SCIENTIFIC ABSTRACT NEPORENT, B.S. - NEPORENT, B.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136610013-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

P/ 7
(V
USM/Physics Infrared absorption anisotropy FD-3257
Card 1/1 Pub. 146 - 16/44
Author Zaytsev,, G. A.; Neporent,, B. S.
Title Anisotropy of absorptien of gypsum crystals in the infrared regioa
Periodical Zhur. eksp. i teor. fiz., 29, No 6(12). Dec 19551 857-863
Abstract Designs of a polarizational, method for and microscope adjunct to
infrared spectrometry. The authors investigate the anisotropy of
absorption and reflection of gypsum crystals in the region 2-11
microns. For a number of bands corresponding to the oscillations
of water molecules and SOq- groups they discover pleochronism and
extension to variously polarized components. They make more pre-
cise the origin of certain bands and give conclusions concerning
the nature of the oscillations bonds in the lattice. Fourteen ref-
erences: e.g. On Katsumura, Meu. Faculty Sci. Kyushu Uuiv.) 1 Bp
1-3, 1951 (Chem. Abstr., 43651, 1952).
Institution
Submitted August 32, 1954

T Tnt
JET);
&104h.

ore
USSR/ Ehysical Chemistry - Kolecule. Chemical Bond
APS c1bur Referat Zhur KhImiyap N6 3, 195'(j 7191
Author MPT-1or_ent,_B,S,I-and, Borisevich, N,A.
~Title Spectra and Yield of Anti-8tokes and- Stokes Fluorescence
of V4ora of Arozatic Coppouids
Orig Pub Optilvx i, spektrookopiya- 1956 voi i No 2, i43-l54
Abstract The spectrum:-and the absolate value:of the fluorescence
4*ntua yiel& have. beer determined, for vapors and solu-
tions ~ of -the: derivatives of -&thaljmide 3-amino - t 3,
6-aamino-j 3,6-taramethyidiamino- I
j,:3-methYlamino-,
3-acetamida-6-dirathylamino-, and 3-dimethYlamina-6-a-
MI h as - a functi6n ~ of the - wrelength of the exciting
lightl th46- temperature, and the vapor pressure. -,-Tn the
case of:vapors a decrease in, quaatun yield is observed
Dor shifts both in the Stokes and ia-the anti-Rokes
regiori. The-first of these phenomem is explained by
-Card
1/2
----------

USSR / Optics .1 K
Abs Jour: Referat Zhur-Fizika, 1957, No 4, lo4o3
Author : Borisevich., N.A., Heporent., B.S.
Inst : Not Given
Title : Effect of Extraneous Gases on Spectra and Fluorescence Yield of
Vapors of Aromatic Compounds.
Orig Pub: Optika i spektroskopiya, 1956, 1, 110 4, 536-545
Abstract: A study was made of the dependence of spc-ctra of fluorenceEce
yield of vapors of 3.6-tat--araF-,thyldiaminophtalimide, 3-dimethyl-
amino-6-aminophtaliroide, 3-aminophtalimide, and 3.6--diaminoph-
talimide on the pressure of extraneous gases at various tempera-
tures. It is established that the eff-ect of extraneous gases is
not restricted to reinforcement of the f1uo_re_=;cen-_e as a result
of stabilization of the excited molecules, Vnich takes place only
upon excitation by large quanta. During excitation by small quanta
one observes the reverse phenomenon, weakening of fluoreecence.
Card 1/2

USSR / Optics
Abs Jour: Beferat Zhur-Fizika, 1957, No 4, lo403
K
It is shown that the excitation frequency, at which no changes
occur in the fluorescence yield in the presence of extraneous
gases (called the inversion frequency) coincicip-s with the fre-
quency of the electron transition. The observed phenomena of
the reinforcement and weeakening of the fluoreecence, are explained
by the transfer of energy from the excited molecule to the mole-
cule of the extraneous gas or vice verea. An estimate is made of
the average amount, of energy, transferred upon collision. Com-
parison of the values of the fluorescence yield of solutions and
vapors shows that the action of the solvent on the fluorescing
ability of the dissolved substance is not restricted to a rapid
establishment of thermal equilibrium in the system, which is of
universal character, but exerts also a specific influence.
A method is proposed for separate investigation of the specific
and universal action of the solvent.
card 2/2

Molecule, Chemical bond. BA
miya,No 7, 1957, 21978
Author :,Neporent B. S. and Solodovaikov A. A.
Inst.
Title :,Effect of Helium on.the intensity, of spectraof vapors of
.complex. aromatic compounds.
Orig Pub : Optika I spektroskopiya, 1956, 1, No 7, 951-952
Abstract : Continuing the investigation of the effect of light gases on
absorption coefficient of vapors of complex aromatic sub-
stances (Weporent B. S. Dokl. AN SSSR, 1950, 72, 35; Zh. ex-
perim. I teor. fiziki, 1951$ 21, 112), the effect of He on the
intensity of absorrtion and fluorescence of vapors of 3-
,limethylamino-6-aminophtWimide (1) waa studied. AAdition
of He decreases absorption coefficient of rarifled gases of
1, and at 4ach pressure of 1 (0-15., 0-05 and 0.008 mm Hg)
there is a "saturation" of the decrease In intensity of flu-
orescence (absorption coefficient), whereby the magnitude of
the limiting weakening Is increased and the pressure of ffe,
at which this weakening is reached, is decreased as the elas-
ticity of the vapors of substance under investigation is de-
Card 1/2 -7-

mlpamv, B.81.
Regular patterns lit fluorescence and adsorption spectre and the
surface structure of cmvlex bolecules. Izv.AN SSM Ser.fIz.20
no.4:455-457 AP '56. (HLRA 10:1)
Mminascence) (Fluorescence)

up gavvy, 3,3#; BORIMFIC14 X&A,
Spectra and wisslon of Stokes and autl-Stoken fluorescence of
ar=&tIc ampounds. live ANISM.Sardis, 20 no~4:476 Ap'56..
(laminsicenco) (Fluorescence) (KLRA 10:1)

BaRISWI(E. N.A.; XWCEM. ILS.
Influows, of gessoum Impurities an the spectra and emission of
fraorescowe of vapors of ormatto compaundso InveAN SSSR Serfls.20
nco'.4:477 Ap, 156. OK"duAseeme) (yinorstance) WRA 10c1)

Y-'
USSEVOptics K
Aba Jour: &rerat Zhur-Fizika, 1957, No 4, 10516
Author RePorment-1 ., Klochkov, V.P.
Inst o Given
Title High Transmission Spectrometric Setup for the Investigation or
laminescence.
orig pub: Izv. M SSSR, ser. fiz. 1956, 2o, iTo 5, 661-664
Abstract: Descriptioa of a high transmission spectrometric setup for the
investigation of spectra of luminescence, based on a monochroma-
tor employing a diffraction grating of 600 lines/mm. measuring
150 x 12D mm. The manochromator is constructed according to the
Ebert-ftsty scheme. The focal distance of the collimator mirror
is 500 mm. The radiation receivers are two photowaltipliers:
FEU-18 36o mimmicroaa) and Fw-22 750 milli-
microns). iamMous diffraction orders are used (the lattice reflects
approximately 55% of the incident radiation near 1000 millimicrons
Card 1/2

ussr~optics
Abs Jour: Referat Zhur-Pizika, 195T, xo 4, lo516
K
in the first order, 500 millimicrons in the second order, and
300 millimicrons in the third), and it is possible to Measure
with the setup spectre. in the region of 250 to 1100 millimic-rons.
The calibration of the instrument for spectral sensitivity is
carried out with the aid of a tungsten ribbon lamp with knovn
ribbon temperature.
Card : 2/2

?RtKt16VK0. A-F-
24M ~-3 Imm I 8001c Uzurrarom &wII365
Wv*T. maveray"t i
RRUARIF X ysc--3U--%13 P*
rblekMITarmwa (Papers or th* loth ALI-FIVIOM
Cmf*r*=* On SpeolxnaccV. 1ral. Is X*Ieata&r Spectr*acM)
(Z.Ivavj Zzd-v* Mworakoca UMIT-ts, l9ff. 499 P. 4 wo copies
Prtntod. (Sorless Its: nzychM zblMfc# np.
Additional SOMAG Agewl xcadamirs rtaux 33". romissirm pe
S.L.1 744h. r4.2 Saranyuk, T.Y.2
Editorial BoArdt ta-Asterc G.S. A"deldelm (%aav. rd..
rovoreat, S.B.. 0.4tor or h4;1;,4 ad MathemstIcal 1010MRS.
ftb*I1n4k,Tp I.L. vootor or mW41441 am getbmatical-Saiduces.
FablIkant. V.A.. 60;tor of ftsiml and Kathemat1dal S*Lemem.
XQrnZt*k1v, V.0., Candidate or Ttd!wld4 Sclogoas Mynkly, M.,
Candidate Of r4619181 Cd WMICAUCIU S4L&Wdf, ha; EX.
Candidate Of Pblaidal arA MeATAUGAI 501014,06p r&1=1 V.S.,
Candidate of nval"I and Kat!wx&ttcaZ satema$*, ad alaubemn,
A. re., CaddIdAto of ftraidal ad mtht"tUal Sciences.
cam 1/30

CUULA=Tgklr. T.K. N P. ovill (I. S. vanIS41 am
To. T..Zrr~x. - X14 lag or V4140dgr 64M%
14 KOW144trozyto solutions Stu"" by ra"m 4r rw
framd AboorgUm SV44tra

2
B.S. T-?. 9106h1o". vevendena* of t!-A
Of QrgAnju TAROV0 4u, tbA C=AAQ.
tretlow

1
No o"At N.G. BakhAd4ev. afloat of the
of UA Aboorptiso ratelf" Cor
complex orgode compounds

42
QLftb*Mn, A~ T18. ThGUT of U4%tg4ft 90441*r& Qf
comsmused Sys""
53
A14 Stvrlo.. Flamon, Spestra
214"16-2 2 1-hoptam-.5

9
KJ4 Tall"Odr. 4#A N.A. Zmpdmm,~
UUTS; "W"Suft w ws4" 4w Water v*#* Ift

S
ll.- :j and V. 1% Imciciii I
E
"The Effect of LIFht Cases or. the Nosorption STC--tra of 'Vepors of
[womatic Compounds," o paper stibmItted at the interwitionel iiecLiliL, of A .?
Diropean 114olecular Spectorscopists, Freiburg, Brelugau, West Cerawiiy. / )lfal
y 0 ~l

4,9-4-21/23
i
AUTHORS: F. Belov,
S. Kep_qrent, 0. D. Dmitriyevskiy,
G-.W-.-Zaytsev' G. Kastrov,
L. A. Kudryavtseva and I. V., Patalakhin.
TITLE: Experience gained in direct measurement of the distribution
of the humidity of the atmosphe.-ce by means of thd ,spectral
method. (Opyt pryamogo izmereniya vysotnop raspre'-deleniya
vlazhaosti ataosfery spektralln,7m metodom).
FERIODICAL: Izvestiya Akademii Mauk Seriya Geofizicheskay4,
1W. No.4, pp. 552-555 (56SR).
ABSTRACT: Some recent American communications (Refs-5-7)'refer to
investigating the spectrum of the Sun in the infrared
range during flights in the upper layers of the atmos0ere,
in which observation of absorption bands of water vapours.
are mentioned and views are expressed on the possible
concentrations of these vapours. In this paper the results
are described of the first attemDts to determine directly
the content of water vapour in the atmosphere by means of
specially designed spectral apparatus. The operation of
the instrument was described in detail by Keporent, B.S.
et alii (Ref.8); itO.~qonsists of a step-wise vacuum
monochromator with~&! diffraction lattice of 300 lines/mm
Card V4 of the size 50 x 70 mm which subdivides the infrared range

49-4-21/23
Experience gained in direct measurement of the distribution of
the humidity of the atmosphere by means of the spectral method.
into five sections (1.24, 1.409 1.50, 1.88, 2.2 It), the
wave-lengths 1.40 and 1.8811 belong to the absorption bands
of water vapour; utilisation of two bands is provided for
extending the range of the measured water concentratiorns.
The wave-lengths 1.24, 1.50 and 2.211 fall between
individual bands and serve for determining the initial in-
tensities in the bands 1.40 and 1.884 by means of
interpolation. The linear dispersion of the instrument
equals 100 a/mm; the entry and exit slots are 1.5 mm wide.
Illumination of the input slot is effected by means of a
source with a circular emanating surface fitted with a
dispersion plate of magnesium oxide. Experiments carried
out at ground level showed thatin the operating range of
the spectrum, the role of radiation scattered by the sky
is insignificant. The measured radiation is modulated
with a frequency of 850 c.p.s. using as a receiver of the
radiation a cooled PbS photo resistance. After
amplification the signals are transmitted by radio to the
ground. In ;Adition to the basic signals transmitted in
the operating position of the diffraction lattice (which
Oard 2/4 is turned by means of a cam),, calibrating signals are

