SCIENTIFIC ABSTRACT NIKIREYEV, V.M. - NIKISHIN, G.I.
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CIA-RDP86-00513R001136920017-1
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RIF
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S
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100
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November 2, 2016
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July 13, 2001
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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NIKIRETNV, V. 14. (14oaL-va)
Designing momentlesa slanting shells for permanent vertical
loads. Stroi.mokh.i raoch.soor. I no.6:1-9 '59-
(Elastic Plates and shells) MRIL 13:4)
S/124/62/000/001/036/046
D237/D7104
AUTHOR: Nikireyev, V. M.
TITLE.-. Calculating multiriembered slopirif- shells under,
a vertical load
,PERIODICAL: Referativnyy zhurnal, Mekhani),a, no, 1, IW,
7, abstract 1V43 (Stroit.. me,-han. i rasch(-t
sooruzh,, 1961, no, 1, 7-14)
TEXT: The calculation is made of a sloping roof as a system of
convex, zero-moment shells with diaphragms attached alon.- the
lines of contact and absolutely rigid in their pl:ines,, Two cases
of uniformly loaded roof are considered, one with load uniform
over the whole surface, and the other with the load on one middle
unit. Poisson's coefficient is assumed to be equal to zero,
Formulas for stresses satisfying the basic equations of the prob-
;'er
lem and boundary and contact conditions are based on the earL-
work (Stroit. mekhan. i raschet sooruzh., 1959, no, 6, 1-9-
Card 1/2
1~1
S/124/62/000/r-01/0,76/046
Calculating multimembered- D237/D304
RZhMekh, 1960, no. 12, 16581). Expressions for stresBer, givf- the
geometrical relations of the shell in the plane for Y.Kich this
shell can be considered as isolated. The solution is ~-iven ~cr
two cases of supporting the shell with a rectang,.ilar ,,,Iane.
Limits are determined of applicability of the zero-momentum theory
for calculating a sloping transfer shell., Z-Abstractei-s nutei
Complete translation.-7
Card 212
NIKIREYEV, V.H,
Conference on three-dimensional prE-caat relnfor~:er, c)n(,rf-.tp
elements. Stroi.mekh.1 rasch.aoor. 5 no.2's"+'9 163.
(MIRA 16.-t-,)
(Prpcaflt ronrr,~te-Gorvr-sqA8)
ffilrMHOVA, YO.T., vrach-ekspert
Importance of come hemodymmic indexes for disability evaluation
of patients with brouchleotasts. Trudy LINTIN 200-96 159.
(KIRA 13:7)
(DISABILITY EVALUATION) (BRONCHIRCTABIS) (BLOOD- -rnWULATIOW)
!" , 1, ,, F5.- 'F , , i~4~
Eh -3 ,1 ~ " z -, - : - - , , r - ~ . , a "
i I I
1) 4~ -'b~'~ , I I ~( .1. , , - ' I
t U." . n' c , .
5-i'D4 / BO 56
A7TH,`__-RS: Mardaleyshvili, R. Ye., Pcpov, A. G., Nikisha, V. V., and
Yakushin, F. S.
T'TLE: On Two Types of Elementary Reaction_~ in the Calalyt,_c
Hydrogenatior. of Olefinlz
P ?II--DIC" L: Doklady Akademii n-,jr -:',-3R, Vol .
T '--'X T A paper by N. N, Semenov, V. V. Voyevoiskiy, and F - F. V~_.! -ensh
( Re f 1 )' Eave ri s e to t he r - es en t invt~ - t i gL: t i .7 n. In t he former it was
assumed that the free valences upon solid 5urfaces lead to the formation
of so-called surface radicals. These, c;iu~~e hetero--eneous cataly3is. The
autl;ors comnleted th~'-, assumption by acsumin,.- format ion twrj ty~'c-s 3f
radicals: ",,H + 2cat' - IIH CH + cat"-z
4 2-
cat (a) (I., it ct
CH ~14 +- CH~,-CH, CH 'h Ti,e r;i 1 i s
2 2
cat cat cat 't)
cataly:it (cat) by two olectron:t, tho (1), by
Card 1/~
~n Two Ty~-es of Elementary Reaction~, in tL,-: S/)2C,/(1
Catalytic Hydrogenation ~f Olefins B,004 //K z5 6
The latter. recombine -.,;it,. hydro6er accDrd~ n., to the scrier,,.e
+ C R + 2cat' (5). However, ~~ 13 4s p ro por (,~n i e
C F-C,1,A 2
cat cat
should occur besides the processes irentioned, -If tne assum~tlcn Gf surfhce
radicals is correct: CH -CH + CH - CH --* CH CH, i CH=CF (4);
1 2 2 12 2 1 2 1 2
cat. cat cat cat
CH -H.4 + ~H CH -> CH CB + I
* 2- , 2- 3 1 2- 2 2H6 I c~-t, (5);
9at at cat
CH -CH.Z,+ CH -CH --4 CH=CH + C H6 + cat* 3r. hydrogenat,---n rf a
1 2 1 2 2 1 2 2
Cat cat 3at
mixture of two olefins, such a disproport'.6nation would lead to Products
which do not occur in the case of separate hydrogenation Gf a single oiel~r,:
CH 3- 6H-CH2 + 6H 2- CH 2---> CH 2= CH-CH2+ CH 3- CH 2 (7). On these ccnditiona
cat cat cat cat
the following predicti-ns are made: 1) In the case of joint hydrogenat~cr,
of ethylene and propylene, the ratio w -42 /W 2/4 cf the initial reqction rates
Card 216
On Two Types of Elementary Reactions in tLe
Catalytic Hydrogenation of Olf!fins B,,4/BOrj6
will be smaller than w,/w, (ratio of the initial rates in the case Df
separate hydrogenation of the tAo olefins). 2) The difftrence tetwe-r
and w,/w 2 will decrease with Jrcreasing hydroger, pr,,ssurt- beca,;-ge
71 /W;)
lien recombination f' t1it, i-,irface radicais witi. hydirogen htoms W.11 bt,, the
t
chief process. 3~ Th,2 greatest difference between w ana w 2 must
2/w2, 5/ 'IV I
b e obi e rve d a t I ow t orripe r fi t a res , a t -w h i c h c; I e fi n c: o ric e n t ra t i (,) n o n t he
ca talys t 10 iA gher than i n t lima of hj gh t-)mF,,- rutu - -,i , and t hi~re Forp
'he portion 3f disproportions will :n,:re~ise, in order to check these
assumptions, J-,int hydrogenate )n of ethylene and propylene was carried
out in a circulation device with electrically heated platinum wire a8
catalyst. Reaction was studied by means of a preosure-gauge (measurement
of pressure variat-~ons in the systerrij and mas--spectroscopic analvsis of
the reaction products. The exerimtnti wer, performed at 52' mrn Hg, a
ratio of olefins: hydrogen = 1 ; I tc I : 2,), in the t~mperaturo r.--InKe cf
r, - "800C. The ro:3ults ar.: prenvn~ted in Ttible 1. Thvy confirm the aasump-
tions and predicti n made by the, autl-,rs- Tw,~ typ,.-s of
on olefin hydroLienati-)n, namely -nJ
C~Ird 4111~(
On Two I
.y~ es of Elem;~ntury React: -~r. tt,e
k~ a t a I y t i c H y d r o E~ e r. a t : o nri.,j
Besides, --e results may be '.ker. a Froof cf
molecule;~. There Lire .' f,.6ures,It n t 7, 1
P TU S ,~ British, anLi1 J ~D-- sf-
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y gusudarstvk~nnyy
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Y 7
M. V. L,mor--s-.v~
july 14, :96' uy N. N
SUBMITTED: Tu 1 r)
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Card 416'
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Card 5/6
BC04/BO56
Legend to Table 1. 1) Number of the experiment; 2) torr; 3) torr/min.
Card 6/6
S/137/6 1/000/0 12/037/149
AOC6/A 10 1
AUTHORBi Yevetyukhin, A.I., Leontyev, G.A., N:~ Lnov
_ki~aha V.V.
TITLEi Arc melting of refra(itory metals and alloys under laboratory con-
ditions
PERIODICAL: Referativnyy zhurnal. Metallurglya, no. 12, 1961, 19, abstract
120137 (V St. "Metallurgiya I metalloved. chist. metallov", no. 1,
Moscow, 1959, 106 - 121)
TEXTj The authors describe the design of a laboratory arc-melting furnace,
suitable for remelting Zr and the production of its alloys. in this furnace it
is possible to perfom melting with both consumable and non-consumable electrodes,
on a-o or d-c (the latter Is preferable because of the arc stability in this
case). An inspection of the meqhanioal properties of Zr and Cr specimens pro-
duced showed very slight contamination of the metal during melting 'up to 0 01% W
and 0.03% Cu). The furnaoe is equipped with a hermetic melting chamber with a
water-cooled Cu-crucible. A power connection with a non-consumable tungsten
electrode is top supplied to the chamber; Its motion does not disturb the herme-
tioity of the chamber. The crucible has exchangeable bottoms to obtain different
Card 1/2
3/137/61/000/G12/0,37/149
Are melting of refractory metals ... A006/AlOl
;hapes of castings. Cooling of the chamber conductor and crAcible Is regulated.
