SCIENTIFIC ABSTRACT NICOLESCU, I. V. - NICOLESCU, M.
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CIA-RDP86-00513R001136830009-0
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100
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December 31, 1967
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SCIENTIFIC ABSTRACT
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frActiati And tmvi~ly In Whe, W(srdi the two oALlw-I
te~taw,4 (A, And 00 ~yv drtmutuawq in aw A,1-tim-,
prcwv~. A ugar "a ( I.( ~' Gerhard AuOxef
NiccTli-ISCU, T.
drovh1(-.rA,- Aoid to the
"The Catalyt-*Lc r,(`.~!Itlon of' TT
'y
Fract'c,r, of ',as-s From Oil
4
%ol. ~, No.2-4, Apr./rec. lc1c.l. -_i t i --ima n I a .
,;D!r ~nthly List of has t hiuroc(:cin kcc-essl ons, ',.C .. "o1.2, "c'. 11, "ov. 11-- -
7ri y - - , I
I.TCOLVOCU
"Be 2e arch on tho A d--OrPt I on of Hy(4ro7hl or I c Ac' c to Nuf.~-irpal A lurnos' l I cat
Cataly7.ers. Noto 1. p.2"~." Ll f, L J,T
Bucurre3ti Rumania.
SO: Monthly L.st of Last European Accessloris, L.C.'10-1. 2, :7o.11,
Uncl.
. . . . . . . . . . .
loll
1 11' 11 11 o r-LE!
lo]
MU, 1.
YTCX~LF
Catalytic dehydroconversion of Icerosen.s. p. 171
Vol. 2. No. 31141, July/Dec. 1954, Bucuresti,, Rumania
SOURCE: Monthly List of Eas'~ European Accessions, (EEAL), L. of C..,
Vol, 5, No. 10, Oebober 1956.
NIGOLE-3CU, I. ; 11M~flrlfqU, A.
Stud2es on the catalytic dehydrogenation of certain alxylbenzenes; the activity
of caralysts Cr203 -Cuo - A1203 in the lehydragenation -)f isi,crof-y1cenze-ne into
6 methylstyr.olene. In ?rench. j:. 143.
(AEVUS DE CEIMT-6. RUMANIA. Vol. 1, no. 1, 1956.)
SO: Monthl:f List of Fast European Accossions (FZAL) LC, Vol. 6, no. 7, v-ulY 195?, Uncl.
RtmaA/Ehysical Chemistry - Ki-netica. Coribustion. P-9
Explosives. Topchad.stry, Clrttalyuia
Abs Jow : Referat Zhur - Khtniya, Ito 2, 1957, 3861
Author : Hicolescu I.V,, Hodcatinu A., Popescu A.I.
111st . AcaOE57`of-Truri~nlan ?eqpLe'-% 1:epublic
Title : Catalytic Action of dMw Avaimmin Silicates in the
Synthesis of Isopropyl Chloride from Cracking Gaaes
Orig Pub : Cormum. i1cal. RE11, 1956, 6, izo 1, 63-70
Abstract : At temperatures of 24-1450 and space velocitiea 17-36,
as stuely was ra','La of the catalytic activity (in the reac-
tion C 3H -(--HCI'- iso-C Iff.1) of silica gel, silica c,.-Cl
inpregVed with-l~' 'P lreu'3,, synthetic
silicate (AL20 :,3iO,):?4gO=ll:80:q), and bentonite clay
having the cor4tsitloa Sio,)-Fe 20 -U !0 = 6.".F38:.i2.46:
18.40 W. Catalytlo acti,;Ity Za'li 11c ixlvostigate~41
catalystb decreases vith increase of the reaction ten-
perature; m.3t. rictive was found to be 1~ which ut a
Card 1/2 - 147 -
----- ----------------
COU-NIT-R'.1 il -L L, 7,na
CAT&GORY
ABI". JOUR. RZKhim., ilc:,. 1959, tic). 7e'_-650
AUTHOR 'I iCrjlE i;CU. I
IMST. aaeriy
T ITL orl 'Lltahr,
I.T.
OR IG PUB.
las C'
A33TRACT A Study Of the ~.ff"C.t 0-*
s'-*r,,ict,j-( of naturai calalysts and I)ent,--rit-ic c.'LzyF
sorption char'!Ctc-. i.~itlclz ard CLII~'Iylfc
stuaLc- wc..ve maid-. of ~I~ree
T'I~ C(JT,(! lrli! :z of D(:byc--S,,~.t,:-:-cr pa!-terns; cl,arges "r. sorp"i
c" "a, S t I c s i f 1-C r,.v ity ol. 0!-- P:
st;xlea Over temleruturc I'ari~#- Uf
'uncl of the C)I* tt~ese cl..'rigges on cat,-L-,..t*c
actL't'Lt-,,. L~tbornitcry ex-erli;.ents were COtIJLCLC-Q C'~
c r, i ck, I r: !,, of yetro-cur; diitilla'-.c. Un t~'.E!
ID -,a i; i s c, fexpcrimQrt~A1 f ;Aa tl,f-, authors believe titijt a
(.1 lGst: c ci r re !a t i on e ), i s I s be twe er. mont:t!or i 11 w , I t i c ,)- r*,, n,~
CARD: 3,/2
Tacul
Ls
RWANIA / Chemical Technology. Chemical ProdvcL3. Refin- H
ing of Natural Gras and Petroleum. Mot:)r anJ
Rocket Fuels. Lubricants.
Abs Jour: Ref Zhur-Khimiya, 1958, No 20, 68725.
Author Nicolescu I. V., Popescu A., Papia Al.
Inst
Title Comrlex Catalytic Refining of Gasoline with Simv,l-
taneous Produution of Pure Aromatics, High ()CtariE'
Gasoline and Cyclohexane.
Orig Pub: Rev. chim. 1957, 8, No lo, 625-633.
