SCIENTIFIC ABSTRACT SHOSTAKOVSKIY, M.F. - SHOSTAKOVSKIY, M.F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549910019-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

C-1
USSR/ Ohemistry - Organic ohemiatry
Card 1/1 Pub. 40 - 20/26
Authors I Shostakovskiyo M. F., and Gladyshevskaya, V. A-.

Title I Polymerization of vinyl.compounds. Part 2. Multistage: synthesis of
polyvinylethyl ether
PeriWiCal I Izv. AN SSSR. Otd. khim. nauk 2, 344 - 349, Her-Apr 1955
Abstract I The accomplishment of a multistage synthesis of numeroue-ethoxy compounds
including the dimer and hexamer is announced.' it is pointed out that the.
multistage synthesis was not concluded with the formation of above mentibned~
the .formation of the ~examer thereaction mixture was,
ethoxy-compound; after
,
found to contain products with a molecular weight much higher than,that of
, these-cowpounds could not be separated in individual.,.,
the hexamer. However
'
.
form because they decomposed during distillation. Eight referencesu 6 USSR~
and 2 USA (1935-1955). Table.
Institution Aced. of Sc., USSR, The 11. D. Zelinskiy Inst. of Organ. Chem.
Submitted Decenber 30, 1953

4
USSAI Chemistry - Organic chemistry
Card 1/1 Pub. 40 21/26
Authors $Shostakovskiy) M. F.; Zhebrovskiy) V. V. and Medelyanovskayap M. A.
Title I Reaction of vinyl and polyfunctional compounds., Part 4. Reaction of
vinylalkyl ethers with glycerin,"1,2-glycerin and 10-glycerinacetals.
PeriOdiCal I Izv. AN SSSR. Otd. khim.-nauk 2-350'_153, Mar-mAp
r 1955
Abstract 8 The reaction of.vinylalkyl ethers with:gkycerin~ 1,2-glyearin arid. 10-
glycerinacetalo was investigated in the presence of hydrochloric-acid.-_
The reaction products obtained and their properties are described. The
synthesis of hitherto unknown 1)3-.glyeetinacetal-2-butoxyaceta1 from
1)3-glyearinacetal and vinylbutyl ether is discussed. Two USSR refer-
ences (1954).
Institution Acad. of So., USSR, The N. D. Zelinskiy Inst. of Organ.- Chem.
Submitted January 13, 1954

UM/ Chemistry - Organic chemistry
Card 1/1 Pub. 40 - 22/26
Authors I Shostakovskiyp M. F.; Zhebrovskiy, Vi V.;,and Medelyanovskaya., M. A.
Title I Reaction of vinyl and polyfunctional compounds. Fart 5. Reaction of
trivinylglycerin ether with monoatomie alcohols
Periodical I Izv. AN SSSR. Otd. khim. n 2t, 354 - 358, Mar-Apr 1955
Abstract I The reaction of trivinylglycerinether withmonoatomic alcohols,was inves-.,
tigated by utilizing the glycerin ether in the role of a polyfunctional
vinyl ether and ethyland butyl-alcohols in the role of monoatomic.alco--;
bola. The products obtained from this reactibn (acetals) were found to be
identi6al to the acetals obtained during the reaction of vinylethyl and...
vinylbutyl ethers with glycerin. The structure of the glycerin acet.als is
described. Eigilt rcferences-. 6 USSER and 2 USA (1928-1955).
Institution Acad. of So., USSR, The N. D. Zelinskiy Inst. of Organ. Chem.
Submitted January 131 1954

SHOSTAKDVSKIY, M.F.; SIDELIKOVSKAYA, F.P.; ZFJMSKAYA, M.G.; MORGUNOVA, Ye.S.
Polymerization of vinyl lactams. Soob.o nauch.rab.chl.VKHO
no-3:5-8 '55. (MIRA 10:10)
(Polymerization) (Lactams)

SHOSTAKOVSKIY. M.Y.; PRILEZHAYEVA, Ye.N.; UVAROVA, N. I.
-
Free radical polymerization and copolymerization of thiovinyl
esters. Soob.o nauch.rab.chl.VKHO no.3:21-24 '55. (MIRA 10:10)
(Polymerization) (Vinyl alcohol)

SHOSTAKOVSKIY, M.F.; GLADYSHEVSKAYA, V.A.
Studies in the field of polymerization of vinyl compounds. Soob.o
nuach.rab.chl.VKHO n0-3:25-27 '55. (MIRA 10:10)
(Polymerization) (Vinyl compounds)

SHOSTAKOVSKIY,M.F.; BATUYEV,M.I.; CHEETITAYEVA.I.A.; MItTVEMA,A.D.
optical study of certain ethanolamine vinyl ethers. Izv.AN
SSSR. Otd.khim.nauk no-3:544-55o MY-Je '55. (MM6 8:9)
1. Institut organicheskoy khimii imeni N.D.Zelinakogo Akademii
nauk SSSR.
(Vinyl others) (Ithanol)
It

r
I
14645' Synthols of Sulfutow Substances ou the Da.4 4
Vinyl Ethcrs and Acetylene. Sinfix semlalykh Yeshchestv na CH.
'08nolve prostykii viniloyykh efaroy I alsetilena; X11. Tbe,
Most Effective Catalysts in the Reaction of Combining.try-
drog,!n Sulfide With Vinyl Ethers, Contrary to the Marko"il-ov
Me-. 0 nailialre effektivnAh kamlizatorakh - v reaki3di
prisocilinenNu ~crovoilorodm k proslyni viallovyin eforain,
tl-proflv pravila blarkovnikova. (Russian.) M. F. Shimalin-skii
E. N. Prilmlineva,, and E. S. Shapiro. kcCitiia ukadenjif 6UUK
SSSR, videlcilk; k Initchokik-It nauk, 1955, no. 4, jaily-Atig., p.
34-741.
Includes tables, 17 ref.

SHOSTAKOVSKIY, M.F.; KOCHYUH. D.A.; ROG, V.H.
-
Investigation into the synthesis and conversion of organic silicon
compounds which contain o3ygen. Part 2. The reactions of diethyl-
and diphenylsilan diols with vinyl ethers. Izv. AN SSSR. Otd.khim.
nauk no-5:953-955 'S-0 155. (MLRA 9:1)
l.Institut organicheskoy khimii imeni H.D.Zelinakogo Almdamii nauk
SSSR. (Vinyl ethers) (Silanediol)

SHOSTAKOVSKIY, M.F.- SHIKHIIEV, I.A.; KOMAAOV, N.V.
Research in the field of synthesis and conversion of silicon
organic compounds containing oxygen. Dokl.AN Azez-b.SSR 11 no.11;
757-763 '55. (MLRA 9:5)
1. Institut organicheskoy khimii imeni N.D. Zelinakogo AN SSM.
Predstavleno daystvitel'nym chlenom AN Azerbaydzhanskoy SSR Yu.G.
14amedallyevym.
(Silicon organic compounds)

SHOSTAKOVSKIY, M.F.; KOGHKIN, D.A.; SNIMIYEV, I.A.; VLASOV. V.M-
Investigation in the field of oxygenated silicon organic coumounds.
Part 7. Synthesis and certain conversions of silanols. Zhur.ob.
Khim. 25 no.3:622-626 mr 155. (MIRA 8-7)
1. Institut organicheskoy khimii Akademii nauk SSSR.
(Silanol)

S Y,
_\f_Yjnj~_aiyi others. Ill. C,)polymentation. of vinyl mrYi
der th ence of ionic Cat-
and -nyt iRyl e(rcTrIm o influ
Slv,rako~,kn nd A- V
,Iysls I
h-v _.~jl -- ! I -,;,f
S. R. 2 5,

