SCIENTIFIC ABSTRACT NEPLOKH, Y.M. - NEPOMNINA, V.V.

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SCIENTIFIC ABSTRACT
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4MLOKHt ALIA. Changes In sonsclausmew In -4 fecal arteriosclerotic Wunizzp of the brain. Sbor. trud, Lon, mwbno ob-mm now, 1 Jkb- notefit 19-154.159* =613:22) 2. Is FalkhIstricheakoy balluitay Imeni Skyortgovw4tepuma, WATW mob N.D. Ihilk-4n) I kafeft palkhIatril, r4ningveds1cogo pedlatrichs- skogo institute, (say. - prof S.S *WdLin). -.h?.PWKHt YaJ4. Toxicotraumatic nouritip of the sciatic nerves related to treatment with amirazine. Zhur, nerv. i paikh. 60 no. 2:238-241 160. WRA 14:4) 1. Faikhonevrologicheakaya bollnitea imeni Skvortsova-Stapanova '(glavW vrach_H.D. Bulkin) i kafedra psikhiatrii (zav. - prof. S.S. Mnukhin) Leningradakogo pediatricheakogo instituta. (CHLORFRMWINF.) (SCIATIC NEM DISEASES) NEROIJI, i:?U-14. Causes of fa!.&.':' 1383-1387 1. Paikhon (glavr,yy HEPLOKH, jq~,K..,_(Leningrad) Nuclear bematomas in hypertensive cerebral hemorrhages. Arkh. pat. 26 no*2:68-73 164. (MIRA .17:8) 1. Paiihonevrologicheakaya bollnitsa imeni Skvortsova-Stepanova (glavnyy vrach N.Do Bulkin)v Leningrad. NEPLO101, la.M. Ostoomurmular hypoplaBia and pees excavatus as residual s7r4ptoms of brain lesionv. Vop. psikh. nevr. no.10.*139-146 164- (MIRA 18:12) 1. Polkhonevrologicheskaya bollnitsa imeni Skvortsova-Stepanova (glavnyy vrach - N.D.Bulkin). ZADMA, Ye.M.; CHVAMANIYAO A.Ye.; KUVADINA, N.Ms; BELKIN, M.L,.; MALYKHINA, A.F.; NEKATNINs I.F.; CHUMENKOp R.r.0, MATUSTAK, Ye.l. Cr,mtarative evaluation of various methods of gastric lavage with lTesoentu)d" No.4 mineral water in chronic gastritis, Sbor. naucb, rab& vmch, m.-kur. uchro profaciaza7 no.1179-83 1648 (MIRA 18:10) 1. Tessentukskiy sanatoril Iment T*P.' Pavlova (glavnyy vrach A,,YeQ Chwaianiyao nauchnyy rukowditell kand.med.nauk I.I.,Xonovalov). RVLGTNIXO Ta.r. Physiological capillary permeability In newborn Infants. A-diatrila, Kaskvm no,6:8-13 Mov-Dw 1953. (CM 2.5-15) 1. Candidate Nedical, Sclemes. 2. Of the Institate of Obstetrics and Gynecology (Director -' L. G. Stepanov), Kinistry of Public EfealtbL USM NWWTNlrl ra,f., Imadidat maditainakikh nauk Capillary permeability In intracmatAl birth injuries and asphytia in the newborn. Poidiatrita 39 no.3.-70-74 t~y-Je 156. (KLRA 9:9) 1. Is Insituta akusherstya t ginakologii (dir. L.G.Stspanov) Kintaterstva zdravockhraaentya SSSR. (CAPILLARY PWXWILXTY. in various die. tutracrantal birth inj. & asphyxiasonatorum) (DUITERr, campl. birth taj.. intracranial, capillary permeability in) (BUIS. wounds and tnj. at birth, capillary per. ability in) (ASPHYXIA YMMATCRUK. physiol. captllarypermeability in) SMUUFJAIMs S.B.; TMUKOVAj L.G.;-NEPIMW VX , Syn-theols of setere of N(40-arylaulfonylmnino acide, Part 1. Ukr.Jd2lm.zhur. 27 no.3:365-369 161. (KERA 14t.11) 1, lastitut organichooko7 kh'm4i AN USSR. (Arginins) BABIGHEV,, IrS.; MPLYMV V BanzathlasolylaRyloarbayllo dpids and their derivatives, Part 4s 2-Elonsothlazolylalkylearbinols. Zhur.ob.khim. 32 no.3t857-859 Mr 162. (MM 150) I.,Kiyevskiy gasudarstvannyy universitat imeni T.G.Shevchanko. (Senzothiazole) (Msthanol) BABICHEVO F.S.; NEPLrUYEV, V.M. Bonzot1dazolylearbovIia acids and their derivatives. Part 5: 2.3-Polymtbylenebenzothiazole salts. Zhur.ob.khim. 32 no.3: 86o-*4 Nr 162. (MIRA 15:3) 1. Kiyovskiy gosudaretvennyy universitet imeni T.G.Shevehenko. (Banzathiazole) SEREWAMS S..B.; KOZLOV, *.A. NIMM Teralul grbWat of 'polybedric'protein formed an InfeatIng gm k1berry silkiark;with nual"r polyhedroals virus* jSwr9lL=Tlrua.boabya�w). O'kr. Ms. shl=. 29 no,2t177-180 161. ~ (MM 16t6) lutitut Organichaskay khWL AN UkrSSR. (protaina) 'Wrtw research) NEnMEW - TA j- SOGWAYM TA, I SBFMMANrr, S.B. - - - _7 4-MmetlWlsidno-3.5-dinitrophanyl Inathlocyanate an a %vagent for determining the *ndml sequence In protoinwe Part It of alpdw acids. 1111kr, WISO 51=0 29 no.2tidl-184 163. (MIRA 16W 1. Institut orgetnicheskay WWI, AN UkrSSR. (Amino acids) (Hydantoin) M?Lluyzyp V.14.; CMNUKRINA, L.A.; SERSBRYANYY, S.B. abrowtographic separation of the 4-dimoUylaaino-3,5-dinitro- ,Menylthiohydantoins of amino acids'on paper. Biokhimlia 29 - go, 1151-52 Ja-F 164. (MIRA 18:12) .U~ 1. Institut organichaskoy kbimii AN UkrSSR, Kiyev. SubnItted March 16, 1963. DZYMMOR G.M.; TAVRENKOP V.A.; IMPMHATOV, A.N. ': Apparatus for studyIng the kInetics of cataxytic reaction of 0 recombination of gas atol,--3 an solid surfaces, aur.fiz.khim. 39 no.10:2622-2624 0 (MT',Pl 18:12) 1. Institut probl8m zPaWrialovedenlya XN b'IrT,8SR~ UMMTYKH A. P. Cand Ned Soi -- (diss) *Problems of labor hygiene in the produotion of synthetio fatty aoids and fatty alcohols," Kursk, 1957. 13 pp (Inst Of W -- Ocouvational _ _ jrand I Kaeasea, Acad Wed Sci USSR), 200 I gleu,&4 !tbo eopies (KL, 45-57, 99) -28- 24M SOT/48-22-11-52/33 AUTHOR: Nepochaty1ch, P.P. TITLE: _ __6n Particular -Feit-ures of the Luminescence of Difuryl Polyeass (Ob osobannostyakh eveaheniya difurilpoliyenov) PERIODICAL: Izvestiya Akademli nauk SSSR, Seriya fizicheakaya, 1958, Vol.22, Mr 11, PY. 1417 - 1419 (USSR) ABSTRACT: Three polyenes are the object of this work, which contain CO- or COCO-groups in the chain: 1,6-difuryl-hexadiene-1,5 -dione-3,4; difuryl-1,10-deoatetraene~113,7,9-dione-5,6; difuryl-1,9-docatetraene-1,3,7,9-lioae-5o6. They are crystalline-substances, which are insoluble in water, soluble, however, in alcohols, in hexane and acetone. The information presented in this paper leads to the following conclusions: If the chain of single and of conjugate double bonds is ex- tended the limit polarization will be reduced. The GO-group exerts a considerable influence upon the limit polarization. The durations of the excited state which proceeds from measurements by a fluorometer and from such which utilize polarization do not agree. This may be explained by the fact Card 1/2 that the fluorescing molecule departs from its spherical shape. On Particular Features of the Luminescence of SOT/48-22-11-32/33 Difuryl Polyenes The fluorescence of the solutions in question is exti.a- guished by aniline (Fig 2). Other extinguishing agents, as KaJ, NaJ, and NaBr have no effect. In a non-polar solvent, an in hexane, the fluorescence yield is very small. If ethyl alcohol is added,-the luminous intensity is increased to a certain maximum value (Fig 3). If the solution is heated, the luminescence is quenched. The author expresses his gratitude to VA. Levshin for constant interest, to N.D. Galanin for his assistance with the measurements, and to B.A. Arbuzov for making available test substances. There are 3 figures, I table, and 3 references, which are Soviet. ASSOCIATION: Kazanskiy gos. pedagogicheskiy i uchitellskiy institut (Kazan, ' State* - Pedagogical and Teachers I Institute) Card 2/2 IF I W TOCHATYMt V.I.; IZOQVVI:, Z.A. Q--- Inveoti,guting the possil'ality 01 .0AaLAn,,, 'NII-)urn t4ble derlvati,m of ce2DO-o-,c at,.