SCIENTIFIC ABSTRACT KOTOC, S. - KOTONE, M.M.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R000825410009-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

-9/273/63/000/002/001/010
A052/A126
AUTHOR: Koto6, Stefan
TITLE: An appliance for exhaust gas decontamination and noise muffling for
internal-combustion engines
PERIODICAL: Referativnyy zhurnal, otdellnyy vypusk, 39. Dvigateli vnutrennego
sgoraniya, no. 2. 1963, 10 - 11, abstract 2-39-72P (Czech. pat.,~
c1. 116c6, 6/02, no. '101727, November 15, 1961)
TE)G: Exhaust gases are led tangentially through the hole 8 into the houb-
-ie aleeve 9. Further mixing
ing 1 (see Fig.) and mix with the air coming from I*
takes place in the snail 10 from which the mixture comes into a chamber with
double walls 2 and 4. Additional fuel is supplied through the pipe 5. and by
means of the Ignition plug 6 the final combustion of combustile components con-
tained in exhaust gases is performed. The appliance operates at the same time
as a muffler. There is one figure.
Card 1/2
S/273/63/000/002/ool/olo
An appliance for exhaust gas decontamination .... A05Z/A126
Figure
A. Zhukov
[Abstracter's note: Complete translation]
Card 2/2

KOTOC, S., inz. CSc.
Calculation of continuous cams on an automatic digital comput9r.
Strojirenstvi 14 no.5:337-342 My 'U,.
1. Research Institute cf Motor Vahiclas, Prague.

KOTOC, Stefan, inz.
Suppression of motor vehicle exhaust fume. Tech praca 15
no.2:117-118 F 163.
1, Ustav pro vyzkum motorovyoh vozidel,

KOTOC, Stefan, inz. CSc.
What are the vortex apparatus? Tech praca 16 no. 4:261-263
Ap 164.

inthe (Kotoop Stepan]
-.-W
"Thermal processes in internal-combustion engines" by V.F. Kalabin,
Reviewed by Stepan Kotoc, Vast, mash, 41 no, 51 87-89 My 161.
(MIRA 14:5)
le Prazhakiy nauchno-issledovatellskiy avtonobillnvy institut.
(Gas and oil engines) (Kalabin, V.P.)
I#$.

C. i
-n
Harmonic analy~,is of a ~iinctlon from the di-,r,'-ttil coimputer ti.,J)2e.
StroJircnst-~,*,- 21, S 164
Tr
M

YESMMM, A.M.-, x0m.-POVA, Me
Instrument for determining the percentnge of needle ice In a stream-
flow during the measurement of Its diachArge (nendle-Ice meter)*
Trudy VNIIK no-1:19-31 148. (MIRA 11: U)
(Ice on rivers. lakes etc,- Measurement)

KOTOCHIGOVA, M.I.
Pracision of standard resilient dynamometers. Trudy VITIIM
NO-37.-14-28 159. (MIR1% 13: 10
(Dynamometer)

KOTOCHIGOVA, 14. 1.
Solncting thn shape of a rouilinnt body for d5nittmomotern.
Trudy VNIIM no.17:29-41 159. (14IRA 13:1~)
(Dynammeter)

S/115/62/000/003/005/010
E194/E484
AUTHOR: Kotochigova.. M. 1.
TITLE: Checking machines with a group of dynamometers
PERIODICALi Izmeritellnaya tekhnika, no.3, 1962, 17-18
TEXT; The mechanical measurement laboratory of VNIDI has madt~ a
series of tests to determine the accuracy when a large machine or
dynamometer is checked against a group of dynamometers. A varie*-Y
of dynamometers were available so that it was possible to Jieck th~
accumulation of errors by the group method or, transition from one
set of equipment to another as the load was increased, With all
the dynamometers used the maximum scatter was 0,256 provided that
the first third of the scale need not be used but in the fir5t
third of the scale it was 0.3 to 0.6%. It was found that for
accuracy it is important to distribute the load uniformly between
the dynamometers within the group, To achieve this UnifOrMLy
attention had to be paid not only to geometrical symmetry of
arrangement and levelling but also to the individual rigidity of
the dynamometers. It was found that with dynamometers connected
in parallel the deviation of the sum of the readings is 2 to
Card'1/2

KOTOCHIGOVA, M. I.
Relationship between the deformation and the loading of standard
flexible dynamometers. lam. takh. no.10:22-23 0 162.
(MIRA 15'.10)
(Dynamometer-Testing)

KOTOCHIGOVA, M.I.
First-grade standard flexible dynamometer desiRned by the
All-Union Institute of Hatrolol7o Trudy inst. Kam. stand.,
T
mar i ism. prib. no.50S48-57 61. '(HIM 1646)
1. VaesoyuzW nauchno-issledovatellskiy Institut metrologii
im. Mendeleyeva. Opmomoter)

RAFALIS911, D.I.; VUYKIIL'R, Z.F.; ROMIOVA-, L.M.; NIFOLA-YEVA,
KOTOCSfiGHIKOVA, M.A.; IVANOVA,
Effect of tak:Lng small and moderate doses of bone marrow on
the body of the donor. Report No.l: Effect of takling bone
marr.:tw on hemopoiesis. Probl. gemat. i p-orol. no.10-x
-35 163 (HIRA .18:1)
1. Tz Leningradskogo ordena Trudovogo Krusnogo aameni
izoledovatellskogo institutq perellvaniTYa kro-I (dlr. dotsa-nt
A.D. Belyakov).

KOTOGYAN, A. M.
Apiculture
Dissertation: "Apiculture Jn Arrenia and Yeasures for Incre;-81ne
its Productivity." Dr Agr Set, Department of Biological Sciences,
Acad Set Armenian SSR, 20 Mar. 54, (Kommmist, Yerevan, 10 Kar 54)
SO: SUR 211, 20 !;tpt. 1954

USSR / Farm Animals. The Honeybee. Q
Abs Jour: Ref Zhur-Siol., No 5. 1959., Z13Z4.
Author :-Kotogyan, A, M,; Martirosyan, L, M,
Inst Aiiii*~~I';ii~_Sd'_Dintlf ic Research Institute of Animal
Husbandry and Veterinary Medicine,
Title Raising Larger Bees and Their National-Economic
Signif Icance,
Orig Pub: 8yul. nauchno-tekhn. Inform. Arm. n.-1. In-ta
zhivotnovodstva I veterinariis 1958, No 2,, 3Z-34o
Abstract: As the entire beehive was transported to artificial
combs with 6 mm large cells., bees were raised with
a 1.1 mm. longer proboscis, with 30 rercent heavier
pollen baskets and increased honey prnduction,
Card 1/1
KOTOGYAN, A.M., doktor se1'skokhoz)raystvennykh nauk
Comparative characteristics of the Caucasian bee Populations.
Trudy Arm. nauch.-issi. Inst.zhiv. i vet. 4:27-34 160.
(Caucasus--Bees) (MIRA 15:5)

1-~ -, 7- cr , , ,l - ;-I
BISKIN N,M* (Moskya); &=- A-A', (Grodno); STRXLY.TSKIY. R.Y. (Grodno);
HLISH, G.M. (166); UGAN, L.S. (Baku): W V. Ye.j. (Ufa).
"Geometry textbook" by N.N. Nikitin, A.I. Petisov. Reviewed by
N.M. Beekia and others. Kat..v shkole no.407-69 S-0 157.
(Geometry) (MM 10:8)
(Nikitin, R.N.) (~etivov. A,I.)

KJOTOK, N.V.
Interpretation of the spectrum-luminosity diagram for the Pleiades.
Astron.zhur. 37 no.3:492-495 MT-Je 160. (MIR& 13:6)
1. Gosudarstvenny7 aetronomicheakir institut imeni P.K. Shtern-
berga.
(Pleiades)

KOTOK, E.V. - - - -
Age of the open cluster Orion I. Vop.ko3m. 9:196-199 '(3e
(141RA 17: 5)

A ~ -'T *,- K).t:
of o:'. t'.:c i-, or
T IT
s tri,.c t-.,,u-o os to rs %eld a I.- U,
';:o. 1' 3, 103- 0~)
nn Lmor sil",,Cturf, of ~A-T- 1"Old --T,.
T:
of
19 t t s tr o r hy s i c :a I G lb sr va Ir o vLt -,v ii-,.
liri enfis i's from It-,sco-. r aku, Ki ev tJ c4,,- tod.
Lenimn
Cbsorvatory (,'DTI) also Via sclenti'-f-f;
ntill,~- pallors vc-re: A. -,viell,
0 :-). I . 7 oob"O.CV3
!,0v, c7eijov, 71,7.~
an(l -1. Saak,.,an.

ACCESSIM NRa AP3004321 S/0033/63/040/004/0659/0667
AUrHORs Masevicht A. Q.; Kotok, E. V.
TITLEt On the evolutionary-interpretation of the Horzaprung-Ruasell diagram of the
cluster in Orion
SOURCEs Astronomicheskiy zhurnal, v. 40, no.-4, 1963, 659-667
TOPIC TAGSs Orion I clusters star age daterminatioho cold star# hot star# star
evolution, star formation
ABSTRACT: The age of the hottest stars in the Orion I cluster is determined
under different assumptions concerning their evolution. The age of the cold starst
which are apparently still in the stage of gravitational contraction,, is also
estimated, assuming radiative equilibrium and taking into account the convective
zone in the subphotospheric layer. The reenullts show a dispersion in the ages of
the hot and cold stars which is of-the order of the age of the cluster. Possible
reasons for this dispersion are analyzed. It is concluded that the duration of
the star formation process in the cluster is considerable. Orig. art. hast
6 figures, 3 tables, and 4 formulas.
ASSOCIATION: Astronomical Council, Academy of Sciences SSSR)
Card 1/2

MASEVICH, A.G.; KOMI- E -21-- ; DLUZHNEVSKAYA, O.D.; MAZA7, A.
'Me neutrino Iliminosi ty of star: . A,, tron.zhur. 42 xio.21334-346
Mr-Ap 165. (MIRA 18:4)
1. Agtronomicile-;I-iy sovet All SSR i Obzi~rvutoriya di Brera, Italiya.

KOT-OK, tl.V.
Calmilut!ou oV the uarly ntw~,ca ot' ovoluLl.,, ,,r 'Irs With uk'L."'lJos
0 t, L
of 15.6 ;, 20 M!- I , and 30 . A3tron. zhur. J,2 no.6:1221-
1227 ~"-D f65. - ("ICTT?-." 29:1)
I. As trolloMic lies', iy 80vat ... C, ,
A., OSS7.

KuTJK, K. F.
Dissertation defended for the degree of Doctor of Juridicial Jciences
at the Institute of Government and Law
"i~s3ence of iocal Nationa! Autonoay in the C.'.inaou People's liepublic
(,Cain Problems of the Theory and Practice of National ~;on~3truct-Lon in
in the Chinese People's Republic, Using the ~~xanple of the iisinchiang-
Ugurskaya Autonomous Oblast, 1949-1957)."
Vestnik Akad. Nauk, No. 4, 1963, pp 119-145

LIBMUN, L.',J., KOTOK, M.B., GILIDUM, B.B. (Deceased
Technical Normalization, Organization and PlanninL of Labor in Ferrous ,!etallurgy.
Noscow, 1950

KOTOK ZAVM'SKIY, Z. I., redaktor; VATNSHTIrN, TO.B., teichnicheelcLy
redaktor
(Measuring labor productivity In ferrous metallurgy] Ismarente
proizvoditallnosti truda v chernot metallurgii. Khar1kov. Gov.
nauchno-tekhnAzd-vo lit-ry po chernoi I taystnoi metallurgil,
1952. 94 P. [Microfilm] (MLRA 8:12)
(Labor productivity)

IOM"-,
H
I
city of -id 194, ial-
J
.12.
1 '1- Au.--uo', 53, (Letopis 'Zhurzial 'riykll No. 22, 10,149)

and
7.:-".'aly p~-
into c4- r. n a :.P,
U-43'i3, 1-9 A-11 U-;t 5., ~D~touir, 'Zhurrial :'o. :22,

KOTOK. V. F.
Europe - Ecorariic Conditions
Economic basis of the people's democratic state.
Izv.AN SSSR Otd.ekon,i prava, no. 2, 1952.
Monthly List of Russian Accessions, Library of Congress,
Augsut, 1952. UNCIASSIFID).

