SCIENTIFIC ABSTRACT KUZNETSOVA, G. P. - KUZNETSOVA, I. K.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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POKROVSKAYA, L.I.; PLYUSUCHEV, V. Ye.; KURIFTSOVA, G.P. Study of the system lithium sulfate-cesium sulfate -water. Izv. vys. ucheb. zav., khim. i khim. tekh. 7 no.5:705-710 '('- (MIRA 18:1) 1. Kafedra khimii i tekhnologli redkikh i rasseyannykh ele- mentov Moskovskogo instituta tonkoy khimicheakoy tekhnologii Imeni M.V. Lcmonosovae "of rare L; -QL -Ilh L~, I 11, L2-1~ i-I 2 . . ~.: -~ ~., ~~ ~j - . -;. ~ , . , , " -, -1 1 'i . . .:., .. , ~ :: , ~ ~ . i . .1 11, if. -f -A TQ 7 , - - ~- --A-~- tl- PLYUSHCHIEvr, V.Yp.; SIIKIOVFR, L.P.; SHKOLINIKOVA, L.M.; F!j7*;N-E-,bOVA, G.P.; IMUSIJ TNA T.A. ~ .9 Yttrhim and erbiiun formates and the"r propertAlpl. Zhur. ob. khint. 35 no.lOtl783-1790 0 '65. (MRA 18;10) KUZNETSOVA,,P~.~.; STEPIN, B.D, System at RbBrF-IlBr - H20 at 250C, Zhur. neorg. khim, 10 no.2s472-475 65. (MIRA 18tll) 1. Vo&ooyu%nyy nauchno-iseledovatellskly institut khirallcheakikh reektivov i osobo chistykh khialchaskikh veshcheaty. Submitted Aug. 24s 1963# -kVr4IETSOU,.S,P.; SIIVARTSp M.M.1 STEPIN, B.D. Preparation of highly pure sodium and potansium monochromates. Izv. AN SSSR. Neorge mat. 1 no.11:1938-19" N 165o (MIRA 18:12) 1. Voesoyuznyy nauchno-iosledovatellskiy institut khimicheBkikh reaktivoy i oBoboohistykh khimicheakikb veshchastv. Submitted May 14, 1965. BALANDINA, V.A,j XLESHCHEVA.. M,8,j XUZHETSOVA 0.3,; TURKOVA, L.D. ~ , Quantitative evaluation of chromatograms with the aid of a detector of heat conductivity. Zhur,anal,khim. 18 no.7:808- 810 Jl 163, 1(14JAA 16 M) f 1. Scientific-Research Institute of PolymerizationIklantics and Experimental Plant) Leningrade I KARIAKIN, R.N.; PUPYNIN, V.N., kand.tekhn.nauk; KUZNETSOVA, G.S., inzh. Experimental investigation of the ourrent drain circuit of a.c. traction substations. Vest.TSNII MPS 22 no.022-25 16). (WRA 16:10) KARYAM, R.N., Y_!,nd.tekhn.nauk (1,1,()-kva); KUZNPJ~~GVA linzil. (!-;c1jyV[1)_ FUMIM VA.? MIT rfF f?. ~nz",. kand.tekhrl.r,auk (MrsW~;O_j7 P P Be le c LIon of effective networka and optimal paramotxra of t1he power take-off circuits of a.c. traction substAtions. E1ekfrichs.,f3tvo no.11:10-18 N 164. (HIRA 18.2) KUZNETSOVA, G.S., inzhs Experimental study of the thermal stability of grounding systems. Trudy WIT no.199:165-177 165- (MIRA 18:8) Puiyrflfilp VeN., dQtrant, kand.tekhn,nauk; KULNI,"TSOVA, G.S., Inzh. Appro-yimate evaluation of the thermal stability of the grounding stages of a.c. traction substations& Trudy MITT no.199.178m-183 165. (KRA IW) NOVOOMHOHENOVAp N.S.; XMNMCNA O.S. 1--l-1-- - - Characteristics of the flea ecology of groater gerbils in places with chronic plague spizooty. Zool. zhur. 43 no.Ils 1638-1648 164. (MIRA 18%n) le VseooyumVy nauchno-UsledoTatellskiy protivachumnyy institut *Hikrob*,, Saratoy. BALANDINA, V.A.; KLESHCHEVA, M.S.; XUZNETSOVA, G.S. Determination of the composition of a mixture of acetaldebyde, methanol,, and vinyl acetate with the aid of gas-liquid partition chromatography, Plast.masey no.?f6l-62 163. (MIRA 16:8) (Aestaldshyde) (Vinyl acetate) (Gas chromatography) ~ TSIRL.M. Yu.A.; VASIMYEVA, V.A.; KUMETSOVA, G.S. Chemical purIfication of sewage containing furfurole. Oldroliz. I loookbim. prom. 14 no.7:15-10' 161. (MIRA 14ill) 1. Nauchno-looledovatel'okly institut gidro]Aznoy i oullfitno- spirtovoy pramyBhlennoetl. Sewage.-Purification) traldehyde) F-,-U -r- (,u Hall" FZTROV. A.A.; BRAVO, Ye.S.; DAVIDOVICH, V.V.; DYATKOVA, O.S.; KMBTSOVA G.V. Investigations In the field of conjugated systems. Part 49. Order of adding alkyl hypohalides to tertiary vinylaostylene alcohols. Zhur.ob. khim. 23 no.7:1120-11,24 J1 153. (KLH& 6:7) 1. laboratoriya organioheskoy khImii Leningradekogo tekhnologicheekogo institute. imeni Zensovata. (Halides) (Vinylacetylons alcohol) PLLIINIK, R.Ya.; 'VlP',`!i4,,4., i,1, Formation and -structure cf the r ur; neglectum Ldb. Trudy TSSIJI; no.7v-)f~44, S/169/61/000/011/058/065 D228/D304 AUTHORS: Kuznet and Soboleva, N.S. TITLE: Observations of solar radio-emisBion by means of the Bollshoy Pulkovskiy Radiotelescope in May 1960 on the 8.7 cm wavelength PERIODICAL: Referativnyy zhurnalp Geofizika, no. 11, 1961, 10, abstract 11G87 (Solnechnyye dannyye, no. 3p 1961p 70 - 72) TEXT:' The observational procedure is described. The end of the ra- dio-emission splash was recorded during the observations (at 9 hr. 55 min.). The chromospheric flare connected with this radio-emis- sion splash had a force of 3+ and lasted from 5 hr. 22 min, -to 7 hrl 33 min. world time. The radio-emission splash was also detected by the Glavnaya astronomicheskays. observatoriya (Central Astronomic Observatory) radiotelescope (3 cm). An estimate is given for the flow, size, and temperature of the evolutional brightness which was still preserved after the splash. [Abatractoi~s note: Complete trans- lation). Card 1/1 379h2 S/035/62/000/005/037/098 A055/A1O1 .1,172.0 AUTHORS: --Kuznetsova. G. Y., Pariyakiy, Yu. N., Soboleva, N. S., Khanberdyyev, TITM; Observations of solar radio emission during the eclipse of February 15, 1961, on the 9-am wavelength PERIODICAL: Referativnyy zhurnal, Astronomiya I Geodeziya, no. 5, 1962, 42, abstract 5A326 ("Solnechnyye dannyye", 1961,'no. 4, 65-67) TEXT: The results of observations of the solar eclipse of February 15, 1961, are described. The observations were carried out with the aid of a paraboloid(D - 4 m) with azimuthal mounting. The open end of a round waveguide. Into which were inserted a quarter-wave plate and a ferrite modulator with 30 cps modulation frequency, was used as primary exciter. The half-power 0 . -travelin&rwave- directional pattern was 1.5 As radiometer, was used a three tube strgight amplification receiver with an equivalent input noise temperature of 4,500 K and with a'passband of 300 Mc. The circularly polarized component of the radio emission and the nonpolarized radiation of the Sun were recorded. The recording wan effected on an 3nn-og (EPP-09). The antenna temperature of the Card 1/2 S/035/62/000/005/037/098 Observations of solar radio emission ... A055/AlOl- Sun outside of the eclipse was 5,5000K. The Moon was used for the absolute 22 calibration. The flux from the Sun on the day of the eclipse was 125 ' 10- watt/m2cps. The opening of the coronal condensation from 8hl7mIn .5 to 8h2omin (universal time) was ascertained from the examination of the eclipse curve. Under the assumption thai the source has a round shape (D.1-1!2) and that the condensation has the shape of an ellipse with semiaxes 0. x 1!14, the brigbt. ness temperature was calculated and proved to be 3.1 - 1090K and 2.75 - '10 K respectively; i.e. it proved to be higher than the temperature of the undistuib- ed corona. No polarization of radiation from the condensation was detected, which is indicative of a sharp directivity of the polarized radiation, this directivity being related to the radial direction of the magnetic field over the spots. The residual flux during the maximum phase of the eclipse was 40 - 50%. M. Gorelova [Abstracter's note: Complete translation] Card 2/2 30426 B11091611006101210011020 /7// CIIA7) D266/11305 AUTHORS: Yesepkinap N.A., Kaydanovskiy; N.L.1,Kuzneteov, B.G., .Kuznetoovap GoVel and Khaykin, S.E. ..... .................... . TITLE: Investigating the radiation pattern of highly direc- tive antennas whose reflecting surface is adjustable PERIODICAL: Radiotekhnika I elektronika, v. 6, no. 12, 1961, 1947 - 1960 TEM The purpose of the paper is to derive mathematical expressi- ons for the radiation pattern and for the effective area of a