SCIENTIFIC ABSTRACT NENCHUK, M.F. - NENITSESKU, K.D.
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CIA-RDP86-00513R001136610006-7
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December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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NENCHUKf Moire
kholent carbonate.ioals pf the Rakhov Massif. Geol. zhur. 2r,
no.j:166-110 065.
gosudarstvennyy universitet !m. I. Franko,
?kqOr.;-..---
let us make a spatial rL-arrangement for the most,.beautiftd
historical momments of Pe=J- Fecsi muss smaml 9 no./+t
15-18 O-D'63*
3/169/61/000/011/013/065
D228/D304
AUTHORS: Kuznetsov, V.P., KuzIminap N.V., Nenelinaa V.3c
Nersesov, IoLev Sultanovap Z.Z., and Kharin, B.A.
TITLEt Seismicity of the eastern part of the southern spurs
of the Central Caucasus Range and some methodical
questions of the study of seismicity of separate areas
PERIODICAL: Referativnyy zhurnal, Geofizika, no. 11, 1961, 18,
abstract 11A162 (Izv. AN AzerbSSR, Ser. geol.-geogr.
n-t no* 50 1960, 21 - 33)
TEXT: Determination of 'he degree of seismic activity on the sou-
thern spurs of the Central Caucasus Range was continued from the ex-
peditional data of 1953 (for the first part see RZhGeofiz., no. 10,
1960, 11944) with a description of the strongest earthquakes: The
Akau-Kyurdamir earthquake of October 8, 1953 and the Avakhil. earth-
quake of October 4, 1953 (the strongest ones~; auj the Caspian re-
gion earthquakes of August 8, September 14 and 19, and October 13.
Epicentral zones - situated in a comparatively narrow strip along
the Central Caucasus Range's southern slopes which follows the main
Card 1/3
3/169/61/000/011/013/06~,
Seismicity of the eastern part ... D228/11304
structural directions - were considered. With the exception of somp
deviationst the seismically-active sections correspond to the t---n
sitional belt from the depressions to the mountain regions, 1.e.tfie
zone of contemporary contrasting movements. In the vicinity of Kut-
kashen a group of epicenters in a small area is situated transverse-,-~
ly to the strike of the structures. Within the seismically-active
belt the areas of epicenter concentration are separated by sections
of complete quiescence. When comparing the expeditional data of
1953 and 1951 - 1952 with those of the network of permanent sta-
tions for the period from 1913, it is established that a certain re-
distribution of seismic activity has taken place# although the lo-
cations of strong earthquakes coincide with areas which are distin-
guished by their activity according to the observations of seasonal
expeditions. The expeditional investigations enable observational
data ti be processed more accurately and a better basis to be con
structed for the relations of seismic and tectonic phenomena, The
complexity of the geologic structure of the study area hampered the
obtaining of the coordinates of earthquake foci with the requii-ed
precision. The use of different methods permitted determination of
the epicenter positions with an accuracy of up to � 5 km, and also
Card 2/3
S/169/61/000/011/013/065
Seismicity of the eastern part ... D228/D3 A,
the propagational velcoties of seismic waves and their ratios. The
ratio of the velocities for different foci varied from west to
from 1~8 (the Vartashen district) to 2.2 (the Avakhil districti
evidently because of the presence of a thick series of sedlment.,t,
rocks in the eastern areas. The low value of the fictitious -,elocr-
ty, which varies from 4.1 (Astrakhanovka) to 6.1 km/sec: 'Durukhshao'
is a consequence of the low value of the velocity ratio ~Abstrac-
tor's note; Complete translation].
Card 3/3
HMMGp Lasslo; KOVER, Gyorgy; DUBEGZ, Krzaabst; NIM, ~Yorvr
Effect of kqpothermia an the Inmlin space. Kiserlates orwastud. 13
no-4:381-384 Ag 161.
1. Budapeati Orwastudomanyi Egyatem glettani Intexate.
(BODY TMPEnT=) (MMIN metab)
68-58-3-1Y22
AUTHORS: . Kenich, -4~ Drinfelld, P.I., Tselykovskaya, R.K.
~Tlstavlro . F. 1.
TITLE: Iffluents from the Indene-Couma one Resin Plant and
Possibilities of Their Purification (Stochayye vody tsekha
Inden-Kumaronovykh smol i vozmozhaosti ikh obezvrezhivaaiye.)
PERIODICAL: KokB i Khimiya, 1958, Nr 39 pp 40 - 44 (USSR).
ABSTRACT: Biological treatment of coke oven effluents deteriorated
when the effluent from the Indene-Coumarone Resin Plant was
added - Methods of pre-treatment of this effluent were investi-
gated. It was found that the bestiesults are obtained when the
neutralised effluent is passed through a vacuo-filter in order
to separate aluminium hydroxide (derivedtom aluminium, chloride,
the catalyst used for polymerisation) then into a settling
tank for the separation of benzole. ifter the separation of
benzole, the effluent is passed into the biological treatment
tank. At present, an installation based on the above scheme
(Fig.5) is being designed. There are 4 tLbles and 5 figures.
ASSOCIATION: Kadiyevskiy koksokhimicheskiy zavod (Kadiyevka Coke
Oven Works)
Card 1/1
SOV/68-58-10-13/25
`AUTHORS: Yastrzhem'skaya, O.V.t And-reyeva, V.S.,,_Ke jxj4 v.N.,
-
Royter, M.K., Drinfelld, P.Ye., and Bilym, L.M.
TITIZ: From Experience of Putting the Indene-coume one Resi4
Plant on the Kadiyevk&LCoking Works into operation (Opyt
PUBka i raboty tsekha inden-kumaronovykh smol na Kajiye-
vskom koksokhimicheskom zavode)
PERIODICAL: Koks i Xhimlya, 1958, Nr 10, pp 40 - 44 (TJWR)
ABSTRACT: The plant was put into operation in 1955. The mheme of
the operation of the plant as designed is shown in
Figure 1 and changes introduced are shown in Figures 2
and 3. Aluminium chloride is used as a catalyst in a
PrOPOrtion Of 0.35% of the raw mgterial~ The polymeris-
atiog process begins at 20 - 30 0 and is finished at
110 C. The main difficulties were encountered ig,tthe
.
the
distillation plant due to the incorrect design of
evaporators and due to an excessive corrosion of the
condenser. All resin pipe-lines were found to be too long
and complicated. Cooling drums for resin were
insufficient. The initial 'Losses of hydrocarbons amounted
to 18-20%, and were reduced (by un pecified methods) to
Card 1/2
SOV/68-58-10-13/25
From Experience of Putting the Indene-coumarone Resin Plant on the
Kadiyevka Coking Works into Operation
6-8%. Bcftgaing temperature of the resin produced
100 - 110 C. It is pointed out that in order to decrease
corrosion, an enamelled distillation apparatus and a
reactor for the preparation of aluminium chloride complex
should be introduced. There are 3 figures.
