SCIENTIFIC ABSTRACT KUZNETSOV-FETISOV, L. I. - KUZNETSOVA, A. G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000928220001-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KLWRATIXEV, S.N.; -- !_qW7OOV-=XSOV-r Lwlw--
Inhibition of liquid sulfur trioxide polymerization by boric
anhydride. Trudy MTI no.26sl6l-266 159. (KM 15 s5)
le Kafedra fisicheskoy i konoidwy Wail Kazanokogo khimiko.-
tekhnolo icheskogo institute, imeni S.H.Kirova.
Islulfur trioxide) (Polymerization)
(Boron oxide)

30506
S/194J61/000/008/058/092
D201/V304
AUTHORS: Batuyev, Yu.V. and Kuzriateov-Patisov, L.I.
TITLE: Intensification by ultrasonic field of certain
reactions in the nitrogen industry
PERIODICAL: Referativnyy zhurnal. Avtomatika i radioelektronika,
no, 0, 19610 11, abstract 8 E81 (Tr. Kazansk. khim.
tekhnol, in-ta, 1960, no. 29, 128-132)
TEXT: The effect was studied of ultrasound on the reaction
of inversion of nitrite into nitrate and on the synthesis of nitric
acid from liquid nitrogen oxides, The frequency was 21 kels and in-
tensity 6-7 11/cm.2. It was established that ultrasound intensifies
considerably (as compared with mechanical stirring) the inversion
reaction of nitrite into nitrate; the reaction does not depend on vle/
the solution concentration and is accelerated considerably with
temperature increasing to 60-800C. Under the effect of ultrasound,
the synthesis of concentrated nitric acid from liquid nitrogen
Card 1/2

3D506
S/194/61/600/008/058/092
Intensification by ultrasonic field... D201/D304
oxides takes place at 0-200C with no pressure and with air as an oxi-
dizer but always with an excess Of N204 (- 100% com2ared with the
stachlometric mixture). 3 tables. 7 references . L Abstracter's
note: Complete translation2 I X
Card 2/2

30507
S/191i,/61/000/008/059/092
A 0 D201/D304
AIJTHORS:- Kuznetsov-Fetiaov, L.I. and Datuyev, Yu.V.
TITLE: The ultrasound intensification of the process of
producing concentrated nitric acid by the direct
synthesis
PERIODICAL: Referativnyy zhurnal. Avtomatika i radioclektronika,
no. 13, 1961, 11, abstract 8 E82 (Tr. Kazansk. khim.-
tekhnol. in-ta, 1960, no. 29, 139-140)
TEXT: The mixture of nitrogen oxides were placed in glass
and steel vessels and oubjected to ultrasound at a frequency of
21 1=/s and intensity of 6 W/cm2. With a 100% excess of 11204 in
the nitrogen oxide and --aitric acid mixture, with nitric concentra-
tion at 5076 and air as oxidizer, the concentration of nitric acid
reaches 82.279 after 15 minutto of ultrasonic action, it reaches 88%
after 30 min. and 92,2% after 60 min. With industrial oxygen as an
ox.idizer the concentrations are 85.4%, 92.376 and 95.1% respectively.
Card 1/2

30507
SA94/61/000/008/059/092
The ultrasound intensification... D201/D304
With a 50*16 excess of N204 compared with the stochiometric composi-
tion, the concentration of nitric acid is as followe: with air oxi-
dation and 15 min. of ultrasound 78.9%, after 30 min. 05.3% after
60 min. 88.2%; i-rith oxygen oxidation the values are 81.4%, 67.6%t IX
90.576 for 15, 30 and 60 min. of ultrasound effect respectively.
The change of the reaction temperature from 0 to SOOC does not mat-
erially affect the concentration of the nitric acid obtained. The
concentration of nitric acid in a glase vessel, with other condi-
tions remaining the same, is higher than that in a steel vessel.
All experiments were carried out without an pressure being applied.
Z-Abstracter's note: Complete translation7
Card 2/2

KOMDRATIYEV) S.N.1 KUZETSOV-FETISOV. L.1.; ZINKICIIEVA, K.A.
I
Vapor pressure, density, and viscosity of stabilized sulfur
trioxide. Trudy KKHTI no.30sl9&-204 162. (MIM .16 s ID)

KRASNYY,, E.B.; KUZNETSOV-FETISOV L I.
-4
Study of adsorption and desorption of nitrogen dioxide - nitrogen
tetroxide, an toohnical silica gels ASM and No,6, Trudy MMI
noJOt223-?39 162. (KM 16:10)

KRASNYY, E.B.; KUZNETSOV-FETISOV L.I.; ROZENBERG, G.I.
Adsorption of small concentrations 6f nitrogen peroxide - nitrogen
tetroxide under dynamic conditions. Izv.vys.ucheb.zav.;khim.i
khim.tekh. 6 no,51802-806 163. (MIRA 16112)
1. Kazanskiy khimiko-tokhnologichookiy institut imeni S.M.Kirova,
kafedra tekhnologii neorganicheskikh veshchestv.

Dynamics and flow of pbytoplankton In the Volga River near
ahoy. Trudy probl. I tome Bove n0-7:108-110 '57. (KM 10t4)
(Volax-River-Ph7toplankton)

- - -, -- --- *---L----u" 1
1. SIM1.914OV, A. P.: CHENIKOV) 11. V.: KU.~'J!-TSOVA A A.
2. USSR (6W)
4. Tobacco - Analysis and Che-Istry
7. Effect of tobacco tar on its steeping rate. Tab;~Ik 13 no. 6, 1952.
9. YAMthly List of I~ussiqn Accessions Library of Cangreas, karch 1953. Unclassified.

Kuznetsova, A. A. -- "Sequel-ie of Severe Tnjuries of the II-',Lxill,-ry-T--)ental Pystern,
1~
(of Gun-3hot Origin) and rtinciplrjs of Orthopedic Trerltmpmt, " I,An !',u' lie
licalth IMFSTI, Ioncow 1'edical Stomatolotdcal Inst, "oscow, 1955 ( Dissertation
for Degree of D6ctor of Mdi.al sciences.)
SO: Knizhnaya Letopts', No. 23, Moscow, Jun 55, PP P7-104

I-Kum- TS_O_VA-t_A-.A-.
. "Preventative Vaccination Using Live Ampule-Packaged Cultures of TAishmania
Tropia for thi Prophylaxis of the Spontanoous Borovskil Disease (Southern
Loishmaniasis)." Cand Biol Soi, Ashkabad Inat of Epidemiology, Microbiology,
and Hygiene, Min Health USSR, Ashkabad, 1954. (KL, No 1, Jan 55)
Survey of Scientific and Technical Dissertations Defended at USSR Higher
Educational Institutions (12)
SO: Sm. No. 556, 24 Jun 55

KORSHAKOVA, AA-,~ SKAVINSKIY, lfu.V.; 'xMNxT�OYAj,, 'OTNTERKO. O.M.;
; TMINTN"At I
ARXHIPOVA; V.A.; OALIPERIN, I.P. 11K., rja.; KIYASHJW,
M.A. I'
Studying the immunogenic factor in per os Immunization against
dysentery. Zhur, mikrobiol. apid. I immun i8 no.2:131-132
F '57 (KLRA 10:4)
1. Iz Instituta opidemiologii I mikrobio'logii imeni N-1P. Gamalet
ANN SSSR,
(DYSENTXRY--PRIVIINTIVI INOCULATION)

LITVINOV9 VA; KU2WSOVAp A.A.
We are protecting mustard against posts. Zashch. rant. ot vred.
i bol. 2 no.6s48 N-D 157. (MIRA 16il)
1. Predsedatell kolkhoza Leninskv Leninskogo rayons, (for
Litvinov). 2. Zaveduyushchays Leninskim punktom sluzhby ucheta
i prognozov (for Xuanotsova).
(Mustard-Diseases and pasta)
(Spraying and dusting in agriculture)

KAUFMAN, Mikhail Simonovich; KUZX=qVA,__AMp_AlqKfLey iTg; KHRU4ICHEyp
t
Yuriy Andreyevich; BRODSKIY, S.I., red.; BOIWNOV, H.I."
tekhn. red.
(Manufacture of spirals, grids, and leads of electronic
vacuum devices]Proizvodetvo spiralei, setok I vvodov elektro-
vakuumnykh priborov. Moskva, Gosenergoizdat,, 1962. 262 p.
(MIRA 16:4)
(Electron tubes)

BELTAKOV, V,A.; VAN rlj~WHM (Wang Young-chlang]; VIRYASOVp NX;
DU YUAN'-IVAY [Tu Yuan-t9'ai];i= XHI IN; XUDNITSKAYA Ye.N.;
KUZNETSOVA AA.j NGUEN DIN TY; FENEVp V.N.; SUOLOVAP fe.S.;
-g65FREL?EiiU
Prop rtie; o; mesons produced together with otrange particles
erah
in p-int wo one and 7f C-interactions. Zhur.ekspA teor.fis.
no,. 5 1'1474-1480 Vq 063. 1' (MM 16 16)
1, Ob"yedi We Inatit t yadernykb loole4ovanly.
Obs it Ilddear Motions)