The displacement of remelted metal during melting with a non-~'onsumable electrode
is carried out with the aid of manipulators. The are ignition Is performed with
the aid of a spark generator. A table is preaented showing the duration of
melting depending on the weight and shape of the specimen; the order Cf the
melting process is described; means of absorbing the gases, liberating inside
the chamber, are analyzed.
L- Povedskaya
[Abstracter's note: Complete translation]
Card 2/2
GRUZIR, P.L.; TVSTYUIHDi. A.1.; ZZKSKIT. S.V.; lj~IZISHOOW..T.T.
Investigating the redistribution of sulfur during the zonal
malting of chromium In are furnaces. Ket. I metalloved.
chist. met. no. 2:276-279 160. (MMA 13:12)
(Chroniuw-Metallography) (Suflur--Isotopes)
3/137/62/ooo/oo6/050/163
Aoo6/Aic)l
AUTHORS: Yevstyukhin, A. I., Nikishanov, V. V. Milov, I. V.
TITLE: Niobium zone melting by the ar- method
PERIODICAL: Referativnyy zhurnal, Metallurgiya, nc~ 3, 1962, 17, abstract 6G133
(In collection: "Metallurglya I metail.,)vt~d. chist.metallov", no. 3,
Moscow, Gosatomizdat, 1961, 152 - 162)
TEXT: A unit was designed and tested, intended for zone melting of re-
fractory metals by the elecLric-arc method, Zone meiting was carried out with
specimens, 230 mm long, and 15 mm in diameter; the zone width was 20 mm. The
speed of the zone motion was 0.5 mm/sec for all the specimens. The number of
zone passes was different and equal to 16, 32, 32, 64 and 128 passes respectively.
A chemical analysis of the specimens subjected to zone melting at 0.5 mm/sec zone
motion speed shows that there is no substantial refining of Nb from Si, TI, Fe.
Pb admixtures were concentrated after refining Ln the end section. The refining
effect Increased with a greater number of passe5 The coefficient of C distri-
bution in Nb is more than one, I. e. C is concentrated in the initial portion
Card 112
Nlob"um zone melting by the arc method
3/137/62/000/006/050/163
Aoo6/Aioi
i.,' --ne ingo*. -*Lr-i moves opposite to the zorie mo!~.'or- There are 7 references.
G. Svodtseva
LAbstracter's note
Complete transla Ion]
Card 212
S/137/62/ooo/oo6/ol7/i63
Aoo6/Aioi
AOTHORS; Yevstyukhin, A. I., Milov, I. V., Nikishanov, V. V,
T"TLE- Electron-beam method of metal melting and refining
PERIODICAL: Referativnyy zhurnal, Metallurglya, no. 6, 1,)62, 1, abstract bW
(In collection: "metallurglya i metalloved. chist. metallov", no.
Moscow, Gosatomizdat, ig6i, 249 - 263)
TEXT: The authors review the principles of developing and desIgning of
.inits with electron-beam heating, used for melting, zonal refining of refracl~cry
m-tals and welding pure metals. The difficulties are pointed out which are en-
rc,untered in the way of development of this method.
G. Svodtseva
LAbsti-acter's note: Complete translation]
-/b 3/0151027
S/M/61 00 0
~ov
;AIJ.THOR$,t;,Y Ir-MA
.1h .zone
am
k V at all,ova
~FPY4-~ -rl~!
a-
As' of t
,:, .. ~j~j
- -,~ - -4t ll~~ '... ".. nAIRWA-It
~~-M ... "1,.---- 2 ~
s/lBo/62/000/003/013/ol6
E071/E192
AUTHORS: Yevstyukhin, A.I., Nikishanov, V,.-V.. and Milov, Z.V.
(Moscow)
TITLE: Redistribution of carbon and tungsten in niobium
during zone refining
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye
tekhnicheskikh nauk. Metallurgiya i toplivo,
no.3, 1962, 98-101
TEXT: Commercial niobium was zone refined in a 500 amp
arc discharge working closely to its transition into glow
discharge by operating at low helium pressures aknd imposing a
coaxial constant magnetic field, shifting a 15 mm long-molten
zone at a constant velocity of 0.75 mm/min- Into one niobitm
ingot with the initial carbon content of 0.03%, 0.005% 0 Cl and
into another with tungsten content of 0.03%, 0.01% of W192 were
introduced to follow the zone refining. The isotopes were .
introduced into a few holes uniformly distributed along the length
of the ingots and plugged with N b. Uniform diffusion was
Cara 1/3
Redistribution of carbon and tungsten.. S/180/62/000/003/013/ol6
E071/EI92
indicating that carbon has a smaller influence on the hardness of
niobium than other admixtures which concentrate at the beginning
of the ingot. It is concluded that the C and W content in
commercial grade Nb can be considerably reduced by zone refining.
There are 2 figures.
SUBMITTED: September 23, 1961
Card 3/3
YEVST'fUKHIN, A.I.; NIKISHANOV, V.V.; MILOV, I.V.
Zonal refining of niobium by the electric arc method. Iasi. po
zharopr. splav. 9:218-226 162. (MIRA 16:6)
(Niobium-Electrometallurgy) (Zone melti")
ACCESSION NR: AT4005961 S/2755/63/000/004/0069/0083
AUTHOR: Yevatyukhin, A. I., Nikishanov, V. V., Milov, 1. V.
TITLE: Distribution of impurities In zone refined niobium
SOURCE: Moscow. Inzhenerno-fizicheskiy institut. Metallurglya I metallovedeniye chisty*
kh metallov, no. 4, 1963, 69-83
TOPIC T AGS: niobium zone refining, niobium zone melting, niobium impurity, impurity
distribution, impurity transfer, Impurity accumulation, impurity elimination, niobitim
zone melting, zone refined niobium, high impurity niobiurn
ABSTRACT: Following a brief discussion of the theoretical basis of zone refining, In
which the authors classify the impuriLien in Nb un the haida of their tiolubillty pi-oportlon
and point out that W tihould move in the opposite direction from C, Fo and 1%, they report
experiments in which the distribution of C14, FeW W182 and nonradioactive Ph was
detel-mined in bars of commercially pure niobiurn (230 mm long and weighing 150 g)
after zone recrystallization in an electric are furnace (500 amps, , 24. 5 volts). The bars
were smelted in a helium atmosphere in Cu crucibles, with a zone length of 25 mm arad a
rate of 0. 75 mrn/mIn. (also 30 mm/min, for Pb). The results shown in Figs. 1-4 of the
- - 1 1/6
ACCESSION NR: AT4005961
Enclosure confirmed the theoretical expectations and revealed good agreement between
the radioactive and chemical tecimiques. Thus, tho distribution coefficients of C, Fe and
Pb were less than 1. 0, while that of W was greater than 1. 0; the concentraLion gradients
between the bcKinning and end of the refined bar wore 1:8 for C (best purification in zone
3-4). 1:5 for Fe and 1-11), ruid 3. 1-4. 65:1 for W (Accumulation of W in the bottom of the
bar). Due to the high solubility of Pb in Nb, evaporation plays a significant role here,
this being the reason why purification is more effective at 0. 75 than at 30 mm/min. Orig.
art. has: 7 tables and 8 figures.
ASSOCIA71ON: Inzhonerno-fizicheakiy institut, Moscow (Institute of physics and
En&eoring)
SUBMITTED: 00
SUB CODE: M-M
DATE ACQ: 17Jan64 ENCL: 04
NO REF SOV: 013 OTHER: 020
-2/6
ror-1.
ACCESSION NR: AT4005968 S/2755/63/000/004/0175/0181
AUTHORs Milov, 1. V.; Skorov, D. M.; Nikishanov, Ve V.