55M/6
105,2
KOIUKI V F A8
----------------------
Ra7,vitiye osnovnykh inatitutoy gosudaratvennogo prava Fol'skoy Narodnoy Res-
publiki (Development of the fundamental institutions of state law of the Polish
Peoples Rezublic, by) V. F. Kotok i A. G. Mozokh na. Moskva, A~:ademkniga,,
1955.
272 p.
At head of title: Akaderiya Nauk SSSR. Institut Prava.
bibliographical footnotes.

XOTOK' V.O.; CHAYKA, G.V., red.; TWj, A.A., tekhn.red.
[Aid in cases of poisoning] romoshchl pri otravloniiakh.
Tashkent, Gom.med.izd-vo H-va zdravookhraneniia UzSSRj 1961.
209 P. (14M 15:5)
(TOXICOLM)

RUTKOV, V., polkovnik; KOTOLEVSKIYI A., polkovmik
Inculcating the principles of the scientific Weltanschauung
in the studeate of military schools. Ko=.Vooruzh.Sil
3.no.19:56-59 0 162. NIRA 15:9)
(Military education)

13URKOVSKIY, Yu.A.; AVDROSOV, A.A._LAQrQ4UE,-G..A.; BAGRYANGVA, G.D.
Some problems of the overall mechanization of extraction
operations at cement plant quarries. Sbor.trud. Novorosegiprotsementa
no,1:34-43 161, (MIRA 16:2)
(Quarries and quarrying)
(Cement plants)
qN

128-58-4-1211r,
AUTHORS: Boldyrev, V.A.; Kotomchanina, M.S.; Itskovich, Ye.A., Engineers
TITLEt Use of Oil-Less "BTKII "Core Binder for Magnesium Castings"
0
(Primeneni,ye bezmaslyanogo krepitalya "BTKII dlya magniyevoZo
litlya)
PERIOLICAL: Litcynoye Froizvodstvo, 1958, No- 4, p 26 (USSR)
A.35TRAQT; Ae oil-less core binder "BTK" - which can replace the
scarce oil binders " 4 GU"p " 4 GR" and the "S" oil - consists
of 40-4Wa low-melting petroleum asphalt of "BIN-211 or "BN-3"
grade, and 60-55/o kerosene solvent "TS-1" (Tuymazinskiy). This
oil-loss binder has a low gas-generating capacity, and the
quality of castings has improved since it is used; it is
10 times less expensive than "4 GUII. The short article gives
information on the composition of the core mix with which the
now binder is usod, and on the "BTX" binder production proCCOS*
AVAILABLE': Library of Congress
Card 1/1 1. Castings 2. Core composition-Ec,=mic aspects

18:6)

KOWTYY, S.G.; KOTOKIN, V.A.; NMIBAUM,
Iucreaslagg the productivity of
sumption during grinding. Prom.
(Canant plants)
K.L.; NAUMOV, P.A.
cement mills and reducing power con-
suarg. 12 no.3:25 Mr 157.
(KLRA 1o-.4)

Will
no. 8:
arld d i rl i f c.,
i:f 111~,na
upravien, y -ro-iysh1F:i-ny-:1' ,rcdli-i-~Puti
s t' rovc-n i ye 11av: - -a y n i rd n oc) Ec,,, rv, svt L S11
`for
.' -1 -,- 1 Y
S 1. 7,
L C. A
khe::yi-v-Otva ES3"' k"Lor 11'i-
if I I ona "T opi ivnaya 1~l"Inuv t I va 71 e!-,
rc, 'noro E', P. f 3e g i ri ~~n
0 ra
t v'!
"',!o1odnay- prcay~;Iilcnt-
(for

KOT%IINA,,,A,A., inzh.; IVANOV, G.N.., Who; SHINKARFIIKO, P.A., inzh.
Aluminum anodizing. 14ashinostroenie no-4:8.1--84 il-Ag 165. (MIRA 18:8)

IV.-Ijiov) G.N., ir,.zh.,, KOMAIRTA, A..,l-, inzki,, SH-111-KAFINKO, inzli.
UBI.ng n pyrophosphatA electrolyt.e In yellow and whitF-- brorizinR.
Mashinostroonie no.6,-89-90 N-D 165,
(MIRA 18:12)

KOTOMKINAIP-,A.j.; KIRILLOV, V.P.; DZUTSEVA, A.V.
Exhibitions and displays of speoial Items. Inform-.-biul.
VDNKH no.8:3a-12 Ag 163. (MIRA 17ig)
1. Glavnyy inzh.-matodist pavillona, "Toplivnaya. prowyahlennosti
i geologiya" na Vystavke dostizheniy naroftogo khozynystva SSSR
(for Kotomkina). 2. Glavnyy inzh. i glavnyy metodist pavillona
"Lesnoye khrzyaystvo, lesnaya i derevoobrabatyvayushchaya
prmyshlennost'" na. Vystavke dostizheniy narodnogo khoz;raystva
SSSR (for Kirillov). 3. Glavnyy netodiat obPyedinannogo
pavilions. nPishchevava promyshlennost' na. Vistavke dostizheniy
narodnogo khozyaystva SSSR (for Dzutseva).

PIKALEVA, V.Ya.; KOTXIRIA~ G.L.
Use of gas anesthesia in the analgesic stage for the treatment
of massive postope:rative pulmonary atelectasia. Khinirgiia 39
no.7t82-85 J1163 (MIRA 16:12)
1. Iz fakulftetskoy khirurgicheskoy kliniki (zair. - prof. V.I.
Koleeov) I Leningradskogo meditsinskogo instituta imeni akade-
mika I.P.Pavlova.

KOTOIIINA, I.N.; ROGOVIN, Z.A.; LARIN, P.S.
- -% :,
Properties of viscose cellnlose related to the location of the
original spruce wood in the tree. Khim.volok. no-3:27-31
058. (MIRA 12:11)
1. Vuenoyuznyy nauchno-issledovatel'skiy inatitut iskusetvannogo
volokna (VNIIV).
(Cellulose)

SMAKOVA, KONXIII, A.A.; KOT014IIIA, I.N.
Preparation of extra-atrong vincose cord. Khin.volok. no.l:
15-21 '59. (141RA 12:8)
1. Vaeso-.,razrAvv naixchno-iseledovatollskiy inntitut lakusetver,
nogo volokna.
(Rivon)

XOTOMILk. I.Y.; XGUITSUVL, A.I.
Branch conference of the workers of the synthetic fibers
industry. Khim.volok. no.1:65-67 '59. (MIRA 12:8)
(Teitile fibers, Synthetic-Conp
,resses)

15-5~500,1'-5-5530
6 -

AUTHORS:
Serkov, A. T. -pandidate -," Te-nzi-Ica; Scienc ' Kotominal
L esj"
I. N., Bagomolova, N A.
TITLE-. lNew Produc~ion Me-1--hod-1 `c~r V-1 Scose Fibers
PERIODICALi Klhlriicheskaya nauka Ji promi-o h) Vo 1 11, Nr 6,
'
;
pp 730-737 'USSR
ABSTRACT: AboUt 3056' of all tires used in ~Issq, ar(2 '.."Ovn Out
prematurely because of' cacc~a,:,o breal,~do,,--, due to the low
tonsile, and Catigue. stpeiiE7~.-h -X '.he cord. The applica-
tiOn- Of "SLtper"-type cord t-.,ith a break llen--tli Of 35 to

0 - hi C t-
' km i.e. 20 to 25", gher than ~fiat o -he cord
3
used at present' ~Iould incr,,:-a,.,e 1~he ,r~-- i,-,-ileaEe by
15, to 17%. The article descrlbes types of
"oreign high-strength visc~jso (BX, D,,zPont~s
Supercordura, Courtaulds" Tena~;c(- Siiuf,
I I r -0 and 105, etc.)
and gives their chemical and ph.yoical characteric-tics az;
well as production methods. h
C-1 of cations oC
polyvalent metals, partic-,,.-.1ar-1y c-,1' zinc call-ions,
in the forma!-ion of Za nt, hate Clioer:,* is dis-
Card 11cl, cuosed. The v.iscose fiber -,f' ar, linner ccre

i',Te!-j Production ?+21ih0dS f'or High-Strenilf-h
Visco:3e Fibers

a i id ashel.1, c- la t !'c~ rv- L; , I i- ii or fj'.f~ r,-,4"
cr"33 of' ~he Viber and i,,-, 1 ts stant, part.
Z-inc catlm; !v,lth xanthat., I'ni,vi at lw.,-~r-mc~d-'Lary
insoluble compound, zinc ;.ai-i'lhar -much
stable than sodium xan' ha! e; L:) ~~ ;~ -an',- hal auses a
ra pp roc her-nen t o f t he mqc rowv-l I a it~a 't. e s
the- forria-,ion of 1nt-err,-1.o1,2--u1ai cht2,micai bl-)nds and of'
a fine c rystal -tine structur--, ,Dt' ~ne Cibel, shall. It
'1Z. A.
e3tablished
a.o (DC he
Chernistry -and oC Ch-iu ic-J" F."be-ro-Oorlovy
-J 11-ekhnologii proizvodstlva vclokon--

Gizlerprom, 1957, P 364i Vestn. ,
~ekhn. i olkonom. ,
inform. , 1958, tit, -t , p -a'-) ; I( I-i-im I ci~ra , 1,),-- a, "Tr I,
P 15) that zinc xanthal e can Ct~r m oi! I y at cert-ain
deCinite pff values. The thlckri~~ s,-! -C ~.he is
determined, therefore, and cart b e rei~u-!ai:ed by t-he

relationship between the rate's, Lj
P jiff,-13ic)n of t,
he
reagent,,i Into the f'iber, ~'Mld linr~ .'I Of ceiluio~,c-
Y k.. i J -.Y - ~
xanthate. It was sho,.-;n -i-,a'- h, e "~t-r shel I t h, cr: i i e s s
-Increased with the concen~ra-icn zinc and sodliu-M
sulfate and aith the decreaze- of acid concen*:ra-
Card 2/5 lion in the 3pinninc, bat-h; iz in
CD creased al-lso .-,,ith the

Ne,.-; Production Methods for High- St re ngt h
Viscose Fibers
dec-ree of esterificat-ion of' cell~_,,Iose xanthate in the
. tD - J - 1-he all-aii and
V2.3cose, and aith the mainta-inincl- al -
cellulose concentration in the viscose ,-iith-in certain
de I,-. e prii ned i in, i t sThe add lon osci-,i(~ mod iI's
(ar,.ilneo-, quaternary wTimoni,,,,m basv-,z3,
~tc.) to the viscose and the spinning bath 'facilitates
the formation cf a fiber structured ~-hrou--hout
by sslo,.-jing dovni considerably the rate of xanthate decom-
position during the first 2-3 seconds of the reaction.
L
The mechanism of this modifier action is discussed, and
is explained by the formation of insclulble zinc dithio-
carbamate or other compounds ltorm a mechanical
barrier hindering the diCt'u3ion of' the ac.id into the
fiber. The addition of modifiers LI-quaIlly llowers ~he
surface tension of the viscose and of the water in
the spinning bath; the lowered adI,,e--,I.on ol' these
liquids can influence adver--lely th~- Jischar-e of uni-
form visccoe streams f om ti-~e opirinevets,. The increase
in the rate of the fiber l'ormation a consIderable
Card 3/5 lo,.-jering of !,-he cord's piiyoical and constants.