-o. llidl.volo'r. #61, .1. 1~t'askovslziy tekstil'nyl., inutitut. C.-LA 14-2) (viscose) (To:,,,.-jje 3ynVictic) IEPOCHATYKP., V.I.; ROGOVIII, Z.A.; Prinimal uchastiye ROMNEM, R. ...W.-.- ...... - i Development of the method for the production of thiourethans cellulose "haktaks" fibers and investigating their properties. Kh1z. volok. no.l: 64,68 162. (MM 1814) 1. Moskovakiy tekstillnyy institut. L 45460-66 Ftrl(m F4P(j)IT i;Lm 7ACCNR- AP6022725 (A) SOURCE CODE: UR/OM AUTHOR: V. 1.1 Ragovin, Z. A.j Finger, G. G.; Magilevskiy, Ye. M. 2gachat ~kh ORG: [Kepachatykh, Rogovin] 14TIl (Finger, Mogilevskiyl VNIIV S TITIZ: Production of copper xanthate f1berj5 SOURCE: Khimicheskiye volokna, no. 2, 1966t 49-51 TOPIC TAGS: synthetic fiber, xanthic acid, bactericide, wood chemical product, copper compound, organic sulfur compound QC "I A.- ABSTRACT: The aut4ors; used available data an the change occurring in the stability of cellulose xAntha flin accordance with the nature of the cations contained in the salts to investigate the possibilities of manufacturing a fiber made of cellulose copper xanthate in order to study the basic properties of this fiber and to determine the fields in which practical use could be made of It. While production of the fiber is possible using a single bath, the use of the process proved to be undesirable because the copper sulfate in the precipitating bath entered an exchange reaction not only wit] the sodium xanthate, but with the sulfur compounds in the viscose as well. Copper can sumption was increased and the fiber obtained was dirty. Use of two baths was resortei to and was found to be quite simple and caused no complications in the technological processo The first bath contained sodium sulfate and sodium bicarbonate or sulfate of ammonia, and was used to coagulate the viscose. After washing in a Na SO solution thi 2 4 SUB CODE: lit 07t o6 / Sum DATE: 25 Apr 65/ ORIG REF: 005 OTH REF: 003 Card 2/2 CSTROVSKIY, lu.M. [Ostrovd lkyij IU.M. ]; N-E-1,0C.TELOVIGH, N.'. (NeFo:-he, ovy-h, N.S. ] Activity of tlasue transaainases in colvuls-ions prokiu~:aa by t1niar-ica. Ukr. biokhim. zhw. 35 nOOM8-731 163. (MIRA 17; 5) 1. Department of Bioa~smlstry of GroLno Medical Institute. OSTROVSKIY, Yu.H.; LUKASHIK, U.K.; RAZUMOVICII, A.H.; BALAMMEVSKIY, A.I.; DOSTA, G.A.; TRFMKHINA, R.V.; LARIN, R.S.; KARFUTI, S.N.; KOHAROVA, B.P.; WOCHELOVICH, H.S.; DVORTAKINOVICH, L.N.; MOYSEYFIIOK, A.G.; KODATIC, K.A.; GALITSKIY, E.A.; %,%TYSIK, M.S.; PODOBEDP V.G.; MAKARINA-KIBAK, L.Ya. Differentiation of specific and nonspecific metabolic shifts in an acute avitaminosis B1 caused by oxythiamines Vopopit, 24 no.4:41-48 Jl-Ag 165* (MIRA 18:12) 1. Kafedra biokhWi (zav. - dotsent Yu.M.Ntrovskiy) maditsinskogo institutat Grodno. Submitted July 23, 1964. SUMOV, V.; NMGCDIN, G., Insh. Exterior finishing of large-panel buildings. Zhil. stroi. no-5: 23-24 964 WM 17e7) 1, Starshly prepodavatell Usanskogo inzhenio-stroitellnogo instituta (for Sladkov)* 2, Glavn7y Inchener. azanskogo savada zhe- lezobetonn*kh izdeliy No.3# Kazan' (for Nepogodin). 11 FAYBIGH, 1-1.11. - IX It I _LF MIT; N.F.; KORMYEV, A.A. Lmunogenic characteristics of some fractions of the pathogen of plague. Biul.eksp.biol. i med. 55 no.1:77-80 Ja'63. (MIRL 16:7) 1. Predstavlena deystvitelinym chlenom AL-111 MR 11.11.Zhukov7m- Verezhnikovym. (MMMELLA) (NUCUIC ACIDS) (IMMUNITY) t 7/dj_j'b6 ACC Nits AP50275-90 ly'5065 6 CODEt U AUTHORt Vorozhikhinal V.I.; Neeptyav2 A- V_; HXazan0V, L. S. On: 'Kolomna Diesel Locomotive Plant r a od) (Kolomenskiy teplovozostroitelirw) av TITLE-t Adsorption processes.involved in the consumption of additives SOURCE- Khimiya i tekhnologlya topliv imaselPno. 1:L',, 1965~ 50-5'2 TOPIC TAGSi lubricant additive, adsorption, desorption _21 AWTRACTt. To study-the natwe of chFmge in the concentration of additiveJ lator oilMduring the first 50 - 1,00 hr-of its ugep the authors carriecf -outexperiments on a Yaft-20h engine using DS-14 oil with 2%.Of Monto-613 additive Pnd 0.1,3% of Santo- lube-h93 additive. It was faund that in addition-to chemicql reactions of the additive with the fuel combustion products and the oil oxidation products, the additive ia.involved in adsorption and desorption processes,, A sharp decrease in the concentration of the-,qctive lubricant which occurs during the first few hours of its SA4--VA-VIIV won vu Fjllu - Elmourvulan Processett-clinom Tpne-True ourve reprouvima% WIV :112 Wes 540188 .59, SOMM. T.: VATAVOTA. T.; MMWq I.; NUMOTA, L-T FAXM LUCEMKO, Ife.., SCOP=Ilo V.; ARSAXPOTA. r*. not 14m of gftta witit vatbA brodde to tk* dilpla k*U. X*6- ster. prow. 26 u*.lOtl2-% 4160. (NM 13814) (&"s-4x*lufwtlm) (Ibtbylno) P-POKLONOV, A. A. 14in Higher Education USSR. Moscow Veterinary Academy. NEPOKLCKOV, A. A. - "The motor, secretary, and evacuatory functions of the small intestine of cattle." Min Higher Education USSR. Moscow Veterinary Academy. Moscow, 1956. (Dissertation for the Degree of Candidate in Biological Sciences.) SO: Knizbnaya Latopis' No. 13, 1956 S/006/60/000/()6/07/025 BOOT/H005 AUTHORs Nevoklonov. B. V. A-- __ - --, wv~ TITLEs Experience Made With the Application of Photothoodolite Surveys for the Compiletion Survey of Aerial Photographs )~-D PERIODICAL: Geodeziya i kartografiya, 1960, No. 6, pp. 27 - 32 TEXT: The author reports on the experience made by the Sredne-Aziatskoye aerogeodezLoheskoye predpriyatiye (Soviet Central Asia Aerogeodetical Enterprise) which has used phototheodolite survey for the compilation survey of aerial photographs iince 1955. As a rule, such a method is use~'/B for the conjunction of aerial photographolin making malps of 1 z 25,000 for high-mountain areas. The coordinates and altitudes of fixed points are determined both by the method of stereophotogrammetric and photo- grammetric terrestrial survey. The formulas used for computing accuracy in determining the coordinates and altitudes are written down, and Table 1 shows