ASSOCIATIONS: MIN and Kadiyevskiy koksokhimicheskiy zavod
(Kadiyq--vU-,- Coking Works)
Card 2/2
I- MICH T.R.- BRINFILID, P.I.; TSILYKOVSKAYA, 1F.K.; ACORWO, N.Ya.
~
Dephenollsation of waste waters fron recover7 plants by the Inicrobe
nethod.0 Lake i kh1m. n0-1:38-41 160. (MIRA 13:6)
1. Fadlyevsk.1y kokookhtmiaheekly cayod.
(radlyefta-Sawage disposal)
(Phenols)
Card 1/1
ics - Yar-.bquake focus
V. L
Pub- 45-02
Ful-i
Author Savarenskiy, Ye. F., and 11enlltm, V. S.
Title Taking account of geological inhomogeneities In the determination of
the position of source (focus').of earthquakes
Periodical % Izv. AN SSSR, Bar. gaofiz.,, 17-30, Jan-rob 1955
Abstract : The authors discuss methods for detierminlug the position of earthquake
foci under the condition of establishing the velocities within plane-
parallel horixontal. layers of the terrestrial crust. They propose a
method for taking Into account the geological inhonogeneities. This
method is applied to certain observations carried out In 1951 by sta-
tions of the regional type of the Aralo-Casplan expedition, Academy
of Sciences WSR. Four refereaces (e.g. S. I. Golonetakly and A. A.
Treskowp "Method of Isochrones.." Trudy Geofiz. in-ta AN SSSR, No 21
(148), 1953; 'Wthod of bypocenters," ibid., No 14 (141), 1952).
Institution : Geophysics Institute,, Academy of Sciences WR
Submitted : Xanuary 25, 1954
BAGDASAROVA, A.M.; ISLAHOV# K.Sh.; KORIDALINp TeoA.; KU2MTSOVO V.P.;
KWHINA, N.V.; NENILINA, V.S..j HERMSOV, I.L.; SULTAKOVA, Z.Z.;
KHARM, D.A.
Sainicity of the eastern part of the southern spurs of the
Greater Caucasus and some problems of methodology in studying
the seismicity of individual regions. Report No.l.-:- Izv.AN Azerb.SSR.
Ser.ge*ol.-geog.nauk no.6:121-131 159. (MIRA 15:4)
(Caucasus-Seismology)
BAGDASAROVA, A.M.; ISLAMOV, K.Sh.-. KORIDALIH, Te.A.; KUZNETSOI, V.P.;
KUZIMINA, N.V.- HENILINA, V.S.: HERSMV, I.L.; SULTANOVA, Z.Z.;
KHARIN, D.A.
Seismicity of the eastern part of the southern spurs of the Greater
Caucasus and some problems of methodology in studying the seismicity
of individual regions. Report No.3. Tzv.AH Azerb.SSR. Ser.geol.-
geog.nauk i nefti. no.4:13-24 161. . (MIRA 15*1)
(Caucasus--Seismology)
GIBIUS9 F., kand. mad. nauk; DAKTAtUVICIEUE, E.p kand. mod. nauk;
JAHZEMSKAS, J., kcand. med. nauk [deceaaed]; JOCEVICIEVE,, A.,
kand. med.nau ; KRIKSTOFAITIS, M.9 kand. med. nauk;-KWSM.,,J..',-_.
kand. med. nauk; STEMUrLIRIE, L.,, kand. med. nauk; SURKUS, J.,
kand. mad. nauk; SIMANAS, S., kand. biolog. nauk; CEPULIS, St.,
prof.; KUPCINSM,, J.,, prof.; WAS, VI., prof.; SIDERAVICIUS,Br.,,
prof.; KANOPKA, E.,,dots.; hVIKLYS, V.,dots.; LABANAUSUS, K.9
date.; POLUKORDASp U., dots.; BABUBUS, F.9 doktor; CAPKMCIUS,,V.,
doktor; MAKARMIALS, P., doktor; PAKOIIAITIS, P... doktor; STUOKA.R.,
doktor; SURGAILIS., H., doktor; PAULIUKONIEVE, J.,, red.; AMITIS,J..,
tekbn. red.
(Health and diseases] Antrasis pataisytas lAdimas. Vilnius,,
Valstybir- politines ir zwkslines literaturc; leidykIn, 1961. 356 p.
WIRA 15:3)
OrGIM) (PATHOWGI)
SDMNASt V,; MASLAUSKIENE, H. j; ZAIKKUMM, M., red.; ZILINSKIRIE,V.,
red.; KVIKLYS, V.p kand. med. nauki red.; MOTIFJUNAS, L.p
kand. mad* naukv red.; NEMISM, J.9 kand. mod. nauk, red.;
STECOVSKIS, A.L.9 tokbni~~reft----
[Lithuanian medical bibliograpby] Lieturiekoji medicinine
bibliogra ija. Vilnius, Valstybine moksline medicinos
biblioteka. Vol.2. 1958-1960. 543 P. (HIRA 170)
1. Prodoodatell Soveta Gosudaretyermoy nauabno-meditaill.-
skoy biblioteki Hinisterstya zdravookhranoniya Litovokoy
SgR (for Zaikauskao). 2. Direktor GoeWarstve=oy naucbno-
meditsinskoy bibliotski Ministerstva zdravookhranenlya
Litovskoy M (for Zilinskiene).
- KENISKIS
, -
Apropos of lowering the mimber of abortions performed outside
of hospitals. Sveik. apsaug. 9 no-*lt35-38 .1064.
1. LTSR Sveikatos apsaugos ministerijos vyr. akuseria-gine-
kologas.
*4
IOKTL,, Ghoorghs, ing. (Hucuresti); MITL,, Eugen,, ing. (Rucuresti)
Automtion of hydroelectric power stations in ftwnia.