cer- tain class of antennas. The antenna investigated consists of a lar- ge number of elements (rectangular metal plates of heieht h and width a) whose position and inclination are adjustable. The elements are in no mechanical contact with each other which facilitates grea- ter accuracy of manufacturing. They can be adjusted in such a way that the main lobe of the vertical radiation pattern is in a speci- fied direction (8 . in Fig. 1). This condition Is satisfied if the radius vector of the center of the elements is given by The follow- Card 1/# 3U426 8/109/61/UU6/UI2/001/020 Investigating the radiation pattern off D266/D305 ing formula P P R0 - a0 Cos go 1 + Cos 00 COST 1 + Cos go -008 q where p constantp T - angle between the radius vector and the x axis (see Fig. 1) , If 0 ---- 6 0-< St/2 (1) represents an ellipsey for 80 = 0 a parabola# and for 0 0 = IT/2 a oircle. It follows from (1) that the distance between the primary source and the reflector de- pends also on 0 0. The inclination of the metal plates is determined by the angles p and X (see Fig. 1) which are related to e 0 and as follows sin gin go (3) + Coe 00 Gas rp) and t an X 811a ce (4) COB 00 + cog re Oard 2/4-~ Investigating the radiation pattern S/109/61/uu6/Oi2/OU1/020 D266/D305 In a plane perpendicular to the direction of the main Lobe, the waves are in phase (this ujust be always the case because the an- tenna was designed according To -this criterion) and the shape of the illuminated area in this plane is an incomplete ring. The dis- tribution of the electric field kboth poiarizations are present) in the aperture is calculated by geometrical optics and The far field is obtained with the aid of viave optics. The arising inte- grals are in-ceerated out leading to an infinite series of Bessel functions of the lirst kind. The radiation pattern is calcuiated for the reflector current as well. No analytical solutions are found in this case, out some numerical calcu.Lations indicnte simi- iar results to Lhose obtained by the aperture nethod. Aperture ef- riciency is also determined and wonotonically decreasing function of 0 0 is found. in conclusion the authors express their 6ratitude to V-13. i3raude for his assistance. There are 15 figures and 9 re- ferences: 8 6oviet-bloc and I non-6oviet-bloc. The reference to the B~nglish-language publication reads as foilovis: :3. silver, mi- crowave Antenna Theory and Design, m.I.T. Had. Lab. zierics. SUBMITTED: February 22, 1961 Car(I 3/4 !qJ-ZNET3QVA,-G.V.; S-30BOUNA, N.S. Polarization measuremonts with an antenna with a variable profile reflector. Izv. GAO 23 no.3:122-127 1(1,. (MIRA 17:11) PETRUNIKIN, V.Yu.; YESEPKINA, N.A.; ~F~IFETSOVA, G.V.; MIZUETSOV, B.G. Effect of rotation of the principal crons Bections of the directivity diagram of an antenna with a variable-profile reflector. Izv. GAO 23 no.3:160-161 164. (MIRA 17:11) ___Tj ACC _Nxj SOW= COMS AUTHCRt Xelfaikovo Me Net H-uridshAMB. Ke A2; K=111stsova. Go Vt; gunn- ORG: All-Union Scientific Research Institute of-Chemical Aents of Plant Protectil Xoscow (V8eaq_y__u-%nyy nauchno--Isoledovatolvskiy Inatitut khImicheakikh aredstvMM rasteniy) MIES Herbicide~arvd plant growth regulators. XLII . Synthesis of chloramethyl- arylw-alphazp_~ionic and chloromethylaryloxy-gana-butyric acids SOURCE: Zhurnal organichaskoy khimii, Y. lp no. 12, 19658 2166-2169 TOPIC TAGSt plant growth,, herbicide# chemical synthesis,, carboxylic acid, methyla: chemical reduction, Mar &mine ABSTRACTS Study 0 6jjrr'oj;vthyUtjm of arylox7a2kylearbo3wlic acids -has shown that in &21 cases the gorrespowurg Gh1or*mtVUry2*jW&lky1_ cav~box7lio &oide a" prodWed In pod JUM4 MA the rwtift 00=0 lullder rolativoly n11A oonditionve TM chlormet1W). gmp entmg povj+Ao3% 4, but 'it position 4 Is fIlled, It entors position 2. %1~ course, of the reaction Is domonstrated by the fact that In tbos redu4tim of ehUramthyl derivativas tho corroxporA4ng matIVI dwivauves described in the Uterature are obtainods For examples reduction of the prodmt obtained by oblorameWlation of 4. chlorophwoxy-gomma xxtyrin acids reaUto in 4-ohlaro-Zwoethyl-phenoxy-gamu- butyrio &OAd. StV4 of the pbpioj0gjQ&j &GUdty of the ocapowAs synthesized abows that eb1ar6*sthAA*UKPM.&-#___WUo ac"s Gro 1"s to3d to Plants than the oorrespondim &rY2WW"42G&rboX*-Uo saidae Th find now compounds physiologicaw seuve fW plabut weral 2074"tkd&X7163W&W1"rbox;y1iG 1 acids 0 UAL 4 odk In us utecata" wwo wPosizods. urge art* hast %ffi a 001 SUB C 06 / SM DAM 30 __MG RIW: M~ IM, 22 3 MKINIXOV, IRIIIIII)ZHANYAN, F.A.; L.P. ilerbAcIdes and growth promoLing substances. Part 43.6 Synthesis of chloromethylaryloxy- o~-propionic and chlormathyl-aryloxy- V%-butyrio acids. '"bur* org, khlm,, 1 not 120166-21.69 D 165 0 (MIRA 19t1) 1. rbasoyuznyy naucluio-issledovatellak3y InsLitut khlmlche--k:Lkb sredstv vanhchity rasteniy, Moskva. Suhn-ittq5d Novembor 10, lgfd,. KUZNETSOVAp Ids Aleksandrovna Changeableness of Forms and Structures of the Famw and Applied Significance Dissertation for candidate of a Medical Science degree, Chair of Normal Anator#W (headj Prof, V.I, Bik) Saratov Medical Institute, 195h KnMSOVA,I.A. 0 &a n wilpose tissue in relation to the photoperodic reaction and diapause of insects. Scol.shur. 34 n0-3:532-541 vq-je 155. (KU1 8:8) 1. Wedra antomalogii Loningradekogo gasudarstyeanogo universiteta im. A.A.Zhdanava. (Insects--Physiology) (Adipose tissues), I. A. Kuznetsova, 1. A. -- "The Biology of the Black Pine Beetle in the Fores- ted Fepirms near the Steppe in Connection with the Development of Measures to Combat it." All-Union Order of Lenin Academy of A'Igri- cultural Sciences imeni V. 1. Lenin. All-Union Sci Fes Inst of Mant Conservation. Leningrad, 1956 (Dissertation for the Degree of Candidate in Biological Science) Fot Knizhnaya Letopist No 1,~, 1956 / , 1 -//7. /_1 1~r r USSFVGonoral and Systematic Zoology. Insects. Harmful ;naects and Acarids. Forest Posts Abs Jour Ref Zhur - Biol., No 3, 1959', No 11657 Author Kyznetsqyi~~_.I-A, Inst A1r--UEf6n Institute for the Protection of Plants* Title i Biology of the Larvae of the Black Long-Horned Beetle, Orig Pub i Tr&' Vaes. in-ta zashchity rast,, 1957, vyp. 80 75,688 Abstract t Investigations were conducted in the Saval foros- try. The long-horned beetle Monochamus gallo- provinicalls bears a one-year jeneration; however, in a portion of the population a larvae (L), the diapause (D) stretches out to 2 and 3 years. The characteristics of the 1-year-old and 2-year-old L are presented, The numbers of the diapausi% Card 1/3 USSR/Gdnoral and Systematic Zoology, Insects. Harmful P Insects an4.Acarids. Foroat Posts. Abs Jour Rof Zhur - Biol., No 3, 1959, No 11657 L increase sharply in old dying-out nidi; this is connected with drying of the trees as a result of their tops being defoliated by the beetles. Prior to pupation, the beetles feed during April on decayed bast fibers and sapwood, crawling out for this purpose from passages under the bark. L. remaining in the D state during the spring per- iod, are distinguished from the individuals feed- Ing after hibernation by the Intensity of breath- ing, the character of metabolism and the quantity of water and fat in the organism. A low-breathing coefficient and profound changes In the structure of the tissues, confirming the prouonoo of D In L, are peculiar to them, The effect of deep D on the Increase of the beetle reserve in separate years Card 2/3 - 41 - KUZNETSOVA, I.A. Possibilities for acallmatizing local ecologic races of Lapidoptera in other zones of the range of the species. Vop. ekol. 7t89-91 1624, (mikk 160) 1. Leningradakiy gosudaretyannyy univerBitet. (Leningrad Provinoe-Lepidopter'a) (Acclilr4izatign) -KMLITM-t-~- Factors causirg the begiming of the diapause in the mal2ow moth Pectinophora malvena Hb* (lepidoptera,, Gelachiidae). &to oboar, 41 no,31510-515 162o (MIIU 15:10) 1. Biologicheskiy institut lan3ngradskogo.gasuderstvennogo universitetat Staryy_potergofs (Goloohiidael (Diapause) LEBEDEVA, M.N.; KUZIIWfSOVA, I.A. Pharmacology of the preparation hexachloroparaxylenes Mod. paraz. i paraz. bol. 32 no.6t691-696 N-D 163 (NIRA 18:1) 1, Iz laboratorii farmakologii (zav. V.F. Gladkikh) otdela gellmintologii (zav. - prof. V.P. Pod'Iyapollskaya) Instituta meditsinskoy parazitologii i tropicheskoy meditsiny imeni Ye.I.Martsinovskogo (direktor - prof. P.G. Sergiye-w) Mini- sterstva zdravookhraneniya SSSH. ZKVINA, G.B*; KUZNETSOVA, I&A,-, STAROSTIN, I.V. Compoeition of foullng in the Gaspian Sea. Trudy Inst, okean. 