SCIENTIFIC ABSTRACT KURDYUMOV, E. V. - KURDZIEL, R.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000927710007-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: June 20, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

B. T. R.
Vol. 3 No* 4
Apr. 1954
Metals-4,leohanloal Working
54" influence of Inlernal GrQln Structure of.Ausernite
an the, Srl( niffuslon of Iron. Ohmian. Y
wiL - -a--? M , h+
Nwrdig '~ Dona v Ukadc ?TI Naijk SSS It to. (), Me.
Y.I. MI. P. 1021-im.
DixtMes Attvt of hittmil gTain structute in in%-estigating
diffusimi inechanism in alloys whae tLere at* phav- tmuforma-
tions, GraA. 6 rcf.

DOEROXHOTOV, V.11.J BABAYEVA, A.G.; KURDY12,IOVAp P.G.
j,jitotic activity of nplls of the liver and the outer
orbital gland In white rais. Dokl. All SSSR .142 no.2:458-
461 Ja 162. (MM 15;2)
1. Institut oRoperimentallnoy biologii AW1 SSSR. Predstavle-no
akademikom A.N.Baku:Levymo
(KARYOKINESIS)
(LIVER)
(IACRIMAL ORGANS)

111OBTDOOTOV) V.N.; Kl,'.;MYU,',I-)','A, A.G.
24-hour per-lodicity of mitotic divialon, of' coll.,j in thfj op!~'ulium
of the enaphaguo of white rats. Biul. ekap. blol. i med. 54 no.8:
81-84 Ag 162. (MIRA 17: 11)
1. Iz laboratorii gistofiziologil (zav. V.N. Dobroki-,otov) Instituta
ek3perimentallnoy biologii (dir. - prof. T.,':. 11-Sayokiy, SSST,,,
Moa~,-;a. Predstavlena doystvitellnym chlenom A,"',' ')'S.,P. N.N. 7hukovyr,-
Verezhnikovym.

DOBROKHOTOV,, V.11.; MARKELOVA, I.V.; SOKOLOVA, L.V.; TIMA1~11KEVICH, T.B.;
NIKANOROVAP R.I.; XURDYWOVA, A.G.
Effect of the time of injection of sareolysine o- the change in
the mitotic activity of the tissues of white rats. Trudy MOIP.
Otd. blol. 11:165-185 164- (MIRA 18il)
1, Laboratoriya gistofiziologii Inct-ituta eksperimentallnoy
biologil AMN SSSR.

DOBROKHOTOV, V.11.; MARULOVA, I.V., SOKOLOVA, L.V., TIK%SHKEVICH, T.V.j
NIKANOROVA) R.I.j KURDYU140VA, A.G.
Effect of sarkolysine on the 24-hour periodicity of mitoses in
some tissues of white rats. Biul. eksp. biol. i med. 57 no-3:
97-102 Mr 164.
(14M 17: 11)
1. laboratoriya gistofiziologii (zav. - kand. biol. nauk V.N.
Dobrokhotov) Instituts, eksperimentallnoy biologii (dir. - prof.
I.N. Mayskiy) AMN SSSR, tloskva. Predstavlena deystvitelinym
chlenom AMN SSSR N.N. Zhukovym-Verezhnikovym.

VOROROV, B.G.; GUSEVA, L.M.; KURDYUMOVA, A.M.j KRAS110PROSHIN, V.A.
Spectrum analysis of girth joints in high-alloy steel. Avtom.
avar. 17 n0-4:94-95 Ap 164 (MIRA 181l)

)--i (iqlii~::Tiont for thf,~ of steel]
Frimc.-nen.1-7-, imtanwikl !'U- -' 11 no vo a-.na3i--a
-italel j,enlri!rad, , '10: ')