Knergetica Rum 10 no.7:302-310 JI 962,
le Proiaotant oaf I& Inatitutul do studii si proiectarl.
energetics (for lonita). 2. Proisetaut la Institutul do
studii, si proiectari energetics (for Kenita).
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I
&A
i
i
h
6
.
m
a a
w
t
an 0.
.
k
rvic ctif"
etWerAte, "" (Cftvd with 90 W. No. to stuall tumm U"t & 4 him. WAKfA W4.4 (be
Ne Wd (OR* added, OW I . 4"1t was "Plogeo with ff"k (W. At OW tea the "m
t
l
60,3 altv was w an with a
iffm 140 ad frogliapaced. Vield. 4P6 C. crekwmitana. h.
v
, MY g, aftemAt4k7dopft(awer. twm FtAvAlm, met'll and
IIQW~T
1 1
f
300 m. eem trc*W as ANWO with 9) 1. me. Ffm 6 me the Ykid Mo W C, (of
004 (pu%v), SnIffit yickto men 4441mil with (Kke kettmes.
.
Vsa"b At. Parer.
I V
t L A SOVIOLLU914KA4 C416WIMAt /&
106
AB3. JOUP. RZXhim. ic. ?l 19-59, -'0. 748
A:
ORD, PUB.
of aitii 'v.103r ana, chrominm Jic)xide
uf t~iu
of m1r, ;t6, (fn~w I~he oxjd~itiorj Qf Til
!:Itli c!.rollillLl 6.10)fide Klves twtvyl-(3-kFtor;yclo-
perityl)-ketone, ~~C mp i)41, his-DNPli mp 2`9*
(from G5 H,, N). Th,~ raecKanisn by whIch the various
nes are form,id Jiir'- nr, thc; reac tion of Crl~ COC1
aith cyclooli-Vin.,i Lzu ' he presence of AiGl, is
di ,-, c t i s, F, P d
Za yn 10 v
t, I ~ - i r " , I. T I
V - - tz~. j - iA I-4U
RUMANIA Organic Chamistry~--Synthetic organic chemistry. G-2
Abe Jour :Rof Zhur - Khimiya, go, 14, 1959, Ito. 49514
Author :Nuenitescu C. D.; Recaoicu, I.; Zalman, M.
Inst :Rumanian Academy of Sciences
Title :The Condensation of oxalyl Chloride with Substituted
PY=Olos
Orig Pub :Comm Acad RPR, 8, No 7, 659-663 (1958)
Abstract :The gradual addition of a solution of 2,4-dimethyl-
pyrrole in a mixture of petroleum other and other
(1 : 1) to a imall excess Of (CO012)2 in the same
solvent (at temperature of from -?5 to -300 under an
atmosphere of N2) results in the formation of a
precipitate of 3,5,31,51-tetramthyl-pyri-yl-2-diketone,
,Yield 15.5%, mp 2450 (from aqueous a1c); the mother
Card 1/2
G-i6
RU14ANIA / Organic Chemistry-Synthetic organic chemistryl G-2
Abs Jour Ref Zhur - KhiMiYS,, NO 14, 1959, NO,' 49514
solution on remval of the solvent and hydrolysis of
the residue with hot 10 Na0H gives 2,4-dimethyl-
pyrroleglyoxylic -5 acid (yield 6%), mp 16r (docomp)
The reaction of (COC1)2 with 2,5-dimetbyl-3-carbethoxy-
pyrrole in ether (-100, fol1owed by refltming for 2 bra)
gives 2,5,21,51-tetramthyl.-4,4,-dicarbettloxYPYMI-3-
dikatone, yield 22%, mp 234 - 235' (from aqueous a1c),
and 2,5-dimothYl-3-carbothozvpyrrolecarbcxylic-4 acid,
yield 4%, MP 2340 (decomp; from aqueous ale); the
latter product is converted to 2,5-dimethYl-3-car-
bethoxypyrrole (mp 118 - 1190) by thermal decarboxyla-
tion. -- D. Vitkovskiy
Card 2/2
AUTHORS: Henitsesku, K. D., Iliye G.Dinulesku
----------------
TITLE: The Equilibrium Between the Iso and the
Hitrofluorene (Ravnovesiye mezhdu izo- i
formami 9-nitrofluorena)
PERIODICAL: Izve3tiya Akademii nauk SSSR. Otdeleniye
1958, Nr lo, pp 1226 - 1232 (USSR)
SOY/62-58-lo-11/25
gormal Form of
normallnoy
khimicheskikh nauk,
ABSTRACT: In their earlier papers I-Tenitgeseu and Isaceseu showed
(Ref 9) that iso-g-nitrofluorene has a considerable
stability. The normal form of this nitro derivative
could, howevert not be separated. rThe normal form of
9-nituro fluorene (Ref lo) proved to be an equimolecular
mixture of 1,2-dinitro-1,2-dibiphenyl ethane -and fluorenone
oxime. All attempts to convert the isoform into the
normal form resulted in a mixture of the two substances.
The authors of the present paper proceeded from iso-g-
nitro fluorene (synthesized by Vislitnenuo and Valld-myuller,
Ref 10) as initial oubutance. They carried out a number
of bromometric titrations of the iso-g-nitro fluorene
Card 1/3 solutions in ethanol, dioxane and benzene. In crystalline
The Equilibrium Between the Iso and the Normal Form SOV/62-58-lo-11/25
of Vitrofluorene
state the isoform is thermodynamically more stable
than the normal form. In solution an equilibrium was
attained in which the normal form is the more contained
the less polar the solvent is. The normal form of
9-nitro fluorone can not be ceparated as it is diz-
proportionated by the for!iation of 1,2-dinitro-1,2-
dibiphanyl ethane and fluorenone oxime. Thi3 reaction
takes place more slowly than the reaction of the
formation of the normal form from the iso form. There-
fore thore are at cert,_,in times considerable concentrations
of the normal form in the solvent which were found in
the chemical way. The Great stability of the isoform
of 9-nitro fluorene is given by the mesomerism between
the cyclopentadiene nuclous and the nitro group:
Card 2/3 owl, OH 0 0 H
The Equilibrium Between the Iso and the ;14yrmal Form soy/62-58-10-11/2=,
of Ifitrofluorene I
There are 2 tables and 16 referencoo.
