SCIENTIFIC ABSTRACT SIMON, V. - SIMONCIC, J.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R001550710008-4
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
August 24, 2000
Sequence Number: 
8
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R001550710008-4.pdf2.29 MB
Body: 
SMC1,19 V. SiLION) V. froductl-,n e-~tiirzte of vheat srecies. T-- 5 Vol. 11, no. 12, June 1956 ~-11 YAGYAR VEZA~'217ASAG AMICIII "-URE P#daT.est, Ifunranj "0: EA2T FURCTEAN AGGIESSICINS, VOL. 6, no. 3, Yarch 1057 0 04 0 10 Ito 01 0. '011 101 011 m of I * I - NJ 0-4 Lao P-z m 0-4 (f 11paj-1. 4. I'll, It I ~41 C ~h i~MOA M ~W.U o in J~hrjnj'ol Anal -k-. Ill. O.j. dinselric Orlertninalitin to( Mantlartroe, I., itler. I In Eltill4l ? It. 1,111)11 S11114,11 11"ll Uz'.11-1"Itl Chr".1,01 .164. P1.11.111- M t"llylvitc, 4 NN J11.1 C'# "Ill, Ill- 'At-Fe Ittlillill. Dlff(-1~1111,41 $11,411111ts 4-018111I.At" 'A,'FV U.Cd Ill J It -A.4~ fAMIld thAt tilt- dut(1111114"ta"ll its J1.1 Ile. (wrfliclut'll m prvu-n(v Ill ft., Col. N I. Ct. hi. Al. 1'9. Cr. Mg. Nit). W, tilt[ 4Ik.'Iltw-v.tFtII 8.1, Uk ct., A? a - 14. A OTAtLiArKil 4,111#A144111 CLOSINFICATicte t, 014,11,411 llra** K691t it 0 0 0 0 0 a 0 0 a & 0 0 0 *100 09_9" '00: 019 o 0 0 a 0 a 0 a 0 0 0 0 0 0 lot, To 40 :too t I Joe .111if; jell 0.. .1, -;0r0, UO n I m a 0 019 0 0 0 L0.010 0 0 0 0 0 00 -7 ductometric determination and prool LI L V. Sirnnn. jand 1. Dotclal (Inst. An-A. Chein, KAr- 510JIM.1 PY&MR, A ma'r 1952, W.Mb. Fel lex with ethylent(liaminctetraacetic acid (1) at I pli ~-Muces Ag salts to elemental Ag. This reaction has been used for POLentiornetric, pO)jT(WJphiC, and SP)t-tcSt detn. of Ag in conen. above 0.001M. Ilest results are ob, tained with Ag/I ratios 1-2. lfg(l), Ifg(II), Au(III),. PtLW), and I'd(II) Interfert. Herbert ?*farawctz cotnplszonlsul,~ft li, PhArmat z W W T zf 1. 1~ftllk. L-DOIrLMLV utd, ka.-9', -it 2u 1?414 n -0952)(Pub., ID53), e1. C.A. 43, 2085e.-Za, Mg ot d Cd N-H salt"I an diiectly t1frated in iolm. contg. suffici CI IM4011 with dl knd I -Na ethylenedlaminatetraac tate (1) p Y-11"f with Friocbrc=o- Black T as ran Indicator. I-IganiAlsalts- ;uredisiolvtdinemssoff. Tlieunreacted1iititratedivith 0 Cbemical Abst. Simon. VI:: ZAkL-3 Delefid, J.. and rl~ kvalifatinif smr, 1 .4; fe, Vol- 46 rnikrfxlnaly~~Y. -ttel,tv, Cv,'g-1ovetW Apr. 10, 1954 Awl. vN1. In-a 1:7 pp. 10 Kds. Revicwed ht C.4f r Li sty 47, 12 )(N Analytical GhemifitrY CIHALIK, J.;DOMAI, J.;SIMON V -ZYKA, J. - 1" 1-1 1- Determination of thiopental with silver nitrate solution. Cook. farm. 2 no.2:43-47 Feb 1953. (CIML 24:4) 10 Of the Institute of Analytical Chemistry of Charles University, Prague. onalysis. V. Deferswilaucin 04 Inagrierrium. I 110-il J. 611alik, 1. Notiv $1twitt it.1 (Ccwk,,sl. haroomi.. lfj.*,3. 2 16% MU-IR5~ h"Pt"he ,~j Yk. ICI .. Ahw lN-,. 20,359)~ - Nlagllc~lulll . hate -it dfl,,dd,! is di mill s-lv,d in watt Awt thc :4.1dition 4-1 f, to 8 mi ot linifer soln. at Ill I I [I alul V,mKim,one Mack *r uraimtjr. utrated with 0. 1, M %lilo. d -millilevull. --do1w are vil In tilt tilt lillium flualltity if "'11C. 114A. and the LiAller alul ill: ;Ire then Ailed. Ntignt.itim can be tlet~rimm I I" mixtures With N;L.Stj,. NUCI. X.A.CO', suct"... ~r citri,, acid. th,, enur is -,~ 0-ho per t:cat, L. 4 Ion 6,111,pit! 76 Hi 1 ;~l f.-, 'd in %0 mi ut water, 1,1(1 (1-1 M %I HI ~;I.L (ift~o-.t 21 iril in jxct-n4~, etiv jr,j) cf -nt~.yj l'td ~ct,n and uj.. NIf, luln, to gi%,i 1% fi~int, 1101!014 CukUr.." 'IdICAtOf ;1113 I'L*61e thO Add Lrimlixoritc Mack T L exceds of C6111PI'sona I'll Nvit). 13-1 U ~taSO, uarJj tbr colour clhzngt~ fropi to wina-M. an AJalvs~s ni powdcri or t.1M.U. tbo V~pplv diwlvodb~ 11'.0ing With a little Conc. th) c4oled F,041, On,5 d1up Gi tnethyl led iq OtitA dded an'l thtt "YF4 is r put3 Ma. of Al~ prror, 4,- b. mid tor ph"rrpsrAqWA1 ,I -PO70 1 ~" %-t Z /V 14 lexometric'fitmOoni in 'phamacieucaT -analysW- On!b'il, J. 6halik, J. DoWil, V. Sinton, I/R.CPH ,~nd J. Zfka ,q,p(Charh UDIV., Prague). Pharmax-ss-Ir.--561-'72(1953).- A review with 14 references. w Metallurgical Abstracts July 1954 Analysis *Use of 6mplax-one-s-in MIC4. A XXXV -A alllati" Test for 811var R.'PHILYAolefal, and V a7vz-ar c0 odov. Chm. Commun., 1953 18, (8), 7ir T 1-7ay-41n E~njolixhj. Cf. ibid., 1951, 16. 573; M.A.. 20. 882. Aspottestis escribed for the detection ofAg. Theroduoing pov er of FeSO4 is increased by the suldn, of a soln. of Nu, ethylenediaminetetraacetate (complexone 111). the complex formed between the latter and Fes~ ions being much more stable than the corresponding complex formed with Fet" ions. the most favourable conditions being atpH 3-6. Oneortwo drops of complexone III are placed on a spotting plate, one or two drops of Nz acetate added as a buffer. one drop of the aotn. to be tested, and finally one drop of FeSO, soln. A black or grey coloration indicates Ag. Limit of detectiou- L'11,.Wi, v. "Use, of' in ct;e-I.ACIII, firjOysi"'. XXXV] . New II.etky] !'or th,..~ detection of sliver. " ceskos.ovenska 'orfololoie, Fraha, i0-.. 4-1"p NO. 11 jail. 1911". -". pe. SIO: Ea:.tery. ;1I'Uj,DPeI.II) Acr-levAons 'ist, Vol. 3, iso. I , i,ov. .11)54, i.G. Chemical Abst. Od* of am Vol. 4,8 No. 6 A1'hx1fk!5j&n Vladimir Simon. and jwv. Mar. 25, 1954 Ma Inorganic Chemistry NHI. MMUs, N(MMOII)s. C4HuN4.. and HIN NH1-HOCO(CHOf1),COOH, (1) solus. hu been For the pola!ojraphic deta. of Pd to the presenq.( IROMM AWL Simon, V. ----------- MS. use of "Mokma in 4=61011 subd-L 1-13a mild VL ftnalled I=ly and po M at VH 4 66 $4 (at Wof Whe Irpuss F*Y~ which the redox potes 10 -1 iso-117'v) with Peso thoplemerAg -- -- - re-M. 5 to Joe us at 41 add .111 (1). Proc4du 9 10.1 M I In an swount Adjuet ttMpopplt 6& Ag I ratio of I to 1. with an acetate buffer (3 to ?Owl . dil. to a Ag' poucn- of 0.003 M and titrjkte vith L M Faso, to M, of pb, ao= Co. So mg of BI aad% Mg of do clot in . Provided suffident I Is added to* bind thew usetals. G. GLAaaa SUICN, Vladimir Chemical that. vol. 48 Apr. 10, 1954 Ilectrochenistry WIlao" MM take pad In the Au~+ e+-ed the presence .0 V 2111. P +,X lm -0.65 T. apk* tin I The formation of the Pd*+ cmpkx than that of 1. V. P I Main. OW saw Maisie lb". 