.61CZ lllii~ 11%.11.6035IU4 SOURCI!-; CODE": UR[0l37/GG/000/008/D034/D034
AUTHOR: Alferova, N. S.; Bernshteyn, M. M.; Kurdyumova, G. G.
TITLE: Mastering of technology for making pipe from N36KhT steel
SOURCE: Ref. zh. Metallurgiya, Abs. OD233
REF SOURCE: Sb. Proiz-vo trub. Vyp. 16. M. , Metallurgiya, 1965, 41-45
TOPIC TAGS: pipe, pipe manufacture/ N36KhT steel
ABSTRACT: A detailed analysis was inade of the manufacturing technology of pipe
from austenitic precipitation hardenable N36KhT steel. With this technology,
more than 8000 m of various gages of pipe were produced from centrifugal hollow
billets by cold rolling and drawing. The results of technological tests (flattening
and expanding) indicated that the finished pipes meet all requirements. Compari-
son of their qualities with the qualities of cold-formed pipe produced from rolled
drilled billets; indicated that the two types of pipe (lid not differ one from another
in mechanical properties and impurity contentration of nonmetallic inclusions.
Orig. art. haB: 3 figures. L. Kochcnova. [Translation of abstract] [NTj
SUB CODE: I l/
Card UDC: 621. 774. 35

13 7- 58 - 3 - 534 5
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 3, p 1Z5 (USSR)
AUTHORS: Yankovskiy, V.M., Zil'bershteyn, L.I., Kurdyumova, G.G-..,
r rr i, I.-, The Effect of the MicrostrUCture of a Strip on the Quality of
Pipes Manufactured by Resistance Welding (Vliyaniye mikro-
Struktury lenty na kachestvo trub izgotovlennykh elektros-
varkoy soprotivleniyem)
PERIODICAL: Byul. nauchno-tekhn. inform. Vses. n.-i. trubnyy in-t,
1957, Nr 3, pp 39-47
ABSTRACT: Studies were performed in order to establish how the qual-
ity of welded pipe seams is affected by the microstructure of
the original strip. It is noted that microstructural nonuniform-
ity in the welded scam is attributable to the kinetics of phase
caused by the great heating rates in the pro-
cess of wMllngi- The transformation proceeds in the manner
of a non-diffusive transition from an c~ to a6' iron lattice with
subsequent dissolution of carbides therein. Thus the structure
of the welded scam will be determined by the size, shape, and
distribution of the carbide particles in the initial structure of
Card I /Z the strip. Both laboratory and shop experiments with the weld-

137-58-3-5345
The Effect of the Microstructure (cont.)
ing of flat specimens and pipes made of steel 10 with different initial micro-
,structure have shown that mechanical and technological properties of the
iwelded scam are adversely affected by the structure of strip edges that
contain unequal and unevenly distributed areas of structurally free cementite.
A.P.
Card 212

ACC NRi AP7005658 (A, BOURCE CODE: LM/Ohl3/67/000/OU2/0115/0115
INVEnTOR: Zbar, N. R.1 Baburina, 0. Ya.; Korotkov,.N, F.;.~,.L.rdyumova, 0. V.;
Ebell, 1. 1.
l
IORG: None
TITLE; A memory unit. Class 42, No. 1.90661 [announced by the Design Office of the
Main Administration for Bignalling and Communications, Ministry of Means of Communica-
tion SSSR (Konatruktorskoye byuro Glavnogo upravleniya signalizataii i eVasi Mini-
~sterstva putey soobshcheniya 888H)l
OURCE: Izobreteniya, promyehlennyye obraztey, tovarWe znaki, no. 2, 1967, U5
TAGS: computer memory, thyratron, binary code
TRACT: This Author's Ceriificate introduces a memory unit of the static type which
s metallized paper for recording binary coded information together with attachments
changing the paper by winding from a feed drum to a take-up drum. The recording
ceso also involves the use of indicator and control units based on cold-cathode
ratrons and cownutation elements. The design provides for simplIfication of the
to for monitoring and signalling of a completed recording without erasing previoual~
orded dataxith repeated uBe. An el"tic pad bolde a contact plate against the
allized paper. Holes cut :in this plate fors inrormatlc~ storage cells. Within
card 1/2
um 681.142.

