SCIENTIFIC ABSTRACT SHELESTOVA, YE.P. - SHELINA, T.A.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001549020004-6
Release Decision:
RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
August 23, 2000
Sequence Number:
4
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
File:
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CIA-RDP86-00513R001549020004-6.pdf | 1.93 MB |
Body:
KIVI, K.A., aspirant; DEGTYA-R:,VA, A.S., kand.biolog.nau-1c; S' LESTOVA, V.S.
Brief information. Zashch. rast. ot v-red. i bol. 8 no.12:46-47
J 163. (' XIRA 17: 3)
1. Estonskaya sel'skokho:~yaystvem:aya akademiya, Tartu (for Kivi).
2. Ukrainskiy institut ze-shchity rasterdy i Ukrairlskaya sellsko-
khozyaystvennaya akademiya (for Def-tyareva, Shelestova).
DEG'TIAR'CVA, A.S. [Dehtiarlova, ...S.1; SHELESTOVA, V.S.
New insecticides for thc. co-itroll of the apple codling moth. Khim.
prom. [Ukr.] no.1:44-46 Ja-Mr '64. (M1RA YI:3)
~ I
SHXUSTOVA,J~19~P~, nauchi*ry sotrudniic, VASILICHOKO, T.Aoq nauzha" Sotrudnik
oomltlng of the color of coffee grounds in dysentery in infants.
Padiatrila no.2:39-40 Kr-Ap '54. (MLRA 7:6)
1. Iz L'vovskogo nauchno-iscledovatel'skogo institute, okhremy
matariastva i datstva (i.o.e-irektora-karlidat meditsinskikh
nauk M.L.Zalotavina, nauchny-i rukovodit:!'-prof. S-I-Ignatov)
(DYSMA12Y, in infant and child,
*vomiting, dark brown color of)
(VOKITING, in various diseases,
*dysenr,ery in inf., dark brown color of)
7 -:7
SHELESTOVA, Ye.P.; YERSHOVA, A.S.
Rare case of tuberculosis and cancer of the uterus. Akush.
i gin. no.2:129-130163. (MIRA 16:10)
1. Iz Llvovskol~,o nauchno-iss--.edovatellskogo instituta, okhrany
matei-irstva, i detstva. (dir. -- kand.med.nauk L.Ya.Davydov).
(UTERUS - CAECER) (UTERUS - TUBERCULOSIS)
WSHELESTYUK, P.I.
Came of extensive resection of the small intestine. Klin.khir.
no.6tW -Te 162. (MI-14 16 W
1. Warodichskaya rayonnaya bol'niLsa.
(INTESTIVES-SURGM)
6HELL6TYUKUV, G.
Entering the year 1963. Mostoprom. i khud. promys. 3 no.1:6-7
Ja 163. (MIRA 16.2)
1. Glavnyy inzh. Restovskogo oblastnogo upravleniya. bytovogo
obsluzhivaniya J. Rostov-na-Donu.
(Rostov-on-Don-Service industries)
VEZIROV, R.R.; SIMIEVOY, G.S.; BORTS, I.S.
Remote control of the operation of flowing wells in the Zyrya
area. Azerb. neft. khoz. 39 no.2:23-24 F 160.
(MIRA 14:8)
(Apsheron Penir-sula-Oil fields-Production methods)
(Remote control)
SRFLEV0Y,-- N, Sh ~
Determining th,~ parameters of -an oil layer in norlinr' jr flow into
a hyd rodynam ic;i! 11 y F.(. r fect wtdll .. ~ ~ ,~ .3~! rlo.11:46-cc, N
,(;l . MRA 14:12)
(Oil reservoir engineering)
. . Y:, . ,1, ~. . .
;;~ I T I ', . V .',:ikroklimp-t, iu/hn,,,,,kh goro,Jqv. I-loscow, ikal. me-IL:.b.
na-,zk 'i33R, 191,8. 11 1 - .
- 1,1 r.(,-1 .
L;, ;o,~iet G-~).:ranhv, Fart 1, 1951,
e
SiLSIO.-ii-isl 588.71
s
hch ;Wyndenle gorodov. LSmoke in citie&] M09COW. %finisterstrot
Ll~.ktjvs G
!lC.munal'!DQgo Khoxialst!M 1949. 234 p. 96 figs.. 44 tables. 72 refs.. J7re-qsDLC-U3efulI
experimental as well as theor.-GLal information on the dispersion of smoke-arid in cities or
Meteorological Abs*,r CLs, Methods of -neasuring and charting the horizontal and vertical st7rucllure of JUM
~~!ieed ~bv a stack are treated in considerable detaiL Se-Mral chapters give the theory of dispersion.
V01- 4 No. 2 Of imok-c anti gases under var3 ing conditions of wind. lapse rate. turbulence. stack height. practicaf
;size. or type of gas. Thejhcary is profusely supported by tables and charts based on
Feb. 1953 empirical
;fitld or laboratory data. Aw-leirof recommendations 13 presented for an In t"M plarm ng in the
Bibliography on light of wind (frequency of -91irction and speed) and other metcotologkal condifloru. (For fuller
J%IrWact Ste item 3(1~249. july'419S2. 31AB,) SOjeci Htselitsits: 1. Twhalm diffusion 2. !LIbIn 1,
Turbulent Exchang6
Mrsistaincy 3. Vlsl41ty 4. Atmospheric p*11titlos S. Smoke abatement G.-ftbile health.-
1 . -).': F L -'7-,' ~ I X A , Y e . ,' .
2. USSR (600)
4. Surgical Instruments and Appaz,,Itus
7. Prevention of prerAture we. r of surg:'.cal iznstrumt~-nts am, appz ratus. Fell d.iakush.
no. 11, 195Z
9. Monthly List of Russian Accessions, L:-brary of Congre5s, February, 1953. Unclassified.
SHVEDSKIY, B P MIESSINEVA N. A.P
CHEWITSOVA, T. A.; STBOLEVA, Yu. G.;
SHELIGAS, L.'V'
e.
Functional study of the adrenal cortex in leucoses under treatment
with hormones and chemotherapeutic preparations Probl. gemat. i
perel. krovi no.10:34-42 161. ~MIRA 14:12)
1. Iz gematologicheskcr7, klinilci (zav. - prof. M. S. Dul'tsin)
i klinicheskoy laboratorii (zav. N. A. Messinneva) TISentrallno-o
ordena Lenina instituta gematologii i perelivaniya krovi (dir. -
deystvitelInyy chlen AM SSSR prof. A. A. Bagdasarov [deceased])
Ministerstva. zdravookhraneniya SSSR.
(LEUCOSIS) (ADRE-,iAL CORTEX) (FORMOICE THERAPY)
(CHEMOTHEIR-APY)
MESSIVEVA, N.A.; KARASEVA, Ye.V.; GARD, IT.D.; SHELIGAS, L. Ye.
Study of the blood coagulation system after infusion of the
protein blood substitute BK-8 during experimental surgery.
Probl. gemat. i perel. kr-)vi 8 no.6: 45-1+8 .1063 (MM 17t4)
1. Iz TSentrallnogo ordena Lenina instituta gematologii i
perf-livaniya krovi ( dir. - dotsent A. Ye. Kiselev) Minister-
stva viravookhraneniya SS:3R.
L 4152L-65 EPA(s)-2/EWT(M)/EWP(w)/i:PF(c)/EPF(u)-2/EWA(d')/Ej~R/T/EWP(t)/:-
LVP(z)/EWP(b) Pr-4/Ps-4/Pt-7/Pu-4 Ijkc) KJW/JD/WW/JG
ACCESSION NR: AP5001723 S/6130/64/6160/0191001100231
AUTHOR: Shelgayev, Yu N. Donets, Is Tilin, NI-&
TITLE: Protection of metal with argou'during bottom pouring
SOURCE: Metallurg, no. 12, 1984, 2A3
TOPIC TAGS: equipment design, metiz~~argon, bottom pouring/
13Khl2NVMFA eel
ABSTRACT: Equipment was designed for. i~rotectinjz metals MAK AMA during
bottom pouring (F~ 1). The apparatus consists of two threaded~.44nders--
stationary cylinder 6 and the movable cylinder 5 equipped with an asbestos filled
closing device 3. The threads are protected, from liquid metal and slag by ring 7,-.
ceramic bushing 2 and asbestos packiDg 4. Prior to pouring, the apparatus is
mounted (with the movable cylinder in the lower position) ontowprepaped trumpet-..
and connected through pipes 10 and a fleidble hose to the argon'giupply line. The
ladle with a special flange I is mounted on the apparatus and locked by turning
Card I
41557-65
ACCESSION NR: AP5001723
handle 9. Air is forced out of the.tn*unpet And the mold, the stopper is opMe
d
and the steel poured into -unlubricated molds under argon pressure (0. 5- 0. 7.
