SCIENTIFIC ABSTRACT SHOSTAKOVSKIY, M.G. - SHOSTAKOVSKIY, M.F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549910017-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR/Chemistry - Vinyl Alkyl Esters Se-D 48
Chemistry - f~jdrolysis) of Vin~
_I Alk-jl Esters
"Hydrolysis of Vinyl Alkyl Esters in Aqueous Dioxane Solution," Ye. N. Prilezhaye-va,
E. S. Shapiro, 1-1. F. Shostakovskiy, Inst Org Chem, Acad Sci USSR, 11 pp
'IZhur Obshch KI-drdill Vol XVIII, No 9
Tabulated data shows that rabe of hydrolysis of vinyl butyl and vinyl ethyl esters and of
dibutylacetal by hydrochloric acid decreases with increased content of dioxane in water used-' a
as solvent. Discusses mechanilsm of this reaction. Submitted 21 jun 47.
PA 30/49 TI-0

SHOST..,TOVSKTT~ ?. F.
E. N. Prilezhaeva, E. S. Shapiro, M. F. ShOBtakovBkii, Hydrolysis of vinyl-alkyl ethers
in water-dioxane solutions. v. 16163
The hydrolysis rate of hydrochloric acid in water-dioxane solutions was measured:
Vinyl-butyl ether, vinyl-ethyl ether and di-butyl-acetal were found. It is shown that
the rate of hydrolysis drops from water to water-dioxane solutions. An hypothesis was
examined which, e:rplginB the mechanism of hydrolysis of vinyl ethers and a reaction
scheme is given which takes into account the interaction of the hydronium ion with ethei~-
oxygen as well as with the/5-carbon atom.
Institute of Organic Chemistry
Acad. of Sci. USSR
June 21, 1947
SO: Journal of General Chemistry (USSR) 28, (80) No. 9 (1948)

SM 1z ST ;~ K-'- V 3 v: IF
1; kovskii, To thf,
I A. Gt;rc~itf-irt and M.F. Shoste transforw-ti.)nc of simple vinyl ethers,
III. Int~-ractior, -.f simple vinyl ethers and or-1:Lnic acids. p. 1~',)89-
The repction of siraple vinyl etherz and organic acids in the abEr-nce of a catalyst
was studied. It is sho~-.-i that the organic acids of th,- aliphatic series attach themselves
tc the simple vinyl ethers at room temperature "out to complete the reaction P. longer time
is needed. A new method of synthesis of alkoxy-dprivativeE of complex Pthers (ec-iples)
with n yield of 90 iiercert an~.. more is established.
Inst. of OrEanic Chemistry
Academy of Scierces, USSR
Lab of Vinyl Compounds
December 1, 1947
SO: JDurnnl of General Chemistr:~ (USSR) 281 (80) No. 11, 19118

bltci~vliam of ndulUm ~f viny

moicov;).,
OV Sdv
fir"Til, Dphody 0-0 Icanf.
VYJ 1A, 5ardhsefjiymn.',rlkaJ, Ydsik 1940,
'4-44.
-Vinyl alk-I ~tb,nt ran polysucrizz by dtlizi- radiod
ilanin or lonk nt-nimaijim Tljty R:e YmL prone to poly-
ulerilmloil ImIltr the a,;tWI% of au". 0 C'I WuAwcs. '111C
tictinn oi pemyWea cons6ts of actiyat!un 6t vinyl catus foe
V;iTlcu!6! rtacti-im Thus,'keping W .4c. Clf2:CIlOAc !a
41A ml. 11t,0H WO, OA g. 14-0t several (lays utK), gave
ain-ang othvr milistanevs, 05.1i g. MeCH(Gl3u)OAc, ~bu
~

-50-l' d:. 0 10"W it- 1 4060 TmArrietit of Ctli-CIIO--%c
w; th H;i~a ~O 1 i-lb E-Y. 17p AcOll I
T
7' 89"
' 4
i

. CH.: QHC-Ek d
22. ell,: CHO
O
r(
g. B?~Ch iu all amp%d (or to dlly~ at 60' W~tvc 20.021;"p biud
'I. from br. -toll - -C 9.8
which on te,)pt, .12vile-13 - ga"

1
, I. 4~
c~5;)otptizr having mol. wt. 4920. G; M. Kool: t.~
aoor I
.1

Z--E 4J/49TZ-l
USSR/ChemiBtry - 'ilriyl Ethers Mar/Apr 49
Chemistry - Chlorohydtine
Interaction of Vinylalkyl Ethers and Halohydr1--sr'-
M. F. Shostakovskly, N. A. Ger-qhte~n, A. K-. C-(,rb=---',
InGt of Org Chem,, Acaft Sci USSR) 8 pp
"Is Ak Nau1-,SSSR-,1-C;E&6l Xhin Nauk" No 2
Studies reaction of vinylethyl and vl--yl*ou-,.y-i e-vh
with ethyl(-np chlorohydrin, Chlorine lerivatf-ves
of the corresponding acetals were bbtained., 5-;b-
mitterl 16 Apr 48.
43/49T2cl

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see
all yujinjimis*461 must
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Um Ckmw. 6 U.S.S.R.. [U.S. &Md.. 12,M_
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affonk tbs bW
M ~.Ttfthanganimatsotwmo-auddi-vinyi
obw it wandoit ciff, is We& lu mucl. aw &vinyl Oben uv
aydimedtocleik
AddItIC41611 m =411 1J*$MMS1yMokvD0ftAfn9l0% KOH.
at HID-190*110, atm, = RIP4191 WWW SIAN Q - I - 3-
bhptg164-1GG,f?w MXD..
drify-1 ~.. P 1,)43C8jli
asing oulf got of the
theoretical ammut of C.H.,agorda of wl Almall
0l
-unto of z6vow I &WROW ewr 11 3-4wwykffly~.2.0n.
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