SCIENTIFIC ABSTRACT PARIN, V. V. - PARINI, V. P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001239220019-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 15, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

PARI~, ANTIPOV, V.V.; DAVYDOV, B.I.; PANCHENKOVA, F.F.
Study on the biological effects of certain factore in space
flight. Kosm.issl. 3 no.2015-324 Mr-Ap 165.
(MIRA 1814)

V.i A' POV.
,,hange 'in tne Jn
the irLf luence of ionizing radlaton E;nd the dynamic! fartors
space flight. ,zNT, AN SSSR Ser. bio-. 30 no,,-i:3-9 Ja-F
T Pl

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Aii~tt-h t
af
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'if
67- -70.
____oI
hoh -#-vWdro oi*k
to bit-
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gg~ r
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JUPP
SUB co i

P4XlAf4 /,). e
~ .10/
sea junAmommus *you W iWaWN MW olon"awl
wgsx4s pelymos, A. .1. W-M ON Jild JI, 1. PAWNA.
1. ..1% Li., 1, h I." T I, HOW. I a, '-1b ; h" pjjjglrj
L W~ -l M-,-, Im-Ji-ah. I-10, N- 7,

GORBUROVA, X.P..-PARIINA, F.V.
Variability of antigenic properties of drV,-rexistant strains of
Balmonolla typhoon. Zhur.mikroblol.epid. I immin. 29 no.7:27-29
ji 058 (MIRA 11:8)
1. 1z Fafedry mi)-robiologii 1-go Hookovskogo ordena Lenin& meditsinskogo
instituta Imeni Sechenova.
(SAIMONELLA TYPHOSA, effect of drugs on,
antibiotics, variability of nntigento propertion In
resist. strains (Rue))
(ANTIBIOTICS, effects,
on Salmonella typhosa, vnrip,bility of antigenic
properties in resist. strairts (Rue))

PARTNAO Ye. V-
1313ALITIV, . 1~,T,14,OMIAYA, 1% !,.; J J,AP.IIIAq Ya. V.
T. ~T.,
"Electrochemical Reversibility and Acid. Alkali Denaturation of Giobulf-,r
Proteins," Blokhim.1, l4p No. 6, 1949.
Chair of Biochem., Kharlhov StELtO IL, -3.949--

BULANKIN, M., PARINA, YE., V., SHE-RESHEVS-KA,, TS. Y1.
Proteins
Matiirial on reversibility of acid-alkaline denaturation of' globular proteins,
Ukr. biokhim. shur., 22, No. 3, 1950.
9. Monthly List of Russian Accessions, Library of Congress, October 19'At Unclassified.

BULAWKIN, I.N.: PARINA. Te.V.
Obanges witb age in oxidative pbospborylatlon. Ucb.zap. EW
53:135-141 154. (MIRA 11:11)
1. Kafedra blokbinit Kharikovskogo gosudaretvenn-ogo univerBiteta
iment A.M. Gorlkogo.
(AGN) (PEDSPHDRrLATION)

BULANKIN, I.W.; WVIKOVA, _
Cbenical nature of so-called structural proteins. Uch.zap. KHGU
53:73-80 154. (MIRA 11:11)
1. Kafedra biokhimli Khir'kovakogo gosudarstvennogo univeraltata
inent A.M. Gortkago.
(PPIDTRINS)

USM/Eumn and Animl Yhysiology - Liver. V-8
Abs Jour : Ref zhur Biol.,, no l., 1958, 4o84
Author : I. Bulankin,_Ye- Farina
Inst : Eharkov U14versity
Title : Qualitative Changes in the Hepatic Ribonualfaic Acid in
An4mls of Various ABes (Relationship Between Fhosr2ioruo
and Pentose)
Orig Pab : Uch. zap. Kharka un-ta) 1956,, 68, _':;5-41
Abstract : Admitting the possibility of the exletence of phoophory-
lated Rim Z-ribonucleic acidl, the authors studied the
relationship between P and pentose in RNA in animals of
various ages - in the hope to get an indirect indication
of the intensity of tbe RNA phosphDrylation process at
various phases of ontogeny, The rge of the rats ranged
from 1-5 days to 10-12 months. In new-born animalsp
Card 1/2

. . . . . . . . . . . . . . . . . . . . .

7

Slims FA- (A. M
-Zhar. 24,2R-1.11in Russian_
0),
*0 factomiffed tht Incivase iii optk
I
4atlov.
t 1, ~91) -the~-~riixir4l is
14 ule %rl*h micelle format it'll.
--a-sputtirtnecm b
tic! arrangement of' cm,;
Per 37:::
7 thd 2ad faclor-is-related -to strifcbirie -farviaticin
iiffoii of the ga': - Thns; ~j strefc1led c1mili skould
her-speci& -otatibn than a globular:mciL - Since'
ef-:'
-matimproteins,'natirc cgl, ulbuinin is cbimct
fenaift1j6d),eid albarnin' JOUld ajj6 jje~.Cjj - a
pempyota,1011.1-1 Mm
was~Wzep.:jrcnzf. acid- and -Ak. iolils.
y Aenatitted rii~fiimvhm- inii's. vmId. tiist ii i-;-' q, ,
vWbed form; i.e.onicellar proteht.- --~Dy kilaidag
CA~dtqtlorl or, d6natumi protein.: iC4-
allit- sit: t C~
iimL its
Specific rotmiion~wblch, hbuW PrDdtl~ttl
of terAts _11cutrAization is' readily calsed. - The i.~'
.1,
,f denatuma. and;- native',-Prolcins.,. the:txpjl..-,
re soln.-.!l %_
8 ;AF &Q-ix64-11ir.1~~-;g1v.t -1`0 it'
point formed ;.Was,:mpd. by I "SIS.
ki the- Jctntrlihisatt_
buml
t. Was WaSN& 2 -mcs 7 -h
and t tert-A, The OP I _U -it
'dild, ~Tjth UrCall,
11 rjf kviid id tiii- wmAlvig r= to
~,e_rvtation of this ijilil, ppt. VMj
Ile Ilmd
at tbe mniv 6-mr -N
i well'i of the .4upcrnatwht,~~
hl) wii~ dctd. Slieetfic rotation was (Icti. for ma re i
)c6rditions of soln, had n
I elk' U linder tlic
.511. spedfic 76tation of sup&uatan
~smml for nitivr, DrttDn,-
elks
ibutah -W ASIrcv4i~.;ibly 4chituredand upou ututral-
JmA -pad c a.1-
he' nestat
ivierti c-~,'At the same tim
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wai I cV~-slbli~-dmtumd. and m doubt wnvLbe,,:
ahui7 nirh;c-h~icharicteriz~d76vtbeunfoldcr1lom)
ahiglm and~ianit.i~~ficfoinb,ri. TherOatio.1%
k stris Ic tire Ic m.1Aian_o1.1be-jc] mctr.-prk and
_15", l1ow3;_,.:3U%-'ilkah
as jo
.r q11
W. of um Fa is jldd&l it) Z% ciz albu-
e latt! ~cbnverti 'tapidly,46 a firin ye];ivIflcb was
i
ford Irs. Wa - arinicter. "I A ple.
F4
nil ullich
min.-; head fair. Nmin- ~mt
11UP ilij 'alliiiiniii ~ ma's-irreversibly'll tin the
f6tad n of INtiefied tel'ideasured. c
i~tivej -Idgh' nj so'.
5 Ic ro cmn
rsiiO ch irdicAcAd max. clui atimm, -cif
mmyci -b Tcltidaj~tion, _rvs-:sbon~i by~ h d --d .
thnt
roia6 for, tbf'~ liquA
jtflect.~ not'vmly the nature
N111v; !1
of Q IV &natUrAtIOMRS 7 53~d 10 11401ding
Cl
syton

The chemical nature the so-called s,tructuroLl prot*A.
0
V E V.
Ith-
h
g, C.'k11 Me ... "0v
R
1
Z bUr. 25. 147-&Rin RUSSUka~
1953).-To det. the
~1:
cbew. compn. al structural proteins and the possible vuria
tions caused by different methods of ist,lation, Hirers of 3-4-
month-old white mice were extd. with n 30% urts. in Rdsall
son. (1), Edsall soln. alone (II) and 10c' XaCl Wn. in
`4
1
r
carbo"te buffer. The exts. we
1
t. Vath 5
e Pitt".
vol. of Water -at 0". The isiolated stru,!tural protems'repre-
sent a Uponucleoprotein complex comr.-Ked of nuclek acids
-of phospholipide. tiss"es. Soln. lwasa more effective sot-
:J vent, extg, the Proteins almost completely. ~Thc slight
difference In ribonueleic aclid content of the whole tissue and
the ext. could be due to the presence of free AMmucleic
acid in the cytoplasm, which is not cfztd. Thtre was no
difference In the varsons fractions of P cxtd. with sdIvent I
or 11. MCI was not sultnble. The stmictural pittelm are
obviously prefortned in the orgd-tism and can.be readily
Artd. bv tjrra solo. B. Gutofl

BUIAWU~, I.N.; FARINA, Ye.V.
Changes with age in the protein synthesis of the organism. Uch.
zap KHGU 108:7-22 160. (M-M 141:3)
Ia. Kafedra biokhInii Kharlkovskogo gosuderetvemogo univerBiteta.
(PROTEIV METABOLISM) (AGE)

BUIANKIN, 1.1f.; Y~e.V.
Cbanpe with age in protein synt1esis. Report No.2: Incorporation
of S-~~' methicnine into the proteins of liver slices. Uch. zqp,
KMU 108a23-28 160. (MIRA 14:3)
1. Kafedra biokhimii Kharlkovskogo gosudaretvennogo universiteta.
(PROTEIN METABOLISM) (AGE)

MILAIMN, I.N., akademik-,C.PARMA, Ye.V.; GOMM, R.I.
Albumin synthesis In liver slices of white rate of various ages.
DDkl. SSSR 134 no.6:WI-1463 o 16o. (MM 13:10)
1. Eharkovskiy gosudarstvennyy universitet im. A.M.Gorlkogo.
2. ANUSSR (for Balauldn).
(PROTT"IN MABOLISM) (AGI)
11

PARINA YO-V., BUIANKIN I.N?~ . (US.~--R)
"Influence of Age on the Synthesis and Renewal of Proteins in the Liver."
Report presented at tho 5th Int'l Biochemistry Congress,
Moscow, 10-16 Aug. 1961

