SCIENTIFIC ABSTRACT NEFEDOV, YE. I. - NEFEDOVA, M. N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136410016-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: June 21, 2000
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Categol-j: USSR / Fhysic&l CherniaLry :rystaI3
Ab3 Jour: Refera-. Zhur-Khi:niya, No L)57,
b 10. c 2h M; b e La I ' ha.3 a rhombic lattl e w4 ',h a
b wh'ch ii ir. Cuod agreement with j-,onio-
MeLric measurement daLa. Crn cal r in-ing up to 1000 C aptical proper-
Lies Emi stricture cf anlsrtropi , I indergo nc -har-.ge5; lm meLam" -t~'
varianto thi.3 brings; al;-iL a r(-L;LOratf )r, r:f Lhe -)rIlgIrtal ~,,7stalllin,~
structure.
~.ard L)l -, -12-

KJ14KOV, A.I.; NFIFEDOV, Ye.I.
New diata on langite. Biul.VSFGEI no.1:157-161 158. (MIRA 14:5)
OAagite)

HVEDOV, Te.1.1 KAZITSYN, Tu.V.
All-Union conference on mineralogical methods used In prospecting
for rare metal deposits. Zap. Vees. min. ob-va M no.5:632-.634
159. (KIRA 13:2)
(Metal, Rare and minor) (mineralogy)

K~ -- "'PU; b. 7. NE..~
on a
1. ins, 1
t..b khii AN

NF , Ye. 11. (.-',osk-va) ; '-I. G. (Mosk-va,
Axisymmetr.lc lie! ica. "j )w tfirough a cramne! .rith a w1ver. profl-e.
' 7 Me
I v. All SSSft. ' yri. ' muiBrunostr. ro.3:1-3-1'76 '64.
.7:7;

L 2096,o-66 zw(i) AILA W
ACCESSIO NR APS013341 Ult/0109/65/010/1)05/0879/0889
N
621.372.822
AUTHOR: Nefedoyj XSUIA,
TITLE: Dielectric 'rism in the bend of a M wide wayeguidt-
p A
SOURCE: Radiotekhdika i elaktrortika, v. 10, no. 5, 1965, 879-889
TOPIC TAGS: flat waveguide, waveguide bend, dielectric prism, bending prism
iABSTRACT: A dielectric prism inserted in an easy bend of a wide waveguide
compennates the spurious modes caused by one of the waveguide natural modes,
1when the prism size considerably exceeds the wavelength (at millimeter waves).
The problem of failing a natural mode an the prism is solved 16y the method of
longitudinal sections, and the solution to obtained in the form of a small-
parameter-(4 power series, where (*ivt (1)Fa) 1; "1" and "a" are the half -
width of the prism base and the waveguide width, respectively. The method
permIts estimating the variation of amplitude of the mode that passed the prism
'Card_

L 209('0.
~.ACCESSION NR: APS013341
i -1)
laven in the zeroth order of pt - however, the method is inapplicable for higher
incident modes. "The author wishes to thank B. Z. Katsenelembaurn for his
constant interest and great help in the work, and also G. D. 14alyuzhinets, B. V.
ostroy, and V. V. Malin for their attention and useful discuissions. " Orig. art.
tae: 4 figures and 45 formulas.
1ASSOCIATION: Institut radiatekhniki I elektrozLiki AN SSSR Lmstitute of
pjLinqeAnjE and Electroake. AN WISR)
i SUBMITTED: ISApr64 EXCL: 00 SUB CODE: EG
NO PtEr sov.- 0 is OTHERt 001

311IRINO P.K. (Moskva); POVXWINyy, L.D. (Moskya); KAJCUW. 14.0. (Koskvn);
BARCH. I.Z:,.in h. (Kharlkov)-, MSHKAIMTo T.T. (Novocibirsk);
RAIABAN. A Mrlicov); DZHIOYHT. I.M. 00mrlkav); RUBIRSH7311.
M.Z. (Khnr$kov); RYABCHIGA, W.F. (Parnitogorsk); SOU)VAROV. K.N..
(r^mn'): KHODOROVSKAYA. 0.F. Uharlkov): I Tq "N Laniverad).
JL
Discussion on plans and regulations for the organization and the
technology of building. Strol. prom. 35 no.12:5-20 D '57.
(Architeatwv- Designs and plans) (mm 1111)
(Construction industry)

rI f f V 1) (' V, 'Y'- YC
ZLLIKINWON, Te.l.; NMDOV, To.Te.:, BZRZZINSKIY. A.R.. professor. loirtor
tskhnILqW0ftkh nauk, redaktor-, CFMBYSH!CV, Te.A. tekhnic~eskty
redaktor
CIPI&t steel gates for hydraulic constructions] Floskie ctallnye
zatwory gldrotekhnicheekikh -sooruzhenit. Pod red. A.R.Rftrezinskoeo.
Kooky&, Goo. izd-vo lit-r7 po strottel'stru I arkhitekture, 1951.
44 p. 6o i. (MLRA 9:2)
(Gates. Hydraulic)

N179DOT, Tejo, Inshener.
Construction of double-walled. twin sluice gates. Rdr.stroi. 22 no.7:
10-41 TI '53. (ia-RA ): 7 )
(iluice gates )

ZALMINDSONO Ysvgenly 1111oh; I IIXIT- XWOMMI-F TA's-26"SON14h, GUROVIGH,
I.Th., red.; V020UMAU, L.T., takha. red.1 ZABUDIRL, A.A..
tekba, red,
[fteel Taintor gates for hydraulic englasering oonstrwtioul
SegmatWe stallas, j!atvory gIdrot*k%nichsskiW sooruhanil.
Hoakws. Goo. anerg. lad-wo. 1958. Ift, _ (Atlas of
deal&@] Atlas konstrAteli. 1958. 39 d II am. (NIIIA Ilt9)
(Sluice CateTs

KHITRIK, S.L; VLASENKO, V.1A.; GASIK, M.I.; lEml A.P.; NEFEDOV, Yu.A.
Refintmg 75-per cent ferrostUcon from &Iuminu.-.. Izv.rym.ucheb.
S",; chern,mt, 5 n0-4:45-53 162. (MIRA 15:5)
Is Dnepropetrovskiy metallurgicheakiy institut,
(Yerrooiliom-Metallurgy) (Alilmimm)

BEIL AIKOV, Yu.7.; IEFED07, Yu.A.
I -- -
Using Ilikcqo! I, 2d and 3d-p-rade, 'ell. - - - . , - - -
facture -)f silicomp-riganese. Naucr_ *.r'.A-~:/ ',!": 1. . . I , -,
I V~ ~ -j. , '" : '. -1 )

P V F.IP(t) lip(
L 2n7A:x66 F.PF(n).2/EIXP( )LEWT(m)/EP."(m)-6/T/EWA(d)IE-NP(w)/ENP 0
ACC NIh APGW3747 EN/JD/.,V KKMCZ CODE: UaIO126/65/000/010/0027/OOU
AUMOR: Nekbeedsi, Tu. A. (Doctor of tacbmical sciences); Sbpindler. S. S. (gaginser)l
20
TrfLKi On the tboory of the alloying and composition of heat-resistant stools for~~
highly stressed cast turbine blades
SOURCE: Litey"y proinvodstvo, no* 10, 1965, 27-31
TIOIPIC UGS: bigh alley steelg turbine blade, metal casting, cooling, susteafte,
ferrite, high tomperature strength
ANSTUM AustouLtic steals of the Fe-Cr-Ni system containing various amounts of Cr
and Ni, so$* 20/100 13/15, 20/20, 15/35, etc., addittonally treated with No, W, Nb,
Ti. Al, and otber alloy elements wbich dissolve in the sustenite and form hardening
pbesee (carbides, carbonitrides, Intermtell idea), 0: widely used in industry for
the temperatures 600-750"C. to this counection, sod ace the cooliag rate of coatings
of Cr-UL stool. greatly affects their phase a tucturo, particularly the formation
of ferrite. the autbor describes new structural diagrams specially demloped for h
alloy stools of the re-cr-Mi eye function of the cooling rates of thLe-MIC
csstbqs of the goo-turbime-blade=9 usually produced by the lost-wex process th
pearl" isto earawLe solds beated to GOO*C. In additiont formula atitatively go-
UK: 669.14.016."-14

L 20785-66
ACC MR, APGOO5747 7
lating the chemical composition of the steel to tba poseLbl* amount of ferrite in %
are presented as substitutes for structural diagram of this kind; by we&no of the"
formulas the phase composition of Cc-NL steel can lie determined as a functi '105 4tba--i
cooling rate of this-weLled castings in ceramic moldso The alloy elements :Zt V 'Nb -1-1
create In the V-solid solution a nonuniform and distorted electTVP distcibaiioi~ igis
"neiderably enhancing its bigb-temperature strength. A high Hiliontent is not al-
ways necessary to attain high values of stress-rupture strongitVand creep strng 1<
In steel. Given a specific content of Cc, Ni and C in a steel, a specific amount of
ferrite-fonLog alemouts Is required to obtain the limiting saturation of the y-solid
solution wder specific pro&Action conditions so as to waxisize, in relatim to a
given 0 ml rature, the bigb-t4sperature strength of the ftoducts cast from this steel.
These said otber principle* of the alloying tbeary expounded bar
~beea
ally coafinted and so" to develop ~ boat-resistmat foundry s=lls b-1 and FU-2.1
for the castift of turbine blades end rotors with higher stress-ripture straegig-9 _wn
stable wetwitle stuctun end grestu ecommy (lawr content of 81 end no). OrIS.
art* bast I f1wresp 3 tables.
= ~1 11. 130 w/ ~ shut same/ am Awl 014/ On awl 005

I I
BUSTGIN, V.Te.; NZINDOV, Tu.G.
......
A method for determining the rate of spreading of the pulse wave in
man and to tinimals. Blul.ekep.biol. t ued. 43 no.1 supplauent:48-50
157. (MlU 10: 3 )
1. Predstavlana do7stvitellnym chlence AMN SSSR A. I.Nestarov7m.
(IPUI.Iol. Physiol.
d.ateru. of pulse vave spreadAng in animals & in man, method)