.A.; -UZMSOVA, A.A.; YAViIINAt" N.ie.
On the natura of opherulites in pol3rtrifluorochloroothylans Lvith
summary in Inglish. Zhur.fiz.'-,him. 31 no.9:2o6l-2o65 s 157.
(MM& la: 1)
(3thylene) (Spherulites)

23870
S/l86j6l/OO3/OCI/003/020
A051/A129
c;N, Co2oo
AIUTHORBs Kusnetsovap A*A69 B&SOYIDTf O*Y&.t Tikhomirov, V.I.
TITLEo The salting-out action of cations and the ooval*noy of their inter-
action with the water solsoules.of the solution
PERIODICALs Radiakhimiyat v 39 no.~ 1961% 10-13
TEXTs The cause for the decrease in the effectiveness of the salting-out
agent with an increase In the odyalenoy of its interaction with water# vis.
the fact that the covalent interaction of the oationvf the salting-out
agent with the water molecules closest to it-brings about a decrease in the
effective charge of the cation (Ref. 1), was investigated. 1 comparative
study was made of the'salting-out action of the nitratest the cations of
which have the same charges and radiip but differ in the structure of their
electron shells. A further stud5 W9,44 made of the effect of nitrates of ru-
bidiu2t thallium (1)t nickel (II an cobalt (II) on the distribution of
small quantities of uranyluitrate between aqueous solutions and diethyl OK
Oard 1/6

23570
The salting-out aotion of oations ...
311861611003100110031020
A051/A129
other. It was established that the chosen aalting-out agents in the experi-
aents were poorly soluble in diethyl other and did not pass into the organic
layer under the given conditions of the experiments. The relationship of
the distribution coefficient of uranylattrate to the concentration of the
salting-out agents was investigated In the Initial aqueous solutions. Table
I shown the results of the determinations of the aranylnitrate distribution
coefficients between diethyl other and aqueous solutions containing Rb+ and
Tl+ nitrates. It is seen therefrom that the oooffioisAts of the ur&nyl-
nitrate distribution between the diethyl other and aqueous solutions can-
taining these nitrates are very low, and the difference between the average
values of OL in slight. Table 2 lists the values of the coefficients of
ur"ylnitrate distributi2n b*two*l diethyl other and aqueous solutions in
the presence of Ug;4+, NO+ and Go +1 and the graph shown the graphical re-
lationship of OL to the concentration at 2500, 31ron the letter it Is seen
that in the came of cobalt and nickel nitrates the relationship otot (o) in
expressid by one curve and they are such lose effective as salting-out agents
than Mgz+. With an increase in the temperature from 0 to 250C there is a
drop in the distribution coefficient of the uranylnitr&te in all cases, but
Card 2/6 qK

23870
S/18 61/003/001/003/020
A051YA129
The salting-out action of cations
2+ 2+
the indicated diffe once in the salting-out action of Hi and Cc as oom-~
pared to 'that of U95+ is Main:tained both at'O and at 250C. The authors con-
clude that the former relationship of the salting-out effect to the oovalency
of the interaction of its cations with the water molecules of the solution
given in Ref I is oonfirmed. The observed effects were also investigated
with relation to the pH of the solution. It is assumed by the authors that
in view of the experimental'results this observed effect should decrease
with an increase in the acidity and the salting-out agents can become re-
verse in their salting-out action. There are 2 tables, I graph and 51soviet-
bloo references.
Oard 3/6

A051 ~1611 ~003100110041020
29
4 C o
AUTHOM Samoylovp O.Ta.t Tikhomi.rovq YeIeq Ionovg VaNj Kusnoteova,.L.A.
TITLEs The relationship between the effactiveneas of the salting-out agent
and the hydraticn of the salting-out Ion
PERIODICALs Ridiokhimiyav v 30 no 1g 1961t 14-18
TEM In the present vork the authors have investigated the relationship
between the effectlTeness of the salting-out agent &Ad the hydration of the
salting-out-ion, ustng,the qualitative theory developed in Ref 1. It is
seen that the stronger the salting-out oation is hydrated, the more offoot-
ive the given salting-out agent should be in relation to ito i.e.# the
'higher should be the value of its 62salting-ont (a deere"a in the energy
of aetivation of the water molooule extraotion from the closeat surroundings
of the extraoted ion). Thus, k
AEsalting-out 23
Card 1/6

3/186/61/003/001/004/020
The relationship between the effectiveness too A051/A129
where k is a coefficient depending on the cation charge of the salting-out
agent, dipole moment of the water solsoule and aharacteristice of the water
Malu-tiont and 51~&thv avoings (pffective) distanoe between the salting-out
cation, and the tion of the oaltize-Out agent. with an increase in the
hydration of the ealting-out ion, the value of 2Galting-oat re lated to the
action of a certain salting-out agent on it incrossest (4)
(AE salt.-out)i , (6 salt.-Out) j or ('6 Eaalt.-Out)i-rr ('6 Esal t. -out)j
whore the coefficient ^r > 1. For varioue naltiug-out agents it in assumed
that the values of the ooeffioionts are about equal, thent
( 6 E asalt.-Oul)i W 7 ('6H$salt.-out)i (5)
where a = 1,2,3, corresponding to the different salting-out agents. The
anthore,investigate the salting,.out ion& i and J, whereby the i-ion in
,oharaoterived by a higher hydration than the J-ion. It is established that
the relationship of a Emalts-out to the hydration of the salting-out ion
Card 2/6

The relationship between the effootivonseepoo
brings about the squ&tiona
23871
0/18 611003100110041020
A051YA129
01
-) - (a ) (9)
&2 1 92 j
(where a Is the distribution coefficient ffief 12). It is confirmed experi-
mentally by investigating the extraction of ura:Wl and thorium with tributyl-
phosphate from water solutims ocataining saps4ium, calcium and strontium
nitrates. Equation 9 indicates that with a strengthening of the hydration of
the salting-out-ioA the relative increase in the distribution coefficient
growei determined by the growth of the effectiveness of' the salting-out agent.
Table I lists the determined values of the distribution acefficients of
uranyl and thorium, and table 2 lists the ratios of the distribution cooffi-
oients for uranyl and thorium in the presence of various salting-cut agents
from a group of magnesium, aaloiurm and strontium nitrates. The ratios taken
are that of the distributien coefficients in the presenot of a more effective
salting-out agent to the value of the distributicn. aoeffioiant in the pre-
sence of a loss effective salting-out ag*nt. The dot& of table 2 show that
these ratios for thorium are greater than for uranyl. Since thorium is
Card 3/6

2)871
8/18 61/003/001/004/020
The relationship between the offootiveness... A051YA129
hydrated more strongly in aqueous solutions than uranyl, it is ooncluded that
the experimental results oonfirm the validity of equation (9). There are
2 tablee, 9 formulae and 6 rererenots, 4 Soviet-blne, 2 non-Soviet-bloo.
Oard 4/6

ACCESSICK AR; AP4032D,96 810186/64/006/002/0173/Olft
AUTR01h .' Tikhomirov; Ve I.; lWactsova, A* Aq Betorovs1cayap Be Do
TETIE: Extraction of uranimn (VT) with n-triocty1mim (TOA) in the presence of
.certain cations. I* Nitric acid solutions.
SOURCE: Y. 6,, nof 2., 1964., 173481
TOPIC TAGS: uranium (VX),, extraction.. trioctylamine., salting out agenti, nitratep
~cation chargep cation radius., partition coefficientp distribution coefficient#
nitric acid
ABSTRACT: The effect of different concentrations of nitrates in aqueous nitric
acid solutions containing uranyl, nitrate on the extraction of the U(vz) frM these-
vas
.solutions vith TOA weA investigated* A o*537 K solution of TOA in CC14
.used as the organic extractent; 0*05.8 M aqueous nitric acid solutionsp lose than
~0.02 M uranyl nitrate., and different concentrations of potasslua, slymonlin..
,lithim,, strontim., caUiumo ca&dumj, zinc,, nickelo cobaltj, -w sium and a2UM1VM
I
.nitrates vere usede The U(VI) In vater van determined colorimetricaur with
arsenazo.1 or arsenazo M and in the organic pbaaq vith arsenazo =e In the
C*rd

