SCIENTIFIC ABSTRACT PALGOVA, M. - PALGUYEV, S. F.

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• Collection: Scientific Abstracts
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• Document Creation Date: January 3, 2017
• Document Release Date: August 1, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

1. 3EFOEM9 V.: --WRKOVSKAYA, G.: PALIOVA, M. '
2. USSR (600)
4. Butter
7. Storage stability of molded sweet cream butter. Mlol. prom. 13 no. -11, 1-352.
9- Monthly List of Russian Accessions, Library of Congress, February -1953. Unclassified.

BUIN, Valentin Yakovlevich; BALAKAYEV, T.B., kand. ist. nauk,
otv. red.; PAL-GOVA., Z.N., red.
[Heavy industry of Kazakhstan in the Great Patriotic
Warl an historical Btudyl Tiazlielaia promyshlennost'
Kazakbstana v Velikoi Otechestvenno! voine; istoriche-
skii ocherk. Alma-Ata, Nauka, 1965.. 162 P.
(MIRA 18:7)

FAL'a V, N.N., otv. red.; VILESOV, Ye.N., red. 7'- UNA, V.A.,
- 21
red.; MAY-*11-Mi, K.G., red.; Clal.KAS~--,, ' A., red.;
TAIPGOVA , Z.N. red.
[Glaciological re3earch in Kazakhstan] Cillatsiologicho-
skie lusledovanlin v Kazfikhstane. Almn-Ata, Nmuka.
No.5. 1965 . IN . (!~i",A 19ti)
1. Akademiya nauk Kazak);Bkoy SIDI , Alxji-Ata , Sek tor fl, z'-
chankoy geoRrafii.

GAUJZO, Petr Grigorlyevich; DUBROVSKIY, S.M., dok-Lor IsLor.nallk,
prof., red.; FALIGOVA, Z.N., red.
(Agrarian relations in southern Kazakhstan in 1867-1914]
Agrarnye otnosheniia na IUge Kazakhatana v 1867-1914 gg.
Alm-Ata, Nauka, 1965. 3" p. (MIRA 18:4)

PALIGUNOV, 11.
New stage of news photography. Sav.foto 19 no.3:1-3 Mr '59.
(MIRA 12:4)
1. GeneralInyy direktor Tlegraftogo agentetva SSSR.
(Photography. Journalistic)

M IGUNOV
Pablic representation council attached to the department of labor
and wages. Sots.trud 7 no.1.103~-106 Ja 162. (Mr-U' 15,,4)
(Leningrad Economic regior)--Radio industry)

':~aev, Det-~rrdn---on of ~he t.-n5ler nxn--ber~ D~ c",~Dn --n~
--nion in puce --I'ed salt.
Tl~e transfer n-xibers of '-.~ie c ; tion n an-- z)n `n mc ite i
-neasu--ei w, th --,ni 'h-) :~ a ~,-)ro ~s i- -;- ~-ra7!-.. V for thie
th cat' on~ ~,ni nion we-- 1 in an ~n~~-rval )1 0.' --:."
Dr,
t~, -t the -iol-i Ii ty the ca t' on '. n
I ie
of an-on.
-i~,e U:-. l Dr-,nc~. --c.-, 1. of' U
lea i Ie are!
tran-fer na.bers 3f
7,nd 0. 1--0. %-1y;
S E;7. e:- n
J) ::-n I of ihyq-'r-,-IL

PAL t CIEEv 3 S.
25538. O-ovyed Yelenie Ahis Yel .7yevyenosa Yatiom V C'Kfstcy Raar;~2E-V--,C-n-n~-v
Qoli. Zhurnal Fi7. Khir-ii, 1949 VYP. F c 942-52
SO: Letopis' Zhurnallny~h Dtz-tey, Vcl. 34, Moskve, 1949

r 4
sad SAW in a Part Mahn lbh~ S. Katpwhcw amt S
ital, . Zh&,. Fw Nima 11, P42 M'(1149).-Thre-
Intl= "" umd: (1) Two clam test tutors were con.
urcted twat th, bottom by a Shm tube contl stlie.to-ovi
then 61W with known amts. of itsollen salt Afterl"-v
of eiec. current tbr sets, cd the salt in the test w1w. w,-r-
detd. again. 2) A radioactive 6tAolr -a. :04M t. ih,
sall it aor of the abvwe test tubes. (3) Thr r.adkortive
i*otopsr was used but there were anodic, carWic, n I
'"iddir ompartmrsts all joined by wide tutses withirit
Astorstus. ftclwissibr salt, Ra Dtbr indicator.andth.-
,in-trntles ss"o wettally of C. TIsr tran4misre n,. f 11f,
Isetwtma U) mul fW' wa, W 14) 2 and OW A Cl () M is ~#
TIw agrormesit bnown 0 ~ ant) i:D %how* ihr A-arm-tnt-
,-I arrangement (1). and the agreement betwtrn ~:?~ mi-l
,3: shows that ekctro6zmAxis throstab *61testas itirm
hearse was walwhir. J. J. flikertriAn