New~ Production Methods for fligh--Streng~;h 7"'273
Sr
Viscose Fibers
For example, when the rat-,~ ()C ap'nnin~~ ot' tl-als'ed corgi
7
frc,ili 3 1
.1115/2/480/1100 ;,,as raised tile
tensile s~renrrth of the cord d~~-reased f'rom 3 .57 to 112 .55
Irg; i.e., about 15%. Accovdi-q,-J-, ~jio cZure, of
- L, - . Ell - . - I
super-type cord can considevably I o rthe Output of the-,
spinning rriachines. This loss can be compensated in the
opinning-finishiriC units PN--300-1'," and P14-300-13 by
increasing tile rumiber of' ~~pinnitii~ pllace!~. Vijeose and
nylon cords are compared and theIr respecti.ve character-
istics discussed. The advantages of 'uhte v1scose cord
are its lower cost and lower loss of tensile strength
at higher temperaturea. The nylon cord has a higher
elongation due to which the size of the tire increases
in prolonged use and causes a crack-ing of the tread.
After 40,000 11cm, viscose card tires sho-.-.,ed a thickness
of the tread t%-,-ice as high as rylon cori -,-Jres. There
are 9 tables; 3 figures; and 24 referenceu, 8 U.S., -[
U.K., I Canadian, 3 German, 5 Soviet'. The 5 most recent
Card 4/5 U.S. and U.K. references are: D. K. Sml~,-h, Text. Res. J.,
Ne'vJ P"OdUction Methods for
Viscose Fiber,,3 tD
v
29, 32 (.1959); J - Ilearle, SSLJI,,~ Lir-cl
(1958); Text. Week, 57, 96D9 (L9',',-); ap- r Presented
at Technical Symposium on Rayon Tir;--, Yarn Procrress,
L~I
Akron. Ohio, :1958; D. N, Tyler, N. S. vlooding, J.
So~~. Dyers arl Coloi1r..
Card 5/5

SIMOV, A.T.; KODKIII, A.A.; KOTOMINA, I.N.; SHUIIHA, Te'v.
Surface phenomena occurring in the system viscose - spinneret -
precipitation bath. Khim.volok. no-5:31-33 '59. (MIRA, 13:4)
1. Vaeso7usnyy nauchno-inaledovatellskiy inatitut iskusutvannoro
volokna (VNIIV).
(viscose) (Rayon) Ourface chemistry)
4k
4

5 ( 4 '/' 7 / r";"; -( ."; -7
Q: -;, ~'
, . - C)./
.
AUTHORS, 1
Serkov, A.. -T, , Shevchenko, A.. 3, i 0 B ',-, ~j 7
1 A,
Kotomina, I.. N, I Konk in it_
TITLE, The Application of 9urface-arti.~--3 Snbotan~:!,j~: in the Production
of Vi9cose Fiber,.
PERIODICAL Khimiche5kiy volokila" 1959, Nr 6, pp 3~ 1. (TTS'-,R)
ABSTRACT,- The present paper lo baosed mainly on '-.7-,stern pubiicalion3. the
data of Phich have, in Oome been :!hock,3d 'by the authorO
evil e7'periments, be by sur-
face-active tribotances io poiznte~ out (incrunt~n --.n the s~';rength
of rificose.-cord by 50-71(yil)~ TM canception of a 3U-rfj_,CP_-active
substance (modifier) 4--1 defined and it3 mm,~de of operation is
explained. There follmis a Fiur-eY of the appii,,ation of such
modifiers in the morcerizatinn, xanthoi7oriat-i.nv, and sp1nning
of "iscose--oolutilons, Ment icn is made of th,~ invent-11gatian car-
ried ~-ut by Ye M. Lev of the emulnifia'.ion --.f orrbrin disul-
phide by aebacic Pcids Pit7 w1vire the itab-in emulAloll
io obtained lby m,3an5 of ac?bacic Z~Cids wi'n ~~ t:~ 7 C-atoma, Piz.-
uren 2 and ~ 3hov th,i effect r~ perol, 11(" lln'on the rate
of filtrbtion and th.,; clearnos-3 of the 1 In This
Card 1/5 conneution giveo the rocult., obtairil_~iii by !,*, -io~,d , ir . 1~auch

The Application of 3urfaoe-active Subatazicr.,J in tha VOO*7
duction of Viscoar) 'i'iher~i 11004//B007
and Goetzo Oef Tho i.nfluc-nce e,-erlv!d by the modifiers
upon the elimination o4' air fr,~. 11f-~ vi _0 di3cusaed!
Oxyethylatei aliphatic amineo give les-- stable 'loam than sul-
Phurized sehaoic acido and oxyi~thyli~lr,,.i Tablon 2
and 3 mention ."'ostern reaults Nef* 1, 2) conc%-rninj, the nec-
essary additions of modifiers and their eff'ei~t upon keeping
the spinnereto clean., rigures 4 to 7 shf- the ~~lffe,t of the
concentration of 11 so ZnSO,,, iia SO aTil-I of notlifirirs upon
2 4' 2 41
the adhesion of the viscose to 'he spinnerets accordi-ng to ref-
erence 11, which was confirmed by experim~-nts Clarriad out by
the authors, Table 4 shows vurious modifiers of '111~eqtern origin
(nmines~ quaternary amnoilium comzpound~3i nol-,!omyethyl derivatives),
which are u3ed for tha purpoo3 of obtaining 9trong viscose fibers.
Table 5, figui-e 8 jhow the 9xj-.?ri1,anta1 recu!'14~3 obtained by
the authors, according, to which amines with ', to 9 0-atoms give
particularly honiogeneous fibers --ihicIn -nly little -n
nater, Tabla 6 shovus the effect prod-oce,,'t 'by the oxye t, hyl -group
Card 2/3 content of th;~ irtodiflor upon thp'prorerti__~~ of the- fiber (Ref 16)
The Application of Surface-active Substances in S/lf33/5~-/000/06/002/027
the Production of Viscose Fibers B004/BOO7
Table 7 and figure 9 show the dependence of the effect produced
by cyclopropane on the concentration of the ooagulating
bath (Ref 16). There are 9 figures, 7 tables, and.18 references,
6 of which are Soviet,
ASSOCIATION; VITIIV - Vsesoyuznyy nauchno-,issledovatellskiy institut
iskusstvennogo volokra
(All-Union Scientific Research Institute for Synthetic Fiberp)
Card 3/3

3/1 a 5/:59/000/06 I'D! 1/027

i,"UTURS, "13007
)?rkov, A. T., ?edurova. 11. N., BOOJr/ I
Koto,~Iizna, 1.- '111.1
TITLE - The Dependeneq of the 3tructure of tho Fi~-,er ori th,~
h a ri c te r io ~ i c Ta la a -. o f t h e '; i s o, os e
T) 1 1, A L volokna, 1959, Nr 6; pp 337 - ~%9 (Ui~'i
3 3 TR The authors inve3tigrited the influence of visco3e ripening,
of its -c-ce-Ilulose content, and of the lye concentre-tion
upon the ot-ucture of the fiber, S-oinnine of the fiber was
carried out in an acid-lve bath and in ~n ammonium-sulfate
bLth, Yor the rurpost, of eliminating the influence of
mechanical factors on fiber formation, spinninl~-,- and the
further tret.-tment of the fibero -aa3 carried out !;ithout
I
dr,t;iinr.r, 9o1_,rmjntLt_*on of t1w, !ij-1.)Cific -voi,-ht of the fiber
y
,3 ca;-ried out ascording to E,11 --M., (11af i of
i~ fle, k
5wrllinl,~ iii according '.o E- Hu*,)Cr', (Hef S
), ;-ind of
.
tne str,_~rtur~3 of it:3 cro32 :3o~,tion (parct!:it~.,-q of tiiu shell
in th,i gection) b col.orin.~ by .,f,, ins oi r~
Of~rd 1/2 dlicct (aril blue). Table 1 shows 1,11c~ influence
A-) Depervt,~n,_,~ of the itrUf;ture of the Viber on 3/18---/59/000/06/011/027
the of the Vj~s,-csrj B004~BOO-f
V~ftrd
f:ho :r-looning oC the vioco-ge, t_ible 2 the
iiffiu~m~!o ,!' tho NaOlf-ccn!.nnt, and 3 010 illf"Luklikut,
Qx"vt-,,~d 'U.y ~-he ic-ollula.3k, ecntc.-nt of tho vi_-~ose
thes,_~ C teritj tic valutini The author:, obt:.1ined the
increa.3in;,- rireni,Tw, int! incro~Qing
~-C611111o,~te ,on~.ent of the vit3eo6e~. thie s-.7t2'!11Jni A. 1_1
; o' t!
fib_-r Tho found., i n
.,ccr)r,i
w: `h if ~ V. Likhaylov -ind N 211 '7,-, i vzef '1)
it ii ~1 8 j "i a 0 11 C o n t,ln t i n t hv v I' o ,I u t i o n IL
INC- viw; obtairicd j1ollininj: ill
ai aold-s.~t 11: 1),: th 'It 30'~~ an 111,LOH-contcrit of and a 16
hours o!,; In fi;, ers -.:i t'., a lo-,-r zvoecl f ic L the
of t~la .1 "or J?10!~th ill thO tOL:,!, oition is
hj.~;Ii,,, - Thoi- -,i t: 1) 1 t i d I I r (? f o v r,!i,- o.; o f w I j;~ h
t1'
Scientil ic. 3t!siir~h
_~!-Union
fns~-i 'tit- "o-c 3-mtheti,,, 'Fi6-2r.3

SMKOV, A. T._;_ KOtOMINA, 1.11. - SMJBIIIA, Ye.T.
Surface phenomena during the formation of viecose fibers. Report
Vo.2- Khim.volok. no-5:34-36 160. .1, (MMA 13:12)
1. Vaesoyazny7 nauchno-iseledovateltakiy institut iskusatvennogo
volokna. I
(Viscose)

SERKOV, A.T.; KOTOICINA, I.N.;-BOOMOLOVA, N.A.
New methods of obtaining the high-resistance viscose rayons. Analele
chimie 15 no.3:168-180 Jl-Ag 160. (EEAI 10:2)
(Rayon)

SERKOV, A.T.; KONKINI A.A.; KOTOMINAp I.N.; SOLOVIYEVA, X.I.
Effect of the structure of freahly formed viscose fiber on
stresses during spinning. Khim.volok. no-5:34-37 161 j,19RA 14: 10)
1. Vsesoyuznyy nauchno-issledovatellskiy institut iskusstvennogo
voldkna.
(Rayon spinning)

SERKOV, A.T.; BOGOVIOLOVA, N.A.; KOWMINA, I.N.; IVANOVA, Ye.P.; GUTMAN, G.M.
Machines manufacturing extrastrong viscose cord. Ehim.volok.
no.6-2-8 161. (MIRA 14-12)
1. Goskomitet Soveta Ministrov SSSR po khimii (far Serkov).
2
~. Gosplan SSSR (for Bogomolova). 3. Vsesoyuznyy nnuchno-isvledova-
tel'skiy institut Iskusstmennogo volokna (for hotomina, ivanova).
4. Spetsiallnoye konstruktorsko-tekbnoloCicheskuye byuro Lensov-
narkhoza (for Gutman).
(Rayon spinning)

SERKOV, A.T.; KOTCMIKA I N - KOLCHINP V.A.
Zinc sulfate regeneration in the production of extrastrong
viscose cord. Khim.volok. no.5:30-32 162. (MIRA 15;11)
1. Vsesoyuznyy nsuchno-issledovatelfskiy institut iskusstvennogo
volokna.
(viscose)
(Zinc sulfate)

SERKOV, A.T.; KONKINq A.A.; KOTOMINA,,,,I.N.; BLT)NITSKIY, G.A.
Formation of the supermolecular structure of viscose fibers
during spinning. Khim. volok. no.5:40-45 163- (MIRA 16tlO)
1. Gosudarstvennyy komitet khimicheskoy i neftyanoy prorqshlennosti
pri Gosplane SSSR (for Serkov). 2. ~bBkovskly tekstillnyy institut
(for Konkin). 3. Vsesoyuznyy nauclizio-issledovatellskiy institut ,
iskusstvennogo volokna (for Rotomina, Budaitskiy).

SERKOV, A.T.; CIIFRKASOVA, Ye.V.; KOTOMINA, 1.N.
Some causes of filament breakage during the formation of
viscose fibers. KhIm. volok. no.4!33-37 165. (KRA 18:8)
1. Vsesoyuznyy nauchno-issledovatellskiy 1nstitut iskusstvennogo
volokna.