BULANKIN, I.N. [Balankin, I.M.] [doceasedj- PARINA, Yg.Y. (Paryna, IE.V.);
AGRANOVICH, R.I. [Abranovych, R I Y,-'-95aTM-EVA, L.A. [Liubartseva,
L.O.]; KOLESKUp L.S. [Ko2eanfic; L.S.)
Role of disnafide groups in the formation of gels during acid-
alkel-In denaturation of egg albumin.- Ukr, biokhim. zhur. 33 n0.3'.
307-314 A '61. (MIRA 14: 6)
1. Kafedra~biokhimii Khar!-.kovskogo gosudarstvennogo universiteta
im. A.M.Gorlkogo.
(DISULFIDE GROUP) (ALBMIN) (COLIDIDS)

NAGORNYT, Aleksandr Vasillyevich, prof. [deceased); NIKITIN,
V.N.; RULANKIN, Ivan Nikolayevich (deceased]; SIRDTININ,
N.N., prof.; KUMINIKO, V.I., dots.; PARIFA, le.V,,
dots.; POLEZHAYEV, Ye.F., red.; LTUDOTS-KAYA, -NI., tekhn.
red.
(Problems of aging and longevity) Problma starenlia i dol-
goletiia. Moskva, Pedgiz, 1%3. ?54 p. (MIRA 16:11)
1. Chlen-korrespondent AN Ukr.&SR (for Nagorny). 2. Aka-
demiya nauk Ukr. SSR (for Bulankin). 3. Deyetvitellnyy
chlen 91N SSSR (for Sirotinin).
(AGING) (IDNGEVM)

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Ya. 1. cbLHWv V P PaTinil and
1). barsbrT. Orp Cissis. 101. (U.-9--V'V-ff41',
120%xr,).--8oLns. of 10 it. of individUld iwmrtk cvVWAs
(KShjb&Um) in a 1. of ". adn~ were treated with Cl at
room lamp. After the domimpe. of excvn Cl with Na
115(h and the adda. al Ha, " clJorocTewls (1) wrm
Cap by sleam disin. As the optimum ratio of .1'
.111 to I Mai. cresol, ff-mools gave 411 g. 4,15-do -
thitwo-O
a -mr-W in. 38'. bf, 138 0 . and w-
11-12 It. (IV). rn. 45',
z"=- I decompates by distu. at SIM. Pfelvilltr
With korreasing Cl ratim that I yields decreased as a nroult __9O
of oildatkat and formaskm of a&. pmducts. These prol.
W awy we analogous to the at-ids, obtained by flamm%rh ce 0
(off, 22, 1238) froca pbmb and C1 in aft.
K4ns. 5 S.) digested with IW cc. of aqua "Xia
A
ago
so J an a water batb for 1.5 b". gave. freap., Ill and 25~;.
in. 233". M under Then couch
fions gave a red-crange vmou3 Froduct. which could not
tar identified. Fdl"v rele7enc". Chas. B)anr
t:9 0
ORTALLOOKIL LITINITWE CLAISIFICAT1111 9-1- - -.-~ I i
La 1 a: I I. &_ is 0
a
ON 311: Qv ill
T-8 --I ~13
U 0 AV so At 1 3
Is a IS 1111
so a 111:19t It Iowa I a
0 0 0 0 0
tre. 09 0000 0 000009 0 00 0 0

0 0 0 Si 0 0 W
0 a I a I 1 0 15 11 u 1) $1 is 14 V aAl 34 ,7 A N , K )) 11 u Ais Wa
00 0 A L 7 -LAN J*W pp(r.1 k
0o
00 A' deAl psartkahm ef AMMIAMI woM oaten tootow"
=. Va. 1. chulkov and V 11 I'muslij kx, OMOR, .00
0e
so OD048,-in thr pulifiralsor of sonuoni--al .00
00 contaminated with PhOll by Imanim-sil -ith CillsOll 1, On"
0 Cl a rMowl-ral.), %tvins of Cl can Ix ~R-lm by J-
..I w1fid" with Fe 14111, In 1,~
fir"loval 'If 11's
4n.litt and
A 0
0 -06
of zoo
-00
00
0
'm
00
0
00
0-9
0
0
;:o 0
_* 0
--- -------
S01063 .40 Ishv 09(
a) &__I~
ad 4141111 man ifel ask
.0" 0- 0.00 * 0 00 000
1:0 1&0 1141'
UL p 0 0v 0 0 a a 0 : 0 0 0 SPA0*000*00090*0000*0
0

10 0 10
AN[
P,
0
9 a If it is SO Is Mr, V Z' It V1.1 v a 1) 10 a 10 a a v a a a 41 a U 'm a X (a
11, M
a CEO a A_b__A *--A
w L40#03 4% Ipa
*IO-D " Flr~
c~Mbletd wymfiraffirim of slyrtor and viriby) motis
0 A 11, N. thilils-All ro"I V. 11. Ilifilli. (off. Ch'"
09 -I S. S. W) 7. "1 4~IMM-~;
l4 am-two(l) *fill his mel lairt vial t- (11) and thrif orilt. -00
o0 * %fill 117, 1 at %'is- Ills m Ill... th, 1.110c-01a;
la I ill its,
a mi-S. and enlivOy &,apjwm%A &I a "awn. -fol'i I ami
Ifiglary. The rittliv, mlxl~. gavv ilawl"S.-Ill
atail twafly clthwims trAns rA)I. in bill Al-011, in whirb I
1,olvintil; atv inug. Als,mit 601" of dimalvtmt jsflpnvr~
ppid. m -t*lJitjS mW #hr vrmoi;iisiX full off diln. *lilt
11,0. J'hr Us Iravimm.4. sabru analypkA, lilamcd Ibr %asisr
c"Illrut 14 M& simpis t mind 14V,!~). Thrormillitig -to
09.31 dola his* n'twiffiw0y that. conlravy Io Stlaill, e( al.,
I` A . 33, 31XV). file it.ina fivinvil In the sracilmn air
filim. ~.f I an'l 11 t-lymor, 1.111 Polls all
lisr ff-h. .4 2 1. ."tAist. fit t If, 1-1vill.-I
chmilm P.4voirs val I,,$$ i's 5 Vol,- 'll fill f of to V 10 101 Ill,
0, and cm-Unut -.0 Up ( 0, all "1111WIVISIS affrill
00 V Kiwith-d Up to 104", "t life '.0iffllylla I %%fill -121julgal-1v
iliff-I m.4. W1, f011111, 5 512ill-liLt pill. and i~ CAMN
It
rahviind, Thr IWA.-Itird mulbotS -4 (4
And It "ilh \'If. Aj-ah m. '11all'if vins ocroll cannot Im
11-1 al Ills, ja%-Jj.~, .11 Ills. 111,J1, 1'%Vj$jj~ JVJ,~j
"DID
0:
tie
Wit ICA WIDOW (4.51-K-1.
-4itill I Doi alip
Maill"t
#14 Run He
In If I

Of
6 sad ba*
at.*=
/Z ~ ~ rp*. ~1- W! - ~~ ~d: 7 A" A
Jp/
Rod i A:Aim. Is. W-Sw 949),-A
Tbw

Dvhnmh*Mon of so AWSOWL" v6owtv W big%
13, 106-11
(IMO-11 MIMS tmm j'fi*nIw~hrT*q1 equatiom (CA 26.
MW tbzl le) - B**./#) 4w- "x op it amt th, wt
nmm. rrrkoryM Imr ommmis"I - X9 i A A- lb,-
"M61, X "a bp drod. Mon I**, W'.1;1 , ow -1-1 ...IV i,
timw to dri. 1101. 71" drom. is owlin oh" unsw of IN.
drinp, nwmtd bir DiDvwm.? (C.A. 40, 6010 at mbpan by
=HIWTatwv dou im IN 0l polvmy"fbt hl ertk6flooml,

P,kRin, V. P.
Author: Iraft,, P., - . and/Laja~V. ~P.
Titles On the neture of red fterhanjU
Journals Doklady Akademii Nauk SSSR., 1951, Vol. T79 No. 1p pp. 57
Subjecti Chemist
From D.S.I.R. Oct 51

R.
"Mink,
UM Ahim
"On I
It d id.,
~4 Jo , . I
Whkil
Of
".-Phc~o~dfymcfization white P
Insol.' substid~es -xv t undo
hich Cin un
-jituth
t Ces an 0
me~ halopti; -these substa I nt the p tv - .
ki.
~~.eyaj..
CM
96hu~ but
ire po yot
-N atoms and vrg~ radic:dg W, 1IN1
term
contain mli
I
er res lFor phiitorcacWns of In.
structu 05%1
r- i I
ph6ij
'1W8);: CA; 2,13M~Aottrr-'-
rend.146,401t, --witti
3,4492; -Michaelis and -Arendr, Ann. 314, 259 -C-1M
cri- C.1
mi C.A. 31i 17104). Dry HIS:,
Ain
Re-P satd 'at:20'? 1:1 Wfel, R tL Hul; 1-0- I,:--1eVnjk;
-_-.PhIj 111111 ?hBr; aba PhChn scabd ampuls 1H COI atm."
snt&
-.Vcre Irn led, at 60-SP wit?j a Ili-lamp milialion for 15-
-180 h1s.- 6 limssure developed in the tube-4. Solor, in Wit1j;
r. kaiCirmall ~ bits. of'ppL, and most
an
ti-tive-solas. of RI type..- The
I -thi rcid
!.,more p
(violet from -Mel
~n rem- paw -treattlirithIl
1 halides) wbich rontained.about SD70 P.
to rik
ifi~, 1-M C,- Foxidized.'slowlY on coutnc(-:~
5-17 solid.
a 1) ..-Vigo Oybn ~Oliiart with S)VIIN03
r
libtraa 9 Ind] c: oxiacs.:,"None were Sol- In org. :-.
-andil.4.
Akw
ed, )ut In smtj~_whlch did- f
ypl~d upt.' 171 .-Phi W" ase'dark wftb_.,~,
Out P~ for. a - dw 0,*s AULmd e 4.17.
I led
sq* expowd to wvmim-,~
if 191 ds at 16- g.- orenge powd
Nybeil led
-1.3 th H utull[Witieconteit
hm VA lot
u~iid 5.78~. Cr to-4A jr. drie4pr6duct Wastedoda
I ~,J OY20vv1L5NHNC6;. theresultiaXsoln;
- ag
01'a
-bads',0be" brielly with I jnl. Imid
ri"Peatodly, with An Tmore 11NO., the.
t~&q I t% WASM (until CCN, -
nC
i0W UOPPed) a et and,extd, with hot
crapn.-. ext 11c, it resiifue of 'mde`
-
iodue a - w uj~ In _11.0 and trimled
P.) MAC PlUvp1tenylphuspboriatei
N Pb -te.was:1rented. with:
jjo, jamon "CM pb,. the Imirste **j repeatedly
V Tlh,lfG to rcum"4cOH11atuf a.
tbti resW
ivii NaC(%, ev0do. to drytiilp;_ -d'rkd it 150-70-
05% RWR; thp coned. cirt. trea"
lci AgNOj Save =y Is trace of; doudims.ludimfing
of a phosphlose sM."
I (OA C.) taken up In 20'
Al
1hig 701 ACOH --was dod., WIth 2 paM: HsO and
-rdtered,tMgftraU:evapdmvemlthnes
cip AcOH; enpd. to dryuess, y1eftleit 03 S.* brownt-1
*Iikh- gave MCNNCAPOMRN~-W 13"1 (from
The _mWou PrOdW bum 220 bc~"I
4
mounted to a C. (amk 2D bre, =101)
'i 43% (bow Mt the
ti atment describW abb"I x1p,
free la_z.W. 211ti, A*
3~ Oared an vrL of ted
Me, 0.9%; Zt,'
04 IT 1 4!m WH
ot;;ji; ]is
j
~7.
Y
3,

