SCIENTIFIC ABSTRACT SHORYGIN, S.A. - SHORYGINA, N.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549910013-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

3FORYIUN, 3. A.
"Annotated index No 67 of Astronomical Literature Fublished in the U3M in Arril -
T.~
19501l., Astrono.~,Ac',:,--skiy Zhurnal, Yol. Mll, No. 4, pp 268-272, 1950.
.ay
SO: W-17490, 22 Mar 1951

SHORYGINY S. A.
Ili
~.S. A.
irldex 110..68 of a--tranomical literalture (,Bibliograpyq)
Astr-anondcal Journal
vaia 27,, Hot, 53 1950,1 )&323
of Re Trms, Sci-i-lec., Verl. 2; Sopt,, 19511, p.?

SHORYGIN, S. A.
71 of
'N'o. 2, 1-951-1 p.i,).,g
all. Of

USSR/Astronomy - Bibliography may[Jun 51
"Bibliography: Annotated Index NO,72 of
Astronomical Literature Published in the USSR
in February and March 1951," S. A. Shorygin
"Astron Zhur," Vol )WIIII, No 3, pp 203-20T..
Lists 32 books and brochures; 5 dissertations.
for candidacy of physicomathematical sciences;
1 dissertatijanfor candidacy of technicalsci~
ences; 3 assignments and programs; 1 yearbook
or ephemeri&; 25 periodicals and publications
of institutions and observatories; 23 artiplee
,in journa4 of &general nature- and- accordirq~
to other specialties.; 2 bibliographies cf.aui--
tro.nomical bibliography.
1~qT6

SHOFCYG~-, S. A.

V SHORYGIN, S. k.
L
A-anotated lkdzz No. 71, fccr I'm Astwcm=lo LJLtcmtura (BlbllcV&pW)
A04.rMw.ja Bull.
And. Sol WSRV meemw
VD1. 26,, ioe 5o 2-951p ppe 416
?~xmz Ocutbly lint of RuwaUnz Acc-assims
19511P Volo 4j, No. 9v p. 26

SHORYGIN, P. P.

Astronomy - Biblio-raphy
1. -1 -)r)ks on and astronomy. Piz. v shkols No. 5, 1952.
'lei. b
9. AONTFLY 71ST OF RUSSIAN ACCESSIONS, Library of Congress, December 1952. Uncl.
- -- 1, -

~`ihliograplly
-,)t--,k3 in l,hy,5ir= an~ ?-,'-z. v. shkol~.- 12 no. 3, 1/62.
Library of Congress, Septemb--~r 1952. Uncl.
9,

1. SHORYGIN2 S. A.
2. USSR (600)
4. Physics - Bibliography
7. New books in physics and astronomy. Fiz. v shkole, 12, No. 6, 1952
9. Monthly List of Russian Accessions, Library of Congress, PebruarY -1953. Unclassified.

SHORYGIN, S. A.
WSh/Astronomy - Bibliography )kr/Apr 5'2
'Tibliography: Annotated Index No 77 of Astron-
omical Literature Published in the USSR in Decem-
ber 1951 and in January 1952," S.A. Shorygin
~'Astron Zhur" Vol XXIX, No 2, PP 238-244
A list of 86 items including (a) books, brochures,
collection of articles (32); (b) periodicals and
publications of observatories (16); (c) articles
in journals of general character and on other
specialties (21); and (d)'bibliographiea of astro-
nomical bibliograpbieg.(13).

I ' -j , ". ; 1,; . , , ; . 11 .
Astronor,rj - Bibliography
Annotated index no. 78 of astronomical literature published in the U.S.S.R. in Feb, and
March. of 1952. Astron. zhur., 29, no. 3. 1952.
Monthly List of Russian Accessions Library of Congress, October, 1952, Unclassified

~ i1. * - ~
I 1 1. , ,. . il .
Bibliography - Astronomy
Annotated index no. 79 of astronomie'al literature published in the U. S, S. R. in
April and May of 1952. Astron zhur. 29 no. 4 1952
Monthl List of Russian Accessions, 'ibrary of Congress November 1952, Unclassified

S
USSR/Astronomy - Bibliography Sep/Oct 52
"Bibliography: Index No 80 of Literature on
Astronomy Published in the USSR During June and
July 1952," S. A. Shorygin
"Astron Zhur" Vol 29, No 5, pp 624-628
Lists 11 books and brochures, 2 manuals, 3 dis-
sertations, 2 yearbooks, 40 periodicals and
publications of observatories, 25 articles pub-
lished in periodicals, and 3 reviews of new
books.
r"A 2 12;4T6,E
234T66

SHORYGIN, S.A., radaktor; TSIRULIMITSKIY, N.P-, tekhnicheakiy redaktor
(A school astronomical calendar for 19551 Shkol2nyi astronomicheakil
kalendarl na .1955 god. Moskva, Goa. uchebno-pedagog. izd-vo Minister-
stva proaveshchanila RSFSR. No.5- 1954. 79 P. (MLRA 8:3)
(Astronomy-Yearbooks)

SOROKIN) V.I.; SHORYGINI V.A.
Association of sulfides of the chalcbcite-bomite-chalco-
pyrite-pyrrothite (pyrite) series under hydrothermal con-
ditions. Geokhimiia no.6:590-602 Je 163. (MIRA 16t8)

IYORNIKOVA, N.Yu.; SHORYGIN, V.A.; VASILICHIKOVA, I.A.
Growing calcite single crystals under hydrothermal conditions.
Rcst krist. 4c.92-94 164. (MIRA 17:8)

- I *Zll:i-HEBI,'O'J, I.V., red.
,Ioiv~ r!.
pr3duct On
i~a,,'. r-n c T- ; - ~ - 1 . - t.. I
rxom-stroini-Lproekt., 1964. 38 p.
(MIlU 18: 5)

SHORYGIRA, L. (g.Ivanovo), BFIZENOV, S- (g.Ivanovo)
in fi rat lines. HTO no.4:48-49 kp '59. 04IM 12: 6)
1. Zamssti~tell predesdatelya oblastnogo pravlaniya Mauchno-
tekhnicbeekogo obabcbestva legkoy promyshlennosti (for Sborygina).
2. Chlen grganigatsionnoy, saktoii,oblastnogo pravleniya Hauchno-
tekhnicho.skogo obshchestva legkoy prom7ablennosti (for Bezenov)
(Researcb, Industrial)

SHORYGINA, L.; BEMOV, S.
Reflect vital problems in planning. NTO no.11:54-55
N 159. (MIRA 13:4)
1. Zamestitel, predisedatelya Ivanovskogo oblastnogo pravlexxiya
Nauchno-issledovatellakolo obshchestva legkoy promyshlennosti,
g.Ivanovo (for Shorygins. . 2. Chlen or&unizateionnoy eektaii
Nauchno-ii3sledovateliskogo obahchestva lagkoy promyshlennosti
g.Ivauovo (-Lor'Bezenov).
(Ivanovo-Textile research)

SHCPYGD-1A, L. T).
Y'osco-,r Frwirce -
Princinal stages in the formation of the relief of 'Moscow Province. Trut, Inst.
J I
L7eol. m?izzk. AT. SSSR no. '-F, 1947
Y of Rus~~*-,.,m A,:!cess~ong, Librpry of Congress, September 1959- MICL433IFIED.
Nonthly 1AaL _

4,~
46 ~tnw' f TU
~~4'tatms at part o the i~ "toada
!rmow Regkm- V. P. Er=---zv and L. D. sh~
- y Ind. Graf
hd - - Aak, Akad. Mrsub Z. . 7
T
;PdFqrC9f- Sker. Nro. 47, study is pregmted
-of widely dit-tri1xited loarns ft= the point of view of their
-uitability-fcr brickmatiuff. The more pImL;c red brick
clays &!s& were mdled. Ganditims of cccf=ence of the
~Jayi re= discussed.- kl; ~..f yda xe give--
for clays MMA Imms ef the eentmi V= a' Tuva. A table of
- tests is also nrovided. In addn., beating curves and
ceran31-
rendu of gmuloakric tests are recorded. Fhotomicr-i
gmpb-s of some of the ctzy- are provided. Studitsmadeare:
a Ist attempt to eve brief qu3l. prupcrties of deposits of
raly rateri2l for brickmking. 6. %f ac-x

