SCIENTIFIC ABSTRACT PANCHENKOV, G. M. - PANCHENKOV, G. M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001239010004-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

S/081/61/000/021/067/094
B138/B101
AUTHORSt ~G.M.~Yang Kuang-Hua
TITM Kinetics of coke formation on the alumino-silicate catalyst
used when cracking petroleum fractions and hydrocarbuns
PERIODICALt Referativn zhurnal. Khimiya, no. 21, 1961, 401, abstract
21M75 ([TrYT Groznensk. neft. in-tp ob. 23, 196o, 26o-270)
TEM In order to study the kinetics of coke formation during the
cracking of the kerosene - gas oil fraction (200 - 320'C), the Golovanov-
Panchenkov method is used, in which the catalyst is in contact with live
vapours from the raw materials during the whole course of the experiment.
The aependen,.e of the amount of coke formed, on the cracking period, was
studied for the case of the kerosene - gas oil fraction (200 - 320 0C) of
Komsomol'sk petroleum, hexadecane and decalin. To understand the kinetics
and the mechanism of coke formation it is important to know how the coke
is precipitated on to the surface of the catalyst. The percentage coating
of the catalyst by the coke can be calculated for a monomolecular layer.
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s~/081/61/000/021/067/094
Kinetics of coke formation on the ... B13a/B101
)2/3.N/M.10-40/S), where M is the atomic weight
It is (0.866) (M/4 Y2 Nd
of the carbon, N is Avogadro's number, d is the density of the coke, which
is about 2.25 9/cM3, C is the coke concentration on the catalyst, S is
the surface of the catalyst, which is 305 m 2/g. Eqi!ations are derived V
for the kinetics of coke deposition on the catalyst during cracking.
There are 8 references. [A~straoterls notet Complete translation
Card 2/2

P"CHENKOV..-G.M.; ZHO.ROV,'Yu.M.
Jeneral mothod of determining effeatiVe diffunion coefficients
for catalysts used in tho Otroloum chnical Industr7.- Trudy
MINKHiGP no.28-.3-9 160. (MRA 14W
(Petroleum) (catalysts) (Diffus3on)

PANCHENKOVi--A,U..;~-I.OLESNIKOV, I.M.
Kinetics of the hydrogenation of unsaturated and aromatic hydro-
carbons in a flow. Trudy MINLUiGP no.28:10-25 '60. (MIRA 14;4)
(Hydrocarbons) (Hydrogenation)

B/195/60/001/002/001/010
B004/Bo67
AUTHORS: Panche k_~"_R,.M., Baranov, V. Ya.
TITLEs Kinetics of Thermal Oracking of Hydrocarbons and Their
Mixtures
PERIODICALt Kinetika i katalizt 1960, Vol. 1, No. 2, pp. 188 - 196
TEXT: The authors attempted to derive a kinetic equation for the
cracking of hydrocarbong. Proceeding from the radical chain reaction
A ---)' 11A1+ 2A2+ .'.. VnAn (a) (A initial substance, A i reaction
products, V stoichiometrio'coefficients) they write: W 1 - k[Rj [Aj (2)
(WI reaction rate, [R],[A] concentration of radicals and initial sub.-
stance) and W . k rAj + k r-'[Al (3). This equation takes into account
I 1L-j 2 V-j
the possible effect of two processes on the reaction rateg a) decomposi-
tion of the initial molecules into free radicals; b) reaction between
free radicals and initial molecules. Furthermore, the rate W 2 is derived
for the formation of free radicals. The following is assumed: 1) The
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45
Kinetics of Thermal Cracking of ]jydrocarbons S/195/60/001/002/001/010
and Their Mixtures B004/Bo67
radicals are formed by collision or by a monomolecular decomposition of
the initial molecules; 2) the free radicals are consumed by reaction with
the initial molecules. The Lnteraction among the free radicals is
negligibly small due to their low concentration. The authors writet
W = k [Aj 2+ kl(A] - kL, r" (4). Taking account of the
2 3 4 LAJ
they obtain: (k /k )[A] + k /k (5)~ By substituting (c.) in (2) or
LI'Li 3 4 1 4
(3) one obtains Wk' I + k3l[AXA] (6), where ki - k.k,/'k , k- /k,
1 4 '3
if (5) was substituted in (2), and k' - (k1k4+ k1k2)/k 49
k3' = k2k3/(kIk4+ k2kj) if (5) was substituted in (3). At low pressure.,
the collision among the initial molecules does not essentially con.-
tribute to the formation of radicals, and equation (6) will be of first
order. The following relation is written for thermal cracking in con-
tinuous flow and gaseous state, the results of R-bf.3 being taken into
accounts nodx/Qdl ~ k' V + Ic3CAICA (7), and by using the equation for
ideal gases, one obtains CA ~(1 - x)P/(l i- Px)RT (6). n0denotes the
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Kinetics of Thermal Cracking of Hydroca=bons S/195/60/001/002/001/010
and Their Mixtures B004/BO67
number of moles of the initial substance entering the reaction zone per
unit time; x denotes the amount of initial substance entering into
reaction; A - 1~1 + V2 + ... -1; P total pressure. Substitution of (8) in
(7) and integration give n 0x - -(A/B)n 0ln(I - Y-) - kfPVr/.BR2T2 (9)i where
A - (14A) 2/m+n; B . p2 /n+(P/m)(2+R-mA/n) - (14A )2 n/m(m+n); m - RT + k;P;
7-
n - ORT - kP; V - volume of the reaction zone. For the case where
3 r
cracking takes place under the decomposition of an intermediate producti
A-->~Y, +92A 2 + *3 A3 - -.% V 4A1+ V5A29 where A is the initial substanceg
A, gas, A 2 coke, and A 3 gasoline (as intermediate)$ a similar equation
(14) was derived. The authors, howeverg used equation (9) to evaluate the
experiments on the cracking of fractions of paraffin-containing Groznyy
and Romaahkino petroleum, and calculated the eonstants of this equation.
They observed a pressure and temporature dependence of A/B. With a
pressure change between 1 and 50 atm, the rate constant passes through a
maximum at approximately 10 atm, which becomes more distinct at increased
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Kinetics of Thermal Cracking of Hydrocarbons S/195/60/001/002/001/olo
and Their Mixtures B004/BO67
temperatures. A. V. Frost and A. I. Dintses, A. D, Stepukhovi--h,
M. G. Gonikberg, and V. V. Voyevodskiy are mentioned. There are
2 figures, 1 table, and 9 Soviet references.
ASSOCIATION: Moskovskiy institut neftekhimicheskoy i gazovoy promyshlen-
nosti im, I. M. Gubkina (Moscow Institute of Petrochemical
and Gas Industry imeni I. M. Gubkin)
SUBMITTED: December 21, 19rD9
Card 4/4

PANCIMEOV G.M.- ROLESMIKOV, I.M.; BUDARIM, Ye.P.
Kinotics of the alkylation of benzene by isopropyl alcohol
on an aluminoailleate catalyst* Izv.vys.ucheb.zav.; neft' i
gaz 3 no.6:89-96 160. (MOA 13;7)
1. Moskovskiy institut neftekbimicheakoy i gazovoy promy-
ablennosti im. akad.I.M.Gubkina.
(Banxene) (AlItylation) (Alumi== silicates)

ZHOROV,, Yu.M - PANCHENKOV G M
Relationship between the size of gramles of the catalvst and
the'area where reaction takes place. Izv. vys. ucheb. zav
noft' i gaz 3 no.7t65-69 160. (MIRA 1;;:5)
1. Moskovskiy Inatitut neftekhimichaskoy i gazovoy promyshlennosti
imni, akadwaika Gubkina,
(Catalya-ts)

PANCHENKOV, GM~.- SKOBLO, V.A.
Corrections rogarding the article "Kinetics of the sorption of
benzene vapors within a wide temperature range." Izv.'vyo. uoheb.
zav.; neft' i gaz 3 no.SjI22 160. (MIRA IA14)
Oenzene) (sorption)
0

PANCHENKOVp G.M.; BAUNOVj V.YQ.
,raoking. Izv. V/'Bo
Effect of pressure on thD kinetics of Viemal c
ucheb. zavA; neft' i ga2: 3 no.10:93-98 160. (141RA 1414)
1. Mgskovakiy inatitut neftekl~Wcheskoy i gazovoy promyshlemosti
imeni akademika I..M.Gubkina.
(Cracking process)

8n60
S/152 601000101110011005
B024/06
AUTHORS: gaWL Karryyev, Ch. S.
TITLE: Polymerization of Propylene on a Mixed Rickel Oxide
Molybdenum Catalyst on an Aluminum Oxide Carrier
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Neft' i gas,
1960,vNo. 11, PP- 71-74
3
TEXT: The authors report on their tests concerning polymerization of
propylene on a molybdenum oxide and a mixed nickel oxide molybdenum
catalyst, respectively. It was ascertained that neither pure aluminum
oxide nor a molybdenum oxide catalyst on an aluminum oxide carrier effects
a polymerization of propylene, so that mixed catalysts, i.e., with addition
of nickel, cobalt, copper oxides~ etc. are widely used. Relevant tests made
by the authors at 140 - 2000C showed that the optimum conditions for a
polymerization of propylene on a mixed nickel oxide molybdenum catalyst
onlan aluminum oxide carrier under atmospheric pressure are a temperature
of 1600C and a moderate (15-20 h-1) rate of gas supply. These test results
are graphically shown in Figs. 1, 2, and 3. An increase of teirperature and
supply rate results in a decrease of the yield Of D'Olymerizate fractions.
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PINCHMOT... GA.; vuo~(W, YU.N.; Yu.YuT-Lm, [Yu. YU-1inj
Characteristics of tho kinetics of the catalytic --racking of
heavy distillates. Xhim. I tekh. topl. i masel 5 no. 11:1,-8
N 16o. (MIRA 13;11)
1. Moskovksiy institut ueftekh~micheskoy i gozovoy
promyshlennosti im. akad.GabkiD~k.
(Cracking procea's)

PANCIMKOVO G.Not NAWOV* A.V. PZCHALIN, L.I.
Separation of boron isotopes by the method of chemical exchange.
Vest, Mask. un. Ser. 2: khim. 15 no.2:3-12 Mr-Ap 16o.
I OURA 13:6)
1, Kafedra fizicheskoy khimli Moskovskogo universitets.
(Boron-- Isotopes)

mmmmm~
,~w /~, " i I /".. /,/ I
(- g- 1/ ~-, . anikkQyj O.M.3
zp~)j
0 Z.V. [Gryasnova, V o 4: ~PAC ---- , _.z
GRMONGVA oture and activity of bydrated aluminosillicates.
Catalytic stru 160. (EW q: 11)
ele chimie 15 no.2:161-187 AP-Je (Cata:LystS)
. Anal (Alwdnosmeates) (HydratiOn)