L. A. 6?,T101
USSR/Radlo Jdn/Feb 1948
Oscillators
Vacuum Tubes, Triode
"The Limiting Wave Imigth of a Triode Oscillator)w
L. A. Katomina, Candidate Tech Sol, 15 VP
"Radiotekh" Vol 171, No 1
Study of the frequency range within which It to
possible to effectively operate the triode oacilla-
tor. Discusses various fmadamental factors that
determine its range, nal" ly the influence of elec-
tron Inertia, the virtual cathode, output Impedance
(plate resistance) of the tube, electron-optlcal
and geometrical dies W laritlea, and the parameters
of the cathode. Submitted e6 Ayr 1947.
64T101

VOTOIM~A L. -%.
14-14 Teoriya Primeneniya. Generatorrrjkh IAmp V 'flezhl-mpkh Usileniya 11'soshchnosti I
Uinnozbenlya chn3toty M. 1953. 7 L. -o sm. (Akad. Nauk SSSR In-t Radiotekhniki I Elektro-
niki). B. 7s, Otpech. Mnozhit. Appa'ratom- (5,,-52819)
SO: Knizhaya Letopisf, Vol. 1, 1955

KOTOMI17A, L. A.
"The Theory of-the Application of Os6illator Tubes as Power ArTlifiers
and Frequency lbltiplicrs." Cand Vch Soil Inst of Radio Engineering and
Electronics, Acad Sci USSR.. 9 Dee 54. (VVII, 30 Nov 54)
SarVey of Scientific and Technical Dissertations Defended at USSR Higher
Educational Institutions (n)
SO: Sum. No. 5 21., 2 Jun 55

KOTOMINA, M.G. (Ch6lyabinak)j USOVA, A.V. (Ch6lyabinsk)
Practioal work in physics in industribl laborktorlop. Fiz.
v shkole 23 no.3t43-44 MY-Je 163. (MIRA 16:32)

Kolrl~)M 1,N ~ !, .
' c.Tc ot,7rrvationts concerning the wark of Qi-,~ preparntior Rnd
1%
i
a ~,~ ~ rjz. 2
noribly &part-nont!) of' nibbor plimt,n. Kwich, I , 3
no.6.~52-53 - ,I
Jz) 164. (M'RA 17,91
1. Moz;kovskly shinn~y zavod.

KOTCI,II?IAJ S.I., dotsent
Some current problems in the diagnosis and surgical treatment
or multiple ulcers of the stomach and duodenum. Kaz. mod. zhur.
no.3:15-17 Itr-Je'63. (HIRA 16-.9)
1. Kl:Lnika obshchey kkirurgii (zav. - prof. A.I.Kozhevn:Lkov)
Gottkovskogo meditsinskogo instituta imeni S.,M. Kirova.
(PEFTIC UILEij (STOMACH-SURGERY)
(DUODEIM-SURGIM)

- KO TO Nq NA. R. A.
Minctric fluctuation field of a uniformly heated nomispace, Izv.vys,
ucheb.zav.: radiofiz. I n0-3:166-167 ' 58. (14IRA 12:1)
1. Ivanovskiy pedagogicheskiy institut.
(Field theory)

ALI-ZAIM, M.A.; KOTCHINA, R. 1.
3ffect of gibberellin on the gowtb of young tea shoots.
F12iol.rast. 7 no-3:343-344 160. (MIU 13:6)
1. Azerbaijan Scientific Research Institute, Baku.
(Gibberellins) (Tea)

KOTWINA. S.I., knnd.med.nauk (Gorlkiy)
i;;p ome of perfornting- gnstric nnd duodannl ulcera. Felld. i
akuoh. 23 no.1:33-35 Mr 158. (KIRA 11:4)
(PEPTIC ULCER)

KWAROV, A.S., kand.med.nauk;_KOTCMA, S.I., kandemed.nauk
Chemical barns of the stomach and their treatment. Sovemed.
26 no.12:13-16 D 162. (MIRA 16:2)
lo Iz kiiniki obshche-y khirurgii (zav, - prof. A.I. Kozhevnikov)
GorTkovskogo meditsinsko instituta.
(BURNS AND SCALDSIG (STOIACH--SURGEM)

KOTOMINA. S.I., kand.med-nauk
Rupture of the gall bladder following a blunt injury of the abdomen.
Xhirurgiia 34 no.9:109-110 S 158- (MIRA 12-24)
1. Iz kliniki obahchey khirurgii (sav. - prof. A.I. Xozhevnikov)
GorIkovskogo meditainskogo instituta imeni S.M. Kirova (dir. -
dots. N.N. Mizinov).
(GALL BLADDLT-RUPTUR19)

TOTOMMA, S.I. knnd. med. nauk.
Course of peptic ulcer of the stomach and duodenum following surgical
repair of nerforating ulcers; abstract S.I. Kotomina. Khirurgiia 34 no.12:
93 D '58. (MMA 12:1)
1. Iz kliniki obahchey khirurgii (zav. - prof. A.A. Ozherellyev)Gorl-
kovskogo meditsinskogo inatituta.
(PIPTIG VICHR)
KOVEIKA, S.I., dotsent
Di seases appearing after gastric resection. Terap.arkh. 33 no.10!
50-55 '61- (MIRLA 15:1)
1. Iz kafedry obshchey khirurgii (zav. - prof. A.I. Kozhevnikov)
-Gorlkovsko o meditsinskogo instituta, imeni S.11,14 Kirova.
&CMAGS-SURGERY) (STMACH-DISEASES)

50-58-4-6/26
A.will OR I
TITLE:
PERIODICAL&
ABSTRACT:
Ca-rd 1/2
KotomXing N. Y11--
A Squall in the Region of SUEW
(Sbkval v rayono G. SUMY)
1958, 11r 4s gr
'Aeteorologiya i Gidrologiyaq
25 - 26 (USSR)
In the evening of August 23, 1957, a heavy thunderstorm Of
rain accompanied by gale struck " he area in question.
Delting atmosphere (29 - 340C) prevailed before the
i very hot and dry ble front ran-ed through the
storm. At noon a hardly mova U the town
the neighborhood of
cyclone valley (the centre in -agitations . it ranged
Kherson) which was marked by some wave rds of the Krym as far
along the surface of the earthg northwa
high South-east wind (70 - 80
as Nezhin-Smolensk. In SumY, a
km/h) blew at the entrance of the cyclone valley in a layer
long the rear-side of the cyclone 0
between 300 to 1500 km. A ng down the atmosphere to 17 - 20 C.
cold air was extending cooli i-th high-layered cloudsi
At 18 houres or SO the sky covered w thunder-
dust haze turned up in the air. Towards 19 hours d of the town
storms formed near Sumy. In the close neigbborhoo
a wave generated along the idly-moving front which formed a
A Squall in the Region of SUIV
50-58-4-0/26
sort of a turbulent micro-motion with a radius of 30 m. At
19-15 hours a huge ash-grey thundercloud turned up shaped
with a higil top and having a low basis, On its edge the cha-
Otic movements of the torn parts of the edge were clearly
visible. The wind stopped blowing and the first thunders
were to be heard. At once at 19-40 hours the dust storm
rushed over reaching 25/28 M/S6C. A dorn, paur set in uninter-
mittedly accompanied by thunder and lightning . The visible-
ness deteriorated down to 100 m. The storm raged for 40
minutes. The t8mperature dropped rapidly at first to 200C
and then to 10 C. Discharges of ball lightning were observed.
The front of the storm-zone was estimated from 30 to 40 km.
Lots of trees were broken or uprooted in the woods and parks,
roofs were carried away, telegraph poles were tossed over,
and so on. Several houses were Set alight ~y discharges and
burnt down. The development of the storm wa's caused by the
interaction of tropical air and by the cooler air of the
temperate zones and by a difference in temperature of 10-120C.
AVAILABLEt Library of Congress
Card 2/2 1. Mateorology - USSR 2. Storms - Analysis

KOTOMKINA, A.I.
Chemistry is the wings of progress. Inform.biul.VDNKH no.3:1
Mr 164. (MIRA 17:31)
1. Glamyy inzh, pavillona "Neftyanaya promyshlonnost'" na
Vystavke dostizheniy narodnogo khozyaystva SSSR.

GAIZfEVA, N.A.; P-Irimali uchastiyez, PULIPENKO, G.M., raladshiy nauchnyy
soturadnik; STEERMOVA, T.K., m1adshiy nauchnyy sotrudnik; KOT'CYKI'7
-- %A,
L.-V., ladshiy nauchnyy sotrudnik
Production, bleaching, and use of high-yield sulfite woodpi'73
and hemi cellulose obtained from aspen. Trudy LTITSBF no.13 83-
9o 164,, (MIRA 3-8:2)

we 11"M 9 Kraure and Z Kotumaks
rX.M. Warsaw, Wt-4.
ffl) 5 ?).-The amm" (1) and dthydtoucm.
aW(11941
~oi It applaseve" Attbatsperlmentalslatloctol
K
.ae Sclsool of Agriculture was detd. by thration with dand-
ord win. of 2AWieblorophenclindophenot (cf. Fell4nalxTs.
CA. J?. 44819). The vulues varied for different kinds ul
:fVW frous 0.4 mg. % to 21.0 mg. e1c I and from 1 8 NWA
+ U. In aw" of the 30 varietWt the cuncn.of 11 was
Appreciaw hicher than that of 1. comfictrilon Of (he
methods 3 dem. shows that the Official A 0 A.C. methiki
girt* t"rr values than the one ust~l. 7hV SlAblilly Of I
under a vatitty of treatusents I% dismsscd and Its cvnttnt in
hurscradish (45.3 nig. 7fu I and 80 mg. % I + U).
L Z, R.

L 3642f
-'ACC NR,
Wr(l)/EWT(M)/WP(e)
Ap6Oj_%2.8
IMOY WH
SOURCS, CdO38 UR/6051166/020/005/OM/08.52
AUTHCR: Samson, A. K.; Kotontsevap L. A.
ORG: none
TITM: Calculation of amDlifted luminescence in a polished generating rod
SOMCEI Optika, i spektroskopiyat ve 20P no* 59 1966v W-852
TOKC TADS9 light reflection coefficientp luminescence, quantum generatorp noody:dum
glass, ruby
AMTRACTI Using formulas derived earlier for the brightness of noises on the axis of
a polished cylinder, the authors analyze the angular distribution of noise bri Wig
du'o to luminescence, and the density of the noises is calculated tor7a-riov,s sizes of-
the rod and values of the negative 'absorption coefficient. The cylinder has a finite
length, an amplification factor k that is constant throughout its volumej, and an
sivity 9 . The dependence of the luminiscence, brightness along the axis of the rod
the direction of propagation was determined$ and the probability of luninescence-sti
mulated omission was calculated. Concrete calemlationso in which the coeffici uts o
reflection fpm the ends of the rod were neglectedg were carried out for rubyl4nd no
dymium glass%-samples. Comparison of the revAts of rigorous calculations--~ the
results of approximate calculations based on simplified transport equations (A. M.
UDCI 621-375-91535

-77

U
lwt
7 T-g-,-
A0

KOTONP I., starahly naucAq7 actrudnik
Improving workshop a&inistration. Sots. trud 8 no.5%123-126
M7 '63. (HIM 16:6)
1. Vissisoyu2nyy nauchno-issledovatellakiy institut organizataii
proizvodetva i truda chernoy metallurgil.
(SU61 induatry-Managament)
(Rolling(Matalwork))

- "I
KOTON, I., nauchnyy sotrudnik; PATVISUZYKO, L., nnuchnyy sotrudnik.
Reducing the number of engineers and technicians In railroad units.
Sote.trud no.6:125-127 Js 157. (MLRA 10,7)
1. Organizatsiya proizvodstva chernoy metnllurgii.
(Railroads, Industrial--3MDl07ee8)

PEYCHEY, G.; KOTON, I.; ZAMKOVSKIY, V.
Technical control at the steel plants. Sots.trud 4 no.8:
72-75 Ag 159. (14IRA 13:1)
(Steel industz7-quallty control)

KOMNO I.
Wages in the railroad workshops of metallurgical plants. Sato, trud 6
no.3:124-126 Mr 161. (min 14:3)
1. Vsesoyuznyy nauchno-issiedovatellskiy institut organizatsil.
proizvodstva i truda. cherno metallurgii, g. KharIkov
(Railroads, . Indus?rIaj--Sa1fLrie.s 9 pensions 9 *etc.)