1315-22i-Tbe 'ft. VA. LU. I , As. Z ~8-.. M, Mo. ard Zu In various sakta. J cc aw compiezone I it a" IV amunarined In a tabk;i Q-we" pt 01 conel. not, to -kU faster w of A*. Pd. ~e. Cr. Ch. NI, !r eompoom b 9. RnWs W-1W `V 'MI, CZE- C 11 Plibil '&WysU. VM Dellimfullon of Its& R . , ' Cib lLk t D l Simon l V d Zft a o a . o an s j. , J. 16 - Ro f ma 11- 3 lium (CoA l i 1954 84 Be - ci . or c.. fera . , , j A.. KAim,. 1964, Abetr.'Pu. 46,924).-Lead is datannined in (C%COO),?b.1lI,0, PbO, ' 2pbco"Ph OH)" 1=4 Plasters and ointments ccm- M com?ound% ?'y treatment with an exceac tslnlW of EDV A (disod Unx sA%1) and titmtiozi td the sicaw i h Z S l l l ead com- W t n n. A samp e of a pure O, k) pound (50 mg) or of a lead-coutaining phama, ccutical preparatio 3,11 to 0-5 g) is dWalved in 3 and to 10 MI of 0.1 M UTA (dleadium salt) soln . diluted to HOW; 6ml of sq. NH,-NH.CI buffer win. (pH 10) add Eriochruma black T indicator (asixture with Nacl, I + 200) Oxe a4dod Lad UM solution to Wratod;with 0-1 M ZuSO, sola. until Mik coloar chtp4 to wfa6-md: E. 144yxs 1 .51mott I/ GjH&LIK. J.; VOLRZAL~ J.; Simon, V.; ISIRY. V.; ZYKA'J. ....... Polaromrtric titration in pharmacoutic analysis. 7. Determination of cyanides in aqua laurocerazi. Cook. farm. 3 no.4:136-137 Ap 154. .1. Z Uatavu pro chomil analytickou Larlovv university v Prase. (CYANIDIS, determination, Opolarometric titration, in aqu& laurocerasi) Al v PRIBIL, R.; CIHA1IK, J.; DOWAL, J.; SD40H. V.; ZYKA, J. Complexometric titration In pharmacautic analysis. 711. Determination of insulin xinc. Cook. farm. 3 no-7:242-244 Sept 54. 1. X Uatavu pro chemli analytickou rarlov7 university v Praze. Z Tyzkumneho ustavu pro farmacil a biochemil v Praze. (INSULIN. determination, sinc insulin, complex titration) S/A/ 0 A// ,,-I~-~~nnd polarometric study of soalt twisk mfTITF---VT.--;-)electlYe po -!Arographic deter T-W stion of -b) jilalik, jais Dolchij, Vladimir Si ", :111(l L461-1 FLIV-1 f;va rNG. A,r ~C'I. 11 Chem. "Thv 0.13,11- uthyleiiediantine tartrate aud OAM-Naall,(), solit. is at stfloble electrolyte for lite selective iletti. of Ass. Sime tither metak cast be drtil. shmiltmipotolv~ A graph of polarographIC stwOril and 11 table IJ half-w.1ve potetiliall of 22 tnelnis its this suits. sart, givria. H. Urd&- Wt for selenlum nd t'lluri'll-, V. '~;ftv.q v- Grim 1415-NI'J". va rcibiceli v'Uh m. Cie, plm:lcf. of (M) to fal S': a PH J. Te~).-- to ,1,44, Tv at 1,11 11). Th-'! reaclium, ~m! Fvit'llAe [tic the jg,,7~ggg V~92. Detildlon, iuA 04lartniuWa o1 selaulum WMOMblexalL V. I.-Amon and V. Grim fl(Aflovy W-16., Pr U, MHoslovkiA). Chim. Listy. 2;- 1964. 48 12 . Gi774-177S.-Undat acid cantlitions. selftatas n selenitos wo reduced by ascurbic Wd to red Be Quantitatively, So (r, to 30 mSL-O.,%bv, determined by polarvaictric titration at witb 0-1 N &warble add In sWalluns adjusted to pH I to 2 by means of dil- 11CI 4Er metals i4tarlere. =,. NOL40 Copper must he Wed by tn. as CuFe(CU), and Fe masked by mean.- of .F. The reagent should be sUbiti" by tbe M addition *( 0-1 g a( EUTA (diemllum salt) and I nit a( formic acid per litre. G. (;LASFK e-LonditalLm of d of- ,H,01"1:lllomr4il"lw4ith~hydrocuin one soltit X,CrA in acid soln. Avith diphenylainine soln. as indicatoror Potentioluetrically. By exact diln., O.OIN and 0.001N 50111s. were prepd. Thtic sulzis, cbecked at iatervab tip to 50 days showed no significant change in tPer, althnugh after 2 wetks, they shosved some coloration. At pit 0-8. ht the presence of NaIICO$, I iF reduced to iodii!,! according to the Nuation C,11,(011), 4- Ii - CjIA + 21- + 211+. With 0.001N soln., 10 -y of I was detd. potentionictrically. In 20ci'o lf3SO# or 15% IICI. free Cl and hypochloTite are re- duced quantitatively. Q. IVJjargrcjtv"- ;19 d A;j 1,vir-i. aa. IM G.(~)IN) art. vlMt;~Vmlv A-iblv fo. Wrft, USPLI f0r Cle volum, trir dttn, (,f -mct C.vin;)~ lind ani")III 1), indlinfiva, Ind im 'ri-re cwio, vi-,luxt irdkaticm Mol? Ph"N'll (or tiAinc w:l% det'j. lit pit (1-8 In 0.1-0.ill IV softij. culllg il NOICO, ill IV) nil, ,t lbe l1q; id a:i Vie indi"ll-ir drtn~ of fir W;Z~i cirrico 4311t it? Iticl or III )nL7, I WIX), in '~a lilt. v J.. k1le cletn. of Cl In ~O nil. 2~elZ. HtSO. (or lVt, llcl. Mot- wlistktd. ill I-WNQ IICI or 21% IfoFP41 10,- ill 11131 )" 11CACN).- - 41,50% 1ji,!41 Illave-L 14 2G-3llInl.NvithlI:1mIIl. Ato W-t4 tit Vat"I tj!t AuCij ill ~0 tril. v(ij. zlt pli It ijt%d at ('it. tri, C,., i1t), fir, 141t, ritIj Ir 14) 11"t ilit, rivie, Pit awl PC do; VI.. call lie lv,*A~4 witli Crvits (Icid. irt 11,Y), t,r JIC) it v K:.jF_ of 04)- 3Q0 tni. lit tildpx'llp to 0, wildl MINI! a., c !1-.' rat,,r. Ni, Co, M it, Vb, So. Ti, W, Cu, Zn, Col. Ali and Mg (to not intutcre. A largc "cem ril FcCls rtitpqt be masked it with IfIN4, Cc I :Ind VO,- filtuftre. VO,- was dr(d in 2017, 11,50, Ivith MIMI, Ce4+ in 20"'o 11,50, with fvrr vI 15 111 mixt f i 0 jo l l ! I i +* - . - f t) y it ct. Cr ts ster , ju g. To ( 121V (1~90. -ind 5 rvil. HIM, (4:5), after In 5 m 7.51V 11NO., cvap~ tile sioln. On Me stc.-Jil liath unt white Itiflit.-S E1111p,w, dif. to 290 in:., add JQ mi. 151% ( NJWr- -4 lii(o, (joil NVWI 2 mi. 570 Nacl, dil. (it ZA nil., and titrabe a - W.Tril. aliquot ;ifter the a(ldn. of 10 int. 18N HiSo,. To 1% clet. v divu'lvc I g. of 11 iitce), fly brOng with 30 ru). 1. 4 I aud r9 vil. 11`1110i (1:2j, dil. with 22M triL I It) j(M ith 11tristy %0 f V%tflo. if) it role -IN-ohnim -ifter 1-2 min. wil-h l7v c"lor, Own rrvw~. WJ I). "t (01' 0-, all(I t i I ,I t r aftq,r jillin; I I IS( ). to reach tile concti. ZECHOSLOVA-M!.~.nalyt. i c ril Che:rLLstr,,, - Analjsiz; of lnor,Sanic G-2 SuIbs Lancee Abn T,jiir Referat Zhur No 2, 1957, 4-,81 Dt?le:~al J,~tjj, _L)JU)jj_Yjx6jjmjX, ZyRa Jar~jslrtv Titic MIcrG-DetermtnaUori of Cyanides in Bi~ter Ilmonds Water by ViEual Titration. Orie Fub Ceskosl. farmac., 1956, 5, No a', 339-34o Ab~~tract Me i,-iethorl ir., 'Cased on the formation of a relatively stable cyanide complex in ammoniacal medi=. 