49-4-21/23
Experience gained in direct measurement of the distribution of
the humidit7 of the atmosphere by means of the spectral method.
Card 3/4
transmitted and also signals from the pressure gauge, etc,
The respective switching is effected by means of a
commutator which is coupled with the cam for scanning of
the spectrum. The full cycle of the instrument is 2.5 sees
and, therefore the slow changes of the location of the
scattering plate of the light source relative to the Sun's
rays caused by random oscillations of the instrum;eat
during free flight should not affect the results bf
determination of the relative intensities of the adjacent
parts of the spectrum. The results are plotted in graphs.
rig.1 shows the calibration curve obtained on the basis
of the exponential law; Fig.2 shows the graduation.curve
obtained on the basis of the square rooti Fi 3 showe a
part of the absorption band of water vapour ~i.41L)
measured on the spectrometer with altitude scanning, whereby
the spectral width of the slot is shown at the bottom part
of this Figure. Fig.4 shows the dependence of the
absorption function A on the altitude (UP to 17 km) for
the band 1.41L; Fig-5 shows the dependence of the quantity
of water precipitating along the vertical on the height
reached by the instrument;-Figi.6 shows the dependence of

49-4-21/23
Experience gained in direct measurement of the distribution of
the humidity of the atmosphere by means of the spectral method.
water concentration in the atmosphere on altitude, in
mm of water precipitated per 1 km of the layer. Although
the obtained data require further checking, they do
indicate the usefulness of the described method and
apparatus for such measurements. Increased accuracy and
sensitivity of the instrument for measuring low water
concentrations could be achieved by using more intensive
absorption bands.
There are six figures and 12 references, 4 of which are
Slavic.
SUBMITTED: November 13, 1956.
AVAILABLE: Library of Congress.
Card 4/4

N&FORW B- 5-
51-2-10/15
CarA
AUMRSI Mdtr*wijJd& O.D.., Separeat,, B.S. and Ifikitin, V.A.
TITLICt.4 high-speed infrared spi-aTE-5-d--mr-for the 0-8-3-0)z region.
(Skorostnoy infrakraa4yy-sp*ktrometr'd2ya oblasti'0-8-3 0/,&).
PNRI=CALs fOutika I ftektrookovi 0 tics and Spectroscopyi
V0103, No.2,, pp.1 ~0191 (U.S.S.R.)
ABSTUM ~Q_OIW12t _trazelatjon; The usual methods of measurement of
the. Infrared (le re I spectra require considerable time and can
therefore be used to study only sufficiently stationary ob-
jects. There exists a number of problems where rapid measure-
meat of.the L.r. spectra would yield importaat theoretical and
practical results. We constructed a laboratory model ofa
high-speed spoctroxoter with a PbS receiver for the region
0. .3.0fis. In, the monochromator interchangeable dispersing
elements.wore used: a li%hL=fIuorJd* prism and an echell
reflection diffractioa grating. RapId scanaing of the spectrua
was itchieved by m4ans of an oscillating plane mipror. A, wide-
band amplifier (with a time constant -V*5 x 10-0 sea) and vi.
bration (string) and electron (cathode-ray) oaaLlIagraphs were
1/2 used for,recordiag the spectra. The vibration-ogaillograph re-
cord represents a succession of "mirror" pairs of spectra of a
a*lecttd portion of an object, as showa-ia Fig.l. Pulses from
an additional source /Ref.l/ art used for wavelength calib-
ration, (as in oncillogram 2,1a Figel); the time scale is given
by a 2000 c/a siausoidal trace (-ahown In, FIg.lq 1 and 2). The

51-2-10/15
A high-speed Wrared spectrometer for the 0.8-3-OPregion WxQ
vibration osaillograph has the greatest inertia (It= 5 x 10-5
sea) in the system employed At, higher recording speeds this
causes "Smoothing" of the s;ectra. When a cathode-ray oscillo-
graph (e,r.o.) is-used, the apparatuo is limited on1y by the
inertia of the receiver (,V* 2 x 10-2 see) which makes it poss-
ible either to Increase the recording speed or to improve the
resolutton at the aame speed. Spectra obtained with a c.r.o. are
shown in Fig.2. This-figur
,# &bows that, on recording spectral In-
tervals of ACkXvm. 001A& in time at,* 0'.001 sea the spectrometer
has a resolving power Pg6250 (in the region 2.0-2.5,~&) and is
therefore an improvement on the iastr=eats described in the
literature. Fixure Caotiods. Liz. : Beazeas absorptioa band at
2.2 p(l) and.abloroform spectrum at 0*8;2.5p (2) recorded with
a vibration oscillograph (the 2000 c/o Lausoid gives the time
scale). A and 6' are the two amirror! spectra, the distauce b 'a-
twee4,th#m being roughly equal to the half-period of the scaim-
09rd 2/2 alag mirror. The recording speeds aret 60 spectra/sea (1) and
120 spectra/sec (2). F:Lz*2: The corsoo-recorded spectra. 1. 2#3
represeat respectively benzene absorption at 1*7 and 2.2t and
tmospheric pti
a water vapour abaor on at 2.6A*. Recording t mes
seWare shown in the figure6 R f I/I/ B.W.Bullock and S.
0 a. J. Oot Soo Am. 4 gogr8nees
SUBMIAR a rua;y-zb; 197'r- (1950
AVAILARTMS Libreryof Congmes'

1:~:,e /e E /V 7- /6, S,
AUTHORS: Yeporent, Bo So, Vasilevakiy, Ke Pe, Lapina, 14. A.
ana FurvenkoV-, V. A.
TITLE: A Vacuum Spectrometer with a Diffraction Grating for the
Oo7-3," Spectral Region. (Vakuumnyy spektrometr a
difraktsionnoy reshetkoy dlya oblasti spektra 0.7-3p.)
PERIODICAL: Optika i Spektroakopi7a, 1957, VoloIII, Nro3, pp.289-293.
(USSR)
ABSTRACT: This paper desoribed apparatus of high revolving power
for obtaining spectra in the region 007-3r . It consists
ofa mording vacuum, spectrometer with a d ffraction
grating and a call which light Is made to traverse many
times so that its path length in the vessel can be 180 m.
This apparatus is suitable for recording of spectra of
rarefied or weakly absorbing gases at temperatures from
room temperature to 10000. The optical part of the
apparatus is shown in Figl. Fig.2 shows the general
view of the apparatus with the control panelo The cell
used in this apparatus follows in its construction Refo
14 and 15. The diffraction grating used is of eehelette
Card 1/3 type, 150 x 150 mm, with 300 lines per millimetre. This

51,-3-13/14
A Vacuum Spectrometer wit h a Diffraction Grating for the 0.7-3 /14
Spootral Regiono..
grating reflects 75% - of the incident light at 2
:65% at 1. 5, 0" and 60%_ at ~2.*.3 /.40 The monochromiLter used
follows.Ref*16.. The speotroketer is placed in a vacuum
chamber (0.1 11M, Ag-) T'Jae signal X alls on a PbS
photoresistanae and Is amplified-4p - For this purpose
the~iqaldent;U ght Is modulated by a perforated disc at
550 q/* frequency. This apparqLtus makes it possible to
resolve spectra-do.wn to 0.1 =-'* rige4 shows radiational
iine-s'of water vapours near 3900 am--L obtained uaf*g the
apparatus described. The #lit width was 0.06, cm-4 and
lines approximately 0,1 am-* distant from each oeher are
resolved. This means that the resolving power of the ,
instrument reaches 40 000, and this corresponds to 45 000
resolving power of the diffraction grating. Fig.5 shows
absorption, spectra of water vapours near 2.7 /& obtained
using path lengths of 8.8 (broken curve) and 120.8
(continuous curve) metres respectively,* When the
container used was of quartzabsorptioa and emission of
Gard.2/3 carbon dioxide could be measured with this-apparatus.

51-5-loAl
AUTWRS: Nepo rent, V.S'. and Klochkov, V~.P.
TITLE: On the Mechanism of the Effect of Light Gases on the
Absorption of Vapours of Aromatic Compounds(K voprosu, o
mekhanizme deystviya legkikh gazov na pogloshchen-iye
parov aromaticheskikh soyedineniy)
PERIODICAL ": Optika i Spektroskopiya, 1957, Volr*III9 Hr 5v
pp.529-535 (USSR)
ABSTBACT: The first of the authors has shown (Ref'.1) that light
gases andt in particular, helium, have an effect on the
intensity, of the electron absorption spectrum of
0-naphthylamine vapours. In a subsequent work (Ref.2) it
was shown that the phenomenon occurs,in vapours of
3-dimethy-lamino-6-aminophthalamide and therefore is of a
quite general nature. The phenomenon takes the fbrm of a
considerable decrease in the absorption coefficient of the
vapours when light gases are added to them but is not
accompanied by a change in the form of the s ectra. The
qL*~sorptionavefficient E of the VaPoUrS uNer investiga-
ti gradu y decreases as the vapour pressure of the
added gas increaseav, or, as the number of collisions, z
between the molecules of the vapour and those of the added
Card 1/?

51-5-10/11
On the Mechanism of the Effect of Light Gases on the Absorption
of Vapours of Aromatic Compounds.
gas increases. The reduction in the value of the absorp-
tion coefficient ceases at a certain value of z and re-
mains constant thereafter (Fig~.2). It was established that
the limiting value of the ratio e,,,, to s0 reached under
the action of helium decreases when the vapear pressure,
PR t decreases or the temperature increases. Results
support the hypothesis of the existence in the vapours of
intermolecular interactions at "large" distances. From
the energy dependence of the limiting absorption an estimate
is made of the energy necessary for the formation of an
excited st�Lte of a 3-aminoPhthalamide molecule on collision
with a helium atom. Using the example of acetone and benzo-
phenoneq it'is shown that the phenomenon under investigat-
ion is characteristic for most aromatic compounds.
There are 4 figures, 1 table and 7 referencesv 6 of which
are Slavic.
SUBMITTED: March 11, 1957.
AVAILABLE: Library of Congress.
Card ?/?

20-114-3-20/60
AUTHORSt freporento B. Sol Kloohkovt V. F.
Z------ L--
TITLE# The Dependence of the Absorption Spectra of the Vapors of
Organic Compounds on Concentration (Zavisimosti spektrov
pogloshcheniya parov organicheskikh soyadineniy ot kontsen-
trataii)
PE.RIODICALs Doklady Akademii Nauk SSSR,,1957,Vo1-41140Nr 3,PP0524-527(USSR)
ABSTRACT% Anthracene (1), 3-acetylaninophthaliaide (II), 3-aminophthal-
imide (III) and 3-dimethylamino-6-aminophthalimide (IV) were
used as test objects. The molecules of substance I which has
spectra with partially permitted structure belong to simple
monstomio molecules. in substances II, III and IV continuous
spectra were found which belong to complicated multiatomic
spectra. On transition form II to III and IV a transition from
nodulatiozi.spootra to fading speatra takes place. The device
used in the measurements was already described in an earlier
,paper. The results of the most important investigations are
compiled in a diagram. The values of concentrations belonging
to these curves and the intensities of the bands are compiled
Card 1/3 in a table. Then the concentration changes within a certain

20-IU -'-20/60
The Dependence of the Absorption Spectra of the Vapors of Organic Compounds
on Concentration
interval the form of the absorption spectra also changes. The
character of the changes and above all the domain of the
concentrations In which these changes occur depend on the
type of molecules to be investigated. The authors here examine
the character of these changes taking the vapors of 3-amino-
phthalimi4~ as examplIg The reduotioi of'the concentration
fro= 6-10';' to 20A'10'1~' molecules/ca does not cause any
change. in the form of the speq~rua. Upon further reduction
of the concentration tn 0,100';~ molecules/cm--' the band
slightly narrows and besides it is displaced toward the side
of higher frequencies. Thereafter traces of an oscillation
structure of the spectrum also occur. Upon transition from
anthracene of 3-amino-phthalitaide the lower limit concentra-
j tiont at which the form of the spectra begins to change, de-
creases. The Intermolecular interaction im reasee with in-
creasing innermolecular interaction. Finally some provisional
remarks are made on the nature of the Intermolecular inter-
actions to be investigated. There are I figure, I table, and
Card 2/3 13 references, 8 of which are Slavic.