ASSOCIATIOY: tdel-.:himichesI:ikh issledovaniy Akademii Rumynsizoy Narodnoy
31 --.:;PU61iki (Department of Chemical Investications AS
Roumanian People's Republic)
SUBMITTED: May 9, 1958
Card 3/3
Synthew of Sdae.
and lagW t
stirrini ~x durfn 2
; th MO ce.11 ,q.
-
f
ft= I
ll
11
dUd
h 600
t
U!I7_kCfffRAkI3UCnamzt Aamaala
) adde
Na0Ac
d
(SO ,
uxed I
, w
t
ze
w.
u.,
,
washed with C41-4, treated with C, addified with coucd~
-std
t -101 froin
d with stirring
t
t
cr
HCI
d th
t
,
.
g.
w
Ao- W cc, AW,01 the mixt;tteated rapidly with 100 0-
fIC10
119
efiuxed a min
t
ff
CIfico
R
0 . a
.
e
. an
e crys
j
. pp
y
Ht0H and 100 cc. HjO gave 88 g. J,5.C?(PkCH*0)CjHr!
1220 (atoll
NCII
V (5
d 2
6
H
co
ff
V)
)
.
3
U
' r
l
,
00
"4
RX
O the taidue
tim excess Ax
my
dUtd
t an
I.
-
.
, In.
g.
C,
l
I
(
ol
01n
of 2
ti di
d with
m
i
a
KOH and
Co
6
.
o re
t
t
cooled
0 to billing
i
ith 750 cc
H
h
ti .
ss
wm
n
.
ve
X.
l
4
g
d it U
l
fl
ith
2 5
C0
i
40
HA th
V
.
rr
.
s
ng w
%
11 ted VY t
about 86 S.) gZ4
'
I uxe
cc.
e 6o
n. re
n. w
n
4
,
f
ll-tk'C. powder, Wtued, dU4. with 400 cc. HA w
at 70
, the mixt,
120 g. NQ*A.T_ffj0 in 1.0 1. Hi(
1
It
d
d
fi
d acidtfied with cooed. HCIyWded 5.7g. 2,4-Hp, Aciro)-
ere
uct
. and the pro
and coole
Stirre1l 'A ba, at 70
- I
1980
oxime
m
m
d
a
d
4
U
l (1) Q114NHCHC0.H (VI), in. 221 (decorupn.) t0H with
H
I
0
-
.
n
g.
c
osy
,
,
;
',Off laided 4
y
r tnpn.1 (50 WOH). 2 4-di?IfIrPPknyIhydr4I0Xd :
-177 (dew
'NH
0
!a 75 S
~;i
OAc (4
d
Of 11,0). V
(15 g.) and 27 jr. NasC
s.lO
t0 In BOO cc. 1190
eated dropwist with shaking with 6.7 j, A40. shakm I
In
~
i
i
HC
C
d
i
ld
d
.
g.
eemapn-
d
; 202
1p
(
50 ce-
i
NCCHtC&h
tre
rVo
th 15
hou wamed e
ed with conal.
I to
ongo re
e
ju
., and mc
dif
y
-
110* with
f VI
eviom
115
6
&
i
N
A
M)
l
g.
a
'
,
f
Y C. And. 16 it. 1. refitzed 5 -hrs. with the amtropic reo
'
to rerowie the
stento di5td
f:tb
the aftt
11
0
l -
o
.
r
.
c
, m.
r. (
g.
pr
&WV4. VII (11 c.) treated In the untal manner with 25'
d 4
b
t
l
"i
A
i
.
mva
.
o
a
.
,
ind cam residue allowed to stand ovtr~
the 3 .
-t
e
de
emy
cc. 4c# and if g, MO
c y
g. j,
M. 110' (Utol (6 Mjded to
'14 ..", td, from JIM pye 10.5 g. I-acayt-J-
. "112' (CCI
C
U (2rJ
d
11 9.0 9. Na65%. 7H&O In 180 cc. H*O and 180 cc. WH at -
-
=
ru
e
I)-
). M-
a
Awro
11 marlud (
jIj9Q
d 00 cc. 30% sq. Moll nOuxed 6-7 hrs. and add
wed stand o
x tem fluxed I hr and a to
7au
night 3"S
R
ju . !~xdolyk4ok "id (hetarmuzin) (111), M,
Ila V .Of (
OH). NjaHtWiti (4.6 g.), 13.8 cc. rylene, anti t
,
n fl I ff.1 ~2td. into 1.0 r UAJIL IT .,Idmi M 22A ff- Mott and 1.2 ff. NHA)Ac and
941304 8 9,NAUR tu luucc- HN gnu Ow uu- `6u"~
b". wlj~ 7Q cc. PhCHXIF treated drogwke with
- ---------------
~j
I
L
F t
10 Pienated over
Pd-C, and ~er
ptd. 0.13 ed. and the filtrate dild. with dry. jit,0
ac[d oxalalf Of $0400s
108-
. M.
tdecompa.)
aox
MOH-Et,0).
X (191) in W cc- MtAC0 treated Ith
40 cc. 2% ail, N40H and 10 cc. 30% li& kept 24 h:3, at
C-C- room tc-P.~ ftAuxed 6 Olin., tvupd. in mzuol. jjPd the
r"Mue cooled deposited a
bg
64
I
.
C.
eftly kdofyL
acelamide. m. 148%
F. W
VIrImano
II tlml
A/,C 1L/ T 2L c~7-- c v
Distri: 4E3d
-Mi-ih'idttn'of,lbolLf'6,iiinsfir in the 9clical reao- - g4fae a -IV, y"etlow p atft,W.17340 (MeOR)' . '2-47,411ij
i- I - abon (jtdL,` 013t bra.
1011. --D)stir- U. Nellitzescil and Alcmder 1317h at-19W,
J%un 7. C
4. Chem.Bm9I,2I(YS4(V andt-
-(10581;-Slight jlcating of I-CIGH1013 -ws IV fro, afie, but CAY resinous pr(41-'
-t (1) with aphyd 1, in the sq. PIL
1;~l In all ca
I I ucts front the PhNO, soln. 11 (14 g.) in cold dry
-ISCLM 1) in,1?11110~ yields (4-Ei0c,011A (91) and 11"
i, ~JYGUASP*11V).: . IV was also obtained from. PhNHOH, treat=d drrpwisc-with-10 g. PhMfOll in RtO dri"itcCL
%ad U in nonpolar sulvents. indicatinf, that PhNlf(31( is the PANHW11, needles, decomp. about 70*; a sampic licutetv
1"Im reduction prtiduct from PhNOt in the reaction of 1~`in a test tuGe oil the 1110 bath underwent vlc4eut dtcouspa.,
~
ith 7in Ph NOi, ~ The it) dride transfer trum the dihydro-; unit formed tarzy products. U (20 Jr. I tit 11'. Call. licated tf;
aromatic lateratedlate formed lit the Scholl reaction to thi boiling, trcared drupwitc with 7 g. PhNlIOf r in :Yll cc.