r
L`--~Ridoiwtott arm -Xid.ph I YX 02mit;ixl-d limad -I;N Ilj4N
Jbid. ~'M_g p j0a~~'.
40
Iii fim PW4 In Ow. to;" klea4atlK freq,
-Wine A z6 ptbduet f6fiximl t1i I CA~ filays; PVoA2-j-. I*kht VIA opt. ffol N) Dir
such vtoduito
litton 61 the 11410gs'n utiams 14 :,Pull[l4 61100 (06 hi cipli. tmrt).. .1t, .;Ztt
A
ed alid taxittatibli7of such Phos- 12) g~) was added'to UOlgj frimi~ 33.5 S. 7&I
ithonic v6 .4; th" sholving tj~ai the 1%glageta contr. forifts of R -d.1 hirs., the ppt. irwilleit millf:
Find mil; re UZI
nearely adsm] jd~ -H,
-4- j Lq-
frrd~P art notI ptlon -products -1 Schenck ~PtiOi er *,the jimduct (11) v~j nimf powder which
-4202(IRM)j ~iince-ttzatlarlcnt~of aluch,-irith.: fu,tne In Ar land. Contained -4 .57, 1wUnc, .6rilalkin-
dlil niirfll
orgallo.'riti allic,-
-yeaptats - shotild,' -a%-- Yielded tuive: X%plainic acids uly.-
h -tertiary: of gj*fraf this idth SM JlNOx
-.1pbosphini C-Avs-, Hence tb,~ halogen -atoms in such forms teikiar~ plamphine-ollities. but il-M -all iinit.4 Pit rirthl-l-
'of- red '-F. P
-tv
"Ittrit attaftn' in: the gebirrally-'Polyineric pbjxaspl~ojtate was tilatalned. - It (I+ .), ra trr.-ittri wit]) I
g BOLS,
nd P~ 'Relluxin white P In 740 9. I'Dra
10hriii-go e 97g. red P
_jiOt,._-whjch v6sfiltered off, inialoll. t"tited-With Pi it. filtemi. Lite 1;
pp
.~,avlth ME ~wad. with bou--CEj,fiud EtO. 'When this prod. with 2N uct, 10. MdXji, BI;O, drir,l in
tict. was i Actl 1.5 hra. With H101- It IVA 8 6% 61 Its lltr~ I red allal. vbtib with HN vi 1.2
09. 4)MUP
content 'ginall crintent 15.4%); a ~;!Gj U hrs.' g.~
a
11,0 - the uct turned,cartinge 6d wirtahird 95.7% P, with Jam ng HNO.-. reiiiaval of ~ Phl Mth - 11;8A*, follotrM,
~~,Ml hi ase to the ContentlexMtcd Wier TC]PIOCienittit. Of- bj~jtte~tment derueiiW In-..Nrt I 1:0,militau aboar.),clive
Jlr by H( grotrps'.- To PhUsBr, Ircan 34.1 j. PhDr) iras- I) ~ g.,-:Pb' ethylplimpliftate (ME "ceit of posolle -Pit:
...... dd(,l 10~ red P Mtz~ Br) and theinhti -
destrIbed aix
1 2 1j, 'V&hotat! evidence of,viAle-Ttuiction. RtjZn.~ Elio pvc- the jame it ~f b I th
M e yiekl ;)f, the
1:1A.1tert ent wilb lIjOand dil;HtSO,. theRtiOl-washe&'-. orjanj~.:dotjv.-. wag'm YnL
11ch
smaller.,11111 (0-4 j.) In
"'iolid RM_j -led to 67 sq.'- layer -was extili,with boll 709'o-AcOH was tllhl.~ with- 2 Psirts HA treated -irlth
.-Mloand, e combined org. I i;yer on ev2pn. zave some HA, Pjtcrcd. refacattrily tin 0 12
The red I Idtie,-.-6ntuIned,V,8 Rr; can.furth-A-AtInEnt, EtPOiRs.- rn.44-4*~ QMM OW). ~jCoaat; ip~j P ~Schler nj
J,* Trio PbA gBr the 'Bronte 7rdpped-to 0.4%, while. the ;tiriC.-Phosphor Paj ~ux ri6ticd With IIAClio
A 1M.
again- Ittiled. to show uny' evidence ot Pb;P or lidtlii wive boutaml aftc~ lho:.
LILL*
of tM
~-Wirwlntan% red P. .'11 *iO1441,
tfl
H 1,
L4
MEN

'Vm�r
PIZ-

MINI. V.P., kandidat khImicheakikh nauk.
,Mmwiii~~
Noteln-vitamin paste. San" i shism' 20 a0-11:35 N '33. (XUU 6: 1-1 )
(Feeding and feeding staffs)

IVANOV, P.P.; PARINI, V.P.
Making a popralar book scientific ("Miraculous atom". A. Daianov.
Reviewed by P.P. Ivanov, V.P. Parini.) Khim.v shkole 10 no.2:71-
74 Mr-Ap '55. (MI2A 8:7)
(Chemistry--Juvenile literature) (Buianov, A.)

-? r-\ Ra 1\~ TL , \J- P
USSR/Chf=iBtry Of High-Molecular Substances, F
Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 61692
P
rin
a i, V. P.
-----------
Institution: None
Title: On Inorganic Polymers
Original
Periodical: Khim. nauka i prom-st'.1 1956, 1, No 1, 44-51
AbBtract: A review. Bibliography, 88 ~ I
Card 1/1

FIIATOV, I.G., ?Mllil, V.P.
"Fundamentals of the manufacture 6f gas-expanded plastics and
Instomet-ars" by A.A.Berlin. Reviewad by I.G.Vilatov. V.P.Parini.
1
1m.prom. no.4:254-255 Je '57. (MIRA 10:10)
(Plastics) (Elastomers) (Berlin, A.I.)

1/4,
ROPIM, A.A. Ideiensed); ZAYONCHXC)VSXIY. I.D.; YA,3FO. Yn.M.; PARINI.
PARAMOLOV, V.G.; GLUZMAN, G.M.; M.G.
Increasirie water repellenc,v :u "esL~Lcr by moens of r, veinn-tynG
romulot,.--,d. Leg.prom. 17 no.7;2')-?5 i1 57. (MI:RA lo:~))
(Leather Induntry:;

ie-b
ucts'~

at. J 700-C77
"'A

5(3)
AUTHO-~S: Berlin, A. A., Pa.~ini, V. i.
TITLE: On Some Ch~,.r: cteri--~tics of zlolznuclear Aro7,%tic Co-,.r.ou
and on t~-.e Svnthe~,~is of 'ol,,-iers Resista:.t t~~ H~~
nek,otnrykh osobennostya',:h nnogoya-dernykh
soyedineniy i sinteze tor7,ostoykikh poli-rr.,r-,v~
PERIODICAL: Izvestiya vy~i~,hi,h uciiel).nykh
kaya tekhnolob~iya, 1956, 11r 4, pp 122. 127 (T"C"7ER)
ABSTRACT: The do-i-ands made W1 1103,".10r 'WhOtIM000, fn-~,t 1
with re'.9poct to thi,jr M-11 hent -resituta"Icu, ~1ttvp 1~eull
incrcaoin~~ durint, the last years due to the r;.P'd
.1
development of airplane construction and rocket
technology. T-,e he,,:t resistance of polymers dep. :~"s
on the c:io::~ical bonds strenjth in the main chadns and. t..e
side jroups of the macromoleculeE. The lower tnp free
ener,-,j of the bonds, the higher is t~.e temperature li-it
of the existence of a chemical coml;ound. The
mentioned in the title h...ve a hi~;h resistar.ce to '-.er~t.
Card 1/5 This is caused by t~,.e characteristics, of t'-.e

On Some Characteriszics of Co_-.,:13un~s S~71/--7-.-~~-?-Z--~/'-'Z-
and on the Synt-esis of ~Polymers Reni~.tant to Heat
bindinZ of such sul st,.: ces. In . lane syster.-.s ~)'L c-)n-
ju.,'ated bonds (Ie:.z-ane, naipht.,.alene, aiA other
molecules) the ~ot,_-.-tial e!,er~,-y of the n-electrons i-.
extre-ioly low. The bi d-,,r-,C f~)rmed by ci-el~.cl,rons
in t1-.e --rom'%tic compounds is covallent; iqis.simia-ar
to the meta'14-c one. The che:~,ical bord. in t..e::C
compounds should, accordin,~ to its chnr~_cter, be
termed as metullic -covalent. The resistu-iice to )f
tiie aromatic nuclei -is con.,:ected with the adv,,.,rtace-.u,-,ne_-:.-
of such a bond with respect to e.ierCy (due to the lDiv
potential enerCy of the n-electron). With the incre,-se
of the system of con,,ujated bond!3 the enery o' ' the
n-electrons decreases still fiirtlier. Th-us, the re-
sistance to heat of the molecule should increase with
the increasing number of conjuja- 'ed ben:~ene nuclei
forming the mol-cule. The a--clm1ulation of t-e benzene
nuclei car, take place in t%-ie following ways: For- atic rf:
a)Linear polypheryls, b) Polyaro:-:atic compounds -,Yi-h
condensed nuclei in one line, c)E.,amified po1,,arom,-_'io
Card 2/5 comvounds with a main chain of linearly bound or