the root mean square deviations computed by these formulas. Con- clusions are drawn on the basis of these values. The method used in photo- theodolite survey by the above enterprise mentions is described. The Card 1/2 Experience Made With the Application of 5/006J60/000/06/07/025 Phototheodolite Surveys for the Compilation B007/BO05 Survey of Aerial Photographs author enumerates the preliminary operations, mentions the circumstances to be considered In setting up the working projeotp and describes the field work to be carried out. He describes a method of determining the base lengtht which makes it unnecessary to use range-finder fixtures. The evaluation of the data obtained is described. Table 2 shows the data used to estimate the accuracy of determining base lengths. The accuracy AB of determining altitudes in terrestrial stereophotogrammetric surveys was estimated by the divergence of geodetic and photogrammetric altitudes of 288 triangulation points. Table 3 was compiled on the basis of these data. By means of these data it was possible to derive an empirical formula for choosing the length of photo bases. Finallyp it is pointed out that for a full utilization of all possibilities of phototheodolite surveys for the compilation survey of aerial photographs it is necessary to combine terrestrial atereophotogrommetric with terrestrial photogrammetrio survey. There are I figure, 3 tables, and I Soviet reference. Card 2/2 BONDAREV, G.r.; zINOVIYEV. Ye.Sh.; NEFORMNOV, ru.A.; YENDOVITSKAYA, I.S. -- ~; -~ ... Supply of vitamins C, Bl,, E2 and PP for fixh proosesing workers on fishimg ormft in the North Atlantic. Vop. pit. 22 no.5:58--60 S-0 163. (MIRA 17% 1) 1. Tz otdola gigiyany pitaniya, (sav. - kand. mad. nauk G.I. Bondarev) T-Sentrallnoy nauchno-isoledovateliskay laboratorii gigiyeny vodnogo transporta, Moskva. DONDAREV, G.I.; ZINWITEV, Ye.3h.;I&T-011-LONOV, Yu.A.; rMIDOIJITSKAYA, I.S. Energy expenditure of fishery workers on trawlers fishing in the Barents Sea and North Atlantic. Vop. pit. 21 no.6:40-43 N-D 162. (MIRA 17-5) 1, Iz Tsentrallnoy nauchno-issledovatel'skay laboratorii giglyeny vodnogo transporta, Mosk-va. REPOKOMHITSKIY A.G. (Nopokoichitskii, A.H.); TAKKOVSKIY, A.A. ............. __ -M L cyvoRr,, A.) Combustion of a proportioned quantity of matter In spectrum analysis using the photoelectric method. Vestsi AN BSSR. Ser. fiz.-takh. nav. no.3tl2/v-127 163. (MMA 16:10) ZHMOVM'f. T WOKOYMITSWA. I.; YUKBUICEF, He Results of combined treatmOut Of Pulmonary tuberculosis with para- aminosalicyl.1c acid and streptomycin. probl. tuberk., Kcal-m noel: 52-55 &=-Feb, 52. (CLHL 21:5) 1- Of ths Clinic of POmonarY Tuberculosis of Gd=ok Radical Academy (Head of Cliale-Prof'. He Telyat7tddy) and of the Student Sanatorium In Zakopane (Director-M. Tasinakly), Poland. NOZOSELITSE7,, V.S.; NEPOKOYCHITSKIY A.G. 9-Mg mw 4apects of the behavior of semiconductors in polar liquids. Uch.za p.FAd.Inst.Cjerts.Ifa*233-239 t6J. (MMA 16-- 5) 1. Mogilevskiy gosudarstvannyy pedagagicheskiy institut. (Semiconductors-Electric properties) (Liquids) NOVOSELITSVP V,S.; MMKOYCHITSKIYO L.G* Some slactrCe -properties of cadmiun cUoride. Vah.zap.Ped.inst. Gorts 07-247-242 (MIRA 1625) 1. Wagilmkiy gqAp4&rstvsuW pedeftichookiy institute (C-d-Jum chliAde-Electrio propertiod) 7 ACCESSION NH: AP404M26 9/0250/0.4/008/006/0372/0376 AUTHOM- ypblW Yankovsdy'.A. A. y. TITLE: A method of quantitative eminaocr spectral'analysix aCCOtding tcp tho'Maximal spectral Me Intensity In the process of substance bum-up SOURCE: AN BSSR. Doklady*, v. 8~1 no. .6, 1964, 372-275 TOPIC TAGS: quantitative analysis, spectral analysis. . emission spectrum, ffpectrosc opyr apec" line Intensity, combustion spectrum, metal determination ABSTRACT- ne authors show that the change In intensity of a spectral line In the pro;- cess of complete burn-up of a measured quantity of a substance under the action of an electrical charge can be described by the empirical ation equ 0 where I Is the intensity of thd-lineio thi tntqnsity ofithe line at the onset of an 'a instantaneous Increase In Intensity, 4~~andp are constants characterizing the rat9s of substance bura-up and spectral line Intensity growth. depending on the andytical d 1/2. Car ACCESSION NM AP4042725 procedure, and t Is time; they also shove that the intensity of the line rbaches a maximural expreawd by the equation" Y0 4L+ (2) aud that both* the integral and maxWUm intensities may be following which it subsidei, used for measuring the ca6ceniiratloA of the elenihnt being deterthined 4gantitatively. by emission spectral analysis., Calibrating curveslor the quantitatEve.datermination of Cr, Ba, Zn, Ma, Ag od M In solutions Mn, Cr, Za and M in alloys,'platted La a coordinate systm of Igi maxversus, 19cs are piesented In the article. OrIk. art. has., 2 Ugures and 4 formulas.. AWPqAUON*- TMU4t OX114 AN BSSR (Physics Institiate, M 13SSR). SUMMED: izirl" ZKCL:, 00 SUB CGIDX: 1C, Op REV 402 OTHER: 000 2/2 rd -7!7 fMFGKOTCHIT5XITp_..4q,; YANNUISKIY, A.A. Relationship between the burning out of a measured quantitjr- of a substance and calcination in spectrum analysis. Dol d-. AN BSSR 7 no.12014-816 D '63. (MRA 17:8) 1. Inatitut fiziki AN BSSR. Predstav2sno akademikom AU BSSR B.I. Stapanovym, NEPOKOYCHITSKIYS A.G.; YAHOVSKIYt A.A. Method of quantitative emi3sior. spec-~L-um --rialysis based on the ma*i=m intensity of' Lipectral llnes in the procr-m-3 of hurmir, a uubstance. Dakl. All BSSH 9 no.6:372-375 Ja 164. (!,1111A J`/. -~6, 1. Inatitut fiziki M,.' BSSR. Predstavleno akademikom AN BSSR M.A. Yellyashevichem. ~MFOKOYOTTSKr.7. V.S. Effect of natural factors on the planning aM blacks,in fibrillsk. Stroi. v raion. Toet.Sib.i construction of residential Krain.gev. no.20-27 t62. (MIRA 18:7) L 322~~6 guu-= CODEt UR/2925164/000/010101021021 ACC N,Rg AT6023835 Ann: KIN, p!!q?XqUji#iY, Vis So ORGS ~soisjtjftc-Researoh m2ding Institute$ Krasnoyarsk (11duchno-4 j"Utut po strolte'LlatVU) -TI= I features of 014 planning In Morillsk U MU* Komissip po, problem= never&* ProblavV severat nos 10# 1964olO2-1 economic planning. '~TOPIC.TAGSt Arctic climate, general construction, government structuzal engineoring Haril Isk, a city of 11590009 has sspicial planning problems becauset 11ocated near the 10th parallel# it has permafrosto severe colds strong winds# "Ispares Vegetation# and polar days and nightso Frozen construction sites are ~wpable of holding multistory buildings; but