700-25 163# (MIRA 17:7) TATEEVOSIYAN, Georgiy Ovanesovich; KUZNETSOVA -I,,9,,,-nauchnyy red.; BDNDAROVSKAYAO G.V., red. ZLOVSKAYAg M.D.0 tekhn. red.; PERSONt M.N.# tokhn. red. [Presser of plastics] PresBovshchik plastmaes. Moskva, 1~en. uohebno-pedagog, ltd-vo Proftakhizdat, 1961, 318 p. (MIRA 15W (Plastica-Molding) 7-UTEVOSIXAN, GOO.; XUZNETSOVA, I.B. lYete=ining the photontability of coloro of plastics. Pjastmassy no,l2t54-57 161, (HM 14812) (Dyeo and dying-Plastics) - --- - -- -- - --- ---- - --- -- - - - - FOLYAKOVAi ~ - MMTSOVA, I.B., TATEVOSIYAN, G.O., nauchnyy red.; C I - ; IM - .0 TISHCH*Ew- . N.I., red.; TRUSOV, N.S., tekbn. red. (Manufacture of toys from plastics]Proizvodstvo igrushek iz plasticheakikh mass. Leningrad, Goomestpromizdat, 1962. 318 P. (MIRA 16s2) (Plastics) (Toys) 34948 S/19 62/000/003/007/010 S-1 ,p Is- D 0 0 B101X-147 AUTHORS: Tatovostyan, G. 0., Va-gnot-finva- T.D TITLE: Problem of weather resistant film materials PERIODICAL: Plastichoskiyq massy,-no. 3, 1962, 44-- 51 TEXT: Films made of polyethylene (PE)i pol,,vinyl chloride (PVC) plastic- ized with a:BGT (VSF) plasticizer, or PVC type 230 were exposed to atmospheric influences or to the radiation of are lamps or mercury-ouartz lamps. Aging was tested by measuring the tensile stren&h d (kj:/c9) and the relative elonEation F_ at the moment of breakinC. For PE, graphs d versus T, and F_ versus T, where i . time, were DIfted, and a-in- wa3 assumed to end when FE reached 50Vj' (T50)' Por PVC, aCing was assumed to end with the occumnee of brittle fraotural when bent 1800 at room tenpe=r- ture (rDCT 5960-51, COST 5960-5l)- Results: (1) Under atmospheric influences,aging of PE was MO) faster in Fergana than it was in Mloscow ('r 50 in Moscow 16.0 days). (2) In the laboratory, aging in arc light yielded comparable results. A conversion factor K - solar radiation Card 1/3 5/191/62/000/003/007/010 Problem of weather resistant ... B101/B147 houro/laboratory light hours - approximately 3.0 was found. The ratio Ir Moscow, daya/Tlight hrs ,, 1.737, 'Fergana, days/'vlight hra whs 0*421* (3) I-To comparable results were obtained with H,-,, lamps which cannot be used for age tents since the procenses are completely different. (4) A 1.51,19' addition of carbon black to PE increases its light resistance: without carbon black F- dropped from 400 to 501;~) after 300 hrsl with carbon black it dropped from 533 to 38%j- (5) Reinforcement of PE with cotton fabric (percale type A (A)) also increased its service life; Ir 50 -600 hra. (6) Stabilizer additions to PE showed the followint;: with 2-hydroxy-4-octyl benzophenone: %50 - 252 in Moscow, with phenol - styrene combination : 7 50 - 338 in Moscow. (7) In PVC stabilized with lead silicate, brittle fracture occurred after 367 hrs in arc light. (8) Service life was increased to 954 hrs by lead stearate +3A-5 (ED-5) epoxy resin owing to synergism. (9) Effect of stabilizers: PVC 230 had Tloo * 1727-5 hre without stabilizer. Addition of diphenylol propane or 1,1-bis-(4-hydroxy-phenyl)-cyclohexane gave 1 100 , 2162. 2,21-4,4'-tetra- Card 2/3 S/191/62/000/003/007/010 Problem of weather resiatant ... BIOI/B147 hydroxy sebacephenone (,r 100 ,2350 hro), 2,21-4,41-tatrahydroxy adipophanone (T 100 "2459 hro), and 2)2-bis-(3-methyl-4-hydroxy-phenyl) Propane (,rloo - 2715 hra) had the best effects. Z. V. yopova, Ye. N. hiatveyeva, and A. S. Danyushevskiy prepared the specimens. There are 8 figures, 3 tables, and 5 Soviet referencen. V4/ Card 3/3 40207 511911621000100910111012 Bi01/B144 AUTHCRSt Antropovat N. Yuzne_ta.ova_,_I__J11__-j_1~t evoolyant G. 0.9 Sharova, A. V.' TITU: Surface treatment of theM'--4 (PK-4) film with stabilizing substances PERIODICAL: Plasticheakiya massy, no. qj 1962, 61 - 64 TEXT. In order -to stabilize the PK-4 polycaproamide film used in agriculture it was treated with potassium, iodide, manganese chloride, copper sulfate, potassium bichromate,R -naphthol, benzophenone, resorcinol dicalicylate, resorcinol dibenzoate, formaling or tannin, The chanees in the tensile utrength 00 and br akin& elongation & were tested after artift'ciel aging by ultraviol:t (Hg larips) or Qrc lightf or after. natural aging under atmospheric conditions in Moscow or Fergana. Potassium iodide,A -'naphtholl,benzoplionone, potassium bichromate, and tannin-ahowed a sliCht stabilizing effect against ultraviolot irradiation. The data -:ot by irradiation with arc lumps were better compdrable with those obtuined by agine under atmospher-io corditions than the data from Card 112 S/191/62/OCC/009/011/012 Surface trcatment of the ... MOI/B144 ultraviolpt irradiation. For r, measurud alon6 the nonstabilized film and alonK the film rtabilizod by tannin the followine data were obtained respectivel,ys nonirradiatod 371, 452 kC~cc12j aftor 50 hr ir)radiation 395, 677; aftor 120 hr 5C0, 6301 after 140 I,r 316, 36( kg/cM2. The durability of films exposed to atmospheric effects was 3 months in Noscow and 2 ' months in Fer&ana. Treatment with 1~ taBnir, solution reduded the thermo- oxidative destruction of the film at 200 C to 1/7 as compared with untr-jated film. Untreated film contained 11.7% products soluble in watdr, that treated vith tannin only 3i3~,. Treatment %vith tannin chanees the optical properties of the PK-4 film. Thu maximum of liGht absorptiont which i3 250-310 up for.untrouted fIlm, shifto towards 280-400 n*. The useful life of the filn ie elightly increased by treatment 'with tannin and this also renders the film more frost-resistant. There are 2 figures ;~,nd 4 tables. Card 2/2 4*11, 0'. 40906 B/i9IJ62/000/010/001/0io AUT110IIj i lie DI Kovarokaya, 11. M., Levento I Dral %j:n, L. v8 Sidarov, V. ":Iah G, 'V. AxLkaxA+-M-P- A. tk.~, V. Troi mIn,1G. 6.1 Tatevoslian: 0. 0., Kuznetsova, 1. B. TITLEs Jt!.billlation of p6lyamide films for agriculture PFRIODIGALs Plonticbeakiye mosey, nq. 10,,.1962, 6 TLIT, , Prnto.tio. of polyamide films, type 54, an used in hothouses. arid aLlon; from arrectn.or ph* 6m and tharmo6xIdatIon,'was+teated by trying varloiia nd-litiven under Y.!i6us test conditions. - The following were added' its ultrnviolot lipht nbeorborne 2-hydr*XY-4-mothoxy-bonsophonone Oh G~ .(OMBF) (I)9 2-bydro)4-4-alkoxy-bonsophenano (a fbixtur:.of benzophenone: *ita, vnrin us nllgoxy froupsIof th.e.type 007 H15 , OC H7 or 0 9 9 ) (it) and 2-hyAroxy'-51-motbyl-bonsotriasole (Tinuvin) (111). As antioxidants, KI and doppor naphth nato and or4unio stabilizers of the following ty a were usads .4) derivatives of aromAtic aminesi 2) phenol d*rivativ 35 aromatic oxamineal 4) 2,6-4itert-butY~-4-mothyl-phonyl-pyrocatoohin ph::Plbito OonO4 :t Card"1/2 -'7 -7- S/19i 62/000/010/001/010 6tnbil17.ntlon of ... YB I ! B101 Bie Polyamido film "alanka producci by condensation, namely heXamothylene n4ipi%. nate and 4 -caprol.