Abstract: A new method of catalytic aromatization of gaso-
line with stwultancous production of benzene, t:)-
luene, xylene3, high octane gasoline and cylohexar.-.e
is described. 'Catalysts employed are: Pt-A120 3 and
Ni-SiO with -36% NI. A complex converslon with the
fullesi utilization of the 65-1950 naphtta fraction
is thus attaiaed.
Card 1/1
67
11-JIGAIIi, /phys-ic--Il Ch.- K.In(AL-8. Combus- B
tjorj, Explc)--i-,)ns. C
"IbF Jour: Rcf hur-Khi-niyj, No 11, lqc~b, 35471
AUth r NJ_Q-,,~ - ~2c
Inct 14 0 t ~, -~ ri
Title , ~. u c" o f t h r h i s m o L' H t E r o v. c~ no u s C a t , I y s i s
P,rt I
Orl~r PUL R E Ci 1957 NO 11, 6~38-~'91
Abstrnct Pr,)c t~ (- d 1, r, f r -),-. rlusic, s dr--..i,, fr,-)!,i
theorics, nu -,"L if t,1 oJot,Lii,-d
by ct'-,~,r Euthi)rS W,)-)i tnc oC the --,ro--
~iatizatlo f I i,_ p te C y c 1 o 11 e x a n c ad M E I-InY 1
C y c 1 o m c xc o. i c ay ss S c o n s i a c r c dThe c-~t,2-
lysts rirE: I'fi-1-12()3 vl,t" 5.4-36.6% N:i, and Ni-
~',120-Pt Wit" '~h(- quri .ity o, Ni and addi -
tion of 0.;)% Pt.
C --rd 1/1
RUNIMILI/Chardcal Tcchnolc,-~y - Cliculcal ProductG and Their H-15
Application, Part 3. - Induotrial Orj~nnic
Syntlicisis.
Abs J,,DLLr Ref Zliur - Nhii,Li3re., I-la 14, 1958, 47632
Author I.V.-Niccleecu, Ucxe P)PcScU
Inst "C.,*T. Pnrh,.r," Uri-tersity.
Titlc Method of --Imultancous Preparation ~;f Benzene anI
Cyclohexai-w at Catalytic A-romr-tizaticn.
Gri g Pub im. Univ. "C.J. Parhon". Ser. stiixlt. nattv-.1. ig,)--l', 4N~
15, 93-9:5).
Abstract Beazene (-:) and cyclohexane (II) are obtained at
catclyt~c arumtization c-f Lwoline fractions (GF) by
plutfon:-iiag, at wbich occasion thc., forming (pses c,:)t-,-
tcini-ng from 75 to 85% of R2 are utiliz(!d for the Pa-
rallel cotalytic hydrogerztion of pure 1'. jr cf a
Card 1/2
RUWJ,rrA/CheLdcaJ. Techno-ogy - Churdcal Products and Their H-15
Applicat:'.on, Part Industrial OrLpalc
Synthceiii.
Abs Jour Ref Zhux, - 1(himiya, No 14, 1956, L-7682
direc-c; Ca? aromatization product. The experimer~ts were
carried out with a CP boiling in -the range fron 66 to
900 aad .,ontaining (in 0) paraffins -- 38, naplithenes
58, and i3xocatic corTo-unds - 4; the fLr,x3:LtizwcJ.oii pro-
duct contained (in %%) aromtic compoumis - 52, naph-
thencs .. 8p and paraffins - 40. The optirmn czmditior~s
for the industrial hydxogomtion of I are: termerature
I
- 1600; zmtALlYst - 56%, of Ni and 44% Of c'i02; pressure
8 to 10 atm.; volumetric rate from 0-5 to 1; molecular
ratio 0J.' gaSes to I - 1-5 - 2 : 1; yield of 111 - 100b.
The chmmcteristic of the produced Tj'.: (.120 = 0.7790;
r,E = 1.4260; nni I in point - 31 .0; boil:Lng point - 8o
to 81-5c)- At the hydxogenation af I containing frac-
tions, fractions containing about 50% -of 11 a:re obtaLied,
yield of 11. - 100%.
Card 2/2
/Y/
~UP~J,'T-AlPhys ical Che!ristry - Kir(!tics.Combustion. B-9
E)-plusi~ris. Tupochci--'stry. Catalysis.
Abs Jc,ur Ref Zhur - Khiraiyu., 1170 8, 1958, 24254
r Nicolc~.-cu, I.V. --ru Mlircou
D-st
Title Cataly',ic Fe--Lcti,~-.s )f Alkyl Metal Halides. tit ic n
I. cf
Orig Pub ;,%. Univ. "('.J. Cer. stii--A. natur., -'S,57, 1~il- 15y
97-101.
Abstract It is sl2,)wr. --h--T hulrgunides c.f aluminuia al'ql car. ac'- as
catalysts in the j?f:,lyrrzcri zar ion --)f cyclohexane. The f,)1-1~-
wing catalysts w(!-re synthesize-d: be.-Lzyl alLmduum cl-l~,ridc
and br~,rnide, butyl al-xzJ-n,,;n chl~)ridc, d-ich1:-.,-a-,han,,J. alwai-
num and dibr~-),--,ocyc-'-choxurE! aiminum. With the3c, cojapcunds
whid, are partic.lly sc1uble in cyr-1c,hi'mene higner y-iel.--
were obtaint~d t1,,Qi w-Ith A.= 3- Benzyj alunin-um 2hl-.,--idc
Card 1/2
4
RUMAIIIA/physical Cherdstry - F.Incticst Combustion. B-9
Explosions. Tolx.-,chemistry. datalysisi
Abs Jour : Ref Zhur - KhimLya, No 6, 1958, 24-25L-
and broulde weru found to have thf.-., highest aztivil:y.
T -esponds to the pentamer
Me reaction py.,-r)duct obtained cori.
of cyclohexene.