I
20-2U 1--20/60
The Dependence of the Abaorption Spectra of the Vapors Of Organic Ccmpounds
on Concentration
PRESEMN January 14, 1957, by A. 11. Terenino Member of the Academy
SUBUITTEDs January 9. 1957
Card 3/3

WORM. B. S.
4~ ~
"The Status of Nalecular SpectroscoW in Soviet Countries: Theory of
Characteristics of vibration almetra, 191,stemtic studies of &~ :E~pectra,
Study of water-vapor spectrum in the reeions 50-150 and I to ') . 0
Faper presented at the Joint Cm--Assion on Spectroscopy and Iflith aeneral AssezWy
or Intl. Astronmideal Union. Hasbow, Aug 195k
12-15

51-.4'-2-2812e"
AUTHIORS: Kaliteyevskiy, N., Neporent, B. and Feofilov, P.
XI-th Oonfc-2:ence on Spectroscopy. (XI soveshchaLiye
po spektroskopii.)
PERIODICAL: Q Vol.Ijr,
ptika i S,.ektroskopiya, 1958, ITr.2, pp.282-281,
(USSR)
Ai-D&Ni4LOT: XI-th Conference on ISpectrosco];) . or5inized by the
Spectroscopy Conudesion of the leaden, of Sciences of
the USSR, vraz held in 1-iloscow on 2-10 iLcember, 1957.
This Conference was limited to the problems of physics
of atcnic and molecular spectra and to spectroscopy of
solid bodies including luainescence methods. 600
delegates from 36 Soviet towns took part in the
Conference, as well as 12 foreiga visitors from, 8
countries. The Conference was opened by S.L.
Mandellshtam and a review lecture of S.B. Frish,
'Soviat Spectroscopy in the Last 40 Years" was heard.
r
In 1 plenary and-12 sectional sessions about 130 papers
were read. Ovor 30 papers were on atomic spectroscopy,
about 60 dealt with uolecular spectra and the reminder
were concerned with the spectroscopy of solid bodies.
Card 1/3 A more detailed report of this Conference will be

XI-th Conference on SpectroscoPY. 51- 4-2-28/28
published in "Uspekhi Fizicheskikh Nauk". In atouic
spectroscopy the papers dealt with four main problems:
(1) calculation of ener(,7 levels of atous and determin-
ation of atuoluic. constants, (2) inteniction of the
nucleus with the electron envelope, (3) spectroscopy
of gaseous discharges, (4) spectroscopic methods of
deteimination of teuperature. The largest nunber of
papers presented at the Conference dealt with molecular
spectra. The subjects reported on included electron
and -vibrational spectra, Raman spectra, rotational spectra
and Rayleig~a scatterinG of light as v..-ell as dispersion
in orGanic substances. Papers on crystal spectroscopy
dealt with the followinL probleL~s: (1) spec'UroscoD17 of
Laolecular ci-jztals, (2) spectroscopic detectlion of
excitons, (3) spectroscopy of ionic crystals containinC
activatin- cen:La.-es, (4) spectroscopy of colour centres in
ionic crYs'Gal_-. Papers on -spectroscopic instinments
wei,e also read at the Conference. In spite of limitation
of the subjects dealt with at the Conference, the
sessions were overloaded and further limitation of the
Card 2/3 subject is sug-ested for the next conference. The
C-)

XI-th Conference on Spectroscopy.
general conclusions are that the spectroscopic theory
has reached a higher stage of development. IiVrther
advances vve2e made in the infrared spectroscopy as well
as in radio-spectroscopy. Spectroscopic investigations
of gaseous dischar6tes and the viork on Raman scatterin-
were well represented. The number of papers on
spectroscopy of solids had increased and -t-he technique
of spectroscopic studies has improved.
1. Conferences-Spectroscopy-Kascow 2. Spectroscopy-USSR
Card 3/.3

AUTHORS: Vasilevskiy, K.F. and4o=aat. 'II.S- Sov/51-4-4-7/24
TITIZ; Dependence of the Infra-red Absorption by Water Vapour
on its Concentration and on Path Length for the Case of
a Separate Line and for a Group of Lines in the 2.7 11 Band
(Zavisimost' pogloshcheniya infrakrasnoy radiatsii parami
vody ot koatseatratsii i d1iny puti v sluchayakh otdel'noy
linii i gruppy liniy polosy 2.7 10
PMUODICAL: Optika i Spektroskopiya, 1958, Vol IV, Nr 4,
pp 474-480 (USSR).
ABSTRACT: A preliminary communication on the subject of the
present paper was given atthe Tenth Conference an Spectroscopy
on July 129 1956. The paper gives the results of measuremen is
of the infra-red absorption by a single line at 4 025.38 cm-
and by a group of 9 lines in the region 3 970-3 978 cm7l which
belong to the -4 3 and -J, bands of water vapour. Concentration
of water vapour Cms vLried*XraVL2xJD.-7' to 45-5 x 10-7 201/eM3
and absorption path lengths were from 8.8 to 1G0.8 m. The
part of the spectrum containing Vie4025.38 cm-1 line is shown
in Fig. 1. The group of 9 lines in the region 3 970 - 3 978 cm
is given by arrows in Figure 2, whicJh represents the spectrun
Cardl/5

Sov/51-1; 4-7/24
Dependence of the Infra-red Absorption by Water Vapour on its
Concentration and on Path Length for the Case of a Separate Lin
and for a Group of Lines in the 2.? IL Band
obtained at a water vapour concentration of 7-37 x 10-7 mol/cm3
and absorption path lengths of 8.8 and 120.8 m. The equivalent
width A was determined by integration of the spectral curves
by means of a planimeter. Dispersion of the spectrograpt was
2.5 cm7l/mm in the region of interest and the beat resolui-ion
was about 0.1 cm-1. A lead sulphide photo-resistance was used
as the receiver. A multiple-passage cell had a construction
similar to that described in Refal?, 18. The cell temperature
was 60 00 in all ex1jeriments. xhe results of measurements for
the 4 025 cm-1 lines are given in Figure 3 in the fo_-m of
dependence of the equivalent width A on VTI - Figure 3 shows
that or A from 0.1 to 0.9 cm A is in fact proportional
to A linear dependence o A/C on 4-L for the
4 025 cm7l line is shown in Figure 4 for the tango of values
of A from 0.1 to 0.9 cm7l. Departures from straight lines in
Figures 3 and 4 are observed at low concentrations (Curves 1
Card2/5

sov/51-4-4-7/24
Dependence of the Infra-red Absorption by Water Vapour on its
Concentration and on Path Length for the Case of a Separate Line
and for a Group of Lines in the 2.7 1z Band
and 2 in Figure 3 and at high concentrations (Curves 7
and 6 in Figure B. In Figure 4, Curves 1, 2 and 7 show
departures from the general trend. The departures at higher
concentrations (at values of A greater than 0.9 cm7l) are
due to overlapping of'the studied line (4 025 cm 1- ) with its
neighbours as shown in Figure 1. Departures at low concen-
trations are due to a decrease in the line width when the
Doppler width can no longer be neglected as compared with
the collision width. The results of measu;ements of the
equivalent width A for the 3 970-3 978 am" group ar, shown
in Figure 5 in the form of a dependence of A on at .
The square-root law is observed up to values of about
2a--2-5 CM71- In the region of applicability of the square-
root law, the angle of slope of the rectilinear portions of
curves of Figure 5 is proportional to the squAre root of
the concentration of water vapour C. This is confirmed by
Oard3/5 Figure 6 which shows dependence of A/C on IT . The black

sov/51-4-4-7/24
Dependence of the Infra-red Absorption by Water Tapour on its
Concentration and on Path Length for the Case of a Separate Line
and for a Group of Lines in the 2.7 U Band
circles and the continuous curve in Figure 6 correspond to
the rectilinear portions of the Curves 2-5 of Figure 5.
Figure 7 repeats the results of Figure 5 in the form of a
dependence of A on logkCl) . In this case, the points
for values of A [~Teater than 2.5 cm-1are found to lie on
a family of parallel lines. Such a logarithmic dependence
for absoprticn due to a vibrational-rotational band was
first suggested by Elder and Strong (Ref 10). A more
precise expression, in which dependence of the line-width on
concentration was taken into account, was obtained for
"strong" absorption bands of water vapour by Howard, Burc-h
and Williams (Ref 9). The rectilinear portions of the
curves in Figure ? follow the equation obtained by Howard
et al. for dependence of A on C and
Card 4/5
4.

Sov/51 'I '1 7/24
Dependence of the Infra-red Absorption by Water Vapour on its
Concentration and on Path Length for the Case of a Separate Line
and for a Group of Lines in the 2.7 tL Band
There are 7 figures and 20 references, 16 of which are
in English, 3 Soviet and 1 German.
ASSOCIATION: Gosudarstvennyy opticheskiy institut im. S.I.Vavilova
(State Optical Institute imeni S.I. Vavilov)
SUBMITTED: June 19, 1957
card 5/5 1. Water vapor--Spectra

AIMOR t _nmnt_E~ 51-4-5-28/29
TITM Kinetics of the Effect of Light Gasai on the Intensity of
Absorption Spectra of Aromatic Compound Vapours (Kinatika
daystviya legkikk &sLz0V_'n% intensivnost, spelctrov pogloshchani'ya
parov ar-siti char. ki kh; Boyed ineni y)
MIMI CAL Optika i Spektraskopiya, 1958, Vol IV, Nr 5. pp 703-705 (USSR)
ABSTRACT: This effect, discovered by the present author in 19~-5 (Ref 1),
consists of a decrease of the absorption by vapours of aromatic
compounds on addition of light gases (HO, H2, NO, Y2). The effect
is ascribed to collisions with light-gas molecules which causa,
changes in the structure of aromatic Laoloculas accappanisd by a
perturbation of the RE-alectron systm whIch is responsible for
the appropriate absorption band. Tha author gives a brief thaoratical
discussion of these collisions.
Card 1/2

51-4-5-98/90
Kinetics of the Effect of Light Gazes on the Intensity of Absorption 51)5cira
of Aromatic Compound Vapours
A fuller account is to be published elsewhere (Ref 5). Thera
are 3 Soviet references.
ASSOCUTION Gosudarstvannyy apticheakiy institut im. S.I. Vavilova
(State Optical Institute Imani S.I. Vavilov)
SUEUITTED: November 18, 1957
1. Arowatic compounds - Absorption 2. Molecules
Collision - Theory
Card 2/2

. NXXOUW# B.S.; MIFILOV, P.P.
Sixth conferenos on luminesceace, Opt. t spettr. 4 no. 6;810-811
A 158. (MMA 11:8)
(kelaesceace-Congresses)

AU TRW I Meporent, B.S. and Ba~-hshiyev, E.G.
TITIZ: latearAties in the O'psetra of rolyatmlo X-0161ulas (ratensivaosti v
rpeictr%kh mnorcatomnykh molsimli
PMODICAL Optiia I Spektrosicoplya, 1958, Vol 5, lir 6. pp 634-645 (USSR)
ABSTACTs The authors discues the effect of a solvocat an the magnitude of the
aboorption integral and the "cited-st&te lifetime, and on their
relationship in polyatomic moloo4loa. It is ahowa that the concept
of tAe intoGrai intensity of electron transitions may be applied
unreservedly only to complex polyatomic molecules. Foe simple
polyatomic molscul&i the autftora~fUA conditions and limits within
which this intogral intonsity still retaiw Its physical sons*. It
is also anown that a solvent may be regarded as &a external dielectric
medium in the case of complex anid some simple aolocuLes. Various
models of the myonea consisting of &a absorbing molecule and a golvent
are consiaered &ad it to found that the model in which a solvent is
regarded as an isotropic medium which "Imprepates" a molocsile to
untenable. Cor-roctirwa are fouW aecag;ary for themof.?4ok 4f;,,fte,
Ca rd l/ 3 internal field in ei-.4plation; ;.thor-*qjk(jt
~*!on applied

Intensities in the Spectra of Folyatecl4c Molecules SOY/51-5-6-2/19
may be that of Kravets (Rof 1) which in based on Lorentz's theory
or it may include the reactive field. The authors discuss their
own experimental values (Ref 19) of the absorption Integral and the
excited-state lifetime of vapours and solutions of plithalixide (I) and
five of its derivativess 5--acelylaminophthallmide (11).
3-aminophthallmide (111), 3,6-diaminophthalimide (IV),
3-dLmethylamino-e-aminophtti&llmide (Y) and 3,6-tetramethyldiazino-
phtbAllmide (VI). Only the last three (IV-VI) were reprded by the
authors as complex molecules. 112a absorption and fluorescence spectra
of vapours tthin curves) and othyl-alcohol solutions (thick curvegi of
substances I-VI, together with their structural formulae, are given in
Fig 1. The absorption and flaorascence spectra were constructed using
the data of Ref 19 and are normalized to equal areas. Fi&% 2 and 3
show theoretical and experimental valuer. of the corrections to the
absorption integral, which allow for the effect of solvent@. Table 1
gives the oscillator strangthm for the six substances discussed
(experimental data taken from Ref 19) both as vapours and as solutions.
The following solvents were used; methyl alcohol, water, other,
Card 2/3 n-heptsae. dioxane. benzene, haptans + benzene, ethyl alcohol.

inte4sitles In the Spectra of Polyatmic Koleculas
Fige, 4 and 6 show the corrections to the excited-state lifetimes
which allow for the effect of Solvents. Table '" lists these lifetimes
for substances 11-V1 (phthalimide does not fluoresce), both an vapoure
Mai as solutions (solvents as above). It was fouad that the
theoretical rel%tionahips a6ree with the experimental values *.an
Onsager's reactive field is alloved for. Semewhat Pooror agreement Is
obimined using Loreatz's correction. 7here are 5 figures, 2 tables
and 34 refereaces, 13 ef which are Soviet, 9 American, 8 Geman,
2 Onglish, I French and I butch.
SUMITTED: January 7, 1958
Ca rd -3/ 3

AUTHOR: Neporent, B. S. SO7/48-22-9-1o/',o
kTLE: --tr ~co~f'LightGaaes an the Electron Absorption Spectra
and the Interaction Bet-~,een the Molecules of Aromatic
Compounds (Deystviye legkikh gazov na elektronnyye sPektry
pogloshcheniya i vzaimodeystviye mezhdu molekulami aro-
maticheskikh soyedineniy)
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1958,
Vol 22 , Nr 9, PP 1051 - 105.'/ (USSR)
ABSTRACT: This abstract is a survey on papers dealing with in-
vestigations of the effect of light gases upon the
absorption of light by the vapors of aromatic compounds
(Ref 1); this effect has been discovered by the author.
Besides, the relation of this phenomenon with the
remote interaction between the aromatic molecules is
inveatigatod. Such intoractions were oboorved alao in
the course of other experiments carried out by the author
and Klochkov (Ref 2). As result of the investiffation
(Refs 1,3,4) a scheme of the observed phenomenon was
suggested. The light gases cause a weakening of the
Card 1/4 absorption in substances that contain chains of conjugate

Effect of Light Gases on the Electron Absorntion Spectra and SC7/48-22-9-1o/-~o
the Interaction Between the Molecules of Aromatic Compounds
bonds (save benzene). The collisions with the particles
of light gases cause changes in thestructure of the
investigated molecules; these changes are accompanied
by a violation of their n-electron systems and by a decrease
of the absorption. Because of experimental difficulties
and the limitations of the spectral range accessible
to investigation, which are resulting from these
difficulties, the experiments to discover the structural
rebuilding of the molecules in the transition from the
state N into N' (according to the alteration of the
infrared spectra of the vapor) have not brouaht any
definite results as yet. The totality of experimental
facts allows to assume that the investigated interactions
(Ref 6) are connected with the displacements or other
alterations of the n-electron shells of the molecules.
It is very difficult to study this phenomenon by using
the alteration of the spectra as a vehicle of investigation.
The results obtained from the analysis of the effect of
Card 2/4 light gases upon the absorption by vapor are decisive.