USSB / Human and Animal Physiology. Blood Circulation. T-4
Abe Jew t Per Zhur - Al'ologlys, So 1, 17,9, 110- 3347
Author xeredov,,yu. G.
InAt Not given
Title On an Experimental lethod or NiterminIng Circulating
ilood Volume
'iy
Orig Pub t Ayul. okmparim. biol., I med., 1957,ANo 1, prilorhenie,
50-52
Mastract 1 ml of an Indicator that contained 30 - 4011 Curie Zn65
vas injected into the ear vein of a rabbit. Tvo minutes
later, 0.5 - 1 ml of blood vas taken from the vein OF
the other ear, a awar made or. a glass slide of 4 cm
in surface, arA its activity determined by means of a
counter. The circulating 'blocd volume vas calculated
from the formula A
a
Card 1/2

BURNA7YAN, A. 1. ; YAKTSMKO. I.D.; MAYMV0 -U.R. "'. ~
3anltkLr.f nnd hygieLic mensures on the atomic icebreaker Lenin.
.V~;~C.=4-4 no.4*70-72 Ap 159.. (MaRA 12:7)
(SHIPS,
rndiation T)rotection on ntomic icebreaker Lenin (Ibis))
(RADIATION PROTWHON.
on nt am ic icebreaker Lenin (Rus ))

LL:6F, I 11;SKlY , A. V. ; ',Flo IN3EY , ,,.V. ; NFFELX)V , Yu C,.
I ~njquv exper t - f ~ f " 5r ~ '!rt ~ 3 t3 . AV , A r,3= '. , . ~ , :
,~ 1.-31 N '(,4. r ~-, , -.-A . " : , ~

~z
Q
OP
".A
TO
7z9/d2d5q5f*/OOi/CiOt0
sk' M P rtt;bov
6
PT -,01MM-lit A. ff. lAbedev, 13, 1.
_i.; ensk aj~',Wk:~ B LkOVA A,
r
., i~of_
adiktion bY fiot4e
-protons on do
1~ MAI f ~;Alaft
obi
Olost
I.J
)TO-VA M
du
ec
rot t
g
7i
F~ra OnIL-.
7 -biol~gicaj effectiveness-
thit6r126d- b~- the tLuthols t e
%-, CM )n_1
tMeed than 'ow~small animals. To
'd!be mord.pr6no
'do '-divided ato tv group
0
_a (6 dogs
Wdaithor
go
_t Aition ofL i vAiation -
!;WZIL 'Re5oll na-1.0-dorl 11S.- TT tha. first group.~-was irradiate(i 10
-A d"ot',40" with, a t*ta.1,60e o:t-- 6W Z~ ~.,.Jrce 6econd group was
doys'
. ..... 15 "d ~b "t 'doo 'of radio,
-a to %I 1- 690 f. -The
Re vd~ o oVs i~~
I-- _~~r; on -se
112'.Ith6 cond group,. frM
-the:
were- lionductid eiri Joint Uatituttf,of Nuclear Be-
`.teI;U di~ CAI is-, OP _Ayncb~ocyd -0 rM ged sd~ that -a, 510-Hav~
I t me iuiit:VM arronj
~hi 4A. e-detion - or~'C in Adameter ab;l it
I: radA ad.-- it -found th
was that to

~7
BMW
=mum

teJ 'A!

at 6h. it par
onk-I'Seilerally,had the u%w effects'4' However, dope irradiated with
ilhoifeir-doide. ',to: this, radiation; -the hewrrhagic syndrome'.
1~00unced,-:Amdl -when death t6olt place, there waa a relatively higher
bout. tilt -:b1, I them Pe~~Pheiral- blool and gentirsIly lower bone-marrow blood
;n A;W'forz~!ot a somewhat _gmater depth'!of dulage to cells', of the erythro-
on of-the-structurei *~__f th- ral nerrous system
iaunittati c- e cent
ie
and_fluid.~
and'Slial structures ani disxWtion6f 'AoodL
5 A tcbl
J
A
ENCIA 00'_
Di~~`:1919_' a-CODE: EB
ALI,
3201
f.4

PHASE I BOOK EXPLOITAT10K SOV/5294
Akademiya nauk SSSR. Institut biologicheakoy fiziki
Iseledommniye rannikh reaktsiy organizes. na redistalannoye vozdaystvire (study or
Early Reactions or the Organim to Radiation Effects) koscow, Tzd-wo AN SUR,
1960. 220 ps Ermte slip Inserted. 5,000 copies printed.
Sponsoring Agency: Akadealys nallir SSSR. Institut b1ologicheskoy riziki.
Reap. Ed.: G.M. Y'rankp Cor spondlng Member, Academy or Sciences USSR; Ed. of
Publinhing House: B.V. Garian; Tech. Edo.*.V. Volkova and Ye.V. KakLuti.
PURPOSE: This book is intended for radiobiologists.
COVERAGE: This in a collection of nine articles by different authors an the effects
of radiation on life processes. The following an discussed: the relationship
betveen reflector mechanisms and d1sturbances in hemo0yusaics; the &irked diainu-
tion or total absence of hemodynamic reactions under soft irradiatioti upon pre-
limJLneu,y treatment of the skin with novocaln; reflector-induced changes in the
central. nervous system and the almost instantaneous advent of fine physico-
chemical reactions following irradiation; changes in the stability of the
Card 1/3

Study of Early Reactions (coat.) SOV/5294
erythrocyte level during the first several ha4re after irradiation# blood albumin
changes aP*.or irivAlation, occurring earlier than believed heretofore by scien-
tists;and nev and important data on tissue breathing and disturbances in the
physicochenAcal properties of erythrocytes. N.N. Livehits, Doctor of Biological
Sciences, Is mentioned. Each article is accompanied by references.
TABIZ OF COWTEM,
Preface (A. losbedinskiyl
Frank, G.M. Introduction. Radiation as a Disruptor of Regulative
3
Controls of Life Processes 5
Nefedov, Yu.G. Disturbances in Blood Dynamics in Acute Radiation Injuries 14
Polivoda, A.I. Changes in the Elasticity and Hysteresis of Elastic-Type
Arteries Due to a Total X-Ray Exposure IJ2
Card 2/3

Study of Early Reactions ~Caat.) SOV/5294
Veyze, L.G., and G.M. Fraak. Changes in Blood Dynamics and Changes In the
Mechanical Properties of Blood Vessels in Total and Local Irradiation 60
Gemburtsev, A.G. Changes In the Physicochemical Properties of
Erytnrocytea Under the Effict of Radiation 35
Blokhina, V.D. Alb=in Fractions in the Blood Plasma of Animals Exposed
to Different Doses of X-Rays 93
Vysochinap I.V. Effect of X-Ray Irradiation on tne Gas B&lance of the
Blood 113
Sneznko, A.D. On Changes In the Oxygen Content of Brain Tissues Under
the Effect of Radiation 125
Aladzhalovs, N.A. Characteristics of Physicochemical Changes in the
Central Nervous System for Different Periods of Exposure to Radiation 167
AVAIIABLE: Library of Congress
Card 3/3
JA/rn/gmp
7-29-61

'10(~q
3/177
D234X305
AUTHOR,S% Bogatkov, P.I., Canlidate of Chemical Scier.-t-9,
Nefedov, Yu.G., CErdidalle of Medica: a-ni
Poletayev, M.I.
TITLE Expired air as a source of carbon mun(.xAie am 1 1" a-
tion of air n hermetica.4 sealed roumF-,
PERIOLICAL: Voyenno-meditsinski~ zhirrai, no. 2, '~6', 7-
TEXT% Carbon monoxide in the expired air of a healthy man :s formed
endogenously. Shostrand ~-Abstractor's notet lio reference giver-7
measured 0.0021 - O.OG24 % and noted a marked rise ir. disease-9
eing an oxygen deficit, after hard physical work and the ins~ira-
t i on o f 6 - 7 It C02 0) r -x--t-#--n d e f i c i e n t a-'r . Kon-A,. re L'A- 1 s tra
nc.tet No reference given4l,
/ added asphyxias and severa.
ical processes. The level of carboxyhae:,,oglobin may r-eact.
4 ~ as a result of endogen-)us formation. The mechanism cf f-rmal'.-r.
is not yet established, In vitrD, experiments with animal t-':-J
sh--w that rarbon monixaJe is f(.rmed at 380, the :!cn'ent
Card 1/4

21889
S/17 6 1 1~r
Expired air as a sour-e of ... D234405
by 83 % in 20 h(;urs. Dur:ng haem3lysi8 the carbon mc,nLxide
5 , . It increases in the ccn%'ersv 3r~
doubles (Shostrjrd I qg7'j )
Ictin t-,) -.holehaemuglobin binder thc Infiaer.ce of R'A
1952). knalok-&,A9 res,-i',',9 -here Ltalned in in-vitrc, -h-.rk '~r, ",r,.e
~
combined -xidati(in of myriglobin ar,:j ascorbir acid. Myoglobin is
converted to bile pigments, giving ~-ff carbon monoxide. Endogeno-~.q
CO Is excreted by the reversible dissociation of COHb: CO + H1,
COHb. While studying the air composition in a hermeticai~','
sealed room a gradual rise of rarbon monoxide concentratior. 'Aas n
tel. There were no technical sources to cause ttis, yet by t,.e ~-,nl
of the experiment the concentration was close tc tre ind-,~stra',,Y
f,crml tted limit. Therefore, the ossibllity of the rise , ~i-
sed ty Ine p1lilmunary ELrA, ~ trt~aj s ,sk in reqpi rati , r. c ft -e
In 'r,P -~(M was Investi6ated. Three s,.~tle -1,9 werf, .,. Et I
doing norma' r.-,!3: al ani mer."a, h~-:-k. Tf.i~ e
r
in the !'irst experiment -AiaB :--a i n *. a . r. e d a t
at 11,, relative vapGr density 41- - ~O A a a A
e carbon J1 I le J1
--j replenish oxygen &nd remov Ll X A
Cari 214