USSR/ Che niis try
Card V-1
Authors, Lho-0;akovskiy, -V'. , '~hplbrovskiy, V. V. , and "..'r-Idelyanovskaya, 1.11. A.
Title 'ItUdy of the reaction of vinyl and ~~olyfunctional compounds. Part 2.-
2caction of vinyl others -...-!Lh polyvinyl alcohol.
Periodical Izv. AN ESSH, Otd. Hauk, 3, 535 - 54c), i~ay --June 1054
Abstract The reaction of polyvinyl alcohol trith vinyl butyl and vinyl phenyl
ethers was invesiiCated at different co-inponent ratios. The reaction,
orocess which leads to the formation of polyacetals of polyvinyl alcohol.,
and the stages of formation of mixod acetals uith their consequent
cycli-
.~ation, are explained in detail. The differences between the analytical
and calculated data concerning the-elementary coxpos-~tion of tl~b
polyacetalo are e,,mlained by the nature of the rvicroinolecular substances.
E-even references: 6 ussa, 1. USA. Table.
Institution Acad. of Sc. ULM,, The H. D. Lelinslciy Institute of C!rg. Chemistry
Sub:iiitted i~arch 25, 1953

Laryt ethers. In. Copolymerization of .Inyl aryl
-d vinyl alkyl Oilers tinder the influence of i
aud &, V- Rogtnnva. k )rk,
-
JIL 1,114 1 1 - mo~a ,
Ar 46"~ wl- Zhur. ObACh I
Khin'. 25, 1550-5(1955); cf. C.T.799'YM, 49, 13941e.-
ArOCH7CEll copolymerize with ROCII:CH2 if the catalyst
cruployed for the reaction is BF3-EtIO. A no. of copolymers
of EtOCFI:Cff, anti BuQCH:Cff2 with PhOCU:CH, and P-
Nfe,CC4H40CH;C,1It Were prepd. %vith vurious proportions
of the inonomers. The reaction occurs rapidly aud is exo-
therraic. The qual. soly. of the copolymers. itt
BuOH. BtOH, AfeOll, AcOH, Lind gasoline is given in
tabular form. The raol. wts. of the products are generally
G. M. icosolapo
below 7500,

Subject USSR/Chem'stry
Card 1/1 Pub. 152 - 14/19
AID P - 3931
Authors Shostakovskiy, M. F., V. V. Zhebrovski-y, and B. A.
Aronov
Title Copolymerization of vinyl butyl ether with vinyl
chloride
Periodical Zhur. prikl. khim. 28, 10, 1123-27, 1955
Abstract The copolymerization of vinyl butyl ether and vinyl
.Lsobutyl ether with vinyl chloride was carried out in
a water emulsion in an autoclave in the presence of
ammonium persulfate at 30 and 500C. Four tables,
6 references, 5 Russian (1949-53).
Institution : None
Submitted : F 17, 1954

KASATOGHKIN, V.I.;.SHOSTAKOVMT. M.F.; ZILIEBRERARD, 0.1.; KOCHKIN, D.A.
Hydrogen linkage in silanols. Zbur.f1z.khim. 29 no.4:730-733 Ap '55.
(MI,RA 8:8)
1. Abademiya nauk SSSR, Institut organicheskDy khimit.
(Silanol)

SHOSTAKOVSKIT, M.F.; SIDELIKOVSKAYA, F.P.; SIIAPIRO, E.S.
,
Pol.vmerization of the vin7l iseproprl and vin7l cy-clohex7l ethers
under the influence of 2,21-azo bisnitrile of isobutytic acid. Izv.
AN SSSR.Otd.khim.nauk 86 no*-6:1085-1089 MY '55. (MLRA 9:4)
l.Institut organicheskoy- khimii imeni H.D.Zalinskogo Akademii nauk
SSSR. (Ethers) (Nitrilea)

WSR/Chemistry - O-rga'nic chdmistry
Card 1/1 Pub. 22 - 23/50
Authors i
Title I
FeriOdical I
Abstract I
Shostakovskiy. M. F., and Bogdanova, A. V&
Study of vinyl aryl ethers. Reaction of vinylpheinyl ether with dibutyl
acetal
Dok. AN SSSR .100/1, 89-92, Xan 1, 195,5
Investigations were conducted to determine the reactivity of Vinyl aryl
ethers during contact with compounds containing active hydrogen. Results
indicate that vinylphenyl ether will react with dialkyl acetals leading
to the formation of alkoxypheno.-x7a1kanes with a darbon chain of various
length. A study of phenoxydibutoxybutane hydrolysis products and 1,1,3-
tributoxybutane and.butylphenyl acetal formed during the basic synthesis
led to a conclusion that this reaction is also followed by the se aration
.P
of the alkozy-acetal group. Seven referencess 5 U-15M and 2 USA (1949-
1954)-
Institution s Aced. of Sc., USSR., The N. D. Zelinskiy Institute of Organic Chemistry
Presented by i Academician I. N* Na=ov, Tune 24, 1954

S -7/4 1~'f /27,
USSR/ Ghezdstry - Orga-:iic che-mistry
Card 1/1
Authora S
Title
Periodical I
Abr,tract
0 Institution
jPresented by
Pub. 22 - 21,/52
114iostaako-vskiy, 1-1. F.; Kondratyev, Kh. I.; and BolyaYev,, V. I.
Synthesis and conversdon of wzygen-containing silico-orgaide coimpounds
Dok. AN SSSR, 100/2, 287-290, Jan 11 1955
EeTerimental data -are presented regarding the synthesis of n-butyl-, i'90
butyl-, secondary-butyl-, and tortiary-buti(ldin~etliylplienylsil.anc-:a--et~,-Is.
A study tms ;-made of the chemical properties cf rn:Lxed silico-organic
acc-;tals, i. e. acetals containing alcohol and silanol.radicnis, Snd it
wa* fo-ard that they are miuch closrcr -to the al-kk.-laryl acetals and that
their s3imetrization is accomma-piled by a ser"Lf-i-F, of Q'Ulwer ren-etio-nz. Tho
presc-11ce Of a in silico-m.-L-anic :at'.1-is by
thoir t1h ernial deconpos it ion charl-lctfristics. Ten U36R r-;:fcr_-411r(~'5 ~`--),1:3-
1954).
A-,ad. of Sc. USSR., Thc N. D. Zelinskiy inst4tute of OrCazLic Ch~-:_,U-t'--~-;
A-tadismician B. jr-Ay 101, 10/1T4

V,
USSR/ Chemiatry - Organic chemistry
Card 1/1 Pub. 22 - 25/45
Authore Shostakovskiy, M. F.; Gerbhteynt N. A.; and Notermant V. A.9
Title Reaction of benzoyl peroxide withvinyl atheril
Periodical j Dok. AN SSSR 103/2~ 265-268,, Jul.11 .1955
Abstract t Investigation was conducted.to~determine the.I.,eaction between benzO71
peroxide and vinylether and~to establish the. characteristics of the.-
liquid phase and the composition of the gassoits phaae. It was found AfiA.
vinyl ethers react well with benzoyl peroxide forming acylall. addition'
products. The reaction products obtained duripg.lov peroxide ooncearation'.
were found to be low molecular vinyl ether poIlLymrs .similar to'telcme-rel:
Twelve reiferencea: 8 7JSSR- 3 USA and 1 German (1925-1954) Tablesi..
botitution Aced. of So., USSR# Inst. of Orga. Chem.'im. ir. D.: Zeliiskly
Presented by t Academician B. A. Kazanekly, February 16# 195,1,

-T-Iride Iy
--
&
---------------
M. S. mamlavska~ if.
kim (N. rniL Org. Chluxt,. A=d- Sci. US.S.R.,
hi6f. Af4d. Sauk S.S.SR., 09d. K-Um
!rw)

