SCIENTIFIC ABSTRACT NALBANDYAN, A.B. - NALBANDYAN, A.B.

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SCIENTIFIC ABSTRACT
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V-0 wrowill we p e-~ 0 0 as .0 I's 102 lei f Mp ! 1 M j is 0 44 - AL k L r 11 #A n 4 - - _ - - - - .11 .!!P itatical 01144dod a Kr&od-en 11 Th. torst.- ~ IT , ! .tjolu at high tourpetatutors. A. 11, NAIIMIIIIYAJI (141, Cho-ol, I'hyp , Acold. U.S.A.W, M-lorl. J. Pill. OA 'hem. !It 11046)1 its ' :0 C C.A. 34,27MO.-Mixtt. of L1 11, + 0, lit a quarti; tuLt 011; ill n it W is were Irradimed fly a It diicharge lainp. r, rewtv total ith ti d on w re formation of 110) increaw p ' , still showed a III*%. at nit U. 2S trisn. I IS) at ' P-348 as i it higher temp. (368-3A11). At-MWignitilitate-kplattle by tile 4.4rk rearli-iii, it., Ill rof o A t a ciso.t f l .hich lu.-Tom- w-otiv %.III, I, tap. ('.,(1 111110 tho. istilitiml tvillp. lit ille.lAlkisr" 6 1 Is'. Al"I ' . is IO1AVICkI fly the 1LIIOUgV%1. IIIIIIIIIIIA11011 115CII Ill ;P11 Near the ignititin hinit, r itirrvitses with temp. sold tile ttraoioo of th i1 k T h d e ese atit itk i on. illiettity it( irradiali."I 1. and floor t -ul.A. Min, *14V tlli~ lengill I, imle. I it vitalus, call lie 4 Ill 0 #3 I-mtent Of 1 and w 214. Alsolve :041' it i, sit. Al,o tvillp. WIl'st 0 v the greater 1. The ouut- Irsirth ..f chain adlivwd 1. ' , at the tile chaill 1, 1 irl'stion lAke, i, 11 at tile 1111AIII-0. sitill I of A greatest I ti-ol. The vi-ty 10119 C113iliN IX-111141411 IlY nwill Willi 1 Settle ON., (C.A. 31. 7M_1.sI) near the iguilitist firuit V r-oom riot tw if, reelect. 'rise effect of troop. and I ,is I lie ellaits I-Atil k its issf-sirott Willi tile 111teltani.111 1-111. -P r re -, j latest toy I I-TVIN 1111.1 Flloo,, 6-boo-Isen. and hLip".. . U. 47.sll). 111. A theory of the 111 14 Ga 14's I C i,1 S " I Ile Int ction of chains. 1bul. 12~3-s.!iist ItsissiAti).- 4!rs k,*1 - I i m nit orajowt 1 11110 44 file ignition tcuip. T for irfailiat . l ievall. Llow.1 toy tile thorlowl fly".t. of tile illudiutiOll orst c -it, shows thew effects to lie vttv small. A correvi i" (fir reactions i lettientin b h i :4 veo y 5til hitirripit-listion g p g tnechalli'l liostulAtedby Lorioi,,tatid 1-*Itjc soffit tire + 0 lit which 2 tela. reaction 1114 + 110, - 11.0 + Ch I ert radicals lyrolucr a new active atoni. Then ivrly lit of lutn"er, no' .*Ibc Vie reactims alepentlis on the oori~nal I ITT . , - 7- ; is u Is AT to L% An 1 IT to It it of a a PC u cut I I fill IT I I.- 114. 0 0 0 410411460 1 0000*90000696 0-0-00000000-00000060ooooose; T 00 0 00000000 U 14 0 AT AT It tld/4! " or Is k or . A. It A _1 is. 'et"Iss :-a* Oo 00 To ill,- IgI111111.11 1,4- I'l-e h.." 00 4 Ff. errale-I Ivy irgsduti,rl I- rated 1=00 lit- valoe I I. "Ni.146"I .,f It, of r,--; , ,e ow phot-twit Ile cli.till ieligth i, 1. I'tom tht- vAlit, on- -ritts; .f 7' all( I at tile I-. I Kill al vari.,Ili iltaduti."14 art- c3lird. ill logtre 00 llikTrinan CNI'll, dalik. Joe coo ea- Wet. 00 Aile $ Or z CIO* I., 'too a'9 1 i i- ow ol"a .1 ; ~~~ -09 4o 0 rw 0 To To I V AT 'I is 0 0 0 0 0 0 0 6 0 6 a 0 0 0 0 O'~ -10-11 11-111 11 4 AF to b m -A A -L -A ut-I .