SCIENTIFIC ABSTRACT FR:OGLOBLINA, Z.B. TO:OGLOBLIN, K.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001237800012-6
• Release Decision: RIF
• Original Classification: U
• Document Creation Date: November 2, 2016
• Sequence Number: 12
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTR

.,ro~~y~rlwYiX'3~.:t~m;iP iCitla~~n, --
Ogloblina, z: A. ~
', prC; nano
1
,, hos horus. Class 12, Na� 181082 [announced by
Z IT LE , 1Z �thod o~f obtaining p F
the Ural Scientific Research and Planing Institute for Cc-ncentr. anon an~~ Mechanic;~l
~.,~..,,.~.,.,.. ~~ ro~ek,tt ini 8 titut J
shy p y yy
Processing of iVtinerals ~~Ural' skit' nauchno-issleciovat~,.
po obogash~cheni.yu i mek,hanicheskoy obrabotke poleznykh iskopayemykh)~
SOURCE: Izobreteniya, promyshlennyye obraztsy~, tovarnyye zna~Ci, no. 9, ] 966, 1?
TOPIC TADS: phosphorus, phosphate mineral, sintering, fluxing additive
ABSTRAC':C: An Author Certificate has been issued foY~ a method of obtaining a ,
hosphoru:~ from raw pr~osphate in the presence of fluxing additP~oem~ry~~e `~{ ~ n cI.
p ._
phosphorite wii:h subsequent electrothermal reduc:tiora of the age,
To simplii'y tYi.e process, the fluxing additives are introduced before s~interi [ ~,e
phosphorite. [Translation] ;
SUB CODI~:: ill./ SUBM DATE: 03Dec64/
Card 1
C: 66
631.3
=4
.~~~
- .- -~ _~ r _.._ _,M.~_
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Polyr~1eri"atian of s./065/b31O~p/QO~I/OC~2/Ot~S
Pr+~pylene ... ~+~'7,5/E4~6
100 hours. ~ After 1100 hours the yield clis~~r$a,ged to 6C-ryG and
grada,aily to 24�,6. After activation at ~ ~I ' then
the catalyst Wa,e extended to 2520 hours, ~th~iGyielda ~ five lif~s of
this tame amounting to 440 kg/kg of tlhe ca~;al st;. Theolyme~^$ for
costa of detergent; alkylate using the silica-tungstic acidodixction
catalyst are about; 2596 of those
catalyst, There are 2 figures.produ,~ed wii;h a phosph:arac acrid
ASSOCIATION: Groz N.iI
~,
Gard 2/2
~-~
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s/o63/b3/Op0/001/'G02/oc~5
~075/E4~16
� Vol'pova, Ye.G., Ogloblina,~L.Z.
;~U.CiiGRS
l'ol me::�ization of propylene on ~-ilicu-tungF~tate
TITLE: Y
catalysts ~ 6
' i a i tekhnologiya topliv i. mase:l, no.:l, '~ ~ �
FERIGI~ICAL : 1912~y
s c~-rried out to discovla:r active supports for
TEXT : The work i^-'a
cid fromsd.nerals avai.labl~e inAskan~andeTrosh.kov
si.lic~~s-tungstic a ware : Kieracelguhr, The
'fit-e m�~terials inveeti$ated
activated silica-al.umine- and alumina . -1
clays {catalyrsts}, GO atm a,n,d 0.3 r- f
ro lens at 17a to laOoC~s ids rate vrhen t/
polymer{.nation of p py rocs�ded at the. most; rap
space velocity of the feed P -ellets and
..tun sti,c scid was supported on silic:~gaar~dib5�~~rssPec~tiv'ely.
silicc, $ the yield of polymers bein~~ For
Tro;shkov clay, o:^ts eXCimined.
�� for all the other asupP
01 mars contained l~.:s�~~ trainers and 34i� tetra-
The yield was be~.ow 25/ 4 hour's being up
Tros~7~kav clay, tl~~e p Y thi> first 2
field of all the polymers in This did not take
mers9 they steadily with ti-n�.
to b~~�?'P~ buminacrthgicatalyst conserving its activity for
pl.ac4s on aXu r
Card. 1~2
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ACC NR: APGOLi4i~1(i SOUR.CTa~CpnE; ~'l~,~p~1p~~7G~Opp ~pp3~~.,._..____...__~.__---~-~--.-___,.,.,. ~
/ppp5/ppll
A~THCI~,: Ogloblina, If P. ; ~:rasnyy, 1~. B. ; YefrE~rnov ~~, ~,. I
~ ; lVlusin, ~", G,
~OI~G; x,lone
'T'ITLE; Preparation and Properties of high-purity w;ilicon ~diaXide sorbentc;
.~.i4tJRCI,~: AN I3,SSR. Vestsi, 6>ezyyya khitr~ichtzylth na,vuk, n~a. 3, 1l~6~, 5-ll.
