SCIENTIFIC ABSTRACT KUZNETSOV, YE. S. - KUZNETSOV, YE. V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000928210017-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

.K=3TSOY,-Tevgedy Somenovich;- Prinimali uchaetiye: RYTCHBNKO, T.I.;
UVY, -T.P.; ZMff5_,D.A.; ZATATS, T.P.; MOPTEY, Y.T.,
P
LBITBRKANt S.Re; NOSff ~ L01g; -SWOLOT, O.Y.; TULUKOT, G.A.;
SHIBIN, P.Y., LIWAKOT, ?.I., red.; DONSK-ATA, G.1),, tekhn.red.
12fficient systema of maintenance and methods for their correction]
-Ratsionallnyo rexhimy takhnicheskogo, obeluzhiveniin i metodika ikh
korrakti;ovaniia. Koskya Avtotransizdat. Pt.2. (Second stage of
motor vehicle maintenancei Ttoroe takhnicheakoe obolushivanioe
1960. 98,pe (MMA 14:3)
(Motor vehicles--Maintenance and repair)

KUZNF,TBOY, Tevgeniy Somenovich; PUMINOT, Ivan Petrovich; PAPMI,
takhn. red.
(Sketches on traffic safety] Ocharki po bezopasnosti, dvizhanii.
Moskva, Goo. isd-vo "Fizkallture L sport." 1960. 135 P.
(MIRA 14:5)
(Traffio safety)

KMIMOTP UP-, kand.takhn.nauk; WROPTzv, Y., inzh.
Maintenance of motortruck brakee and clutches. Avt.transp. 38
--*.j,3tj5-22 7 160. (MIU 13:6)
(Notortruoks-Maintenance and ropqir)

iL-
----SHM~IBOK, Los inzh.
I - YUZNgTSOV,-fe.-,-ii-u~.ii~~.naukj
Efficient methods for wheel inspection and alignment. Avt,
tranap, 38 no. 5t18-19 160, (MIRA l4z2)
(Automobileo-Mintenance)

T yiq~; PLEKHANOV., I.P.p.red.; GORYACHKINAO
_MMSO ...Tqygqniy,,P~mepo
R#A*j tskh~i. red. '' 0 1
[Conditions of the maintenance of motor vehicles] Reshinq
tekhnicheskogo obalushivaniia avtomobilei. MoBkva, Avto-
transizdat, 1963. 246 p. (MIRA 160)
(Motor vehicles.-Maintenance and repair)

KUZNETSOV Ye.~Sjj kand. tekhn. naukj MWLUWKO, O.Y.., of.,
pr
ret: VIASOV, A.I., red.
(Maintenimce ;f motor vehioles) Tekbuicheskain"ekopluatatsiia
avtomobilei. Moskva* Roevwizdat, Noel. 1963, 60 p.
(KIRA 17: 4)

R~ TSOV,je.~,', kand.tekhn.nauk I
Some pro'spects of structural changes in automotive transportation
rolling stock. Avt.prom. 30 no.lsl9-22 Ja 164. (MIRA 17%3)
1. Hauchno-Issledovatell9kly Institut avtomobillnogo transports,

auomoui io induatry luor i -ax, t;uu .y -,-1- 14 ILI u

12,

SHL-- ~1--:mt-_-

Acc HRI-AP6025927- SOURCE-COD8v UK/0208/66/006/004/0769/0773--
AUTHOR "sod)
iORG: none,
-TITLR: A solution to the radiation transfer equation for a two disensional
:anisotropic dispersion
~SOURCE: Zhurnal vychislitellnoy mate W~tlki I matematicheskoy Miki, v@ 6, no. 4
~769-773
TOPIC TAGS: transfer equation, animotropic dispersion, optic property, iteratIOR'..'',
ABSTRACT: The author discusses the transfer equation for a two-dimensional layerl
of optical thicimess TA which has the form
ury
me--- INal NO) 44aWt4a) (0. 1 44e).
4x.
Here
is the optical thickness of a layer of height a computed from the lower boundary; and
Cord 1/2 UDCt 5174036924,

.ACC MRs AP6025927
a(z) and a(z) are coefficients of absorption and dispersion considered as arbitrary,:
functions of height z. The integral in Eq, (1) is extended to the surface of a
,sphere corresponding to direction W. The dispersion function y(c DID)-is xtand_~~
ardized in the usual way, i.d.,*so that
It is assume& that the boundary conditions have the form-
1(0' 0) 0 1 > 0), 'W, a) - 0 (0 0).
jf the boUndary conditions*of 6e problem are not zero they may be reduced by
ordinary substitution to the immediately preceding form, which will be reflected only
the free term f(T,D) of the 3q.(1). A program was composed for computer solutiow-,
of the final result by an iterative method using certain basic parameter values and
having its number of iterations dependent on -c*. Orig. arto'hasl~ 17 formulas.
boll"
SUB COM 12, .20/' SUBM DATZ: .14jan66/ ORIG RRt~
,cord 2/2

KUZNETSOV, Ye.q., kand..takhn. nauk
Mpthoda for datermining.the-pariodicity of Wntenancm and
the expediency of.compulsory rapair, Avt.-prom. 31 no.6s
10-14 is 165, (MIRA 181l0)
1. Nauchno-isaledovatellskiy Institut avtomobillnogo transports,

it Carbon on
:/The Influtnes c . im I
,the
IM-Mickel gaWri- , l'- 14, urup w." V Kiwail-Y
(VoklOdy Akadelftit AM& "Or"'WWOM.
[In Russian]. 'the inflitatice cir carbon on the FWAf.(ljfrUXIOn
of iron in R-Ni alloys %Ynii atall,*-11, wSing rnillonctive Vell, in
the tomperaturo rangen 800-1300, (". and 105(1~4330* (,~, for
alloys contnining 20% wid 2501 or niclicl rvpjwcjj%,vly. 1110
time or (liffunion lit%tilig wm Puell flint tbe cliffulviall jilyor
was 4M0 times tbicker thnn the vlociroplat,41 Inymr or mElio.
Jmrnal of the Iron and St(!cl Inst. active fron. The dvpviub,"co of Ihn roi-tricirrits of e4r.
diffusion of iron on ilip enrlion confecit of fbo lron-itirkni alloys
June 1954 are r%re*piited 1)), tho formulin: (1) For Hip)," "illialijilig 21)61
of file at
.0.0"p
6 fir
!and (2) for alloys iontaining 250.1 of nirkel
D 71-10 0 Rr
photo p to the carbon content in fit-". R a gas consituit. imil
:Tthotempemture(*K.)
in solid setut ions-PT Iron mid viiekel.

MA at inurgrifint" Kmiure of austenite an (t8 fell-diff1wou
of fract. V L (awm. E V Kuznci-, I ( V ......
(11"h" lbad Iia.A i(c.ii
c:wff ;It fif irt"I In 5(-h -w.'-Ing 14 M '4 'i
2o I t) i a no 0-69~"' C' Is the, %;ime A." ~ 11,oK) l"r 1" yi, 1- ;1
wcrc '1-0-1 it,"m C306, to. wal lk'lmo "', , I t)(H I
1h. 'ahw. lf~r thc lanif"Ars coolcd in lvjwd N --to F--t-
This i% -:rifwtI to, t lit, prv~,v v:,tl(,n.
affm N.. Wlum,ofjh-~ ,I to. U't'ujt'. "t
.:faiji l'fo"m!Ar'- .03, ","It

GRUZIN, P.L.,knnd.fis.-mat.nauk; XMNWSOV, Ye.Y.; XMTUMOV, G.V.,akademik
Effect of the intergranular structure of austanite on the self-
diffusion of iron. Probl. metalloved. I fis. met. no.4:494-497 155.
(Diffusion) (Iron alloys--Metallography) (MIRA 11:4)-
(Austenite)