PANCHESKOT, GH,; MALIROV, A.V.; ROZYWOV, B.V.
Kinetics of the isotopic exchange of boron between boron tri,
fluoride and its anisole complex. Vest.Moak.un.Ser. 2: Khim.
15 no.3:7-10 MY-Je 160. (MIRA 13,'8)
1. i4fedra fizicheskoy khimii Moskovskogo univeratteta.
(Boron--laotopos) (Boron trifluoride) (Anisole)

PANCRENKOV, G.M.; KUZNRESOVA, Ye.M. -, AKSHAINSKATA, N.V.
Folarographic determination of alkali metals in aqueous and alcohol-
water solutions without the supporting electrolyte. Zhur.anal.
khim, 15 no.4;424-426 Jl-Ag 6o. (MIRA 13-9)
1. H.V.Lomonosov goscow State University.
(Alkali metals)

ZWROV, Yu.A.
SAMICKRIN, L;
Separation of. carbon Isotopes by the blearbanato 200thod. Yost. Hook.
-url. Ser. 2: Xhim. 15 no.5.-6-i2 s-o l6o. WRA 13: 11)
1. Hookovskiy goaudaretvennyy univeroitat, kafedra fizicheBkoy
khimile
(Carbon-lootopes) (Isotopes-Separation)

tj S/079/60/030/011/024/026
BOOI/2055
AUTHORS: and Kolesnikov, 1. M.
TITLE: Alkylation of Toluene With Propylene Over an Aluminum-
silicate Catalyst
PERIODICAL: Zhuz!nal obahchey khimii,,1960, Vol- 30, No- 11, PP- 3B46-3847
TEXT: The-authors were able to prepare eymenes in high yields by alkylat-
ing toluene in the gaseous state and under atmospheric pressure in a
stream of propylene, using an industrial aluminum"silicate catalyst. A
special device (Ref. 1) was used for this alkylation. The alaiminum-Bilicate
catalyst had the following composition: 14.01 A12 03f 84.66 SiO 2' 0-36 Na20'
0-13 Fe 0 and 0.60 CaO, and traces of zinc and MgO. The toluene was
2 39
chemically pure. Propylene was prepared by dehydratlon of isopropyl alcohol
over aluminum oxide at 380 0C. At 3000C, a molar ratio of toluene.: propylene
of 3 : 1 and an addition rate of 0.45 volumes of toluene per hour with
respect to the catalyst volume, the authors obtained eymenes in 77% yield,
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PANCHXffOVI GOM*-, EDLESNIEDV, I.M.
Alkylation of isopropylbenzene by propylene in the presence of an
aluminosilicate catalyst. Zhur. prikl. khim- 33 no.6:1425-1427 Je
o6o. (MIRA 13:8)
1. Moskovskiy institut neftekhimicheslcoy i gazovoy promyshlonnosti
im. I.M.Gubkina,
(Benzene) (Propene) (Alkylation)

---MamOv#,A-V -0 PANCBWOV~ G-04-1 (Moscow)
Solubility of boron trifluoride In anisole, phenathole, A IS -dichic-
rodiethyl ether (chlorex) and sulfuric acid. Zhur. fiz. khi?u 34
no-3:639-643,Mr 160. I%MIU 13:11)
1. Hookovskly goaudaratvennyy universitet imeni H.V.Iomonosova.
.(Boron fluoride)

b'L--
5/07C 60/034/o6/20/040
-Doi 5XBo61
Gr-Yazu VEL9 (U03 Dow)
rG. the Cracking
n
On
110
Ch
no
an
1.0v -Age a" to (;atalySts
P!a
2..A
Tium 111arogen 14o. 69
DOute Cumene~~On 'IUMOD 347
T-ITLB% ILeaction 0 -7~~ khimi- 9 19609
,,b..,.al lizicheskOl ,mosilicate catalysts
-pZRjo-D1CJ"% 12so..i285 of the order to S',13 9
ppq t the activity cate cataly
conner, I tt, -Br6lsted typeosi
,hers 0 e 86 or euteTiumt
um e f d
Many researe Toton acids -kir 9 on cas
TFXT'- e, of P the oral . were
.With .11, 'pTeseuc f the proton inexcliangO C1 4, U this 0 0 ex ituted
was a
Is catalyst erizatIon to the te,
rium t of
elp, in tile role 0 1,& the isom h a 8
esul
a rogell jr, t1 f cumene a carried Out wit e r tne 'Use
the hya crS:ckV0g 0 -ments were tal'Ysta* As
an& the )erl Cato ca -ferenc
a The exi VO alu"'O'lli announced at the ~-9' in teriLu'll
ej:amine - , are 91
Al 0 540 and t been bas3-C da. uivalent d ea
9 2 IT e ady 19) only
2 3 18) hale ~ (Ref. 9 ith 90 mill1eq
(Rsfs' for RR~~s to catalyst w
192t mosilica
of . a,
on tne a
aper.
Card
5'15
ing S/076J60/034/06/20/040
Duteriua - Hydrogen Exchange and the Crack. -BO15/BO61
umene on A lumosilicate Catalysta
Reaction Of C as el3tablichod tilat tho kinetic'], of the
'pe jo0 g catalybil It rRefs. 20-25). 1w
r ey G. M~ Panchenkov's equation ( deuterium -
tion of cyclohexene ob d the
Simple conngetion between the catalYtic conversion an he temperature
hyal!0gor, axohAnga could bo determined. The action Of t
I. "sparittion of Wata; from the catalYst
and duration Of calcination on th 0 at 0410ined at 700OCt whi"
'Table 1, results). A ataly
were exauiinea_0.9~ . ter, was used for the investigations of cumone
contained 0.8 a ange. The results (Table 2)
cracking and the deuterium - hydrogen exob imum at 0-1-0.2~
ty of the catalyst 1,eaches a max
show that the activi Fen exchange is most intense On
adsorbed vbLter. AS th~e deuterium - hydrOg
the alumosilicate catalyst, less intense on K120 39 and does not Occur at
3 it J.s assumed that the alwnosilicate centers play an
all on Si129 e exchange. Testa with deuterium dioxide showed that
important part in th lace, whilst only 50% of the hydrogen is exchangsd
a 100% exchange takee p (tests
-+"tintural water of the catalyst by..gaseous deuterium
4n thanked for MaSS

S/07 6J6010341008103q1O 391XX
B01 5/BO63
AUTHOR! Panchenkov, 0. M.
TITLE: On the Article "The Corrected Formula of G. M. Panchenkov
for Calculating the Viscos4ty of Fluids" by A. P. Toropov
.and G. A. Brodskaya
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Val. 34, No. 8,
PP. 1883-1884
TEXT: -The author notes that Toropovts and Brodskayale interpretation o f
the temperature dependence of A' and 60 in his equation for calculating
the viscosity of fluids is incorrect. He further notes that he has shown
in Ref. 2, that A' depends on temperature, as may be seen from the physi-
cal signifizance of this quantity. Thus, the temperature dependence of A,
requires no further proof. As the author had assumed in Ref. 2 that A'
is constant only within small temperature rangem, Toropov and Brodskaya
found,certain rules in the divergence between calculation and experiment.
It is further pointed out that the assumption of a constant temperature
for A, is wrong when calculating F_ 0 for different temperatures, since
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6 f
88352
S 60/,034/009/040/041XX
?J, 1.2 A-2, /A& D B/002;%056
AUTHORS: Kolchin, A. M., Malakhov, V. F., Panchenkov,.G. 11.
TITLE: Mass Spectrometric Analysis of Boron Isotopes by the
Thermionic Emission Method
PERIODICAL: Zhurnal fizioheskoy khimiij 1960, Vol. 34, No. 97
pp. 2124-2125
TEXT: Mention is made in publications that the method mentioned in
the title may be used for the isotopic analysis of boron, and offers
the fo.7.1oving advantages as compared to other methods: 1) Low material
consumption, 2) no "memory" effect, 3) a small number of peaks left
over due to impurities, and 4) high probability that no secondary
processes act upon the analysis results. For the practical use of the
method mentioned in the title, the ion current, which, according to
published data amounted to jo-13 a, had to be measured acourately by
means of series mase spectrometers.- To solve the problem, the intensity
of the ion current must be increased to 10-12 a, and its siability must
be improved. All measurements were made by means of the mass spectro-
meter MC-4 (MS-4) with a thermionic source. For heating, 20 mm long,
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88352
Mass Spectrometric Analysis of Boron Isotopes 5/076/60/034/009/040/041,YJ
by the Thermionic Emission Method B020056
0.8-1.0 mm wide, and 0-05 - 0.1.mm1hick bands were used. Borate, meta-
borate, and a borate-boroxide mixture served as emitters, the first
compound being the most favorable one. The intensity of the ion current
increases with the reducing properties of the band material (Pt, Ni,
W, Ta). From an annealed platinum band, no Na BO+ ions were emitted.
2 2
The ion current emitted from the surface of annealed Ni :J9 W-, and
Ta-bands had an intensity of the order of 6-10 14 - 5 .10 a. There-
fore, the attempt was made to increase the intensi';y of the ion cur-
rent by addition of pulverulent reduction agents (Al, Mg), of which
magnesium was found to be the most effective. When using a mixture
of borate powder as emitter, a sufficiently intensive (of the order
of 10- 11 a), constant ion current was obtained, permitting the analysis
of-boron isotopes with an accuracy of 1%. The optimum vorking tempera-
ture was 700-750 0C. The analysis results are given in Table 1. In cal-
culation, no correction was introduced for the content of heavy oxygen
isotopes, To explain the "memory" effect,analyses of specimens with
highly different isotope compositions were carriel out successively
on one day. The results are given in Table 2. In contrast to the results
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S/07 60/034/010/007/022
BO! 5YBo64
AUTHORSt Panchenkov, G. M.. Razanskaya., A. S.~ and Pecheykin. V. A.
TITLEs Exchange Capacity of Alumosilicate Cracking Catalysts
PERIODICALs Zhurnal fizicheskoy khimiiy 1960, Vol. 34, No. 10;
pp. 2217 - 2222
TEXT: Alumosilicate catalysts used for the cracking of hydrocarbons have
an acid character. The type of acid and the role of the various acids upon
the cataly-tic process have hitherto not been clarifi-ed. V. A. Chernov
(Ref. 7) showed that in montmorillonite aluminaj besides proton exchange,
also an exchange of aluminum ions is possible, and that alumina can be
regarded as an aluminum salt of alumosilicic acids. The present Dapex deals
with the ion exchange of an alumosilicate cata
,~jst in aqueous salt solutions
a-A. 84.66%SiO-
alkali metals. A commercial catalyst 4.0 1? ' V 0-36e/-Iqa2qw
0-13%Fe20 3. 0.60%CaO) with a specific surface of 305 m2lg was used., and
annealed at 5500C for two hours before the experiment. The experiments were
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Exchange Capacity of Alumosilicate SIO!616010341010100-11022
Cracking Catalysts B015/BO64
conducted with NaCl, LiCl,, and sodium acetate solutions of differsnt con-
centrations. The acidity caused by the exchange of the alkal-A. metal for the
proton in the catalyst was determined by a method of V. A. Chernov (Ref. 8).
The ion exchange was determined by potentiometric titration of the soluticns
(after two days' vigorous shaking with the catalyst). The results obtained
show that the amount of the exchanged protons is much smaller than that of
the aluminum ions. After the exchange reaction, aluminum was detected in
the NaCl and LiCl solutions, while this was not the case with the sodium
acetate solution. This is due to the fact that aluminum acetate hydrolyzes
immediately on the surface of the catalyst where It is aeposited aq aluln:'rjum
hydroxide, an equivalent amount of acetic acid being di-t!solved. Experiment
and calculation show that the maximum amount of the hydrogen and aluminum
ions of the catalyst exchanged by alkali metal ions is 1;ractically independ-
ent of the'type of the latter (i.e., the values for Li and Na ions are
practically equal). Por the above reason, the amount of acetio aoid
forming from the sodium acetate solution during the exchange of the ions
of the catalyst for Na ions corresponds to the sum of the equiLvalents of
the exchanged hydrogen and aluminum ions of the catalyst,, There are
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S/076/60/034/010/021/022
BO15/B064
AUTHORS: Kuznetsova, Ye. M., Panchenkov, G. M., Filippova,_ R. S., and
'Maldkhov, V. F.
TITLZi A New Method of Separating the Boron Isotopes-r-1
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol. 34, No. 10,
pp. 2370 - 2371
TEXTt A method of separating boron isotopes by a selective extraction
with water and isoamyl alcohol in an apparatus already described (Ref-.-16)
has been developed. After the distribution of boric acid along the cells
of the apparatus the first and last fraction were analyzed for the iso-
topic composition. The analysis was carried out on a MC-4 (MS-4) mass
spectrometer by a method alrcady described (Ref. 17). The results obtained
show that together with the distribution of boric acid between water and
isoamyl alcohol, a fractionation of the boron isotopes takes place, i.e.
in the first fraction a concentration of the light isotope B 10 , and in the
last fraction of the B 11 isotope. Thus, it if; in principle possible to
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A New Method of Separating the Boron Isotopes S/076/60/034/010/021/022
B015/~064
employ the method of an extraction by liquids for the separation of boron
isotopes. A calculation of the separation coefficient of a single
fractionation yielded a - 1.0027. It is assumed that by a combination of
the complex formation characteristic of boron and an extraction, the
separation coefficient is increased and the method described rendered
more economical. There are 1 table and 18 references: 6 Soviet, 6 US,
2 British, 1 Yugosl&a-j. and .1 S.African.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lorionosova
(Moscow state university imeni M. V. Lomonosov
SUBMITTEDt March 319 1960
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B/076/60/034/011/011/024
B004/BO64
AUTHORSt G
PangjZez Makarov, A. V.~, and Pechalin, L. I.
.,,,g
(MOB co vw~~
TITLE: Separation of Boron Isotopes by Chemical Exchange. II. The
Complex Compound of Boron Trifluoride Withp V'-Dichloro
Diethyl Ether (Chlorex)
PERIODICAL; Zhurnal-fizicheskoy khimii, 1960, Vol. 34, Vo. 11,
pp. 2489-2494
TEXT: This paper deals with the exchange of the boron isotopes between
BF3 and its complex with Chlorex. The following reaction equation is
writtent B 10F 3+ B11F 3(C 2H 4CI)20 I-r---'&B 11F3+ B10 F3 (C2H4C')20 (1). BF3was
prepared by the reaction 6NH 4BF4+B 2 03+6H2S0 4 =BBF3+6NH4Hso 4+3H2O (2) in
an apparatus described in Ref- 5- A new apparatus (Fig. 1) was used to
separate the boron isotopes. The process is described. 6 1 of Chlorex are
poured into the vessel 15 through the funnel 10 and the stop cock 11,
Card 116