ACC NRt AP7005658
these holes are contact springs which are used for recording infomation in the
storage cells and also for readout of this information and signalling t7 current which
is respectively sufficient and insufficient for breakdown of so electrically conductive
layer. These operations are carried out by connecting thG contact springs to all or
some of the indicator elements based on thyratrone through the contact elements of the
control systemse
0 7-
oil
areas of the electrically conductivd layer; 2--electrically conductive layer;
contact springs; h--metaUized paper; 5-41astic pad; 6--metal plate; T---holes
CODE: 091 SM DATE: 29Mar65
Card

BU'CYa,'NKO,., O.K,; HIMUMOVA, I.G, [Kurdi=ova, I.H.); TIRFFILOV, V,I,
Determining the activation energy of chromium roury3tallization,
Ukr.fiz,zhur, 4 no.6:813--814 N-D 159. (I'MA 14: 10)
1. Inotitut metallofiziki AN USSR.
(Chromium crystalB)

/7
n- -7/7 2
"S i t n I
j 41.
Kon onov Kurlyll.7.. JV~L
4~
T I' T.I,' Inve 0 t i i on of c c o 0 f
f -.r Ga s 0 1 ine Re lL c! I r, Van 3'.. v L:n 0 -
tall iC..C:3% I kiltali~;LA-)rov e. C o:.-..,;l
nic~_t ion Con-!~,r.-Lno of 'L-.'.c C L_ o i at '.". o
Boili),': `0`!It B",5-12r)o 00 V-0 it I'c 0,
C 3 (So -,c Pvevr,-.s'i ciii a
1i t. kip.'. -1 -0',0 ncftc~- vto-~j -o nr
E.TZ1ODICz'.L: Izvestiya Ak lc:.ii.i N_.,,,k SS';R).
Ot~jejeniA !T,juk,
1950, Ifr 4, P1'. 4~2:~ - 43:,
A1;3-RA~;T: T;,.e )rcvioi,,o (2ur.1.c:,cer 1.2) C,,-:' :..Ll t
fornd in V~c 1:ivor,4-:; oil -f
. ~'j_:..0 _t4.
so..-,c etrilcum, ty,c.,,. T'-.c i:- rC
of t:.c on. V.-C activity (if t*,e c
d e.; c r i., c d in c., r 1 i L, r T
C,,.i-d 1/13 of V-2 Ir. t, c r- 1cu of :7

I r.,.re.,jti ti- on of V,c Pro.- u, Of '-o,,Ide f 0
): Conv-roio:izi c).L , ~ - ;. I i , I i - 0 P at
tile Boilin- Point 12')0 of tl,i. .1 ?,.1-1: o-,. 1
dium Catalyst
I-,.I C,,
of a I I L 14,,.!-.
t,-,o r Vol'A I. t,~ t e 1-.~in - t c f
o c ~ -.11.
12'. 0 -_. * 4
z-t 2o e,
t!JLL'~, bOU41 of' t'.c c~ o,,. t t ru 1 .1 r
,~c al,icn of -.:(!21 s 'U, c, c- on r j i o n
of rc.,,I)erod c,,cl-.~::; orez t
:;I,, j-'3 co -uli'L de!iydro.-:c-~-, t-, on) 0.
o c :3 c
ex 0,1 C, -C7
~.L.r,~!Tinej J~,ined '6-:.e ' r-)ccr:3 -f If t c; f
C e:~ J 4- :!,.),,C.
,;rcoc-ce of cutal.-st 1.2 V,~--:i i:.- t' of n. 1 .-cover
n.2 (14-tin-, 1, j j' 00 j.1 -.4 C'
er Canto~,
Card 2,13 of ramificd ;n:.17Z-Tines.

62-58-4-7/32
Investir-ation of the Pro~lorttoa of T:vt. 1-ocide .talynta for ranolirc
ReforminG. Connunication 3; Convcr.,;ion3 A' Lic (I.-soline F,.action at
the Boilin- Point 89,5 - 1260 of t'-.c Second Balu Petroleum on llul.La-
u
dium Catalyst
Furt'siermore the composition of the initial fraction and
of trio catalysis were determined b~, mean-- of a combined
method.T.here are 1 fi6aire 7 tublec,and 2o referance3, 13
of which aro Soviet.
ASSOCIATIOTT: Ini3titut orCaniclieskoy khinii im. 11. D. Zelinsko,-c Aka-
demii nauk 339R (In3titute for OrZanic Cl-.emigt---y imcni
11. D. Zelinskiy
,, AS USSR)
SUBIIITTED: November 3, 1956
AVAILARIX: Library of Con.-re3s
1. Petroleum- Gasoline rrac tions -Analysis 2, Metal oxide
Card 3/3 catalysts-Fropertie3
-3