TITLE: Mechanical properties of zone refined beryllium
SOURCE: Moscow. Inzhenerno-fizicheskiy institut. Metallurgiya i metallo-
vedeniye chisty*kh metallov, no. 4, 1963, 175-181
TOPIC TAGS: beryllium zone refining, beryllium property, beryllium micrcp-
hardness, beryllium ductility, high purity beryllium, zone refined beryllium
beryllium zone melting, beryllium purification, beryllium mechanical property
beryllium
ABSTRACT: Wide application of beryllium as a structural material is limited-
because of its brittleness at room temperature. There are several techniques
currently being tested for the production of plastic berylliumi
(1) hot working of ingots, aimed at a certain orientation of
crystallites;
(2) alloying, aimed at fixation of the bets phase having a cubic
1/4 lattice;
Card
ACCESSION NR: AT4005968
(3) grain refinement to 25 microns by powder-metallurgy processes;
(4) purification by distillation, thermal decomposition of halides, I
and zone recrystallization. i
Beryllium ingots were zone refined in a water-cooled copper crucible by the inert
gas electric are method, applying a zone propagation velocity of 0.75'mm/min. A
columnar growth of grkin3 was observed directly from the bottom and walls of the
cooled crucible toward its axis and bending in the direction of the path of zone
propagation. The length of the obtained grains reached 40-45 mm at a cross sec-
tion of 2x3 mm. X-ray evidence did not disclose a clearly defined crystallogra-
phic orientation. Hicro-hardness measurements, conducted at surfaces cut at
right angles to the ingot axis, revealed that micro-hardness increases Plong the
ingot in the direction of applied zone propagation. On the basis of nAcro-hard--'
i ness measurements and crystallographic evidence, it was concluded that the basal
plane, with smail deviations, is oriented in the ingot at right angles to the
i direction of grain growth. This conclusion also confirmed the results of X-ray
investigations.
2/4
card
ACCESSION NR: AT4005968
Specimens for compression teats, 7mm in diameter x 9mm long, were prepared
from different regions of the zone refined ingots, choosing for the specimens a
similar grain orientation. Beryllium plasticity is strongly dependent on pre-
ferred grain orientation and grain size. Basal planes (0001) in the,test ape-
cimens were inclined approximately 50' with respect to their axes. Prepared
specimens were compression tested on the recording type testing machine
(TsNIITMASh-1) with a capacity of 4000 kg. The stress-strain curves obtained
were similar to compression curves of plastic metals. The following mechanical
properties were determined by compression testing of specimens taken from dif-
ferent locations along the ingot, and from ingots subjected to different numbers
of zone refining passes: ultimate compressive strength, ultimate longitudinal-
strain, yield strength, longitudinal strain at yield stress. Specimens which
have been cut from the zone-travel-starting-end, exhibited the greatest strength
and ductility. The zone-travel-starting-end contained beryllium of higher pur-
ity, and the impurities migrated in the direction of zone propagation. It was
concluded that strength and ductility of beryllium decreased with an increase
of impurities content. It was observed that some of the failed test specimens
vere sbwevhat twisted around their axis. Difficulties arose in the investi-
gations of deformation and plastic properties of polycrystalline beryllium when
directions of grain grovth during recrystallization were curvilinear in the
C,,d 3/4
ACCESSION NR: AT4005968
ingot. Investigation of the deformation mechanism on specimens exhibiting a
normal grain growth was suggested. Orig. art. has: 4 figures and 1 table.
ASSOCIATION: Inzhenerno fizicheskiy institut, Moscow (Engineering .- Physics
Institute)
SUBHIWED: 00
SUB CODE: M MTC
DATE ACQ: 17Jan64 ENCL-. 00
NO REF SOV: 004 OTM: 004
Card 4/4
18(4)
AUTHORS; Sharov, M. V., flikishayeva, 0. 1. SOV/1611-59-1-1~'/"_~G
TITLE: Degassing of Aluminum-Silicon Melts With the Help of Fluxing
Agents (Degazatsiya alyuminiymkremniyevykh splavov pri
pomoshchi flYU80V)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Metallargiya, 1959, Nr
PP 58-62 (USSR)
ABSTRACT: This is an examination of the oportUnities of using de--a.-sin-
fluxing agents in pot furnaces and in radiation furnaces
intended for the meltin- of cast iron alloys. The res-lts
were also checked under operation conditions. The experiments
were conducted with the alloy AL-1OV, which is widely used
in piston production. At the begi3ning of each experiment
hydrogen at a rate of 0.8 - 0.9 cm /100 -a was introduced into
the melt. The hydrogen content was measured with an instrument
developed by A. P. Gudchenko. Three fluxing a~ent3 were
investigatedi Nr 1, with 47,.. of KCI + 3011- of NaCl + 2.', of
Na AlF Nr 2, with 50',-, of KC1 + 10,,5', of NaCl + Ti~ of Na Al:'t,
3 61 3
+ 3~'~ NaF, and Nr 3 with K2ZrF 6' The method ai~.lied in ~h-
Card 1/3 experiments and that ap7ilied in the tests on a procaction
Degassing of Aluminum-Silicon Melts With the Help SOV/163-59-1-13/50
of Fluxing Agents
scale are described. The experiments lead to the following
conclusionss 1) If the alloy AL-10V in a liquid state is
treated with the fluxing agents in question degassing proceeds
to a sufficient degree if the melting is done in pot furnaces,
The fluxing agents Nr 1 or 2 are added in a quantity of 0.2A
of the alloy weight. The total time required for the treat-
ment with the fluxing agents depends on the depth af the
bath and is 2-3 hours on the average. 2) For the production
of steel free from blowholes a treatment of the melt with
potassium fluozirconate is very effective. The treatment
can be timited to a time of 5-7 minutes. 3) If the metal is
melted in radiation furnaces with continuous charging, the
use of the fluxing agents Nr 1 and 2 leads to a reduction
of the hydrogen content in the melt. This reduction is but
smaller than if melting is done in pot furnaces. 4) A treat-
ment of the melt with potassium fluozirconate reduces the
gas content of the melt by a factor of 2. If degassing is
carried out with potassium fluozirconate this salt is added
in a quantity of 0-4-0-5~L of the melt weight and is ke8t at
Card 2/5 the surface of the bath for 10 - 15 minutes at 730-780 -
Degassing of Aluminum-Silicon Melts With the Help
of Fluxing Agents
ASSOCIATION:
SUBMITTED:
Afterwarda the melt is mixed through.
fluxing agents Nr 1 and 3 are used as a
be replaced at least every hour. There
tables, and 1 Soviet reference.
SOV/167-59-1-13/5~,
In this case the
blanket which must
are 2 figures, 2
Moskovskiy aviatsionnyy tekhnologicheskiy institut (Moscow
Aviation Technology Institute)
Dece.,,ber 10, 1957
Card 3/3
E5835
1 S,5000A 2 5- 0 9 S/536/61/000/049/003/003
10~1~ E021/E435
AUTHORS: Sharov, M.V., Candidate of Technical Sciences
Nikishayeva , 0, 1,
TITLE. -6e8assing of aluminium alloys by hexa~,hlorethane
PERIODICAL. Moscow, Aviatsionnyy teklinologicheskiy institut.
Trudy, No.49. 1961, pp.47-72. Voprosy tekhnologii
liteynogo proizvodstva
TEXT: The disadvantages of using chlorine and chlorides for
degassing aluminium melts are discussed and the use is recommended
of hexachlorethane which is readily available and inexpensive in
relation to manganese chloride. Experiments on the degassing
ability of hexachlorethane have been carried out on alloys A312
(AL2) and A119 (AL9)~ Melts of 5.5 kg were prepared in a graphite
crucible Gas contents were measured by the method due to
A.P.Gudchenko (M.V.Sharov, A.P.Gudchenko, Fundamental metallurgy of
light alloys, P-306, Collection of Papers, Oborongiz 1957). The
hydrogen content before degassing was 0.75 to 0.9 cmi/100 g metal, VX
This was obtained by addition of moist asbestos wads, Samples
50 mm in diameter were bast and plates 3 mm thick were cut from
them for radiographic examination, Experiments on AL2 alloy were
Card 1/10
258 '125
3/536/61/looo/o49/003/003
Degassing of aluminium alloys E021/E435
carried out at 700 to 7100C. F19.3 shows the change in hydrogen
7ontent (H2 in -m3/loo g of metai) with increase in quantity of
hexar-hlorethane (%), the analysis being carried out 10 to 15 min
afl-er degassing. Radiographic investigations showed that sound
castings were obtained with 0.2 to 0.25% hexa--hlorethane.
