SUPPLY OF AND DEMAND FOR SULFUR IN THE USSR

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CIA-RDP79-01093A001200050009-2
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April 15, 1957
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orl~elease 4999/09/02 C+A-:F~DP79-04093A001200030009-2 - N? PROVISIONAL INTELLIGENCE REPC)RT :CIA/RR PR-15b _. 15 'April 1957 CENTRAL INTELLIGENCE AGENCY OFFICE OF RESEARCH ANb REPORTS Approved.: Fo,r Release 9' _.C Cr"D CT 3A0~~ Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 This material contains information affecting the National Defense of the United States within the meaning of the espionage laws, Title 18, USC, Secs. 793 and 794, the trans- mi?lion or revelation of which in any manner to an unauthorized person is prohibited by law. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E.-C -R -E -T .PROVISIONAL INTELLIGENCE REPORT SUPPLY OF AND DEMAND FOR SULFUR IN THE USSR CIA~RR PR-156 (ORR Project 20.868) The data and conclusions contained in this report do not necessarily represent the final position of ORR and should be regarded as provisional only and subject to revision. Comments and data which may be available to the user are solicited. Office of Research .and Reports S-E-C-R-E-T Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 FOREWORD This report develops an over-all estimate of the total sulfur produced in all forms in the USSR and a sulfur supply and demand balance for the 1950-55 period. Because more than g0 percent of the sulfur produced annually in the USSR is obtained as a byproduct of the recovery and processing of non- ferrous metal ores; the cleaning of coals; and, possibly, the refining of natural petroleum crude oils, very little direct information on produc- tion is available. The data developed in this report, therefore, are sub- ject to a rather wide range of error. The estimates of production, con- sumption, and reserves are presented with the qualification that they are preliminary and are subject to revision as more complete and more reliable data become available. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Summary I. Introduction 2 II. Raw Material Resources 3 ~ III. Production + A. Major Sources ~ 1. Pyrites 4 2. Elemental Sulfur 9 3. Waste Smelter Gases 1~+ B. Miscellaneous Sources . 15 C . Total Production of Sulfur 15 1. Current 15 1956-60 . cast F 2 16 , ore . 3. Potential 16 D. Unmined Reserves . 18 A. Imports lg B . Exports . lg V. Domestic Demand . 21 VI. Supply and Demand 24 ~ VII. Inputs 2 + VIII. Prices 26 IX. Capabilities, Vulnerabilities, and Intentions 29 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Appendixes Appendix A. Methodology . Appendix B. Gaps in Intelligence . Appendix C. Source References 1. Principal Pyrite Deposits and Mines in the USSR, 1955 2. Estimated Production of Sulfur in the USSR, 1950-55 . 3. Principal Sulfur Deposits and Mines in the USSR, 1855 - ~+. Known Imports of Sulfur into the USSR, 1950-55 5. Known Exports of Sulfur from the USSR, 1951_55 . 6. Estimated Consumption of Sulfur Products in the USSR, 1950-55 123 Estimated Consumption of Sulfuric Acid in the USSR, 1950-55 j23 8. Estimated Supply and Demand Balance of Sulfur in the USSR, 1950-55 g. Internal Prices for Elemental Sulfur. in the USSR, 1950 10. Estimated Production of Copper in the USSR, 1950-55 . 11. Estimated Production of Copper Ore in the Ural Mountains in the USSR, 1950-55 . Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500 ,9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Pa e 12. Estimated Production of Pyrites in the Ural Mountains in the USSR, 1950-55 3~+ 13. Estimated Production of Pyrites at Alaverdi in the USSR, 1950-55 35 1~+. Total Amount of Sulfur Recovered from Pyrites and Pyrrhotite in the USSR, lg5o-55 35 15. Amount of Sulfur Produced from Waste Smelter Gases Used in the Manufacture of Sulfuric Acid in the USSR, 1853 37 16. Estimated Amount of Pyrites Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR, 1832-~+0 38 17. Estimated Amount of Pyrites Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR, lg5o-55 39 18. Estimated Amount of Sulfur Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR, 1950-55 3g lg: Reserves of Unmined Elemental Sulfur in the USSR, 1 g~+8 ~+2 20. Reported Productian of Selected Commodities in the USSR as Percentage of Production of the Preceding Year, 1951-55 1+g Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500a 9-2 Following g age Figure 1. USSR: Principal Sulfur and Pyrite Mines and Deposits, 1955 (Map) 8 Figure 2. USSR: Estimated Consumption of Sulflzr, 1950-55 (Chart) 2~+ Figure 3. USSR: Estimated Consumption of Sulfuric Acid, 1950-55 (Chart) 2~+ Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 CTA~RR PR-156 S-E-C-R-E-T (ORR Project 20.868) SUPPLY OF AND DEMAND FOR SULFUR TN THE USSR Sun~rnary Sulfur is one of the basic raw materials in an industrial economy. Sulfur and its major derivative, sulfuric acid, are key materials in the chemical industry and are used either directly or indirectly in many other industries. The supply of sulfur in -the USSR has been, and will continue to be, adequate for all industrial demands. The major economic signifi- cance of sulfur in the Soviet industrial structure lies in the fact that more than 90 percent of the total supply of sulfur must be obtained by costly byproduct recovery processes from nonferrous ores, coals, and smelter gases. The USSR has no large, accessible deposits of high-purity elemental sulfur like those in the US, where more than 80 percent of 1955 production came from easily recoverable deposits of 99 percent pure ele- mental sulfur. Production of sulfur in the USSR is estimated to have been 1,767,000 metric tons~-~ in 1955? Of this total, 1,414,000 tons were obtained from pyrites and pyrrhotite in nonferrous sulfide ores, 108,000 tons from pyrites recovered in the cleaning of coals, 105,000 tons from smelter gases, and 140,000 tons from deposits of low-purity elemental sulfur. The total 1955 Soviet production of sulfur was about 12 percent of the estimated 1955 world production of 14,375,000 tons. US production of sulfur in 1955, about 7 million tons, constituted almost 50 percent of world production. Proved and probable Soviet reserves of the kinds of sulfur raw materials now being exploited in the USSR are estimated to be 1,442 mil- lion tons. Almost 96 percent of this total is made up of pyrites in coal beds, and only 2 percent is elemental sulfur. US reserves of ele- mental sulfur are estimated to be from 50 million to 100 million tons, and US reserves of sulfur contained in pyrites, other mineral sulfides, anhydrite, and gypsum have not been estimated. ~ The estimates and conclusions contained in this report represent the best judgment of ORR as of 1 November 1956. ~~ Tonnages throughout this report are given in metric tons. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 The largest sulfur-producing area in the USSR is the copper pyrite belt of the Ural Mountains, which accounted for almost 80 percent of the total Soviet production of sulfur in 1955? The largest potential area. of sulfur production is the Donets coal basin. The Donets Basin cont 1.ns more than 1 billion tons of sulfur reserves in pyrites associated wit the coals. Other potential sources of sulfur in the USSR are the vast deposits of crude oil and natural gas in the Baku and Ural-Volga area. The Soviet Sixth Five Year Plan (1956-60) calls for increased pro Lion of sulfur and sulfuric acid and stresses greater recovery of sul from the gases of nonferrous metal ore smelters and from crude oil an natural gas. During the period of the Plan the increase in the produ tion of sulfur probably will keep pace with tYie planned 65-percent in crease in over-all industrial production. I. Introduction. uc- ur ~- Sulfur and its derivatives are essential to the industrial economy of the USSR and to those of all other industrialized countries. Sulfur ~.s necessary for the production of food, fertilizers, clothing, medicine , and nearly every industrial product, including military equipment. The production of explosives, weapons, tires, fuels, guided missiles,; ships, rail and motor transport equipment, and many other end items ojf military supply depends, in part, on derivatives of sulfur. I In the USSR, copper and iron pyrites always have been the major s'urces of sulfur. In 1938, pyrites accounted for about 65 percent of the 22 ,700 tons of sulfur produced. ~ Mined elemental sulfur and byproduct sul ~zr recovered from waste smelter gases and the refining of petroleum prov,'de the remainder of the supply of sulfur.~'~ Production of sulfur increased throughout the 1930's but declined sharply during World War II because of the disruption or capture of 5 percent of the Soviet sulfuric acid industry, the chief consumer of For serially numbered source references, see Appendix C. ~-~ Estimates referring to sulfur source materials throughout this re~ort are stated in terms of sulfur content. I Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 sulfur. ~ Sulfur or pyrites were not shipped to the USSR from the West during the war. The ensuing shortage of sulfur and sulfur products was partially alleviated by the shipment of large quantities of finished products such as explosives and steel, which require sulfur in their production. II. Raw Material Resources. The USSR has an almost inexhaustible supply of sulfur-bearing ma- terials. These include elemental sulfur; pyrites, a natural sulfide of iron or copper; pyrrhotite, an iron sulfide; gypsum, a hydrated calcium sulfate; glauber's salt, a hydrated sodium sulfate; coke, generator, and other gases containing hydrogen sulfide; the sulfur content of petroleum; and combined sulfur in the copper, lead, and zinc sulfide ores. ~ Not all of these sources have been utilized in the USSR for the recovery of sulfur . Elemental sulfur deposits vary in size from small to relatively large, low-grade, surface or near-surface deposits located for the most part in the middle Volga area and Soviet Central Asia. No domes of the Texas type have been located in the USSR. Elemental sulfur deposits account for only a small part of the total sulfur materials recovered annually in the USSR. ~ In the US, mined elemental sulfur accounts for 80 to 85 percent of the production of sulfur materials. ~ Elemental sulfur deposits in the US are associated with salt domes in Texas and Louisiana, and the mined product has a sulfur content of 99.5 percent. ~ Pyrites account for only 5 or 6 percent of the sulfur materials recovered an- nually in the US. Pyrites are by far the largest and most important source of sulfur in the USSR. Pyrites are obtained from mines operated for the recovery of pyrites alone and from copper, lead, and zinc ore- mines from which the pyrites are recovered as a byproduct of the dressing of these non- ferrous metal ores. Iron pyrites are recovered at coal mines in the cleaning of the coal. A large deposit of pyrrhotite located in the Kola Peninsula is being utilized as a source of sulfur for a sulfuric acid plant at Monchegorsk. 10 Experiments on the utilization of gypsum and glauber's salt as sources of sulfur have been successfully completed in the- USSR. It is not likely, however, that commercial production of sulfur from Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 i Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 l gypsum and glauber's salt, which involves a more complicated and cost ier operation, will begin in the near future. 11 Although the methods o recovery of the sulfur content from coke, generator, and other waste aces containing hydrogen sulfide are known in the USSR, there is little ev'dence that utilization of these sources accounts for much of the total sulf~Zr. produced annually. 