SCIENTIFIC ABSTRACT SHANOVSKAYA, S.S. - SHANTAROVICH, P.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548310014-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

VLADIMIROV, N.A.; GAYWRONSKIY, A.A.; YEBASHEV, G.S.; BAYKOV, A.M.;
SHANOVICH, L.P.; LOGVINOV, I.I.; WIN, H.G.; SAFIULLIN, M.N.
EffeCL of a cemenr ring on the capacity of casing strings
to resl8t, collapsing ionds. Neft. khoz. 42 no.6:19-24 Je 164.
(MIRA 17:8)

SHANOVSKAYA, S.S., starshiy nauchnyy sotrudnik.
Irrigation with wetting agents as a means of controlling coal dast.
Bor'ba 9 ail. 1:126-133 153. MHA 7:10)
1. Makeyevskiy nauchno-isaledovatellskiy institut.
(MINE DUSTS) (WETTING AGENTS )

Phil
5oIul!ttn,_, id S. S. 2221noivska _a. Zhur.,
06,1"" 'k T637.=" -Y . I .
. ffiftoTl a pRMTMmoIybddtP-
tind SiNcOHIGlYbdilte complexes were vrepd. by adding
fillitnoniacal MoO., 0.1 mol.A., to (NalSi0s), 0&
mol./l., mid acidifying with UN JINO-,. For the P corn.
plex the oider of addii. or the Interval between u4dns. and'
the titne of swiding after the prelin. didnut affect the optical
detisity (dett.l. with n photoincter and ligninst Na,CrO, barax
c0lor stupdards). This indicated camWete rtwerslblllt~ of
tItervactim.
,~ulctl (ui,.-riljed to thu joranation. of colloidal 112810j, The
"St pru'v'Ittre iii prepg. It %vas to U(Id the nuitawlacal ?vIoO;
it) tile NuiSiOjantl humedhatelY acillify 1000-1,40s. Forpil
0.7-2-0. -fit, uptival density was expressed us it flulutlou of'
t1juNlo/11 (SOrittia for Nio + P - callst.. hlocallst., and P.
con,t.; ;,,It ctirvc,; pus~eil through it max, corrrsptiniflay. to
tuldit. ol'113110, ditl not uPPreclably decrw~e the color Inteit.
sity of ilia Si Complex, it decolorIzed the P complex. Thi
Color 111'.t:11sity decreased with Increased Mo coucti%, at Oi7st:
mitt) thtti beemat: const.; at p11 1.7-2.0 all excess of Me
weakewul the color intensity, 'file dissocu. conat. IPO,3-1
l(M000J4APCNfo,O1SV- 1 5.6 X 10-W. J, 11,

BEKIRRAYEV,..D.'B.; GRODELI, G.S.; GULISHIN, P.A.; KLEPIKOVA, M.S.;.PETRMIN,
P-M-; POLYANSKIY, I.P.; RASSOLOY,.N.I.; TARASOVA,.A.A.; FERTELI-
MEYSTER, Ta.N.;.COERVjffSKjT, M.S.; SBANOVSKAYA,,S.S.; KLIMANOV, A.D.,
otv.red.;,ZfflXGV, V.V., red.izd-va; PROZMOVSKAYA, V.L., tekhn.red.:
KONDRATIYEVA, M.A., tekhn.red.
[Coal and rock dust control in mineq] Bor'ba a ugollnoi i porodnoi
pylliu v shakhtakh. Moskva, Gos.nauchno-tekhnAzd-vo lit-ry po
gornonu delu, 1959. 499 p. (MIM 13:6)
(Mine dusts) (Goal mines and minin&--Safety measures)

SH&NOVSKAY-A. 6.S., 4and.khim. nauk; WSONOIGH, A.A.
I
Ways of increasing the effectiveness of controlling dust in mines.
Bor'ba s sil. 5:92-106 t62. (MIRA 16:5)
l. M~Lkeyevskiytnauchno-issledovateliskiy institut po bezopasnosti.
rabot v gornoy prowyahlennosti.
(Mine dusts-Prevention)

v "T
-y'TY
PETRUIKI~.N P ;j t - "
F 'PC -11 -,
Y-
S L~OBVUTSF
HFC, V b
LUG -d~ po-
-Iecl v
V., I
jspra.
coal B,
,,.T.,, roiiirIg
Olr
() !,= ~
e po bor
0~
O.t~ne a'