KOTON, I., starshiy nauchnyy.sotrudnik
Efficiency of the new forms of quality control. Sots.trud 7
no.3:123-126 Mr 162- (MIRA 15:3)
1. VsesoyuzW nauchno-issledovatel'skiy institut organizataii
proizvodstva i truda chernoy metallurgii.
(Steel industry--Quality control)

46
5 6 1 1 V is 11 '1 is m is is V a is 1 11 Al is a x 8 a If kill VU lip ***#I dume.90,
AIt - CA.-L-1 _&_JL_A__L_J_ A AL. P a A.- I-IL-1- M-SWUM A-k--t
A
G. A, KAWYANY AN
04 A CAqw. (U. & R.) 1, ffit-74(1141)~-Thr decumim. J inetallo.
00 'A "It. COUllids. with actid. of meW VW lannatima of the carmiswilins hydmilitsims
wait carried out with I'll derim of the nortalis o( the Ath group by Ipatiev and IL (C. A.
00 24, 3%77) and d Ilb by 11patiev, SL and DoCilanov (C A. 241. 2W) and is here hnvsti-
fill and
of fix firsim the Its-M. mmpdL of the ty;srs of R.Ifs (R
Pfeil in the
go
00 all
s
o I-
41~
09
of
00
Ofu
of
00 1
0
411,
-
Wisn.
VhClfs) and kf(&Cl (It - Ilk and M*CjfI4), anti " from IfcCla ill heating 24 first,
at U) atm. ill If pfrimurr In Cj14sm4t HtOll, The lid twitic delKafteil fill 11444,41lect 114m).
the wpa. tA Jig insist II&CI, and RIf&CI delwistts on the natu' thus the
triactioti with litCh. NleCJIJIgCl and I'llifel in C.11. begia"s at 32h-N) while in
EtUIUS170 of jig is dtfiosittif Imm Ifelf and 9517. (tow Ms,C.IfjlgCl at Will. The
Selm. f, from IfgCJ~ In water It even SmW than in R(Oll. Similar rmflost in
the absence of If showed no ppta. of lie. The decmillm, of 11bilig and 01hCHIMIC
detruds on the temp. and is lifutt"Ify itide;sendent of the nature of the siolverst. (Ill.
CRAfig Is dftmpd. into fig and (MCII.)i with and without it* presienct of It showing
that the reaction is Purely pyrisigenctia Phjls in Calls in the sissence of H isbows no
mrt!. ~tllg after besting 24 Ism at 27h,', and only U% after heating 301 hm. at.W,
w h I I the sirpri. of fig reaches 90% on brating 1.14 firs at 2,,p, the mirlion pro-
cetilialthus: I,b,Ifj+ Ill -2C4lIj+lIsl, 'list formAllull ol Colff
b stocking with l1bills in ligroin and gelwg. C4)1# s3 j,hN()l by llitralion, while no
tax"
7PbscmAdbeilctected. Similarrrction takes I)hice without the use of & "%Cnt.
It i3 Ammed thzt with the inCmawd temp. the bond between 11h and JIS bectsine,;
weakened and Partially dbwcd. with fonsissition txf free radicak which react with If:
I'llifle+211 1. 2 Cif. +
Its (1111pert and Crilmirr. C, .4. 7, 27,rAl; Gilman, C, A. Imaelb. C. A. 23,
St-"9;andTaykvnnd)-m~,C.A.24.IMI). S"Chilms"Cu. of the tKmdlctwrcn rh anti
41-31, 4 OTAILUIRW CAI, 1,171114,11,41 CtillstFICA11*461
a..
41"41 a" a.. sit
-
USAVOO &1,; IN .1 1. .1 4 4 1 IN M I a 4 3 4 V
-00
-00
.00
roo
coo
Coo
goo
SOO
weill
ISOO
goo
woo
Alist

399, is slupwn ty di~rtwtpt-f 81j.11a int. fig I C.11. evil hearing it with W with.,ui I,
Will "t any other inti-dium whkb tradily gives tA its M and Ila rrawtsvit, at 411 in
jifttv rkairly was slinjild The rvacil,,ol j4 I,b.llg i., lilt)ji
a(l50'.I75'and2tq)'. The and. of CsIlIftwined c,,rtei%IxviuW to lite anit. tJ fig ppid.
while the awt. of the aldchydc in LiOll Ottir the reaction wu Icu than Wed. ackurdins
to the following acherne: Illlig =-- Its + 2 M: 2 Ph- + McClljOll ----* 2 CJf. + 0
Acli. floweret. the proem is intit, coniplicated. and It was fountl that a clectram in
%be rotten. u( Pholig in EtOll had no effect m the 7a of pptd lit; thus the %jwrd CA
the i1rattkvitiv ii itsdrivii4fent to( corecti. An sittin. u( t"taltic US halt al.. no Oviltjm,
On the fr&Ctkln; the Addil. 14 an ithl~11Y~k ALV~V]ClAtClk life VtMflifl Inqtl ;.*[ tO Wit 00
00 W ppld. HS in 13CAling 24 lim al 17"1". a rwi 14 the 41111rhylle Il-ing oiWil"I to vin cb,j 00
hrAtins 22 1 be%
wh& the addu of C&Ilj rrlAnli the reaction frorn 21
V~ pptJ- Ila
00
liv
lit
'

0

0* at had tile salive earct.
tile in'"tigatioll is
Atito In ltr 6111. 1113 MU-i cll,iq~ lit Aw .
00
4 * 00
so 00
00 100
00

0
0 00
00 00
00 so
00
00

00

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 0 0 0 o 0 q 0 0 0 0 0 o 0 0 0 0
0 0 0 0 0 0 0 0 0 9 0 0 0 0 0 0 0 9 0 0 0 0 0 0 4111 0 0 0 0 0 0 0 0 0 0 0

ror ariv'41
m is Is v is p 4 Al .1 -1

AL Kot
e f G
t"
f MiNaw tk ftift litm
1ft
C"
u
0o op
.
fog
o
osay
m
'
JI
8
34&
2719
1
?
19M
d
R
V A
26
1
R
R
) 2
d K
, -
.
atuysev an
.
.1
.
.
rv and
. V
.,
(
pat
.
),
,
;
,
(
00 C A. 24. ZW; U. R, and PAvdamov, C. A. 24,2M).-The them mechan6m of wim
of Wortalm from metfifb~mj- counIds, Was AW" In the MW of M%, which b. al-lwr
00 g 420aritbouidemopm. PbSn was bested In xyla*34 hmatMatin' 11prmum Ole'
*
WI*"71
Tb
i
h
I
%
d
;;i;z4S
-.90
*0 .
ec*nW testittr
tbout t
e We of
at
t
w9
A%stM
no 4mlomm. of Pb-qL%. them 9mvim that the evaction is cattwd by It trdtwtkm and not
' -416
09 RONAUM *T Pb.44 um*r It M-
urr withmit a solvent
00
00 Produced CJU "tetame Fa.umbuwd Ph-Sn arA no Pth, The-chrmtofthtfvaction -
00 ~MAY be compAved as in the came of Pbdfg thus: PbAW ---a- 4 C&Hr + So; C#1fr + Hs
CJ1
R
00 a
4 +
; Pb.Su + 2 Hs 0- 4 Wt. + So (R. end X., loc. cil.). The intermtediatv
00 fOmAtim of fnv Radical Ulm- was demonstrated by hestins PhsSn with sWrmu which
nuzditY Wit Off thtif ", thus WOr P"uced Sn. CJI. and Me,CO with MerC110". SIR
and DIII with
111tclW11 VA So With
tetirsu
n.
CHAS. PLANC
.
.
.
.

o0

06

-400

go 'APO
00 1
00 3
_"i C" 11 too

~
so is L' n I K4
1
l
91 pt a a It 31 4nl
0 0 Ipt A
t
?
-
4 0 IS 0 0 4 0 0 a 0 0 0.4 a a a 0 0 0 0 0 0
i *
'
o 0 0!0 to # 0 0 00 0 0 0 49 0 0 0
48 0,0 0 0 0 0 0 0 * 0 0 0 O
"I

IIIIIIIIIIIMM
604 0 4 0 Wee * 0*0
,a 00 go *0 *so* 0 6 00 0 9 0000*0*04090e4offi
is V U )d is is I? a do 41 a il #A one
12 13 W It I# I? to t-1--I L A k A 0
A- -E~ 0-m- -I. -k-fil-1-1-LAnA
$1 0-- I.,)-r,~Dtol
AJ
00
490 .4 , .
Ru
Of th~ 6841 of hotd"Kydk arsemic derivatitIss. G. A. RAIUVARV AND ;_0
hi. M. =116. J. rOm. C". (U. S. S. R.) 2, IQ9,3:Xlv32)-. cl C. A. IS, IKJI: 16. -00
1934-Theltshilityof the rinpoldihydrophensmuine. phenatanine anti liphenylenr -
ars'ne combined -th chi-falam XM Aninic acid, was investigated. By anal.gy 00
00 A Pwihtchnolioa-icsi~nto-9-1"lbydmphen&nm'ne (1) (Zeidt SM Gorski]. C. A. 24. IV) chlogto.
M) mW diphenylenedderoarsin, (M) (also the non-cyclk compts.. sucil -*G
"m'i'n1g'121CiT' rieac)t)1o&nm "C=Pd- 00 beating with IICI with liberation of AsCh by rv - .00
0 1 of sy-utbuis. R(CA)sAsCI + 211CI =-- MIR + AsCIj Pb,-
Cl + 2HCI a--- A2Ch + 2CsHs. (a) R - NIf (Lcwis, Lawry and Hcrgrim
~, L-C"!
IS, 1720); (b) R - 0 (11ficke. Weinksuff anti Hargreaves. C. A. 24, 1628,.
single bond; W reactim of synthesij (Meland. C. A. 17, IM) AsCl, +
3CJ-14 ---o- PhsAs + 311a. The dtcotnpn. proc,,eds at 125-2LW)* in the following too
00 onder: phenarsarine derim: 1. lf)ibtom2,7-dimethyi.9.1&dibydrophtnaruuin,- z0 0
(V), 10-chloco-9,10-dibydro-IZbmunphenarmuine ~Vll) and 10-chloro-10,10-tithydro-
0i J,+bcasophenarsaxine (M), then phrmoxchloroamne and diphmy!cnechImxvnine.
WO V For the syntbc%is of b, t: sm! d was uted AsC4, which with equal force Catalyzes the
reversed reaction of decotopa. Arsink addi am decompti. on heating with 1fj0 intfo
'I ago
0 Pb,R and AsQOII)*. The reaction procretis more easily in mid stAns., while the salt.
00 z ofthe acids are considerably Inom stiable, and the addn. of alk. Wts retards the dectmilIn ::0 0
09 2 'Ube results In the &-ompa. of Intrious cyclic adds showed that the stAbdity of the ring, 400
M-zj changed. phenexarsinic acid (VM) being most stable followed by diphenylemarsinic
(IX) mW them phenarnzinic acids ( N t
X). The cyclic aninic acids are kiq itable thall
the non-cyclic acids. A mist- of O.OU2 mol- of a chloroartine wul m. CCt. (CmtS.
5
00 :j
too Ez 0
C
ETALWFICAL LIMAI'401 CLAIDISICATI 10 too
L Jj a
A
n
opto X61 Nd Wil "rtjf
a 0
* 0 0 * : : 0 0 0 0 0 * 0 4 0 o 0 0
0000000i00*000 6900

9 0 0 * 8 0 0 0 0 0 0 0 0 0 0 a 0 9
0000000000f00000#
00
00
of
90
0 04 0 -** 074 -0 0 S 0 0 0 0 0 0 0 0 a 0
00
.00
00
00
of
0.10A mck a 110) was heated 24 hm In a omW %tAm tube, the rux" wm thra -11AILICU
with N&,CO# to bydrdyte AaCfe and f1traW with 1. Optimum dc~cnpm.: I without of
caWy%t 57 57g at VjO* with AIC4 M at 173' Orsini6mlion); VI OJ 5 at 175* and 8K
at IWI; ifil X;5 .1 i~)' W 97 at 173'; V 16-4 and 441.3 at 175% U 4.4 and W 5 it
-"W'; 1U 24 and 49 at 2110'. A mist, of 9 g IV and 113 cc. of CC4 satif twith
heated 48 hrs. at 2504, Prucludat Wis. AsCh and resin, Arninic acidi ('/,t .0
heated with 100cr- ffrOor aq, alkalies In a As tubc tuid" ret-t4urv. t1m inxts was wailied
with alkalki. water " EW. the &W. %An. was ejiW. with Etc(). m4ofe ao4. the attinic
a6d filtered off. dried and welshed. A0011.4 and Ai(oifi, wrfe detJ rho ~th.-r
ext. of X gave Phs,'411, in. 53", of IX, Ph,, m. 70'; and of Vill, which, tr~jt,,,J
with fir in CSo acid tmy%W. from atc, in, S14', CHAS, HLANC
0 0 0 0 0 0 0 0 0