Experiments showed also that sound sand -castings of modified AL2
allay :could also be obtained if the alloy was first degassed, It
was shown that temperature, in the range 700 to 750*C, had no
effect on the soundness of AL2 castings, Table 2 shows the
effect of degassing time on the hydrogen content by adding a number
of portions of hexachlorethane over a period of time using a
constant total amount, The best results were obtained when each
portion was less than 25 to 30% of the total added. Table 3
shows that hexachlorethane is a more efficient degassing agent
than manganese chloride, Radiographs of AL2 alloy after
degassing with 0.1% hexachlorethane, or with 0.1% manganese chloride,
are reproduced in the paper. Degassing of AL2 alloy was tried
under production conditions. It was shown that degassing by
hexachlorethane was advantageous both from porosity checks and tests
of me:hanical properties. Experiments on AL9 alloy showed that the
Card 2/ 10
25835 S/536/61/000/049/003/003
Degassing of aluminium alloys Ed2l/E435
hydrogen content (in Zm3/loo g metal) decreased with increase in
addition of hexachlorethane (11.), Fig-7. To produce sound castings
0.7 to 0.75,'0 hexachlorethane was required. Table 6 shows the
effect of increasin.- the degassing time by increasing the number of
portions added, using the same total qua'ntity of degaqsing agent.
The best results were obtained when each portion was less than 20%
of the total amount. Table 7 shows that for AL9 alloy, with
increase in melt temperature there is a decrease in hydrogen
content. Experiments on modified AL9 alloy showed that it was
practically impossible to obtain sound castings. Tests under
production conditions showed that a lower porosity and higher
mechanical properties were obtained when hexachlorethane was used
as a degassing agent for AL9 alloys. Acknowledgments are
expressed to Ye.L.Bibikov, B.A.Tikhomirov and N..M.Galdin for
assistance in tests. IM.F.Nilritina is mentioned in the paper for
her contribution in the field. There are 11 figures, 12 tables
and 11 references: 9 Soviet and 2 non-Soviet. The two
references to English language publications read as follows:
W.Mannchen, W.Fisher, Metal, 1953, No.6.
Herrman, Aluminium archiv, 1937, No.6.
Card 3/10
'~j I c-0 S/806/62/000/003/013/018
A~-T
12RS: Sharov, M. V., Nikisha5Lgy&.~I.
't . -
TVrLE: Modern methods for the elimination of gaseous porosity in aluminurn-
silicon-alloy castings.
S QURCE: Akademiya nauk SSSR. Institut metallurgii. Issledovaniye splavov
tovetnykh metallov. na.3, 1962, 149-162.
TEXT: The paper describes an investigation of the diffusional elimination of H
fram a melt, the degassing by means of special fluxes (a relatively slow process),
az*~he more effective degassing of Al alloys by rneans of blowing gases (Cl, N, Ar,
or tie) through the melt. Of the latter, Cl is the most effective but is little used be-
camse of its toxicity. Chlorides (of Mn, Zn, and Al) are effective and nontoxic, but
a~e highly hygroscopic and, hence, require prolonged drying and protection during
st6rage. Hexachloroethane (carbon trichloride (C2Cl appears to be effective and
n6nhygroscopic. At melt temperature the following rtaction appears to occur:
3C Cl' + ZAl = ZC Cl + ZAlCI . Both the tetrachloroethylene and the AlCl remain
. Z 6 4 3 3
in vapor form an articipate in the degassing process. The losses in Al are rela-
tively small. Thh 2GI6 does not require preliminary dehydration, nor does it re-
quire any special protection in storage, and is readily and inexpensively available.
Comparisons with MnCl are given in each instance. Tests were made with the
Al-St alloys AA 2 (ALZ),? AL 4, and AL9 in graphite crucibles (rnean charge: 5.5 kg).
The initial H content was near the maximum observed in industrial conditions.
Card IIZ
SHA.ROVf M.V.; NIIKI SHA YEVA,--9, I -
Degassing aluminum alloys by hexachloroethane. Ali=. splavy
no.1:129-138 163. (MIRA 16:11)
L .296834� EWP(J)/EVIT( I )/ENT (m)/RP(t)/ET I1JP(G) RM/JD
ACC N" AT6011848 SOURCE COD& UR/2536/65/000/063/0045/W6l
AUTHORS% !Ukia�Weval, 0. L (Candidate of toohnical sciences); RMOTO M. V,
(Profesuorij, 'v 50, (Engineer)
ORG: Moscow Aviation Technology Institute Uoskovakiy aviatsionnyy tei"~logicheskiy
inatitut)
TITLE: Coatings for surfaces of-casting jaolds for aluminum-siliGon ealoys
1% -0 T 1
SOURCEs Moscow. Aviatsionnyy tekhnolbechookiy instituto Trudyp no* 63# 1965-
Proizvodstvo otlivok iz legkikh aplavov (Production of castings fron light alloys)o
45-61
TOPIC TAGSt aluminum alloy, silicon alloy, metal casting/ AL2 aluminum alloy, A19
aluminum alloy
V
ABSTRACT: The affect of coatirj the surfaces of casting molds with carbon black,
M-F
hexachloroetbane, and hexa. oroVenzene on the properties of the melt and the quaslity
The results supplement the investiga'-
of aluminum-~silioon castings iras investigated.
tions of G. F. Balanding Yu. A. Stepanov, et al (Liteynoye proizvodstvo, 1961, No. 8).
The experiments were carried out on alloys AL2 and AL9#-with the chlorinated IWdro-
carbons being applied to the surfaces with an atomizer in the form of a 24 acetone
solution. The carbon black was deposited with an acetylene gas burner. The experi-
mental procedure followed is described by K. V. Sharov and 0. 1. Nikishayeva (Trudy
C,,d_1/2 UDCs 669.7.161001-5
L 29683-66
ACC NRs AT6011848
vYP- 43, Oborongiz, 1961 ), and the experimental results are sil"Mo ized in phs'
MATIj gra
and tables (see Fig. 1).
Fig. 1. Influence of the temperature of
melt on the fluid-flow of AL2 and AL9
alloys when cast into a mold coated with
carbon black and hexachloroethane. Open
circle, dash, dot, dash, open circle - 0:
0
alloy AL2; cross, dash, dash, dash, cross - 4
alloy LL9; open circle, dash, open circle -
10
no coating, cast temperature 70OC; cross,
dash, dash, dash, no coating, cast
temperature 710C- 4-4
.1116ar bon black
AV
1.
e
L
.4
We $0 &V MO 7W M
Temperature of casting in C
The use of carbon black or hexachloroethane coatings considerably improves the degree
of mold filling, permits lowering of the casting temperature, increases the dqnsity of,
castings, and prevents the formation of hot cracks in the castings. Coating of molds
with hexachlorobenzene had little or no effect either on the properties of the alloy
melt or the quality of the castings. P. F. Od participated in the experimental
work. Orig. art. has: 12 tables and 9 figures.
SUB CODEs 11/ SUBM DATE: none/ ORIG REPs 004/ OTH REFt 004
Card 2/2
KREMNEV, L.Ya.; NIKISRECHKINA, L.A.; RAVDELI, A.A.
Stability of emulsions. DoV1. Ali SSSR 152 nr;.2s372-3?4 3 16-A
(MIRA 16:1
'i)
1. Leningradskiy tekhnologicheskiy institut im. Lensoveta.
Predstavleno Akademikom P.A. Rebinderom.
SIXISHIM, A.A. (KIYev, ul. ChelyuAkintsev. D.6. kv.8)
Lar-USTMm"T-lon of the large intestine as sequel of subovicaus
lipom. TestAhir. 78 no.3:114 Mr '57. (KIRA 10-6)
1. Is 2-y kafedry khirurgil (sav. - prof. I.I.Kallchanko) Kiyevalcogo
institute, usovershoustvovaniya vrachey.
(INTUSSUBC M ION. stiol. & pathogen.
large intestine caused by submucous lipoma (RVs))
(LIPOM. compl.
submwous lipoma causing Intussusception of large
Intestine (Rua))
:FIXISHENKD, ,,,(Xiyev. u. Oktyabrlakoy revolyutaii. d.16, kv.5)
,V,T,5~~ --
PRthogenesis of Dleuropulmo-, y shock; ex-nerimental investigation.
liov.khir.arkh. no.2:32-140 Kr-Ap 158 NMA 11:6)
1. Knfecira khirurgii (zav. prof. B.Ye Pankratlyev) i kafedra
patoloiricheakoy fiziologil (zav. - prof. R.Ye. Kavetskiy) Klyevskogo
instituta usovershenstvovaniya vrnchey.
(SHOCK)
NIKISMKO, A. A. Cand Med Sci - (diss) "Experimental data on the
pleuropulmonary shock and its prophylsods," Kiev, 1960, 15 PP, 150 cop.