-ictam at 260 C in an N-atmoophora, were subjected to .thermo- -ind photooxidntive action. Light sources were carbon-aro'qnd morcury,qu-rtz lampa, typo nFK-2 (PR4-2). Temperature in the test h b Win 70 It POC. Thormoozidation moaaured by Aho drop In oxygen-pressour7ZO; -Y eliminated most officlently by the pyrocatechin enters and phanyl-p-naph- thyl-wainc. It v.lao found that stabilisers 'of the OILBY and Tuvin typee sat' 'l" an antioxidants. ilh6tooxMation experimen'ta showed the followlaf rosultat ~ in moat cocoa the elonLisi,ion at rupture dropped even on Initial *xpoeure. t After 200 hru of exposure time, breaki ng tenacity of both stabilized and f nonattibilized films fall by approximately 20 - 25~. Ageing time until embrittlument wna determined. Without an inhibitor it began after i" hro or expocuro to the light of n Optimum resulti were obtained 101 pjrcontechin *#torn W h4r8r3,la71p+ copper naphthen1tj 260 hro).and wontover) o ((2,6-di-tort-butyl-Wroquiabne)) (240 hre . I Different so- tion of the light from the are lamps and tbo.maroury lamps;was explained b apeot m differoncee. Vurther fibld tests *ro reconmi Pn4ed. There are JYf igure and I tables ard 2/2 h1918 k- 3/191 62/000/011/014/019 B1 ~ YB1 86 AUTHORS: Tatevoslyan, 0. 0.1 Losevs Is Pop Kusnetsova, I. B. TITLE: Chemical analysis of polyvinyl chloride plastics subjected to photoaging PERIODICAL: Plasticheskiye massy) no. 11, 1962,-59-62 TEXT: Polyvinyl chloride plastics of the t~p so 230, 239, 251, and 489 with a composition of 56-70% polyvinyl chloride, 21-33~ liquid plasticizer, and about lc~4 stabilizer were irradiated at 700C by carbon arc lamps (6BO-1000 hre) or mercury vapor lamps (24-180 hrs). The changes in composition, tensile strength, and resistivity were studied. The composition was arrived at successive extractions with ether, acetone, benzene, and chloro benzene, by determining how much plasticizer remained in the plastic after irradiation, and by determining the chlorine content. .Results: (1) The loss of plasticizer as referred to the total weight of plastic was 6-10% after irradiation by arc lamps, and 11-15% after irradia- tion by*Hg vapor lamps. It is noted that determination of the weight lose alone leads to deviating data. (2) The chlorine content decreased, but on irradiating with lfg lamp this was masked by the intense loss of Card 1/2 S/1 91/62/000/011/014/019 Chemical analysis of polyvinyl ... BIOI/B186 plasticizer. (3) The resistivity of non-irradiated specimens was in the order of 1012 ohm-cm, that of,specimens irradiated by are lamps in the order of 10 13 1 and that of specimons irradiated with Hg light was 10 14 ohm-cm.2 (4) The tensile strength of non-irradiated specimens was 2 217-280 kg/cm . Under are lamp irradiation it dropped to 105-176 kg/cm under H9 light irradiation, it dropped at firstg but then increased to 238-328 kg/cm2- Conclusions: Destruction processes prevail in arc lamp irradiation, and structuration processes in Hg light irradiation. Structuration processes increase the tensile strength and the resistivity, and accelerate the volatilization of the plasticizer since struoturized PVC is no longer soluble in it. There are 5 tables. Card 2/2 8/191/63/000/002/013/019 B101/B186 AUTHORS: Tatevoslyanj 0. Ott Kuznetsoval I. B. TITLE. Long-time and alternating effeato of water and molet air on plastics PERIODICALt Plaetioheekiye massyl no. 29 1963P 52-50 TEXT: With,a view to uses of plaotics in building and agriculture the following materials were tested for changes in physicomechanical and dit~ electric properties due to the effect of water and moisture; prees-mold94 homogeneous thormoplastios suoh a" styrene copolymers CHTT (SNP) p MG (Me) and MCH (MBR), polystyrene, polypropyliine, polyamide 60, Butvurw ethyl collulose etroll molded powder-filled inhopiogeneous thermosetting plaotios based on phenol formaldehyde resins including such modified with rubber, PVC.j or polyamide reeinj monolithic phenol aldehyde plastics based on novolac resins with organin curing agentl thermosetting laminated plastici based on phenol furfural or polyester resins with glass fiber reinforoemen4.6 The toots covered the water adsorption at 20 or 400C and the adsorption of moisture at 4011C during 1-56 days by weighing the moistened and dried ard C 1/2 S/191 63/000/002/013/019 Long-time and alternating.&** H1 01 YBI 86 specimens. The change I n weight after five 24-hr.dippings into 20*c; water and drying at 40PC.was determined. Conclusions drawn from the tabulated data: (1) Permanent action of water or moisture produces the greatest changeo of physi come ohani cal and dielectric properties in thermosetting plastics, and the least In thermoplastics. The great changes in thermo- setting plastics are due to capillary formations. (2) Among thermosetting plastice.the highest water adsorption In reached by materials based on novolao phenol formaldehyde resinu, the lowest by material6 based on resol' or novolac and resol resins modified by thermoplastica. (3) 200G water changes the properties in the same Wal as 400C air moisture, so the simpler 200C water teat is to be preforredi 41,Long-time action of water changes the properties moro than alternatei.M8 v. ning and drying. (5) The tests ean be used to estimate the ut1litij 01'~Iaetics under atmospheric influen- ces and to help in their proper ael-Ation. There are 3 tables., S/191/63/000/003/016/022 BlOi/B186 A'.'TIIORSt Kuzneteovat 1. B.9 Tatevoslyant 0. 0. TITLEs Standard method for testing the weather- and lightproofnose of. plastics PERIODICALt Plastichookiye.masay, no. 39 1963t 54-59 TEM In 1963, the POCT not 10226-62 (GOST no. 10226-62) standard published in Standartizatsiya, no. 3, 1962, was introduced in the USSR to standardize the testing'.of weatherproofnese.and lightproofneas plastics. Some explanations and recommendations for applying, this standard are given* Weatherproofne3a is tented in various climatic regionse The specimens are ;o, mounted on frames fixed at an angle of 4500 facing the south. Two of theme frame constructions are described. Equipment such an heliograph# Tani- shevokiy pyranometerg ombrometer, thermometer# psychrometerp and anomonster is recommended for opeciai' meteorological stations in caves where no re- gular reports are obtainable from a state meteorological station. calibra- tion of the pyranomoter according to the actinometer data from a State meteorological station is briefly described. The laboratory conditions, the Card 1/2 . S/191/63/000/003/016/022 Standard method for testing BIOI/B186 AMTTCT-2-4-2 (AIPST-2-4-2) apparatus is used. It consists of a case mount ad on a rotating holder, for testing the samples in -horizontal or vertical po- sition, two carbon-aro lamps, four mercury-vapor lamps# two fens to mainteLa a temperature of 20-9000t a moistening apparatus# and signaling system which indicates irregularities or when the rotating cases atop or a lamp faile, otc. Measurement of the light intensity with the Yanishevskiy pyranometer is described. There are 3 figures.and 3.tables. Card 2/2 T': TATEVOSIYANO 0.0s; KUZN.ETS.OVA#.I.B,; LAMINAq ReAe Aging of polystyrene under the e"ect of ultraviolet light. Plast. savvy no.8t66-67 163. (MIRA 16:8) (Styrene polymers) (Ultraviolet rays) EpR/EWp(j)/EpF(c)/EwT(m)/BD19 AFFTcA9D P&-4#o-4/Pr-4 L 1 M-63 RMIWWIMAY ACCESSION NR: AP3006531 S/0191/63/000/009/0010/0012 AUTHORS: Tatevoolvan, G. 0,;ILosev, I. P. (Deceased); Kuznetsova, 1._Bo .......... TITLE: The effect of plasticizer upon light aging of vinyl blend. SOURCE: Plasticheskiye massy*, no. 9, 1963, 10-12. TOPIC TAGS: polyvinylchloride, vinyl blend, light aging, plastics, plasticizer. ABSTRACT: Authors showed that the.aging process of a plasticizer does not increase its specific gravity, but increases its acidity, which indicates a decrease of the specific volume of electrical resistance. The resistance of polyvinylchloride plasticizer to the effects of light energy is primaril determined b aging which takes place in the polyvinylchloride resin .PrAs a result of this aging, the mutual soLuDi=y in the Fesin and plasticizer changes. Card 1. / 2 L ACCESSION NR: AP3006531 the observed continuous change of plasticizer quantity in the afing process ofovinKl blend by light'did, not show :a dec sive effect up n t e stability. Orig. art. has: 3 tables. ASSOCIATION: none. SUBMITTED: 00 DATE ACQ: 30Sep63 ENCL: 00 SUB CODE: CH NO REP SOV: 002 OTHER: 0011 Card 22 ACCESSION NR: AP4046022 B/0191/64/000/009/0032/0037 AUTHOR: Kuznetsova, 1. B., Tatevoslyan, G. 0. TITIX- - Change In the properties of polyamide film under the influence of light SOURCE: Plasticheskiyo mtwsy*l no, 0, 1904l 32-37 TOPIC TAGS: polyamide, lighti aging, spectroscopy, tensile strength, elongation, light absorption, polyamide film, film PK-4 ABSTRACT: The changes In the properties of polyamide film PK-4 during aging under fa, atmospheric and laboratory conditions were studied by spectroscopy under the separate or combined Influence of artificial changes In climate. A colorless un6tabilized PK-4 film was used as the test sample, with an elongation at break Eo = 292% and maximum M2 tensile strength & 0 = 388 kgs/c The test sample was subjected to atmospheric aging on a laboratory apparatus, to atmospheric aging in suspension, excluding direct solar radiation, to artificial aging at 70C under artificial light (500W incandescent lamp, arc and mercury lamps), and finally to aging under the Influence of moisture.with are and mercury ramps. The following characteristics were determined: yellowing factor, % mwdmum tensile strength (e.); relative elongation at break %) for 80-mm-long and'. 1/3 Card ACCESSION NR: "4045022 8-mm-wide strips; the monomer content, by extraction with boiling water for 15 hours; the molecular weight, from the viscosity of a 0. 1% solution In 40% F12SO at room tem- perature; and the ultraviolet and infrared absorption spectra. The experimental data are plotted. -t and d -t curves show that variations in relative humidity and atmospheric drying greatly affect the properties. The process of thermal aging proceeds relatively slowly, however. At a temperature of 45-48C in visible light, the change in properties can be attributed to light aging. Yellowing of the film appeared after 145 and 75 hours of irradiation at intensities of 0. 442 and 0. 866 Cal/CM2 min., respectively. The mol. weight dropped from 23, 600 to 19330-19062. Visible light together with atmospheric oxygen affect the polyamide film markedly causing Its destruction. In samples kept In distille water until the weight changed, ~,increased to 365%, and cf decreased to 267 kgs/cm. ; in dried samples the opposite occurred. In addition to moistum, the monomer content also affects Lhe film properties. The effect of heat under light from incandescent and mercury-quartz lamps was also studied. The combined effect of heat, moisture and light was investigated, and analytical data for monomer content and oxygen content are 'tabulated. The absorption of light by the film before and after aging under differentcon.;, ditions was investigated and the changes in light transmission In the ultraviolet and in- frared regions of the spectrum during aging are discussed in dotaiL Under the influence 2/3 Card ACCESBION NRj AP4045022 of hout and visible light, the absorption in the region 250-290 mp Increased rapidly; later it Increased Ions rapidly In the range 290-680 mil. During aging under atmospheric con- ditions, the general light absorption decreased in all regions of the spectrum. it is im- portant that the light absorption Is smaller after aging In all cases, especially marked changes being found In the regions 800-000, 1800-2800, and 3600-4000 cm-1. Orls. aft, has: 6 figures and 2 tables. -ASSOCIATIONt None SUBMITTED: 00 ENCL: 00 BUB CODE: MTO'P 'NO REF SOV: 021 OTHER: 016 Card 3/3 - , ~i7 1 -. I . . -. I. , - I .. , ., e , .;-I- . I .I . . 1. I .-- I - I-- f I 7L, KH. L.S.. kandined.nauk; KUZUSTSOVA I.D., kend.med.uauk; MALINOVSKiYA, T.N. Controlled bronchograpby with sufoiodol [with summary in Anglish]. Yestooto-rins 19 no.3slOO-103 My-Ja 157. (MIRA 10tlO) 1. Is kafedry rentgenologii (zav. - prof. Yu.N.Sckolov) TSentrall- nogo institute usovershoustvoveniya vrachey. (BRONCHI, radiography contrast sodium, todized poppy seed oil) (CONTUW KSDIA iodired poppy seed oil in bronchography) JK ZNETSQY~A, FALKINA., D.A.; ANONHINA, K.P.p red.; KREMENETSKATA, K-7.-,red.; ELIBERT, O.A., red. [Scientific and technological information in the U.S.S.R. and abroad; a bibliographic Index to the literature published in 1960 and 1961) Nauchno-tekhnicheakaia Informa- telis, za 1960-1961 gg. Moskva, 1962. 215 p. (MIRA 16t10) 1. Moscow. Vasooyuznyy institut, naucbnoy I tekhnichaskoy in- formstail. (Bibliography-Soience) (Bibliography--Technology) Thiodiphouylastize is uot toxic to fishes of the Volga delta. Medparas.i paras.bol. no.6-.563 I-D 133- (mu 6ti.2) 1. ;X,r&vpIyekogo'.UG5qynOTOgo filial& vassoyUsnogo nauchno-Issledovatell- skogo Instituta morskogo rybnogo khozyaystva i okeanografii. (ThiodiphenylamiW) (Volga-71shes) (Fishes-Volga) KUZMSOVA-i-I-.-I-.-"KHLATIJ91,-Y6-.-S.,-x~e-d,--, GOTLIB~_R.A, -taktuired, ~reefnn pike parch on spawning and rearing farms In the Volga Delta] Razvedenia sudsks. v nerestovo-vyraotnykh khosiaistvakh dellty Volgi. Moskva, Pishabspromizdat. 1955. 16 p. (MIRA 12s3) (Volga Delta--Perch) KUZNZTSOVAj I*Isi kandobiologichookikh nauk. Ilaments of gas exchange in young bream on fish spawning and rearing farms of the Volga Delta. Tru,dr VNIRO 32:76-91 '56# (MIRA 10:10) (Volga Delta--Dream) (Respiration) KUZIMSOVA, I.I., kand;blol.nauk 114mente of gas exchange during early developmental stages of bream. wild carp and pike parch. Trudy sov.Ikht.koz.no.8:346-358 1 58. (MMA Ilt2l) 1. Tasplyskiy filial Vaesoyusnogo nauchno-tooledovatellskogo Inatituta morskogo rybnoro khosyerstva i okeahografii. Wspiration) (Corp) (Perob)i 26-58-6-30/56 AUTHOR: Kuznetsova, I.I., Candidate of Biological Sciences TITLF. A "Chomicnl Theory" of Fish,Migration ("Khimicheakaya teoriyall migratsii ryb) 10 PERIODICALi Priroda, 1958, Nr 6, p 102-104 (USSR) AB5TRACT: The author reports on the spawning habits of two Volga fish varieties: the sazan (carp) and the vobla (roach). They in- variably choose recently inundated plots for spawning, but avoid places that have been covered by water over longer periods, to protect the spawn from enemies and to furnish the young fish with sufficient food. Hydrochemical observations have proved that the chemical composition of inundated plot water standing longer than five days, differs considerably from water of recent inundation, which shows an important in- crease especially of chlorine in the first few days of inun- dation. Hence it must be assumed that the above-mentioned fish are being guided by a "chemical scent". Card 112 There is 1 diagram, 1 table and 1 Soviet reference. A "Chemical Theory" of Fish Migration 26-58-6-30/56 ASSOCIATION: Kaspiyakiy nauchno-iseledovatellskiy institut rybnogo khozyaystva i okeanografti (Astrakhan') (Caspian Scientific Research Institute of Fishery and Oceano- graphy - Astrakhan') Card 212 1. Fishes-Higration-Chemical theory KU7?4V,,TSOVA, E.I. Survival increase in the progeny of carp (Cyprinus carpio L.). Zooi. zhur. 41 no-91l367-1373 S 162. (MIRA 15ill) 