'ACCE=(Xf M.' AF40310(A
'extraction of U(VI) from IMO solutions vith TOA,, as in extraction vith o3WVn-
containing extractantso the Utz; out action In a constant concentration of
nitrates ond IWO increases vith anincrease in the charge of tha salting agent
cation and ine"Les an the cation radius decreases. The effectiveness of the
salting out agetnt decreases as -tho aovalena of the reaction of the cation vith
the vicinal vater molecules decreases. As tha acidity of the NwOUS PhAiG
increases, the effect of the nature of.the salting agent cation is less definite;
at nitrate concentrations above 7-9 gasions/I the partition coefficient
decreases independently of the nature of the cation of Vw salting out agent and
independently of the 0 OrIg* arte Me: 3 tables.. 3. f4puvs
"WO3
and I equations
issoci=m Itow
rrTTR': 94Nov,(e DM AM: 30AVA RNM: 00
SUB C=t NO MW SOVII 015 '329119 012
card

Acassim NR: AM31097 8/03B6/64/006/002/0182/01ST
AMOR. Tikhomirov) V. I*; Fj=etsove A. A,,, Batorovskeya., E. D.
TITIE; Extraction of uraniun (VI) with n4rioctylamine (TOA) in the presence
of certain cations. no Hydroohloria acid solutions*
SOURCE: nadiondmiya.. v. 6.. no. 2, 3.964, 182-18T
TOPIC TAGS: uranium (VI) extraction, triocty1mine extractioup salting out agentol
chloride, cation radius, cation charge, salting out Wat concentratioa) partition.
coefficient, hydrochloric acidp distribution coefficlent
ABSTR=: The authors continued their study (Radiahimiya, 6) 2., IT3) 1964) of
the extraction of uraniun (VI) with TOA from acid solutions and the effect of
salting out agents using hydrochloric acid solutions containing different concen-
trations of potassium,, amumium., sodium, lithium., strontium, calcium) magnesium
I and aluminum, chlorides* A 0,10 K solution of TOA in C014 wac used an the
extractant. The behavior of-tba chloride and nitrate salting out agents in the
extraction of uranium (VT) vith, TOA from HC1 and ENO solutionso respectively,
is analgous,, Lee* -the salting out corresponds to Merease in the radius of the
:Card 1/2

ACCEMICH NR: AP4031097
cation and increases with increase In the cation charge, Rowever, the nature Of
the cation of the salting out agent Is more distinct in the case of the nitrate$*
Increasing the HC1 concentration to 4 Wincreases the partition coefficient
of uranium (VI). With Increasing concentration of the salting out agemt., Ig
deviates from a straight line.' This is attributed to a decrease In the concentra-
tion, of free extractent (TOAOHCI) becau of tha wctraction of HC1 In the
organio phase. Orig. art. hue. 4 fip"s and 3 tablese
ASSOCI=CV: None
SUBUTTO: 24Nov62 D= ACQ: 3oApr64 WCL: 00
Sm 0=-. 10 MW SOVI 003 OMM 001
Card 2/2

t
Acamicu n: m4o3wo 5/6186/64/006/002/0187/01$1
MY~HOR: Tikhomirovp V. I.; Khznetsova.. A* A.; Batorovs]Wap Be D.
TITIS-. Extraction of UmUlUn (VI) With U-trI00tYlaMinG (TOA) In thO Presence
of certain cations* Me Sulfuric acid solutions.
SOURCE: Radiokhimiya., ve 6.. no. 21 19640 187-191
TOPIC TAGS: uraniun V1j extractionj, trioctylamine extraction, distribution
coefficient, acid solution., sulfuric acid solution,, uranium trioctylamine
complex$ salting out, particition coefficient
AWTRACT: The distribution of uranium (VI) between a 0.1 M solution of TOA in
C1 and 0*05) 1 and 2 N H SO solutions to which different amounts of the
2
1at!~s of lithium, sodia,
S kznium, magaesium and aludmun were added was
deteyzdned. This is a continuation of simila wDrk using nitric and hydrochloric
acid solutions (Radiokhimiya, 6., 2,p 173 and 182., 1964. on extracting the u(vx)TU
cm*lex from sulfuric acid solutions, the addition of sulfates decreases the
distribution coefficient 0. regardless of the concentration and nature of the
cation.. There is lumever a clear relationship between the reverse and the
Card

ACM=Cff NR: Ap4o3logS
cation radius of lithium, sodium and -onii- sulfates. The order of the effect
of caiions of different valency changes as the acidity of the aqueous phase is
increased@ In comparison with extractions with IMO end HCl solutionsp the natureI
of the cation of the salt affects the distributions3of U(VI) much less; the nature
of the cation is less clear the greater tbA anion inclination to form complexes
with uraniume On extracting in the presence of Na.SOh the sold content InAbe.I
oreanic phase is less than in the presence of US oil Al sulfates; N%SO4 causes
less salting out of the U(VI) in strong acid solutions than the polyvalent,
sulfates* Orige art. h": 3 tables and 2 figures.
ASSOCZATICK: Nona
EXCL: 00
smmum: 24Nov62 DATE ACQ. 30Apr&
SM CODEs GC' NO MW WVI '004 OMRI 003-
212

- - '?' -
airritratrachloride and

M 'I, RT F -~flv - IME

BLSLAY?V, A.A.; PODZO'I'KO,,, Yu.G.
A-mmonolysis of tungsten (Vf) oxo ;hlorldes. Izv. AN SSSR.
Neorg. mat. 1 no.6i903-906 Je '65. (MIRA 18:8)
1. Inatitut obehohey i neorgardehaskiy khimil imeni N.S.
Kurnakova AN SESSR.

TIKHOMIRGVv V.I.; KUMETSOVA., A,.A.j BATOROVSKAYAp E.D.
Extraction of uranium (VI) with n-triootylamina (TOA) in th~
presence of some cations. Rad:Lokhimiia 6 no.3s171 ~11 0.1
Extraction of urani= (VI) with n-triortylamine (TOP
rresenne of some cations. Part 2:Chloride solutions- lbld.:182-7187
Extraction oC uranium (VI) vith rv--trioctylamine (TOA) in the
presence of some cations* Part 3sSulfate solutions. Ibid.slF"-191
(MIRA 317 -.6)
GOGOLIN, A.A., ..bnyy red.1
GHICHKOVP N-V.r,red.; BABICHEVA, V.V.t tekhn, red.
(Water-cooling system for mali rgf~rigerath LW pUnts; scientific
report] Gradirnaia, d3ta xmiyktL kho
Boobohcherds. lodi3.'nYkb ustanovok; nauobnoe
moskvat aos. i2d-vo torg. lit-ry, 1958. 7 P;
(Refrigeration and refrifOlrat.ing machinery) (MIRA .1437

'B-l Inshf; KET4NMSOVAt A., insh.
Standards tor refrigeration equipment of food stores. Khol.takh. 35
no.5:4"l 3-0 138* (MIRA 11111)
1. Vessoyusnyy nanebuo-Issledovatellskly Institut kholodillwy
prourehlonnosti.
Ofood--Preservation) (Refrigeration and refrigorating machlner7)

--- - KUZMUSOVA,--A.-,inzh.-,
Methods of testing refrigeration equipment Cilth sumary in
Inglish]. Khol,takho 37 uo*2:36-40 Y6r-Ap'60, (KIRA 13: 10)
1. Vassoyuxnyy nauabso-lesledovatellskiy Institut kholodillnoy
promyeblennosts.
(Refrigeration and r of rigerating laReh'inory-Testing)

KaZNETSOVA, A., Inzh.; M BRAZMSKLYA, I., insh.; BLIKIN, I.
Triple-dock refrigerated display case 33-13. Zhol.tekh. 37 no-503-
35 S-0 160. (MIRA 13:10)
1. Toesoyusayy nauchno-looledovatelleiriy institut kholodillnoy
promphlonnosti (for NUSAOteova and Proobrashouskaya), 2. Xharl-
kovskoye opytno-konstraktorskoys byoro torgovogo mashinostroyanlya
(for BlIkin).
(Display of merchandise) (Cold storage)

BER., Boris Arkadlyevich;.-IW=SOVAO-A!!i~_4~lpiya.AleksaWrovna.j_GOGOLINs A.A,,p
kand. tekbn. nauk, nauebrWy red.j UPLUN, M.S... red.; BRODSK37, M.P.;
tekbn. red.
[New types of commercial refrigerating equipment] Novye vidy torgo-
vogo kholodillnogo oborudovaniia; nauebnoe voobabehanie. Moskva,
Goo. izd-vo torg. lit-ry, 1961. 44 p. (MMA 34 sio)
(Refriseration and refrigerating machinery)

KUZNETSOVA, A.A., inzh.
Norms for the equipment of self-service &tores vith commercial rafrig-
orating machinery. KhqX.te~h, 39 no.4:76-77 JI-Ag 162.(MM 17s2)

KUZNETSOVA, A*A*) inzh,
-,. I-.
Film cooling tower for simll refrigeration systems. Khol.tekh.
41 no.lt65 Ja-F 164- (MIRA 17:3)