(Department of Biological Sciences AS UkSSR) (KL, 44-60, 132)
MIKISHENKC), A.A. (Kiyev, u.I.Oktyabrlskoy revolyutsii, d.16, ;rv.,))
Two caaes of benign nonepithelial gastric tt=rs. Nmi. ar?-n.
no.2:11&-119 Hr-Ap 160. (Ml -A W12)
1. Kafedra khirurgii II (zav. - Prof. I.I.Kallchenko) Kiyevsko~-,i-
instituta usovorslienstvovaniya vrachey.
(STCMACH--TUMOI-S)
NMSHMO.--A.A.
bwagination of the stomach due to a submucous neurinom.
lbirurgiia 36 no.81125 Ag 160. (KIRA 1311l)
1. 1z kafedry khirurgii (zav. - prof. D.F. Skripinchemko) Kiyev-
skogo instituta usovershenst7ovaniya vraohe7.
(STCMACH-TUMORS)
IWKO, A.A. -(Kiyev,, u1. Octyabrlskoy revolyutaii, d.36.kv.5)
Maltiple liver abscesses caured by ascariasis. Yest.khir. 85
no.3-ltl25-127 N 160. (KMA 14:2)
1. 1z 2-y kafedry khirurgii (zav. - prof. I.I. Kallahenko) Kiyev-
okogo instituta usovershenstvovaniya vrachey.
(LIVM-ABSCM) (ASCARIDS AND ASCARIASIS)
NIKISHFINKO, A.A.
Clinical aopects and troatmont of gastric tetany. Vrach.
delo no.2:35--37 F 162. (K-7,V% 1 '/ - 3')
1. Kafedra khirurgii 11 (zav. - prof. I.I. Kallchanko)
Kiyevskogo iw9tituta usovershenstvovaniye vrachey.
(TETANY)
(STOMACII-.-DISWES)
SUKHOV, Vladimir Iveno-vich, professor doirtor tekhnicheakikh asuk; YUROVSKIT,
Ta.l., doteentlkandidat takhnicheskikh nauk; LIODT, G.S.. professor,
dolctor geograficheakikh nauk [deceased); NIXISHL.-H".. starshiy
nauchnyy sotrudnik, kandidat geograficheaVikh nauk; OZEROV, V.N.,
redaktor; SOKOLOVA. N.N., tekhnichaskiy redaktor
[Compiling agricultural maps] Sostavlania sell skokhoz ia istvenrqkh
kart. Pod red. V.I.Sukhova. Moak-va, Gos.izd-vo sel'Ichoz.lit-r7,
1957. 263 P. (KLRA 10:9)
(Agriculture--Maps)
NIKISHICHEV.9 V.N.; SINITSYN, R.V.
Colloquium on the de-gign and use >I oetatrons. Atom. energ. "
(1,
no.0:596-597 Je 16". JRA
(Betatron)
ACCESSION NR: AT4011453 S/3065/63/000/0"/0103/0118
AUTHOR: Nikishin, A. A.
TITLE: Analysis of various methods for calculating the bending stress in sandwich
plates and comparison with experimental results
SOURCE: Moscow. inzhenerno-stroltelIny*y institut. (Trudy*), no. 44, 1963.
Sterzhni I plastinki, 103-118
TOPIC TAGS: elasticity modulus, sandwich plate, sandwich panel, filler, deflection,
bending stress, foam plastic, elastic deformation
ABSTRACT: In sandwich plates, the thin, strong outer layers are connected by a
relatively weak filler which guarantees joint operation ard durability of the en-
tire panel. The stress in such plates is usually calculated by one of six different
methods, varying in their degree of simplification. In the present paper, the
values of stress and displacement for various segments of a sandwich plate are cal-
culated by these different methods and compared both with each other and with the
experimental results obtained at the Laboratoriya armirovannylckh plastikov IKhF
AN SSSR (Reinforced Plastics Laboratory) with a 350 x 155 x 77.8 mm panel made of
KAST-V glass-textolite and reinforced foam plastic. The results of these calcula-
tirsl/qPow that the main stresses in a sandwich panel and the nature of the stress-
Car.
ACCESSION NR: AT40111453
ed state in the filler depend on two principal parameters: (51 (the relative
rigidity of the filler compared to that of the outer layer) and & 2 (the re-
lative rigidity of the filler compared to that of a hollow beam. Whe;1 & 2 is
greater than 3500, the deflections calculated by the various methods differ on;y
slightly. With smaller values of 02, however, the deflections can best be cal-
culated by the method which assumes that Exx (the modulus of longitudinal elasti-
city of the anisotropic filler) = 0. This method is also applicable to the
estimation of the distribution of normal and oblique stress through the depth of
the filler, as well as the maximal stress and the distribution ot stress along
the length of the filler. The approximate values of the normal stresses in the
outer layer during elastic deformation can be determined by the usual formulas
for the resistance in a hollow beam, over a wide range of values of G, and &2'
Although the stressed state in the filler can thus be described by a method
which assumes that Em = 0, the elastic deformation in the outer layer should be
taken into consideration when determining the carrying capacity of a sandwich
panel under prolonged stress. Orig. art. has: 7 figures, 15 formulas and I
table.
ASSOCIATION: Inzhenerno-stroltel"ny*y Institut, Moscow (Institute of Construction
Engineering)
Card 2/3
ACCESSION NR: AT401l453
SUBMITTED: Oa DATE ACQ: 23Jan64 ENCL: 00
SUB CODE: AS, MT NO REF SOV: 010 OTHER: 003
It
! C.,d 3/3
-L 19563-6i EPWkPF(C)/EWP(J)/EWT(m)/BDS AFFTq/ASD p..4/1,,..4qc_4
. PJ4/VW&AY
ACCE~f= NR: AP3004338 -S/Odi8/63/000/007/0028/0032
.'AMEQR: Wildshina'Ao Ae
TITLS: Methods of determIning hyperelastio deformation parameters
of oriented fiberglass
SOURCE: Standartizatsi7ag no. 7# 1963& 28-32
TOPIC TAGS: oriented f1berglass,, hyperelastic deformation, parameter,
Maxwell's equationo compressiont tension, relaxed deformation,
SUM fiberglass
ABSTFiACT: Samples of oriented fiberglass of the SVAM type with a
BF-4\~binder\.twere used in this study. The samplas-were7 tested for
st-a-Fifi-ty of properties and the insoluble part of the binder was
.determined by the extraction method. Maxwell's equation generalized
:for the case of an anisotropic body was used to describe the various
Iload conditions for,oriented fiberglass. The hyperelas 'tic deformation-
modulus,, the logarithmic speed modulus, and the coefficient of
,initiAlIvisoosity were determined experimentally by deformation
relaxation after removal of compression. A special piston type
Card 2/2
L 19563-63
ACCESSION
device with an electronio deformation motor (EM) and an oscillator
imeasured deformatio4 relaxation. The *fter-offoot curve was
irecorded after unloading. Hyperelastic,deformaiion for tension can
ibe measured similarly. The other parame tore can be found by
isubstituting the experimental parameters in the after-effect equation
,based on a generailied form of Maxwellfs equation. Orig. art. has:
:4 figs, 6 equations,
ISSOCIATION: None
!SUBMITTED: 00 DATE ACQ: 2OAug63 ENCL: 00
SUB CODE: MA No REP SOV: 006 OTHER: 000
Card 2/2
SARKISOV, D.S.; FIRSOVA, P.P.1 NIKISHIN, A.A. (Moskva)
Giant-cell malignant thymoma. Arkh. pat. 26 no.12:26-31 164.
(MIRA 18:5)
1. 2-ye khirurgicheakaye Otdelenlye (zav. - doktor med.nauk
M.M.Varopaye--l i otdel patologicheskay anatemil (zav. - prof.
D.S.Sarkisc%) Inst'tuta khirurgit imeni Vishnevskogo (dir. -
deystvitelInyy chlen AMN SSSR prof. A.A.Vishnevskiy) AMN SSSR.
'1067
S/ ~~6 6/230/ -1 C
M,
0 C B' X
A'~'T MR 3 1 Azimcv, S A Corre4povilne Mem~,pr AS Uz~,~k:,~jtpl
-i, .5 K., Chernova, L P , Chernev.