1. Volgograd Branch of the State Research Institute of Lake and 1 R iver nahery Management. (Fish culture) KUZNETSOVA I.L. Increasing the productivity of fisoands by regulating the vater regime and timing the reproduction of fishes. Vop. ekol. 5:112 062. (KERA l6s6) 1 Volgogradskogo otdeleniye Gosudarstvennogo nau#no-issledovatel,17 siogo instituta ozernogo i rechnogo rybnogo khozyaystva. (Tsinlyansk Reservoir region-Fish culture) ACC WRs AP7002603 S OURCE CODE; UH/0413/0AW/023/01-10/0110 MENTORS: Agayovp As Iq Kollchenko, A. V.1 Malkin, B. D.j 0~6 Iti- Kumptos Nikitin, G, M,; Gusman,, M. T. ORG: none TITLE:' A stopped rolling axle support. Class 47.. No. 189251+ SOURCE: Izobrateniya, prowlshlenrqye obraztsy, tovarWo znaki, no. 23, 1966, no TOPIC TAGS: antifriation bearing, ball bearing, bearing race - I ABSTRACT: This Author Certificate presents a stopped roning axle support containing thrust roller bearings, spacing collars, and an annular elastic element (3ao Fig. 1). To eliminate loose We holes and to increase the efficiency 'under cbmamic loads, the ball bearings of the support are placed in two rows.. with the balls running be- tween the outside flanges and the-internal flange. The annular elastic element is mounted on each side of each ball bearing at a sma3.1 distance from a spacing ring. A split bushing is placed between the inner flanges of,the corresponding ball bear- ings, Card 1/2 was 621.822.3 ACC NRs AP7002603 Fig. 1. 1 - bans; 2 outside flange;, 3 - inner flange; I+ - a=ular, elastic slomentl 5 - space; 6 - spao~ing ring; 7-.split bushing Orige art, has: I figurs'. SUB CODE: 131 SUBM DAM 03YAr66 2 /2 NIKITINA,, To.I.; BERZINA., A.Pq Y.U*TS0VAr I.K.; SOTNIKOVv V.I. - I Svonbergite in the Oornyy Altai. Dokl. AN SSSR 149 no.4t942-9" Ap 163. 1 OURA 1613) 1. Institut goologii i geofisiki Sibirskogo otdoleniya Af', SSM. Pnidotavlano akademikom V,S.Sobolavym. . -(Altai Mountains--Svanbergite) AUTHORs Sheynker, Tu.ffo, Xuznetsova, IX 76-i24V27 ------------------- TITLEt On the Tautomerism of Some Derivates of Heterocyclic Compounds (0 tautomerii nekotorykh proizvodriykh geterotaikliaheskikh 9oyedinaniy). V. Spectra aa Structure of Some SulfW'Jand as M Spektry I stroyeniye nekotorykh sullfanilamidov) PERIODICAL Zhurn&2 Pizioheskoy Xhimils 1957# Vol. 31, sir 129 pp.2656-2662 (USSR) ABSTRAOTt Reference in made to the preoeaing paper [Ref - 17 , and -oy means of infrared, and , in Individual oases, also of ultraviolet spaotra, the ntzuoture of 2-sulfanylamiaa3 of pyriaine and of pyrimidine, as well as of some suirwismiaes of the alicordlio series (which are used as medical preparations) is investisatea. The measuring method ban al- ready been described in previous works. From the data obtained it follows that in the pyridine and pyrimidine series, which have 2-Oulf lamidets in the crystalline state, have an imido structure (1), (171, and are derivatives of 2-pyridomine and 2-pyrimidonins. As in cases investigmted previouslyt this is due to the strong acid- ifying influenoe exercised by the So 2 group on the wMe group NH, Consequently, the ratio of the basic proportion of the nitrogen atom outside the ring, and that of the nitrogen atom within the ring, Card 1/3 changes in favor of the latter. It Is shown that in the aqueous On the Tautomerism of Some Derivates of Heterocyclic Gompounda. V. Spectra and Structure of Some Sulfanylamides Oard 213 76-12-807 olutions the 2-sulfanylamiaopyridin shoym essentially an Wdo ruoturep whereas in alcohol solutionso besides the imido-foms N also the amido-form is contained in substantial quantities. The lat- ter form prevails in diczan solutions and the content of the amido- form can be evaluated by 99%. In the case of the sulfanylamides of the pyridin, a tautomerio system is concerned, which is very close to the state of equilibrium. Further it is shovm that -the sulfanyl- amides of the alicyolto series (sulfarUliacetamid, sulfanylurea ~(urosulfan)), both in crystalline state, as well as in solutions, have an amido-struature. The lAtter because they keer the same strip- systems in infrsrad spectra of such Bolutiony (alcohol, dioxan)p and especially the cakhonyl-atrips (1700 =7') under the conditions prevailing here. Gonsequentlyl the aoid-propertioa of the NH-group, in spite of the strong acidifying effect of the sulfanil-group do not increase to such an extent that the amid forms (V) and (VI) be- coem more acidifercue than the ImIdo-forms (VII) and (VIII). The obtained data correspond to the oonoeptione of the acid-basio ohar-- aater of the amiao-imido tautomeric equilibrium. It is finally shown On the Tautomerism of Some Derivates of Heterocyclic 76-12-8/27 Compoundso V. Spectra and Structure of Some Sulfanylmided that the baoteriostatic activity of the sulfanylandd-preparations cannot be correlated with the imiao-struoture of their molecules. There are 5 figures, ana 8 references, 3 of which a" Slavic. ASSOOIATION: An-Union Scientific Chemical-Pharmaceutical Research Institute imeni S. OrdzhouiKidalej 908cov (Vaespyuznyy nauchao- issleaovatellskiy Khimiko-farmatsevtichaskiy institut im. S. Ordzhonikidze, Moskva). STBMITTED: Ju3-Y 21, 1956 AVAILABLEs Library of Oongress Cara V3 B/i)62/61/000/008/005/010 B117/B2O6 T 1700 AUTHORS., Andrianov, X. A., and Xuznetsovag 1. K# TITLE: The reactions of'ohloromethyl mothylalkoxy~ilanes with sodium salts of diethyl phosphoric and dimethyl phosphinio acide PERIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeloniye khimichookikh nauk, no. 8, 1961, 1454-1456 TEXT: The authorB,investigated the substitution of chlorine in a-chlor-o- methyl-alkoxy-silanes by dialkyl phosphorio- and phoij~inio aciA roe to The sodium salt of diethyl phosphate was prepared according to the method described in Ref. 3 (Canad. J. Chem 1819 (1956)) and carefully dried in a vacuum exeiccator-over phosphorus pentoxide. The sodium salt of phosphinic acid was produced in the usual way by neutralization of, dimethyl phosphinic-acid in absolute alcohol, dried in a d5rying chamber for several hours at 1200 t01300C and stored in the vacuum exeiccator over I P 0 The experimento were mado*in a three-neoked flask with mixer and 2 5* 'Card 1/4 3/06y~ 61~000/008/005/016' Theftreactions of ahloromethyl.00 B117 B20 sealing, recooler with calcium chloride tube'and thermometer. The experi- ments showed that chlorine in a-ohloromethyl alkoxysilanes easily reacts with the sodium salts mentioned. Organic compounds containing Si and P with an Si-C-0-P bond are formed thereby, containing simultaneously functional groupe at the silicon atom. 'The synthesis of the compounds mentioned was made according to I I _N set 1) (CH,),-SI(OR),_,+NnO-P-.~.(CH9)t--(CH.s).-Sl-(OR),-,; Lip 0 H,' ~"P-Pflh 0 and :2) (Cffs),-SI (OR)&-,, + NaO-P-(OCjHs)s (CHJ~-SI-(OR)j_, I~Hj _P-(OCjH&)s 0 1 - . 0 shoved.tha~,t%e where R-C 2H5; lie(CH 3)2 nm;1.2. The yield of the products Card 2/4 CH2Cl 64 I / 0)"6' E P?!1/000/008/005/010 B TITe reactions-of chloromethyl... B117 B20. salt of di6ethyl pho'sphinic acid reacts more easily. new organic compoundi containing Si and P were obtained as results of the reactions carried-ouW; methyldiethoxyoilyl mathylester of dimethyl phoaphinio acid (I)i dimiFthyl'. ethoxynilyl methylester of dimethyl phoophinio acid (11); methyldiethUy- silyl methylester of diethyl phosphinic dimethyl ethdxyeilyl methylester of diethyl phosphoric acid (IV); t stramethylsiloxy-l,~- .4i disilyl methylester of dimethyl phospbinio acid (V). The propertids of -- these compounds are comprised in the Table. There are 1 table and 3 non-Soviet references.