Card 212
"WIM
RUWAIA B
CA'3EGORY P?ivsie a I Cl P.- :'I* -k-. Kin r'!'' -)n. '7100-
i.n t3
114 TI-1 MTE
7 r
1
Illf" propurtlam d ca,~d cg 81, U_ A Oudy 0 the
eltntr*4 canductidw of cAfWjrNm_.
used b "averdq; Vieth-
I. v. 5 -~"' M ' Rian StAnzi, Cristiana vcr~
Diistr i; 4g3d/
19,M(04.6,fK(h3l.!
4E2c(4)/4E]c Ate~LQ %p!L..FcL( ;IjL ts spl-pqr , ILac#q 054
_C
At" and Mgo 6%) are fa=d at 240',320*, 49)*, 560*
Ivid 00, in an utm. al (h cm.- Ut In a 4-nd.
f.'Uractcristic valu4s fat- I(PAcc l,R me -8.08,
..6M. -5.74,cutd -4.4D for th4se temrs. Thisbxdlw;!~
i4ek of cft=i!=vVnn way fie due tc, the vatur- of thel
13. D.- Wit
wdyst
j,
-M`T,, 1, AM)
0
C
Elect rocomluctam,~i,ric arvi'1717!As of U)e ctital,.zer ul,ed in reth~ine-convarsi,)ri
process. T.. 2537.
Acedenia Rxrub11cl Homin-.-!, 9T'ji) T '~ I f1j ,I Jj T L ~. CI.
Bucuresti, Runnnia. Vc]. 6, no. 1n58.
Monthly List of East Euror,ean ~iccn33i-'-nS (EE.".11) '1,)!. P, nf~, 7,
Uncl.
c -11IRrrRy :
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y COW
and,
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chk
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d %her
r
h
7
150003 can be
up tq
at wt
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-
m
li) !n a PS.
'
CE40 (1) irkh Cjh I
0a
c
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W
r
U
a
C
kd
lim
tmtiy made & r0s by a .11 With
V
VIC
atC4 with Mac
d
v
U
.t1sL.WqM.bvLf--wdwj*Cl.CH
fecamt;m al the catx~ lijoks of
g I timle of Al Is T
Ab
m
L Mwr Cado of u
n, hiOC4 awl. wt. is obtshied "ft
1.2
&=Ises frma 1.2 1 taY
An tw. (
1 1
of 1
.
.
I I
to =d- P-thyl) beu=e
C.,)Ul,.try Ruman JI a L
T, r .-r Pro d 12 (7 t a -A r i -ri r
A uplic at., onE-, ri-ti F,
h n No 5
CO I F~ SC 7 VRt L LI--(- IJ An~,P:
1, 13 n t 3 r -ie 1 7.
it r v e r
';nr.E~t,irati~d ~'at y A c. d t-~ " r crr a A c i .1 s t a d y
the on parb r,!.
An Tl!-,i v T a r '~c)!i r t ~ i t Na t u r No 11~, -,7-
h, F I.-.v F, t i_ ~-,a t eo th r o,i)j c t lo, of un-
t d f F1 t t 't -i c i A r),! t,:e chlor 4 Ila f f a t
a n n o f twi ra f fj- n , f .3 11 o gv e d
by I I I r i ri n o h e c n I c) r 0 - 8 u -,:=~ t i f u t e d a c -
d!~ c) o' a-, n e d ne rc.,q~eriaif=. ii~~eri coy,si:3t of
op
2
e c r 7-,,1 t o- -,.roc t- re ~e I --n r
a r i c Fi.- r. , e ~ Fi r r i " dol~t 3otn n sclution
aunt ry li-15
r
I t
-'r
t r I c t- a S C) u L Tau in c- or 1~ c -I a
aC a 24-30~
a r c-. e. D o c -11 r i ria t, or. in e r~ r E , ~io I -
I- rot i6ed, c 3' th-~! .rocc-ss in the rres-
n c v- 7,0-71 react~~O-. 0- U-
F, n r- r, c, t a n I 3an
I -rS, a
;Drr L~u C ~:C. 7 T-
:- f: r
-3 r. d after nrs, a prod
t I . -t74 . 0 p t inu -. c ) r d 4
h e n C i a., -I-ihydroc~illorinat-
2/~ a.,-ent have open found to be as if
-0110rq.
It t,
r i r,
2,
D
c b t r n
e r t -).I ?1 0 rr, a 710!] r t
pref sure
r n t a ~,,)v e c iii on E- ar,:!
f r r .1 ac i. d:: c,~n'ajni:-,v I-
'r- t a ~mvd 2 frac t , o ri o f
f r "! "* t 1 - !-, insaL,,ratea faLty acids
q r,~ u,~ q rulu,-tion of unsaturated
of r5
3 1 alix ~v a
Ph, as of solid Caw SES. Ill. blettro-
coqdurtmetric Stud d 0 cat yst - .0. used in the
Hicrareacter equipment forthe deter-
midation of G(GCtt*A1 uct(vily and (or the semiconductor
I.V.NiooleV
Par.-WU, -suld a
jAmJ. rip. IF OrThw4ige 4. 7 imxin Flftuch);'
cf. C.A. S3. 110,21-A microveactor for the study of efec.
cond. of valid cmislyits wu consfirmtod, Reproducibility
,was studied by imlibrating elec. cQnd. of MO and ZnO (a
sk AM la 4 discaadnuoui 11 stream, confuuJus the hy-
,as a *-type getakonductor In the tcsnp. Inteml 280-600*.
,As recards the wariatim of eke. coM. as 4 function of temp.,
'At^ bchav" aLs a very weak vemicanductotwith pot. holes!
?.Lt tuw temP. WW as ea clectronle semiconductor at higher i
Aemp$. "a CIWYIC Pt an AhOs (IVo Pt) useAl In Flat-
PIli 10MIttg appears to be a compt" eaergntle system that be.
V Wes u a very, wtak conductur with pos. hates.