ACCESSION NR: AT4008735 S/2631/63/000/004/0003/0090
AUTHOR: Neuymin, A. D.; Pal'guyev, S. F.;Strekalovskiy, V. N.; Burov, G. V.
TITLE: Investigation of the structural components and electrical conductivity and R8
nature in the systems Zr02-CaO-NiO and Zr02-CaO-Fe2O3
SOURCE: AN SSSR. Ural'skiy filial. Institut elcktrokhimii, Trudy*, no. 4, 1963.
Elektrokhimiya rasplavlenny*kh solevy0kh i tverdy*kh elektrolitov, 83-90
TOPIC TAGS: refractory oxide, electric ceramic, zirconium dioxide, calcium oxide,
nickel oxides, NiO, iron oxides, Fe sub 2 0 sub 3, ternary oxide mixture, ZrO sub
2-CaO-NiO system, ZrO sub 2-CaO-Fe sub 20 sub 3 system, metal oxide system, electro-
lytic ceU, solid electrolyte
ABSTRACT: Maintaining the relation Zr20:CaO = 85:15, the structure and electrical con-
ductivity have been studied in a series of oxide mixtures of the above systems. X-ray
examinations combined with phase chemical analysis were applied in the study of the
structure and a "Ural I" computer was used to calculate the interplane disLances and
lattice parameters. Thle conductivity was measured with an alternating current bridge at
a frequency of 3000 cps. Its nature was studied by the emf method. The procedures are
given in detail in Trudy* Instituta Elektrokhimii UFAN SSSR, no. 1, 1960, 111; no 2, 1961;
Card 1/2

ACCESSION NR: AT4008735
no. 3, 19G2, 133 and in DAN SSSR, 1960, 13-1, 1138. It was found ffiat NiO is only siigntly
soluble in mixtures of Zi-0,2-CaO -a-nd so;id solutions form when FeZO:j is add(~(J' lj-r, ions
place themselves xirtly in the intersections, m.d partiv in the interspaces of ',~c cul,,c
lattice of a solid solution. The COJAUC~1\'ItY Of 1110 111iXtM-0 d(T1-Va,';t?S 111011010111)LIS,V '11)(1
-ely ionir imluro as Uie Ni content increases UP to :'o 11 / r11.
remains practically of a pui )0I ,
in a wide teiriperature rwige. Fc20:1-addaions up to 6 mol 'Yo cause no noticv.6)le decrease,
in conductivity a-nd do not affect its nat-ure. Greater Ie203-additions enhance the electron
component of conductivity. Orig. art. has: 5 fij~ures, 2 tables and 4 formulas.
ASSOCIATION: Institut elektrokhimii, Ural'ski), filial AN SSSR (Electrochemical Inst-itute,
Ura-Is Branch, AN SSSR)
SU13MITTED: 00 DATE ACQ: 25Jan64 ENC L: 00
SUB CODE: GC,SS NO REF SOV: 011 OTHER: 013
Cord 2/2

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'I; YE7 ,
Nit-,-ry"c ~, , .-,. It, V-,-,3~:- 4A . L, .,) , cl,,CI!l N!,lY(-J , Y~-, ~ M, ; PAL' G, S,Fz
r,: ~ . ,: - -9-, -'~ - Sr-- .
--I~ ~, -
k. *,: ok nim 7jFAN S17.3'~ TI- ~ 41111 -11 -) ' ~;3 .
Truly 1 ns o,- le I - '!ERA Yytb'.

PALIGMV. S.F.; SHIRNOV, N.V.; KARPACEIRV. S.V.
Dependence of the quality of cathodic nickel deposits on the presence
of Impurities in the electrolyte. Zhur.Priklad.1him. 26, 50-4 '153-
(CA 47 no.14:6794 153) (KLRA 6:2)
1. Chen.-Met.lnst., Ural Branch Acad. Sci. U.S.S.R., Sverdlovsk.

FALICATYIET, S. F. Y. -1. - KARPACHEV, S. Vv-
Nickel
Dependence of the quality of cathodic nickel precipitates on the
pressure of admixtures in the electrolyte. Zhur. prikl. khim.
26 no. 1. 1953
9. 1091thIF -List At itagelan Accessions. Library of Compass, May 1953, Unclassified.

do baths.
U QM"k 9P.1-1 rnalad.
Tr i W, 1. - &AM V I , Y~' U-. - (. A. 4 - ,
I 04i.-Properties
of c-afthmode deposits Of I obtained in CI baths strongly de-
pend on c.d.; 0.005 amp./sq. cm. gives a fairly dense cryst.
lbovase In cd. inzreases the at-t. of dendrite5
n
Optimum c.d. is at 0.015 amp./sq cm. with a
thlelmmoF0.11rarn. Preliminary bubbling of NO shows-
hdlutoce oil the character of cathode deposits of Ni only in
the cam of CI and phwhate baths, but not in F baths.
This indicates that the characterif the cathode deposit is
io&mmced, apart from the for=Rtlqn ol oxide films on the
surface of the mete], by the nature of the anion. The spe-
cific influenceat P- on the properties of cathode deposits of NI
on decftly* from molten baths can be explained by the
poor wetting of meftb by m4ten fluorides. V. N. B.

SMIRNOV,M.V.; PAL'GIUM S.F.; IVAIJOVL;rIY,L.Ye.
A chlorine-copted graphite electrode for compnring fused chloride
data. Zhur.fiz.kb-im.29 no.5:772-777 MY'55- (KLRA 8:12)
1. Ural'Bkiy filial Akademii nank SSSR., LaboratoriyR elektro-
khimii, Sverdlovsk
(Electrodes) (Chlorides)