On Some Characteristics of Pol.'.,nuclear Aro,-.iatic Car-nipounds
and on the S.~,,nthesis of ?ol.y:-,ers to Heat
condensed nuclei, 11) Condensed compow.,1s wltn
I ne cf t!!e :r,,;cromolc~cules of tl:e
a p I
0'a;-quet" type' C-) Three-di:wnaion,Ll 5'ri ~,.tur s. T~-.e
llblurrin,~" of the electron cl,'-Jud in poly:-ier
structures allows the for ation of "bifadlic-loid.,,"
or "polyradicaloids", in the 1;-,ttLr case also t--.,-t of
f a r L,:3 t C &U'
polyrac-licals (Ref 2). As ~! [ r~ -&:~ ':~. j
i~roved, the r-~-,asta:.ce to '-,c-,--t of t-e
cases a. --n-d P. is inci-~,ased (He's 3-5). To a still
-reater extent this t-,i-, c,',se in t'-e cases 'J. -I:.
(Refs (,7~. The authc).rs deami.-.,.ted ber-,zidJ.-.P . v t ~.e
action of active cop~)er. It vva.~; obt-tined by t-~e 0 C a
'-olution or, bis-6 i..zo-ben-~ -idine co~-.
cupfaus oxide
A dark red n'on-meltalle po-ymer was formed, wKic,"! W~.c
partly soluble in or~:anic oolvents, and coit;-.d!,ed
nitro,~;en (see probable for-7ule). A deamination carri-d
out in a similar way with benzidine dicarboxylic-3,31,ciJ
yielded an ext2rrally similar product, ~-;hich -;;as, hovieverl
soluble in alkalies and soda. This substa.-,ce (F-rmuia)'
Card 3/5 is decarboxylated on heating; thus, a linear polyp-e_-1".e,:e

On Some Characteristics of Polynuclear Aromatic Conrmpounds
and on the Synthesis of Polymers Resistant to Heat
can be obtained. PoJlym--~riq aith aromatic nuclrji in
the side chain alone consist of more flexible chair:
molecules. T~.erefore t:.ey ,.,.:-e less br-'ttle and less
resista.,-;t to heat than polyphenylenes. The ctre-~-~tl.
of their intra and int-=olecular bonds can,
be increased by a sufficiently =eat number of
condensed nuclei fo.-:.-.i-ig sifle t,-rou.,-',-3. Fr-,)--. t.i~~
it :~,uy be conc:u'cd t,).ut tlle che--istry of
polymers offers possibilities of pr-duci.,-,6 hi~,*;.1,-, i.-.t
mat,--ri~-Is, ~-. vin.- a cor~-,~Iex of
intere.,~tin-- There -re 1 fiC,;A,r,-, 1
and 25 5 Df v;hic',-, S,-)vi.,t.
A-'-~ SC T.'. T 10 Mor~!:ov.,~I-iy instititt myasnD, i I c,
produktsii(lL) -covi Tec.:-iological I,--E:t.Jtute of
and Lill- Prodl,ctioi: =LTILa~P)L%boratoriya
ny 1, 1-1 - oy e d i n c n ~y (La b c r L, t o ry o f H i - -"o'- ul r C o:-
Vsesoyuznyy z~ochnyy institut tc,1:f:til',noy i
lennosti (All Union ',orresponulence Institl,,te
and Ligl-t indii,.:try) K~-fedra obs-,,chey khimii (C~-.r,-Jr of Gent-ral
Card 4/5 Che.istry)

5(3)- SOV/62-58-12-21/22
AUTHORS: Parini, V. P., Berlin, A. A.
TITLE: Letter to the Editor (Pialma redaktoru)
PERIODICAL: Izvestiya Akademii nauk SSSRt,,Ol;deleniye khimicheskikh nauk,
'1958, Nr 12, pp 1499-1499 (U9SR)
ABSTRACT: In this letter to the editor the authors state that: Multi-
nuclear aromatic compounds are characterized by a special
resistance to heat. During the last years the synthesis of
polyphenylenes has been devoted great attention. We synthesized
such compounds by way of the aromatic biB-d-iazo compounds.
Benzidine-bis-diazoni,am.-4s,4,salts separate nitrogen on the
action of monovalent acpp(?r and form a non-fusible nitrogen
containing polymer of the probable structure:
KD H.~/j=Ar-)y -
Card 112 An Insoluble, non-fusible polymer +~,,~O.O,- )Z-

Letter to the Editor
SOV/62-58-1 2-211122
was obtained by the bis-dia.ZOtiZation of benzidine carboxylic-
3,31 acid by the mentioned methcd with subsequent decomposition
of the biB-diazo compound. On heating it separates carbonic
a-,id. Hard foils can be produced. from its solutions. The
produced poly acid offers new possibilities of synthesizing
linear polyphenylenes and their derivatives. Similar trans-
formations can also be obtained by way of the di-(N-nitroso-
N-acetyl) diaminee.
ASSOCIATION: Laborator4ya anizotrcpnykh struktur Akadem'.i nauk SSSR
(Laboratozy of Anisatropic Structures, Academy of Sciences,
USSR)
SUBMITTED: June 12, 19.18
Card 2/2

50):
-AUTHORS: Berlin, A.A., Parini, V. Y. SOV/62-59-9-29/40
TITLE: On the Synthesis of Aromatic Polymers Via Bis-diazo Compounds
PERIODICAL: IZVeBtiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 9, pp 1674-1676 (USSR)
ABSTRACT: In the present pamper the ayntheals of polycyclio aromatic
compounds becoming of inc:veasing interest owing to their high
chemical stability is reported. Me following observation was
utilized for synthesist The biphenyl-40l-bisdiazonium salts split
off nitrogen on treatment with copper(l) compounds and form a
nitrogen containing non-fusible j.:.olymer with the tentative
composition
y
Z
coo, '00,
Card 1/3

On the Synthesis of Aromatic Polymers Via BOV/62-59-9-29/40
13is-diazo Compounds
In this manner a.bia-diazotized benzidinedicarboxylic acid was
transformed to a bisdiazo compound of the type (II), which
contained approximately 2% nitrocen. (1) and (II) are not fusible,
both dissolve in concentrated H2SO giving a purple solution, W
is also soluble in alkali and '4fbrnamide. From the low
vi-ocosity of their solutions the wathors conclude (1) and (II) to
have a low degree of polymerization. The results of the ultimate
analysis are given in a table. The compound (II) was found to
contain 1 carboxyl-group to each benzene ring. The existence of
free radicals in both compounds vras verified by electron
paramagnetic resonance spectra. Purthermore, it is concluded,
that both compounds contain azo groups, (1) 1 azo group/4 benzene
rings, and (11) 1 azo group/10 bowzene rings. Cl and 0-0 function
as terminal groups. The stability is explained by the high degree
of dislocation of the ir-electrons, The weak electron paramagnetic
resonance of (II) is explained by the destruction of coplanarity
of the molecule by the two COOH-groups. Investigation of the
thermal stability of the substancegi showed (I) to decompose at
400 and (II) at 4500C. After heatingo (n) was insoluble in
Card 2/3 alkaline mediums. Finally, the authors express their thanks to

On the Synthesis of Aromatic Polymers Via SOV/62-59-9-29/410
'Bis-diazo Compounds
A. K. Kalmanson and L. A. BlyumerrPel I d -for taking and interpre ting
the EPR-spectrum, and I.P. Yakorlev for the infrared spectrum.
There are 1 figure, I table, and 4 references, 3 of which are
Soviet.
ASSOCIATION: Laboratoriya anizotropnykh struktur Akademii nauk SSSR
(Laboratory for Anisotropic Stractures of the Academy of
Sciences, USSR)
SUBMITTED: February 25, 1959
Card 3/3

PnSZ I WN ZXPLOrTATION SUVA984
Intoer"atLonal syWonjues ate macromolocular chemistry. Moscow.
1960.
so" arodnly simpozium pa makromolokulyarnoy 1chiall S3SR,
rat
f
t
6
ore
o
y.
0 g.; doklady I av
Nandcrap I IS Ijunya 10
Saktoiya. 111. (International Symposium on Maeramolecular
14-18, 19601 Papers and
M-tstr7 gold in Moscow, Jun
:
Sunisarles) Section 111. [Ron am, lzd-vo AN SSSR. 19603
469 P. 55,000 copies printeed.