Yo. V
k U-~ )qt-- Tr 0 v
Cntegory : USSR/Solid Stpto Thysics Diffusion. Sintering E-6
Abs Jour i Ref Zhur - Fizike, flo 3, 1957t No 6681
Author t Noskov, B.M.p Kuznetsov) Ye.V., Shcherbodinskiy, G.V.
Inst : Gor'kiy, 'USSR -
Title : Influence of Intragrenuler Soprration Boundrries on the
Coefficient of Self.-Diffusion of Iron in Iron-Nickel-Cerbon
Alloys.
Orig Fub : Fiz. motelloy,i retr1lovadoniyo, 19"l, 2, No 3, 4e9-493
Abstr-et : The coefficient of solf-diffusion of Iron Ir 2-3 tines
grectur In alloy sreciLranc thnt hvve boon subjected to
martensitic trunsforrintion end hnve boon egrin restorei to
austonito, then in spoci-ions thrt hrve not been subjected
to martonsitic trnnsforuntion. This is caused by the pro-
sense of treces of provicus nertersito bounderies, elonc.,
which intercrystellino diffucicn is more rapid. These
traces are eliminated grrdunlly as the tomporeture Incropses
during the time of hertinF. The energy of ectivption of the
procesz of ellminctinr the trrces is nerrly equol to the
retivation energy of the interarystc1line solf-diffusion.
Card 1/1
Ae~_NRi AP666,876
SOUKE CODE: UR/0190/65/007/012/2146/2149
AUTHORS: Kuznotaovt,ye* V.0 ullina, D. A. ; Layzq111i~1_ 1. 4. ; Prosolov;,~.,'T
payz
Avvakumova, N__,_ I
Of 4%-
ORG: Kazan' Chemico-Technical Institute 16, S. M, Kirov (Kazwwkiy khlaiko-
tekhnologicheakry WHEUE)
TITLE: Interaction of aromatic disulfochlorldes vith dimothylol-containing orgnno 3)
phosphorus compounds, 2nd commmication in the serien Phosphorus-containing poly-
aulphonates
SOURCEt V~mokomolekulyarMye so7odineniya,, v. 7# no. 12, 1965t 21464149
TOPIC TAGSt polpert poll, M01-1--il a phosphorus compound, organic sulfur
compound, sulfonic acid j) 6~:- .4""d iWCAJ4_
/ I .
ABSTRACTt This work vas performed to extend the proviowly, reported results of
Ye. V. Xuzaetoov, D. At Faysullinap and R. F. Tywikova (Vyookomolek. soyed., 7,
761, 1965) and particularly to Investigate the possibility of synthesizing linear
polysulphonates on the basis of aromatic dioulfochlorides and dimothyl-containing
phosphorus organic compounds, The following phospborus-containing polysulfonates
based on bin-metbylolphoeybinic acidl propyl-t isopropyl-i isobutyl-t dimethylol-
phos 11non an zone-,, ~hlorobenzene-, diphenyl-, naphthalinedioulfo-
-01
chloridoollwvr- esized. The reaotdons wre carried out either in the malt or
2/2 VDCs 541.64+678.86

L 1152o-66
ACC NRt
AP6Wl87O
in n-hoptane at 70-130G, Several pbysical properties, a,g,,, refractive index#
solubility# viscosity, etc. vere studiadg and the results were tabulated, It vas
found that polyoulfonatets derived from bia-wthylol-phosphinio sold hardened when
treated vith.diis Orig. art. hass 2 tables and 4 equations.
Omnatas.
SUB MEOW SUBM DAM 29Jan65/ ORM RZFs 0031

L 13222=66 EWT(z)/T/EWP(J) RM
.ACC NR*- AP6000330 SOURCE'-CODE-- UR/0286/65/000/021/0019/0019*
Kuznetsov, Ye. V. Favzulllna. D. A.; Fay~E ~11in Prasolova, 1. N
;7yurikova
,iORG'. none
JITLE: A method for producing RoliregifMates Ylich cofttAll) 16992borual class 120
No. 175964
;SOURCE: Byulleten' izobreteniy I tovarnykh znakov, no. 21, 1965, 19
TOPIC TAGS I polymer, organic phoophorus compound, sulfonation ,3uj. FOR eo,"ApOvi)
~ABSTRACT.- This Author's Certificate Introduces thod for producing polysulfo-
,nates which contain phosphorus. New Pqu-Mers1dalmduced by Interacting dIsul-foch-
';lorides with organophosphorlas compounds which contain hydroxyl radicals.
ISUB CODE: 07/ SUBM DATE.# 06Ju162/ ORIG REFs 000/ OTH REF: 000
jW

V
USSR/General Section Metrology. TAboratory Technique.
Abs Jour : Ref Zhur - Fizika) No 4, 1957) 8362
Author : Ye.V. Ku=etsov
Inst
Title : Scheme for Measuring Rapidly Varying Capacitances.
Orig Pub : Pribory i tech. eksperlmenta, 1956, No 1, 58-60-
A-6
Abstract : Description of a einsple one-tube circuit for measuring
rapidly-varying capacitances. The sensitivity of the
circuit is 1.8 ma/ue; the "c,wrent-capacitance" cha-
racteristic is practically linear. The circuit can
measure capacitances varying with a frequency from 0 to
100 -- 200 kc. The circuit is developpd for the control
of the operating conditions of the bubble chamber, but
can be also in the investigELti6n of working cycles in in-
ternal combustion engines, to study mechanical vibrations,
etc.
Card 1/1

JY
321STRUMENTATION: CHANAIEL ANALYZERS
"Twenty-Four-Channel Amplitude Analyzer Using Type LP-1 Electronic
Switch", by Ye-V. Kuznetsov,, P-Tribory i Tekhnika Eks2erimenta, No 2,
September-O(~_t_,Dber 1956, pp b2--M7.-
In the simple twenty-four-channel analyzer described in this article,
the vidth of the analyzer channels is stable, on the average, with an
accuracy of 2% of the width of the channel over a week; the stability
of the threshold is 0.3%. The speed of the analyzer is 40 pulses per
second per channel. Using supplementary counting circuits, the speed
can be :increased to 5 x 164 pulses per second for the entire analyzer.
Provision is made for narroving and widening the working range of the
analyzer and for shifting this range to various places of the investi-
gated spectrum. The analyzer is designed for positive and negative
pulses rangin(~ from 3 to 500 millivolts-
Card 1/1

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at a ilmdart how Wbikh was WoWed I _2
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52).-The metQ, ape., and intrtprttatica of expti.
M
I
relilts wed by Gellman C.A. 42. Mfg), are critsdiM.
The msix. miscibility beat fit the tcritafy sysietti IIM
:0,-Sol cortcjpoud% to the ewnpn. 311NOv.450, (11ite.
ID
todetris. by K. and Is equal to 137 cal. w C. of
mist. instead of Om 64 cal. as vmviou;fy- reported. fir,
Iftimt Lkbt%kW

6- --:A= - - JL 4 ir- --- ----
u 11 nL A

2o-6-20442_
AUTHORSs Gillm Kamay, Kuznetsov, Ye. V. , and Valetdinov, R. K.
TITLEt Cyan Substituted Dialkylphosphates (0 tsianzameshchennykh dial-
kilfoafitakh)
PERIODICAL: Doklady AF SSSR, 1957, Vol- 116, Ur 6, pp. 965 - 968 (USSR)
ABSTRACT: Hitherto the cyanic substituto3 of the other of the phosphorous
acid have not been dencribed. Because the introduction of the
cyanogen Group into th+olecule of the dialkylphonphite must strone-
ly modify its properties, the authors studied the interaction re-
action of equimolar quantities of some c?,-cyanhydrines with phou-
phorue-trichloride. Thereby it has been stated that this reaction
passes on formation of a mixture of products, and so of chloran-
hydrides of the Ot-cyanalkyl- and the di-ce, -cyanalkylphosphorous
acids as well as of tri-c4, -cyanalkylphosphites. A scheme of the
reactions following one another is mentioned. The latter compound
will not be changed into the second above-mentioned aiid, in spite
of difficult reaction conditions (high concentration of the re-
a6enta), although the here known rerrouping of Arbuzov could be
expected. By the aid of manifold fractioned destillations altoeath-
er 21 IX-cyanogen substituted phosphites ard their chloranhydrides
Card 1/4 have boon isolated from the mixture of reactions (table 1). They

Cyan Substituted Dialkylphosphates , 20-6-20/42
are achromatic liquids fuming in the moist air. Purthe.,:,lore, the
saponification 7~eaotion of the chloranhydridca of the di-o(.,-cyan-
alkylphosphorcue acid has been studied under different conditions.
With an exactly measured qu&ntity of water in the etheric medium
and at the presence of pyridine, this reaction leads to the for-
mation of acid cyanogen substituted ethers of the phosphorous
acid. Table 2 shows 6 of those compounds including their proper-
ties. The isolated di-CK,-cyanogen alkylphosphorous acids are
achromatic liquids with a weak smell. They retain as derivatives
of the trivalent phosphor us in difference to the not cyanogen
substituted acids. Since more than a half century Arbuzov has drawn
the conclusion that all mean ethers of the phosphorous acid are
built up on the base of the trivalent phosphorus, meanwhile the
acid itself and its acid ethers contain a pentavalent phosphorus.
Already at that time Arbuzov expressed the conception about a
possible existence of the phosphorous acid and its acid ethers as
tautomeric format V III
R> P P ... on
R H RO
Card 2/4

20.6-20/42
Cyan Substituted Dialkylphosphates
According to Arbuzov the structure I has the free form of the acid,
In solutions it may be existing in the tautomeric form. These
conclusions have been brightly confirmed by the recent physical-
chomioal investigations (rof, 4 - 6). At the phoophites mentioned
the tautomerio equilibirium seems to be removed in the direction of
the trivalent phosphorus* Therefore the position of the equilibri-
um of the acid ethers is also dependent on the quality of the ra-
dioals (ref- 7)- Furthermore, it has been stated by the authors
that the di-9t.-cyanogen-containing radicals also show properties
of the mixed others of the phosphorous acid. By the influence of
heating-up the hydroxyl group within them is exchanged intermole-
oularly by a corresponding radical. But, In the case of the di-O(- -
-oyanisopropylphosphorous acid containing a teitLary radical, this
practically will not be so. There are 2 tables, 7 Slavic references.
Card 3/4

