SCIENTIFIC ABSTRACT NEIMAN, M. B. - NEYMAN, M. B.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001136810018-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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makt* umbsood, A further erAmpic ol thij " to the tamediste pruttocts into the Initial rescuats. Specifically,
reaction V + 4/1 fit - U114 (Ifurke and Smith, CA, 42. it adwqrcion of the gamous mactut on the surfwe 41 the
KUb), the balf-time ol whick passes thromb a mitt. (Le. coad"wd reactatit it (aUdwed by the famulkis Of an In-
the rate thsough a man.) at 2251. For the reaction be- terawatat that ran tith" CiVT the final P"dws or re-
t - FtSr and the a&ry S-1-t. P-dwing Sufft*. r has 4 Cenerate the taittas rege ant. am ands. for the Woctloa
min. at W. wo thm a man. at 62'. fallowd by a -9w pmicd, the vetatius i/r - a - w, wbere a - r - r,. the
(AU WfAb (USIbCf fi%i"g ICUJP,. XUAS axr%,VmdiaS to Xv- dLfmncc betwon Ube temp. of th- eipt. and the temp.
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the temp. mace; al ict- le- IW=ftk-t to
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TIK' tuto, of r Al 2*JJ-K-., god its 1u1VwqUC"t rise At still Cur%Vs. N' 7,bm

I IIII j
111-7,N M. 5., GOWDI3M,11A G. la., .111 AKCIA 3. 1. and 3~4`M R. 75.
51f,'5- GDR0D1331"-',IA G- Ia., NEII'dk'~ V. ". J171AF(WA S. 1. and SHMOL R. D. Ef -'ect of
cam.rhor and iorlidn on -hosphorus metabolisul in rato '*r T's
Dz)~--I--di Akalemii Nauk 33',R, Ifosccrw 1'150, (1-'~"I'-~3-,) C;r:.,T:ho 3 Tables 2
A study of r~hosphorus netabolis-m urv-ler the influence of carm,-hor (I) -and
morlm iodide (II), usinc- ra,-lioactive phos-phorm, showed that 'he I increases
phos-,horus -,etabolism in various tis-;,ies 'h- rat, while II has 'he =7~osite
ef!'ect on nhosrhorus ietanoiism in frog miuscles. Tile kinetic i~~thod o' investit-a-
tion licel 13 r~co-!:,erided for thi3 kin,! o' wor!~, sirce the asli2l elhods
le!id to F,ro,33 errors. Ft~-s - Za -rel,
SO: Excerpta 1-:edica, Section II, Vol,-ir~e III 711o. O~

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HEYMAN, M. 13:.L MILLM, 11. R. and 03HAI-OVALOV, Yu. M.
"Inv,~!stii,,ation of tho lootopic -,,'Xchan!re of Broiaine 3etween I rr)[)yl aromide and
Sodium 3rouLide in an Alcohol Solution". Dokl AN 3SM (Novaya 3eriya), Vol. LCM, No. 3,
1.950.
Inst. Chem. 1hys., Acad 3ci IJS3R
SO: W-18143, 1P May 1951

. . I I... I I... I.
N,-VAN. M. n.., -1. V. and KDOIT!EEVA, A. I.
IIA New Method for Detemaination of Solubility ~,-rith The Aii of 'tadioact~.ve Indi-
cators", Dokl AN 33SE (Novaya 3eriya), Vol. LX)rV, No. 5, pp 719-721, 1950.
Inst Phys Chem, Acad Sci USM
3C: W-17381, 16 Mar 1951

USSR/chemistry - I:ivotovem VAY 51
"Tracer Atoms," Part 1, Fr.of,M. B. Neyman, Dr
Chem,Bc! I~tiair of Piiys CMm' GorIkiy State U;
.,,Lab-Of Oxidation Reactions of Hydrpcarbons, Inst
of dhem Phys, Acad Sci USSR
"Nauka i Zhiza.'" Vol XVIII, No 5, pp 17-20,
Presents geneisl discussion of subject, emphas-
izing-applicatIons 1n fuel chemistry and petrol-
eum technolofnr. Describes USSR work on kok-sag-
hyz, wherei.n,under application of radioactive
sugar, syntheisis of rubber from sugar in the
plant was estAblished.
19M3

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c2, rr' -if, r n.;- neiuc i --~n -T~ com~,.lisLion of' bil~.;nne rever
r C
-in ox.:r-'-tionof r p r.
al

att 'LlItt keutdo in dM11,91C 4dullan M - 11 Nthila" -110
vo XV Shmmalow (Ac4d. %,I, I I S S'V7- Uti;wvw,
104"y Akatil~ Nii*bS,-V S N 17, ON (4 filf.1 I Ifto 1,61,
'-f quhAvt Wds fawfalfttal.j its . mtjs~ ..I 111 11101.11-1-
Ofeellcyl 'Iff dt(d 10 milliuma" NaRr I4CC"f with 1A'I"'-
active Be" In Iful "d. NOW 111C thtd~wtlcr uto mots
(I mok -1 jec.-Ij at 14), W, 40. A"M 4)1*, Age 10- k - 4p 6,
2.0. M..". Ituf 46. At equil , Ot" 14 "Indifs, diord-utrA
I.fwcvn owl Naffc. The ON-tivakm vfq-
'117 E - f 11.5 ketf./tw4c. Ike swiv fact,* P - I X W 1,
,as Compared With F - 114m. 11 - '_1 x W I (4w the radwip
IWtWVCn PfIff AM] NAHC (C.A. 45, :! "')mt 1. 1 he (ACt IIIAC
011;CHCAN& M11409" Etc 41"Ut 2A :01 ((tut, . ;,pWI
AXI*fltl dmfb~fhtft Am wthe kmfi it, 1-he wr tit iuwjt1AN
'%.64419C 4,ft"j.1"fas
I's CS(ItiltrA. I ItJO, UV..NI CII, t'lj(* 1.11,
ft 1"NKV11 41 -41 IS t., VI It. tmdr At 1.2 v %, 11.40

C
caboky,graef is (he raw WAW(di foe (be eyedledo Of
rubbeir Is 1kaft %I. R Neltutu. A A Wokol'rv, And
V S MA01"micV, PAN,( '11". N'toch S-S-S.& To.
107 714 11151) Mav" 4 k24aighys 1,14ni- *vre p"hil"I
daily U ith a 150' .040. (4 C1l-lAtWkd MACTI)w (vocits. a %mill
Atilt. of g6~1 Atict the O'C"I. WhiCh Were ~U%JWWW ill A
""O-Ait ChAtUtWit, were trifitil of Littic dAdy. laid (fie C"
a"ivily wAo -Irld Tlm C"' iopgra" in thr Weil within
lkc I me 10 dayt tit the expu. aud k% mAM locatkas to the
Abber pctWr was pguvcd try 6olatigis of the pucificd vuhhrr
Ifetto. of it% C" Activity. No C" wAs Nuad ta (he,
=
Water-Wi. cmpmcot~ but was found In MCXO~4. own.
g-ocivats. Aptiareatly the Latex t"ests is wAjtqti~d. not
with -upirs at visch, but with Wave p"Kicicis C4 their Jecra-
dA(iQn Or d(AUC4. [ICK"ItdY thiS ChAVCe CCV(M iU the
Wembytrucir okourv of the raceii. Tliv Active sucrow
was It"pd. WaloCk-ally by keepike; Turkish tobdcm plAnts
in an AtM. rkt, in C"(h. G. It. KOVILaptiff