Effect of Light Gases on the Electron Absorption SOV/42-22-9-1,o/4o
Spectra and the InteracLion Between the Molecules of Aromatic Compounds
If the coefficient 4. is introduced they allow to
nvestigate the interaction between the molecules
N-N quantitatively. To a certain degree of probability
it can be assumed that these interactions can be
described being of a dipole-dipole type; on this
occasion the theory developed earlier by Vavilov
(Ref 7) and lately by Galan6v (Ref 6) can be applied.
The investigations probably will help to explain the
mechanism of the intermolecular relations N-11 as well
as preventive measures against the Iinteraction with
the atoms of light gases (N+A -4 F+A). There are
2 figures and 8 references, 8 of which are Soviet.
Card 3/4

24M '- SOV/48-22-11-20/33
AUTHOP- _____Jepama_J1_ S
TITLE: Relation Between the Absorption- and Luminescence Spectra of
Polyatomic Molecules (Svyazl mezhda spektrami pogloshcheniya
lyuminesteentaii mnogoatomnykh molokul)
PERIODICAL: Izvestiya Nkademii nauk S!T~R, 13ertya fizicheskaya, 1958, Vol 22,
Nr 11, pp 1572-1576 (USSR)
ABSTRACT: In this paper the author presents a solution of' the problem of
the relations between the absorption- and luminercence spectra
of molecules, which was obtained by a method, logically quite
opposed to that used by Stepanov (Ref 9). The author proceeded
from the assumption that between the absorption- and emission
spectrum of a system which is in thermal equilibrium there must
necessarily exist certain relations. The information collected
substantiates that the differences in the spectra as demonstrat-
ed in references 1, 2, and 14 are always preserved. For this
reason they will have to be sabjected to further investigation,
just as other differences of the molecales which correspond to
different relations of the spectra. The considerations advanced
Card 1/3 In references 12 and 1 concerning the generation of the two

SOV/48-22-11-20/33
Relation Between the AbsorDtion- and Luminescence Spectra of Polyatomic
fdolecules
types of spectrum cannot be considered to offer a final solution
of this problem. This was also remarked in reference 1. Never-
theless they permit to draw certain conclusions on the nature
of the relations between the spectra and the character of
molecular interactions. Among the results thus obtained the
solution of the problem seems to be essential, whether it is
necessary to take into account the interdependence of the
electron states and of the nuclear structure with the electron
transition of the molecule skeleton and the electron cloud,
respeotively. From this the necessity of a relaxation proceeds.
If this process is taken into account a system of electron
states is derived, which can be represented by a four-level
scheme (Fig 2). The degeneration of such a scheme into a two-
level scheme (Fig 1) is, within the limitations of this study,
a special case for complex molecules, just as is the exact
mirror symmetry of the spectra. Real complex molecules poesess
a system of electron states of the type portrayed in figure 2,
which more or less deviates from the idealized scheme (Fig 1)
Card 2/3 which has hitherto commonly been used. The boundary form of the

:N 1 , -2015 ~5
Reia,on Ret uen the, -1.us(.)rp6iofi- ana Lumineccenec "p(-ctra oi F, Iyatomic
Molecule3
ir.terreiations t,tie irveio iv, I kg-r(? 2 1:; not, kno.,.n. 1-or
tne boundary cass- sp(-~,-Lra nave beon i'o.),-,d i.~ieh are de-
scribed by tne relation &V - kv it rplation.
between the widtns of tne acsorp,.ion. rinct rpt~ctra
must serve for a determination of trio ;.rt;rtnrties 1,;.. tne 1Pvel
systeins. Further i nve* t igat ions mu6L tirjow to whit' cA,"'4-ree the
wiOth of the typical damping spectra, is dependent upon tn-F'
relaxation rate of the molecular system aiter an electron
transition. In ,,,ome cases the scheme presenteti in tig~_rq ) ~110,o
applieD to moiec;jies wtj, mcitiulat-inn srecTra. '11here are 5
figurec, I tabip. ana 11, references, 1) of -;.;i-,ich are soviet.
Card

~4 (7), SOV148-22-11-22133
AUTHURSs Alentsev, M. N. Neporent, B. S., Agranovich, V. M.
TITLM Discussion of the 1~,eotures -by B. 1. Stepanov, B. S.
Neporent, M. N. Alentsev, and L. A. Pakhomycheva (Preniya po
dokladam B. I. Stepanova, B. 13. Neporenta, M. N. Alentseva i
L. A. Pakhomychevoy)
PERIONCALs Izvestiya Akadenii nauk S:M, Seriya fizicheakayq, 1958, Vol 22,
Nr 11, pp 1379-1379 (USSR)
ABSTRACTt U. N. Alentaev comments an the lecture given by Stepanov as
followst The equation specifying the energy of individual
frequencies of the emission spectrum is determined only by the
distribution of the molecules on the excited levels and by the
probability of the corresponding transitions, if a forced
emission and an interaction of the excited molecales is practi-
cally absent. Hence the luminescence spectrum under these con-
ditiona must be similar to the spectrum of thermal emission, and
that means lum DI This conclusion demonstrates that
W~ - -YOV'V,T-
if Stepanov's relation is satisfied, this only indicates that
Card 1/2 the equilibrium distribution of the molecules with an excited

SOV/48-22-11-22/33
Discussion of the Lectures Held by B. 1. Stepanov, B. S. Neporent, U. N.
Alentsevt and L. A. Fakhomycheva.
electron state is stabilized with respect to the oscillation
energy. If this relation is not satisfied, it can be proved
that at the moment of emission the distribution is not an
equilibrium one. It then corresponds to a distribution charac-
terized by a temperature TO t T.
B. S. Neporent comments on the lecture held by R. N. Alentsevt
It appears to 6e difficult to approve of the assumption that
the excited molecules in solutions do not reach a thermal
equilibrium in due time. This assumption is at variance with the
experinental data on the transfer rate of the oscillation
energy. Moreover it does not furnish an explanation of the diver-
gencies found in several investigations.
V. M. Agranovich agrees with Stepanov concerning the joint re-
lations between the luminescence- and absorption spectra. He
rejects, however, his conception concerning earlier papers (A.
S. Davydov, S. 1. Pekar, M. A. Krivoglaz, and others) and thinks
that the equation found by him should be compared with the re-
Card 2/2 sults presented by other, earlier theories.

Wq~~Bl~ , doktor ftziko-matemattehaskikh nauk; FEWILOT. P.P., doktor
ficilco-matematichaskikh nauk
Molecular fluorescence and fluorescence onmijeje; conference in
Losaingrad. Test. AN SSSR 28 no. 6:108-110 Js '58. (HLRA 11:7)
(Laning--,-ad-Ifluoresci-nce--Congreseas)

53-64-3-4/8
AWTHORS: Dmitriyevskiy, 0. D. ,Ileporent. B_ 3. , Nikitin, V. A.
TITLE: High-Speed Spectroscopy (Skorostnaya spektrometriya)
PERIODICAL: Uspekhi Fizicheskikh Nauk, 1950, Vol. 64t Ur 3, PP- 447-492
(USSR)
ABSTRACT: The present survey is divided into parts as follower the
main rules for the registration of the spectra in scanning,
i.e. of the development of the spectrum with respect to time
to be investigated (the general time equation of the spectro-
meter, the distortions in form of bands by the monochromator
as well as by the receiving- and recording system, of the re-
solving pover of the speatrove-ter as a whole, the mutual
connection of the energy an,11 -.Ime characteristics of the
spectrometer, the relatiens oz, high-speed recording of the
spectra in scanning). The ap.-Arstus for high-speed spectro-
scopy (the apparatus for the infrared region with thermal
receiverag and with photo-resistances, apparatus with photo-
-multipliers and photo-cells with external photo-effect, ap-
Card 112 paratus with electronic scanning, multi-channel spectral

High-Speed Spectroscopy
53-64-3-4/3
analyzers and cinespectrographs, the comparison between the
parameters of high-speed spectral apparatus). The highest
speed of recording is obtained with the best inertialess
PbS-receivers using a: circuit breaker. The tendency to develop
higher registration speed with given (thermal or semicon-
ductor-)receivers inevitably leads to a decrease of the re-
solving power as well as to an increase'of temporal dis-
tortions, which is tolerableg howevert only in exceptional
cases. Acocrding to the authors' opinion the so-called appa-
ratus Kr~8 is beat approximated to optimal operational condi-
tions. For a PbS-receiver this apparatus has a rather high
speed (v e-10~') and also the resolving power remains suffi-
ciently good. Above allIthe distortions in this apparatus
are not great. A table gives the publishe#ata on high-speed
spectral apparatus of various types. There are 29 figuresq
2 tables, and 71 references, 18 of which are Soviet.
spectAdc6j~llli~k 2. Spectrographic analysis--Equipment
Card 2/2

AUTHORS: Kaliteyevskiy, 1f., Neporent B. Feofilov, p-65-1-6-110
TITLE: Transaction of the XI* Con ass on Spectroscopy (XI Sove-
shchaniye po apektroskopiiFI. Atomic Spectroscopy (I.Atomnaya
spektrookopiya)
PERIODICAL: Uspekhi fizioheakikh nauk, 1958, Vol. 65, Nr 1, pp. 141-145
(USSR)
ABSTRACT: The XI. Congress on Spectroscopy was held at Moscow from
December 2 - lo, 1957. The program was devoted to physical
problems of atomic and molecular spectra and to the spectra
of solids. The congress was attended by 6oo delegates from
36 cities of the USSR, as well as by 12 foreign scientists
from Great Britain, Eastern and Western Germany, China,
Roumania, the USAp France and Yugoslavia. (The X. Congress
on Spectroscopy held at L'vov in 1956 was attended by about
15oo delegates who delivered 3oo lectures). The XI. congress
was arranged in 7 plenary meetings and 12 sectional meetings,
in the course of which more than 125 lectures were held, 3o
of them dealing with atomic spectroscopy, about 6o with mo-
Card 1/3 lecular spectroscopy and the remainder with the spectroscopy

53-65-1-6/lo
Transaction of the XI* Congress on Spectroscopy# is Atomic spectroscopy
of solids. S. L. Mandel'shtam opened the congress. S. S.
Prish held the opening lecture; "40 years of Soviet Spectro-
scopy" and the participants honored the memory of the de-
0098W Member of the koademy Go So Landaberg. The theoretic-
al and the experimental lectures concerning atomic spectro-
scopy dealt with 4 basic problems: The computation of the
energy levels of the atoms and the determination of the
atomic constants, the interaction between the nucleus and
the shell, gas discharge speatrosoopy, and finally to the
spectroscopioal methods of temperature determination. The
following scientists lectured or took part in the discussion:
Yu. ff. Demkov (computation of thaeaergy of the He-atom in
its ground state). ff. 0. Veselov, 1. B. Bersuker, A. P.
Yutsis and coworkerst L. A. Vaynahteyn, ff. P. Peakin, Yu. 1.
Ostrovskiy, L. ff. Shabanov (spectra of atoms with a filled
3d-shell), A. U. Shukhtin, V. S. Yegorov (application of
the "crotch-method" (met. kryukov) by Rozhdeatvenakiy for
the investigation of fast varying processes, e.go pulsed
discharges), Yu. P. Dontaov (investigation of about 6o lines
of Zr I and Zr II) 1W. G. Morozova, G. P. Startsev, A. R.
Card 2/3 Striganov (U 1, U 11 spectra), M. S. Frim, N. I. Kaliteyevokiy,