W-4- cf. C.A. SO. 11015z -To 29M
V 4 IQ
ja,
prepykite adde (1) addled 76S6 Isq-BuEt&'CIH kqel)m-

ow=Ight'-file inkt. gave,
Cl. bsw~-Sqls% kV
'
,
4:
f
rS C
Cff cir-
gjvem)* 7SZ%1J
tafuO(bp W6
auddr.
q
0755
SOS%
437S
1
CHA"M
75
54% 1
4
.
.
.
.
~
ss
4
1
*
*
-
2% Cfft.
(OCM&CHIIcC7~. b2 85.2-5.4
, 1.4405, IASSO; 7
CHSOCHiCHMCCEN, b% 140-5-A', 1.4W7.1.1457. Sh2k-

CHMcCI)* with mucd. HN% andheaft
Ing EtSMOXH,
I ar. a., 501 FoLve MeCHCIMEI, 'the r=flts iad!rx,te that
the r1of R-opeas at tha-priw=y C atom AL%,fn5uU.
IOSO
6a941
&C
A
f
&R
M$
M
Xhi
.
.
rat
o.
,
.
n.
,

96 V5

ynthesis wid L*"

1
'
L
Zelins' CPO
.
3
1
Im,i. Org- Chem., Acaj. Sn~ U.S.S.R., M,~scwv)_ 1_'1F
Akad. Xauk S.S.S.R., O!ele,'. Kkim. N--ith, 1956, 811-16; cf.
C.A. 50, 102c; 51, 1026i.-Pli.MgBr from '14 g. PhBr
treated in I hr. with 258 g. autt tile ~tquid portion
sepd. and distd. vicldcd fmciiou~ with mixts. of Me2l?bSiCl
J,
and Nfetl?hSilk suitable f(,r us_~ b! Elie following syntheses-
Into 16g. iractiun, bj,744;". above, i~i T-t.OwaspasstzdXf13
at 0' yielding 50 g. 188-70', b.--3
12S-9', d, 0,9871). 0" This (74 g.) In )DO in). 1110
and 250 ad. 17t.,Cj ,ii irez.-ed diopwi!ie with IMAI HC1 over
2.5-3 firs. until re-.wt iui~ %v-s coniplete, maintaining Eh,: 50111.
oil the basic side; dism. gave 62.6 g. He-PhS.'Off, bio 99-
9.5% d.,a 0,990S, Y~Op 1.61f.10. which oil direct distu. gave
91'.217c (.IfezPkSi).,O. b, 1011-8% (11, O.OMG, 1.5170,
seal, M6,,PhSiOl1.46J g.,NfC0Cj1.-'
Kceping ina cd tube 7.7 g. I
CH,, and I drop cmied. F(CI '21(1 tuiu. at 20* and (3 firs. at "0'

65.95f A&OCILTIe'330fe.Th. bi cl~3 0.96fA,
gave
,
ri :1~0'~ Sl"Idarly
xecrei prQpd.: 7t3J5)1,,, HtOCf1NTeO-
1 70-7', ej. 0.0542, 0' 1.474~, rO.57, P.O-
C11,11eO.~i.11clPh. bq 78-0,', J_O;19 13E), 1,47-1-4: u1l!;LltCd
()-
j OAMO, n1O
ield of isc,-PrOC1J.VeO.;i.YejPh. b, 7-1-6'
Y D
.
,
1.4737. Shaken with 211' HSO, these am Ity-
drulyzed tapidly ;it 1`00111 tellip. th~ miction rate llerrmEiug
in ordcr: Me, i~,j-Pr, Ut, 11r, in t1u, OR radical,
G. M. Ko-fat).q

V"
6, an ypa-
F777
7
-7-of-silanedials of -M.,-F.
and Kh. F. Kondra
j~Dv (M. D. ZefinskiT Irm
S,S,S,R,, 014el, KU., Nak 1956, 907-7,'
8005i; 90, l451N.-l-Ct.H-,SiMeCI, ([)'pre
guard method was shown to he contaminate
MrSiMeErCl (2.5-70/p Br vm found antdvt
Specimm-4 prepd. from I-cJOH,MiBr and,M
1'(290'g.) with 7-HuO
183-7c, bt-
DuOH and 43 g. Na in xylCne gave 81.24
~401B; j, lh,.G~jj 105--204*. dto 0.9983osV 1
witit 0.25 mole I In yetr. other at 44
SiMe(04c)j (11), bit 175-9- lVn4er,1445
zantalnin
1A
orn
Shosuileovi kit
. Litz,
Akad. Ncu
d* CA, 911,
d. by the Gri-
by Som.
ally in typ cal
sic), Which b-,~
a-from 131,,
g
M270. NaOAC
gave j,-Cjjj1jm!
-,shavf4 Li.in;.

7
Rk 0

-and-
Frce radic,~I pj:yrrzeri=~tjoa

27 =- AC41 Z. I 105C
0,taa. 7MMS.S.3-R., Oidel. Khitts. Nauk 195,5, 1220-5
'
Bu0cfiI(,I-LSClT:Cl:ft _Ivaq, polymwizvd Mtb._Bz.,0-
or,.

e:~,curvesls Own.-
iiobu zonitrile catalyas witis kined
(
Th
ruc
o1
mui
es and c
ie
o~ ~jith
6l
i
e m
mv)
z
r
z
yri
r p
op
y
y readil
CNIV"Coq
Me ver uy, b Ole aettve:than*- us
IeI?9 -
'
T .. ..
Zuli
vinyl sulficleS. Isobutyroa
z
I

catalyst (ban is BiA yieldingjip.io 6&-8% polynki and
_
_
' V:,
(30*~ ~
:A~-90% copolyiner in 24 bxs-
at
The

repd. contained f ru 0 to 1006A
p .,_.ro -Onyl

0i

J.

f
0 yj I iamb
A 'V
_
-123(
IS
Wad
Oftl!kc _Mecm:ZZ 0i ccli.'~ith viqylph
"d 'vinyl ethA. Ohms (11Q, In pres=co-O I
ets:i -at:
Via t th Lm'abk t6lorui,pi6dticts
ME
t ti
Li~i4lq
h
d
an
~
a
o, pa
.
.
.
6f 954V ~
feldof
T
f
j
-
l.~ .
A
tno
'i X
y
d tit,79L
us6ol. -004 mqlafUhC
0 lkj
fft =om.. -reac ,Wd witk
U012
%c

Hon
uZ
Flo yf"r
sLU-tt-, 25*
cotound- actsi' I
res~naufi dfss
Otod
d tota
la
an
t
-
s
_TF
benza* hat
iyllbutyl.aj. AF_14..'. 3~` S
a
oand
h
N
I
~
m
Ct
'r org. sclvenbi Mum XL- x
Awarding. to mol. i
7a Of viny i
l
s &cicw
py pw&c

D, V
-j
v -c:.~.,;
frano
8yathesis and- Of
Ar odormild nsiol!j
L~ Syntheds dartri.
cm acetylleilic alcoh_013.~-
mq_aosWc
rgnao z
M ' and:N. WK6
1, A*..'- t lev, marov
QILT.. Sh
kd
O-cow
Well. 'hirn. 1956,1
X N4uk
CH- was added.,~ith;Oollng4 the
BtBr 42~:g.. McIC(OW)c
,I-
C4 andT 11 9-i- -
pt- ormxj=
stirred -37-ri.l le ovollfjht#- 0io j..cul
mith, 64~
Wed and,irmted
if P1 ad4ed, tim mixt. c
lftx.~Ott- it wkit~ I
fitirred.3,11m, 11tatfAff bAt I
Sin)
tkated with.aet,- M1 ~ gave 02%, AfesSiCl Cclife3oll" bill
W, .42-2,45', 'this (16.'63 a.) nnd 03 9--)!uOC1(XH
m
-treated with 0 2 int, 33% HC1, kept.30 tril". at 90" and lefl'.
.overuight gave, af rafizatlon:wft. -KtCO1 60.4%.
ter limit
A10,Sic1cc2rcoc1DfeoBfs, be 95-()1, itV _~ 1131j,'' dis
If:$O,. gave- 02-40,, AcH,
-0.8511, whidi. heated ivith2
ul 0
--of flm tt,~,tylcuic-nlc, 'OVO P( 111
Ojdjj_ ,
guvc Afc,5ic1f:c1fcJ1(:j01f; L.443
'3~47' 1- 7.
N kuv , 2
.3- A.8377, and ImirogetiatiQu over.R. icy, i 9
F-Z
by copvctitionat-metlicids (0
Mic followiag iven: prclid.
"A0cf.b.p. Y;V,andd-3gWcn).- BWJcSiCtCCA I
icl.
0~
1.4322, u.,Sd 14 Ettilfe-SiCH. CHCJ e. ff~ go 3
'ri.4512, 0:85 508; R t, A riSi CIT. C11, CA le: 0 H 4.1
r
1.44 1 078340, M
<
IMF-,
ON
wmb", ~~7