1-5 r-LI bitter aLaond walker are diluted with water to 25 ml, I rai of amionia anad r.,orexide are wided and the red- violet Golution is titrated, with 0.01 M sol-ation of NiS04- Just before reaching the end poiat the solution is orange-red and on addii-Ion of one more drop of the titratLzir, solitt'Loil the color charCes, to yellow. The methol fields a:!ci:ra-t,2 res~ilts. Card I/ I - K) - G, - ~bs Jour R,jfcrat 7hur - Mhimi.a, No 2, 195'1, 4652 Authcw Si.rGn, 1'. , 2,yka, J, InF,t Title flydroquinoue as Ct flow Ori g Pub Sb. chjk~osl. khw. rabct,, 1956, 21, No 2, 32'j-338 Abstract 3c~c~ RZhKhim, 1956, 56338, Card I/ /I - rS - 7 v V. eagentL 1110n an Y.UIOVA my., Ue, Czec; a). csitcb Che"o. COMMU".. to , 81 67 i-avl_ Some compounds U~W M vtf fr:q : photographic ddevelolix-re ba metric tcagcnts (Chem, Mity, 1904, 49, 1 U6), -aml the para-substituted phauols (metot, P en I p-phenylenodiamitie) react stoidt--iome the factor of a 0-1 N goin. remains conitant foi two months, although the solu%ioas discoloar. The end-point is bftt detected potentioractrically, but fndicawr3 may also be used, Iodine (down t* C'c so gg) way be determined in NatCO, solutla*4 C1 dow to in HCI or HSO solution, and tt",10%, 93rO, 60~,, HO or 10 to in 10 14S0 %by the VO,- and 4 M titratAd, with diphanylamins or Orraia as indicators. Two potential steps asre found dvAn# the reduction of geld solutions, dependirg on thi coriditions, conupandiag to tl%a reduction to We uvivalant state and toth* metal. Ironinmedmiq quantity does not inmiere with any of the" determina tiou, and It pm4ent In ILrX* excqn may be CzMP!ex.-d with F- of P041-' P. S. 6% tont. m c n " m " en VtrSt c p"do as reduct tric t N~F~ir ar, d J7 -4e - I .-P- e 1950), - 1) %;? and p-HOCjHdNj1 I (u1) c. t (W) were u successluily T, ~ s. The sulas. (0. IN) of 1. he analysis of inorg. compd 11, and 111 were quite stable though darkcaing. Thetiterot I dki not change after 2 munths-, U and UI showed tigible change after 3 weeks. Iodine was best titrated CO in a soln. of NaHCO.. ebloramine T with all the reagents in HCIorHSO,9oIr4 BrO -with Win 15%UCI. Fe(CN)4---, with I and TU, Cr - - i ~5;. ' and C " with KTtRnlsir. with I U and U1 was le-m ad,6 sntmzvous). and Au ... with 0 Uli at PH 6 and BD*. Au could also be titrated with 11 In Ob- o IICI. Peq+' Interfered with tht detn. of Au if present' I In L 10-fold excess. P- had to be used for snasking. Ortho- and Ineta4utialtuted in:)pheuolj were -dibask phenols -x am fc;jnd uwaltable, as volumetric. reagents. IJJAEk~ L Ma 1~ 1101. Use of go agenta. an!l . ~Zka, rt, paixr wis been riibllqhc-,l in 50 p), 3MVJ C,c,rm;tn In Call. CwA. Chem. Commuti.. 1086, 21. 571 Atial. AbSIP., 1057, 4. 2). UKA CZE'CHOSLOVAKIA/Analysis of InorC.,inic 3ub-,,tnnces G-2 Abo jour: Ro-L Zhur-]:himiya, ;'o G, 1957, 19579 Author Valdimir "Jii,wii, i~uf,,-unio Fri,)latova Ills t : -~:- Titlo Col-ametric DotcrviLnntlor, of Urrmiwm w1th Appli- cation of 1-'erricyanido Orig Pub: Chel;i. Listy, 1956, 50, 1i'o 6, 907 - 910 Abstract: Thu salts of U (6-j-) (155, - 1-70 mg, of U) are raducod using 31' Zn amalgaa and 5'. 110scii, In a geparating funnel to U(S04)21 the solutlon of which is stable in ai ~4 5 hourL;. :~ftur tho mnoval of the amalgam, tho U solution is noutralizad, with 3 - 5 g of 11"111C0,3) 2 - 3 6 of 1:CN ~nd 1 g of N114C1 are added and Tf is oxidized to UO 2+ vilth 0.1 n. solution of C,,ird 1/2 - E-1 - C--',-,C'iu~-LC)",'Al',IA/Aiialysis of Inorgan-ic bubstances G-2 Albc Jour: Ref Zhur-Kiii.miya, No 6, 1957, 1c)579 If Fo ( C N) by tho potentiometric method at 18 - ~A 0 "-)b and L tho air in acgordanco with the oqua- tion~ _ 47 . .7. U02 2Z-Fo U4 9FL, (C 11) ~0 - + 40 H- Z; (C~ t r a~ + 21120. Tne angular fac o the in- flee ion point ir. abotit 1400. Pb, Bi, 9U. Sn, As, Sbj Zr, Ni, Co, Cr, Ca. M,-;, Th, be, WO 4 - And littlo amounts of Ti, Fe '~'nd Al do not intorfore. The intorforinF, irfluanco of a large amount of Fo is chL.,cked by tht) adlition of tirtaric or citric acid or F. Ag, Cd, Mn, V and Ca interfere. Tho dascribod .-iati.od was appliod to the determination of U in ores. Card 2/2 - 55 - CZECHOSLOVAKIA/Aiialytic Chemistry - Analysis of Inorganic E-2 Substancest Abs Jour : Ref Zhur - Khimiyap No 10) 1958., 32162 Author : Jan Dolezal,.Vladimir SirDn, Jaroslav Zyka Inst : . : Titration witl_~~ Title L Otassi!um=ide Solution. Orig Pub : Chem. listY, 1957, 511 110 5) 880-883: Sb. chekliosl. khim. rabot, 1957p 220 No 6, 18o5-18o8 Abstract : The complexometric titration of Cu2t'-and N12 *with 0.1 to 0.01 M KCIT solution in NH OH medium with the use of imurexide as an indicator is 4escribed. Mal, Hg2* Ag-i''Au"tand Pd2-t-are determined even in very low concen- trations by an itidirect method - by the titration of the excessive KCIT with 0.1 to 0-01 M NiSO4 solution in the presence of the same indicator. This titration method is very accurate and it is suitable also to the determi- nation of cyanides. The direct Ili determination in Card 1/2 CZECFOSLOVAFU-/,'u~alytic Chemistry - Analysis of Liorganic E-2 Sub5t-ances. Ab s Jc ur Ref Zhur - IOUmiya, No 10, 1958, 32162 c,cneentrationn, up to 0.01 M., as woll as the indirect Cu detc,rn!jrv-ttL(.,-- are not so advantafcousi Pd Is dctemi- ned. in the ~,:rpseuce of Ir and Rh (but riot of Pt), and 1[g and Ni are determined in the presence of Zn up to tile ratio : Zn ~~2 : 1. The sir.:ij1t=eous deter- Mirlr_-t~.On of Ag-rand Cu2-'~in mixtures is possible, at which ozcasion first Cu is determined by titration with coriplexone III solution in weakly ar.=Dniun medium, after which Ag is deterrained by indirect titration as descri- bed above; murexide is used as an indicator in both cases. Card 2/2 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1958, No 17, 57214. Author Krejzova E.,_ZJM2Z_V., Zyka J. Inst Not given. Title Titration with Hydroquinon and Similar Reducing Agents. IV. Determination of Azides of the Ex- change Precipitation Reaction. Ori- Pub: Chem. listy, 1957s 51, No 9. 1764-1766. Cj Abstract: A method of determining small quantities of azide (A) based on the exchange between A and A92CrO4 is described. Since AgN~ is less soluble than A92 Cr04, when a 8uspenst n of A92 Cr04 is added to an Card 1/4 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1953, No 17, 57214. Abstract: A solution, the following reaction takes place: 2 NaN3 + A92CrO4 = 2AgN3 + Na2CrO4. An equivalent A quantity in the filtrate is determined from Cr04_, by titration with the solution of hydro- quinon (I). Due to a lower NaN equivalent (lee of 0.1 n I corresponding to 4.31 mg NaNI) this me- thod is more sensitive than that involv ng the direct titration of A with AgN03 solution (lcc of 0.1 n AgNO3 corresponds to 6.50 mg NaN3)- In de- termining A, the analyzed samples, containing ap- prox. 3-60 mg NaN3, are dissolved in a small volume of water followed by the addition of approx. 