M3/T at a casting rate of 2. 2 T/min
Examination of 13Khl2NVMFA steeLthum
poured showed that the mwcrostrudWiml~'defee,iii'vere,easientlall,* ell -.ed.-'-..
~-ultrasonically detectab4e defects wero reduced, and the steel had increased,
strength and ductility,',Vess nonmetaUia inclusions and improved inpt 6~ilace.
.0rig. art. has: 3 figu#.es and I table.
ASSOCIATION: Metamur
Chelyabinskly metaDirgi. thelyabinsk
gi-
cal Works)
SUBMTTED.- 00-
am-CODIC.- mm.
NR REP..SOV..% 000 OTJ 000 Y
Wits,
-'A -
CWdZ/3
&P4
tti~
KA-PELINITSKIY,, V.G.; SHM, M,~ VARTShV, M.A.; IIJL1-S, N.A.; POZDEM, N.P.;
3i;I-CUEYFIVY A.B.; ~IERENISRQJMVA, I.I.; KALININA, Z.H.; POZDNYAKOV, ICV.
Prinimali uchastiye: KUZON'ATOV, V.11.; MAKSUTOV, R.F.; NYSINA, G.Ye.,-'
SIOLAYEVA., A.V.; ::*HIVICHK"N, L..--.; GAYDUK, Yu.A.; GALYAN, V.S.;
~&-VY D.A.; EIIIELEV., LI,,; PARABINA, G.I.
Making steel and alloys in vacuum furnaces. SLall 23 no.4:325~-328
Ap t63. WaA 14 -.4)
(Vacuum metaiiurgy) (Electric furnaces)
S/l2q/6o/ooo/ooq/oo4/ooq
E197/E483
AUTHORS: Gorelik, S.S.: Candidate of Technical Sciences,
Faynbron,-S.M., katkova, A.M. and
She.1 veva. L.4. Engineers
TITLE: Causes of the Formntion of Cracks~ During the Forging
of Bars
_2_- _~P -0
PERIODICALs Metallovedeniye i termicheskaya obrabotka metallov,
1960, No.9, PP-17-19
TEXT: The object of the investigation, described in the present
paper,yas to study the effect of the cast structure of the alloy
E14iZBk%n its hot workability, To this end, cylindrical
specimens, 10 mm in diameter and 20 mm high, were cut from both
the outer columnar crvstals and the inner equiaxial grains, zones
of the ingot, the axes of the specimens being parallel to the
ingot axis and normal to the axes of the columnar grains. The
specimens were then subjected to various degrees of plastic
deformation at room and elevated (950 to 1050*0 temperatures,
an Amsler drop-hammer having been used for this purpose. In
contrast to specimens consisting of equiaxial grains, those cut
from the columnar crystals' zone did not deform uniformly, as
Card 1/2
s/12q/6o/ooo/ooq/oo4/ooq
E193/E483
Causes of the Formation of Cracls During the Forging of Bars
indicated by the change of the !;hape of their cross-section from
circular to elliptical. This effect was found to be due to the
columnar crystals being more ductile in the direction of their
longer axes, the degree of anisc-tropy of plastic deformation
increasing with rising temperature and increasing degree of
deformation. The anisotropy of' plastic deformation, attributed to
the difference in ductility of the interior of the columnar crystals
and grain-boundary layers, caused the formation of cracks during
hot rolling of material with traces of columnar structure,
Although the harmful effects of the presence of columnar grains in
alloy E1437B can be minimized by strict control of the forging
temperature and degree of deformation, it was concluded that even
a small proportion of columnar grains in this alloy renders it
unsuitable for critical applications or for manufacture of forged
articles of complex shape. There are 2 figures and 2 Soviet
references.
Card 2/2
POPOV, Nikolay Alskseyevich,_ SIIELGIJNOV, Nikolay, K*ns-tan-tinovich;
V1110GRADOVA, 11.14., red.1zd-va; TOMAKOVA, T.T., tekhn-.-i-fid.
[Using hudraulic calculatians in the designing of navigation
channnlsl. Opyt primpnenliq gidravlicheskikh raschetev pri
prnaktirovanii sudovykh khidov. Moskva, Izd-vo "Rechnoi
trans-Dot," 1959. 94 p. 04IRA 11:12)
(Inland navilgation) (Hydraulic engineering)
SIINL,GLJNOV, NIK., Inzh.
-!, -I `,,.. ~ ~,
-t,;..,. . ~,
Use of dredging machinery In the building of river straightening
structures. Rech. transp. 1.7 no,1:32-34 Ja 158. (MM 11:3)
(Dredging machinery) (Rivers--Regulation)
STMLGU-TV, N.K., inzh.
Opprational oxperionre on the Kama RRnervoir. Rech.transp. 1?
no.10:41-45 0 158. (MIRA 11:12)
(Kama lie se:7vo ir--Navigat ior)
SffEL(,UM)V, N.K., inzh.
Uning alkaline batteries to illuminate navigational beatcong. Rech.
transp. 18 no.3:L~2-43 Mr '59. OAIRA 12:10
(Electric batteries)
(Beacons)
. W.K. , iiizh.
-1, - -.I-,.-- ---, -
Sairlban'r- aM ifipth support patts~rzis in rzlopirr 7onnrn of re'lvr-
voirs. "'nch.trannp. 19 no.5:4-:,-44 My 159. 1~2. 9)
(linsf)rvoirg)
SHSLGUNOV, N.K.
Rechanization of river improvement operations on the Kama
River. Rech.transp. 18 110-9:37-39 S '59. (MIRh 13:2)
1. ZamestiteV nacballnilca Bluzhby puti Kamskogo baBseynogo
upravloniya putt.
(44vars-Ragii1ation)
SHELGUNOV, N.
Regulating te=orar7 used river sections. Rech.transp. 19
no.3:49-50 Mr '160. (MLRA 14:5)
1. Zamestitell nachaltnika sluzhby puti Kamskogo basseynovogo
upravleniya puti. (Rivers--Regulation)
ITANDBASHVILI, Ye.M.; Sf(ELIA, N.G.; IVVITSKAYA, L.V.
- ~
Formation of thallium sulfides. Soob. AN Gr-jz. SSR 19 no-5:557-562
11 '57. WRA 11:6)
l.Institut k-himii im. P.G. Vilikishvili. Predstavleno akademikom
R.I. Agladze.
(Thallium sulfides)
ALEKSANDROV, Yu.A.; SITLIKL, R.
Qtudy of the EU148 decay scheme. Izv. AN SSSR. Ser. U7. 26
no.9:1162-1163 S 162. (MIRA 15:9)
1. Ilauchno-issledcrvatellskiy fizicheskiy insti,ut Leningradskogo
gosud--rstvennogo universiteta im. A.M. Zhdanova.
(Europium-Isotopes) (Gamaa-ray spectrometry)
SHELIKHANOV, M., uchitell mashinoved3niya i elektrotekhniki
Schools and scientific Institut9s. Politekh.obuch. no.11:85-86
N 158. (NIRA 11-12)
1. Khimkinslaiya arndnyaya shkola No.4 ~bskovekoy oblasti.
(Khimki (Moscow Province)--Field work (Educational method))
LUTS-KO, S), SlIELIKifOVIG.,
I , -a= (~LI , -1 r 'on.
I , --,,n ? !, .: -;-
i. Magnetic f axd3tee-t,
A-. -3 kl,sm. 47 S I t' 2 ( ml P-, 1-:8"
I
'?C!," CODE;
Slnelikhov, G. S.- Lutr.'ko, S. Krents, E. A.