20-6-20/42
Cyan Substituted Dialkylphosphates
ASSOCIATIONt NAw I -, rWj*wW p~f ~ftvdoA j.*oWj*gy!-LM % B.. Mi. - Kirov
(Kazanakiy khimiko-tekhnologicheskiy inatitut im. S. M. Kirova)
PRESFXTEDs June 6, 1957, by B. A. Arbuzbvl Academician
SUBMITTEDs June 3v 1957
AVAILABLEt Library of Congress
Card 4/4

BOV/120-59-1-33/50
AUTHORS:Kuznetsov, Ye. V., Timoshin, I. Ya.
TITILE: The Use of Carbon Dioxide Ps the Working Liquid in a Bubble
Chamber (Ispoltzovaniye uglekisloty v kachestve rabochey
zhidkosti dlya puzvrlkovoy kamery)
PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 1, P 132 (USSR)
ABSTRACT: In some cases, for example, in experiments connected with
the theory of isotopic spin, exDeriments on the determination
of the parity of particles, as well as in experiments with
polarized particles, carbon dioxide is very useful as the
working liquid in aAubbleoigamber since the spins and the
isotopic spins of C and are zero -while their masses
are not very different. In this respect a carbon dioxide
chamber is analogous to a helium chamber. The present authors
have investigated the possibility of using such a chamber. The
volume of the chamber was 2.r- litres. The compression time was
,0
a x 10-3 see and the decompression time was equal to it. It
turned out that the chamber was sensitive to ionising radiat-
ions for saturated vapour pressures in the interval 37.5--48.5
atm which corresponds to the temperature interval. 3.5-13-50C.
At 13.5 OC the limiting pressure was 36 atm. It must-, be noted
Card 1/2 that carbon dioxide dissolves in plexiglass and rubber. This

SOV/120-59-1-33/50
The Use of Carbon Dioxide as the Working Liquid in a Bubble Chamber
is not important during the actual working of the chamber but
leads to difficulties after the working liquid has been re-
moved from the chamber and the latter cannot be used again.
If for some reason the working liquid has to be removed from
the chamber then the windows must be made from ordinary glass
and polyethylene. There are no figures or references.
SUBMITTED: January 25, 1958.
Card 2/2

KUZNMOV, Ye.V.; BOGDANOVt A.?.
Reactivity of nitrophthalyl chlorides, Report Nool: Synthesis
of 3- and 4pnitrophthalyl chlorides. Trudy KKHTI no,26.*73-77
159* (HIM 1585)
(Phthalic acid)

-- KUZNEIIBGV., Xe.V.; BOODANOV8 A*?*
Reactivity of nitrophthalyl chlorides. Report No.2: Interaction
of 4P-nitrophthalyl obloriden with saturated monoatomic alcohols.
Tnidy KKHTI no.26t7S-87 159. (MIRA 15:5)
(Phthial4a acid) (Alcohols)

PZNETSOV, Te.V.; BOGDANGVP A*F*; DIVOUNI S.M,
Reactivity of nitrophthalyl chlorides. Report Soj: Synthesis
of fully substituted alkyl-its-nitrophthalatess Trudy KKHTI
no.2618"2 159. (MM 1595)
(Phthalto acid)

AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/3
Kuznetsov, Ye. V.0 Valetdinovp R. K. SOV/79-29-1-49/74
On the Reaction of a,y-Diohlorohydrin of Glycerin With FC1
Poci3 and PSC13 (0 vzaimodeystvii aol-dikhlorgidrina glit-3
serina o PCIY Foci 3 1 PSC1 3)
Zhurnal obahchey khimii, 1959, Vol 29, Nr 1,
pp 235 - 238 (USSR)
In continuation of the papers by Kabachnikov (Ref 1) and
other chemisfe (Refs 2-5) the authors found that glycerin-
a,y-dichlorohydrin reacts with Pcl (1!1) under formation
of a mixture of products the constants of which are given
by the table. The former two, the chloranhydrides of bis-
P,01-dichloro isopropyl- and 0,01-dichloro phosphoric acid
are heavy fluids fuming in the air. The third is a viscous,
colorless and non-smelling oil and does not react with CuC1
and phenyl azide. The transformation of the compound of tri-
valent phosphorus into the compounds of pentavalent-phospho-
rue probably proceeds according to the scheme one suggested

On the Reaction of a,y-Dichlorohydrin of Glycerin With
PC1 3' POC13 and PSC13
Card 2/3
SOV/79-29-1-49/74
by Kabachnikov with respect to tris-p-chloro-ethyl phosphite
(Ref 2). in the case of saponification of chloranhydride
of bia-Pfol-d1ohloro-isopropyl phosphoric acid with water
in ether solution, in connection with the binding of chloro
hydrogen to pyridine, the corresponding acid was 1~he result
(boiling point 145-)4t0 at 0.4 mm). In the case of reaction
of a,y-dichloidWdrin of glycerin .with pbosphoroxy chloride a
mixture of products is formed: the chloranhydride of P,01-
dichloro isopropyl phosphoric acid (ClCE2)2CHOPOC'21 the
chloranhydride of bts6-0,pl-dichloro-isopropyl phosphoric acid
L(CICH2)2CH012POCI-and the tris-P,pl-dichloro-isopropyl
phosphatec(CiCH 2)2CHO~3 PO. The first of the three chloran-
hydridea has hitherto been unk4own (constants in the experi-
mental part). Tria-ptpl-dichlor'o-isopropyl phosphate, as
already earlier synthesized by Jones could not be preserved
in pure stat( by the authors. Thea,y-dichlorohydrin of
glycerin reat-ts with phosphorus sulfochloride less easily
than with PCI 3 or P001 30 only in the case of boiling of the

On the Reaction of a,y-Dichlorohydrin of Glycerin With SOV/79-29-1-49/74
Pol V POC13 and PSC13
reaction mass, In this connection it was impossible to
preserve certain reaction products. There are 1 table and
5 referencest 2 of which are Soviet.
ASSOCIATION: Kazanskiy khimiko-takhnologicheakiy institut imeni S. hl.
Kirova (Xazan~ Chemotechnological Institute imeni S. M. Kirov)
SUBMMITED: October 28, 1957
Card 3/3

5 (3)
AUTHORS: Kuznetsov, Ye. V., Valetdinov, R. K. BOY/79-29-6-53/72
TITLE: Synthesis of the Triallyl Phosphate (Sintez triallilfoofata)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Ur 6, pp 2017 - 2018
(USSR)
ABSTRACT: The synthesis of the triallyl phosphate from allyl, alcohol and
phos.phorus oxychloride (Ref 2) has been described in publica-
tions. The reaction takes place in a solution of toluene in
0
presence of pyridine at a temperature of -35 * It is pointed
out that the distillation which takes place therebyp proceeds
-under decomposition of the reacting substances, and often leads
to an explosion. It seems to be difficult to obtain a suffici-
ent quantity of a pure product in this way. Only the boiling
temperature at a pressure of 0.5 mm; is mentioned. The authors
worked out a new synthesis of the triallyl phosphates which
:consists of an oxidation of triallyl phosphite, while dry oxy-
gen is passed through it (70-800). This synthesis is simple
and does not require low temperatureal there is no danger of
explosion during the distillation. The synthesis takes place in
Card 1/2 two stages: I ) According to A. Ye. Arbuzov and V. M. Zoroastrova,

Synthesis of the Triallyl Phosphate SOV/79-29-6-53/72
(Refs 3,4) triallyl phosphite is synthesized:
3CH2 ~CH-CH2OH+Pcl 3 + NO5N -4 OH2-CH-CH20)3P + 3C6 H5X Hal
2) The oxidation of the triallyl phosphite, according to the
method develo d b the authors is carried out as follows;
(CH WMCH_CH 05'8P +Y0,,50 -4 (CH -CH-CH 0) PO
2 2 3 2 2 2 3
The progress of the oxidation is checked by the change of the
refractive index of the light. The separation of the mixture
of diallyl phosphits and triallyl phosphite is somewhat diffi-
cultv because the boiling temperatures are close to each other.
Triallyl phosphate was obtained in pure state. Its constants
were determined for the first time. There are 5 Soviet refer-
ences.
ASSOCIATION: Kazanskiy khimiko-tekhnologicheakiy institut imeni S. M.
Kirova (Kazan$ Chemical-technological Institute imeni S. M.
Kirov)
SUBMITTED: April 9, 1958
Card 2/2

AUTHORS3 Kuzneteovp YeeV,j Minimullinap L. SOV/80-32-2-53/56
-----------
TITLEs On the Synthesis of Tridimethylpihenyl-n-Cresylphosphate (0
sinteze tridimetilfenil-n-krezilfoofata)
PERIODICALs Zhurn~l prikladnoy khimii, 1959# Vol XXXIII Nr 21
PP 464-465 (USSR)
ABSTRACT: The phanyl athers of the phosphoric acid are used as plasti-
oizers, antioxidants, insectofungicides, ate. During the
synthesis of these polyphenyl derivatives of the phosphoric
acid trimethylphenyl7n-cresylphosphate is formed. Magnesium
chloride in a.good catalyst for this process.. 'The substance
boils at 390 - 4000C at 0-1 mm mercury column. The melting
point of the crystalline product is 1420C. It is soluble in
tricresylphosphate, benzene, butylacetate, acetone, ate. It
may be used as plasticizer for polyvinylchloride, nitrocellu-
lose and other polymers.
Card 1/2 There are 4 Soviet references.