YERVEYEV, V.P.; SHORYGINA, L.D.
-~
Clays and clayey sails in the central region of Tava Autonomous
Province. Trudy Inst.geel.nauk no-165:31-46 155. (MA 9:4)
(Tuva Autonomous-Plrevince--Cla7)

SOV/11-59-8-16/17
AUTHOR: Shorygina, L.D.
TITLE: Remarks on the Article by N.A. Yefimtsev "On Quaternary
Glaciation of Western Tuva and the Eastern Part of the
Gornyy Altay"
X~
PERIODICAL: Izvestiya Akademii nauk SSSR, Seriya geologicheskaya,
1959, Nr 8, pp 119 - 121 (USSR)
ABSTRACT: The author disagrees irith the findings of the author
.. 0
of the above article, published in Nr 9, 1958, of this
periodical. The following geologists are mentioned
by the author: Ye.N. Shchukina, L.P. Aleksandrova,
and O.A. Rakovets. There are 18 references, 15 of
which are Soviet, 1 English, and 2 American
Card 1/1

SHCRYGINA, N. N.
11, 11, Shorygina and T. Ya. Kefeli - "Fission of lignin by metallic sodiiiz- in liquid
ammonia. IV." (P. 1190)
SC: Journal of General Chemistry, (Zhurnal Obshchei Rhimii), 1920, Vol. 20, No. 7

0
0e 0
;
7
.
A % 1 6 . i !
L . a . L
C
12
1x)
s- .
! 4
-
-
.
-
ik,-At~o 1-kDOSRE-Ok- 100 ANO ATM Cap$*$
r
PROCESS#$ ..a FOOP991,95 W095
Aid" of mobak W& GO
00 14. =-M(1044)(Ra /0

00 my.).-)jethy ulow (40.8% McO) (16 S. in cc-
Uquid NHm WU treated With 10.1 g, NO the blue color i
9 .111 dime alur 48 111S. and, OR, =In- Colored rut
.;; 1
At of the NHs, *A "Wile t9-W W"
uts: boa
to 3
l
l
h
h

o ..
t
n
e rea
"
Ht EtOll scpd. t
p
vm pptd. by
C', UOF) (Ome), mol, wbkh
the
CjI;b;(OH)(OMt),
;e
ki
lli go

00
: : .
ew "
ty 9'
,
S ye
liquor from the abovewasvapd. f. vatme to a glassy ma",
of UIA(01-1)(HAIDS10 and Callt-
a mist
"
*00

S! .
I
'i. Xle a-glucodde (3,77 s.) - treated
(MaROM 0
00 h 33'; after 144 turs.
M -
N& in liquid Nils at
v
0* was "*pd.. the residue treated with MOIR
Z
bU
the Ida. treated with COI am Alleged; 3.5 S. uachami;~
was recovered. the name result was obtained
0 methyl tetramethyl--gincoside
suffered little change
49=1 in a 11 atm
ith 3;1
d
h
Woo
.
.
w
eate
only wmc 6% of Meo grmps being cleaved off; treatment
xo 0
.0.111164 n( this glucoside, however, with Na In liq kt NHj
:0 too
9 days gave a drupy mixt. of CjjtO(O.%Ic)j(OH)(II)j and
C.HO(OMe)e(OH)*(H). well of
TZ= ::* 0

the vatting mater-W. woo
woo

, woo
aln ttoo

S L A WETALLURGICAL UTFRATURE CLASSIFICATICM
ILI
00
slam 41"Lftv
Islas') L, O.V cat VILIII 0111 *my All
-7
.
a
F N
0
1
I
I
U 9 AV 10 Ll
ZA An a S a ad 5 do a 3 0 1
0 Is C1 Oil OPM Kit MU Knit ItiLl-11 to
00 Of 0

S'110RY,~~ENA, N'. I.T.
USSR/Cha~tistry -,Ligain
Chabletry - SeparatIon
"Splitting of Lignin by Metallic Sodlum in Liquid,
Azmonia. II.," N. N. Shorygina, T. Ya. Kefeli, Lab Of
Callulael and Lignin, Inat Org Chem, Acad Sci USSR,-
6 pp
ffZhur Obshch ]Khimff Vol MII (LIXI), No 3
Molecular weight of lignin.19 decreaLed by separation
Of-m-olecules by hydrogen bonds. 'Supplementary proc-
essIng of copper ammonia ligainvith liquid BE, does
fi6t~alter campositimof lignin.. Separation ~; ROCK3
bond in lignin by a solution'of Na in liquid Hff -
.3 pro
oeedis slowly andl-dwwnot o-M_ a to -a-'66tisfactory- vonz~
clusion. Submitted 12 Feb,1947.
4W 69T5

ca~
Is r Df-
"o" c;,~: ~i
ec~unn-,I-a

SHORYGINA, N.N.
26gr4: SHCRYGINA, N.A., -.G., TREYVkS, MI.G., RCGOVI:i, Z.A.-
.Ir
Cvili-yanii kharakftera funlr-tsionallnykh Lrupp v mnIcro=cIek-ue tsellyulozy
na svcvstva tselyuloz-f i poluc-ayer--,,kh it neyezfirov. Soobshch. 24,
Avt: Z.A. Zhurnal Pri'--!. Khimii. 1949, No. 8, e. 857-A. -Dibliorr:
s. s64.
30: Leto-jis'Znurnal'ny',:h Vol. 56, 194C.

-?n ~Jrl I Ij I rtR111, 11,
26974 YASHTINSKAYA, A. 0. SHORYOTMA, N. N. ROGOVIN~ 9. A. Poluchyeniye preparatov
dialtdellyulozy i eye zforov (Soobshch. 25). 9hurnal prikl. Xhimii, 1949, )Lo 8,
S. 865-73.-Bibliogr: S. 873
A. geologogeogr a fichyeskiye nauki b tselom. Geologiya. Petrografiya.
Mineralogiya. Kristallografiya.
SO: Ieptopial Zhurnaltrqkh Statey, Vol. 36, 1949

SHORYCINA, N. N
276-34. SHORYGRIA, N, N. Racshecheplenle
anmiake. (a-)obsch.) 3. zhurnal
66. bibliogr: s. 1563 - 66.
lignina metallicheslcim natriem v zhidkom
obzhchey khimii, 1949, vYp- 8, s. 1558 -
SO: Knizhaya Letopis, Vol. 1, 1955

"Splitting Off SOkple.3ther Bo7ads by Ketallic
cy, Sodiv~z In r4quid. A=niO6, 0 ff - N. Sh6rygina., A. Yo
SaiLechkIna$ jab'ot -CellUlose and Ligain, Inst of
0j.8 Chem, A-cad L901 USSR, 6t pp
thur Obshch 021~2%,Vdl =, No 6
Allrygluoos ides galkyl ethers, and wetals of the
aliphatic izpe ar% not split off in such solutions
and aryl others, ~w& arematic aoetals and ketals
are only 911gbtly' affected in this womer. The
different bebavia of O'Osi1tuted phenoglucosides
64/49T21
MW Chemis*y O*Iuobsldes Jun 49
(Contd)
Is explained by the effect of the substitutes on
gluooci&ic oxygen% Submittecl 23 Feb 48.
64/49T21

P-4
GN
4-4
USSR/Chemistry - Lignin Aug 49
Sodium
"Cleavage of Lignin by Ketallic Sodium in Liquid
A=Onia, III," N. N. Shorygina, T. Ya. Kefeli,
A. F. Semechkina, Lab of Cellulose and Lignin,
lust of Org Chem, Acad Sci USSR, 8-', Pp
"Zhur O~shch Khim" Vol XIX, No 8
In decomposition of cuprammonim lignin with
metallic sodium in liquid -= nia, approximately
8% of dihydroeugenol is produced and can be ex-
tracted with ether from aqueous aMmline solu-
tion. Action of metallic Na in liquid 'M3 on
TJSSR/Chemistry Lignin (Contd) Aug 49
coniferyl alcohol produces saw substance with
approximately 86% yield. In view of latter
reaction, authors suggest that dihydroeugenol
Is produced from lignin in the first reaction
by hydrogenation of the product of its decom-
position, formed according to Shorygin reaction.
Submitted P-7 mar 48.