SHOSTAKOVSKIY, M.F.; GERSHTEYW, N.A.; NETEMN, V.A.
Exchange reactions of acetaldehydedibutyl acated. Izv.AN SM.Otd.
khim.nauk no.3:378-381 Kr '56. (KWA 9:8)
1. Institut organichaskoy khimii imeni N.D. Zelinokogo Akademii
nauk S=.
(Acataldshyde)

USSR/Organic Chemistry Syvthetic Organic Chemistry~ E-2
Abst Journal: Referat Zhi-- K~~Lmiya, Wo 1. 1957, 958
Author: Mastruykol4ra, A., Pr:Liezhayeva, Ye. N., Uva:-olra, N. I., Shostakov-
F._,,a-nd Yabac1mik, M. I.
Institution: Academy of Sciences USSR
Title: On the Reactioyi of Dialkyldittuophosphates with Thiovinyl Ethers
Original
Periodicalt Izv. AN SSSR, Section aii Chemical Sciences, 19,16, No 4) 443-450
% = CHSRI (II)
Abstract: It is shown that 'ROVSS'~' (1) -ombines easily with CH2
in accordance with Markovinkoff's rule with the formation of
(RO-)2PS-SC11(CH-A)SR' (III). The following con~-pcunds of the type III
R" . 20
have beer) Drevared (RY the yiela in percent, bp in 0 C/mm, nr) ,
and dg0 are indicated in that order): C2H C H (IV), 70-75, 109-
g: 12 5
110/2.5, 1.5290, 1.11o!2; C2H5, C4HQ M, 6 09-110/2, 1-519B,
P
1.o965; C2H-, C4H OCH2CH2, 80, 1023~125/3, 1.5.125, i.og4o; isO-C4H.,
9 M
C2H5, 78, 113-115/2, 1-5070, 1.0556; is0-C4-dq, C4 90, 121-122P,
1.5052, L,0'843 iso-c4H9, Ci~,TqOCF-pc!~2, 60-80, 124%-16/3, 1.5012,
Card 1/2

SHOSTAKOVSKIY, M.F.; SIMMIEDVSKAYA, F.P.; ZELENSKAYA, M.G.
Use of the iodoform reaction in the anal7sis of certain vin7l compounds.
Izv.All SSSR Otd.khim,nauk no-5:615-621 M7 '56. (MLRA 9:9)
I.Institut organicheskoy khimii imeni N.D.Zelinskogo Akademii nauk SSSR.
(Iodoform) (Vinyl compounds)

SHOSTAKOVSKIY M F -KOCHKINI D.A.;ROGOV9 V.m.
Research in the synthesis and conversion of oxygqn-containing organo-
silicon compounds. Part 6. Prer~Lration of secondary dialkyl-(aryl)
chlorosilaues, dialkyl-(aryl)silanole and some of their conversions.
Izv. AN 3SSR..Otdkhim.nauk no.q:1o62-lo6q s ;56. (MLHA 9:11)
1. Institut organicheakoy khimii imeni N.D. Zelinskogo Akademii usuk
SSSR.
(Silicon organic compounds)

CHKIN, D.A.; VINOGRADOV, V.L~; NITARMAN, V
SE)STAKOVSKIY. M.P.; -A.
Research in the synthesis and conversion of orrge&-containing
organosilicon compounds. Part 6. Interaction of hydrogen-
con-taining alkyl(ar7l) dichlorosilanes with alcohols. Izv.
AN SSSR. Otd.kbim.nauk no.10:1269-1271 0 '56. (MIM 9:12)
1. Institut organicbeakoy khimii imeni N.D. Zelinskogo Akadsmii
nauk SSSR.
(Silane) (Alcohols)

USSR/Organic Chemistry Synthetic Organic Chemistry E-2
Abs Jour Referat Zhur - Khimiya, No 2, 1957, 4469
Author -Shostakovskiy,.K.F., Shi-Miyev, I.A., Komarov, N,V-.
Tnst kcademy of Sciences Azerbaydzhan SSR
Title Investigations of the Synthesis and Conversions of
Oxygen-Containing Crgr Q-io silicon Compounds
Orig Pub Dokl. AN AzerbSSR, 1956, 12, No 3, 17Y-181
Abstract On heating (0"o-650, 35 hours) equiraclecular amounts of
vinyl ether, gamma-hydroxjpropyl-trimethy',-silane and
corresponding organic acid (91ac'al CH3COOH, propionic,
isobutyric) and subsequent fractionation in vacuum, were
obtained the following partial organosilicon acetal5
CH3 CH(OCCR )G(CH2)3S'(C"3)3 (listing consecutively R,
yield in ~b, BP in OC/mm, n2OL, d20): CH 3' 59.5, 92-93/8,
1.4218, C.902'(j C211 52 73-15, 9910/7, 1.4242, o.8970;
(CH 3)2 CH, 64.o, 110-111/7, 1.4262, 0-8935-
Card 1/1 - 110

SHOSTAKOVSKIY, M.F.; SHIKHIYEV. I.A.; KOMROV, N.V.
Investigations in the field of the synthesis and conversion of
oxyg"-pontaining silicon organic compounds. Report no.3; Synthesis
and conversion of some vinyl eaters of Y-hydrozipropyltrimethyl-
and*methildiethylsilanes. Izv. AIT SSSR. Otd. khim. nauk no.12:1493-
1499
-.D. 156. (KMA 1o:4)
1. Institut organicheskoy khimii imeni N.D. Zolinakogo Akademii nauk
SSSR.
(Silane)

SHOSTAKOVSUY, H.F.; SMKHIYEV, I.A.; BELYAYZV, V.1.
-1-1- --,
Research in the field of oxygen containing organosilicom compounds.
Part 5. Preparation of organosilicon acetals. Zhur.ob.khim. 26
no-3:706-709 Mr '56. (MLRA 9:8)
1. Institut organicheskoy khimli Akademii nauk SSSR.
(Silicon organic compounde) (Acetali)

USSR/Chemistry of High Molecular Substances. F
Abs Jeur: Ref Zhur - Khimiya, No. 81 1957, 27084.
Author Ztpstakevskiy, M.F.j Prilezhayava, Yo. N,i
Tsymbal-,--L-.V-.
Inst
Title To The Question of Synthesis and Conversions of
Vinyl Ethers of Higher Polyatomic Alcohols and
Cellulose. II. Vinyl Ethers on Cellulose Base.
Orig Pub: Zh. obshch. khimii, 1956, 26$ No. 3, 739 - 71+50
Abstract: The conditions of extension of the irinylization
reaction of Faverskiy and Shostakovskiy on
cellulose were studied. Th* possibility of the
synthesis of vinyl ethers of colluliose at the
interaction of alkaline cellulose with aetty-
lene (10 to 15-fold excoss 0; acetylene) in
dioxane medium ut 130 to 150 in 5 hours' time
Card 1/2
Card 212

