SCIENTIFIC ABSTRACT MYULLER, K. - MYULLER. R. L.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 2
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

BINKO. I. (Chekhoolovakiya); KOLARZH, Ta. (Chakhoslovakiya); W~_,&_K, -
(Chakhoslovaki7a); PONCHIK. I. (Chekhoolovakiva); RUZHICHKA.'_i'-_
(Chekhosl9vakiya)
Some little-known orientakl tannins. Kozh.-sbuv. prom. ne.5:35-39
Ky '59. (MIRA 12:6)
(Tannins)

NEXWOVI L.N.1 MULLER, L.
GathmUc reduction of oxygen on platinum in all-line
solutions studied by means of a rotating disk elec*ode
vith a-ring. Dokl. AN SSSR 149 no.5-11M-1110 Ap 163o
(14IRA 1635)
I* ~bskovmkly gosudarstvennyy universitet im. H.V.Lomonosova.
Predstavleno, akademikom A.N.Frumkinym.
(oxygen) (Reduction, Electrql;tic)

WULLER, L.; NEKRASOV, L.N.
Electrolytic reduction of oxygen on a smooth platinum in
acid solutions studied by means of a rotating disk electrode
with a ring. Dokl. AN SSSR 154 no.2:4)7-"O Ja'64.
(W RA 17: 2)
1. Moskovskiy gosudarstvennyy universitet im. MS.
Lomonosova. Predstavieno akademikom A.N. Frumkinym.

HELIER, L.;. NEKRASOV, L.N.
Electrochemical behavior of hydrogen peroxide on platJ lir.
Zhur. fiz. khim. 38 no.12:3028-3030 D 164.
(NIRA 18:2)
1. Moskovskiy gosudarstvennyy universitet imeni M.V. Lomonosova,
Khimicheskiy fakulltet.

MITILLER, L, , j
Effet~t of twc--cnq,-ge cazlo~-.s or. ',he pronaps -st .--ducti~_n
on plG'~num in alkaline sol-_,'ton. E_-E-ktrokh,,mJ'_a 1
ja 10.' 5. (11TRA 187r,)
1. Moskovskiy !~riv-.I!il-'.

83571
9/056/60/038/005/004/'050
B006/BO7O
AUTHORS: yuller L. 0
TITLE: Investigation of the Structure of the Main X-Ray K-Absorp-
tion Edge in Selenium
PERIODICAL: aburnal eksperimentaltnoy i teoreticheskoy fiziki, 1960,
Vol. 38, Mo. 5, PP. 1381-1362
TEXT: In order to investigate the K-absorption spectrum of crystalline
and amorphous selenium, the authors used a spectrometer with a bent crystal
having a diameter of 41.6 am; the absorbers were vacuum-evaporated or
powder films 4 - 160 4 thick. The position of the main absorption edge
for crystalline selenium was found to be at K = 12652.6 ev (977-86 X),
which agrees with the results of other authors. According to the method
of Sandstr6m, the width of the main absorption edge was found to be
17.2 ev (1-33 X), which is essentially different from the value of 7.9 ev
obtained by W. Zinn following the method of Ross. The "white" line was
found to be separated from the mainedge by 5 ev, and the "black" line by
13 ev; this agrees with the results of Ref. 3. There appears a noticeable
"structure" of the main absorption edge with increasing thickness of the
Card 1/2

83571
Investigation of the Structure of the Main 3/056'60/0 3 8/00 0 4, 05 0
X-Ray K-Absorption Edge in Selenium Boo6~BO70
absorber. This structure was observed by E. Ya. Vaynshteyn ot al. on the
short-wave side and explained by him; the authors of the present work have
found such a structure also on the long-wave side (cf. Fig.). When the
thickness of the absorber was increased to 160 A , the point of inflection
of the K-absorption e4ge was shifted by 1.8 ev toward the short-wave side
The results of investigations for amorphous selenium are collected in a
table. The observed shift of about 4 ev for A K agrees with the results of
Ref. 9. In going from the arystallino.-to the amorphous state, the width of
the main absorption edge increases by (4.65 + 0.5)ev. The selenium investi-
gated had a purity of 99.9%. Even small impu-rities complicate the observed
effects. There are I figure, I table, and 9 references: 1 Soviet, 4 US,
1 Japanese, 1 French, 1 British, and 1 Danish,
ASSOCIATION: Institut atomnoy fiziki Rumynskoy Narodnoy respubliki
Bukharest (Institute of Atomic Physics of the Rumanian
People's Republic, Bucharest)
SUBMITTED: October 16,1959
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LIvsHrTS. G.; MOIMIIDV, B.V,:MYULLFA, N.N.- SAVOSTOYANOVA, N.A.
.,~ cp;~i -
"
Kschaniss of ordering In 913 Mn &1lors with var7ing mol7bedemim.
Fis.met. I metalloved. 3 no.3:477-462 '56. (MLRA 1013)
1. Moskovskiy institut stalt.
(Nickel-magnese-mol7bdanum alloys-Metallography)

A UT 110 _R S Livshitq, B '~yuUe r, 11. N. 7
TITLE: The InvestiEation of the Phase Equilibrium in t..e
Cobalt - Chromium - Aluminum f .-.0vo"C'
ravnovesiya v si5tt~me kol.al ' t - khrom - alyu'fli.l,
PER, I OD T C AL Naucnyye doklaly vyssney s,kolly. Metallur,--/7~,
2-)' - 2o6 'USSR)
A S T R A C T In the present pa- er the diagram of the phase e i.uUJ_
librium in the system Co-Cr-Al was determined. Witi-in
t-,e range of concentration of the triangle C -Cr-Al
the ranjes of the a+@ .-phase weie investik;ated bused
on t*,.e resul-.s ob'e-ined; this was done by conssir-
ti-e three isot'le=-.al sections at 12~_)Oo, 100,30 and 9006.
Furthermore phase equilibrium at 12500, 101100 nd
8000 C was investiE~ated. The samples investi,-_-ated
wern at t-e respective temperature-. for
and 128 hours. The investi.-ations were car,`,j
out by micro-ztrlirtural analyses and x-ray sirl,ictl~rai
analyses, s well as by determinin.- their
112 lcys investi~ 'J,
Card All al _:at;d may be div4-ded into two

-~e
e Investigation of V Phase Equilibrium in tne SOV/
c
S~~stem Co-.alt - C:~r3:._!,z:% A1,1mi-Im
in homoLer~ecus :,nd -etej-)j,,c,~!erus alloys. T.--.;i-
have two and t*,-.ree o-sases.. T e resiilts o'lta~:~ed
made po2sible tI,e determinatIon of limiti-c
Dhase rFn-eo in the inves~i,ation of ti.e
for the cobalt corners of th~_, diagram Co-Ci--Al.
When the tempe-ture is decreased from 12500 +0 i0-
the phase ray-, a+9 widens viith an increase of -..e
aluninum content, the mono-phase ran,~~e of 9 decreas(_.s
with an increase -jf t%e chromium corte:.t, and t*.,-,e
phase rant:e of E is lar,~;er at 12500t- an at 1
T" e r e a r ef i ~,- u r e and 4 re_.ere%-.cef:,
is v i e t
~A SSOC !AT IjN: L t :14 ut st -A i (Loccow Steel 7.-. ~;t i t,,t e
B. I T T ", D0 ~ t ol P r )')7
21, 2

MASZ 1 WCA ZIPWITATION SCV/4T82
Moscow. Institut stall
ftmlgVodetvo I obrabatka stall I aplavoy (production =4 Troatmect
or steel and Alloys) Moscow, Metallurgizdat, 1960. 462 p.
(3oriess It*% Sbarnlks 39) 2,100 copies printed.
ad. & To. A. Borkol &d. of Publishing Houne: 3. L. Unger, Toth.
Md.s M. R. Kloyraman; Z41torlal Coancll nf the Institutes M. A.
Gunkov. Professor, Doctor of Technical S.Ionces. R. H. Grigorsam.
Docent, Candidate of Technical Sclancoo; V. P. Yolyutin, Professor,
Doctor of Technical Icionceaj A. A. Zhukhovitakly, Professor ,
Doctor or chouicni sciences; I. x. Kidln. Professor, Doctor or
T*abnlc&l Sciences; B. 0. LivalUts, Prorossor, Doctor of Took&-
oI4&I ScIenecol A. P. Lyubimov, Professor, Doctor of Technical
saienaeaj 1. It. Favlov, Corresponding Member. Academy of Sciences
UM; and A. N. Fakhvionew, Professor. Doctor of Technical Sole-s.
POWCOSs ftle book Is Intended for technical par-sonnal In industry.
solentifto Institutions and schools of higher education. dealing
wIth Open-hearth and alectrio-furnace steelmaking, metal rolling,
physical Metallurgy. motallography, and beat treatment. it may
Card VIC
also be used by students specializing in these fields.
CCVXRAGXx The back Contains results of theoretical and 4j;por3ment-
&I In"Stigatlons of metallurgical and heat--incer-Ing pro4~ 3
In open-hearth and electric furnaces. Data are Included on th:13
followIngi desulfurizing of pig iron outside the blast rurnftce.
Interaction or oaades of the carbide-Corming metals with solid
carbon, the change of content or gance In the bath of the open-
hearth furnace In varlous parloda of malting, IntenolflQation or
the electric aaltlng of steel, ato. Other articles d.a.I with
the oonuolformlty of deformation In rolling. the study or the
ocatInuous rolling process, rho depandenco or the friction-
slippage coefficients In rolling on a number of factors. and
other problance In the prosaworking Of Metals. Articles On
physical metallurgy and the theoratloAl principles and techniques
or the best treatment of steel are also Included. No parsonall-
Use am mentioned. References accompany moat or the articies.
there are 20T references, both Soviet =a non-Soviet.
Card VIC
or, g"didat. of Too Sol-
C
L graphfj~ Investigation of the Phase
ftullibrium In the CO-Cr-Al SySts, 26T
_J~LA~ 51-halft. Candidate of Tochnicaa Sciences,
and 1. A. lachikovich, Engineer [Department of Physical Metal-
lure-Wrd-Iftat lrefftxantl. Kinetics of the Inotheroal Trans-
formation or Austealts Generated During Induction Heating,
In RaLl-boaring Steel 204
berasht"no M. Z- Docent, Candidate of Technical Sciences,
?j:RZ'=jph0vK- Engineer (Department of Physical Metallurgy
::d
moat Tr..t=~. - iff.at of Conditions of Austoo4tlzln6 on
the Tendency of Steel Toward Temper Brittleness 297
Z"Myuller, M. 9 , and a 1. Xrimer Candidate of Technical Sol-
once& (Lop"ont Properties or Co-Cr-Al
Allays 306
Ildlo, 1. 9. Relationship Between Carbon Concentration In
card ?/ Lo