/0
C-4
The cleavage of 118nin by metallic sodium in liquid &m.
MOMS. III N N~ Sh,-rVXi11A. T, Y.I. KV(01. atid A. F.
$vmr, hkiml ~/ Ce" chm. V.SS R IQ. INIP 77 (19111)
(F.,K1 .... ~ S- CA 44.3911h. U 1. %1
/ f 'j-7

Influence of the character of functional too in oil
10" macromolecule Uporn the proportics at ce uloss and -
esters derived from It. Z. A. Rogovin. N. t\-ihmy
A. G. Vathunslutya. and M. G. Trclvas. --irar. Pfi lad
Kitim, (J. Applied Chem.) -Thefollow:
Ing conclusions art summarized from cxptI. results whit-h
are t' be publkhed at a Liter date. Introduction of mall
a1114. of C(NII. Ir CIIO groups by w1mlive oliqlAtion
( J"'. tept.". .111 44 ()It ~harplv Wrr. lite -'1y.
of Velful'ov C'tell (nitrate and acttair). And at 11) 1,)*:;
rept.wetneut the esters are insol.; this usay be due to % tov%
linking through the residual Oil groups. ApIxtrently
this occurs more readily with Coll[ Froups in 0-positions
than with those in the 2- or 3. itim; hence, cell lose
dicarboxylic clefivs. give mom sor. (nitrate, acetate) I
than the monocarboxylic derivs. (1) o( the %unc percentugc
WCO~11. The positions of Oil groups are also important.
as trans-location, as in pectic acid or hic dcriv. of 1, IcadN
to high "y. of nitrates in IWICO whereas-
I gives but low Only. of the nitritte (13%). Cleavuge of
the pyran ring also affect% ester ~Ay. by altering ch'sill
Mobility. G. M. Kow4alk)(I
f:j, Jat-, hwalu

C,f
Mc,p.v*Uon of speciintris of dicubosycidlulose and Its
A. 6. YaAjun,k.Y N, 1-4 ( . aisd Z. A
(M~ow Textile '761ir. iikW Khi..
.Iir,I cbrol.) U. JIM 031.1'.11wi 4.1 C110
in diAhIChYdft-9IIUI4%W WA- 44. K1111) t" 0),11
ivy IICI(h y1ckis produclai hAving 4.4-13.3tle Ovill
c3chAnse reaction with o-O.\C,11.(.)Ag. (K 1.11
4,7'7,, as detd- Ivy rxcbA,'Sc with CA(OAc),. tudkitting dul
the prMuct 6 A hemiacew of rry1hronic and x1roxalic
"Mi. %hi-:h hAs 2 types of COJI in dimxm.
,%uws. %'cry little Clio content 6 left after the w6dAtion
d the products, are much mom stAble to the action of aq.
AII than the Initial diaMehydecelitthm. Acetyktion of
M
BE=
1,11 2A 30, WtAiued hv adda. of AcOll, for (I firs. at 25'
11-1,irk. Alin whh-h The product was Filtered And wvishr,
110. 11.0. MOIL n,1 M.O. 0 X1. K

.3
Preparotion at siplidmens of monocabosycallulosst and
Its estarm hl. Tirelvall, N, N. Slitury". and Z. Rugovit
,momcuw Tritilt: lust.). Atir. Prtl4d. Kkim. (J. AppliedN
Ckem,) 22. 1214-24(1949).-The presence of even a Small
Ito. of COSI I groups %Willy lower% I lit ully. of till FAIM de -
lived houl "bulycCifulonc. thi,l .Iy. i4 It.% Om,th4l of
1111TAICA Ol A191114- Or pectic aridi~ The prrmlence of COJI
ill tile 11-1-ilu'll of tile Imly,Avirti.1lide null. Als"Ificantly
lilwec% file rate of Ocetylatioll. ccllulole (linten) was oxi.
dIJVd Ill A inotilwarboxy airily. by ineans of NO.. With either
the t.,11C or the dynAmic melbolls (cf. Vackel and Kenyon,
C-A, 36. 117,31); the latter wA4 clitTint out in is drsl%cmot
conts a beaker of liquid MN And (he residual air Wall pultl;lell
0111 I'lle V0,11 content .I .41sinic aCid WAS not itICICAWd
with Nth (feAtIttlitt. hence SICINOndAry Off groulJ4 are on-
attsckcal. 14timarv Off anti CIIO xroupi are midily oil.
dired (diatd,laydee Iluf~ ill oilkliml to A product conic.
:12 1,*;. CWO File extent of chatill .1"lluction cannot be,
c,l(d mucr lutro,itiction of COJI arlitsi. lowerv the stability
to AII-11 it the O-C it AttAcked and the viscoinctric method
it un,uil4ble. The fragrurrititive action is shown by a
10 to 13-folA decline in the viwosity of alginic acid treated
with No, (Coill content is coult.). The inanocarboxy-
11111011! (1) is 100% VA. in '-N1'70 NAOII anti is 50-411%!uorr
hygr,"ie than the initial linter; the name is a pmrimoll.41
Me It- the 4M TirlililinS (MM d-C "Nil IA%kM anti hAving the
structitre of pl,firglyruronk- acid. Nitration of I rAvc m.
trAir4 l,lhose ally. in NleCO is 9.7-18.77,1 with 1317c N
content and C0,11; nitrates of alginic or pectic,
O"Cid, are 96 ltxle`~ stil" The so," in %,1T. MST be attrilmlled
'to Vtll~tl-VhAill "tClIfil-3tiOn 14 Coill ;till[ Ito. a pt-e*,
Irraddy visuallml ill nitiatiolls In nolla,piroull 111"H4 (.11ch
~"" flq~*, IIX(h. 41- 11j'O.. and 2"', It" fm 4 hm at Z1*1;
! when nitration is cirtiell out tit -Ins clinic 101" lilt) tile
istily. nf the Product rises to M fl.. W; maAi. 4444~~ in
i0xinic acid tand pectic detIVA. Art attributed to the different
lateric arTantruicult tit the acid anti till-. groups, I Wits
atetylated in holljo- And Ovillel"S. the procrilt
IS MeVrFVIY rflAldOll by CChlI groups MMI Is SIWCII%Srn C0411g.
1.11% C0,11 thirg not completely react lit 24 hm. undcT con-
dition which completrly acirtyLate totion linterst. Incom-
Mr,420 only. (3.7%).
pletely acttylated products have low, .
rimers show molubilit" mnsing (Toot
I . 7.107. for speelmens having I ~9 41,11% COsIL It
Is lictirml that AcjO forms suixed nnhy,164tra with the Cli-Nif
crimps which then reacts with the M11 groups of interchairi
type.is fAct,w which preveovt further swelling anti thut
reduc ng the reaction rate. Solo. of I in dil. NsOll anti
treAtment with AcN`Ch Save the imsel. Ag late which, treated
with MCI ill U1011, vicht" the Ile file, which is wil. in It.0
(,%~, foe Opn . ft-nn Act) and inkA. in UtOll. G, M, K~

and A, F. .1fernechkina
T. I a. lCrk
VIN iii-02).-Wixxi and ai;
vZonliFMI by tho!%low re"tinit
Semijamitaje, A., M17, IM2171fri, which I rithet
(a) being exclosivo when
je) Roll + R'H or (b) RION +
R -02-1 and R' - sJkyl: the probable structure of fignin in
diacu , Liffain (10-1111.) and firfulif Nit, (400 ml.) are treated
with Na (W-75 wt,% of I gnin) until live reaction mose dik-Wours
no fatthef: in the come cd~cuprammonlo I*fn -2114. (A monninefic
aromatic Cabstances am obWiwd camprisin 8-4- lot Initial fir' if
mat-W M extractable by EtsO from allatne ~Autioo and I S
im extractable from add- ~AO%oflisdih)drt*uKerA(beaseate.
m.p, 74-73'; phenylurwthane m.p. 122*) , two other sotwitances
are also pmvnt. one ungxamined, the other solid hydrocarbm
(CIIIH &I amounting to 0-401. of tho initial li~io- U consists of It
12% of initial lignin) and acids, The lihrnA-J was