USSR/Chemistry - Isotopes
Coubustion
21 MaY 51
"Synthesis of 2-C14-Propene," M. B. Neyman, A. F.
Lukovnikov, B. Z. 1ofa
"Do-k Ak Nauk SSSR" Vol LXXVIII, Ro 3, pp 493-496
Use of 1-Cib-propene-1 it, combustion investigations
is difficult, because (1) its synthesis is com-
plicated, (2) the double bond migrates at high
temps, and (3) there are many side reactions and
low 4ield of radioactive roducts. Synthesized
2-cl -propene-1 from BaCl-& 03 according to the scheme'.
C14o:) + MeI4gI- MeC1400V
Q:j * (jja(~,l4oo)2Ba-+ Me.
c.14o mex14waxe '# Ch3 .cL4j5scjj_O.
.Me
186Tu

S. G.
d9464ce.
Chem Plays.. Ac44.
Srl~ US S R'. M'hcuw):'- Vittay At". Maut S S~SR.
79. KI-W 1951).-P4~Artw-mis In SON. In U)", ifio-PrOff
l
u" a bickgToond of 0 1 N Pt'SA),11 gAvc the Ix"
tentiAlt (ag4init uld. Montt) MeS(hCl --0 02, Ph.KItCl
P--%lc4)CONJfCJf.S(hCl -903, P-CIC-11-SkhCl
05 v , un;affecte) by thepif between I an,] Is Suppm-
sion of the m2x. "quires 0.1% CriAlin. The no. of elct-
trons invrAved in OW r"Juction is Z Canwqut-ntly, the
rcductkara Is Frpreicilled by TISO.C) + 20- - 143-0,, + Cl-;
formation of Cl- itans in the course of the electrolytic reduc-
II'm of I'hS%Cl. ard jw-AliclinS it, was drrnonsvAted
'Itir'-ctl This schtme acceints for the cA the
refluct L. JKI(eflflAl Uf the Pit. POI4FOV2PhiC MIUCtiOn Ct
PbS,Chlf (product of the reduction of M%Gcl) cave a half.
wavr only at - IRS v., ident" with the It wAvc at other
,u:ids; the antan PbSOj- is not retiticcd down to -2A Y.
The t"luctim of PhSO%CI to PhSO.11 confirms the %true-
ture of the lAtter with Met to GIMt booding of It to S.
The rate Of hYdrOIY=j the sulfazialor-WeS is of the Ist
order. independent at the r.11 between I and 9; ;above pit -
9, the fmc iacrrwm shar 1y. At '25* t pit - 2. the tit.
order rate constil. for tE e b trolyu-'saaar , for kfe%khcl,
10% - 0.211, anti for PtISOJI1. 1014 - r.0 wc.-I. The
rite of hvdf'AVSi!' is Stowef with R.S%Cl reluced at lower
poteratials. The r-luctican potenti-A Is Mate pars. with a
mixt neir R. N. Thon

Ey q 7-----_~

ydmism,
'On feet&dd ppers. -Ii. U*. NewAn, N, u4b"Aw
;
-
tutfil. 7. Lulowtvikov. - 7,141444kod. NoWil S S-SX
ti, T. V. WtR and K I Maw* CA 44
Ailapt t he mrthads ef pAptr c iramrdoc-.
n.phy ta ticaipLAm, hYdmqJiohk~Abitvrww d~c chem.:
t, "Utatmani prq"ai by Kola ~ No. 01.) bi tuciii ~TW
4 polar OR
method ciumit-U of ~mpladng Ch. grou 4 of feliv-
-
;~
-
i-
*
h
i
1
h
h
mll
=
v
wr
e
c
kscby At
ereby
air t
jmups. t
y
'
alwolpiper. The optimuns emlitions (cruetykajam ace..,
dibetmwC The paj~ff. tbut treated, h aised tcr the ogn. at'
Cie' dw nes of fom=Mehv&, &cvt*Uc-

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oil

NEWAN, Fx. B.
USSR/Chemistry - Isotopes Sep/Oct fj2
"General Mlathod of E'tudying Co-Prec-Lpitation and
Adsorption With the Aid of Tagged Atoms," V.B.
Miller,'~M.B. Neyman, and L.A...Sazonov,Jnst of
Chem Physics, Acad Sci USSR, K-_~Scolw
- Zhur Anal Khim., Vol 7, No 5, pp 269-280
Developed a general method for studying co-
precipitation, usin3 radioactive isotopes.
Studied the relation of co-precipitation of
SxCr04 with BaCr04 .9t different relative concns,
at various pH 1ralueB. The rrax co-precipitation
261T29
261T29
was detd at a defin1te pH value. A spatial dia-
gram of the co.-preeLpitation of ftCr04 with
BaCr04 was Dlo*~ted. With the aid of this diagrarN
improvements were made on the chromate method
of separating Ba from Sr.

1
4F87.41 Ira
41. Owtv Mar,.. Ar.1 Sci U .4 S k
"d N.,44S.'s "i R. 11J. i" Nvj.,2,
I V k,414 anit lr, .1,14ug. I IS kt t( I. it
4.11,11w -laym.,lots rtalvail, gmm"I hy flittpk".
A. f 29 ftj (IA4. Mr. is. mt, ,I "I fim. hilt,
;4 Is lit", f.An..f Ifisq-04h .4 Ar - its .4 ftw , tit
It"Ir. the Wk. I. I'mitiatit"'.1 tki IIAV ... mte fliAl'of lit..
ArW tit IN, -olit , NIIIA!, Vt-ms (1w ,10mitum-
:1C4K-fJHC1g MC C1W4(&V% Of t4' LUd.ALV 4-141C114 HI 11147 COUPW
'if OW 41WAV WOU-111 (lit VW
N - F*,o#q4.t4% kJlA1rd.ItA I -MA'. IM'-All
iii4941V WCA Of 11W 114 41f0p. 461 IfIf FAIC t114121 it# OW III--- tt .
,# dw Avilvity, - n41 . IN, 11kovkh (ov HA Pr4cti-
cAlly the oame P."I it, futual by integratitm,4 the difkn-mLal
Thtrdfilctutctic'. 4110 ('11 Ike t(IIA
"Mm Ad
flu- Au-id, Autd4vd. N #, [(.a- Vi vs ill, Ail
A, to - N N. (1w dttiv. JA 4, A4,tthi NO with imv~,,itljg
%vm~ of tW iwid. Al low concts.%, r < A. it thouist itmi
failtirtIM64 Valura" -, atul at bigb,vtft~41 e ~poK. it ofti"Alif
(~Ui tit N. Ffww mvl~ t,,C,,l its V%pt.. ill% ~
'" Ad ""It 0"N Am a dr.,ppiciplig eA16M'. ill All mg-fret
N aq .4n. C4 Lic), at ~.Is * . curt., 44 , .. . faurtwo
A4 c ""V cam4truct"I wilb the Aplid of .tuic- f N 'Itrid
(rain 2 valtict of Ao. For (CIA10t, CSKICtlidlf, -(III-
C411X(NH, 1.44C(Mi. atflif. P1tCjjX4h1j. itul AcUll. the
VXPO twitiolit, v"T
CAW vatace 41 1 1VT in mch fee Ilorr"Witt ftith thr
rspili v4ttus- "a OW 4."J"Apolms of %rr. %1". J~-" 114.t~
me Out .micut'llitict (4 W-t. ItIctc I,.
a dr(atite kilactic Nmittiitica %if I to tbv'd~
CkatrCt, Of It * kM* it* 0 4. 44 WvAk leids. s tlwm
. til -