-CKMAIS 'xE!tfffI ~"s 002 a It u U-34111-111, 1) 11119411 It 41 tj T* Effect o( n=ien dioxide ou the regim of the low- *( hydiragm &no oxygest. A. 11. Irl"Peratwe n t'.s S R 1 10. 41.11 jJ1116tihi kill- mt, istION 10.~: I 'Iffil"trA. It', IW Ill '""It 'NO.. of Lit "Im. 11K aml 3.0 virithout NO, I- al-nit 1111 .4 N4 I, 1, I.V lit. 1401I.K it, 41 hish N1 I. he Nt I m.4- Au" A I a I A &#,lALik1MGKJ%t tillINAIWO C1,4411MOtOm 00 I'll" 44. Inv vilill aA O.'i-ill ,&L is no S, u 0 0 0 9 0 00 0,0 0 0 a a 0 0 0 0 0 4 0 0 coo 300 1100 I-001 NAMANDYAN, A.B. Keaour='~t of the quantum yield in the oxidation of aqthans, senBitized by iftercury. Dokl. AN Arm. SSR S) no-3'.101-103 1480 (Kr2A 9:10) 1..Dwtl~ut khimicheskoy fisiki Akademii nauk SSSR, Khimichakiy inisiiut Akademii'nauk ArVauskoy SSR, Kosic7FL-Yerevan. Predatavleno I.I. Semenovym. (Kethane) (Oxidation) NAiZANDYAN, A. B. PA 56/49T22 WWChemistrl - Photochemical Reactions Dec 48 Chemistry - Oxidation "Mechanism of the Photochemical Oxifttim of Vathane A. B. Nalbandyan) IAb of Kinetics of Photoohem ; Reactions, Inst of Chem Phys, Aca4 Bot U36R, Moscowt lov, pp "Zhur Fiz Ehim7 Vol MIP No 12 Discusses (1) experiments under fixed conditions, (2) quantumoutput of the reaction, and (3) researc'h onIntermadinte -?roducts of the reaction under dynamic conditions. Submitted 22 Apr 48. 56/49T22 W - 1W - - - - - &00 StMeta$ OWNS OUAWAW W MKN- A. & 00 I Itut. Cheen. n W. U4 is Aved OdWy AW, SJJA IN& W r-259"Me, z do** Ohl, C U OV11% t"66 tAl me. tbjt 4.2 tin. disel" - Im. SWAN St am I A 0 4' mummew by "S He low. S10fiff* d do a ftoeme-eem I. : W=-Gk d 00 a Al otber t lColf TW 11H .00 so W" ON.0 I tim"wes irkh tat* of Am 9 (A c m" -00 00 49 l go 4 ing th" of Sul I ad tin" tba fWAU" tam), 1framm a I. PAW" makt., 9 - I A& WAR. W. 0.0 *0 o ce./ftim. (t m 106. WA,- 14J. 62l 8.4 me.), i(6H t 00 00 44.6, 6A 5 9 *J I I me Nomm. the r-W=rW. 8. of'HaO (;4b elpocc " "m Cit 0 coon ) detrmses wkb F. thew, #A T ' 04 Iva bec a .- 43 and 263r1i ilkn t t l a th _ ISO ., m a m a m , a With its lbrumatiou, HCHO 4' PF am- dws 1~c~ much more loi lot ftpcvmntsl ve to the axis Wo" b b 6 * l "*d1m. Cocklileft amlyals of the po"" dwared the ab..PU6 dets. of coo am of CO cream e T k WW'Y At erti to it " 1 V"T low h f CIL h i jog . linly sun Goes of Kay of the Ps In socie, tw yiews of CO mW of HCHID tribe lameeleat" * Putrated by t at O t , the HCHO almod cofixiifft W I ,, way from It as r locream. In 'but u," ft yQ lornam fSpimy with loct-slog ze 0 0o the "I at 4001 4d Sam. Iff, total Vol. vaned JIM 2 10d SM 11 CUM convex to ibe "it of I. This behavioc " .A 4 ce.Inde. I r - So$ 12 . , * at) Is see - c0 633,1046 2. If 00, OAS cc.; HC A HC, ce emsecutive reactiomm, it Wkm that ' t mW Met CO ix tonuM by '; V prodwt r(wAr bib* 400 o 7. 