On the Synthesis of Tridimethylphenyl-n-Cresylphosphate SOY/CO-32-2-53/56
ASSOCIATIONt Laboratoriya kafedry tekhnologii org&nicheskogo sinteza Ka-
zanskogo khimiko-tekhnologicheskogo instituts. (Laboratory of
the Chair of Organic Synthesis Technology of the Kazan'
Chemioal-Technological Institute)
SUBMITTEDj PebruarY 3v 1958
Card 2/2

XUZNZTWV, Te.Y.; VIZILII A.O.; SHJPJCMMRII, I.M.; ffULIM, S.S.
Relation between the molecular weight of polyethylene torephthalate
and.lthv~viscosity of,its solutions in a mixture of phenol and dich-
loroethane. Vysokom. soad. 2 no.2320,9-209 F 160. (MIRA 13:11)
1. Ilaxanskiy Wmiko-tekhnologichookiy Institut.
(Terephthalic acid)

KUZNETSOV, Te.T.; BOGANDY, A.?.; GILI, A.p.
Synthesis-of resins on the basiskof 3- and 4- nitrophthalic acids
and polyatomlc alcohols, and study of some laws of their polyc*A-
dnemation. Tysokom.soed. 2 -40.5;759-764 My 160. (MIRA 13:8)
1. Kazanskiy khimiko-takhaologichaskiy institut.
(Resins, Synthetic)
(Phthalic acid)
(Alcohols)

31552
3/081/61/000/022/024/076
o 22 Z101 ZZ D1 B110/B138
AUTHORS: Kuznetsov Ye. V., Bakhitov, M. I.
TITLE: Interaction of dialkyl phosphoric acids, trialkyl phosphites,
and unsaturated carboxylic acids with diisocyanates
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 22, 1961, 208, abstract
22Zh244 (Tr. Kazansk. khim.-tekhnol. in-ta, no. 29, 1960,
105-107)
TEXT; The followinj was obtained by the reaction of equimolar amounts
of OCN(CH 2)6 NCC and ( RO)2p(O)H (11) in ether:
OCN(CH 2) OHC(O)P (0) (OR) 2 (R- CH2_ CHCH 2' C2H5t n-C 3H79 n-C4H9 BY
heating equimolar amounts of 2,4-(OCN)2 C 6H 3CH2 (111) and II for 4-5 hr,
1 equivalent weight CO 2 is separated, and the substance (IV, where
R- CH 31 C2H59 n-C3H7' iso-C3H79 n-C4H91 iso-C 4H9f iso-C 5R11 ) is formed.
Card 1/2

Interaction of dialkyl phosphoric...
3N52
6
S/081 61/000/022/024/076
B110/B138
H3C NH
000, CPO(OR)2
N IV
The following was obtained by reaction of I with RCOOH: (CH 2)6(NHCOCOOR)2
(crystals) (R - CH 2-CH, CH2-CCH 39 C6 H,CH-CH). In the presence of RONa,
I and II yield (CH 24~NHC(O)P(0)(OR) 2 2 (R - CH39 C2H 5' n-C3 H71
iso-C3HV n-C4H9P iso-C 4H99 iso-C5 H11 ). By heating I with (HO) 3P,
polycondeneation products are obtained under separation of CO 2- By
reaction of I and III with (HOCH 2) 3PO or (HOCH 2) 4PC1, polymeric products
are obtained. [Abstracter's note: Complete translation.]
Card 2/2

S/02o/6o/134/004/033/036XX
B016/BO67
AUTHORS: Kuznetsov, Ye. V. and Bakhitov, M. I.
TITLEt Addition of the.D:Lalkyl Phosphorous Acids to 1,5-Naph-
thylene Diisocyanate I
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 4,
PP- 830-832
'TEXT: In studying the addition of the dialkyl phosphorous acid (DPA)
to 1,5-naphthyl diisocyanate the authors found that the acids of this
group are easily added (see scheme). In the scheme R -CH 3; C2E5; n-C3H 7;
iso-C3H7 ; n-C4 Hq; 'so_C4H9; 'so_C5H11; CH2 _CH_ CH2 . The possible trans-
formation mechanism is based on the fact that first the sodium alcoholate
enters the exchange reaction with DPA. 'The enol form of the sodium salt of
DPA formed reacts with one of the carbonyl groups of the isocyano group
of the diisocyanate molecule. In this connection the intermediate M is
formed at the beginning. (1) reacts with DPA and yields the product (II)
which is the naphthalene isocyanate-1 of the dialkyl eater of the
card 1/3

Addition of the Dialkyl Phosphorous Acids S/020/60/134/004/033/0.36XX,
to 1,5-Naphthylene Diisooyanate B016/Bo67
amidophosphono formic acid. Subsequently, the second NCO group reacts
according to the same scheme under the formation of naphthylene-1,5-bis-
dialkyl eater of the acid mentioned last. The reaction proceeds in the
chlorobenzene medium.with short heating in the water bath. The addition
products are white, crystalline substances, soluble in acetone, alcohol ,
dioxane, and other solvents (Table 1). The structure of the products
obtained was confirmed by the synthesis of naphthylene-1,5-bis-di-n-buty,
ester of the amidophoaphono formic acid (according to A. Ye. Arbuzov's
method)from naphthylons-1,5-bis-acid chloride of the carbamic acid and
tri-n-butyl phosphite. In conclusion, the authors state that thereaction
between DPA and diisocyanates proceeds readily. They thank T. P. Veselova
for assistance in the experiments. There are 1 table and 3 3~e-ferences:
1 Soviet and 2 US.
ASSOCIATIONi Kazanskiy khimiko-tekhnologicheskiy institut im. S. M.Kirova
(Kazan' Institute of Chemical Technology im. S. M. Kirov)
PRESEWTED: May 23, 1960, by B. A. Arbuzov, Academician
SUBMITTEDt May 17, 1960
Card 2/3

--KUZI:,'-ZTSuV~Yo-.v~j -PROKHOROVA--I-.F.--;-Ftl)[ZliLLINA-D-A-
Chemical transformations of polystyrene. Vyookom.soed. 3 no.10:
1544-1548 0 161, (MIRA 14:9)
1. Kazanskiy khimiko-takhnologichookiy institut imeni S.M.
Kirova.
(Styrene polymers)

I-_ KUZNETSOVO Ye,V.; KAMAYEVA& Ye*B.; VALETIANOV, 4.K.; ROYKH, A.I.
interaction between d,-hydroxy acids and phosphorus trichloride.
Zhur.ob.khim. 31 no-9:3013-3015 S 161. (MIRA 14:9)
(Acids, Organic) (Phosphorus cbloride)

27502
S/07 61/031/009/003/012
10 D215YD306
AUTHORS: Kuzneteov, Ye.V.,-and Bakhitov, M.I.
TITLE.: AddiLton of dialkylphosphoroun acidu to 116-liexa-
-methyleriediisocyanate
PERIODICAL: Zhurnal obalichey khimii# v. 31, no. q# 1961,
3015 - 3017
TEXT: It has been found that the above reaction occurs in the pre-
sence of alkali metal alcoholates or alkali metals according to
the following reaction
2(RO)IP(O)II + Nn -b (110),PONa
2(RO),11ONa+O-C=N(Cll2)dN-C=O
42(110)311(0)11
(RO)jl'OC=N(C1lg)GN~Cl,O(ol1)2
I
ONu 4Nn
(RO)2l'OC=N(Cllj),N=CPO(OR)2
All bit
--*(RO),II'OCONII(Clit),INIICOIIO(011)t
Card 1/4 n -cit.. wf,. it,wi,. wte-cjt'.