Sepaz~ation of Boron Isotopes by Chemical 5/076/60/034/011/011/024
Exchange. II. The Complex Compound of Boron B004/BO64
Trifluoride With~ P'-Dichloro Diethyl
Ether (Chlorex)
conveyed into the lower vessel 23 through the stop cocks 12 and 33 by means
of a rubber ball, and 15 is filled again with 6 1 of Chlorex. The BF
formed in the generator is conveyed into the vessel 23 through the siop
cocks 22 and 33, and after saturation of the Chlorex contained therein,
it is passed into the vessel through stop cock 17. Stop cocks 16 and 21,
and balls 9 and 20 prevent Chlorex from being sucked opposite to the flow
direction of BY . A complete and a partially saturated complex
BF (0 H Cl% 0 a;e obtained in vessel 23 and 15,1 respectively. From 23
3 2 4 )2
the complex is sucked into the vessel 29 by the rubber ball and the stop
cocks*19 and 31; then, it is lifted into vessel 8 by compressed air. The
half-saturated complex 15 is passed into vessel 23, and 15 is filled with
fresh Chlorex. From vessel 8 the complex is sucked into the electromagnetic
regulator 3 through glass filter 5 and stop cock 8; the regulator is
controlled by the time relays 2. Regulator and magnetic coil are water-
and air-cooled since otherwise the complex would decompose. The flow rate
through the column filled with passivated nichrome is controlled by
Card 2/6

Separation of Boron Isotopes by Chemical B/076/60/034/011/011/024
Exchange. II. The Complex Compound of Boron B004/Bo64
Trifluoride With f,of-Dichloro Diethyl
Ether (Chlorex)
dropper 38. The column is in a thermostat whose temperature is varied
between 20 - 6000. After having passed through the column, the complex
is heated to 17500 in the desorber 35 filled with glass pipe pieces and
heated with the oil of thermostat 3~6. The liberated BF is conveyed back
into the column through the reflux condenser 39, and Chorex is collected
in vessel 25'. BF samples are*taken in a complex form through stop cook
37 and as a gas hrough cock 41, Chlorey being frozen out in test glass
46 by an acetone-ice mixture. The isotopic analysis was made with an M(-3
(MS-3) mass spectrometer on the bssis of the peaks 10 and 11. The following
results were obtained: In the exchange reaction between BF3 and Chlorex,
an-isotopic separation occurs, B10 concentrating in the liquid phase. The
.separation factor increases from 20 to 6000 when the temperature of the
column rises, and amounts to 1-015tO-OO5 at 6oOc. S.J. Babkov and
N. M. Zhavoronkov are mentioned. There are 3 figures and 17 references:
5 Soviet, 5 US9 1 British, 2 Dutch, 2 French,-1 Swedish, and 1 Swiss.
Card 316

GORSHKOV# V.I.; SHOANOVs A.A.; ?ANCHENK09 G.M._.__.,,
k---------
Electrochromatographic separation on a cation exchanger, Zhur.
fiz. khim. 34 no.'U:2530-2533 N 160. (MIRA 14:1)
1. Moskovskiy gosudarstvennyy universitet in. M.V. Lomonosova.
(Base-exchanging compounds) (Chromatograpnio analysis)
(Electrophoresis)

50) 5/020/60/130/06/028/059
kUTH011Ss Panohenkov, 0. M., Zhorov, Yu. M. BO04/BO07
TITLEi A Method of Determining the Kinetic Constants and Ranges of
,the Coiarse of Chemical Reactions Carried out in a Flow
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol 130, 'Hr 6, pp 1280 - 1283
(USSR)
ABSTUCTt In reference I the first-named author set up general equations
for the kinetics of homogeneous and heterogeneous -catalytic re-
actions in the flow process at constant total pressure. As,
however, in many caaeb the form of the kinetic equation and
the reaction moohanism are not known in advance, the authors
developed a graphical method by using experimental data, which
makes possible a direct determination of the reaction rates ex-
pressed by the variables x and n
(x - quantity of substance
o
- rate at which raw material is
entering into reaccion, n
o
supplied), The equations given in reference 1 are modified
accordingly. The method is demonstrated by using the example
of cumol cracking. Table I gives the experimental data for
cumol cracking. Figure I shows the experimental curve of the
Card 1/2

68996
AUTHORS: anchenkov, G.- .9 Kolohing A. M. 8/020/6o/131/02/042/071
B004/BOO7
TITLE: The Part Played by Chemical Reactions in
Thermionic Emission
PERIODICAL: Doklady Akademii nauk SSSR, ig6o, V-31 131, Nr 2, PP 357 - 359
(USSR)
ABSTRACT: The authors give a report on their experiments concerning the
interaction of an ion-emitter with a Fuetal base acting.as a
heater. The investigations were carried out by means of a mass
spectrometer of the type MS-4. The Ion exchanger A120 3 -4SiO2*XH20,
which was impregnated.with a CsCl solutionp was used as emitter.
Applied to a carefully cleaned platinum base in form of a thin
coating, no ions were emitted by the emitter. Applied onto a
tantalum base, it emitted Cs+-ions. On a platinum basep which
wasq howover, mixed with tantalum powder, the emitter gave the
same ion current as on the tantalum base. The following investi-
gations vrere carried out for the purpose of determining the in-
fluence of the chemics.1 activity exorted by the metal powder
admixed to the enittp,.r up
,pn the ion current. The effect of Cu, W,
Ta, Zr, 11, and j2MpLiiitevWas Investigated. The ion current in-
creased m1th the activity of the metal. Graphite powder yielded
Card 0 1

68994.
The Part Played by Chemical Reactions in Thermionic S/020/60/131/02/042/OT1
Emission B004/BOOT
the same emission as tantalum. Also platinum, which wes repeated-
ly exposed to the flame of a gas burner, may cause an ion current,
probably because of the absorption of impurities, chiefly of car-
bon. Farther experiments concerned the emission of Cs* during
heating up to 15000 without addition of metals to the emitterp the
following temperature decrease to 6000 also resulting in an ion
currentp probably as a result of the thermal dissociation of the
emitter by the previous high temperature. Addition of MnO 2 -led to
an initially considerable decrease of the ion currentp which in-
creased, however, again in the further coitrse of the experiment.
From all these results, the authors draw conclusions as to a
chemical interaction between emitter and 7)aeel the formation of
Cs-atoms, and their ionization on the surface. They carry out a
calculation of A Zo and show in figure I that the logarithm of
T + 0 0
the ion current of Ce at 655 depends liaearly on AZ 10 They
refer to papers by M. A. Yeremeyev (Refs 1,2). Finally, the authors
thank Z. F. Kolchina for her great help in this investigation.
Card 2/3 There are I figure and 5 references, 4 of which are Soviet.