83290
2 so ISA500 S/14 60/000/007/011/01-1
2- V)'& A161Y4029
AUTHORSs Gorelik, S.S.; Kyuller, N.N. ji
4. -_
TITLE: Dependence of ~~aryChromium Alloys Recrystallization Temperature
on Alloying Components
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Chernaya metallur-
giya, 1960, Nr 7, pp 146-155
TEXT: The temperature of beginning recrystallization shows approximately
the heat resistance of metal, and the effect of different additives is of
practical interest. The effect of B, Be, Al, Ti, Fe, Zr, Nb, Mo, W, and Sb
on the temperature of recrystallization beginning was studied here, as well
as of chromium smelted by different methods. The composition of the
studied alloys and Cr are given (Tables 1 and 2). The alloys were smelted
in alundum crucibles in an induction furnace in an argon atmosphere and
poured into a copper ingot mold; an unalloyed Cr ingot was prepared in the
same way. The distribution of alloy elements was determined by spectrum.
analysis, the microstructure by electrolytic pickling in 10%-HC1, the
beginning recrystallization temperature by the X-ray method which is
A
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83290
3/14 60/000/007/CII/01A,
A161YA029
Dependence of Binary Chromium Alloys Recrystallization Temperature on
Alloying Components
usually employed for investigating the recrystallization of high-melting
and brittle materials /Ref 1/. The article includes details of ex-
perimental techniques. The data obtained led to the following conclusions.
1) Addition of small quantities of Mo, W, Fe, Al, Be, B, Ti, Nb, Ta, Zr
and Sb Z0-.03-5% (atomic),7 raises the beginning recrystallization
temperature, or 11-t9" (4), of Cr. 2) For binary allgys that have one
phase in this concentration range, the increase of tr was 20-100o C. It is
proportional to the effective atomic diameter difference of Cr and the
alloying element. In aging binary alloys tb rai�es by 200-2500C. Aging
r
Cr-Ti, Cr-Ta, Cr-h-b and Cr-Sb have the highest tu (1,000-1,0600) and a
recrystallization temperature/fusion temperature rratio above 0.60. The
abrupt increase of tb in these alloys is due to the inhibiting effect of
r
the second phase on the growth of forming crystals. 3) In single-phase
binary Cr g1loys containing several atomic per cent of the alloying
element, t depends on the way this element affects the strength of the
r b
interatomic bond. If the bond strength drops, tr decreases and may be
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83290
3/148/60/000/007/011/01c,
A161/AO29
Dependence of Binary Chromium Alloys Recrystallization Temperature on
Alloying Components
below that of Cr, as for example in alloying with iron. If the additive
raises the interatomic bond, the recrystallization temperature rises, e,g,
in alloying Cr with tungsten and molybdenum. Repeated remelting of' Cr in
a neutral atmosphere without crucible, and reduced saturation of Cr by gas
and products of the reaction with the crucible material, lowers the re-
crystallization temperature from about 800 to 7500C. There are 5 figures,
4 tables, and 6 references: 4 are Soviet, 1 English and 1 German.
ASSOCIATION: Moskovskiy institut stali (Moscow Steel Institute)
SUBMITTED: November 5. 1959
Card 3/3

8/03 60/026/009/003/0-8
B01 5YB058
AUTHORS: caller, N. N., Bernshteyn, M. L
TITLE. Application of the Microscopic Method for Studying
Structural Characteristics of Real Crystals
PERIODICAL: Zavodskaya laboratoriyal 1960i Vol. 26; No, 9,
PP. 1084 - 1086
TEXT: The structural characteristiOB of samples from refractory aus
tenitic-0395 (EI395) steel (16% Cr, 25% Ni, 6% Mo, 0.1-0.2% N 2~ 'up
0.1% C), from the refractory N4437 (B1437) alloy of the type "nimonik-80",
and from metallic deformed chromium, were microscopically investigated,
The E1395 steel was hardened at 12000C, cold-formed, and subjected to
aging for various periods at from 5000 to 7000C. After differential
thermal pre-treatment, the polished sections were electrolytically
etched. On the basis of photographs (Fig. 1) of the microstrunture 'it
is stated among other things that the microscopic picture obtained is
to be explained by the dislocations of plastic deformation. The E1437
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Application of the Microscopic Method for S/032/60/026/009/003/018
Studying Structural Characteristics of Real B015 B058
Crystals
alloy also underwent thermomechanical pre-treatment and electrolyti,-
polishing. The structural pictures (Fig. 2) also show "pitting beads' at.
the grain boundaries, like in E1395 steel, and it is stated that at first
gliding only takes place on grains suitably oriented in corresponden-,e.
The etbhed spots are in no connection with a possible phase formation.
Metallic deformed chromium underwent "thermal etching" '. i.e., heating in
the MU-2 (MVP-2) furnace in helium- or argon atmosphere at 15000C f--)r
12 or 24 hours. The influence of inclusions on gliding can be seen ir
Fig. 3 and it follows therefrom among other things that the deforming
influence of inclusions on the configuration of the gliding structurr~ ~_z
also visible at some distance from the inclusion. The change of the
direction of gliding at the grain boundaries of metallic chromium is
shown in Fig. 4. The present experiments showed that a propagation -f
deformation from one grain to the other does not take place in chromi-)m
in any case, which is in accordance with the brittle charactor of hr~-
mium rupture. There are 5 figures.
ASSOCIATION: Moskovskiy institut stali (Moscow Steel Institite;
Card 2/2

LIVSHITS, B.G., doktor takhn.nauk; MULLIR, N.Y.. ksmd.tekhn.nank
Investi&tivg phase equilibrium in the system Go - Or - Al.
Sbor.Inst.st&li no-39:267-283 160. NIRA 13: 7)
1. Kafedre metallogrefil Moskovskogo ordena Trudovogo Krasnogo
Uameni. inatituta stali im. I.T.Stalina.
(Cobalt -chromiunk-&lumirm- allay a-Me tallogre-phy)
(Phase rule and equilibrium)

HOLLIR, U.N., k-nd.teIdm.nfuk; KRIM, B.I.. kand.takhn.r-u
Properties of cobalt--chromius-aluninum alloys* Sbor.Inst.
still n0-39:306-314 160. OU3& 13:7)
1. lafedra metallografit HovkoTskogo ordens TrudoTogo Irasugo
Znmenl Instituta st&li Lm, I.T.Stalin&-
(Cobalt-chromium-alumium alloys)

100
27239
S/14d/61/000/003/010/015
A161,4133
AUTHORS: Myuller, N. N., Orlovskaya, Ye. Ye., Panchanko, Ye. V., Strag, Ye. M.
TITLE: On the anomalous change of ahmmitbu properties at room temperature
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenly. Chernaya metallurgiya, no-
3, 1961, 134 - 137
TEXT: The results are given of an experimental Investigation-with chromium
of different degree off-put%ty-ftlong with ref erenoes to data of two English-language
publication3 concerning analogous studies. 4-ohart gives the content of impurities
in a few of the studied chromium specimens, determined by spectral and gas analysis
The anomalous effect of-volumetric changes in specimens with different impurity
contents reached ita-maximum in the temperature range, of 20 - 460C, and the ob-
servations confirmed ti-,Le data of Fine, Greiner and Ellis (Ref. 1: J. Metals, 191,
56 1951) in respOot of the effect of impurities. Anomalous electric resistance
savior at differaht temperature points was also stated, as well as points of
anomalous t.e.m4t. It isapparent that the anomalous electric resistance and t.e.m.
f. variations afe connected with a peculiar interaction of chromillm electrons with
the electrons of the impurity atoms and dislocations. The artiale inoludes three
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A
27239
S/148/61/WO/()03/010/015
On the anomalous change of chromium properties at 1.. A16l/A133
graphs showing dilatometric curves of chromium smelted under different conditions,
dependence of the electric resistance on temperature, and the depowdenoe of t.e.m.
f. on the temperature in chromium that had been melted in different ways. Conclus-
ions: 1) Anomalous changes of ahromium properties (contraction of vQlume, drop
of electric resistance and of t.e.m.f.) has been revealed in the temperature
range of ~P - 460C; 2) The nature of the anomalous effect of property chw,groU
and the temperature point of anomaly are connented with the purity of n~iromjilm
and the anomaly is the more pronounced the purertik chromium.There are 3 figures,
1 chart, and 3 references; 1 Soviet-bloc and 2 non-Soviet-bloo. The two refere
ences to English language publications read as follows: Fine, Greiner, Ellis.
J. Metals, 191, 56, 1951; Pursey, J. Inst. Met., April 1958, P 362.
ASSOCIATION: Hoskovskiy institut stall (Moscow Steel Institute)
SUBMITTEW August 31, 1960
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2-' ; -
S/1,8/1;1/000/005/007/015
E07-5/E:1~`1
N, N
1"T ji 0 P.5
TITLE f I
PER1 flu II-L' t. h eiii Chernaya
t 1 31
AXT, I,- tthor estab) 1h c d I n c:, r 1 3 1 work (Ref 1~ Izv.
%. I-sshil,h ii:-: -! -i I "deiii , , th e r n a e r~ 'I I it r gr i y a , 1960 , No ~ 7 )
It ~' at - 1, r ':'11 , I-, I, I% I ur I r " -I I (-,I ,, U t I ru,-- ib] e possesses
.1 r P I a t v t-! J v v -i ~ t a I I I. i a t i , n i a r~,- L r e . I /T f z 0 . 48 -
rf ~ I I s '- (I I 1 -5 ' I , 1. 1 if h - r th,in 1h(, L. I I ~ 1, ri,ii;ig ratio for other
we f I h- -.ij - Of p 11 r C I pos.91 b1 I I t y tha t
~he *e f ea t u t 5 o r i z~%tioii :,f' 1! r ro I I., I and of its allojs
I ILL e r ~3 t L it r- q t r!j f~ ;i thf~ deformed
T.-I n t. 1 --,3 r r i e d Q 1.L po; - ; k - i i rve s I: i ga t inn s
~ 1, he ch iin z F l. 0 j 11, ,- tul e ,III Ing i~-! o. 'n--1 tioll of
"Ir-OrIll 11th '~fld Of C,!: C I -, ', .: ti'l d I S '. C, I I r '.111 The y
all.-11 'zi F! d W I d t-, I I - 11 g Yr -I j n P 9 1 11 1 )1 - d k. f (, r it. c. d s t. a t- e
t h j F p e r - -I t) n o t t n-- st ru-- ture and
(v (lei vi initte
at 6 115