Cleava of lignin with Illetallic joiflunt in liquid ant
list V. N, N Slu-tvgm-l aml 1'. Y.4. Kch-li
:tion YI
cellult'.W. tim'-lisit. Clicall., Alt,ml. NI'l
4., h4, hel K 4 1,,, , I I Owm 1 20. 1199
.1*' 1. ,,, 1 '111
-4 N INI ; 0. C .1 44. :1919. .1 1
mmium ligniii %uh ','.I tit liqmd Nit, t-v
am.,nK
11.4, Ilse l"It'lm I M. I Ill 1.411 .... .. it I, NI"'A I.
I all 2 N N.,01 I js.~ %, I %,1t .... .. i1v milMmi,m I-t-lml. b,
MA -14)" llrbi'It ~,ifh KNI..O. It
VICIlled %viraltic a6d. I Irmv Ow initiA plit,amlic ,If~tmlce
%.a. (1), if,
.11hem.-mle (liv file Shottris' I Us Itsial till llwtllo~l) tit. 90
tit"Ill Ill VIOIII. I'llile tilt sit
INI-15" th-t, Ill I;ttlll). tmi Ilse his A Itylu'rikals) its.
lui-V* (fout.-I C.Ild-twitf. athirl). a4l.
I.. M.M. I(
..
sit. 1U, 711". Is, 1112 :1
;&fill .1 1is ILI J% liv.1r.'r I"m .4 ""llf"VI A.,
lives ItAtirv NI 111 1-14,11 1j.4- file
with file ;J-W~ mllmlon -1111 KNIIIII, I.tlIr.l I.,
Aeoll. I re.j.111v vi(1,1,,l
if 1.5 S. 1,411111in I.- FIX14111
till be, pl-b" I f...
Millis. r'l-salls. if it 1%1
I;t.Ni]tU# -,1e -A .11h."a I-,I ... e. I I.,
Ywhimr on'. "'. J.%ji
twlictl. she
"llier, Ill. It'-- 17 . tit ... It FtOll Ilse d,-Se.:,ssji,
-"froxy -J- lliethovirpli,nvii
III, Ill! 15, (frmtj
Ille 'tilletille I'll I .11c.1 a1..%.

r, A-
The 4tltsv&le Of fignin with Metallic sodium in liquid
aimtoaia. M N. S. Sh,3r%-gi,,A aud '1*, y, Krfrjj. ~r
Gen. Chem. U,S.S.R-'20 '- 121~-52OU50)(Fticl. tntu~Utiott,.
-See C.A. 45, 1531~. R. NI ,~,

1. SHORY-UNA, N. N.
2. (600)
4. ShostakovsIdi, F.
7. "Vinyl ether3.11 M. F. Shostakoviskiy. Reviewed by N. N. Shorygina. Usp. khirn.
21 no. 10, 1952.
9. Monthly List of Russian Accesskons gress, 'Llarch 1953. UnclassifiecL-
, Library of Con.

USSR/Chemistry - Lignin 21 Oct 52
"The Chlorination of Hydrolyzed Lignin," N. N. Shory-
gina, A. A. Chuksanova, inst of Org Chem, Acad Sci
USSR
"Dok Ak Nauk SSSR" Vol 86, No 6, pp 1135, 1136
The chlorination of hydrolyzed lignin at room temp
without catalysts and without an excess of chlorine
takes place with a part of the chlorine going into
the aromatic nucleus in the 6 position. Presented by
Acad A. N. Nesmeyanov 9 Aug 52.
PA 234-T30
234T30

SEMECHKINA. A.F.; SHORYGINA, U.N.
Decomposition of ligain with metallic sodium in liquid ammcnia. Zhur.
Obehchey Khim. 23, 593-5 '53. (MIRA 6:5)
(CA 47 no.20:10843 153)

_N
i1

h
l Ab
i
t Cleavage of to with metaffl. Sodlu.
quid ammorda,
etalut-0 . . liqui'd ~rnwp~ . on fir
V~~-Ine__41
kA
AW
Sh
E
5
hid
em
ca
s
. an(
a3 ani
ma
_
_
zmc;
Acaff. W, EJ,.';.,';,R w ~Wla
Vol- 48 No. 3 -7(1953); c1, 'i - 47, 108,1.3f.-
xhim. 23, 1593 , .&1.15, 153(
Feb. 10, 1954 Fir sawdust,. "td. ivith 1; 1 EtOl I-W6, 5~~ 111.011, and
'

Cellulose and Paper t?q_-at,~-i with 1005'o.ex-,
2% AcOH and dried over P,O, wxs
'cess Na (on wt
of wood used) in liquid Nil
; after 7 days -
.
,
the solu. lost Its color and thc solid re,;iduc was st:pd., kept'
overnight under moist MO. mid extd. wit It 11:0. Theinsol.
residue (10.32 g. from about 30 g. wood) was colorlesj fibrous
cellulose. Exta. of the aq. sdIa. witit Ht,O gave 1.23% di-

a C
u enol (1) (beazoate, m. 74*). Acidification of tile
a !with HrSOA pptd. a rn-xt. of liguin (11) and hend-
6
il
La
0
m
hi
td
ith M
27%
h
..
Ce
.
o
c
. w
, gave
, ex
) w
3
(
This was fractionated, yielding 0.45 g. I and an unidentl
-fled mater-W. bat above 100*. The M20-insol. part was
eztd. with hot EtOH, and the ext. evapd., giving 9,270
y0lowlsh powdery H, with 0.43% McO; this was treated
with an equal. wt. of Na in liquid Nl[j and gave, after the
usual treatment, a minute amt. of an unidentified low mol.
wt
ll-1
r
duct a
e
id
d
l 11 with 9
Th
08%hf
O
011
-
.
n
r
s
ua
c
e
.
.
,
p
'
W residue consisted of gray U1, with 1.97% MeO. The
~
results indicate a clote relation between the natural and the
~Lsolatcd t1guln. G. W Kosol ff

Actjpn of metallic sodiq_m in liquid ammonia on sPrUCO wooll.,
A. F.'Scineckina and'-\'. S.751iorvgina ( l--jjse)jj)rvrj~ if pig 'I'l%triffechnik.
l93-f-5-,7U=9rj.-T6e-rencttnn avlojr- tell, IjvT;tt ure w,14 examined
and the results found to be sinfilar to tli,,,v it-orn ilic ~anw reaction
applied to isolated lignin, dih5-droi,iigvnoI being mio of the deconi-
rosition products in Lach caic. Thizi indicates'a. fission of all ether
inkage present in the lignin and tltws tint support Freudeidierg's
theory of the lignin structure. Confirmation that the Cellill(L'Al
and hernicelliflose present contain inethoxy groups was obtailled
and the easy separation of the lignin from the wood complex ilidi-
cated tl;at a chemical conibinatio~l of the former with carlwhydrates,
is present which Is not split up under the ct)ntlitions of the reac tion
T,%nMAN,
M

SHORYGINA, N.H., doktor tekhnicheekikh nauk.
One's life for one's Country. Znan.sila no.6:10-16 Je 154. (MLRA 7:6)
(Shorygin, Pavel Polievktovich, 1881-1939)