USSR/Chemistry - Padioactive Isotopes Aug 52
Halogens
"The Exch-an.-e Mechanism between Alkyl Halides and
Hetal Halides," M. B. Neyman, G. V. Maksimova, and
Yu. M. Shapovalov, Inst of Chem Phys, Acad Sci USSR
"DAN SSSR" Vol 85, No 6, pp 1289-1292
The kinetics in the exchange mechanism of halogens
between an alkyl halide and a metal halide were
studied with the aid of sodium bromide tagged with
radioactive Br, An eq Is given for calcg the rate
constant of thIs exchange. Presented by Acad N. K.
Semenov 3 Jun 52
23ftlO

MR/Chemistry - Isotopes 11 Sep 52
"Inve.~tigatfnn of the Reaction of Formation of Thio-
sulfate From H-S and SO, With the Aid of Radioac-
tive Sulfur," M.B. Neyman, Ye. S. Torsuyeva, A.I.
Prdoseyeva, P.S. Shantarovich, Inst of Chem Phys,
Acad sci USSR
"Dok Ak Nauk SSSR" Vol 867 No 2, PP 317-320
The mechanism of the reaction of the formation
X& from SO and IL;,S was investigated usir4
0203H~,05 an~ inactIve SO Th s35 was
acTive 2;00_leo~go to B&s35,
prepd by-reducing BaS3504 at
235T26
vhich was decomposed to E-P, 35 with HC1. The cen-
tral S atom of the thiosulfate mol is derived from
the inactive S02. The peripheral S atoms come
from both the H~S and the SO 2 Presented by
Acad N.N. Semenov 3 Jun 52.
235-L26

I-L~KLISOV, G. I.
2. U331 (6W,
4. Carbon - Isotopes
7. Synt'-Iesis of acetaldehyde tag,-ed -with radio-carbon. Dokl. AN SJSR 87 no. 4, 1952.
Radioactive acetaldehyde was prepd In two ways. In the first
procedure the methyl &Tgup is tIgged with CI-4 and inthe other, the carborql
group is tagged with CJA PaC440 as a starting material,, and LiAM4 as a,reagent
forthe reduction of Et ;cetate Oe used In both cases. Both procedures are
described ladetail. Presertted by Acad N. N. Semenov 8 Oct 52. 256T12
9. MmonthlX List of Russian Accessions, Library of Congress. February _1Q53. Unclassified.

MATRAMOVSKIT, S.G; EMYMAN. 14I.B.
Pol&rogmphic reduction of sulfones and of sulfonic acid caters.
Doklady &ad. Mauk S.S.S.R., 87, 805-8 152. (KLRA 5:12)
(CA 4", no-13:6271 '53)
1. Institut khimichaskoy fiziki. Akademiya nauk S.S.S.R., Moscow.

F VM fl N,
I The Use of radioactive carbcaCl, fa;;:mcarbon oxl~~
Investigations im the [Lisa
KaUlaa ir KraMr-ailitos, Sp"Obviolit 41 Sir srs
1913. ~ M-00,-& ritttlswi is dewtibcii for thi chhAtia
r fmphfcsegwt. of aldchyde atte, ate, derivy. fornted in the dia
f 4 -n!-. - The radinactivity of hydrt':
curlxmsand i-f (lw(ryWt-s,NA W um-tstucif witka; ctitwer-.
[ist(ru.t3ty-. cvIJU idilvItydc-s are fcrm(.qt
wf~lll is locaull
togrilwr with vuritul other stdchydei duriuIr hydrocutmit
w4flrb,tt. Tlw Etc( 41tat ArIf and C11,0 am finind to form -
ft(41; pot dittj!~ t,t (tie oxidized hytIrrocarbon Wh(rk-
dict~q tbc dc%frucdie~ liydtwal Wit oxitfation theory.

NZMAN. N.B., profeanor,
Use of narked atoms La chemiatr7. Xhimov shkole no.4:20-32 Jl-Ag '53.
(MMA 6: B )
(Traces (Chemistry))

MSIR/Chemistry - Kinetics of JUVAU9 53
Combustion
"Investigation of the Conditions That Produce Igni-
tion of Gas Mixtures. =I. Effects of Admixed
Ethyl Peroxide (I) and Acetaldehyde (TI) on the Kil-
n,-t"--s of Cold-Flame OxIdation of BiLitane," A. A.
Dobyinslmya, M. B. Veyman, Inst of Chem Pbys, Acad
WSR
Iz, Ak Nauk SSSR 01W, No 4, pp 623-628
Demonstrated that admixture of I to a butane-oxygen
mixt shortens the period of induction of a cold
flame. With I added, org peroxides and aldebydes
27OT7
are formed during the induction period. Showed that
added II shortens the induction period of a cold
butane flame. With II added, organic 'peroxides are
formed. These peroxides are reduced at -0.25 V and
-0.6V. Admixture of peroxides and aldehydes in a
quantity x shortens the induction period Z accord-
to the lav. 1g b - k
27M

Wl
y T-- -Lq Nov/Doe 53
14 14
"Synthes is of I-C Butene (1) and I-C -Butaft
(11~*'M.B. Neyman,'G.I. Feklisov,~Inst Chem Pb7s,
Aca Sci USSR
Iz Ak Hauk SSSR, OMN, No 6, pp 1129-1131
Descr%be the sy-athesiz of 1 and 11 starting with
active MeI prepared acc to a method publishedby
them earlier (DAN SSSR, Vol 87, p 605, 1952).
2'17~'Mrlc