137-1958-21-1646
Translation from: Referativnyy zhurnai, MetallurgiNa, lq~,S, p t3 tUSSR!
AUTHORS: Smirnov, M ~ V., Pal'guyev, S - F -, Volchenkova, Z . S
TITLE: The State of the Oxygen in Salt Melts Containing Titanium (0
sostoyanii kisloroda v solevykh rasplavakh soderzhashchikh t,'tan)
PERIODICAL: Izv. Vost. fil. AN SSSR, 1957, Nr 3, pp 94-101
ABSTRACT. On the basis of experimental data on the electrolysis of
fluoride/c hlo ride melts containing Ti4 + it was shown that the effect
of the atmospheric 02 within them and the suspended insoluble
dioxidi led to the formation of oxy-cations of the TiO2 I and
T'203 + type, which when discharged at the cathode yield well
formed crystalline precipitates of the lowest Ti oxides. These
oxides were precipitated with potentials 1.3 - 1 .11 volts more posi-
tive than the potential used to segregate metallic Ti, and Z.2 - -1 3
volts more positive than the potential used to segregate an alkali
metal. Tests were made to clarify the nature of the processes
which take place at the cathode and at a carbon anode when electro-
lysis occurs with small current densities. It was found that t))e
Card I /Z reduction of Ti4 + to the lowes, valences at the cathode was

13 19 ~8- 2- 2646
The State of the Oxygen in Salt Melts Containing Titanium
accompanied bV the discharge of oxy-cations with the formation of
precipitates of'the lowe'st Ti oxides At the anode, simultaneousiv
with the oxidation of the lowest-valence Ti, an elect rochemical
reaction took place with the oxy-cations adsorbed on the carbon
TiO 2+ + I /Z C - 2 e z Ti 4+ (melt) + I /ZCO 2 Chlorination re-
actions involving the particles of TiOz I Ti,)03 and TiO suspended
in the melt were also possible. The anode potential during these
processes was r,,,0.4 volts more negative than the potential of a
chlorine electrode.
N.P.
1. Fluoride wlts-Blectrolysis 2. Chloride melts-Electrolysis
2. 0~7gen_Determination
Card 2/2

I I i . ..I

Z7 (Aj - - F,6'7
C(' SOV/81-59-13-450-115
(-A
Translation from: Referativnyy zhurnal. Kh1miya, 19~9, N,- 13, r) 44
AUTHORS: Smirnov, M.V.. Ivanovskiy, L,Ye., Fal'Kuyev. S- .,-Volchenko. Z-
Yusl~jin~. D---.
TITLE: The emf-Method for Studying the Therrpodypamics of 3ome Hea~tions al.
High Temperaturesl~
PERIODICAL: Tr. in-ta khimii. Ural'skly fillal AS USSR, 1958, Nr 2, pp 143 - 151
ABSTRACT: In the electrolysis of fused chloride baths C02 is separated on the
anodes prepared from an intimate mixture of oxides and carbon and the
ions of the corresponding metals pass into the electrolyte, The oxide-
carbon electrodes of thorium, calcium, beryllium, etc. in equilibrium
are reversible In relation to their Ions being in the electrolyte.
This permits to utilize them by the emf-method for elucidating the
thermodynamics of reactions, In which oxides and carbon take part at
high temperatures. The equilibrium potentials of the electrodes are
determined by the activity of the Ions of the corresponding metals in
the electrolyte and by the CO pressure over them according to the
Card 112 electrode reaction M 20n + n/2~ - 2-ne -,."~'2Mn 4 (Pusion) + n/2CC2, F

669 7 '~
sov/81-59-13-4503r,
The emf-Method for Studying the Thermodynamics of Some Reactions at High Temperaturel-~.
const + (RT/n) FinaMn + (RT/4F) ln'PC02 . They do not depend on the molar ratio of CC
and carbon. By measuring emf the changes can be found in the isobaric potential L
in the entalpy n H and entropy n S of the corresponding reactions of chlorination
M20n + n/2C + nC12 = 2MCln (smelt) + n/2CO2. Oxide-carbon electrodes in combination
with metal electrodes made it possible to study the thermodynamics of the Interact.lor.
of the fused chlorides of thorium, beryllium and calcium with the chlorides of the
alkali metals. For determining the decomposition tension of the fused chlorides of
higher valencies a method has been developed permitting to measure the value of the
decomposition tension Of PlC12 and ThC14 The change in the thermodynamic parametp-
has been calculated for the reaction Th (solid) 4 2C12 (gas) = ThC14 (liquid), & Z
= 2.772 - 5.61-10-4 T. Based on the emf of the cell Th MC1211KC1, ThCI 1 C12 C.
it has been found for the decomposition tension of ThC12; E = 3~27 - IO.A.1 0 T,
L Z = 150,900 + 49.7T cal/mole. For the reaction ThCl4 (liquid) + Th (solid)
- 2ThC12 (liquid), L Z = - 2'4,000 ;- 23.8T cal/mole ThC'2. The thermodynamlos of
formation of alloys of thorium with zinc has been studied. For the reaction of re-
ducing Th02 by carbon to metal n Z = 20,000 - 7"I.5T cal/mole.
Card 2/2 A. Zolotarevskly

67625
(.0
Translation from-. Referativnyy zhurnal, Khi-miy-n, '959, Nr- 14, p 31
AUTHOF3; F4 F. t- Vol chenkov a, Z,-'
TITLE: Tne Problem of a Solid Electrolyte for F)jel Elements
PERIODICAL. T-. In-ta kh1mii, Ural'skiy fil, AS US,)F., 1958, N,-- P, pp
ABSTRAC'11'~ A method of preparation has been dez-cribed and results art, ct-.e,J of
measurements of the electric conductivity of solid electroytes for
elements; a') O.K. Davtyanls e2ec-trolyi.e -and Its individual --Dmp'~Irerjt-~
(Na2C03, calcined monazite): b! A aeries of mxtures of oxides .,n
base of zircorium dioxide: 60 moia-r % Zr02 + 40 m~,-ar 7t
molax % ZrO 2 + 33.3 molar % La203i 3ZrO2 - 2~DeOp + 10 weigh,
measurements of electric conductivity were carried out by T~ne
bridge method at a frequency of 1,000 cycles. The c-Ircu!t permItAp,i
determi-nation of the resistance with an accuracy of I - !G-X, dept.-il-ti,
on the value of the measured resistance, The co,~dj,:tivlty wa7,
in a range of temperature from room temperature to 1,00,07.
Card 112 erlerwies were ca-1--ulated fron, 9~e curve of ,,he