12 ~ III. Production. A. Major Sources. 1. Pyrites. a. Distribution and Characteristics of Major Deposits. The principal pyrite deposits are in the Ural Mountai~s area, the Kola Peninsula, the Transcaucasus, Kazakhstan, Central Asia East Siberia, and the Soviet Far East. 13 Most of these deposits ar mined primarily for copper, lead, or zinc, and pyrites are the princi al byproduct. The only known exception is the Zyuzelskiy pyrite mine in the Polevskoy district of the Ural Mountain area, which is mined for pyrites alone. The nine copper pyrite mining areas in the Urals* whi r~ produce copper and zinc as the primary product are the largest produc rs of sulfur in bhe USSR. 14 Other important pyrite sources are the co per pyrite deposits at Alaverdi and Kafan in the Caucasus and at Almalyk n. Uzbek SSR and the lead-zinc sulfide deposits at Salair in West Siberi and in the Lake Baikal and Tetyukhe-Pristan regions of East Siberia. 5 Although much of the coal in the USSR has a relatively high sulfur co - tent in the form of pyrites, the recovery of pyrites from coal has be n reported only from the Moscow and Donets Basins. 16 The principal p rite deposits and mines in the USSR in 1955 are given in Table l~ and in Figure 1. ~ b. Methods and Quantities of Production. Pyrites, the major source of sulf~zr in the USSR, are recovered in a byproduct operation, and little direct information one The first nine areas listed in Table 1, p. 5. Table 1 follows on p. 5. Following p. 8. Continued on p. 9. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Principal Pyrite Deposits and Mines in the USSR 1955 it o oreD Mi Location Coordinates Name of Mine Remarks ep s ne of North East pyrites, Copper Degtyarka 17 56?44' 60?05' Degtyarka Single pyrite lens located 18 , and zinc pyrites Copper Blyava 18 51?24' 57?45' Blyava kilometers (km) southeast Revda. Second to Degtyarka in magni- , pyrites, Copper Kirovgrad (Kalata) 19 57?27' 60?03' Levikha tude of reserves. Consists of 12 separate , and zinc Karpushikha lenses. One sulfur pyrite Copper and pyrites Krasnoural'sk 20 58?20' 60?03' Kalata Oblavenskiy Belorechikha Nevyyansk Shaitunskiy Novo-Levinskiy lens, 1 polymetallic lens. Consists of 4 lenses. Located 12 km south of Kirov- grad. Krasnogvardeyskiy Spasso-Sernia-Chalchedonia Andreyevskiy Kahan Mountain Yasvinskiy Vinnovskiy Sma11 deposit. One small lens. Approved For Release .19.99/09/02 :CIA-RDP~9,-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Principal Pyrite Deposits and Mines in the USSR 1955 (Continued) of Mine or Deposit Location Coordin ates Name of Mine Remarks North East Copper, pyrites, Karabash 21 55?28' 60?15' Voroshilovskiy Consists of 2 parallel lenses. and zinc Dzerzhinskiy Ore body located 1 km north Copper, pyrites, Nizhniy Tagil (San 57?54' 60?00' Stalinskiy Pervomayskiy Severo-Pervomayskiy Pionerskiy Yugo-Kuznechinskiy Severo-Kuznechinskiy Third International of Voroshilovskiy. Most important mine in the and zinc Donato) 22 district. Pyrites Polevskoy 23 56?30' 60?10' Dinamitnia 071ihovka Zyuzelskiy (Zaleski) 0.5 km northeast of Third International Wor:~ed solely for sulfur Pyrites Baymak 24 52?36' S8?22' Bakr-Uzyick (Bakrusak) pyrites in 1935? -6 Sibay (Cebi) Buribay Yuluk Gumerovskiy Turbinskiy - Located 30 km northwest of Baymak. New deposit in 1935? Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Principal Pyrite Deposits and Mines in the USSR 1955 (Continued} of Mine or~Deposit Location Coordinates Name of Mine Remarks North East Copper and pyrites Verkhnyaya Pyshma 25 56?55' 60 37' Aleksandrovskiy Pokrovskiy Srednic Mariyenskiy Kvanovskiy Pyrites and Karelo-Finskaya ASSR 26 0 0 pyrrhotite Parandovo 6~+ 00` 34 19' Parandovo Developed to form basis of acid plants for use with local phosphate rock. Pyrites and copper Pyrites, lead, Monchegorsk ~ Transcaucasus 67?5~+' 32?58' Monchegorsk Sulfuric acid plant associated with copper refining opera- tions. copper, and zinc Boron 28 ~+2?47' ~+3?59' Buron Mine located in the Ardon Valley near Sadon. Alaverdi 29 41 06' ~+~+?3g' Alaverdi Copper pyrites. Kafan 30 39?12' ~+6?26` Kafan Copper pyrites. Mizur 31/ 42?52' 44?05' Mizur Lead-zinc sulfides. -7- Approved For Release 1999/09/02 :CIA-RDP79-01A93A001200050009-2- Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Principal Pyrite Deposits and Mines in the USSR 1955 Continued) of Mine or Deposit Location Coordi nates Name of Mine Remarks North East Pyrites and copper Kazakhstan 32 Kounradskiy 47?00' 74?59' Kounradskiy Copper pyrites. Dzhezkazgan 47?51' 67?14' Dzhezkazgan Achisay 43?35' 68?53' Achisay Lead-zinc sulfides. Leninogorsk 50?22' 83022' Lead-zinc sulfides. Zyryanovsk 49?43' 84?20 ? Lead-zinc sulfides. ' Dzhetygara 33 52?ll' 61 12 Pyrites. Pyrites and copper Central Asia Almalyk 40?49' 6g?38' Almalyk Ores processed at nearby metal Kansay 40?29' 69?44' Kansay plants. Lead-zinc sulfides. Lead-zinc West Siberia 35 Salair 54?13' 85?47' Salair Lead-zinc sulfides East Siberia 36 Lake Baikal area 54000' 109?00' Lead-zinc sulfides. Far East 37 Tetyukhe-Pristan 44?22' 135?51' Located near Tetyukhe-Pristan, lead-zinc sulfide. Sulfur, pyrites Donets Coal Basin 38 48?32' 38035' Other sources of sulfur are Mosetra Coal Basin 54?40' 39?32' the "pyritee brasses" in the main coal basins. 3 to 4 per- cent sulfUx' reported in re- coverable pyrites in the Do- nets Basin. 2 to 6 percent sulfur reported in pyrites in the Moscow Basin. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 SECRET 20 40 80 120 160 180 t ` t :, r -~~ `+ o J, / ~ ~? ~ ~''' ~.. OMo hegorsk j~ i ~ ~ ,, i ~' r' o / I _ r Paran~? ?~ i ~ / a / . ~ V t ~ ? k ~+~~. ~ S / ?~ COAL BAS a \ / n .f '?~ \ \ ~ ' ~ \ ~ ~+ F'Y y9 S l / r ` /, ~ ~ G~ 1 1 / / _ qq_7r i '_ _ - ._ .._ .- ~ Lr.~Q pON c " D4 Pefro vlovsk! \ 4r \ mY okur L Krasnou al's %~ - k ~ t9a y ~ i ,~ 4~ ~0~ Sevem-Kuril'sk'yy 7 {/ 'no zhniy gil S IekseYevka / (fin-DO to) ~ ^-y pN w. ~r6i' Karabasfr~Q Kiro (Nalata) ~i 40 Bur ~ Izur Yerkhny Pyshma mLT + ~ r D t k ~ ~" eg yar a ,: ~ no Metlnog V Ketrisi n~M K ur yev (Blyava) ~ ~~zhetyBara Pole~ko \ I l ~ e~ A~ ~YAl~ver h~". ;. ~?['Yl tea, t U )) t $alair 0 TRANSBAIKAL # ~ Lake `. ~ ~ ? L.. 111 ~ LA E B 9aikal \` \4 ~ y ~L~ i/ fib' `REA \ .~ Py ~'7 f.~ ,r Nat. QDzhezkazBan (cpyPN MOUNTgyN 1~ ~ \\ Leni o ""~ ~J ~.~,. JJ d ~ 40 rasnwo sk ( y : -~?- Tetyukhe a 6 o,f~~ ZYryano~ "?.., yS') \..i---~.. 11 ?~ ~ ^ KOUnrad3 ~ r~lq r ?DdN / M~U 1 h r \ NJ'gINS nyy Zavod ~ Achisay O ~-~,~ O ? ? \ ~d ~5 ' ~k PI lyla. aea ---. ffi ~FrYunZe ~'~ ~SJJ 5.~ A A Gaurd~k~ nay ~Changyrtash ~;~~ Q P A 1? Shor- J ( Kushka ~ i1 Boundaries are not n~ssarily those ~ ; recognized by the U.S. Government. :.-~?..t / so ea loo lzo USSR: PRINCIPAL SULFUR AND PYRITE MINES AND DEPOSITS 1955 ~ Sulfur mineldeposit 0 250 500 loon O Pyrite mine/ deposit -^- ussR boundary Soamoe miles s ..~ ~-~ Economic Region boundary 0 250 500 1000 Kilometers SECRET 25431 5-56 SECRET Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 production is available. 39 In some mines the pyrites are separated from the ore and shipped to chemical plants for sulfur recovery. 40 In others, some of the pyrites are shipped to chemical plants, and the remainder is included with the ore shipped to the smelters. When the pyrites are shipped to the smelters with the ore, the sulfur content of the pyrites -- and the relatively small quantity of combined sulfur in the sulfide ores -- are re- covered from the waste smelter gases in the form of sulfur dioxide. The dioxide is converted to, and reported as, sulfuric acid or as elemental sulfur. 41 The iron pyrites produced at coal mines represent pyrites re- covered in the cleaning of coals and utilized by the sulfur industry or the sulfuric acid industry. ~+2 Estimated production of sulfur in the USSR in 1950-55 is shown in Table 2.~- 2. Elemental Sulfur. a. Distribution and Characteristics of Major Deposits. The elemental sulf~,ir deposits in the USSR are of medium and low grades. The sulfur occurs for the most part as thin seams of impregnations in limestone, sandstone, and gypsum. Although some of the deposits are relatively large, the sulfur content averages only 2~+ per- cent. Sulfur of a 99.5-percent purity comes from domes of the Texas type in the US. Such domes are not known to exist in the USSR. ~+3 The major deposits of elemental sulfur in the USSR are in the middle Volga area and in Central Asia. ~+~+ Other smaller opera- ting mines are the Chokor-Koyash in the Ukraine and the Changyrtash mine in Kirgiz SSR. ~+5 Deposits of sulftizr in East Siberia and the Soviet Far East have been reported, but exploitation probably has not begun. ~+6 Principal sulfur deposits and mines in the USSR in 1955 are shown in Table 3-*-~- and in Figure 1.~~~ b. Methods and Quantities of Production. All elemental sulfur deposits in the USSR are of law grade and contain many impurities, and all mined sulfur ore must be beneficiated~~~~ ~ Table 2 follows on p. 10. -~-~ Table 3 follows on p. 11. ~~~ Following p. 12. -~~-~~ Continued on p. 13. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release.1999/09/02 :CIA-RDP79-01093A001200050009-2 Estimated Production of Sulfur in the USSR 1950-55 Raw Material Source Production (Thousand Metric Tons) Percent of Total Production (Thousand Metric Tons) Percent of Total Production (Thousand Metric Tons) Percent of Total Production (Thousand Metric Tons) Percent of Total Production (Thousand Metric Tons) Percent of Total Production (Thousand Metric Tons} Percent of Total Nonferrous ores Pyrites and pyrrhotite q70 77 1,210 80 1,500 83 1,316 S1 1,237 79 1,414 80 Waste smelter gases 105 8 105 7 105 6 105 6 105 7 105 6 subtotal 1,075 85 1,315 87 1,605 89 1,421 87 1,342 86 1,519 86 Pyrites in coal ~ 83 7 89 6 92 5 97 6 101 6 108 6 Mined elemental sulfur 100 a1 8 loo J 7 loo J 6 110 ~ 7 124 8 140 8 Total 1,258 1,504 1,797 1,628 1,567 1,767 a. For the methodology used in the derivation of undocumented estimates, see Appendix A. b. Production estimates are given in terms of recoverable sulfur content of the pyrites in copper, lead, and zinc ores. c. Production estimates are given in terms of recoverable sulfur content of pyrites recovered at coal cleaning plants and shipped to sulfuric acid plants. f. g? 50 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Table 3 Principal Su_1f'ur Deposits and Mines in the USSR 1955 Volga Area 51 Vodino 53?22' N -, 50?26' E Two productive horizons Alekseyevka 53?15' N - 50025' E in Permian limestone ores range 7 to 20 per- cent sulfur. Ore averages about 11 per- cent sulfur. South (Ukrainian SSR and Moldavian SSR~ 52 Chokur-Koyash ~+5?03' N - 36?12' E Georgian SSR 53 Ketrisi 42?36' N - ~4?2~-' E Abano ~+2?12' N - ~+3?1+5' E Central Asia 5~+ 37?50' N - 66?0~+' E Fifteen percent sulfur ore is mined through adits and treated in an ore-dressing plant at the mine. Deposits located on the north slope of Gora Kazbeck along the Georgian military high- way. Ketrisi was worked from 1896 to 191+. Mineralized area extends to Shirabad: largest single sulfur deposit in the USSR. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Principal Sulfur Deposits and Mines in the USSR 1955 (Continued) Central Asia (Continued) 7 Shikh 38?46' N - 63?56' E Small, high-grade de osit averaging 50 percen sulfur. Krasnovodsk 40000' N - 53?00' E on the east coast ofithe Caspian Sea. Darvaza ~-0?10' N - 58?20' E In the Kara Kum dese~i;. Sernyy Zavod 39?59` N - 58?52' E Deposit located abou~ 140 km north of Ashkhabad in the Ka~a Kum desert. Frunze 42054' N - 74036' E Sulfur mined within , 25 to 30 km of Frunze. Located in the Sosa~ir Mountains. II Changyrtash 55 40?50' N - 72?50' E A high-grade deposit in the Fergana Basin. Kushka 35?16' N - 62?24' E Near the Afghanistan border. Shor-Su ~ 40017' N - 70050' E Outcrops of bitumen- bearing limestone th high sulfur content deposit averages 15 -t;o 24 percent sulfur. ~ Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 II Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Table 3 Principal Sulfur Deposits and Mines in the USSR 1955 (Continued) Kazakhstan Gur'yev East Siberia 58 ~+7?07' N - 51?53' E Sulfur deposit and springs. Up to 19+0 had produced ~+, 000 tons of sulfur . (Altay) Sayan Moun- tains 52?