~ 1~ 1.7-A
WE
z
Of
Wt C!
D A
&ia~v
i
V (J~tltt-
ta
'4 Add-_ c. M g. L'~,HlClt Liz 50 =_L Eta in m1b I to 3"
, - t_~ mo K , rt.. TArM
CA- NaOlq, 9Q0 tat. ff" a M! g~ E44:
r d.
Arcxvi at ro'bux

T ~
.1 n'b'r d Chilli,
..
-
llovk~ by a
tm=
fa
T
.
.
l
P_
.'
'
'
VY
Vt.-vton" '
V
10'T
sn'
was
W
z
4s~ h
4

.
~
.
.
12
.
'
11Y&Ipf- 41 slimultanems ovda. of M.
-A NOR qr ECOR and 40 g. 9tv-SiC1t in 300 9. 1:4C to 20 C.
dry Htrp aq-4 a drop of phezolphthattfa bttpw to, Itue
-At 604 ch"re~ to a liquid but can be Wired
d1of kept with
ti tohturc-for a lcmg tine ix. the cGH.
out conta" VA I atm.
;
.
ly; EtSiliCh gayfj a gelatinous produ
tVIU-Its. chaAged to a glass. which docompd at r:,Ya 400*;
lventsithesubstanccKp=.4tobes
0
6inii1arly, F112&'C4 Pve 18'Vtr'* phjs~-
trimot MM014),
':
'
icls save
?from voptatane-EtjO); U(Ph;
49
74-5'
"d 40.3c;o O(VUTWH
~

21 z
,
,
rm-112-19'
In HiO of the soomad cotnvct
by insoly
stepd
.
.
,
,
j7h1cl) Is pqt1fled by crrta. from C411s~isopaatsji-t. Slml~
1
'
'
44
:Si
lliw
r
M
Was
oni
6_167
t
zi
y
i
-
o
' Tbe chlarbalawit used as
pd aL 68,5
Afr =;
iven): JUSMM
dl
i
t
e ~b
d W
e2 wer
e
a
.
lp~, k
n, an
g
"
l
74.5% IM49. 1.4120,
jit~, b-,a IM-30
, I-10M.
1.4wo.
PbS&- &di 227-W', 1, IS377. 80; ze.~
PhSft bin 2973-
'
d
A 0
6
e
dm. j
5.
by a
the tatter w0j) pr
pd.
hr-. at IB-'201 to 102 g. i-C.H,Ll ir 20' ml CJT4
after heating 2 hrs. at W-W% the ;aii. was.
~cooled and the product filtcred off. G.34. K(1!4DLj=ff_
AM\- -

,SW
0. -5, 1-4

W

t:
Tl~
vi
N
G
1
EW

-
--
-
m
oa
A OU 6
I
C
--
t -
, 5ii
t
ikI
4iT
o
ZA
Rki
1956
A
m
S
i
4
7
q
"
-
-
.
5a
m
.
m
m.,
~
a
. Pr
g
v (
,
'
)
p
~ontaiviug 20--40% oxnen vms.taken; Its chemical
aml p(itro.;
-cyl groL
graphic amayms are given. Hydro ps viere deteriving(l. b
the Sch9tten-Ua;jmann method, showing that taponified
-
'
~roducts.zire of lowii mat. structure than untreated
ioat - 3 - 1:
'
CO gniaps'prewat 1ijA to be
radu~ed to Off-gioups before vicyWim
the detailed ve

Vinylation took place at 170-1751, method:
3 gi n..
-1 and 60%
to vin
l
rou
l
s
Werc found In thr c"
ol
til
l
ow-mo
v
i
e
.
y
g
p
,
ethers
to 'i Of the or
ic mass dissolves In alcca!ols
U
.
,
P
w
ethers, benzene, toluene, acetone cmd light petroleum. R. Low).

%

I .: ,
I I

USSR/Organic Chemistry. Synthetic Organic Chemistry. E-2
Abs "-Ijur: Ref Zhur-Mlimiya, No 6, 1957) 19257
P,ut'.-ir ShostEk4qyqjLiy~M.;1-F., Shikhiyev I. A., Kounrov 11. V.
Ins -L
Titic Inveotigations in the Field of Synthesis and Conver-
sion of Unsaturated Silicoorganic Compounds. SynthesiB
of Silicoorgania Clucoles of Diacetylete Series.
Orig Pub: Dokl. AD` SSSR, iqc'6, 109, No 2, 344-346.
Abstract: is the sy:xthqsis of dip_c3tylene silicoorganic
g_~zcoles HOC(CH 3),_C-CSi(R)2C-CC(ICH3)2VH (Ia-c) 'ka R-CH
b -17'=C,H ', e R=C3117) . To C21151ASDr, prepared from 48 9. 4
a,-Id 20s C H Dr are addad, under coolinzi, 1 mole of dime-
2;lcarbinole in 100ce abs. ether and 0.5 mole
thylacetylen
(CH3)2SiClo, after 12 hours is added 11-`-15~ HCI, from
the ether layer is isola~ted Ia, yield 64,3"p, m-P. 80-820
(from benzene). Analogically were obtained Ib, yield 55~,
m-P. 76-780, and Ic, yield 48c,',, m.p. 70-i'l'. The presence
Card i/2
USSR/Organic Chemistry, Synthetic Organic Chemisti-
.y. E-2
Abe Jour: Ref Zhur-10iimiyal tTo 6, 1957, 19257-
Of two (OW-Groups is proven by the preparation of acetyl
derivatives of Ib. A mixture Of 0.1 mole Ib and 0.2
mole (CH CO)2O is heated 8 hours at 700, after 12
hours ELAer the distillation of CHIC00H diacetate Ib is
obtained, yield 61r,,', b.p. lc4-iW/3m, n2)D 1-4639, d420
0.9675.
Card 2/2

'
'
la
s
4
Il
.',
-
ar
A
a
g
0

E. N.- F-M~-Zi:v D.M. flzd
'kin -11 P Mal*,anoga -na
-
'
(N; D. 7 ILL, mio~~
b
w
Aka, va;tk -5-7.S'R~ 109,777-9)(19t
-
CH, CH. S-)71' bi 2 5 - 6~,Ll -3 3-0,
1. 14 4 5; 5 % (E" 10)
1040;
bj jgs--90"~ . I-D-Ro. I.IWA;

-FrO)zPS-CIJ-,f-d:Sfz, b4 4-50, 1.5,189 87
108
94% (iso-PrO)-PSjCH-jCFItSD:i,
&152%

b'188 xffl55.,-
-9 1 1 The Ist kbod

n
i
aticidal and a6tricidal pTopertics, with jiysIi!-niic actiox"'- -

J.
A!,

IT
zc 1 ins--
...'sear

e pro P~ettiei of T

339-44; rf. C-4. 50i rMi.
17-48 atni. to an autodave conti.: hi) g.' 2- i 30 1161
Hto, and 16.5 g, powd. KOH ~t 181-~S' ka e
0
OCHXH~, bs 114'. b:2 147, tn. perc6oljA, ~000
1.6172, d-~ 1.0612). This by 1y pletel~ ou h!at~
0/0 I-I-SO4 an a steam bat age of Ary I-I"Cl
in- with 2
Y-7. into the ether gave in 5 h 3 1- P I'!
CUre, 4 powders decotup. 18-20 lifell es hi-Ildi;
this heated in racuo to 1001 under N. Ig dimez,
(Cj.-M.O)%. m.. 186-7'. 2-C,,HrjCHClNla 5 iu..Os.
EtIO was treated with 5 g~ 2-C and t witV Aw
f
stream of dry NIT,, yielding after tngovernight.'O.l I: g.
4-methyldinaphtfic~2',11;~2.3-111.21 yran in. ~ 1: 79- -ij.i
-ve
similar reaction in BuOH gave 76. above-pyvan pud
'
-69% (BuO),CHAIc.- Adda.- of 15
2-C-CMOCHC-lhfe to
EtOXa from 1.7 g, Nia in EtOH gave 25% dirner, in. 11 ilia,
ideatical with that described aboverthd 47,5% py= desi;~_
m. 1720, identical Mth the above, along with WC11.
(OEt)!. Adding a little condd. HCI to 10.g. 2-C"SHIOCII:-a
CU., and 5.8 g. FhOH in CJI; and beating 5 brs. at iV
gave 82% abov,, pyran deriv., in. 171*. -9-0~--2ff?Off with
appropriate v;uyl ethers in presence, of a catalytic IlML of'
HCI gave Afe C11(011h) (0 CjjIT7-2),, b1. 183', ul? 1.61.3%. d" -