-- The three referenoes to English-language publications-read as folloWs: A. Canavan, C. Eatorn, J. Chem. Soo.' 195~, 375); W. Garden, N. Thompson, Angl. pat. 815231; 24, 06, 1959; R. McIvor, C. McCarthy, C. Grant, Canad. J. Chem. a, 1819 (1959)- ASSOCIATION: Institut elementoorganicheakikh soyedineniy Akademii nauk SSSR (Institute of E~emental-organio Compoundat AS USSR)- SUBMITTED: October 12, 1960 Card 3/4 2t272 5/o62 a, etsOve 1. it", sthy' X U ~U%n hinto Set ar DOI is tria"Ityl(srtle'r-'e"'Of dimethl hi,jobesy-i~Lh Reaction 0 Sethi I es tae-jenile -IT LJ~ etho%Y still J.Z.Vestila. roup by . 555?~. 1192 - 1194 the allco%y 9 UV no- XV I r1ous orga .O&emils na I j961i tion 0 Va oily' 10 sub6t it %X UPS on etho%y 0 at naux I no ell th e end gro aimethyl silan t So the ting &-r0%1 trietbil inIeStigs hes, thil " OC an& r%edX thors dAG5 +hot by j+ rie f0 frh e a U old Ta h t 150 hinjo a foun& old V t W)o - - act ter Of TF,)LT I phosy t % So hinjo a te6 5 hosphinle Uet e Pounds - SP separs thy' V i.111- git aimetlay 0 -nil gas , jime e Or e m Of dijAct - Pho 0 e hO%y a sil alcohol t &r0% an isi,10% a ester -1 ester dimethy iuLet at ~jl 1 '19 thy, m,thj I Of lie I - methy of it ne et tol + e 1-3 61 e 0 ph stio From the reS hll P I eth g ere 0 a r disilo%a d with diSe A~M I aiSetbil -6imet 'Pe and res 5- 14. 'aic Be i,snet. acid id, in 64 Y 'hoslDhl- i n',c Phi Set'hyl P . . hydro%Y phosphin 0 hos di 11 diphenY dimethyl j climethy, V Seth'. , ester Of ester 0 Sethloxane jethl'- aist CaT& i/A 28272 s/062/61/ooo/010/007/08 B117/B101 Reaction of trialkyl ... atom. are substituted on the silicon Not only one but two ethoxy groups hyl di- Thus, from the reaction of dimethyl phenyl hydroxy silane with met ethoxy silyl methyl ester of dimethyl phosphinic acid at a ratio of 209 1,5-dimethyl phenyl-5-mothyl trisiloxane methyl ester of dimethyl phosphinic acid was obtained. similar reactions were conducted with tri- I ihenyl hydroxy silanea" All reactions were con- ethyl. and dimethyl dip silane and methyl ducted without a catalyst. The dimethyl phenyl hydroxy diphenyl hydroxy silane used were produced by the method of Y- A. kndrianov and N. Delazari (Ref. 3: Dokl. AN SSSR 1229 39 393 (1958)), and dimethyl ethoxy silyl methyl ester and methyl dietl~O-X-y silyl methyl ester of dimethyl phospbinic acid by the authors, method described in Ref. 4 (Izv. AN SSSR, otd. khim. n. 1961, 1454). Ethyl alcohol produced during the reaction was distilled off and identified on the basis Of boiling temperature and refractive index. Reactions conducted yielded compounds not yet described with 2 or 3 silicon atoms containing a di- methyl phosphinic group. The compounds obtained are colorless liquids readily soluble in organic solvents and may be distilled in vacuum. Their properties are listed in the table. There are 1 table and 4 referencesi 2 Soviet and 2 non-Boviet~, Card 2/4 20272 S/062/61/000/610/007/018 Reaction of trialkyl... B117/B101 ASSOCIATIONs Inatitut elementoorganichookikh soyedineniy kkademii nauk BSSR (Institute of Memental organic Compounds of the Academy of Sciences USSR) SUBMITTEDi April 6, 1961 Legend to the Tables (1) number; structural formula; (3) boiling point, OC (p mm, Hg)1 (4) foundl (5N)aleulated. 3/4 28670 J1- 0/020/61/140/002/015/023 A B103/B101 AUTHORS., Andrianovj Ko A., Corresponding Member AS USSR, kuresheval No As, Kuzneteoval 1. K,t and Garkhardtp B. 1. TlftEi Synthesis of polymers of regular structure of the polydimothyl- Biloxane series PERIODICAL: Akademiya ftauk SSSR. Doklady, v. 140l no. 2', 1961 365-367. TEXT: The polycondensation of the mothyl-diethoxy silyl-methyl sot or 0t dimethyl phosphinio &aid (1) with various alo-dihydroxy-dimethyl'eiloxan'es II) was studied. The' distance between the dimethyl phosphifie groups,. NIP) could be varied by using II with different numbers of dimethyl- siloxane links between the OH groups - The DMP groups were evenly, distributed along the molecule chain. II was synthesized by the reaction applied for diphenyl ailanediol (Ref - 3 1 see below). Its data are presented in Table 1. IX react with I at 1700C without a catalyst in the. following wayi 2867o 9/020/61/140/002/015/023 Synthesis of polymers of regul,ar B103/B101 Hj)j CH tit + M HO_ 1,0 H- P(CHO)l -0- 0, - jCH-, &6) + 2W,4H&OH. O-P(C%)$ The end point:of the reaction was determined from the quantity of liberated ethanol. It wag 76.50 of the theoretical amount at a degree of polymeriza-. tion n a 9, and 73% at n a 13- At n a 53t the reaction was considered to be completed when a conatent viscosity was attained. The molecular weights of the polymers 'obtained j determined by the visooeimetrie method, were 2190, 7250, and 31p620. The vitrification temperatures of all these polymers was low: -110001 -13000. A slight increase of the vitrification Card 2/4 28670 0/020161/140/002/015/023 Synthesis of polymors of regular ... B103/B101 temperature was obtained by reduaing the distanos between the DMP groups, The low vitrifiottion tomperstures of polymers with polar DMP groups in their chains are explained by. the fact that the DUP groups which are large as oompared with the CH 3t groups, reduoe the paoking density of the molecule chain. There are I able and 3 references: 2 Soviet and i non- Soviet. The reference to English-language publication reads as followes Ref. 33 Yoshio Takiguchug Bull, Chem. Soc. Japanq 12l no'. 6, 665 (1959)- ASSOCIATION: Inetitut slementoorganiohookikh soyedinaniy Akademii nauk SSSR (institute of Elemental Organic Oompounds of the ,Academy of Soisnoes USSR) SUBMITTED: May 171 1961 Card,3/4 3551,32 .coo/003/009 /W4 S/o62/b Blil/B144 tsove. and j~,jzrie ethyl methyl' oric- ohlorom dithi-opho a ph ~.nari ov 1 i~ - I- an in CL- aibuty 0, chlorine thyl-~ A:UT11QRS oil i e of ate OjdB 'heny Slabst'tuti du a into a silarkes by res O-phosph himi -jTL'F dithi Otdelen'ye nd silepes diPhe uX SSsTL ' -17,yestiya' thylet -holLy - na 19629 456-461) txaaemlyo 31 oromethyl-me hosph"'Ic Ohl 1-dithio'p with na'a'K, DO - Drine in CL- d d,phony ..O.Y811sne -050C f chli oric. all 6 hre at j30- Lou 0 h metIly .1dimethyle 10 tholcy A substitut! ai thi 0 Pbc,8-Phj Oro 'd f or almetbIle 1, f2he dialy-'Yl- of horic; horic beating to 94 0'and ithiophosp aithiophosp comp residues 0 il'i re - by tadied- its yield of. '08's 8 letbyl-d f aetbYl tions jo 44 n f to increase I acids salt 0 yi eld, 0 f diethy 86 es, Ophosph,1%11 9 possible 'a'nte 0 Bsiut , (1i t a 116 30 of DO ' .2 Onl"Y -it via 3. yie . rodUceu tic aT,10 . dipheul t yl- P stop (1) - tO6lJ '6 j th r O~ an c lorom 1 0 daing 00- 6. W s' h( i & CL - methy similal thlophool) A fter 3-4 hre by ain a di an e Ob tained f dibutY methyletbO74 (-j-1) was salts - 0 P.tass"111 ChIOTOM acids Ifith Igloo Card 1/3 s/062/62/000/003/009/014 B117/B144 Substitution of chlorine jyj aniline also produced y silane in the presence of dietl jilyl- and methyl- methyidiethox tstive yields (90 ~) of dimethylethox.YE" (,,I), (IV), (V) and almost quanti ters of the corresponding acid hyl-dithio- IiethoxYailYlmethyl es -1,3-di,ilylmethyl eater of diet a 65 ~Y 1). Tetraji )horic acid (Vill) (Yiel (V iethylsilOxl dithiophoor d from phosphoric acid (VII)p of dibutyl- lid (IX) (yield 85 ~) were obtaine and of diphenyl-dithiophosphinic ac ramethyl disiloxane in the presence romethyltet of diethYl reactions with 1$3-bie-ablO The catalytic ef*fect diethyl aniline amounts. cipating in the formation of a of catalytic robably connected with its parti thoxy silanes. Owing to aniline is P omplex 'with a-chloroulathyl-methyle of chlorine in transition 0 f the 0 - Cl bond, this favors the mobility obtained are listed ionization 0 The properties Of the products the chloromethyl grOuP*j table and I Soviet reference. in