Ex~ired air as a source of D234X305'
the air composition in the '_,hamber to be maintained as %
oxygen, 0.2 - 0.8 carbon dioxide. Possible experimenta: SC-!T.'F9
carbon monoxide formation e.g., burning organic materiai, BMCk:nC
etc., were excluded as was formation by the replenishing a~~arat,s.
Air analysis for CO was made twice per 24 hours usinF ai~parat,,s,
type LKB 3267A1. The specificity of the method was checked on cne-
mical components of the chamber air - carbon dioxide, a17.r.0r.1h, mt-
thylamines and aldehydes, and fourid to be reliable. Air analy.913:
the subject made two fu'. expirations
through a gas pipette, volu
me 250 m3; two successive trials were chosen; air fr~,m the :ipe~'P
passed through the indicator tube and the carbon monoxide cur~tent
was determined by comparing the color intensity of the react,,re a..-
stance with the standard scale. Data for smokers and non-sm,_kers
are given in tabulated form. The expired air of non-smokers -c,:-,-
tains on average 0.016 mg/I uf carbon monoxide of' Bmukerfi 1'."J
1. The results for non-smokers are approximately 20 % below
Shostrand's due to the different methods cf carbon mcn~~x:ie leter-
mination. Carbon monoxide c~,rcentration went or. rsnp- Pis as
Card 3/4

21889
3/17
Expired air as a source cf D234YD305
the experiment continued reaching 0.023 - C-02- after n,..,.E, ti,
!en days. Temperature had no effect on the rate 3f increase _r n
to ev 1 4-
,~cn entratlon. It is not yet possible fukly a.-.iat. the s:gr.,-
fi :ance of this carbon moncx`A#- f(,rmation from a san:' tar- ar. 1
g1A anic p,,)int of vieA,'but nuch high concentratiuna ~f arb~'r. !.. r.
Xide may be reckoned Jtsadvantaee~,us especia:ly if Kav,~
be in such hermetically .9ealed chambers continuously ard fcr R
icng time. There are I tab:e and 11 fig,,ire.
SUBMITTEDt December ljll-q
X
4/14

BURNAZYAN, A.I., kand.med.nauk; GORODINSKIY, S.M., kand.med.nnu~: EOYSMENKU,
I.D.-. 'IFF"DOVI Yu.G., karxJ.mr-d.nauk; PRAVETSXIY, V.N.
Frovidinv radiati,)n rrotection on the, atomic icebreaker "L-ni-."
Sudostroenie 2? no.P:11-14 Av '(1. (FIRA 14:9)
O-nin (Atomi,-! Fhip)) (Radiation protpction)

LEBEDINSKIYF A.V.; NEFEDOV, Yu.G.
Problems of radiation protection In space flights. Probl.kosm.
biol. 211l-2-4 162. (?URA 16t4)
(SPACE FLIGHT SHIELDING (RADIATION))

JIMDOV, Yu.G., kand.medonau~; 3,'.VIIIA, V.P., inzh.
Steam ejection cooling machi-nes as sources of air .-,oEuticr, b-, carbon
monoxide. Sudostroenie 28 no.5:28-29 My 162. WIRA 15:')
(Shipe--Air conditions) (Air-Pollution)

LEBFDINSKIY, A.V., prrof.; NEFEDOV, Yu.G.
Space flights and ionizing radiation. Priroda 52 no.7tl9_24
-Tl '63. (MIRA 16t8)
(Radiation-Dosage)

LEBEDRISKIY, A. V. ; LEVIrOKlY, S. V. ; NEFEDOV, Yu. G -
"The general principles in reaction of the organism on trie ~,ompiex environmentai
factors acting in the --abirA of cosmic vehicles."
report submitted for 15th Intl Astronautica.1 Cong, Warsaw, 7-1;' Sep

NEFEDOVP Yu.G., red.j GOR'YICHEVA. N.A., red.
[Problems of the radiation safety of epace flights;
pkWaical and biological studies with high-*mrgy protons,
ProbleaW radist8ionnoi bezopasnosti komichesidkh pole-
tav; fizicheakio i blologicheekle lasledovWla a proto-
nami bollshikh energii. Mo8kyar Atomizdatp 1964. 237 p.
(MIM 17t12)

L 2027-65 EEC,-2/PSF(h)/FSS-2/EWG(r.)/EWTIJ>/FS(v)-x/EEC(k.)-2/E'tiG(I:')/EWA(d)/
VU a,/EW,3 (012WG(J) Pb-4/Po-4/Pe-5/Pq-4/Pac-4/Pae-2/Pi-4. BSD/k;D(ft)-5/WdL/
iPETRIAM(0, T DD/GW
k
nD/ T/
Mi. A0401*9501 S/0209/64/000/011/0024/CO31
1 AUTHOR: Ub' d t ~ A v LA
ki _-V "Le inikii, S~ V. LNefedo4,4u. 0.
T ITLE-OT.:. -n anticipation of new space f I ights'l. a unique experiment of Stiv I et
scientists
-Y iyia~-, 1166smiop6vt1ka, now, 4r,
24 31
I P'tolco'ged I solaitlon:,-'cosmonaut traininq, I, lzing radtatitri, tempera-
on
t6ra~, nolse le4el,: carbon dioxtde concentrai-Jon,adaptation
ABST,MC'Tt -T'h is art,tcle deals with the problem. of' studding Ehe reactroit of the
humaa'~or
ganism to a- prolonged stay1n an hermetically-seated chamber. :,Results
wit I make possible;,the setting up of further experiments using differe~)t environ-
ments. :Theso,experiments, which Varled.from 10 to 120 24-hour perlodsi In length,
studied the effects of this Isolation on the vital functions of 10.human beingso
Other conditions, Including small.dose.s of.1onizing radiatton'and periodic rn-
creases In temperature and noise-lievel, weirO simulated.. Not only did'the varying
environments -'#'nf luence' the human subjects, ~,but. the human organIsm. was1ound to in-
fluence the environment.. A ~onstderable tocrease In the number of bacteria I(% the
arr of.the chamber'and on the skin of the iiubjects was noted. There was also a
C:jakea t2crease In carbonyl hemoglobin in. 'the blood, and C02, In the atr of the

synwtoms or auto-intoxication. During the Initial 10 or 15 24-hour periods, major
adjustments to tho new environment were made. Systole decreased and reaction time
delay'Jncreased, light sensitivity was lo~sered and the error factor went up.,
Nevertheless, adjustment was eventually irwide, light sensitivity returned, and the
number of errors:decreased. Fatigue remalned constont and heart action was found
to be'Wa sub-noival level. The artlcle'alsG deals with Irritability, nervous-
ness, ands other non.physical reactions; : *rho, Inf luence of the indiv[dual on the
environment 4-stressed, wl'th such Inf tiences differing from individual to In-
dividii4l qrtg*'art. has: 4 graphs.
ASS6CIATIOW~' .,nolle,
I --sum'WEVO ;00 ENCL: .00
SUB CODE, PH
NO AMS.01,: -000'
OTHER: '000.
~'Wd 117.

L 45965-66 VIT (I SC;TB-___ DL)/RD/AljGl)/JXT (Q11) --- - --
ACC NRs AT6030695 SOURCE CODE: uR/oooc/66/ooo/000/0035/0051
AU7HOR: NggedoX. 111. L ~ Ar~i s Lxrb2~f B. V. ; Veselova , A - A. ; KftlR~ S ~-I.
_V__ - _L~ ST a
Zhuravlev, V. .; Iseyev, L. R.; Xciumbarov, N N.; Kartsev, A. S.; :vanenko. 0. T.;
Levinshiy, S. V.
ORG: none Aw
"he aeroion composition of the a'r o'. nermetic cnamberG and its nflaence on
the hunian organism
SCUPCE: Konferentsiy~i po Ko5mirheskoy biol()jii medi tsine. mliterla,y.
VOG C ow, nst. mediKo-O 16 -1 . _p r 0-1, -4e IT. I? IT r 71 - 1
1 C T A aero i on i z a t i on , t,umi,n pny s (,i;r_y fe s il,-,por 1. sy s t em, 3 liy irj
ABSTRACT: A number of prrvilour, itudie!; r,iv,, that whils, nf-r, ")n!, are f
minor consequence, chronic, exposure to them -tit. iefill to sut,~tnritlri, nar"v"s In t.,,e
`),nctional condition of th- orrrun~i-~m. f'lrfi,-r stu'ly trii! 'llctnr, '.v- -x-,,riments
of 20 days duration were rnndu,lod on mn;e v,_~'jritevrs fr,,m i ItionrFi?c -Y Irif t
ed). 'he first exp~rim-nt wn.; for r7ozit,! , j ; ,r:)( ~eq t,,
a.r.d pnysio ngical lata. 7he di,r iity of tont r, li,lr, oxporins,rit,
50-1000 pairs or loni3/(-m3. 'llne second, tn~rl, and fourth xp(,rImf-.-iT:.
exposure to positive, negative, at,,(] bipoiar ioris wenerated ~)y "Sntoynbott" racilofictive
ionizerF. !on concentratinn in trie respiriil,,~ri
Card

L 4')(16-,--~~i
ACC NRI
MOO
e a,.-,, , o ris
"harve Pxcnange
rTI
logo t14
cut I
my
too
+
Fig. 1. Aerion composition during a 10-day erperiment
Card
to

L 45965-66
ACC NR- AT6030695
Unntrol
Control 11
Negntive
Pf,!) , I I Ve
H i po I nr
de-ionization
10
U)
wi
Ln %
f 2 J 6 7 9 9 /0 12 IJ 4 IS IS f 7 no ts 20 1 J /0 r,
Before Druring Aftpr
Fig. 2. Pulse dynamics during various experimental regimens
--Card 3/4

L 45965-66
ACC NRI AT603c)695
/so-
/so-
140-
130.
so
80
70-
i$ 41 is /j 5 )k1jj I J3.N013 s I Jf pis/ jJ1 J,513,5
ra Norma-1 Control Negative brislPositive- Ions ipolar lore D~ionization
Fig. 3. Pulse variations during bicycle ergometer tests
_qard 41 ~__

4'31765-66
ACC NRI AT6030695
170
AW
ISO
140,
12D[
IV,
100
3 .5 1 J~ I j S 13 S ;,"o f 3 53 f 3 -T 3 f
rr,zn Normal
ront.r,,! NP91-t".'r 1, rr, 'on:31 --zzj, i-n
Fig L. Changes In systoli- pressure during
exercise on a bicycle ergompter (merLn vnlups)
Card 5/8

L 45165-66
ACC NR~ AT6030695
I-IF
if- 0
R)
1/0
140
120
rj I
80
fol
40
+
characteristics
F:g. ~- Comparative
0'r rhaMeff-lTi -ttv"'.t. enpttr of nenrFa
processes in various experimental
regimens control)
a - Character of reactivity curves;
b - changes in the coefficient of
reactivity to light (whitie) and to
opening the eyes (stripea).