Toeb. Id.t P. 3. Kashina.
Sponsoring Agencys The International Union of Pure and Applied
cheemaistry. Comenissicen on Racromoleculmr Chemistry.
rURPM3 ?hIs book.le inteend6d for chemists Interested In VOl1T_
"rization reactions and the synthesis of high molecular
isompounds.
~CWZUOZ& This Is Section III of a multivolume work contain-
LOS papers on macromolocular chemistry. The articles In
general deal with ths kinetics of polymerization reactions,
t" Wthgllis Of SPOOL&I-purpose polymers, e.9., Ion oz-

0
resins. Semiconductor ematerials, *to., methods or cat-
=9
1
19 VOlimserization roactions, properties and chemical
lateraOtiOng Or high molecte-lar materials, and the orfects or
various factors 011 V01709rIzation and the degradation or
hith 111016GUlar compounds. So personalities are mentioned.
KarIkShass given follow the articles.
-
-
-1-
Ra
be
k
. T. I., and (Poland). Chlorination of
ftanal-Formaldeehydo Resins 27
-t1. QprAV. and A. Clovinel (Rumania).
Cyan *4t
and AmInopropyl Ethers of Polyvinyl Alcohol 34
ILMOVIC K,slan4koy ye, m-

r
I
"
OL
6
1. Trot
Va
Fkorev (USSRI.
IL
id
N
C '1 44
the chemical onvers ons or Polycarbonates

'
n
yn, a d Z__H__BalxawAua (USSR).
'
.
_
T_
r
d%=
11, to
so
t
.n
.
.
am or
tho Activating Action
1
C11ecuble-3yatems or Vulcanization Accelprators
_b~T 8, 11, A. Shlrakau. and M. P_
-MqR,. K-_t~-re el ~Ujf~.Irj,! A~,Id nd Polyvinyl
alcohol
73
vol"bgr, 7- and a Tho Inter-
rine (Hungary).

a,
I
nation of an
P
, I
nyl Chloride T9
-Z
_
1
TSL2_v

3 la
hi d R IL
yo
a .4.11TV
vton
AA
,
,,
9_01#dua on""a ~vFoj_;2m1*RZae-Mat:n aj-6which k-A 1bj%
od~:
a on 0 Poj~ ri R
Proportion 85
and L. 11 ~ gavArm (Hungary), Chemical Proportion
of Kpalar Ion-ftchan'. Raton 93
I
, and J. N.riewietc (Poland). 9ffact of the Struc-
_A
19:k_

1110 AmT"_0__~0_0P_0_u_n_aX an the Properties of Anion
;
.
org
lp!qfteenge Monica From Polystyrwn*
XJLL-KN (USSR). The Problem of the Effect of the
or Ionita
on Ine-Exchange' Processes Between
lomitas and 22.0tro to 3Plutlons 107
~
DoWIn A A . B_I___LIaZq
and_y__t,+r (LSSR).
,
tlii;~
Y
r
d Proportion a.
some Aromatic . lymers 115
e
V I. I
A. S. Toylina 3 a
-
1. -
g
;1
en-jao tOLINI
C~emicAl
convetralons or r-naoluble Copolymers of Styrene 124

~n" (Poland).
JAAdCV, Thor-mal Stability of Strongly B~aj.
Anion Exchange Resins 146 kto

8383,8
S/190/60/002/005/008/015
B004/BO67
AUTHORS: Berlin, A. A., Liogon'kiy, B. I., Parini, V. P.
TITLE; Production and Properties of Sonie Aromatic P
2jjL0.r 6 1
PERIODICAL: Vysokomolekulyarnyye soyedineniya, 1960, Vol. 2, Nc.
pp. 689-697
TEXT: In an earlier paper A. A. Berlin and V. P. Parini published the
synthesis of homologous polypheny-liseries by decomposing bis-diazobenzi-
dine or bie-diazobenzidine-3,31-dicarboxyl:Lc acid by means of salts of mc-
novalent copper (Ref. 11). The present paper reports on this reaclicn and
on the properties of the products obtained. The bis-diazo compounds'Oere
decomposed with an ammoniacal solution of copper sulfate, which had been
stabilized with hydroxylamine hydrochloride. No different results were
obtained with air supply or in argon atmosphere. An addition of the di-
azo solutlon to the copper solution, howev-0r, yielded products with
higher molecular weight than those obtainej in the inverse process. Ana--
lyses of the products obtained are given in Table 1. Nitrogen could nci
be completely removed. The chlorine content decreased with increasing
Card 1/3

83M
Production and Properties of Some Aromatic !3/190/60/002/005/008/015
Polymers 13004/BO67
molecular veight (Table 2). So, it is probably bound to tkeend group. Tne
following polymer structure is assumed: Cl 6H:5 H N =N"R6 H3- ?6 HjY----Cl;
t~ .16 3- R
R = -H or -COOH. The content of azo groups increases with increasing len6nh
of the chain. The carboxyl group in ortho-position favors the eliminaticr,
of nitrogen. Fig. 2 shows that the loss in weight on heating (up to 450 C, C)
attains rapidly a limit for every temperature. The infrared spectra taken
with an WKC-11 AIKS-11) spectrometer proved the mere para-subst tut;cn
in the aromatic ring as well as a probably quin-Didal structure of the ring
and rod form of the molecules. The iatter fact explains the anomallus VK
viscosity. The spectrum of electron parajDagneti". resonance taken Aith
D. G. Semenov's radiDspectrometer (cf. Ref. 11) indicates unpaired electrons
whose concentration is of the order of 1018- 1019 and confirms the radial
character of the reactions. The shortness of the polymer chains obtained
is explained by the formation of stable biradicals which, due to the
delocalization of unpaired electrons, have only a low reactivity. The
formation of such biradicals was proved by reacting polymers vith P-di-
etbinylbenzene at high temperatures. Unmeltable and insoluble products
were formed. The magnetic properties and the electrical cond-ucti-vity of
Card 2/3

8383B
Production and Properties of Some Aromatic S11 90/60/002/005/008/0 15
Polymers B004/BO67
the polymers will be described later. The authors thank 1. A. Bly-umenfel'
Yu. Sh. Moshkovskiy and A. A. Slinkin for studying the spectra and
magnetic properties. There are 2 figures, 2 ta'~les, and 19 references:
8 Soviet, 8 US, 2 German, and I Dutch.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics of the AS USSR)
SUBMITTED: January 18, 1960
Card 3/3

6. 1043 0
sAgo/60o2A10/009/026
B004/13D54
AUTHCHS: Liogonlkiy, B. I., Lyubehonko, L. S., Berlin, A* A.p
Myumenfel I d, L. A., anti Parini. V. P.
TITLE: Polymers With Conjugate Bonds ani Heteroatome in the Con-
junction Chain. n. The Spectra of Electron Paramagnetic
Resonance of Linear Aromatic Polymers
PERIODICAL: Vyookomolekulyarny7e saysdineniya, 1960, Vol. 2, No. 10,
pp. 1494-1499
TEXT: In previous papers (Refs. 1, 2), the authors obtained arm-atic
polymers by reaction of bis-diaZOti2ed benzidine, benzidine-3,31-dicarb-
caylic acid, and o-toluidine with nonovalent copper-i to; the
structural formula is given: R R R If
Cl K2- _C~_O Cl
Jn
(polymer 1: R = H; polymer II: R = COOH; polymer Ilf.N_= CH. The
electron paramagnetic spectra (epr) were taken (Figs. 1-3) 61 ihese poly-
Card 1/2

Polymers With Conjugate Bonds and Hettiroatoms in S/190/60/002/010/009/C)26
the Conjunction Chain. XI. The Spectra of Elec- B004/3054
tron Paramagnetic Resonance of Linear Aromatic
Polymers
mers and the copolymer from I and p-diethinyl benze o, and the concentra-
tion of the nonpaired electrons was found to be I a 09 in 1 g of
substance (Table) by comparison with the epr spectrum of diphenyl-picryl
hydracyl as a standard. All epr spectra showed a signal with g-factor
2.00 which remains unchanged on heaVLng to 30C-3500C and cooling to 770K,
and in interpreted as a signal of the conjugate bonds. The broader epr
signal, which is superposed to this nignal in unheated samples, could not
be analyzed because of the superposition, and is interpreted as a signal
of less actiVe, free radicals with localized free valency. The signal ap-
pearing additionally in the insoluble fraction with g-factor 2.05, which
disappears on dissolution, is ascribed to low-molecular particles. The
stability of the epr spectrum in tho wide temperature range indicates the
paramagnetic character of at least ):art of the polymer. There are 3 figures,
1 table, and 9 references: 8 Soviet, and 1 US.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR (Institute of Chemical
Physics of the AS USSFI)
SUBMITTED- April 25, 1960
Card 2/2

0-11
gt c) 2)_D5
84831
S/020/60/*34/005/019/023
B004/BO64'
AUTHORS: Balabanov, Ye. I., Berlin, A. A.. Parini ' V P
Tallroze, V. L.,'Franhevich, Y?. L., and Chert-t-t`tn, M, I,
N
TITLE: Electrical Conductivit-t1of Polyiners'yWith Conjugated Bondsl
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 134, No- 5,
pp. 1123-1126
TEXT: To investigate the electrical. conductivity a and its temperature
dependence. the authors synthesized the folloising polymers: 1) P lymers
vith a noncyclic conjugated chain, such as polypbenyl acetylene, and its
copolymers with hexine or paradiethtnyl benzene; 2) polymers wi h benzene
rings in the conjugation chain, such as polyphenylene, polyphenylene
diazo compounds, polymeric-aromatic and aliphatic-aromatic compounds with
quinoid and amino groups, such as
C6H 3- C6H3- X H, Cl at R = H; X = H at R = C00E);
R R X--",, Z-- NH-
Card 1/4 U " n

84831
Electrical Conductivity of Polymers With S/020/60/134/005/019/023
Conjugated Bonds B004/BO64
poly-p-.phenylenediamino quinone, polyhexameth:rlene diamino quinonel
polyphenylene azoquinone; a polymeric triazent)'/[-C6H4- C6H 4- NH-N-N_n
and a substance (16) vith a quinoimine group F C6H 4- N=C6H 4~ NJ n; polymeric
chelate compounds of polydiphenyl aminoquinone with metals (e.g. cu);
molecular complexes of acenaphthene sith chloranil, and with a pyridonium
derivative of polyphenylene aminoquirione; 3) chelate compounds, such astetra
salicyl ferrocene and its polymeric chelate complexes with 7
Fe24 (21) and Be2+ (22); polymeric chelate complexes of percyanoethylene
2+ 2+
with Cu and Fe In all compoundE, a rose with temperature according
to the equation 0 a exp(-E/kT). a and E are constants characteristic
of each compoi4nd (Tab?e 1). E vari.edofrom 4.6 kcal/mole (substance 16)
to 49.5 kcal/mole for polyphenyl acetylene, and reached 92 kcai./mole in
the complex compound of acenaphthone voith chloranil. The treatment of the
sample influences a and E. If the polyphen~-l acetylene film obtained from
0 1
the solution is pressed into tablets at 200 C, 00 decreases by 22 orders
Card 2/4

8h831
Electrical Conductivity of Polymers With S/020/60/134/005/019/023
Conjugated Bonds 13004/Bo64
of magnitude. Since, however, E decreases at the same time, a remains
almost constant. (a ranged from 10-12ohRri.(;m-1 in polyphenylene to
51 -1 -4 0
6*io ohm 1cm ' in the complex cf acenaphthene with chloranil.)
This compensation effect was observed in nearly all substances, as may
be seen from the function log cc, .~ f(E) (Fig. 1). A change of a0by
60 orders of magnitude and of E by 20 timeE was observed in substances
of different structures. In the substances (16.), (21), (22), a was close
to the electrical conductivity of organic nemiconductors~ In the case
of polyphenyl acetylene, which is an insulator at room temperature, 0
rises -with rising temperature so much that, in consequence of its
high a the conductivity of many polymers is reached that are con-
ductive already at room temperature. There are 1 figure, I table, and
17 references: 14 Soviet, 2 US, and I German.
ASSOCIATION: Institut khimichenkoy fizilci Akademii nauk SSSR
(Institute of Chemical Physics of the Academy of Sciences
U !SR)
Card 3/4