-L 1693o-63 Y-,PF(P)/hWP(q)AWr(m)/BDS k-Mr, JTD
S/06/63/037/004/022/029
6a
ALTHOR: Sar4ylova_, _A. N., 11,al I tsev, V. A. TatGvskiyj Kurdy=ova,
1. N., Kuzrietsova, L. A.
TITLE; Absorption spectrum due to photolysis of boror. CELoride with ozone
7-7
-FEERIODICAL; Zhurnal fizichaskoy khimii, V. 37, Nlo. 4, 1963, 9-)9
TEXT: The authors studied~-the reaction of uxWation of boron bromide by
oxygen and of boron chloride by ozone. It is shown tL',.at in pulse photolysis of a
mixture of boron trichloride with ozone it is possible to observe a band of 41780
X, for which the carrier is apparently an intermediate compourd in the process of
the Oxidation Of BC13 to B02- There-is 1 ftguro.. The most imp)rtant English-
language reference reads as follows; Johns,p Canad. J. Phycics, 39, 1739, 1961.
ASSOCIATION: Foskovskiy gosudarstvennyy univorsitat JYoscow Stnte University)
SUBIMTED. June 14, 1962
Card 1/1

KURDTUMOVA,_K.N.; DILMO, $.L. direktor.
Determination and study of VI-antigen in paratyphoid B ..-ultures. Zhur.mikro-
biol.opid.i Immun. no.8:33-36 Ag 153- (NUU 6:11)
1. Gosudaretvonnyy kontrol'nyy institut vakteii I eyvorotok im. Tarasevicha.
f
,Paratbyphoid favor)

MIKRAYWV, B.M.; KURDYUMOTA, K.H.
Structure and properties of azamethine dimstallic compounds.
Part 1. Struct4re of axomethine metal compounds. Zhur,ob.khim.
25 no.9:1734-1737 S 155. (KLaA 9:2)
(Schiff bases)

rm
D ~fu . . 0 V."& , i - . -4 1 . , (,--I n do V :,hori ',c i - - ( d I ,~n ) 11 .~j triv! tu rf.,, _- nul ;o~ a I Lr. a,].,+-
for.-natilon orr-,anlc alll.[a).lnltj corip(-,unds of urmlino:3." Y)57, I,, r):,
lInstitute oE Experimentnl Pathol,).7y and Cnncer Therapy, Academy of I-de-dical
Sciences ='Jll), 120 coplas (h-lLo 37-57P 10,?)

Dissartaticna. Branch of Chemical Sciences, Jul-Det,* 1957.
Vest. Ak Fauk 880s no. 4, 1958, pp. 1.16-117
At the Inat. for Organic Chemiatry lia H, D. Zellunkiy the folloving dissex1ations
-.ure defended: for the degree Candidate of Chemical Sciences:
BUISM, L 1P. - Catalytic Hydrahenolyola of Fumne Mmologn.
KUMU40VA K N. - Structure and Chemical Transformations of Organo-Alkaline
Anyl ompounds
NIWCRCVA - Investigationa of the Kinetics of and of the Sequence of the
Hydrogenation of Couplings in the Functional &ries of Some Hyperoxidic Compounds.
POLKOVNIKOV, B. D. - Catalytic Bydrogenation of Cyclic Hydrocarbone with the
System of lAnked Double Compounds.
At the Institute for Phynicb-Memistry the following diesertationa were defended:
for the degree of Cand. of Chemical Sciences:
0. Abrarov - Determination of the Discharge Velocity of Wickel Ions end of
Cobalt Ions.
LIPIWp A. 1. - Investigation of the Precipitation Process of Electrolytic
Coatings an Aluminum Alloys.
for the degree of Candidate of Phyalco-MathematIcal, Sciences:
WIMINp S, S. - Theory of Diffusion Powers of Remote Eff ect in Aerosols.