Frederick C. NacW *j:
-W
[Nicolescu, I-V-J; MODESTINU-NIKOLESKU, A. [Modestinu-
Catalytic dehydrogenation of some alkyl benzenes. IV. Derivation
of methylstyrene by dehydrogenation )f lsopropylbenzene over the
catalyst based on ZnO. Rev chimie 4 no.2:199-206 459. (EEAI 9:7)
1. Akademiy RNR, TSentr Khimicheskikh issledovaniy, Bukharest.
(Catalysts) (Dehydrogenation) (Methylsty-rene)
(Alkyl groups) (Zinc oxide) (Gumene)
Oenzene)
NICULESOU, I.;POPESCU, A.
Physical properties of solid catalyzers. 111. Eleczrocon,--I,icttouietric Sully
of the Pt-Al 03 utilized in the process of platforming and deteruiining the
properties o? tL seud.ConduCtorr of PLC). p. 49.
STUFAI 81 CERWEARI DE CIUMIE. Bwxpsti, Rumania.
Vol. 7, no,41959.
Monthly List of Last EUropean Accession (LZAI). LC, Vol. R No. 9, September. 1959
uncl .
Distr: 4E2c(j)/4E3d
ton mhsije,
"d FMI
A. Ekwevams
,
-IMId
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R
IwAdmc
.
.
ri '".I,
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of IML-coine). Mot resdto fm *U coses (w(th the execodw
of di-St phthglate) were obtaftied with IR-123 (Wamboa
1 H.S. beft very claw to It). Ect the can at AcOH, the age-
fac of SAacirb)a U.S. was studied. No daemon In
-catalytic activity was observed after 20
H +
A I kv I at lor; 0 A o rT 1 o 'o,
Cyc lol-exe-e e e- e, ZOO-
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ASSO,- A- ION' K F 1~o P, ~:4
Sl-'BMITTED: De, e ri.b r-
Carr; 4/4
R/OOV60/01 1100;'~'Ioo2lorj-
A 1 25/AO~--`~
AUTHORS: Nicolescu, I.V.; Nicolescu-Nlodestinu, A
TIT.',,E,, Study of the Selectivity of ~Zatalys*s Used in DehydrogenationlReac-
tion of 'sopropylbenzen to Alpha-Met,hylstyrene
PERIODICALi Revista di! Chimie, 1960, Vol. 11, No. 8, pp, 452 - ql.:)8
TEXT: The producition of alpha-methyls~.yrene by catalyt,lc dehydrogenatilon
of isopropyl-benzene I,-, mainly performed in the USSR at the SKMS Synthetic Rubber
Combine, The same method will be used in the Combinatul. Chimic (Chemi-cal Combin-el
in Borzepti - One~ti for production of synthetic rubber_~ In prevtous works ( S,
I and 2), the authors presented some laboratory results obtained by dehydrogenat-
Ing isopropylbenzene to alpha-metftylstyrene and using the following catalysts
, CuO Al 0 Cr~:~O CuO-A120 , ZnO4 promoters. In subject article they
Cr203 -A'203 - 221 - 3- 3
present a more gener, criteria of appreciating the practical value of a catalyst
by considering the correlation between the activity, selectivity, selectivity In-
dex and the values of apparent activation of the primary and secondary reaction.
The catalytic dehydrogenation of isopropylbenzene has been already studied by VA
Balandin and G.M. Marulcian (Ref, -~), and by Nickels and his assistants (Ref. 7).
Card 1/3
R/003/60/011/006/002/005
A125/A026
Study of the Selectivity of Catalysts Used in Dehydrogenal-ior Reac,,Ion of Iscipro-
pylbenzene to Alpha-Methvlstyrene
The Industrial catalyst 1707 and the Cr20 -A1203 catalyst proved to be the most,
advantageous, The aLlthors briefly refer ~o 6e physioo-~-.hemical properties of the
alpha-methylstyrene gionomer. At the catalytl,: dehydrogenatlon of isopropylbenzene
there are, besides tne primary reaction of the formation of alpha-methylsty-rene,
also a series of secondary reactions producing benzene, toluene, sty-rene-ethyl-
benzene, gaseous hyd,~ocarbons, et-c (Fig. 1), The dehydrogeration reaction of
isopropylbenzene is powerfully endothevmic. The quality of catalysts with regard
to the development of a chemical process can be as well appreciated by tak-'rIg in-
to consideration ~,he ELctivlty., selectivity, selectivity index and the apparent
power of activation, The activity increases with the temperature and vice-versa-
The selectivity varies in function of the volumary speed. The temperature reauces
the selectivity, but increases the aotivity. On the basis of Table 8, the authorB
examined five catalysts. Generally, the active component Cr203 presents for a chain
dehydrogenation a reduced selectivity, because 27 - 481% of the raw material are
transformed into secondary products, As compared with the industrial catalyst
1707 (with Pe 0 as active component), a catalyst on the basis of zinc oxide (Zn
2
III) proved to ~e superior. Zn III produces approximately '~IZ alpha-methyl styrene
Card V3
R"/00 -'~ /6c) /0 11 /00c'2
A125/AO20~
Study of the Selectivtty of Catalysts U-zed in Dehydrogenatlon Reac-,Dn of '50::ro-
pylbenzene to Alpha-Met-iylsty-enp
and only 6 7% secondary products Compared wIth the other catalysts of Table 8,
Zn. III has the lowest activity value, I e_ 58A, but has the highest values of
selectivity and selectivity index, and supplies the best practical results I e
a high efficiency In the primary product and a minimurn of transformation of pri-
mary material into seco:E.dary products. The value of the apparent activation power
is 18,779 kcal/mol, whereas the cracking reaction has an apparent activation power
of 56,585 kcal/mol. The appreciation of the practical qualities of catalyst-s can
be extended also to other hetherogene catalysti- rea-tions But, this appre,~ia-
tion does not always jiistify the economv of a helherogene-ral-alytic p,ocess Some-
times It Is interesting to Use cal,alyss wh-i:-h produ--.e at a single passing a smad-
ler efficiency of the pr1mary product, but finally lead to a hlg~h. afficlency bj
recirculating the non-transformed reac4.ant There are 8 tables, 2 figures and 6
references-'. 3 EngLish, _.. French, I Rumanian and I Soviet
ASSOCIATION.- Universitatea AC_!, Parhcri" Bucure.5ti, Laboratorul de catalizA (Ca-
taly-tic Laboratory of the "C 11. Parhon", TJn1versiLy in Buchares~)
Card 3/3
R/003/60/011/()11/002/007
A124/AO26
AUTHOR: Nicolescu, I.V., Professor
TITLE, Soviet Contributions to the Study on the Mechanisms of Catalytic
Reactions of 'Some Hydrocarbons
PERIODICAL: Revista de Chimie, 1960, Vol. 11, No. 11, pp. 626 - '029
TEXT: Subject artic'-e deals with Soviet theories regarding the catalytic
transformation of organic substances, especially of various hydrocarbons. A.A. Ba-
landin,oiith his abhool supports the theory of multiplets, S.Z. Roginskiy, F.F. Vol-
kenstein and I.A. Miasnikov ~.n Moscow, A.N. Terenin and his co-workers in Leningrad.