_7
USSR/Chemical Technology Chemical Products and Their Application. Wood Chemistry
Products. Cellulose and Its Manufacture. Paper, 1-23
Abst Journal: Referat Zhur - Khimiya,, No 19., 1956, 6334o
Auth,or: Chuksanova, A. A., Sergeyeva, L. L., Shorygina, N.
T_
Institution: None
Title: On the Action of Dilute Nitric Acid on Isolated Isignin
Original
Periodical: Izv. AN SSSRY Otd. kbim. n., 1956, No 2, 250-252
Abstract: Study of the nitration of hydrochloric acid lignin and hydrolysis
lignin (I) a boiling with 3.5 and 7% EN03 has shown that the nitrating
agents are oxides of N. Content of N in the nitroligmins thus ob-
tained varies within 1.89-3.05%- If during boiling of I with BN03 no
evolution of N-oxides is observed. The resulting reaction product
caatains traces of N. In nitration products of I the OCH3 CODteDt is
decreased and COOH-group content is increased. From products of ni-
tration of I was isolated by ether e-xtracti.on in the cold a 0.82%
Yield Of 3.,5-dixni~ro quaiacol, MP 122.53 and also (COOH)2-
Card 1/1

15-57-4-5525
Use of Hydrolyzed Lignin (Cont.)
lignin neither melts nor dissolves. It contains only a small number
of free functional groups, which is one of the causes of its chemical
inertness. Chlorination and nitration will convert a hydrolyzed
substance into a product which contains a greater number of functial-
al groups (carboxylic and hydroxylic) and which is soluble in
aqueous solutions of alkalines. The tests showed that activated
lignin effectively reduces viscosity and surface tension of argil-
laceous solutions. Preparations of lignin nitrated with 8 percent
nitric acid are most effective in drilling solutions.
Card 2/2 M. G. M.

SERGEYEVA, L.L.; GHUKSANOVA, A.A,-,*, 1.111GIN~
Action of diluted nitric acid upon hydrolytic lignin. Izv. AN SSSR.
Otd. khim. nauk n0.5:653-654 MY '57. (MIU 10:8)
1. Institut organicheskoy khimii im. N.D. Zelinskogb Akademii uauk
SSSR.
(Nitric acid) (Lignin)

ace of properUes of cb-fora derfvxtivas of
on the conditions of chlorimtLoa. N- Ru
00

20-5-34/60
Conversion of Levogluaftan into Aromatic Compounds
(0 prevraschenii levog~~zana v aromaticheakiya
soyedineniya.- Ruserian)
By pea~iodic shaking it could be accelerated almost
fivefold. Organosodium Intermediate producte(bright red
color which disappears after some time) might be expeo-
ted here. As can be seen from tab. 2, the yield of phenol
is directly pr portional to the amount of sodium up to
a maximum. Ii. lorresponds to the 6 atoms per molecule of
trimethyl-levoglucosan, which are necessary for the
cleavage of 3 ether groups. Sodium excess does n6t in-
crease the yield pf phenol. This fact is of essential
importance, since it indirectly confirms the mentioned
reaction system by Shorygin and Shorygina. Tab. 3 shows
the influence of temperature on the course of the reaction.
The shortest cooling time which leads to a maximum yield
of phenol was determined. Beside 1-atom phenol the forma-
tion of 2-atom phenoles, ;~yrocateohlin and resoroin, was
disclosed. The work is continued. (2 tabl., 2 Slavic ref.)
ASSOCIATION: Institutefor Organic Cheristry "N.D. Zelinsky" of the
Academy of Soienom of the U.S.S.R.
PRESENTED BY: B.A. Kazanskiy, member of the Academy.
SUBMITTED: 25-12-56
AVAILABLE: Library of Congress.

SHORYGINA, N., kand.tekhn.nauk; OTLIVAITCHIK, A., kand.tekhn.nauk
Using s7nthatic materials in construction. Ila stroi. Mosk. 1 n0.7:
15-16 Jl '58. (141M 11:9)
(Plastics)

SHORYGI-WA.--H-X.,-IZUMRUDOVA, T,V.; ELIKIIONES, N.M.; STAROSTINA, K.M.
Chlorolignin and its industrial preparation. Gidroliz. i lesokhim.
prom. 11 uo.6:8-10 '58. (KMA 11:10)
l.Institut organicheskoy, khimli AN SSSR (for Shor7gina, Isumrudova).
2.Gosudaretvanny7 nauchno-issladovatel'Bki7 institut redkikh metallev
(for 1911khones, Starostina).
(Chlorolignir-)

7C'-
AUT -70PLS Semec"-.kin_z, A. F. Shor~7-Jna, 7
L
TIT LE: An Investiil-ation of the Ilusk L 4 gn -'I: of the Seeds of the C-D"cn,
Plant (Issledovani,re liL,'rnina sheiln'hi se:nyan kh1cpchatnik.p.)
P"RIODICAL: Zhurnal Ohshchey Khirqiii. 1950 ~, Vol- t 28, Nr i , pp. 119-121 (USSR)
I~BSTIZACT; Fro,2 the earlier papers on. the compcoition of the husks of
the cotton plant is to be ,ieen that it is dependent on the
sort of cotton, its ripenin5 and other properties., The num--
ber of components varies rather obviouslyi ash 2 - 2,88 T.,
pentosan 21,6 - 27,6 cit, cellulose 36 -- 4G,5i,,, lignin_19,6
- 32 11o, fats and resins 21 - 38 clo, Uronic acids 4,4 5 , 5
proteins 3 - 9 Vo. The ccntent of methoxyl groups in the
husk varies between 0.05 -- 1;87 1/0. From these dat-- follcuS
that in spite of the considerable content of li-nin in the
husk, the quantity of methoxyl groups in it is about 3 - 4
tines less than in the~i L-neous f-;ber of coniferous trees
and 3,5 - 4,5 tiLles less thar in the 11*~nOOUS fiber of de-
lignin of the
Card 1/3 ciduous trees. This indicates that the hU31', L

...25/63
An Investigation of the Huak Lignin of the Se_eds cf "he Cotton Plant
cotton seeds is accordirig to its composition highly diffe-
rent from that, of lignpous fibers, or that its content is
considerably lower than in the latter. In the latter c-ase
lignin is polluted by humification prcducts. For this pur-
pose the husk liGnin of cottQ-n seeds vias more closely in-
vesti-ated. The separation of ii-nin was performed accoriinc-,
to different methods deccribed in the report. Ripe cotton
seeds from the Ferganian Factory viere used for processes
of hydrolysis: They had the following compositioni ash 2,31';'),
.-nin according to Koeni- 33,35~o,
resin products 1...42ri"" 140
OCH3 - 1,5W% pentosan 25,2910, delint 2'Qjj~'). As the table shows
the husk of the cotton plarn't cortains conside:nbly less meth-
oxyl groups than the li,-,neous fiber, like the isolated lig-
nin of the cotton plant in compar-1son with the separated lig-
nin of ligneous fibers. From this follows that in the husks
of cotton seeds the contet, of aTomatic components which are
characteristic of the lignins of ligneous fibers is lower
than in the ligneous fiber. Amon,- the content of the husk
lignin of the seeds of cotton plants are components which
contain aromatic nuclei of an elder-(lilac ?) and .:ruayacyl
Card 2/3 structure. Elements vrith oxypheny! radicals were not de-

79-1 25/63
An Investigation of the Husk Li~,,nin of the Seeds of the Cotton Plant
termined in lignin. The composition of 'he aldehyde mix-
ture obtained by the oxidation of cotton husks with nitro-
benzene and alkali indicates the fact that the "natural
lignin" of the cotton husk is similar to the lignin of de-
ciduous trees. There are 8 references, 7 of which are Sla-
Vic.
ASSOCIATION: Institute for Or8anic Chemistry AN USSR
(Institub organicheskoy khimii Akademii nauk SSSR)
SUBIMITTED: December 30, 1956
AVAILABLE: Library of Congress
Card 313 1. Chemistry 2. Lignin-knalysis