If i AIR:, V.17KAV Till
y of lutionn of various
,.;.i tima t i ng the wetting capacit S_Q-
stir 'ace--active agents In relation to'lnduaLrial dunt in
ccal TnAy MakNT! 15:206-240 t63.
(MIRA 17.11.1

ROZEITBERG, B.A,; 'SHANOVSKAYAP S,.S;; KOCHAIT, L.D.; FISHILEVICH, Z.A.;
BABIN., Ye.p.
Increasing the stability of foams used for dust suppression in
coal mines. Zhur. prikl. khim. 37 no. 4:908-911 Ap 164.
(MIRA 17: 5)

S/(52161/027/005/007/017
B--30/'B220
2 Do um 71

kinetics of polyrnerizm~ on of vinyl compounds. It
Photopolymeriziationot &IIYI chloride. P.S.SiLuitarovitis
.IINI s. s %lr,IvnIvv (Acad. S.,i.
14. to, ,
Kh... . -41MINI: 0. C.A, 44, Lx0s.
AIM vbl,wult, III ill Ft0Av 1 -1v titer itol in Ilitlit of 311:10
31A0 A. .,I I ijle r 'd t2.11 111,2 Ill -d
pl..I-Flomll 1,01011 ml..'I'liv 1. .11 1 - 1; ~ It, -
,--7.4 x W'.5 I x 11) 6. ;; -I XIII "'111,128
N-N- "I % I I. j 1 -1." -. I I"'. IA " L I I I' IM"' I -I - 1 '114 1 Ile$ 1211 -
I I ... I If I I lie 11.41 k , 't I., af let III till I i I Na IN",. wa, licit I I K I Wc
rttq- wt. .11, 411-(i1. V. Of (1[e finAl [Iftithisk
was 1,01 - 12(111. Will, .57.0, mul 41 O.it 75', LW,*. 45'. and 30 .
reap.; it was itulefictoicia AA dilit. The A p1mircilt energy of
activatinii was 41(m) 4110 cal. Tile nelive milicat (11) of
the Krowing chain rcart~ with a tool. of I forining (%ith
mwti- --t. III.) a rmlical Cll,:Clt.Cllr- (111) -1twh i,
I ... I --tivc elloogh to ic."'i with I ItIlt 1., 11, thos ill-
t"trupting tile r1win. Tlji~~ turch4nisin yields I lie ciluatioti
r - ,k,kdA!kk.; thcc consul. tire for the mictiolts "c-t-
etied morumier + normal incininurr-2 norinal nintiorrim-
t #.I. -vi,61M nummm,r - ra-fical- (kO. lamf "r4dical V
duller- (k,). TIN, rqtmlum Qu- fluil r I,
J '16111, MNI U,1-16.twl to I III llll~ ill.
.t the irooll of tile - hictic 01.1111- 0 - IIN, 84" It
mmmtiter~ mvolvril ill it ch.tin init6ted fly anc is
equA to that of (lie -mol. clWn" (A - the no. of triono.
Ithl, III tilt! oull. of I)olvlncr); it-ill were its active as U. I
w,,uM Iw morli gmttcr duin )~. The kitictic~s of juilynteri-
rat,-. dq-d, - tile Irclati.1, Itet-ell x and 1.
J. J. Itdx ........

USEM/Chemistry - Synthetic Rubber Jul 51
'I'SK (Synthetic Rubber)," P. S. Shantarovich, Dr
Chem Sci
"Nauka i Zhizn I" Vol XVIII, Wo 7, PP 27-29
A plane requires 500 kg of rubber, a 6-wheel
truck 200 kg. Ten~twelve tons of potatoes or
9-10 tons of sawdust . yield 1, ton of aldI ~ ton
of alc yields 600 kg of buta:diene. The ]~ropor-'
tion of natural crude rubber used inLISSR 'rubber
manuf is low, but natural rubber is a valuable
compounding ingredient and the demand for it
grows 'with increased use of synthetic rubber.
19W10
USSR/Chemistry - Synthetic.Rubber Jul 51
(Contd)
The properties of crude rubber obtained from var-
ious speciee of cultivated plants are uniform,
but michurinist rubber growers are trying to de-
velop plants which will`yield products exhibiting
a greater variety of properties.
V, 199T10
a.
~71