If the permafrost melts the und lose* almost all of Its loadcarrying capacity. Winter in Norillsk -'lasts.8 months with temperatures dropping to -510; mean annual temperature :Is close to -80* Kenn annual wind speed Is 6 to 7 m/sect reaching hurricane of aver 40 alsec. Weather severity Is scaled in conditional points computed by adding the temperature to twice the wind speed* 45 points being :the limit of human activity outdoors. Snow storms coinciding with severe coldpiapid variations In atmospheric pressures# and the oppressive polar ~twlllght has bad effects an human psychology and physical well-belpts- ~""L 32909--66 ACC HIs AT6M3835 Lowaovorpeens am extremely slow-growing and trees die after transplanting; birch and willaw withstand transplanting but grou slowly and show leaves only batmen June WA SGPU*er and their decorative value is thus quite law. Although more than -,~.3009000 Ir of modem living space has been cRmplated, more than three timas the exist. Ing 21TIng Mice Is required to provide 1.3 v& par person. Also involved is the ro- ~~wma ~of numerous temporary building anti barracks that ban sprouted around the indirls trial plantse Uving gace being provided is In the form of efficiency apartments residential-typs hotels e Together with large 5-story apdrtments,. consideration is being given to high-rise types. Among the problems facing city plaradng, the most Important Is permanence of the permafrost fourdation; protection from wind and drUtIng snow and beautification problems a" secondary. Underground UtiUW lines Improperly can break down and adjacent structures can become damageds Above- grounl.Unes also engender problems; heat-aonducting pipes laid on trestles break U_ courtyard areas, Interfere with movement, and are unsightly* * The beat solution fovmd was to build utility tunnels with lines in the upper part and a passagwasy below for 'Inspection paToseso To keep heat away from the permafrost around building foundationag these t=*2s are laid under the conterlines of the streetig. cted buildings are built around For OR siaLlar reasons Interconne central courts*' Ike court areas are thus protected from winds and utility interconnections an simplified. In one blacks divided Into courts by dn ilaterconnected-maze of buildingsp wind speed was decreased by 60%* According'to the general plan of 1961# the basic construction unit In .;a mtcradistrice that almost completely close& off -the Internal areas and :cdurts from windg"and drifting snove Microdistrict No Is typical of tva L 32909-66 ACC NRs AT6023835 others discussed, covers about 24 hectares. In the center is a sports field !flanked by schools, apsrtmentso and service buildingso Windward outer Walla -of the di'strict are solid and have a minimum number of entrances* Foundation integrity is maintained by spacing the buildings farther apart than required by proven standardso Origo art. has three typical plan layouts Of micro- At striate.- out table -for alctla~aitieg* ' or.,,g., arts hAst 3 M9=69s Lj-njs SUB CMEt 05,:13& 04 SM DAM none Card 313 L 30,698-66 EdP(J)1Ee,' lill(c) TIIIPL~ICD_11~0 T (m )III ACC NRs AT6008944 SOURCE CODE: UR/0000/65/000/000/004 & AUTHORSs Kragellsidy, L V.; Ne ORM none TITLEs. The theory of wear of highly elastic materials SOURCE: Abscow. Institut mashinovedeniya. Plantmauay v podshipnikakh skollzheniya; (Pl-a-97ff-cs in friction beari research and experi- iseledovaniyat opyt primeneniya meat in application). Kosaow, Izd-vo Nauka, 1965, 49-56 li~ TOPIC TAGS: material testing, friction, elastic material, wearability, destructive testing, resin ABSTRACT: The process of wear of highly elastic resin materials is studied in condi- tions of friction along a hard, rough surface. Three basic types of wear can occur, depending on the properties of the material, the properties of the counterbody, and other fri6tion conditions. Of particular interest is the appearance of zones of tension in the material in the vicinity of the zone of slip (see Fig. 1). The authors .conducted model tests on contact fatigue, in which a spherical indentor slips along a resin surface. ifter a known number of cycleaq the indentor was removed and the resin surface inspected* Fatigue curves were then plotted and compared with curves of ordinary fatigue. This comparison shows that the curves are parallel. Based on this resultj it was concluded that the applied contact stress a is proportional to the L Crd 1/2 L 3969"6 Acc Nit, AT6008944 Fig. I Diagram of the interaction of a tao Ing rigid spherical indentor with an elastic half space. unit force of friction, that is, the force of friction F in contact with the area of actual rubbing Ar (d~ k where k is a coefficient of proportionality. This equation is used in constructing quantitative relationships for fatigue wearing of highly elastic materials. Wearing Intensity is given by A-'I where ih is the Unitwearing intensity and A. is the normal contact area. The unit intuensity ist in'turno related to deformationp goometryt the number of cycles until failure', and to other material parameters. Photographs of surface wearing and plots of test restdta are' shovw 'Origi art. has: 7 figures and 6 '--7 equa, ions so COOM, Ali -29/ SM DATEs 3ljul65/ MIG MW.- 009 Card 2Y2 -~!~ -7 Operation of the g7necological exinining clinic. Zdrav.Belor. 5 no.6:56-57 Je '59. (HM 12:9) lo Glavkvy vrach Hosaonskogo rayona. (GMVOA-,IV.-d CRGAIIS, MAU,-DIS-USES) MoKanx, 1. 14QL-r~- With rest and treatuent. Prou.koop.no.1:33 J& 156. (MLRA 9:6) I.Zamestitall predsedatel" pravlonlya Vaekoprometrakhooveta. (Health resorts. watering places. ate.) Nuom*Yrt I.F. Frco a departuent to a university of health. Zdrav. Roo. Feder. no,7:24,-26 So 160* -.~ (KmA 13:9) 1, Glavnyy vrach Podollskago doma sanitarnogo proaveshobeniya. (MOSCOW PROVINCE-MUH EDUCATION) 35288 D2077D.,,01 14~ W29 Ali 11 ~02: i"E, llleuuitu~' of un of thc L;'V-,Lb-_i.'_,_itj Of S OUIP, 3 E, n, oyi T:.jtytUt 0 4 n L cy b c.) r i tu i co v v 18 , 1961. Vo.,)rOS,r i-m-cren-Ly, 125-127 s 0 1 , I n a I - le t c f 1 u. c b, , i) c L L i i c n t e t, L; or 4 C. C, years' s o r a e v i a s i n v c s t c, +v e d '-!'h e .: i n e t 3 0 _- e ,-,I e o f A i d A-3 a.,-.d z1""03 ) Fe-'_Tli-.~' al O,rS, --red as spjecJfied. in 7 4 4 0 2 - 4 8 G O'S T 402-43). The had va-rious L;ha.)es: Horse- ohoo, bar, hoo.1- -.,.n(I liol-Low cylindur with diou-Iieter. SO-Me I-11"L.