2s9O Mr-Ap 162.
(MIRA 15:11)
(Interference (Light))

A- .1@@
111-i Qe Im se. ""in ,@!er '@du@,t' n v urjc-:- -)f
Len@n 'oly+.p Ilni -In-vt.. ^h@ir n -hr@o-r-tiiil ."rir. i I-,-
FtA i nv-ngin- erin.,. Ki- v,I r
i -e hni @ @l i@ t+
(Dlssert-it.ion for ', h o Do r,- -0-andiit'e in
KnizhnA-v Leto is', No

MIKHATSKIT, Tu.V.
Calculation of the error of pulse diode voltneters. Izv.v7s.
ucheb.zav.; radiotoicb. 2 no-3:316-320 My-Je '59.
(MIR& 13:2)
1. Rakomendovana kafedroy tooratichesklkh oanov radiotakhniki
Kiyovskogo ordena Lenina politakhnichaskogo inatituta.
Ociectron-tube voltmeter)

9(2,3) OV/'. 15 - 5 9
AUTHOR: Mikhat
TITLE: Designing Circuits of Diode Pulse Voltmeters
PERIODICAI: Izmeritel'naya tekhntka, 1959, Nr 8, pp 44 - 47
(USSR)
ABSTIZACT: In this paper the author analyses the influences of
the initial diode current and the grid current of the
reflex circuit tube on the function of a diode peak
voltmeter. The combined action of-these t7wo currents
determines to a considerable degree the zero-stabili-
ty of a voltmeter, its readings and t@e input resis-
tance of the reflex circuit. In this connection, the
author considers problems encountered in designing
the most efficient pulse voltmeter circuits. Based
on these investigations, a circuit with a closed in--
put is recommended for measuring positive pulses.
For measuring negative pulses an open Input circ,,iit
is recommended. Fcr peak-to-peak measurements of
pulses, the circuit must be designed according to
Figure 7. There are 12 circuit diagrams,. 1 graph and
2 Soviet references,
@ard 1/1