~+5' N - 96?00' E Deposits of sulfur known but not explored. Transbaykal Far East 51?58' N - 116?35' E Deposits of sulfur known but exploration not completed. Severo-Kuri1'sk ~ Kamchatka 50?~+2' N - 156?13' E Mine located 1.5 km south of Severo-Kuril'sk. Peninsula 60 Petropavlovsk- 56?00' N - 160?00' E Sulfur in volcanic areas. Kamchatskiy 61 53?0l' N - 158?39' E Natural sulfur discovered in the vicinity of Avachinskaya. before marketing. 62 The mines are either relatively small open pits or shallow underground mines. 63 Totals of production by mines are not available. Alekseyevka and Vodino in the Volga area and Gaurdak, Darvaza, Sernyy Zavod, and Shor-Su in Soviet Central Asia account for Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 I Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C19-2 the bulk of the annual production of refined sulfur. 6~+ These minis have processing plants adjacent to the mines. The annual capacity ~f the refinery in the Gaurdak mining area, the largest single sulfur- mining area in the USSR, has. been estimated at 50,000 tons. 65 i Just before World War II the Sernyy Zavod and Darva~a mines in the Kara Kum desert accounted for about one-third of the total Soviet production of sulfur. After World War II, new deposits were' discovered in the Darvaza area, and a large flotation plant was in- stalled there. 66 Production and processing costs are relatively igh because of the lack of basic transportation facilities, and supplie , equipment, and the refined sulfur are moved in and out by air trans port. 3 The mining of elemental sulfur in the USSR is a rel - tively simple operation and requires a minimum of equipment. 68 e processing of the mined material is essentially the same in all of he large plants. It consists of primary crushing of the ore, mechanic screening, flotation of the screened product to obtain a concentrat , charging of the concentrate to an autoclave furnace for melting, au pouring the molten sulfur into molds. Some sulfur is shipped to co - sumers in the molded form, and the remainder is ground to a fine po der before shipment. 69 The total estimated annual production of elem ntal sulfur in 1950-55 is shown in Table 2.~- In addition to the production of sulfur estimated i Table 2, possibly 50,000 tons of byproduct sulfur may be recovered annually from the processing of natural crude petroleum in the Ural Volga area. Sulfur derived from petroleum has not been included 'n the production estimate, however, because there is no evidence that the USSR actually practices such counnercial recovery. 3. Waste Smelter Gases. Soviet copper, lead, and zinc sulfide ores -- such as chalcocite, chalcopyrite, galena, and sphalerite -- contain quantit'es of sulfur. Because sulfur is a harmful impurity in finished metal, this sulfur must be removed in the processing of these ores. The ~ sulfur is in the molecular structure of the ore crystals, and it ca~iriot be recovered by mechanical separation but must be driven off as a g~s. -~ P. 10, above. -~~- For the derivation of this estimate, see Appendix A. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 The waste gases from the smelter pass through a precipitation unit where the sulfur content is recovered in the form of a sulfurous anhydride (S02), which is reduced to either elemental sulfur or sulfuric acid. B. Miscellaneous Sources. In an effort to create a sulfur industry, the USSR listed as early as 1933 all domestic sources of sulfur and possible methods of recovery. 70 Commercial production from some of these sources, however, has not yet been reported. In 1953 there were published some details of a Soviet method for the production of elemental sulfur and sulfuric acid from anhydrite and gypsum using anhydrite or gypsum and alumina in the form of kaolin. Commercial production of sulfur or sulfuric acid by this method has not yet been reported. Several processes for the recovery of sulfur compounds from combustion gases are also under investigation in the USSR. 72 The large Kara-Bogaz-Gol sulfate combine, which recovers glauber's salt (sodium sulfate), is another excellent source of sulfur. Although much has been reported on the quantity of sulfur available or recovered, the latest reports show that the Central Committee of the Turkmen Co~nunist Party and the Council of Ministers of Turkmen SSR have not yet arrived at the final solution to the problem, and indus- trial production of sulfur from sulfate raw materials is to be started by 1957. ~ The recovery of sulfur as sulfuric acid from the waste products of the manufacture of phosphate fertilizer is also being in- vestigated in the USSR. Although pyrites have been recovered in coal-cleaning opera- tions in the USSR for about 25 years, efforts were still being made in 1953 to perfect a chemical gravity method for recovering ash and sulfur from coking coal. ~ The chemical gravity method is said to improve the coal product and also to increase recovery of pyrites and sulfur. C. Total Production of Sulfur. 1. Current. As shown in Table 2,~ about 92 to 9~+ percent of the total sulfur produced in the USSR is recovered as a byproduct in the dressing and smelting of nonferrous sulfide ores and the cleaning of ~' P. 10, aT~ove . - 15 - Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009~2 coals. Mined elemental sulfur accounts for the remaining small percen- age of the total annual production of sulfur. Although a recent repor indicates that greater emphasis is to be placed on increasing the annul production of mined elemental sulfur, 76 it is probable that pyrites ; will continue to be the mayor source of sulfur in the USSR during the Sixth Five Year Plan period. 2. Forecast, 1956-60. Because of the many industrial uses of sulfur, the planned 65-percent increase in industrial production during the Sixth Five Year Plan 77 will necessitate a similar increase in the production of Bull fur. By 1960 this increase will be more than adequate for planned consumption, even if a 91-percent increase in the production of sulfurjic acid takes place as planned. 78 Estimates of the Soviet production c~f sulfur in 1956-60 are as follows-: Year Quantity (Thousand Metric Tons) 1956 1,990 1957 2,200 1958 2,550 1959 2,690 1960 2, 915 3. Potential. In addition to the estimated production of sulfur in the USSR in 1950-55 as shown in Table 2,** it is possible for the USSR tcj increase production of sulfur considerably by enlarging the present i type of equipment for the recovery of byproduct sulfur at coal-cleaning plants and petroleum refineries. Annual sulfur recovery from the Donets and Moscow coal basins has been estimated at only 83,000 to 108,000 tons for 1950-55j but the potential from this source is tremendous. The sulfur contend of the coals in these 2 basins, in the form of pyrites, is estimated; at 1.5 to 6 percent, with an average of 2 percent recoverable. ~ , ~ For derivation of these estimates, see Appendix A. ~~ P. 10, above. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050p09-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 From these fields the total production of coal in 1955 was 168.5 million tons, 80 from which 3.37 million tons of sulfur could have been re- covered. A large part of this potential could have been recovered by better utilization of the present equipment at coal-cleaning plants. A Soviet source reported in 1955 that if electric power stations which burn coal mined in the Moscow region were equipped with installations for sulfur recovery, about 500,000 tons of sulfur dioxide, 200,000 tons of elemental sulfur, could be recovered annually. 81 In the US, on the other hand, production of sulfur from pyrites recovered at coal-cleaning plants is negligible, principally because of the abundant supply of low-cost elemental sulfur. 82 Some sulfur has been recovered from Midwestern coalfields, but the cost of a sulfuric acid plant utilizing pyrites in the US is about twice as much as one of the same production capacity using crude elemental sulf~zr. Consequently, production of sulfur from such material in the US proba- bly will remain small. 83 The potential tonnage of sulfur recoverable from crude pet- roleum stocks in the USSR in 1955 has been estimated at 737,000 tons from the Ural-Volga fields. Although high-sulfur crude oils are also produced in the Central Asian and Sakhalin Island fields, the quantities are small and are not considered in this report. 8~+ The potential of 737,000 tons is based on an average of 2.2 percent, by weight, of sulfur in the natural crude petroleum of the Ural-Volga fields 85 and a 1955 production of 33.5 million tons of crude petroleum. 86 Adding the potential recoverable sulfur from pyrites in coal beds and natural crude petroleum stock, the total additional potential sulfur available in the USSR annually is about 3.9 million tons, which is more than twice as much as the 1955 estimated total production of sulfur. The desulfurization of natural petroleum crude oils in the US, for example, has been practiced for many years. The recovery of this sulfur content, however, did not start until the past-World War II period and was not really significant until 1950. In 1953 the pet- roleum refineries in the US recovered 81,298 tons of hydrogen sulfide containing 7~+,96~+ tons of sulfur. This tonnage is estimated to have increased markedly in 1955 because of the generation of hydrogen sulfide gas in the new catalytic hydrogenation processes for desulfurization of naphtha stocks installed in 11 US refineries. 87 - 17 - Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 1 { 1 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 I S-E-C-R-E-T I The USSR has an almost unlimited supply of proved and probable unmined reserves of sulfur raw materials. At the current rate of p~o- duction and consumption, the supply is adequate for many years of operation. Iron pyrites (coal brasses) found in coal beds, as shown below, contain by far the largest share of the total known unmined reserves. 88 Elemental sulfur is the next largest reserve. 89 ~he 9 million tons of sulfur in pyrites must be considered as a minimut~, since it represents an estimate from only the Ural Mountain area. jzn addition, there are reserves of pyrites in the Caucasus, at Noril's , and in the Kola Peninsula, as evidenced by sulfuric acid plants in hese areas which utilize pyrites as the raw material, 90 but these res rues are believed to be small. The reserves of unmined elemental sulfur in the USSR are la~r,ge, but the material is of relatively low grade. In addition, the dep sits vary in sulfur content from 11 to 50 percent, with an average of 2 per- cent for all deposits. 91 Estimates of the known exploitable unm' ed sulfur reserves in the USSR in 1955 are as follows: Type of Reserve Million Metric Tons Petroleum 17 Pyrites- 9 Pyrites in coal beds 1,382 Elemental sulfur deposits 34 IV. Trade. Soviet trade in sulfur in 1950-55 was very small and was made t~p largely of shipments of pyrites within the Sino-Soviet Bloc. Sul r from pyrites accounted for 55 percent of total imports and 7~+ perc nt of exports for 1950-55. The total tonnage of sulfur involved in t ade did not exceed 2.5 percent of the total production in any one year. ~ For derivation of these estimates, see Appendix A. ~~ This figure is a minimum and is not a total estimate of sulfur from this source. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500 9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Trade in sulfuric acid during this period was also very small anal fol- lowed essentially the same pattern as sulfur. A. Imports. Estimated annual imports of sulfur by the USSR in 1950-55 were so small that they may be classed as negligible. The peak year was 1951, when 22,781 tons were known to have been received, a total equal to about 1.5 percent of the total Soviet production of sulfur in that year. In 1952-54, annual imports totaled only a few thousand tons. With the exception of 1,000 tons received from Iran in 1953-5+, supplies were received only from Sino-Soviet Bloc countries. Sulfur received from Communist China in 1954 was shipped to the Oji paper mill on Sakhalin Island. 92 Reports indicate that the USSR requested shipments of 10,000 tons of sulfur from Communist China in 1954, but evidence of shipment of the total quantity is not available. The only other known Bloc supplier of sulfur to .the USSR in the period was Bulgaria, which shipped small tonnages of pyrites in 1950-52 and 1954? Sulfur suppliers outside the Bloc countries were Norway, Yugo- slavia, Tran, and Afghanistan. Imports from Norway were received in 1950, and there is no evidence of imports of pyrites by the USSR from Norway since that year. Imports from Yugoslavia and Afghanistan were reported in 1954 and 1955 and from Iran in 1953-55, in conformance with trade agreements between the USSR and these countries. ~ The known imports of sulfur into the USSR in 1950-55 are shown in Table 4.~ B. Exports. Exports of sulfur from the USSR in 1951-55 were also small and were confined almost entirely to shipments to other Sino-Soviet Bloc countries. The peak year was 1952, when 37,655 tans of sulfur are known to have been exported. Of this total, 32,378 tons represent the sul- fur content of 107,928 tons of pyrites containing 30 percent sulfur shipped to Hungary and Czechoslovakia. These two Satellites have large sulfuric acid industries which use pyrites as raw materials. 94 It is therefore believed that the sulfuric acid industries of the European Satellites received the bulk of the annual Soviet exports of sulfur. Small shipments of elemental sulfur to Rumania were reported in 1952 and 1954-55. This sulfur probably was utilized in the manufacture of rubber and insecticides. ~- Table follows on p. 20. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Table ~+ Known Imports of Sulfur into the USSR 1950-55 Me tric Tons Exporting Country 1950 1951 1952 1953 1954 1 55 East Germany 16,230 ~ 3sOOO ~/ 1,544 Bulgaria 2,740 ~ 6,505 ~ 4,250 ~/ 238 Poland 481 46 Co-n*m~nist China 3~ 01~ Yugoslavia 9,000 Afghanistan Norway 9, 833 200 s~ Iran 1,000 ~ 1,000 ~ 1,000 n/ Total 13, 054 22, 781 7, 250 2, 541+ ~.,1E$1F 10,000 a. Unless otherwise specified, figures represent elemental sulfur. b. c. d. e. f. g? h. i. ~? k. 1. m. n. Represents a total of 9,134 tons of pyrites, estimated to contain 30 percent sulfur. Represents a total of 21,685 tons of pyrites, estimated to contain 30 percent sulfur. Represents a total of 11+,166 tons of pyrites, estimated to contain 30 percent sulfur. Represents a total of 792 tons of pyrites, estimated to contain. 30 percent sulfur. resents 30,000 tons of pyrites, estimated to contain 30 percent sulfur. 98 Re resents 2 6 tons of P 3 ,77 pyrites, estimated to contain 30 percent sulfur. 100 101 102 10 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 The export by rail of 5,000 tons of sulfur to Finland in 1955 represents the culmination of trade discussions that began in 1953. 10~+ The sulfur is reported to smell of petroleum, and it may have been recovered in the processing of crude oil from the Ural-Volga fields. 10 The known exports of sulfur from the USSR in 1951-55 are shown in Table 5.~ V. Domestic Demand. Sulfur is one of the most important basic raw materials used in the chemical industry of the USSR. A Soviet author states the following concerning the uses of sulfur 106 Sulfur bearing ores are valuable raw materials for pro- ducing elemental sulfur, which is partially used for the production of relatively concentrated sulfur gases (used for example in the cellulose industry) and sulfuric acid. Sulfur is also used as the starting material for the production of carbon disulfide, sulfur chloride, the vulcanization of rubber, the production of several types of synthetic rubber, for the production of matches, luminous compounds, and other materials. Sulfur is also used as an insectofungicide, especially for the protection of grapes and cotton. The estimated consumption of sulfur in the USSR in 1950-55 by type of product is shown in Table 6*~ and Figure 2.~*~- Figure 2 shows graphically that consumption of sulfur in the USSR increased steadily from 1950 through 1955? Sul-furic acid accounted for about 7~+ percent of the total amount of sulfur consumed annually. The next largest single consumer is the sulfite pulp industry, which accounts for about 10 percent of the annual consumption. Estimated consumption of sulfuric acid in the USSR in 1950-55 is shown in Table 7~~~ and in Figure 3.~ Table 5 follows on p. 22. Table 6 follows on p. 23. Following p. 2~+. Table 7 follows on p. 23- Following p. 2~+. (Text continued on p. 2~+.) Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Table 5 , Importing Count 1951 1952 1953 1951+ 1951 Czechoslovakia 1+,600 ~ 21,-086 ~ 5,000 ~ 6,81+7 J _ Rumania 1,552 1,1+00 ~ 6,93 Hungary 350 ~ 11+,292 ~ 11,768 ~/ 15,011 ~ 5 88 ~ North Korea 725 500 ?,~ , Finland 60~ 5, 00 Austria 5,00 Bulgaria Total 1+,950 3 655 16,768 23,818 6 22,87 a. Unless otherwise specified, figures represent elemental sulfur., b. Represents 12,000 tons of pyrites, estimated to contain 30 perc~nt sulfur and 1,000 tons of elemental sulfur. 107 c. Represents a total of 60,287 tons of pyrites, estimated 30 percent sul~'u.r and 3,000 tons of elemental sulfur. 108 d. log e. Represents a total of 22,823 30 percent sulfur. 110 f. 111 g. 112 h. Represents suli`ur . 113 i. Represents sulfur . 111+ j. Represents sulf~zr . 115 k. Represents Known Exports of Sulfur From the USSR 1951-55 pyrites, 1,165 tons of pyrites, estimated to contain 30 percen 1a-7,61+1 tons of pyrites, estimated to contain 30 perce t 39,226 tons of pyrites, estimated to contain 30 perce t a total of 50,037 30 percent sulfur. 116 1. Represents a total of 19,602 30 percent sulfur. 117 m. 118 n. 119 o. 120 p. 121 of pyrites, Metric ~'ons contain tons of pyrites, estimated to conta~iri Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Table 6 Estimated Consumption of Sulfur Products in the USSR 195 0- 55 Product 1950 1951 1952 1853 1954 1955 Sulfuric acid 728 814 892 981 1,124 1,316 Sulfite pulp 107 119 l30 143 157 163 Carbon disulfide 16 19 25 30 38 47 Rubber (vulcanization) 7 8 9 10 10 10 Other ~ 119 135 150 165 188 220 Total ~ 1,095 1,206 1,329 1 51 1,756 a. For derivation of these estimates, see Appendix A. b. This category includes consumption for dyes, matches, explosives, insectofungicides, paints, and other minor products. Table 7 Estimated Consumption of Sulfuric Acid ~ in the USSR 1950-55 Consuming Commodity 1850 1951 1952 1953 1954 1955 Superphosphate 540 580 627 680 788 954 Petroleum 420 470 526 590 660 785 Coke chemicals 313 357 407 444 480 518 Steel 70 80 88 97 105 115 Rayon viscose 50 62 81 g8 121 151 other ~ 647 731 771 841 g96 1,167 Total 2,040 2,280 2L500 2,750 3,150 3,690 a. Calculated on the basis of 100 percent acid. b. For derivation of these estimates, see Appendix A. c. This category includes consumption for dyes and intermediates, syn- thetic ammonium sulfate, hydrochloric acid, paints and pigments, ex- plosives, nonferrous metallurgy, and miscellaneous chemical and indus- trial uses. The amounts indicated in this category were obtained by difference between the total amount of sulfuric acid available and the amount consumed by known consumers. -23- S-E-C-R-E-T Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 l Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 VI. Supply and Demand. 1 Soviet trade in sulfur has been so small that the supply and de~and position is determined largely by annual production and consumption The estimated supply and demand balance of sulfur in the USSR in ~ 1950-55 is shown in Table 8.~ As indicated in Table 8, the supply c~f sulfur in 1950-55 was more than adequate for domestic consumption arid. for exports. 1 Supply is estimated to have increased steadily from 1950 througY~. 1952, to have declined in 1953 and 1954, and then to have increased~in 1955? Z`he reduction in 1953 and 1954 has been attributed largely tc} the failure of the Ural Mountain copper-pyrite mines to meet planned production goals. On the other hand, demand for sulfur is presumed 'to have increased steadily throughout the 1950-55 period. Because sulr is an essential ingredient in so many industrial processes, it prob bly will continue to rise as long as industrial production increases. e reserves of sulfur raw materials in the USSR are almost unlimited, d the supply of sulfur in the foreseeable future probably will not be.ome a problem. As indicated in Table 8, the USSR is estimated to have had a sur- plus of sulfur in 1950-55 amounting to about 1.6 million tons, a quantity large enough for about 1 year's requirements. The existenge of such a surplus is in agreement with all available evidence that ~ the supply of .sulfur in the USSR generally satisfies annual demands .I An annual breakdown of this excess supply shows that stocks were ! built up in increasing quantities in the first half of the period ar~d declined in the latter half to an approximate supply and demand bal-~ ante in both 1954 and 1955? VII. In uts. Information on the fuel, power, manpower, capital, and energy requirements for the Soviet sulfur industry is not available, becausle 92 to 94 percent of the total sulfur produced (see Table 2~-~) is recovered as a byproduct operation in the processing of copper, lead, and zinc ores and in the cleaning of coals. A breakdown of the per- centage of the various input items utilized in these byproduct opera- tions is not available. Elemental sulfur recovered in mining operatjions ~ Table Mows on p. 25. ~--~ P. 10, above. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 -SECRET isoo QF SULP BY TYPE OF PRODUCT OTHER RUBBER (Vulcanization) CARBON DISULFIDE~I=` ussR ESTIMATED CONSUMPTION 1950 1951 t2o6 SECRET Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 SECRET ussR ESTIMATED CONSUMPTION O~F SULFURIC ACID, 1950-55 BY TYPE OF PRODUCT RAYON VISCOSE STEEL 2~so 1453 1954 1955 SECRET Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Table 8 Estimated Supply and Demand Balance of Sulfur in the USSR 195?-55 Supply _ Demand Total Total Year Production J Imports ~ Supply Exports ~ Consumption ~ Demand lg5o 1,258 13 1,271 977 977 1851 1,504 23 1,527 5 1,095 1,100 1952 1,797 7 1,804 38 1,206 1,244 1953 1,628 3 1,631 17 1,329 1,346 1954 1,567 ~+ 1571 24 1,517 1,541 1955 1,767 l0 1,777 23 11756 1,779 a. See Table 2, p. lo, above. b. See Table 4, p. 20, above. c. See Table 5, p. 22, above. d. See Table 6, p. 23, above. Approved For Release 1.999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 accounts for only 6 to 8 percent of the total annual production of~ sul- fur. Input requirements for this part of the industry are, therefore, of little significance. I VIII. Prices. The only available internal prices for Soviet sulfur are the 1}50 prices reported by the Ministries of the Chemical and the Metallurgi- cal industries. 122 Those reported by the Ministry of the Chemic~ Industry are the f.o.b. mine prices of mined elemental sulfur. Th metallurgical industry prices are for elemental sulfur produced as~a byproduct of the smelting of nonferrous ores. The mined elemental sul- fur is reported as ground sulfur and lump sulfur, but only lumps fur is reported by the metallurgical industry. The internal prices fo elemental sulfur in the USSR in 1950 are shown in Table 9.