12 gr of pure A92CrO4, and of 1 drop of 2% KNO solution, by the dilution with water to 50ce volume and by the filtration. 25cc of the obtained filtrate is Card 2/4 26 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zilur-Khimiya, 1958, No 17, 57214. Abutract: then -acidified with 20% H2SO4 (20cc) and titrated (With the use of either potentiometric or visual methods) with 0.1 n I solution and using diphenyl- amine as Indicator. The above method is also suit- able for the determining of Cl-, Br-, and I-. Pri ciple of this method is also applicable to the S04 determination. In this instance suspension of BaCr04 is being employed (Ref Zhur-Khimiya, 1957, 8534). In order to obtain quantitative exchan6e involved in the latter reaction, the reactants are acidified with hydrochloric acid up to approx. 0.1 M concentration, heated for about 10 minutes on a steam bath, neutralized with NH 3 while hot, kept Card 3/4 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of Inorganic Substances. Ab5 Jour: Ref Zhur-Khimiya, 1958, No 17, 57214. Abstract: for 8-10 hours and then steps similar to those of A. For Part III refer :L96oo. Card 4/4 E-2 subjected to the analysis used in the determination to Ref Zhur.-Khimiya, 1957, 29 CZECHOSLOVAKIA / AnalYtical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1958, No 17, 57163- Author : V, Kre jzova Es -a4jaq .p Vos Zyka J. VIe Mras L., Simon V, I 'Zyka J. Inst ! Not given. Title ! Titration with Hydroquinon and Similar Reducing Agents. V& - Determination of Cerium in Pharina- coutical Preparations. VI. - Utilization of the Exchange Reaction of Tetravalent Cerium with the Salts of Divalent Manganese. Orig Pub: V -Ceskosl. farmac., 1957v 6s No 8 38-440- VI-Chem. listy$ 1957o 51, No 10, 10-1831. Abstract: Ve - A new method for determining Ce in the Card 1/6 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1958,, No 17, 57163- Abstract: "Vomitin SPOPA" tablets, that contain cerium oxalate, and the "Khemotser QOTIKA" solution., that contains cerium nitrate in the mixture of sodium eacodylate and nikethamide, has been developed. The method consists in the oxidation Of Ce(3+) to Ce(4+) with persulfate in an acidic medium and with the aid of Ag+ catalyst. Ce(4+) formed Is titrated with a solution of hydroquinon (I) using ferroin as indicator, In the determina- tion of Ce, presdnt in the "Khemotser" preparation, it is essential either to destroy beforehand an organic complex (by combustion) and to remove Asp or to mineralize the preparation, or to isolate Ce(3+) as an oxalate. The latter method$ probably, is the most convenient one. Titration determines Card 2/6 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances4 Abs Jour: Ref Zhur-Khimiyas 1958s No 17, 57163- Abstract: the true Ce content of a sample, whereas the weight determines content of other lanthanidess Presence of La and Y in certain "Khemotser" preparations is established by means of spectographic analyses* The described methods are considered suitable for control purposes. VI. - A method for the selective determination of Ce4+ in the presence of strong oxidizing agents (Cr207 2-,, in particular), has been developed. It is based on the 2 Ce4+ + b1n2+ + 2H20 = 2 Ce3+ + + Mn02 + 4H+. An analysed solution that contains, Card 3/6 CZEC11,103LOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1958, No 17, 57163- Abstract: along with free H2S 04o 50-200 mg Ce(SO4)21 is neutralized to 0.2-0.4 n acidity . 20 cc of con- centrated K2SO4 solution is then added (the total volume of the solution at this point should be N< 30-40 cc), heated up to boiling point, 20 cc of 0.1 n MnS 04 is addeds boiled for a short tiine, followed by the precipitation of Mn(OH) 2 and fil- tration. nder described conditions the reaction. between Cog+ and ?An2+ proceeds quantiatatively, Is selective with respect to Ce4+, and MnO(OH) 2 formed precipitates in a form readily separated by filtra- tion, The determination of Mn(4+) (the quantity of which is equivalent to that of Ce4+ present) in the Card 4/6 12 CZECHOSLOVAKIA / Anslyti6al Chemistry, Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 1958, No 179 57163- Abstract: residue is conducted either by an indirect or by a direct reductometrioal titration with I solution, or by the complexometrical titration method. In the former case, the residue is dissolved in 4 n H2304 that contains an excess of 0.1 n solution of I. The H2SO4 concentration is increased to a level of approx. 2 n, and the excess of I is backtitrated with 0~1 n Ce(SO 4)2 solutionp while resorting to either potentiometrical visual observation of an end point obtained with ferrion indicators The direct potentiometrical titration of Mn(44-) with I Card 5/6 CZECHOSLOVAKIA / Analytical Chemistry. Analysis of E-2 Inorganic Substances. Abs Jour: Ref Zhur-Khimiya, 19589 No 17# 57163- Abstract: solution in 2 n H2SO4 is not considered asjsuitable. Tn the second case, ?Ab(4+) is first reduced to Ym(?-+) by means of adding (NH20H)2H2S04 solution. An excess of 0.1 M solution of complexon III is then added to the solution together with the buffer solution (ammonical solution of pH 10) and an ex- cess of complexon III. The resulting solution is then titrated with 091 M MgSO solution in the pre- sence of "eriochrome" black T * indicator. Cer- tain cationsp adsorbed on the MnO(OH) 2 residue, in- terfere with the titration. 2- The strong hydrolizing ions also interferee Cr207 , VO3-'v and No3- do ot For Part IV refer to Ref Zhur-Khimiyap 1958, 72i4- 9 Card 6/6 13 CZECHOSLOVAKIA/Che.-aical TechnoloMr. Pharmaceuticals. H Vitamins. Antibiotics. Abs Jour: Ref Zhur-Xhir-,., No 24, 1958, 82711. Author Krejzova E.,_Pirqn V._, Zyka J. Inst, Title The Oxidiraetric Determination of Tartaric Acid and its Salts. Oria Pub: Ceskool. farmc., 19561 7, No 2, 82-83- Abstract: The indirect oxidiretric determination of tartaric acid and some of its salts with FC2Cr2P7 and with salts of Ce4 was investigated. The best results were obtained with K2Cr20-7. The conditions were found under which the mthod can be used for volu- metric deternination. The excess of the reagent Ccrd 1/2 CZECEOSLOWMA/Chemical Technology. Pharmaceuticals. If Vitamins. Antibiotics. ilbs Jour: IL-f Zhur-Khim., NO 24, 1958, 8L>711. is titrated potenticretrically with the standard solution of hydroquinone. Card 2/2 21 ,~;DR / -j-alytical Cliemistry. jap3lysis of Inorganic E-2 Substances. ,,bs Jour: Ref Zhur-y-himiya, 11o 1, 1959, 932. 