7,,~ r i -ILI ~i
7 4
AU'21110113: Mikhaylav, 13. M. Xurdyiamova, K. N.
T I T LE Structure and Chemical Conversions of O.-,'~aric Alk,--il-i Cwipolinds Cf
Anilo (3troy(.,niyc i lkhimicheokiye
nicheokikh soycdineniX anilov)
III. Or the Conver31onu of Disodium- ;.ind Dili thiun-Coi.ioound j of
Benzophenone-o-'&'olylinide and Under the
Influence of All,yl Halide (111. 0 prevrailicheniya-1-.1h dinatriyevykh
i dilitiyevjl:h ooyedinuniy benzoff-~rioii-o-tolili.-licl,-, i benzofenon-p-
-tolilijAdu pod vliyaniyel.-i ~,%lcidnyl:h ilkilov)
PBRIODICAL: Zhurnal Obolichey Khiraii, 1958, Vol. ~81, Nr 2, -pp. 15", - 35" (USSR)
ABSTRACT: In the precudir,-, infornation (reference 1) it wz.,s Z',,,o-);n th~,t the
influence of alkyl halide upon dirietrallic ccm-poundL, of benzophenon-
,phfmYlimide caviTt2;_~ co,,ipliczited eunwraion.;. Ao a ro4;ult
hydril--awinc. - a T)rOdUet Of X-1112titution of twc utom,3 c,.- the alka-
line by hydro,;en utDns - and :7, nu~.iber o.' oubitw-ces forming,,
due to the, to the c:,V'Oor-nitro,~en
linka~;e are obtained: ;_-nilin;_a, ~~-.hQnylated et,'.,Z(lznic liydrocrtrbon3,
LI,2,3,3,-,tt,trLtl:'n-2njlbtit,ne (with th~2 uoe o1.' it!kyl h~_.lidlc) as nell
as t;u3eous h~,dracurbon.-- Par detc.-r.,.dnin, tli, in-fi-L,,(_,rc,~ by
Card 1/3 Vw ar,vIrodical itrlicturp on th.-~ nitroen Ll-,;(,ri the cuur3c of

Structure and CheiAc,,.1 I Conversion3 0z' G-_ ir:i c Al':ai Co:-;-_-un~ - of Ari lc. 111. On
the 0011ver:Aonj o 11, M -,o6iim.- It-A Dili j f ,2 1 i- m, i -
r tl..c In f 1;,~ n Ce G 1,
t" " u rL Lc t 1] :11,- 1 L. t -i 11 i c a n ()!.ti o on u' z
th,~ act.ion ui(jn dizodima- ~--nd
1 i'Lit i- nk, j "I"ont ."Ild ~cnzonht:110n:_-
thc 'ormatim of
u., tc,ncca 't, ir. t'lQ int~,rm-,tion of the cl~_
v r i c 3 :2 ub z, L
litilitim co",,.jound of L.w_' met'rjyl iodide.
,.,L,h(-, -Toduction &
,.nd 11crforti,:1 Lmar t,,,c sa!.,,e condi-
tic)n.j as t!:eJ d,(.,!criwjd fri or,,.,nhJ,, co:~tpounds of
(refcrcnee ConC1110"Onj: 1) '.LIIL preserice and
t'ci~j pcsitior of the ::,,cthy-_j in Ptryl ratdical at the nitro-
n of t1l ,o,
,,,cn atton I -it: !- %ict'r4rm bond exert ccnoiderable influence upon
Vic ccurse -.f che process un,_;er the action rif the methyl halides
ui:on diii,~talllc benzor)l-.Pnone-c-tol~,limidc-,ii.d benzop*.110 none -p-to lyl-
iiii~:e-clurivatives. 2) Under influence of methyl-iodide dim-~tallic
0VfiV,.-tJVe3 C;!.n svb;3titute i~-(!tal atc;.12
v., i,~',Iiyl ,,,oujp3, t1he formatisn 0Z th(- secondary t:.iine - 0-to-
lyl-1 ond the terti~,try amine - muthyl-o-tolyl-
letlh.,,1~t!,Iine. wit1h, t1j,: fcr-.-i;t~ion of n;.An-
t2L, on.., c.!n obj~irve th~. n-littin,- oi' L*r,,(, ')Cnc, in the di-
Card 21/3 liot;illic derivativu ~_nu the formation c.." o-toluidine , 1 1-diphenyl-