67625
The Problem of a Solid Electrolyte for F~ei Elements SOV/81-10-14-50,212
1/T (T is the absolute temperature) for sections with different slopes. 'In - ',I~ naEiz
of the obtained data assumptions are made concerning the character of T-~e e1e-tzij
ductivity of oxide systems. There are 30 references, LK I-'
T. Lukcv,-zell
Card 2/2

SOV/58-59-8- 182(j7
Translated from: Referativnyy Zhurnal Fizika, 1959, Nr 8, p 168 (USSR',
AUTHORSt Volchenkova, Z.S., Pal'guyev, S.F.
TITLE: The Temperature Dependence of the Electrical Conductivity of Nickel
and Chromium Oxides
PERIODICAL: Tr. In-ta khlmli. Ural'skiy fil.-AN SSSR, 1958, Nr 2, pp
ABSTRACT: The temperature denpendence of the electrical conductivity (~5 '/ of
polycrystallino namples of NtU and Cr 0 3' sintered at 1.5500C, waE
studied in the interval of 150 to 90o9c. 6 WaB monsured by IT101VI'A )I
the contact method with the aid of an alternating current bridge at a
frequency of I kc. Contact resistances did not affect the temperature
dependence of 6 . It was established that 15 for NiO, unlike Cr2u3, In-
creases sharply with an increase in the quantity of adsorbed oxygen,
while the activation energy of the conductivity of Niu, measured on
rectilinear sections, decreases. In the case of Cr2o the activation
energy of45 falls with an increase in temperature. ~~e absence of ionic
conductivity under the conditions of the experiment was established by
means of a chemical analysis of the areas near the electrodes.
Card 1/1 E. Yenikeyev

T-) ', '(' ~ e ~ / - )
1114 2 ' - i
SmIMOT& Niv&j PALIGUMj S;Y;; KRkSNDV,' Yu;N.
The behavior of carbon dioxide calcium electrodeB during alectrol,7siq
of fused chlorides. Zhur. prikl. khim~ 31 no,-2:226-233 7 158.
(Ilectrodes, Carbon) (Mectrolysis) (Chlorides) (MM 110)

5(2)
ALITHORS t Pallgayev, S. F.,Aiyamovskiy, S. I,,
TITLE: Investiestion k,4 tho llinoc Couiponenta
PERIODICAL: Zhurnal ne,~rgar.ichEskoy khimii, 1959,
pp 2571 - 2576 (JSSR)
05878
5 ~'V
Volchenkova, Z S
Df the System, Ce~_~ 7 r-~
Vol 4, Nr 11,
ABSTRACT: This is a report on the structure and the ceramic prc,-,,:r*.-fs
of the system Ce02_ 7r0 The samples were prepared frcm -.L.x-
tures of pure oxide,,. ~h'e spectroscopically determined c_:f-!.t
of impurities in th,, initial substances is given in tabie
The powders were pressed, a binding agent (natural rub~,er
in ben2ene) being used for samples with more than 80-z -IrC,, T.-.a
samples were theri 31ntered and X-ray investigated wit*n copp'_r
K -radiation (powder camera of type RKD and invertir.., camera
0? type KROS)~ Besides, the density, color and linear snrink-in~
(Fig 2) in z;interin.- were determined. Table 2 gives th~ cr.-e-
mical cowposition. the phase composition, the latt4ce
and the color of the samples. A solid solution wit,. 2u,),t:
lattice develops between 0 and 50 mold-' Zr02, a monoc'lri
phase exists between 0. and 10 M01% CeO a tetragonal p-ase
Card 1, 2 at 70 mold Zr02, Fig-are 1 shows that t~e' Is t t i c er i c d

05878
Investigation of the Phase cf the System S:-'V
CeO 2- ZrO.
linearly with %-=.s -tion and exhJbits stat' s~
aistribu+t~c 'at-.ce aefects which are probably Sit,ater,
the lattice 4+ 2-
. po,,nls by the Ce - and 0 1.1-,,,S j,
samples w:th 7,0 '-rO? have the greatest harcro,_zs; n-ar
shrinkan,s -3~xh_b_s aminii:.um at 20-25 mol% ZrO ; -:he
M-_ I, 7r-
with 10-2C ar- most intensely colored A -5
interact:_;n '~.e 1--wc componertc secms t~, *aKe p'a';'
this ra.,.6e 'C and 10 mol" ZrC2) This
7o
cannot te 1-; X-ray investi-ation. 4t s:-;'.c
0
e Ve r , C ee :L~_ .n the t:lectr4c propert4cs. T.,.--- are
2 fig_ire3 , - * ~i:~ ~ re*erences.
ASS'C.CIATIGN: iral 'skid- '1-a~ AN S1`Sh,1n.9tt-A elektrokh-.u~l: r
~)f the AE ~SEii. ~,1- ~.n,i:;.,cal Insti!.,ite)
SUBMITTEL: J LAr, e 5 .5
Card 2,12