53-65-1-6/lo
Transaotion of the XI* Congress on Spectroscopy. 1. Atomic Spectroscopy
VO I. Perell, I. M. P. Chayka,(mapetio ond quadrupole-inter-
action between nucleus and shell), 9. R. 'Ratarchukova, G. F.
Drulcarev, Ve I., Ochkar (determination of the exciting
function for 9-atoms at low impact energies)t G. G. Dolgov,
S. E. Trish, 1. P. Bogdanove. (excitation of spectral lines
in the range of the negative glow), V. A. Fabrikant, Yu. K.
Xagan, M. A. Mazing, S. L. Kmdellshtam,(spectral line
broadening), V. I Ko ang Lokhte-Kholltgrevsn (Western
Germany), R. Ritche fNatern. Germany), r. V. Dvornikova,
K. ff. Sobolev, Bartel's (Western dermany)p A. L. LabudA, Ye.
G. Martinkov and 1. 0. Nakrashavich. Finally M. Z. Kho-khlov,
Lo V. Leskov and L. P. Vasil Oyeva reviewed the problem-:of-~,
the determination of the discharge temperature according to
molecular spectra.
1. Neutron spectroscopy-MR
Card 3/3

53-65-1-7/10
AUTffORS: Kaliteyevskiy, ff., Iteporent, B., Peofilov, P.
TITLE: Transactions of the XI. Congress on Spectroscopy (XI.Sove-
shchaniye po spektroskopii) II. Molecular Spectroscopy
(II Molekulyarnaya spektrookopiya) First Part
PMIODICAL: Uspekhi fizioheskikh nauk, 1958, Vol. 65, Yr 1, pp. 145-1511
(USSR)
ABSTRACT: This congress was held at Moscow from December 2 - lo, 1957-
The lectiftres on molecular spectroscopy dealt with the appli-
cation of these spectra to various scientific and technical
problems as well as to the suitability of the spectra for
special problems. The lectures dealt with the electron spectra,
vibration spectra and rotational spectra in the mentioned
order. L. A* Borovinskiy and M. N. Adamov, M. 0. Veselov and
T. K. Rebane spoke about theoretical problems of electron
spectral the latter in partinular dealing with the computation
of the electric and magnetic properties of molecules accord-
ing to the metal model. B. 1. Stepanov and L. P. Kazaoheako
Card 1A spoke about the agreement between the absorption- and luml-

53-65-1-7/10
Transactions of the XI. Congress on Spectroscopy. II. Molecular Spectro-
scopy. First Part
nescence-rangea in compoun& molecules; B. S. Reporent and
H. 0. Bakhshiyev as well as U. Do Galanin and Z. A.
Chizhikova deal? with intensity problems. A. 1. Nikitina,
No Do Galanin, 0. So Ter-Sarkisyan spoke about the connections
between optical characteristics and molecule structurep B.
No Kikhaylov, To To Zelinakiy, V. P. Kolobkov and 1. 1.
Reznikova dealt with the fluorescence and the phosphorescence
of frozen solutions. L. To Gurvich and 1. T. Veyn dealt with
the study of the equilibrium in flames for the determination
of the dissociation energy of diatomic oxides of the ele-
ments of the III. group and V. 1. Dianov-Klokov spoke about
the absorption spectrum of liquid oxygen in the temperature
range of from 77 - 153 0X. To L. Levshin and Ye. G. Baranova
lectured on concentration extinguishing (konteentratsionnoy
tuaheniye) in solutions. B. Y&. Sveshnikov, To I. Shirokov,
L. A. ]Cuznetsova and P. 1. Kudryaahov spoke about the kinetics
of fluorescence extinction, and B. So Neporent about new
investigations of the effect of light g&Se3 on the absorptioa
spectra of vapors and V. P. Klochkov about the long-distance
Card 2/4 interaction of aromatic molecules In gases. A. V. Karyakin

53-65-1-7/lo
Transactions of the XI. Congress on Spectroscopy. II. Molecular Specturo-
scopy. First Part
and A. V. Shablya dealt with the fluorescence extinction of
adsorbates,, V.-H. Gryazziov, V. D. Yagodovskiy and V. I.
Shimulis gave a report on the speatroscopical investigation
of the catalytic transformation on metal films sublimated
in a vacuum. V. I, Danilova, V. Do Golltsev and N. Aw
Prilezhayeva lectured on the spectrs~,investigation of in-
ternal- and intramolecular interaction in simple benzene
derivatives,and U. U. Belyy and K. F. Gudymenko spoke about
the influence of various anions and cations on th; lumi-
nescence of lead salts. A. A. KalXubin lectured on the
emission spectra of carbon and of the alcohols of the ali-
phatic series in an electrodeless discharge. 1. V. Obreimov
and I* Ya. Xachkurova reported on possibilities for the
representation of electron spectra-of molecules. Among the
lectures dealing with vibration spectra, that delivered by
1. 1. Sobeltman was about the quantum mechanical theory of
line intensity; U. No Sushchinskiy spoke about the results
Card 3/4 obtained by the experimental and theoretical investigation

53-65-1-7/10
Transactions of the XI. Congress on Spectroscopya II* Molecular Spectro-
scopy* First Part
of vibration spectra within the range of valence oscillations
of CH for some hydrocarbons. M. 1. Sitshchinskiy and V. D.
Bogdanov reported on the computation of the resonance inter-
action of totally symmetric valence- and deformation oscil-
lations of the CH-group for notmal hydrocarbons.
1. Molecular spectroscopy--USSR
Card 4/4

S_ 53-65-1-9/10
AUTHORS: Kaliteyevskiy, N.t Iteporent, B.9 Feofilov, P.
I - ~ 11
TITLE: Transactions of the XI* Congress on Spectroscopy.(XI Sove-
shchaniye po spektroskopii) III. Spectroscopy of Solids
(III.Spektrookoplya tverdogo tela)
PERIODICAL: Uspekhi fizichaskikh naukt 1958, Vol. 65, Nr It PP- 151-155
(USSR)
ABSTRACT: This congress was hold in Moscow from December 2 to December
lot 1957. The lectures on the spectroscopy of solids dealt
with the following basic problems* 1) Spectroscopy of mole-
cule crystals, 2 Problems of the spectroscopical electron
determination. 3~ Spectroscopy of ionic crystals with aoti-
vated centers and 4) Spectroscopy of color centers in ionic
crystals. The first lecture of this series was held by A. F.
Prikhottko (Kiyev) on the absorption and the luminescence
of crystals of organic compounds and on the influence of
structural factors and of-external actions on the electron
spectra of such crystals. V. S. Nedvedev reviewed the methods
Card 1/4 and the equipment serving for the optical and spectroscopical

53-65-1-9/10
Transactions of the XI. Congress on Spectroscopy. III. Spectroscopy of Solids
investigation of crystals at low temperatures. A. F. Prikhotlkot
I. Ya. Fagoll and S. Z. Shul$gi investigated th8 luminescence
of anthracene crystals in Dolatized light at 2o K,and V. 1.
Broude lectured on the Influence of deformations on the elec-
tron spectrum of crystals. A lecture prepared and held by a
group of authors of the Institute of Physics AS USSR and
from the Physical-Chemioal Institute iment Karpov (V. L.
Broude, Ye. A. Urailevioh, A. L. Liberman$ Me I, Onopri ankof
0. Be Pakhomovaq A. F. Prikhotlko and A. I. Shatensh=~
concerned the investigation of electron spectra of aromatic
hydrocar~bons and of their deutero-derivatives at 2o K. Me S.
Brodin. and Me S. Boskin. reported on anomaly investigations
in benzanthrene crystals. E. V. Shpollskiy communicated new
results of spectral investigations of aromatic hydrocarbons
in frozen solutions. With the theory of molecule crystals
dealt the lectures by A. P. Lubeheako and E. 1. Rashba, as
well as by H. D. Zhevandrov. A. F. Yatsenko reported on the
investigation of infrared absorption spectra of barium ti-
tanate crystals and of some seignette-electric substances of
Perovskite type. Ye. F. Gross and his coworkers devoted their
Card 2/4 attention to the spectroscopical electron determination in

53-65-1-9/10
Transactions of the XI. Congress on Spectroscopy. III. Spectroscopy of Solids
semiconductor crystalst as'well as B. S. Razbirin, V. V.
Sobolev and Lt. A. Takobsoaq E. and H. Griyo (France) reported
on structural analyses of luminescence spectra in CdS-crystals
at low temperatures; a similar subject was dealt with by
V. L. Broude, V. V. Yeremenko and E. I. Rashbat I, S. Gorbarx'
spoke about investigations of the temperature dependence of
11exciton" absorption spectra in cuprous oxide, Be I.
Zakharchenya reTiewed investigatiorLs of the Zeeman: affect in
cuprous oxide.-I. Z. Fisher gave a theoretical discourse on
the existence-conditions and the spectrosoopical determina-
tion-of the exciton. Great interest was aroused by the
lecture by S. 1. Pekar on the propagation of electrouaguetic
waves in a medium.-V. S. Mashkevich, Te. L. Feynberg spoke
about their propagation in crystals, and I..I. Sobellman
reported on colledtive oscillations of electrons in crystals
and Yu. Te, Perlin spoke about theoretical investigations of
light dispersion in crystals. The following lectures dealt
with the activating impurities in crystals: by H. 1. Petrasheal
Card 3/4 and T. L. Gultman, Ch..B. Lushahik and N. Te. Lushchik (lumi-.

Spectroscopy.
53-65-1-9/10
Spectroscopy of Solids
nescence spectra in alkali-halogen crystals) and H. L. Kats.
Lectures by V. A. Arkhangellskayaas well as by G. Dike (USA)
dealt with the Zeeman effect in crystals. V** T. Aleksanyan
reported on investigations of absorption spectra of compounds
of quadrivalent uranium and A. 9* Sevchenko gave a survey
of spectral investigations of uranyl compounds. I. V. Abarenkov
reviewed quantum mechanical computations of some properties
of the F-centers, V. H. Buymistrov and A* A, Shatalov re-
ported on similar problems. V. Ke Prokoflyev and7I. A. Shoahin
finally lectured on new designs of spectral apparatus.
Spectroscopy--USSR

AUTHORS: Nallmov, V. T. Keporent , B. S. SOV/53-65-3--8/11
TRW: System of Documentation of Molecular Spectra (SistaW
dokumentataii moleWjarnykh spektrov)
FMODICAL: Uspekhi fisicheakikh nauk, 1938, Vol. 65, Nr 3. PP. 521-540 (USSR)
ABSTRACT: On the basis of numervus photocopies the authors discuss the
various system used In Westem countries (especially in the USA)
for tabulating the spectra of individual ccmpounds including all
kzwwn data. The codes in use as well as punched-card systems are
discussed &."d ompared (for instance the WS and NBS systems).
Photocopies are reproduced of all system discussed. There are
16 figures, 2 tables, and 15 references, I of which is Soviet.
1. Molecular spectroscopy 2. Data-Analysis
Card 1/1

-AUTHOR: Neporent, B.-S. 20-119-4-15/6o
TITLE: General Relations Between Absorption and Emission for the
Modulation Spectra of Polyatomic Molecules (Obshchiye
sootnosheniya mezhdu pogloshcheniyem i izlucheniyem dlya
modulyatsionnykh spektrov mnogoatomnykh molekul)
PERIODICAL: Doklady Akademii Nauk SSSR, 1958# V014 119,
Nr 4, pp(, 662 - 685 (USSR)
ABSTRACT: According to the author's opinion the problem of mutual re-
lations between absobption spectra and emission spectra of
polyatomic molecules of all types can be solved in the same
manner as in the case of systems with narrow levels: the equi-
librium of molecules with equilibrium radiation is examined,
and in this way the characteristics of the individual molecules
are obtained. These characteristics are then used for the inve-
stigation of the luminescence induced In statlowry conditions.
The author here studies molecules which can be characterized
by modulation spectra. In such molecules the electron states
can be considered to be independent of the oscillation states.
Card 1/3 The conditions for the equilibrium of a system consisting of

General Relations Between Absorption and Emission for 2o-119-4-15/6o
the Modulation Spectra of Polyatomic Molecules
such luminescent molecules with equilibrium radiation are
apparently the following: A) The molecules must be distributed
over normal and induced states according to the lama of sta-
tistical equilibrium. B) According to the existing amount of
oscillation energy the molecules must be distributed over both
electron states. 0) The radiating power of the system investi-
gated must be a product of the aboorptim capacity and the
spectral density of equilibrium radiationt i.e. the luminescence
spectrum must agree with the spectrum of the thermal radiation of
the system. A formula for the condition of equilibrium is
written down. The author then introduces the experimentally de-
termIned quantities into the ekloulation: the molecular ab-
sorption coefficient, the spectral density of the quantum
yield of fluorescence, and the measured life of the inducel
state. The general expressions obtained here describe all
relations existing betweon the spectral absorption and emission
of polyatomic molecules with modulation spectra. These ex-
pressions apply in the same manner to simple polyatomic mole-
cules (in which the structure of the spectrum is conserved) and
Card 2/3 also to complicated molecules. The results obtained here seem,