and V.S. Liashenko with his ,ichool in Kiev have developed the electronic theory of
catalysis. F.F. Volkenstein (Ref. 1) believes that the electronic theory is lead-
ing to conceptsof proper characteristics, Including the existing concepts of the
actual theories. A.A. Balandin expressed his ppinion in a paper presented at the
International Congress on Catalysis in Paris in July 1960 (Ref. 2), according to
which modern theories of heterogeneous catalysis are completing each other. The
electronic theory could contribute to the extension of the theory of multiplets.
Based on this theory the academician A.A. Balandin has worked out the study of the
kinetics and mechanics of the hydrogenation process (Ref. 3). The kinetics of hy-
Card 1/3
R/003/60/011/011/002-/007
A124/AO2(
Soviet Contributions to the Study on the Mechanisms of Catalytic Reactions of Some
Hydrocarbons
drogenation were thoroughly studied by S.E. Yelovich and G.M. Zhabrova (Ref. 4).
A.A. Balandin and N.I. Shuikin (Ref. 5) have studied on nickel catalysts the rela-
tive speed of hydrogenolysis of different combinations. The hydrogenolysis of C-C
combinations has been discover(!d by N.D. Zeliriskiy, B.A. Kazanskiy and A.F. Plate.
Based an B.A. Kazanskiyts experimental studies, A.L. Lieberman and A.F. Plate have
accomplished the geometric representation of the process. The kinetics of the
heterogeneous process of the dchydrogenation of cycles with six carbon atoms was
thoroughly studied. The equation of the dehydrogenation speed
(C)
'Id = Kd (C) + (B)
in the presence of metal catalysers has been established by A.A. Balandinand N.I.
Shuikin for the first time. AA. Rubinstein, N.I. Shuikin and their assistants
(Ref. 6) have established that, as more Pt is dispersed in the carbon, the dehydro-
genation synthesis of the cycloliexane agrees with the intensity of X-rays reflected
from the (111) faces. A.A. Baluidin and M. Isaguleants (Ref. 7) recently studied
the dehydrogenation of the cyclohexane (I) and decalin (II) on Ni-Al 203 and
Card 2/3
R/003/60/C~1/011/002/007
A124/AO26
Soviet Contributions to the Stud5- on the Mechanisms of Catalytic Reactions of Some
Hydrocarbons
Cr2o-A-Alj03' IN. Nicolescu and A. Popescu have confirmed their investigations
condi5cte on the interrelation be-tween the electric properties and cataly-tic capac-
ity of Pt-Al2C'-A, Ni-Al2O,-Pt and Mo02 _A120?ccatalysts. There Is the possibility
of an interdependence be ween the, electron theory and the theory of multiplets
for the cataly-tic aromatization )f hydrocarbons. There are 7 Soviet references.
C ard V 3
NIKOLESKUP I. V. (Nicolesell, I. V.1; POPEM, A. [Popescu, A.]
IV* Electric properties of the nickel and p3.atim= catalysts, used
in the processes of the arematization of hydrocarbons. %v chimie
no.1:115-123 161.
1. Universitet im. '..i. I. Parkhona, Bukharest, Fakulftet khimii,
laboratoriy% organiheskogo kataliza.
S/06 63/000/001/630/C61
B 144 X1 06
AUT UJIS ~erban, G., Nicolescu., 1. V.
'r IT L -1: Solubilization of alkyl-ikromatic hydrooarboAs in solutions
of colloidal olectrolytes
PERIUDICAL; Referativnyy ,,.~urnal. Khimiya, no. 1, t963Y 110, abstract
1-B773 (Ser. ptiinj. natur., v. 10, no,* 30, ic"61, 141-150
. Rum. -, summaries in Huss. and French] )
TEXT: The solubilization of ~umene and diisopropylene benzene was studied
in solutions of nome surface-ictive aeents (SAA). The following
conclusions were drawn: the jolubilization of hydrocarbons increases with
increasing concentration of SAA. Solubilization depends on the nature
both of the SAA and of the hydrocarbon. Additions influence the
solubilization of hydrocarbonn, Na 2C C)3and particularly increases the
solubilization. In all cases a change in the solubilization rate was
observed in the SAA concentra'ion range from 0.6 to 1.5%. From the SAA
3tudied, the sodium salt of i.;ooctyl toluene sulfonic acid gives the
Card 112
Solubilization of alkyl- ...
hi.,tic3t solubilization. Ab3t.7acter's note
5/06 63/0GO/001/00/061
DI 44Y31 86
Complete translation .1
Card 212
RICOLESCU, I.V -., prof.,dr., IaLI.reRt al Fremiului de Stat; TRUIA, Maria
Eleboration of some crd",eria for the selection r.A' solid catalysts.