79-2- 17161,
Cnumicul Conversions of Omanic Alkali Compounds of Anjl:j. 111. Or,
thu Conver3jonc of Disodium- and Dili thium- Compounds of Benzophunone-o-Tolylinti-
dc ;.,n~ B,~nzoplhanonc-p-Tolylimide Under the Influence of Alkyl Halide
ot1iyL_,nc and 2,200-tetraphonylbutane. 3) Under the influence of
the methyl halide upon dinetallic benzophanone-p-tolylimide deri-
vatives and under the simultaneous formation of the tertiary amine
riethyl-p-tolyl-1,1-diplienylethylamine - the splittin~~ of the C - 11
bond in the dimetallic derivative and the formation of p-toluidino,
1,1-diphonyletylene and 2,2,3,3-tetraphenylbutane is observed.
There are 1 table, and 4 references, 2 of which are Slavic.
SUBMITTED: April 20, 1957
AVAILABLE: Library of Con(;resj
Card

AUTHORS: Bruz, G. I., Antonov, V. Y., SOV/79-28-11-16/55
Kurdyumova, K. N.
TITLE: On Some Eth:710nimino~1.3.5-Triazines (0 nekotorykh etilen-
imino- 1 3,
PERIODICAL: Zhurnal obshchey Ichimii, 1958, Vol 2j, Nr 11,
pp 2972 - 2977 (USSR)
ABSTRACT: Ae is known,for the past 6 years the 2,4,6-triethylen-
in,ino-1,3,5-triazine (TET) has been already used as
a medical preparation a0ainst new jrowths; its use
is, however, limited as it has very hiCh toxic
effects. With the intention of finding compounds with
hiL,her chemotherapeutical efficiency the iuthors
synthesized -already earlier (Ref 1) the compounds
(I)-(X) which h,,tve a similar strrcture as TET, and
have two ethylenimine resitlues as well as a substituted
amino, alkoxy, or alky-1 mercapto group. These coi,,ipoizr~',s
;-fore obtained by the condensation of the 2,4-dicth~-- 1C11-
imino-6-chloro-1,3,5-trilzine with the corresDondiii,
aminos or sodium alroholatnn and nodium
Card 1/2 in iinhydroua oolvents. Some amino diethylenimino

On Some Ethylenimino-1,3,~:-Triazines SOV/79-28-11-16/:J~5
triazinea were synthesized by the condensation of
the 2-amino-4,6-dichloro-1 3,5-triazine with ethylen-
imine for reasons of comnarison. According to this
method also the compound (I) obtained already by American
scientists in another way was synthesized. The
synthesized ethylenimino triazines are white crystalline
products and are stable at low tei,iperatures. Only
the compound (II) is an exception as it cculd not be
obtained in cryctalline state. The results of the
bioloZ;ical investi-ations have not yet been obtained.
There are 4 references, 2 Soviet references.
ASSOCIATION: Institut ekcperimentallnoy patologii i terapii raka
Akademit meditainskikh nauk SSSR ( Inntitute of Ex-
perimental Pathology and Cancer Therapy of the Academy of
Medical SciencesUSSR)
SU-MUTTED: September 28, 1957
Card 212

BERLIV, A.Ya.; Kp4p~~~ u.
I~rnthesis of p-diazoacetyl derivatives of yhenylalanine. Zhur,.
ob. khim. 30 no-11:3759-3766 H160. (PURA 13:11)
(Alanine)

JURDYUMOVA K. N.; BERLINY A. Ya.
--
Derivativex of 2-benzyloxY-4,6-diethylenimino-1.3.5-triazine.
Zhur. ob. khim. 33 no.1:129-131 163. (MIRA 16:1)
1. Inatitut eksperimentallnoy i klinicheskay onkologii AMN
SSSR.
(Triagina)