General Relations Between Absorption and Ecission for 2o-119-4-15/6o
the Modulation Spectra of Polyatomic Molecules
by the way, to indicate the impossibility of describing the
spectra of atteamAtion by means of the scheme discussed. There
are I figure and 14 references, 12 of which are Soviet.
PRESENTED: December 9, 1957, by A. N. Terenin, Member, Academy of
Sciences, USSR
SUBMITTED: December 6# 1957
Card 3/3

iz-1
21M.24(o) pan : COOK EXPLOITATrof Sov,~32 1 PA
OOIM14110171k nOuk 33SR- PlZiohoakiy I-IStit-At
_U
loolodarbalya PC eksperlsentAl.noy I tooratichaskoy, Mike. jaborn1k] C~
(Studlas on lAxperimmtal and Theoretical Physical Collection or
Articles) Moscow. lad-16 AN 3333. 1959. 304 P. Irrats. slip -7%
lamorted. 2,300 copies printed.
Sd.t 2. L. rooliftski7, Doctor or Physical and Hathooltical Sol-
u
Ch*rn
ak and V
Dork
us
hin
A
&
0
bli
a
a
f P
-
.
u
s
sez
.
.
~
Sa
oncem;
go., o
y
g
Tech. XQ.z Tu. V. ftlins; Cotmalaslon for Publishing the Coll*ctl,;n j
In Memory of OrlprLyA Samilavich tAndaborat 1. Ye. Tom
(Chairman), Acadermialmi X. A. &*.ntorlcb, Academician;
P. A. basnulln, Doctor or Physical and Mathematical 3clencla;
S. L. ftn4ellshtsm, Doctor of Ml&ic&l and Mathematical ftlanx; zk~
Z. L. Fabollankly, Doctor of Physical and Mattiountical Science
F. S. Landebarx-baryahanskaya. Candidate or Physical and Moth-
smatic4a Sciences; and 0. P. matulovL" (Secretary). candwato or
Physical. and Mathematical Sciences.
?Uftr=t Thin book to Intended for physicists and researchers
engaged In the study of electromagnetic radiations " tattr role
structure 'and composition or materials.
COVERA(Ma The collection cant alm 30 articIaa
investigations In spectroscopy. @onto&, molecular optic&, east-
conductor Physics, nuclear physics, and Gthtr branch** at
Physics. The Introductory chapter gives a blographICS1 profile
or 0. S. Landaborg. Professor and Ns~4 of the Department or
Optles of the Division of Physical Technology at Moscow Unt.
4 reviews him work In Rayleigh bQattering, Combat
varsity, an

a No personalities are
, spectral analysis of octal&. etc.
=
oned. References accompany osch, article..
,
Xqa2"q9-.A-3. 1EInativa of the Action or Light osses on the
Spectra or Vapors of Aromatic Cos.
pounds 149
ob"UMT. 1. V. and rakbev~ The Resistance at Rics
T
C,m
,a,,, ,an* 159
a ov ; M. The Co.. lotion Thsax7 at Rayleigh Light SOO.
1-I
"*
XI
-
Z-
IT5
r IS
Sabolsma, X. 1. The Quantum RechanLon Tromory at the
Utenalty
.
-r-Wf-CqiUIhoW-54A%tsrIhs Lines 192
Sus;qhin4kIZ,A M DapenOomy or tbs Width or CoutiUled-
Zi
A
l
t
l
d
ft
Kh"
ve
of the
n
so
r
ropy or A
OaCtsi
ng
PolarIzability Tenser 211
To",- ?meant State or %he Tboary of Weak Utaractlons
Imuntary ftrticles 235
Tvi"z?aBA I. A. and U. A. Chsyanov. Tto t1lusinatIon at
Dlizeatrics In jugh nalds 231
WWOLIA S. A, and M. Z_ftanlj*. Investigation or Combined
~70ring'T-9-10tra In Ha -H20 and H202-Dlo"ne
Solutions 244
raballgakIrl 1. L. The Thin Structure of Lima of Rayleigh
-
1;Q t4aitfis
r0a in Cases 25%
Jrpqp~-~. Tho Role of the Oroup Speed of Light in Irradle.
tion in a flarractiva Medium 261
3 8 and 1. P. p?Lqanova. Xxeitstlon or Spectral rings
In a ass Diacnarg* 275

The ftselbilltr or
Frlshb2r&-A" , and
--Uoressins the Sensitivity or the, Spectral Determination
of Sam Blements 28T
3hgjj!&kIj_-1-3. The Interpretation of Spfsetra at Aromatic
hydrocarbons in Proton Cryotallint Solutions 296

7-1
49yeshohanlys go skaperimeatalincy texha"as I "soon Tooketempers-
.. turn7kh jasledo"Alf, 1"6
UsParlainataltnala tokhalka I too Ingled ugly pri I"Qukh "a-
I trudy somhobame gxper=jital TweLgdques and
CUh!r.Mr Investigation at Tr&=&S%IQM Or US
Omforance an Experimental Tmoh;Uques and Awth"S of Inveot2gatIOR
at RIgh Temperatures) Moscow. AN SM. 1959. 789 p. (Series:
U0081117S nAUX 833B. 1RMtItU% IGSUS$4& P% fIXIkQ-
kbWaboakIn asnavon proUvedstva stall Z 200 coplex IVIOUG.
9009. 24.s A.M. 3amarin, Corresponding Amabor, UM AQ&4107 of
SeZenossi Xd. or rubIlahL% Houses A.L. DBA"ItSer.
r=M=i This book In intended for metallurgists and Metallurgical
easIfters.
COTIRAOSi This collection of scientific papers Is divided Into *%a
parw 2) therngornazio activity and kinstlax or hub-tomperatur*
processes 2) constitution dissran studies 3) "laal properties
Or lIqLad metals and slag* 4) now Analytical methods and Pro-
duction or purs metals 5) pyrometry, and 61 statral questions.
for more specific coverage, #ad Tabi* or Contents.
Asuarin. A.M.. and D.Ta. Seat. rhotoolectria rrrofttz7 at JAquia
j%tal 636
Investigations were mace or the spectral ra4wins Power or the
surrace or metal baths or various chemical compositwna using
various exthods. Assulto were In agreement. The regularities
established 44teralned the connection between color temperature
" actual 14 ture or clean and Oxidized Matia-bath 4UL-
facts. On th:Pdr.18 or a large mimber of InTestleatIona It was
established that the value of the goorrIalent of transition
C, color temperature to actual temperature has practicalIT
NO relationship to the Presence or alio7ing elements and is un-
:VW71na In the presence or carbon between the limilts. Or 0.01
&no 3.5 percent. A comparison 'or various a#ttka4a of radiation
PYroottry showed that the optical amtral-ratle method is the
wet effective for continuous temperature control and %berm-
graptif or liquid metal.
SVqtj.5'q.TA. A Simplified System or Spectral Ratio Optical
try 645
b
Andrerev. I.C. and A.Z. Ran erg. ApplIxation of too Optical
lyrometer for Measuring the Temperature 0: LI4uI4 Steel 655
Mlkhalapkiy. T.D-AJ-Noporent. V.I. ?mkotly*v. and X.A.
Tel-tevakly. ZQUIp1"-NWr-'V1rM1nIn6 Juan Temperatures at
oases U7 the Optleal Roth" r
----------------

HEPO.fNT.j,~~
"The Influence of a Solvent upon the Electronic Spectra of Polyatomic
Molecules."
report presented at the 4th International M4sting of Molecular Spectroscopy,
Boloena, Italy, 7-12 Sept 195.0.
University of Leningrad.

KRAMS, Torichan Pavlovich [deceased]; SKIRROV, V.I., atademiki red.;
TO IN, A.M..-Skadealk, red.; GOROMOVSKIT, ru.N., red.;
jumwjwT# B.Sot red*; SATOSTITAKOVA, X.T., red.; TOPCMS, A*Sov
r;CL*; jrALUMAn. tto.re, red.; ~90V, L.Se, red.Lad-ve; 233MI,
Kelso, takhnored,
[Works In pbysical Trudy po Mike. Moskva, lzd-vo Akad.nauk
PS-Me 1959. 339 P. (KIRA 12:11)
1, Ghlea-korrespoudent Ali SM (for Kravets).
(physics)

24(7). 3(7) SOV/51-6-6-16/34
AUTHORS Kisslevs, U.S., ggporent, B.S. and Fursealcov, V.A.
TITLE: spectral Determination of the Humidity of Air in the Upper Layers of
the Atmosphere (Spektrallnoye opredelonlys vlashnosti vozdukha v
varkhnikh sloyakh atnoefery)
PRRIODI CAL OpWa I spektroskopiya, 1959, Vol 6, Nr 6. pp 801-803 (USSR)
ABSTRACT: Diffraction-&rating spectrometers were used to determine humidity of
air at various heights of the atmosphere from attenuation of 9olar
radiation in the regions of absorption by water at 1.4, 1.9 and 2.6 IL,
The spectral regions around 1.2, 1.5 and 2.2 IL were used for control
purposes. The various mavelangths were presented successively to the
spactrometer slit by means of a device which uses a cam. The optical
signal war, modulated at 100 c/4 and photoresistors of PbS were used
as receivers (they were supplied by S.P. Tibilov and I.G. Kopilevich').
The instrument used is shown schematically in Fig I where D Is a matt
aluminized plate used as the source. The instrument was calibrated by
means of a special call in Yftich the optical path could be varied from
8 to 100 m, pressure of vater vapour from 0.9 to 10 mm H& and pressure
of nitrogen which imitated atuosphere, from 50 to 500 mn HS. A
Ca rd 1/2 calibration curve for the 1.4 IL region is shmm in Fig 21 it gives the

SOV/51-6-6-16/.34
Spectral Determination of the Humidity of Air in the Upper Layers of the
Atmosphere
reduced absorption as a function of the square root of the amount of
mater. The instrument was made as light as possible end Ms stint up In
a balloon from Coatral Aerological Laboratories near Khar1kov and Moscow.
After reachine; its maximiua height and drifting for a while, the balloon
releasod the spootrometar and the latter Coll to the ground attached to
a parachute. Fran the absorption spectrograms obtained at various heights
the amount of meter vapour in the atnospbere was calculated and it is
given in Fig 5. Humidity of air could be measured at heights up to
11 I= using the b" at 1.4 it,- for higher heights the stronger bands
at 1.9 " 9.6 ii were used. curves 1, 11 &ad III in Fig 3 give the
amount of meter vapour as a function of height determined from measurements
carried out in 1957. 1956 and 1956 respectively. The 1957 dat& for
heights or 11-11 km (curve 1) are not regarded as reliable.
Acknowledgments are made to G.I. Golyahav, V.G. Kastrov, A.S. Mastinkie
and I.V. Ntalakhin for their help. There are 3 fi&prea and 13 references,
8 of vhich are English, 3 Soviet and 2 German.
Card 2/2

'24 (7)
AUTHOR:~ Neporent, B. S. SOT/53-68-1-3/17
TITLE% The Development of Molecular Spectroscopy in the USSR in the
Last Years (Razvitiye molekulyarnoy spektroskopli v SSSR za
posledniye gody)
PERIODICAL: Uepekhi fizicheakikh nauk, 1959, Toi 68# Nr 1, pp 13-29 (USSR;
ABSTRACT: The author gives a su"ey of the most important articles on
molecular 3peotroseopy published in the USSR in the last five
to ton years. This article is based on a lecture delivered by
the author at the Joint International Committee for
Spectroscopy in Noscow on August 13, 1958. In the field of the
spectroscopy of molecular oscillations papers were published
by M. V. Volskenshteyn, H. A. Yellyashevich# B. 1. Stepanov,
L. S. Wayants, M. -A. Koyner, L. Mw Sverdlov, M. K. lushchinskiy,
et al on the theorj of oscillation spectra, by L. I
Mandellshtam, G. S. Landeberg, Ye. P. Grosa, L. N. Ovander,
B. 1. Stepanovo P. A. Apanasevich, P. A. Bazhulin, Kh. Te.
Sterln~ 1. 1. 30011man, H. M., Sushchinakly, Ya, S. Bobovichl
M. V. Vollkenshtayn, V. T. Aleksanyan, B. A. Kazdnakiy, V. 1.
Nalyshevs Sh. 8h. Raskin, I. I. Batuyev, H. D. Sokolov, V. M.
Card 1/3 Chulanovskiyt V. A. Kolesova, K. F. Vuks, T. A. loffe, et &I