Kintfics of pillymorization of compounds with conjugated
Pollyllurrisallon of methyl "Ifthiscrylete t'
.,II.Imai... I, It _tl no. Client, I'll v 4. Arad - S-i. V_ - S k
11ad. Namil" S-S.S /?_ 01M. K41"t
.k lQ5Z' W .;; 0. C .1 42. 2195'- Metlivi ulcth.'c7f
(1, In bulk ..'. to light .(3- KI 313 #too for vArl"ll,
J,uglls, vf tout. . I., Jaring which r-Ayou,tiialinto altain.1 a,,
, 'ft'.f if I, then the illulninatain %a4 shut off
Itmi,ir (It,- INslylurritaluat loclan after .?,
mdu, t-" 1. fl-I if A...it 1 5 tuirl . 11141 then procretleol .41 a
--1 -1. out '.'~ .1efVeil 'if 4
0.- -.1 't I.*",;, -11"I'aal 1,414.1 .1"O'latioll
M I., it,, hauleimaelv 1,44-lux the intrifujili'al
Ow Of . ........ 1'.-. 1.,Ivl;lcllyjfi ... I t.-Illuml first at a hish
- %hoOf fell (Id %try rapidly ilia con't. tum. vel(ocity I,_.
?it- cini%l . r- i~ ilia ilir.4i-f. with only a slow lncrra.~.
III- t"thVI-lut -11[~ICHUI716014101.
ra-, III-It M-tKe I~ trach"I m :0-*1% conversion
I miti th,ot rwlint tin, the rate of joulructitation again begill,
lit "%1'l, olb 1. - its. pl. 21. atuI32 mm .
7 11, 16. 2;.51,.~. The lieriwl ,( if"
d., L 1, j ri,o. th,- gir.it--i i, r,. In thi, it..
1. 1''.. - hL. . lot ....... re"e 111 'vel't Ill"t lite trail-
sitkm from the slow coust. rare to the raphl nonstationArv
'12% conversion instead of 9-
polymer iza lion occurs at about.
10clo with U. Further ist contrast to U. the ithalte of the
kinetic curvc of the dark polymerization of I is independent
of xi. And the end prufuct is the saint, Irrespective of x,
The dependence of r... On X). or X.- (Amt. 01 Foolyrurr
formed at the munlent of tile estAblisfuncut of the const
No. lit theilark) iiof lite Itwita ri. -W~.wilhm - 0.53
And 3 - 1 42 N 111-1. 1% Ith three valtirti. the formula I,
in very " Ith t tic extid. 414W: s-. -0JvCW'.
IMAN-13, to 0,0079 111, r.'.
tomcAur.,.. The-Itcayoftheno-it
of active centers oil interruption of the illumination is de-
~R-t by -dn,ldi - k..t - /n. all-] hencir r,. - kj4k.
This is coliNi%tclit alit, thv -titi. furtailla it ka - ko/%1;.'...
And the kinctics I,( tile talk reaction 3,, de.~R-i by da,di
- Ja - k.v Do, intrgialing this equation, Anil tak-
ing kfjok. - 1.42 X 1() -1. file rjtCS (If the dark tCACtiGn Cato
be calcd. :is a function of tile -1clirce uf conversion X, fur Illf-
ferent x, allmu"t durtnoi the illumination perio,L The
cAcij. L'I"-.1tiTec v'~Iy 'Alisfacturilt, ilh tile rzl,tl. cll"-
'I'lle sp-v re-AI'm it. gctlerAtoal alal Prol'asati .. I
of chaiu., lit Ihv liquid ph.- .,It, the f th,
illutllillatiqjll~ 'I'llo: dark fvA"Ioa cauNW' in tile
merit of tile sp.4tiAly branched %tructurc of the iol"arr, an,l
the rate of t,-rujijiatimi f the growinit ch.,jus follo" III,
law - k"n't. N~ 'I"

SHANTAROVICH, P. S.
USSR/Chemistry - isotopes
.11 Sep 52
"Investigation of the Reaction of formation of T-h-i pstdfatle From F2S and SO~ With the
Aid of Radioactive Sulfur," 11. E. Neyman, Ye. S. lorstiyeva, A. 1. Frdoseyeva, P. S.
Shantarovich, Inst of' Chem Phys, Acad Sci USSR
I'Dok Ak Nauk SSSR" Vol 86, No 2, pp 317-320
The mechanism of the reaction of the formation Na S,O, from SO~ and H2S was investigated
35 2
using I~tive H2S and inactive S02. The F.2s35 was-pr"'epd by reducing pas35 04 at 900-1000o
to PaS which uus decomposed to H2 s35 with HC1. The central S atom of the thiosulfate
mol is derived from the inactive S02. 'he peripheral S atoms come from- both the H2S and
the S02- ;resented by Acad N. !I. Semenov 3 Jun 52
PA 235T26