Rf) (0 Cab-;) bi 1 168' 1 VC." 1.081k!".
111fC11(o

Tif IJOVITC in~, i~. I o" 10.' 1,. 412,
WK
_
'
-
s" ca
OCS
19
8
h
4
-
t 152
A.1292j~
5
t MM
V.
g.. r~jlld pot
complete k hyz
.
I f- q -
90*,,
.
-Na _~Lnft Oxmu, Mot( gii~ I Ch C11,
AIF C,
li
COM i
t
AO 14 I
.
.
t
t

fizM th~ Cnide pripfi, 0f-1 Witfiolsvffii~~ -ti
a

t~liltft poNa
'to~j gage CC13CHiCII(O'
z
.
i. !M2" Uccli-Wtit
E';
IM ccj
l CRCO(ac
lf
m
at
;
i
f
4
) i
'12 - ", .- . -
* hiM hi
t'814
1404
68 9
62
CC4 an
6
4
4
0 : - I-
, . , , . -. - 1-11
.
.
.
,
.
g.
1
s.
''
ra- 42~
yClIdw
40 id polytrier cantg
I% M
Wth ,
,
-
.
,
-
0"
d
f o
d
O
IM
ile
o
I
.
ll
"

'(0'
0 C?!'~
~

O
(
P
O
9, b, 1 4940,`0.07% atiffix 70
k
)
A O r.
,
I
O
EI
C
O
)
~

?4 6
4;~
lonte ai r& r
it ethe~_oj_
1. Boed v
E.
a % in
0.
Akad. Nd
56.412ab. Ad& a. t 6 1 W'd reaBf
6rf
'of Ws-EW dnd stlrHnt__*!thdu I iij
a
P40 yMerS Wi
OCH:M, MCIffocliff
these *re L iW ~abwish'sbllds;- solL 'Jlw~uwoUtbfi.~
common swivenfi~ _-_'Cppqlym__C"'pf thei6 ~Withlillaw.cm:_
BuOCH:CH,.and FhOCfVCH*'were OiW4, hi al-
ekb the pr6duets-laWn't w6l- wts~ UJ
P, lit
y
o soUd - Aia

5/405 rA V61<

L
'Ef.7 04 -V- IL
H
Wad. Nauk T.S,S,P 01M all i ill!
1,

~091M-5- Cf - c
din 'I
*'
'
U
c H, i~ -'Pt"titit t."C
lit, buS
C
R, d
d*3MA OIV4 With UK
' -

-cly few livo wi.
*is. of tbq p
11
1wts. wem dkd~ 6Y
tIEpVdd:Ivifb 21gui-id Ea
.
which rJeaves the prvdu'~t

vinyl ethe ii- lwds V
a~'d 8
il
IC
M N
T
l
vh
iak~~
ki
A-
uravaeva,
.
az
1u
r
ftag
s
l.
;
.,Vdtli
-
J3a'ICFI
;
d Ph"CH
CtSCII
Cff
z
CH
h -
.
ie
.
;
e
ore
, an t
:,
"14 . cite
hand, wid Vhal-cilu ctr,!CIICQNIe. and C S.
P~~Ie oa -he other, with tuing NC-Me!CN)~ at (0..,
urves of the czabpn; ard'the. YicW!a'iDf, copal iith-
YL'eM,.V
various proportions cf,ri~pnomep am
*
licts are bfittlesolids rhow str;:iigtli &-jin4
~h 111M.-

copolym~ts dc-cJbIe ivith th~ bo*l to:
the suffide filik. - G 11 ff

AUTHORS, Shostakovskiy, M. F.; Khomutov, A. ~4; Melyayev, V. I. 62-1-10/a
TITLE: Investigation of Chemical Conversions of Unsaturated and High
Mlecular Compounds. Part 7. Copolymerization of VirWlter-
tiarybutyl Ether and bbthyl Ether of ~bthacrylic Acid
(Issledovaniya v oblasti khimicheskikh prevrashcheniy nepredellnykh
i vysokomolekulyarnykh soyedineniy. Soobshchenive ?. Sopolimerizatsiya
viniltretichnobutilovogo efira i metilovogo efira metakrilovoy kisloty)
PFMODICAL: Izvestiya Akademii Nauk SSSR., Otdeleniyr,, Khirnicbeskikh Nauk., 1957,
No. 1., pp. 70-74 (U*S.S*Re)
ABSTRACT- The laws governing the copolymerization of vinyltertiarybutyl ether
and methyl inethacrylate are discussed. It was found that the yields
of the copolymers obtained depend upon the chemical structure of the
initiators. The reduction in the yields of copolymers os methyl-
methacrylate and vinyltertiary butyl ether is explained by the low
activity of the polymerization chain having a butyl ether with free
Card 1/2 valence. The use of dinitrylazoisoblityric acid leads to the formation

AUTHORS: Shostakovskiy, M. F., and Chek-ulayeva, I. A. 62-i-ii/23.
TITLE: Synthesis and Conversions of Vinyl Ethers of Ethanolamines. Part 8.
Vinyl Ethers of Beta-(Dimthylanino)Ethanol and Beta-'2,5-Dichloro-
phenylamino)Eth,-mol (Sintez i prevrashcheniya vinilovykh efirov
etanolaminov. Soooshcheniye 8. Vinilovyi- Eftry beta- (dine tilamino
et,vmlai beta- (2,5-dikhloz-fenilamino)etamla)
PERIODICAL: Izvestiya Akademi-i klaulc SSSR., Otdeleniye ilhimicheskikh Nauk,, 1957,
No. 1, Pp. 75--79 (U.S.5.R.)
ABSTRACT: The authors synthesized vinyl ethers of beta-(dimethylamim ) and beta-
(2,5-dichlorophermlamino) ethanol and studied sorm conversions of these
ethers. The relation between the natur-, of the amino-group and the
reactivity of the vinyl ethar is explained. It was established that
vinyl others having the primary or secondary amino group are inert
toward ion conversions. The substitution of the hydrogens of the
Card 1/3 amino group with alkyl groups and especially with phenyl radicals

62-IL.-II/21
Synthesis and Conversions of Vinyl Ethers of Ethanolamines. Part 8
leads to a higher reactivity of the vinyl ether. Vinyl ether of
beta- (dim thylamino)ethanol is perfectly identical in its character-
istics to vinyl ether of beta- (diethylamino ) ethanol; when subjected
to reaction with alcohols if forms acetals: CH2 = CHOCH2CH2N(CH3)2+
HOCH2CH2N(.CH3)2 --->- CH3CH[OCH2CH2N(CH3)2] 2-
Vinyl ether of beta-(2,5-dichlorophenylainino) ethanol is identical
to the vinyl ether of beta-(phenylamino) ethanol; thanks to its
greater hydrogen mobility in the presence of nitrogen and traces
of concentrated hydrochloric acid, the V'",nyl ether easily subraLts
to certain conversions (see formulas on bottom of page 75).
Cawd 2/3 Table. There are 8 references,, of which 6 are Slavic

SHOSTAKOVSKIY, M.F.; KONDRATIYEV, Kh.I.
Synthesis and transformation of organic compounds containing
o.Vgen and silicon. Report NO-7: Sy-nthesiB of dimethyl-oc-naphto'--,
methyl-c CHs=-EC-CH CH-OR, (1)
Card 1/4 where R - C
H
H
H
(111)
(1); C
(11); C
6
11
10
17
4
9