The Development of Noleoular Spectroscopy in the SOV/53-68-1-3/17
USSR in the Last Years
on Raman spectra, and by P. V. Slobodskaya, M. L. Veyngerov,
T. M. Chulanovikiyg V. M, Tatevskiyj Tu. P. Pentin, V. M.
Tatevsklyj Tu. He Sheynkerg As V. logansen, H. Gi Yaroslavskiy,
0. S. Landeberg, A. A. Shubin, T. I. Mayshev, V. N.
Chulanovskiy, V. A. Florinakaya, dnd many other authors on
infrared speotroCcopy. In the field, of electron-spectroscopy
papers were published by V. F. Kondratlyev, A. N. Terenin,
N. A. Prilezhayeva, V. I. Denilova, I. V. Veyto, V. L. Gurvich,
A. V. Yakovleva, 1. 1. Gromove., X. Z. Khokhlov, L. V. Leskov,
A. V. Kleynberg, A. A. Shishlovskly, and many other authors on
the spectra of monatomia, diatomic, and triatomic molecules,
by A. N. Terenin# S. I. Vavilovj P. P. Feofilovq D. H. Lyuist
M. G. Teselov, T. N. Rekasheva# M. V. Vollkenshteyn, L. A.
Borovinakiy, So M. Yazykova, H. V. Adamov, B. S. Neporent, B. 1.
Stepanov, SL 1. Pekar, A. S. Davydov, V. M. Agranovich, A. F.
Lubchenko, M. V. Pok, N. A. Borisevich, A. N. Terenin, B. Y&.
Sveshnikov, T. L. Levehin, ff. D. Galaninp V. M. Chulanovskiy,
and many other authors on the spectra of complex multi-atomic
molecules, and by I. V. Obreimov, A. F. Prikhotlko, K. G.
Card 2/3 Shabaldas, A. S. Dav-,).:.jv,, Ye. F. Gross, V. A. Arkhangeltakaya,

The Povelopmont of Noleculatr Spectroscopy in the SOT/53-68-1-5/17
WON in the Last Years
P, P. Psofilov, S. 1. Tavilov, A. N. Sovehenko, L. V.
TolodIko# *t *I on electron spectra of Metals. Among other
salentistaq A* T* loganxon, K, W. Sushohinskly, 1. V.
Pepakhoong-S, Q: Rautian, G. G, Pstraxhq 1. S. Abramsong
A. 1. NogilevskiTt 0. D. Dmitriyevskly, B. S. Isporent, V. A.
Nikitino B. r. stepanovo A. P. rvanov, Yu. 1. Chakalinskaya,
A. S. Toporets,,Z. V. Zhidkova, L. D. Kislovskly, ?. X.
Geraslmovg N. N. Bushchinakiy# Ta. S. Bobovichp D. B. Gurevichq
V. K.'Prokoflyev (survey of spectral apparatus constructed in
the USSR), 1. V. Obreinov, V. 1. Dianov-Klokov, L. A.
Tmerman, and many other scientists performed methodical
investigations. There are 153 Soviet references.
Card 3/3

AV/51-7-4-27,13
amm s vusiLevsuy, x.r. arid ITaporent, 5.U. U2
TITIZ The Ofteat of Foraiga (Asse ou Absorption of Infrured Radiation by
Water Va~cur in the Region of a &'Anrle Line in the ".7 IL Lkind
FORIOULAL., Optt= L iwpektrosicopiya, Vol 7, Ur 4. pq 672-574 (US"'X)
.IBS TUCT: The authora stadiad ttto affect of foreign gaess on the intagrul
absorption by a Ingle wt6r-vapour line at 4025.4 cm-1 (transition
I - I ~
0, J" = 5- Vs 1 ~j = .
T P T 6-2). Abeorption of the H20 + A.
'R?.O + 112 and U20 + GO2 mixtures ms iae-Aaured at tutsr-vapour prdsoure
p1. -. 0.00895 aft (6.8 mm Hg), total presaures uO to 0.83 atm and 11rht-
beam path-langths t from 8.8 to 1604 m. These uiwAsurawents rare made
using a spectrometer with high ravolving power and a multi pie-pdssage
call. described, earlier (Ref 2). The experimental technique was the
Sam* as that given in an earlier paperW~)j Fir, 1 shows the integral
absorption A (in cm-1) of the 4025.4 cm-1 line plotted against (ple) at
PI = 0.00895 atm dO COZ pressures p2 = 0. 0.057, 0.188, 0.386. 0.596
and 0.852 atm (curves I-et respectively). These data Show that the
Integral absorption botwaoa 0.07 and 0.9 cm-1 can be 6iven in the form.
Card 1/2 A = 2 4- -S-

:iOV/61-7-4-27/32
The Eff .act of Foreign asses on t&bsorptioa of Infrarad Radiation by T(ater Vapour Lit
the Region of a Single Line in the 2.7 IL Hand
where 30 is the integrul intensity of the line at p, a I atn and Y is
the,line half-width. Because of the liI2&%r dependence of If on
'(pj Crl2p2)jth* L slope or the curves 1-6 in Fig 1 in proportional to
(pl- 4rj2p2) wherij M12 in the relative efficiency of optical collisions
between molecules of waiter and of forsip gas. Similar dependences were
observed mhon nitrogen and ar6on were used as the foreign games. The
authors determined the values of Mig as ~xoll as the optical diameter& (d)
or collisions between water and foNign molecules. *kll these Yalu" are
given in,& table on p 574. There are 2 firures. 1 table " 6 references,
2 of which are Sovi st, 5,English and I translation.
SULMTTZD.- -1-pril 23, 1959
card 2/2

14081/62/000/015/001/038
B168/13101
AUTHOHSt Neporent, B. S., Bakhahiyev, N. G.
TITLE: Influence of the internal field on the spectral
characteristics of polyatomic organic molecules in nolutions
PERIODICALS Referativnyy zhurnal. Khimiya, no. 15, 1962, 8-99 abstract
15B24 (Sb. Nalolekulyarn. spektroskopiya", L., Leningr. un-i,
1960, 35 - 51)
TEXT: This article gives results from a number of investigations, conducted
by the authors during the past few years, into the universal.influence of
the internal field on various spectral characteristics of polyatomic
m6ldoules in solutionsq such as intensity of absorption bands and of
fluorescence, position of spectra, etc. New expressions were found showin6
110W the value of the absorption inteeral, the duration of the excited state$
and the displacement of the bands on transition from gases to solutions,
are related both to the generalized physical characteristics of the solvent
(dielectric constant, refraotion index) 'and to various microcharacteristice
of the dissolved substance (dipole momenta, polarizabilityl etc.). Exten-
Cara 1/2

3/081/62/000/015/001/01:8
Influence of the internal field ... B16a/Biol
sive experimental verification of these expressions, taking several dozens
of organic molecules of different types as examples, showed that quantita-
tively they agree well enough with experimental findings. It was oancluded
from these data that with fair approximation, as regards the complex poly-
atomic molecules and many aimple ones, the action of the solvent on the
various properties of the electron apectra can be idontified# with the
influence oi the physical 'dielectric medium, vihich alters the size of ~he
internal field acting in the solution on the particle under examination.
LAbstracter's note: Complete translation
Card 2/2

30V
8/058/61/boo/009/0A/050
AOOI/AIOI
AUMOSt Vasilevokly, X.F., Kineleva, M.S., Keporent, B 3
TITLE: Investigating absorption laws of Infrared radiation by water vapors
and determining humidity of atmosphere upper layers bithe spectral
method
PMUODICAL: Referativnyy zhurnal.-Fizika, no. 9. ig6i,-91, abstraot*qV111 ("DoW.
Mezhvuz. na.uchni konforentaiipo spektroskop" I spektr,-analizu!,
Tbmsk,,Tomskiy un-t, 1960, 82..-- 84)
TW: ihe,aUthors investigated dependence of infrared radiation absorption
by-water vapors-on,partial pressure,of vapors, length of path.and pressure of
other.gases, (argon,N2, airand 00g). The relationships-obtained are wed for
determining concentration of water-vapors inthe atmosphere from attenuation of
radiation In absorption bands 1.4j.1.9 and 2.7 microns, measured at various alti-
tudes with an automatic spectrohygTometer during the flight of the Instrument in
a stratosphere balloon.
K. V"Ilevskiy
[Abstracter's note: Complete translation)
Card 1/1

AUTHORs ITeporent, B.S
TITLSs Discussion of Some of the Papers Frasented at the Gonf arenas oa the
Theory of Spectroscopic Instruments
PERIODUALs Optika i speLtrcskopi,ya* 1960, Vol 8, Hr 1. p LZT (UM)
AFZTRAGT-. The problem of siiaultaaeous allowance for systematic and random errors
should be dealt with in a sufficiently general form. Determination
of the minimum total error (when the errors themselves are small) is
only of Importance under frequently employed but limited experimental
a.onditions. Representation of the square of the total error as the
sum of the squares of systematic and random errors, and determination
of the conditions which define strictly the optimum values of the
parameters such as the scanning rate, v, the time constant T'and the
alit width a to not the only possible approach. &ince under experintental
conditioas the ratio of the alit width to the width of a measured band,
and the ratio of the scanning rats. v, to the time codstant, r, may
vary within wide limits, the author at a!. (Ref 1) did not -consider
it necessary to analyse the optimum relationship between systematic
and random errors especially as in many cases only one type of error
Card 1/2 needs to be minimized. I.V. Paysakhson and D.I. Shchookila showed that

SOV/51-8-1-31/4D
Discussion of Seme of the, Papers Prassated at the Conference on the Theory of
Spectroscopic Instrumenti
C
even considerable errors, due to the apparatus function may be amAly
allowed for by an appropriate treatment of the records - If such
treatment was carried out it would not be necessary to include the
apparatus-function contribution to the total error (the term ar,2 in
Eq (81) in RaxAtian's woric, Ref 2). One must ramamber also that In
some cases the contour of the band Is required, In others - its area
and in still others - the intensity at the band maximim and its width.
All these are special cases as Mr as errors are coucerned and this is
also true of rapid methods of recording. Themethod of recording
should be selected bearing in mind all these factors. Consequently a
general formulation of the relattonships between a, v and %, would be
more useful than the suggested "universal" conditions of recording.
There are 2 Soviet references. .
Note. This is a complete translation.
Card 2/2

s/o5l/6o/oO8/005/007/02?
9201/IC491
AUTHORSt Keporent, B.S. and Mirumyants, S.O.
TITLEt A Spectroscopic Investigation of the Processes of
Transrormation of the Vibrational Energy of Complex
Molecules During Collisions. r. Determination of the
Amount of Energy Transfer and the Collision Efficiency
FERIODICALs Optika i spektraskopiya, 1960, Vol.8, No.5, pp.635-642
TEXTs Stabilization of excited complex molecules, i.e. decrease of
the probability of radiationless transitions by transfer of the
excess vibrational energy during collisions with foreign particles,
was used by Neporent to explain the intensification of fluorescence
of aromatic vapours on addition of such foreign gases which have no
quenching effect (Ref.1). In later work Neporent (Ref.2)
suggested that the intensification of fluorescence by foreign gases V43
can be used in studies of energy transfer in molecular collisions.
The results reported in!these two papers and in other work (Ref-3 to
9) are reviewed in some detail (Fig,,l to 3). It is shown that in
studies of the processes of vibrational energy transformations
during collisions of complex excited molecules with foreign
molecules, it is necessary to allow for the energy exchange both
Card 1/2

s/o5i/60/008/005/007/027
E201/E491
A Spectroscopic Investigation of the Processes of Transformation of
the Vibrational Energy of Complex Molecules During Collisions.
1. Determination of the Amount of Energy Transfer and the Collision
Efficiency
with the foreign molecules and with the translational and rotation&/-g
degrees of freedom of the excited molecules themselves. An improved
expression was obtained for the accommodation coefficient and it was
applied to the reported data (Ref.1 to 9); the results are given
in Tables I to 3. The paper ends with a short discussion of the
equations and numerical results reported here. There are
3 figures, 4 tables and 20 references: 8 Soviet, 10 English and
2 German.
SUBMITTEDs July 22, 1-959
Card 2/2

I rest Bas' and Bakhahiyoy, N.G.
TITL9% The Role of Universal &04 gFocifi-a. Intorsolecular Intonations L
the Iffect of a Solvwt on the Sloctreniallpoctra of Molecules
PUZODICALsOpUkR i spektrookopiya, 1960, Vol 8, Nr 6, pp 777-786 (Ussit)
AWTVACTs
Card 1/2
TAtermolocular interactions in solutions are divided by the authors
Into two =in types c univorsal. due to callectiv* effect on the
**late molecule of all the nurrouiding solv,4ut molecules, and specific,
due to individuAl Intaxsetions of the soluto molecule with one or
nor* of the surrovAdift solvent mologtaox. The universal interactions
are seacroscopic".'effects, of the solvents described by proptrties such
as pomittivity,,refractivo likdez. dispersion. atv. The specific
igtoncti"'s are affected by the structure of the solvent molecules
and are called %icroscopiO effects. Internal fields in a solution
are used to seporat* the univernal fron specific interactions.
Wanoraw and varied experimental data are employed to show the
applications of the@* ideas (lip 1-1) and a short discussion is
given. of the published varic which does not allow for the collective

80545
8/051/W/008/06/00(j/024
2201/2691
The Role of Universal an& Specific Intermolecular Interactions in the Iffect of a
Solveat an the Blectronic Spectra of Molecules
offset of the surrounding =odim on the absorption or omission centres.
In conclusion the authors point out that only in the ideal ossa, c"
wo a operate entirely the universal f rcu a pacific lattrections. In.
real systems we find continuous transition frois pair Interactions to
collective effects of the surrounding nodium an a solute awleculs.
Nevertheless the basic Idea of tivo typos of interaction cau be used
as a foundation of spectroscopic studies of solutiow. There are
I f1proo, I table and 21 ref oroaces, of vhLoh 10 are Soviet,
6 Inglish. I Freach, 2 Glorma and 2 Japanese.
SUMTTSOt October 17, 1959
card 2/2