NG:-.C
dev*cc for automatically contro'-ling the intensity of the magnetizing field
notic flaw detectors. Lass 42, No, 182386
S C Z': lzobre-.eniya, prorqyshiennyye obrc.ztsy, tovarnyye znaki, no. 11, l9bo, 92,
TAGS: flaw detection, mna3netic detEction equipment, magnetic field intensity
-`~STRACT: 7.-,-4s Author's Certificate intrcduces a device -for autom&tically control-
!-I*,-,,- zl-lc in-z;ensity of the magnetizing field in magnetic flaw detectors by using an
~n~'cator w-~ch measures the intensity of the magnetic field at the surface of the
A. I - I
-Cein.~- z~aonetized. This indieator may be a Hall transducer which generates
vo-ta:-e to serve Ls a uositive feedbac,t for transmission to a magnetic-ampl'ifier con-
neczed in the maGnetizin,7 current source circuit. The device is designed for im-
7roved accuraqy in magnetic inspection of parts with complex shapes by maintaining
a majnetizing field intensity on the surface of the component. A current
cr with. an adjustable range is connected between the transducer and the magnetic
a=plifier. The range of this limiter is set to correspond to the required intensity
of the magnetic field to be checked by the transducer.
Card 1/2 ux; 620-179.i4-05
iv,ccompcnent ",o* be irtagnetized,,
2-,otransduceri 3-amplifier;
4-limiter
.D,;'B =-E: C-9, Ili/ SUI-u%; DATAE; 10,vay'3
_q~~,d 2/2
ACC NR: AP6035735 ---SO-U-,ZCE--CO-D,E-:-UR-/-0-413/66/000/019/0()O,',/0098
INVENTOR: Shelikhov, G. S.; Lutsko, S. P.
ORO: none
TITLE: Method of magnetic inspection. Class 42, No. 186750
SOUKCE: liobreteniva, promyshlennyve obra.-tsy. tovarnyve znaki, no. 10. 1966, 98
TOPIC.TAGS: noncigstruCtive i-~-~weld inpsection,
ABSTMCT: This Author Certificate introduces a method.of nondestructive mametic
weld inspection with a magnetized powder sLspension. To make the suspension selective
Lor some specitic derects, magnetizing of the suspension is done by a magnetic field
adjusted to a certain intensity.
SUB CODE: 13/ SUBM DATE: 09Jan65/ ATD PRESS- 5106
LCa,d UDC; 620,179,141
KODESTOU, T.A. lredaktorl; VIZMOV, P.G.; SHK-MOV, N.N.
m
-extile scip.::ce for the sewing indistry] Ykterialovedenie sh-.einogo proiz-
I
.,odtFira. F')J red. T.A.Modentovoi. Mos~-vu. Gos.nauchno-tekhn.izd-vo legko-i
VrOM:-8111. , 1'~15 3. 135 r. ( n-RA 0' : .9 )
(Textile fabrics)
MODESTOVA, Tatlynna Alekneyevnit; VIK):ROV, Pavel Gmorg'yavich; SHELMOV,
Nikolgz I;tkolayovich; SOBULIIIA, V.11., redaktor; MXDVMror, -Till-,
'T"Whnichaskiy redaktor
[Textile fabrics and sawing Bipplies; merchandise guide for the
clothing Industry] Haterialoveiente shveinogo proizvodstva. Mo-
skva, Goa. nauchno-takhn. izd-7o Ministerstva promysh. tovarov
shirokogo Dotreblentia SSSR. 1955. 190 P. (MLRA 8:6)
(Teitile fabrics) (Sewing-Mouipmant and supplies)
VE)EI;KI'~, inzh.
KC S'-' 1Y Ya.., inzh.;
red.; inzh.;
Ve. I inzh.,. red.
red.;
red.;
LF~ice li-q-, for -~ie azsembl-i of equipmenru i-enrik na
monta-zli oocrudo-:anila. ','oskv.i, Stroiizdat. No.ll. l9t5-
104 1). (MILU 18:0
1. hu~;Mn (.1923- Qosuclarstvenn~y kc~~nitet po de-
iam stro-'I.t-ellstva. 2. Gc)ss-.i-o:r SSSH (for Ve6enkin).
3. :Institlit ekonomiki stroitell-
iitva Gosstro-va SSS"' (t'ov Zaslivskiy, Kovallskiy, Voytova).
4. Pro-,ektno-konstrukLorskoye by-uro No.12 Glavi-.ontazhavto-
iTAtiki (for Neudakin). 5. ',*sp,3oyuzTriy bank finansirovaniya
kapitalInykh vlozheniy SSSR (.or Shelikhov).
.51E&LIKHOV, V.1f.
Mechanisms of generalizatiorL of excitation induced by strychnine
and pain stimuli in the ceriibral cortex. Fiziol.zhur. 45
no-8:910-915 Ag '59. (HIRA 12:11)
1. From the Department of Physiolop_y, I-H-Setchenov Medical
Institute, MOBCOW.
(CIE RA CORTIOX, physiolo&-r)
(STRYCHNIM11. pharmacology)
(FkIN, phyEiiolog7)
Tr-, loral zF, OT7 o
of
~~Cn 1 ?7)
SHELIKHOV, V.N.
Electrophysiological studies cn the role of subcortical formations
during the generalization of excitation in the cerebral cortex.
Zhur. nerv. i ps~ikh. 60 no. 2:145-149 160. (IJ'-RA 14:4)
1. Kafedra normallnoy fizioloE:ii- (zav. - prof. F.K. Anokhin) I
Moskovskogo ordena Leni3ja meditsinskogo institrta immeni 1.M, Sechenova.
(BRAIII)
31111~LIKHOIIA$ A.
Tuberculosis HosDitals and ')a.,.aLori-=s
Work of imrses in a tuberculosis win.a and sDecial features in the cl-re of patients.
;I
led.sestra L10.
3, 1953.
I Unclassified.
'~onthjj List of Russian Accessions, Library of Congress, JM0 1953-
SHELIKHOVA, N.A.. meditsini3kaia sest~a (Baku)
Surgical treatment of pulmonary tuberculosis and post operative
care of the sick. Med.sestra, no.9:27-29 S '55 (MLRA 3:11)
(TUBERCULOSIS, PULMOMM, surgery
postop. care, nurves role)
(POSTOPERATIVE CARS, J.n various diseases
tubercb,pulm.,role of mirse)
SHILIKHOVA, N.A.,meditsinskays, sest:,-a(Baku)
Methods for subcutaneous and Intramuscular injections. Ned. sestra,
no.1:21.-23 J& '56. (KLRA 9:3)
(INJW,TICKS)
SHNLIKHOVA, D.A. (Baku)
I
' - :..-' Hartia Yedorovna Rimcizoook. Ked.sestra 16 no.5:29 My '57. (MLRA 10:7)
(RIKDZIMOK, MARIIA JWMOUU)
0
SIMLIKIOVA, B.A. (Baka)
Work of -Ghe aursesl councils. Med.sestra 17 no.8:lffl Ag '58 (MIRA 11:8)
(BAIaJ--YURSES AND IMRSING)
SHELIKI]OVA, N.A. , ineditsinskaya sestra
Work ot' ward attendants in tuberculosis institutions. Med. sestra
20 no.9:52-53 S 161. (MIll 14:10)
1. Iz legochnotuberkulemogo sanatoriya ineni My-asnikova, Baku,
poselo", Buzovny. (HOSPITALS-SUFF)
SHELIKHOVA, S.A.
Panotitis etiologically related to foreign body. Vest. ato-rin.
16 no-3:71 My-Te '54. (PI-11A 7:7)
1. Iz Leningradakogo nauchm-issledovatel'skogo instituta bolesney
ukha, gorla,, nosa i rechi (dir. prof. I.A.Lopotko, nauchnyy ruko-
voditell daystvitellnyy chlen Akademii meditsinskikh nauk SSSR
prof. V.I.Voyachek).
(FOREIGN BODIES,
*ear, middle, causing panotitis)
(OTITIS, etiology ani pathogenesis.
*for body in middle ear, panotitis)
(EAR, MIDDLE, foreign bodies,
*causing panotitim)
~-, , -I
, -, I -- -,.-.
Sheep Shearing
Electropechanical sheep shearing on the "ChervlenrWe Buruny" breeding farm.
Sots. ziiiv. 14 no. 11, j-952.
Monthly List of Russian Accessions, Library of Congress,
I
5(2) , 5( 3)
Alj-T~--'ORS: Andreasov, L. M., 'fay!, Ye. I., SOV/7
Kremer, V. A., She."-ikhovskiy, 7. A.