PhN01 (actinj as acerptor) is cuWyzcd by 11, The cata- t1g, heat&t 10 njin., and coriled detAmitcd to g. II,-,dt of lv,~
ilytic effect of I oil the hydride traritfer waa demonstrated nt.'2054'., 0kh with alkah gave IV, n1.- 101*; pier-atc, iliq
~on t1m modk-L1 system 9,U)-dihydroatithraccrie (V) which with" 173*~ A aludlar full with the reversc adrim of tljv rcael;,n(.~
*11 in Phl,10, yielded antitracene atal IV; no hydride tran4i.--* gave (lie PhNHi II balt Laid front th(- Foln, PMN(0jI1l,j
Ifer occurred In the absence of It. The mechanism of them V (5 g.) and 11 g. U fit 60 cc. dry PhNO, heated 4 at,
;SchnIIrcuctinn1JdisctL"ed. 1 (6 g.) in 52g. PhNO, and 9.8, 100* and cooled deposited 3 g. anthracene (1.1 g.2ndcrupj
11 keated 14 hrs. at 75% cooled, and filtered gave 1.2 g.*, 'obtained by strain dis;tn.)-, the aq, distn~ r"iduc tre-ate&!
111,"m. 113*, the filtrate steam-distd., and the resinous trs-: with KaOff gave 1.3 it. IV, tit. 10t*1 , A similar run prvi-,
Idue(about 3 g.~crystd. from C.1-IrEtOR yielded an adtial.:; ceeded, In th,! same innnuer during I ulonth at'21P. V in 11h.,
1 .0 g. III; the -4q. steam d6im. r6littac. basified with Nq~, -NiDii heated for is limiter perind of titnc.a 100' without 11-,
Off Fave 0.9, g. IV, ncedlon, m. 101*; N-Ac deriv. of IV ~ 1rave only unchanged V; a similar run at 260' daring V~
tit. Ull-(ati. EtOft or CsHrpetr ether); ffl-PhSO, derivi lira. g-Aveandiracene and smallamts. of PhNIfj and 11~0., V,%
of IV, ril. 128* (C&Hrli or -aq. HtOfl)- c,mplingl 'in Call, refluxed with It gave only unreactet! V.
product with - 2rCoff
L Ciff needles-m, .157'
Lz&
IV i IV-is
13
Ms
All
B
Ilk I
I ga
--. a -,-. 3. 0. - .
Zvi i. ..a U
V2, I?
93 *J
Sh
Hip
ts in 'a t
.1" Sk2 A -h.
9.-- 1 3.
io;a . j~H~ftza.
17
In " a .6. _ I
D
C
h
=
o9
to
t
t
inM G
D i
..-
t
'dI"6qcIobtxann was ta-vestilgated follow Ds
f
!it
-Work (C.A.'37.37401) on ff+mfgration In FrWd-
CMfts typt Mctioi-s- llresent~work concerned behavior of
d1btbinocyclohexanes in the Presence of anhyd. AlBr.- At 0"
mane komerized to: yield 70-87% bomerfe product coutZ.
Approx, 250/. cryst. Aranx-t.4-Ctff,4Brt and 757g liquid,
mostly 1.3~wflrt (proWbly transy, dissolvinIr Wtly the
'44-isomer. _QrMi&C Of initial 1,2-Liomer was. detected.
-
Th
C saine final equil. clunipa, was obtarserl witit Irans-I t-
W14BI-t. I'a-ClIfilgrt (Probably tws), and (rams-1:'t.
Br, - as initiat isoracm.
The reaction conformed- to
:* bocatic formation. under inaujwce of the clectrophilic
st;lfaoUawedb
~-=
H*mi
work with it
iati
n
Siw
i~
.
x
o
~
y
y
g
PoUr weditim. HHr' Kavc differeqt: rcstdts, fcf. Goesigg find
krus). dot
D'.
IVEN ITZCSC U
1
:4
(W 0, fi"W at M-fCt* t fir- 7cma the M trayed,
Koff
(VU wdensed In a trap, and Mw 4
HCfCCH:Cff
1
4 co
.
~
#
oriania). ~Frr C11 was adwrbed in & Cull) sda. V11 WU Idead6ed br
St
Cal T
15"i(Ig5g) 1mbromovirylacrtylene. A. mixt.'
converting It Inta - te
'
d., C.A. 53, INW; preceding abstr. (10.7 0 of M and IV &xsolved la 10 cc. CSt Ym mixed with
Both, d.-- (1) an&bwss.1.2-cyclobutAnedicarboxylic acid 13 z. AlBrt dEisolved [a 80 cc.'C$L at 0", satA. with dry
(11) were C01iVtrW.Int0, a Mixt. of cis- (111) and Irmu-1.2- HBr, iWitated 2 ho. it 00 and 6 hT5. at 16% The solvent
dibromacyclobutune (IV) by. the Hunsdiecker reaction
k
ii was decanted, evapd.. and the residue distd. 6% wv4.
,
2
2m9
I(A
d
b
P
l
(wh
h
u. therefore, not ftereospecific-). I (36_g.), m.
60
129"
15G-200
1
o
it
h
d
id
0
(VI i -
.
, n
u
,
.
t
Tribromobutane: (VM) ( 0 .~,
) heated at 110' with S'
ed
bt
M Z
L
RM
i
was
.
r
s an
r
e
n
cc.
4
,
y
to 86 z. AgN(h In, 170D cc. 140. The Ac salt of T a
.
, was o
n
.
C,
S. KOH gave VIL 1.2-Dibromocyrlobutant-1,2-dku-'
,&~Wpptd. The salt was dissolved in 1100,cc. dry
00
dd
D
~r
l
d t
B
d
d
(97
)
yLic: acid QX) (30 4 r.) was dissolved in 200 cc. H.G. neu-
box
-
of A
s
d d
t
l
ti
d
i
h NH
li T
d I
an
coo
e
o
.