.~-, */00 ~ 0,6/007/024
Z0.36,00 :,.- .1,
AOTWA t nnnne!vS.O. and No rmb. B.S.
TITLNz A Aveatroscovic investi ift of the Froc4sass of the Vibrational
MWCY Transfamations During Collisions of amplex Mqlgculgd.
M The-Iffectof revoiga (keen an the Fluorescence Tiold of
halLaid * I
PUZORIULsOptiiam, L spoktromkopiys, 1960, Vol 8, Mr 6, pp 767-708 (USSR)
ABSTUCts A largo amber of foreign gues (Zs. No, A, Xr. U. 12. U2. 112, 00,
1110, 020, Imp 06112) me used to study their effect on the
fluorescence yield of 3-dinothyla"ne-g-dainaphthallaide mpour wetted
at four wvel~~bm (402, 436, 405. 3.65 xjL) from an SVWIL mercury
Imp. the measurements were carried sut with a phOvelectric set-up,
slimilar' to that doic.ribed earlier (Rof 2). The tatall. intensity of
fluorescence is& meavAreds IeEna* 4pecial experimestA showed that the
fluorescence speatno of 3-41mot 9-6-mizophthallmide Crig 1)
Is net affected even at Igo a proaaares of $00 an Ng - The
vapour pressure of the fIgn pses vas kept at 5.4 x 10-3 = Ng.
the temperature in all toots van kept constant at'526OX. The results
Card 1/2 are sham 14 Figs 2-11 and in a table on p=. From the experimental

80546
6/051/60/000/06/007/024
A Spectroscopic Investigstion, Of the Processes of the Vibrational Inergy
Tromformatiess During C412ifis" Of Complex Molecules. 11. This Iffeat or
Faioicm ases ion the Fluorescence Ueld of
values of intensification or weakening a.f fluorescence the authors
deduced for ~aoh for'elga-Va Koleoule the amount Of vibrational energy
exchanged in a single collision with an szolted nelemdo of
3-dlftthylmlno-G-aninsphthalini4s. For all cases the authors found
the accommed&ftoa caefficLostwhLch giro w the officlency of collisions
in the amse of the asamt of energy exabangod. It ims found that auch
collision efficiency depends mainly an the Van dor Thals interaction
c i.e. an the durations , ef collisions. It vas also towd that
transfemal4on of onergy of fereip-gas aclocules Into the vibrational
snergy of 3-dinothylodue-6-tolnephthoLliniis meloculos is much loss
officiout than the revers* process. There are 11 figures, I table
and 36 references, of which It are Soviet, 15 Inglish, 2 German and
2 translatiens Into Russian.
SUNITUDs July 22, 1959
Card 2/2

KIMMUNTS, S. 0.; IMCRUT. B.S.
Nff4Ct Of COUt&=ln&Ut &8868 OIL W20 Int6U&ItY Of the
electron absorption of 3-dime~17lealw-6-amino
'phthalimide
varorso OPt-I sPeldr. 9 no-1:7-15 J1 160.
(MU 1397)
(Phtha,11mide.-Spectra)

81278
5/048/60/024/05/04/009
,:;1 3,570 0 B006/BO17
AUTHORS: Hirumyants,.S.-O., Reporent, B. S.
TITLEt Spectroscopic Investigation of Vibrational Energy Transfer
in interactions of Complex Molecules ~1
PERIODICAM Izvestiya Akademii nauk SSSR. Seriya fizibhoskaya, 1960#
Vol. 24, go. 5, pp. 514-515
TEXTt The present article is an abridged reproduction of a lecture
delivered orL the occasion of the Eighth Conference on Luminesoenag
(Minsk, October 19-24, 1959). The authors-investigated the transfer of
vibrational energy in both directions (absorption and release by excited
molecules) by means of a method which is based on the investigation of
the.dependence of the fluorescence yield of vapors of aromatic compounds
on the pressure of.foreign gases. An intensification of fluorescencell
corresponds to,a stabilization and a weakening to a labilization of the
excited molecules due to absorption or release of vibrational energy in
collisions. The stabilizAtion of excited molecules of 3-dimethylamino-6-
aminophthalimide in coll .:.one with molecules of foreign gases was studied
Card 1/3 LIr

81278
Spect-roscopic Investigation of Vibrational 51048
,/60/024/05/04/009
Energy Transfer in Interactions of complex B006/BO17
molecules
with regard to its effect on the fluoredoence yield of the vapors of the
matter investigated on excitation of various wavelengths in a large range
of the spectrum. The investigations were made for the following foreign
gasest He, Re, Ar, Krj le; H20 D29 N21 CO, and H20, D20' NH30 and C 5 H12*
The mean vibrational energy transferred to or from the complex molecule
per collision event with a foreign-gas molecule was determined. It was
observed that the mean vibrational energy released by an excited-
3-dimethylamino-6-aminophthalimide 'molecule increases with the mass and
the complex structure of the foreign gas. However, this dependence cannot
be formulated uniformly. A monotonic dependence could be observed only
in monatomic gases; however, also in this case a considerable deviation
from the theoretical dependence was observed, which had been computed
according to a conception of elastic collisions of balls. This shows the
inadequateness of this model. It is assumed that these deviations can be
explained by the fact that an energy exchange takes place not only among
the molecules but also between the internal and external degrees of tK
Card 2/3

81278
Spectroscopic Investigation of Vibrational 3/048/60/024/05/04/009
Energy, Transfer in Interactions of Complex B006/BO17
molecules
freedom of the excited molecule of the matter investigated. To study this
phenomenon, the aacomodation coefficient was computed by employing a
formula deduced by the authors in Reft 4 and all degrees of freedom were
taken into account for the energy transfer. It was found that. the
efficiency of collisions with respect to energy trans-for depends monotord-
cally on the van der Waals' interaction constants of the molecules of
foreign gases. An estimate of the part played by rotational and
vibrational degrees of freedom of diatomic and polyatomic molecules
of the foreign gas in energy transformation was given. It was
experimentally found that the reverse process (energy transformation of
the foreign gases into oscillation energy of the molecules investigated)
is much less probable than the direct process. There are 4 Soviet refer-
ences.
Card 3/3

I T
--,_NMRENTr k4,j,$;OLDOVAf O.Ve
1.
Orlentatim photodichroim of visomm oolutions.- Opt. L spektr--
10 no*21297-288 IF f6le OMA l4c2)
(Iticbrolm)

N 7,
PHASE I BMK EXPLOITATION SOV/6181
Urallskoye soveshchanlye po spektrookopli. 3d, Sverdlovsk, 1960.
Materialy (Materials of the Third Ural Conference an Spectros-
copy) Sverdlovsk, Metallurgizdat, 1962. 197 0. Errata slip
Inserted. 3000 copies printed.
Sponsoring Agencies: Institut fiziki metallow Akademli nauk SSSR.
Komiaslya po spektrookopit; and Urallskiy dom tekhnIkI VSNTO.
Edo. (Title page): a. P. Skornyakov, A. B. Shayevich, and S. 0.
Bogamolov; Ed.: Gennadiy Pavlovich Skornyakov; Ed. of Publish-
Ing House: H. L. Kryzhova; Tech. Ed.: N. T. Mallkova.
POPOSE: The book, a collection of articles, Is Intended for staff
members of spectral analysis laboratories In Industry and scien-
'tific research organizations, as well as fnr students of related
disciplines and for technologists utilizing analytical results.
COVEUGZ;~ The.'collection presents theoretical and practical prob-
iems or thei application or atomic and molecular spectral analy-
sis inicontrolllnx the ohemIcal composition of various materials
in ferrous and ncnr4.-rous metallurgyg geology* chemical 1ndus-
:try, ahd medicine. The authors express their thanks to 0. V.:
jC:entx~qva for help 10 preparing the materials for the profs.
R fleft can follow the Individual articles.

'Materials of the Third W&I Conference (cant.
PA" 11
Vasllevskiy,~~ P., and R, 5. Iteparent. Absorption of In-
frared radiation by water vapor In mixtures with foreign
&age$ 145
Kislowskly, L. D. Now metho4 of absorption analysis based
on reflection 151
B090molov, 3. G.. A. P. Kolesov, M. P. Grabenahchlkova, and
E. 1. aorbunova. Utilization of ultraviolet spectma-
copy In analysis or by-product coke xylene 157
Korshutiov, A.!V., and A. A. Kolov'skly. Spectra of low-
frequency fpmn light scattering by some haptahydrate
crystals 164
Card 12/1~

Po c-r1V--t-
STRUCTM AND PIMSICAL PROPER= ULr xArMR IN A LIQUITI STATE.
reports read at the 4th Conference conwaned -in KIY97 from I to '5 June
1959# Published bY the publisholn House of KI ME University. Klyrv,
USSR, 1962
Preface
M.I. sji,,jjTARa scy, Dielectric Parmembility an4i Molecular
.itructure of Solutions 4
PC, on the Connection t1utween the Rotary Mobility
of Molecules and viltaosity
41.j. PEA14 and I.L. F(bWt;51IY,_Jitje Structure of the
,lolecular Lijht Scatter Line arv4 the
llropa'~Itlorj of filtenound In Liquids 15
A.V. HAKOV, !Wsct of Intermolaculhr Interaction an the
Line ..idth of the Costbination-catter
49ectra in Liquids 20
G.P. %0SHCHINA, 4.S. K&UXVA.,_I.D. BUJ'U"VA Atnd T.G. POPLATMZATA.
Lit,-ht-!icattur of the
fluctuations in 11cohol-aqueous ani
Acotor4--tuloun ';Olutions
T.W. %APT-Irvicu, laotoro ~,If*ot in th,, Viucojzt~- of Doutero-
"'Mund.;
tion of the Internal ia 45
A.?. SK43HEn-ray. V.P"&LQCHKCV and YU.V.
1;4~~,~tgen'o_ra phi c InvoFC1-g._"'Vi_on ~f the
3tr4ctur,~ of Some LiqL:ld Silico:i-
crg~nic Compounds 50

s/o5i/62/012/002/008/020
E202/E192
AUTHURS: Klochkov, V.P., and Ne-porent, B.S.
TITLE. Fluorescence polarisation and the spectral
classification of complex molecules
PERIODICAL: ~ptika i spektroskopiya, v.121 no.2, J962, 233-238
TEXT: The object of this work was to determine the degree
of polarisation in fluorescence in the fluorescence and
absorption spectra of compounds characterised by wide and
structureless bands in their spectra. The authors disagreed with,.-_
-views expressed by G.P. Gurinovich, A.N. Sevchenko and
A.M. Sarzhevskiy, who claimed that with a constant frequency of
the exciting light ,,)e the degree of fluorescence polarisation
P of complex molecules in solutions depends on the frequenc4, N)f
of the portions of fluorescence spectrum in which the measurements
were carried out. The same apparatus and substances were used as
in the previous works. In the apparatus the light from the
source prior to the falling on the sample was passed over the
diffraction grating monochromator and a polarising Glan prism,
and the emerging beam was passed through another polarising
Card 1/2

Fluorescence polarisation and the ... S/051/62/012/002/008/020
E202/EI92
prism, a filter separating the orders, and another diffraction
grating monochromator from which it was passed to the photo-
multiplier with its amplifying and registering circuit. The
parallel and perpendicular components of the luminescent light
were measured with respect to the plane of polarisation of the
exciting light. The measurements included 3-monomethylamitio-
phthalamide in glycerol, 3-dimethylamino-6-aminoplithalamide in
glycerol and also solutions of fluorescein in glycerol. The
fluorescence spectra of the first two substances did not show
the claimed relation between P and -4f, while the last
substance showed the dependence of P on of. The fourth
substance tried, 3-monomethylaminophthalamide in polymethyl-
methacrylate, gave S-shaped curves and the detailed studies
showed that the dependence of P on Vf is,due to the presence
of various types of luminescence centres. Hence it was shown
that the change in the degree of polarisation along the -
fluorescence apoctrum in due to the presence of at least two
luminescence centres with different degrees of fluorescence
polarisation. There are 6 figures.
Card 2/2 SUBMITTEDt February 20, 1961

E039/EI20
AUTHORS: 11-lazureako, Yu.T., and Neporent, B.S.
TITLE: On tho question of the relation between electron
absorption and luminescence spectra for complex
molecules
I-ERIODICAL: Optika i spektrookopiya, v.12, no.5, 1962, 571-575
TEXT: One of the present authors, B.S. Neporent, has shown
previously that the relation between absorption and luminescence
spectra can be described by the expression:
i -11-(Vi - V)
2V ekT
1,0 r
Z'V
where: JV is the spectral quantum intensity; EV is the molecular
absorption coefficient; and vi is a frequency correspondin~g to
the distance between'normal and excited electron levels in which
the stored oscillatory energy is zero. This expression is verifi-ed
Card 1/2