4. uthor Uraz, L., ~~imon V., Zyka, J. Inst Not given. Title Titration With Hydroquinone and With a Similar Reducer. VI. The Utilization of the Reaction of Four Valont Cerium ~','ith the Salts of Di-valont Manganese. Orig Pub: Collect, Czechosl. chem. commun., 1958, 23, No 6, 1061-1065. .""bstract: See R. Zh. Khim., 1958, 57163. Card 1/1 C trj : --zecboslovak.4a G ry ; Analytical Chemistry - Anp-ly3is of InorLanic Oubotiuicez AU3. J~-ir. RLf ::biu'-rjdmIyx$ No 6, 1959 19105 t-lr'h~'Jr Krejzovaj BI.; Simon, V.; ZY'Kal J. Ins!"Itut. - ------------ Titic Titra~tor with arld jIntilar Re- ducIng Agents. VIII. Potenti cmetric Determi- .3-Valent Th-.tiiL;m c'alt. nation of 0 1, 1 Chem. listy, 1953: 52, No 5, 936-938 41 bg'j r:~. c t;Iydroquinone is used as a rk;duc:L-Lg agent in potent I oms~ tric' determinat ion of T13-1. Oxidation of -Jl+ plor to analysis cart be effected with 0102SPOF In acid medita; Br-w~Ater usually utilized for this purposc, is not suitable, The solution to be titrated must contain 5-20~6 by weight of F12SOI-, and 3-33 mg TI, and Its maximum volume should be 30 ml. On determination of TI, approximately 20~ solution Of E2804 is added to the sollrtion being arialyzed, in a 50 ml beaker, diluted to about 20 ml, added about 0.5 solid M023208, heated gently for 1.,-20 miriutes (finzAl o-=e of the solixtion should be abouL 15 wl), and after cool.inr, it is pott--ntio- mecrically titr--,ted with 0.01 '1! solution of hydroquinone. Card: 1/3 z e e r., 0 S I OVAa E-2 C"~- t "i'; Analytical Chemistr y - AaalrjiB of inorganic Substances 19105 I,.bB, rtf 2bur-mimiyal No 6., 1959 Aut, 1 ) ln3tituLs TILIc Ori~-,. Pub.: Abotrc*.c t : The Inflection point is Lt about 500 mv (relative 4o saturated calomel electrode); change in potential at ~e uivalence point is well defined (angle coefficient about MO. Determination of TI is n k, 3t interfered with by the lpresence of CU2,t Pb2+t Ag+t B + C02+ Zn2+ A13+, Mg2+ 9 V ii I ,As5+, M001,2- and W042-, even when they are present in 10-fold eXCesst also no interference results from the presence of ~considerable amounts Of P043-1 N03-1 B04 2-, and Cl- (up to a concentration of about 0.01 N). The presence of Fe34, Sn4+, Sb(5+), Hg2+, Cel++, Cr207 2-1 Mn04-, interferes as does the presence of even sy,-,all amounts of Br- and I-. Por reasons Card: 2/3 E-21 Czechcs1ov&kia Anrdyticra Che::dstry' - -Azwlysiu of Inorganic Substances P~f Zhur-Mxird4m, No 6., 1959 19 F 077 t Krejzova, E.; Simon, V.; Zyka, J. Titr~ttion with hydroquinone arid. Similar Re- d,-ii-ag Agents.VYI. Determination of Eigher Oxlits of Manganese arid Lead. Grir Ch~ N b. e7a. listY, 1956, 52, 0 5, 9'7(-c-'8 b st rLA k t1t.rimetric metf,od was developed for dettrmi- nation of MnO2, Mn2C)3 .111e. Pl)()2, which Is based oa their re- ductior, with hydroquinone (1) and sub.;,~~quent titration of excess I with CeW,,,12, usinf ferroln as indicator. To the finely cctrzninuted sample- (about 60 mg P6021 o~- 1+5 mg Mn02, or 40 mg Mn2(),)are added, in a titration fla~!k with a ground glass stoppe7, 10-20 mi 0.1 N solution of I ar.d about 10 ml 2 N H2804(10 M1 of '~'$ CH COOH in the case of Pb02), the mixture is shaken wi. .0 th glass beads (5 to 10) for 5-10 minute! until the sample is completely dissolved ferroln is added and titration with 0.1 N solution Ce(SOJ2 is carried out rl: 1/3 E-9 Country Czechoslovakia L-2 ci-'to"~f 01"y AnalyUcal Chemistry - Analysis of Aba& Jour. TnorswUc Substances 19077 Ref zhur-mamiya, no 61 1959 AutIv.,r Inut It,-It. TItIo s 711~ 11). Orl, I Abstr--,.,t until the color of the scluticn changes from red to briViant-blue or green. In dpteritinations of oxides of Mn the back-titration. of I can be effected with K2Cr2O7 using dipheriylamine as Lidicator, b3wever the titraticn with Ce(SO02 is more sensitive. Fe + and CL~' need not be removed or masked, since they do not reacit; with 1. By the described procedure active 0 is dete-mined in che sample; the ',*.otal metal content can be dt-termined by complexometry after reduction of the higher oxides. To do this, there are added to the sample ix, the titration flask, an excess of 111 1 - 'F'20",'-'2SO4 solution and 0.1 P solution of Complexon TIJI 2/3 _5;A1,1A), )11111VI~11~111.t- CZECHOSLOV;,Klh/Ix-alyUca! General Tcmics, .'-bs jour: pef ZIiur-JCjJ,,:;., 11o 9, 1959, 30926. Mr6z, Ladislav, Sii.ion, Viadii-.,dr, ZyIra, Jaroslav. iris Title Titration with Illydroqu"lione and Sinilar !educI116 Agents. IX. On t:tc SLability of Hydroquinone Solutions. Or'.L; Vub: Chem. listy, 1958, 52, tic) 6, 1083-lo88. ,,bs ~, ract: 'rie effect of various factors on t!)e stalility of a hydroq:jinone solutions (1) was studied b:r :,,cuis of systematic control of the titer of 0.1-0.001 noxnal solutions of 1 by visual, photometric or potention~etric titratio-a with K-Cr ,,0,7 solution or with Ce(Wt),~ solution (in the C~asc of hiGhly di- Card 1/4 C~Iz,c-,-,,OGLovtxr,/Iamlyt~-cal Clico-.i~.stlxry- General Tap-iLes. E .'.bo Jour: M-f Zhur-faiin., Ho 9., 1959.- 30925. luted solutions of I), and also by imans of photo- Uetric measurcr--.eat of the intensity of the brown- ish-red color which formed in the preseLce, of the disassociation of I. It was established that the I solutions acidified with 1-3% HISO.~. axe the Liost stable ones. The titer of these solutions does not begin to change until 3-4 months after their preparation. lirlicn, boiled these solutions retain their stability for at least 1 hour. Ileutral solutions of I have a somewhat lesser stability., but even in this case chan(ps were observed only after 2-3 nonths. The conceatration of I has practially no effect either on the acid or on the neutral solutions of I. Vie I solutions n-Umlized with the addition Card 2/4 of L-lorGI:,Iic ,bs Jour: 1~cf Zhur-Mi-.i., 110 1), 1959, 30966. :.utliar Mva'z, Ladis)-av, gii~:cjn Vla(linilr, Zyl"-, jaroslav. Inst Titl,! Titration wit.1, 1~rdroqpinonc Si,:iil--r BcducinG X. Titration of Ccriu~.i, Chro-.-,_LuT.-, caid the Feasibility of T"heir Dctcn.