27502
S/07 61/031/009/003/012
Addition of dialkylphosphorous to. D215%306
It has been possible to prepare lioxamethylerfe-1,6-bio-dimethyls
diethyl, and diinopropylamidophoophoformato in the I)ure state and
in good yield; highor alkyl ester, crystallize with difficulty.
Ile xame thylene-1, 6-bi c-di-n-bu tyl eater could not be obtained in a
cryutal'Line form and propyl and isobutyl eatorn crystallized out
on standing for 3-6 months. The oaLora are readily soluble in al-
cohol,etherp benzenog dioxan and carbon tetrachloride. To establif3h
the structure of the eaters obtained one, -hexamethylene-1,6-bis-
diiaopropylamido-plioaptioformatep was produced by the A.I,',. Arbuzov
method. The addition reaction between some substituted dialkyl-
phosphorous aci4s and 1,6-hexamethylenediisocyanate was also stu-
died. It has been found that the introduction into the molecule of
the o,'ano group reduces the ability of the latter to enter into an
addition reaction which may be due to the influence of the cyano
group on the mobility of the electrons of the phosphorus atom.
196-hexainethylenediiaocyanate and a-dicyanisopropyl-phosphorous
acid were sealed in an ampoule and left for 2 years. After the
first year.the increase in viscosity was notices. 0,01-dichloro-
Card 2/4

27502
B/079/61/031/009/003/012
Addition of dialkylphosphorous ... D215/D306
diethylphosphorous acid reacts faster with it6-hexamethylenediiso-
cyanate under similar conditions which indicates that chlorine has
a smaller effect on the mobility of electrons of the phosphorus
atom. The addition reaction was conducted by introducing 0.1 mole
dimethylphosphorous acid, a piece of metallic sodium and 0.05 mole
196-hexamethylenediisocyanate into an ampoule which was then sea-
led and left standing for 10 hours* After initial exothermid,reac-
tion the viscosity increased and the product cyrstallized within
a further 2 hours. The yield of recrystallized product correspon-
ded to 85 % yield# and its melting point was 880C, (recrystallized
from Ccl 4)0 The preparation of hexamethylene-lp6-bia-diieopropyl
amidophosphoformate was conducted by reacting triisopropylphosphi-
te with hexamethylene-lp6-bia-carbonic acid chloride. The product
when combined with the addition product above did not depress its
melting point. There are 1 table and I references: I Soviet-bloc
and 2 non-Soviet-bloc. The references to the English-language pu-
blications read as follows: R.B. Fox,; D.L. Venezky, J. Am. Chem.
Card 3/4

27502
5/079/61/031/009/003/012
Addition of dialkylphosphorous .06 D215/D306
Boo., 78, 1661t 1956; Reetat D,H. Chadwick, J* Am. Chem. Boo., 77,
3813t 1955-
ASSOCIATION: Kazanekiy khimiko-tekhnologicheakiy institut im. S.M.
Kirova (Kazan Chemical and Technological Institute
im. S.M. Kirov)
SUBMITTED: October 199 1960
Card 4/4

, KUZNETSOV Ye.V,,- BAKHITOV, M.I.
=-I-
Addition of dialkylphosphorous acids to 3,31-dimethoxy-diphenyl-4p/#'-
and diphonylmethane-4.-41-diisocyanates. Dokl. AN SWR 141 no.5:LIO!~-
U06 D 161. (MIRA 14:12)
1. Kazanskiy khimiko-tokhnologichookiy institut im. S.M. Kirovao
Predstavleno akadsmikom B.A. Arbuzovym
(Phosphorous acid) (isocyanic acid)

NUVIETSOVp Yt V.
717~~
PHASE I BOOK MCPLOITATION, SOV/6034
Konferentsiya po khImii I primenaniyu foefororganich6skikh noyedineniy. 2d,
Kazan!, 1959.
Xhimiya I primenenlye foofororganicheakikh a y (Chtmistr
oyedinaniy; trud ~y
And Use of Organophosphorus Compounds; Conference Transactions) Moscow,
lzd-vo AN SSSR, 1962. 630. p. Errata slip inserted~ 2800 copies printed.
Sponsoring Agency: Akademiyp nauk SSSR. Kazans
Reap. Ed.: A. Ye. Arbuzov, Academician; Ed. of blishing House: I- S.
Povarov; Tech. Ed. t S. 0.; Tikhomirova.
Its intended for chemists,
JURPOSE- This collection of 'conference transactio I
process engineers, physiologists, pharmacists, h sicians, veterinarians,
and agricultural scientists.
COVORA0114i The transuctions Include the Nil textviot most of the scientific
PAPAR? roventad al tho Becand Conferq;jaa on the Chemistry and'Use of
CCd 1/1~4)'

No
Chemistry and the Use of Organophosphorus (Cont.) SOV/6034
Organophosphorus Compounds held at Kazan' from 2 Nov through I Dec 1959.
The material is divided Into three sectionB: Chemistry, containing 67 arti-
cles; Physiological Activity of Organophosphorus Compounds, containing 26
articles; and Plant Protection, containing 12 articles. The reports reflect
the strong interest of Soviet scientists in the chemistry and application of
organophosphorus compounds. References accompany Individual reports.
Short summaries of some of the listed reports have been made and are given
below.
TABLE OF CONTENTS: (Abridgedl
Introduction (Academician A. Ye. Arbuzov) 3
TRANSACTIONS OF THE CHEMSTRY SECTION
Gefter, Ye. L INII plastmass (Scientific Research Institute of Plastics,
Moscowl. Some Prospects for the Industrial Use of Organophosphorus
Compounds 48
Card 2114

Chemistry and the Use of Organophosphorus Wont.) SOV/6034
when 0.001 to 0.1 mol of methyl iodide per mol of cyclic phosphonite
is used. They form polyphosphonates with molecular weights of 270
to 3200.
Kuz~netsov, Ye. V. R. K. Valetdinov, and M. 1. Bakhitov [Kazanskiy
u hno*16-gicheskiy institut im. S. AKirova (Kazan' Institute
k
of Chemical Technology imeni S. A Kirov)]. Substituted Organo-
phosphorus Compounds as Monomers of High- Molecular Substances 296
C)mno-substituted esters of phosphorus acids have been obtained and
it has been shown -that carboxy- substituted and amine- substituted
crganophosphorus compounds and polymer products based on them
can be prepared. Amine- substituted esters of phosphorus acids
have been synthesized; the synthesis can be made either with chlo-
rides of alkylphosphonic acids or with esters of phosphorus acids.
Methods of synthesis of phosphorus- containing thiokols have been
developed, and it has been shown that a new type of phosphorus-
containing polyurethan can be obtained by the reaction of diisocya-
nates, phosphites, and dialkyl phosphonates.
Card V14

.7, N E YF- V.
~i. VINYL U,` . . . . . . . . . I . . . . . .
Z2. 1--MM OF 1j1;~*.'M;,',j*,Tr.D f!~1:,-,Z'~.0:,,j~!;; ACID3. C:..%,$ 744,.-1 Yul . . . . . . . . . . . . . . .
63. or ACH11. G. nal V. 51. 711?Au:!r . . . . . . . 317
54. REAMO%111 W, W'-,!
AM) rTr),1;i~!O1r1j.) A. P. nn! D. A. KaMt~*~ '.24
55. si"mu= on 7-4=aaia~ 11, . . . . . . . . . . . . . 1122
56. RYAM011 OY WAIKYL, NIAIM , TAWKIT. AND r!1O5PJ11,= Wird nq(DTAI~Ivy-
N. N. at a, . . . . . . . . . . . . . . . . 335
67, P14 OF Y-%. A. ~hrwlellbmun at. % .. . . . . . . . . . . 340
58. SYMY-IM AN"d MiLRICri-LACrIVITY OF 0.0-M-Mi-M
SMYL AND 0,0-M-IMI'M DI7i1IOPhCS.AA-.Q. M. P. =;o:;tA-
. . . . . . . . . . . . ;
. : . I . I . . . . . . . . . . .
346
59. TrUTRWIM OF MIDM AJ-4) MIMI &M-83 OF plioarHOPU13 Acira 1.111i 11=iply
ACTIVITi". P. 1. Atl,~*i tt n1 . . . . . . . sm
60. &MMU OF ACID 4i:TUM PADICAW AND FUN11CMAL 0:
X0 et al . . . . . . . . . . . . . . I . . . . . . . . . . . . . . . . . . . 359
6). Af,'T:Vl"*I, L, D. Protz~-r- ..0 . . . . . . . . . . . U2
62, I-AWLEXIMUZ 1AMPIAT71r.3 (1~ IT1,31TUIC "JiD AND
TIMM BIWORCAII, IsMoi A. A. Krul-nCii-vit ~,t a I . . . . . . . . . . . . . .
C,. MIMM"11MON OY CHMP04 ATUII IN CH1,0101j? h' A.141*4
AN'D DI0WGIrJL ACTIV171 OF rrMl OY ANJTO DMIVATIV-43. A. A. Xr.,Ac~,.vu
ut a, .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 372
64. MYCHATRIN, OF TIX ACTION OF OTrX;0P11O5P11OHU3 MMOtPUM ON WiLkH AND FRICTION.
11. 1, thnin tml A. V. 011yanoat . . . . . . . . . . . . . . . . . . . . . . . . Z?G
G5. Uri% OF DtAtnf, 1,14 Im1,,j;;11"y. P, 4'. rh"In pt &I . . . . . . . . . . . .
6 G . ORGANOMMP)MU5 WNPOWri 3 WJT'~j CCl, WCWY3 AS OIL ADDITIM, P. 1. MIS., at Al.. , , i
67. 1411CHLOPOni ICV..=L AS A POLY(VIML CRIDIUDY)PAX-ICIM, V.A. Vonkrtoeiviki
T 395
Go. AZC-,vFTjj3jiE DYF~- COTrAI'.1j1* 111.0MI.OrO GnOUIPS. X. G. Irvl~v . . . . . . . . . . . . . 399
MMOUM UFMOU
69. EHYSIOLOGICAL ACTIVM OF GPCA!ZPUO3P1-.'ORUS CWVPZDS. E. V. Zeizl at *I . . . . . . . 403
70. v.ECI"I&M AIM XIM"ICS OF TiM IMACTION OF MUMMOMI.-OFM Cavom= WI-AH
M.A5Z. V. A. Ukovlev . . . . . ... . . . . . . . . . . . . . . . . . 424
MAniya, I Priwninl~* So,7edineu4 (cl-etdntry &Ta Applicaticn
of organoyboaphonm A. Ye. Arbuzov, Zd. ruj~j. 'by Xazanf Affil, Pcad. E cl.
trusR, Foccow, 29(2 632-pp.
COnOctlm Of ec=PlvtePvP*rfi PrODOntea at the 1959 Mean Conforcnco On CL-snistry of
org = phoophoran Corpounilo.