TITLE: Potentiometric Tit:?ation of Silver, Copper, Lead and Thallium
With Thioacetamide (Potentsicmetr-icheskoye titrovaniye serebra,
medi, svintsa i ta .-liya tioatsetamidom)
PERIODICAL: Zhurnal analiticheskoy khimii, 1956, VC1 13, Nr 6, pp '057-660
(USSR)
ABSTRACTs The use of thioacedamide for the potentiometric titraticn of
some metals on the basis of thei::- precipitation as sulfides
is of great interest. 7n the present paper a method is
devised according to which thioacetamide is used for the
potentiometric titration of silver, copper, lead and thallium.
The principal difficulty in ;he use of thicacetamide as a
hydrogen sulfide scurce in potentiometric titrations is the
low rate of hydrolysis in aqueous solutions (Ref 13). In
practice only the Frecipitation of silver ions from Ammoniacal
solution takes place at sufficiently high velocity. Ions of
other metals (Pb, Cu, Hg, Tl and others) are precipitated by
thioacetamide very slowly. Increase in temperature and change
Card 1/3 of the pH-value of the solutions increase the veiccity of
Potentiometric Titration of Silver, Copper, Lead SOVj'7I5--3-V'-6/21
and Thallium With Thioacetamide
precipitation, yet not tG such ar, extent that titration with
thioacetamide might he possible. On the basis of a number
of experiments the authors of the present paper found that
the velocity of the -irecipitation of lead and some other
metals with thicacet3mide is considerably increased by addition
of a small amount of hjdrazine hydrate. The mechanism of
this accelerating effect of hIlrazine hydrate is obviously
complex and was not investigatqd by the authors. Titration
was carr 4ed out by means of a sulfid4c indicator electrode
made of synthetic Ag2S (Ref 14); a saturated calome! elec-
trode was used as standard electrode. The measurements were
performed by means of the PPTVI potezitiometer. The compen-
sating current was determined Iby means of an- M-91,gaivanometer.
The aqueous solutior of t~iioacetamide does not modificate
its titer for a loni time (about 2 moriths) and dcas not require
any special conditicns of storage. The determinations of Ag,
Pb and Tl according to this method (from ammoniacal sclution
under addition of hydrazine hydrate) are described there ia
detail, The method is also applicable to the analysis of
Card 21/3 silver-copper alloys. The determination of both elements
.11-1 5-0-0/ 21
Potentiometric Titration cf Silver, Copper, Lead C 7j 7 5.1 , ,
and Thallium With Thicacetamide
from a-Tie sample is p,)ssible since borh sil-fides differ ir.
solubility and the time in which the.,, aie precipitated. First,
silver is precipitated from ammoniacal Eolution, hydrazine
hydrate is then addei and the copper tii-rated also with
thioacetamide. The most accurate resul,s are obtained a. a
copper content of 10 - 90%. There are ~ figures, I table. and
14 references, 3 of which are Soviet.
ASSOCIATION: Kharlkovskiy gosudarstvennyy urivers-ite- im. A. Y.. Gorlk-,go
(KharIkov State University imeni- A. Y. ( orlkiy)
I
SUBMITTEDt May 3, '957
Card 3/3
SHCHEREAV, A.N. [Shcherban', O.N.], akademik; KRENW, O~A. [Kremnlov, 0.0j;
KOZ10V, Ye.M. [Kozlov, IE.M.1; SHMIMA30V, V.A. [Shelimanov, V.0.3
WOMP&
Principles for calculating the temperature and relative humidity of
air in mines. Dap.AN URSR no.11t1527-1529 160. (MBA 13; 11)
1. Institut teploenergetiki AN USSR. 2. AN USSR (for Shcherban').
(Mine vontilation)
3IICIJE-KBAII;, A.N.., akademik; KREIMNEV, O.A., kand,Lekhn.nauk; KOZLOV, Ye.:-I.
i.nzh.; 6HELLIOOV, V~A.,, iazh.
Analytical functions describing the processes of temperature
and relative humidity charges in mine shafts. Trudy Sem.po gor.
teplotelch. no-3.25-28 'U. (MIFA 15 !4)
1 . Institut toploonergetiki A14 USSR.
(Pine ventilation)
SHCHES-1-All-, A.N.- akademik; K.U12'410f, O.A, kand.tekhn.ri--uI:, KOZZOV, Ye..',,,-
inzh.; SHELIHANOV. V,,11J, inzh.
Analytical functions descrLbing the processes of mine -~enperatare
and relative humidity ch8A,),es. Trudy Sem.po gor.teplo-Lekh.
no .3 -.2-9--32 161. (,kMU 15.-,4)
1. Institut teploenergetikl AN USSR~
(Mine ventilation)
ZIMAVLENKO, B.Y.; SHELEMANOV, V.A~
Gooling the air in walls of mines deeper than 1200 m. Trudy SeM.po
gor.teplotekh. no.3:8-~,90 161. 04IRA 1.5,4)
1. Institut teploener.,,etik:L AN USSR.
(Donets Basin-Mine ventilation)
SHELIMANOVI V.A-, inzh.
Experimental determination of the heat eraission of rocks in new
workings of deep coal mine~i. Trudy Sem.po gor.teplotekh.
no.3,78-.82 '61. (PILiA 15.4)
1. Institut teploenergetik-L AN USSR.
(Mine ventilation) (Rocks--Thermal properties)
ZHURAVLENKO, V.Ya., inzh.; SHELIMANOV, V.A., inzh.
Predicting the heat conditions in tunneling for purposes of
supplying Yalta with water. Trudy Sem.po gor.teplotekh.
no-4-.141-145 162. (MIRA 15:8)
1. Institut teploenex-getiki AN UkrSSR.
(Ay"Petri--Tuanels--Ventilation)
KRDtNEV, Oleg Aleksandrovich, doktor tekhn. nauk; BOROVSKIY.,
Vladimir Rudollfovich, kand. tek-hn. nauk; DOL121SKIY,
Anatoliy Andreyevich, kand. tekhn. nauk. Prinimall.
uchastiye: PIYEVSK.TY , I.M.; DUKIRUNKO, N.T. ;
SHELIMANOV, V.A.; CHERNOBYLISKIY, I.I., doktor tekhn.nauk,
retsenzent; GAVRILOV, V.N., red.izd-va; ROZUM, T.I., tekhn.
red.
[High-speed drying) Sko-rostnaia sushka. Kiev. Gostekhiz-
dat USSR, 1963. 381 Y. (MIRA 17:2)
KRF?OIEV, O.A.; BOROVSKIY, V.11.,, SIE11MANOV, V.A.; SHERENKOVSKIY,
Y*
Heat treatment of ~!yrthetjc fibers "jur-ing their si-e"Ch ~C',:-Mng, Ka~.
volok no.6~1--,--23 '63. 'IMIRA 17.- 1, )
1. InstItut teploenergetilti AN RrSSR.
T!'RESHCHEN1~0. k-in,!.t(,.klir..n-quk;-qi'E.L,IMANOV, V.A., inzh.
Charactt,rjs*.ics of heal, releasp as a result of rock crooling in deep
mine stcpes. Ugoll Ukr. -, ne.11:27-29 N 163. (~ffRA 17:41'
a i:
A ad----rri
Fv-
A-ad 0- th-: ~n -r
ukr SOM ~n
. Hoat and f4a--s Ti-nan-,-f~--rr.