X=09, V.I.,, kand. tekhn. nauki KELIMANp L~F,p inzh.-khimik;
MELITSERv F.R,p inzh.-khimikj-!~MNETSOVA,, A.A.,, laborant
CanparatJve phenol characteristics of smoking preparations
and uncooked smoked sausage. Trudy VNIIMP no.16:211-220 164.
(MIRA 18: U)

KVJZTIETfa-'OVAs A. B.
Cand Phys-Math Sci (diss) "Problems of the theorv of entrance
and exit of particles in the synchrophasotron," ZDubna, 19617
8 PP; (Joint Inst of Nuclear Studies, Laboratory of Nuclear
Problems); 160 copies; price not,~iven; bibliography on pp 7-8
(10 entries); (KL, 5-61 SUP, 17

TS227.L66 TREASURE ISIAVD BUOK ~IiLViSi; AID 786 - s
KUZNI~TSOVA, A. D., V. V... and Y,ROVINSKIY, L.
(Eng. )
5VAKKA VYSOKOPROCIINOG(i CHUGUNA 80 SFEROIDALINY,i ~~Ik'ITOI'l (A'elding High
strenght bast Iron with Spheroidal Oraphite). in K. V. Lyubavskiy, ed.
Novoye v tekhnologii avarki (Innovations in the WeLling Tecimique). 1-!ShGIZ
1955. P. IJA-157.
This article prtisents tho resluts, of investif,,,ation of the wolubility of high-
strength cast iron and arc welding with steel elecLrodes, iron-nickle electrodes,
and electrodes of special cast-iron alloys. it also -iisousses he oxyactitylene
welding of high strenLth cast iron. eive picturos and rlrafhs, and 4 tables.
L Russian re:'oreuces, 1947-1953.
1/1

e~l

F 1
t

KU21MOVA, A.D.; RUBELI, I.A.
Creatinuria 1z some fOTMO of labor anomalies; preliminsry report*
Sbor.nauch.trud.Kafakush, J gin. I IMI no.2tl37-141161.
(MIRA 16:7)
(CREATIVE) (LM, CCUPLICATED)
(IMM-AVILLYSIS AND PATHOLOM)

VASILIYEVA, Ye.T.; KUMETS011A , A. D. ; IAYZAN, Ye. 1.
Use of colpeurysis according to the type of commnicating vessels
in pelvic presentation of the fetus. Kaz. med. zhur. no.6:75-77
N-D 163. (MIRA 17:10)
1. Kafedra akusherstya, I, ginekologii (zav. - prof. I.I. Yakovlov)
I-go Leningradskogo maditsinskogo instituta imeni akademika Pavlova.

kUZNFTSOVA A.D. ROBEV A.A.
Creati~uria n labor atunia, one of the abnormal labor f--ms.
40 no.508-41 S-0 164. (MIRA 18%5)
1. Karedra akushorstva i g1tickologli (zav. - prof. I.I.Yakovlev)
I Loningradskogo meditainikogc instituta imcr1P&V1ov&.

KUMMOVA, A. F.
MNETSOVA, A. F.: "The reaction of certain varieties of potatoes to
drying conditions*" Min Higher Education. Gorlkiy Agricultural
Inst. GorIkiy,, 1956. (DiBsertation for the Degree of Candidate ink
Agricultural Sciences)
Sourcet KnizhEM letopisl No. 28 1956 Moscow

KUZNETSOVA, A.F.
Recent data on the Asiatle smelt Onmems aperlanus dentex
Staindachner. Isip. TIVRO 482214-215 162. (Mmi 164)
(Amur River-Swits)
A

YEVRNIMVA. T.N.; KUZ10TSOVA. A.7.
Interference microscopic determination of the weight of individual
coacervate drops. Dokl.AN SSSR 124 no.3:688-690 Ja 159.
(MIRA 12:3)
1. Moskovskiy gon~4arstvenMy universitet imeni N.Y. Lomonosova.
Predstavleno akademikom A.I. OparliWm.
(Coagulation) (Interferometry)

KUZ94TSOVA. A.F., felldeheritea (Kolomna)
roes$ activities in a therapeutic consulting room in polyclinic.
14od.sestra 17 no,2127-29 F 158o (;IRA 11s3)
(UURUS AND UURSIIIG)

KUZNETSOVAt A.F., maditainakaya sestra (Kolomna)
Work of the nurse In the infectious (intestinal) consulting room
of a polyclinic. Med,sestra no.6t5O-51 Je 162. (MIRA 15s8)
(NURSES AND NURSING)

KUZUETSOVA, A.F., meditsinskaya sestra
Conference of subprofessional medical personnel of Moscow and
Moscow Province. Med.sestra 21 no.8:55-57.Ag 162. (MIRA 15:9)
(MOSCOW PROVINCE-MEDICAL PERSONNEL) (NERSES AND NURSINC)

V-
170)
AUTHORS: Yevreinova, T. N. SOV/20-124-3-56/67
TITLEs Weight Determination of Isolated Coacervate Drops by Means of
Interference Microscopy (Opredeleniye vasa otdellnykh koatservat-
nykh kapell a pomoshohlyu interferenaionnoy mikroskopii)
RERIODICAL: Doklady Akademii nauk SSSR, 19591 Vol 1249 Nr 3, pp 688-690 (USSR)
ABSTRACT: The phenomenon of coacervation is wide-8pread in organisms and can
also be reproduced in artificial objects (Refs 4,6). In the latter
case, a concentration of the colloidal particles from dilute so-
lutions takes place, the particles separating from the liquid in
the form of drops or of a layer. Consequently, the nature of
coacervation-conaists in the transition of a dissolved, diffusely
spread substance into more solid formations that have new, specific
properties (Ref 2). In this process, the concentration of the sub-
stances reaches considerable dimensions* As, eog., the concentration
of the nucleic acids in individual drops was fifteen times as high
as that of the nucleic acids in the solution, it was possible to
determine these acids in individual coacervate drops by means of
an ultraviolet microscope. However, there are many compounds which,
unlike nucleic acids, do not absorb the ultraviolet rays, but which
Card i/3 readily form coacervate drops (proteins, carbohydrates, lipides).

SOV/20-124-3-56/67
Weight Determination of Isolated Coacervate Drops by Means of Interference
Microscopy
Scientific publications do not contain any data on the concentra-
tion degrees of these substances in individual coacervate drops.
In the paper under consideration, the concentrations of protein
and carbohydrate were determined by -the aid of interference
microscopy. For this purpose, (a) a bifocal interference microscope,
and (b) a Shiring microscope were used. The coacervate drops (9 -
177jL diameter) were obtained separately from aqueous gelatins and
gum arabio solutions (Fig 3)9 as well as by the addition of ribo-
nucleio acid (Figs 4,2) and desoxyribonucleic acid (Figs 4,3)-
From an analysis of the curves in figures 3 and 4 it can W neen
that_(1) the dry weight of the drop increases with increasing volume.
The concentration of the dry substances, calculated per volume unitq
decreaBes (Table 1). In coacervate drops which contain ribonucleic
acid and sodium acetate in addition to gum arabic and gelatins, the
dry weight increases by the 55-fold witt a volume increase by the
141-foldt whereas the concentration recedes to the 1:2-5-fold. The
same applies to drops containing desoxyribonucleic acid instead of
ribonuoleic acid. (2) The concentrations of gum arabic and of gela-
tine in individual coacervate drops is 12-47 times higher than in
Card 2/3 the initial solutions. The highest concentration of the 5 above

SOV/20-124-3-56/67
weight Determination of Isolated Coacervate Drops by Means of Interference
Microscopy
mentions d substances was observed in the smallest drops, which also
showed greater density than the large drops. The small drops are
characterized by'a linear dependence between the volume of the drop,
its weight, and the concentration of dry aubstance therein.
(3) In one and the same coacervate, consisting of drops and a li4dd
in equilibrium, drops of most different weights and volumes occur.
Their weights may equal those of certain unicellular organisms.
Pmfessork.l.Zakharlyevskiy assisted in the investigations, A. I.
Oparin, Academician, conducted the work.- There are 4 figures,
1 table, and 8 reierences, 4 of which are Soviet.
ASSOCIATIONs Moskovskiy gosudarstvennyy univeraitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
PRESENTEDs August 169 1956, by A. I. Oparin, Academician
SUBMITTED: July 7P 1958
Pard 3/3

BRODSKIT# Velasi
Interference microscopy of ganglionic cons during various functional
states of the retinaa TSitologiia 3 no. 1:89-91 Ja~F 161.
(MIRA 14:2)
1, Inotitut morfologii, shivotnykh AN SSSRj Moskva i Gosudaretvmmyy
opti'afts3dy instituto Leningrad, - 0
(RETINA) (CEL18) (MICROSCOPY)