USSR/Chemicstry - Combustion Kinetic* Nov 53
"Investigation of Conditions of Ignition of Gaa
Mixtures. XXIV. Cold-Flume Ignition of Propane
W." M. 1. Gerber, M. B. Neyman, Inst Chem Pkys,
Acad Sci USSR
Zhur Fiz Xhim, Vol 27, No 11, pp 1617-1621
Investigated the kinetics of the oxidation of I
and the accumulation of peroxides and aldehydes In
the beginning of the reaction. Demonstrated that
addition of ethvl neroxide acrelerates the nwida-
tion of I and shortens the period of induction of
the cold flume.
274T17

USSR/CheMistrY - Combustion Kinetics Nov 53
alavestigation. of Conditions of Ignition of Gas
Mixtures. XXV. Investigation of the Cold-Flame
Oxidation of Butene (I),," A. A. Dobrinskiy, M, B,
Neyman,%N. K. Radnevskiy, Inst Chem Phys, Acad
Sci USSR
Zhur Fiz Khim, Vol 27, No 11, pp 1622-1630
Investigated the kinetics of cold-flume oxidation
of 1. Detd the extent of the cold f! am& in thia
oxidation, Derived the math relastic=hip acc to
wb1ch the period of induction of the cold fl=e of
I in reduced with increased temp and pressure,,and
274T18
ed that during the period of Induction. accumu-
lation of peroxides, satd higher aldehydea, and
croton aldehyde (II) takes place acc to an exponen-
tial law. Proved that in the slow oxiaatioa or I,*
02 is added not only at the double bond (with
formation of CH CHO) but also at the terminal ear-
bon (with formazion 01f 11).

DORINSFAYA, A.&.; HHHAN, K.7.: RTMNEVSKIY, U.K.
Study of conditions for the ignition of gas mixtures. Part 26.
Effect of methyl amine on the cold-flame oxidation of butane and
butens-2. Zhur.fiz.khin. 27 no.12:1784-1791 D '53. (KLRA 7:2)
1. Akademiya nauk SSSR, Institut khimichaskoy firiki, Koscow.
(Butane) (Butene) (Oxidation)

A,
USSR/Chemlstry .. C(xibustion Kinetics Dee 53
"Investigation of the Conditlonto of Ignition or Oaf;
Mixtures. Comm 26. The Effect of Methyl~vnine M
on the Cold-Flume Oxidation of lhitane (II) and
Butene-2 (III)," A. A. Dobrinskaya, M. B. Neyman,
It. K. Rudnevskiy, Inst Chem Phynics, Acad Sci USSR
Zhur Fiz Khim, Vol 27, No 12, PI) 1784-91
Investigated the effect of I on the cold-flame
oxidation of II and III. Derived the mathematical
relationship according to which the period of in-
duction of the cold-flame oxidation of II and III
275T11
is increased by addition of I. Found that admixt
of I reduces the rate of accumulation of peroxides
aturing induction and brings aboutt formation of
considerable qusntitles of CFE20.

USSR/Chemistry - Combustion Kinetics Dee 53
*Invest1grkt1on of 'the Conditions of ignition of Gas
MixtUres. Co= 27. Kineties of the Accumulation
of Peroxides and Aldehydes in the Oxidation of
Pentane (I)," M. 1. Gerber, M. B. Neyman, Inat
Chen Physics, Acad Sci USSR
Zhur Fiz Khim, Vol 27, No 12, pp 1792-96
F,xpts described ahow that the coacn of aldehydes
and org peroxides increases exponentially during
the induction period of cold-flame oxidation of I.
Admixt of hexadiene (II) inhibits formation of
275T12
Intermediate products in this oxidation and in-
creases the induction period. II increases the
rate of forwtion of initial active centers and
at the same time reduces the autocatalysis factor.

7n
Vol. 48 No. 5
Mnr. 10, 1954 S.
Analytical C~,e:idstrj
Describes applications of radioactive isotopes in analytic
chemistry. Divides the material into 3 sections: phys methods, chem
methods of analysis, end applications to research. Pefere to own former
works in UspeW Khimil 17 (1948); works of 1'. Daudel, Anal. Chim. Act&
5 (1951); and those of P. Sue, Bull. Sac. Chim. Fr., ID, 5-6 (1951).
261T102

USSR/Chemistry - Radioactive Isotopes 11. Jan 53
OThe Synthesiz of 1414-Pentane and 3-C14-Pentane,"
A. F. Lukovn1.kov,,'!M. B. ffe)mvin,~' A. A. Bag,
L. M. Rodionova,' 11. S. Samouklna,'N. V. BI:Lznyak
DAN SSSR, Vol. 88, No 2, pp 297-300
1414_11entutie and ~-C14-petjtun,~ were prepd by
starting with BaCl 0 which yielded tagged C02.
This was then treatel with the appropriate
organo-Mg-halide. Presented by Acad N. 11. Semenriv
15 Nov 5:2.
255T18

Kid thyde witlklr-"~
Twinit Agin Kcaction of Qx1dation of atel I
radiocarbon. l4, Ti, KrTilum and G. 1. pet-livov.
Akad. INICNk'S.S.S.9, 90, -'M-4(l953),-1T%To lsotopic lso.-
MM Of 40.11 wetr prep4wil ixith C"11 is, 01k. Me er."IP (I
Q10 in the CO groe~ (11) (Cf. C~I. 48, 110), 0:0dation ol
them 6xnen- in A vaCUU6 S)M-rnl AVA3 followed separately
fi), tlmm~uring chwivs in pr~~Jtre an(I annl)mhiq the products.
'Xhezmxt.,rjAC11+
0 (whtm x was varit-d fnvn 2 Im 14). vmj allowed to remcil
Prior to and within tlif!. r"ion of g-oni 041ne- at
I from 10 mri. to 240 min. 11olarograins of rcu,6-
VU-
.C
A~
mmm.prcssureaua i
additkuk to 0. CH,. CO. CO., and Arli, contained CI1*O.
Alit WC1,49"Mc A ccific n0lvity a the iabeled CWtO (in hu-
pulses/min, V.T rortned f. I . 80, SS, 9% and 87-und
from rX it was 11. 11its indicates that during oxida;" of
AM the C atom of CHiO comes from both tht lit owd CO,
EMIP3. 71be prolvability d. f%vvnntion from Me group,
3 thnes " grest as the probability of Its formation from,
tht CO voup. On thQ bmAr of new obumtkal tim
followint scherne of,oxidat-ion 4 AtH is wmtstvd: (1)
C"jf#CjjO + (N + Ct%&Co_.
(2) C,jhC()_
Ciq4CM)WH +, C,,jj M. (4) Ciqjaao)C*~ -4 C% +,
't0111.0 SOM + Cj#
C
-; ( 09140. +, V614010 ~ Von
J1.CO-; (S)WH10- - C141W + H--. (T) H- + C"JISCHW
+ pm. nr lr"t- + -Cff-ftl
0"AtO + 0- - H, 4- 046 + %-. or W> + CNN.'
4KTrPS-01 temp. in the Its rntejis ~. ter''
OR of C1410 and C111M The pn7pos"t 51 I.e., fo"n3t-
tkm ior 26ethavol in rm" . 0. ims been qmMrArTued,
Ulan
by its pft*mce in 1.11a products 7"Ution. Atj~,_-