AUTHORSi Seme.--hkina, A, F. , Shorygina., N. 11. SOV/79-28-12-23/41
TITLE, Decomposition. of Lignin With Metallic Sodium in Liquid Ammonia
(Raziozher-iye lignina metalliches-kim natriyem v zhidkom
ammiake'- VII. Chromatographic Investigation of the Phenols
Formed in the Decomposition of Lignin (VII. Khromatografiohes-
koye iss1edo,;ar.,4--,,-e ferol.01y, poluchavughchikhsya pri razlozhenii
lignina)
PERIODICALs Zhurnal obshchey khimii, 1958, Vol 28, Nr 12, pp 3265-3269
(USSR)
ABSTRACT. Shor-T-gina and he.-.? -~:)operatcrs had earlier found that metallic
sodium in liquid aa--moni-a decomposes lignin under the formation
of monomeri's phenols (Refs 1-3). To investigate these products
of daoom-pos~7.cion mot-e in detail paper chromatography was
t~.,mployed. Lignin WaS Droduced from the wood fiber according
to Freudenberg and WillstUtter (Freydenberg, Villshtetter,
Refs 4,5). The treatment with the solution of sodium in liquid
aw-wonia was carried out according to reference 1, with only a
s
'light. modi-P4,:ation of the extraction of the decomposition
products treated with et-her and water, which was carried out
Card 1/3 in aci-d solution. The phenol mixture was separated from the

Decomposition of Lignin Wit-h Metallic. Sodium in SOV/79-28-12-23/41
Liquid Ammonia. V11, Ch.Tomatographic in%restigazion,
of the Phenols Formed in the Dec~rnpcsition of Lignin
an.i.du by extraction with ether from the bicarbonate solution.
In the pa-)a:t- ~;hromatogjraphy of zhis viscous mixture the
f ollow:-_ ng S017enta were used: 1) Petroleum ether-benzene-water
1 1), 2' F-itzileum ether-benzene-acetic acid-water
(1. 0.2'- 1)z 3) Petroleum naphtha saturated with water.
~he phr-inols were determined by means of the diazotized
aulfanii3nide. Their 3omposition was rather complex (Figure).
T he. abo*,-~. and below abows the (4-OXY-3-methov-
pheryl)-Pr-OPar,013. and thus proves the presence of all three
posa-ib-'e -somerg cf gi:,.aiac-.1-z,..-propanol-1,2 and 3 (11, 111
and 111). To expla'n the behavior of the phenol alcohols
d_=te:rm-_".-.~d in the decomposition of lignin the compounds (n),
(III) and (IVI were treated wi-ch a solution of sodium in liquid
ammont.a, mer~tioned above. The phenols separated from the
-mass (after C_'?coloring) proved to be mainly initial
with a minimum amount of dihydro eugenol, which, by
ths way, was also ebtained in small quantities according to
o-,L,er (Pef_- 0', 7). Part of the phenols formed have
Card 2/3 not v~~t beeLi There are 1 figure and 13 references-,

Dero,7,posiTion of ~,4~.gnin With Metallic Sodium ir, SOV/79-28-12-23/41
LiQuid kmmonia, VI I ~Chromatographic Investigation
of,tilie Phenols Formed in the Decomposition of Lignin
" of which arz Soviet.
Aj3OC!r~.TION: Institut organioheskoy khimii Akademii nauk SSSR (Institute
of Organio Chemistry, Academy of Sciences, USSR)
SUBMITTED% Octobex 28, 1957
Card 3/5

7' (2,(.6
o -,,rl ~ -.) P i -'-.
-D j - -!L) - ! ( ~,/-y~
AUTEORS: Shorygina, N. N. (Doctor of Chemical Sciences), iz,,urirudova
,
-T-. V-.-CCd-ffd-1U-at-eof Technical Sciences)
TITLE: Modern Concepts of' Structure,, Properties, and Ways of
Utillzation of Lignins
PERIODICAL: Khlmicheskaya riauka I promyshienno3t 1, 1959, Vol 4, Nr 6
,
PP 747-750' (USSR)
ABSTRACT: This is a review of the structure, properties
and use of
,
lilo-nins (lignin compounds, as the authors propose to call
it), based on the literature. Numerous formulas of the
structural elements of lignin compounds and Freudenberg's
theory of lignin formation in plants ,,,,ere considered and
corripared viith the properties of the "lignin", product of
deh,, dropolymerization (DHP), which was obtained in vitro
by Freudenber-2; and associat-les. The authors come to
the conclusion thaL vresent knowledge of lignin chemistry
is still limir-ed, and that therefore the lignin compounds
Card are the viastes of cellulose hird-rolysis and paper

Mcaerr-i Cor-icept-.s of Szri-Icture, Properties, 77276
ar,J Wal/s o" Utillization of Lignins sov/63-4-6-10/37
Card 2/2
industry are not properly used. It is estimated that in
1960 the USSR cellulose hydrolysis industry will acc4imu-
late "00,000 tons of lignins. 30-35%-Of ",-his amountIwill
be used as fuel, which is not itS proper use. The authors
reviewed different patents and ways of lignin utilization.
Such uses of lignins as rubber reinforcin4 agent, tanning
agent, exchange resin bases etc., are considered. Con-
version of lignins into monomers (preparation of ~yro-
catechol and protocatechuic acid by alkali fusion
nitration, oxidation, preparation of chlorolignin,
preparation of heat-insulating materials, and other
uses of iignins are also discussed. There are 71
references, 14 U.S., 4 U.K., .13 Swedish, 8 German, 1
Japanese, 31 Soviet. The 5 most recent U.S. and U.K.
references are: E. Adler, Ind. Eng. Chem., 49, Nlr 9,
"37-1 '1957); E. Adler, J. Pepper, E. Eriksoo, Ind. Eng.
Chem., 49, Nr 9, 1391 (1957); L. Bock, I. Anderson,
Chem. Eng. News, 35, Nr 15, 29 (1957); U.S. Patent
2724723, 1955; C. A. 50, 10779 (1956); D. Bland, Proc.
ROY Austral. Chem, Inst., 214, Nr 2~?. '~~,7 7).
7j _~; (1951

!I
5 -3400 7 7 08 ~
SOV/62-59-12-28/413
AUTHORS: Chuksanova, A. A., Sergeyeva, L. L., Shorygina, N. N.
TITLE: Behavior of Lignin Models an Nitration
PERIODICAL: Izvestiya Alcademii nau1c SSSR. Otdeleniye khimicheskikh
nauk, 1959, Nr 12, pp 2219-2225 (USSR)
ABSTRACT: Nitration of lignin is accompanied by oxidation. The
reaction of nitric acid with lignin model compounds
was investigated. The following rpnomers were used
as models:
(1) Ri=CIIOII-Clll-CI[3, III = C113
(11) R I= C11011 -CIII - C113, 112 = 11
(111) 111 = C11, - C,11011 - C113, R2 = Clio
(IV) Ri=Cf1z-C1101[-C119, 112 = 11
(V) Rt = C112 - CII! - C111.0fl,
Q R2 = Clio
\ (VI) III = Cil: - CIL - C112011.
I OC113 R2=H
URI (VII) III = C112 - CO - C113, R2 = C113
(Vill) Ri = CH, - CO - C113- 112 = H
Card 1/3

Behavior of Li.anin Models on Nitration 77o84
SOV/62-59-12-28/413
The nitration was carried out in CC1 4, at 5 0. .1-(3,4-
Dimethoxyphenyl)-propan-l-ol with 3 M IM03 gave the
.Lolloy.,.ring nitro-compounds: 1- (6 -nitro-3', 4 -dime t hox-y-
phenyl)propan-l-ol (M.00 860), a very small amount of a
dinitrocomDound (mp 95 ) and 2 compounds (C22"2809 N2)'
(1) M-0 2060, mol. w. 462 (cryoscopy In benzene) cxl-
dation (15% HNO ) gave 4,5-dinitroveratrole. (2~ MCI-
30. -dinitroverat-role. Nitratulon
134o oxidation gave 4,5
of Il gave 3,5-dinitroauaiacol (M 1220) and a nituro-
CD
comnound C20'1'2409ii2 (mP 14o-1410~, mol. ;%r. 4!6.
Nitration of !!I with 1 M H!~O ':7-ave l(6-nitro-3,4-
3 (D
dimethoxyphenyl)-propan-2-ol (A) (mp 99-1000) and
with 0 'M HNO3, in addition to A, also 1-(6-nitro-3,4-
din, e t hox-yphenyl) -propan-2 -one. Nitration of 111 with-
1 M FHO gave a mononitro-derivative (mp Q!z-960). V
with 1 Ld 3 M M03 gave 1-(6-nit-ro-3,4-dine-uho.K-ypr,-enyl)-
Card 2/3 propan-3-01 (MID 92-930).