~klr I- t :it I h
I 10~ 'kila I of
t0f, rill
a r d Pn t-d
ro m ii Lm a nIitjj ~j 9 iv oii pt i i t!ti s w o r k i i
def r ni,~ 1 n ti rwc! u ta Ywi 19 c) c, n s i~ it W.) I Ik Ilardenea b.,
11 r f I L S -1 1.1 7 : nk.).- I -kIiISfT11 , II I1113 1 r~ I 1 11e P;) w c-r
,i,-foTnir,d i n % nit, t iiwit t-,i :io r ;3 1 o (JI u t- i t i v itv v n .~ i r; t I , ' (,- rill
o n a L ho X - f ~ a t ii -~i i, ~ r- t-- ma (I i. n
I in d a I Yi a n rjD i ii d , t, i,re 1 c r c,, j 7 e sian (A r d
p t: w I v- r ~-, I t h e i I iIt ean i i e e d s 1. a t e i, a z, u5e-l Cr - f f-
In ad'i I r I oil t I--. t 1 0 '11 :A'r, :j p o e: i w t- n s .C r F e (2. F ) an I C r - Ta
,,I% T& )I lovs -z*? I IC" 1 11 a t F (I Undar tht, iondi t i c) r. .9 o f
0 )' 1) ~- S u I E! i tfie -- i n e s t r i~ Ina r d qn d iro i, A a F:
de ( e r m i n c- d t h e I rprIva - pro(III.- e d L' y fl 11 11 v Thi~ t, i d en t n z
anal -,r-sed 1) y hp Irima t i on me 'hod u ~ ii i (,y a s a ri ap r i r,-) x i mo t e
f Lin c t _i o n I / I + xii- a I '.. u I a t I o n I... a S c a r r i ed out by co;:;parinv
the widening a f t h,*~t( 1 1-0 )a and ( 2 11 )a . usl nit t he rad !a t iota
froin a , liromium a I Ic, -,, he rbtained results indi cate that
d e [o r ma t i o n c f c h r.D r. i u ii a c - o m p a n i e I ba s i c a 1 1 y by di.'3persion of
the struc tLI.re and i t I -,;3 to the rreation of sli gh t ela s t i c
s tre2ses wh j c h ar(. :zu ( I i ha t the -i uo no t have an influpnce on the
widening of the X ti,' -i i i frac t.ion I ines This conclusion is
Card 2/ 3

Fra!urr,~ h+- cft.ln.tt: in tile S/I VVOKO/005/007/01 i
2073/E535
c,)rrect olso io. -hi.. inveatjl.~ated Cr-Ta and Cr-Fe alloys and
conclusive evt,-I-rice of the correctness of this conclusion 3s tii,~
f.,3,c--t thot nnal~sis of deforitind iron grave an oppatiite result,
nAlne I I ill the uj0enin,v.,3 proved to be due to microstrr~,,ses
Tht- follovin u (-ot,clusirms are irived ati
I Me Structural ~ ranxe-,i durin)~ d,iormation of chromilim -Ind it,,,
allois ra-ilrilly conc~ist in refinirl~, ol the structure. The inLCrO-
itre5tls~6 ir,e relati vely Ik)%-4 arid do not have an,i infllien(e on the
Widening ~)f the X I a rli f Cr a c t i on pa t t ern -s The a 9 Sulno t 1. on 1.3
expr,a6.ied that the hi~s--h relfitive recrystallization tenipcretturr-
( vr/I, i us - 0, 4 11 ) 1 9 ivith the low valid- of the
stressee arid the weal-f-ried rele of elastic clLstortions in
a,:celeiatiti 'P recr~stallizatiori rhe letter ptoceeds basicaLly
as selective r e~ r j s f a I I i zpk t i on whi cli i. a a t imul a ted -,; i mA r i I :, b~:
the t(-nden,.-Y (if t1te systotit tn be in a state for Wiich tnr., surfac'e
energy of thi, 5:-;Tew ii et! a minimum There are I table atid
3 rpfer~-ncoq~ 2 S(Y-1'1#`t'bIOL and I nun-Suvief blob:
ASSuC IA IJON ~ ; illstitut -3taij (NIO%-~Ow steel 1116tittite)
SUBMITrED JaIIIIi't ~ 20 ~ I Ih I
Card 11/3

-JUULT I N- N-; SOTNIKOVA, L. I.
Studying certain properties of copper cathodes deposited in
presence of various surface active additives. TSYst. mt. 35
no.10:29-33 0 162. (MIRA 15:10)
(Copper-LUctrometallurgy)

MYULLERY N.N.; SOMIKOVA, L.I.
Kffect of additions of surface-active substances on the structure of
cathodic copper. TSvet. met. 36 no.l12l-22 Ja 163. (MIRA 16:5)
(Copper-Electrometallargy) (Surface-active agents)

14YULLER, N.N.; SGTNIKOVA, L.I.
Effect of surface-active additions on the structure of
cathodic copper. Trudy Giprotsvetzretobrabotka no.24:139-
145 165. (Map, 18:11

MYULLFR, N.R.
Effect of dimesole and vitamin B12 on the metantasia of different
inoculated tumors. Vop. onk. 9 no.9:27-33 163. (KRA 17:9)
1. Iz laboratorii eksperimentallnoy onkologii (zav.- zasluzhennyy
deyatell nauki prof. N.V. Lazarev) Instituta onkologii AMN SSSR
(dir.- deystvitellnyy chlen AMN SSSR prof. A.I. Serebrov).
Adreo aytorst Leningrad, P-129, 2-ya Berezovaya alleya, 3,
Institut onkologii AMN SSSR.

LOGINOV, A.V.; UYULLER, X.R.
Cholonergic properties of chlortetracycline. Ant"biotiki
7 no.3:8340 WIM2. (1-111-u1 15:3)
1. Kafedra fiziologii (zav. A.V. Loginov) Leningradskago
khimiko-farmatsevticheakego institut&.
(AUREOMYCIN) (cH=xrr,)

HIULLER N R.
Role of histamine in cancerogenests. Vop. onk. 8 no.7:105-111
162, (MIRA 15: 7)
1. Iz laboratorii skeperimentallnoy ankologii (zav, - zasl. deyat.
nauki, prof. N. V. Iazarev) Inatituta onkologii ANN SSSR (dir.
daystv. chl. AMN SSER, prof. A. I. Serebrav)
(CARCINOMMINS) (HISTAMINE)

MALYUGINA, L.L.; MYUIIER '..R.
Some peculiar-; t.,,es -f me-rastassizat'on of rat sarczma S.IR
fol-loving incculat-= ~-nder Lhe skip cf the I~ail. V-.~p. onk. 9
no.6:56-59 163. UMTRA l":8)
1. Tz laboratcrii eksperimentailroy onkclogii (zav. - zar-lu-
zhennyy deyatell nauki prof, N.V. Lazarev) Inatitu-,n onk(-Icgli
AMN SSSR (dlr. - daystvi,.ellryy chlen AMN SSSR F-of. %f.
Serebrov). Adres avLcrov-' IA-ningrad, P-129, 2-ya Berezcvaya
alleya, d.3, Institut onk(,Iogl;i AM SSSR.

GERSHANOVICH, M.L.; KAUFMAN, B.D.1 WMLLER,,_.N.R.
,cf,
Conference an problems of drug therapy in an oncological clinic.
Vap. onk. 11 no.12:98-101 165. (KRA 19: 1)

i~iverall
the gr1ruiers K o ml , I e K ,i ria I a mo ai T -,,L t
-ovki balansa k- defibreram. Nc-zskvtx,
issl. in--t
lesnoi, tselliulozn,--burnazhr.c-', dere',
proiqsh-1. i lesnom-u klicz.,

a 9 v
Ole 0 0 0 0 0 0 0 0 0 0 0 0 a 411
1 4 1 a I _101 Is
.:LU_
MAPI
T

00
99A

Tho VAR 40 Me allircirkal canifuctivily of barate
d It d &I" COGUM. R. Jilyallicir MW B. Mjutin-
'
Add has'
'S 00. U. R. It%) MWW(in
Cwtinal"). - "Wevare Alf the jittecumirmm
a
6. %1, tit. tly upitatom 41 trillivit. st which Ilse 141. viev.
"Wido. . III Irciusal. The truips. .W given
41 lufal 2 IL NA14)
ialovirs 04010s
2
few
f
l see
a
tieli o
va
are 4 X PV .
.,
.,
s
- WA 3 x It)-, at 41,17, 114 2m%
to -"at 317 fail 72% 4 X 10`01 2MV MI -. INA&ASs-
*
(fork Idwri, are rvA Wwwru by tbror fikem as 317
alki , 2, . I .. v twWair. GUM-0 wilb If" IbAll 111.5%