ZAKHARIYEVSKIY, A.N.; KTjZNETSOVAj A.F.
Biological interference mi6roscopes. TSitologiia 3 no. 2.-21,3-224
Mr-Ap 161, (MIRA 14:4)
1. Gooudarstvonnyy optichookiy institutp Leningrad.
. (MICROSCOPE)

ZAKHAR'YE;VSKIY, A.N.; KUZNETSOVA A.F.
Uoe of interforence,microneopen in biology. TSitologila 3 no.31
245-253 M.V-Je 16.1. (MIA 14:6)
1. Gooudarotvennyy opticheskiy institut, Leningrad.
(INTERFEROMETRY) (MICROSCOPY)
IV

KUZNETSOVA, A.F.
Awlication of interference microocopy to eoacervates. Biofisika
6'n'o.3.s2S8-293 161. C (MIRA 14s6)
1, Mookovoki osuddrotvennyy univereitet imoni M.V.Lomononova.
WGROSCOPY) (COACERVATES)

IYEWEINOVA, T.'!,; ?I,!l'll,:TSr)VAf A.F.
flistone-protamIne - nucloic coa~virvtLi.-3 drops. Bi,,)f ii!ika F 1,,,-).3:
395-398 163. (!-"! j.7. I) )
1. Blologo-pochvennyy faleulltpt 1'1()SkO7SkOgO gO:3G:lFf!;tvb.,inrgL; ,ail-
versiteta Imeni Lomonoso7a,

L 3558*-a EWT(1)/9EG(k)-2/FCS(k)/EV1A(h) WR
ACCESSION NRt AP5024414 UR/0286/65/000/015/0095/0095
AUTHORSs Zakharlyevokiys A. N.1 Kuznetsovae A. Fe
TITLEt Hicrointerferometerp Class h2p Not 173454
SOURGEt Byulleten' isobrateniy i tovarnykh Snakov, no* 15, 1965, 95
TOPIC TAOSt interferometer P/
ABSTRAM This Author Cortifioste-presents a microinterferometer according to-
Aqthor Certificate No. 80251, To utilize it as a microprofilometer, the inter-
fe.romete,r plates differ in thickness. A slit diaphragm is mounted in the forward
focal plane of the ocular (see Fig. 1 on the Enclosure). A direct vision spectral
prism and a readout device are placed behind the ocular. The readout device iss
for examples in the form of a luminous readout index projected on the spectral
prism. The index in put into the field of viev by rotating the apoetral. prism
using a micrometer screw with a readout drum, Orig, art, hast 1 diagrams
ASSOCIATIONt none
SUBIRTTED i MaY64 ENGLs M SUB GCD31 OP
NO-REF.SOVt 000 OTHER 1 000
Card 1/2

ENDOSURSt 01
Fig, 1, 1- interferometer plateBj 2- ocularl
3- BIA diaphragmi 4- direct vision spectral
prienj 5- micrometer screwl 6- readout drum
carj 2/2 . ..... . -
A 4
~T,

KUZIRINYKH, I.M.. professor.; SLOTTIMIT, N.P.; NUMMOVA, A.G.
Obtaining sulf its said from crushecl limestone. Bma6prou.30
no.4:5-8 Ap 155. (MLPA 8:6 )
1. Noskovskiy khimiko-tethicloglobeskiy Institut insmil D,I.
Mendeleyeve, i Koskonkiy filial Untrallsogo nauchno-issle-
dovatellskogo instituta bumagi,
I (Sulfites)

I
= IKINM. I.N., professor; RMSEaRk, M.D.; BAIKABOY, To.Ta.; KWIVIS, I*N,;
~TSOVAP- A.G,; BRARAPOU, Z.1.
- lw*Mu*A
Testing an enlarged bubbler installation for the produotion of
sulfite Ilqw. Bmaprom-31 U0.3S11-13 Mr 156. (KMA 937)
1.0okollskiy toollyuloxne-bumashnyy kombinat i Hookovskiy filial
TBeitrallnego wmahno-issledovatallskogo inotItuta bmagis
(Sulfite liquor)

KUZNFT,90VA, A.G., Cand Tech Sci -- (dise) it 1A^4
absorption of oni rand pyridine bases from
coke gas on f vy-X444er platez." Mos, 1958
11 pp (Min of Higher Ldication USSR. Mos Order of
Lenin Chem Tech Inst im D.I. Wendeleyev) 150 copies
(n, 5o-58, 125)
69 -
4,

_7777777~~
BOV/156-58-4-46/49
iUTHORS: Kuzlm'Lnykh, I* No, (Deceased), Kuznetsovaj A. Go
TITLE: New Production Scheme of Ammonium Sulfate in Chemical Coking
Plants (Novaya skhema poluoheniya sullfata ammoniya na
koksokhimicheskikh zwrodakh)
PERIODICAL: Nauchnyye doklady vysahey ahkoly. Khimiya i khimichaskaya
tekhnologiyal 19581 Nr 49 PP 799w803 (USSR)
ABSTRACT: The method is based on a simultaneous adsorption of ammonia
and pyridine on procaoeing coke-oven gases and on the sub-
sequent transition into ammonium sulfate and pyridine bases
The formation scheme is indioated in figure 2. In order to
prevent crystallization of the ammonium sulfate in the absorbent.,
"hei added solution must be unsaturated with a concentration not
exceeding 40% of ammonium sulfate. The uncombined sulfuric acid
in the solution must be of I-lo5%. The crystallization of the
ammonium sulfate from these solutions is carried out in the
vacuum crystallizer. On this occasion ammonium sulfate
crystallizes to large crystals. The pyridine base is separated
from the mother liquid. The large-crystal ammonium sulfate is
Card 112 pure and an additional drying is not required,

SOV/156-58-4-48/49
New Production Scheme of Ammonium Sulfate In Chemical Coking Plants
There are 2 figures# 1 tablep and 8 references, 3 of which
are Soviets
ASSOCIATION: Kafedra takhnologii minerallnykh kialot i soley Moakovekogo
khimiko-tekhnologicheakogo institute im. D. I. Mendeleyeva
(Chair of Technology for Mineral Acids and Salts at the
Moscow Institute of Chemical Technology imeni D. 1. Mendeleyev)
SUBMITTED: March 27, 1958
Card 2/2

AUTHONSt Semenov, Yv. N., Zhinkin, D. Ya., 32-2-26/6o
lluznctsova, A. G. , Kollorkin, R. G.
TITLE: Short Reports (Korotkiye soobshcheniya).
PERIODICALt Zavodshaya Laboratoriya, 1958, Vol. 24, 11r 2, pp. 192-192
(USSR).
ABSTRACT: A method operating with a magnetic scales for the dotorminat-
ion of the density of motal-coranic forromaGnetic products is
applied 'by Yu.N. Semenov (Polytechnical Institute imeni A.A.
Zhdanov, Gorlkiy). The tear-off force of a permanent magnet
is directly proportional to the density of the material. The
duration of examination is similar to that accordine to the
graviLictric mothod.Danod on experimental results D.Ya. Zhinkin
and A.G, Kuznetsova proposed a modification of the method
accordinC to rOCT 6909-54 for lacquers and paints, published
by the lacquer and paint industry. An infrared lamp should be
employed for the dot;..rnination of the dry residue ofq~orcanic
silicon insulation lacquers, because by this means the dur-
ation of analysis is much reduced. R.G. FW1d=k1n (Polytechni-
cal Institute imeni A.A. Zildanov, Gorlkiy) determined the
Card 1/2 cross-ocotions of bodies with a complicated shape by means

Ohort Roporta. 32-2-26/60
of displacement of liquid.
1,1330CIMOH: Gorlkiy Politeabnie 7matitate Ameni A. A. Zbd=m (GorlkavwW4
PoUtekbnlaheskiy Institut im. A. A. Zhdancrm)
AVAILABLE: Library of Coneress
1. Scientific reports-USSR
Card 2/2

hUMMOVA, A* 0.
A. G. Kuznetsovaj K. A. Andrianov and D. Ya. Zhinkin, The basic Reaction
0-
J.or Obtaining Polyorganosilicoxane Resins."
Report presented at the Second A1.1-Union Conferonce on t~e Chemistry and
Practical Application of Silicon-Organic Compounds held in Leningrad from
25-27 September 1959.
Zhurnal prikladnoy khImU. 1959, Nr 11 PP 23P.-2.40 (USSR)