PUDOVIIK, A.M., KUZNETSOV, YE.V., MALICHENKO., B.F.0 GRISHINA, O.P.
The synthesis of various phosphorus -containing monomers
Report pres-nted at the 12th Conference on high molecular weight compounds
devoted to monomeraq Bak~ix 3-7 April 62

,XUZNFTS(NI Ye.V,; LEVITAYEVA,, R.S.
Phosphorylation of polyethylene. Trudy XKHTI no.30:63-0 62.
(mA 16:1o)

KUZNETSOVO.Ye.V.; SHERWRGORN, I.M.; EELYAYEVAI V.A.
Synthesis of polyesters based on trivalent phosphorus acids by
condensation polymerization at the interface. Trudy KKHTI no.30:
7o-76 62. (MMA 16s10)

KU.W.TSOV4 Ye.V,.j VIZRLI, A.O.; TYULENEYj S,S.; SHERMERGORNg I.M.
Stabilization of polyethylene terephthalate. Trudy XMI no.30s
82-88 162. (MIRA 16s10)

.KUZNETSOV Ye.V0j BOGDANOVp A.P.
Destructive oxidation of 0(-nitronaphthalons under pressure. Trudy
KKHTI no.3009-91 162. (MIRA 16210)

LYZENTSEVA, M.A.1 VALETDINOVp R.Kol KUZNETSOV, re-Ve
Fireproofing treatment of cotton fabrics. Trudy KKHTI no.30i
170-173 162. (MIRk 16slo)

KUZNETSOV, Ye.V.j BAKHITOVI M.I.
Reaction of dialkylphospborous acids with 2,4-toluylenediisocynnate.
Zhur; ob. khim. 32 no.lt278-279 A 162. (RIPA 1512)
1. Kazanakiy khimiko-tokhnologicheskiy institut.
(Phoophorous acid) (Isocyanio acid)

8/056/62/042/006/042/047
B104/B112
AUTHORS: Xuznf-t-qoy-j Ye. V-j Kuzneteovp Ye. ~., Shalamov, Ya, Ya.,
Grashinp
TITLE: Experimental data on the.existenco of resonance in the K OA?
system at 1650 Mev
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheakoy fiziki, v. 42,
no. 69 1962, 1675-1677
TEXT: Previous papers (Ya. Ya. Shalamov et al., ZhETF, 40, 1302, 1962;
1. A. Ivanovekaya et al., IX. Intern. Ann. Conf. on High Energy Physics$
Kiev, 1960. Plenary sessions I-V, Moscowp 1960, P- 459) have shown that
in the pair production of Ko and A0- particles by 2-8-Mev n- mesons on 0
complex nuclei (C' Cl, F), i e.9 in the reaction n- + (AjZ) + X
+ mn + (AZ)* (m -1,2, *#a) Mp the angular distribution of the AO
particles in the center-of-mass %stem of nN is directed backward and that
the angular distribution of the W particles in nearly isotropic. These
angular distributions cannot be attributed to the.production of
Y14 + K0, YA + XW, or + K with the subsequent decay reactions
Card 1/2

S/056./62/042/006/042/047
Experimental data on the existence ... B1040112
Y + n and K' --* Ko + n. The angular distributions are explained
by assumingp in (I)p the intermediate reaction x- + N --> Zo + mnp whore
m, a 1 1 2 p ... , and ZO + KO. In the oenter-of -mass system, the ZO
particle travels from nN to the rear hemispheres Results: M zIV1650 Mev;
strangeness 8 a 01 spin I = 1/29 2/3o ... I isotopic spin 1,. 1/2. Z0
interaots as an individual particle with the nucleus. There are 2 figures.0--*'_
ASSOCIATION:. Institut teoreticheskoy i eksperimentallnoy fiziki Akademii
nauk SSSR (Institute of Theoretical and Experimental
Physics of the Academy of Sciences USSR)
Fizioheskiy Institut im...4. N. Lobedeva AN.SSSR (Physics
Institute imeni Po H. L6bedev AS USSR)
SUBMITTED:. March 249 1962
Card 2/2

ACCESSION MRS AT4033969 S/00.00/63/000/000/0076/0080
Kuznetsovo Yet Val Valstdinov, Re Kel Vershininap"96-IM8
TITLEt Phosphorus-containing polyee'terx*and polyamides-of the
.aliphatic series
:SOURCEi Geterotsepny*ya vy*sokomolekulyarny*ye soyedinenLys
il(Heterochain macrom6lecular. co'mpounds)l sbornik statey, Moscow,
Xzd-vo "'Nauka," 1963, 76"80
~I'TOPIC TAGSs polyester ' polyamide, phosphorus containing polyester,
;phosphorus containing polyamide, aliphatic polyester, aliphatic poly-
amide, polycondensation, refractory polymer
4BSTRACT: The article reports on polycondonsation reactions involving
bis(beta-carboxyethyl)phosplitne oxide (previously synthesized by the
authors through hydrolysis of a bio(beta-cyanoothyl)phosphine oxide)
and ethylene glycol,-propyle'ne glycol, glycerol a-chlorhydrLn.. or
hexamethylene diaminee These reactions were carried out to study the
preparation of'phosphorus-.containing polyesters and polyamides of the
aliphatic series. Principles of a,second order reaction governed for,
Card~ 1/2

ACCESSION NRI AT4033989
the range of temperatures 165-185C and-reaction times of 30-240 mLno
All the polymers obtained)exca't those based on glycerol a-chlorhydrinj
p
were colorlessq tra' onflammablas had sLgnificatnly higher':
neparent'. n
melting points than comparable polymers lacking a P atom,(ise,~,
50-170C)0 and were suttable for fiber of film prod4ctions Reaction!
i I
rate constants and activation energies were determiqede Origa art*
has: I figure and 5 tApbless..
ASSOCIATIONt Kazanekiy khLuiko-tskhnologkche4kiy instLtut 101
Ituts of Chemical Technology)
S. M. Kirov& (Kazan'tuRt
SUSMITTEDS 29Jun62 '~t,ATD PRESSi 3061 ENCLs,- 00
N6 RE FSOVt 006 OTHER 0
-SUB CODE: -00i OZ
a
rd
-2/2

KUZNETSOV, YS.V.;-LqHw# V.Y6'
Copolymers of jalts of unsaturated dicarbox7lic acids with
methacrylic acid., Vyeokom.soed. 5 no.1124-27 Ja 163.
(KrRA 16 11)
1. Nazanakiy khIml tekhnologiobeekiy Institut im. S.M.Kirova.
(Acids, Organic) (Mthaerylic acid) (Polymers)

AMM/0-D. Ps-hlttc-h/T~h
A'0~1-251M MR: AP,',00CYT01 s/ojQo/63/oo5/c>o5/o72-./0728
7Z
ATUTHORi V%Mchenkov, V. A KUzWtsoV' Ye. V.) Iakhakov, 0. A.; lach-kina, V. M.
TMS: rractionation of Mst*'JJWL~E~imte tbAcrylic mcld%Q22i~rua tbe
properties of the fractions
SOME: "okomolekulyarny" isopdineniya, Y. 5. no. 5, 1953, T24-T28
J
TOPIC TAGS: fractionation, copolymers, mettacrylAte, methurylic acid,, weromole-
cules, IA
ABSTRAM The purpose of the present investigation consisted in a study of the
physical and chemical characteristics produced in copolywre of methy1wthAc--YUte- I
D11-thacrylic acid by varying its composition. To this end, a copolymer vaa produced
by heating for 40 hours at 450 a mixture of 9-T5% mstbacrylle acid, 90.2% metbyl-
rmthacrylate, and 0.05% lithium methaerylate vith the addition of an initiator. Tho
obtained copolymer vas dissolved In acetone, from wbich fractions were precipitated
by a 2:1 mixture of hexane-dichlorcethane. These were dried, and their properties
studied by viecosimtry and spectroscopy. Tile examination of the fractions of the
copolymer gave an Identical =tbAcrylic acid content of 7.4%, the 92.6% balance
being accepted as methylwthacrylate. nw constants K and a of the Stwdiger-14%rt
equation for a oppolywr of the given composition in acetone were determined. It
,Card 1/2
ism

L 13554-63
ACCMIMI Mt: AP3000TOt 2,
%0
vas demonstratsd that the addLtton of litblun wthanrylate
the polymrizing
mixtuxe caused the reaction to proceed vith the formation of a tertiary copolymer.
Orig. art. hast 9 formulas, 5 rigures, and I table.
MOCMION: Kazaaskly khImiko-tekhnologicbeskiy inatitut im. S. M. Kirava (K!~w
Institute of Chemical Enginearing)
.'~';SLW In s O5Nov6I. n= Am,. i7jun63 3=: 00
!SUB CMi -CH NO R" 86VI W3 OM
2/2
Card