0
~ N4~,(),k, allow puWarialkies laccattiar tile tffcvt. title to
low Val is "twarrv W OWY at tempt. attA.Ve tile
wAt as or after a very Ims little. The ciacut.
1x1ra
1e il saa knik. ew an efectrunk. claa&

Oa this pti,m the obwfvcd . hir Mevi,Vil A-tdi"Am
I.lactlill III I fill, atralysia Indicall" N&.0 "mir"t .4
tiar,
Raithillat's.0

J,

a - I a & ae?ALLURGSC&L 1.119441 LASIVOCAIMS
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ir- V_~
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A$* L A -f 'ALL UPGKAL LMNATLo
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It
b V "w
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0 0 0 0 0 * 0 0 0' 0*
10!;
0000900000000,0000*006*0,0000004000*0000*
IV lft~Fm . -- -.;
'C's- "I , a
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v
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rst
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-
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u IOU ita&v 'J., ..ge
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lWaAki s%4 III L. MA&r. -Wd flAwfumkin. V M
%~MACI
'

'
kv. r."1. 4 WO 4-
12W-71. IM 711%14). - The r
W 71. 1 711
1
'
%,jbey2 the equ4-
%bLvw% vilivirr Rf - Ij, K. Rh,w (
ht- Nt X
it
- -A,' r + B in the raw -1 hifier alkau ron-
A r + n in
fn
fn
t. 0010%. at COMIRs. 1.5-2.5 1f the Vablie Of the
t
at
jo
j
Coed. inMILVS rapidiv. All" a min.
i_
(minced for K.0 ghtwq. The r-im"ancy ot .4 % -l
coum.) wim tiffided ffw high 41UH content. The -00
er ol mabilfty of the Inn% is ht the order Li* > W >
eramithIlf,
a he

at'. C(.
> Rh'. cf. C. .4. 29, 2"'. F. It. R.

see
we*

tie*
f
CLA%SWKATiGN tie
00

*0
coo
lt ~;
ax
n It x 11 1 to
n 1
,
"
"'
O
0
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a 0 0 0 0 0 0 0 0 0 a 0 0 0 0 4 0 0 0 0 0 0 0
r!
f
:
0
,

0 4 006 *0 9 *go*** 00OW
0000000000000000090 0 0:0 0,0:"* 1& 0 0 * 0 0 0 0 4 0 * 4 * 4 0 6,10
M is 14 it 0 " tin Djax 16"imp fill U
0 IAP is" N to a 41 Q to a Gco
-
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'

)OP P.J.
fit ..v t.0 cow*$ go
-.111 A I
q
OtO IM LIS
S
2
Aas S
R
I
4P" I
.
.
,
.
..
,,
(IMIMin (kintan); J Phyl. C". (V, S. S, R.) 6, Oil$-
it 30 ltfjS)(ia Ku&w&n)-By cunsuirrmt; gl"wz as enter-
nwfiate betwvcn iuck crymai fattkcs w0 liquid salt
~4tas. an attempt was mwk w a thc~wctical intcrpretatatin
4 c1m. cmitt of jltawc The I-tvnkcl vmd. theiwy Is
oti,ldsorable d a currectim ftw ivnip. depectwkswe is inadr.
04 4 I'm Bokh aad'-Ah Am" cutw., iu ithwh A is
*0 .1,`ctAd b Ow f-wricouls fa, iv - ckv. ccicod.. In (A ~ r)
";
1
D
l
W
F
= ft**

00 .3 oo. - :
at - .
~...
.
d
+
A ti
,
be SiO. glaiow~ Ar - 4. A dissificatim of clason is given. zoo
000 1-4tw-alWi g&wjws act "miklewd as frusim "ns, o( %0s ago

000 :S4~) to the Name (od"te). Witte twirritior tit 11.4h
j
OO
, --,nwu. V,4 tl.,A. (win aud i1wiraw in sisr. Uxptl. late
1 Z
oo "C-01
'. ~Atkxf% alkali I.Wate 11. to. R .00
of Joe
Argo
We i so
~o I

As. ik. 41TALLUMPLAL Ultfl&y6ft (LAWFICAMN

j. all
--
t- V v
w too
ao a I & 00
i
to " R ~
'10 A
0 0 0 00 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 oje 0 o o 0 0 & 0 o 9 0,

Olpflosts" oftill
Igo, ..v m LITVIO
04P
00-:
oo-
!
go:.
V 0
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oes
w-Aq. !5W, a
pwnFop 41 of x
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4
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so-'
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roe
00
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00

sot NO
t
A iffnMIT Mmk-
OSWASUS SAW 004"at*6 a"&
00 00
lilt nm abowa, a embowd
00A UNw. Aaw 16 10-116, In& to -00
zlr_ ohm@
009 ft now ad 00
that t
00 06&*atim. [au"
a
so 4 bet -00
tdatme to akwownive whMmum
go a &ja Sur tie voludds
00
ad nkdnd bkuvmm tta uAmundwas mkntm see
0691 ddledommehan 4140mmeam"N" w" 41101IM31fir hudw f so:
* a 13 surwinwow d'C"'timmaing 01 tow N 8y of activvtim 411
000 kmoigW"bwgingiv4s&vabwodlo~-lak.cal. AnattemptiGmadc so
004
to clarity the Physical ad tim coma of activatim Of ~WutbmL Ono*
00 Simakamemnly a definW= is Ovem Im On tmtW Of Octiv&bm Of dw
00 am"11-timm I Fimn a computan of dw experimem"My dedowd goo
0 wahm of C in the I 6w the ,-joedy ol mAutwa Vm - Cc - AIT see
with the tboure4kally calculated valves. it to concluded that ft valAw of OA
emAcient. acconling to UyamoWs tb-y on the sWutKm p-ocem bawd on 400
dm WA94k pa %b-y is am -voic- . The cakulailion ol the constant C 6*0
aggardift to tbw adsorption tkAm)f oj,Fgjmhel and to a certain deirme
see
J,I to dw wMautica tbmy ad Pdanzi and W4P- I-A to 6040
all! detwecturymaks. jSmmAbdrwtIGU(I9M)-1 J. K.
e ASO-SL& IRTMANIMAL LRMIM CLMWKATM see
81 1 4"m 7-~' 7
It L-HT-
140"Inoff
W, go w9 I a p 0 1
02 so a a -Fw w '. I a. 9 d
074 'We 0 al ow , s 2" I I a 4 d 0 1 6 0 9 4 1 0
is 0 0 0 o 0 0 0 0 0 0 0 0 0 a 0 0 0 0 9 0 * 0 a 0 0 0 6 0 0 0 0 0
11 000*0000000000 00010

90*009909000000060 sees WWWw
1) 14 to 1# 17 )#,)1, 11 V z is is 111 17 x 10~ Ja v to It a J. v a A Q t3ce
~L-f -r. gL-.k- JL -i. &,- -o,$ a
411114 adw R71, ulkr Ada Pkysw-
CUM. V. R. S. S. 4. 4111 W(MMI ~'& C- -A 49, WAP'.
1U igmed tid *An. iq coculit"Kii toy Ito rate of "I"Ch
traullptort acid toy the rate d chutt. reaction- A ~ti-
faculty calirr"oll 1W the turama-I rate ulu,14 ilocluAk
-Aftmoo c"Nesploo"fing 1.) owto Uf Uw~c pffoxe~'- It 1,
alwalomord 111koas a curicti. turbulent film of sin. exillb in th. -00
locighbollooluld 419 the intolfwc lu"t that The thkklw,, 'd
thor film Lq pragairt4onal to the sp" td the CWTVtot .."I t.,
00 the daw. Trouts(keFt through this fart talw. VW, Iq 0
fucatts of tak-ro-ciLlks soul currvtat~ sold
00 not by diftion. By equating the rate at whk-b rrt&trrL4 -00
00 is latrodwed =0 reauned from the layer an exWessicta tot
'Aftined far dw measured rate in tcrM%,)f the spwd of the 0 0
00 z
tionlat OW of the reactim rate. Atloavspvcdsothcom~ 00
*0 veeUvw rate is oneAsured; at hish nxvds the mcimard j (# 0
late approwbrq the Muctiom vats 6% nmenitude. cons
00 joarivou to olawk with tittit. P, 5. "Ict, ~00
0 0=2 ;00
see
woo
00
001
.:0
00
we0
0 0 0' 0" 0 0 0 0 6'0' 0' iio 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
~169*" 0,0 0 0 4;0 0 0 0 41 0 0 0 0 0 0 0 0 0 0 0 0 WO 0 0 a 0 0 a 0 0 0 0 0 0 0 & 0 0 0 0"

0
a 1 a it W U so t$ is U a to a -it a at v a a v cl Ad a 1, u a a Al
&
I
I a A
a .0 a d) 0 4lio
A. IL-L-A-L-L-A-- -
.
dl~ r- a

l
b
111"W8141111 49 68 11111111 all 0*99= al
W8t*
AWAS
,
Malla-r
Ab
To
V
ValmAtilgo and R
J
limm
L
4110 .
.
.
.
.
.
.
y
g
UI.An
"
t,-uajpn,
ui water of 9 and Na tomate ommw~ us tb
I
)S
00 a A (in big q in the umA. froctum
q,%
jMh + (I - #
'd mmalkAt'SmAh) is flor elb"i vr~ft lualitj At a tutu -
*0 a I km at tim *=~. said da case of anxing. r�W Imainsund 0
,f tbr vWW rime of slow dec. maid - and t Im, ImItinning us t th

'
foss
'
of she aw of WAIL M fumlkm* of m"Jc Usti as j
y
IZ
kooke gamm IU dbc. outat. iA a
,
iu
a a"M
lvil
sul 41" go(* of moft. 6 6 (unclim Ut Iculp. and Im.ans
c atc, Wbm q - 04 the cute cA mals. is nut guvcrwmi by
clsfamigma. 6m a 6Mp, mcf, at 7 N%IdrVm anti in i Jw
o
rtsuallm Vag 411. A - II&M, maW C - 73 with a co
Wav probalmle gam. Wbes q - (1.1 even ralmd tumois
I
k
MIRM votat
ou, -.) did mot O&Allk~ t. It," t tW -1 -
do 0
the phaw4mandwy reaction tate bt-Cins iv Ix the rai- Xo*
Jeog. step. Tlw rck(l%v mtca u( sula. *( IfIll'. 73' and
'
'
1