L 4t965-66
ACC NRI AT603o695
L
L
1- /30
0
C: 120
" * /to
0
/00
so
80

ontrol t 0
1 A

PN %
I
1
N
Z 2
%, 11 /,--A-
-

Bef3re After S M M
Before 1 S, A? j
Be fo re AOt er f III$ aj
Fie fore After' 0 f 3 J Pi 3 7 d
iBefore A ft e'r
Fig. 6. nanges in the sensitivity of central (E0)
and peripheral (LO components of the visual analyzer
(mean values): I - Eo; 2 - L3
Card 7/8-

L 45965-66
ACC NR, A-.603o695
during erperimentation. Allowing t?,at the natural exposure (Jose for the lungs is
1 1960), :,t was ralculated that I g of unp receives
12.87 mr(!m/week (Sivintsev, , 1
3.33-10" pairs of ions per day. I.', in the respiratory medium, there were 500
pairs of light ions/cm3 and 5000 pairs of heavy ions/cm', then 0.7-1010 light and
7-iOlo heavy pairs of ions would reach the lungs of a man during a day. In these
experimentE, the average subject received approximately 1011 pairs of light ions
per day. In the fifth experiment, the chamber was de-ionized using a system of
fiiters and special ion traps. However, complete de-ionization could not be
ac-'Ieve(i arid the density was ')0-60 pairs of ions/cml. Some results of these
experim,~nt, are shown in Figs. 1-6. Tht~ results of the experiment generally showed
_,rew;-,ri muscular working capacity, externad respiration, and an increased level
of gas exchange during exercise in the expermerA with ro-gative aerotonization.
'artia, normalization of some in(iices occurred during the respiration of negative
aeroioris. However, for a number of indices, a normalizing effect was also noted in
responi;e to the respiration of poiiitive and bipolar ions. Nonetheless, the general
trend of the majority of shifts noted during experimentation lends credence to the
;,roposition that prolonged exposure to positive ions or a de-ionized air leads to
some changes deleterious to hunitui health. It is possible thatane-Mrdw approach to:
this problem would be to combine negative ions with positive or bipolar ions. The
establishment of optimum aeroion regimens requires additional research. Orig. art.
,,as:
7 figures. [CD]'
SUB CODE: o6/ SUBM DATE: 14Apr66/ ORIG REF: 011/ ATD PRESS: 5o86
-Card - ___8_/8 hs

L 04625-67 EWT(m) cl)
ACC NKs AT6029632 SOURCE corE.- uR/oooo/66/000/000/0235/0241
AUTHOR: DarenskMa, N. G.; Derbenc YaA-N. I.; Nefedov& 1u, a ; 1~rzhoy. N. I.;
Serga, V. N.; Domh A, M. P. (P fessor) 1~ C I
ORG: none 6~41
TITLE: The RB; of hi -energy protons
SOURCE-. Voprosy obshchey radiobiclogii (Problems of general radiobiology). Moscow, i,
Atomizdat, 1966, 235-241
TOPIC TAGS: proton radiation biologic effect, dog, rat, mouse, relative biologic
efficiency
ABSTRACT: The RBE of 510-, 240-, and 1.26-Mev protons was studied in comparati
experiments with dogs. rats, and mice. A proton flux generated by the 01Y&I S~chro-
cyclot-ran at Dubna wan used. Polyethylene and lead absorbers were used to decrease
proton energies from 660 Mev, at the same time Increasing the beam (Liameter to enable
I rrad" ation of large animals. Me dose rate varied from 0.3-1.5 rad/sec. Rats and
mice were irradiated in a rotating chamber and dogs were irradiated from two sides
in orier to equalize the dose di3tribution. RBE values were determined during both
single and multiple irradiation: during multiple irradiation dogs were exposed
B-19 times in the course of 2-5 weeks for total doses of 200-6w rad, and rats were~
exposed 20 times in the course of 4 weeks for total doses of T50 and 1115 rad. SingW
Co,d--

L 04625-67
ACC N1. AT6OZ9632
proton doses amounted to 136-55C- rad for dogs and 100-1200 rad for rats and mice.
It was observed that irradiation of dogs with small doses of protons altered their
i-nological reactivity, as ind.Lcated by the depressed phagocytic activity of
neutrophils in the first days after irradiation. In proton- irradiated dogs a
decresoe in oxidative processes vas also noted#. CO liberation and oxygen consump-
2
tion dropped 35-50% shortly after irradiaticn and remained depressed until the ani
died or until most radiation sickness symptoms disappeared. Experimental results
showed the same periods of appearance of various symptoms of radiation sickness
(such as increased temperature, diax-rhea, changes In peripheral blood, etc.) for
proton- and gamma- irradiated dof;s (except that dogs irradiated once with 510-Mev
protcme developed symptoms somewhat earlier), RBE Yalues for protons in the energy
ranfif.- Indicated were based on comparison of percentage survival, duration of life of
survAying animals, aeverity of individual eymptoma and results of laboratory tests.
It was concluded that the RBE for dogs during multiple Irradiation with 510- and
126-Mev protons Is 1.0. For single irradiation, the HE is 1.15 for 510- and 240_mi!vl
protons. and I for 126-Mev protons. It should be noted that these RBE determinational
are made on the basis of direct radiation effects, and may have to be altered for lor+
tem radiation effects. Analoepus experiments were conducted with white rate weigh-
Ing 180-220 g and mice weighing 18-22 g. It was found that the RBE of 510- . and L
240-, and 126-14ev protons for rats van 0.75, 0.73 and 0.69. respectively, based on
the LD 0/30. The RBE based on the LD was 0 T5 for 510-Mk!v protons, and O-Tq
ror 248- and 126-Nev protons. For mlg/'Othe RBE* value for 126-Hey protons was set

L C4625-67
4C-C--RRI-AT6029632
at 0.7. The difference in RBE values obtained for small and large animals is
conniderable, and indicates the danger of extrapolating data from small animals. for
study of the spaceflight radia".Ion hazard to man. Orig. art. has: 2 figures and
2 tables. [is
SUB COEC: 06/SUBM DATE: 23Apr66/ ORIG REF- oo6/ omi REF: oo6/ ATD PRESS: SV(2_3
Cand

Acc mks M603606 SWKCS CQUEs Uit/0000166/000/000/0287/0287
AUTHORs Nefedqy_t_Yu. G.; Zalaguyev, S. N.; ShiLov, V. M.; Borshchanko, V. V.
OR.': none
MIX: Cgrqblem of d*$igQj%,a habitable smocrtfl cabin enviripmen I-Paper p
at the nrerence on too of Space Mad c no e d in Moscow from 14.27 May Ng6ey"',
SCURCE: Konferentslya po probLett-va kosmichaskoy meditainy, 1966. Problemy
kosmichaskoy meditziny. (P&vbLems of space medicine); materialy konferentsit,
~bsco% 1966, 267
TOPIC TAGSs autordaroflora, closed ecological system, life support system.
space cabin habitability, space hygiene, Inan nology
X13STRACTC
Pralonged spaceflights require that man remain in a closed enviroment
'with an aitered medium under the influence of a series of unfavorable space-
flight factors. In sealed-chamber experiments with human subjects,during:
-'Which certain spaceflight factors were simulated alonef with various work
and res
t schedules, in addition to physiological, psychological, and
clinical observations, special attention was given to the study of the rnicro-
flora of the medium, and tho automi.croilora and immunological reactivity
!of the human organism.
Card 1/3
L

--36656
A--%- VIA& 1-1
Ex-periments with humans in sealed chambers havi: indicated that as
experiments increase in duration,there is an increase in general bacterio-
logical contamination of the surrounding medium in the chamber and that the
,number of pathogenic microorganisms increases significantly.
Studies of the processes of interchange of microorganisms between
'humans are of particular inierest. Results of preliminary investigations
'based on phagocytic and serum studies have indicated an exchange of
rnicroorganisms between humans under these conditions.
Along with bacterial contamination of the environment, definite
shifts in the immunological reactivity of the organism were noted. nlese
shifts are characterized by disruption of the bactericidal function of
the skin surfaces, depression of the phagocytic activity of leukocytes, anda
t
duction in the lysozyme content of the saliva.
7%e observed changes call attention to the need for finding methods
of preventing the occu-rence of infectious and autoinfectious diseases,
!which can arise as a resuli of the depression of immunological reactivity
,of the oreanism. changes in environmer%tal microflora, and disruption of
CWd 2/3

I ACd- Nit.-AT6036658
the normal microbial biocenosis in cosmonauts.
The problem of biological compatibility of microflora in relation
to individual differences of space crew members deserves consideration.
rW. A. No. 22; AID Report 66-11�7
SuB c=g 06922 SUM DAj%j OOWy66
Card 3/3

ACC NRs AT60647)
SOURCE CODE: UK/0000/66/000/000/0020/0021
AUTiliOR: -Alolcr-nndryuk,_~j. P.; AnIsimov, B. V.; Xomarov, 14. N.;
1~tnLov, A. N.; Sarova, L. V.; Tikhonova, G. P.
ORG., none
TITU: Air Ionization as a spaceflight factor Cpapor pronented at the Conference
on Problems of 5paco t~idlclno hold in I!Dscaw from 24-27 May 1966]
SOU'CE: Konferentstya po, problemam kosmichoskoy mcditsiny, 1966. Problemy
kosnicheskoy meditsiny. (Problems of space medicine); materialy konferentsii,
1-bscow, 1966, 20-21
TOPIC TAGS: neroionization, closed ecological system, life support ayntem,
human physiology, aerolon biologic effect, cosmic radiation biologic effect
A3S TRACT:
The physica'l and*cnemical properties of space cabin atmo!~p_~-Cres may
be changed by cosmic radiation, which produces ions and dissociated mole-
cules with high (10 to 15 ev) potential energies. The latter have considera-
ble chemical activity. A study was therefore made of the ionization of space
cabin air. Radiation equivalent in intensity to average galactic radiation
~(O. 3 ber) produces an atmospheric ion concentration of 1-05 mollcm3, which
.-s easi)y _reproduced under laboratory conditions.