-_i-._atiDn Mien prosent Sirml- tancously. Or~_G Dab: Men. listy, 1958, 52, ilo 6, 10&)-1092. ,.,b st r,% c t:;cthod of %ccuratcly s;-nI). au".4-ititics of Cc, V and of Cr 'Ms boon clcvclc~cd. 71his :.,.ethod s based n-_~ t' ca ~'oi.,.ctric ti'_tratio--. c--7* Cc'l"tl j Cr ,AOI V03- C a 214 CZECHOSLOVAM,/t,nalytical ChcFdStry, ',-Aalysis of Dioroanic E Substances. ,',bo Jour: Ref Diur-Milm., No 9) 1959)30966. quantities of 11j'1004, mid the detemimtion of V is hindered by the presence of HC1. Me titratim., of all 3 of the above -mentioned ions ma be carried out in the presence of MiO&t since the jx-p -i,-, j?o- tential corresl3ondinG to Mr.0 is clearly OListinct fro;-.1 the jurr-) 1-1he ;~Otcntillls f t:ie ions bein(, .L 0 dotemined. L-i corri.,arf -scu with the mctu;iod of ti- tration. witi Fc-~I- soluUlon the hydrcquiacnc m- thod is rmch uore scisit-ive. From t*.ic cvi.:b-*'.=tions of Cc, Cr ai~d V I.t is possible to reliably deter- 1~dnu VO to-ct',ic- w-T V~, Cc 'r and sw.,cuh,-.t less c1cmrly'Cr'?O7 Cc +-f'. Si;-mltancous de'ller- -1 - and VO is dif ficult or of OrzO 7 Card 3/4 T, _n CZECHcsLOVfjKIA / Analytical Chomistry-Analygio of in,)rSnntc substances, ,,, Rof Zhur - Khimiya, No 14, 1959, No. 49229 Jour Abe Author yraz) L.;,Simon) V.; Zuka, J- Inst Not given tions with Hydroquinone and similar Reducing Title Titra The Determination of Cerium in Various Agents. XI- biLtorials Orig Pub Chum Listy, 52) No 7) 1354-1356 (1958) othod dia cussod in Communication X (RZhKhim, No 9, Th Abstract o Bl for the titration of Cc (4t) with hydro- 3o966) i 1 C n c f 959, s been applied to the detormination. o h a quinono nds cerito motal (Go, la, Pr) Nd, Y) Fo, monazito sa Ni, Si, y6, Ca~, Al-Th-Co alloy, Auer gas mantles) and during cloctroly3i'3 'Cs 12.7 - t ca In the raw material was C (W with K or ammonium t o CO (3t) is first oxidizod Card 1/3 B-15 %homidtrY--ArJalY8J3 Of 1norganIc CZJEIIOBIMAM / Azal.Yti"3- (%' substances * No~ 49229 Abe JOur No 14P Rof Zhur - KhimlYa, 19,59, E-2 . of Agi as cata'Vto and the In taoi presence 0.001 N solutions persulfato with 0.1 - 20tentiolwtric or solution Is thoh -titieto' Stabilizer. dontaining 1$ 112p4 as a ) techniques are used In the ual (forroin IrAlcator joint - The ;ro,~Bblq average via Df the ondl cations determination 1 0 IS is 10-3%; MU -I, do error in the dotormiTlati r~ i and Y, not COOP Zn2+ ICU2 1, Cd2 I Na , n present in (o g ., ~, the titration even V go awuntO Of Of interfere witl atiOns- The presence t 0 Ag + Bi 0 +) and (6 high concontr NJI(2i), two or FoOf), Pb(21.) ' AlOt), rablO c a (the first ks(5t) Introduces consido ereas the rust i), vh positive deviations, of lig(2 cations causE The)presenICO tions). Jh lative devil" - 4 , and 0 0 even Introduce nof r(V), Da(2 ,w(6+), Sb(5+), Ca(21), S o a lowering of the results* The in small 5=U'ts loads t Card 2/3 ~~Tffntkii idth hydr uln,',onod and anslo'gous -re'duckil Santa. VHI. potenAe atermination of (111) salt. H. Krel V, Simon d tiox Csscho$Tw.-Cjpvm-v man). Se C.A. 53. 3974i. L, TA~ck . 1 01MON1 V.; ZYKA, J.; MRAZ, L. "Titration with quinol and analogous reducing agents.* X. Titration of ceriump chromium, and vanadium, and the possibility of their simultaneous determina- tion." In German. p. 1487. COLLECTION OF CZECHOSLOVAK CHF141GAL COMMUNICATIONS, Praha, Czech., Vol. 24, No. 5, May 1959 Monthly List of East European Accessions (EEAI), W, Vol. 8, No. 6, Sept. 59 Unclassified 1; Fv f V i,,,i init in jpvt,~7tigating basic tl,~-,rr-j issled.-)vanic- oonoyMkL Lermodinamicim sk: h h I t..: "d k! 1 v-rty:% )l knii. Mlnsk., lzr4-vo "'v' V. I ~-, t 1 "r I r ~ 3 ~'! WN"'. 1":i~) of 6~1,3n!es, 1:147 1. j.1-eyrowsky Inatituto of PularogralAW, Czechoslovak Atudi or Sciences (for JAnor)l 2. Laboratory for Onanic Lhemirttry, LEIdg I Technical Institute, (Laborstorim fur Orpateche i-hemie, 14cig. Tachnis,:Ue Hach- schule), Zurich, &wltzerlawl - (for StwAn). 1'r%Me, ollaction of ;4echoolovak i.1swical Communications, ho 12# 1*cember 1961, pp 40TS-4094 "Aryl derivatives of hydroxylamine. t'4rt 121 Dissociation constants of hydroxmic acids and their functional derivatives." (L~eedicated To Vie 75th birthday of Acadeadclan J.HeyrovAy). 1. SIMON. Ye. 2. USSR (600) 4. Feeding and Feeding Stuffs 7. PreDaring feed crops for feeding. Kolkh.proiz. 12 no. 12 1952. 9. Monthl List of Russian Accessionso Library of Congress, Marc 1953. Unclassified. SIMON, Ye. 1. I ~ - * [Methods of determining the nitrogen balance in form animals] Metodika opredelentia balansa azota u sallskokhoziaistvenuykh zhivotnykh. Moskva. 1956. 15 P. (xIju lo:4) (Nitrogen metabolism) USSR / Farm Animals. Swine Abs Jour: Ref Zhur-Biol., No 5, 1958, 21492 Author Simon Ye. I. Inst Title The Use of Antibiotics in the Meat-Type Fattening of Swine (IspolIzovaniye antibiotikov pri myasnom otko- rme sviney) Orig Pub: Svinovodstvo, 1956, No 1, 39-41 Abstract: Of 4 groups of young pigs, the first group was fed basic rations consisting of a mixture of corn, oat- meal, bran, with 5% hay flour; the 2nd group was re- ceiving the same rations with an addition of 30 mcg. of biomycin per 1 kg. of feed; in animals of the 31d group, 30 to 40% of grain mixture was replaced by potatoes; the 4th group was also receiving biomycin as a supplement to the rations of the 3rd group. The Card 1/2 USSR / Farm Animals. Swine Q Abs Jour: Ref Zhur-Biol., No 5, 1958, 21492 Abstract: average daily weight gain for 120 days in pigs was, respectivtly (in g.): 455) 574, 537, 593. The feed units used per 1 kg. of weight gain were 6.2, 4.9, 5.5, 4.9. Card 2/2 4o VARVA~.o P.M.; KIRUPWO, V.I.; CIIUDNCVSt.IY, V.G.; Z.I.; UIMYAN, V.A.; IVAN~,V-DYA7LOV, A.Ye.; N.M.; IZAYSCN, 'K.S.; KUYDICH, S.A.; SVFRDLOV, A.I.; HOLOTIN, V.V.; GOLIDENELAT, I.I. KRYLOV, V.K.; HRAUDE, A.I.; FRANC-V, P.I.; A:31:A7kT-':, a ; 21 S.I.; SI~K.1,I.Ju.A.; 6h~- [?c)rjt-. rpvlevis and 1.1bliography. Stroi. makh. I rasch. soor. 3 no.,j:46-50 161. (MIRA 15:/,) ~ilftliography-Structtires, Theory of') HOSITI, S., dr. :' SRIONP Z. A quantitative ctudy of granupoesis and the valuation of myelotransfusion. Ked. intern. (Bucur) 17 no-5:537-5" My 165. 1. Lucrare efectuata la Institutul oncologic BUcuresti directors prof. 0. Costachel). IiLR6J-II;,/0jjtics - Lui:d;*.escc;acu# K Abs J~ur : Ref Zhur Fizika., 11o 11, 1-959, 26o66 ."ut' ~ )r : Sin.)II; Zeno Inst Titlu 0'.. 7the ~P:;ss ality Df 4',.13peara'.ice A Fluzorescence in mDlecules Ori(; Pub Stu0ii si cercetari fiz. Acad. RFR, 1956, 9, N-j 4, 469- 481 AT.