Of
5, 5 god I fia
d i
11, toki 1
mw ohms A, 2 mod 1. hir f
"
I'lorcalrof OW". I* Stmol dl 1) A o.'
I(N Na hotale

00 al Andat (1.4 4131 (,w K (Kwao and al%put I potilt it% volur
Rafluumill

wee
i
Ao
,
"A4 Liloo&IWW CL&SIAMPICSTION
I&I.&W
wee
ago. 514,611"
load a* ONO aft 3W
I
40
0 0 0 0

4 4 A i a 0 FIG I venal) RUN an
u
a 0 0 at a 4 0
$I Cm AV a
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ow
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upy
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U 0 At 00 1 IV It oil 41010141 1901111 Ital w
u
w 11 1 am a a
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2
0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 * 0 0 We 0 a 0 0 0 0 0 0
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06A --.wdldft 4 0ft
U. A. S. J., a
band -W ONIM

004 IMP I
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ess ~
W=b. a
004
004

sow

000
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o00
DWI" The dbmwo.
Ike wmtbe AM owed ift tee. 40 a VOWN of Obw-
ktdm Od
tm " 66,5
.
0 to dm etbw. am

l, . M. d"i"d
VAMd IA ilta b
md"r 11 qqxqnwdimm 6w dw ". 4kc.
as*
in op. al dm while auks. E '400
W4d dk~., R We emma.. T abs. imp. ad v mtia 1-000
* Im w 004m"w 0 Stamm (0 do on. OF kmww 0 410
to wify
L 1900

'
b dad. by do ahtma im do Om d a nktim be
fewindeadva4malmd0"ems. Abmbkwibc gee
of dw 34VURNOUnt wha If akw.
C300
the mWy* d dw twake at SM 11
i;
OWAS. of thm skam is 61"0. The canto of t Is**
"Pumil" to *A 3. Ow 340000mat avatclus
400
a 6" GWAW mstw* of Cho cbmams ud the dw. coews.
wVbx and Work si~. The at.4~Wc sam"wai
gee
WM am appficew to 11, ad makate &I"-.
-Soo
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po'
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ton UWW im is attwmd to 0 doofflawk clumboub
0. The Snop O-Ka* cam-be M-.
a 4
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a A . n 5
I 'I
11 ;'5
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/V r1l /- 4 F T W. ~L -
USSR/Physics - Conductivity of glass FD-808
Card 1/1 Pub. 146-21/21
Author : Kyuller, R. L.
Title : Nature of electric conductivity of glass
Periodical : Zhur. eksp. i teor. fiz., 27, 264, Aug 1954
Abstract : Criticizes article by M. S. Kosman and R. T. Paranyuk. Accuses Kos n
of ignorance of the chemical composition of the tested glass, which led
him to erroneous conclusions. Six references including one German.
Institution :
Submitted : February 2, 1954

ccInce 9.1 A-1
rig
ca iiepz
6:be
All--Giitliili ~(1931

- ---- -- Gas
-Ki

1'ub. 153
L(-: I ~Iju:.ler, R. L.
L .1 i tf ~)l a iol I C C -a tom. C va 1-- --.t S ULl.; a-,-
T
f
'-t In the present work the author describes an c--xpertment _i.
cal physical analysis of the electrical conductivities Of iCL:--
atomic valent amorphous bodies, with the electrochemical vicw-
point representing a subsequent development of existing,,
physical notions- In su,-ceedinE~ works the author will show that,
-'r, Rre in agree2inent --It
the views eypoundt!d in the prei;,int wQt h
pcrien,:e and coni~idcrably expand the circle of facts)
amenablH- to theoretical generalization. Author's conolusion-
According to Stj'aCtLiral chemical and ag6rc-Sate --I- ri. -t4- of
a medium one must distinguish the electrochemistrl Cif a)
molecular, b) purely ionic, and u ) ionic -at;:)mi~- vaivi,L
to the latter variety oelongir4L the ciectruchnnis'-ry of
cates and allied refractory vitreous substances; the *p~--cifilc

characteri.~;:-e f ;cn; :-at(jmi,,:. valent systems distin,~uish:ng them
from all cLh,,.j is their -nvariaole caL,-'oni,-- c,:,ndU,-Li-, n,
awmic val,Wl- at-u- closc to 6(.1-"d I:cni(: ~.:ryLla.Ls '11 -heir
properl;ie-.~ (Wea4 degree 'If electroly!~ic
n for compal dissoclate~4 cw~lons), an'
-atLVely t.,r(D(-,d mobility of
close to liquid electrolyte sulutions in nunpolar .311.'~LnL,~
Ing to their con,.,entraLion dependence of electrical.
S llbTq t t- y

US~-'P-/Phy~~4cs Electrical conductivity
Pub. 153 - 9/23
Author Ryuller, R. L.
Title Electrical conduct-"vity of I-ol-d
II Cxperimental theoret.'cal expressions 1'oi- tlfllt.~
cjndu:-,4,v1;Ly c)f burosiiicatcLi
Zhuz-- te,-ih. fiz., 25, February JL.~~, 24' -2c5
In the preceding work the author erpha3iLed that cations -n bcrG-
silicates are bound electrostatica2ly nugativel'i :,~n-,zed
boron atoms or oxy_,,en atoms, of hf-, enerrr
t MY
of -,u,,h bonds b-ein6 c~-.r.,~iderable (arc-11.1
calories per mole), U) whiLh is due th(~ very IL)w
troly-tic dissociation in borosilicates. In the present wor'! he
expounds a strictly founded theoretical derivation of ~he e(;tta,ion
of molar electroconauuttvivy of buruL~1.11cat,, after the
tion of changes that rjjr~e more prk:clce
also expouxids the cheoretically reasLned tran- fc i -,ri c C
equati6n of molar electrocondLl,~L-V-A~ appil*cablc
lzbile sbate (in the critical rufl---on , f temperatures). He concludes

wilh :han,--e of and ccmocs t:cn of Ela-;3..~ cnt~ rb-
-iL-ruo c chan,cs Li the pc,-,enta6e uf catiun.;
Lpatlinj~ 'n Uip clectricai c~onducrlv~uy, thus confirmLrC Lhi,
L~;ccnce ;.n gla,z~(f, c-f very weak degree of clectroiytic dis~,~Gclation
,A polar- -.Aru,~Wral elerncr,'-i~ and the le(-;;;Ive -,;pnif'.-ancc of the
Jl';3~-UCiaL,Jon c2nevil'y for ( m(li:cU,'vjl.y.
Jubvi-: t -..ed May 29, 1954

USSR/Physics Semiconductors FD-3131
CaA 11. 15~ - 6,,iq
Author M3nCLler, R. L,

Title Electr4-cal conductivity of solid ionico-atomic valent substances. IV. Prob-
lem of polarizational-electrolytic phenomena
Periodical Zhur. tekh. fiz., 25, No 9 (September), 1955, 1567-1574
Abstract In the preceding communication, III, the author emphasized that specific
electrical conductivity as a phys'-cal quantity uniquely characterizing a
substance of definite chemical c(,mposition and, first of all, of definite
volumetric concentration of cations can be experimentally determined only
under the condition where near-electrode concentrations.! polarization is
absent, which is eliminated by means of inverse active anodes. In the
present work the author considers only such electrical conductivity, i.e.
in the case where near-electrode polarization Is absent. He remarks that
A. M. Venderovich (ibid., 23, 282, 1953) and G. 1. Skan vi (Fizika dielek-
trikov, Moscow, 1950) extensively investigated the problem of drop in ini-
tia.1 current with time in consequence of formation of volumetric polariza-
tion when surface-electrode polarization is absent. The author concliides
that stations y ("settled," "residual") specific electrical- conductivity
is physically the most strictly based quantity for specific electrical
conductivity that uniquely characterizes borcsilicates of given chemical
compositicn (and of preliminary thermal treatment), and is experimentally
determi.ned by means of reverse active electrodes under the condition where

Pard 2,121 FD- 31- 31
near-electrode concentrational polarizaticn is absent. Norista~iunary ele-
tr--'ca,L conductivity, including conductivity determined by an a.1ternatiniz
c-rrent) is in most cases arquantity that does not uniquely charac-erize
tne substance of g3ven chemicai composition. Correction for decreasing
r1it external field by polarization phenomena changes slielitly the tht-oreti-
cpC- va:Lue of the power quantity pt in the expression for molecuIar (,Itz~,:ruri-
cal conductivitv. APDroximate computations of free ener-y of elecrTc-ly-tic
-11*.-uc~atlor I!! vitreous borates of alka-14- metals in nonpoiar and in priar
fllf-)~& irldica',e the ic-,tering action of self-3clvational eff---1, u,)()r : !-u
C-nergy o-f electrolytic dissociation. The author also e-tab-:14shed a ~.eries
Twelve referpnf,es;
of mobilities for boron [_xIaoses:
R. L, Myuller, "The vitreous 3tate and the electr~.-chemi~;try -.1'
Dissertaticn, Leningrad, 1940.
Tnstitution : --
Submitted : March i9, 1.954

-------------
fit'.