84831
Electrical Conductivity cf Polymers With S/020/60/134/005/019/023
Conjugated Bonds B004/Bc)64
PRESENTED: June 14. 1960v by V. N. Kondratlyev, Academician
SUBMITTED: June ii, 1960
Card 4/4

S1020160/135/002/021, 034
B016 B052
AUTHOR: -Parini, V. P.
TITLE: The Relations Between Some Characteristics of Polynuclear
Aromatic Compounds
PERIODICAL: Doklady Akademii nauk SSSB., 1960, Vol. 135, No. 2,
pp. 335-338
TEXT: The author discusses the distributJon of electron density among
skeleton-forming atoms of a molecule which consists of condensed aromatic
cycles. The electron density (differing from that of benzene) is
irregularly dietributed among sutch atoms, and the molecule is therefore
easily excitable. The author first discusses the most simple case:
aromatic polynuclear hydrocarbons which only consist of six-membered
rings. If the double bonds in their structural formulas are arranged such
that all electrons are paired, cycles may appear which cannot be
represented by the conventional Kekule' benzene cycle struesures. The
author calls these cycles "non-benzoid cycles". He reports that different
Card 113

The Relations Between Some Characteristics S/020/60/135/002/021/036
of Folynuclear Aromatic Compounds B016 B052
types of quinoid and triquinoxylic. structures are frequently ascribed to
such cycles. The structure of a nUphthalene molecule can thus be
'represented without the quinoid structuxe; in other words, such a
molecule contains no (zero) V ---, rion-benzoid cycles. However, the
anthracene molecule C04
V "I ;Q
" Z ycle (indicated by x). Benzene holds a
I contains a non-benzoid c.
special position, since the electron density among its C atoms is
reugularly distributed. The author states that the excitability of a
molecule is related to non-benzoid cycles if double bonds are introduced
In its structural formula as described above. This characteristicv
however, is largely formal and does not reflect the actual structure of
the molecule. Despite its simplicity, the information it gives on some
basic properties of polynuclear compounds is sufficient. The coloring of
the compounds changes bathochromically as the number of non-benzoid cycles
rises from 0 to 4. The absorption maxima are shifted from 200 - 300 mp to
600 - 700 mp. At the same time, a tendency toward greater excitability
becomes noticeable. Compounds with more. than four non-benzoid cycles in
their structural formula are so unstable that they have not been
Card 2/3

Re! tiofis Betweth Some Charact erictics'
a
S/020/60/135/002/021/o36
of P61ynuclear Aromatic Compounds, 3016/BO52-
ru -which only exist in
synthesized so far. The occurrence' of, ist ' ctures
radical'state is probable. The aut'3or mentions 'a paper by M. Yo. Dyatkina
.;~,and Ya. X. S~rkin (Refs. 2,3), but nono of his own investidat~ions. Thure
Arel figure, 1 table, and referencen: 2 Soviet 3-US 4 3ritish, and
~1 Jayanese.
Izistitut" khimi6heskoy -M~iki Akad'emii-nauk ssn (Institute
-A SS OC IAT I ON
of Chemioal Physics of' tjie Acadbmy of Science-, USSR)
~j "z"',
yev, Academician
-;'TRESENTEE D.-; June .23P 1960, by 7.
MITTED: June 9 1960
CH#- CHq- Clis. i'Clf; CHg - CHs CHo CHs CHs - CHs

AUTHORS:
TITLE:
PERIODICAL-.
,/61/003/003/004'014
S/190
B101/B204
P 11"i V. P., Kazako-va, Z. S., Okorokova, M. N.,
Berlin,
Polymers with a system of conjugate bonds and hetero-atoms
in the conjunction chain. XII. Synthesis and Xoperties
of several polyaminoquiriones
Vysokomolekulyarnyye aoyedflneniyaq V. 3. no. 3, 19611
402-407
TEXT: A. A. Berlin and N. 0. Matveyeva (Ref.l: Vysokomolek. soyed., I
1643, 1959) described the formation of polyaminochloroquinones by reac
tions between diamines and chloranil. These compounds have a positive
magnetic susceptibility and the properties of electron exchangers. The
present paper describes.a. study of the formation of polyaminoquinones by
means of reactions between diamines and non-substituted quinones. The
reactions were made with p-phenylene diamine (reaction product 1),
benzidine (II), benzidine-3-3'-dicarboxylic acid (III), and hexamethylene
diamine. The diamines dissolved in alcohol or the acid dissolved in
Card 1/6

4989
Polymers with a system... S/190/61/003/003/004/014
B101/B204
aqueous-alcoholic solution of NaOH wero added to boiling quinone. The
resulting precipitate was filters d off after 24 hr, treated for several
times with hot alcoholl 50A NaOH, and !i% IICI, and vap finally rinsed with
water, alcohol, and ether. On the basis of the polymer yield and of the
quantities of hydroquinones that had formad, it was concluded that only
the first of the two possible reactiono
0 0 off
0 1
n H2NRNH2 4- 3n 01- 1- IINRNJI - Z~~ +2-(1) (1)
0 _n 611
and 0 Oil Oil
nlf,NRNII,+ 2n IINIINII - +n
oil 1 (2)
0 off
takes place, and that it is not affected by excess diamine. Therefore,
further experiments were made with a ratio diamine/quinone - 1/3. On the
Card. 216

89989
Polymei~s with a system... S/19 61/O03/QCVOQ4!G 1
BI1010IB20A
basis of data from elementary analysis and of the chemical behavior of.
the polymers which indicates quinone terminal groups, the following
formula is assumed: 0 0
Nil - RNit -
-.0 0
where R (CH C R - C R - C H A degree of polymerizaton
2)6; 6 V 12 6' 12 6(COOH)2
of 5 - 10, and thus a molecular weight of 1000 3000 followed from the
ratio N/C. The substances I - III are dark brown powders. They form blue
or violet solutions in concentrated H2so4 and are partially soluble in
quinoline, and only slightly soluble in other organic solvents. III gives
a brown solution in dimethyl formanide and alkali. Hard films were obtaln-V\
ad from this solution. III dissol7ed in dimethyl formamideforms a black
precipitate with copper acetate which probably has a cross-linked chelate
structure. Benzidine dicarboxylic acid dissolved in dimethyl formamide
Card 3/6

89989
Polymers with a system...
B/190/61/003/003/004/014
B101/B204
was caused to react with quinone *in order to obtain polymers of higher
molecular weight. The result were black substances. The reduced viscosi-
ty of III dissolved in dimethyl f ormamide showed an anomaly. (Fig. 1) -
The substances I - III have electron exchanger properties. They may be
partially reduced and are oxidized ELgain by atmospheric oxygen. The fact
that they can be reduced only difficultly, and the epr spectrum observed
lead to the conclusion. that the conjunction of the bonds is not inter-
rupted by the imino group between the benzene rings. These substances
have a positive magnetic susceptibility, are highly refractory (loss in
weight after I hr of heating at 350*C '10-5 - 11%, after one further
hour at 450 OC about 5%), and are not combustible. Their conductivity
obeys the law for semiconductors:_ 6 =_110 exp(-E/kT). The following Was
1 1 - I -I
found: Polymer E, ev Cr., ohm cm P 6200) ohm am
1 0.9 30
JI 1.0 30 10-16
111 0.4 2.10-3 10-10
According to these data, III has semiacnductor properties. The possibility
of a partial semiquinone structure is discussed. The reaction product
Card 4/6

89989
Polymers with a system... S/190/61/003/003/004/014
B101/B204
of quinone and hexavethylene diamine, a brown, elastic, easily combustible
substance, was not examined in detail. There are 2 figures, 3 tables,
and 10 references: 6 Soviet-bloc and 4 non-Soviet-bloc. The 3 references
to English-language publications read as follows: H. G. Cassidy, J. Amer.
Chem. Soc-, 211, 402, 1949; H. G. Cassidy, J. H. Updergraff, ibid. 11,
407, 1949; D. Bijl,.. H. Kainer, A. C. Rose-Innes, Nature, 174, 830, 1954.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics, AS USSR).
Vsesoyuznyy zaochnyy institut tekstillnoy i legkoy
promyshlennosti (All-Union Correspondence Institute of
Textile and Light Industry).
SUBMITTED: July 5, 1960
Card V6

Polymers with a system..*
VII
45-
4. 1.15
C,
pue. I
Card 6/6
89989
S/190/61/003/003/004/014
B101,(B204
Legend to Fig. 1:
a) g1100 ml,

AUTHORS,- Berlin, A. A., Liogonlkiy, 11
TITLEt Aromatic polytriazenes
28178
S/190/61/003/010/007/0'5
B124/B110
I_ Parini, V. P.
PERIODICALt Vyeokomolekulyarnyye soyedi-neniya, v. 3, no. 10, 1961,
1491 - 1494
TBXT~ The present paper deals with the synthesis and study of aromatic,
polytriazeneB of the composition N - N
N~] n
the diazoamino group of which is between benzene rings and characterized
by high proton mobility, The compounds studied were synthesized by reac-
tion of bis,-diazonium salts with diamines in the Dresence of sodium
acetate: nCIN R - N C1 + nH N -- R -- NH CH3COONa Cl R - N
2 2 2 2 -HCI
- N-NH -1-2n-1 - R NH2' A bis-diazonium salt solution was added dropwise
under intensive mixing to the aqueous-al.coholic solutio .n of benzidine and
sodium acetate cooled down to OOC, and the reaction was carried out in
argon current, The yield was 92.5% referring to the fundamental unit of' Al
Card 1/4