S/020/60/132/04/27/064
3.7100 BO11/BOO3
AUTHORS: Kazanskiy, B. A., Academician, Panchankovp Go Mop
Lazarev, V. I.
I
TITLE: Hydrogenationlof 2-Mathyl-butene I in the Presence of
Platinum Black in Deuterated 11-cohol
PERIODICAL; Doklady Akademii nauk SSSRj 1960, Vol. 132, No. 4,
pp. 832-835
TEXT: In the article under reviewp the authors intend to clarify the
problem as to whether the hydrogen of alcohol hydroxyl directly parti-
oipatos ih the ronotion of oatAlytio hydrogenation* For thip purpooo
they studied the hydrogenation mentioned in the title. The rectified
ethanol which served as medium contained 3-3 per cant of deuterium in
the hydroxyl. The hydrooaxbon formed was analyzed on a mass spectro-
meter in order to determine the deuterium content. Results listed in
Table I demonstrate that isopentane with a content of about 2.3 per cent
of monodeuteroisopentane forms in hydrogenation. No dideuteroisopentanes
Card 1/4

Hydrogenation of 2-Methyl-butene-1 S/02Y60/132/04/27/o64
in the Presence of Platinum Black in 3011 B003
Deuterated Alcohol
alcohol yields hydrogen with a content of 3.4 per cent of HD, whereas
leopentane formed by hydrogenation contains only 2.3 per cent of mono-
douteroiaopentaneo The authors explain this fact by the different rates
of exchange reactions of C2H5 OD for H2 as well as by olefin hydrogenation
on the surface of the catalyst. Hence'it results that the hydroxyl
hydrogen of the alo*ohol solvent does riot directly partioipate.in the
reaction of hydrogenation. The hydroxyl hydrogen is exchanged for the
hydrogen sorbed on the surface'of the catalyst. If, however, an olefin
is present in the system, it reacts with the sorbed E2 and RD in such a PK
way that it is also sorbed on platinum, Thusp the two possible reactions
of isotopic.exchange between the olefin and hydrogen and the alcohol as
well as the reaction of hydrogenation of the olefin have a limiting
stage in oommong i.eep tba sorption of hydrogen on platinum. If a7l
these processes take place simultaneously, the exchange reactions are
retardedq whereas the exchange of the olefin for alcohol is completely
surpressed. The authors thank L. N. Gorokhov, Z..V. Gryaznovag and I. V.
Gostunakaya for their assistance. There are 2 tables and 17 referencesp
.Card-3/4

86842
8/020/60/135/005/033/043
67 ~,I/j 00 0 /-2 ;~~q BG04/BO75
AUTHORS: 9-P-QW-1-v G. M*-and Zhorov, Yu. E.
TITLE6. Method of Determining the Rates and Kinetic Constants of
Complicated Chemical Reactions in a Flom
PERIODICAL: Doklady Akademii nauk SSBR, 1960, Vol. 135, No- 5,
PP- 1.172-1175-
TEXT: In a previous paper (Ref.. 1) it was shown that reaction rates can be
determined from experimental data of the conversion of the initial sub-
stanco as a function of its feeding$ without the kinetic equation of the
proceas being known. In the present.paper, this method is applied to re-
actions producing a~stable intermediate. The following relation is written
for 6ELtalytic cracking: A (Wj) al VB + VD + 9 C
Y4D + 1)50
where A is the initial substance; 11 'is the intermediatel C and D are the
Card 1/3

86842
Method of Determining the Rates and Kinetic S/020/60/135/005/033/043
Constants of Complicated Chemical Reactions B004/BO75
in a Flow,
W, "/1)1)n dz dI is'o~_iained for the product B i with the yield
I oA /so I
z,. In homogeneous reactions, the cross section Y of the reaction vessel
is substituted for So* There are I figure and 2 Soviet references.
ASSOCIATIONi~ Mookovskiy inatitut neftekhimioheakoy i gazovoy promyohlon-
nosti im. 6-M. Gubkina
(MoscovInetitute 'of Petrochemical and Gaseous Industry imeni
I* M.: Gubkin)
PRESENTED:
Juhs,'21, 196o, by A. V. Topdhiyev, Academician
SUBMITTED: June let- 1960
Card 3/3

FkqCHWC.OVj__qA.) TOLMA#OEV, A.M.
"Zur Trennung der Isotope des Sauerstoffs mit Hilfe organischer
Komplex VOrbindungen des Kobalts."
RepIort pre.aented at the 2ad Conf. on Stable luotopes.
East German Academy of Sciences, Inst. for Applied Phyaical Material
14eipzig, GDR, 30 Oct-4 Nov 161.

PANCHENK,D'Vp G. M., KOROVKIN, V. K. and SEMIOMIN, 1. A.
------- --
"Zur Trennung der Isotope des Sauerstoffs bei der Elektrosynthese des Ozons."
Report presented at the ;nd Conf. on Stable Isotopes.
East German Academy of Sciences, Inst. of Applied Physical Faterial
Leipzig, GDR, 30 Oct - 4 Nov 1961

IM~Cfv,__G.M., AIARKOV, A.V. AND PECHALIN, L.I.
"Zur Trennung der Isotope des Bors durch chemischen Austausch."
Report presented at the 2nd Conf. on Stable Isotopes.
Fast German Academy of Sciences, Inst. for Applied Physical Yaterial
Leipzig., GER 30 Oct- 4 Nov 1961.

Georqjy. Mi h; LEBEM- Vladimir IT' Lcbj GOLIDENBERGP
traf4lunEx-c 9 ptror
G. S red YEIMOV p M * S tekhn. red.
[Chemical kinetics and cata3,ysisl Xhimicheskaia kinatika i kataliz,
Moskva, Izd-vo Moak. univ., 1961. 550 P. (MIRA 14:8)
(Chemical .reactiong Rate of) (Catalysis)

ip J12-
t
is
-,Z'a
"~ , ~.. .~- I E,
a v
I 8~
~j %IP
lid
it 'A
ils
it :1 ;, 0 11 1 " ~
11M
; t 45-
.4 ~I.. .11~ 'I -U ~~ Ud
* $0,
it
J-44
0i, Owl'
Ulu I I"

.-I
S/66 yl6l/000/006/057/081
D267 D,302
AUTHORS: Gundyrev, A.. A., Topchiyev, A. V., Panchen-kov, G. ii.,
Nametkin, 11. S. and Ku Chlang-ling
"'ITLE; pendence of the viscosity and de
De nsity of oome classes
of organosilicon compounds on temperature, and t,--,e relat-
ion between the interaction enerv",ieb of molecules of
.L
these compounds and their structure
SOURCE: Xhimiya i prakticheskoye primeneniye kremneorganicheskikh
soyedineniy; trudy konferentsii, no. 6: Doklady, diskus-
sii, resheniye. II Vses. konfer. po khimii i prakt. prim.
kremneorg. soyed., Len. 1958. Leningrad, Izd-vo, UT SSSRt
1961, 239-240
TEXT: A discussion relating to a minor detail of the above paper
(this publication, no. 3, P. 80)9 in which Ya. I. Vabell (I"'loscow)
took part. One of the authors stated that viscoeity of mixturea of
polysiloxane liquids had not been calculated, and that viscosities
at temperatures below OOG had not been measured.
Card 1/2

38589
5/08 62/000/910/072/085
B168XB180
AUTHORSt Panchenkov, G. M., Karryyev, Ch. S., Haia Tze-chih
TITLE& Polymerization of the propane-propylene fraction in the
presence of an alumirlosilicate catalyst with chromic oxide
added
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 10, 1962, 598, abstract
10P20 (Izv. Ali TurkmSSR. Ser. fiz.-tekhn., khim. i geol. n.,
no- 3, 1961, 97 - 104)
TEXTs The process of polymerization of the propand-propylene fraction was
investigated at atmospheric pressure, a temperature of 150 - 2100C and
with gas supplied at a weight flow of 0.1 - 0-4 hr-1 in the presence of an
aluminosilicate catalyst with Cr 203 added. It was found that an addition
of 0-05% Cr 0 to the catalyst will inoreaso the yield of the polymer by
2 3
25 - 30 (calculated on the basis of pure propylene). The maximum yield
of polymer (85-7% on the basis of pure propylene) and also of the trimeric
fraction, occurs at 1900C. If the temperature is raised to 2100C the V
Card 1/9

S/081/62/000/010/072/085
Polymerization of the... B168/B180
yield of the dimerio fraction increases, but if it falls to 1700C it is
the yield of the tetramerio fraction which inareabee. The physical and
chemical properties of the products of polymerization were studied.. It
was found that all fractione consist of unsaturated hydrocarbons. ~_Ab-
stracterts notes Complete translation.]
UY
Card 2/2*

30690
S/152/61/000/012/002/002
B126/B101
AUTHORS: G. M_,,'Yakov1ev, V. I., Kozlovt L. L., Zhuravlev,
V. A., Ryabukhin Yu. S.
TITLE: Radiation thermal cracking of gas-oil from Romashki petroleum
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Neft' i gaz, no. 12,
1961, 99 iol
TEXT: The effect of gamma radiation,on the cracking of gas-oil, F. B. P.
NO - 3450C, from Romashki pptroleum'has been studied. For the experiments
a gamma unit, k -18000 (R-18000), was used, and the dose was maintained
constant at 100 r/sec.; the temperatures were 400 and 4250C, the maximum
dose was 5 Mr', and the experiment took 14 hr. It was egtablished that
CIo60 gamma.rays intensifies the cracking process considerably, and that the
feed is converted twice as rapidly as in thermal cracking. The yield of
the lightest fraction, I. B. P 2000C, exceeds that of all other fractions Vill/
from a dose of 3-5 Mr upward and reaches 30 to 35% of the feed at a dose
of 5 Mr. However, the olefin content of this fraction is lower than that
of the corresponding fraction in thermal cracking. There are 6 figures and
Card 1/2

PARCHERKOV, G.M.; ZHOROV, YU.14.
Method for determining the rates., activation energy., and zones
- -of.simple and-complex reactions in a stream. Neftekhimiia 1
no.2.172-181 i4r,-,kp :61. (MIRA 15t2)
1. Moskovskiy institut neftekhimicheskoy i gazovoy
promyshlennosti imeni 1.M. Gubkina.
(Chemical reactions)

X,OIXMIKOV9 11.M.,,\,,~AWC~il ~Kffq ~G.M,
Derivation of a kinetic equation for 'gas phase reaction of the type
2A - 2AI - A 9 proceeding in a flow under hom6geneous c.onditions.
Kin. i kat. ino._It9-a3 Ta-F 161. -'(MIRA 14:3)
1. Moekovskiy institit neftek4lmieheskoy i gazovoy promy~hlennosti
imeni I.M. (bibkina.
;'..(Chemical reactiong Rate of)

PANCHEhTKOVp G.M.; GORSIIKOV, V. I.
Swelling of cation-exchange resins in mixed solvents. Vysokon.
Poed#3 no.2:177-183 F 161. (MIRA 14:5)
1. Moskovskiy gosudarstvennyy Imiversit-at imeni M. V. Lomonosova.
(Base exchanging compounds)
(Resins, Synthetic)