5(4)
AUTHOR: Pallri.,yev. 3. F.
TITLE: On the Nature -f t~-.,- C,~nluctj vit,,,- cf 5ol il Sc,
PERIODICAL: Zhurnal fi:~ neskoy khlmii, 1.1''. Vol '?3, Nr 0
7799R)
ABSTRACT: Althcu,-h sodium carbonate I) is bead, silon- rr in
as a flux. its electroconductivity (E"~ has so far r~-,t teed.
examined. In t~~e present ca.-3.~ the transfer n,.,:.-er :.f s
ions (TNS) in solid W was Measurilf! at 40r'-CrJ0'C ~7-c-rd~r-
o t I. e mo I hod do acribu I in refer or, ce 7o ,
gaseous electrolysis ;products of t- C
currerW was leterr-ined at various te::],eratures r1r. *.~ie
The measurement res,.,.Its ',T;~!~le 1 ghow that the - I'S --~n;7eS
,C,r,1 i.c, t
froz C,qO '40OCC) to 1.00 (6oO_6 1
,
C,
is a cati3r. conductor at tezi~eraturea cf 6CC L~n_,
invest4ation resultq (Table 2) rei,,-,-rdin~, t!,e
y2eld sl.!:vv t%at -.he y4eld in
O,F. /T 1, -4 to Faraday's lai at C n
c3rres:0..-
sincs the yield falls f)O1/16') as the %e.-- erat 1 w
e
(400 C). '_'hia aiil,-~,ests thizi at te-Leratures -
Card 1,,'2 frnct,cn cl" clectror, con,'L~tivity r,~ses rc)!,a~_Y

On the 'I attire of t,,e C --n I v i T,.,- of' S -)l - I 'c~ I i,--l!n Ca:`-
r i --e - c,;-ve of t-.o temi a:-al r e
f
fl
4s rl-3e :n *:it: activaric-r, ener-v --f
ev
C".BrH" t,,,:- cf the EC r,,,Lre sire 2 t;j~'l
o r wi i -.% .Ize .~,()v e %
ASSOCIATION; "ra 1sk iy f i 1 i :~ Iiii e--, i nai! k SSSR
ve s k
,rn Br~,n~-.-i of I ~,e A.;a I c - ij f Se r 7 e J
Electr~;2he-iistrv ')ver,31ovsk
7, 1
Carl 2/2

681-2
_57 0 0 9071/20- `2)-6, -
AUTHORS: 1~allguyev, S. F., Karpachevj S. V., Yushina, L D-.
TITLE; An Electrochemical Chain With a Solid Electral.,-te
PERIODICAL: Doklady Akademii nauk SSSR, Vol 1? Mr 1~`
(USSR)
ABSTRACT: The authors investigated the temperature Je~enierce of tne --'-ec-
tromotive force of the chain Ag//AgEr solillf Br,C in the re~Ti-n
25-4210. The electrochemical cell consisted of ~r~s-d ~-:-.VE;r
bromide, to the one end of whicii a silver wire an! tc t~e `-'er
a carbon rod is attached. The entire cell was in a '--rozire
atmosphere. Figure 1 gives the measured emf of the cell-in le-
pendence on temperature. The values between 113 ani 421- lie
on a straight line, for which an em7irical equation 4-E se'
0 op -
Extrapolation to the melting point 4754 f the AgFr ~.ives un
emf of 0.0033 v, which is in good agreement wit'.. ti.e
given in reference 5 for liquid AFzr V), cc:-.f-r:~3
the correctness of measurements,and points out that
AgBr electric conductivity near nel,,ing -.~,in* i-.aq
acter. The occurrence of electron conductivi',y in !a
Card 112 atmosphere is proven by the fact that the ion transfor

68172
An Electrochemical Chain With a Solid Electrolyte C, V/2:1- - 12
+ 0
for Ag at 20 was between C.V and '.0', un~! at
0.06 and 0.11, whereas that for Tir - wns zer-. D,. *ne
of the thermodynamics of irreversibl6 proces.7es tt.e
tion gradient of Br dissolved in solid Af-!Ir ani,
gradient of the holes was calcilated and ti.e transfer
number of the holes was found to be zero fcr the
0~ - I f n I e,-. -, : - --- n
interval of from 100 to 434 The authors thank .1
A. N. Frumkin for the eva2uation of their work, -here :i;e
figure and 8 references, 1 of which is Soviet.
ASSOCIATION: Institut elektrokhimii Ural'skogo filiala .',kalem-.i
(Institute of Elect roche mis try )f the T.Tral lrircli ~f
Academy of Sciences, USSR)
PRESENTED: July 16, 1959, by A. N. Frumkin, Academie~ian
S7BMITTED: July 15, 1959
e
Card 0

S/65 1/60/ )3U-/'C)01
B140/ B1 10
3miri,ov, -. V. , Palguyev, F.
TITLE: I-enavior oi anodes of an intimate mixture of titanium dioxide
I
and carl~o;. ;uri:.,, e"tjctrol,-'sis of salt melts
SOURC Elektrokhimiya rasplavlennykl, solevykh i tverdykh elektrolitov,
no. 1, 196C, 29-33
TEEXT: Experiments 'TiG- electrode-- were conducted to examine
c
their suit:~bilit,, for deter::!'J.-.In6 t.-.e solubility of "2il4icnloride- and
fluoride-criloride melts. Electrolysis was performed in a closed
element at 10-4 _ 1 a/cm 2. . i'he anolyte was separated by diaphragrr. fro:T,
the catholyte. Electrolysis of ttic. pure equimolar NaCl - KCI melt was
conducted at 700o', that of the fluoride-cnloride melt at 7"0 0C (201,, by
..eight of NaP). 2-3 -,r after immersing the electrodes in the electrolyte,
the potential of tne TiO,,, electrode attained a constant value. At
Card 1/ 1:4