::: 0
'00" W~Uverl=t 00000000*000:
I t u a ii w is I) is j n a x V 9 1 It u M Is is v up! 6.1 CIALI Waco
If
lion sad beem(nat6w of Woriseydic arsivali; derlyalivive. 4; A 14 %,vv Ii-
CAwiss (if K S, 14 12, "1 W(II6,121, rl 1' .4, 27, 9-41
ClibinphrnotaNur (1) ancl dipheavirvierMic-aralut, (11) subjCCted fit 1111l't facratt"n
prv;AIu&-t the nitrates of pbctsortusrv~nk- and diphenylene. -09
arwaic ", ft"HAAXOMMMOII. vvV. A visore aitratiov. of the chlota-
a!- Mines and the corrr~vondkc,*" resultet! in dw = of 0-diftitrit Ovidl Uith 00
00 the probable ~xumlm O(CAH&N(hWU(:O)OIf and (CHANCk),A-(:O)OIf. IfirsnaJivy 1-00
with nan-i~ chWcovirvlaft I aM U 4M Res, the requiting halo "m twins caily
66 Al hy1froly"d to the coole -64h. Qw4malletcl + 1110 . WMAM .00
(:01011. th lik b(T c 104Moto-9, l6dilsydriiiiheisam sine (111) is Ism
00 t Oxidized by HIN a an = UlTbut 114mis mono. and dinitro derivs. tif chlopi-
"ne, while tbeactiostiol 11rcausestbonotumof theheteracyclic nucleus with forins- moo
t1ono((CsIf*8r1IN'If. These reactio" led to Ilse proposal for Ill*# t lit hillaw ing -true-
09 tural formula
H .00
j + coo
Cl
+ ~r,,.O fl .0 0
so
0,0
00 2
which Served'as esplanisdon of its colocing (Kappelmeier, C A. 24, 2W; Obvin. Z:9o
johin" wid Vining. C. A. 23, 107). The specific reactions of III may be ch~cristk 4,00
r of the Ilvacral livaperlies of the phenarissitine nucleus wid other "vs. of dihydro-
go 11 200
phruarutine (ewept the tertiary "nes) might rew Amdarly rvxurdlets 4 their
coloring. The colorless 10,acety14,104hydropbetwistitine (IV) reacis anAotlou%ly
to 111; 1. 0.. the, nitration of IV In AcOll produced a ppt. of mono- and ditutro i1cm-t.
of IV wid a sisin. of dinitropbenarisaiduk while bromination ftiulted in the rupture
of The phenansine ring. CWAS BLANC
oleo
7 :7 its 0
jt ..t 1~1
Its")
�0 0
U 11 A? .0 it to it u, u, It as It It 9 U jean Italwn 1!14
0
00000~00000*0*0644040::::ieoooooooooo*oooooo
~105404oooooieoeooo#060 60006 is -*0600410000006000:1

Arl

0 0 , 0 - 0
0000006
6 1 1 It It u Mahvistfaila 41 M As V.0
AA f., A-L-1 N F,-Q It I.. I - 9 -Tr- I-I.. AA 0 CC W U 0
4
Iu. OW
00 A -, , . i _00
00 .4 il" L rg'=PCkt: -00
0. A. IVA U. It. Kam. J.
I ~. IL ~- W.) 4. 447-32(19U); "d. C. A. 37. A313-14.- ~41 4
I'd -w-liftlesl decampa. of P-twWhated PWis in the
00 st

00 811

00 4
00 C! folintring In-alswe order: --cijf" U-CA. BrC.H...
I"OCAIf4.UeM.H4.Pb.PhM. Tbecontpels.arefiat
lvcnrvPoftd into Inctals and radicals, the latter unitins at
the Iturfam of the cataylt to Pb. eamods. The relative
lKvd a( decompri. of (a-CmIlthlig is al-o givcts by the -0 0

00

.00
0 111 ri

Of j

00

0 above scrics; Cjokip is fanned at the expense of emne C,ollt
groups which are dehydrated to C. The relative effeviq

of catalysts in sk. am. in decreasing ard", Pd, Ni, Au.
Ag. Cu. in tetralin Pd, Au, Ag, Ni, Cu. In ak. (.-
C..Hr)Jlccivu RUcompds.; anothercomptis. treated give
RR; ir- tctralin hydration alone is ob~rved. 16 tablrA
give the readim of expts. ZU. c4cwum& of had and

-00
I'l =00

0 zi
--
of 21
00 f

00
04

Of
00 da. M. M. Koton. IbM. 6&3---.-Ph.Ph (1) and Ph.Sn
(U) undato d of pa. at M' under the catalytic gctitm
of metal filings. In the ab*nce o( It the tcIAtjvt_j1a-'
creasing effects an the decampa. of I ate rcptemdMI by
the serics I'd, Au, As. NI and under ptmute of It by I'd.
Ni,Au.At.Cu.
oIncryed at 1501, but 6 complete at 2tWr"zfdkv4 4 the
nAtuteolthccatal"t.
Tben42tivedtcrraAiigeflectioi"ta-
I"ts in the caft of U. In the abomce (A 11. are I'd. Aft. Au.
Ni; in the presence of It. Al. Ni, A& A u and Cu. C. If.
resultsfrom bothlandUla thep"senceof Ni, while with
0

-:0 0

-40
0

6
%o 0

.00
'
00
I S L A
00 I'd Phi Is formed; An stimulates both reac6ons. In the
W A LLL'rK A absence of H Ph. is formed in all cases. G. Tolpin -.;o 0
It'

tj AV W3 LS:
ooeee**

0 0 0 0 0.0 -71 Z;7
-- --

It W is tf It
M A# K
*Oooooooooooeo0
0 00000 0 0 49
0 0 0 0 0 0 jo
A, -I I W IW A& 1 4 7A~

Is
00400000011040,1*000000
0 0 0.0 0 It 09 00000 490 0 0 0 0 4111 0

iv-*Av 0 0 a 0 0 6 4 0 0 0 0 a 0
11 12 33 A b ; 9 u u Is W 11 a 0 onre
Ayll t IN I I I It 4JL- A 0., 1_1 4_ p -4 J--1.06
t--s
tow
gr'G, A. Ism,, M, V KrAOR, A G". .
-
: :
.
go ICAW". (11. H. 14, R.) 1. iml A IOU): W Ir. A. No 9710;
96 39. M1,11anher n evW.-Oft is furttlo;hord to the
!l -
the III 41mys. C4 fill. Ph ¬ -00
00 of the i v He f. accoodupastiord by an inirimeAtoodd,,
7 a
.00
0 # Ph fadiculdo, which the" retul with
fooorm6lidoort
valilu. cludspotoo.. while that 4 the 1"W (14,01.1.11C 1. -41114
00 a puce pyvactwic torwim. Phjig with tl,hNll), hi
so or ligroick. whits bested s( IFAP for I" hro.. nvxted IM!"
PhNIINIIph
Pf
H .00
ac, ng to the (MMtda:
g +
%
0 * .
2104M + Ile + P%N:*iP%. P%Ifc, horatcof with toivitivl
'
'
00 -1 14 24 hn.. setid. 74-ili)
~ If K
:nd isanwraw at 250 WO
not gAvr -it isissA. stolid devompti. prLdolticto ar.1 no,
69 j coolf.amptiv. Amilar readtloarforolptamorit with pl"144.
00 atIZ5-!W*. lividently to dsesecosse-s the free Ili sad"i
teact with the tinissid. corvapdoi. with the famaiian of
00 prAytort-lialicst pitod1wo arA out the soldn. "11111141%.
'
00
00 4 wrIA. IIS ¬ Gwin"I a
11NIIS with 2-faroornor at 311D -
iyt4k-^v 1%%ol even .. loorrhiahlir po-C.11,11s fort. IfirliA,lis, 400
lt,v. 88, ANN lMk%)). 11MIC014 with 11.4), lorat"t .1 175'
00
tow 48 his. at SO If atm.. was sm,,,dthly Ar. -.
voccirtling to the rewi(xv: PWIfcOH + 112 - C.H. + gee
e 0 [IS + 1110. A mist. to( Pb.Pb with 5 hmtc4 at 1.1on' (w
1
1
1
00 4),
h.
piradt"t (1
2-4 lon. and that of Plid.% with 8 st 211
*
ArAl lots aft" 1
004. "ail. ~MC110*116 with sthrat"t of
"
-
'
'
I%S
tlilll
bC11,10, I
IWO4111% &dAt it IN)
to* I Ilt., 94VT l1
Chat. IllAne
00

LOV(041~111 CLAWIKATICk

Am L s a aw a
I
-LlM I ..
it rc if 'I do i v s,
to 1, rp of a
~
0 4 6 a 0 0 0 0 4 0 a 0 0 0 0
0 0 0 0 sees, so-**@ 0 see : :1 : 0 WO 0 see 0 0009 0 0 * * 0 0

WWI
I , a
k
i
I 1-
a w t, 12 13 is Is it a at a a -
I$
n It Al U him kumpooloumsee
A A -a F IL AL -1 -t- so
-

00
CA The AlutboWs of sclefs by the dohydrogemAlion, of at.
NI 'M lim-i
lUctiv
11
90hats at QMS&tl
N
pmattee 0
.
.
,
,
I
Cho
d
J
l

Os .
.
m,
e
I hX115).-Wbeft FIOII is pea-vil at 27.1V inul A we -4 U, - v
w
.
f
cr
at
.l
It
t
CU
l
t
CuMAO
M
i
ver a
,
.
c
a
.
n
y%
rg
, A
1wr
;
4
FtOAc. It the KAA 11111t.
-~tg- CU5. Cc. it sly" X1%
i~ IM."I 4 tim" "Ves tb~ ~Iiilym .1 2N1" Ow
sit 407. HIOAv. !M% ArOll and I&A% AM. 1,.,;s
00
c,4unitts uf vataly.t give better yu.m. 4 r-tri. rhe .
17 catidyst IV vM stable atut can be rccritefatel r&mly by .00
p&king air An't thm III ovrf it, Pike fesilk arr
t:I else
'
taiturd it Ilic c4taly-t i- posed. or IV (frittmilctl ml 10 'c "'
-d
r
b
t It it I% d
it
l
it
k
l1
Th
C
00 -, we
v
w
u
rj"
i
ar
.
mi gramu
e
,
-
*0 :;1.1n, 4 11,0 So the EMU uw%I ~ivrrrs fl- wihf of estrr
O
A
4
h
l I coo
, -A
atul
t
e JIMAY-jr, Ar
l
it ralvit that (
YUtC the COIAIVO. Whih- I-Mill, IWAc atul MrClIO)FI),

'so
00 and HoOAc (by1wrialwi. t,( the vr4ethmi lkwr spi od" I
, on It. It is theirf1p I In keep a A& rar-s 44 I-M)),

.
1
d'o
10 ~00 i
PdWand loo-DuCH under
chmbor
o a
i
a
a
h 09
r on
.
n
w
10rosent in t
e rwAl
g
s4p
Ki
b
f th
t
t
f
ld
t 1
li
l
d
i us
. '
#0
J
! em
z
e correaponi
ng en
s. o
a
roactla
a
es.
ou
o
to yie
9* o :;
not sly* good yields of tilstore. the mochanim and possible nose of the" re-
00 1!
sations or* dismesed. X.M. Loiceater