28178
3/190/61/003/010/007/019
Aromatic polytriazenes B124/B110
polymer. The polymer is a brick-red powder pELrtly soluble In anil4ne
aoetone, benzene, dioxane, pyridine. acetic anhydride, and qlAinoline, and
entirely soluble in dimethyl formamide, concentrated H2SO 4' and formic
acid at room temperature. When heated, the polymer is also completely
soluble in pyridine and quinoline. Extraction yielded two fractions, one
soluble in acetone (36~6), one insoluble in acetone (64%), the latter being
solublP in dimethyl formamide, When the polymer is heated in argon, no
loss in weight occurs up to 1000C. The lose in weight is 5.2~a at 1500C,
and 20,2~o at 2000C. It was found that heating did not cause a progressive
polymer decomposition; because the loss in weight did not surpass a certain
limit for any temperature. The infrared spectra of the two fractions
differ only by their absorption intensity. Another paper will describe
the infrared spectra, The linear structure of polymer
C1 N = N with the end groups
NH -In -I _4CL_-~ NH 2
--C1 and -NH2 In the ratio ',;l and a mean molecular weight of j 4000 can
be assumed on the basis of the infrared spectra, the anomalous course of
viscosity ckzrves (see Fig. 2), and the results of elementary analysis.
Card 214

28178
S/190/61/003/010/007/019
Aromatic polytriazenes B124/B110
The anomalous course of viscosity curves proves the rigidity of polymer
molecules and their tendency toward association. The epr spectra of
aromatic polytriazenes are 7 - 6 oe wide s:Immetrical singlets with rather
high intensity with the g-factor of free electron and superposition of a
30 - 40 oe wide signal with the same g-factor. The total concentration of
paramagnetic particles of the unfractionated polymer and the polymer
soluble in acetone fluctuated in the o:rder of 1019. Cooling down to 770K
does not change the character of the epr E;:Lgnal; its intensity rises,
however, according to the Curie law. The epr spectra prove that the con-
junction along the chain is preserved and unpaired electrons in basic
state are present. Magnetic susceptibility was 0.55-10-6 per gram. The
aromatic polytriazenes are electrical insulators at room temperature;
electrical conductivity rises, however, considerably with temperature.
E = 1 ev, aON 50 ohm-1-cm-1 at room temperature; E = 1.3 ev,
cfc~j 6- 106 ohm- 1. cm-1at 2000C was found for the values of equation
cf = (Y0exp(E/kT). There are 3 figures and 9 references: 7 Soviet and 2
non-Soviet. The two references to English-language publications read as
follows: C. Marwel, G. Hartzell, J. Amer. Chem. Soo., 81, 448, 1959;
Card 3/4

Aromatic polytriazenes
(18178
S/190 /61/003/010/007/019
B124/B110
J. E. Stewart, M. Hellman, J. Res. Nat. Bur. Standards, 50, 125, 1958.
ASSOCIATION: Institut khimicheskoy fiziki All SSSR (Institute of Chemical
Physics AS USSR)
SUBMITTED: November 14, 1960
Fig. 2. Dependence of intrinsic viscosity of the solutions of aromatic
polytriazenes on the concentration
(solvent: dimethyl formamide, Fig. 2
Ubbelohde viscosimeter, temperature z
20 t 0.020C). (1) Fraction of
polymer soluke in acetone; (2)
fraction insoluble in acetone
Legend: (a Nintr /c; (b) c, g/100 ml.
Card 4/4

3/190 61/003/012/012/012
B110 IB147
AUTHORS: Parini, V, P., Kazakova, Z. S., Berlin, A. A.
TITLE- Polymers with conjugate bonds and heteroatoms in the conju-
gate chain. XIX. Some properties of aniline black
PERIODICAL: VysokomolekulyanVye soyedineniya, v. 3, no. 12, 1961, 1870 -
1873
TEXT: The formulas for aniline black by A. G. Green (Ber.,,L6, 33, 1913)
have been doubted by 1. S. Ioffe and Ye. M. Metrikina (Ref. 2: ZhRFKhO,
629 1101, 1115). Aniline black probably consists of polymers or
oligomers with repeated quinone diimine groupings. V. P. Parini found
a connection between the energy of the lowest unfilled level, the activa-
tion energy of conductivity, and other properties of aromatics having a
benzene ring and accumulation of quinaid r4llngs Inthe molecule. In quinone
diimine groupings with nitrogen atoms unsaturated with respect to coordi-
nation, the molecule should be excited even more easily. According to
Card 1/5

S/19 611003101210121012
Polymers with conjugate bonds ... B110YE147
A. G. Green and W, Johnson, 16 g of aniline, 46 milliliters of 31% HCI
were dissolved in 200 milliliters of H 20. and mixed with a solution of
24 g of K 2Cr207 In 600 milliliters of H20. After I hr, this solution was
heated to 700C and sucked off. The lye was obtained by boiling with NH 5*
The complex-bound chromium was removed by treating with HCI (1.19) at 40
and 800C, dissociating of hydrochloride by aqueous NHV dissolving in
acetic acid, and washing with 2% NaCl solution. The authors found 14.22%
of N In the lye (Green: 13-85%). In hydrochloride, they found 12.90% of
N and 6.83% of Cl, which well agreed with Green's data. The results, how-
ever, contradicted the formula for aniline black given in the literature.
The authors studied: (1) the substance obtained at first and not extracted
with alcohol; (2) Cr-containing hydrochloride obtained after alcoholic
extraction; (3) the corresponding lye; (4) t.ne hydrochloride obtained after
Cr removal and reprecipitation from acutic acid; (5) the lye obtained
therefrom. The magnetic properties were examined by X-ray spectroscopy
(wavelength = 3.2 cm). All samples showed a wide epr line(~ 450 oersteds)
Card 2/5

S/190/61/003/012/012/012
Polymers with conjugate bonds ... B110/B147
corresponding to the epr pectrum of chromium oxide. This epr line had a
narrow singlet (11 13 o:rsteds) having a g-factor-of 2.00 and an integral
intensity of 10 19 10 20 paramagnetic particles per 1 gram. Paramagnetic
absorption decreased somewhat with Cr removal by HCl. After several hours'
heating,at 200 0C, the wide line vanished In all samples, which proves its
dependence on structure. The narrow epr signal was observed several times
0
in conjugated bonde. Between 20 and 80 C, the alectrical conductivity is
subject to the equation for semiconductorst Of- 6,*exp(-E/kT) (Table). In
0
hydrochloride, it is essentially higher. At normal temperature and with a
steep course of the curve Or- f(T), low E and 6 values lead to conductivi-
ties comparatively high for organic substances At 400C, the sample not
purified from low-moleoular fractions by alcob;:Lic extraction showed a
salient point of the conductiviti-versuB-temperiature curve and a sharp
drop of activation energy and rise in conductivity. Catalytic activity
was concluded from the magnetic and semiconductor properties. All samples,
especially the hydrochlorides and the Cr-containing samples, catalyzed the
Card 3/5

S/190/61/003/012/012/012
Polymers with conjugate bonds ... B110IB147
Table. Electrical conductivity of various aniline-black samples.
Legends (1) substance; (2)
initial substance before alco-
holic extractionj (3) Or-con.
taining lyej (4) the same, a*wrpmVDwxrwn pnumnsF o6pa3nwo Aq
hydrochloride; (5) lye after
Or .'removal; (6) in the range
~QY velgwmo Tir- as
(bnOPM110118"hMob SotpOT&D 00454 to" 10-61
AD 'OHOPOKIMI ClUIPTON ro.2D#* 101.60#
0.81
100.9 for"
Q To w, xn6pmApsr 0,35 10-2 for-$
@n0 YAMME XPDV8' OC130-
nexe
,
x
OT 0,61
0
17 10-1.6
2
10-2 10~-Iv
lor's
o me, xnupr
r
qp9 , .

Card 5/5

pp-
loo~s I
(Al
Or,
0,&o Got,-, 010,
a16 ,C~u
16 r
C,~
f~ 0
oc~ ac
cl:
~fl IO..?,o ~, \3,15
eb ol 0 r T 15 0 ?T)e
,D
V3. noll -j I .Oil D~
:~.,c ot.
fie selN o?
e ae
oa 01
,30., 01 0 B
pr
u :),o 01
e
01 oil.
e1.
-Q 0-~
.0io
c
a
0

S/19 62/004/004/005/319
Polymers with conjugate bonds and ... B119YZ138
were obtained (Ar is the aromatic grou,? corresponding to the initial
product). The compounds contain 5-15 benzene nuclei per molecule
(estimated molecular weight 500-1500). The nitrogen content of the
polymers, which depends on the acidity of the reaction medium, is 0.55
(with neutralization) to 11.6%. The compounds are heat resistant (3% loss
0
of weight at 300 C) have electron exchange properties, and emit epr
signals with an integral intensity of around 10 18 - 10 20 paramagnetic
0 -10 ,
Particles per gram. At 25 C the elec;ric;al conductivity is 10 110
-20 M
10 ohm om ~he compounds with the fundamental molecules
0 C02H P0211
P and
react with heavy metal salts (solution in dimethyl formamide) to give
insoluble compounds, probably with formation of cross-linked chelate
structures. *There are 1 figure and 2 tables. The most important English-
language reference is: D. E. Xvalnes, J. Amer. Chem. Soc., 56, 2478,1934.
Card 213

4kk
37h3O
S/190 62/004/005/006/026
B110 B144
'UT--
-:0"~S. Berlin, A. A., Liogon'kiy, B. I., Parini, V. P. Leykina,
M. S.
TITLE. Polymers with conjugate bonds and a heteroatom in the
conjugate chain. XXIV. Synthesis and study of the prop-
erties of linear aromatic polymers with methylene groups
between the benzene rings
PERIODICAL: Vysokomolekulyarnyye soyedineniya, V. 4, no- 5, 1962,
662-669
TEXT: Bis-diazollized 4,41-diamino-dil,henyl methane and 4,41-diamino-
dibenzyl were converted into the lineEx polymers
cl C 11, N - N
-I.- [-CD
polymerr 1)
c1 C111CU2 N = N nonjimep
tn- (polymer II)
Card 1/3

s/igo/62/004/005,/006/026
Polymers with conjugate bonds ... B110/B144
by an ammoniacal solution of univalent copper in Ar atmosphere at OOC.
They were light-brown powders insoluble in ord 'Lnary organic substances,
soluble in benzene, pyridine, quinolinia, and di.methyl formamide, with the
molecular .,.,eights 7 - 1250 and 74 TI .. 2600. The almost normal
Pi p~
viscosity proves the rqacromolecular chain to be very flexible. The
molecular weight of II is higher, since the two methylene groups between
the benzene rings (1) reduce the electron dislocation, and (2) effect a
slower decrease of the radical activity on recombination. The slight
loss in weight when heating after evacuation is based ont (1) distillation
I
or decomposition of low-molecular impurities, and (2) inhibition of the
decomposition of the high-molecular product. The epr spectra of I and il.
show two signals with the &-factors 2.00 (a) and 2.06 (b), respectively,
where a consists of a narrow signal (6-8 oersteds) and a wide signal
(50 oe.-steds)'which is caused by the poorly active, free radicals
remaining in the polymer. b is a triplat (25 oersteds) caused by low-
molecular biradicals. The decrease of the degree of conjugation in the
polymer chain is explained by a decrease in integral concentration of
paramagnetic particles per g of substance and by the intensity of the
Card 2/3