- a
e
.
r
~-
e to, 65')
the sofa
r
fili
d
3 a
AUS0 o
n.
n
o a
tra
ze
w
t
. an
roppe
. to p
t
ItofEC(47-W
Ef
Th
NO
l
800
A
(X5
0)
)
.
c
e
.
.
q. L
.
the soln
washed (If
discoloration om
inxed
O) cc.
fE
.
e
C.
g.
g=
j
t
8
) zmve 3
e HunWiectre
eaction of this (18
Th
td
.
.
j
.
dried (]=), the solvent evapd. In, a colunw, and the .
c.
.
r
pp
ir. 1,14,%-tetrabromocyclobutane W, m. 126' (MeOH'
"'
resW11 ~e ix Muo to give M mixt. A
AlUrt (126 X.) dinolved In 100 ce. CSz was added to 19
21A Ir.) of 14% 111 and 79% IV. II. w. ME-1.51. w" W. X at G' and agitated at 10-20* 10 hrs. A mixt- of ho-
Vrepd. from the di-Et ester of 1. bw 139% by converting It mers (CIY.Br,) was obtained, bt 114-10. 1 (T.2 V.) dls-'
.With MOM to thedi-Et ester of U, bs IM% and then ball- solved in 5G = CX% was mixed with 7.0 c. dry pyridine
Inc wM dAr,UCL 12 hrs. T-he AX salt of 11 was converted
I-E
Into a mist
oma
of 267
1H
b
nd 66% IV and 22.2 g. Pb(OAch, and stirred at "* I fir. Cycfa-
[
-
.
a
as a
ove.
r
a a
butene (XI) evolved was introduced Into a soln. of Dr
cyclobutene was 6=1ved in 130 cc, Isopentane and dry CHClr, from which 1.6 C. 1.2-dibromocyclobutane was ob-
HBr was Introduced at 01 under ultraviolet Illumination talned, bw 95-1001. & da* coatC. Ito, cc. dry CC14.
&4 bra. Fractionation gave 10 j. 111, 07% purity, b,& 17 g, bromosuccinimilde, and 0.6 g. benzoyl peroxide was
I - 14.5 to -m- R.2% dz 2.0103, nV, 1.54981. IV, filled with carefully dried X1 and agitated at 7G40 6 Us.
97 tY. b". 03-4-. m. -3.5 to -4.0% da LQW51, nV *The = sok. was decanted from the polyintr (oll) sepd.,
I was prepd, In CHC1j by brominatiam of eyefo- and the solvent evapd. By fractionating the residue, 1,2-i
butane. k mixt. (21A C.) of III and IV. 21A X. AlBr,, and dibromoeydobutane (2.8-3.5 V.), ba 80-6% was obtained.
OM6 ft. %0 was stkred In 160 cc. M at 0-15* 10 firs.
The M soi
w
d
which
nted f
m th
i
d
N VL The decoTpoddon. of quteruary Wta of 0-dfamlao-
:
n.
n
eca
ro
e re
res
ie
n
.,
washed
evapd
and the residue fractionated in WCU0 cyclobutane. Margareta Avmm and C. D. Nenluescu.
,
m
.
.,
. 16". 169~74.
-Theattempted Roffmann degradation of IA-
Thus, 1543,T. mIxt. was obtained contg. 19% Iff, 47A%
IV
and 33.5% 1
Mbromocyclobutane (VI) (detd. by jas bis(dimethylamino)eyelobutane dimethabromide (1) Im the
ilk
l
f
h
U
,
,
,
chromatography). This inixt. (IG.T g.11 and 20, C. powd.. -,
) was found ta be anoma
ous, g
presence o
P
U (
Ing phenyleyclubutene (MI. 1 (13 C.). tn. above 266%t
6=
Distr:
'Additim emieW
OmAcycloSeft
-:Wm. -=wd. I
into 4W Co. liso"
ffid a ~hnl Potired
Of IV (12.5 jr-1
discet"r deriv. (VJ not
(sted I hr. Vw
dimethyt acetylanodkub an ad with,
r. P, Gh Whaf 'dV Nq -V.R*
P
U
W
B
Y
-+ ,
described to far,, was obtained, m. 15"" (recrystd- from
V (2 was heated t
StOll white needles, m. 157*).
~149)
(4
tS
s
t. R~~
9te.
fxej. Sxdsi I
~ ,
o
4~
WO-900
1
Subtfinatfoa in skscw at 180-W - gave O
1
W C
~er"Idr~ chilff. 7, 23M
IGau= I.- -
.
.
.
dfiLcetozynaphthalene, zu.- l2f~-T* (MeOff), and'iL.don-1
qMene (I
Phenyicyckdetate K.)
was heated with 6 C. dl-
1)
olatile polymer, which wax converted into benzole acid as
Me acetyknedkerboqUte t.U) at 180* 49 brs., under a above. It waa concluded th&tL the structures of III and IV
atm. Fractioustim T W
O an R4d=UUCt (M were as Indicated. - The Ph substitutnt In both ILL and IV.
:11awWt firup; and s' . black reesidu
C,=,
uz ke
t 2801
V1 (5
t u
) v
d
t
h
a M
i
G was either at the 2- or at the 8-position. The thernat I
'
w
n
er
a
et
Ir.
mosp
a
as
.
p
(60 m.) was evolved,.the residue was fiactimated ix-, decoinpti. of M and IV followed thi Alder-Rickert wherne.
mcue. Di-Me phthalate (145 j.), bt~ tIO-12*, and a H
nonvolatile polynter of phenylcyclobutadlene were oh.
tained. The latter was converted Into,benzoic acid by
OxIdit. with XKnOg. I (9.5't-) and bcnzorlujunne (9 g.)
was bofted in W cc. Ctff* under &a Inert atm; 24 brs.
From the solid residue obtained. by removing Cjrg in cam, CwMe
III It tr.XV. m. E74-76", wisextri.with EtORandrectystd. m.
guy (IV).
j
(MOHI.. IY(tLir.1ws%WledI=IOGcc.AcjOa*d
T. "
-V-
'Distr.- 4E?-C(J)/4E3b/4E3d
of YclobuUdlene. C D. N
Prepirstlost c
A~ram. Elba Marco, hLarte h1w
r center Bucharest,
-cc
nan C rep
po
.
~
L 0
cunt. T I- mj.
ik tit am review M
I . : .