~- There has been no explanation reported for the great differenc in price between the mined sulfur anc~ the byproduct sulfur produced a smelters. A possible explanation of the relatively high price of mined sulfur may be that the large native sulfur producing deposits in t e Volga region are low in grade, averaging only 11 percent sulfur, 1 3 and the other major sulftiir mining area is in the remote Kara Kum d sert region. In some parts of the latter area, supplies are brought ink, and the finished product is shipped out by air transport. 12~+ On the other hand, if the USSR follows US practice, prices of byproduct materia,~s are arbitrary prices set by the producer of the major commodity because input costs of the byproducts are not available. Profits obtainedlfrom the byproducts are entered as~a credit against the cost of the major product. This practice could account for the relatively low price~re- ported if a similar practice is followed in the Soviet sulfur indu~try. The 1950 US average price for elemental lump or ground sulfur ,o.b. mine was $20.00 per long ton or $19.x+0 per metric ton. 125 On. th basis of these data, the ruble-dollar ratio between the US and Soviet sulfur prices is calculated to have been 66 to 1. It should be noised, however, that the occurrence of the tremendous quantities of high ade and cheaply mineable elemental sulfur in the US is unique. With the exception of recent discoveries of this same type of sulfur in Mexico, virtually all other industrialized countries in the world utilize pyrites as the major sulfur raw material. Thus costs of recovering sulfur in other countries are relatively high when compared with t ose I * Table g follows on p. 27. -26- S-E-C-R-E-T Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E-C -R-E-T Table 9 Internal Prices for Elemental Sulfur in the USSR 1950 Rubles per Metric Ton Type ~ Percent Ministry of Sulfur Grade ,, COST _/ of Sulfur Price Ministry of the Chemical Industry 126 Ground I 127-41 99.5 1,275 II 127-41 98.0 1,240 III 127-41 95.0 1,200 Lump I 127-41 99.5 1,125 II 127-41 98.0 1,095 III 127-41 95.0 1,035 Ministry of the Metallurgical Industry 127 Lump I 1223-41 99.6 600 II 1223-41 98.6 500 III 1223-41 96.5 400 a. COST is the Russian abbreviation for Gosudarstvennyy Obshchesoyuznyy Standart (State All-Union Standard). in the US. For example, the sales price per metric ton of sulfur in 1955 in East Germany was 224.9 East German marks (DME) (US 101.20) 128?; the import price of sulfur per ton in Poland in 1954 was US $76.00 129 , and a similar price for imports in Czechoslovakia in 1952 was US $114.88. 130 Most of the sulfur produced in the USSR is from pyrites which are shipped to chemical plants to make sulfuric acid. A smaller tonnage is combined in the copper matte and is taken off in the converters in the form of gas. Some of this gas is converted to sulfuric acid and the remainder to elemental sulfur. Thus the selling price of the pyrites by the metal mining company, or the percentage of the total cost of the manufacturing of sulfuric acid made up by the cost of Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 pyrites, would be of the most value. The only available estimates ?of cost (in rubles) are those which show (1) the cost of the pyrites and (2) the percentage relationship of this cost to the total cost of s~u1.- furic acid production in 1950 by the contact process. 131 In 19501 the cost of pyrites required to make 1 ton of sulfuric acid by the contact process was 140 rubles, which represented 60.4 percent of the total cost of the production of 1 ton of sulfuric acid. 132 Inasmuch as 1.2 tons of pyrites containing 30 percent sulfur are required to produce 1 t n of sulfuric acid, 133 the cost of the pyrites per ton to the sulf is acid plant was 116. rubles. A comparable US price for pyrites in j 1950 was $6.83 per ton. 134 These data yield a ruble-dollar ratio for pyrites of 17 to 1. The Third Five Year Plan (1938-42) provided that 50 percent of ~he sulfuric acid would be produced by the contact process and 50 peace ~t by the chamber and tower process. 135 Plant studies show that thi ratio still held in 1953. 136 An estimate of the costs of pyrites used in the chamber and tower process for producing sulfuric acid i the USSR is not available. On the basis of US experience, it is con- cluded that if pyrites were utilized as raw material, the-cost of p~o- duction of sulfuric acid by the contact method and by the chamber aid tower process would be about equal. 137 Assuming that costs are comparable in the USSR, the total annual cost of pyrites used in tY~e sulfuric acid plants in the USSR in 1950-55 is estimated as follows;: Year Production of Sulfuric Acid 138 (Thousand Metric Tons) Cost of Pyrites at 140 Rubles per Ton of Acid ~ Delivered to Sulfuric Acid Plants (Million Rubles) ~ 1950 2,040 285.6 i 1951 2,280 319.2 1852 2,500 350.0 ~ 1953 2,750 385 .o 1954 3,150 441.0 1955 3,690 516.6 j These costs cannot be correlated with US practices, because the ra~ material for producing sulfuric acid in the US is almost-entirely ! elemental sulfur and the manufacturing processes are entirely diff~rent. i --Ii Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E -C -R -E -T IX. Capabilities, Vulnerabilities, and Intentions. In 1955 the USSR had an estimated supply of elemental sulfur or sulfur equivalent of 1,767,000 tons. This amount is considered ade- quate to meet all the domestic and trade requirements in that year. Soviet reserves of sulfur-bearing materials are so large that exhaus- tion is virtually impossible. The Soviet sulfur industry has no significant vulnerabillties, and it is not a reliable indicator of national intentions. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E-C -R-E-T APPENDIX A METHODOLOGY 1. Estimates of Sulfur Production. The recovery of the pyrites associated with the sulfide ores of copper, lead, and zinc has never been reported separately by the USSR. At some mines and smelters, pyrites axe separated in the concentrating process and shipped as a byproduct concentrate to chemical plants for the production of sulfuric acid. In other mines, however, a clean separation of pyrites is not made. Pyrites axe contained in the con- centrates, the sulfur from which -- together with the combined sulfur in the sulfide ores -- is recovered as sulfurous anhydride (S02) from the waste gases. 139 This sulfurous product is reduced to either elemental sulfur or sulfuric acid. 1~+0 In view of the lack of infor- mation on the separation and disposition of the sulfur content of the pyrites and the sulfide ores, the only method considered feasible Cites obtain a measure of the sulfur available in the iron and copper pyr and the combined sulfur in sulfide ores of copper, lead, and zinc is to estimate the sulfur content of these ores. a. Byproduct Sulfur from Pyrites Contained in Sulfide Ores. (1) Ural Mountains. Although the sulfide ores of the Ural Mountains are mined principally for their copper content, they also contain large quantities of sulfur and small amounts of lead and zinc. When the ores are pre- pared for smelting, they are concentrated in the ratio of about 10 to 1, 141 so that of each 100 tons of ore mined, 10 tons actually enter a smelter; the remainder can be considered to be tailings. As indicated, however, these tailings contain a large quantity of sulfur in the form of pyrites. Assuming that 60 percent of the tailings are pyrites and using. 30 percent as the average sulfur content, the quantity of sulfur available from pyrites can be estimated. There are no primary data on production of copper ore in the Urals. The first step in estimating the sulfur content of the pyrites of the copper ore, therefore, is to calculate the quantity of ore mined in order to yield the amount of copper estimated to have been - 31 - Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 produced. The estimated production of copper in the USSR in 195-55 is shown in Table 10. ~ I Estimated Production of Copper in the USSR 1950-55 Thousand Metric Td ns Year Total/ USSR J Kazakhstan ~ Kola peni l ~ Other (Excludi g ~ ! nsu a Urals Uralsl d 1950 1 1 246.6 28 92.7 6.0 57.x+ 90.5 _ 95 1952 1.1 2 98.3 7.0 62.5 113.3 1 3 3.3 8 log.4 8.0 65.0 140.9 953 1 4 320. 6 8 120.6 8.0 69.0 123.2 95 1955 . 33 143.3 8.0 70.0 115,5 377.3 166.0 8.0 71.0 132.3i a. The production of copper in the USSR in 1955 is derived fr m the production in Kazakhstan, which in turn is based on state- ments in Soviet publications linking current production to pro duction in 1913, which is known. In 1913, production of coppe in Kazakhstan was 5,070 tons, 142 and in 1940, production was 7 times that of 1913. 143 Production for 1950 was planned at 2.6 times that of 1940, 144 the plan was fulfilled 100.5 per- cent, 145 and the 1955 production was 79 percent greater than that in 1950. 146 In 1955, Kazakhstan produced 44 percent of the total production of copper in the USSR. 147 Except for t e 1952 and 1954 figures for Kazakhstan, which are interpolations, figures for production in intervening years are based on annua ly announced percentage increases. b. 148 c. Includes copper estimated to have been produced in the ! Transcaucasus as a byproduct in the nickel operations at Noril'~k and from scrap at Moscow. d. Obtained by difference between the total for the USSR and tie estimated production in Kazakhstan, the Kola Peninsula, the Transcaucasus, Norilsk, and Moscow. I Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 The second step is to calculate the quantity of copper ore mined. The estimated production of copper ore in the Ural Mountains in the USSR in 1950-55 is shown in Table 11. Estimated Production of Copper Ore in the Ural Mountains in the USSR 1950-55 Thousand Metric Tons Year Copper Metal J Smelter Losses ~ Mill Losses ~ Total Amount of Copper Metal in Ore E stimated Production of Copper Ore J 1950 go.5 lo.0 16.3 116.8 5,840 1951 113.5 12.5 20.4 146.2 7,310 1952 14o.g 15.6 25.4 181.9 9,095 1953 123.2 13.6 22.2 159.0 7,950 1954 115.5 12.8 20.8 148.1 7,455 1955 132.3 14.7 23.g 170.9 8,545 a. See Table lo, p. 32, above. b. 149 c. 150 The copper content of Ural ore averages about 2 percent. The third step is to estimate the quantities of pyrites recovered in the Urals and the sulfur content of these pyrites. The estimated production of pyrites and their sulfur content in the Ural Mountains in the USSR in 1950-55 is shown in Table 12.E (2) Transcaucasus and Kola Peninsula. Estimates of production of the pyrites recovered at Alaverdi in the Transcaucasus and at Kirovsk on the Kola Peninsula are based on the reports of sulfuric acid plants at these locations. The plant at Alaverdi uses pyrites, and that at Kirovsk uses pyrrhotite, both of which are also reported to contain 30 percent sulfur. Thus 1.2 tons ~ Table 12 follows on p. 34. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500g9-2 of these products are required to make 1 ton of sulfuric acid. 15' The estimated production of pyrites and sulfur recovered at A1ave~di in the USSR in 1950-55 are shown in Table 13.E Estimated Production of Pyrites in the Ural Mountains in the USSR 1950-55 Thousand Metric Toffs Year Coppery Ore ~1 Copper Concentrate (10 Percent of Ore) Pyrites Content of Tailings (60 Percent of Remainder) Sulfur Content of Pyrites (30 Percen ) 1950 5,840 584 3,153 945.9 1951 7,310 731 3,947 1,184.1; 1952 9,095 909 4,911 1,473.3 1953 7,950 795 4,293 1,287.9 1954 7,455 745 4,026 1,207.8 1955 8,545 854 4,614 1,384.2;. a. See Table 11, p. 33, above. The annual capacity of the sulfuric acid plant at Ki~ovsk is estimated to have been constant at 40,000 tons in 1950-55. 