Nikish
v m
TITLE; Inventiga~i~_r. '~f
PERIOD-.CAL; Akademiya nauk Uzbekskoy SSR Izve-'-.Ya seriya '1z'-':'--
matematichegkiki. na'~k. r:o
TEXTj This is a -)f previ,)~.,_; stuies, -.cverine:
y an! m3rnei.tum ~or.servatlor, 'aw -n *ne
influen(~e of enerv - I
_f s--cn~arv stuly of azim-ithal ef'e r. ',n%
Slr.'g'y _h'3r'~7ej i-irtir.les. witi. heav.v emlils~,
mil in c": -ollisions ~xf --M: :,.son
te,ween t~.eorv 5n-i ex-jeriment The infl-.ence Df momer.tim wa,
x iata on r-.ndom
s j -i i e I-_-i f-valuat~ni- e perimental stars 'he
Th-
Be, ~-, -Ilisions of statistical t~.eory
tht- azim~rY.al anE-~_Iar distrih-_;tions were f--.,ri tc te ',_e1-_T- 'ne va_!C~ea_
Card '/7,
; ioe17
S/16 61' /000/01
A 1 8
Df the azimut~ial P102Y3 1)
eX,-~'-.ted fOr 130troric The effec, --f energy anI mcme%tm rserv
le--reaseq wlth in-'reasinE- !i.-,.Ier -f shcvier Da ~ a f r,, n I e r.. r
~m s i ^- n S e xp c 3 ed t B e v 2 r - to n s a t t *,. e Ot 11 ye i in e n r. vy : ns v e r n. -,-
:s, -c.,variy kjG--r,- In~t:itlte cf Nu,--ear Resear-',, were ~sel
,e- r~ e
1 tne "AEI's f
m,
%I ~oliisi~ns Mo~'
rr
!i
ai effects in
z;
, -
-
-
..
,
.
a
p,
-
-rs anJ
i s i
ed cosmi,~
artic! es were
N col
P
1e char
: 1 sicn b
sin
S~ 4
Ia
e
-
I ,
-
l
a.-
p
p
g
g
y ~
y
an azimulhal ari3etr:,-,y cf !',.e 3ec3ndary zartices The ang--ar
was less 1:.sturbe-I oy azim:~t~al effects ~.an was isc-r-.--y
A?. azim-' r-a. eff~- --t, was he resent ~.n :c1lisicrs --'wec-n
--;:,-,e.y -harged -,z-sm:c ~:.arti7leS r:l heavy em.,Isi~n 'n
je t, s This 1~c !,,,e t-e nimb-r -f in
ivag wea-er char. in
--p zarwe, rj--Ie~ls T-e azir.,-~t:,al -~r- es
-f ~:ec~ f:iar. , . . S.
~ :,
n w -- t t e r -~ 1 y n a r- t he -) ry c, f 11 'et" fcrm,-'-. r. 'Z
r~,, r S S :en* er mc~,e.'
M, m m ~-. a:3 a s c. ~e t~---Ke:. -,.-,nt sz~me
ent.er modp-., are I :s- issel
-.C- ~x I-', A'i L e a
r ELI r,-.,
C di 2
31067
5/16 61/00C/cC6/OOe/CI0
Investigat;cr of t',e azim-.:t'-.a'_ B102Y3138
'11 Sov~e, -arid 8 non-Soviet The refere:.-.e to the English-ianguage
J- Marks, Phys Rev. 9~,
Pu-_~c,;tion reads as followsi W L. Kraushaar, L,
326, '954
ASSOCIA710"'i FizJ.kc-tek-.ic*,.eS*&i,,, in_~Iit-.it A'i '-'zSSR
Ir.--.tu*e Df AS
S-P--_7'-ED: 1
'IX
C-rd 3/3
AZIMOV, S.A.; NIKISHIN, B.K.; CHERNOVA, L.P.; CKERNOT, G.M.; CHUDAKOV, V.M.
Azimuthal wiguldr dWribution of atmospheric shower particles.
Izv. AN Uz. SSR. Ser. fiz.-mat. nauk no.6;65-76 161.
(KRA 16:12)
1. Fiziko-tekhnicheskiy institut AN UzSSR.
2. Ghlen-korrespondent AN UzSSR (for Azimov).
T
SUB CODEt 20 / MM DATEj
09AU965 / ORIG REF: 003 / 001 REF, 0~11
D
USSR/Physiology of Plants Respiration and Metabolism. 1-2
Abs Jour Ref Zhur Biol, No 3, 1958, 10372
Author Nikishin, F.M..,..__
Inst Kalinin State Pedagogical Institute.
Title Conditions of the Formation of Anthocyans in Petals of the
Chinese Primrose.
Orig Pub Uch. zap. Kalininsk. gos. ped. Inst, 1956, 20, 269-274
Abstract The petals lost anthocyans both when starved of carbohy-
drates at a 350 temperature (created by lacing them in a
light chamber with a 150 watt light bulbs end when kept
under weak illumination or when the leaves were removed.
When cut plants with white flowers were nourished with a
2% glucose solution, the flowers turned red.
Card 1/1
NIKISHIN. F.M.
Biological characteristice of seeds and vegetative reproduction of
Salicaceae in the temperate zone. Bot.zhur. 43 no.10:1473-1478
0 '58- Nru 11: u)
1. Kalininskiy gosudiarstvenny pedagogicheokly institut.
(Willows) (Plants--Reproduction)
A new habitat of the water lily Nymphaea tetragona Georgi Bem.
in Kalinin Province. Nauch. trudy Kal. otd. MOIF no.2...~29-231
160. (141 A 14 10)
(KOKOSHKI REGION-WATER LIIMS)
NIKISHIN, F.M.
Extremely large oak stuKp in F-aUnin Province. Nauch. trudy Kal.
otd. MOIP no.2:232-234 '60. (MIRA 141.10)
(SHMYAKOVO ItEGION--OAK)
ITIKISHIN) F.M.
Floral pollen ard prospects for its utilization in the na,,iror~---
economy. Bot. zhur. 47 no.7:982-986 il 162,. (?If;,Fip ic:q)
1. Kalininskiy pedavogicheskiy institut.
(POLLEN) (MATERIA MEDiu, VLGETABLE)
NIKISIUN, G. I*
Chmical Abut.
VC!I. 413 NO*
Feb, 10, 1954
Organic Cheidstry
t
of
tetra.
halositan" In RW of xytene 12-20 tics. gave: tile foltowincl
Cofnpds. FR - 'ClIft0fe:01", yield M, b.p., "it
Yand tin shown),* MIsSiRp 40, 178-8.5'. 1.4515, 0.8012;
MeSUIRs. 21, NY 1.411M. 0.78M; V#SiRi. 33,
231.9-2.14, 1.4772. OA=- SiR4 40, 269.5-70.5'. bit
1104'. 1.4950. 0,8M. Llhu ifWi 7.0 C. 1.1 slid 82.2 g.
BuDr was treated with 34 S. eydapentadlene with cooling
ever 40 min. in N attit., then Itntntdiately with 05 g. Mcr
SICL and the mixt. gdtowed to stand overnight. refluxed 12
hrs., and hydrolyzLd s3 usual with HIO, yielding 9 g. tri-
methyte3vto mtodierylsilane, b. 138-40*, nit 1.4622, d.
0.9308; wrich forrm aa addad. m. 102-2.6* with malfic
anhydride. The Grignard reagent from 8.2 t. I*fg and 41 g-~
fife~SiCflaCl refluxed 12 firs. with 50 g. Cllj-ClfCfl3Br
it% EtO, evapd.. and heated 8 hri. to 70-90* gave 27 4 g.
,VesSiCffvCHxCH:CIjFs, It. pilif 1.4148. dv
0.7358, whose Rar"a ' tru. )-.wed lin" (m -1)
2), 207(5), 247~(12~7,' 1). 324(3), 521(3), M(3),
-51149),016(4),413 899(l), 0 I(g3), 1014(2). 1 10--j-
(3), 1173(3 ). 128 1298(d), 1415(8), 1039(t()), 28450).
2897(20) 2959(g), 3002(6), 30W5). The -f-donble bond
frequency 1639-fits welt with existing dats on such compds.
Passage of IIBr yielded the id Br deriv., bit 64% x1f
1.4542, dm 1.0894, which, ;tddtdll
~o MUM, coned., and
heated to 00" final y to 1000 (10 604.biav,-211 fife#S(71 -
ClItCHAteEf: 11 R.
It. 54-4.3". nj," 1.41 0. d, .7450, 1e
results aft held to support alternation of 1,-rity In C stmu
chain. C. V. Kosofapo(F
U-54
Ki,
d---
1 1-,
, ; ~ ~ .:%,-,
ta
pql~ 40 lip
4ps
j;jR,eA'c'tivir-I
ia sit: 0 :1. n a
am
Axpe 4s 'ablisMd
or
,iqmd r
if"~-- -found that all
lily d: iee--: charke te azed'b'
~4dtid-ftusrand alod-b. -vldr~t 9h:
Speo-
th
asxe, by,!,. 0. pl~ooance 0
p
41 ilt- . . ....
--7.7
POLYAKOVA. A.M.; KORSHAK, V.V. ; SAKHAROVA, A.A.; PMOV, A.D.;14IROBOV,
NIKISHIN. G.1.