;' 9
1
Of tl~ on it) was p
-
1- 1-;
wi of cyclobutadieft or
cycloba d&erdivs. d ion of ~ the
diquaternarT base of LA4kminocyclobutane, thermaF
decoxnpa. o( cycloddatetraem adducts, and allemptA to.
utadlene from brominved. derivs. of cyclo.,
=
=
m ptiformed. CmMutadlene was detected In!
e
AgNOl and Hg complexes, as wed as (for a short period)
,
in the gaseous state. TransfarmatiotE of the ug-cyclb-
ne was accomplish
utadkne were prepd.:
lftft
E
ng
~.
Md
b[. Lapidek
..Distr4 4E2c(3)/40d
and its ImpWtIw4 In the metma= 01 We =OR AVA
.-I.Gaftermana-Kock reactions. Atexandru T. Balsban.und.
meniue= (Org-cNem- 1a5._Xsjytech.
mam), Aead.rcP.PQPUareKmfm..)tmdj$:
Ch(ML 7, OIA(IM) -t,4-Dibydrv,-Imnaphth*,._
_jOtid HV
(prq~d. Irani 1-naphthoic uld and 1% No,-
Its derivs the chlocide (the Wd vVith exce" =2
.2mMv (U~sotu
gas), the wwwe
oftim-chlorlde and NR&
.
fthe-Chlo" ind. mullue'la abs, ether), and the vitrile'
'
ot the
"Miad iLhd: PCI#). were. vmpd.. Tmtment
'
_
with AICIrin C& -sid Its deempi.-Into HCI;
IV
CO and vaphthain e, with fohnflaq of 2,2.- tia thyl,
tter vu fonned. In larger amm (t%Vtfiw wit-li hiAer
the stw;.
~tuole. Vrtt
= It naphthatme w" pre"t from
-
'If tile w" replaced byaafwle or, to P~
g
readlow 0&=rc(L with- thest solviias ti) yield a~
craft$
mixt. of #-- wA p-anW 1,4-dilrydro-l-na Vone
-
4wdih
dro-l =Dath
tol
t 1
f
t
d
0
~
~ w
a
p-
x
4 w
.
y
y
'-f This confirmed the proposed for the;
'
ha,l of the
i Scholl reactku and W a bearing on the wee
0 Koch reaction. (32 rettiences) (SummaHes in
Rnsff= and Eng[~h). M, 40_401--~
IOAN9 V.; TEODORESKU, L. [Toodoresoug L.3; TSITSMA, Sh. [Titsica, 6.1,
acad..; MENITSESKU.-K.D* [Ninitesoug C.Delp acad.
Mechanism of the reaction of alkylation of the ar=atic ring. III.
Catalytic action of bentenesulfonic acid in the reactidn of
benzyl chloride with benzene. IV. Alkylation with various benzyl
halides. Rev chimie 4 no.2:171-187 959. (FEAT 9:7)
1. TSentr Dinicheskikh issladavanty Akademii RNRq Otdel Organiche-
skoy khimli, Bukharest. 2. Redacteur en chef, Comite de redaction,
Revue de GhUnie (for Menitescu)
(%nzene) (Alkylation) (Armatic compounds)
(Ring compounds) (Catalysts) (Benzonesulfinic acid)
(Benzyl group) (Halides) (Chlorotoluene)
AVW9 Kargarsta; KWCAp Eliza; JF~~~,gos tin D.[Menitesou, CtD.J,
acad.
Research in the series of cyclobutane. V. On the bromoderivatives
of cyclobutane. VI. Research in the obtainment of quaternary salts
derived'fron cyclobutanediamine, Rev chinle 4 no.2:253-270 '59*
MAI 9,*7)
1. Aus den Chenischen Forschungslaboratorium der Akademie der RVR.
Bukarest. 2. Redecteur en chef, Comite do redaction, Revue de
Chinie; Nitglied der Akadenie der Rumanischen ValksrepubM (for
Nenitesou.)
(Ring compounds) (Cyclobutane) (Bromine)
(Quaternary compounds) (Salts) (Cyclobutanediamine)
HEMITESCUj,..,P. .-,#q,.D.# acad.; AVRAM, Kargareta; MARICA, Elira; MUM, Maria;
Tests for obtakting the cyclobutadiene. Studii, cerc chin 7 no.4:
481-5o4 59. (EUI 9:7)
1. Comitetul. de redactie, Redactor responsabil, Studii A cercetaft
de chijde (for Menitescu). 2. Centrul. de cercetaft ebimice al
Academiel R.P.R., Sectia de chimie organica, Bucuresti.
(Mercury) (Cyclabutadiene) (Alkyl groups)
(Aryl groups) (Silver nitrate I/ (Complex compwnds)
NENITESCU, Costin D.; GIATZ9 Alice.
A new regrouping of phenylalkanes: regrouping in the diphenylbutane
series. Studit cerc chim 7 no.4:505-519 959. (EEAI 9:7)
1. Centrul de, cercetari chimice al Academiei R.P.R., Sectia de
chimie organica, Bucuresti.
(Phenyl group) (Paraffins) (Diphenylbutane)
(Aluminum chloride)
B4ABAN, Alexandru, T.; MMITESCU, Costin D., acad.
On the decarboi7lation of the 1.4-dihydro-i-naphthalenecarbwlic
acid, and Its effects on the mechanism of the Sscholl and Gattermann-
Koch reactions. Studil cerc chin 7 no.4:521-529 159. (EW 9:7)
1. Institutul politehnic, Bacuresti, Laboratorul de chimie organica.
(Dihydronapbthoic acid) (Carboxyl group) .. . -
(Aluminum chloride)
C ow"111 Y t Rumania
I Organic Chemistry-Organic synthesis.
!AM, J'XII. I RZKMM*p 1?0* 5 1960v 7 74 3
AVVICR I Nenite6c,;, C. D. and Badea, F.
q c a. a-ety 0
nces
U L 3. Scit,
On Lht, Catalytic Dehydrogenation of CyclooctaLetra
ene
C, ,PUEk, S Colnun, Aclad RPR, 9, No 3, 245-248 (1959)
j,1,,a-T,RAr,T I Exporiments with the dehydrogenation of cyclo-
octatetraene by papsing it through heated Pd/C
gave unidentified gaseouz products and ettylbenzeni
in tns place of the expected dimflrs of benzocyclo-
butadien-~-.