6t ;:: I !
L 308/EPR/EPF(c )IEWP( j )/F-.VT W/ES (a) -2-- AFFFTC/ASD/SSD'1
ACCESSION NR: AP3006757 S/0190/63/005/009/1351/1353'
Faytullin, 1. N.
AUTHOR: Kuzuetsov, Ye* V.;.
I 1 114
TITLE: Synthesis of or~anophosghorus polysulfones.
SOURCE: Vy*eokomolakuly&rdy*YS soyedinentya, v. 5, no. 9, 1963,
1351-1353
TOPIC TAGSt inorganic polymer, orgdnophosphorus pollsulfone. pot~-
merization, synthesis, polysulfone synthesi co~olymerization
%Osp anic acid est'r,
2-butoxyvinylphosphonic acid, 2-butoxyvinylp e
su if ur _L__ -a- --to sc
d OXT4 9 *azaL" - &c-4 A-, fnitlaLt r, yL__"fty'i
reduced vis-cd4lty- curt pdlysulfone curing, cuting agent, po~y-w
F7
sulfone property modification, property modification, 1-naphthyl Iso-i
cyanate, 1-6-hexamethylene diisocyanate, 2-butoxyVinylphosphonate
ABSTRAM Phosphorus-containing polysulfones have been synchevice
by the reaction of 2 Ide
-butaxyvinylphosphonates with sulfur diox
O*C. Coaglymerization1waLs conducted in benzene with constant bubbi
ing of the S02; isoprop~ylperoxybenzoic acid served as the initiator.;.
Card 1/4

'L 17230-63
ACCESSION NRt
AP3006757
The reaction proceeded According to the equatLont

j
~
r-CH CH SO
CH CH
2
n SO
064H 9 P0 2 Oc 4H9PO (OR) 2 n
_C3R7-n# -C3H7-Ls
where R to -CH -C H 0, _C09-00 C4H t o'
9 0i r
t
2 5 V
5% was obtained. The p
C6H13 -n yield of _2.lvsulfQnesVkr t &as-!
parent re as light yellow to brown in color; they exhibit
adhesion rcilaLn, paper, and cloth and do not b rn*or
4p0 glass, po U
upport combustion, Like carbon-chain polyoulfones. phosphorus-
containing polysulfones are slightly soluble in many organic sol-i-
vents, At room temperature they are readily soluble in methanol
and slightly soluble in bencene. Evidently the molecular weights:1 ;i
of the polysulfones areinot hight as they show viscous flow at'room
temperature, Viscosity~:of the polysulfones was measured for t%
solutions in methanol, ind their reduced viscosity was calculatedi:_
to be in the 0,054-1.5~O range. It was assumed that the polysulfh~is-_'
have -S020H and groups., Curing of the polysulfones was attempted~hii
Card 2 / 4

L 17230-63'
ACCESSION NRt AP3006757
reaction with toocYahatese The polysulfones were mixed with
h
thyl isocyonate or 1,6-he:xamethyleme ditsocyanate and were heated fbr,~
13 hr at 75C and for 3 hr at 100C. The reactions proceeded as fol
lows..
0 0
OMCM
R-9-0H + It-S-0-CONHW7 I
0 0
0 0
V I
RS-OR + 0-C-V02)6H-0-0+ HO-S-R
0 0
0
0
+ RSO-40SH(M)SHM-0SR,
2
0
wtard 4

ACCESSION NR: AP3006757"
where R Is a high-Molecular-weLight radical. The 7roductafthereadAmwith
1-taphthyl Isocyanate did not differ in appearance from the orig-
inal polysulfons, but was highly viscous. The reaction with 1,6-
hexamethyleno dlLsocyanate ad to the formation of solids which are!
insoluble In benzene even aMr prolonged heating. The purified
product is a light yellov powder with a malting point of 115-120C.,
The reaction Is of particular interest since it can be used both
to cure polysulfones and to modify their properties. Orig. art,
has: I table and 3 formulas.
ASSOCIATIONt Kazaaskly~khtalka-tekhnologichaskly institut Lm. is
M. Kirova
_(Kosan' lastitute of Chemical Technolo3y)
SUBMITTEDs 2*Fab62 VATS ACQt 30Sep63 ENCLt 00
SUB CODEt CH, MA NO REF SOVt 006 OTHERt 010
rd 4/4
ca

MYAGCHENKOV, V.A.; JJUZ �qY,-Ye.V.; ISKHAKOV, O.A.; LUCHKINA, V.M.
FractionatIon of a copolymer of methyl nethacrylate and
methaorylic acid and the properties of fractions, Vysokom.
Ooode 5 no.5t724-728 My'63. (MIRA 17:3)
1. Kazanskiy khimiko-tekhnologicheekly institut imeni Mrova.

KMNEMOV re V ; VAIZTDINOV, R. X, I ROrTBURD,, TS. T&.
Synthesis of aliphatic phosphorus contalhing dicarboxylie acids.
Zhur. ob. kbim. 33 no.1%150-153 163. (MIBA 161l)
1. Kazanskiy khIml a-takhnologiabookiy in8titut imeni
SO He Kirovat
(Phosphorus acids)

IGNATIYEVA, E.K.;_KUZNETSOVL YsjV,_
Interaction of acetone cyanohydrin and allyl, alcohol vith
trialkoxystibine, Zhur,ob,khim. 33 no.2s617-622 F 163.
(MR& 16:2)
1. Kazanskiy khimiko-tekhaologicheakiy inatitut Imeni SX
Kirova.
(Lactonitrile) (Anyl alcohol) (Stibine)

I
-
KUZNEVSOV, Ye.V.; SOROKINA, T.V.; VALETDINOV, R.K.
Realkylation of bis- and tris (#4-cyanoetbyl) phosphines.
Zhur. ob. khim. 33 no.8t2631-2634 Ag 163. (MIRA 16:11)
1. Kazanskiy khimiko-tekhnologicheskiy Institut Imeni SA Xirova.

Sil(y.ved considerable adhesion to meW and glass. Orig. art. has: 7 tables, I figure and

ACCESSION NOt
AP4009146
S/'0190/64/006/001/0031/0033
AUTHORS: Kuznott)ov, Ye. V.; Gill, A. P.; Shermorgorn, I. M.; Kuznotsova, S. F.
TITILS: Synthesis of polyesters and polyamides or the basis of nitrophthalic acids
by-interfacial polycondensation
SOURCE: Vy*.sokomolekulyarnT*ye soyedineniya, v. 6, no. 1, 1964, 31-33
TOPIC TAGS: synthesis, polyobter, polyamidcj polycondenuation, interfacial poly-
condensation, nitrophthalio aoidp dichloride3 of nitrophthalio acidsp torephthalic
acid
ABST,RACT: Solutions containing 0.2 Mol/liter of dichloride3 of terephthalic-,
nitroterephthalic-, 4-nitrophthalic-, and. ~-nitrophthalic acids in n-xylene were
reacted with aqueous solutions of 2,2-d1-(4-oxyphaziyl) propane (OPP)-or hexamethyl-
. -nediamino (MO) of the same molar concentration in the presence of 0.45 Xol/liter
of NaOff. The synthesis was conducted in a flask, with 10 minutes of energetic
mechanical stirring. Following this, the obtained polyesters or polyamidea were
separated by filtration, washed with water, and dried to constant weight. The
yield of the polyesters, obtained by the interaction of the dichlorides of nitro-
terephthalio and 4-nitrophthalic acids with OPP amounted to 86.8 and 36A, their
Card 1/2

ACCESSION 110: AP4009146
respective specific viscosities for O.~ji solutions In tricresol averaging 0.072
and 0.019. ks to the polyamides synthesized from the dichlorides of nitrotereph-
thalic-, 4-nitrophthalic-, and 3-nitrophthalic acids with IDIDItheir yields amounted
to 88.0, 84.2, and 76.6%, with respective specific visoositios of O.Y% solutions in
concentrated sulfuric acid averagin& 0-352, 0.280, and 0.223. The higher yields
and viscosities registered in the polyenters derived from the dichloride of nitro-
terephthal4.c acid as compared with the onos obtained on the basis of the dichloride
of 4-nitropni.nalio acid is attributed by the authors to the fact that the latter
ingredient has its nitro group located in a meta-position in respect to the chloride
group. A similar trend, although on a less pronounced scale, was observed in poly-'
condensation products of diohloridea of nitrophthalio acids with E11D. Orig, art.
has: 2 tables.
ASSOCIATION- Kazanskiy khimiko-takhnologicheskiy institut im. S. 11. Kirova (Kazan
Chemical-Technological Institute)
SUBMITTED. 07jul62 DATE ACQ: 1OFeb64 E21CL: 00
SUB CODE: CH No Ru sovr oo6 OTHER: 003
Card . 2/2