USS,R/Kinitics Combustion. Explosions. Topochemistry. Catalysis. B-9
Abs Jour Referat Zhur 1qiimiya, No 6, 1957, 18559
Author P.S. Shantarovich. D.V. Pavlov.
Title of Methane.
Ori,- Pub Zh, fiz. khim-ii, 195(, -10, No 4, 6ii-82o
Abstract The kinetics oi *ze t"-?rmal homogeneous dissociation of
Cfft, at 850 to 2(),"-D v~z~ studied. I- t-Oo transformation
depth- wac aot ct..-j- -"-p to 3%), th- ;_,,oc-iation proceeds
accor:fzlilL. to the w = k/ CHI, k = 4.28 x
101.2exr. (-- _j5000ifli~-~ j' see --L,;' In case ~1' g-crat trans format-itcn
devthls, self-brak-ing is observed, -which is caused by 'Lhe
inhibiting infl~.-.,~nce of H2 forming at the dissociation.
The authors prop-)se and analyse tLe chain scheme of CH4
dissociation in detail. It is shc-j- that the found ef-
fective unergy the activation rf 1~he gross process is
the actual activation 2nergy of t17.--i rea.~tion CH3 ---)' CH2
H as a limiting stage of the chain dissociation.
Card 1/2 - 230 -

20-2-26/50
AVT ~ i C R Shan tarcvich P. S.
TITLE: The Kinutics of V,e Decay of Diazc7ieth~:-.e in -_ `.;trogen Bea::
irinetikri ras,~aja ciazo,!metana v struye azot,~
19
PERTCDICA T Do'clady AN SSSR, 11957, Vol. 116, Nr 2, pp. 251~ - 258 (USSR)
A B S'2 R A C _2 I'lethod and Restzlts: '11he diazomethane obt;~iilned by the decomposition
of "nitrosez.-iethirl urea" in an al-11-p-line nedium was dis,3olved in
COld dibLItyl p~-;tnlirc from it aas conveyed by means of a beard
of a*-,-solutel,7 ~;ure nitrogen in a receiver, In this way it was pos-
sible to chanCe the ccrcentration of CH 3?T2 in the S-as. In previous
ex~:,erinents it was found that the sior, (non-explosive) decay of
diazo,methane at bd`rl te-mDeratures c,,-.n "be observed only in a noble
,-as. A jia,--,r,L::i ohows the quantity of the mentioned C H transferred
from t~,e reaction ~,ases, -ind a second `ia-lra-i sho~.-.rs i1rij quantity of
ethylene, izz chtnined by the decomposition of the rot reacted
diazomethane. 2he sur.-i of these quantities supplies the content of
CH-1,NT, in the ori~;inal mixture, and Vfl~eir ratio shows t1le degree of
13e-`de:,, the v-ibe_9 of tho constnrits are driven which wEre
CO:'.ipL1tC-d in 1ccordance with the law for reactions. From all these
data it follwas that. the sloa dc-cay of diazc.-.,cthanc levelops accord-
Card 1/3

7-,e o~' the Dec2y of DJ--o17et'=e in a Nitrc-er. Bea-
2o-2-26/50
in.- to the equation CH,NT, = 11 + OTT
2
Cj!
~ 4
Con3equentl.7, t1--cdcpendence 2 L P = x mus t be t rue "or thi s
reaction at stleady f-c-ndition-c-, wltere x(-im) dc-notes 'he --mount of the
decayin.- CH2IT,,. Another dia,~,ram s~o-;.s the results of the comPutation
of the kineti8s of the dec:-.y of diazomethane accordin:~ to the law
of reactions of first order in consideration of a certain theoretic-
al rel--tion :-iven here. The ~;cod a.-,reement uf ex-periments points
sLi of the diazo-
with 'the computed curve confirms the decany mechani I
nethane and the r.-!tio of the -rO']L-,CtS obtained. In the case of
hi-her concentrations of diazoniethane ir the gas --nixture computed
results agree viith Vie experiment only in +.,ie initial stLnzes Of de-
composition. ~-ext, the temperature dependence of the velocity of
deca,, of the diazomethane and thedecay meclanisn of diazomethane
in the nitro.-,en beam are discussed. The occilrrence ofethane in the
d e cay products Cain be e:---ploined only either by the reaction of the
disrroportionin,- of L'Ihe methyl radicals or by their interaction
-aith the ori,in~-l di-_-.zomethane molecules. At present neither the
one nc_~ -,,he other nossibilit- can be L-r-oved. -;'here are 3 figures,
C a r 1 za'vle -a-nd non-Slavic refere-ces.