ACC NRj AT6036473
~ - Data from tne literature and our own experiments show that air
-ionization is an active factor causing definite changes in the stalke of the
organism, particularly during stress or injury. Twenty-day experiments
have shown that an appropriate air-ion regime can reduce the adverse ef-
fects on man of prolonged sojourns in sealed cabins. Single exposures of
animals to ionized air caused changes in the resistance of peripheral blood
erythrocytes to osmotic hemolysis and in the vital stain sorption properties.
shifts in the metabolinm of a number of physiologically active substances,
changes in the ion permeability of the skin, and increased mitotic activity
in the tissues. All these data confirm that even brief exposure to air ions
in doses approaching those possible in a space cabin I(I to 5 105 ion/CM3)
has a definite effect on the organism.
Because air ionization is an unavoidable spaceflight factor having defi-
nite biological effects ', its mechanisms of action must be studied further
and wava Mund to realize energy recombination of ions (n the livin organism.
5W. A. No* 22; ATD Ra __' 66-116
Part .7
SUB CODE& 06 / SUB G=s 00maY66

L 38519-66 EWT(jm)/Ewp(w)___1JP(c )EM/WW
ACC NR, AR602oo62 SOURCE CODE: UR/0l24/66/ooo/ool/A014/A014
AUTHOR: Nefedov, Yu. M.
TITLE: Determination of forced v~'bratlons of nonlinear stal.-ilization
systems
SOURCE: Ref zh. Mekhanika, Abs. 1A93
REP SOURCE: Tr. Leningr. in-t aviats. pr1borostr., vYP. 44, 1964,
43-52
TOPIC TAGS: -(forced vibration, frequency characteristic, approx,:-.ation
_btitilizatlon *V*bL%n
nlethods'~~
A
ABSTRACT: The article deals with the application of the melhoj or I's
approximation for determining forced vibrations of nonl-lrear s~-E;1,C-:-.s
based an logarithmic frequency characteristics for the st~udy of multl-
circuit nonlinear 8tabillzatlon aystems. Bibliography oC 5 titles.
(Translation of abstract] (KI-]
SUB CODE: 20/ SUBM DATE: none/
Card I /I _&~_ I

L 31#411-66 E74T(l) SCTB DD/GD
ACC NR: AT6009451 SOURCE CODE: UR/0000/65/000/000/0297/0301
AUTHOR: Malakhov. A. N. Maksimov, A. S.; Nefedov, Yu. Ya.
ORG: None
TITLE: Electromagnetic hypothesis on "o
SOURCE: AN SSSR. Nauchpyy sovet Do kompleksnoy probleme Klbernetlka. Blonika
(Bionles). -Mo-scow-, Iz8-v_0
TOPIC TAGS: communication, electromagnetic radiation, spectrum, very low frequency,
bionics, animal physiology
ABSTRACT: The authors measured the spectrum of the biopotentials of certain biological
objects. The spectrum Included the frequency band from 1 to 500 cps. The electromag-
netic radiation from biological objects was also measured at frequencies of 3 to 150 kc.
These measurements were conducted In order to verify the other results (e. g., W. K.
Volkers, W. Candib. 1960. Detection and analysis of high frequency signals from muscu-
lar tissues with ultra-lcrw noise amplifiers. -IRE Enternational Convention Record, part
9.). The apparatus and conditions for these measurements are discussed. The results
show that the biological activity spectrum of animals is compact and falls with frequency
Card 1/2

L 34411-66
ACC NR: AT6009451
increase. The compactness of the spectrum indicates a stochastic noisy character of the
blopotentials. The dimensions of the spectrum at high frequencies indicate that the energy
of biological activity occurs at subsonic frequencies. R is shown that electromagnetic
radiation of bloobjects does exist. The final results show that electromagnetic emission by
biological objects cannot serve the function of Information carrier in biological communica-
tion. This conclusion Is based on the fact that the electromagnetic emission to too weak up
to 160 kc. Orig. a . hast 4 figures.
i~rl
SUB CODE: 06109 SUBM DATE. 260ct65 / ORIG REF: 002 / OTH REF: 001
Card 2/2 60~ - - - __

lc-'_59.57C~ .5
LeCESSION Me 15737,
,APSO
tb -bydrobi6i'
W a its and its weak absorpti*n by the ground determine the
fYdrotroplc type Of-distribi,ition of radiosodium by the basic components in the watet,;
at tha end (if the experiments an average of about 00% of the radioisotope ivmained i
X0 solution4hile the other 20% was*redistributed betweenthe ground and the hydro-1-
the plants ihe highest degree of ffa~7--uptake was noted in the frog'-'!
~Lontn. - Ami~ng ' - - g .
1AV. (Cic~ivity up to_17X10 decaylmin; coefficient of accumulation up tD 1138); the
I'I~west degnse in hornwort (,activity 1.5x.106 decay/min; coefficient of accumulation I
119out: Si-. 5) 0~ Theimolluses eKhibited InsipifIcant species-differences in this re-
spect. The.-bodieO of -tie motluscs Invariably contained much.moz-- radiosodium -than
d;ld the shells. The distrib4:ion of Na?2 In bodies of water is very similar to that
-0t* its,qhemica2 analog-ceeiiiie. - T'he'latter too is generally characterized by low
val-uss of the coeffi-ciaots o1r,accumulation by aquatic organisms. "The authors
thank their coworkers 11. V. 41tid Ye. A*. Timofeyev-Resovskiy at the Institute of
B blog3r LWAN ISSSR ftrprovidizAg working*9pace.end for valuable corznntso 1. H. Ver-
khOskays of the, Institute of! Biophysics AN SSSR for reviewing the manuscript and
advicev and laboriatory assistant 1,. Is; Kononova, for help wM the experiments."
Olit art, hasl~%-_~ figus"
0.1~table&
Cai

A~21$7
AP50157137
ASSO
lbatlt4t bfologizhisk6Y ff gdki
IJ
'Foscov anst
Itute of Oiophy-
.919 M* blol6gif: -flUala AN 85 k
1) OM
SRi SY tYvkar (Institute of
SR)
00
OTM* 00
0
i -r
le
Ty p!L_
67j,'

I . .11 1 . I I I .t I III . .~ . , . . .. I .. . . I I . , . .
. . . . . . . : t - . I - . -
I " I

LADYMIOXAYA, F.M.; ~
New developments in rosearcri. 3tall 25 no.S:R71 Z 11~51, N,:-~- 1e:9,

SOV/7e-3-8-2,14e
AUTHORS: AdamovIch, L. P., Nefedova, E. I., Vetrova, 1. M.
TITLE: On the Problem of the Isomolarity of Solutions According to
the Ostromyslenskiy-Zhob Method (K voprosu ob izomolyarnoAti
rastvorov, izpollzuyemykh v metode Ostromyslen8kogo-Zhoba)
PERIODICAL: Zhurnal neorganicheakoy khimii, 1958, Vol. 3, Nr a, pp. 178',-
1790 (USSR)
ABSTRACT: It is shown that in working with non-equimolar solutiDns the
position of the maximum in general does not only depend on the
initial concentration but also on the parameter characteristic
of the equilibrium investigated. A theoretical consideration
of the method according to Ostromyslerskiy-Zhob was dealt with.
By means of practical examples of complexes with a composition
of I : 1, 1 : 2 and 1 : 3 it was found that the displacement
obtained for the maximum satisfactory agreed with the one cal-
culated. In using non-equimolar solutions also a displacement
of the maximum to the middle of the diagram may uz-ir. The
Ostromyslenskiy-Zhob method with non-equimolar solutions may
also be employed in investiFations of complexes of higher co-
Card 112 ordination numbers.