r,
Behavior of Lignin Models on Nitration 770d
sov/62-59-12-28/4'3
ASSOCIATION:
SUBMITTED:
Card 3/3
VI with 3 M HNO 3 gave a light-brown powder containing
5.32% nitrogen. VII with,3 M HNO 3 gave 1-(6-nitro-
3,11-dittiethoxyplienyl)-propan-2-otie (mp 125.50). VIII
with 3 M HNO 3 gave a dinitroketone (mp 1840) of
unknown structure. This seems to indicate that lignin
contains 60-70% phenyl-propane structural units
capable of being nitrated. The yields are not given.
There is 1 table; 9 references, 3 Soviet, 3 German,
1 Finnish, 2 U.S. The 2 U.S. references are: M.
Kulka, H. Hibbert, J. Am. Chem. Soc., 65, 118o (1943);
Ph. C. Roberti, R. F. Jork, W. S. MacGregor, ibid. 72,
576o (1950).
Zelinskiy Institut of Organic Chemistry, Academy of
Sciences, USSR (Institut organiche3koy khimii -imeni
N. D. Zelinskiy Akademii naulk SSSR)
March 31, 1958

Ch-UKSANOVA, A.A.; SHORYGINA, N.N.
Action of nitric acid on /,Y-Suaiacyl ether of 016-veratryl, glycerol.
Izv.Akl SSSR Otd.khim.nauk no.8:1511-1512 Ag 360. (MMA 15:5)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Ethers) (Glycerol)

SHORYGINA, N.N.; DAVYDOVA, G.V.
Carbocyclization of 1, 6-anhydrogalactose. Izv.AN SSSSR Otd.kbim.
nauk no.4:728 Ap 161. (KMA 14:4)
1. Institut organicheskoy kbimii im. N.D.Zelinskogo AN 3SSR.
(Galactose)

s/-,62/61/000/007/009/000,
B117/3215
MHOR: None given
TITLE. General Assembly of the Otdelenive khimicheskikh nauk
Akademii nauk SSSH (Department of' "Chemical Sciences of the
Academy of Sciences USSR), 'March 9-10, 1961
PERIODICAL: Akademiya nauk SSSR. Izvestiya- Otdeleniye khimicheskikh
nauk, no. 7, 1961, 1357-136o
TEXT: This is a report on the meetings of the General Assembly of the
Otdeleniye khimicheskikh nauk Akademii nauk SSSR (Department of Chemical
Sciences of the Academy of Sciences USSR) held on March 9 and 10, 1961 on
the chemistry of cellulose. Professor Z. k. Rogovin reported on new
methods of modifying the properties of cellulose, and mentioned some
trends of research work in this field: (1) Synthesis of new types of
cellulose esters; (2) introduction of new types of functional groups into
the macromolecule of cellulose; (3) synthesis of graft copolymers of
cellulose with polymers containing heterogeneous and carbon chains,,
0. P. Golova, Doctor of Chemical Sciences, repcrted on a "Study of the
Card 1/3

s/o62/61/000/007/009/009
General Assembly of the B11,7/B215
thermal process of cellulose decomposition". Thermal decomposition was
studied in two cellulose modifications of different physical structures:
cotton cellulose and hydration cellulose. Professor P. V. Kozlov
reported on structural characteristics of cellulose and its derivatives.
He said that V. A. Kargin, together with a number of other scientists,
proved the amorphous structure of these natural polymers. He also men-
tioned that the ideas on the"packagell-type structure of polymers expressed
by V. A. Kargin, A. I. Kitaygorodskiy, and G. L. Slonimskiy are of
greatest value for the examination of the macrostructure of cellulose and
its derivatives. S. N. Danilov, Corresponding Member AS USSR, reported
or, the "Reactivity of esters of cellulose and chitin". He pointed out
that -hitin and cellulose supplied esters of great practical value. Their
production, however, is still difficult. In his own name and an behalf
of P. N. Odintsov, Academician AS Latviyskaya SSR, A. I. Kalnin'sh,
Academician AS Latviyskaya SSR, reported on the prospects of development
cf 7imber chemistry. He stressed the necessity of finding new methods for
the utilization of large timber resources, wood waste and vegetable remains
in agriculture, and of rationalizing conventional methods. At the same
time, theoretical work in this field is to be intensified, 'N.N. Shorygina,
Card 2/3

CHUKSANOVk, A,A.; GRUSHNIKOV, O.P.; SHORYGINA, N.N.
Study of 4trolignin inhomogeneity. Izv.AN SSSR.Otd.khim.nauk
no.10:1810-1812 0 161. (MIM 14:10)
1. Institut organicheskoy khimii im. N.D.Zelinskogo Pji SSSR.
(Nitt)lignin)

-SHORXQINA+-R.N-; IZUMRIJDOVA9 T.V.; ADEL', I.B.; ZAGMIMISTR, O.S.;
SALOMATINA, Z.T.
Prospects for the use of hydrolytic lignin in the protroleum
industry. Gidroliz. i lesokhim. prom. 14' no. 1:5-6 161.
(MIRA 14:1)
(Lignin) (Petroleum industry)

TURETSKIY, Ya.M.; SHORYGINA, N.N.; IZUMRUDOVA, T.V.; GRISTAW, Ye.L.
Using chlorine lignin for the flotation of iron ores. Gidroliz.
i lesokhim. prom. 14 no.8:10 161. (MIRA 16:11)

SHORYGINIA, N.N.; DAVYIX)VA, G.V.
Carbocyclization of 1, 6-anhyd rider of D-pulose and Diiido5e. bokI.
All 553fl 240 no.3:6.17-(19 5 161. (Y,-rRA- 14:9)
1. Institut organicheskoy khimii im. N.D. Zelinskogo Ail SSSR-
Predstavleno akademikom B.A.Kazanskim.
(Gulose) (Idpse) (Cycli2ation)

SERGEYEVAY L.L.; SHOR UNA, N.N ; LOPATIN, B.V.
Nitration of lignin and model compounds containing an arylearbinol
group. Izv.AN SSSR.Otd.khim.nauk no.7:1295-1302 J1 162.
(MIRA 15:7)
1. bistitut organicheskoy khiTrii im. N.D.Zelinskogo AN SSSR.
(Lignim) (Nitration) (Alcohols)

.-SHORYGINA, N,N.; NIYAZOV., Kh.R,
Study of lignins extracted from cotton plpnt by mechanical grind-
ing. Izv.AN SSSR.Otd.khim.nauk no.6:1122.-1123 -162. (WRA 15:8)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Lignin)

S/062/62/000/011/018/021
B100144
AUTHORS: Kuznetsova, Z. I., Ivanova, V. S., and Shorygina, N. N.
TITLEt New nitrogenous cellulose derivatives
PERIODICAL: Akademiya nauk SSSR. lzvestiya. Otdeleniye khimicheskikh
nauk, no. 11, 1962, 2087 - 2089
TEXT: The possibilities of modifying the pr 'operties of cellulose by
introducing new functional groups in the macromolecule were studied. For
this purpose, the condensation of dialdehyde cellulose (19.2% aldehyde
groups) with nitro-methane in alkaline solution at 50C was carried out for
the first time. The following general reactioni course is assumed:
Card 1/3

New nitrogenous celluloae derivatives
Clio rHO
I<
--o--, H
I
i,
C11 I I
C. N 0 No CH,
"
"
"
1
0
0-