US&R/Ph-ysics Send.conductors FD - 31.3G
card 1111-2 15") - 5/19
Author Mlyul-ler, R. L.
Title Electrical. conductivity of solid ionico-atomic vallent substances.
III. Problem of polarization in an external field
Periodical Zbur.. tekh. fiz., 25, No 9 (September), 1955, 1956-1566
Abstract The author finds that the polarization of ionico-atomic valent bodies is
characterized by peculiarities absent in purely ionic crystalline bodies,
namely by: activated ionic polarization of bolind cations as a result of
their transltion from one potential well to another of same structurFOL
element ', and orieDtation of polar complex occurring with freq7.~encies
m-ich less than jol 3/sec and upach greater than un-' ty as a result of va-
lent electrons ', in structural atomic groups, occurring during flllc~'Ua-
tion in distribution. The activated ionic polarization explains the
increased dielectric losses at low temperatures in borosilicates poor
in alkali oxides and in substances allied to them. Orientation of
fluctuating polar ionicoatomic complexes explains most probably the
anomalously high polarizability and dielectric losses in bodies with
structural perovskites and rutile. The existence of critical region
of an--,ma:Lousl-; ~-,rreased dielectrip losses is due to the disappearance

Card 2/12 FD-3130
of rigid valent bonds at high temperatures and to tte difficulty of
C.-iletuatton of oriented polar complexe3 at low trmperatur-s in ~onz--
11
quence of lowering of intensity of thermal valent oscill-lations.
Institution : --
Submitted : Mar,-h 19, 1994

Category : USSR/Electricity - Dielectrics G-2
Abs Jour : Ref Zhur - Fizika, No 1, 1957 No 15o6
Author LN[n~, ~R.L_
Title Electric Conductivity of Solid 13pnic-Atemic-Valent, Substances. VI. Electric
Conductivity of Borosilicates in labile State.
Orig Pub Zh. tekhn. fizikI, 1955, 29, No 14, 2428-2439
Abstract A critical review of metheyls usv-.d to determine the characteristic values
of electric conductivity of glasses in the labile state. These values
are given and it is established that in the labile state a-11 these values are
functions of the temperature. The causes of variations of electric conduc-
tivity during the hardening and crystallization of glass are also briefly
e)-mined (see also Referat Zh. Fizika, 1956, 25944),
Card 1/1

Category USSR F-lectricity - Dielectrics
Abs Jour Ref Zhur - Fizika, No 1, 1957 No 1507
G-2
Author Myuller, R.L.
Title Electric Conductivity of Solid Ionic-Atmic-Valent Substances. VII Concerning
the Temperature Dependence of the Electric Conductivity of Crystals
Orig Pub Zh. tekhn. fiziki, 1955, 25, No 14, 244o-2W
Abstract An ex:perixaUal-theoretical investigation shows that the electric conduc-
tivity of cr7utalline borosilicates is caused by the motion of ions in the
crystalline lattice over a wide range of temperatures. At low temperatures
the electric conductivity is determined by the number of vacant sites formed
as a result of the emergence of the ions to the surface of the crystallites.
Such a transition is effected without a change in the entropy term. The poor
reproducibility of the low-temperature electric conductivity is attributed to
the dependence of the energy of formation of the vacant sites on the degree of
dispersion of the substance. At high temperature the electric conductivity
is related. to the number of vacant sites appearing when the ions pass Into
the interstices, and this is accampanied by an entraSy effect. The energy of
the entropy formation of the vacant sites diminished with the temperature.
See also Referat. Zh. Fizika, 1956, 15ob.
Card 1/1

USS R/Chemical Technol3gy. Chemical Products and Their Application -- Silicates
Glass. Ceramics. Binders, 1-9
Abst Journal: Referat Zhur - Khimiya, No 2, 1957, 5158
Author: Miyuller, R. L.
Institution: 'None
Title: On Vitreous State of Matter
Original
Publication: Stekla i keramika, 1956, Nc 4, 11-14
Abstract: Conslderat�on of chemical class'-fication of glass-forming substances
that characterizes them in the liquid state from the standpoint of
capability to form glass. It is pointed out that of substantial im-
portance is not only a character-I.stic of the final state of the
glass, but an atamic-kinetic cbaracteriatic of glass-forming body is
needed during all the intermediate stages of its cooling. Glass is
nonequilibrium solatioD supercooled tn- the stabilization temp4rature
of certain complex structures that are intermediate between liquid
state and crystalline equilibrium state. Glass of a given composition
Card 1/2

USSR/Chemical Tecluiology. Chem~,-al Products ard Their Application -- Sillcates.
C-lass. Ceramf-cs - Binders, 1-9
Abst Journal: Referat Zhur - Khimiya, No 2, 1957, 5158
Abstract: must be considered during the development of its transitory states,
taking into account the initial 1'.qu-d state and the not yet attained
crystalline state.
Card 2/2

AID F - 3924
Subject USSR/Chemistry
Card 1/1 Pub. 152 - 7/19
Author Myuller, R. L.
Title ialence theory of viscosity and fluidity in the critical
temperature region for high-melting glass-forming sub-
stances.
Periodical Zhur. prikl. khim. 28, 10P 1077-87# 1955
Abstract On the basis of experimental data on the viscosity of
silicates, values were established for the relation of
temperature to the free energy of activation, as well
as the enthropy and heat of activation. Three tables,
3 diagrams, 9 references, 8 Russian (1945-55).
Institution Kemerovo Mining Institute
Submitted Mr 17, 1954

SUBJECT USSR PHYSICS CARD I / 2 PA - 1815
AUTHOR NJULLIR,R..L2
TITLE Electric Conductivity of Solid Ion-Atomic Valence Substances.
TIM The Dependence of the Electric Conductivity of Boron- and
Silicate Glasses on Concentration.
PERIODICAL iurn.teohn.fis.26, fase.12, 2614-2627 (1956)
Issued: 1 / 105-7
On the occasion of the analyses of an electrolytic dissociation which in in
thermodynanio equilibrium, the fact that the structure of the glass as a whole
is thermodynamically not in equilibrium was neglected and the structural pro-
cesses on the occasion of an electrolytic dissociation within the critical do-
main of temperature is underestimated. For these reasons it has hitherto not
been possible to,explain the physical nature of the observed dependence of the
electric conductivity of glass an concentratian. In the present work the depend-
ance of the solar electric conductivity of boron silicates A w ce.,
2RT
on the concentration of the metallic ions was investigated in consideration of
structural chemical peculiarities. The dependence of molar electric conductivity
on concentration is determined in first approximation by the dependence of
"dissociation energy" Tj (in kcal per mol this is the energetic quantity of
electric conductivity and serves as an approximated measure for the free energy
of electrolytic dissociation). An exception is formed by the silicates of lead
which must still be examined. On the basis of the modification of 7 the molar

S071 I I Z-58-Z- 181-1
Tran,qlaticn from: Refezativnyy zhurnal, Elektrotek'~LnAa, 1953, Nr 2, p 10 (USSR)
AUTHOR:__~_~y,_,ller, R_ L.
TITLE; Polarization 3f Atomic-loxiic DIfelectric i-.- an External Field
(0 polvarizatsid atomn~)-ionnogo dielektrika vo vneshnern pole)
PERIODICAL: Isv. T~;mskcgo politekhn. i-YI-ta, 1956, V_-1 91, pp 239-246
ABSTRACT: A review of papers on the structure of glass is Presented. it is noted
that exieting statistical tfieories of physical p-roperties of glass are somewhat
abetract, as they do n-A ai_!,'3w f-_)r real ph,,sical and chemical str-uctu-re 3f
g'.ass. High quasi'-e1a2t-.c fo-rces of covalent!y linked atoms of glass-forming
oxides determine the pecaia.Ti.tiea of amorphot:s stvactu-ire of glasses, as well
aR the-ir Physical and chemica' properties. 7t is planned tc replace mechani-
cal exam3nation of the reticu.'3r stract-a:re of refractory inDrganic al-umir=m-
n-a~`-ate with in a-ialysis of Phenomena from V~e viewp.3int cf t~ie atom'c,
bor- -L.,
valent, a!id ionic L-o-n-ds arnong elementary particlep. V--e theory cf V-Iermal
i~D!-_ic polarization doec, nct de.p-;ct the mecl%anism ci the process, because it
Card 1/2,

so~,,, /112, -~18 -Z - 1361
Dielecti-c ;.:. a.,-I Exte-ra.1 Field
rernai--Ft w~Let4er cations make "cof~,qiderable tripa Wit,';,-. Sack, Weak
Witil-Oll", t&k".Tlg PdTt ;TX Ole tt-,--z-C,-tgh CCO-.XdUCti-Vit~ , c~r if their di-place -
rne,~ts are comiparab'e vvitl-- the &mef:-,3-'.Dr-a ~f tHe F-2.-ticles tt,.emselves - Tt~e
rf P-e-tial elt~,,.er. TKe -ionic. -atomic -valcrice O~e-)37v
s'iggeAeted by the ~7- -arswe.~-,A t-.~ above questicns an-d presents
rl,mical qtr",.Ct2la" f---: a tt-~eovf -,f thermal io:ailc V!-,,aTiLatiO7!.
41". -tems. in .,, Kerner~:vr; -..-stit!,te), Kemercvo.
A. M. A.
C,~-, r d 2 1?