SAC/ -f*sf
C.. -5
7kAt
A. TL
of iron in stickef in the temrArsture mop M-1 130* C. w"
MOW twing radio(ictive Fe,.. Thin nickel fall was plated
on one oide with Iron cont4ining r&Jkqwtk,O Ifew,4, pfft-ml in a
silica vrWI Awl hentr4l im IVICUO to a itivon tomj*wum. This
rato of diffilsta" %a* (Oltomml by MrAturestionts of tho mdi*-
itrtivil), sit Will Odra of tho fall. Tho tompamturo (I
(tvneo ol' thm diffuslon co-Alcient oU irm In nickel itz"Tin.
sion n( iron Into ititkel In enmItIcrably higher than th" of
nickvi into iron-v- a.

UM/Chemistry - Isotopes I Avg 53
"Investigation of t.he Oxidation of 1_C14-Butone
and the Theory of'Destructive Oxidationl'!'M. B.
Neyoun and-, G. 1. Feklisov..' Inst of Chem Physics,
Acad filici USSR
AA11 SSSR, Vol 91,.No 4, pp 877-880
According to the theory of destructive oxidation
of narmal straight chain hydrocarbons, formulde,
We can only form from an 14d carbon atom of
the eha'M- Sy-athesized 1-0 -butane and oxidized
it to check this theory. Results Indicate that form 3,
deWe forms from the'central atoms of the chain as
well ae the terminal ones. Presented by Acad N. N.
Semenov 22 May 53.
272T8

-;Igil' the m6atinkuil
Th kketic tiietha for ctud
Irlit'reactions by tome of f4ge(I at3nm- M. 11. Ndong
lied Client. FE

Cf.
-J. lt)winial*tr.-Auew,kinctlemeth~dofusior tuogt:d life=
0 study the mmiuillism of a rmoklit is d,!xxibed. The
nictluxi is uml to vwdy- &.t ta"natica ard dmompa. of

3110w
Adl bt the oxidattm of batatim, The expti. muffs
Cult tile AcEl decomp. a sfiOificant exf=t udy durfur~
to
-
iot beft I
the inithd and fitud perkdr whem the butaue Is
'~bddfud t% any gteat exfcnt~ VMmAlic, QxWtion of
bftt&" It PCOMPAVIC mpft, oxidation of A,R #V:;~

z.

=/Chenistry Isotopes, Reaction 21 SeP 53
Kinetics
"The Influence of the Structure of Alkyl Iodides
on the Rate of Their Isotopic ExcbALnge with lone
andAtome of lodine,'k.:X.B. Neyman B.A. Kuzuetsov,.
and:~Yu.M. Shapav-a-lovi~-'lutst Of Chem, Physics, Acad-
Be i USSR
DAN S85R, Vol 92, No 3, pp 611-614
Using 1131 in both the ionic and atomic form, stvdi-
ied the effect of the structure of normal as c M"-
pared with iso-propyl iodide on the rate of ex-
ebauge vith iodine. Iso-propyl iodide exchanges
26&,115
iodine with iodine in the ionic form 20-25 slower
than normal propyl iodide. The rate of isotopic
exchange of iodine in isopropyl iodide with atomic
iodine is 25 times faster than that of normal
propyl iodlde. Presented by Acad N.N. Semenov
17 j!",
26ft5

mat/chemistry - Isotopes 11 Sep 53
"The Influence of Pressure on the Velocity Of.IWIC
Reactions -of Isotopt R-cchange, - M. B. Neyman,' H. G.
Gonikbere,;-V. B. M. Shapovaloy and-V. S.
Zvezdk1nj,,.Inst of Chem Phys and Inst of Org Chem,
Acad Scl USSR
DAN SSSR, Vol 92~ NO 2, PP 365-368
Studied the effect of pressure on the reaction velo-
city of isotope exchange in reactions of propyl
iodide with active Lo1ide ions and of propyl bromide
with active bromide iorz at 190 and pressures of
lp 1500, and 2400 atm. Used alc solns of Nall3l and
269T2o
NaBr82 as source of halogen tons. Found that the
formation of an activated complex in these reac-
tions is associated with a decrease In the volume
of the complex characteristic for no:mal blwlecular
reactions.

NEY' ;0
N MAN, ',!. , (Professor, I' ctor of Chemical Scl,~mces)
Neynian, M..,_ (Professor, Doctor of Chemical Sclencep) - Llsted as outhor of articlp,
"The Ener", of the Atomic NUCIEW," which apppnrs In ProMqarldist I A~,,Itator,
No 6, 1954, of the Vain Folitical Administration, Miinistry of' Defense USSR.
(Ka-asnaya Zvezda, Foscow, 4 Apr 54).
SO: SIAN. 1~2, 13 August 1954

7~
hWQ W
Mine t of at. 0.
Ulm-
Vkkwdaradas, 1 -
14-10-113 the ti
It tk osmpr All-Unlon mittUrg a May to.,
hisrease In the use of petrojenin jr, 'Chemical industr
adrocited. A brief summiu-y ivz-t given of the
ac
I Ments In this Md in U.SJJJZ. durwg the last 10
Mvel;pment In tb& theory'of cbstin oddation at hy4
tam. D1. N. ZSMMi,)X,,, Ibid. 13-0).--A cornr
Mim' COVITHIF Ule followialf topics Wl's given: irc~
Han b!xwew two saturated hydrocatbm~; Ichain lengt
lwio~ 46free radicals; eff-t of bfiat!6-as on the
PrOpa competition b
etyrten the chain reactla
d fate*
the Tervttadion anloug, Out mohi.i branching of
fe;ictkai ind limiting phenoinena; decay of chatu. reas:
del of" le parluft
s; wall efmu tn chain reac
tfitp 99kadstuf ti re Catalysts In
ces. oxh
MiRmocabono. e-R.B7reU5ffMd.".-Az
of of simple I
"whIt'll rderences7
tubm with Stasnic on.,, L. 1. Afr="kio =d
1
.-OUMT151 WEVAR , et

references. Unique features of a
hTdrocabosts In 11(rdil pbass.- A. N.)Udkimv mid,jU6,

7=A
l
B
k
Ibid
IWI
C
17
-
bert
ow.
.
; c
udff -1 r-r7mrincet, The itan
nlilfftwai;
Ullet; cc,
U