Rev chimie 4"Itin petr 13 no-11-9-15 Ja '62.
3. Membru al Comitetillul do radactio, "Revista de chimie" (for
.Nicol escu~
faco,,.mcu, 1. V.
Research on the activity ard st9lectivity of the cat-
alysts susceptible for !.romatizing and dehydrogenizing
hydrocarbons. Rev chimie 7 no. 1: 35'~-367 162.
1. (centre de recherche: chimques de 1'Academie de la R.P.R.
at Faculte de Chimi..~ de 1111niversite de Bucarest.
L 3o763-66 Ewp(i)
ACC-Nks-A 0250 SOURCE CODE: RU/0003/65/016/11-/0550/0560'
AUTHOR: Nico Grul
lescu, Ala; La.,_ Haria; Nicolescu, I. V. (Winner of the State Prize;
Professor; Doctor)
ORG: ResehLrch Center in Organic Chemistry, Academy of the Socialist'Re ic of
Rumania (Centrul de-Ce-r-c-eTa`r-1-UFUhimia Organica al Acadiii~ne Republ-icii 6ocialiste
Romania)
TITLE: Active alumina as a support for catalysts
SO(JRCE: Revista de chimie, v. 16, no. 11-12, 1965, 550-560
TOPIC TAGS: alumina, aluminum hydroxide, aluminum oxide
ABSTRACT: A critical discussion of catalytic aluminas. The authors discuss the
structural forms under which aluminum hydroxides and Odes occur and the correlation~
of form with catalytic abtivity; surface chemistry and physical properties are also
examined. Experimental data is cited to show that catalytic activity can be raised
2 to 10 times by influencing isomerization activity through the introduction of
organic surface agents in the precipitation medium. [Based on authors, Eng. abstract]
[jPRSj
SUE CODE: 07 / SUBM DATE: none / ORIG REF: 003 / OTH REF: 037 f
SOV REF: 006
UDC: 661,862.22:66-097-5--
NTCOLRSOU, L. AND OTH7-M..
Monsaturated fatty acids extracted from the fatty acids after the oxidation of
paraffin. T. p. 57.
ANALTME SFRIA STINTLOR NATITRTI. Bucurasti, Rumanla. Vol. 7, no. 18, 1958.
I(onthly List of East European Accessions (EEAI), LC, Vol. 8, no. 9, Sept., 1959.
Uncl.
NICOLZL;('U L
--I =--~
".Jorr.e romarks on the modulus of continuity.
P. 2 7 ',Buletin 'Aiintific. .,)'ectia Dc- 3tiinte '-Latematice 3i FjZ 4C,
c L4 -1
7ol. ), no. 2, 1~,57
Buchare3t, AurTkwua
30: ',Ioithly Indey of East European AcceS31ons (KIAI) LC. Vol. 7, no.
April 19158
dir ~c'-second-order dif erertj:,,~jl )f ti~o zjeconj or,
(:r aatea-,Lyls SenFe. In 2-'-.
aJIUL JE i-illl-
T; C (,~c,.de:.,da Rep-Dlicii op,,dare ~-.omine) 3ucurestj ',-V;mania.
Vol. 13, P.O. 2, Ic 5-;~.
:,'ontlil-f Lj:jt. f ~~-ist ean ikcce: :'o.
"T 71, -ji
.Pr.
r'C' 7."'Tr,, 'J.
-.1) LC, 'J~j
Ea -ul'o"O'n A~C-
Urr I
NICOLESCUS - if. J.
On an extension of a Bogel lemma. Rev math pures 5(no.2:451-455
16f , EFAI 10:9)
(Spaces, Generalized) (Groups of points)
NICOLESCU, Lilly-Jeanne
On'the integrability of Frechet differentials
Rev math pures 5 no.)/4t625-653 160.
(Spaces, Generalized) (Conformal mapping)
(Integrals) (Differential equations)
(Groups, Theory of)
of an arbitrary order.
(EW 10:5)
j'ICOrEl3CU, Lillv Jeanne
Direct differentl.al of the second order in the Frechet, and lateaux
serse in the locally convex ipaces. Comunicarile Ar 31 no.12:1431-
14.115 D 161.
1. Comunicare prozentata do Al Ghika, membru corespondent a2
Academiei R.P.R.
NEOLESCU9 U-11y Jeanne
On the equation wil,;h variations, attached to a 1-inear syszem .dth
mixed partial derivatives of the second order. Caminicarile AR
12 Yio.7:783-789 -rI 162.
1. Commicare prezentata de Al.. Ghika, membru corespondent
al Academlei R.P.R.
IIICOLLSCU, 1'. J.
On the analyticity of the dirE.!t ser,cnd order d~ff'erentia'
in Gateaux's sense. --.ev math ID- reS F no. 2:305-30- 'r-,3.
1,
I - .3 .
"~..Iements of mathematics" by N. Bourbaki. Vols. ?-3:
"General topology." Reviewed by L. J. Nicolescu.
Rev rriath pures 8 no. 2:326-5.28 163.
NICOI-ESCU, L.J.
On mixed direct rlif f-irentiation of vector val-it-d ",z:c-.,-or.5. mp-*h
piwev 8 no,4,6.,.7--b52 '6 3.
CU, Lilly
Cn a ,4e.,-, ~- m. a!, valL~- :-. --'- n- ..- : -. ~
I t-,5.
1. :n2t~ '. '~ --e c ~ !.'- : --- ~f '.-.e --Lranian Y.
m~ -,,ed A-u.--..t; ~ R,
NICOLESCU L .1
-- - . I-- -
On a theorem of mi!dium. S%!id-' mat -i, ~,4.