T. ip~ratlx-, Ki~-- Sc lent if Sessi:m,
?,6
v, 2-L Apr '-
TI - -2' PF
J-1 -S 2L
c -n
ic i- lit
83566
3/020/60/134/001/019/021
I/S_0 0 B004/Bo6o
AUTHORS: ,-Sh-alimov, B. N.p Bubnov, N. N., Fok N V
Voyevodskiy,_~.'T., Corresponding Member AS USSR
TITLE: Detection of Hydrogen Atoms in the Phototransfer Reactions
of the Electron A/
PERIODICAL: Doklady Akademii nauk SSSR~ 1960, Vol. 134, No. 1,
pp. 145 - 148
TEXT: The authors proceed from the photochemical reaction in the aque-
ous medium: M tj~H20 + W + + OR- + H (1)2 where M may be metal ions
of variable valency, or anions. The formation of hydrogen atoms in this
reaction had been hitherto proved indirectly only. The authors wanted to
give direct eviden6e of H-atoms by means of electric paramagnetic re-
sonance (epr). Because of the strong reactivity and mobility of the
H-atoms, investigations were conducted at 770K in aqueous solutions of
H2so4 or H 3P0 4(in concent.-:ations between 40 and 96%), which contained
small quantities of FeSO 4 or KI. The samples were irradiated for 1 hour
Card 1/3
83566
Detectlion of Hydrogen Atoms in the S/020J60/134/001/019/021
Phototransfer Reactions of the Electron B004/BO60
with the ultraviolet light of a ffPK-7 (PRK-7) mercury vapor lamp. The
epr signals were recorded by meens of a previously described (Ref. 7)
epr spectrometer. It was possible to give evidence of the H-doublet. To
check the correctness of reaction (1) definitely, experiments were made
in solutions which contained heavy water. As is shown by Fig. I, the
D-triplet was observed besides the H-doublet. Further experiments were
conducted in the system C6H6 - E'20 - H2SO4 . Here as well (Fig. 2) the
H-doublet occurred. The central part of this spectrum, the quadruplet
shown in Fig. 3, could not be explained yet, but it might be due to a
paramagnetic particle whose free valency is localized on the aromatic
ring. Weaker components were detected in the epr spectrum of the
H-atom (Fig. 4), which are ascribed to the spin reversal of protons
surrounding the H-atom. While the H-lines were strongly saturated in
the experiments with benzene, saturation did not take place in the
presence of Fe 2+ due to higher concentration of the paramagnetic ions
of a short relaxation time. The study of saturation and intensity
distribution between the main ani secondary lines in the epr spectrum
of H* may serve to clarify specific features of its weak interaction
Card 2/3
83566
Detection of Hydrogen Atoms in the S/020
,/60/134/001/019/021
Phototransfer Reactions of the Flectron B004/BO60
with adjacent molecules, and also to establish the distance between
H*-atoms and primary particles raleasing an electron under the action
of light. There are 4 figures anti 12 references: 3 Soviet, 8 US, and
2 British.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova-~
(Moscow State University imeni M.V. Lomonosov). Institut
khimicheekoy kinetiki i goreniya Sibirskogo otdeleniya
Akademii nauk SSSR (Institute of Chemical Kinetics and
Combustion of the Siberian Branch of the kcade-m--y-o-Y
Sciences, USSR)
SUBMITTED: April 27, 1960
Card 313
BUBNOV, N.N.; VOYEVODSKIY, V.V.; FCK, N.V.; SHELD-OV, B.N.
Study of electron phototrarsfer reactions in the solid phase
by the electron paramagnetic resonance zethod. Dpt.i spektr.
11 no.1:7&83 JI ~61. (~a?A 14:10)
(Paramagnetic resorance and relaxation)
(Photonuclear reactions)
2903-0
S/O'; C/61 /1 40"G04/01 1/021
L9 31 Ob/ 31 11 0
AUTHORS: Varbanskaya, R and Fok, N V.
T IT L-:~' Reactions of met;lyl radicals in solid i~hase at low
temi~eratures
PERIODICAL; Akadejaiya nauk SSSR. Doklady, v. 140, no. 4. 1961, 818-821
TEXT. The authors studied the zondition3 of stabilization and the conver-
sions of methyl radicals obtained by photolysis of methyl iodide,
azomethane, acetone, and acetadehyde at 770K, The role of "hot" radicals,
4 ,e, , methyl radicals with excoss ener-y, in these processes was
clarified. The analysis of ga3ecus reaction products and data of electron
paramaE;netic resonance (epr) spectra were used for this study. Transparent
solid solutions of the tested compounds in methyl cyclohexane were
~,hotolyzed in a quartz vessel cooled by liquid nitro.-en, The cancentra-
tion of solutions was 0 02-0, 15 moles/liter, and a TTPK-7 (PRK-7) mercury
la.mp was used as irradiation source. Tne e;)r s, ectra were recorded on an
gTrP-2 (EPR-2) device (Ref ). A- G. Se-111,.ncv, i. Bubnov, Pribory ir
tekh.q. eks,~tjrimn (Devices and t~nC',,njCaj E.X-eri.~j ItS~.. 'T~; 1 , ~'j' 1959
e.
Card 114 Vf/
29010
Si
31 C6731 10
-lethyl
6 C 5 ( BS 1 t e r e rv J ~)u s J t u F > 1 0 0 and a ter led
,,vith a ii.ixtui-Q of' CI and Br. atid pervious to lie"." --f ..< 2)OG S, "Vere used
, of tLe exper mvmts In the photol~sis of azomethane in solid
n sirkc.
ohase, one :;,olecule of nitro~-en a,id ethane each were formed per
decomj,osin~, molecule of azomethan~, and, additionally, methaae in a ratio
3f CH 4 /C296~~0,04 indei)endent of the -Lateksity of iiijit !,',ethane was the
only 6aseous reaction product in the 2hotolysis of methyl iodide
Acetone was not decomuosed under the conditions aotlied, acetaldehyde
sliEhtly decomposed to about equal quantities of CO and 017 4' The fact
tLat the ratio CH /C -H found for azomethane decomiposition -,-,aS
4/ 1 6
indeL;endent of the intensit.; of -.1ght indicates that ethane is formed by
recombinaticn of radicals in ~I,e interior of a "cell", and not by
recombinatic;r, of radicals., The formation of methane in the
phutol~,sis of methyl iodide and azorn-ethane at low experimental temperature
(7700 sug6ests the formation of "hot" methyl radicals in the solid phase-
Tile stability of acetone to -photolysis indicates the abs--:-nr,~ cf "hot"
rrad 4- c a I sTI- rea3nn is the lar(~e difference between Lh,.-- bond erer,~ies of
the C-C bond 4,-~ acelone (77 kcal/mole~ and of t-E- I,-'- b~-,n-d in I-leth'.1
bard ---/4 - i x
2 K,10
7Z~
S f
y s
r a d i
:a in
L
a S
7
n 7 r e as -S
a 7
re capa-
cund
d 3 re '-
~L e t'f- al, e d ate!
- 1. =,. 1 Mme
in
onr -
:-na' 1 on + - r re a,: t :. On s
T, C, ri 2~ t
c '1`6 ) ; '
n and a , "y ~, e r e H s t h e radical cf
ctj
11_7 1
zatt r. eme r,~ence f r o r;
s~:abtL- t 171 - - - -
I - tl-ese
d4 - C,
The rac4 c,
three raa:t 4- Dns dei,prds on the f the ac-so 111c-rease 31
e, ra~;ed format;c-n of methyl reactin,;2,
- -P S,11 t s ~ r P-n irLc--
r-aCt'r-.F.* acco.-d--*r.,g and in
n, compared with
acccrding c (2) as compared vi,-'~'i th-2
met' --1 -a'd J c a I s r .3 a c - i,
'n, rad'icals in the
an :-.-r.?ase h. j ZD
t',,.c,sc- reac-~.in~- acc("rcl,-n-, ';c ~Lj Tne fcrma-,--~
ot'~, s 4- S o f C'- 1 and IrL s.-,lid ,,.ase has anus, been cl~-arly
3
o~' the react~-,n o: 'rhesp- tt~,cTll methyl
~Iard "/4
29010
a c:.s
b-,~:,,d en,~ z ii_-s o f the mole cu I es de compos 1 rig wi th rmat Ic n D f me thy.
rad '. :!a 1 s and --In th e wavel enCth o f the 1 16-h t us ~d f:) r de - -=p-, si ~ i -7- T h s
P I'f e c t i s s ly rel at ed tc. d~ f fe ven - e s ~ n 3 ~ ex.2 i ta- t --' or, c f
It h t ra i -u 1 s vnh i ch a re ormied in di,--_`~r,~-nt wa,:3 Finall.y. th.., auth~:rs
V 11 _J,~ v -. r; -
T~ 'S 'uSSR. f- r ass s,~2
In
t'- evalu - of resul-.s a n d Bu-tnov --ecordin6 Fle e-,,, s-.---czra
TLe s~,ectru:-. of the *hex,,I r;--d'- ~'-_-,a'ned b-.