S/152/61/000/001/003/007
B023/BO64
AUTHORS: Panchenkov, G. M., Skoblo, V. A., Zhorov, YU.N.
TITLE: Determination of the effective diffusion coefficients in
porous sorbents
PERIODICAL: Izvestiya vysohikh uchobnykh zavedeniy. Neft' i gaz,
no. 1, 1961, 73-77
TEXT: The authors studied the sorption process basing on the cpherical
grain of sorbent of the radius R gr' -They assumed that 1) the coucentra-
tion of the sorbed substanoo on the surface of the grain remains constant
and equal to CO; 2) the concentration decrease of the norbod oubatance
within the grain is linear (D. P. Timofeyev, Ref. 3). When describing the
sorption processo the authors used the model of the so-called quasi-
homogeneous grain according to Pshezhetskiy (Ref. 4). Since sorption
proceeds more quickly than diffusion, in each point of the grain an
equilibrium is established between the sorbed substance in the gaseous
phase and on the surface, i.e., in agreement with the form of the iso-
Card 1/5

Determination of the effective S115 61/000/001/003/007
B023YB064
thermal line of sorption. The following is asnum ed: After the time r
since the beginning of sorption has expIred, the front of the sorption
zone reaches the layer r in the grain. The concentration of the sorbed
substance decreases from C 0 on the surface of the grain to zero on the
spherical surface with the radius r. The concentration C a and the
pressure p8 may be determined for any layer a between R gr and r by the
following equations; CS . (9-r)Co/(R gr -r) (1) and pe . (a-r)p,/(R gr-r)
(2). The sorbea substance in the interior of the grain in the layer
Rgr - r is contained on the surface of the sorbent in a quantity a ad s and
in the volume of the grain in a quantity avol, therefore aads-tavol
(7). The amount of the substance sorbed in the layer (between the radius
s and s + ds), is equal to: da a a = 4n5 2ds ( ac~(cr0)ds (8), where aCO is
the amount of the substance per unit of the sorbent volume in the case of
Card 2/5

of the effective
S/152/61/000/001/003/007
B023/Bo64
ion
-Determinat to the pressure Of the Borbed
which corresponds (I is that Part Of the 00,3upiod
rillingi PO; 8 )tion at the
complete ~ tile gaseous Phase othermal line of sorl OBsible
sub at ance in the is equation (6) it i S. P
j.,. j Sdetermined by
iuTf see 'Ort . 1. orbed substance. From
of the 5 'b ,tance:
pressure P0 - e sorbea au
to find the total amount of thaco Rgr 45 s2ds (9).
= 41E __ s JUS B and
aads (1 0 r the limits of the rad
in the layer betveen ion of tiie
The SMO"Int 'Which is P 2 where a is the fract I amount of
is,-davol (Z il 41ES da 009 From (j0) the tota gaseous
,.+ ds, ,f the grain- he grain in the
lume in the interior ( in the interior Of t the f inal f 0'rm'
free v0 substance which is is written down as 2
the sorbed rmi-ned. The following + -2-- P s
phase, is dete t 9r a (!dPa__d9 RT ds-dr (15)-
gr
r ~Rgr r) 'r
Rgr DeffV I .- --- - Liu-
Card 3/5 graphical,3r
ving a number of

Determination of the effective S/152/61/000/001/003/007
B023/BO64
values for aads the values r and x are found which correspond to the
same value aads' The quantity Deff is found by introducing r and 7 into
equation (16). The equations mentioned describe) as is emphasized by the
authors, only the first stage when the front of the sorption moves toward
the center of the grain. There are 3 figures and 6 references: 4
.Soviet-bloc.
ASSOCIATION: Moskovskiy institut neftekhimicheskoy i azovoy
-promyshlennosti im. akad. I. M. Gubkina Noscow Institute
of the Petrochemical and Gas Industry imeni Academician
I. M. Gubkin)
SUBMITTED: June 30, 1960
Card 5/5

111.210
AUTHORSt
22281
6/152/61/000/004/002/009
B126/B219
Panchenkovf Go M., Bazilevich, V. V., Boyeva, R. S.,
Zlotohenko, V. N., Kikolov, N. I.
TITLEs Investigation of the influence of the catalyst composition
on the hydrocarbon content of gasolines from catalytic
cracking
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Neft' i gaz,~'ho. 4,
1961, 57-62
TEXTs The above investigation was carried out in view of the growing
importance of petroleum as a raw material for chemical synthesis. The
combined method of B. A. Kazanskiy and Go So Landsberg for detailed
examination of gasolines served as a basis, (Ref.3i Landaberg G. S.,
Kazanskiy B. A., Bazhulin P, A,, Bulanova T.-F,t Liberman A. L~,
Mikhaylova Ye. A., Plate A. F., Sterin Kh. Ye., Sushchinskiy M. M.,
Tarasova G. A., Ukholin S. A. "Opredeleniye individuallnogo uglevodorod-
nogo sostava benzinov pryamoy gonki kombinirovannym metodom" ("Determina-
tion of the individual hydrocarbon content in straight-run gasolines by a
Card 1/3

22281
5/15 61/000/004/002/009
Investigation of the influence... B126YB219
combined method"), Izd-vo AN SBSR, 1959; Ref- 0 Landsberg G. S.,
Bazhulin P. A., Sushehinskiy M. H. 110snovnyye parametry spektrov
kombinatsionnogo rasseyaniya uglevodorodov" ("Basic parameters of the
spectra of Raman scattering from hydrocarbons"), Izd-vo AN SSSR, 1956).
A distillate with a boiling interval at 300-40000 was used as initial raw
material. Cracking was brought about in the laboratory at a temperature
of 4750C and a feed rate of the raw material of 0.7 ml/hr, and lasted for
I hr. The experiment was carried out under the same conditions in two
equal apparatuses with aluminum silicate catalysts of various Al 203 con-
tent, viz. a commercial aluminum silicate catalyst consisting of
12.8% Al2039 85.1% S1029 0.2% Fe 203t 0.05% Cr 20 39 and a synthetic
aluminum silicate catalyst with 30% Al 203 and 70% S102* The fractions
55-95 and 95-122 0C were subjected to chromatographic adsorption, the
losses being far less through use of the method of A. V..Topchiyev and
collaborators (Ref. 6t "Khimiya i tekhnologiya topliva i masel", no. 11,
1957). In the determination of the individual composition of the narrow-
band fractions, the method of the Raman spectra was used. The results of
the investigation showed that the catalyst with the higher Al 20 3content
Card 2/3

2h656
8/076/61/035/006/008/013
B110/B220
AUTHORSs Panchenkov, 0. M., Makarov, As V.9 and Romanov, G. V. (Mosccw)
TITLEs Separation of boron isotopes by the chemical exchange method.
III. Production of B11F 3 concentrate
PERIODICALs Zhurnal fizicheskoy khimii, V. 35, no. 6, 1961~ 1315 - 1320
TEXT: Since the effective capture cross section of thermal neutrons
amounts to 0.05 barn for B 11 , it may be used in form of zirconium and
yttrJum boride, etc. as heat-resisting material in reactor construction.
The present paper deals with a chemical exchange method for the separation
of B10 and B 11 isotopes according tos
B 107 + B11 F C H OCH .3 11 F + B102 0 H OCH (1).
3 3* 6 5 3 3* 6 5 3
Phase transformation is obtaineds
BF 3*06H 5OCH 3-desorber 12Q!2,,BF3+ C6H 5OCE3 (2).
absorber 2000
The liquid BF 3'C6H5OCH3 passes from the "infinitely large" tank 1 (Fig. 1)
Card

2 656
8/076 61/035/006/008/013
7
0~B!,
Separation of boron... Bil B220
with constant velocity into the desorber heated tojl500C by anisole. From
2 BF 3 enters the bottom part of column 3, the liquid anisole passing the
pump system 6 enters the absorber 4, where also BP 3 enters after having
passed the column. Here, the complex compound BF 3-aniBole is formed again.
Samples were taken periodically by means of 5. By means of 4, 5, B (Fig.2)
6 1., anisole were filled into the 15 1. glass vessel 1. The electromag-
netic JMtAb(EMIB) agitator 2 was started and then BF 3 introduced. The
water cooling of absorber 26 and coolers 14, 24, 44 was put into operation,
the thermostats 19, 42 connected and the temperature of column 41 and de-
sorber 18 adjusted. The boron complex passed through a rubber bulb and 10
into the siphon preceding the dosing device 12-17. By means of electromag-
net and impulse transmitter a copperplated iron bar fitted in the glass
tube 12 was moved up and down rhythmically as desired (2-12 imp/min). Then
the complex passes the water-cooled elbow 14, the buffer vessel 15 filled
with a glass spiral, and the dropper 16 and enters the desorber 18. The
best results were obtained with the mechanical pulse transmitter with,
Card 2/9

246,56
S/076/61/035/006/008/013
Separation of boron... B110/B220
CA -2 (SD-2) synchronous motor, PkC (RKS) relayt 4 imp/min. The optimum
flow velocity was 2 ml/min. The electronic pulse transmitter withq AM-26
(DGTs-26) rectifier, Cp2C (SG2S) tube, ~r_M-l (M-1) and P4-90 (RN-90)
relays gave a large-number of pulses (3-30 imp/min) with low consumption
of liquid. The complex was decomposed in the glass-packed desorber 18
(length = 0 cm, interior diameter = 20 mm) which was heated by warm oil
from the 4-24 (TS-24) thermostat 19. BP 3 passed through the return con-
denser 44 into column 41. The anisole contaminated by resin entered the
evaporator 21. It flowed through the inner tiibe and then over the glass
beads, where it was evaporated. The resin was evacuated by 20. 21, 22,
and 23 were it was heated by a nichrome coil, The anisole vapors passed
into-the oolumns 22 and 23 consisting of 3 glass tubes telescoped into
each other. Anisole vapors passed through the inner tube (diameter - 1cm),
the niohrome spiral was wound around the intermediate (diameter - 2 em) ,
the outer (diameter - 4 am) served as heat insulation. The temperature of
the column was regulated by means of a rheostat and controlled with a
Cr-Al thermocouple. knisole for spraying the absorber 26 packed with
glass rings was supplied by the cooler 24. 25 served for evacuating the
CY presumably formed. The complex subject to isotopic exchange in
Card 4ilq

24656
Separation of boron...
B/076/61/035/006/008/ol'A
B110/B220
column 41 was formed in the absorber. The column consisted of a tube
(length - 1.5-2.2 m, diameter - 18 mm) in the outer jacket of which water
coming from the TC-15 (TS-15) thermostat circulated. The inset consisting
of Fenske glass rings etched with HF + NH4F occupied a space Of 3-3-0.6 mm.
The sampling system 27-39 was evacuated through 38 in a prevacuum. Then
26, 32, and 33 were cooled with liquid nitrogen by means of Dewar vessels,
31 and 35 closed. A certain quantity of gas tapped from the column
through 29,25 being closed for this period, was frozen in 36 by means of
a Dewar vessel and further cooled in 32 and 33- 32 and 33 were unsoldered.
The analysis was made by a MC-3 (MS-3) mass spectroscope, the sample ob.-
tained in test 3 was converted to borax and analyzed by means of K-4
(MS-4) according to A., M. Kolchin. In the first test (I) (length of column
= 2.20 m, of absorber - 6 cm) a part of the BF3 was not absorbed by anisole
and escaped~ thus the low coefficient of separationg 1-05. Also in the
second. test (II) (column = 1~5 M; absorber - 50 cm) BF3escaped. Only in
the third test (M) (dimensions as for (II)) BF 3 was absorbed quantita-
tively. A coefficient of separation of 1.42 was attained after 32 hr.
Card 4/9