4 201,34A,1.0ce.; %HCHObOw. 1 '014. 43. .5. The mot. of Med"Mond b a Raw , p With the chaw mecbmimen 4 k - "a - cit + 0 s Al too I= I. e.t. (data from , . .p ) T I ism); [ , flfj~lr 14 -CHO + If C I HIM oil + Cit# - CHI + 11 1 o ()If vW o a . jA,QA As m. , . N. TUM to Ali $LA MULLUMICAL LITTRAIM CLUMPKATIM, a ' ;10.0 S11"llawn -- - __pr Nowifir lkL' $A"Vo 44 1 1111080 %it 041 4199 10"noms) 031121 go G"v sit U 0 At .0 JkJj;.4 '0 Sri j" ; .1 p A I I - AN A I I IV 0 0 9 1 V 10 0 A Im 0 0000190000 0 0 0 0 0 A is 0 a 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 .02 WO 0 0 0 0 0 a 0 0 0 0 0 4 0 0 0 i 7'.;W ' Af FT Iffr M I SOA to A.# Ao goo I-" oo V.: Melikim Ism 11.1. M4 ryo o4a Mechanism ld #be 10dar I = Ox 1 dAUGO SOd C IM I llydrorn), Mimow. o Unt l t Khi PU " l " : o as . m. . te .Ak4d. Nauk!5.541.14. 1049. R9. Reviewed In UsockkiKkisp. 18 37d(1149) . . 400 goo =00 fed Sed coo W goo 00 XQO Vo I, .................. ... .:--- Ate-ILA M41ALLUNCKAL LITINAVOCCLASSIFICA11001 za-,= U00 slam slylo lly. saam momov - Pali "it owl 43st -l- - * - " 'I 611131 aw &$W lit 6- I b u it At so ' - l # r r r I ,I I i Is it 0 JA I 1W 0 " @I* otaaa Is , ' L 0 0 I 0 ~ 0 o 0 0 *" w 4 0 00-000 al lose of 0 000000 0 0 041 f 0 o C, A 0 6 0690f 0 0 010 0 a_& 0 0 *,* 0 0 0 0 * #p 0 0 a 604 WALBANDYAN-r-A,B, -~ Editor-)- - -- --- -- -- -1 A conpendium of work on kinetics of oxidation chain reactionst including oxidation of oxygen, mechanism of low temperature oxidation of carbon oxides etc; published by the Adademy of Sciencesq USSR* i goreniia vodoroda The machinery for tho oxidation and combustion of bydre- gen 14ookva, Izd-vo Akademii nauk SSM, 1949. l?8 p. (52-28543) QD 181. HlN2 TJAWAND)~Ul, A.B. & V- V. VOEVOI)SK-Il RT-1158 (The process of acidation and combiistion of hydrogen) 11reface, Qhapters I a:e II (pp.) 3-41) of: IMIMITZI-I CKISLENIIA I GOUMTA VODORODA L"oscoirr-Leninerad', 1949- 1,UUM1DYA11J, -A. -B. ---- --- --- -- -- , - -- "Mechanism of Photochemical Oxidation of Ethane Sensitized by Mercury," Vest. Ak. Nauk, No. 6, June, 1949. Discusses new methods of microelementarj analysis developed in the Laboratory of Quantitative Microanalysis, Institute of Organic Chemistry, Acad. of Sci. It 11 Is 11 if Isda 1, a 0 Is I Is I Is A it J- -1 1- A -2 it cc MIL A I , of the products. A. It. Nalbarec.111211. DOIJI -I It is'l[blis evident I hit Co if fill C(;t., re Ila Inverilkation I try pn.ltwi a of detorillin. Ott tile 116111,11111, blamed AhlPhelli. :0 k4y Allied. Xljok N.-S-S. R. 66- 413 VIIAIII Itature, .4 tile le.ictiml k I,v tile I" P0`;- 4h- %Atll- will' 119 "14" a' cirair .4 file ifilit. 44 Ahlorhydr, %ah it., ls~mv . ofm-, 41 I lie III And 941100ftl 14? 4 1111-0118 lilt 14131 of ;011), all.) - it XJ we,. I." ~Um Am. 9 1. 111, amt.. 4.1 JI.Ir 00 W noll. it. air A lillivil ... 14.1 jKo doV, %el,wity v. At lite - hydes at 2S. 190. wid 1:10 were 0.118. 