IDA

Is 0 S!
0 0 t W-.5., M
- 00
U U IV
0
of, 0 0 0 41 0 0 4, 0 a 00000 00 0 0 6
6
'
4
10,14
s 0 0 0 6 0 0 0 0 r, 0 0 0 41 0 0 a 0
0
0 O
LA-G 0 0 0 Is 000 * 0 *1

a 4 1 a I a I so it 11 is U q to to (a 1, a JM# J~ 1y ,1 14 !411 lit) J#n ism istia, A) U it of 040
so A I ~ _;J I F 1 0 1 d . --A- it- ?- a. A f.rIt-I.A_401 ~C &0 It
F Vt'. --rit 11 -C,
0$
--------- --- ---- ---t; -1
-Now "ath"S at (cacti Milleta If. N. M the formation ot AM (3M :D4;1%) &all "if p).94 ~96
I"-
go At. Kotcon Ittid S. 1). W'dink, Ort. 0-T latt" 6 (tertocif at the ""t of file -A i
JIUVI tnirl~ I-T Will 0 VAIMaistif Ilk. over a tatalyst calodyst, Ike yierlds of Acolit are tin-mitsed and thow of
of under atin. tel"MOT at Husicli,- tmp-. Witt- "03'1 Its a AM sail AcOlf ate hicirast4l, Witle greater "n * A
WOlf (1-&07~ 11,0) tite yitM4 4 Ar0i-3 anti Arlt de.
new per -rdut,. 'Ulm cirialli o( a ifitioW study of tarkwit
NW Ukaw of AWII i-ortriaw.
'in" The 4d
hictiwo -tictiol the valtilyix atWi11%k*tkaA id 81.01111. "Van verse taw
00 telt-110011, saul their Illixt%., out the mccktlu- its the dilrit. above lo"'s, lit(?. `Ubc Use, "I
VU011 and I SM H 1.1111duffitrially IM"-J with the liviii. 4
94 um itel Use Ireirtkals air distia*d- TIW -tAJY94 Will AtoKt 1, AM 18, acetal 3 and Aroll !I'-* witis 4o- 00
Alodlik4of dfqjviiw a sign. 4 Cu(OA0t HIM (by WO fir"rMed. The effect tit
P' b~ 411111i'd. N&Oll wit
4 CC(NOO, into a hAA M. of the reaction, an the cattilyat was stuillcol fly rieridill, fillit
s"' -2
1; do-, ,be. palbed p9t. at 105' &M r-ditrisis it with lit Kahlbaum AcORt. AM, .4coll and sactal 4n-cf it uu4i"
at Tb* .0.6tution of Cu(NOs)s for Cu- the Co"dowl of C&U]Ytk Cotcrtficitt"I. AtOFI anif
J: MAO, in the Piet-n. of the catalyst gave W-liat restUlts. sacetal did not Injure the activity ol the catalyst. Alt,r "0 0
'J: 1 he optialtion t-n.116KIA of "Icrifirati"n ate coctiluctioure 4 r"imulationti of Acff tht ristAlyt
. i I~evanv coated with a 0
ill rateatit"I odvc 461 A sate tel 15 CvJhr~ at IS5, awl M fib" of 4 reshlauts matter. Acillf and cerotonakthyt6.
OW CS11.) all 1hr catalyst in a 510~ tube hiratk4l et". Milking Its arlivity 41M.. Attempts to vreettivate, tW 041110
V
trivally. In it ~jaglt out, iAi% litoll gave AcOM .
*91.7. catalyst have Jaiw. Cooduclitig ArOll In nsixt-- tsith
AcOll 6,6. AcH tit, SiTtAl 2 AM 9" 4-3%-(VMe` 111) Mile Acil of AcOI(t over the catalyst circulted. in a -h4op
ia ~*Iloag
tiy 5 m*culiatiom of the coculralatC the yields 0114)lii d"Itraw of the AcOFt yields tat"ittic ol the "invers"i uf
III were twIres" to 45% and of AcOll 1.) N% whole thtwe AcH into par"hyde and the atitemptioti of AcOU11 on the
J ~
14 AM writ Mlix-ect to II',-V dth 20% All Ktoll ull. surfacir oil The estalyst, preventing cotiWit with the A.
M17, Ill i
,06 changed. TIw activitV -4 (hC CdOtt"t 11 VM4K-"I ;rs 1`111,011 and i-,o-HuOll gave JNC(J~Il Lni) 2--T,
4! 1#4 dare, and StJ% in LA d&", and 6 F-t0ml at M Wo' 24 34.4. FirCOflu tit.6-19-04 and gas I;%. 'A*
C116
i by oxillseticen in dry an and redu0i"111 in It- The method In corstrast to EtOll a stsbe"acut revitculettion ow
oi irsirrifiCAtitYll I1Y V'Onli"110"s Cit"Atlia f"8 h".) condensate gave no increase in ester yicl&. In the r,trit.
60 lvtlwtt% the formatime AORt (5 2t).9%) and imr-- firiatim of lnists~ of FIQOH, i~RwCtll and EtOll in vNi.
ow. Ocoucerti(ocaq. the won. a( "ot theist lit feat tit*
A I I L A MITALLOCICAL kilt*AIVNI CLikitsFiCATWX t
1.1-M .7t C- 4.1
&-a 'i-j-,
ff [fit: trc:n 'Raw fictet I'all It I a
Ana
a 4 0 0 0 0 0 q 0
0 41111 0 0 0 41111,1111 0 0 0 0 0 9 111 4p * 0 0 0 0 0 0 0:

411 In the'",mit"tc is diflik-ult'. (M the 4 IpKw4hk
nd MON
Fi
b
t
4
0
0 a a
u
yrdi
.
estets AcOEt, hu butyiete,
t
the letter predominatitt. The YW& of UAW "hyd-, 0
00
00 adifs MW tstm (10- 21 %) are mean frSURS (Or the "-
The He fraction oil UW S"uw* Mbbec
i
l
i
h to RoOlf. and this reart* with the A,4111, giving Arf)llu.
TwAndo
ic
l
U
f
h

06 v
g
sa
a
m.
doctinn lisiv resolts simidar to than of ftOH. V= a
- o
t
p-
t s"wais W q" Weeje 00
g
b9F dw now Motbod. N. M. Fkfsel, 11, E . Ifel'sus mrA
'
so
so I't Ifarl" Save a lasp 14 44 WM4 Mlo IST
t" M MW
WH li
1 W , Called
4W the S. L. W
chuk. 11-4. IIC 7-All iiiiiiwiant ph&q" tit
-
th
i
d
i
l
d
-
t
by (be ilecumPa. 0
. e
u4tr
n
a
tit
Iwo
tion of AcOM anj fecowty nif be. 00
,

00
subs"writ dovop", of 161fteo, into AC0111 Wd (NII,
IM
howil -in I 1W MINIve Iffrohnif Orr Oful
4

it the ditAn. of the 010(ign"tc of the utoll tatet'Willits" 90
air twtir"fink- with wheinatic futogy outlay I*
there we formed ascot At (I% r." there
71,c
no
A t 25% Rt0H cont
d 7
d ,hown. Smv the wifrtjlsl~m of the -iftsir-tun rdwdlect. 041
I -
i
fi
i
1
s.
l en
distila a mist. (
2%
distdf
H it raw l
k1kh
&
A Ate
s
tilwart
cal
,ccati-e -4 1 he luoivining 14 the rs(xly%t 00
i
h th
AM
I

11
,
c
.
WW or
s
y
y
Auttallftact b. sp. tp Chico
ptil
181
IM
I
1
1
w
t
e
t i- jrfjw,-rdJ the AcH at D112
,
V
atut either rediscr it with (fit, wwor if ere Ftol(,dr asidise so
i

: 0,
1.
s post
of AcORU. Tbf final I"M
,
,
l
i t with air I" A-4111. On the Ita,k 4 recirrislati-iti -4 9111- 00

1
0 it"
sadi
AcOlf. Them I% no 46111 - ue, "W Changed I?tf)if 1441-70)1 Von "W,% Will git" In a .4"sk
tjW reaction 6 thus inurprcted. (1) EtOH ~ AM nut Ac()Vt wilyeiit 1707d A,4)1-.'l + 25% MOFI) 16W 01411P. 00
00 It.; (2) 2AM - AcOIRt (Tishchraked. J- Rudy. NO
-
= Acf)I1 Wil. dirrtal 491 it antl If WO" 12.1 hg. 00

00 4K. IW4); Ac4.)Kt in tic at%% (..Cnwd by
C",
7 62-. Plant-
Ad W (3) Iswinatiosi of
feacaint than so
&CeW (fum Aq:If andl KIWI to the turwice ill A4011 :

0
Adf + FWII -# MCCUMHO, -f 114) Irsdruther, 410M. 00

06 12CM0141130; actiall iticli DAY be CAWOL-Ally &TW'Pd-
inu, AM, A4-4 olit. 1*3011. Of. sto It: (4) -P-4-41, the
66 %ckwt with 11AD Attained in like (datuat" dill aLvtd Ug
c,,ntained in &k,. The houlatitm .4 a fittIr A,01)u in the
so nterificatkin ut litull U'SY be'explitiocd by the Ivad--

00 olifith off 114) 1!& CW-
tion ot AM hil'i aldw; " h
d
d 00
uce
1
VcyW into ctutjjjajdkhydv, vu - s to a I atm. re

of

L

T
e
Is of 14 to to is 44 a
A
0 1 u it 0 mor
a v a P.* 1
,
I-,P .
0
00
00
-00
00 Synthesis ad Ily the d4hydre"tim of aleshou
l
1
4
s Cam
161
m
f
"
La
M .00
.
"
am
.
.
e F"We 4
e4
amp
y
S. S. R.) 6. 12111-4(lwd): cl.
C. A. 217,46-Tits Pftvkm ambod was umed
9
ill the COU!"ic dthYth'00"tiou of &be. HtOll And HuOH
by CANWUCI The V%POVS At alm. Toreoolt" and 250-75"
i

j at a rate of
1ce.ilit. O"r itx)cc. of contact gnilltoo. t4 CU
1-01
1-1311% Zt
0
The catal
sit(]
sts coaq
.
.
.
y
9.
'

00 I.W1. /rate pyr"hork.
MIS cliaractelilt, i heir cut At

so Ititicarlivity. (*tltnwn resultsul Aire EtOAc niter ibw
'
A
of flor.
"
065; mt0k, with a tux. of 37, Acoll sell
no UrCII(OROv. and a&. ctmtfi. WSI~ If,.
'
j
ter 4 runs wen obtsaled vvith the late of a conjac
M..,
00
conic. O.W1# It. Milt 96% ak., the yield of AcOH anti
AM iacn*ftd and that of RIOAc decreased (4870). The 0
I-statyst showed but litille dewtirstion After 162 hroo. ut
i
I
i
0
lift.
t
s easily rewtiva ed by Oxidin
ng in fitnt 0 anti
r
70"
250'
d
i
i
If
150
B
OH
;
-
re
uct
on
lk
u
# at
.
at
t 34
ga
, -00
-
PfCO.Bu. 3.65"'t, PtCOsH and 12.W50 Milo. A con-

C1
I I ruist. of CO Mix. 0.21r. Ce gave umder Identical
60 =ditiom 33% EtOkc and twice as inuch AcOll andArIf 440
4d. C. A. 30,617P). Chat, Stane
.00
Aso
00 1 Ali 9. WALLUP.GICAL WERAMIlt CLAHWICAMN r:
00 11, woo
It: ~* 0

,
-
- I ft, L
a sc a cc it x olla A I t a OW 0 1
a m
j
N It A) 13 3 0 v
0
0
0
0 0 a 0 Ome it ro it ar it
t
g
0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0
0 0 0 * 0 0 0 4 a 0 0 0 0 0 0 0 0'a 0 0 0 0 9 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 0 0

,9100 0 0 so**** 00: 104*0e
461 -00
i4* 084,11OW6*04 *Osseo

18,
is
it a it a a Is a Is 1) IN to 0
U aAL is a U a one
LA"'CL.N
a- I.- A_ A. 1, V
2 M-

tiYumt1u; at ostitte t7 dalifftectwat6as d akebols. friults in Crater aint. of AA-011 and Witer yields of AcOFI,

00 C
U. The Muesso of mistM& of pceperstim suW actfist- g to the traction: A(,()I't ~- 11,0 ~r ACAM +

0 rt ACAMI + H
il + 11
ibl
h
A

00 0 tjoes of catalysta and separate US at the "stmods p-
at:
c
elopt. or poss
y t
,
Addius. of G-&)% ArOll, Atli, AcUEt and NtCI[Ft, -00
rdn".4. D*-.,M- U.
M th4 dab
'
_ td that the pFemntv of AcOll rriards the rate -11
ab- .-as
Sill j