SO V/78 -3 - 8-12/48
On the Problem of the Isomo lari ty of Soluti ons According to the Oetromys. ens -
kiy-Zhob Method
There are 4 figures, 2 tables, and 1 1 rpferences, ' of which
axe Soviet.
ASSOCIATION: Khar'kovskiy gosuduratvennyy unlverfiitet A. H. Crjr'k(jgf)
(Kharlkov State University A. M. Gor'kiy)
SUBMITTED: JulY 8, 1957
Card 2/2

FRAU 1 -9009 1XPLOrTATIC1% SM/40%
I1%t~rna1tI0n&l SYMPOGIvue oti Sacroftoleoular cj%ouixtr7. Hosa".
1960.
JbsbManaro4np alapazium, v k=kll SSU.
Walton. 14-18 lTunya 19 go g. . dokl.dy I -tor.f9roty.
B"tolya LIZ. (International 3yttposl~ on PU,crvaol lar
Chimletry gold in Moscow. Jun 14-13. 1960; pipe.-
jumbarleak Soo tic"i 111. (Moscow. IZ4-0 AN SUR, 1;001
469 1p. 5 000 cap as printed.
ftaft. &d.. P. 3. Laaft1na.
2poo&oring Agancyi The International UnIon of P~re and "1104
Chemistry. Commission an nacrooolvaular Chemistry.
IURP=t IWO bo" is Int,rnd#d for chenlazo Interested In poly-
Norization rea4tims and the s"tresis of high moloc.12r
scopou"',
COVIRAGSI This 10 Section III Of a VUltlT0lu=% wort ccxnt4ln-
Lag papers on sacrosclocul&r chomigtr7. 'Me rtlz..s in
$Moral deal with the k~-t*Llos or polymerisgtion %*tIms,
Lbe a"tnesis of opocisi-purv... poijuers. 0.9.. ton *A-
GILARS9 rNSIAS. owalsonductor materials, *-a.. not-hods of tot-
AITILIna Pal-vIftortzatlon reactions. PrOperti" and cht,11.41
Interectloas of ILIAP Solocular "Zorlals. ond the effe-to of
varlo" factors en polymerization and tne dtc~-adstlon of
high inolocular aoopo~ds. No parsonillties axv sectioned.
Seferences siven follow the artlcles.
labok. ?. I., &ad L_f=j~LeL(Pol*nd). =ml.ri-tion of'
Phaneol-YOZILAWwAydo Resins Z?
d A -- C%.~,-l (Ruma-1. 1.
CM!'-ft AICCM0, 34
Gord,-. ~ . 1. - It
4-4; and d-R
ZILO ~V,
I gone. n20
SUKF of the efts"44 rvions of P.4,-rj-ot.3 44
D_ A., X, 3~ Fel'daht.
,n, cJ 7SZx
in teractlov, of =* &zt.on
_SfD=bIq 3YBt*M& Of rUlC4njZAtlOn Acol4ratort
1 1 _Alurrj~.
2 WE :: I - - -
A 6-t*ro of-T.Ifuric Acid and P.-y,iny!
Alcohol Tj
jf,1kAb,r_ and 0 (ffung~r7;. The inter-
"Itloo of Aromatic no$ Chl.rid. 79
_v Kut-
0T,:hl ... 0
WUU14ZL-, hL4 d
a rod 'a _n
SMI..~;duT*nQ~r rPodudt1,0,n,wO Po4me ric torl- C. LLilb d5
ILS&G-J.-A. . and L. l- XnyLX_i RungAry ). Ch*a1ca. Proportlea
0t 21polar lon-Axc"nae Resins 93
won
~~~ I., and j. Rorawiet (Poian,ii. arr*ct or t:%* struc-
to" of Organic Am1_n_a-Z_cm;wu~a on --no Prcr;ortl.% of &n.-on
LIChAnge Roston Pras Polystyreno 10.1
( =A). The Of t- Eff- ~f t-
3tructuro or lonites on Jon-Li=.~ngo' Procoo-a Batoq~
lowiltes and Lle4trolyto 3o;utions 107
jLjjt, _d
mn,,O~ r4n.d. ?O-rv-'pwr"t1,*anof Son* P3.y..r.
P. Loo-. 4 3 1,-.-,j
------ Yr 3. S.
An ", ;~ ~- .rUSLN .
C.P.1y.-I of Styr-
AAAAC&~~m (Poland). Thermal Stability of St,,,, PL-1.
AftlOn ~nA;7,&s Reaj~s I" to

TROSTYANSKAYAp Ye.B.1 LOSEVO I.P.j NIYED(YVA, G.Z.
Synthesis of insoluble polymer complexes. Zhur. VKHO 5 no.1:108
160. (KRA 14:4)
1, Moskovskiy 1-himiko-tekhnologioheakiy institut imeni D.I.
Mandeleyeva.
(Complex oompounds) (Polymers)

TROSTYANSKATA, Ye.B.; NEFEDOVA, G.Z.
Cation exchar are of higher selectivity it the processes of
Lon exchange 1polymer complexons). Zhur.anal.khim. 17 no.4:
411-415 JI 162. ()GRA 1518)
1. D.I.Mandeleev Moscow Chemico-Technological Institute.
(Complexons) (Ion exchange)

S/190/63/005/001/UC7/020
BIOI/B186
AUIHOhS. Trostyan8kaya, Ye. B., Neledova. G. Z.
1111TI.-I. Synthesis of insoluble polymer complexones
et;h1OD1C,%L: VY80KOMOiekulyarnyye soyedineniya, v. 5, no. 1, 1965, 0-56
TEXT: Styrene divint. benzene (zDj copolymer containing 5~6 aiviny!
benzene was used as initial substance to synthesize insoluble comp,-exones
for ion exchange cnromatograpny, wnicn together with cations form
chelates. (A) Styrene aiviny, benzene was swollen in dicnioro ethane,
chloromethylated witn HCI and paraform in the presence of ZnCl 20 then
aminated in chloroform containing nexamethylene tetramine, and acetyiated
witr, enloroacetic, bromoacetic, and iodoacetic acids or with ethyl
chloracetate. The r(~auiting products nad a very low acid number and no
complex-forming capacity. Tney probably contained more aminoacetic than
iminodiacatic radicals. (B) Cnlorometnylated SD was aminated witli
dietnanol amino, the degree of amination of chloromethyi groups reaching
80~. The hydroxyi groups were then oxidized Into Oarboxyl groups.
Experiments with Kkno 40 chromate mixture, and HNO3showed that thb optimum
Card 1/5

W
S/190/63/005/U01/007/C,;1U'
Synthesis of insoluble polymer ... B101/B186
oxidant was 56~; HNO5aA 700C in the presence of ?eC1 2' The resulting
-2 (KT-2) complexone had an acid number of 5.5 - 5.7 mg-equ/g and
COnthined 1.7 - 1.97t, N. Oxidative degradatlon of the copolymer occured
as aide reaction. Bezause of tnis reaction tne copolymer is assumed to
contain 73;~b iminodiacetic radicals and 2716 carboxyl radicals.
?otentiometric titration confirmed a two-stage dissociation. k0/
Chlorometnylated bD %as aminated with iminodiacetic (1) dinitrilp or
dietnyl eater, iminodipropy.Lic (11) dinitrile or diethyl ester, and was
then saponified in 0.1 - b.~ N NaOH. Oxidative degradation did not
occur and tne degree uf amination reacned only 60 - 701~ in :, ~&7m in
Dicnloro ethane wa.9 U-.e uest solvent. The degree of amination wan lower
in tetrahydr~)furan, dimethyll formamide, dioxane, nitromethane, or ethanol.
The acid number of -2 (KT-2N) complexune, a copolymer containing I
groups, was 2.) - 2." mg-equ/g, that of tne -4 (KT-4) compioxone, a
copolymer containing 11' groups, was 2.6 - 2.8 mg-equ/g. Tne aweiling
capaoility of these complexones in 0.1 haUH was 20 - 25A. If the K*
sorption is put at unity the following values are obtained for tne
complex-forming capacities of KT-2N, KT-2, and KT-4:Cu 2. 0.625, 0.432,
Card 2/3

3/190/65/005/001/007/020
Synthesis of insoluble polymer ... B101/B166
2t
U-657, 0.570, and 0-550 respectively;
ard 3.560 respectively; Zn
ca 2+ 0.544, 0.228, and Q-170 respectively. The weaker complex-forming
capacity of KT-2 by ~omparlRon with KT-2-N is explained by the oxidative
degradation and that of AT-4 by the greater distance between the nitrogen
atom and the carboxy, group. There are 4 figures and 2 tables.
ASI-OCIATION: Y-ookovskiy 4nimiko-teknnologicheskiy institut im. D. 1.
Mendeleyeva (Moscow Institute of Chemical Technology imeni
D. 1. Mendeleyev)
SUBMITTED: July 14, 1901
Card 5/5

T n
V
VA"h.A

TP,C,-Y A IFKAY At Ye B.
pol-
165.
V%r-ft-:~N'U 7Trrj -,)J I K -I
(,I "bo

ACCESSION NR: AT4033532 8/0000/63/000/000/014vol"
AUTHOR: N~fWoVa, 1. D. (Candidate, of chemiml wisnoss); Somova, A. A.;
Maslenallwva, A.'A;"---
TITLE: Stainless steel for equipment producing caprolactam by air oxidation of
cyclob
SOURCE- Poluprodukty*Wya sinteza pollamidov (Intermediates for polyamide synthesis).
Moscow, Goskhimizdat, 1963, 132-169
TOPIC TAGS: stainless steel, steel corrosion resistance, caprolactam, adipic acid,
cyclohexane, cyclohexane air oxidation, caprolactam, production, adipic acid production,
cyclohexane oxidation equipment
ABSTRACT: Samples of ton stainless steels (designations and chemical composition
given) were tested for effects of corrosive environments present in the reactor, separa-
tor, filter, distillation column, reservoir and sedimentation tank of a plant producing
caprolactam and adipto acid by air oxidation of cycloh-le. Temperatures ranged from
140C to room temperature, pressures from 0 to 16 ati. . exposures from 784 to 849
hours. Analysis of the results, expressed in terms of cor ..-osion rates and presented
graphically and in tabular form, indicates that Mo alloyed steels are bect suited for the
Cafd 1/2

ACCESSION MR: AT4033532