3.21S. aml XW IV.. I lowest v - o.t)l the products were N.1 cc. *lite- - 09 - The yiclds W Coe k resp. At coust. tillte CIF illuillifution, the yield tit mahle. hydell. W cc. CO. cold ILIW cc. Co. OlIdi-Arl-ruring Ilydrs Is prollisivillenal III 113P MI'Llre 1,44 Ott file Inkmity. d of CO Isill vv1Y fi-t with 111cm1i'llf r- altog"lwf at About r - it. CO fit 13 cc-Allito consequently. tcirvakiallon tit the r1mim ovi-m, thf-Aigh te, he yield rtsitibincilloo col the chjle cirrier. ice tile v..I, Ittroarner .4 60 a6laldithydrs lost hicir"atva fes"'ItIchAt with v At very Im "P ,is- Pt"'Zill" WAS daItMted; their 'Line. 41CCICAW4 %CFY 00 -3 1hens &lit, Imssing thnough it mAx.p dmfOrAws ctRitintiallY acj, with furthcr incereAsini %d`jwIl to I vol. ~; of (he Cilia IY linearly with luarazingr; thuj,at.,jj(j*. (or (WI cc. pailmd at P - 42 cc . The ratio of IICJI0 to AM Call$ P45", At v - 0, IM$, still 210 m.ejidii.. the oti.,q I'll, nf, MnAin, appeals. mactst. liltelselidelitly of R; thill. f4mr Is. lit licrolfil" Jointed Waim. r"ll.. 4m, :1. 1, And 2,11 x 00 111". the 130. -A' aldch~,de 000 2,j cc, paurd tile glotle. tit IICIIO and Act[. field. liothor-1- graphically. writ. at If 7-354"d lr*ll - ,(%,fly ex).111troll.11 V, M. I x It 14, 1. ;111.1 1 N 60 D` 2 and ).all. I.lrj ^11d U.I..J. JI.L1,1 &list IV. It J11116-All'. I00. With hirma%I118 1'. tile ?.III., A I.Iolldvi I" ItAt of the 2 tracti-1114, Call. + 115VII.) - 2 ellm t hYdric, llivma~- At very higil r, I v.. *.rry %hitf, I. 1),,f Sit oxidrs should lk-Onle tile ottly ittivnimimir linklilt-tS. 10) anti Cilia + Ilselp - Calls + 11 + IIX(i. the rachl'i'm of Uldcliv.1m Thir feadjon Al'itcul, Its Ill.,. the drift is the rstirr "'M In t"nis .1 the titue III MAY r la the firradill"I scene, tile Octal. of C,11. rt"Isatilvi I. eved over org. r4dival%. loirming liensihicri Merritt with Ila Coen On I a straight line; tile mint. Of Allichyd" tins. anti then Stable liennitles *file C,I I.; lite tit4ble lictimi,jr, ""' I I " r4cird lit lilt,) 41.1rhydr. "Itit'll, m wnfler hma ductrit Macilleg aticactly *1111 thit III file Call$ I A Jkleit r 0 10.35 -2 Kv., but then it levrls "a to a value ,Cry CO slid COO. nearly C*n$t.. while tht hielf-11011111 Of CO + COO. StAftilit from jem at r - 2 sec.. riws vefv neArIv linri,lv with r. S 5 S- to Dori .&P cos. Col IV 700 19 t9 It It to 0000000*000000*0004 go 0 gellegligisgif is 1 6 4 0: seeo*OOOOOOOO *00-!~- ~o~sams .1 Q U of q -00 -00 -00 000 COO 1900 000 aro 0 asic 40 woo t9of boo o*ooloooooooooooooo: 0 00 a a a is 0 * 4 0 a 0 0 111 so 0 0 0 ei USSR/Chemistry - Photochemistz-Z 21 Jul 49 Oxidation "Mechanism of Mercury-Sensitized Oxidatio-a of Propane.," N. V. Fok., B. B. Beres.Lavskiy., A, B. Nalbandyan, V. Ya. Shtern, Inst of Chem Phys, Acad Sci USSR, 3 PP "Dok Ak Nauk SSSR" Vol LXVII., No 3 Formerly, high temperature necessary for Dhotochmeical oxidation of methane and ethane prevented any sub$tantial yield of peroxides and aldehydes. Here, yield of these