1~ The annual production and the sulfur required were calculated byjthe same method used for the Alaverdi plant. The total sulfur recovered from pyrites and pyrrhotit~e in the USSR was obtained by adding to the production from the Ur l.s the sulfur equivalent of the sulfuric acid produced at the Kirov~k and Alaverdi plants. The total amount of sulfur recovered from pyrites and pyrrhotite in the USSR in 1950-55 is shown in Table ~4.~-~ ~ Table 13 follows on p. 35? ~~ Table 14 follows on p. 35? - 34 - Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 i Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E-C -R-E-T Table 13 Estimated Production of Pyrites at Alaverdi in the USSR 1950-55 Sulfur Content Year Sulfuric Acid ~ Pyrites of Pyrites 1950 26.0 31.2 9.4 1951 30.6 36.7 11.0 1852 34.0 40.8 12.2 1953 38.0 45.6 13.7 1954 41.8 50.2 15.0 1955 42.0 50.4 15.1 Table 14 Total Amount of Sulfur Recovered from Pyrites and Pyrrhotite in the USSR 1950-55 Pyrites Pyrrhotite Total Sulfur from Year Urals ~ Transcaucasus ~ Total from the Kola Peninsula ~ Pyrites and Pyrrhotite 1950 945.9 9.3 955.2 14.4 969.6 1951 1,184.1 11.0 1,195.1 14.4 1,209.5 1952 1,473.3 12.2 1,485.5 14.4 1,499.9 1953 1,287.9 13.6 1,301.5 14.4 1,315.9 1954 1,207.8 15.0 1,222.8 14.4 1,237.2 1955 1,384.2 15.1 1,399.3 14.4 1,413.7 a. See Table 12, p. 3 , above. b. See Table 13, above. c. 154 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 i i Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 i b. Byproduct Sulfur Obtained from Waste Smelter Gases. Production estimates of the sulfur recovered from waste smelter gases are derived from reports on the capacities of sulfuric acid plants situated at the copper, lead, and zinc smelters. These pla is utilize the sulfur recovered from the smelter gases, making 1 ton ~f sulfuric acid from 0.36 ton of sulf~.ir. The amount of sulfur produded from waste smelter gases used in the. manufacture of sulfuric acid i~s shown in Table 15.E Because there is no indication of any change 3~n the capacities of the sulfuric acid plants during the 1950-55 peri~d, the 1953 production has been taken as the average annual productio of sulfur from this source for the entire period. { c. Byproduct Sulfur from Iron Pyrites in Coals. Estimates of production of iron pyrites recovered in the cleaning of coals and recovering the sulfur content were obtained 1$y the following method. The only available figures on pyrites recov~red from coal in the USSR are for the coal from the Moscow and Donets asin. The Moscow Basin data are for 1933-35 and 1940, and the Donets Bas n data are for 1932 and 1940. 155 Factors obtained by relating tot 1. production of coal in the Moscow and Donets Basins to the quantity ;of pyrites recovered at these times were applied to current estimatesjof production of coal. These factors, 0.772 for the Moscow Basin ands 0.049 for the Donets Basin provided the estimate of the current re} covery of pyrites from coal in these basins. The amount of pyrite from coal in the Moscow Basin and the Donets Basin in the USSR in 1932_40 is shown in Table 16.-~-~ These factors derived in Table 16 applied to the 1950-55 e~ti- mated coal production from the Moscow and Donets Basins provide an! estimate of the pyrites recovered in 1950-55. The estimated amoun~ of pyrites recovered from coal in the Moscow Basin and the Donets sin in the USSR in 1950-55 is shown in Table 17.~~ The estimated pyrites recovered from the 2 fields were the~h totaled, and a sulfur content of 30 percent was again utilized to obtain the sulfur equivalent obtained from the coal pyrites. The ~ Table 15 follows on p. 37. Table 16 follows on p. 38. Table 17 follows on p. 39. _ 36 _ Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050049-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 estimated amount of sulfur recovered from coal in the Moscow Basin and the Donets Basin in the USSR in 1950-55 is shown in Table 18.-~ Amount of Sulfur Produced from Waste Smelter Gases Used in the Manufacture of Sulfuric Acid in the USSR 1953 Thousand Metric Tons City Sulfuric Acid Sulfur Content Norilsk 11.7 ~''2 Dzaudzhikau ~ 25.0 9.0 Chelyabinsk ~ X0.0 l~''~' Kirovgrad ~ 60.0 21.6 Blyava 20.0 7.2 ~ Revda e x+5.0 16.2 Leninogorsk ~ 25.0 9.0 Krasnoural'sk ~ ~-x-0.0 1~ ? ~" Ust'-Kamenogorsk ~ 25.0 9.0 2gl?7 105.0 a. 15 b ? c. 157 15 d. 159 e. 1 f. 1 1 g. 1 2 h. 1 3 ~ Table~ollows on p. 39? Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Table 16 Estimated Amount of Pyrites Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR 1932-40 Amount (Thousand Metric Tons) Amount (Thousand Metric Tons) Year Production of Coal Pyrites ,,/ Percent in the Moscow Basin J Recovered J of Total Production of Coal Pyrites in the Donets B R i Percent as n ecovered of Total 1932 45,044 15 0.033 1933 3,833 28 0.73 51,060 1834 4,618 38 0.82 64,486 1935 5,7~ 40 0.70 6g,5oo 1936 7,100 78,600 1937 7,506 77,542 1938 7,416 80,733 1939 8,100 85,300 1840 9,950 80 0.80 94,400 54 0.057 Weighted average 0.772 Weighted average 0.048 a. 1 b. 1 _ 3g _ Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S -E - C -R -E -T Table 17 Estimated Amount of Pyrites Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR 1950-55 Year Production of Coal in the Moscow Basin J Pyrites Recovered Production of Coal' in the Donets Basin ~ Pyrite s Recovered 1950 29,850 230.4 g6,ooo 47.0 1951 32,000 247.0 103,500 50.7 1952 33,100 255.5 107,600 52.7 1953 34,500 266.3 114,500 56.1 1954 36,000 277.8 122,000 59.7 1955 38,500 297.2 130,000 63.7 a. 1 b. 1 7/ Table 18 Estimated Amount of Sulfur Recovered from Coal in the Moscow Basin and the Donets Basin in the USSR 1950-55 Amount (Thousand Metric Tons) Year Moscow Basin Donets Basin Total Sulfur Content 30 Percent 1950 230.4 47.0 277.4 83.2 1951 247.0 50.7 287.7 89.3 1952 255.5 52.7 308.2 92.4 1953 266.3 56.1 322.4 96.7 1954 277.9 59.7 337.6 101.2 1955 297.2 63.7 36o.g 108.2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 d. Mined Elemental Sulfur. Estimates of the production of mined elemental sulfur have ben given in Table 2,* which also indicates-the sources for 1950-53. Simji- lar data are not available for 1954 and 1855. In order to extend thej production series to 1955, estimates of production in 1954 and 1955 w~re obtained by relating the production of sulfur to the increase of Bros production of industry. Production of mined elemental sulfur for 195 was 124,000 tons, an increase of 13 percent over 1953, 168 and refle is the increase of gross production of industry as a whole of 13 percentt over 1953 and the estimated increase of production of sulfuric acid i 1954 over 1953. 169 The same percentage increase of 13 percent was applied to the 1954 total to obtain the estimate of production of sulfur. For the 1955 estimate, in addition to the increase of gross production of industry of 13 percent, an announced increase of 21 per- cent for mineral fertilizers for the first half of 1855 was considerejd. 170 Inasmuch as a large part of the native sulfur produced is utilized four agricultural dusting, 171 the increased fertilizer production presu - poses larger crops and an increased dusting of these crops. e. Byproduct Sulftiir from Processing Petroleum. Although the natural crude petroleums from the Ural-Volga, Central Asia, Pechora, and Sakhalin Island fields all have moderately high sulfur contents, only the Ural-Volga fields are considered, bec se the quantity of crude oils produced in the other fields is relatively small. The natural crude oils of the Ural-Volga fields have a sulfur content of 1.25 to 4.8 percent by weight of sulfur with an average o~ 2.2 percent. 172 In processing the average crude oils from these fields, 45 percent of the total sulfur is concentrated in the residu 1 25 percent of the oil stock. The production of natural crude oil in the Ural-Volga field in 1955 is estimated to be 33.5 million tons. With an average sulfur content of 2.2 percent, the total sulfur pres~n,t in these crude oils amounts to 737,000 tons. Because of the lack ofd the necessary technical information in practically all aspects of th~ various problems involved, conclusions as to the probable production' of sulfur from the 1955 production of natural crude oil are based on the following approximate correlations. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500d9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Assuming that the principal conversion refining operations were confined to thermal visbreaking of residues and that the thermal types of cracking and reforming were applied to the distillate stocks (gas oils and naphthas), probably no more than 10 percent of the total sulfur would have been recovered as a byproduct if the refining had been for maximum yields of gasolines, and probably no more than 5 percent of the total sulfur would have been recovered as a byproduct if the refining had been for maximum yields of middle distillates such as kerosines and various types of diesel fuels. It is probable, therefore, that no more than 50,000 tons, less than 7 percent of the total sulfur, were recov- ered as a byproduct of refining operations. 173 2. Estimates of Sulfur Reserves. The latest available estimate on unmined reserves of elemental sulf~zr in the USSR was presented in 1951. 174 The reserves reported from the various deposits, however, are estimated to range in date from 1g46 through 1950. For purposes of this report, 1948 has been selected as the date of the estimate of elemental sulfur reserves. The estimate of reserves of unmined elemental sulfur in the USSR in 1948 is shown in Table 19.x- Using 1948 as a basis, the estimate was obtained by sub- tracting the total production of mined elemental sulfur in 1948-55 from the 1948 reserve total. 175 The total estimated production of elemental sulfur in the USSR in 1848-55 is 844,000 tons.-~~ Subtracting this quantity from the 1948 reserve estimate yields the-1955 reserve estimate of 33,735,000 tons. b. Sulfur in Ural-Volga Petroleum Fields. The Ural-Volga area is the major area in the USSR which pro- duces natural crude oils whose sulfur contents exceed 0.5 percent by weight. 176 Total proved reserves of crude oil in the Ural-Volga fields at the close of 1955 have been estimated at 769 million tons. 177 With an average sulfur content of 2.2 percent, the total sulfur availa- ble in these crudes amounts to about 16.9 million tons. ~ Table 19 follows on p. 42. *~ See Table 2, p. 10, above, and Appendix A for source of the pro- duction totals for the 1950-55 period and add 85,000 tons each year for 1948 and 1849. - 41 - S-E-C-R-E-T Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02.: CIA-RDP79-01093A001200050009-2 Reserves of Unmined Elemental Sulfur in the USSR 1948 Sulfur Ore Elemental Sulfur (Thousand Sulfur Content (Thousand Location Metric Tons) (Percent) Metric Tons) Volga area 200,000 11 22,-000 Chokur-Koyash 100 15 15 Kkhuit 80 20 16 Gaurdak 10,000 12 to 15 1,350 shikh 1,200 50 600 Kara Kum 5,000 30 1,500 Shor-Su -650 15 98 Kushka 5,000 30 1,500 Gazgan Kyzyly 25,000 30 7,500 Kenimekh Total 247,030 34579 c. Production Forecast, 1956-60. The estimate of the annual production of sulfur for the 195-6 period was obtained by multiplying the 1955 Production estimate by 65 percent, adding this quantity to the 1955 production, and using his latter total as the 1960 production of sulfur. Using a straight-li e projection, the production of sulfur in the 1956-60 period was talc - lated. d. Sulfur in Iron Pyrites in Coal. I The sulfur content of the coals in the USSR varies greatly.