Polymerization Fmd copolymerization of alkanylailanes under high
pressure. Part 2. 1xv. AN SSSR. Otd.khim. nRuk no.81979-985 Ag 156.
(MLRA 9-.10)
1. Institut alementoorganicheakikh soyedineniy AkRdsmii nauk SSSR
i Inst1tut organicheskoy khimii Imeni N.D. Telinskogo AkRdemii
nnuk SSSR.
(Polymers ftnd polymerization) (SilAne)
7f
:
F
o,
tl
jz
~
r -hr-.t
WhO
IN
; I
&
it
II
'1611 OV
y i
--
~
7
77 "I
g
ft,
-'r 2 074
,
0 70
C 146
1
,
'
482,
0,8242, 1.
mexsi cl
Sicill 0? ff-I
g-
~
ros
C7.sir'a- CU
A 00116- 1
lf-jliCl die e-lzt- '00~
j
I
u,
C'u".
'914, --.44;j1, AM, ki~~i
IAN- 400'v 1,;tjSi Ma diji
iWSWIR 6~ I OW
'04M' 6114,;
Wd of Si(CH: cmes) i, ui~.64'50;
2
1:442-8, 1.55/a (RIO)z-,
M988i 1422L Wohnatiom of
r tdtraviolet 411t -S his. until We
179-800. LM20~4.4802,wWch-*.
bm 156-
44pectruin shaws uo b~lndi aL x
re'ch=vtu-bGc of tlt6-- term in-,d
'romidle (Sfj--g"y tMated with ifie
d39.5'g; CICUtSi
I-AZ
jcNj~;C fil; v-76' (final wrip.)
Alti, L"14-'; j
-:'~Unlkjrly JIM pas-ced intdsx g.
uhleft with O.IX KOHr gavi 45%
1100 ctzj.'~' i0ii&-l
mp)- 771!~oaotyl
e14' ga
-rw
frold 5-3'w~ If, ii
tj dr
gave i~a!ojlea& AiLl 1,
~~-Wlth 0.1'v Nam ar blihi
6-1 d'm LIM. V 1.408,
7
K -1 ': 2- 121 2C
AUTMIRSi N ikin hiril v, V.D.
TITLE. The cf Ercrvlc,~e
PERICDICAL: I,-vestj,~L- kT,. :.1- 12,
(USSWI
The hovicl~-tic teloaerizntlicr. ---i c -,resence ,f e rc-~Ad c
c~o talc s t.- -.-rLz -~ ess rril-e4 the ba6 1 n -,f -i,-, r- u-: e-c- ~s A rc-
sult of thia i--n-tiun t~e hiihegt funct--~-,,! zicnn!
-a3 recel-rea. The
cu the. 3thar hnn6, h2.-q ',een mitch rio.e r-xcl~ T.-.-
d(- it ti-sh tc '-MeStjg:~tl; '~'JC
.A
esturs .1ti. - r-,Afic," -,rrbcn --id --tCi: i ti-le
telm I- C-n t'-*s
,crini~ti.)n cf -:rthyl ;"DIT"'irte ril
thev found t1rt ,-" U- -3 -ction tl~L
th'--I fomiate (in t'-,L thc reaz t
of telomeriz-~16-lor- takt~; U'tr. il.--tlll~-l the F.,.rcn-t-3~
acid. The ti ):I on t,
cther liarid? tllk~-,~ ~lth the f-natiL l-,
C a rd 1/ 2 fcrl-iate --ritli t:tl.--.,If Lie re r3
The Tclomerization of Propylanc Pinil Et~~I(:ne 3--th
Ktthyl Fomiate
an average molecular weight cf ',~5C re--e --btziint;~. Tl~,; te],m!e--lz-,,-
tian of etk-'-cve -ipq carrit~L' under a piessurti of LCC- atrics-
phere5 and Pt -_i tomperature of 1.~~Cc. T'r-,-re --rc mfarc,.cas, .1 -,f
Whioh art Slavic.
ASSOCUTTON- Institute :',-r Gr,,,iilc Cheii.Bt~:-.- A;. ITS31i iiiic-ni
(Ins"itut or.~q,-ic~.cssh-y khia,ii iu~. ~Illfdemii nnul-
3LBLITTED- JTOL; 4, ',-~.57
AVAILABLE: Librrary c f --ci,.greso
Ci,rd W2 1. Ethylene-MettWl formir,Lo-Telomeriz- -ion
formiate--elo.,,-eri:6; tion ~Xhylenc-Homoljtic
Peroxide c--Lilyst
M
SIL4, V.T.; POLTAKOVA, A.M.; SAKHAROVA, A.A.; PMOV. A.D.;
MIRONOV. V.?.: GLUKHOVTSEV, V.G.; NIKISHIN. G.I.
Polymerization of unsaturated silicon organic compounds under
pressure. Part 4: Kono- and disilanes. Zhur. ob. khim. 27 no-9:
2445-2449 S '57. (KM 11:3)
l.Institut elementoorganicheakikh soyedineniy i Institut
organicheskoy khimii AN SSSR.
(Silane) (Polymerization)
AI: T H 0 R S Mirjnov, 7.
TITLE: Tie Rel,:.tior B,:twep- t... S, IL
-.e ir c,~:u'
i ikh mole-:Ulyarn.,mi
A IS E C e 71 e 3 o f c c t 7- e
c f 'D I* c c o -i i, s -- c, n zpd t
o f t c- S " I t i 7~ f t v 1 1 1
eac.,-. cor.. in t~.--2 zole2ule. T.
o f t e m c I c -, 1 m -~ S t (; 0 t n t o
calcul-.tio,n. T..e c-II t i jr of
4 0
0:~ 0 U,,. ~I
i.,i o n 1.y brje':.,.-
t.a C, r VI 1. 1 C
t it Re:_f~
w'.. o s e
:~y Q X:I
Card 112 several -rit e 0'-
T-e Re--~ttior. Bet-een t:~e
Comi,ounds and T ~. er ol e cI a r R f-. ri o n
n eviy 4. -, c 0 v e r e (I r-1 1 C'~ :-; . I t '.'/ rl st
in t~-.e moiec,:I---r refraction is %n ai,! t i v e
which is fJirectly oro~;ort.;)~,.I tO t . -~. --,:
which cause t,.is i-.cr, -t ~ T
as cert a 1::ed the refra- ior: co: * rit
radicals wr-c,, bon-led t~) t- !:i":c -it
5 tables and r~!.'ore, ces, 2' )f w,.-,
ASSOCIATION: Institut orga:.ic:.esk,),f ,i-mi-
SSSR ( I.,::1 t i tu t e o f or, --C t
3 UB N, I TrEl) Fetr ;:,rv 15,
Card 2/2
2-
5 ( 3 e ! Z 0 1 ,
AUTHORS: Pt!tr,:-,;, A, 1). , 37rti . arik_~ rip-, N . P. N~ ki
TITLE: SyritneEl' 2 )f I -D-- 7,:
opentane pryaM3.,
s-~ r. I, ez I,! J4 khlor - 1-s- 1 a - sik lopent a na 1)
PERIODICAL: Izvestyr, kkademfi nauk SSSF. Otdelen"ye knlmicht-~skl`kt~ na-iR,
(USSR)
ABSTRACT: In the prtosent papur it was found that in a r--~actilon of 1,4--
dichlore. butu-..i.- w~.th qdlicov, as basic product the 1,1-dichlor-
f
4 its yield (in the condensation
was 30%. Som-c- _f i-s chem-.ca-- proTtrties ivere in-
Thus, _n the chlorination with sulfuryl chloride
the h~-dlrogen )n the ~"-carbcn atom is substlt,_;te~ ty .-nlorine.
In an 4n-.eractiDn beuffletin l,'.,~-triciilcrz)-i-s4'acyc.opertane
meti-. I
. y. magne3_-um cilorii*- the suostiLLit_~,n -1-f the chiorint-
at.:,m!3 ~,y T.E gr,_.ups and an DperJ.ng of the cycie "ehind the
.~I' C l,crJ, -):- the Flace. The
propertie-i ~,f lhe 1-(trimpthyl sily'-)-butene-3 farmed duta
thF, cp~nlrg Df the cycie iurned out to b- iden- 'fca' w-th the
prope-ti,es c." this si--icon hydroca:7bon ea--J-if-r ~lbtrllr.~.d after
Card 2 Gr--fl' af..Vyurt.,3 r--actiur. f-orr, chl,)rc-methy'
y
Dl-.-e:, Syr:. 1&,-y ,!.,;pp. ntano Sovi 8 -1 22 0, / 2 2
Et I) q L tP /Rqf h, In '. Ke li dr,- 1y -,::I f
Y
0 an e 'n aqu,, (,l.; s a, k a 'Re f t e
c r f? r, :1 -, :7~ ~
Ln".19z x an x as,
a -n Eg- -i j7 um L? a-, ac, e c an n. v e ax c''
A
q t xy I gr~-,irs- llBr a~ -100 ,s
A af F- a t a n e
f C if 3 C11 CHI~i-OH 1 s ,nitub',i~. Heating:
a ..:z fi t h T,:- Y I kc n e cini
L
ASSOCIATION: e I s A x a :4 e r-
k S S' R 1r. s f Cirga,,- "~.-.c-m4s'ry
; e,,y es, ',SS?