basic separator components of, a plant. Stools containing 0. 03 to 0. 04% and the Nb
alloyed steel Kh19N14B exhibited beat corrosion resistance in the principal components
of a plant producing adiple acid. Orig. art. h to- 3 tables and 3 graphs.
ASSOCIA-77ON: None
SUBMITTED: 120ctG3 DATE ACQ: 06AprG4 ENCL: 00
SUB CODE: MNF OC NO REF SOV: 000 OTHER: 000
Card 2/2

0
/T/WMAWk
Ic)/gWP(b)/EXA(o)
ACCUS -1011 a i_ AJIMI"
xftog,k Quilild&t__ -3i Not firaddia, i Yawmllskgn, L. No; Kamenskayaq To
containing 0#1 4,6
Fd
SCOOS t Art6mxtichoskaya tivai*at no. 11,~ 19649 92-.93
].10M. TAW.
11tanjumt tit"inium a1loy yajjjkdjMm metal'welding, cor
V* rosion
re"s im 6-s' fk~66chloric, atid
c
A-MRAM;
04in to. t~ S~ natut,4:11y'-high corrosion resistanii-O-FlitaniuYL in
;,Wrrb4i*4- I Lts-.~4s* in-chemi-est uschLntry in coniinUously tzpanding.
Airiit many fl*lsitigstLitris- have been tarried out iti the lost few yeace on
Aita Itze problem of further improving its corrosion
the 40plications of it
reaUtants was solved by~:%lloying it with various elements. It was found that-
EL
he;'' at effective $44itLves. AddLtL6n of 0.1 to 0.2%
us* ons of t j w
Pallifto to t,LtAftLu*-s14PtLfLcsntly Lncreallon ths: stabMty of tho metal to
-seLds as well as other d
sulf ric mad hydrothlorin is
1A

&'W' woo MWrjUM1WUj1WKn~-
A NO
qc*fttl:t no studies have been made of the behavior of welds made
iof ouch sin alloyAn mgressivs Wdis, and furthermore there is little basis
Cf
i torl recommending, thiis allo for welding chemical equipment.
:V414ing Imeni Ye, 0. Paton Akrainian Acadeuya>
~of sit tatipted the corrosion rasistance R we'rds made of
k 0.1 and 0.2% palladium, as well as type OT4 alloy
~containLnjg 0$2% Pd Lm boiling dilute aolutLonA of hydrochloric acid. Plates
wellided In an argon chamber with a nonconsumable electrode.
1.5 sim thick were
:-The welding condition" were: 1w_* 100 to 120 sup, Ud u 10 to 12 volts, V.
IS */hr. Test ploten were 25 X 15 X 1.5 WAI test media were 1.0, 1.5, 2,5,
and S,jO% solutions oi! boilLr4 hydrochloric acid. It shoutd In noted that
tachnical-gradeAftattium. at JOOOC is stable in hydrochloric acid concentratkins
.,not exceading--005%,
AllorLhS'_tLtmjLux with 0.1-to 2.0% Pd does fot noticeably A'ter the
.-4tructure of the semi, As forthe bass material) palladium in tho'studied
quanUtles Iwo littla offs -ct'on the mechanical properties of weld jointes the
yield Point do*# not.;~Tise by sort than 5 to 6% and the ductility rms-ino the
same as for Welds.
TIA torroo Lott ~',rsslstsw* of alloys mith. 0.1 and 0.1% Pd and their
_M_ to boiling I Oj-1-3-ahd 2% solutions of AC

L~4124,645
7,
Y
qi;
w ~eorv ty~e:~Qm_ alloy wLtb 0.2% Pd Lts weld Jobts
T tion of HC1 I in a 1.50 2.0 and 2.5%
t W il ing solu
Thai ,torrosLon rate reacheo*0.2 w/year, Alloye,with 0,1 and
-but tbeLr- weld seams are less
0. 20L w ii~ La ` in 'a 2.5% boiling Wi
Aii
O'bec .au 0
As. f t 1 extensive disorder of the metal in tha,s a d best-
'it ':_t "S'j44' b IlLng _3% solution of RM crates the alloys and their
- 4 doted
J
4 joints atilt and, - t1ift letter to an *van greater degree. It should
"tJ in the cortosion tests "do on the alloys and their weld seams in
&S indL5% UPI that in sAfty-coewthe corrosion ratis in not duplicated
in - i44"ttioal ssmploi;6~ Thus, we any say that titanium alloys with 0,1 and 0.2V
rd avid - thil it 1011d Joints are resistant to boiling solutions ot hydrochloric
acid, ot* up -to 2% contientration. In 2. S% RCI -solutions these alloys maintain
:,thew~Vessive- SlAtat individual instance #'-breaks dovn,
in,
tot,loss$ ,aIare- r an& the bra akdown bf the passive I
sit
-*to 6 14 ob' Ved vioto froquentl
per
y.
alloy -Ath, &-.2V Pd-Is --resistant only to boLlLng IS Hn; a
~tarthe*:indrense,z in 04~ncentratLoin accelerates corrosion appreciably. In active
drrdaLon proc"91" oll~wald joints, 4 deterioration -of the vald setal
abs p4wily.-in'the,hilat-affected NOM4 Thinjudicatis that 0. 1 and
7-
y ,.1
_~A

t 'U'r" of -OAS metal,-- -is
not' ~.xr *f f4at an in-Abs bass metal-rolled allay, Special messurao wus~
ot wAd joints- sadw of
47
had
t
Mgurs

WO UTIOX

L
SUB CODE: MM, IE

i: t

Yf

i 7

IjP L
9~
JWCM
ACCZQ 435 TOOT6165/0391000011/01
p" AP
7,
Pdk
I.- D,- KL&DWshchikov. 4
f 06vii~ Ni Pi~t Nkfedoito
A, I.mm
Nitm~ alloy-a'
tItaA=-qLP
471
OU,%,4,9,.;':',,Zhurnal,.fiiieheakoy- kht*iiO i390 no. I
6 VIb 1965,~ Ali
TOPIO, TAGS: titanium, titanium ~~alloy, niobium containing alloy, alloy corrosion
AIIC~Aj.anddic befiaVi6r, sLuor Padsivation
dit--behaipio'r 41' Ti4%- alloysAn. -5NJ17S0A,_&t 25C has been investi-~
the
96ketl, ~'Idditions of 2 and 10%- KV decrease the density of the critical pansivation
cutra. t -:"from 22Z Ijazip/ezz
for ut's.1loyed Ti Ito 116 and 71 pamp/=7 (see Fig. I of
-the Haclosure). ~.ffovever, these additions~do not appreciably.~%ffect the current
the:-Paasive region.~ :An addition. or 35%;Nh decreases the -critical passiv-
orl m2 an-
'60itY- to T-5 ua~o c the current in. the passive regioa.
Addi~iofis of. iO,.snd 35% IM shift-the steady' potentialtoward more positive vaJues,
from OM _,to;4().-32-,_and:. -0,21 v but -at
2% the steady. potential becomes more
e 7- t. has. ures. [M)
gative..' OrIg, dr, 3 fl`~
A

7, 1-
.

;4z, ,ii

-A4
S 001
A

hl46hoati*- (State, In
olV

titulel
-
,

iOiie c
63 ENCLI.' SUB CODE: KK-

-46 k0 ATT PRESS: 3185'
1. t-,,t

r
r
.
W,
TO im F,

-
-
7
777
77-IF

r I
'A

kd IwAkrMsCof Of buw MM of

l"t -
A. M. so
Wx patlacta__ guller And 1. 1. NdedGva
(Itu 1
It , Acad. W1, 3d.- U R.. Motdo*). ~ A14- P4&j.
0-
5
YIV
W4
U
S
,
?.otop. 19
-At a
I 1,3519.
,
;
M;
A 1; 100 MPA tfont;~171~al iudivi'RIZ wid that lt*tn
UICS' CoUtisf 4net arterloockrosts V*tieso bad no effmit on
the 4tiv
Itafrog heart Pte", Iforgycr, the amplitude.
dtiv
a
tt
tl
id
bl
l
d
h
e
u CoA
Ac
an vras ccas
era
acream
e
bT t
y
on a. from 34 of the 47 hymtonk Individuals studi*& The
-octicts Tras cayMmic mad was not obtsUnd with bk"d. A
nmot snaW affect was WAaiftdwfth blood. The
*
'r=
h-
iffe
l
f
oop 1w a
et
S Ascut $
fnascity
line, which
acts 03, way of the sympatbetic System. It prently win
t
ta
tdo
Su
Oro
s
wo,
V

.4

t

v

KUGHKRUK, V.V.; NIMMVA. I N.; DUNATIVA, T.N.
On the importance of small mammal self-defense against the larvae
and nymphs of ixedid ticks (with Znglish summary In Innart].Zoole
thur. 35 no.1111723-1727 D 156* (KIRA 10:1)
1. Otdol parpitologii I meditainskoy soologit Instituts, epidemlo-
logii I miktobiologit Imeni N.Y. Gamaleya Akadouti weditsinskikh
nauk SSSR.
(Ticks) (Parasites-Rodentia) (Parasites-Insectivora)

v . I . -- 111 " -
NEF-r -,,( ;~ , - . T, . ; . I . , . . .
, - - f 1~, ; ' , (7, : - - : - El ' . * 5 . ' - .
.41 ' , f! -- -~ .r It ' . r I :' ~ * , , . . . . . It .
X: ,
n, . f, : i ' -1 ' I 1 1. . , --.A !F : I ,
I . IjauF'EiVI)l 1 ssk ;.- zav .. 41 ! : , .. * . ~ R." ", .")i ,.rii.

NEFEDOVA, L.A.
Study of Lmmogenesis following the application 04' associa-,ed
vaccines. Vop. virus. 7 no.2s2O6-211 Mr-Ap 162. (1-UU I 1 5: 5;
1. Moskavskiy nauchno-i;391edovatellskiy institut virusnykh preparatov.
(VACCINATION)

NEFEDOVA, L.A.
Imm=ological activi-i of a live vaccine againEt po.Lio-
myelitis in the vacc-Inatior, of children previously vacci-
nated with an Inactivated poliomyelitis vaccine. Trudy Moak.
nauch.-Isal. Inst. virus. prrep. 2:196-200 161.
(KRA 17% 1)

SOKOL40VAO N.M.; APANASHCHENW, N.I.1 NEFEDOVA..~.A.
3tudy of the reactogenicity and Immunological effectiveness of
Influenza-diphtherial and iiifluenza-diphtherial-whosping coiggh
vaccines. Top.virus. 7 no.6s688-693 X-D 162. (KIRA l6s4)
1. Institut, virusologii iumd D.I.Ivanookogo AMR SSSR I Inatitut
i9pidadologil I mikrobiologii ismi X.F.Ganalei AMN SSSR, Moskva.
INFLUENZA-PREVENTIV9 INDCUIATION)