Behavior of anodem; of an i..tirr-te
low current density ~1-1o- 4 _ 1-10- 3 a/ ;,cm2 ), the potential changes li.--,
but it rises quickly at higher current densities. The redox potential of
4+/1 ~~ I -
/Ii~ j -0 - ..encp, i is concludej
Ti c:. c, --.I V.
Ti ,asse-z, n. r~ o I I
reaction ta?.;--. Dice. -.i. ~1, + ~u '~Ti = melt). The '7i lon-
enter trie me Ir I J ke 1 ow Ti oxidc-- ;,nodic dissolution depends or.
diffusion froi.-. tia.- el ecfro.yte tr.' t no Ti 0- - C electrode. The anode
c u r r e ni, ~: e r. -, i t th~ di~,cnarvud chlori.,:e ior:s
react wit.,, P;,rticl,.-~; fall to
2
1 cm of elk-ctrode r effectivt- croso sect~o.,; of' th- oxile
layer wa.,; The :. i ~,, r, 1. ol , r i z
obqervL-,j 0 ... ... r cm jr, thk- surface of oxide
p,rticlt.-~- In cort-~ct iv-:.. '.,.e -melz ~,nd ~r. ti-.o ctricentr~itior. of Ti ions
Card 214

,ehavior of anodes of a.,. intimate . . . 4Cj/'B 11 G
on the anode layer of t,-,e eiectrDlyte. -'..e Ti'-, - .' electrole w~-s: --ce:
for dissolving Ti-'I i!; trie salt -neit under conditions wriere only
4 2
passes into the ~_Ielt: -node ~,oterti;:! --j.4 v, -'Ja,:t~U-5 a/Ic,- In y
is formed at tni.- cur~(-nt jen-,,ity. t~,.e ;~:l is consumed for c,-lorina-
tion of' the 'i'iu, fter s,,t~iratior, of the melt, the ratio V-/
ici Li t t -11, e" t., V ~' U zlectroly,.~is was c. ~ndu(- (,A ;it
41
- u.5 a,,c;i.' until tio- f'ormhtion of Ti,,l'4 vapors. Electrolyte
were taker, :,nd exaiziined f:)r their Ti content. The ;olubility of' Ticl 4
7U()ot: in t he equi mol :,r mel t o i Eacl and KC) was found to be ~-5~/. by
weig~it of Ti--l he part ial pressure w,,.,; 57() mm Hg. The rolubi-' ity of'
TiCl 4 rise-, in the of' NaF viit,% risint, fluorin.- ion conc-(-,r,tr.-.i,,,
in the melt. Witi, NaF con'..ent, tii, -,~oluLility of TiC1 4 was 7,. by
we d ..geasur,--nuriL~: by al IKuyev and A. D. Neuymin were
mentioned. There are 1 f iEurv, 1 t:,'rle, and 1) references: I., .3ovie! :iiA
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t2 v 41 o ~- o :rc,:. n : n t i-. a , tf 14'), E 1 1
1 non-Soviet.
I I 1~ -;,I ' :ikoj.,o I'i I iila ~~k em 1 1
i Vi lid
ln,,it i tu! e of' rocii-mlill ry ()F I
c): -clenc, 'I
Cz,rd 4/4

KARPACHEV, S.V.; PALIGLM-V, S.F.
Electromotive forces of electrochemical cells sc-LA
electrolytes. Trudy Inst.elektrokhi-n.Ux-AV SSSR no.1:79-8c
160. (AURA 15:2)
(Electromotive force)
(Electrolytes)

KARPACHEV, S.V.; PALIGUYEV, S.F.
Functioning of a primary cell vith a solid electrolyte
baving both ionic and electron conductivity. Trudy Inst.
elektrokhim.UFAN SSSR no.1:101-103 16o. WIRA 15:2)
(Electric condtwtivity)

:1941 ~
SIOV11/61/000/31" 3-
AUTHORS Karpachev, S. V , Pal'Kuyev, S F
TITLE Electromotive forces of electrochemical _-irzuits
electrolytes 11 Coexistence of n-type and P-type
conductivity in the electrolyte
PERIODICAL Referativnyy zhurnal, Khimiya, no. 1-7. 1961, 67, abstrazzi
176495 (Tr In-ta elektrokhimli Urallskiy fil AN SSSR,
no 1, 1,960, )1-96)
TEXT An exor, : s ieriv~-j *,D:- tne emf of a galvanic cell
A/A X /X C*,A kA - metal of valency z X- metallold of vaien,-y z-,.
z2 zi
salt or oxide) taking account of icn_c,
-carbon electrode, A Z2 , Xz 1 -
n-type, and p-type conductivity. It is shown that if n-type and T)-~ype
id in 'ne
conductivity are due to dissolution of the metal or the metallo~'
solid electrolyte the emf of the circuits under consideration may, urier
certain conditions,be approximately the same_as its thermodynamic_ valup
[Abstracter,s note Complete translation,!
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29)JJ4
S/0 a 1/6 1/ 1()00/017 " 0 ' 46
2130 (11V2-11190"/i/ k 2-) B 102,1B 138
AUTHORS Karpacnev, S V., Pal'guyev, S. F.
T IT LE Electromitive forces of' circuits with solid e.e-,tr,1AYte&
possessing electron besides ion cond-Activity
PERIODICAL Referativnyy zhurnal. Khimiya, no. 17, 1961, 0-68, acstra-t
17b496 (Tr In-ta elektrokhimii, Urallskiy fil. AN SSSR.
no. 1, 1960, 97-100)
TEXT: The effect of n-type conductivity on emf is considered for the
electrochemical circuit Br,C/AgBr(solid)/Ag as an exaTnDle, It is sh3wn
that E =E0(1-t), where E is the total emf, E 0 the emf without n-type
conductivity, and t the number of electron transitions into the
The efficiency of this kind of cell is described by the ratio
(Ag)
WOO, if' the efficiency of a cell without n-type
conductivity is taken as 100 % When current is obtained from !he e'emenz
the Br distribution along the electrolyte changes, and the efficiency
increases. LAbstracter's note Complete translation ,y
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PALIGMV_,_S.F.; KARPACHEV, S.V.; YUSHINA, L.D.
Problem of meaeuring the decomposition voltage of solid
electrolyte solutions. Trudy Inst.elektrokhim.UFAN SSSR
no.1:105-110 160. (MIa 15:2)
(Solutions, Solid)
(Electromotive force)