-stract Ar. attempt is rmde to (;ivc a quantum-nechnnical rieth.)d A esti:mtint; the pr,),)nljility ;f Liternal c-inversixi of t.',,c cner.,y ~)f the clectr.-);i excltatL)n int.; vibratij~-al cacr_~y. The perturbatija method is used. The perttirba- tion that deternines the frequency of the nx;-radiative transitims is [,-Iven by tor-.~is ne~;Iected in the Born- C)ppc::.'aeir.,.er ap,,prDximtiDa. UsinC; the zietallic rxAcl f.-)r Cle (Ucctron functims )f state aiid tl:c 'zar-maaic ap-i?r,.)xi- natioa for the oscillation ft;ictixis :)f the nuclei, the Card, 1/2 'cc - Lurtinescei. "'bo jjur &.ur Fizikn, N3 11, 1959, 26066 K - 'ieoreticallY certain ')t t -, j,-Istify t. attcEr UA,,lir vakes issibilitY af 3ppcarance -,f err,)irical rules fDr tte 1) fluDrescelice- Card 2112 - io5 - Distr: WbAE3d Issociation of angina molecules: a theoretical he A&d. rep Populare R,-(.-- d. discussion. z * S' fis. ShAt cerct rs JU a t I L':"j SO, I.M15J.-The prcf%ponential coe!f. Of thL veliwity of the plititodkmicn. of aniline tm)1!1. excited in ultraviolet (25W-210) A.) light was ailed. The r(i, ti,mic imiL ti,ms of state are lia" ots tool. orbital%, calcd. I)v the simpir oicthi%l, The effi-et of the Nits sr"'a sidemi an a tier turhat imi (kpoodent oti tho C-m If,=* For the function of C-N vaknce vibration, the hatinouic uppro)(n. is USCd in the case of Elie excited state, and the approxit. of the potential box in the case of the fundament2l state. T'he agreement between the calcd. predxponential coeff, a ... I the general form of the velocity const. of the ph()- totli~socu. with EVI)tl. data, justifies the tbemetic-~ -hy- potheses advanced. M. Lapidat-J / V~-~ 7. radiationless. transition-. 3, 5 - 3, t V, - t 135 -i ReCerritlvnvy ZhUrnal., Flzlka, no 1 2 b ~' r, p1hys. Acad. RPR", 1,961. v. 6, no. 1, 10`7 lip) , Cic-M-1n) Tne u:;e of thp nonztationary pert~urbatlon methcd is su6ZF--:-,11ed "or cal- tie probability of radiationless transitions in complex molecules by con- ~11;1 :'unh States 11o be isoenergetic as are comprised in the en~-.rgy range to the overlapping vildened vibrational levels. Under these ccndi- ti,~P frequency d,,B of the radiationless tran5ition between ti.,,o olectron states iz- fcund ar. d~"B = 2 V&11/h, where wAB is the matrly element of non- acliabatic or spin-orbital interaction between the ztatez A and B, and An is the mber -.)f levels in the region of overlapping. The quantity wpB, estimated nithin the methol of LKAO 140, for singlet-triplet transitions was found to be of the order of o.04 ev for in--> 31-,* excitation, and of 4 - jo-5 ev for 3~~, excitation. it is noted that W, t, perature-dependent only provided tile ,,B can be significantly ten C:1vd 11", 'J1c58AP10G(VO()3A)--91G92 rwitationless trrLnsvitions ATj I/A 10 1 positions on surfaces of potentlal energy difl'er in that states A and L) considerably. S. Vetchinkin. 'L,',b5tracter's note: Complete translation] SAIIINI, V,; SIMM, Z-.. Tnfrfired "ctrum of cis-trans isomerism in coordinativv compounds. rl, Gor-rtlation between the vibrations of complex ions and those of 11- Irt--,? zomplax-forzing anions. Studii cerc chim 9 no.3:573-577 '61. 1. Laboratorul de chimie-fizica al Universitatii 'C. I. Parhon', Sectia de obimie-fizica a Centrului de cercetari chimice al Academiei R.P.R., Bucuresti. SIMONP Z. Noixadlative trarsitions, Prd luniniscence of molecules. DerIvatives of the cation of diphenylzethyl and other torsiorable arwatic systems. Studii cerc chim 9 no-4:667-672 161. 1. Centrul de cercetari chimice al Academiel R.P.R., Sectia de chlmle-fizi-cn, Ihicuresti. SMODY Z.; BALABAN, A. T. Relative stability of isomeric aromatic monocyclic systems appreciated by M. 0. methods. Rev chimie 7 , -;.: 555-560 162. 1. lystitute for Atomic Physics and Chemical Centre of the Academy of the R.P.R., Bucharest. MURGUIESCU.. I.G., acad.; ~ ON RL_j Z.!_ Computing the pre-exponentlal coefficients of some manomolecular reactions. Studii cer chim 10 no.1:11-30 162. 1. Contml de cercetarl. chimice al Academisi R,F,R,, Sectia de chimis fizica,, Ducuresti. 2. Membru, al Cemitetului. de redactiev *Studii. A cercetarl, de chimie" (for Murguleacu). MURGUIESCIJ., I.G. acad.;,-SDIOII,-Z.l Pre-exponential coefficient and the activation energy for the uni- molecular decomposition of cyclobutane. Studii cer chim 10 no.1:31-37 162. 1. Centrul, de cercetari chimice al Academiei, R.F.R.J. Sectia, de chimie fizicap Bucuresti. 2. Membru al. Comitetului de redactie,, "Studii A cercetari do chimie" (for Murgulescu). S/051/62/012/001/0011/020 E2o2/E492 AUTHORi Simon, Z TITLE Calculation of the energy level shifts of diphenyl, phenylpyridines and salts of phenylpyrile PERIODICAL. Optika i spektroskopiya, v,-.12, no 1 1962. 22-31 TEXT The author extends the L, Goodman and H., Schull method (Ref.li~- J, Chem Phys... v,22, 1954, 1338) to the substituted derivatives of benzene in order to calculate the energy levels and intensities of the transitions in diphenyl phenylpyridine and salts of plienyl and plienylpyrilium, starting with the experimental data for benzene, This type of method is particularly convenient since it has the simplicity of the N10 method and the advantages of the highly complicated and purely theoretical ASMO The author-s method is substantially MOLCAO but with correct-Lons allowing for a very simplified treatment of configuration interactions. The naive semi-empirical approach is complemented with theoretically computed repulsion integrals and applied to the compounds in question Sufficiently good agreement of the calculated results with the experimental data j-s explained by the fact that in the low Card 1/3 S/051/62/012/001/004/020 calculation of the energy level E202/r492 symmetry molec"les which were -studied the degeneration of tile energy levels is either weak or completely absent . Altogether 11 forms were studied and Cut- some of them there are included fU data of tile energy of configuration interaction. apart fruit, tile symmetry., wavelength and f-riumbers- Wave functions corresponding to the levels of the first two bands in the spectra of pyrilium derivatives are also calculated, Acknowledgments are expressed to Doctor A,T,,Balaban of Institute of Atomic Physics (Bucharest) and Doctor V,.Ye..Sakhin of Ehe Physical Chemistry Department. Bucharest Universxty imeni K,.I,Parkhon for their discussions and to Doctor I. Zamfiresku of the In5tLtute of Atomic Physics for assistance E Keplinger is inentioned in tile arttcle. There are 11 tables and 12 referenzes 3 Soviet-bloc and 9 non--Soviet-blue, The four most recent references to English language publications read as follows Ref.2~ R,, Pari-ser. R.G.Parr- J Chem, Phys, v,,21, 1953 466 767. Ref-3 I1,C,Longuett-F1_l_zgins J .