DIMITHERIA.-PREVENTIVE INOCUUTION)
(WHOOPING 0OUGH-PREVENTIVE 130CMATION)

3TAROSELISKAYAP K.B.; BERD4, M.G.; UUMOVA, Ye.'( . NEMOVA# M.G.
Action of some organic phosphorus compounde on microorganisms.
Zhur.ml obiol., epid. i 1-min. 32 no.11:87-91 N 161. (MIRA 1-4: 11)
1. Iz Kazanskogo gosudaretvennogo meditsinskago instituta.
(PHOSP11ORjS OhW[IC CalFOUNDS-PHYS I OLOGI CAL EYFFECT)
(BACTEiCIA, PATHOGENIC)

r= of rhe
Kit--
r,i ""X'. prof.
13 5ed ova
mf,d i tu i nn ko~ r..,

oj
X
e fj v

BILIA, I.L.; NEFEDOVA, M.G.
3aturation of the organism rith vitamins in ~eptllc ii~-
Nauch. trudy Kaz. gos. mod. inst. 14:373-375 1~4.
,Y.:ILA
1. Kafedra gospitallnoy terapil (zav. - prof. K.A.MayarsPava,
I teentrallnaya nauchno-insledovatellskays, laboratorlyFt (:Ftv. -
:3.V.Senkevich) Kazanskogo moditninskogo institu*.n.

GAL I FFJI IN.. :;oloxron I I I ich; GOLTSHI:V)~, K~avdiya ~etr,)-na; N-'-- --.- i "'A,
I red.
x.M. p
[Physiology of man and aninals, Flzl.-Ioglta cn-Iov-ka ,
shivotrqkh. izd. 3., perer. I dop. Moskva, Vy,shala
shkola, 1965. 571 P. IqII)

ACCNR,~~*026P'99-
AUTHOR: Kursanov, D. N.;
ORG: Ln5titute of_Organometall.~,c -compounds, s K--
soyedineniy AN 355111- 1
TITIE: Isotopic exchan if hy(irof-r, iii
SOURCE: AN-555R. ~ya.
TOPIC TAGS: isoto--)e, hydroggen, ferr,)rerie,
chemical kinetics
ABSTRACT: The
reaction of the isotopic oxchango of hydroCon in acid modia
was uGod as a modcl for investigating the lawD of olotroprdlic substitution
in aromatic systents. Forrocone readily ontors Into this roaction and tho
acotyl groups introduood into the forroceno itioloculos markodly roduco the
exchange rate of the hydrogen atoms on th,j nLclous. By investigating the
effect of electrort-donor substitutes In forrocone on its roactivity, the
authors determined the rate constants of the Isotopic exchange of hydroi~on of
motby3, ethyl. and 1.11-diettUlforrooonos In a mixture of doutoroacotic and
trinuoroacetio acids. It was shown that tho Introduction of alkyl groups
enhances the reactivity of the forroceno nuclaus to a much Gmallor dogroo
than that of the I)enzene nucleus. In alky1forrocones &U the hydrogen atoms
of the farrocono nualous participato in the oxchango, and tho kinetics of
isotopic exchange is not affected by the difforoncos in the reactivity of
the various positions. Orig. art. has: 4 tables. LJM~;: 36,455"
SUB CODE: 07 / SUBM DATE: 21-Apr65 / ORIG REF: r)rJ3 / OTH RFF: -X~l
ard 1/1 -/ qDc: ~~.2~7!54~. 2+M6.11.2 - -,

R, - 5
_7~
W AA Tt
CcrSstoff NK, 2767 /0020/65/161/006/1349/13S1
UR
A] 61
4, Neameyan, Kursanov D. N
5v A. M. lCorresponding member AN S9SR)
Me N.; 1 inal V* N.; Perevalova,
TiTL_C,.A;~:Tha:'mplaiWtaent` of a halogen by a pr6ton, in halojzenofepZRcenqs
'AXISSk,'j~ Doklidy
SOU= n6,,.6 W65, 1349-1351
terium~:
T( feirroce6e.. deu
"A POP
-j
-.ASST9AMk7-j'-, W -acid media 'an unexpect-I
xc,e~changeljof-hy o n
gen
a - C wig
d ji~a~p pf .1 Oforrocint-41th,-the'-4 id is, (i4tect'ed. In 'treating solUtions of
16dofermcendAytAftenic solvints :(benzenai chlori-Je) with douterotri-
it ltdd ~05 'Atomic percent deuteriuO there is rapid fomation of the.
fluoroacet
lerria6e, C' on. 40 a Loferrocene, with iodine.
at! _.cCmP ex C0112bund of i~c The ferri-..
c1he batibif 'after 44duction by sodium sulfitalyit~lds_ft ene containing 9.5 atomic
ie replacement of the iodine atom
by ~deuttpikx iv4the'ciade of bt*m- and dhlc~."~fermcene the substitution of deu--
teriunt- fbrr -~the - hAl4gen also is-,obsirved but t,~ -a lesiser extent than with iodoferro-~
cene.,- or t tealfi 1, ml of. deUterotrifluoro4d'etic acid (95, atomic percent deu-
~7 ~7
Y 71.,

~J-
77
APHO12'
757.~
Rik-'
Ob ch' had -bo rs*jousXy' sattirated with
fe
0-:7 4ittf6n duoi6'' (MOIT. W. of lodofemdene -6al-16in r--..-
gram
A;.
C) 11thanol). Iti: 1~5"Ml. of -bou''Zolift-In a--'stream of pure dry nitrogen,
Imai.ately; A Violet - color appeared and a blia-violet precipitate settled out.
After 1-2 hours tfiO precioitate was removed -ind the-ferricine c-&tion was eKtracted i
fron the filte e~,";Ath water. The aqueoua 14ue extract was treated with sodium
at
d

E'47 (m ) /&T-41 am SOL-RcS CODF-i
025536 _0~_160"_766_1036/001/0122 10126'
A=gtj Nefodov. . A ; Nefedovs, Mo No
CROt none
Synthesis based on organic derivatives of mercury* I. Reaction of morewated
ferrocenes with copper salts
no. 1. 1966. 12-2-126
Zhurnnl obahchey ldiilmLi, v- 36,
70pIC TI%GS: chordeal syntheuist morcury, forroconos copper coopound, mercury con-
powid, anion, reaction rate, rt spoctrun
ABSTIRACT: Halo-, thiocyanato-, acetoxy- and hthalimidoferrocenoslvere pro-
p" from morcurated f;wrocan"Iby qxc"aMq 0 rcuI7 group JrFr VIO
mdan of a copper valt. The rate of exchange of the mercury residue was found
to be proportional to the strength of the acid corresponding to the anion of
the copper salt. Me halogen in bromoferrocones was replaced by the ph6noxy
group, yielding previously undescribed phenoxyferrocenes. vith potassixm
Vk4nolate according to the UUmann reaction. A series of now sulfur doriva-
tives of farrocene were synthesized fr= the thlocyanatof4rrocenes. The
structures of the in-oducts were confirmed by their infrotred spectra. The authors
t_:I. Droad for providing som of the substances for co=Ari:;on. 'i,3y -IIUO
thank -Y
thank S. Go Porovalava for her critical renarka on the vrork. 1;-P,-I.S: 35,99�7
SUB CODr:,: 07, 20 1 SM-I DATZt 12jun64 / JRIG REF: 008 7 orH Go.,
CWd I./i ux: 566.261
I'll/ P ~74__

L 3L327-66 1-:1er (M)/EWP( JR11 - b374/0377
ACC NR, D602MI36 SOURCE ODDEs UR/0020/66AW-662
AUTH3Rt Jefedova. U.N.; Kursanov, D.N.(Cox-responding member AN SSSR); Setkina, V.N~,-
Perevalov~-,~.G.--l-ifesmeyanc)v, A.N. (Academician)
ORGs none
TITLE, Effect of substituents on the rate of I e In fe
derivatives
SOURCEs All SSSR. Dklady, v. 166, no. 2, 1966, 37h-377
TOPIC TAG31 ferrocene, electron domr, dis.3ociation constant, substituent, reaction
rate
ABSTRACT: The authors determined the rate constants for acid isotopic exchaMe
of hydrogen In isix monosubstitutod and four disubstitutod ferrocenes. The
rolative rate constants Kr wore then calculatod assuming unity for
unsubstituted forrocone. & substituents studied included both olectro-
donor and olecti-on-accepter types. An analysis of the resultant data shows
that the effect of the substituont on tho reaction rate in an aromatic
compound may bo described as a combination of induction and conjugation. The
conjugation offoot Is much less Important in this oaso than It lo In oloctro.
philto substitd'Lion in the benzene series. It wms found that the substituent
_.g. ~dJ2 UDCt 5h6.U.2+5h2.957+5h6-.-7?-

3' 327-66
FACC NR, AP6026836
constants obtainod from the dissociation constants for phenylacotic acids may
be used as a quo-ntitativo index of the effect which the substituent has on
the reaction rate. Curves for 1n k/ for all substituents studied show a
linear correlation with thoso consL-ml. Heterocyclic disubstitutod doriva-
tives lie on this same line if doubled values of substitu6nt constants are used,
i.e., the substituenU have an additive effect within the limits of experimental
i error. The authors thank S.L- Portnova and G.P. Syr-ova for taking the nuclear
I resonance spectra. The authors further thank V.A. Pallm and N,P, Gambaryan for
participating in the discussions of the results. Orig. art. has$ 1 figure and
1 table ZMR�t 36, 45F
SUB COMI 07 / SUBM DAM 23Sep65 / ORIO REFt 013 / OTH REFj 010

now=
DZWENKO, A.K.; EFFDOVA, M.Yu.; Y'FI,YAK;"V, C, 1;.
Nuclear mN-netic reinnanc- ar.-. ir..rnrf-~ 'S
isolated from ginnnfng. Pny' Mv
1. InstitiA bIr,'ngichf--9ki -k 1,;r
f I 'I I a I n 7) 1 W, - ~k,v ~ I - ~- I - r . " , , ; . I i ,r, - - .- ~ N, v,