24656
S/076/61/035/006/008/013
Separation of boron... B110/B220
With too high (A) or too low (B) temperatures in the column either complex
formation occurs in the column and sampling is impossible (A) or a part of
BF3 escapes (B). Consequently, the temperature of the column has tD be
such that the complex of given composition is saturated. This was ob-
tained in the following way: the temperature was slowly increased until
BF3 vapors left 25 and then reduced by 2-30C- It was found that the red
color of the anisole complex is due to products of resinification formed
under the influence of atmospheric humidity. The complex is colorless in
the column. The plant may serve for any complexes whatsoever, provided
that the temperatures in desorber and pump system are changed. The
production of B10F3 concentrate requires charging into the top part of
the column. A. M. Kolchin and V. F. Malakhov are thanked for their
assistance in the experiments. There are 3 figures, 1 table, and 15
referencess 10 Soviet-bloc and 5 non-Soviet-bloo. The most recent refer-
ences to English-language publications read as follows: S. V. Ribnicar,
G. A. Bootsma, Bull. Inst. nuclear Bei. 11B. Kidrich" (Belgrade), 3, 91,
1959. A. L. Conn, I. E. Wofl, Ind. Eng. Chem., ~0, 1231~ 1956.
Card 5/9

2h656
S/076/61/035/006/008/013
Separation of boron ... B110/B220
A. A. Palko, Ind, Eng. Chem., 51, 121, 1959.
ASSOCIATIONs Modkovskiy goBudarstyennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTEDs September 28, 1959
Card 6/9

'PANCHWOV., G.M.; PECHAIMI, L.I.
--------------
Determination of the single-stage separation factors of sulff~
isotopes. Complex compounds Of S02- Zhur. fiz. khim. 35
no.7;1643-1644 JI 161. (MIRA 14:7)
1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova.
. (Sulfur-Isotopes)

S/07 61/035/007/018/019
B I 24YI323 1
AUTHORSt Korovkin, V. K., Semiokhin, I. A., Panchenkov, G. M., Jui
Shih-bhuag
TITLEt Separation of oxygen isotopes'in the electrosynthosin of ozoie
PERIODICAL; Zhurnal fizicheskoy khimii, v. 35, no- 7, 1961, 1648 - 1650
TEM It has been discussed by the authors at an earlier occasion (Rbf. 1.
I. A. Semiokhin, G. M. Panchenkov, V. K. Korovkin, A. V. Borisov, Zh. fiz.
khimiij 11, 1933, 1959) that the steady state in the separation of oxygen
isotopes sets in long before the equilibrium ozone concentration is
attained. The concentration turned out to be about equal to that found
as a result-of investigations carried out under different conditions
(different values of the specific energy U/v, different dimensions of
ozonizersq different methods of ozone accumulation and sampling), and
showed to be independent of the concentration of the ozone obtained. The
present work engages in changing the conditions so as to attain the isoto-pe
equilibrium and the concentration coefficient at changed pressure- and
temperature ratios in the system. The investigation was carried out in a
Card 1b

3/076/61/035/007/018/019
Separation of oxygen isotopes in... B1~4/'B231
device described in 7-,ef. 1, that is, in a ievactor of 600 mm length
provided with a I mm wide spark gap. The discharge power was determined
from the volt-ampere characteristic with the aid of the equation
U - Vo(Iav - or ) derived by Yu. V. Filippov and Yu. M. Yemellyanov
(Ref. 2: Zh. fiz. khimii, 31, 896, 1957; a, 1042, 1959), where I av is
the mean value of the current flowing through the ozonizer, Ior the mean
value of the current in case of a critical terminal potential in the
ozop,izer, and V0the amplitude value of the ignition voltage discharge.
The effect of pressure was stuO,ied in the range 300 - 900 mm Hg with the
walls of the ozonizer exhibiting a temperature of 200C. The mean concen-
tration coefficient was constant within the test errors, and is computed
from the equation 8mean - 1.100 � 0.013, where 0.013 is the mean errori
in more than 75% of the tests, the mean error was smaller and equal to
0.010. The steady state in the process cf anotopic exchange would be
attained if the values of U/v were close to one whirh corresponds, in our
case, to a duration of the gas in the discharge of 1 - 2 seconds. The
Card 2/ 5

-61/035/007/018/019
S/076/
Separation of oxygen isotopes in B124/B231.
e uilibr" ozone concentration,will be attained only in case that the
U~v-valuleusmexhibit an energy'of 5 -8.watt:�/I,.*hr and increases when pressured
is raised (Fig. 2). Five series of tests were'carried out at a Wall
temperature varying between -19 and +920C and 'constant pressure of 76Q mm
Hg. The results obtained showed that a rise in temperature causes the-
concentrati6n. edeffioient t*0 increase ('Fig. 3). A temperature ride in the
.i-reactor causes a considerable drop of the ozone concentration. Thp data
p-obtained indicate that the separation of oxygen isotopes in the electro-
synthesis of ozone is not determined by the exchange of oxygen isotopes
'but
between oxygen and,synthesized ozone, directly by the formation of
ozone from oxygen. Indicative of this is the independence of the distri-
bution coefficient S on the durstion of oxygen in the discharge zone and-
the relatively high experimental. value of S (about 1.10 at room-temiperature)
as compared with the equilibrium values of 3 for the exchange reaction
for the comp!atation.of Which the method of statistical thermo-
(S, 1.03
dynamics was appliod. There arb 3 figures, I table, and 2 Sloviet-bloo
ref erenc es.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. V. Lomonosova,
(Moscow State University imefii,M. V. LomonoeOVL)
Card -3/5

!~.~ i4, 1, ~Nlr~lq -i,- ~.,: ~ 1:
I", _c .
t~ " 1~ - 'T , * , , -:
,.. I - r ,

SEMIOMM, Z.A.; KOROVKIN, V.K.; PANGHENKOV, GA.; ZM SRI-CHZHUN
[,Tui Shih-chuang] --------------
Separation of -oxygen isotopes by the excIump 602 H20
in an. electric dise-barge. Zhurefiz.khim. 35 no.8:3.881-.1883
Ag 161.~ .(MIFA 14--8)
1. ljo~kovskiy gosudaretvennyy universitet imani 14.V. lftii~a.
(dvgeu-iboto~es)
(Carbon dioxide)
(Water)

27680
5/076/ 1/035/009/009/015
B1061B110
AUTHORSt Panchenkov, G. M., Makarovt A. V., and Pechalin, L. I.
TITLEs Separation of boron isotopes through chemical exchange.
IV, Complex compound of,boron trifluoride with phenetole
PER10DICALs Zhurnal fizicheskoy khimii, v- 35, no- 9, 1961,.2110
TEXTs In previous papers (Ref. 1i G. M. Panchenkov, V. D. Moiseyev i
A. V. Makarovt Dbkl. AN SSSR, 112, 659* 1957; Ref. 2s same authors, Zh.
fiz. khimiij ~19 18511 19571 Ref- 3t 0. M. Panchenkov, A. V. Makarov i
1. Pechalin, Vestn..Moskovsk. un-ta, seriya "Khimiya", No. 29 39 19601
Ref. 42 same authors, Zh. fiz. khimii, 3A, 2469, 1960; Ref- 5: G. M.
Panohenkov, A. V. Makarov i G. V. Romanov, Zh. fiz. khimii, 3a, 1315f 1961),
the authors had reported on using isotope exchange between boron tifluczide
and its complexes with anisole and Chlorex for separating boron isotopes.
Iri one of these studies (Ref. 2), the possibility was mentioned of using
the isotope exchange between boron trifluoride and its complex with
phenetole1or separating the boron isotopess
BIOF3 + B 11 F3 0C6H5002H 5 1, 13 11F3+ BtoF3 '06H5oc2H5
Card 1/3.

'2768,6
S/0~6'~_1/035/009/009/015
Separation of boron isotopes through ... B1067B110
The first results obtained for this system are described. The separation
of boron isotopee,was carried out in an installation designed for the pre-
11
paration of the isotope B . Design and mode of operation of this instal-
lation had been described previously (Ref. 5). The only alteration con-
sisted in a more effective attachment made of W1819T (lKhl8U9T) stainless
steel in the form of three-faced 2 by 2 mm spirals of 0.2 mm diameter wire
instead of the glass attachment used previously. Phenetole "p. a." without
additional purification was u.sed. The experiments with the phenetole
complex showed that this complex foams at a slight temperature increase.
Thia.greatly complicated the operation of the siphon through which the
co4lex entered the column. The column temperature during the experiment
was 3000, that of the aesorber AJ17000. The complex was admitted at a rate
OfIVI ml/min. After 14 hr of operation a gas sample for the isotope
analysis was taken from the absorber. Mass spectrometric analyses conducted
by A. M.-Kolchints method using borax ions as emitters (Ref. 6: A. M.
Kolchin, V. F. Malakhov i G. 14. Panchenkov Zh. fiz. khimii, 3A, 2124,
1960) showed that the isotope ratio B11/B16 in the specimen had the value
5.1e + o.13 ( for the reference specimen the ratio was 4.09 � 0.06). This
result corresponds to a total separation coefficient of 1.26. As in
Card 2/3

S/ 76/61/035/009/009/015
Separation of boron isotopes through ... B1061BI10
other, previously studied complexes, the lighter boron isotope is enriched
in the liquid phase also i;3 this vxchange. The authors thank A. M.
Kolchin and V. F. Malakhov for conducting the mass spectrometric analyses.
There,are 6 Soviet references" [Abstracter's notet Complete translation]
ASS.001ATIONi Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
Xhimicheskiy f-t (Moscow State University imeni M. V.
Lomonosov, Chemical Division)
SUBMITTEDs- December 26, 1959
Card V-3

IMNETSOVAP ye*M.; j4AYjj'IOV) A*V.; -PAIIGHENK
Application of the multistage ex1reriment formula for
devising the scheme C)f an ideal cascade.. Zhur-fiz-kh~M-
35 no.9;2116-2119 161 (IMI.A 14:
ilsotope, separation'