ACCESSION NR: "4042192 8/0190/64/006/0017/1328/1322
AUTHOR: Kuznetaov,l Yes V:0 Faysunins Is No# Meralyakoval go Yao
TITLE: Synthesis of phospboorganic polysulfones. III. The reaction of sulfur dioxide
with unsaturated phosphoorganic polyesters
f4s j;A4 1322
pq.
TOPIC TAGS: polyester, InWA41dal candwsatim. B0ft-(*AqtQvi
vlaylphosphiWo acid. dipbecol. dleMoreank3mdride. b3drvpexazide, dkaaa*,
sulfurdloxide, polymer hardening, polymerizattoninittator. pbospboorgazlepobesum.
unsaturatod polyester, polymerization catalyst, polymHone, pbospboorganic poly=lfbae
ABSTRACT- Several unsaturated phosphoorgante polyeatere were Mthesixed by tbe intft*-
facial condensation of the dichlorides of vinylphosphinic and J~-(n-butox~~j vln.~Iphosphlnic
acids, and their properties were Investigated. The resulting polyesters are liquid or soilid
resins of various colors, depending on the initial reactants. The talxdated data on the
properties of the synthesized polyesters show that for polyesters obtained by the inter"Hod~'.
of diphonols with tho dichloroanhydrides of alkylenephoaphinio acids the specifio viscosit
Y
i1/3 t

ACCESSION NR- AP4042192
Increases during the transition from diphenylolpropano to resorcinol to hydroquinone.
The main product to a cross-linked polymer which Is Insoluble In organic solvents and
melts with decomposition. The equations for the reaction of unsaturated phosphoorganic
polyesters with sulfur d1oxIde are given. The experimental data show that polyesters
'.based on,6 -(n-butoxy) vinylp4osphinic acid d o' not react with sulfur dioxide, apparently
because of sterio factors. With the other polyestera, when dichlorQethane, dioxane or
their mixture are used as solvents and the Initiator is isopropylbenzene bydroperoxido,
f reaction proceeds with evolution of beat. The resulting products do not dissolve in
dichloroothane, dioxane or other organic solvents. A change In the reaction conditions
does not load to an increase In the amounO of sulfur In the polymer. The curves reladq
so In thb amount
the degree of hardening and the amount of initiator show that an increa,
of initiator decreases the formation of an Insoluble residue. This Is explained by the
assumption that the addition of an Increased amount of hydroperoxide forms a compound
containing B03H groups with the cross-linked polymer.
ASSOCIATION: Kazanskly khim.1ko-tAbnologiohe#1dy insUiut im. B. M. Klro'va (FAzan
Chemical-Engineering Institute)
V,
2/3
card
the,'

-_, : ~F , , z ~z~ ;.. ,
~~. ,

MYAGCRENKOV, V.A.; IUZNETSOV, Ye.V.; KITIKEVICH, V.Ya.
-,
Concentration effect in the degradation of a series of Polymers in
dimethy1for-mide. Vjrsokom.soed. 6 no.8:1366-1370 Ag 164 iMIRA 17:20)
1. Kazanskiy khimiko-takhnologicheskiy Inutitut imeni S.M,Ydrova,

MYAGCIIENKOV, V.A.; K Ye.V.; DOMINOVA, N.J.
Viscosity of rnoluLionu of copolymer fractions of methyl methacrylate-
methacryll.c acid In organic solventz. Vysokom.soed. 6 no.9t1612-1616
S 161~. (MIRA 17t10)
1. Kazanskiy kh1mikc-tekhnolog1cheskiy In3titut Ki.rova,

hUZ1,FZTSOV,'Ye.V.; DOCOYAVLENSKAYA, L.Ad
Polarographic study of the copolymerization of methyl methacrylate
with methacrylic acid In the presence of some of its salts. Vysokam.
noed. 7 no.2t259-263 F 165. (MIRA 18%3)
1. Kazanskiy khimiko-tekhnologichoskiy institut imeni Kirova.

, - ---- -- - - -,I- -
" . U- - I - - --- --- , - -;~Ilm
- , -

(4j- SOURCE W-LIT-WUR704
ACC NR 7k.~ -Cut IT/66/boo/014/boW/bo&~-
INVENTORS: Kuznet-90 jp~_Y.j Guaev, Ve Ioj Zhi4kovap To No; Andreyevaj I. NO)
RV-
Somenovas 1-. -97-
ORG*. none
TITLE: A method for obtaining copolymers of propyleno. Class 39, No- 183938
SOURCE: Izobrot prom obraz tov znj no. 14, 1966, bo-81
TOKC TAGS: polymer,, copolymer, propylone, polymerization, eater, phosphoric acid)
catalyst, titanium compound, aluminum compound
ABSTRACT: This Author Certificate presents a method for obtaining copolymers of
propylene with unsaturated compounds in the medium of an inert carbonacoous solvent
at the temperature from 20 to 60G. The process is carried out in the presence of a
catalyst consisting of titanipm tetrachloride and aluminum alkyls. To impart the
property of fire resistance to the copolymers,, unsaturated mixed esters of phosphoric
acid are used as 'the ursaturated compounds,
SUB CODE: l1/ SUBM DATE: 065ep62
UDCt 676,

ACC Nki
AP7001408 C~ --i6CR&E, 66E--fi~d~lif~6-10001-021 /01 10/ Oll0
~INWZNTOR: 'Kuznetsov, Ye. V.; Bakhitov, M. I.; Volkova A. V.
IORG: none
j
!TITLE: Preparative method'for polyurethans. Class 39, No. 188003 [announced by the
~:Kazan Chemical Technology Institute im. S. M. Kirov (Kazanskiy khimiko-tekhnologiche-
t
okly Ina ti tut)
ISOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 21, 1966, 110
d e, trlmethylolphos-
:TOPIC TAGS: polyurethane heat resistan'CLe
.o~, dusocyanat
phine,' pyridine, chemical synthes :Ls,
ABSTRACT: An Author Certificate has been issued for a preparative method for poly-
urethans with an improved heat resistance. The method consists of reacting
diisocyanate with trimethylolphosphine in pyridine. (BO]
SUB CODE: 11, 07/ SUBM DATE: 06Sep65/ ATD PRESS: 5109
-d-, 1/1
8. .664-9

L 4iZj ;--OD I ~M)/~ IV I/ I,,' t7al'tj 1.1 It f,W.
ACC NR3 Ap6o11236 61%) SOURCE CODE: UR/0413/66/000/006/0075/0075
INVENTOR: Kuznepsov, YO, Vs; Chichinadze,-N, M,
ORO: none
TITLE: Preparation of-polymers, Class 39,, no. 179923
SOURCE; Izobreteniya, promyshlennyye obraztsyo tovarnyye znaki,
no. 6, 1966, 75
TOPIC TAGS: copolyiner, methacrylic acid, polymerization
ABSTRACT: This author Certificate introduces a method for preparing
copolymers1from methacrylic acid by radical polymerizationliria reactive
compound. To obtain copolymers with a high_j_~"y onicapacity and
surface-active effect, M-CaProlacin'ta, in suggested as the reaction
medium. tTrainslationl (LD]
SUB CODE,:0'1,11/ SUBM DATE: 23Sep63/
card uDc: 678.744.332-139

ACC NR. AP6015669 SOURCE CODE:
UR/0413/66/000/009/0075/0075
INVENTOR:- Kuznetsov, Ye, Gusey, V. 1,;_ Semenova. L. S.; Shuryginal- L. 'A.
ORG: none
TITLE: Method of obtaining "Pt Not alle'M 'y
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye znaki, no. 9, 1966,
TOPIC TAGS: polymerization, catalyst, titanium tetrachloride, trietylaluminum,
organophosphorus polymer
ABSTRACT: An Author Certificate has been issued for a method of obtaining orgaqo,
erization
phosphorus polymers by po ~)f unsaturated phosphates in a medium of In
inert liquid upon heating in the presence of a catalyst. To expand the variety of
catalysts, the a stem of titanium tetrachloride-trietylaluminum is used- a6 t1le-
y
cataly&Lq (Translation] JNTJ
SUB CODE: 11/ UBM f)ATE: 22Feb62/
0
'*)n
UDC: 678.745.73

(MI/ETC(F) fr~W_) /kwp I/RK
AP6000985 SOURCE COM UR/O286/65/OOQ/b2MdO59/6D55_
AUTHOHSj KuzneteoiV_Ye;,_Y&; Loahkinp V. Ye.
ORGI none
TITLEt A method for obtaining carboxyl-containing cation exchangei-81- clads 39, ~0_*
176 eannounood by Mano- Chemical-Engineering Institute im. S. 9, Kirov
TE-zane iY khimiko-tekhno1og1oheokiy inst
i I tut)/
SOURCEt Byulleten' izobreteniy i tovarnykh znakov, no. 22, 1965, 59
TOPIC ~AGSt polymer# copolymerization, cation, ion exchange, resin
ABSTRACTt This Author Certificate presents a method for obtaining carboxyl-containing
cation exchangers by copolymerization of unsaturated dicarboxylio tLoids, methacrylic
aoid, and arose-linking (vulcanizing) agents. To obtain highly bacic, chenically
stable sorbents, diisocyanatwes4lare used as cross-linking agents.
SUB COM 11/ 8MM MTES 258ep63
674
6(2,
I Card 1/1 UDCs 661,183,123.2t618.7".33-1 4_43i2J.