rradiatior. of
fr.-z-en imlmt~-I -_-Tclit~exane ( 7 7) K x 4 h 4~ a s I ~e r,7. -, s w a s r a c c r al e d b
T 1 C',,,khe, d:! e -. n the e:c;- e r,.zient al 1 an,~ f t- 7 ns t i u I kh4 mi cheskoy
fiziki All SSSR (j!!3ti_t'.;te of LS l-'SSR). T h e re a r e
s t alh a nu I C, r c, r c, - s S.-v:-. und 11 . '.h e
rel .erences t-: ~:ublicaticns read as
-1, 0 11 - -N S C j , G, ca__,~,ert Lm, S~:
eupy,
T C cl e L7 0 -Pritchard , IT R Dav-' dsc n , H , I' C c n n e i !.::I y s
410 G~:-rd,-, C, ~3, 11`2C:,rm~tk, 3- IL rr Che:::~ So c 78,
ASSCC1,LTICN; i','osL-cvsk,.y ~:)sudars'~lf~-nny- n
s c (:os S t a U r, s , t y -L-en-_ c - S DV
T 17 :.T
S-3 -17:), r:!h I
ca
P. 12 0,
312
VCYevoaski-Y,
V an-
,-jj"e
0 W
T
of "Ydroca:'Oorls
Y v -"G
lauk sssa-
O:j Y a- -
"Otoctriamica. decl)-.
rl
bc,~n s-- 0
17' a-- 770Y
b E:a GI U.L
C) i S a sub 3 t 4 t -I t -j d
-. z,.. -, 0 S
'ca- El C, ',o
the h,,,,droc,~-roon T,,~dium 2.-,, 4
d in
-ad-c-s ~,re -Por-.e
f ail-!-, -adi cals ca.)-noz bE: expjaj-ned by -6he react--ons hithlerto
is
t4 on o U~14e` ~he
-70 4- 0 n0 -ecus ':)rozuc-.s was St
O-F T in, cyclonexane and
d w4t',. concentrations ra"61rig
711
8 - 1 G--~ 10 2 .1 -1 C-? mole/1-iter. 'L..e MerCUrY VaPor
Ai - -,ior, , the soluiion was
,.,;as usad as Lhe radia-i-icr. source. kf-.er
c F- r d 1
2
77
f Z; 2. P u C 1L 0:,* 2 Z r I C 'I r~ a L V 3 i L -..o irr--l-liated
n-pcntane V) arld the &2ciunt c,--' 1-I fcnred by
r.-.easurad s3ectro-j-otomatricallly at 27~-' The apr s-~ect:ra
'IT were founa to '-e
f en z --; c a!
G the irrad~a-.ed solu-~J ns of I -ir, ~o
z'----L o' the radica-L obtained by radiatia n o f f r,-~ (TIT
.:- - cycichexyl - ,:^, 1 1)
Wi.h fa--z electrons. The spectru= o~f soluzions of I ir. 1V consists of
hyperffire structure components -aith a uniform naztern
snlitiin~- of about 24 oerst v;nich is probably due to the
C-:1
CT-1 - CH radica' "ormed )y 2p-;It-*nZ off one at= froz
2
C Om 0., TV.
ry -en i is ir::-adiated in 17, H fonns., in a d d c n
~e F_S-~--St4 tUte -..j I e C D, -riel-'s s"a'! azcunts of ad4ition
6 0
'o -in the safe hydrocarbon. ~-'ha .;-i.:.-,;ltanecus formation of raai-
c a' s ~-s obviously due to -".-e decom-,;o.;ition of the hy4rocarbor. 'Chotosen-
by T. The L~cst important ~ea-.ure o-;7 -.he reac-.-*on 4s t"-e
(112 kcal/m3lel Js transferred,
licht cuantum absorbed by 1 ) - -
--t, he hydrocarbon -o7ecu-e, which, results in sp14-tin:.
to T C.
.3 a r. s t i z e
2
~L L L- C, C'.., e rcturnz fr3z. itj exc:.~~,~d
t
C
v 0 r
0: -.re
--s cf a '-re Or 3:
0 e I Z,? r r E s :),a C'Z :.,I e y '2a yial-- of increases
is
0
::~e irlcrEase of v4eld Of JS C y
4ve 4ncrease s 2.3 and 1.1 fo,d. are
--osud--rstvarmyy u--Jvcrs4-,Le-. 7
C, Oncso.'a
il:..cScoiv S-.a-.& Univerzity -4:zeni :.,. V. :,ozcnoso-.r) 5 1~ i -. U Z
4 jEorenfya S~b4rsko~o o-.de-'en--'--a -kade=iJ nauk SSS?
c,--' and Cozbuss-~fon of the Siberian
D e ;D a r n z of t-e ;.cademy o-f Sciences USSR)
S Fe ID'uary 24, 1962
0 a::- d
FC,r, SH---Ll-,I-rV, B.N. , VOYFVCIDSKI~ y v.v.
"On the Fhotosensltizej deco7ponitlon of hydroc,rbons by benzcne and
its &?rlvatives a+. low te-perature.11
Report subr,ittprl to the SJxth lntl. Symp. on Free Radicnls,
Cambriegi-, 1~ngland 2-5 July 1963
- SHELIMIUVVB.N.; FOK, N.V.; VjYLVuDL;KIY, V.V.
Photochemical uccomposition of alcohols at low temperaturus.
Kinetics of methyl alcohol decomposition. Kin. i kat. 4 no.
4:539-548 Jl-Ag 163. 04IRA 16:11)
1. ~bskovslkiy aosudarstverulyy universitet imeni :I.V.Lomonosova,
a
khimicheskiy fak-ulltet i Listitut khimicheskoy fiziki A14 S6SH.
ODINTSOVA, S.F.; SIELIMOV, B.N.; FOK, N.V.; VOYr-VODSKIY, V.V.
Te.mperature r-, zln=- rates of benzene photochem--cal
reactions in hydrocarbon solitions. Izv. AN SSSR. Ser.kh-Lm.
no.3-572-574 Mr '64. (MIRA 17:4)
1. Moskovskiy gosudarstitennyi universitet im. M.V.Lomonosova I
Institut khimichesl-oy fiziki AN SSSR.
C E, I 1 -1
'."'."ION NIV. AP4010761
S/0020/64/154/001/0188/0190
V. G.; D. IT.; Fo1c, N. V.; Voyevod-
V. V. (Correspon"Jing
'~'l decomi):)s1tion of hydrocarbons at low
.e,-aperzatu~-es by luenzene derivaUvas
Dolclady, v. 154, no. 1., 196-4, 188-190
derlva'i-vc , hydrocarbon , aroiTilatic hydrocarbon
roc ar k--iC.T. photoCensitized clecomposition, to"Luene,
_5o-propyibenzene, Pxylen.e. rUphonyl-m-ethane, cb1orobenzene,
-~c, a
-pheny1motha- fluorobenzene, ceophenone,
ul-raviolet o xylLane, m x.-.,Je,-)e
C T solutions of benzene derivatives, such as toluene,
._,~.-1,,ylbonzene, i~,o-propylbenzene, o, m and p-xljlerie, d1pheny1m, ethane,
triphony1metho.ne, fluorobenzene, chlorobenzene and acetophenone in 3-
methly! pentane and deuterium-containimg 3-methyl pentane were sub-
jected to ultraviolet light at 77 C~ Hydrogen was isolated and 3-
Co." 1/_3
0107 `61
'
j
U,
t 1- ble
00
C) 4- NCL
D 7, C
OTHSH: Oll
RE F S, OV 004
Cara 3/3
At,
11'4010761
(~,-j J,
were forme(i i
n all cases except in
"
he initial rate
0~
he conccntratjoll, 01
o tr the tr
I u
-
l
t
p e
e da
,
,a agve(,~3 ;.-:L"
-
-h the
,
aoow
'
iipt
'
) :
ion til:Lt "ii.
in
:
(--
C
,.
0 S
j) -
-ic
Let; statc, pa"t lpate :1
the
ill Ot, 0 -
e v e 1
-
'l
h I e aro-
k
1
c a
, 1 rt o 1 eI,e
:
ii
1~- formiat
Jn z; hi
p
-uld
o r
n,
c
l, Ga ar" it I: L r-PI-e
,a
i. f i-I Of a roma t4L C
c IL t, et I: , L L)
possib--e
abL;orb
to ti-I''a h'--her tvi-,,Ie~, an d
c C)i
n 0 rcy iioeded to rup-
.
the pi"n 1-
j
!._,:.J_I0rI deco
on of th
OvIg. art;
l
.
e
iau. 1.
Card 2/3
L
S
LIELLNCV, J3.N.; FOK, N.V.; V(WEVOIN~KIY, V.V.