SOV/8 I -_59-8-2843',-)
Translation fromi Referativnyy zhurnal. 'Khimiya, 1959, Nr S, o 406 (USSR)
AUTHORSs Smolyan,.Z.S-, Kurdn!Toya NA., Pyryalava, P,S,
TITLE: The Low-Temparature Chlorination of Ethane In the Presence of TrUtiators
PERIODICAL: Tr. po khimii I khim. tekhnol., 19-r,8, Nr 1, pp 187 - 189
ABSTIMM It has been shown that the chlorinatior of ethane at temperatures of
65 - 700C in a medium of CC14 contaLr!:Lng about 1 mol. %-of dinitzile of
the azoisobutyric sold M, bi~nzoyl saroxide i.-.1) or dimetll~ylpeircarbanat-_
(III), leads to the formation Of C.2nCl ari po-xchlorosubstltuted
I, II and. III play the role of reaction Ir_.J.1atcz,9 forming active radi_~eLls
in the temperature ranged- indi:at!~d wh.1ch sta_r~, t1-,5 dev-~hjopment of the chaln
proce3S. Thai convArzion o' f .4~than,! In the of Liltlators at a ratlo
of C12 ~ CA - 1 P, Is about _R0%, and at a ratio of' 1'g 1.7 it 'is 81*,C~~k-6-0'56
II is an initiator of more long-lasting action prod-u-ing the largest quanti-
allation for chlorInatlon Is
ty of-f~2H5U. Tht diagram c.' a laboratory !.,r_s'
presented.
Ca-rd 1/1 O~ cberntsov
V

c 04
SAIeV61/000/018/021/027
B103/BlOl
AUTHORS: Smolyan, Z. S., Kurdyumova I ..,--Pyryalova, F. S.
T IT LE Low- tempera ture chlorination of ethane in the presence of
initiators
PERIODICAL: Referativnyy zhurnal. Diimiya, no, 18, 1961, 340, abstract
181,10 (Sb. nauchn. rabot In-t Fiz-ortran. khimil- All BSSR,
no. 8, 1960, 119-125)
TEXT: The possibility of a low-temperature chlorination of ethane in
CG14 in the prenence of initiators was pointed out. The reaction
products are halogen derivatives of ethane with different degrees of
substitution (27-355, C2H5Cit 65-735 polychloro ethanes). F-ractical hints
for determining the paramete2s of the pru~,~_- -nd its realization in an
apparatus are given. LAbstracterfs note: Complete translation-i
Card 1/1

5M
AUTHORS: Smolyan, Z~S.j Pyryalova, P.S.,, S/074/60/029/01/002/005
Kurd ova, N._A. B008/BO06

TITLE: Progress in the Field of Chlorination of Saturated Hydrocarbons
PERIODICAL: Uspekhi khimii, 1960, Vol 29, Nr 1, pp 23-54 (USSR)
ABSTRACT: This is a survey of papers published in the USSR and in foreign
countries from 1947 to 1958 on the chlorination of saturated
hydrocarbons. A marked growth of the chemical industry of the
USSR is planned for the period between 1958 and 1965. The
necessity of utilizing natural and industrial petroleum gases
as raw materials is mentioned. At present, there is a noticeable
tendency to increase the production of chlorine-Bub3tituted
hydrocarbons. Chlorine derivatives of hydrocarbons can be
prepared in various ways: The methods mainly applied are
1) hydrochlorination and chlorination of unsaturated hydro-
carbons, and 2) chlorination of saturated hydrocarbons.
Valuable work was done in this field by Eutlerov and V.V.
Markovnikov (Ref 6), D.V.Tishchenko (Ref 8), foreign (Refs 10-
13), and Soviet acientiste (Refs 14-29). N.N.Semenov and his
Card 1/5 school (Refs 14,15,16,29) are particularly noteworthy for

Progress in the Field of Chlorination of S/074/60/029/01/002/005
Saturated Eydrooarbona Boo/Boo6
their theoretical and experimental investigations of the
mechanism of chain reactions. By reason of their argument&-
tion,.the chain moohanis of photoohlorinationlmay be regarded
an an established faot..;Xrthe~r papers on this subject are
given in references 10, 29-47- In industry, th8rmal ohlori-
nation of paraffins is carried out at 400 - 600 . These
temperatures ensure a considerable reaction rate. Apart from
chain rsaotionog homogeneous bimolsoular reactions evidently
take place in thermal chlorination. At sufficiently high t.~
temperatures, thermal chlorination is to a greater or lose
extent accompanied by pyrolysis of*the initial and chlorinated
produoteo Also, a certain amount of isomerization of inter-
mediates onours, Thust polyahlorides are formed not only by
chlorination of the monochloride, but also by ohlorinatiou of
compounds formed by pyrolysis or isomerization. Investigations
of the chlorination of saturated hydrocarbons is.mainXy con-
oentrated on the chlorination reactions of methane (Refs 100
230304oO-71). The thermal chlorination of methane, which
has been realized on an industrial scale in the USSR, is do-
Card 2/5 scribed in detail in reference 72, The production of methylens