-:7-C, . Boma.
fhe Kinetics of the Decay of Diazomethane in a Nltroll~l
ASSOCIATION: institute for Physical Chemistry AN USSR
(Institut fizicrieskoi, khimii Akademii nauk SSSR)
PRESENTED: iipril 6, 195'1, by V. 11. Kondrat'lYev, Ac-ademician
SUBMI TTED: April 2, 15,97
AVAMI.BLE: Library of Con.-ress
Card 3/3

S-IFUIPTAROVICII, P.S., SITLUrITIKOVA, I.A.
- - - -- -.- ... .... -- -
Polymerizarion of cyclohemdiene. Vvsoko:i. soed. 2 no.8:1160.-1175
A,g 16 0. (NLU 13:9)
1. Institut khimicheskoy fiziki AIT SSSR.
(Cyclohexandiene) (Polymerizarion)

S/076/60/034/05/03/038
,37_2c2 Oo B010/B002
AUTHORS: Shantarovich, P. S., Pavlovg B. V.
TITLE: Thermal Cracking of Methanek\
T__~
PERIODICAL: Zhurnal fizicheskoy khimiiq 1960, Vol. 34, No. 5,
pp. 960-965
TEXT: The authors investigated t,::a kinetics of the initial stage of
thermal methane cracking at 1200-1400 0C, a methane pressure of from
0.2 to 3.4 torr, and contact times in an interval of from 10-3 to
10-2 see. Experiments were made in a helium current, and crackingswere
performed in small porcelain tubes (Tables 1-2, results) and small
porcelain tubes coated with carbon black (Tables 3-6). Results show
that a heterogeneous self-accelerated reaction takes place. The self-
acceleration of the reaction is apparently caused by the decomposition
of the methyl radical CH 3 10 CH2+ H, which occurs on the surface. It
is quite possible that the CH2 radical reacts with CH 4 and.does noi
Card 1/2

9. k0
AUTHORS;
TITLE~
PERIODICAL!
S/190/61/003/003/001/014
B101/B204
Shantarovich, P_ S., Shlyapnikova, I. A~
The kinetics of the polymerization of hydrocarbons with
conjugate bond. I, Polymerization of phenylacetylene and
the properties of the polymers
Vysokomolekulyarnyye soyedineniya, v- 3, no. 39 1961;
363-367
TEXT: The polymerization of phenylacetylene (PhA) was studied on the
basis of the assumption that polymers with conjugate double bonds must
exhibit high heat resistance. The thermal initiation of polymerization
begins with the formation of the dimer; 2CH =-CR ~' -RC=CH-CH=CR- (A)~
Preparatory experiments showed that the thermal polymerization of PhA
always ends with an 0explosion when it is performed in wide ampoules
(dc-~, 20 mm) at 150 C. At d c < 20 mm, the reaction takes place at thermal
equilibrium. The present paper is a report on the kinetics of this re-
action.. The conditions of thermal autocatalysis and of explosion are to
be examined in a special work, 1) Polymerization of phenylacetylene under
Card 1/6

89986
The kinetics of the polymerization- S/1 90/61/003/003/C 01 /0 14~
B101/B204
conditions of thermal equilibrium -. it was found that at dc-<
~ 9.0 mm and
a heating temperature of th'~ 1800C the heat supply equals the heat loss.
Fig, 1 shows the ratio x/(a - x) as depending on time at 136, 156) and
1760C (a - weighed portion, x - polymer yield)~ From the inclination
of the straight line follows a second-order reaction, The activation enel-
gy EM was found to be 33.7 + 0.5 kcal/mole.. In the case of a high degree
of conversion the rate constant (dashed in Fig. 1) will increase, which is
explained by a change in viscosity of the medium, 2) Thermal Polymeriza-
tion of dissolved phenylacetylene: n-nonane and cyclohexadiene served as
solvents., A slight addition (5fo) of the solvent already prevented self-
heating of the mass at d = 15 mm and 1760C. Fig. 2 shows the reaction
rate6o and the ratio W /8M as depending on C M, the concentration of the
monomer. The reaction rate for nonane as well as for 2yelohexadiene was
proportional to CM? and a second-order reaction 6)= kG M took place., The
rate constant was nearly the same in both solvents; k nonane = 3~02;
Card 2/6