-6 '=n= on hydrocarbons at various stractue'in
~ PbAse. X, 1, IV Md. 11 1-23.-Prep tratim-

e I
c following peroxicut fVJIY revic%cd. heutam: 2-bydto-!
, tn oxide, b.-a 38', xV - 1.43(6, do 0.0072, a - 0-
X,
was ZI/d 10' - 86'64 URD U-7119; 2-awthythi=ne 2-hydto~~
.
.ve-
L '
V MX0, dv OSM, MRU~37.91'
!oxide, biv 21, , a
,
nn.
4-tfhMethYl-3~')Vltan[n1C. -hy
dMpAVVxier'V ti~o. at*
2
U
,

war- .
:m. 73"; cycMexane hydrowo-tide, tn. -2:)'. n".1 1.4&38,'
jive du 1.018, AfRo 31v&); I-ethylcyclohexane 1-hydrnpertaidej.
tack N4 34', gif IAVI, dio 0-M7, 6 85A, JIRD 40.46; 1?
and .
hain propy1cyclopentant 1-hydroptroxide, b.~, 34,5'. nV
d2a 0.101, k 85.0, J14 40-06; Indan 4-hydroT.

and

hain o:dde, bi-i 76% 1-inctilyt-1,2,3.4-tetrah)rtlronaplitha.,ene'

. I
00"
99-
id
b
1
5584
1
.
1-hydroperox
e,
o.t
, RV
8, dw 1.11140
'
ons; flumene
"ydropitmxide, tA. W; 1,4-dibyt
ironaphthaltze.
ons. n" 1.
1-hydroperoxide,
ba D 5685. d,% 1.153; -Iij-'

tion -
hydroperoxide, m. 82%
diphenylcthane 14 PNCOOIL'rd.-~'
view St 0 rderencef~ Peroddeir from sutor!4Ution of sople'
I
dm-o .13. K. 1. IV
Aoa~r' V R
alkimes and cycloOkint
(V%*N~'
Zlu%k
P
Fb;T
1 24-3~1~ "It=
an I V
1 "
9O&
.
.
.
.
112,
"
U-.
L
Lue, 'L
.
L
-
I
(
anit nlivn- unwArtx% am wiv-,-qied aittl dismwied n,detall
is FCVIV~M. is F"UMILMS. rcle"nets. UXlUAUO-1:,Pr0QUCEX 01 L t
117ti of, hydrecafbong hi the jueseace of hydrogen broraide. .-KWI1 wid L. A. Unflq. INd. 140-4.2"rhi; A
'Z. K. ?AaTzu,.Wd'M.,Uj=jU~ W-77~A' 5VE;
V& --nM-ffi aar form-7M =53 sMM!d by malyzhq the nuioxid-A
t
4 relerctioz. -,;; ~04 of oxidAtIon fian products of T!tzalia, The traction cxtd. with 890 44.-~j
afGH-fitbeledprotylent. ~,F-Tuk(nr- 9kov- Ib(d.76-M. 14AHiCOS COMItinCd. 911013 ef
-Synthesbiol C1 prapylen , TUMM" atitlic one and dihYdrottaphth0quitione. Among the i;WcUtion i
-P(!.t, - xnd dem. of railina"tivitA of Proolucts were., y1 bydioper- P
am r Vit-wed. It reretCMCM otb aside; 3,4-diti~-tht)-1(211)-ititplithitlemLile; 4- lydro-
P!oIj ail. Yn. 'Slit2i
2(I11)-nAphtbalvnej1e,'
II.CHtCIlCChtl; -%M ImlymeriLatiou producta. S'Mthe
of I'l-diphilayletfu rapt-roxida and til-hrmal decom-~l
h"
tion of telfwry -roltidts. rifi-en
YAiro PP 161
Piro

MWOMMMI -
OMMOMMMUNNOW
-

-
-
-
-
'
9 led 0%ldatim of pawalauln al
2
4
5
kid. I
AW4 Emog.
W
Un"014% of

E I ~
=40"AInd joWewr~olls in

review if
kim Ibvi. 1674C A review IT
10 reftr.;
1
41
f
i
o
id
i
1 Methods
1
CUM. =14=1 O
on
ox
at
tnileam hr-
f.p
dror
.,Ld"m in aw-phast, V, K. Tlyskoyslil.
A7743~A review.-trith Per
IWO
'=ib4lq-diW nftL itisviums-0 onditinns
'j. jt
for this- Optiumm Yields sit Shft Um lesigth.
, -
b'
f
A
A

" U.' Ra
rom UV
as,
V h
Zaig
atty adds-
,
7-
im
of
la
i
t
th
200
M
w
d

% % -
I
-
ss
,
no
procesm. pRe r
.
c
g
cr
s
Ues d hydro3T adds f
eam.- r*M'u"tj*qW pOrwal
fffin-foradw-matarials P - lf.;11%13~'
,
--ff
-Q
_-Um
n
a
a
,
.,
, scp
p
00% tim bf
it fiat
io!~d.sazl liquid petto unt
-6MCK ty discuesed and, the prqm. ef jamisitew.-
ZMAI EMSt. "I" i~ MVk-gtd. A~
L

y Physical chemistry
1A Pub. 147 U/21
Heyman i M~ B,,, and Feklisov,.G. L,
TWO I Kinetic method of employing marked atoms for tha study ofthe mechan--
i6in of. complex chemical and biochemical processes. Part 2.- Behavior
of acetaldehyde during cold-flame oxidation of loutane.
Ptriodipal Zhu,r,. fiz. Ithim. 8, 1439-14-50, Aug 1954
Abstr"I~ The befavior of acetaldehyde in the: reaction, of butane oxidation at
303PC was investigated by the kinetic marked-atoms method. A dia-
gramatio schame of the installations used in studiring.the behavior
of . acetaldehyde during butane oxidation,is Rapid forma-
presented.
tion oe acetaldehyde wasobserved during the first stages of butane
oxidation but.it.sloweddown sharnly during thet very process; of oxi-
~dition and after the extinction of the cold flame. Twenty references:
1 USSR, 443A,and 4-English (1-930-1954) Table; graphs; drawings.
institut-ion Adad. of So.. USSR, Institute.of Chemical F~Ysics"Hdscow
Submitte'd October 20, 1953

USSR/Physical Chemistry Kinetics. Combustion. Fxp1_G,3j.,reo. Topochifmiatry.
Catalysis, B-9
Abst Journal: Referat Zhur - MMmiya, No 19, 19561.
Author; Neyman, M. B., Miller, V. B., 61iapoval~.v., '~u. M.
Institution: None
Title: Investigation of the Influence of the Structuxe of Molecul'qs on
the Velocity of Ionic and Atomic Isot.c~pe Exchange Reactions.
A,,~,)m Chain of the
Influence of Lengthening of the CarbcL
Alkyl Radical on the Velocity of lsrtop~! Ex~l:wige of ALkyl
Halide with-Haiogen Ions. IL lnfli,~n '"e of Is(~lmerization of the
Radical and Introduction of a Double &:.nd or, the Velocity of
Isotope Exchange of Alkyl Haiide with ffialcgev, lons
0'riginal
PerLodical: Zh. fiz. khimii, 1954, 26, No 7, L243, 195'j. 29, 110 5, 692-897
Abstract: 1. A study has been made Of the - s rif ~iie reanion of iso-
tope exchanle: RX + X* q~ RX* * X-, vr~!r~ R z: CH3~ C2H5. n-C H7
and X BrN or The rr-a-_t,ion-wwi --ar-ied Out in C2H504
Card 1/3