SOV/68-59-6-10/25
AUTHORS: Kuzlminylch, I*N*~ Doctor of Technical Sciences ~Deceasedj %rA
-=netsoya I _L, U,
TITLE: The Use of Perforated Plates for the Absorption of
Ammonia and Pyridine (Primeneniye provallnykh sitchatykh
tarelok dlya. barbotazhnoy absorbtsii ammiaka i piridina)
PERIODICAL: Koks i Khimiyaj 19% Nr 6, PP 38-43 (USSR)
ABSTRACT: In order to obtain data for designing absorption columns
with perforated plates a study of a number of factors on
the absorption of ammonia and pyridine separately and
simultaneously has een made on a laboratory installation
(shown in Fig 2). t artificial gaseous mixture similar
to coke oven gas in respect of concentrations of ammonia
and pyridine was used for the experiments. The
experimental results were evaluated on the basis of
analyses of the gaseous and liquid phases. The influence
of the following factors was tested: the influence of
partial pressure of ammonia and pyridine in gas (Fig 3);
the influence ot acidity of the starting solution on the
degree of absorption of ammonia and pyridine (Fig 1~)i
Card 1/1+ the influence of the concentration of ammonium sulphate
in the absorption solution on the degree of absorption

sov/68-59-6-10/2,5
The Use of Perforated Plates for the Absorption of Ammonia and
Pyridine
or ammonia and pyridine and on the hydraulic resistance
of the plate (Fig 5); the Influence of the concentration
of pyridine sulphate in solution on the degree of
absorption of.pyridine (Fig 6); the influence of
temperature on the degree of absorption of ammonia and
pyridine (Fig 7); the influence of the density of
spraying on the degree of absorption of ammonia (Fig 8);
the influence of gas velocity in the column on the degree
of absorption of ammonia and pyridine and on the
hydraulic resistance of the plate (Fig 9); the influence
of the perforated cross-sectional area of the plate on
the degree of absorption of ammonia and on the hydraulic
resistance of the plate (Fig 10); the influence of the
composition of the final solution on the absorption of
pyridine on one, and three and five plates (Fig 11)
with five plates the final acidity of the solution
should be not lower than 1.5% of sulphuric acid.
On the basis of the results obtained a scheme for the
Card 2/4 removal of ammonia (as ammonium sulphate) and pyridine
from coke oven gas Is proposed (Fig 12). After cooling

SOV/68-59-6-10/25
The Use of Perforated Plates for the Absorption of Ammonia and
Pyridine
in primary condensers, the gas is passed into the bottom
of an absorption column with five perforated plates
(perforated area 24.7%). A solution containing ammonium
and pyridine sulphates and free sulphuric acid is
supplied to the top of the absorption column from a
mixer. In order to avoid crystallization of ammonium
sulphate in the absorber, the solution leaving it should
not be saturated with ammonium sulphate and should
contain 1.5% of free sulphuric acid. Under these
conditions 99.9% ammonia and 95% pyridine absorption
takes place. Ammonium sulphato is crystallized out in
a vacuo-crystallizer and a part of the mother liquid
after the separation of sulphate crystals is directed to
the pyridine installation while the remaining part is
returned to the mixer to be returned for absorption.
The depyridinized liquor is also returned to the mixer.
It was calculated that one absorber 3.1 m high and 1.2 m
in diameter is sufficient to remove ammonia and pyridine
Card 3/4 bases from coke oven gas of two batteries. The volume
of the absorber 90 and its resistance 115mm H20. For

SOV/68-59-6-10/25
The Use of Perforated Plates for the Absorption of Ammonia and
Pyridine
the same cgpacity the volume of the usual saturator
equals about 35m3 and its resistance is about
600mm H20.
Card 1+/)+ There are 12 figures, 1 table and 5 references, 3 of
which are Soviet and 2 English.
ASSOCIATION: Moskovskiy khiTaiko-tekhnologicheskiy institut imeni
D.I. Mendeleyeva (Moscow Institute of Chemical
Technology imeni D.I. Mendeleyev)

AU UN" 113: Andrianov, M. A. , ;,*,hinkin, D. TP.. , 3011/7 9 - 2 9 - 5 - 22/7
Ku,,.notuova, A. 0.
T IT L Ott the Cimon Hydrolyais of Diothyl-dichloro-silsne and
Phonyl-trichloro-silane (0 aov%az-'Qno;,i g1drolizo
-~IetilOikhlorsil,ina I faniltrikhlorsilpnp.)
1,E,H10DICALs Mitirnal obshchey khimii, 1959, Vol 29, fir 5, i-,, 1504-15C7
A "TiZAC,: In the the rasulto obt,,ined in the raui:-cn
yl-dichloro-ail tuan
hydrolysis of equipolar mixturen o-~ dietlr
vnd. phenyl-trichloro-silpna are discussed. The renction
process awi proceed In t-ao conourront directiono, In ono v,sa
P. of poly--ir-ric prod,ict!j of the hydroly3is which t:~olk,
- -,lace 3ep~-ratol.,, in formed - of poly6istYo.rl silo%-nn-,
pol,yphenyl-ailox.n.n,as. Tn the aeoond case prodt;cts oi' the
co-hydrolyal-9 are formed - the polyethyl-i)henyl-z;ilo:c.,izic.-,.
In order to determine the direction of the courae of re--ctior,
the product3 of the co-hydrolynis of the abovo-menti:;ned
tnono-iern ware inventigatedl. To be able to interpret the resultz.
obt,f.inad, the data determined in the analysis were compared
witli the values calciAlated fcr the individual P0lyMCr3

On the Comi,ion Hydrolyn1r; rX Diothyl-dich loro-st lane SOY/'19-29-5-22/75
?,rid
(Table 1 Cn Vie determinption. of the ~ie,-n ;-,iolecular w,2tf7ht0
of frnations of the co-hydrolysto productq tho nolecijl,,-r
wolgmhts anti Vie (lisporsit.- of thene product3 -x-irc found to
6enend on Vie 3olvent used (Fij). The products obtnined on
tile co-hydroly3in of diethyl-dichloro-rliane nrid ~*henyl-
trichloro---11,,ne rit'i craosi wnter waro inveltigated. it -Iry
be Btntad fro,,,l the results obtained th?it the composition of
tho resulting !)olrners cnn 'he exDre3sed by the formula
C H I Sio(c." C if ) Sioc IT LjiO
2 5)2"'0C")"5 2 5 2 6 3~ I .5]n
%,.i + n) - degree o:F nolyrtarlz:~tion, (m : n) - the ratio of
r
Tjol,ydiethyl-lihe*i-,~l-h~,dro,/.~,- rnd polydiethyl-plienyl.
The mean values cf t~Ies~. coo-fficienta are given in table 2.
As can be seen the influence of th~ solvent does not only
concern the diaparaity of thv -.,olyi~cric mixture and tho rle_-:-ea
of pol,,-.aerizntion but altio tlis qu;,ntity of the hydrox,,d-
containin6 compounds occurrin.1 in the hydrolysis products.
Tho ~aaximum content of Ir.,droxyl r~roup:i is foun-i in the
;,ydrolynia oroductr; in athee, Vic -,iini!,x-i in laenzerie. 'ji-erp
I,. M
Cr-rd 2/3 are 1 figure', 2 tpbler,, and I Soviit roferencos.

87923 S/191/60/000/004/004/015
BO16fBO58
AUTHORSs Zhinkin, D. Yaop Kuznetsova, An Gat Chinenova, M. A.
TITLE: Study of the Composition of Ethoxy-phenyl Silanes Obtained
by Phenylation of the Ethyl Eater of o-Silicic Acid
PERIODICALs Plasticheskiye massyt 1960, No. 4, pp. 13-15
TEXTs The authors report on their study of the composition of ethoxy-
phenyl silanes formed under various conditions by phenylation cf the ethyl
ester of'o-silicic acid. Special attention was devoted to various
quantitative ratios of the phenyl-magnesium halide used to the ester
mentioned.'Sinoe a mixture of products with different degrees of sub-
stitution develops at various quantitative ratios the authors undertook
the one-stage phenylation of the ester by means of chloro benzene# in the
presence of magnesium at ester-to-magnesium ratios of I s 1, 1 1 1.5, and
I 1 2. The resulting products are tabulateds ethyl ester of o-silicia acid
(not reacted rest)t 57-8 - 24.6 mole %; triethoxy-phenyl silanel 11.2-18.0%;
diethoxy-diphenyl silanet 16.9 - 37-7%; and ethoxy-triphenyl silanel
14-1 - 19.7%. The authors conclude from these data that the phenylated
Card 1/2

87923
Study of the Composition of Ethoxy-phenyl S/191/60/000/004/004/015
Silanes Obtained by Phenylation of the B016/B058
Ester of o-Silicic Acid
ethoxy silanee are formed at different rates. Moreover, they are of the
opinion that the ester used and diethoxy-diphenyl silane, which have
symmetric molecules, are more stable in phenylation than the other
products (Ref. 1). They describe the synthesis and separation of the re-
action products, as well as their hydrolysis by means of a 10% HCl
solution in the presence of sulfuric ether. Among the hydrolysis products
were solid crystals of diphenyl-dihydroxy silane. The authors finally
determined the silicon content in the products. A paper by A. V. Topchiyev
and N. S. Nametkin (Ref. 2) is mentioned. There are 2 tables and
4 references, 3 Soviet and I British.
Card 2/2