Photol7sis of ethyl al-7oho--,. solutions az '77cK. Y-in.i kat. 5
no.6:1008-1013 INL-D 164. (MIRA 18:3)
1. Moskovskiy gosudarstuvenryy universItet i.m(,-ni Lomonosova,
khj.mdcheskiy fakulftet i Irstitut k-h,-michEskoy fiziki All SSSR.
VITHOGRADOVA, V.G.; SHEELIMOV, B.-N.; FOK, 211U.
Stabilization of a~~om-,~ hycrogen in the lb~,-3nzene-photosensitized
decomposition of hydro.:.-arbc,ns in the --reser,,2e of s--l-ica gel at
771K. Kin.i kat. 5 no.6:11;1 N-D 164.
(MIRA 18:3)
1. r4oskovskiy gosudarstvenryy universitet imeni Lomonosova,
khimicheskiy fakulltet i Institut khl-nicheskoy fiziki AN S'.;'sR.
L 1o837-66 ZWT(m)/EWP(J) RPL 1AVY6SIRM
ACC NRI AT5023445 SOURCE CODE: UR/9000/65/000/000/0249/0253
AUTHOR: She2M__0=B N.; Fdc, N. Ve; Voyevodskiy, V. V.0
ORG: none
7
TITIX: Benzene and its derivatives in photosensitized hydrocarbon decompogili2n at
low temperatures
SOURCE: ~~Rozium po, elementarnvm protsessam khimii vysokikh energi*"' Moscow, 1963.
y_-
Eletnentarnyye protsessy khimii vysoki):h energ y (Ele-mentary processes of the chemis-
try of high energies); trudy simpozitnia. Moscow, 1965, 249-253
TOPIC TAGS: hydrogen, alkane, aromatic hydrocart)on, UV irradiation, EPR
ABSTRACT: Initial rates of formation of hexatriene, alkyl radicals and hydrogen were
studied at 770K %s a function of C6H6 and CA concentrations in 3-methylpentane. The
dependence of f;~mation rates of hexat-riene and hydrogen upon temperature was studied
in various solvents using a 2-10-2 moles/1 benzene concentration. All samples were
UV irradiated at 770K. Free radicals were monitored by the EPR technique. The ob-
ject was to elucidate the mechanism ol: the simultaneous formation of alkyl radicals
and hydrogen during UV irradiation of benzene solutions at 770K. The hexatriene
formation and the photosensitization itere not found to be interrelated. The UV irra-
diation of CfiH5CD3 in 3-mthylpentane at 770K results in formation of 94% H2 and 5%
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L 10837-66
ACC NRs AT5023445
HD; hydrogen is the sole product when o-D- and p-D-toluene In 3-methylpentane are
subJected to UV irradiation; H2, HD, and D2 resulted from IN irradiation of CGHSCH3
in 3-methylpentane. A photosensitizel decomposition of hydrocarboom according to the
following scheme
Am
CACHs + RH --,, substituted hexatriene
CJ"+RH(RD)-,CACE6+R+H(D);
H(D)+RHQP-,.HN(HD,[W+R.*
H(D)+C44CHs--Hs(HD)+CJ%M
occurs in the case of toluene. Results obtained with
-( Ws-C 1 Yj.-+ k H + h,*,
system revealed that the rate of fornition Of C6H5CH2 radical Is 10-12 times smaller
than the rate of foruation of alkyl inidicals. It vas condluded that photosensitized
decomposition of hydrocarbons at 770K also occurs in ethylbenzene, cumene, o-, m-,
and p-xylenes, diphenyl- and tripheny.1methane and other compomda. Orig. art. has:
I formula.
SUB CODE: 07/ SUBM DATE: MeblW ORIG IMF: 003/ OTH IMF: 005
jW
:~`!Z'LI,'-!~IVA, 1. '.'.
Arran',,,ement )f Syntactical Cr~::inninicatinns fOr Prepsitinnal-Case Gr-.uz)s.'*
Th,!!3o!; - C,,nf'~-,ronco on Machine 'frqmlqtl:,,z,,,;, Ij-21- Mvy l'?5"-)', Mosco"..,.
;-fl"-~'AYA , ~-. 'I. , PADU-C"ZIA, Ye. V. , -SHELIMOVA, !. I.'. anri -SIfLMILI-LzA, A. L.
~ 6-11 ntta,:~-Ty) of th,,~ 2-ussian Lanlcuage.
IT'rwscs - Conference on 'Machine Trarslations, 15-2-1 may 1)56, Moscow.
SHELIMOVA, I K,
Establishmnt of syntacticil relat.Lom between prepoAtional
groups in the Russian language. Soob.Gtd.mek-h.i av-tora.iriform.
rab. no.2:117-141 261, (I-111RA 15:2)
(Machine translating)
(Russian language)
VOLOTSKAYA, Z.i.,,; 31ii~i,-ILMOIIA, 1.1i', ; A,L,
Some quant-Itative data ve0arding the foi-=; of rouZI3 and w.-rb~;
of the Russian larguaGe, u3ing materials taken fra-P mathematical
texts. Soob. Ctd.i,-,iekh.i a-vtomi.inform.rab, no.2-254-261 161.
('11RA 15:2)
(Prograrrmdrig languages (Electronic computers))
(Russian language)
AC CESSION NR: APWI981 9 S/0279/64/000/001/0180/0183
AUTHOR: Shellmove, L. Ye. (Moscow); Abrikosov. N. Kh. (Moscow); Sessonov, V. 1.
(Moscow)
TITLE: The pseudo-binary systems GeTis-SlTe and GeTe-PbTe
SOURCE: AN SSSR. Izv. Metallurglya I !rornoye delo, no. 1, 1964, 180-183
TOPIC TAGS: germanium tellur ide, silicon telluride, lead telluride, telluride
phase study, telluride phase diagram, pseudo-binary system
ABSTRACT: The authors studied the phase diagrams of the systems GeTe-SiTe and
GeTe-PbTe (see Figs. I & 2 in the Enclosure), as well as solid solutions based on
these compounds. Test specimens spaced at 10 mol.% we're prepared from GeTe, SiTe.
and PbTe. The results of microstructure studies were confirmed by thermal ana-
lysis and showed that GeTe Is the Initially crystallizing phase In alloys with up
to 30 mol % SiTe. Alloys with 30Lmol % SITe are closest to eutectic character
(m.p. 6850, while SITe crystallizes 1-First In trans-eutectic alloys. The solu-
bility of SiTe In GeTe does not vary !;Ignlficantly with temperature, and the GeTe-
based solid solution range Is not laroge. The eutectic state for the system GeTe- -
PbTe occurs at 20 mol.% PbTe, and the melting point Is.91ven as 695C. PbTe cry-
stallins first when Its content is Increased. The PbTe-based solid solution
Card
ACCESSION NR: APWI9819
range I s wi de, and the second phase wa s f i rst noted at 60 mol. % PbTe. The' sub-
stantial solubility of GeTe In PbTe was confirmed by X-ray analysis .(see F19- 3
in the Enclosure). OrIg. art. has: 5. graphs aoid I table.
ASSOCIATION: none
SUBMITTED: o6jun63 DATE ACQ: 31mor64 ENCL: 02
SUB CODE; ML NO REF SOV: 001 OTHER: 005
Card 2A
9
a vo 9. nos SO- 1964 187
SOURCHt Zhurn-al'n6organichaskoy'khi LID
1882
tellurides: tin tollur do
ellurium sys tots 0tin
TOPIC TAGS: tin t
base alloy, alloy homogeneity rell1oh, alloy microstructureg altoy
aLcrohardneass alloy composition
ABSTRAM 'Sn-Te alloys, In ~tha i:omposLtiojr region near,the SuTs'
compound, containing from 49.5 to 51 at% To with a0.92-0*3 at%
I concentration interval wero.vacuisu-notted1ron twice distilled
ty than 0.
i Te and from Sn with an impur 9"s 003Z$ and hono
genized In an argon atmosphere at a temperature . ranging from 700 t 0!1
300C, Study of the alloy microstructure showed the SaTe compounds.,
previously considered a constant coupositLou,coupound with a Itl
atLo of the componentag to be a ~phase with a. d4fecti4o- structure
Car:
Gard
1
_jJ3
L 11333-65
ACCESSION NRI. AP40435704
and varying composition whose nat~row 1omogeneity region in at a
maximum extending from 50.1+0.1 at% to 50.9+0.1 at% ' at 400C,
With increasing Te content, the microhardness of alloys wIthLn the
homogeneity region increases and remains constant in the two-phase
region, As the To content is Increased above the stoichiouetrLep
the alloy lattice constant Increasesp sage, from 6.308�0.002X to
6.294+0.002X for alloys with 50 and 50.8 at% To, annealod at 700c,
An increase in the Sn content above the stoichtou stric.: however,, ha
no effect on the lattice constant*' Alloys.anneated at.* lower tea- I
er 8L o I dependence of, th.w. lattice'
ature have an analogous compo itt n
p
constant; e.g., the constant decre-sies Irom 60324 to 603,02:0.0021
for alloys with 49.9 and 50o9 at%.* Te# respectively, Annealed at
400C. The increase in the lattice constant -and the decrease in the.-
microhardness, with decreasing Annealing temperature isro ascribed. toi
a decreasing number of vacancies In the Oita. Art, hast
6 fi d I table,
puree an
ASSOCIATIONt none.