31674
S/631/60/000/301/01?/01,~.
24.-1700 B110/B102
AUTHORS: Pal1guyev, S. F., Neuymin, A. D.
TITLE: Study of the type of conluctivity of solid oxides by the emf
method
SOURCE: Elektrokhimiya rasplavlennykh solevykh i tverdykh ele~tro3atov,
no. 1, 1960, ill - 118
TEXT: The present paper deals with a new method for examining the
conductivity of solid oxides and for determining the type of conductivity
of solid oxides and oxide systems. Me Me~(O Isolid electrolytelMell
0 , Pt cells (designed as I a
Me''(0) and (Pt), 0 Isolid electrolyte;12 nd
P
2
11) can be used to estimate the mean transference numbers of electrons ~'nd
holes, fe and f 0, from: E - 1 1 - (Te + f 0)]E . The emf of these cells
are determined from the oxygen pressure at the electrodes.
E0 . (RT/4F)ln(P 2/P1) is valid, where P , and P2 are the oxygen pressures
at the left and right sides of the cell. Since the solid electrolyte
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31674
S 15 1 /60/'D I, ") /Do 1./',- 1 T
Study of the type of cond~ictivity- B11--!-;31U?
in 11 is in contact with oxyren, a comparison bettieen '-~ic
11 gives the dependence of the n-type and p-type conductivitieL.-
electrolyte on the ourtial ox.-;p,-n nregnure in the gaseo,ir phase. x I -
0
calcined at 1200 C %%orp rro,in I wi th t,-,!,iP!)p nr alcnhol
to tablets (2 - 8 mm t'- c k, . ?0 mm i r. d i:~:: ~ t ( rat 00 ir. --t r
sintered at 1") 0 a nnTI3 -1 1 t M- t C. r
,5 C . The authors u!le i
(accuracy mv Y6 1 t- a n M - ct 1/A 9 1A ~ pit a n -),n eP
instruT.-ent 7he resistirce fn- i t i n F -.% (--u.
r. e r -7.,) o, r on o
was on ,,ip elect ru 1 y' e c c-:n' v--i- P.
(accuracy: 0.01 - 0,0? mv a"I t r"
(2 : I i e f t c I or t rA e 1 , C:-I r- - t
calculate.1 tne tht-rmod,-,-n:--,ic k- m f 1 .4 m F. 0., F~-
and Cu 0, 0.
?
electrnl,
%as inado ; r, an r t !,-,i A- i-
electrol.vt-,;. th~- auth-r- -:-,J ro-
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11674
S16511(,0160010-~1,!~I--, ",,I/
:.t.idy of the t,v-.)f, of cnrk-+jt~ I v i ty Bi 10/B102
-h - -
0 1~ FO C-0, - ZrO CaO with ionic
'ov. !'or Tolid s!olutions of
rontainirip 4-1-! malp- ar.,.! ,.ont :ininr R" mole% ThO, + 15 mole
CaO. The emf' mpasur-nentq were wpl] renroducible. The emf remaine.
c.,)nstant !'-)r sever-!I ;inl soon -decreased -rath time and
,.,.nen thF- difi'orenro rc!-Aeon f,!rf' ;inl its thermodynamical value was p r e, i
'"he chan,- ir: mf c,-.irl h- i,iv I () (1) -iiffliqion of oxides into the
t e (- i r )d f,!; a bvenr- , f a c,)m-;Iet(, equilibrium at the boundary betmeen
leotrnle -Ind ,I-tr,i1.vt(, in the earn of ri-tyne conductivity. 85 mo I e-,/,-
!7-1 ), rrcrt n-t
7. Yoe conductor, since CeO 2
m.,,~ E, ra t u re s ;irk 11 1!7 ei !-ily reduced to C,-,
1 rl I the P!IS chlimb. 1,1:o lectrodo.9 senarated to al r:
t n Lr;i r r F! ) f 11 r- q t ,rr~psure~!. The electrolytr-
;-rour;d in !!!t I IvI.1,1 tho i-lpct rode space. Finv-din~)vrr,(,
t an n pa 1 pd a t 1 :-:1:- ,Ivety-ode. A C,)MT)arison of the
that W) molei, ::r0;, + 11~ molc
resultp of' measurprrent (1' 1 -1 nd
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31()74
-m!, 1~11(,0,10D'~1001101?1014
r)f the t.,Ypr, of B I u?
0 wu a u r c r,.c o n i Tho con-i,)ctivitv was independent oil' tn,
irt -.%as a p-ty-ie con]
the n- t v-)(, ; I (,,, I r-) 1
I)r(
-I ICKfIr, r, . - 1 vi I -,ritur, -:n,l an !n( rr,,I
T) U- t v1 tv Im r~:z I at
f), --ri-r-sure is c;iiisel t,.%,
ir~i rc f renc
i !,h -a n ru a re u i c i. ri
Pctroc~iem. Sic