-nets wore oubjected to artifical u-uln, ,.,.n L) - U all ernatin,", f i-eld of i,radually d e creas ing anipl itude ; ot.,,. ; r L; d suecial treatment. All vierc- otored without yo_',,.cs for three c~;_, z; at room temerature. T'he ;J;3 and artific~Lllly aC.,ed (141,"1 redUction Card 1/2 16 "611J I 6103-c /0 1 ,J/ Results olf a--rl observatio-21, ... 2)207/D301 of flux aftijr ",;;-oin'r trc._t-U'-;.jen0 fl-L-:, 'os~L of a t e r t,,e 2.7 8 53", 10'- -c 1-~-~ years, comi)ured wit-.-_ 3 f 0 .1 i-tZ;ed ,.r-tifJ_c_Ja..Ljy. 111he jia -nct-2 -..,i-,de of a~-,d arti-Cicially alred (71:~j -f(Auction Of flaY C> t-Ileir al'ter -,hre ye:-v c -ri d YI loot only 0 . 2 5o Up to 4.21,-,' loss for ma-~~_riets W(;,Y10 ficially. Two AN3 w.1,11" ch not, _rtifi cially werc stored 'or 'hree year6 with t'--C~ir li" 0 no1c's -7n co-nz~-Lct a 30-p' loss of flux. The results indicate tIaLL. are quite stable and, i-f artificiali~r -ded, c,-n be ~Ocd in me,-.su_-i_,iL:I,- -L-1-struments. 2-hiere are I table. Card 2/2 ,;1'7 1 D2 e i'1 Y tu Y Y , Y w r or' f3r,-t-;yt :1 L 'T' C".;;; ~. 2 UJ': -Y I:'..; I Y tLZ `6 C". J'C) . 0 j4 - - - -,, 1. V dov i Vo t ro~;y ,.,i--,n-L u !, or S -L-.y . z- u k n , y , 8 4 - ~3,9 TEX'2 I a u -uho --r-s S t ud id i~-y -i e s J s c ,-v c; S- 01- ed a ho-,,i:;es--,Oe or U i1ollovi cylinder. 2o-- was fomrid thitt reliable resuits (vii thlin can be jb-~aLiad by CA anc. (mJ ddit~ of th, 0- -U, Lf o,uter cG-nve:,, side, of thc elsewh-ere ir C d b,r -~~-d --ia-metic -)r,) erts w e I :-'oi:- ti-e cylindircal h, i o ~ c d e fo r f I the rat- ;-.i air inside the maL.Inez il i o S2/6 here 31 and :3,) are the -IV-o-ual and the internal (air-filled) cros---- Card 1/~, :W-', ~. -V3 -, ,,, ol" ... D207/-j", Z- -, 'io~ 1, 11 i, sect nal ai~eas, resjectively. 'Ohe-ce u-re I a-,d 2 . V/ Caalo- ~ /n ,~ C- / 4~ POW, Gr 11010MIeUicine Dycentery n-2320 Card 1/1 Fut) 148 - 21/36 Author Nelmkupnoy, G. I. r"MONIMINAM" Title A tavy-sided method of inspecting food workers to detect persons who have chronic dysentery Periodical Zhur. mikro. epid. i immun. No 2, 58-59,, Feb 1955 Abstract Rezommands that in addition to other methods of inspection recto- scopic examination of food workers be carried out to detect per- soas with chronic dysentery. Submitted August 30, 3-954 -dbodulff f cratic 5 no.1:43-44 Nr 135. I'aiWutlzwkoy distantsti (ReLilroads-Track) Zhol.dor. tramg. (JURA 12:5) NipomaNYT, (pa"Utino). We do not agree with CourmAe Kuzustsov. ftt' i put. khoz. no.5: 21-22.wy '57s (KLRL 10t6) 1. Mwhallnik Pkautinskoy distautpii. (Railroads-Rails) MIPOEUPM. Ivan Kikhaylovich -- -_1 '-- - - _e .,j I In place of railway guard cabins-track maintenan a villages. Put' I put.khoz. no.11:48 9 157. (KIRA 10:11) 1. Ifachallnik PanyatinekDy distantall Tuzhnoy dorogi. (Railroads-Kaintenance and repair) V.POMMY, I.K. : , Stralghtening out track laid on crushed-stone ballast. Pat' i put. khos. no.4:3-4 Ap 158. (MMA 11:4) 1. Irachalln1k Parwutinekoy distantall puti Yushnoy dorogi, stantsiya Panyixtino. (Railroads--2rack) (Ballast (Railroads)) IINPOMMITT, 1. 14. Storeroon on wheela. Put' I put.khoz. 4 no.1:45 J& 060. (14IRA 13:5) 1. flachallalk distantall, stantalya Locovala, Tuzhnoy dorogl. (Railroads-lquipment and suppliao) NEPOKUPIIYY9 I.M.; SIMANCHUK, V.K. ------ Connecting Instruments to a high voltage line. Putt i put. khoz. 5 no. 103 Ja 161. (UM 14:5) 1. Nachallnik Lozovakoy distantaii (for RepokuprVy). 2. Zametitell nachalinika uchaatka energoonabzhaniyat at* Lozovayav Yuzhnoy dorogi (for Simanchuk). (Railroads-Electric equipment) A...... . ~ NEPOKUPNYYt 1. Oi~i I m.v Group of ~mmunlst labor* Putt I pat* khoz. 5 no*3:3-5 Xr 16-1. (MA 14:3) 1e flaobalinik Lozovskoy distantaiip steLozovayal Yuzhnoy dorogi. (Railroads-Employees) NUOKUPNYYO I.M. Skillful workers of the Ltz"ya district. Putti put.khoz. 5 n*.5:30-31 Ify t61. -. (MIRA6 14:6) 1. Nachallnik Lozovskoy distantsii Tuzhnoy dorogi. (Lozovaya--Railreads--TechnologicaI innovations) NEFOLU I.-, =,L, Prodz:ction innovator. Putt i put.khoz. 6 no.5:19 162. (MA 15:4) 1. Machalfaik Lozovokoy distantsii luzbwy dorogi. (Railroads-Employees) (Efficiency., Industrial) xzpoKgpmg I.M. Two sUfts use the same mahjud~. fttl L put.khoz. 6 na.12:3 062. (KaU 16:1) 1. gaelmllnik Lozovskoy distantaii pmti Tuzhnoy darogi. (Railroads-Zquipment and suppUes) .N-4 ANGKLEYKO, V.I.; ZOLOTUKEIN, G.I.; NEFOKUFM , I.M.; BASIDDVp V.V., inzh., retsenzent; FROVODI~A --- KJIG" - -:11A -ed.; VOROBIYEVA, L.V.p tekhn. red. (Collective of creative labor; experience of the railroad workers of the Lozovaya Division of the Southern Railroad] Kollektiv tvorcheqkogo truda; opyt puteitsev Lozovskol distan- taii lUzhnoi dorogi. Moskva,, Transzheldorizdat,, 1963. 41 p. (KERA 16: 12) (Railroads-Maintenance and repair) t JTDOROIF. X.T.; REPWILUYET. V.F. Basic forms of rhizospheria bacteria of timothy (Phlens pratense) and the chauge in the amber of their cells In the rhizosphere depsuding upon the developmental stage and age of the plant. V11kroblologils. 23 n0.2:266-171 Mr-Ap 154. (mraA 7:4) 1. X961covskays, sel'skakhosysystvays, akadenlys. In. K.A.Timiryateva. (Timothy grass) (Bacteria) USSR/Biology Card 1/1 Author : Fedorov, K.'V. and NeWmiluyev, V. F. Title : The occurrence and nitrogen-fixing activity of Azotdbacter in the rhizosphare of perennial plants Periodical Mikroblologiya, 23, 275-2821 MaYIJun 1954 FD 293 Abatract The occurrence and nitrogen-fixing activity of Azotobacter in the rhizospheres of clover, timothy and perennial grasses is discussed In detail. A correlation between the maturity and state, i.e. fast-groving stage, flowering stage, etc., of the plants and the above-mentioned characteristics of the Azotobacter is shown. The results of the invest- igationa are presented on 8 charts. Six Soviet references. Institution ; Moscow Agricultural Academy imeni K. A. Timiryazev Submitted : September 15, 1953 USSR/Soil Sciencee Soil Biology J-2 Abs Jour : Rof 7liur - Biolio Ito 10, 1958, 110 43803 Author : Podr:ubnyy N.14, Kepomiluyev V.F. Inst : Not Given Title : The Biochenical Processes Occurriag in Solonetz wid Soloth Soils in the PrOsence of F-xccssive Moisture Crig Pub : DokI. Vbsk. s.-kh. akad. in. K.A. Timiryazeva.. 