products was studied as a function of time of exposure in photochemical oxidation of propane in temperature interval 20 - 3000 C at a pressure of 50 mm of Hg. Results show peroxides are a primary intermediate product (with respect to temperaturo),q while aldehydes are a secondary intermediate product. Submitted by Acad N. N. Semenov 16 May 49 Pa. i5oT13 'k. B. USSR/Chemistry - Fuels Aug 52 Rea6fion Kinetics "Inve stigation of the Com position of Pexoxides Formed in the Oxidation of Propane at Room Temperature With PhotQchemically Sensitized Mercury," N. V. Fok and A. B. Halbandyan "Dwssse vol 85, No 5, PP 1093-1095 On-the basis of chem and polarographic analysis a~d through the reaction of the peroxide vith various substances., it vas established that the peroxide formed during the oxidation of propane vith photo- chemically sensitized Hg at room temp is isopropyl hydrogen peroxide. Submitted by Acad 11. N. Semenov 23 may 52. 239T27 US5R/Chemistry - Fuels Combustion Aug 52 ITeriodic Combustion Flashes in Mixtures of Car- bon Monoxide and Oxygen," N. S. Yenikolopyan and C\I A. B. Nalbandyan "DAN SSSR" Vol 85, No 6, Pp 1309-1312 A quant description of the combustion observed in a m-Ixt of CO and Q2 when a small amount of H iq added by diffusion is worked out on the basis of the reaction mechaaism and the coasts of ele- mentary reactions caled from previous work. When the pressure of the H on the membrane is decreased and its Tate of entry to the mixt is decreased, the time between explosions is in- creased. By means of eqs derived from the mech- iinism of the reaction, the article explains why the combustion is only a flash and not a com- plete burning of the entire mixt. Presented by Acad N. N*. Semenov 14 Jun 52 All) USSR/Chemistry - Fuels' Peroxides 21 sep 52 tI.The Mechanism of the Reaction of the Oxidation of Propane With Photochemica;lly Sensitized Mercury at Room Temperature," N. V. Pok and A. B. Nalbandyan DAN sssR, voi 86, 110 3, pp 589-592 Propane is oxidized at room temp vith photochemi- cally sensitized Hg to form propyl hydrogen per- oxide. The reaction proceeds vith a preliminary exitation of the propane mol. Presented by Acad, N. N. Semenov 5 Jun 52 247T17 Nkeltar Sti. FF 7.. This phi"hernical Ovidatlad Of a at bi to Dolkdyllamd' (b.L 'foR tutes. N. V, Fok and Naub S.S.S.R. 89, IN'419_56~3,-T ethotochem. oxida- -tion of CgH. was carried at 100-300*, for equal tnixts. of :CtHaaadClatapressureofbOmm. At 100* Acil is present An the reaction products~ At 200', along with Isopropyl hy- droperoxide and;Afff, formaldehyde Is present lit the reac. tion ptoducts-Walmoat, the s.1tino extent As AtIl, As the 4 temp. Is fiatifeltitrtutd, the ratio of formaldchyde to AM Increases. Among the oxidation products at 300* are ace- tone and CO. The exptl. results Indicate that the active centerstr the photachern. reaction are the peroxide radicals owhkh pirish an the walls et the reaction vessel. Rmftir Leath ri-e Camittee on O'Lalim i,rizen (of vae couricii of Minietere USSR) iii t6i fleldp of 6,~Ience and inventloas annamcee that the follcuring scientIfic works, rpc-,;ulax P-cllem- Ivif iq b-.vokn ', pxd texLbcvXz havc brrn vicn.