V. Skorodumo,,
CWITI I/I
Ai E N i TZ U..
Mfx~WWAW.14. As
AM 340
AAM& KO 444W C% diL P"OJMC&
elf. C.A. $2, (0.52 r.) powdacd and OddW
W]k
4wins" 0 from 1,2p8
mixt. fikered, vre", d Sot 0.1
cd an unIft
4 Vp Br and 7.154% WMCR
Kch pv* StML on, coats. 42
uteluptad dift. in saw. ThebrANWO of
7~"tv .. t "if 2
turt
Of at the wbkb exIsW for AM PftiOdA of ON 10 tW ts
XMI1 j~aX61' , " ~ ~ W. -
ma strat-a by treating Is-lb Wuh a
purr 4'r,
00=4 in, 111-F Z U, dam And gweeping With vir throullft Avearke oW Mr.
(Cloq~ give* w wbkb famed 101; with AqN(h sols.
, Y Y
96 INOP
o4
4~'
N (1b)
Vx)
-4-
1wbe with
~tmted drot
apt._Glte=M*fOMW'I w4vibe'd"IN IM -
4, ~ the dark ant PA,
stou., an "0, aW drW 24 hft.'
pvt Ot s-,* sOli (MR mt M (40 0 And; 5W cc; CC34 -
the
jW19d.
hovilbei bath--WMIS Mtn
disq
7..'wpshtd- &Wik-C~O -'W e L
oWvd ~W' dry-BUD kea A firs. 0*0 NOW6 and 'raw"
1. W 115-20-3a 4060W" OW). 1 (J-.'87;
0
W.) and d12 CAN !~Hj ~uaea 115-20tVat rooin I
with, 35 cc.* abs- the EtSO r thyer decanted, t
the combined exts. washed. dried.
'JIMIge washed With Etta.
-under. N pye j pale yellow on with an ucrid,
and eiapd; decomp-'aho4t, Go*. The, RtIO Wa.
6=-
aALABA , A.T.; HMAITSISKU, X.D.
Ultraviolet absorption spectrun of Tyrylium chlorate. Izv.
AN SSSR.Otd. khIm. ru- no.11:2064-2065 M 160. (MIRA 13:11)
1. Politekhnicheakiy institut I Institut atomnoy fiziki, Bukl=est.
(Pyrylium compo mda-Spectra)
CDORMIMIrcu, ,Catnt-.na-~ BUCUR, Aurora; BANCIU,
M.; N'~NTMSCU C.D.
ion reP-ctiona. Ft. 1. Studii ce-rc chim 14 no.2:127-134
1. Institute c~-' nrganic Chemistry, Rumanian Acaderq, Bucharest.
~ubmltted Ncvsmt6r 17, 1964.
cf.-Ptcmdinj--aWtr.-ne Mowing mecb-
'sill -Imtuutwg dichlorocarbene as Intermediate, wo
Ithm of (c4cco)so In the,
suamted to mwantforthe for=
c 0 .1 ;ccl' + cot + A"
of c c g
rp ylb
M, A - "cc= + Cl
+ lg7c-cM4+4C'-' tIa-* .0 + Aga. Ou auly*'
lVc= the f=uS= of equimda wnts, ol CO& and
i.~Utattdbm~-Qk* me at 70* ykkkd-the wflsydridc~
CHIORLUSKU# E .katerina [Cioranescu, Ecaterinal; BUKURP Avrora [Bucur, Aurora];
WSIX9 yAtiya [Maxim, Maria]; NRVffAI%Ai!ff [Nenitascus C.D.1vacad.
knew method of separating thiourea from ammonium thiocyanate. Rev
chimie 3.no*2:223-226 1160. (EnI 10:4)
1. TSentr khimicheskikh Issledovaniy Akademil RNR# Otdel organichaskoy
khWig Bukharest. 2. Akademiya nauk RNRI, chlen Akademii nauk RNR,
Comite de.redaction, Revue de chimie, membre de 11Acudemie de la
Republique Populaire Roumaineg redactaur de chef (for Henitescu)
..(Thiourea) (Ammonium thiocyanate)
CIORANMUI, Ecaterina; BUCUR, Aurora; MAXIM9 Maria; NENITE,509 C,D-# acad.
9peft"Wr
A now method in separating thiourea from ammonium thicyanide. Studil,
care chim 8 no.ls67-71 160. (ENAI 9:8)
1. Centrul do cercetari. chimice al Academiel. R.P.R., Sectia chimle
organica, Bucuresti. 2. Ccmdtatul do redactie# Studii si cercetarl
do chimis (for Claranesou). 3. Redactor responsabil, Studii, sivwwe~--- -
carcetari, do chimie (for Menitescu).
(Thiourea) (Ammonium thiocyanate)
(Carbon tetrachloride)
BALAM, Aleksaadru To.,- GEMj Aaisiyu [Ganeas A*]; NEWSWU9 Kostim., Do
(Nenitzescal C.D.]
Pr,BpdMtIOU Of pyUll= oalts by bia-acylatioa of o2ef1m. Repart 5s
Bis-acylation of di- ad triisobutylene. lav.AN SMOtd khimonank
no,6:1202-1207 Ja 161- RERL 14:6)
1. politekhaichaskiy institut., BukMmat-
(Propene) (Acylation)
IMSOIU, 1144ma; NMTZzgcul a. m. fireniteseti, ax. I
Chrmic: acid oxidation. VAchanim or oxidation of 1#2-diphm7lothans
and 1#2-diphonypropane, Her chimie 6 no.2:245-257 161.
I.,ChOadcal Institater of the Acg&qW of tho I.P.R., Budmvatp
Organic Chemictrw geetkm. 2. VAmbre du Ccdtg do i4daction. at
r4dacteur"on chef, *Revue Ad'' himis,'fiembre -de likeadeds' do
la. Republique Paupulairei Raumaine (for Nenitzescu)
wmmyu, Ilreffia (yealrolu" Ileana]; NMTMXU, K.D# Werdtagaut C.D.]
Rearrangment of phwqlindans under the action of slusiv=
chlorido. ftv chimle 6 no.2:259-2(A 161.
1. Nauchna-lasledoyatollskir institut khImli Akadeall. nauk MR,
Bukharest, otdol organicheskoy khlis'l. 2. Nembre di Comiti di
r&Uetion at ridacteur an chef, "Revue do chbdem (for Kesites=)