TEODaMCU, St., conf.ing.; 'IJGCF,[BSCUjH.,, ing.
Geometric elements for calculating the jacket evolutes in
spherical pressure tanks.. Petrcl si gaze 14 no-9t457-465
$163.
TSODORESCU, St., ing. ; HIGUABCU, M., ing.
Strength calculation ele,7Lants fnr sph,~.rrical preesure reserv,.--ri.
Petrol si ga-ze 14 no.12a629-638 9663
L 3F5CO-66
ACC NRs AP6027677 rib, RU/ 4/66/Wi/001/0021/0028
AUTHOR: Nicolescu, Maria (Bucharest)
ORG: none
TITIZ; First map of Wallachia
Constantin Cantacuzino of 1700
SOURCE: Natura. Seria geografte-,
TOPIC TAGS: map, cartography
he ma p by
ABSTRACT: An analysis, from a cartog. p)J - aiz~ eographic point of view,
oi the first map worked out by a Ruff,ani,i icholf The ma, of Wal-lachia of 1700
by C. Cantacuzino was the first to properly locate the area on the globe in terms
of geographical coordinates, contains names of mountains, 1. -es, etc., as well as
a 6omplete list of towns, market tolqns, villages and monast ies as well as other
ini4eresting features, and was used extensively by 18th cent., .-y cartographers in
coifipiling general maps. [Based on -.u'thor's Eng. abst.] [JliS: 36,4571
SUB,CODE: 08 / 5UBM DATE: ncne / ORIG REF: 013
Card 1/1
MXQUA/ftsical Chemistry - Kiixticu, Combustiou, Explosions, Topo-
chemistry, Catalysis. B-9
Alia Jour: Referst. 22wrual Kh1miya, No 2, 1958, 3904
Author : 5AQUIcul Vaestinu.
Inat :leadew of sclen-m of Rumaa-
Title :Study of Catalytic DehydrqVination of Some Alkylbenzenes.
I. Activity of Crgq~ - CUO - Alf3 Catalysts at Dehydrogis-
nation Reaction o Isopropylbenzene in a - Methylstyrene.
Orig Pub: XhIm. gh. Akad. MM, 1956, 1., No i, i4g-16i.
Abstract: The delgdrogenation of isolpropylbenzene in Lr\-methylstyrene
was studied in a flow systam at atmospheric pressure and
56o to WO and volwie speele v from 0.20 to 0.60 in pre-
sence of mixed catalysts Cre - A1203 11 : 89 (C-1), CuO :
AIOOj + 8 : 92 (C-II) and : CuO AlA = 10-55 : T :
827.45 (C-III) - The opti=i yfaida of 84 t5 88. 5% were ob-
tained at 56oO and v = 0.4 or at 6000 and v = 0.6 in pre-
Card 1/2 -29-
RUL!i,NL'% Coamochemistry. Geochemistry. D
Hydrochemi8trY.
"bs Jour Referat Zhur--KhImlya, No. 11, 1959, 38166
"uthor Nicolcaou 1,1.
Inst Not given
Title The Fossil Fauna of GaYpsum Deposits.
Orig Pub Natura (Rumania), 10, ro. 4, 14-19 (1958) (in
Rumanian with. English Lind Russian summaries)
.'O'qtract The author gives a detailed characterization of
the fossil fauna of gy sum deposits found In the
pre-Carpatiar. region Xothills17. The preci-
pitation of the gypsum took place In lagoons
where the marine waters accumulated living or-
ganisms which died as a result of the high sal-
InIty. -- E. Cheplzhnaya
Card 1/1
74
NICOLiscu, Mauriciu; dr.
Limastone and Its contribution to tl,p water supply of
Mlet-gorologia Udrcd gosp 5 Tio.4:262-2b6 160.
NICOIESCU ~~uriciu -
Salty heliothermic. lakes. Meteorologia hidrol gosp 7 nc.1:52-56
162..
NICOLESCU, Mituriciu, geolog
New Jata on the geology and hydrogeology of Techirghiol Lake.
Meteorologia hidrol goEq) 7 no.2:101-108 162.
?k
r
NICOISSCU, Hauriciu
The geology and hydrology of the Mangalia Lake, Rumania.
Metworologia hidrol &9p 7 no.4:255-261 162.
"TICOLEISCU, M., gecio-
I. s
....
The Buzias carbogasou-ij waters. Meteorologia hi~Lrol
gosp 8 rio-3:137.-11,-l 163.
NICOIL,")C,:-! , Viauriciu, geo I otr ~ 511cure- ti j
Thei inineral waters cf' - ~snad~ Na, ira -,eografie no. 1:
50-52 Ja-F 'f)4.
,~: r . -. .
, : *,.,, , , , A )11. -1 1 ,-, r - 1 -- , . . " *, 1 "T: I r, ; I .;'I , 'I [~ , . . . j
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.- .. - .. ,)r I I ~
"Prom-, MY 9 - CA
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'
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ne
). (
,
(
manian. Rarman and French sununaries)
If m is a function of m varmbles, x=2 or 3. m is caffed
hyperbolic differentiable at z if there exist A(z) and
-a(z,Ax) such that dt_.u(x)=(A+a)Ax ... Ax and
_
0
t
a-+0 when Ax--*O. A function u of 3 varia
les i:;
caie
d
bidimens onay differentiable at x if there, exist A&)
and (ri(x. &t) (i=l, 2,3)..such that all cr,-.*O when x-.*O
and
==(A2+e~&tt&v*+(Aj+7j +(4%+(Q4XAX1.
Then if u 4 fbidimension4y differentiabk at a point z. i
it is bi ontiamous at x, and z is 2-dimension-
ah Vc differei=le there.
M. At. bay (Urbam. M.).
' 5, 7-
dip
dft*046
We
L MalL Fi7_ a (1951) -S16.(IOS2:1. (I?D-
S07
Film& iiininjAziI4
,
-66nsitiero -varlo-u
v
q Mer~oa~ f
e ,
ower-of a ~riat flinco a
considers idme. of their mutual pi C fibial oq.