Card 2 /3
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j~:
L
UR/0078/65/010/005/1200/1205.
ACCESSION NR: AP5012971
rikovoov, N. t~h.;:,Zh anovd, V. V#'
!AUTHOR; Shelimova, L. Ye.- Ab
m
K
MTLE: The Ge - Te
in the region of the compound GeTe
sys emi
SOURCE: Zhurnal neorganicheskoy khimii, v. 10, no. 5,~1965, 1200-1205
~
!TOPIC TAGS: geiinanium telluride, germanium: alloy, tellurium-alloy, phase diagramj
:thermal analy
sis
:ABSTRACT: The region of homogeneity of GeTe: and-the change- in the temperature. of
:transition from the rhombohe~dral to the cubic lattice as' a function of composition
.were investigated in Ge-Te alloys containing from 49 to 52 at. % Te (with incre-
ments of 0.3-0.5 at. % Te). Photoinicrography was used to identify the phases in
~the various alloys. Heating curves were recorded by differential thermal analysis i.
,after the alloys had been annealed for 970 hr at 400OC; distinct endothermic ef-
Ifects ~:orresponding to the phase transition.were displayed,bythese curves. The
'.change in the phase transition temperature irith composition was also determined di-j
:latometrically by measuring the.coefficient.of thermalexpansion as a function of
otemperature. On the basis of the thermal analysis, microstructural-analysis, and 1!
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L 5W62_65 .......
'
ACCESSION NR:
AP5012971
-the Ge-Te system was plotted in the
'thermal expansion data, a phase diagram of
.~region of the GeTe compound (see fig. -1 of -the Enclosure). The region of hamogenel-;:
Ity of the high-temperature germanium telluride modification lies between 50.31 0.11.-4'-
.and 51.5� 0.2 at. % Te (4300C). The regionof homogeneity of the low-temperature:,
modification is somewhat narrower: it rangas from 50.2 * 0. 1 tcF~ 50. 9 t .0. 1 at. t Te,
'The temperature of the polymorphic transkornation is 4300C on the germanium side
.and 3650C on the tellurium side. The eutectic GeTe+ Te has a melti g point of
i:3800C. X-ray diffraction was used to measure the lattice constant of the cubic
'modification of GeTe with the composition at 6000C. Or.ig. art. has: ~,figures,
A
land 4 tables.
V.
!ASSOCIATION: none
ISUBMITTED: 10Apr64 ENCL: 61 SUB CODEv IC 7 D
;NO REF SOV: 001' OTHER: 003
.5
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-
-'
-
'
-'-
-
- ------
-
2
20
6
6
J- 5
55
AdCESSION NR: AP5012971 ENCLOSURE: 01
Ix
AV
Te sy
1. Phase diagram of, G6 stem
i'L the region of the 'compound GeTe
1--single-phase alloys; 2--two-phase
alloys; 3-data of thermal: analysis
fig
.7
.14tv
RON.
C
rd 3/3 Te
Z
a
L 8594-66 F,--l-I'T(m)/FWG(m)/E,4P(b)/FWP(t). IJP(c.) RDW/JD
ACCESSION NR: APS019885 UR/0181/65/007/008/2544/254
'5-~
AUMOR: Novikova, S. I ; Sbelimova, L. Ye. /_10
4q - ----- T I
TIUL: Phase tiansition in ShTe
SOURCE: Fizika tverdogo tela, v. 7, no. 8. 19659 2544-2545
TOPIC TAGS: tin compound, telluride, solid solutiong phase trmsiticn, thermal ex-
pansicn, crystal lattice structure
,ABSTRACr: To check on similarities between SnTe and GeTe, with which it forms a
ocntinuous series of solid solutions,, the authors investigated the thermal expan-
sion of SnTej with particular attention tc temperatures near 100K,, where a poly-
morphic transition was expected. Mw measurements were made with a quartz dila-
tcmeter from 20 to 300K. The samples were prepared fran high pELV tin containing
-3 - 1%
less than 10 % inpurities, and A-1 tellurium. purified by double v
~Two samples were tested containing 50o4 at.i1b, in the form of cylinders 16.07 and
10.86 mm long. A plot of the results is shom in Fig. 1 of the Enclosure. The dip;
at 75K can be related to the expected polyi=phic transiticn in SnTe from the
rhoubohedral low temperature modification 1= the cubic high tmqxrature mDdifica-
tion. Orig. art. has: 1 figure.
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L 8594-66
ACCESSION ENCLOSURE: 01
2P
fg
14
iz
4-
v 4v Sp 8p w Ag w 2,v 26V
Fig. 1. Dependence of the coefficient of thermal expansion
on the temperature.
Measurements under equ!,'librium temperature conditions,
2 dynamic measurements.
jw
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AP?002396_____
SOURCE CO5__ 3C 2109
Es UR/6-3[a/002/012/2f6~/
AUTHORI Sholimova,.L. Ye.; Abrikosov, H. Kh.; Zhdanovap V. V.; Sizov,
ORG: Institute of I-16tallurgy im. A. A. Baykov, Academy of Sciences, SS3a (Institut
metallurgii Akademii nauk SSSR)
Study of the systems PbSe-GeSe and GeSe-GeTe
Neorganicheskiye materialyp v. 2, no. 112,
lead compound, selenide, telluride, germanium compound, phaso transition
ABSTRACT: The phase equilibria and solid solutions in the systems FbSo--j,:Se and
GeSe-CreTe wore studied by thermal, microstructural, x-ray and dilatometric. analyses in,
the 20-6200C range. It was found that the FbSe-GeSe system Is not a qua,;'-binary sec-1
tion of the ternary system Ge-Pb-Se. Tho polythermal section of GeSe-Go7e showed the
existence of a continuous series of solict solutions at temperatures near the solidus.
Phase transformations at low temperature,-: connected with the polymorphism of GeSe and
GeTe were investigated, and the boundaries of solid solutions were d'eternined in both
systems. Orig. art. hasS 7 figures and 2 tables.
SUB COM 07/ SUBM DATEI 25Dac651 ORIG REF1 003/ OTH REF1 007
546-815'231+5LC289'?-31
546.289023i+cM.2891241
89344
4
S/191/61/000,/001/009/015
3 !:Y; '320
~1_1 v f~c~(3 rova G. el i:ia j T ~ A-,j r 1 L L.; 1,L
TITLE% Application of high-fr-?quency heating in manufacturing tubes
from glass-reinforced -)lastics
PERIODICALt Plasticheskiye massy, no, 1, 1961, 35-37
TEXTs This is a report on attempts of accelerating the hardening of tubes
made of glass-reinforced plastics '3RP), which are used as DroDs.. The work
has been carried out by Nauchno-issledovateliskiy institut tokov vysokoy
chastoty im.prof. V. P, Vologdina (Scientific Research Institute of High-
frequency Currents imeni Professor V., P. Vologdin) in cooperation with
Laboratoriya anizotropnykh struktur IKhP AN SSSR (Laboratory of Anisotropic
Structures, Institute of Chemical Physics AS USSR) and Leningradskiy zavod
sloistykh plastikov (Leningrad Plant for Laminated Plastics), The tubes
are manufactured by winding GRP sheets round metal rods which are ther.
heated by electric coils. Hardening is continued in chamber k-;Ins a:
120-1800C. On account of the low thermal diffusivity of the materlal,
heating and hardening take 6-20 hr, depending on the wall thickness of the
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