S/'190/62/004/005/006/026
Polymers with conjugate bonds ... B1'10/B144
narrow sigmal as compared to polyazopherylenes: Measurement of the
12 -1 1
electrical conductivity yielded for 1: E = 1.7 ev, d, - 10 ohm cm
- 16 -1 1 2 -1 1 -
-6 f(1/T)
~5 3000K= 10 ohm cm 06000K - 10 ohm CM For II, lof,
between 300 and 3700K was a curve whose angle of inclination approached
7/2 as the temperature rose. Introduction of one or two CE 2 'or NE groups
thus causes a steep increase in the temperature dependence of the
epnductivity. The conductivity of theae polymera will be high at high
temperatures owing to the considerable heat resistance of I and II at X1
300-3500C. There are 3 figures and 4 tables.
ASSOCIATIO"'. Institut khimicheskoy fiziki AN SSSR (Institute of
Chemical Physics AS USSR)
SUBYITTED: March 23, 1961
Card 3/3

39851
S/1q0)62/'O04/006/012/oi6
3101/B136
AUTHOHS: Liogonlkiy, B. I., Moshkovskiy, Yu. 3h., Parini, V. P.,
Berlin, A. A.
TITLE;. Infr~ired spectra of some aromatic polymers
PERIODICAL: Vysokomolekulyarnyye soyedineniya, V'. 4., no. 8, 1962,
1241-1246
TEXT: The IR spectra of the following linear )olymcfra synthesized
';X~-Viously (see Vysokomolek. soyed., 2, 689, 1454, 1960; 3, 1491,.1961;
4, 6 062, 1562), were examined in order to ascertain their structure:
11- 0 H C'11 -[-N=N-C H C H i Cl, where R . H (I),-CH (11), or
-16 5- 51 16 5-t6 5Jn- 3
R R R
COOH (III); a block-copolymer of I with p-diethinyl benzenej the copper
chelate compound of III; F- 166H 5- C6H5_]m_11T=1T_C6H5- C6H5]n-m-F;
- IC6H5- C!6H51M_111=N-~C 6H 5- C6 H5jn- with _O_CO_CH3or Oil groups at the end;
Card 1/3

S/19 62/004/008/012/016
YB1
Infrdred spectra of.- some aromatic B 101
138
a-1 C'H -C H 7 _G
2_C~'i5-]M 1N=N_C6E 5_C.E2_C6H5]-_Cl; Cl_["6H5_CH2 'H_ 51 m
o 5 ~7_CO 7
Cl; - H C H C H
166 5- 6 5_N=N_'TH_1n_C6H5_ 6 5-
Results; (1) 4~itoid structures occur'in polymers with continuous
conjugate- introduction of substituents (CH3, COOH) or chairL'
e
links disturbs the coplanarity of the molecui
(-CH2-'-C 72
and reduces the proportion of quinoid structures. (2) In polymers.the
-the molecular weight.
ionization of. parboxyl.groups increases with
(3) The formation of a three-dimensional structure with a continuous
system of conjugatL-4 bonds is characterized by a continuous background in
,the whole spectral region studied, and by the abvence of noticeable
absorption bands. There are 3 figures. The most important English-
language references are:LE* Stewart* M. Hellmann, J. Res. Hat. Bur.
$tanoftrda' 601 10s 19581 X. Vona, :. Amors (1hom"NOO., 790 ~005' 19571
K.- S. Tetlow, Appear'16h, 3, 187, 1950-
-Card 2/3

PARINI, V.P.
Organic complexes with electron transfer. Usp.khini. 31 no.7-.
822-837 Jl 162. 4URA 15:8)
1. Institut khimicheskoy fiziki AN SSSR.
(Organic compounds)
(Chem.istry, Physical and theoretical)

-1 1
A"'ESSION NR: AT4033997 S/(1000/63/000/000/0134/0138
AUTHOR: Berlin, A. A.; Liogon' My, B. I.; Parini, V. 1).
TITLE: Synthesis and properties of a polymer from 4, V--btphmy1Wsdia-zonium tet ra-
fluoroborato
SOURCE: Geterotsepny*ye vy*sokomolelmlyarny*ye soyetlinonlya (Hoteroebain macro-
x6lecular compounds); abornik statey. Moscow, 1zd-vo "Nauka. " 1963, 134-138
TOPIC TAGS: polymer, aromatic polymer, polyazopbenylene, fluorine containing polymer,
polymer synthesis, heat resistant polymer, organic semiconductor, semiconducting polymer
'ABSTRACT: Aromatic polymers (polyazophenylenes) (1) with an average molecular weight
up to 4, 000 or 4, 500 were synthesized ky reduction of 4,4 1-biphenylbisiliazonium tetrafluoro-
berate with monovalent copper salts. Tie resultant polymers were in the form of dark
cinnamon powders, showed significant Oiermal stability (retaining a glassy state even at
450C) and lost less than 10% of their initial weight at 500C, in an inert atmosphere. Similarly
to polymers synthesized earlier from the bisdiazonium chloride (11), the fluorine-containing
polymers (1) had phenylend and azo groups. Infrared analysis, vlicosimetric measurements
and thermomechanical tests Indicated ibat the length of polymer molecules with conjugated
Card 1/2

,ACCESSION NR: AT4033997
bonds is greater In I than In 11, 1 produced PeR sicgrnals of higher Intensity than 11 and ex-
hibited higher magnetic susceptibility (X * 10- = 1. 4 CGSM at H ~ 3500 oersteds, as
compared to 0. 17-0.20 CGSY Electrical conductivity obTled an exponential, law and
ranged from 1615 ohm cm- at room temperature to 10 at 125C. Orig. art. has:
5 figures.
ASSOCIATION: Institut khimicheskoy fizild AN SSSR (Institute of Chemical Physics
AN SSSR)
SUBMITTED: 10Sep62 ENCL: 00
SUB CODE: OC. MT NO REF SOV: 010 OTHER: 002
Card 2/2

PARINI, V.Pt; SIMONOV, A.M.; FRANPEVICH, Te.L.; CHUS, N.K.
Electropbysical properties of some aromtic betaines. Izv.AN
SSSR.Otd.kbin.neuk noJWA-450 Hr 163. (MBA 16 t4)
1. Iwtitut lihirdeheolmy fizikl AN SSSR I Rostovskiy-naZonu
gomidaretvenMy univeraitot.
(Betains)

PARMI.9 V.P.
Organic complexes vith lodi transfer. Analele chimie 18 no.2:43-.62
Api-Je 163.

-MINI, Nladimir Favlo-vich; KAZAKOVA, Zc)ya Semenovna; BELENIKIY,
L.I., doktor teklLn. nauk, otv. red.
[Chemical palette! falitra khinli. Moskva, lzd--v-. 'Tauxa,,"
1964. 126 p. (MEtA 17:7)

PARINI, V.P.; FRANOVICH, Ye.L.; DEYCEMYSTERP M.V.
Electrophysical characteristics of Bome hWcOrfildneo. Izv. AN
SSSR. Ser.khim. no.3:576-578 Mr 164a (MIRA 17:4)
1. Institut khimicheskoy fiziki AN SSSR,

'ACCESSION*.NR: AF4033387 S/0062/6-1/000/004/0705/0709,
AUTHOR: Bisrlln. A. A*; Llogoo'kiye S. I.:
..TITLE: Polymers with a conjugated system. ;Communication 56.
Synthesis ind study of the properties of &,polymer based on
bis(nitrosoacetyl)bensidlue
'SOURCE: A$ SSSR. Isvostlya, Seriya kbialcheska a. no. 4. 19640
705-709
iTOPIC TAGS:; organic sealconductor, semiconducting polymer, poly-
..azophenylene, polyazophanylene preparation
'ABSTRACT: Apolymer containing aromatic rings and azo groups to the
,backbone has been prepared by the decomposition of N,X1-dLn1troso_
.N.X'-d1acetylbenzid1t,e in benzen*:
Lo"CX;
'CWd 1/3

',:ACCESSION NR: AP4033387
The reaction was carried out-under argon at 40-45C for 4 hr. then at
the boiling point of benzene for 4 more hr; nitrogen evolved and
the polymer precipitated.' The rolvvner is partly soluble in aniline,
quinoline, and dimethy1formanide, and is complet 1y soluble
in concentrated sulfuric acid. Pecomposition in air begin: at' 500C.
IR and EPA spectra, concentration dependence of reduced viscosity in
1982 112S04, magnetic susceptibility, and thermomechanical curves were
:,:Measured, and themogravime-tric analysis was performed for the polymer
and compared with similar 'data for polyazophenylene prepared by re-
duction of 4,4'-biphenylbia(diazonium chloride) with cuprous salts.
;The fact that the new polymer prepared In the absence of metal showed
;an EPR signal and paramagnetism was regarded as confirming that these
;effects are due not to the presence of Impurities but to the formation.
;during the synthesis of a homologous polymer fraction of stable bi-
radicals and charge transfer complexes. The temperature dependence
,of electrical conductivity obeyed tin exponential law; vo equals
10-3 ohm-locm ~uals leOl ev. At 125C, the electrical conduc-
tiv-ity Is 10-10 oboe-T-cm-1. orig. aTt'~. has: 3 figures and 3 formulas.
AS SOCI ATION I LNUtUt iddidebookoy ft&Vd,9 AkadwU nauk BM!R CZUWAVW et
CbSOLUI ftsiess AMOW of Mumma UU).

;ACCESSION XR: AP4033387
ISUBMITTEDs 160ct62
!SUB CODE: CH9 "PR
DATE ACQs ISMay64
NO REY sovs 0071,
cor4
ZXCL& 00
oTuall 005