The Interaction of Diacetylene With Some Hydroxyl- 20-1-14-6-31/54
Containing Compounds
CH- --CH~CH-CH-OR --- > CH~_C-CH2_ CH(OR)2
CH 3 - C~_C - CH(OR )21
where R = C4H9(IV); C6H11 M; C10 H17 (VI).
The reaction takes place in steps. In contrast to the alkyl-
acetylenes the first alcohol-molecule is added to diacetylene,
in opposition to the Markovnikov-rule. This is done by the
influence of the second ethenyl group. The next molecule is
added to the ethylvinylether according to the Markovnikov-
rule. It is followed by an isomerization discovered for the
hydrocarbone by Favorskiy (reference 9). On heating to 1000
only ethylvinylethers are produced. Acetals only develop
above 1300. The interaction of diacetylene with P-decalol
begins at 900 and only ethylvinylether is obtained. At higher
temperatures decanol is obtained. In order to prove this
structure of isolated ethers and acetals, the authors used
bromination, hydrolysis (reference 2) and hydrogenation
(a partial and a complete one). In the partial hydrogenation
1-alkoxybutadienes develop, in the complete one - saturated
Card 2/4 ethers of the C 4H9OR,series, where

The Interaction of Diacetylene 'Rith Some Hydroxyl- ;~0-114-6-31/54
Containing Compounds
R - C4H9(VIII); C6H11(IX;C1OH17 (X). From the butynal-
acetals the authors produced the corresponding butyralacetals.
Ethylvinyl ethers are easily brominated. The addition of the
first bromine-molecule probably takes place at the double
bond and is accompanied by an isomerization. The second
bromine-molecule is added to the triple bond and
1-butoxy-1,2,3,4-tetrabromobutene-2 (XIII) forms.
The reactions described indicate a considerable reactivity
ethylvinylethers in the ionic uouversions. In this connection
some peculiarties of their double bond become recognizable.
16 compounds, 10 of whom were unknown in literature, were
synthesized on the diacetylene-basis.
There are 2 tables, and 13 references, 2 of which are
Slavic.
Card 3/4

A JT': 0E Shostalcov.;~-iy, 1. 62-1-11/29
TITLE: The _711vestiZation tilze .,-ec,,.ai1i-..i of Fdy-
halides Jo::moun,::s to Viny! Acetate(Issledovaniye radik--:.11n-ogo
khani--ma ;Drisoyedineniya -)ol4f-aloid.-:.ykh soyedinoniy k vinilatse-
tatu)
PERIODICAL: Izvestip~ A~; SSSR Otdeleniye Ih ii,ii-ciieskik-h Nauk, 1956,
1 -1 r 1 '07 056A)
ABSTIUCT Up to iio,;,, the inter-ction bet,.,cen pclyhaloid--, ethane and Lri-
chlorosilane and vario-Ls olef-ilis and si:--I-,le vinyl esters was in-
vest:,--tecL -ost -~reciscAy. 1, iiis was Clone to a smaller extont,
,,o,,,,,cver, %-iLh the rc-action of them interaction of the above

vii;,l esters. There exizts only
::lentiozied coza-~)uai-,ds -~~ith col..- --j
one A:aeric-,.n .,at,3nt (1~)46, rcf'r-rc-'-Oe 7) --;..*ihich the interaction
between the car*--,c;ri t-,.'. - .~:hloride and vinyl acetate is described.
(CH2CHOCOC"A
Thc. polarization )rod-i~A:i of the-eneral formula CC13
Cl, were obtained as result, ,-iht~re n = 1 .... 8. In the present
,p:i,per the authors report oil th-.~ invL~:~t-'g-.t-ion of the interaction
-) Si-
)etwecll "14, C11C13, Sicl-",, S'1[C13 and C211- ~!C;12 and vinyl
acclate under the influence of ber-,Ziol- erox-ide. It was ioundl
tl;~--Lt thc. ~,ield of tl~c e:.:uJ-;.ioleca1ar a,,~dition com.;)oand of CC14
Card 1/2 to vinyl acetate is i-nereased corfesnondin-, to ti'le Zreater quan-

The 1"vQSti,,ration of the i:iadic:.Il AdditiOll Oi' POlyhalides 62-1-11/29
COLi-)oands to Vinyl Acetate
ASSOCIATIO:11:
t'ty of CC14- The yield o-,' t*-,.e :)-o'uc~ 4--:~roved an,4 -'s
constants worQ defined exactly. For tlae first t-;.-.e e,.-ui..-,olecular
addition compounds viere obtained of Siliv
"13 and C2H35'HC12
to the vinyl acetate. Ht-re SiCli dIoes not entE:r interaction
.";ith vi"Y1 act;tate (in the prosence of bum;oil r)L~roxide). After
the interaction butacen CHCI~ and vinyl acetate has taken place
a tliixture of th~;products of uvi--Awlecalar polyiaerization i-s for-
iiied. There are 2 tables, 7 rcferences, 5 of which arc Jlavic.
institute of Or-anic
0
(In--itut or.,,~-.nicheskoy
nau', S:j~,!O
Che~-,istr~, -i:-icni U. D. ZelinskiyAS LISSTI,
-
'r-lhi--,tii i:.,. -;I. -D. ZQlinskozo Alzade:~iii
SJ-6'I;,-ITTED :
~k V--'. i IA 3 LZ;- :
July 1), 1)5u,
Libr----rz~ of Con3ress
1. Halides-Cherucal reactions 2. Vinyl acetete-Chemical reactions
Card 2/2

AUT11ORS: ShostakovskiY, shap-iro, _1-. 3. 62_-1-12/~q
Sidellkovskaya, P.
TITLE: Investigation in the Field of tine Lactones and 'actams (Issle-
dovaniye v oblast-i laktonov i llaktanov) . itez)ort 1c: Onthe ReactiDn
of the Addition of Hydroug,en Sulf i d e to Vinyllacta;ae3
(Soob-
shcheniye lo. 0 reaktsii prisoyedineniya serovodoroda k vinil-
laktamam)
PERIODICAL; Izvestiya AN SSSR Otdeleniye Kh--'. i:liches11-_ikh Nauk, 1958,
Nr 1, pp 68 - 711 (USSR)
ABST1LIM: The reactions of the above mentioned comDound according to the
general formula have practically not been treated at all in the
references and were the object of detailed investigation in the
laboratory of the authors. Already the investigation of the pro-
perties of the vinyleaprolactame and vinylpyrrolidone showed
that they can quantitatively hydroly-ze according to the ion
raechanism (in acid riedium). The reaction of the alcohols with
vinylprolactame took place under formation of alkoxyethylides-
lactame only up to (since the process was complicated by the
by-reactions). The behavior of the vinyllactames in the above
mentioned react,i,oil is to a certain extent similar to the behavi-
Card 1/2 or of thionj 1 ethers (and of vi-.rlylethylsalphide). (tables 1 and2).