1957, VYp'- 29, 202-207 Abstract Research made in Kokehetavsbmyn and Saratovskaya Oblasts has shown that excessive moisture in sol3netz and soloth soils reduces the quantity of aerobic saprophitic microorganisms, the nitrifying and aerobic cellulose-decomposing bacteria, while increasing, the amunt of anaerobic microorganisms. Under anaerobic conditions the microbiological processes lead to the formation of ferrous compounds, The intensity of these processes depends on the composition of organic substances, as well as on the quantity of diverse species of microorganisms. F.H. Sofiyeva Card 1/1 FGDDU3M* N,K., kandaelcokokhozymystvannykh naukt.NF OMILUT~V, kALnd*b1o1ogicheskikh nauk -F Properties of solodized soils and their biochemical processes under excessively vat conditions. Izv. TSKhA no.3:98-108 160. (MIRA 14'.4) (Solonetz soils) (Soloth soils) (Soil micro-organisms) NJPMIWYW, TJ** kande bLol. nmk; GMHIN, I.P.9 kand. sellskakhazMat- 4wim ~-� , nattic. Nfect of different tillage wthads of dynamics of adcrobiolegical. processes Im turf---%dzolIc soils [with summary lit magliah]'O IWO T3KhA na;UI37-:144 1586' (=A 11:6) (Soil micro-organi time) (Ifillage) KLURIGEMV, I,S-; UMMILUMV, T.r.; PODDUBRT, 9.11. Characteristics of oxidation-re4twtiom processes In Solonets and Soloth soils Lwith summry in UglishJ. Fochvoyedenis no.4:9-15 Ap 159. (KIRA 12:7) 1,3el'skakhospystvannaya akademiya In, X,,A. Timiryateva. .(Solonett soils) (Soloth soils) (Oxidation-reduction reaction) WOMUM, V.P.; GHWHIN, I.P. Characteristia features of microbtalogical. pro(tesoes In tol- Podaclio soils depending on cultivation prdotioed~' Trudy inst. mikrobiol., =7:87-95 160. (MIPA 104) 1. Moskovskaya sel'skokhosAystvannaya akademiya imeni K.A. Timiryaseva, (SOIL HIGRO-OFAMISMS) (TILIAGE) NEM=M., V.F,,,, kand.biologicheskM nauk,; SHISHOV p L L. kand. ---vaTWo-Hi6zyaystvenrqkh na"k, Cultural use mi-croflora of turNmy soils and -its change dur!,~ o~ aoila [with su=ag7 in English]a IsTe TSK no.1 7~.-10/* 162, (KM -IS.-6) (7olga Valley-Soil micro-opanims) NWOMILUMT. V.P.; SHISHOV, L.L. Distribution and nitrogen fixating capability of Azatcbacter in turf- gley soils. Nauch. dokl. vys. chkoly; biol. nauki no.2:191-196 162. L . (min 25: 5) 1. Rekomendovana kafedroy pochvovedeniya Moskovskoy sellskokhozymystvannoy akELdemij im. K.A.TimiryazeVm. (AMOBAGTER) N EMI Xfy Vh nauk; KUZMINA, T.r. ,_VF,_.dotsentg ksnd.~biologichask , Rffeat of tilling peat on the microflorm and microbiological procesmas. Irv. TSKHA no. 1%71-~ft t65 (HIRA 19i1) 1. Wedre. pachvovedeniya Hoskovskoy seliskokhazyaystvennoy ordena Lanina akadamii. imeni Tintiryamvae. NZVMIN, T.Ya.i kand.istor.namk; UaMoy, V.T., otvered.Edecaaaed]; KNOPOT, B.Z., red.1zd-va; GORTOVSKATA, Z.F.4 takha.red. [outline history of the building of socialism in Uzbekistan, - 1917-19371 Ocharki, istorii stosialistichaskago stroitel'stva v Usbakistans. 1917-1937 99. Tashkent. 1zd-vo Akad.nauk Uzbekakol SO, 1957, 216 p. (MIRA 13:9) (Utbakistsn-Mconomia conditions) kand.lator.nauk; ZEEITOV. X.Te.. daktor istor.nauk. otv*redo; RAYZVSKIY9 L.I., red.; SALAMIMIXOTA, A., tekha.red. (Historical experience in the buildinc of socialism In Uzbe- kistan. 1917-19371 IstorichaskIl opyt stroitallstva sotsializma v Usbaklataae. 1917-193?. Otvat.red.K.S.Zhitay. Tashkent. Gos.izd-vo, Uxbakskol SSR, 1960. 381 p. (MM 13:9) (Usbakistan-11conomic conditions) 5 (3) AUTHORS: Uironov, T. F.p Nepomnina, V. V, BOV/62-59-T-12/38 TITLE; The Influence of the Chlorosilyl Groups on the Mobility of the Chlorine Atom in 0 -Chl oralkyl oil anes Dzfng Their Dehydrochl orina - tion by Quinoline (Vliyaniye khlorsililinykh grupp na podvizh- nost' &tome khlora v P-khloralkilsilanakh pri degidrokhloriro- vanii ikh khinolino'm) PERIODICAL: Izvestiya Akademii nauk 3SSR. Otdeleniye khimicheakikh nauk., 1959s Hr 7, pp 1231 - 1237 (U33R) ABSTRACT: In the present paper a P-decomposition product is obtained by the dehydrochlorination of CH 3Cl, 2SiCH2 CH 201 with quinoline which is produced according to the following reaction scheme: /Si - a - C x -4 Si - + C - C + X (X - halogen). The reaction was more intensively investigated in a series of compounds of the type Cl nR3-n SiCH2CH 2C1. HCl is splitted off. It was observed that the formation of a 0-product CInR 3-n51GHCff2 Card 0 proceeds the more easily the greater n is. From the fur- The Influence of the Chlorosilyl Groups on the SOT/62-53-7-12/38 Mobility of the Chlorine Atom in P-Chloralkylailanes Dur- ift Their Behydrochlorination by quinoline, ther investigation of the mobility of the P-ohlorine atom it follows that this atom is more mobile in the chlorine compounds Cl3 SiCRKH2 sicl3and in a,a-, app-, and Pop-dichloroethyl-tri- chlorosilane than in the P-monoohloroalkyl-trichlorosilanes. Moreover, the following substance was obtained from the in- vestigationa: all - as (CH 3)? 5i\ I 1,1-dimethyl-eyelosilicon-pentene-2. CH 2 -CH 2 The different reactions and synthesis methods are described in detail in the experimental part. There are 18 referencesi 9 of which are Soviet. Card 2/3 The Influence of the Chlorosilyl Groups on the SOV/62-59-7-12/38 Mobility of the Chlorine Atom in P-Chloralkylailanes Dur- ing Their Dehydrochlorination by Quinoline ASSOCIATION: Inatitut oreanicheakoy k-himii im. N. D. Zelinakogo Akademii nauk SSSR (institute of Organic Chemistry imeni 11. D. Zelinskiy of the Academy of Sciences, USSR) SUBMITTED: November 23# 1957 Card 3/3 82693 3/062/60/000/008/007/012 Do B004/B054 AUTHORS: 1(iroa*v,, V. F. and-14epounina, V. V. TITLE: Synthesis of Alkenyl Silaneqjby Addition of Nothyl-dichloro Silane to Diane- and Acetylene Compouads PERIODICAL: Izvestiya Akadenii nauk SSSR. Ot4elentte khimicheakikh naak, 1960, No. 8, pp. 1419-1423 TZXT: Other investigators (Ref& 1, 3) arrived at the conclusion that tri- ahlorosilane and nethyl- or ethyl-dichloro silane are added to butadiene in 1,4-Position only. The authors found that this also applies to the addi- tion of methyl-dichloro silane to piperylenelThe structure of the reaction product could be established by the identity of the Raman spectrum of the compound obtained in the following two ways: Card 1/4 A $2693 Synthesis of Alkenyl Silanes by Addition 5/062/60/000/008/007/012 of Nothyl-diahloro Silans to Diens- and Acetylene B004/BO54 Compounds CH3 CHoUgHCH3 + ]lei CH2.CHCH-CHCH3 (CH3J~~iCHCH-CHCH, CH3 Nsica CH CH-CH%CC1273Z CH3 vgci 3 3 Instead of platinum on carbon,, the authors used J. L. Speier's (Ref. 9) catalyst for their syntheses, and than could work under mild conditions at atmospheric pressure. With addition of mothyl-dichloro silane to diallyl, an isomer- with a different position of the double bqnd is formed besides the 6-hazanyl-methyl-dichloro silane expected, which was established-by means of the Razaa spectrum after methylation of the compounds. Furthertthe authors performed the following syntheses% addition of methyl-dichloro silane to phenyl acetyleneil Card 2/4 82693 Synthesis of Alkenyl Silanes by Addition S/062j60/000/008/007/012 of Nothyl-dichloro Silane to Diene- and Acetylene B004/B054 Compounds c6ff5C MOR + MCI 2ON 3 0 06H5 CH-CHSicl 2C'13- 5 C6H5CH-CHSi(CH 3)3' The P-(trinothylsilyl)-styrome thus obtained differs in its Haman spectrum from the a-isomer produced formerly (Ref- 17). Besidest the P-isomer was also produced by means of organomagnesium reaction (Ref. 18); here c6H5cmesi(CH 3)% was formed an a by-product* The addition of asthyl-di- chloro silane to hezine occurs with the formation of the a-isomer which was identified by the Raman spectrum: C H C=-CH + Hsicl OR -10. C H CH 4 9 2 5 4 9 McHsicl CH H H-CHSi Further, the reaction was carried out 2 3 --'No C'4'. 