27659
S/0,`6/6!/035/O09/O`,4/O15
21. hZ00 B1 24/B10 I
AUTHORS: Makarc*i.. A., V., and Panchenkov. G. M,.
TITLE: Separation of boron isotopes by the chemical exchange method.
V. Dependence of the separation coefficient of the column
on temperature and load
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 9, 1961, 21147-2150
TEXT: With regard to the importan:~e of an appropriate choioe of optimum
conditions in the pasked counter3urrent column used to effect separation Gf
boron isotopes by two systems (BF BF C H OCH and BF BF (C H C11 0)
3 -' 3* 6 5 3 3 - 3' 2 4 /2
with different packing materials (glass rings and coils made of Nichrome),
particularly regarding temperature and load, the dependence of the sepa-ra-
tion coefficient of the :;clumn --r. temperature and feeding rate of the X
complex to a column 2 m high was studied. The boron samples recovered were
analyzed with a mass spec-~rometer either in the form of BF 3 Or Of Na2B407*
With respect to the c~cnsiderable deviation of data on the dependence of the
separation coefficient of thq column on its time of operation established
Card 1/4

Separation of boron Js-,,top.-~a
689
S~70 u 61/035/009/014/015-
"YB
BI 24 BI,01
4
by 32 experiments, these data were treated using the-least squares method,
and the empirical equation :3 - 1 - (Sequ - 1) t/It, /2 + t) is used for
correction; here S is the s-9paration coefficient cQrresponding to the t~"m-a
t' Bequ the equilibrium valuo of this coefficient (for t - co),ar-d t4/2 the
time necessary to atta�n the value /8
0/2. This equation is much
equ
simpler than the equation derived by S. 1. Babko-, and N. M. Zhavoronkcv
(Ref. 6: Dokl. Ali SSSR 106, 87-: 1956". The temperature dependqn-~e of S
compi equ
for the anisole complex is high.11 lex (Fig. 2) which is probably
mainly due to the isotopic effec, of desorption. From the curve for the
dependence of the separation sof: ficient Sequ or' the feeding rate cf the
complex (Fig. 3), it is evident ,,hat tne latter has only a sma-,1 effect ~,n
+ t for cases when S sharply de~~reases
the separation c;oefficien., exc e,-,u
at low rates. Calculated optir.m conditions are; column temperature
somewhat higher than room -~emp~;sture (about 4000 for the anisole complex,
and about 600C for the oomplex.,'.~f BF 3with chlorex)9 sufficiently high rate.
of feedingr and use of packing_*!aterials having maximum specific surface.
Card 2/4

PANCHEIROV, G.M.
Dynamics of unsteady physicochemical processes in a flow under
conditions of the bimolecular Vfteess-rate law. Dokl. AN SSER 140
no.2:412-415 S 161. (MIfU 14.9)
1. Moskovskly institut neftekhirdcheskoy i gazovoy promyshlenno3ti
im. I.M.Gubkina. Predstavleno akademikom A.V *Topchiyevym.
(Chemistry, Physical arxi theoretical)

BALANDIN,*A.A., akademik, red.; KOBOZEV, N.I., prof., red.; LEBEDEV,
V.P., dateop iam. red.; 14ALITSEV, A.U., zam. red.; AMOLOI-M.,
A.Ye., dots., zarr,. red.; TOFCI',IYEVA, X.V., prof., red.; YURIT-EIT,
jCIWiKOVj__G.My prof.,, red.; SOKOLISKIY,
Yu.K., prof., red. P,11
D.V., akademikt red.; VOLIM.'5MM, F.F., prof., red.;IAZAP-EVA,
L.V., tekhn. red.
(Catalysis in the institutions of higher learning; papers of the
First Interunivernity Conference on CatalysislKataliz v vysohel
shkole; trudy. MosImaj, IM-1,10 Yonk. univ. No.l. Pt*2. 1962.
325 P. (IMA 15-10)
I. MezhvUzovsk6ye sovesbabaniye po, katalizu. let, 1958, 2. Aka-
demiya nauk Kazakhskoy SSa (for Soko1'9kiy)t-3.,-bImIaheukiy fa-
..kuIttet-Moskovskogo gosudar6tvermogo universiteta (for Yurlyev).
(Catalysis)

S/632/62/000/000/011/015
D424/D307
AUTHORSt Gundyrov, A.A., Nametkin, N.S.,.Panchenkovt
_3,.~~d Topohiyev, A.V.
TITLEt Viscosity of some liquid organosilicon
compounds and the enorgz~ of interaction
of the molecules of these compounds
SOURCEs Issledovaniya. v oblasti kremniyorganiches-
kikh soyedineniy; sintez i fiziko-khimiches-
kiye svoystva.. Sbornik statey. Inst. neftekhim.
sint. AN SSSR. Moscow..Izd-vo AN SSSR, 1962,
205 - 218
TEXT: With the object of establishing general laws
relating their physical properties to their structure, the den-
sities and viBoosities of 43 organosilicon compounds have been
measured over the t~m 'nerature range from 10 to 850C, at 150 inter-
vale, measurements ior three of them being carried out also bet-
ween -600 and OOC (at 20Q intervals). The compounds are:
Card 1/3

S/832/62/000/000/011/015
Viscosity of some ... D424/D307
hexaalkyl derivatives of disilylmethane, -ethane, and propane,
and of disiloxane, trialkyl derivatives of phenyl-, 4-methyl-
phenyl-, and 3,4-dimethylphenylsilanes, and dialkyl derivatives
of diphenyl-, bis-4-methylphenyl-, and bis-3,4-dimethylphenyl-
silanes. The densitiep, measured in a weight dilatometer to an
accuracy of 0.0001 g/ml, were found to obey the linear relation
T
e,. a + bT
whore dT is the density at absolute temperature T,- and a and b
are constants. The viscosities,*q , measured in a modified Ostwald
--iscome-ter to an accuracy of 0.00001 poise, were found to agree
,iell with Panchenkov's formula
Ad 4/3T1/2e_cO/RT e-9 O/RT
where &0 is the energy of bond formaiion between molecules, per mole,
Card 2/3

8/832/62/000/000/011/015
Viscosity of some D424/D307
R the universal gas constant, and A a magnitude which can be
considered constant over a relatively narrow range of temperature.
The formula was used to calculate E0. Replacing an alkyl radical
in aryltrialkylsilanes by an aryl radical leads to a considerable
increase in -11 and 1. 0 . T - dependence of * 11 of the hexaalkyl
derivatives of disiloxane is lower than thatof the corresponding
derivatives of disilylmethane and disilylethane. In the hexeLalkyl
derivatives of disily1methane and disilylethane, the increase in
to as the main chain is increased by one CH2 group averages 295
Cal/mole, as compared with 209 cal/mole for the n-alkanes. The
intermolecular bond energies for the polyz4ethylsiloxanes and the
polyethylailoxanes increase with a rise in the molecular weight,
thoBe for the former being higher than.thdse for the latter.
There are 10 figures and 4 tables.
Card 3/3

/012/05
5/632162'/000/000
-D4?1+/'D3Ol
P'.A
7 -,N r'.111 - S14 ourid's
silicon coz?
,,face tensioll Of 'hes
er Of classes rlic
b yorga
rmelli
of oblast' Y i fj%ilko. nef te "him
aovarliya ~ . . ntez 4 -111st 19621
-I.Sle .,&irkeral- 13 tateY SS~R'
so~ stva. SbOT 'IZ&-VO
S" SSSI~- JAOSC
'26 & to supp"y
219 r4e-nce Of
f tbe clepe teWra-
vestlg .,,ICI 0 a's O'n the L Osiji-
Tne iv . a f 39 OT9 n
_,,uale COMI)o"D the
he little . li.GOTL oull6ary 0 a OJer were
11 t rganOsl ajr b me a S-ur e 'ats
0 matlo .ioll of 0 es %4as sureme deA
r terks or, at all mea sue
rface te-As' lit 0186BS The ose& by
tn e Bu surface (jifrere . teTvals' 86S P-fo'p
t-a-re. TIle Of 12 at 100 JU ter
cor, ComIlouncls -to ()Or" ble -l'scome
20 -bab
.e f Tom all air
raug
I ou
Oka

S/832/62/000/000/012/015
D424/D307
(J.Chem.Soc., 121, 857 (1922) ) Abstractor's note: reference
corrected,7, improved by 14uale and Smart (J.Amer.Chem.Soc., 66,
935 (1944) ), and further improved by the present authors. The
constant of the viscometer was determined with benzene and
checked with n-heptane and water. The following classes of com-
pounds were investigated: hexaalkyldisilylmethanes, -ethanes,
and propanes, hexaalkyldisiloxanes, phenyl-, 4-methylphenyl-
and 3,4-dimethylphenyltrialkylsilanes, diphenyl-, bis-4-methyl-
phenyl-, and bis-3,4'-dimethylphenyldialkyls,ilanes, and linear
and cyclic polyethoxysiloxanes. In all oasfis the-surface tensions
were found to obey the linear relation
where 6t is the surface tension in dynes/cm at tOC, and a and
are constants for a given compound. The surface tensions of
hexaalkyldisiloxanea are 2-3 dyne/cm less than those of the cor-
responding hexaalkyldisilylmethanes or -ethanes. The transition
Card 2/3

S/832/62/000/000/012/015
Surface tension ... D424/D307
from hexamethyldisilylmethane to the corresponding cliailylethane
and disilylpropune derivatives is accompanied by a regular increase
in dt. Lengthening the polyethylsiloxane chain by successive di-
ethylsiloxy units is also accompanied by a regular increase in 15t.
In addition, the following pairs of analogoiis compounds were
investigateds diethylsilane-n-pentane, (lipropylsilane-n-heptane,
dibutylailane-n-nonane, phenylmethylailanti-ethylbenzene, and'phenyl-
dimethylailane-iso-propyl'benzone. The aurfaoe tensions of the alkyl-
silanes were close to those of the corresponding hydrocarbons,
while the surface tensions of the alkylarylsilanes were 1.5-2 dyne/cm
higher than those of the corresponding hydrocarbons. There are 5
zables.
Card 3/3

S/832162/000/000/013/015~
D424/D307
AUTHORS: Gar, P.P., Gur..frev, A.A., Nametkin, li,S.'
Panchenkov, G.M. and Topchiyev, A.Y.
TITLE: Refractometric investiptions of some
organosilicon compounds
Issledovaniya v oblasti kremniyorganiche~s-
ikikh soyedineniy; sintez i fiziko-khimiches-
kiye svoystva. Sbor'nik atatey. Inst. neftek-
him. sint. Ali SSSR- Moscow. Izd-vo All SSSR,-
1962, 228 - 234
TEXT: The refractive indices at 200C for the C and F
lines of hydrogen (for the first time) and for the D line of
sodium have been measured for 46 compounds of the following classes:
the hexaalkyl derivatives of disilylmethane, disilylethane, and
disilylpropane, and of disiloxane, aryltrialkylsilanes, diaryl-
dialkylsilanes, and linear and cyclic polyethoxysilanes. From the
results, the individual, mean and specific dispersions, and the
Card 1/3