USSR/Physical Chemistry - Kinetics.
Catalysis, B 9
Abet Journal: Referat Zhur - Khl iya, No 19, 1956, 61o6o
Abstract:
,:~O in tLe teff-p,:-rature reglon of 100-1000.
Solutions Containing 10% L~,
Considered are the kinetics of dlfferent e~xcbange mecho-niame and
it is abo-.m that the velocity constart remains constant only with
an ionic-molecular mechanism of the react'--jfi. Energies (kcal/mol)
and entropies ~eDtropy units) of activation are for CH Br 17.5 and
Br 18 and 22
19.5; C2M5 .7; C 3R-7Br 18.4 end 22~; CH3, 15.4 and 19.5;
.4 c R I I 'and Frc-m the obtained data it
I 19 and '17 3
C2H
9-3 13.3
Ides
fol ova that alkyl iod undergo exchange with ~,3ter than
j
alkyl bromides with Br-. Lengthenfng of the carbon-atcm chain in
the aikyl halide radl.cai Ej?.owB dow-n ito isoi~ope exchange with ions
of tl*..halogen. II. In a 90% ethanol solul-.1-In were determined
the energies of activation in kcal/mol (firat figure) and the
actions: I)
forexponent (1/mol sec ) for the fol-lcw-ng r 1i
*-
*
0
0
-120
(CH ) CHBr *- Br
(at 90
) 19.0 and 10 3 ~2)_(CH CHI t I
8,2
* 0
0
9
(
6
6
-lo
20.0 and
.o
3 (3) CB2 e, 'H
~HOr + Br
) 1
(1
+
and 2.8-2.08. The data obtal6ed confinn the assimption that in the
case of ionic-molecular react,1,,:ns assc,:J-af,~,d with inversion of the
configi)-ration the vdWtry of t,i,.:? Pr- ~=s-, is determined essentially
Card 2/3

USSR/Physical Chemistry - Kinetics. CombuBtia,3. I'opochemi~irry.
Catalysis, B-9
Abst Journal: Referat Zhur - KhImiya, No 19, 19c-6 -,LQ(')Q
Abstract: by the energy barrier which must be by the carbon atam
on passing through the facet of th,~! (etrah,~dr~%n b,~tween 4"ilb-
stituents. Replacement of 2 atoms of tiydnDgen at the apexes of
the facet by methyl radicals slows dcnfr tft- isotope e-xchange by
more than 100 times "d increaBes ~h-! ei-trgy ef actIvation by
3-4 5 kcal/mal. Love-ring of energy f' act.I,,Iat'.,z,-n cf' isotope
exchange and increase in velocity ~lf *he r~s.CfiCQI -~r. introduction
of a double bond ina,'d-position the p.--Issibility of the
occurrence of the reaction in the Lf al-kyl brui)ide without
inversion of configuration in accordqn:-~-- vith the scheme: Br~-+
CH2 z CHCH2Br +- Br-wCI12CH = CH2 + Br-,-
Card 3/3

nffMM, H.B.; TMISOV, G. I.
Kinetic method for using tracers for the study of the mechaaism of
complex chemical and biochemical processes. Part 2. Behavior of
acetaldahyde during cold-flame oxidation of butaae. Zhur.fia.khim.
28 no.8:1439-1450 Ag 154. (MI13A 7:12)
1. Akademiya nauk SSSR. Institut khimicheskoy fitiki (Moscow)
(Radioactive tracers) (Acetaldehyde) (Butane)

~
C
F --tted-
.Ubm; 953
USYKAN, H.B., professor.
Applying radioactive isotopes In machine building. Vast-rath-34 no.4-,
34-39 Ap '54. (KLRA 7:5)
(Radioisotopes--Industrial applications)

TIMIATI, M. V.; SIITIIYAY-,V, A. Ya.
"Use of Electrolytic Polishing to Remwe Layers of
Determination of the Coefficient of Diffurilon," Dok-lady
No 2, PF 345/348 (or 315/318?).
Metals end A~Iioyr. in Ule
Akwlemii '-SSR 5r, (1-1~4
B-81524, 28 7)ec 54 (Couments and Ovaltmtion)

USSR/Yh~sical Chemistry
Card I/,,;'
Authors t Heyman, M. B., and Shinya.ey, It., Yao
Title t Use of electrolytic buffing for the remoral of metal and alloy
layers during the determination of diffusion' coefficients
Periodical t Dokl. AN,SSSRI, 96t. Ed. 2-. 315 - 319, UaT 1954
Abstract t The method of removing metallic layers through electrolytic
buffing enables a direct determination of the diffusion coeffi-
cients. Using a 60-% sulfurio acid solution and a lead cathode
at a current of 5 - 7 a/dim2, for a period of 10 seconds this
authors obtained a glossysurface of the tested specimen and the
removed layer had an uniform thickness of several micronso The
uniformity of the removed layers was measured with an optical
indicator. The measurements showed that the electrolytic buffing
method warrants a constancy in:the thickness of the removed layers.
Four U&%t references since 1937. Graphs.
'Institution, i Academy of Sciences USSR, Institute of Chemical Physics.
Present4id.by, Academician A. N. Frumkin, March 9, 1954

MSH/Chinistry - Physical chemistry
Card Pub. 22 -34/46
AlLthors
Mayman, It. H; Shapovalov, ru. K.; and Killer., V, H.
Title
Substitution of H-atoms in.a. 01139r moleculaby Br-atoms and. its
effect on'the rate of ion 11sotope exchange.
FeriodicaLl t Dok-.. AN SSSR 97/4, 703-706j. Lug, 1, 1.9154-
JLbstract t The substitution of-H-atoms in a, CH3Br molecule by Br-atoms and
its effe
et an the rate and activation enerfy constant of the iso-
to-pie exchange reaction of 8r-substitutes of methane with Br-ions.,
were investigated in a 90%-4ilcohol solution. Results indicated that
the thermal effect ofthe illotopt exchange reaction equalled zero
and the eauilibriumconstant was ind6pendent of temperature. The
mechanism of isotope exchange, Lit explained. Nine references:
8-US311 and 1-MA (1869-1953). T&blea;.graphs.
Institution Acad. of Sc. USSR, rnstituteof Chemical Physics
Presented by Academ3clah U. N. Semenov,,March~,27-, 1954