( v,
tini
reg
re~.
AAxAY
-
-where thks~
two latter limits are regular limits". The
:
4
authar - shows that if the-$~hwarz wimme6ic derivativve ,
-PuIW, Pu1W, and Du are continuous near'(xs, yi) then
D*u(x#,y#)-D#(x#, y#), IaaddItiqp,'J1Pa/&,O, AulAY exist:
near (x#, yo). and i f continuous- a.ear:
~(xfr ye) then:'
va PIM
M. 0. AW4 (Grenoble).
. .. ... ..
vrF -'-'L :7
affa
-H~
d6=
dr-
wow"to eA---- P Ct-
NO-
a KOM J,
boulida PWchl m
Q) bo+ the-,Gree 6 ction i d let
ction T(P)' teke wegmiAb in -bi~the'
The fun re
e Gl
we, unit i ~Plu fflp3pel
t
phi i -
i- RcvrAni&ct),
The real alijact of this artiele 1* %, stwly of the "utWant to the
p0,",
(111"u 0
When
n 4 - 01N)
IM *4 At the OK414tiOll 4( WIV4VA lelatM wiliflAri, pmblel"
File (1mvity".111thor fl-forii to (fir entire "tiffoo fg
nio - Ali (woo - u
an a thernual furjcti~jn' t% hig-1: is colitinut"Is in ex-twel knawn to-
.dons, An& vaW the known w)1u6mA to A~fxwc- e[juation poly-
thermal funutiotis of t1w p" onltr.
In (he ArA ebitliter, it in show i that xll lkilytherintil finictiors of
the p" order in the vpetnialdomain am anitlyti-tal.
In clups. 2 and 3, issing fenutilet, extewinnit tire e,-
t4litifili'M Gif polytherruni 64-6."A "( pl-tirder.
Its the Ihst lourftgr;ipli 14 diap. 3, uuthor iotraduveJ p3m-
helically anllytir Njloqoi~ A11-11 IJF(- 1141110.11 As 0 flinction,
U(Z't) in (lie ifitcrVal 0 < I < I/ V., if theY cars lie Written ilk the
facm
u(Z' 0
Chop. 4 U devoted to botmd&ry prob6Wtor t& bounded inter-
Authur tLen aulve" tho Dooblem: Wad a PolytbermAl
(Wtka of the secoud Ord" co the lawgior of a redon A It Is
dwwa Mat tM solutkn of thi- ptathin mum about &xu the
solution of four liarar integral eqfations, of the VCAWM type.
The statement of the i *probleni "J" a itudy of a special W
thern,a], functior, hayiag a ctats.'* type of d6scantinuity on one
of the bounding Curves of A Audor calls this function "the bi-
thermal potential" be-auao of the pad -.t plays In the soluMon of
thfa probWax,
Im chap. G. authm dexonstittes, that it the fmxWou ts POSSM"
contlauous putial wivatives necessary for the fumtka of the
differential operstor (jou sod if theme derivativ~m we seledively
zZgebtakally iner-Aved, then the integral obtained fiam, P&wn
InuWal by a change of variables must be derivable at the point
A - 0, wher. the iatepsl isimneidered aftmetion oth, p.
The final chapter of this paper is devoted primarily to a study
d the properties 6f polythennAl fuuctijn% defined for the interval
Ogi4;4. I'he WIL, tool throughout this study is a theorem of
-functions subjected to
Carta;n Conditions of W-I!Wity as = - ..
Tho Lut paragrnph -1 thit ehapwr in cwicerneil with wib-
theraml functions (of order 1,2,3) ."nrd in the interval (0, sf.
Aut1wr indicates the differentv lietween his tWailious for suh..
Otermal functions and dV4-" dcfintj by 1. in 11115.
USA
SO:
U,
"CrgartizP-1 manifestati nis withi-n c--rlre~~ of .1w;Lanian-Soviet Friends-,iL '.orth"
"19, Issued by the Riz-anian 37ocict~- o-~ a:-Z
--I FT-'TCA, A., 701- 11, C','- 1',5L-- z
O:A:-.1%- l'ist of -,uro,,e:.r, xce-,s!jn, (ZLIAL), L~, Vol. 4. '.OV
1~55-
Teolorescu's :--etiode vector.'ale- i:~ -~izica :-atemrti-ra'T.'ectcr-aI
in '--,athe7,;Aica1 -hysics j ; a !:)cok review, 516, srec a-., t~,e --Z:
ociet,~, of '-at,,em~ltics a:-:r] 4 C S r; t r~
Vol. 11, '*ov. 19r4. 7'ucuresti
tM-:1, 7 i-st of '.a~-,t *I-!rc,p- an '.c-essi. s,
urc,-.
Nicolescu Hiron La strurture des solutions deg
-Nuations. !;s partielles du type elliptique OUFTU~'
type parabolique. Magyar Tud. AR(l. Mat. Kutat6 Int.
Kbzl. 1 (1956). 465-479 (1957). (Hungarianand Russian
summaries)
In thisarticle, the author summarizes his researches on
the polyliarmortic equation Avu(X, y) ~((r-/OX2+02/ay3)pjj
=Oand the related polycaloric equation (01/0.0 -alai) j)u
(x,t)=0. Fliqexposit ion includes a discussion of thepolyliar-
monic and polycaloric functions as wellasa statement of
some of the interesUng questions that still remain unan-
swered. Complete details may be found in tire author's
"Les fonctionspol),harnioniques" f1lermann, Paris, 1936)
as well as'in Comment. Math. ff~lv. 10 (1937/8), 3-17;
Akad. R. P. Rorrilne. Stud. Cerc. Alat, 5 (1954), 243-W2;
MR 16, 7091.
M. 0. Reade (Ann Arbor, MiCIQ
Gff,