3,L73blI T TE
Car~t z, -1
PETROV. A.D., NIKISHINA. G.I., Icand. khim. nauk. NEVOLIN, F.V., kamd, tolchn.
asuic. KFLALI-OS-TMA. G.A.. ORMHOVA. H.V.. TUSMVICH. A.Y.
Faffect of the size and structure of the alkyl chain of alk7l
derivatives of benzonsoulfonic acid on their surface active and
detergent oroperties. Kasl.-zhir. prom. 24 no. 8:23-29 "A.
(MIRA 11:9)
1. Chlon-korrespondent AN SSSR (for Petrov). 2. AN SSSR (for Petrov.
Ililrishina). 3. Vessovuznyy nauchno-issladovatallskty institut
zhirov (for Nevolln, Kral'-09okina, Orskhova, Tushkevich).
(Benzeneaulfonic acid)
(Surface active agents)
A *'T 11011 S Petrov, A. 7". , 01rishin,
Vorobl-.1uv, V. D,---- -
TITLE: The Synt~ie~:is of ArA D,),!ec-I'l :c~., T-elr 2-~r-
hydri(iWSf-tez u.,~dct";il- i i
?ERIOD--ICAL: 71,11f. Ll os c'ey kr.i:.ii,
!,P 1761 - 1766 "'SSR'
APSTRACT: Fro:7, t-ie :r-i!.in-'y f.;rei.--n ~---ers -:.e., t 4 O.,.e I!t
1-15) may ~e seei: t,. A d:~dec~(l ~enzet,es s
whic:: se-,-.e as -.i,).Iel 1-17,rlrocarbons for the
benze:-e are only inoLd- ..e,.tl,, T--- 3 Utl e
hydrona I)r,:,
s of t',je C 17 i: c (-.c r
nientio:.A ri~.:.ctior -e es ,vi t). % I de~yl
ra:-!il'Je,1 c~:tii, ' ei :-.,- o'- t. e,l -.,!! 'i P e
se 1 t c t i orl f t., e r: r e,
C, c i,! e e r r o f t t .-I
hi-hly ra-ilfied or
a little ri--.if4e(! c%ain. T,.c- I t o e,~ f r t -c.
s r C! e F hy'! r n 1-11
Card 1, --ilion te ures --nd ki,-, , t C
T'-.e S_int..es' s of es
T nir Pern..-7drides
are --,ertione ir. t,~. e .'.1.::ere the n-'7rl,:lc-rl 1 e,,.
s~mt r-ti-(! ~y S- J It
o f co-! ,uri F, or. T 4 t 4 C.
0
!,n-! t c,
0111v b"1 -lh,-oit 50. A l s i: f !'a r! e e x k~ r
-! ' i. -~t 20C) 1
on t:.e 1-i-e itic vi2co.
r n A I.
bel~)w 00. T C, le !n"
Soviet .
ASSILClATIT I: L;tit,~t o I i 1 3::
SU "MI'iI'ED June 20, 1
Card 2i 3
1-1 1 -
The Synthesis of Undecyl- and Do~-~ecyl Ben-.-~,e -i!A -- ~.: -.-I ." ~_ .'.
Their Perhydrides
1. Benzenes---Synthesis 2. Hydrides--Chemical reactions
Card 3,'3
'MHORS: Petrov, A. T)., Nikishin, G. I., Smet~,nkir.,-, I.
- ------------
TTTI~L: The Behavior of Several Dichloroalkanes and nichlornalkenes
Under Conditions for Direct Synthesis (Ilove,',eniye nekotorykh
dikhloralkanov i dikhloralkenov v usloviyakh pryamogo einteza)
P.RIODI'30-: Zhurnal obahchey khimii, 1958, Vol. 28, Nr 8, pp. 2085-2o89
( T.73 S_R )
_,iB T!!.~CT: Tn the decomposition reaction of dichloroethane ("ef 1) and
1,2-dichloropropane (Ref 2) with silicon only disilane, be-
sides silicochloroform and silicon tetrachloride, was found
in the reaction products. In the case of the chlorobutane
(Ref 3) and 1,2-diohlorobutene-3 (Ref 4) cyclic monosilane
with a silicon atom in a five-membered ring forms in addition
to the disilane, as the author had shown earlie-. Tn the
work reported in the present paper the next homologs of di-
chloroethane, the 1,2-dichloropropane and the 1,2-dichloro-
methylpropene, were studied,since not enough work had
p--eviuusiy been done on these compoundB. The isomers of
1,2-dichlorobutene-3 (the 1,4-dichlorobutene-2 and the 3-chloro-
Card 1 3 2-(chloromethyl)propene-1) were also studied. It was found
9C7/79-28-8-181/66
The Behavior of Several Dichloroalkanes and Dichloroalkenes Under Conditions
for nirect 9~,nthesi~?
.1
that under the synthetic conditions used 1.2-dichloropropane
&nd 1,9---dichloro-2-methylpropane split easily in the presence
of 11C! into ally1chloride and meftallylchloride, respectively.
Theue two products can then be converted using silicon into
allyltrichlorosilene and methallyltrichlorosilane. Using
1,"-dichloropropane previously unknown disilanee were obtained:
the 1,1-,-biEi-(trichlorosilyl)-propane and the 1-(trichlorosilyl)-
2-(dichloroeilyl)-propane (see Diagram 1). The reaction of
the 1,4-dictilorobutene-2 with silicon proceeded according to
diagram 2. The reaction of the 3-chloro-2-(chloromethyl)-
propene-1 with silicon yielded the methallyltrichlorosilane
and 3-.(trichlorosilyl)-2-(trictilorosilylmethyl)-propene-1.
"'here are 1 table and 11 references, 7 of which are ~Aviet.
AS'OCIATION: Tnstitut organicheekoy khimii Akademii nauk '1~39R
(Institute of Organic Chemistry)A9
SUBMITTED: July 6, 1957
Card 2/3
-- 1- 7;." )-2 e-~- 1 s, 66
Tho Behqvior of Several Dichloroalkanes and -)irhIIorovlk&nes Un,~er ConJitions
for Direct Synthesie
Card 3/3
PICTIROV, A.D.; NIXISHIbl. U.J.; GiLWENITSEATA, V.N.-, VOROBOYEV, V.D.
Interaction between P-(ma,-,nesium chloride)-tert.-butyl-benzene
with carbonyl compounds. Zhur.ob.khim. 28 no.9:2315-2319
s 158. (MIRA 11:11)
1. Institut organicheakoy khImil AN SSSR.
(Benzene) (Grignard rea4ents) (Carbonyl compounds)
AUTHORSt Gramenitakaya, V. N., Nil:ishin, G. I._, Petrov, A. D., 2o-3-22/.59
Corresponding Member 0-G01-
TITLE: The Condensation of klkyl Benzenes With Halide Derivatives of
Isobutylene (Kondensatsiya alkilbenzolev s galoidproizvodnymi
izobutilena).
PERIODICALo Doklady AN SSSR, 1958, Vol. 118, Nr 3, pp. 497-5oo 'USSR)
kBSTRkCTo After a survey of single reactions of the alkylat-kc-n of aromatic
hydrocarbons using sulfuric acid as catalyst (ref.s 1-5) the
authors report on the synthesis of alkyl-aromatic hydrocarbons
plus derivatives with branched alkyl radicals containing qua-
ternary carbon atoms. The condensation of the metally1chloride
with alkylbenzenes was carried out. The conditions of reaction
and the yields are shown in table 1, the properties of the sub-
stances produced are mentioned in table 2. The yields amolant to
64-90 and depend on the consecutive order of the addition of
reagents. The amount of sulfuric acid (catalyst) and the temper-
ature value are essential. Only in one case it was possible to
isolate a solid crystalline substance(p(P-chloro-tertiary butyl)
tertiary butylbenzene. The liquid residue and all other chlo-
t
ro-tertiary butyl)alkyl benzenes are, as is shown by heir in-
Card 1/2 frared spectra, a mixture of p- and m- isomers which could be se-