-It"d tor cempetiticn. tor Stailn 11'rizea for tile '1952 aml ).91:"3 M-amuv, riL). 22-1,01, 2f) ?cb -3 hP7 19S'; 71ilbanfl-,~an, A. P. VOye--v,:,,llSk4.y, V:V. T I t.; of t', e anel Lion of 5, Tnstit;.,tc r.f" so. w.-3cm)4. 'I J,-dy 1954 NALRMYAN,A.B., professor, rediktor; EMAMMI,N.M., professor, redaktor; CMMI t O.Y.M., redaktor; ZZlXff0V.A.Ye.V., tekhnichaskiy redak- tor (Chain reaction of gaseous phase oxidation of hydrocarbons] TSepnye reOAaii okisleniia uglevodorodov v gazovoi faze. Kookwa, 19$5. 209 p. (MLRA 1:1) 1. Akademiya nauk SSSR. Inatitut khimicheskoy fisiki (Hydrocarbons) (Oxidation) J. 'V USSR/Kinetics Combustion. Explosions. Topochemistry. Catalysis. B-9 Abs Jour : Referat Zhur - Khimiya, No 6, 1957, 18562 Author : N.V. Fok,,A.B._Nalband an. y_ Inst : Academy of Sciences of USSR. Title : To Mecharism of Photochemical Oxidation of Hydrocarbons. Orig Pub : in the symposium Tsepnyye reaktsii okisleniya uglevodoro- dov v gazovoy fatsii. M., AN SSSR) 1955) 118-139- Abstract : Review of works published by the authors earlier (Nalbandyan A.B., Zh. fiz. khimii, 1948, 22, 1443; Dokl. AN sssR, i949, 66, 473; Fok N.V., Bereslavskiy B.B., Nal- bandyan A.B., Sbtern V.Ya.,.Dokl. AN SSSR, 1949, 67, 499; Fok N.V., Nalbandyan A.B., Dokl. AN SSSR, 1952, 85, 1093; 86, 589; RZhKhim, 1953, 2853). Card 1/1 - 233 - USSR/ Physical Chemistry Kinetics. Combustion. Explosives. Topochemistry. B-9 Catalysis Abs Jour : Referat Zhur Khimiya) No 4, 1957, L1220 Author : Kleymenov N.A., Antopova I.N., Markeitich A.N., Nalbandyan A.B. Title : Oxidation of Methane by Oxygen Atoms Formed on TRFERI -Decomposition of Ozone Orig Pub : Zh. fiz. khimii-, 1956, 30, No 4, 794-797 Abstra6t : Formation of peroxide on oxidation 0:0 CH4 under conditions of flow (mixture CH4 : 02 - 1:1, rate of flow 406 cc/minute) in the presence of 1.45% 0 becomes apparent at the emperaturb (100-116o) that itLn of 03 begins.' On same t auth decompos thi6'basis the ors consider that initiatoraction is'a6aociated'not -4ith the-O3molecule but with 0 atoms vhich are decomposition products of 03- MMILOVA, L.V.; TENIKOMPTAN, H.S.; NALBABDTAR, A.B. Kinetic study of thm Initial phase of nitrogen oxide catalysed oxidation of methane (with English sumary in Insert). Zhur.fiz.khim. 30 no.4:798-810 Apr. 156. (MLRA 9:9) 1. Akadamiya nauk SSSR, Institut khtmichaskay fiziki, Moskva. (Methane) (Oxidation) "r ----AIITC)TIOVA, M -B --FET-lI-.S0Vr, -G. --I. "Tracer Study of the Mechanism of the Reaction of Methane O/idation, Problemy Kin*tles -mrj'-' C6W-yeiis. v. 9, leotapea Is. CatalvvU9, W,4~cow, AN SS&.o 11957, W12P. Modt ef the psp---rc ln thlo enl,!e-.ttc,?3 vtre prask-raml &I- the; Crmf V-X3 -7 !4,,~s At 7 !r ll~ f, 1950., tv. C4-t-O-qir~ vOlhich t