SOV/1 12--58- 2 -1870
Translation from: Referativ-iyy zh~~.rnal, Elektrc~tek~v)tka, 1958, Nr 2, p 12 %'USSR)
AUTTIOR: My-,.,-Iler,
TITLE: Effect of Metallic Concentration op- Electric Conductance of
Boroel2icates (Zavisirnnat' elek-t-oprovadnosti boros-ilikatov at
r I j
netaR40%eak:k~-.
PERIODICAL: Izv. pol--teR~-ri. _7111--ta, 1956, Yol 9 1, pp 353- 361
ABSTRACT: Electric cond--:ctance of harosLi'fcates !~, determined by concentratio-
of ionizecF cornpon-ent parts of ion-atom-valence str,2ctaral lattice; the
of concentration c..77. d,..asociaticrn e-aergy of iGvogenic polar lattice points is -,f
decieive ;Tnporta~~ce- A slight Otange of molar electric corductance of boro-
RKJcB~tes at low conce~tratinns- of alkAline iars is noted, as well as a steep rise
of e1ectric cord---,ctar-.ce at lLigh c:ancentratjons. With low concentrat;0-3, tv~e
electz-ic- conductance ia die to metioa of dissociated cati-oMe o---tside t)7..e polar
rnedium, with )---gh co-acer-Arations, a th"-o---gh conductance is observed in the
P-,13T medi-:rn of -.n.-zed compc.r~entj3 of the valent atomic lattice. '-te-zmediate
Card 1,'2

SOVI 112 -58 -2 -18-70
Effect of Metallic lon Concentration o-a Electric Cor-d,,,.ctance of Bo.-osill-icates
region ccrresponds to tl%.e appeararce of the th-rough cor-di:ctance
d--p- to f,~rrnatior of continWou!3 bonds between iorized elements of borosilicate
lattice. A new mathematical expressionL is suggested for the effect of cc,,,cer.-
tration aja the dissociation energy of alkali-ne cations in the boroRilicate polar
medi--Y.-,n; Ala.) a generalized is a-.-,ggcsted for the molar electric condu c -
tance of "oroailicates. Bibliograph-i: 27 items. Gr-rn,;-y in-t (Minirg Lnstitvte),
Ketne r,)v~,.
M. D. M.
Card 212

Krum. R.1.~
Relationship between the electric conductivity and viscosity of
glasses. fiz. tver. tela, 1 no.2:346-347 Ir '59.
(MIRA 12:5)
(Glass--Zlectric properties) (Viscosity)

5W SOV/54-59-3-17/21
AUTHORS: Mjuller, R. L., Markova, T. P., Repinskiy, S. Y1.
TITLEt __M1a`aolut`ionK:netics of Germanium in Nitric Acid
PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i khimii,
1959, Nr 3, pp 1o6 - 118 (USSR)
ABSTRACT: Pickling of the germanium monocrystal surface is necessary
for the production of germanium transistors. The pickling agents
contain oxidation components, e.g. HNO 3' An oxidation of ger-
manium was assumed to take place in pickling, followed by a
dissolution of the germanium oxide. The Soviet authors Yefimov
and Yerusalimchik are mentioned in connection with a review of
publications on the mentioned process. The kinetics of the
dissolution of germanium in nitric acid is investigated hPre
for the purpose of explaining processes in connection with
pickling. The function between the dissolution rate of germanium
in nitric- and nitrous acid and concentration, temperature and
intensity of stirring is investigated. The investigation method
was similar to that employed for glass-like systems (Ref 5).
Card 1/4 Each individual inveetigation was carried out at constant temper-

Dissolution Kinetics of Germanium in Nitric Acid 5OV/54-59-3-17/21
ature. In preliminary pickling with nitric acid the germanium
monocrystals were intensively treated until a reproducible
and constant rate of solution had been attained (Fig 1). The
monocrystals are lamellae with parallel orientation towards the
crystallographic (lit)-plane. Figures 1,2,3f4 show the ger-
manium surface after intensive pickling, shoft preliminary
pickling, mechanical treatment and treatment with aquaregia.
The rate of dissolution was determined according to the formu-
la
I As- gramsatom/cm 2sec (S - total surface of the
w- 7-2-TO-S &t
sample,,&g - amount by weight of germanium solvin,a in the time
,5-t). With a retarding rate of dissolution in the simplest case
wN= C.e_E/RT holds for w; C= 1.3.10 27atom/cm 2sec. The vaiae of
C is reduced by diffusion of the solving agent in the germa-
nium surface. Germqnium does not solve 4n the absence of oxi-
dizing agents. From investigations of the rate of dissolution
at varying concentration of HNO of temperature and of in-
Card 2/4 tensity of stirring the followiAg' resulted:high concentration

Dissolution Kinetics of Germanium in Nitric Aold liOV/54-59-3-17/21
Infreases the rate of dissolution, a subsequent eddition of
Rue3 without stirring causes, however, a plowing down 40 dipso-
lution. When stirring, a further addition Of RNO I increases
the rate of dissolution and the proQoso obtains in outooata-
lytio nature. An accumulation of reduction produato of RNO
9a the boundary layer of the Go-solution likewise inortaa*i
the rat* of dissolution. The values for w could be well re-
produced and agreed with those of roforenas 2, The following
dissolution mechanism of Go is giveno An oxidation of germanium
is followed by subsequent hydration of the oxidation products.
The oxidizing agents diffuse from the. solution to the Ge-sur-
face and the hydrates forming diffusifrom there inic the so-
lution. The upper and lower limit of the rate of dissolution
were determined experimentally and theoretioally and found to
be
7 and 24 10. The upper limit corresponds
log W
Oard 3/4 to the diffusion rate of the hydrates into the solution, and

pissolution Kinetics of Oermanium in Nitric Acid SC)V/54-59-3-17/21
the lower limit to the limit rate of the diffusion of molecu-
lar oxygen from the air through the solution on the germa-
nium surface. Stirring caases a certain reduction of these
boundary values. The temperature coefficient of the rate of
dissolution increases with rising temperature. There are 11
figures, and 17 references, 7 of which are Soviet.
SUBMITTEDs U~y 11, 1959
Card 4/4

AUTHORS; Myuller, R. L., Kcstr~~'rcin, 4
TITLE: The First Attempt at Investigating 'the Chemical Kinetics of
Ruthenium Distill'-it,on (Pervyy opyt izucheniya khl,~-,'Ic',-.i~sk~-
kinetiki ot6onki rute:-.i~ja)
PE'RIODICAL: Zhurnal neorganic~-,e-,ikn-, kh-mnii, 7c.". .,, Nr 1 2:_~7
(U3SR)
A3STRACT: T1- Idnetics of the d-Istillation proceso of xix+lwnixm dirring oxid-
etion by sodium c.Uo:mte vas invesdgated. initi il
ruthenium, -,,ias nrc~'iced oy cniorinatinE thp 4r
distilla t4 or, 1,13 carrJed out in the air curre,_+,
1.7 1/min. Th,~, of ruthenium
on the conce.-.tra'_`~n of sodiam chlortitu. if 1
content Is raised b'.' 7 to 8 t4me-s, the
of ruthenium rises ~y about 10000 timed:. On
acidity of th~, h,,,,lr3chloric acid solutior, from 0.1, t,~
distillati.3n drops to 1/120. The dppendenct~ of t:i- -f
the effective rate constant of rutheriun
logarithm of 'he initial concentration of sodi-_~,.-.
the initial concentration of hydrochloric acid wert~
Card gated and are shom in figures 2 and At roo:n tHmplr.,~:Iro

SC7
The First Attempt of Investigating the C-e:-.--.cal Kinetics cf RU~*-_.--_-_--.
Dist'. llati on
the rate of distillation rises by about 8/. on 1C *-m-,erature
rise. The effective activation heat lies at 26.511~ZHe~2.:
-,q1 /mo I
The rate of ru thenium di 9 t i I la t i on i s a pprox I ma tel y pr,-, pr~r' icnal
to the sixth power of the initial concentration of 3-1,
chlorate. With a hydrochloric concentration > 0.12 n the r;Lte
of ruthenium distillation is in the inverse propc-rtion to
the a-proximately fourth power of the initial sol,_,tion of
hydrochloric acid. The fourth power of the reaction -x-'-th
hydr3chloric acid is probably caused by the reduction prccess
of ruthenium:
RuO4 + 4HC1 - RuO 2 + 2H20 ~ 2C1 2
The rate of rutheni~_zm distillation from the solut-,c-i rlseZ
with an increase of ruthenium tetraoxide content, a lecreaE~
of hydrcch-icric acid concentration and an intensification -,f
the air current. There are I figureq and 4 tables.
Card 2/3

SO V/7 8 - 4 - 1 -.1,'48
Thle First Attempt of Investigating the Chemical Kinetios C'
Distillation
ASSOCIATION: Leningrad3kiy gosudarstvennyy univers-itet im. A. A. Zndano-,a
(Leningrad State University imeni A. A. Zhdanov)
SUBMITTED: October 20, 19')7
Card 3/3

krULL&R, R.L.- 14MOVA, T.F.; REPIMKIY. S.n.
6~
Kinetics of the dissolving of germanium in nitric acid. Vast.
L(V 14 no.16:106-118 '59. (MIRA 12:10)
(Gqr%aniu?m) (Nitric acid)

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ILI

8/054/60/000/02/13/021
B022/BOO7
AUTHORS: Goryunov, A. A., Myuller, R. L.-, Kapustina, L. K.
The Rate of the Removal of Ruthenium Tstr V
TITLE: aoxidelFrom Aqueous
Solutions by Means of an Air Current
PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i khimit,
1960, No. 2, pp. 104-111
TEXT: In an earlier paper (Ref. 1), which is the first attempt at
investigating the kinetics of distilling-off ruthenium in form of ruthenium
tetraoxide, the distilling-off of ruthenium was found to consist of two
independent processes, viz. the chemical process of the oxidation of
8+
ruthenium to Ru . and of the physical process of the removal of the Ru04
formed, either by direct evaporation or b~, means of an air flow blown
through the solution. In the presence of a reducing agent a reversible
reduction process of RuO 4 to lower oxides may occur. In the present case,
the reducing agent used was hydrochloric acid. The investigation under
review concerns the physical process of removing RuO 4 by means of an air
Card 1/3

The Rate of the Removal of Ruthenium Tetraoxide S/054/60/000/02/13/021
From Aqueous Solutions by Means of an Air B022/BOO7
Current
current from an aqueous solution in the absence of a reducing agent. The
kinetics of the process mentioned in the title was investigated in an
apparatus consisting entirely of glass (Fig. 1). Among other things, also
a Komovskiy pump was used. Five aeries of measurements were carried out at
temperatures of about 20, 40, 60, 80, and 1000C, and a velocity of air
flow of about 5, 15, 30, 45 and 60 I/h. Figs. 2 and 3 show the results
obtained for the rate of the removal of RuO from solutions of nitric acid
in form of diagrams. A summary of the experimentally determined half-
periods and of the rate constants of the removal of Ru04 from nitric acid
solutions at various velocities of the air flow and temperatures of the
reaction mixture is given (Table 1)~ The temperature dependence of the
logarithm of the rate constant of the removal of Ru04 from nitric acid
solutions with an air current at different velocities of the air flow is
given in Fig. 4. Table 2 gives the values of the coefficients A,B, of the
activation energy S, and of the pre-exponential factor Cc for the process
mentioned. On the basis of the results obtained it may be concluded that
the limitation of the process of removing Ruo 4 by the evaporation rate of
water under the non-steady conditions in the quick passage of air through
Card 2/3