"670~
6 7 1 A6 00/00 1 // 0 1/rj 14
0
74. 7700 B1 10/Blu2
AUTHORS: Volchenkova, Z. S., Pallf-uyev, S. F.
TITLE: Electrical conluctivity of solid oxide systems. 11. The
system ZrO ? - CaO. Electrical conductivity and transfer
number
SOURCE: Elektrokhimiya rasplavlennykh solevykh i tverdykh elektrolitov,
no. 1, 1960, 119 - 126
TEXT: The authors studied the temperature dependences of the conductivities
of 100% ZrO 2 - 100%6 CaO samples between 300 and 1000 0C, the transfer
numbers, the structural properties of sintered samples, and their ceramic
properties. Pure ZrO 2 and CaO or CaCO 3 were kept at 1200 0 C for 2 hrs.
For samples with< 40 CaO the authorr3 used CaO, for those with>40%
CaO, they used CaCO Y The mixture (?00 mesh grain size) was pressed to
2
1.0-1.0-0 62 - 0.4 cm tablets at -4000 k9/cM , and sintered for 1 hr at
1500 1 20 C. Linear shrinkage during sintering, properties, and color
were determined. G. V. Burov made X-ray structural analysis of the
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.8/651/60?aolz~001 /015/014
Electrical conductivity of solid ... 13110/BlU2
specimens with Cu Ka radiation. At 15000C, solid solutions and fluorite-
type crystal lattices formed with 10 mole% CaO. The primary solid solution
(10.0 - 40.0 moles- CaO) yields good ceramics of high density, hardness,
and stability in air. Pree CaO contained in samples with 80.0 - 90.0 mole%
CaO reacted with atmospheric humidity. The porosity and sample volume of
zirconate formed according to ZrO2 + CaO --*CaZrO3increases while its
linear shrinkage decreases. The temperature dependences of conductivities
measured with a-c bridges followed the equation x = A exp (-4E/2kT) where
x is the conductivity, A andA E are constants. At 750 - 800 C, the curve
showed a break (eXCeDt for the range where solid solutions are formed).
X-ray patterns of samples with>50 mole~o CaD showed CaO lines. % was
increased by the formation of Ca(0102 and CaO3 and decreased by their
decomposition (700 - 8000C). The rapid increase of x with the CaO content
in the range of formation of solid solutions is probably due to an increase
in oxygen vacancies in the lattice. With increased CaO content, the defects
are no longer distributed statistically but systematically. The mobility
of oxygen ions is thus reduced. With 15 mole% CaO, the conductivity
maximum was observed at the minimum conductivity activation energy6 E. The
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316 5
3/631 60~~00/001/013/014
Electrical conductivity of solid ... BlIO/B102
this case, the transfer of ions is expected to decrease with the time of
electrolysis. This fact and the voltage drop in the cell after the
beginning of eleutrolysis supported the foregoing assumption. No changes
were observed with the anolyte. Since t + t - I and t - t A-16' The
k a k "' 0' a
solid s8lutions of ZrO 2 and CaO, which are almost perfect anion conductors
at 1000 C, can be used as electrolytes for heating elements at high
temperatures. There are 3 figures, 2 tables, and 12 references: 7 Soviet
and 5 non-Soviet. The two references to English-languag6 publications
read as follows: K. Kuikkola, C. Wagner, J. Electrochem. Soc., 104, 379,
1957; P. Duwez, F. Odell, F. 11. Brown. J. Amer. Cer. Soc., a, 107, 1952.
Table 2. Transfer numbers in the system ZrO 2 CaO at 10000 C.
Legend: (1) composition, (2) total.
0,9ZrO, .0, Icao 0,001-0." 0,02-0.06
0,8Zr0,-0,2CaO 0'M1-0,01 0,03-0.04 Table 2
0,6ZrO,-0,4Cn0 0,001-0,004 0, 0", 14
Card 4/4

21~_ 710 L)
6 6
S/631/6 000 001101411014
B110/B102
AUTHOVS: Volchenkova, Z. S., Pal'Kuyev, S. F.
TITLE: Electrical conductivity of solid oxides. III. The system
ThO 2 - CaO
SOURCE: Elektrokhimiya rasplavlennykh solevykh i tverdykh elektrolitav.
no. 1, 1960, 127 - 150
TEXT: The present paper deals with the temperature dependence of electrical
conductivity of the system ThO 2 - CaO. Pure ThO 2 and CaO were ground in
2
an agate mortar and pressed to 1.0-1.0-0.2-0.4cm tablets at- 4000 kg/cm
The tablets were sintered at 1550 t 200C for 1 hr. The linear shrinkage,
ceramic properties, and color were determined. The measuring method was
described by the authors (Ref. 1: Trudy In-ta khimii UFAN SSSR, vyp. 2,
183 g58). Pt electrodes were fixed to the golished tablet faces at
,,,'1;.0' C. Measurements were made at every 10 between 500 and 1100 0C.
The structure was studied by X-ray analysis. The conductivity increases
with temperature according to x = A exp (-al2kT). In the coordinates
log X = f(l'/T), the temperature is linearly dependent on the electrical
Card 1/3

31676
S/631/6()/000/001/014/014
Electrical conductivity of solid ... B110/'B102
conductivity with a break at 700 - 8000C. Small additions of CaO to ThO 2
cause a sharp in 8rease in conductivity (5% CaO incregses it by more than
10 times at 1100 C and by more t4an 100 times at 500 C). Like in the
system ZrO 2 - CaO, this increase is due to the increasing number of oxypen
vacancies in the lattice of the solid solution. The slight decrease !r,
conductivity caused by,