9C (CH3)3' with stbyl-dimethyl-ethinyl silanst CH 5 (CH3 sic =CH + Rum 3cl2 CH ifgal SICHaCEISiCH Cl P. C2H (CH ) SiCH.CHsi(ca The "2"5(0113)21 3 2 5 3 2 3 30 physical data and the,Raman spectrum confirmed the structure of this can- pound as a 192-disubAAtuted ethylene (Rafe 2)., The addition of Card 3/4 $2693 Synthesis of'nkenyl Silanes by Addition S/062/60/000/008/007/012 of Nothyl-4ichloro Silazte to Diane- and Acetylene B004/B054 compounds mothyl-dichlaro ailane to isopropoxy acetylene is also mentioned. The silyl, group to always addol to the C -=C bond. The authors thank L. Leytes for taking and analyzing the Raman spectra. There are 23 references: 15 Soviet, 10 US, and I British. ASSOCIATIOI: Ynstitut organicheikay khinii im. N. D. Zelinskogo Akademii naak SSSR (Institute of OrganichChemistrz ineni N. D. Zelinskiy of the Academy of Sciences, USSR) SUBMITTED: February 27, 1959 Card 4/4 87166 s/o62/60/000/012/005/090 7, 2 D 5, 11--) 1 BO13/BO55 AUTHORS: Mironov, V, F. and Nepomnina, V. V, TITLE- Sy-nthesis of Unsaturated Organosilicon Compounds by Dehydro- chlorination of (y-Chloro-alkyl) Silane Chlorides (The ex- presoicn "ailane chloride" is used by the author to denote that all available hydrogen atoms bound to uilicon are replac- ed by chlorine) PERIODICAL: Izvestiya Aka3emii nauk SSSR. Otdelleniy- ~himicheskikh ri,--vik, 1960, No. 12., pp. 2140-2146 TEXT: In this publication the authors studied the possibilities of pieparing (7-ch-loro-alkyl) silanes using 0,1 N H2PtCl6'6H 20 in isopropyl alcohol (Ref- 7)~ It was found that under the conditions described - apart from methyl di,.hloro silane - methyl diethyl silane, methyl ethyl chloro silane, ethyl dichloro silane and trichloro silane also add readily to allyl- and methallyl chloride. This method has the advantages cf simple procedure, high yields and the possibility of adding new hydrosilanes (expression used to lenote silanes in which the silicon contains at least one unsubnt~~tuted Card 1/3 87166 Synthesis of Unsaturated OrganosilicoL Compcundu S/062/60/000/012/0W-/020 by Dehydrochlorination of (7-Chloro-alkyl) B013/BO55 Silane Chlorides atom) to halo olefins. This could not be affected by the former methods. The authors also added CH 3Cl2Sill to C11 2= C(Cil 291)2 obtaining the (y-halo-alkyl) silane chlorides listed in Table 1. The authors studied various methods of dehydrochlorination of (y-chloro-alkyl) silane chlorides to obtain alKerVIsilare chlorides. It was found that 5-10% piperidine relative to (y-chloro-alkyl) silane chloride is sufficient to attain maximum yields of alkenyl silane chlorides. The (V-chloro-alkyl) silane chlorides given in Table 2 were de-, hydrochlorinated in this manner. This method is without doubt the sImplest and most convenient way of synthesizing allyl methyl dichlerc silanes, methallyl.methyl dichloro silanes and other alkenyl dichloro 3ilanes. The following rules were observed.-(Y-chloro-isobutyl) silane chlorides (with the exception of Cl 3SiCH 2CH(CH 3)CH2C') on dehydrochlorination with piperidine always yielded a mixture of isocrotyl- and methallyl silane chlcrides. The ratio of these two alkenyl silane chlorides varied in the E~xperiments, -Ind-1- eating the cocurrence of isomerization of methally! silanes +,- isocrctyl s;lanes during distillation. Dehydrochlorination of (y-chloro-.Fropyi) silane chloride, however, leads exclusively to allyl ailane chlorides, ECI is Card 2/3 87166 Synthesis of Unsaturated Organosilicon Compounds 3/06 60/000/012/005/020 by Dehydrochlorination of (y-Chloro-alkyl) BO13XO55 Silane Chlorides evidently most easily split off from compounds of the (y-chloro-alkyl)-di- chloro-silane type. (P-chloro-ethyl) trichloro silane and (P-chloro-ethyl) diohloro silane split off EC1 much less readily under the action of piperidine. (y-ohloro-alkyl) eilane chlorides behave similarly. The reverse dependence was observed under the action of quinoline, however. There are 3 tables and 13 references: 11 Soviet and 2 US. ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii nauk 3~~SR (Institute of Or.-anio Chemistry imeni N. D. Zjelinskiy of the Academy of Sciencus USSR) SUMILITTED: June 3, 1959 Card 3/3 14IROMOV, V.F.; IRTONtmo VIV, I- Effect of the character of the si2yl. group an the rate of debydro- chlorination of gone t4 - and 1/--chlormlkyah2orosi2anes by piperldinee Izv.AN SWR.Otd.khim.nauk no*5-.920-921 Ky 161. (MA ]A:~) 1, Institat organichaskoy Ich'sli Im. V.D.Zelinskago. (SL2y.1 group) (312ans) (Piperldine) 3/66 5Y61/000/006/023/081 D20 D302 AUTHORS: Hironov, V. F. and Nepomnina, V. V. TITLE; The rearrangement ofCC-8-dichloro-iso-propyl trichloro- silane on dehydrohalogenation with aluminum chloride. SOURCE: Khimiya i praktichaskoye primeneniye kremneorganiches- kikh soyedineniy; trudy konferent6ii, no. 6, Dokladyf' diskusaii resheniye, II Vaes. Konfer. po khimii i praktq prim. kremneorg soyed. Len. 1958. Leningrad. Izd-vo AN SSSRt 1961t i12-116 TEXT: a -B-dichloro-isoLpropyl trichlorosilane was dehydrohalogena- ted by A101 giving a produc~,which was identified as 0-ohloro- V propenyl trichlorosilane. This is an additional proof for the pro-;! posed mechanism Card 1/2 S/661/61/000/006/023/081 The rearrangement of *1*0 D205/D302 ClIct a Q E~Sic_?W ec-csit -C163!C-C4 + ctsic-is - .,I I. A.