The Rate of the Renoval of Ruthenium Tetraozide 3/054 60/000/02/13/021
From Aqueous Solutions by Means of an Air B022/ 007
Current
the solution is absolutely possible. As to the decrease in activation
energy with an increase in the quantity of air blown through, the latter
may be explained by the use of non pre-heated air, oontrary to the con-
ditions used by M. V. Tobvin and Ye. V. Savinova (Ref. 7). There are
4 figures, 2 tables, and 7 references, 4 of which are Soviet,
Card 3/3

81657
S/161/60/002/06/47/050
-f . 77v 0 B006/BO56
AUTHORt Kyuller, R. L.
TITLEt The Electric C onductivAt
I y of Solid Ion-atom-valency-
substances. IX. The Degree of Dissociation and the
Mobility of' Cations in Glasses With a Single Type of Ions
PERIODICAL: Fizika tverdogo tela, 1960, Vol. 2, No. 6, pp. 1333-1338
TEXTz In the present paper the author endeavors theoretically to cal-
culate the mobility of the ionsV*0 in a glass having only one kind of
ions. w0 does not depend on the ohemical composition of the glass and
changes only little with temperature. It is essentially dependent on
dissociation energy. The degree of the dissociation of the ions in the
glass is determined by TV a quantity, the numerical value of which
As a -isar approach to the dissociation energy of the ions in the glass.
FoT- boron silicate glass with univalent cations, w oT is of the order of
5.6-lo-2 Cm 2/see.w. depends on the concentration of the polar
Cari 1/3

81657
The Electric Conductivity of Solid Ion-atom- S/181/60/002/06/47/050
valency-substances. IX. The Degree of Dissocia- B006/BO56
tion and the Mobility of Cations in Glasses
With a Single Type of Ions
structural nodes, and with respect to the glasses under investigation,
V. in a stable state does not depend on temperature. As investigations
show, T # decreases with increasing content of polar nodes in the glass.
Theoretical considerations are confirmed by the experimental results.
The theoretical value,of (wa)T is determined by equation (3) ((x - degree
of dissociation); the experimental value (w'X)e is calculated from
measurements of the specific electric conductivity according to
equations (4) and (6), respectively. Experimental values, take from
Refs. 3-5, are given for boron silicate- and silicate glasses.in
Tables I and 2. The results obtained are compared and discussed. It
may be assumed that the decrease of T 0 with a growing content of
polar nodes is connected with the solvating effect of the polar nodes
upon the dissociated ions and vacancies. The nature of the quantities
Pa (defined by equation (6)) and _V0 does not change when the glass
Card 2/3

81657
The Electric Conductivity of Solid Ion-atom- S/181/60/002/06/47/050
valoncy-substances. IX. The Degree of Dissocia- B006/ 'm 056
tion and the Mobility of Cations in Glasses
With a Single Type of Ions
passes from the stable solid state into the liquid otatei Table 3 shows
this for sodium- and potassium silicate glass. P. P. Kobeko and 0. V.
Mazurin ar* mentioned. There are 3 tables and 12 references: 9 Soviet,
I American, I British, 1 Dutch, and 1 French.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A.
Zhdanova (Leningrad State University imeni A. A. Zhdanov)
SUBMITTED: October 1, 1958 (initially) and June 30, 1959 (after
revision)
X
Card 3/3

17-c d
AUTHORt Myuller, R. L.
TITLEs The Electric Conductivit of
substances. X. The Electric
Contain Two Types of Alkali
81658
S/181/60/002/06/48/050
B006/BO56
Solid Ion-atom-valency-
Conductivity of Glasses Which
Ions
PERIODICAL: Fizika tverdogo tela, 1960, Vol. 2, No. 6, pp. 1339-1344
TEXT: If in a glass the half of all alkali ions of one type is re-
placed by such of another type, a conkderable reduction of electric
conductivitAnd of dielectric losses ay be observed. This effect has
already repeatedly been experimentally investigated, and the attempt
was also made theoretically to explain the observed minima of conductivity
and of the dielectric losses. There was, however, no general theory,
and to set up such a theory the present paper makes a contribution. The
paper contains a critical analysis of the influence exerted by ions
upon the electric conductivity by using results obtained by earlier in-
vestigations. Tables I and 2 represent the ion concentrations for
various glasses (which are characterized by n,,:7.b-rFt). Fig, 1 shows th.-
Card 1/3

81658
The Electric Conductivity of Solid Ion-atom- S/181/60/002/06/46/050
valency-substances. X. The Electric Conductivity B006/B056
of Glasses Which Contain Two Types of Alkali Ions
dependence of the conductivity of sodium borate glasses on the volume
concentration of sodium ions; here it is found that e.g. the intro-
duction of about 40 weight% barium oxide into the glass reduces the
conductivity of the latter at 1000[N&] - 10 to 100th. Fig. 2 shows the
dependence on conductivity (here always denoted by x) of sodium borate
glasses of the concentration (in mole %) of sodium oxide. Each of the
two diagrams contains two curves, of which the one holds for a glass
without, and the other for a glass with barium oxide. The curve of the
former shows a weakly marked minimum, whereas in the latter case
-log-,cincreases'%onotonically with increasing sodium content. Fig. 3
shows -logx - fkLffa2 0]) with and without barium oxide. H4,re the two
curves overlap at 8 weight% Na 20. In the following, the author discusses
the minimum effect in detail, especially the results obtained by
investigations carried out by German authors. He points out that an
explanation of the minimum effect in the case of two-cationic glasses
by spatial-mechanical slowing-down cation motion is incorrect. The
minimum effect may, however, be explained by the association of polar
Card,2/3

8 L658
The Electric Conductivity of Solid Ion-atom- 3/181/60/002/06/48/050
valency-substances. X. The Electric Conductivity B0061BO56
of Glasses Which Contain Two Types of Alkali Ions
nodes (of. papers IX and XI of this series). The author mentions N. P,
Bogoroditskiy, I. D. Fridberg, G. I. Skanavi, K. I. Marty-umov, A. F.
Vallter, and M. A. Gladkikh. There are 3 figures, 3 tables, and 15 refor-
encesi 10 Soviet, 8 German, and I American.
ASSOCIATIM Leningradakiy gosudaretyennyy universitet im~ A. A.
Zhdanova (Leningrad State University imeni A. A. Zhdanov)
SUBMITTEDs October 1, 1958 (initially) and July 30, 1959 (after
revision)
Card 3/3

81659
S/181/60/002/06/49/050
0 B006/BO56
AUTHORSi 1~yuller, R. L.
TITLE- The Electric Conductivit~of Solid Ion-atom-valenoy
Substances, XI. The Degree of Dissociation and the Mobility
of Cations in Glasses Which Contain Two Types of Ions
PERIODICAL: Fizika tverdogo tela, 1960, Vol. 2, No. 6, pp. 1345-1352
TEXT: In the present paper the s~uthor derives an equation for the molar
electric conductivity of glasses kb containing two kinds of monovalent
cations. According to this equation, electric conductivity, in the case of
a differentiated association of polar structural nodes, is practically
limited by the flux of cations of that type which predominates in the glass.
The existing experimental data confirm that no spatial-mechanical hin-
drance occurs in the motion of cations in complex borate- and silicate
glasses. Experimental data concerning the electric conductivity of two-
cationic borate- and silicate glasses confirm the existence of an entropy
effect in the dissociation of cations, which causes a coupling between the
Card 1/3 L~l

81659
The Electric Conductivity of Solid Ion-atom- S/181/60/002/06/49/050
valency Substances. XI. The Degree of B006/BO56
Dissociation and the Mobility of Cations in
Glasses Which Contain Two Types of Ions
latter and the growth of Pe and 4 according to the compensation law
(Ref, 5). An analogous correlation between P. and T,~ may be observed also
in glasses within the critical temperature range, and the connection
existing wiihin this range with the occurrence of an entropy factor of
dissociation is known (Ref. 6). Tables 1 and 3 contain a large number of
experimental data concerning borate glasses, and Table 2 contains such
concerning sodium-potassium-silicate glasses. The data are discussed in
detail. In transition from pure single-cationic glasses to complex two-
cationic glasses a dispersion of the associated polar groupings may be
observed, which cause an increase of the dissociation energy of ions and of
the statistical entropy factor, In borate glasses which, at the same time,
contain polarized silver- and thallium ions, a reciprocal capt-are of polar
struotural nodes causes them to be mixed, which, in turn, causes the
minimum effect of electric conductivity to vanish; here, the quantities
P and 'Y,4, do not depend on the concentration ratio of ions.(The electrir
e
Card 2/3

81659
The Electric Conductivity of Solid Ion-atom- S/181/60/002/06/49/050
valency Substances. XI. The Degree of B006/BO56
Dissociation and the Mobility of Cations in
Glasses Which Contain Two Types of Ions
conductivity of borate- and alkali silicate glasses containing two kinds of
cations, the concentration of which is M.10-3molh/ml , shows a minimum
effect whose physical nature is determined by Pe ' B10-1g[m] and
Yl* = 4~6 A10 R, where A1(y and B10 are the coefficients of the conductivity
equation ln K - -A/T + B converted to the decadic logarithmic system
LMj - cation concentration). 0. V. Mazurin, Ye. S. Borisovskiy and Frenkell
are mentioned. There are 3 tables and 9 referencess 8 Soviets and i German.
ASSOCIATION: Leningradskiy gosudarstvennyy universitet im. A. A. Zhdanova
(Leningrad State University im. A. A. Zhdanov)
SUBMITTEDi October 1, 1958 (initially) and July 20, 1959 (after revision)
Card 3/3 L41