Inve-ti,-ation in the iield of' tht~ Lactone,.- and Lacta-m_- 62-1-12/29
Re~~)ort lo. On the Reaction of the Addition of Hydrogen Sulfiue to Vinyllactames
In the present naper the au+',-,rs rcport on the investilgation
of thu reaction of the a'~ove Llentioned compound and prove that
on the baois of' the vinjlcaprolactame and vinjlpjrrolidone sul-
fides and thioles can be obtained with a !icneral yield of 75-
-35,;0. .0, urtheri:iore -;it was found th-A the second reaction stage
had a greater velocity than was assumed and thus leads to the
formation of sulfide. The synthesis of the thiale (on the basis
of vinylkaprolactame) succeeded with a yield of It was
shown that the reaction of thc~3ompound of hydro.-en sulfide with
vinylcaprolactaime is retardedt in the case of that the latter had
came for a longer time into contact with air. The synthesis of
thidle with the pyrrolidone rinE; was realized with a yield of
6o~lj (after the reaction between 11-B-chloroethylpyrrolidone and
PaS11 had taken place). There are 2 tables and 15 references,
14, of which are "lavic.
ASSOCIkTION: Institute of Or--nic Oheraistry i~.,i_-ni N.-11.Zelinskiy,,AS "J53H
(Insitut i--..E.l), Z1e.L_ins1-_ozc naukSS"
S1j:3-ITT"-D: jally 6, 1936
2. Lactams-Derivatives 3. Hydrogen
sulfide-Chemicnl -reactions 4. Vinyllacta-mes-Chemical reactions
5. Thiols-Synthe-gis

Zx IN
AUT11OLIj. jhoatakovskiy, F.p Ilhoi,illtov? A, ::,, Ali~~IOV2 A-i'-, 62-1-22/29
TITLI~: The Sy -~the3is of the Complex Divinyl Ether of Tart-ric Acid(Sin-
tez slozhno-o divinilovogo efii,a kisloty)
KMIODICAL: Izvestiya .1,11 SSS-,. Otde leniye _Iii:-.iicheskil-h Nanukj 1956
Nr 1, pp 108 - log ~ ULk; "i )
ABSTRACT: The synthesis of the vinyletherz; by interaction between the
vinyl acetate and alcohols or aci(Is aas already described in
literature (refercnces 1,2).0orresponding to the kind of reaction
accordir.- to this method sim-ple as wull as co_T-',;lex vinylethers
can be synthetized. Tile reaction of the acid vinyliza-tion with
the action of the acetate can be e.,pressed by the followh-
euuation:
CH = CHOCOCH3 + HCOOH 2o-8oO CH2 = CHOOO~' +CH3COOH.
'[9S04
By this way of indirect vinylization the composed vinylethers
of the mono- and dibasic acids were obtained. The authors carried
out the synthesis of the complex vinylethers with dibasic
(4-atoraic) oxyacid (d-tartaric acid) e',,perirqcntally. The obtained
divinylether of tartaric acid is a slightly 1-4 colored vis-
cous liquid which is soluble ir, sulphuric ether, acetone, benz-
Curd 1/2 ene, and alcohol. The divinylether of tartaric acid is poly-

"'he Synthesic; of" the Com-lex LivinylEt~,~r f Tartaric Acid 62-1-22/29
..ierizable in presence of benzoilp--roxide or of the of
azoiso-butyric acid and co-polymerizes aith the methyleth_er of
the meth Ii
'ylacrjlic acid. There are ' references, 1 of which is
Slavic.
Insitut(~ of Or,,anic ClICMi0try
(Insitut or-anichesk-oy khii:iii
jiaul~ SSSR)
SUB..:ITTED: July 19, 1957
Library of Congres.-l-
1. Vinyl ethers-Synthesis
i;.i~mi .-:. D. '07cliziokiy) AS U2 it
il-,i. '". D. Zelins':o,'-o A'-IaL*eAIii
Card- 212

L
ALJT?10,iS: Shostakovskiy, F. , Sh--ionina, L. 1. 62-1-23/29
T IT L-'- On the ,uestion of Production ')f !,I exac.;-iio rob utadi ene
(K voprosu o .)olucheni-I
?~~_RIODICAL: Izvestiya AN Otdeleniye ':himiche_qk1ikh I'lauk, 1950
11r 1, pp. 109 - 1,11 ('JL;~"Z)
A33121t~~.C'f i1exachlorobutaciene bclorl:,s to the best solvents for many
organic substances. There are -.,,any papers in literature des-
cribinLr the various kinds of the s.,/nthesis of hexachlorobutadi-
ene. There is also a series of patents. It was, however, inter-
esting to find also other ways of synthesis, starting from the
available raw material. In the previous re,-,ort of the labora-
tory of the authors it was proved that it is possible to obtain
hexachlorobutadiene on the basis of diazetylene. Furthermore
'the authors were interested to detect whether it is -oossible
to obtain a substance startin- from butindiole (formulae (1)
L, 0
to (4)). 'these reaction were up to now only partly realized.
The aut-iors obtained 1,4 -dichlorbutine according to the known
method of(jolinson, ref. 4 ) with a yiuld of 8oz*O'. It turned out
that 1,,',-dichlorobatine does not combine at all with chlorine
under the r,iven conditions. The realization of this reaction
Card 112 succeeded (with _~- yield of, 98~1v') by chlorination in a solution

On the ~ucst.iurt of t::: Production _;1' Huxaclilui-obatadiale 62-1-23/29
of llutrL~c_-.~on alL a of -'o, -5oO a yield of
,7j~,O. Furthermore it was silo,;;i. that iii the c*-Liorination of
1,2,3,,', -t(~trachlorobut.:Idiono in dle,-endence or., th:-- conGit-ions of
the reaction ass -well --is octachlorobut-
ine c_-In be obtained. There are 6 2 of ahich are
5; -%Vic .
ASSOCIATION: institute of Or~;anic Chemistry i.-:ieni 711. D. Zelinskiy, AS USSR
(Institut orgari-iclieskoy khi-rqii ia. N. D. Zelinsko-o Almde;_:ii
n2u': ~iSSIO
SJ3.-ITTED: july 2'[, 1957
AVAIIA3LE: Library of Con~ress
1. Hexachlorobutadiene-Synthesis 2. Solvents-Production
Card 2/2

A J'I',' I O',L' SShostakovskiy, 1..'. i~., Sid c1 11,ovsk-aJa, F. P. 62-1-24/29
TITLE Invest i r,ati on in the Pield cf L:.ct~3nes aric Lucta,-"s (Is.,;lQdo-
vaniye v oblasti Llktonov i lakta;.iov).
T -
R
ePort 11 : C~~nderisat ion of Et'hylene Oxide i-rith Lactams (So-
obshcheni.ye 11 .1'onderisat,,iya oll-isi ctiiena s iaktawaui
PERIODICAL: Izvesti,,-a AN SSO`;", Otdeleniye 1:hii,iicheskJ.kh Nauk,.1958,
11r 1 , Pp 111 - 115 (i53.11)
ABSTRACT: The reaction of the conL~ensation of or-anic oxides with lacta-qs
has hitherto not been described in literature. In the present
paper the interaction ofpxyethylene with pyrrolidone and capro-
lactai,les was investi,~ated. The process took place at a tempera-
tare of 2o, 6o, and 2ooO in the presence of H 0 CH30H, H2SO4
(or without thei.,i). At te,.qperatures of 2o and goo, t"he oxyethylene
did not react with pyrrolidone. At 2oo-21oO an.interaction bet-
ween the above mentioned substances took T)lace with formation of
N-(3-oxyethyl)pyrrolidone, formerly synthetized from butyrol-
actone and ethanola.-mine 5 stable 1). In order to confirra the
structure N-(f3-liydroxyethyl)-pyrrolidone was transforiaed into
c;
'ilQroethylpyrrolidone by interaction with chlorothionyl. The
yield of chloroeth~ilpyrrolidone ataounted toe-,,qo~,. The results
Card 1/2 of the other expEriMellt3 are shovin in the table. There are

irivesti-atiori i:7 the -vielu of Lacto-iies, ami 1'act--~:s 6 2 - 1 - 2Z,/22 9
Report 11 : Conc~.nsati3.. Ethylene Oxide with Iactants
1 t-;ble, 6 rk~ferer-ces, 2 of which are Slavic.
ASSOCIATION: Distitut~- of Or-anic ChesiiisLry Iineni 11. D. Zelinskiy AS USSR
(Institut or,,7,aricheskoy klhi~iii ii--i. N.D. Zelinskozro Akademii
na-dc S'"SR)
SLJLii':IITT"L-: Jaly 20, 1957
AVAILM`-:-~: Library of Con.-ress
1. Ethylene ox-ide-Condensation reaclt-.ions 2. Lactems-Chemical
reactions
Card 2/2