NEYVANS M. B. Prof.
"The Application of Tagged Atoms
Conferewe of Workers in Plant and
Central Asia, Alma-Ata, 1955
501 TI 17002
in Irdw, try," report presented at the hth
Industrial Laboratories in Kazakh SSR and
Inst. of ?hIsIcai-Chemistry, AS USSR

NFYI4.AN, 14. B.
"The Kinetic Method of' Studying the Chemical Reaction when Aided by Marked
Atoms" from the book Chain Reaction on the Oxidation of Hydrocarbons in a
3aseous Phase, pu P.
I ol. by Inst. of Chem. Phy8ics, AS USSR), 1955, ~ - -

112-3-6221
Translation from: Referativnyy Zhurnal, Elektrotekhnika, 1957,
Nr 3, P. 168 (USSR)
AUTHOR: Neyman, M. B.
TITIE: Application of' Radioactive Isotopes to Instrumentation
(Primeneniye radioaktivnykh izotopov v priborostroyenii)
PERIODICAL: In sbornik: Avtomatizatslya tekhnol. protsessov v mashinostr.,
Moscow, AN SSSR, 1955, PP. 55-73
ABSTRACT: The author presents a survey of uses of Isotopes for the
control of physical processes, and for measuring the
properties of gases, liquids and solids. The application
of radioactive isotopes in measuidng and regulating
temperature, accurate weighing,and chemical analysis is
discussed. Radioactive isotopes can also be used in the
preparation of stable standards of light and sources of
high and low voltages. It is pointed out that the use of
radioactive isotopes opens up new possibilities in
instrumentation.
.,ard 1/1 L. A. V.

lizyw.K.B.
Radioactive isotopes in measuring techniques. 1=. tekh. no.l:
14-21 Ja-V 155. (14L& 8:0
(Mensuration) (Radioisotopes)

KATRANOVSKIY.S.G.; NCYNAN,M.B.
Equation for the diffusional current with calculation of the
screening effect for a part of the dropping-electrode surface.
Izv.Aff SSSR. Otd.khim.nauk. no.3:420-424 gy-je 155.
(141-BA 8:9)
1. Institut khimicheakoy fiziki Akademii nauk SSSR
(Electrodes, Dropping mercury) (Diffusion)

wmwl, v% B.
"Atomic Energy for Peaceful Purposes," Friro4da, No.4, PD. 9-23, 19,5,5
Trarslation !~~6900 16 Aug 55'
Also D-300832, SeP 55

ANTONMA. I.V.;KU74*HnI, V.A.;KOSHKIRA, R.I.;MALRANDYAB. A.B.:MRTMB. HA.;
1307, G. 1.
StuV of the reaction mechanism of the oxidation of nethaao by
means of labeled &taus. Icv. AN SSSR. Otd.khim.nauk no.5 S-0 05S.
Izv.Aff SSSR.Otd. khim.nauk n0-5:789-792 S-0 '55. (KLRA 9:1)
I.Institut khinichaskoy fiziki Akademii nauk SSSR.
(Hathans) (Carbon-Isotapas) (Oxidation)

NEYM&II,H.B., professor. doktor khimichaskikh nauk
Rays that conquer disease. Ilauka i zhizn' ?2 no.6:11-13
JO 155. (KLHA 8:8)
t'Had.ioiEiotopeEi--Therape-utic use)

GlaM, M. 1. , EMYW. m. B.
Study of couditions for the combustion of gaseous mixtures. part
2B. Kinetics of the accumulation of peroxides-and aldehydes
during the oxidation of hemadience-2,4. Zhur.fiz.IdAm. 29 no.3:
533-538 Rr '55. (KM 8: 7)
1. Akademiya nauk SSSR. Inatitut khimicheskoy fiziki, Moscow
(Hexadiene) (Oxidation)

EMYKAR. H.B.; MILLXR. Y.B.; SHAPOVALOT, Yu.M.
IILV astlg#~ion (of the Influence of molecular structure @a the rat*
of onto aah atomic reactions in isotopic oxchazge. 11Z. Influartc*
of the number (if halogen atoms to carbon &tons on the speed of
ionic Isotopic exchange of halogen derivatives of moth&&@. Zhur,,
fIz.kh1m. 29 no.6:1042-1049 is 155. (MlaA 9:1)
I.Akademlya nauk SSSR, Institut kiiinichookey fiziki.
(Ion exchange) (Halidoo-Isotopes) (Methane)

USSR/Fhys I p I Che-.,distry -- Xmolicq. Cr, ~DGS'tl Dn.
2-;, p I C, 5 1 ~, C. STo.p-chpr-~i rtry. Fate 1
bf~ Jovr RofurvT. Zhur - Khimiyrl, 1957 57~6
Au --',.o T 7,!,Icovnikov ;,.V., Nlcyrr-n 'A.1-%
-Itle 'ino-Li(; ~;o~hod of-It7ITZI--eion rf Trsqvvd At-jrii~- it; tl,o,,
~nvo,t!:,r?*-~Icn of 1,.ecl,anij- o4' Cherricel Prid Ticln~iorj
FrocesEes. IV. ~~'ormrtion of CO and (,()2 on Oxid---ion o"
Butpne.
ur- 29, No 8, 14,10-1421
F u 1) Zh. f 1 lc~ j 9F
AbE:tr,ict Rrte of' forn-tior. and of ox~onditurc of C0 durin,- oxid:,
tion of' C411i, were -'otorminol. Only I-A~ CC), nre for, od
fi-D!- CO, tric ro- rtininf, 1?6-99," are for ed froi'- other ~rc-
dacessors. (702 we:; conv-~rt-.d to DeM;. Co ,!E?S OX4 dized
vl1th 1201:~ Pnd the. res--ilt-inF (10 a ~;c r.Led :Lr.
In tents witii C1'O P'~d ~,; ,4,
O".Ectivity of 6,-,' C;-., "'Irts
dctern:.r,.er. viith,pn ~-nd-wina,;,,i ccuntor.
I " ---* CIII
the ropcti.cn U C 2 C 0 C) (C)2 6(; onz+rated by
Card 1/3 119

U' -RIF hy!z ic ri IChai_~i q try Kinu+ic.n. Comiustion. Explosives.
Tc,-,)ochc-- i _~t ry, `iltf ly~'is .
Abc JIUr Reforpt Ziaur - K1A--iyi, 'Tc 2,
jxRcjr1i.cntr on rjYidption c' ',H-c -*n tho Fr,-.-,c-nce -f'
1 1+ 1 ,
C oind ('.0. -hu C~7) isolatod upon co--,letion of the
exporir,c,it w-_.- fcund to b,~- --npctive. Exp;r.Lr,.1n',., rxi
dation of' c4H,c) have rh.jwn Upt wlth rdiition of
the C02 f'cr%,A is of very lot, specific _-ct4vitv. F_Np-~,ri
i,ents ath nddition of s; -11 t. :,-,ints of C G Pnd C02
hrvt~ r.--vef-led thpt in the coursu of the rurcticn s,-~-
cific Pc1ivityO