-Shikhikevs(Baku), R. l(a.,Freydlina (INEOS AN SSSR, Moscow), P. S. Rokiskeweki (Institute of Synthetic Resins, 11arsaw) and A. L.'Klebansk4 (YKIISK, Leningrad) took part in the discuasion. The opinion expressed by the investigators, who took part in the dis- cussion, Was that the pro-osed mechanism is not sufficiently clear. for the time being and fu.,ther..,, more substantial proof is needed* There are 2 Soviet-bloc references', ASSOCIATION: Institut organicheskoy khimii Akademii nauk SSSR, Moskva (Institute of Organic Chemistry, Academy of Sciences~'Iloscow) Card 2/2 MIROMOV9 V.Feg NEFOMNIIIA, V.V. Rearrangement proceeding during the dehydochlorination of 1, 2-bist(trichlorosilyl) dichloroethanes by alusimum chloride. Izv.AN SSSK40td.khia.nauk no.10M95-1799 0 461. (KM 14:10) 1. Institut organicheskoy khimii in. NoD.Zelinskogo AN SSSR. (SUane) (Hydracbloric acid) 28275 S10621611000101010121018 B106 B101 AUTHORS: Mironov, V. F., and Nepomnina, V. V. TITLE: Synthesis of alkenyl silanes by high-temperature condensa- tion of unsaturated comnounds with silicon hydrides PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh nauk, no. 10, 1961, 1686 - 1886 TEXTi It was shown in previous papers (Ref. 1: V. F. Mironov, Author's Certificate 126883 (1959); Byul. izobr., No 6, 19 (1960); Chem. Abstra ~A, 19485 (1960); Ref. 2: V. F. 1bfironov, Collect. Czechoalov. Chem. Commun. 2.2, 2167 (1960); Ref. 3: V. F. Mironov, A. D. Petrov, V. V. Pisarenko, Dokl. AN SSSR 124, 102 (1959)) that ethylene and propylene are converted into the corresponding alkenyl 0 silanes when shortly heated to -600 C together with silicon hydrids s: .6000C: =CFSiCl (20cl',), CH CH=CH + HSiCl 600 C CH 2= CH2+ Hsicl 3 > CH2 3 3 2 3 )FCH 2-CHCH2Sici3 + CH 3CH-CHSiC1 3 (10'/j). The authors used this new Card 1/4 2r,275 S/062/61/000/010/012/018 Synthesis of alkenyl silanes ... B106/B101 reaction to study the high-temperature condensation of trichlorosilane with styrene, cyclopentadiene, and vinyl trichlorosilane. Condensation of styrene with trichlorosilane gives 0-trichloro silyl styrene (yield, 0 20 20 15cp; boiling point, 90-93 C (2 mm Hg); n D 1.5540; d 4 1.2718; IJR 59~87), the structure of which was proved by methylation (perfect agreement of properties and Raman spectra of the resulting substance with those of the well-known p-trimethyl silyl styrene). C H CH-CH + HSiCl 6000C CHjMgCl. 6 5 2 3 C 6H5 CH-CHsicl3 0 C6H 5CH-CHSi(Cli3) 3* The condensation of trichlorosilane with vinyl trichlorosilane yielded a mixture og disilyl-- substituted ethylenes (yield, 1CF/~',); Cl 3SiCH=C.;f2+ Hsicl3 600 C1) CI 3SiCH-CHSiCl 3 + (Cl 3S')2C'CH2 . The high-temperature condensation of cyclopentadiene (or of its dimer) with trichlorosilane yi4-,Alded oyclo- pentadienyl trichlorosilane (yield, 25~'-): L~ + H3iCl 3 -6000C SiC13 CH3ML:24=S'(CH 3)3 Card 2/4 16. 28275 3/062/61/000/010/012/018 Synthesis of alkenyl silanes ... B106/BI01 The properties of the resulting cyclopentadienyl trimethyl silane (boiling point, 138-140'C; n 20 1.4610; d20 0.8834; MR 45-54) do not agree D 4 with the properties of the compound obtained previously (Ref. 6: A. D. Petrov, G. I. Nikishin, Izv. JUI SSSR. Otd. khim. n. 1952, 1128; Ref. 7: see below) by organometallic synthesis. C5H5M + ClSi(CH3)3 ) Si(CH3) 3* (M = Li, MgBr) Whereas the latter cyclopentadienyl trimethyl silane, to which the above structure was ascribed without proof, reactd vigorously with maleic anhydride in ethereal solution, forming an addudt with the melting point 1020C, the cyclopentadienyl trimethyl sildne'synthetized by the authors does not react with maleic anhydride under the6e conditions. The Raman and infrared spectra of the two compounds also differ considerably. Hence, the following structures are suggested for the cyclopentadienyl trimethyl silane synthetized by the authora: =~ Si(CH 03 or (C'3)3S' Card 3/4 2P,275 S/062/61/000/010/012/018 Synthesis of alkenyl silanes ... B106/BIOI Also structures of the type lz~ Si(CH 3)3 cannot be excluded for the t.-me being. The authors thank L. A. Leytes for taking and analyzing the Raman spectra. There are 9 references: 8 Soviet and I non-Soviet. The reference to the English-language publication reads as follows: Ref. 7: K. C- Frisch, J. Amer, Chem. Soc. 12,, 6050 (1953), ASSOCIAT1011. Institut organicheskoy kh-imii im, 11. D. Zelinskogo Akad'~Mli nauk SSSR (Institute of Organic Chemistry imeni N, D. Zelinskiy of the Academy of Sciences USSR) SUBMITTED: April 5, 1961 Card 4/ 4 25400 S/08 61/034/002/022/025 A057YA129 AUTHORSs Chernyahevv Ye.k.~ Hirotav~ V.F., Nepomnina, V.V., Liogunov, S.A. TITLEs Remotion of ailiaon hydrides with etay'A.- and isopropyl- benzene and ;rsparaticn of triohlorosilyl-substituted styrenes PERIODICALs Zhurnal Prikladnoy KhimIU, -v 34i no 2Y 1961,? 458-460 TEXTo AxylohAL.-roeii-tres were vy-nthem-1--ed by resotIons of triohloro- silene "d vith ethylpharql- and istpropylphenyl- -benzenes in liqi).id phaes undex presm.,,ro using H BO %a cate.1yet,, methyl diohlorogilans was more aoti-46 than tri,ih1.crOeiKrI TrichlGrosilyl. -sub- stituted styrene and (A-msth-~31-y:ren~; va!j by -,hIorir_atIL:,r, of - ethylphanyl- and tc mon--4,AL-;rIdea~ ani pyrolysis the la-Itter. N~,wadays -.hree syn"her;i-es cf are frequently st,_,di,~d. The z-stl ~.i the meth~,i st-_A.Iied in thA Card 1/5 25V0 /090/61/034/002/022/025 Remotion of silioon hydrides ... A057/A129 present InTestigation, ';.e., the 7eaitLon botwe6n sa.lioon hydride and benzene (or homologs) in liqj;id phasa ~Lnler presoure at 2001-400'0 with catalysts (BOl&H BO , A10,1 9 eto.). In thfi se,7oal methad Instead of benzene (or ho o ois)3an ar,71hall4o is used (Ref 7a A. B%rry et al.j InI. Eng. Chem-, 51, 91 (1959)) and twi-,e as much sillic,-_ hydride is neressary than in the first method. Ir. the thJrd -variant silioon hydride and aryl- halide reaot in gaseoas phase at atmoephsri-~ pressure in flowing syetems at 5000-70000 (Ref 8s Ya.A. Cherryahoy et al.~ DAN SSSR, 127, 808 (1959), Ref go ibid.132, 1099 (1960), Ref 10i A.D. Petrov at &l.9 ibid.126, loog (1959), Ref ils V.A. Ponomaranko et al., !bid. i30, 333 (1960)). The present experiments were iarried out to compare the yields of the aryl- chlorosilanes and to check. results of other Investigators. The reaction occurred in a rotating steel autoolave 0 1), ratio o; components was 1 t 1 with 0.1 weight % of oatalyst and contact time of 5 hrs at varying temperatures from 2300-360'C. The results (Fig.) indicate the higher activity of methyldiohloroollane in comparison to tri3hlorosilane. This is in agreement with observations in Ref 7, but differs from the stateuent Card 2/5