~l~ The recoverable sulfur occurs in the form of iron pyrites, which ar~ known to have been recovered on a commercial scale only in the Donets and Moscow Basins. ~ Some of the coals on the western slopes ofthe Urals are also classed as high-sulfur coals, but figures on coal re~- serves for the area are not sufficiently detailed to provide a figujre Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 covering the high-sulfur coals. The latest available figures on coal reserves are the 193`7 totals of 88,872 million tons for the Donets Basin and 12,400 million tons for the Moscow Basin. 180 The recoverable sul- fur content in the Donets coals is reported at 1.5 percent of the total reserves, 181 and in the Moscow Basin the recoverable sulfur is 0.6 percent. 182 To obtain a sulfur reserve estimate for these two. Basins, the production of coal far the 1937-55 Period was subtracted from the 1937 reserve total as follows: Donets Basin Moscow Basin 1937 coal reserve 88,872,000,000 12,400,000,000 1937-55 total production 1,503,857,000 412,637,000 1955 coal reserve 87,368,143,000 11,887,363,000 1955 sulfur reserve 1,310,522,145 71,924,178 Because the 1937 figure for coal reserves in the Moscow Basin was made when only 6 percent of the field had been prospected, the coal reserve and sulfur reserve figures must be considered minimum figures. .183 Thus the estimated unmined sulfur reserve in coals in 1955 is 1,382,446,323 tons. e. Sulfur in Sulfide Ores. Pyrites associated with sulfide copper, lead, and zinc ores account for most of the sulfur in this type of sulfur reserve. Combined sulfur in these ores makes up the remaining small percent- age of sulfur reserve from this source. 184 The copper and iron pyrites and the combined sulfur in the copper, lead, and zinc sulfide ores of the Urals area are believed to be the largest sources of sulfur reserves of the pyrite type. The Urals is also the only region for. which any reserve figures are available, 18 but the latest available estimate of sulfur reserves in the Urals area deposits is for 1937. 186 Copper reserves in the USSR in 1939 were estimated at 19?_5 million tons of metal. 1$7 In 1937, 15.97 percent of the total copper reserves were reported to be in the Urals area. 1$8 Assuming - 43 - S -E-C -R=E-T Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 i Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 that the distribution of reserves in 1939 approximated that in 1937,E the Urals can be credited with about 3.1 million tons of copper rese ves in 1938. It is estimated that between 1839 and 1955 about 2.2 milli~ri tons of copper metal were extracted from these ore reserves, leaving++, about O.g million tons. As indicated in Table 11,* about 64 tons ofd ore from the Urals area are required to yield 1 ton of metal. The minimum reserves of ore at the close of 1955 are calculated, therefore, to have been about 57.6 million tons. Assuming that 10 percent of the ore is convertible to copper concentrates, that the pyrite conte~t of the tailings is 60 percent, and that the sulfur content of the pyrites is 30 percent, the minimum reserve of sulfur in the copper o e>s of the Urals was about 9.3 million tons at the close of 1955? The 9.3 million tons of sulfur constitute only a minimum bec~use exploration in the Urals region since 1939 must have resulted in add - tions to reserves. There are, moreover, sizable deposits of pyrite ~res not accounted for in the methodology presented above. These ores al~o contain large quantities of sulfur, but their copper content is so 1?~w that they would not be counted in the copper reserve figures. i It will be noted that only the production of copper in this ~rea has been considered in calculating the pyrites reserves. The lead a d zinc production has not been included, because of insufficient data pn which to base an estimate. 3. Estimates of Domestic Demand for Sulfur. Estimates of the total sulfur consumed in the USSR for each of tie years in the series was made by US analogy. In the US in 1950, aboutt 88 percent of the sulfur consumed was used in the manufacture or pro- cessing of sulfuric acid, sulfite pulp, carbon disulfide, and rubber. 18g The amount of sulf~zr consumed for these purposes in the USSR has bee estimated by assuming that 88 percent of the total sulfur consumed i the USSR is used for these purposes. It is to be noted that this es i- mate is not based on factors of sulfur supply. ~ P? 33, above. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C19-2 I Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T a. Estimated Sulf~zr Consumed in the Production of Sulfuric Acid, 1950-55? Soviet production of sulfuric acid for 1850-53 has been esti- mated as follows 190 1950 2,040 1951 2,280 1952 2,500 1953 2,750 On the basis of an average of the announced results of fulfill- ment of the 1954 Plante for (1) the increase of gross production of industry as a whole (13 percent over 1953) and (2) the increase of the production of mineral fertilizer (16 percent over 1953), a 1954 estimate of 3.15 million tons of sulfuric acid is obtained (14.5 percent over the production in 1953). The estimate for 1955,~~ 3.69 million tons of sulfuric acid (17 percent over 1954), is based on ari average of (1) the increase in gross output of industry as a whole achieved for the pre- ceding year (13 percent) and (2) the increase of 21 percent announced for mineral fertilizers far the first half of 1955? It is assumed that 21 percent was also the increase achieved for the year. A consumption coefficient of 0.36 ton of sulfur per ton of sulfuric acid produced 191 was used to obtain the total sulfur requirements for the manufacture of sulfuric acid. b. Estimated Sulfur Consumed in the Production of Sulfite Pulp, 1953? It is estimated that 1.1 million tons of sulfite pulp were pro- duced in the USSR in 1953. 192 The reported US consumption of sulfur per ton of sulfite pulp is 220 to 300 pounds. 193 Assuming that a similar quantity would be valid for the USSR, it is estimated that 143,000 tons of sulfur were consumed in the production of sulfite pulp ~ Increases reported by the State Plan fulfillment announcements are compiled in Table 20, p. 4g, below. ~~ Subject to change in accordance with publication of the State Plan fulfillment announcement for 1955? -45- Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500d9-2 in 1953. With the production of sulfite pulp closely paralleling tY~e production of paper in the USSR, the increases reported for paper from 1951 to 1955 (see Table 11-x) may be used to estimate consumption of ~ sulfur for production of sulfite pulp. c. Estimated Sulfur Consumed in the Production of Caz?bon Disulfide. The requirements of sulfur for the production of carbon disul- fide in the USSR were based on the following: (1) Estimated rayon production in the USSR from 1950 to I 1953 was 34,000, 42,000, and 66,000 tons, respectively. 194 A 1954' estimate of 82,000 tons is obtained by applying to the 1953 production the average annual increase of about 25 percent for 1950-53. (2) A US consumption coefficient of 0.38 ton of carbon disulfide required per ton of viscose rayon. 195 i (3) An assumption (based on the US use pattern for Garb n disulfide in 1947, when 66 percent of the production was used in th manufacture of rayon 196 ) that about 70 percent of the carbon disu - fide produced in the USSR is used in the manufacture of rayon. (4) The theoretical amount of sulfur required in the manu- facture of carbon disulfide from carbon and sulfur of 0.842 ton sul~ur per ton of carbon disulfide. 197 The amount of sulfur consumed in the production of rubber in the USSR was calculated on the basis of 3 percent 198 of the estima~'ted consumption of new rubber for the 1950-55 period. 199 The amount of sulfur used by other consumers in the USSR wad assumed to be the difference between the total amount consumed and he amount consumed by the known consumers. The quantity resulting pro ably was used for the production of such miscellaneous items as dyes, ma ches, explosives paints, and insectof`ungicides. ~- P. 33, above. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T f. Estimated Use Pattern of Sulfuric Acid in the USSR, 1950-55? (1) Superphosphate. Soviet production of superphosphate in 1950,E 1951, 1952, and 1953 has been estimated at 1.62 million, 1.74 million, 1.88 million, and 2.04 million tons, respectively. -The estimated production in 1954 of 2.365 million tons is based on the reported increase for superphos- phate in 1954 of 16 percent over 1953. 200 The estimated production in 1955 of 2.862 million tons is based on the increase reported for mineral fertilizers for the first half of 1955 (21 percent) and on the assumption that this will also be the yearly increase. The amount of sulfuric acid consumed for superphosphate production is based on the re- ported approximate requirement of 1 ton of sulfuric acid per 3 tons of superphosphate produced. 201 (2) Petroleum. It is estimated that in-1950 420,000 tons of sulfuric acid were consumed in the USSR by the petroleum industry. 202 Based on re- ported yearly increases of the production of oil from 1950 to 1954 of 12 percent annually, and assuming the 1955 increase over 1854 will be the same as that reported for the first half of 1955 (lg percent), the sulfuric acid consumed by the petroleum industry in 1950-55 is estimated as follows: 1950, 420,.000 tons; 1951, 470,000 tons; 1952, 526,000 tons; 1953, 590,000 tors; 1954, 600,000 tons; and 1955, 785,000 tons. (3) Coke Chemicals (Including Byproduct Ammonium Sulfate). It is estimated that in 1954 480,000 tons of sulfuric acid were consumed in the USSR for the production of coke chemicals and by- product ammonium sulfate. 203 Assuming that this input varies directly with the estimated production of byproduct ammonium sulfate in the USSR from 1850 to 1954, 204 the sulfuric acid consumed by the coke-chemical industry for the years 1950-54 is estimated as follows: 1950, 313,000 tons; 1951, 357,000 tons; 1952, 407,000 tons; 1853, 444,000 tons; and 1954, 480,000 tons. The consumption estimated above for 1953 and 1954 shows an 8- to g-percent annual increase. The 1955 estimate of 518,000 tons of sulfuric acid consumed in the production of coke chemicals is obtained by assuming that the increase in 1g55 over 1854 will be about 8 percent. _ 47 _ Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 (4) Steel. It is estimated that the Soviet steel industry consumed 70,000 tons of sulfuric acid in 1950. 205 Assuming that this input has increased at the same yearly rates reported for the production+ of steel in 1950-54 (see Table 11*) and by further assuming that tY~e increase in-1955 above production in 1954 will be the same as that; reported for the first half of 1955, the amounts of sulfuric acid j consumed by the steel industry in 1950-55 are estimated as follows; 1950, 70,000 tons; 1951, 80,000 tons; 1952, 88,_000 tons; 1953, 97,000 tons; 1954, 105,000 tons; and 1955, 115,000 tons. (5) Viscose Rayon. The estimates for the consumption of sulfuric acid in i~he production of viscose rayon in the USSR are based on the following; estimates of the production of rayon in 1950-55: 1950, 34,000 ton; 1951, 42,000 tans; 1952, 55,000 tons; 1953, 66,000 tons; 1954, 82,000 tons; and 1955, 102,000 tons. A consumption coefficient oft 1.48 tons of sulfuric acid per ton of rayon was applied to these figures. 206 ~ The reported production of selected commodities in the; USSR as a percentage of production of the preceding year for 1951-~5 is shown in Table 20.*~ ~ P. 33, above. ~~- Table 20 follows on p. 49. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500g9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T Table 20 Reported Production of Selected Commodities in the USSR as Percentage of Production of the Preceding Year 1951-55 Commodity 1951 J 1952 ~ 1953 J 195+ ~ 1955 J Oil 112 112 112 112 119 ~ Paper 112 109 110 110 10 + Steel 115 110 110 108 110 116 121 Mineral fertilizer 113 Industry as a whole a. 207/ b. 20 c. 209 d~ 210 e. 211? First half of 1955 as a percentage of the first half of 195 -~+9- Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T APPENDIX B GAPS IN IN'T'ELLIGENCE As indicated in the body of this report, most Soviet sulf~zr is of byproduct origin and hence is seldom mentioned in Soviet literature. There are, consequently, a large number of gaps in intelligence on most aspects of sulfur in the USSR. The following are considered to be the most significant ones: 1. Production. Quantitative data on the production of the sulfur raw materials that account for more than g0 percent of the total production of sulfur in the USSR are no-t available. The type of information available on these raw materials does not specify whether the product is in the form of sulfuric acid, elemental sulfur, or sulfurous gas. Moreover, primary data on the yields of sulfuric acid and elemental sulfur from the pro- cessing of pyrites and the combined sulfur in nonferrous sulfide ores, the major source of sulfur in the USSR, and byproduct sulfur from the refining of crude petroleum stock are not available. As a result, estimating the production of sulfur requires indirect methodologies and unverified assumptions. 2. Domestic Demand. Soviet statistical data on the annual domestic demand for sul- fur and the quantities required for the manufacture of sulfuric acid, or any of the other uses of sulfur, are not available. As a result, the estimates of demand for sulfur and sulfuric acid are based largely on US analogy. " 3. Inputs. Because most of the sulfur or sulfur equivalent produced in the USSR is a byproduct of the processing of sulfide ores, data on such inputs as power, fuel, labor, and capital investment are not available. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500Q9-2 ~+. Prices. Soviet price data are adequate for only elemental sulfu~h for 1950. Prices for pyrites consumed in the production of most of ,the byproduct sulfur are lacking entirely. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 S-E-C-R-E-T APPENDIX C SOURCE REFERENCES Evaluations, following the classification entry and designated "Eval.," have the following significance: Source of Information Information Doc. - Documentary 1 - Confirmed by other sources A - Completely reliable 2 - Probably true B - Usually reliable 3 - Possibly true C - Fairly reliable 4 - Doubtful D - Not usually reliable 5 - Probably false E - Not reliable 6 - Cannot be judged F - Cannot be judged "Documentary" refers to original documents of foreign governments and organizations; copies or translations of such documents by a staff officer; or information extracted from such documents by a staff officer, all of which may carry the field evaluation "Documentary." Evaluations not otherwise designated are those appearing on the cited document; those designated "RR" are by the author of this report. No "RR" evaluation is given when the author agrees with the evaluation on the cited document. 1. American Institute of Mining and Metallurgical Engineers. "Sulfur and Pyrites," Industrial Minerals and Rocks, 19+9, p. 1,008, 1,009. U. Eval. RR 1. 2. Commerce. Foreign Commerce Yearbook, 19+8, Washington, 1950, p. 191. U. Eval. RR 1. 3. NIS 26, USSR, sec 63, May 51, p. 63-97? c? Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 i Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 ~+. CIA. CIA~RR 25, The Sulfuric Acid Industry in the USSR, 25X1A 5. 6. CIA. CIA. CIA~RR 25 (~-, above). CIA~RR PR-24, The Soviet Bloc Position in P rites y , 6 Feb 53, p? 10. S. 25X1A g. lo. 25X1A 11. 25X1A 12. 13. 25X1A 1~+. 25X1 C 15 . 16. 25X~,A 18. 19. 20. 21. 22. 23. 24. 25X1 C 26. 25X1A27~ 28 .i 25X1 C29? 30. 31. 32. Interior, US Bureau of Mines. Minerals Yearbook, 1952, Washington, 1955, p? 982? U. Eval. RR 1. The New York Times, 3 Jan 56, p. 58 C. U. Eval. RR 2. American Institute of Mining and Metallurgical Engineers. " " Sulfur and Pyrites (1, above), p. 1,010. U USSR, United Geological Prospecting Service of the USSR. ~cientiiic, 'Technological, Geological, and Prospecting Publ- cation Office. Mineral Resources of the USSR, Leningrad~Mos~ow, 1933, p? ~+~-44. U. Eval. RR 2_ Ibid. Ibid. Ibid. Ibid. Ibid. Ibid. Ibid. Ibid. Special 48. C. Eval. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 25X1A 25X1 C 3~. 25X1 A 35 , 25X1 C 36. 25X1A 39? 40. ~+1. 25X1A -- , --- - 42. CIA. FDD Special Translation no 182, 30 Sep_~+8.T C; Eval. RR 3. 25X1A ? 25X1A 44. 25 ~5A ~+6 . 25X1 A~7 . ~+8 . 25X~A 50. 51. 52. 53? 5~+? 55? 56. 57? 58. 25X1 A 60. 25X1A 61. 62. 63. ia. Ibid. NIS 26, USSR, sec 63, May 51, p. 63-99. C. Ibid. Ibid. Ibid. Ibid. Ibid., p. 63-98. C. Ibid. Tbid., p. 63-99. C? NIS 26, USSR, sec 63, May 51, p. 3-9 NIS 26, USSR, sec Ibid. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 64. NIS 26, USSR, sec 63, May 51, p. 63-g8. c. 65. Ibid. 25X1 A 66. 67. 68. Ibid. 25X1A 25X1A 69. Ibid. 25X1A7o. 71. 25X1 C 72. STATSP~ 25X1 A 75 20 Jun 53? S. Eval. RR 76. lanovoye khozyaystvo, 33 STATSPE 78. 25X1 A79 STATS~~ 25X1A 81. 82. 1956, P. 1. U. Eval. RR 2. Ibid., no 1, 1951, p. 2. U. Eval. Interior, US Bureau of Mines. RI-x+972, Analysis of Tipple and Delivered Samples of Coal Oct 53 U Ev l RR , . . a . 1. 83. Ibid., Bulletin no 55 1 5 2. U 25X1 A 8~+. 85? Interior, United States Geolo ical Surve ~ g y (USGS).? Short Summar Geologic Report on the Ural-Volga Region with Emphasis on the Geology of the Oil and Gas Deposits, 195 , p. 90. U. Eval. R~ 2. hereafter referred to as Interior, USGS. Short Summary Geologic Report. 86. CIA. CIA~RR 61, Petroleum Resources of the Ural-Volga Area of the USSR, 15 Aug 55. S NOFORN. 87. Oil and Gas Journal, 21 Mar 55? U. Eval. RR 2. 88. CIA. FDD Special Translation no 182, 30 Sep ~+8. C. Eval. RR ~. CIA. CTA /RR ~R ~?i ; ,a ~,, ,,, n , .. LL.. TT(Y ('1r ~.. ~- _~ 25X1 A89. CIA. CIA RR 2 4 above) ~ ~ v L ~ 5 ( P? 31-37. SUS ONLY. - 56 - S -E -C -R -E -T Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500d9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 gl. NIS 2(, USSR, sec 63, May 51, p. 63-g8. C. 25X1 A 92 State, Teheran. Dsp ~+~+2, Jan 5~+. 25X1A g~+ . 95? 25X1 A97 100. State, Oslo. Dsp 1548, 15 Jun 50. U. Eval. RR 3. 101. State, Teheran. Dsp 442, 22 Jan 54. C. Eval. RR 3? g8. a e, e gra 25X1 A 99 102. Ibid. 25X1 A 103 106. Vol'kovich, S.I. Obshchaya khimicheskaya tekhnologiya (General Chemical Technology , Moscow, 1953, p? 377? U. Eval. RR 2. 104. State, He sin Z. 105. Ibid. C. Eval. RR 3. Eval. RR 3. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 j 119. State, Helsinki. Dsp 70, 25 Jul 55. C. Eval. RR 2. 120. Ibid. 121. State, Vienna. Dsp 95, 26 Jul 55. C. Eval. RR 2. 122. USSR. Spravochnik-tsennik na osnovnyye stroitel'nyye, tekhnicheskiye i vspomogatel'nyye materialy proizvodstvenno-~ tekhnicheskogo naznacheniya, instrumenty i avtoza chasti v tsenakh 1950 g Price Handbook on Basic Construction, Techni al, and Auxiliary Materials for Productive-Technical Purposes, Instruments, and Automobile Spare Parts in Prices of the Yeas 1950), vol ~, pt 1, Baku, 1950, p. 186, 196. U. Eval. Doc. (hereafter referred to as Spravochnik-tsennik) 123. NIS 26, USSR, sec 63, May 51 3- C. 25X1 At24. 125, n erior, US Bureau of Mines. Minerals Yearbook, 1950, Washington, 1 953, P? 1,182. U. Eval. RR 1. 126. Spravochnik-tsennik (122, above), p. 186. U. Eval. Doc. 127. Ibid., p. 19 U. Eval. Doc. 25X1 A1-28. 129. 25X1,~3o. 131. 132. 133. 134. 135? 136. 137? 138. 139? 140. 25X1A 141? 142. 143. 144. 145. 146. 147. 148. 25X1 C a e, un c sp 75, 11 Jan 5 S. Eval. RR 2. Ibid. Ibid., p. 26. SUS ONLY. Interior, US Bureau of Mines. Minerals Yearbook, 1950, Washington, 1953, p. 1,188. U. Eval. RR 1. CIA. CIA~RR 25 (~+, above), p. 7. SUS ONLY. Ibid., p. 27. SUS ONLY. Faith, W. L., Keyes, Donald B., and Clark, Roland L. Industr Chemicals, New York, 1950, p. 602-603. U. Eval. RR 1. ~- CIA. CIA RR 25 (~+, above), p. 17. SUS ONLY. CIA. FDD AB 505401, Jun 52. U. Eval. RR 2. Ibid. USSR. Godovoy obzor mineral'nykh resursov 1926 (Mineral Reso~ of the USSR in 192 , Leningrad, 1925, Planovoye khozyaystvo, no 3, 1952. U. Kazakhstanskaya pravda, 28 Jan 49. U. Ibid. Ibid., 18 Dec 55. U. Eval. RR 2. Ibid. -58- p. 2 U. Eval. RR ~2. Eval. RR 2. Eval. RR 2. j Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500f~9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 25X1 C 149. 150. 151. 152. 153? 154. 25X1 A 155 Ibid. CIA. CIA~RR 25 (4, above), p. 26. SUS ONLY. Ibid., p. 49. SUS ONLY. Yerevan kommunist, various issues, 1951-54. U. E~ra1. RR 3. CIA. CIA RR 254, above), p. 49. SUS ONLY. pecial 'Translation 156. CIA. CIA~RR 25 (4, above), p. 19-21. SUS ONLY. 157. Ibid. 158. Ibid. 159? Ibid. 160. lbid. 161. Ibid. 162. Ibid. 163. Ibid. 164. CIA. CIA/RR 28 (88, above). 25X1 A 165 . 166. STATSPE 167. 168. STATSPEC 1768. STATSPEC 171. 172. 174. 175. 176. CIA. CIA~RR 25 (4, above), p. 29. S/US ONLY. Interior, USGS. Short Summary Geologic Report (85, above). Maymim, Z.L., edr. Ob uslovi akh obrazovani a nefti po _materialam Volgo-Ural'skoy oblasti On Conditions for the Formation of Petroleum According to Data of the Volga-Ural Region), Leningrad, 1955, P? 188? U. Eval. RR 2. CIA. CIA~RR PR-135, Output of Refined Petroleum Products in the USSR 8 Mar 5 S. NIS 2 , USSR, sec 63, May 51, p. 63-983 ~3-99? C? Ibid. CIA. FDD Translation no 311, 31 Aug 51, Classification of USSR Petroleums According to Gost 912-46. C. E`val. RR 2. Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500C~9-2 177. CIA. CIA~RR 61, Petroleum Resources of the Ural-Vol a Area of the USSR, 15 Aug 55, p. 2 S NOFORN. 178. CIA. CIA RR 28 (88, above). 179. CIA. FDD Special Translation no 182, 30 Sep 48. 25X1A 180. Eyal. RR 3.I 181. CIA. FDD Special Translation no 182, 30 Sep 48. C. Eval. RR 3?i 25X1A182. 25X1 A183. 18~+. 185. 186. Balzak, S.S., Vasyutin, V.F., and Feygin, Ya.G. Economic Geography of the USSR, New York, 19+9, p. 259. U. Eval. RR 1. 187. CIA. Strategic Intelligence Digest, Union of Soviet Socialist Republics, vol 2, Mar 48, p. 10-8. S. Eval. RR 3. 188. Balzak, Vasyutin, and Feygin, off. cit. (186, above). 189. Interior, US Bureau of Mines. Minerals Yearbook, 1950, Washington, 1853, p. 1,181. U. Eval. RR 1. 190. CIA. CIA~RR 25 (1+, above), p. 18. SUS ONLY. 191. Ibid., p. 26. SUS ONLY. 192. FAO. Yearbook of Forest Products Statistics, Rome, 195+, p. 82. U. Eval. RR 2. 193. Perry, J.H. Chemical Engineer's Handbook, New York, 195+, p. 6-201. U. Eval. RR 1. 19~+. Cotton Yearbook, 1953, ~+8th ed, London, Jun 53, p. 679-680. U. Eval. RR.2. 195. Shreve, R.N. The Chemical Process Industries, New York, 19+5, p. 726. U. Eval. RR 2. 196. Faith, Keyes, and Clark, off. cit. (137, above), p. 19~+. U. Eval. RR 1. 197. Ibid., p. 192. U. Eval. RR 1. 198. The Vanderbilt Rubber Handbook, New York, 19+8, p. 97-137. U. Eval. RR 2. 199. CIA. ORR Project 22.860, The Rubber Industry in the Sino-Soviet Bloc (to be published). 200. Khimicheska a rom sY hlennost', no 1, 1955, P? 1. U. E~ra1. RR 2. 201. CIA. CIA RR 32, The Mineral Fertilizer Indust in the USSR 20 Apr 5~+, p. ~-0. SUS ONLY. 202. CIA. CIA~RR 25 (~+, above), p. 58. SUS ONLY. Approved For Release 1999/09/02 :CIA-RDP79-01093A0012000500g9-2 Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 203. CIA. CIA~RR 60, Mayor Aromatic Chemicals in the USSR, 27 Jun 55, p. 25. S~NOFORN. 20~+. Ibid., p. 30. S~NOFORN. 205. CIA. CIA~RR 25 (~+, above), p. 58. SUS ONLY. 206. Shreve, R.N. Selected Process Industries, New York, 1951, p. 659. U . Etral . RR 2 . 207. State, Moscow, Joint Press Reading Service. Moscow Dail Press Review, no 29, 29 Jan 52. U. Eval. RR 2. 208. Ibid., no 23, 23 Jan 53? U. Eval. RR 2. 209. Ibid., no 35, ~+ Feb 51+. U. Eval. RR 2. 210. STATSPE 211. id., 2 Jul 55. OFF USE. Eval. RR 2. - 61 - Approved For Release 1999/09/02 :CIA-RDP79-01093A001200050009-2 Approved For Releas~M~~~l..~~~79-01093A001200050009-2 cc CCr"DCT Approved For Release ~79-01093A001200050009-2 ~._