%,' Murrel. Proc Phys Soc A68 1955 6oi Ref 4 as in teNt Ile 1' 7C A Coulson Va I en ~, eOxford 1953 " I I- d -1 / -) S/051/62/012/001/004/020 Calculation of the energy level E202/E492 ASSOCIATION: Tsentr khimicheskikh issledovan-Ly Akademiya Nauk Ruraynskoy NR, Bukharest (Centre of Chemical Studies, Academy of Sciences, Rumanian PR, bucharest) SUBMITTED; February 23. 1961 Card 3/3 S-DTOI",Z.; Bi'IABU:, A.T. Simple Mickel IM.O. treatment of electronic spectra of some aromatic heterocyclic compounds with five aton cycle. Studii core chim 11 n0.1:53-60 163. 1. Institutul de fizica ato-iica si sectia de chimie fizica . a Centrului de cercetari chimice al Acadomiei R,P.R. 2. Membru corespondent al Academiei R.P.R. (for,Balaban). MURGULESCII, I.G., acad.; Z. Fhotochemical reac+~ions and nonradiative transitions of ketones and aldehydes. Studii core chim 11 no.2.-161-170 163. 1. Sertia do chimle fizica a Gentrulul de cercetarl chimice al Academiei 1R.P.R., Bucuresti. SIMN, Z. Pre-,exponential ol thermal decompoAtion of diazo derivatives. Stsidii cerc chim 11 no.2:171-173 163. 1. Sectia de ohimie f4ZJCa a Centriiiiii de cercet-tri chimice al Academiei R.P.R., Bucuresti. STMOll ) Zeno Third Union Conference on ~,uantic Chemistry. .-Audii cerc chim 12 no. 1:87-90 Ja 164. BALABAN, A.T.; SBQ4, Z. Arcciaulty. Rev -Ai-mie Rourr: 9 nr-,.21,99-1'01.~ F 164 1. Lnbtitutg cf Atjjinl~ Physics and Institute C,,f Phl~lml ~o Chuirdistry of" +he Rimanian Acadenry, P.O. &x 345, Buchares' Z.- BREZEMIU, Marieta I Trans effect in plain oomplex compounds of bivalent platinum. Rev chimie Roum 9 no.2tll3-119 F 164 1. Research Center for Physical Chemistry, Str. Wmbrava Rosio, 23, Bucharest. SIMI, Z.; BALAM-T, A.T. Levels of energy for valts of pyr7lium with phenylic grcups sub- stituted in para. Studli core chim 12 n095:345-355 t64 1. Institute of Chemistry and Physics,, Dambrava Rosie St. no,23,, an6 Institute of Nuclear Physics, P.O. Bax, 35, BUcharest. On= n, CISMARU, D.; SlMDN, Z.; VOLAWSCHI, C. Spectrum of absorption in infrared of bisauth nitrate and bismuthyl nitrate. Studii cere chim 13 no.11:729-732 N 164. 1. Physical Chemistry Research Center, Bucharest, 23 Dumbrava Rosie Street. SIMONY Z. Monomolecular processcs in the photochemi-tr-i of polyatom-Ac molecules. Studii cerc chim 13 no.lM97-724 0 164. 1. Research Center of Chemistry and Physics, Rumanian Academy, Bucharest, 23 Dumbrava Rosie Street. F!, IN-l[l, ~~, 'I. i ~11, ltl:~ tIV ~ ~ :li:j~ : , I 0 th ". , . .f ~ "I ~ T f) -It Irl 1'. .;. ., ~ A F 'I , " UnIv . '.7(-If-ed '"-tai;nun-~tric det-rmin,-itlor. of nitrate ion." ChIm. ;cid. fcl. hune. 3, ?31-6 (1953) sur,:,;ary); cf. L,.I. h6) R57a. SD4011AVICHEiEp Ki[Simonaviciene, K.1; KAIITSLERIS, A.[Kancleris, A.], otv. za vypusk; KURIS, A., inzh., spets. red.; kBR%IATIYENE,Kh. [Abromaitiene, H.]. red.; YEFB-IGVA, F., red.; PILKAUSKAS, K., tekhn. red. [Meebanis"lon and automation of production processes in the wood- working industries; bibliographical index) Medzio apdirbimo pramones gamybos procesu mochanizavimas ir automatizavimas; bibliografine rodykle. Vilnius, 1961. 117 p. (MIRA 15:4) 1. Lithuanian S.S.R. Liaudies technine biblioteka, Vilna. (Bibliography-Woodworking (Bibliography--Automatic ukio taryba. Gentrine moksline- industries) control) - -, , :, - , , - i , , --.- , I.,L,ncr ~nf-ty anp;cto cf decigning GepgyarttEtec -"n 11 - I -_i-, 2 Vr 164. L. ('13 M III! szteri -lu"l. '10 SIMONCHAK, V.T., Inzh. Hooulte or Industrial testing or an airparizontal batch or double-chamber PKI-1365k atartera. Sbor. DonUGI no.31t 47-49 163. (MM 17110) ..r GiW,',F,OVSKIY I Vladimir Fomich; KIKLEVICII, Nikolny Antonovich; - I iv_ ich; Dritriy Ivanovich; ."Tyntimlix- Vn-qi, . '_rrafjrQy____- FOIC-11KO) SAPILOV) A.V., otv. red.; BELOV, V.S., red. izd-va; SABIA"OV, A., tekhn. red.; GUL"IENKO, V.G., tekhn. red. [Electric equipment with 660 volt rating for mines]Rudnichnoe olektrooborudovanie nn napriazhanie 660 v. (By]V.F.Grankovskiy i dr. Moskva, Gosgortekhizdat, 1962. U9 p. (MIM 15.8) (Mining machinery-Electric driving) KDAMCU, N.A~; 51MONCHAY., V.T.; FOMFNI.0, D.I.; FLOSKOGOLOVYY, Yu.F. Some shortcomings of the magnetic FYV-1365A starter for 660 voltage. Upol' 37 no.3:32-33 Mr '62. (YJRA 15:2) 1. Donetskiy nauchno-issledovatel'skiy urol'nyy institut. (Electricity in mining) (Coal mininF machinery) SI"ONGIG, B. The freezing and transportation of fish, p. 401. (Gozdarski vestnik, Vol. 8, No. 12, Dec. 1956, Ljunljana. Yugoslavia) SO: Monthly List of Fast I~uropean accessions (K-AL) Le. Vol. 6. No. 8. Aug 1957. Uncl. GiM014(cle1j- SMONGIGP J. Yugoslevia (430) Technology Standardization in the fbod Industry. p 42. STANDAF DIZACIJA, Vo' . 1, no. 3 Sept. 1950. East European Accessions List. Library-of' Congress, Vol 1. no 14, Dec. 1952. TINCU-351FIED. V 0 . 0-k _j -.'.0. SU: l-'onthl LirL of i:,-~st i~uroc-eari Vol. 3, no. 3. Librar.y of Congress. Alarch 1954. Uncl. J. Organization of transportation of refrigerated products., P, 489, TE11141KA, (Savez inzenjera i tehnicara Jugoslaviije) Beograd, Vol, 99 I-To. 3, 1954 SOU RCE: East European Accessions List (MAL) Library of Congress, Vol. 5, No. 8, Aug. 1956 or%,, ress on tiie use of ealc! tcrrtf,(- In 0, C."'; Z. ~~ I ~ C f-I-P , , U? . . . I I . - ) 2 - L Z~ . , - i , 3 , , , .1 ? r-PO7-7 I :1:- 11 Y ~' j -, j n t n(! fail CA ', ndl., E t T--,' . 11 : . ( ` '-" ~ I - - ' , ,, , L( - I r~l tr,jv . , : t of* L *,uz-( I r-in ( ~ EAI,, ) C . Vr,] is , '. (, . 1(, jUrIf. I ' , Lr, I .~ r, r_ I . -:-I C, (. !('. ~ - " !-,-- C f 1l-, ert s ir tk~e f-4 4 ndustry - f - 137 ~,,c - t I,, -.~ J , ,t cf -:;Ft -A-urolpsr. A cc ess I cn,~ ` C : . I . . 1 -w( .,:. L . ,,, I - ~ , N C . I , -, ~', -, 5 - i ( -., j~'- , jC, . 4. %;~,. 4 , Iur- 'AV~~ " 7 , ~ncl 1. ""-Nf7~ 6-! -I j. Celebration of .-Fishermen's Day in Kopar. p. 29. !'TFAR.W;O. (Udruzenje morskog ribarstva Ju.-oslavije) Rijeka. 11~1. 8, no. 1, jan. 10,56. So. East European Accessions LiEt Vol. 5, No. 9 September, 1956