8743h
3/191/60/000/010/006/017
B004/BO6O
AUTHORS: Kuznetsova, A. G., Andrianov~ K. A., Zhinkin, D. Ya.
%&WAWA,Niffi~
TITLE: Production and Properties of Some Organohydroxy Silanes
PERIODICAL: Plasticheakiye massy, 1960, No..10, pp. 16-19
TEXT: The authors wanted'to define the conditions relative to the
production of dimethyl dihydroxy silane and to determine the solubility
of dimethyl dihydroxy silane, diethyl dihydroxy silane, and phenyl
trihydroxy silane in different solvents. Moreover, they wanted to study
their condensation in the presence of HG1. The reactions took place in
vessels rendered water-repellent by means of the rK~(-94 (GKZh-94)
organosilicon liquid. The synthesis of dihydroxy silanes proceeded from
dimethyl dimethoxy-f dimethyl diethoxy-, and phenyl trimethoxy silane,
respectively, which were obtained by reaction of the corresponding chloro
compounds with the corresponding alcohol in the presence of yridine.
The following processes are described. 1) 40 g (CH 3)2si(OCH X were
allowed to react at room temperature with 24 9 of distilled water, the
Card 1/3

8743h
Production and Properties of Some S/19 60/000/oio/OO6/017
Organohydroxy Silanes B004XBo6o
solvents (alcohol and water) were distilled off at 3-10 mm Hg, and the
crystals were washed with benzene, heptane, or petroleum ether. Yield
70-75~. 2) 44 9 of (C2 H5)2 Si(OC2 H5)2 were allowed to react with 18 g
of 0-5% acetic acid. The liquid turned homogeneous after 5-7 days, and
was then treated as described under 1). 3) 99 g of c6 H5Si(OCH 3)3 were
allowed to react with 50 9 of 0.5% acetic acid, temperature being kept at
5-100C. The product was cooled down to -200C after 3-5 hours and filtered
off in vacuum. Condensation took place in dioxan in the presence of
0.0012t 0.012, or 0.046 N HC1. The dimethyl compound condensed in 0-5N
HCl to 80-85% within 15 min. The diethyl compound reacted more slowly,
but its condensation rose with an increase of the HCl concentration, The
same holds for the phenyl compound. Up to a yield of 40 the condensation
proceeded at a constant rate which depended on the concentration of HC1
only. It is believed that dimers are formed at this stage. The gradual
condensation was particularly well observable in the pheryl compound.
CyclIzation takes place above the 35% yield. Cyclic and linear polymers
with considerable OH group contents resultod, They were determined by
titration with Fischer's reagent. The following data for the solubility
Card 2/3

87434
Production and Properties of Some 5/191/60/000/010/006/017
Organohydroxy Silanee B004/BO60
at 20 0C are indicated (in ~)-
Solvent (CH 3)2S'(OH)2 (C2H5 )2 Si(OH)2 C 6H5Si(OH)3
Water 40.6 9.0 4.1
Ethanol 49.6 44.0 16.0
Ether 6.8 10.8 0.5
Acetone 28-4 29.0 11.6
Toluene 0.0 0.2 0.0
Dioxan 30.8 19.3 15.2
There are 3 figures, 1 table, and 20 references: 7 Soviet, 9 US, 2 Germaj,
and 2 Japanese.
Card 3/3

3/080/60/033,/04/20/045
AUTHORSt Kuztmiriykh, I.N., Kuznetaova, A.6.
TITLE: The Equilibrium Between Vapors and Acidic Solutions of Pyridine
Sulfate -
PERIODICALt Zhurnal prikladnoy khim:Li, 1960, Vol 33, Nr 4, pp, 865 - 870
TMt The pressure of pyridine vapors over solutions of pyridine sulfatel. co'n-
taining various amounts of ammonium sulfate and a small quantity of sulfuric acid has
been determined by experiment within the temperature range 30 - 550C, and an equation
for this purpose has been derived. A diagram of the laboratory installation Is given.
The solutions contained 5 - 35 g/1 pyridine sulfate (based an pyridine), 0 - 515 g/l
ammonium sulfate, 0.065 - 1.89% free sulfuric acid at temperatures of 30 - 550C. The
pressure equilibrium of pyridine vapors Increases with the temperature independently
of the composition of the solution. An increase in the acidity of the solution leads
to a decrease in the equilibrium pressure of the pyridine vapors. An increase In the
concentration of pyridine sulfate and ammonium sulfate causes an increase In pressure.
Independently of the ammonium content in the,solution and the temperatureP the acidity
of the solution affects the pressure of pyr1dine vapors in a power of 1.008 and the
Card 112

'S/0~0/60/633/94/20/045
The Equilibrium Between Pyridine Vapors,and Acidic Solutions of Pyridine Sulfate
concentration of pyridine sulfate in a power of 1.165. The greatest effect on the
vapor pressure is-due to the temperature. For solutions not containing ammonium sulfate
the index of the temperature effect is 4.16, and for solutions saturated with ammonium
sulfate - 6.83. Formulae for calculating the pressures of pyridine over solutions con-
taining 5 - 44 g/1 py-ridine, 0.2 - 2% free sulfuric sold without ammonium sulfate and
saturated with it were obtained.
There arei 05 graphs, I diagram, 1 table and 3 Soviet references.
ASSOCIATIONs Moskovskiy ordena Lenina khlmiko-tekhnologioheskly Institut.im. Mendeleyeva
(Moscow Chemical-Teohnologioal Institute imeni Mendeleyev, Bearer of the
Lenin Order.
SUBMITTED: November 3, 1958
Card 2/2

3/6 61/61/00 0/006/074 8/061
D202/D302
AUTHORS: Kuznetsova, A. G., Andrianov, K. A. and Zhinkin, D. Ya.
TITLE; On the co-hydrolysis of diethyldichlorosilane and phenyl-
trichlorosilane
SOjRCE: Khimiya i praktichaskoye primeneniye le.remneo.-ganicheskikh
soyedineniy; trudy konferentsii. no. 6: Do'Klady, diskus-
sii, resheniye. II Vses. konfer. po khimi JL pru;-t. prim.
kremneorg. soyeds, Len., 1958. Leningrad, Izd-vo AN 303SR,
19619 175-179
TEXT: A discussion on a previous report (no. 2, P. 33, this publi-
cation) in which the authors and P. V. Davydov (11,loscow), N. S. Lez-
nov (Moscow), N. N. Sokolov (VEI, Moscow) and A. V. KarlJn (VIiIISK,
Leningrad) took part. The role of solvents, especially 46-hat, of
ethyl-ether, in the co-hydrolysis process of t6 above-mentioned
compounds and the unfavorable effect of methyl-tric.-.lorozilane ad-
mixtures in dimethyldichlorosilane used in the process urere dis-
cussed.
Card 1/1

SURKOV, Ye.I.; I'kUZIIETSC)Vj*-, A.%; GORILOV, PS.
------------
Water buVole absorption of phenol vaporm from flue gases.
Trudy MIGM no.33:48-51 161. (IIIIRA 14:10)
Plate towers)
enols)
R

3RrAA
S/191/62/000/006/007/016
-S~ JD 0 B110/B138
AUTHORS: Kuznetsova, A. G., Andrianov, K. A., Zhinkin, D. Ya.
TITLE:
Investigation of the hydrolytic condensation of diethyl
dichlorosilane and phenyl trichloroeilane
PERIODICAL; Plasticheskiye masey, no. 6, 1962, 19-22
TEXT: The composition of hydrolytio condensation products of equimoleoular
quantities of diethyl diohlorosilane and phenyl trichlorosilane at
organochlorosilano/water ratios of 1 ; 1 : 2-5 and 1 1 1*25 was studie(L
The products formed are:
h%&03 + (n + ~IAO HO(RM)n1l + 2r&ICI
nR,,SiCl;'+. ~~110 (Raslo). + 2nlic'
nRSICI, + 2~1~0 , jkSi0(0H)jn + MiCl
nRSIC1, + 1,5n1i,O.t-- IRS10i.56 + 3410
Polyorganosiloxanes and non-reaotive diorganodichloroeilane are likewise
Card 1/4

S/191/62/000/006/007./ot6
Investigation of the ... B110/B138
formed at ratios of water to hydrolyzable Cl< 0.5': 1. The'composition of
the hydrolytic condensation products of dimethyl dichlorosilane, diphenyl
dichlorosilane, and methyl phenyl diohlorosilane was investigated in a
homogeneous solution with an insufficient quantity of water, The,ratio
of the components in the hydrolytic condensation of 5 moles/1 solutions of
phenyl trichlorosilane and diethyl dichlorosilane in dioxane (1. 1': 1#25)''
at 0-50C was calculated,by.
2(CS1 is)$SIC13 2CO I&SICI, + 21 ISO
-'C'(Ci"&)r5loSl(q"&)IC'+CIIQ'IbSlOSIC4[IICIS+411CI
Al A)ISIC12 + CGHS."ICIS + HSO --P.
QCI f,),SIOSiQ 160, + 21 ICI
Eight fractions containing 20.61-27.38~'- Si and 51.68-54-56~ C'were
separated in yields of 0.8-21 W119 by fractional distillation between 33 and
2200C. For the fractione between 74 and 1850C about 1C~4 1,3-diphenyl-1,
1,3-tetrachlorodisiloxane was presentp and in the high-boiling fractions
~Bi content, 22.0-22.04~*) the ratio of diethylailoxy groups to phenylailoxy,
groupa was ~JO.3 1. In the hydrolytic condensation of homogeneous i
solutions with an insufficient quantity of water, the hydrolysis of i
Card 2/4 ......