0!
Progress in the.7iold of Ohlorination of 3/074j6O/O29/01/002/005
Saturated Hydrocarbons. B008/BO06
chloride in B%gland and Santern GermwW in t::oatod in reftrenoss
73 and 74 respectively. Yurther chlorination methods applied
in Germany are described in references 75-78, The usual pre-
paration of carbon tetrachloride by reacting elemental chlorine
with carbondisulfido (Rafe 78-79) in replao" d by the thermal
or photochemical chlorination of' methane (Rot 80), A now method
developed in1onanis. is mentioned (Ref 81). The chlorination
reactions of.the other gaseous ps,raffinsl(soget athansp propane,
butane) are less.thoroughly investigated. The thermal ahlorina-
tion of *than* is described in references 5% 82-56l and the
thermal chlorination of propane and other hydrocarbons in
references 6t 19123127#530907-104- Comptratively little has
been published on catalytic and photochemical chlorination
processes. Of thesel the reactions of methane and sthanr were
mainly investigated@ A,V.Topohlyev and Vs?*Alaniya (Ref 1103)
showed that the application of homogeneous catalysts in radical
reactions yields very int 4resting results. it may be seen from
publications (Refs 106r1,11) that various metal chloride@ as
well as adsorbing materials mixed with orushei calcium oxide
card V5 have been used as catalystse In paraffin chlorination, the

Progress in the Field of Chlorination of 5/074/60/029/01/002/005
Saturated Hydrocarbons B008/BO06
conditions required to obtain a certain reaction product depend
not only on the type of catalyst but also on the initial
paraffin. In photoohlorination of paraffins, the substitution
rate of primary and secondary hydrogen atoms is hardly
influenced by the use of catalysts ouch an the chlorides of
antimony, lead, aluminum, titanium, bismuth, or by iodine or
sulfur. The catalytic chlorination of methane is discussed in
references 24,25,48,109,112-138, and that of ethane and other
saturated hydrocarbons in references 11, 21, 105, 109-111, 113,
139-147. The photochlorination reaction, which involves the
splitting of a molecule into two etoms or radicals by a photon,
is of great significance for the investigation of the theory
of chain reactions. Both gaseous and liquid hydrocarbons can be
chlorinated by the photochemical method (Refs 148-174). At
present, great interest is taken in initiated chlorination.
The introduction of materials into the reaction zone, which
are able to form a great number of radicale, facilitates the
dissociation of.chlorine molecules into atoms, thus enabling
chlorination at lower temperatures. In references 7,1o,io6,
Card 4/5 107,110,176-i8o low-temperature chlorination and the applies-

Progress in the Field of Chlorination of S/074 60/029/01/002/005
Saturated Hydrocarbons B008YBO06
tion of various types of initiators are described. The follow-
ing Soviet scientists are mentioned: B.A.Krentsell, A-V.
Topchiyev, D.Ye.111ina, V.A.Nekrasova, B.I.Shuykin, Ya.P.
Choporov, O.A.Tishohenko, Y.T.Vdovichenkol I.P.Galenko, I.G.
Washvili, R.S.Galanina, A.S.Nokrasov, A.Trifonov, A.I.
Kipriyanov, T.Musener, N.A.Pokatilot L.N.Andreyev, S.S.
Nametkin, A.G.Serebrennikoyal A. Dobryanskiy, Ye.Gurevioh,
A.Lemke, D.V.Tishohenko, N.I.Kursanov, R.S.Galanina, Yu.G.
Namedaliyev, M.Efendisyeva, H.M.Ketelakh, D.M.Rudkovskiy,
I.F.Suknevich, L.N. Terenin, and V.N.Kondratlyev. There are
13 figures, 5 tables, and 180 roferences, 53 of which are
Soviet.
Card 5/5

'4-
1'ranslat'lon Iron-1. l(viviativnyy zhurtial. Mel