5/062/62/000/011/018/021
B101/B144
(a) dialdehyde cellulose.
Card 2/3
Ali a A i, A t r imat a A wo3s
G

S/062/62/000/011/018/021
liew nitrogenous cellulose derivatives B101 B144
The nitrogen content of the resulting preparations reached 3.4 - 4-9K
the increase in weight was 17 - 20% of the initial weight. These data
imply that the reaction proceeds mainly in the direction of I and II; one
of the two directions can be selected by choosing the reaction conditions.
The resul-.ing nitro derivatives are-yellow, kedp their fibrous structure,.
and are stronger and more elastic than the initial dialdehyde cellulose.
Further new cellulose derivatives, e.g. those with N`H groups, 4re to be
synthesized by reaction of the NO2 groups.. There is 4 table. The most
dmportant English-language reference is; H. Baer,-H. Fischer, J. Amer.
Chem. Soc., 82, 3709 (19060).
ASSOCIATIONj Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: June 18, 1962
Card 3/3

SHORYG.IM, N.N.; NIYAZOV, Kh.R.
Study of the structure of cotton plant--lignin3:by the method of de,
structive oxidation by aitrobenzene in an alkaline medium. Izv.AN
SSSR.Otd.khim.nA,uk no.9-1689-1690 S 162. (MIRA 15:10)
1. Institut organicheskov khimli lin, N.DZ&lJnBkDgo AN,53,5R,
>D>4w*>

SHORYGINA, N.N.; DAVYDOVA, G.V.
Diphenols obtained in the carbocyclization of D-hesose 1 6-anhydrides.
Izv.AN SWR. Otd.khim.nauk no.lls2058-2062 N 162. ?MIRA 15:12)
1. Institut organicheskoy khimii " N.D. Zelinskogo AN SSSR.
(Hexose) (Phenols)

KUZNETSOVAI Z.I.; IVAROVA., V.S.; gHOITGIN~y_ N.V.
New-nitro derivatives of cellulose. lxv,AN SSSR. Otd.khimnauk
no.ll-.2087-2089 N 962. (KMA 15:12)
1. Institut organichesko7 khimii im. N.D. Zelinskogo AN SSSR.
(Nitroct1lialose)

-SHORYGINA, N.N.; NrYAZOV, Ih.R.
Determination of molecular weights and carbonyl groups of cotton
lignins. Izv.AN SSSR. Otd.khim.na-uk no.11:2094-2095 N "629
`(MM 15:12)
1. Thstit# orSanicheskoy khimli im. N.D. Zelinskogo Ag SSSR.
(Ligifmj (Molecular weights') (Garbonyl group)

NITAZOV, Kh.R.; ~~HCIRTG~N~, N.N._
Studying the structure of cotton plant lignin by the method of
destructiye reduction with metallic sodium solution in liquid
anmonia. Izv.AN SSSR.Otd.khim.nauk no.3:563-565 Mr 163.
(MM 16:4)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Lignin) (Reduction, Chemical)

CCHKINA, A.F.; SHORYGINA N.N.
if
Phenols 'Obtained from aspen lignin during its decomposition by sodium
solution in liquid ammonia. Iz* AN SS~R. Otdkhim. nauk no.4:715-720
Ap 163. (MIR& 16:3)
1. Institut organico~4oy khimii im. N.D.Zelinskogo AN SSLiR.
(Phenols)

SHCRYGINA, N.N.; MIKHAYLOV, N.P.; GRUSHNIKOV, O.P.
Obtaining some modified preparations of hydrochloric-acid lignin.
Zhur.r)rikl.khL,n. 37 no.1:170-176 Ja. '64. (WRA 17:2)
1. Institut organicheskoy khimii -AN SSSR imeni N.D.Zel-inskogo.

iA n' n by
17;
d I c n in (141TRA 17,6~)
n 5 884-RqG
!,a.ogo .11
jr.~-Jtut E Z- "A

DAVYDOVA, G.V.; SHORYGINA, X.N.
Transformation of 1,6-aahydroaldohexoses to phenols under the
action of metallic sodium in liquid ammonia. Dokl. AN SSSR
154 no.1:140-143 Ja'64. (MIRA 17:2)
0
1. Institut orFanicheskoy khimii im. N.D. ZelJ.n,.gkogo AN SSSR.
Predstavleno itkademikom B.A. Kazanskim.

SERGEYEVA, L.L.; SHORYGINA, N.N.; LOPATI'i, B.V.
Nitration of model lignin compounds: 1-veratryl-3-propanol
and 1-guaiacyl-3-propanol. Izv. All SSSR Ser. khim. no.7:125/V-
1260 Jl 164. (MIRA 17:8)
1. institut organicheskoy khimii imeni Zelinskogo AN SSSR.

_7 _71___._'
L ~9683-65 n' VT(0)/EPF(C)/EPP-/&VP( 4) /WIA(c) pc_Vpr_VPs-.4
ACCESSION NR: AP5001604 S/0062/64/000/012/2232/2236
?0
va*
R. Kirnet
sovai
a
_Pkftdration~017several-ce u o i Mi
el
SOURCE: AN SSSR. Izvestlya.' Seriya khimichesk n,
aya, o.:, 12,4964 22 W;
TOPIC TAGS- celIulose dialdehyde nitromethane'condensation primary, nitro-
cellulose derivative. secondary nitrocellulose derivative, tertiary nitrocallu.1ose
derivative, synthesis
A~BSTRACT: The condensation of cellulose hyd %L with
methane was
dialde e nitro
7
effected in an aqueous -alcohol medium,containihg- 0. 5-;. l.equivalents -of NaUfflor
each CMgav oC (a) tD gWe a T-membered ring. (1) (see Entiosvxe). Atb3ijft toti~,y~
of I above ~ 57% by increasing reaction time of NaOE1 were unsticcessiul,'01)
formed with more concentrated NaOH. Condensation of (a) with nitroetharie,
was
nitroethanol and 2-nitro-1, 3-propanediol was more difficurt than,with nftrome---
thane, but the new cellulose derivatives containing secondary and tertiary N02

SeLOVIYEV, Ye.M.; LEONIDOIJA, A.I.; SHORYGINA, N.N.; IZbJMRUDOVA, T.V.
Nitrolignin as a reducer of the viscosity and water loss of
cement slurry. Izv. vys. Ucheb. zav.; neft' i gaz 2 no.3:25-29
T65. (,,aRA 18:5)
1. Moskovskiy institut neftekhimicheskoy i gazovoy promyshlennosti-
im. akad. Gubkina i Institut organicheskoy khimii AN SSSR.

KUZ*ETSO~TA, Z,I.; IVANOVA, V.S.; SHORYGIDIA, N.N
Som-e new dats --n the interaction between cellulcse and gaseous
C4
nitro&-en oxides. Izv. AN SSSR. Ser. khim, na..":,5557-515, 165.
(MIPLA 18: r-)
1. Institut orgnniclif3qkoy khimij im. N.D.Zelinskogo AN SSSR.

SHORYGINA, N.N.; YELKIN, V.V.
Study of lignin of Larix sibirica. Izv. AN SSSR. Ser. khim. no.7s
1279-1280 165. (MIRA l8s7)
1. InstItut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.

IZU~-IRIJDUVA, 'l'.V.; SHORYGEIL N.N.; BOBOVNIKOV, B.~.; IVANOVA-, E.K.
Produ,.,r,4-(;n of "suni-l" In the A-ridizhar. Hydrolysis Plait. Gzidroliz.
1 JeSokj-jjM.prG-dj. 18 r~~.4.,16-17 165. kmlpu 18:~-:,)
1. lps-~itut G-rganicheokoy khimii AN SSSR (for hum-rudova,
Shurygina). 2. And4.zha-.qskiy gi.droliznyy zavad (for Bobovnikov,
17-anova),

7 7 H )h i i1i
n li,~,rnn comrj:~,inlc benzy'--a,:!6h~
I -,he - 7 kh~
71. rL Q ~ -7
AN
he. -'tN SSSF