5/1332/62/000/000/013/015
Refractometric investigations D424/D3()7
molecular refraction for the D line, have been calculated. As
a rule, in any one class of alkylarylsilanes those in which the
alkyl group is ethyl have the highest refractive index. The re-
fractive indices of dialkyldiarylailanes are about 0-05 units
higher than those of the aryltrialkylailan(ts with the same alkyl
and aryl groups. In the case of the phenyll;rialkylsilanes, the
introduction of a methyl group into the 4- position of the phenyl
ring and then a second methyl group into the 3- position increases
the refractive index, while the situation is reversed in the case
of the aryltrialkylailanes. The specific dispersions of aryltri-
alkylailanes are 15 - 20 % lower than those of the corresponding
diarjrldialkylailanes. The refractive indices of the hexaalkyl
derivatives of disilylmethane, disilylethane, and disiloxane
increase with a rise in the molecular weight, those of the di-
siloxanes beind leas than those of the corresponding members of
the other classes. On passing from hexamethyldisilylmethane to
the corresponding ethane and propane derivatives, the refractive
index increases by 0.0025 units per CH2 group added, while the
specific dispersion is decreased. The change in the specific
Card 2/3

5/832/62/000/000/014/015.
D424/D307
AUTHORS: Gundyrev, A.A., Nametkin, N.S.., Panchenkov,
G.M. and Topohiyev, A.V.
TITLE: Dielectric constants and dipole moments of
some organosilicon codpounds
S6URCEs Issledov~niya v oblanti kremniyorgani-*
cheskikh soyedineniy; sintez i fiziko-
kbimicheskiye svoystva. Sbornik statey.
Inst. neftekhim. sint. AN SSSR. Moscow.
Izd-vo AN SSSR, 1962, 235 - 242
TEXT: The dielectric constlints of 16 organosilicon
compounds of the following types have been investigatedt hex&-
alkyl derivatives of disilylmethane, disilylethane, and disilox-
ane, and,polyethylailoxanes, most of them for the first time.
The dielectric constants werc 1-~,asured at 250 in n-hexane at
a frequency of 7.95 x 105 cps by the method of bea-ts, with an
accuracy of 0.02 The apparatus was calibrated with benzene
Card 1/2

8/83 62/000/000/015/015,
D424-YI)307
Y7 0 o
AUTHORS: Kolemikov, I.M., Gundyrev, A.A.,. 14ametkin,
N.S., Panchenkov, G.14. and Topchiyev, A.V.
TITLE- Behavior of some organosilicon compounds in
the region of the solidilication temperature
SOURCE; Issledovanl:ya v oblasti kremniyorganicheb-
kikh soyedineniy; sintez i fiziko-khimicheskiye
svoystva. Sbornik statey. Inst. neftekhim. sint.
AN SSSR. Moscow, Izd-vo Ali SSSRI 1962, 243-253
TEXT: The solidification behavior of 31.organosilicon
compounds has been investigated in order to determine their true
melting points and purity, and the oonditions under which glasses
are formed. The compounds were of the following types: hexaalkyl
derivatives of disilylmethane, -ethane, and -propane, and of
disiloxane, phenyl-, 4-methylphenyl-, and 3, 4-dimethylphenyl-
trialkylailanes, diphenyl-, bis-4-methylphenyl-, and bis-3,4-
-dimethylphenyldialkylsilanes, linear and cyclic polyethylsiloxanes,
Card 1/3

5/832
,/62/000/000/015/015
Behavior of some ... D424/D307
dialkylsilanes, and an aryldialkyleilane. The main feature of the
apparatus used is that the sample was contained in a double-walled
glass vessel immersed in liquid nitrogen, the rate of cooling being
controlled by the degree of evacuation of the space between the walls.
riany of the compounds underwent pronounced supercooling and others
did not crystallize but formed glasses. Where a glass was not fomed,
the m.p. of the material as such and the true m.p. of its main con-
stituent were determined graphically b~ Rossini's method (J. Res.
Rat. Bureau Standards, 32, 197 (1944) . In the series of phenyl-
trialkylsilanes, the methyl and propyl compounds supercool only
slightly and then crystallize spontaneously, while the ethyl com-
pound crystallizes only after the deeply supercooled liquid is
seeded, and the butyl com-und forms a glass. Somewhat similar
behavior is found with ot..ar series of compounds, the following
also forming glasses on cooling; 3,4-dimethylphenyltripropyl- and
-t-"ibutylsilanes, diphenyldiethyl- and*-dibutylsilanes, bis-4-
me-thylphenyldimethyl- and -dipropylsilanes, bis~3,4-dimethyldiethyl-
silane, hexapropyldisilylmetl_~.ne and.-ethane, and the polyethyl-
siloxanes containing 5, 6, 7 and 8 oxygen atoms. The viscosities
Card 2/3

beha ---"Mom
i'lor Or some
or the COMP
bond Ounds 3y~'83216,01000100010
ene are also 61" D ~2
i 1 4/b307
Y ScosItfgles calcu, en
Th ated rom 151015-
ese Sh "I by Pach er tOge ther
ikovi the V,j th
e 11 er - Ow that I tem the
Gles 1. 1 rormul
as than" general PO-ra tul'e d .1 n t erm 0
w-h-ile compounds . abo I I corn 11 (zh. 1', ('Penden,, I Cular
glasses. wa th u t 4ooo Pounds ,It 2- khim c Of th
T1, ere ~.r e4
a 9 eateroal/mole jr h Interal' 1930
-re yatAll! olecul bon(1950))
ar d
fiau.res 4-311termojecular boze on ljn6,
table. nd ene coo
Carci 313

GOLUBEV, V.S.; FANCHENKOV, G.M
layer method for approximate calculation of the dynamics of
equilibrium sorption and chromatography. Izv. Sib. otd. AN
SSSR no.3:45-53 162. (MIRA 17:7)
1. Moskovskiy gosudarstvannyy universitet.

AKC H ENK0
43 7EI
G/025/62/000/004-5/002/005
1042:/1241
AUTHORS: Semioehin, I.A., Pan4likov, G.M.,'and Ko'rovkin, V.K.
TITLE: The separation of oxygen isotopes during the eleotro-
synthesis of Ozone
;-PERIODICAL: Xernenergie, no..4-~, 1962, 300-303
TEXT: The isotope feactionation of oxygen isotopes-between
n and ozone during rhe 4lectrosynthe6is of ozone was investi-
oxyge
-the flow velocity, the length of the ozonizing
gated as a function of
tube, the gas pressure and wall teraperatpro; with a view of utilizing
electric discharge conditions for the rapid attainment of isot6p~c-
ilibrium between species f or.. the. purpose-of-isot.
iequ ope production.
Stationary isotopic fracti:onation was establishpd' much fpLster than
'ion; the isotope .frac-
!.:t~he attaiziment of stationary ozone concentrat
tionating factor between ozone and oxygen was Sbund to increase from
Card 1/2-

7
40926
/62/000/005/001/006
S/189
D204/D307
0
AUTHORS: Panch,.-R~L qvQ~t Makarov, A. V., Wyaclienkot
V. Ya., and Moiseyev, V. D.
TITLE: The v1soosity-of boron trifluoride
PERIODICAL: Moscow. Universitete Vestnik, Seriy~ II,
Khimiya, nov 5, 1962# 11-13
T"EXT: The viscosity of BF3.NBF3 wasImeasured to determine
its dependence, as such data are necessary for thermodynamical
calculations associated with thermal diffusion columns involving
gas. The apparatus (Fig. 1) was made of Mo~ glass and quartz.
For a determination, container 2 (20-1) was fille'd with GO -at
2
e,,keeping taps 15 - 113 closed; Hg was then pumped
atm.-preBBur
-into 14 to just cover the top Pt 'lead (21t 23 and 24 closed).
Tap 24 was then opened, and the time of fall of Hg between the
upper -6wo leads and 14 was measured time required by the C02
Gard 11,V

PANCHENKOV, G.M.; ZHOROV, Yu.M.
Kinetics of the catalytic cracking of light gas oils. Trudy IMIKITiGP
no.370-12 162.
Kinetics of catalytic cracking on alwninosilicates retarded by an
external diffusion at the catalyst surface. Ibld.;12-18
Relationship between the pre-exponential factor and activatiOD ener-
gy in cumene crackingon aluminosilicates. Ibid.:19-23

4?AN KOLESNIKOV, I.M.; KOLESNIKOV, G.M.
Thermodynamic calculations of the realkylation reaction of ben-
zene with diisopropyl-benzene in the gas phase. Trudy MINKHiGP
no.37:24-29 162.
Studying the kinetics of the realkylation reaction of benzene with
diisopropyl-benzenes in the presence of an aluminosilicate catalyst.
Ibid.:29-38 162.
Kinetics of the reaction of benzene realkylation with diisopropyl-
benzenes on aluminosilicate catalyst. Ibid.:39-51
Thermodynamic calculation of the dealkylation reaction of diiso-
propyl-benzenes in the gas phase. Ibid.:56-62
Kinotics of tho doalkylatioA of diisoprolVl-benzone in tho prononce
of an aluminosilicate catalyst. Ibid.:63-76
Kinetics of coking on an alwainosilicate catalyst in the dealkvl-
ation of diisopropyl-benzenas. Ibid.:77-79 (MM 17:3)

Icate c talystF7
presence of_~GZTum sU a
~_~-__PERIODICAL: Reforativnyy zhurnal. Khimiya, no. 5, 1963, 68, abstract 5B491,
(Tr. kosk, in-t. neftielchim. i r, K., yrom-sti, 1962, no. 37, 63 76)
.-TEXT.-- The kinetics of dealkylation of di-isopropylbenzenes (I) and
-the basis of
_+hermodynaimc, iiatft.' showed that isopropylbenzehe may bq _ produced as a result of
dea3kylation of 1~ as wen as a result of dismutation of I. Upon contact of
--I with Aluminum silicate catalysts, in.addition dealkylation Processes of I and
.17ne
dismutations, redistribution of H2, po~xmerizatioyAand hydrogenatiorl of propylene
take place. The optimum conditions t6~ EEF-Fy-N-g'through this prooess~ an IH-e_
basis of experimental data (if the reaction is conducted for the purpose ef
obtaining isopropylbenzene s at a temperature of 3600 C and a molecular
Speed of delivery of 3-10-~ moles of I per 1 CM3 per hour. Author's abstract.
-[Abstractor snote. Complete tra-Tislati
on]

KOLESNIKOV, I.M.; PANCI ~NKOV,~G.M.
Kinetics of the reaction of benzene alkylation with propylene in the
gas phase in the presence of a catalyst applied as a film to the in-
ert carrier. Trudy MIMIUAGP no.37:85--93 162.
Method for calculating the rates of chemical reactions in noniso-
thermal flow. Ibid.0.93--103 (MIRA 170)

P,ANv^HENKOV" G _L4.,;- BARANOV,, V. Ya.
~t~
Determining the order ofibe homogenous gas reactions in flow.
Trudy MINKRiGP no.37slO3-109 162. (MIRA 170)