1 A.
11owisovs, ant! M. A. Nowst. J. Gto.
Kq~m. H.
7
41 h NIC; MOM and
AcOEI feemAlion (newly 5 lin's" wit
:!
00 A ,4
Clio. (U.S.S.R.) 6. 144"1(19M); cf. C. A,30.21
~ jscttkristes thAt of Acif fomatkln tim ni~t in the profof-
The mechanism of the "wheals of AcOM by citWyt i ion to the drcreaAins tatt of "i erification. Theretzards- -00
dehydrosicnittboss, o( EcOll by the awdhad previously
deKT"d aid the factors infitioncing the reactions am Iina d the 2 pha~,,( ttact"i il c-U-cd by the MINKPIs-In
15~'
A~11 mhi!w. tb~
t
t
l
OV -00
Sol tudW. Increased AcOEI *14 with massewsluit VWVV yt
,,.
o
. m cati
, (up
of Ar
'
P"
AcOFt
7
ives otil
li akwi
A
i
fi see
06 AcOH 4M no AM rtsWled by - tht trattily"
p"Pd. .
am.
t
c g
ciii
y
,
o
estrit
AcOll gild 570 crtst-Wthydt. In the pfevence c4
Z*q
Sa by reversed order of addn. of NaOlr to the mint. of Ca. juge c test of Acil the reaction sapidly stoPs, because I
o (OAch and 0.2% CeNO~ at 4W. The subditatim d the adsorption of paWdehyde on catilyits. Ad&,. of 1300
1C.Co'. Nseco. WW Nif.011 for X40H asad that of
cu.
(NO.)s fvr CUMAch Produced interim remits. C~tsxrr
AcOEt and MeCtilit, hjtve no harmful effect an the

to Nvtbatkr and Sroderesss (Comp#. re". 136,738,221, M esletifitatim.
coo
R (19M)), Cu reduced at 3W' save AcOH 11.77, AcH Z3.81
aM AcoEt 14.7247c. Thi3 confirms tbeyeevious, viTw
that the pr-mat is effecied by the InterstsedAte formatioct 2i see

,68
go g
1 and esiterificatkai of AcH- M011 - AtH -* AcOEt.
; 4 a a

1
1 From the cApti. ctsidtz of the scdvatkm of Cu. it Is tents-

I conchttled that the activity of Cu is increased by
ti" Y
1
1
1
v the Wit. of unall austs. (0.1-2%) of (1) dehydrating
i-
1
w! agents (A]1.0~. Th(N. Cc43.. TiO, and CrA), (1) dehydro-

:
-S
11
,
'i
J
tt"ting catalysts (Ni, Co) andl (3) substances capable of
d
i
d d
h
d
Tb
h
i
M0
C

il' rist
c
ragruat
us t
ng an
).
e
&hy
ng
y
1,
-
-Wi
ddi
O
t
Oll
l
d
bW
32
Z
t
f A
i
) b
l -eaj
ou
o
s
i
o
c
s
t
y a
ng
(
t
Y
y
%
the catalyst or by ppt it. the cata!yst an granulate activated

t
40-1W
d
t
i
f
F
i
C
(
C
)
tj
e-
es
s
:Gm
re
n
ree
e
at
omparat
.
(
hydrolictuttim of IM % alk. witb the Cu-ce catalysst with
f t tie 0
siddsts. ol 0-M% 11.0 zhovmd thal Wereassing dilst. of ak. i its**
It 4 r -
-
--
-
-
-
-
-
t
Es u
0 At -0
ft
It UP it 91 0 FaTit 5 pt U to ki K .
i
i W
i
i
ji
W
A
ft I less s, ar
:

4
0~
T oi
0 ~41111 0 a a 4 0 0 00
0 0 070 6 0 0 0 0 0 a a 0 444~
4

KOTMTE~ M. M.
"Synthese des ethers-sels par la methode do la deshydrogenation des alcools. IP
Nouvelle mathode d1obtention at de la regeneration des catalyseurs dletherification".
Dolgow, R. N., Xotona, M, M. at Ssidorow, N. W. (P. 3456)
SO: Journal. of General Chemist= (Zhurnal Obshchei Khimii) 1936, Vol. 6, No. 10

I IF 11, It u u 4 If 4 to 1 11 'Act a m V, A
. - " a it I
Lt 1.
A -41 --p L". ~191-1 - - - - -
I'llpff., Is
00
so
09 c4falytio 44bd&Adw 4f gkohola 0
OH Im dke absesce d wpWc adds.
64m. Choln. (1). S. S. R.) V.
aks. (tvm M-OH to iso,4-mOtt art p
41111 IyUs al 775', the cotTevooding eve
and HIO we (omtd 1(multantwtily.
00 irl are obtained over it fuwd Cu catalTs,
00 PrOH and lqo-BuOlf. With ik)-Ain(
h; pptd. Cu. When the $--1 14 activat
04 w( am fiwq and that of "ter (a11%. eqt
0 alm
041 j
00
00
00
t
0 04000000 f ee
A'Allf uu big %Ij 0"4,4. #J41 a age
It j 0 -L -
".
L7

be serf*@ C.H- 1-00
~f-.-M,Ktton,
VA17).-When the
VW11 OWT CU CSIA-
-00
'm MeOll. RtOll, -00
f !he f,~,t calalym 840
~ with Cc thr yield
7iRlty in the hixh~r
1. Al. I i~t,r
coo

f

izoo

00
A 0
U114KAL
A I a . I L A of 4.1110ATUIll CL*l%IPICAT?Gw UG 0
00 3 ,so".
Uvo
10 411
00 "t - Iq!
It 1 9
0' U AV 1 0 0 (11, lr;dc latt tell Ruff 3XI(Lon 1 1.
0 0 0 0 0 0 0 0 4 0 0 0 0 0 0 0 0 111 0 0 0 0 0 0 0 0
- TO-016 0 0 0 0 0 0 4 a 0 0 0 0 0 0 *1 0 0

-
!000000000000060000 0 * *0-0 a a f a
111,411so 0040 04 00 006 a***: 1
4
MO a of Sli
"OP
MR
? go 00,

LC . 1,
I I is it u u 61
! at 112- u
"
1
1
a 0 a 60110

04 JA 0 go M
ll
so
00 Decowposititto of RHgCJft (whars R to an acid radical 1
In altems. M.-M, x4mou.. J. Gen. Ckew. (it. S. S. R.)
cf. C. A. 34, 31.W-Flwvvim~ly it wa,
0f thit derim of MjIc are (1,voinivill. in alcit. with
-1111. at lig dn,i 6wil'all-A of the rMT-1--mAing turiff-Ar-
Nwis. lbe trilicluill prm,m,14 Willi tile fivillAiii"I A M.'all
ipl3rilitkarilf the ct"trillw3nifing ffcc atilctildrs audvilc!t
R111tw. -here R it an ~Witl radical, tract iumilulv lit

tirvIA, by tile pirviott. inelb-1. are inmr ratily 0
11"If 1401% Willi -I'll u( 73- 1110% till. I lie fill, .1 .1,
t
4 tile
l"
1
i
%0 th
t
Vi
l
0
r
lai
. w
. '
.
m 14
~
ll, TVA-
A
ompli
,( d-ollprit. -( 141101h divfeact in the following ,Oo. zoo
00 1101,11RI'll.
tt,wlme), AcOllcPh, FiCtNill:11h.
00
41111 lljl)IIxI'h~ I'llf. lifolul'Ir Ih,
0
1411KI'll It AIM I'llilt (lie (or imil'al, 0
a I-, I %it It I Ill, jil'. It 1411 f .%,1t,
'j#9
of t- 11011 - 2 lig 1 2 C. 11. 4 Ac 11. 1 fir Avid
I(II), I"lli'v'I Ill Ole fr4ctuill, tell, 1, will) Or at,-. 1-1 xivl.
00
11a
lit -1-~ C"11.0%11 1-1011 110
Ake M.-,

'00

wt I f :t,
to
vio 0
!i
L 1.
1
--
-
u IN &I K
) At
v ?z All I a 41
4 to 4~
Nx
. .
0 0 t q '11 a 0
1 f
4A4
0 0 0 0, 0 0 0 0 0 0 0 0 .
0 0 0 0 0 0 * 0 0 0 0 0 0
:10 0 4 0 0 go** 0 0 0 of

000006,
0 0
0
000
0
0
0
0
0
9
0
00
0
0
0
0
00*004 0
0
B-JS V It It-Alit Ulf AIN NO Moset QUatill!'D

oo A J_ A. IL if f Q 4 it 1-1, w tz-ov i A
p 'a -a _1_4 0
oo
do
00
-00
00 .00
00 it _00
00 1.04
AP 0 Reaction of dijibeilimeirtury with organic mouffbasic 0
acids M. NI. K,,t.,n. J. Gen. Ae~. I I . S_ S. R i
P12 III( IMAJ); (. (" j. 33. 1,11,11t
1,-4,1 Willi ..K, funn"I.Alw wul,
t-quatit-n 11h,111 +. KC0,11 - c.11. -, '00
11COMCM. fit. 1:15-S' (deminim.). Acolifillh, nt.
III'
F
C0
1t
ph 00
.
t
3
s
, M. 'NIfCIIjOII)C0~IIxI1h. =

00 fit. prcwfgml, Ill. 91'. 1:1CII(Officth-
'

00 Ilallb, in. IN
. C.1fiX0,1101h, fit. No., J'. C'111-
'
1
111
CO
I 00
3

00 1, ni. 11101jX1
J
h, If,. 117 M
S
. C.H.-
IOWC0,110% fOwnyliffercuric d-~ mif =
00

04 '-`;goo

00
Eel
~

00 I joo

00

00 go
00
00

00 3 VOO
00 It
'n A I Od a pe
u I A, t? it 2 AC K IT IT A 141 ",a
a 0 is 0 *'a 40 0 00 0 0 0 0 0 4 0 is are '0, of Am. o 00 do o 0 0 0 00 0 0
OT~44
000000000000000*000000000~ooooooo*ooooos

WVO-1 000000 001000 000 0

AA-- C
00 l to ilia tit oil mn 10 V ape is
P- 4443 cAMC*
011111 A
0:

Arl
viva. Gm. Ownt. (11. S. S T) S. 1791 OW1113N);
). PAItuvaev milid K., C. A. 26, '217,19. I'll, oudy of the
dmultspa. of usetidlo-o(j. romilds. ill 1kl(%L With Wj'H- 'if
social and lufmation of the tottv-4oundinig bvdrswastmut~ is
continued by li-ting i. -1-1 cub- I it. 11h.111( itud 11,
rul.olanak.IIOS.mannitol)ataAl*ft.r2-:,'Ihri. Tbv
rain of Pb.lfg dersimpa. in 6 his- in the 1.11-inf, Ak-
smirtv: McUlt 91. FtOlf kit 8, IWII lio(sil ~ml i...
llui)lf 7,7. iv)-AmOlf 79.1-A, I,hCli,(I!t .1W &i, C,11,
00

0 13

00 0::

0 v, U)II), 4.741, glymull 116,A)i and mitinflol W2.61'r. I bui.
I be late of 11h,141 devull) is jTrAlLt ill 2111illjtw' Alv~ with
an ocid no. tit C atom, tg:n -th t-to no. if C at.im. and
is considerably greattf in lbulyhydiiv than in moisithydite

Ak-s. with an equal chain of C atuui~. e. g , 97.71r to
C.11.1011)s and IP.817c in I-I1011. and 66.1t7"c' tit icht,tol
anti 10MU], in PrOli Coll. is finlued '-F-;.mdltljt ti,
the Alill Nig wpd. 'it the retci ion. I ht tri, tiot, plo.
0

oo

00
;l ItTkis With the (OCHUAlki.41 Of -todli 11HA11111W% ol' the Iwiv- .400
00 x

*4111 %IK"Alill free 314thycks (1)ZI 2.3%). v,itrt. (3 I-W; 1, tr.
miliflo-alkm ptoducts of coldolly.h.4 bill 11'. Ill..
formation W titicts C1411 be riplailml b tht- '04i,livitku So 0
traction of aldchyde condensation; L'Acr, - Atol:t. Oil
pfulongd twati--g the dec~mpn. of ph.Ifs into C.H. And
!iff qlian r ch the thesirctwal incill. (P9.21-11"o ill i~j-IjUf)lj
in MIX, though the yields of jildcbyd,s anti t7sit-ts djfl,T
but little. Chas. lllAnV
0
JA 0
A S 4 . S L A NITALLI~PCKAL LITIVA11.4 CLA%SlftCATtCN
06 8
V-F-11- R W--j --- q_jZ JO ~1 Al 0 1
Is is IR :v 64 of & It A q U tt 11 CC "to is l