S/191/62/0 000/006/007/016
Investigation of the B1 10/B138
phenyl trichlorosilane occurs more rapidly than that of diethyl dichloro-
silane. Non-reactive diethyl dichlorosilane and copolymers with a high
content of phenylsiloxy groups are thus formed. In the hydrolytic
condensation of 6-5 M solutions of diethyl dichlorosilane and phenyl
trichlorosilane in dioxane (1 ; 1 : 2-5), at ^J250C, nine fractions were
obtained with a content.of polymer between 3.7 and 20.5~p of Si between
22.62 and 25.44%t and of OH between 1-56 and 3-03~f and with molecular
weights between 834 and 1215. This proves the formation of copolymers
with a variable ratio between diethylsiloxy and phenylailoxy groups# The i
absence of a continuous decrease of the molecular weights is due to the
varying solubility of the polymers, which depends not only on the
molecular weight but also on the chemical composition. The content of OR
groups indicates the presence of 0 6H5Sio 1-5 and C6H5(OH)Sio groups. For
the ratio I : 1 : 2-5 the condensation products are;
E(C2H H Sio SiO(OH)],, where x + y + z is the number
5)2S'03x IC6 5 t 0 ~y 106H5
of structural units in the copolymer moleculej-x . (y + a) is the ratio
of diethylailoxy to phenylsiloxy groups in the copolymer moleculej
z : y is the ratio of phenylailoxy to phonyl-(hydroxy)-ailoxy groups
Card 3/4

B/191/62/000/006/007/016,
Investigation of the 11110/11138
which determines the completeness of condensation. Maximum, minimum, and
average values are respectively: 11, 7, and 8-5 for x + y + z; 29 0-59.
and I for x : (y + z); and -, -, and 0-5 for z : y. The simultaneous
presence of diethyl dichloroailane and phenyl triohloroeilane and.an
insufficient amount of water in the first stage produce
C H Sicl + H 0 --11-C H Siol Polymerization may take,place,-
6 5 3 2 6 5 2(OH) + He"
as follows:
2CHS1a,(OH) ---. aAHSiOS1CJ1,r-1, + 11,0
WjSlatpli) + qislci, --. d,cf(,Siosiqiq, 4: Ha.'
qVICII(OH) + (CS, ,4Sic,$
L1,C41iS1OSi(c%V1j)1C1 + HC1
The low concentration of ~Ujehyl dichlorosilane causes chiefly (9) and
(10), which explains the sence of diethylsiloxy groups in~the copolyme:
There are 3 tables.'
Card 4/4

KUZNEMOVA, A. Cl.j ANDRIANOV, K, Aq ZHINM, D. ra.
Hydrolytic condensation of dime tbylehlorosilane and pborql-
trich.lorosilans. P3Aat. massy no.21tl5-19 162.
(MIRA 16 t 1)
(5i3ane) (Condensation produote(Chomistry))

KUZMETSOVA, A.G.; IVANOV, V.I.
~feot of sulfuric acid on the product of cohvdrolysis of
trimeth.vlchlorosilane and methylpheny1dichloriisilane. Plast.massy
nol!blotl7-21 163. (MIRA l6t1O)

,ACCESSION NR: AP4028548
S/0191/64/000/004/002~/0029
AUTHOR: -Kuznetsova,-A!--q~.; Andrianov, K. A.; Zhinkin, D. Ya.
:TITLEi Formation of pojymers by the hydrolytic co-condensation of
Idiethyldichlorosilane (or dimethyldichloroallane) and phanyltrichloro-.
;silane
'SOURCE: Plasticheskiye massy*, no. 4, 1964, 27-29
'TOPIC TAGSt siloxane polymer, hydrolytic co condqnsation, diet~yl-
dichlorooilanco phanyltrichlorosilane, polydialkylphenylhydroxysiloxane.
~copolymer, polydialkylphanylailoxano copolymer, hydrolysis rate. re-
laction mechanism
'ABSTRACT: This work was conducted to explain the possible mechanism
,by which the polymers are formed during hydrolytic condensation of
equimolar mixtures of diethyldichlorosilan6 (1) or dimethyldichloro-
silane (11) and phenyltrichlorosilane (III). The chemical composition
(Si and OH content) and -molecular weight distribution of the polymers were
,obtained by reaction of equimolar amounts of I (or II) with III; of
.diethylsilanediol (IV) (or dimethylsilanediol M) with phenylsilanecriol
7(VI); and of IV with III. Regardless of the initial monowei, the producc
ic 13

ACCESSION'*NRi" AP4028548
.obtained was [R i0c H SiO(O11)] [R2SiOC 11 Sioljj~nt the copolymer
of polydLa'lkylpg'SMnyl9y3roxy- an2 ;olydialtyiphen -siloxanes. In the
various products the mtn ratio varied from 0.31
-to 0.73 and (m+n)
averaged 3-7. It is concluded that the poiymets resulting from the
hydrolytic co-condensation of the silanes are formed through a stage.,
in which the corresponding organosilanols are condensed or formed by
direct interaction of the organochlorosilane with the organosilanol.
the predominance of the reaction being,determined by the hydrolytic,
condensation conditions. No homopolymers were formed. In excess
water the product always contains an equimolar ratio of dialkyl- and
phenyl-siloxy groups. In insufficient water, when III is hydrolysed
first, the product does not contain a 1:1 ratio of dialkyl- and-phenyl
siloxy groups. Ono of the couaes for the formation of the copolymer
with the equimolar ratio during the hydrolytic condensation of I
(or II) with III or during condensation of tha silanals IV (or(V))
with VI is attributed to the difference in influence of the alkyl
and the phenyl radicals on the charges of the Si atoms in the original
monomer. The alkyl reduces the positive charge and the phenyl incroams
the positive charge, and interaction occurs between these monomers to
form the most stable system - copolymers with alternating monomer
units i~ the molecule. Orig. art. has: I table and 4 formulas.
Card 2

ACCESSION NR: AP4018057 3/0079/64/034/002/0598/0604
A
UTI sova
HOR: Kuznet A.-_Q.; Sobolevskiy, M. V.
TITLE: Research in the area of synthesis and conversion of unsatura-'
tad organosilicon compounds
,19. Reaction of the lotsich reagent of some.tertiary acetylene alco-
hols-wit1h chlormethyldimethylehlorsilane
.SOURCE-. Zhurnal ob~hchey khimii, v- 34, no#12,, 1964., 596-6o4
'TOPIC TAGS: lotsich reagent, unsaturated, organosilicon compound,
.synthesis, conversion, tertiary acetylene alcohol, chloromethyldi-
.methylehlorosilane, methylbutine, methylpentine, chloromethyldimeth-
:ylsilicone, trialkylchlorosilane
:ABSTRACT-. The reaction of the lotsich reagent (dimagnesiumdibromide-
~dimethylethynyloarbinol) with different trialkylohlorailanes was
;studied by 1. A. Shikhiyev (I. A. ;Shikhiyev, M. F4 Shostakovskiy,
~N. V. Komarov. Novy*e kislorodooderzhaohehiye kremniyorganicheakiye f~
soyedineniya; Azlorneftneshr, BA,Wj 71 (1960))- A method was
'Corrdl/3

iACCESSION NR: Ap4o18057
!developed for obtaining mono, di- and triatomic tertiary Y-silicon
:,containing acetylene alcohols. In studying the reaction of the
ilo-Usich reagent with chlormethyldimethyldhlorailane, it was
~established that the reaction proceeds in the direction of forming
;corresponding tertiary Y -silicon containing acetylene alcohols as
!follows:
C11, C1
C11 C113
BrRIgo-~-CAC-MgBr
110-~-CMC-L-CHSCI
113 &3
C113 Clis C113
.0 110-A-CIMC-611-CHSCI
'The presence or hydroxyl groups in the composition of alcohols was
!established by obtaining corresponding organooilloon acetylene acetal';'
!as follows:
Card2/3