a .table.. There are elementoorganiohookikh soyedinoniy kkadomii nauk Institut pounde of th4 ASSOCIATION: 'o of Ejement&j o~ganio com t,tut B53B ('no es USSR) Academy of Scieno SUBMITTED:' October 169 1961 Card.2/3 Substitution of chlo rine in... 5/062/62/ B117,/B144 OCC/ 003/ 009/014 rA Legend to 0o yna T. omn. IG n 20 1 20 d "An POOP& IfUl -the Table: p (P. X4 v?. er.) D & c0 N (1) Number of (Clio)% (CIII&O) Sl - Cllspp (oc,116)l t26 (1) 1,4863 1,0715 81'1 81,M. the compound; It Clio (ClIlho).891CIIISP (S) (OCIlls)l 150-160 (6) 1,48M 1,0919 80.76 86,75 ~2~ Formula; III (CIj2)j(C2II&0) - SjCII*SP(S)(0C4IIrn)j tffi-M (2-3) 1,4821 1.0267 99,82 90,81 3 Boiling IV Clio(Csit&O)DSICI12sp(S)(OCIII*-n)2 M-M (2) t,4770 0,0514 S04,9 105,3 point OC V (C I I')'(C'II'0) Siclis - S - P(S)(Co II0$ UO-220 (P MM HO (4) 0 '" 6 1, 6056 1,148 1 110, 1 100,4 ; V I CIIS(WIo0)jS1CIfxSP(SXC1H01 - 235 - Molecular (I-IGP) I,W,8 1, 1545 115,1 114,82 vil refraction; (5) (Clio), - S1 - 0 St - (Clio), found; (6) (t-io-) 1,4915 I,tl34 138,4 139,2 calculated; *) T t A .H,O)P(S)- IS ~-P(Spc'llo)s empera ures Vill (CI`I')'_SI_0-SI(CHx)j of the bath. 200-204 1,4906 1,0753 176,1 176,42 2(n-C4HoO) P(S) P(S)(0C4IIo-n)j Ix (CH,)g - 31-0- Sl-(CHs)s I I I & T. wt. 126-127 Card 3/3, 1 S P(s)(Colls)II (C-!I6iS(S)PS AMRIANOVS K.A.1 DABAGOVA, A.K.; KUZNF,7SOVA, I.K. Synthesis of unsaturated phosphorooganosilicon compounds of the ailoxane series* Isv*AN SSSR,Otd,khJ-*n&Uk no.q:jlk4m#666 S 162. T (MIM 15tlO) lo Institut 4esentoorganichookikh soyedineniy AN SSSR. (Silicox~organie compounds) (Phosphorus organic compounds) 5/062/63/000/003/008/018 BIOI/B186 Andrianov, K. A., ~uznetsova, K. and Pakhomova, I. Reaction of mothyl-ethozy-silyl-mothyl caters of dialkyl- dithio-phoophoric acids with triethyl-hydroxy-silane PERIODIOALI Akademiya nauk S33H, Izvestiya. Otdeleniye khimiohaskikh naukp noe 3, 11963, 500 - 502 TEXT; The authors studied the reaction (CH3)2'1 i0c2H 5+ (C 2H5 3SiOH (CH 3)2S1'_O_3'(G2H5 3 + C2 H5OHO CH CH , 2 2 B-P-(OR)2 pV(OR)2 S In the case of R - 0 2H5 after heating at 140 - 150 0C the dimethyl. ethoxy-silyl-methyl eater of the diethyl-dj8hio-phosphorio 0 acid was ob- 1 tained, yield 50 16, b.p. 153OC/2 mm Hg, n5 a 1,46iS, d2 m 1.029. Witi 4 Card 1/2 3/062/63/000/003/006/018 Roaction of mothyl-othoxy- B!01/B)86 R - C H the correspd~ding eotor of 04o dibutyl-dithio-phosphoric acid 4 9 20 was obtain ed.in 40 ~, yield., b.P. 150OC/1-10 mm H9, n. .1-4769, 20 d 0,9947. The struoture of these compounds was identified by their 4 synthaois from 1-triethyl-3-chloro-motliyl-dimat,liyl-diailoxane and -DotaGaium diethyl-dithio-phosphate. ASSOCIATIONs Institut elemenioorganichoskikh ooyndineniy Akademii nauk 333R (Institute of Elemental Organic Compounds of the Academy ot Sciences USSR) SUB'HITTED: IMay 29 1962 Card 2/2 MASTRYUKOVA, T.A.j 811111M, Yu.N.; XVZI&T ~4~VA I.K.; MiESUNI, Ye.M,; SAIGWOVA, T.B.; UBACHNIK, ff.I. Hammett equation in the theory of tautomeric equilibritun. Part 2: Tautomerism, ofa -aryloulfaminopyridines,?otentA21MW *,atudy, AO 163. ~qrzt*kbla. 33 no.lQj3328-3335 0 . i Hamm tt equation in the theory of tautomeric equilibrium. Part 2: Tautomerism. ofOL -aft;oulfaminopyridines. Spectro- photometric study. 3336-3342 WMA 16:11) 1. Inatitut elementoorganicheak-ilh soyedineniy All SSSR i In- stitut khimii prirodnykh aoyedineniy AN SSSR. ACCESSION NR: AP4025009 0/0062/64/000/00310454/0457 AUTHOR: Andrianov, K. A.;_"s Wwa.1s. K.; Yermakova, M. N. TITLE: Polydimethylailoxanes containing tris(trimethylsiloxy) and dimethyl- phosphinoxy terminal groups 7 SOURCE: AN SSSR. Izv. Seriya khimicheskaya.- no.- 3, 1964, 454-45 TOPIC TAGS: liquid polydimethyls:Uoxane, terminal polkiner group, tris(tri- methylsiloxy) group, dimethylphosphinojq~ group, viscous flow ictivation energy, polymer viscosity, polydimethylailoxane viscosity, condensation synthesis, polymer synthesis, -polymer molecule number ABSTRACT: Now liquid poVdimethylailoxanes containing the above terminal groups were synthesized by condensation of ot, (4-dihydroxydimethylailoxanes with the dimethylethoxymilybuethyl eater of dimethylphosphinic acid or trio (tri- methylsiloxy) ethoxyxilane, and some of their properties (molecular weight, glass-forming temperature, activation energy) studied. Tho reaction formula to Card 1/3 ACCESSION NR: AP4025009 presented and properties tabulated. In the end products, n, denoting the numbers of polymer molecules, was equal to 9, 13, 42, 45, 75 and 120. Viscosity In the 20-120C range was higher in polymers with terminal tris (trimethylolloxy) groups than in those with the dimethylphosphinoxy group for the same degree of polymerization. The logarithm of viscosity, inversely dependent upon tempera- I ture, to also figured. The activation energy of viscous flow, calculated accord- ing to experimental data in the range studied, decreased upon increasing the distance between the terminal groups, which may point towards a comparatively great influence of these groups, as against that of the dime thyls iloxane groupsi of the backbone. The synthesis to described. Orig. art. has: 2 formulas, 2 tables and 4 figures. ASSOCIATION: Institut elementoorganicheskikh soedinennty AkadeM.U nauk SSSR (Institute of Orpnoejawfta Campowdsp AcaderAy of Sciences, SSSR) SUBMITTED: J00602 DATE ACQ: 17Apr64 ENCL: 01 SUB CODE: CH NO REF SOV: 005 C)THER: 001 catj 2/ 3 V! ACCESSION NRIA?4025009 malms 101 oil arduml pral MHSOH + f ol 1. -.1. till 0 1 ('C' H +(CH 'Jai jug (CHS)l P ~-p 041 whore n 45. 73, 1 20 fe'lls CH l(Cags woll al 0 JAI I'ositow(CU4104MR&OU Card 3/3 where n,~ .ACCESSION NR* AP4033366 0/0062/64/000/004/0651/0636 AUTHO11 Andrianovp Ko A91 Kusnatsovaq Is Ke ';TITLEs Synthesis of certain phosphorus-cont&LnLng orS¬Lt&nLu1W 'compounds !SOURCE: AN SSSR, Izvootiyes SerLya khLmichaskaya, no. 4, 1964, 651-656 iTOPIC TACSt polymersp heat-reiistant polymers# organotLtauLus poly- imers. phosphorus containing organotitanLum polymers# dimethyl- -O-T backbone, phovphLnatolbutrarxytLtanLumg polymers with TL ipolymer'wLth TL-O-P backbone :ABSTRACTs Polymers with TI-0-Ti backbones and pendant dLmethyl- :phosphonate groups and polymers with TL-O-P backbones with pendant ~alkoxy and methyl groups havt been synthesized for the first times ;Honomers with TL-O-P backbones and functional groups linked with the itLtanLum aton-dLuothylphoophLnatobutoxytLteaLums-of the type card 1/4 AMSSION NR9 AP4033386 I (CH3)2P-O-jSI - Ti-(wOCIHg),,-,, where nw2, 3, or 4. were synthesized 0 by condensation at 140-150C of dimethylphosphinic acid with tatra- ~butoxytLtanium,, taken in the ratios 2slq 3slg 4sle Hydrolysis of lbie(dimethylphosphinato) disbutoxy-tLtanium yielded a powdorlLko 'polymer (CIIS)s P - 01 - TIO '(polymer 1) which is insoluble in water and the usual organic solvents' .and has a melting point of 435-460C (thermomachaaLcal curves I and 2 In Fig* 1 of the enclosure)* Reactions of bis(dinothylphosphinato) ,dibutoxytitanium with triethyl- or nothyldtphanylailanolp or of bis .(triethylailoxy)dibutoxytitanium with dimethylphosphLaLe acid yielded solid products with a melting point (thermomechanLeal curves 3 and 4 An Fig& 1) and other properties similar to those of polymer to Retero- .functional condensation of tatrabutoxytitanium with methylphosphisLa g Card 2/4 ACCESSION NRs AP4033386 chlorLde yielded a r~sLnILko polymer with TL-O-P backbone and pendant butoxy- and mathyl groups* Orig, art. bast 2 figures, ASSOCIATION1 ln#tLtut elementoorgauLcheekLkh soyedLnenty AN SSSR (institute of OrSanoeleviental. Compounds, AN SSSR) ISUBMITTEDt 278op62 DLTZ ACq i 151(ayG4 IINC161 01 SUB CODEt CH. WRIVOISOTS 002 OTHZR& 002 LCSrd 3 4