1~OPIC 'TAGS: silica gel, silicon dioxide, sorbent, ethyl silicate, silicon
tetrachl~nride, impurity
ABSTRACTS `1'wo methods, both based on the laydrol.~-sis of ethyl s~ilica,te ~,nc1
silicon tetracFzloride, have bean developed at the Institute of Chemical Ft
~ and Higrt-Purity Substances fT~ZEA} for obtaining hi h- urit� s eagents
dioxides hawing; a variety of adsor Lion ro erties, g ~ P '~' ynthetic silicon + -
P P P These ~~re: Si(C3C~l~i~}4 + 4H2G ,
Si(C}l3} +~�~ HSQH and SiC14 + ~H C- --} Si(OH) + 4HCl.. The silzca els
,obtained fz~m et~yT silicate showed stung water-re ~ellent ro g
son of the capacity of heat treated samples to absorb benzei a and vrater a nor Piz` .~.
3
showed that surface resistance to water is a function of surface deizydration. Silica j
~____
~ Cc: d 1L2 ry y
_ ;~'
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Z~;NX4VA, Z,A.; KEI,~TS~V, N.V.; pC~~pBLTNA,_I.P.~;,_TpROC~~Sxi1~TKCN, rJ.S.
Using new aorbe~ate ~n the advanc~~d~eta~ge deh3rdrt~tic~n ~~' gase;~,
Khim,pct~gt." no,2:100-105 ~' ~ 62. (;t~~:IRA 15 :;? )
(Gases-~-DrYi~~ )
(Adsor'bents)
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UaEj ref new absorbents :for ... S~(~~4/~~l'C00~()02~'00~/008
I31C31~]3ia4
the c1.yna~;ic activity of i;he zeolites fraAi Zi ~;,/100 ~; to 16 �; 100 n. A
ra:e of 3 l~cm2�nin. is asfaumed to be per-issible f'or~ induetr~ 1 adsarbers.
Exper~~iraents with natural ~~as Pro;m the 5t~:vropalc de,~~asit w4-z�e also
conducted a�t 50�C and U. h l fmin. A devr ~-oint of -6C-�C was reached.
Beeat;.se of the selective ~i20 ve,por adsor~,tion by zeolites the other gas
cornpc~aQnts did not affect the ad-~orption. EYE-n the heavy h~rdrocarbons do
not rene~trate the fine structure of the r~.A zec-lite pores, ~-a that no coke
formation sets in during r e~;~Erneration. 200-3`.-p�C is the beat regeneration
temperature, ~'ar re~eners,tion with co1.d has, heating in d~.rec,t flow is
preferred; de~rr point f"ar direct glaw damn tc~ -80�C, for ec~unter flow
only -60 to -65oC. A mixi:ure of 74.2~o NZ, 5�j';; CO, 6.5io H2, ~�~ ;320, and
7.6`~ C02 was also simultaneously dried and puz~ified. U20 was adao:rbed
most ~~f all in the .first zeolite layer and gradually displaced the C02
adsorbed in the folloti~~in~r layers, which left the adsorber at a dew
paint belaFV -4~oC, ~t 12,6 g~cm3 r~oisturs, the dynamic activity oa� the
zeoli�te a�c~tanted to i 0 g~100 ~ re:lated to CO and 11 '
moist-,~re. there arcs 8 fin~urea 2 2' �> x'/100 ,,� re].ateti to
2 non-Soviet. ~' ~ tables, and 9 refs:renaes; 7 Soviet kind J
The .reference to ttte ~,ngli,gh-language publioE~tic~n rE-ada ae
follo~~rer: A. I,. Kahl, F. C. Rieser.-feld, G,ae Puz~ificaition, N. Y.. , 1;160. ~
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8101 /B1 ~~
Zhukav~a, L� A., Kel'taev, N~~ V., Ogl Mina, I�~.?`',
AU'PHOx:i:
'f orocrceahnikov, At. 5�
,i,I�fLE: Use ojr new absorbents far intensive gaFi dryin~3
PERIOD~;CCAL:, Khimil:heskaya pramyahlennoa ~' , no � 2, ~i 9~2 , ~q,._ `fig
., ranulated 4A t4A} and 5A (5A} ~eolites for air--
TEXr:': .~,xperiments with g o the absorptiv+. power
and gas drying mere conduc:teted to 20�E~ and 2a,~~'fg00 B res.pectiQe:ly.
of these zeolite types s.moun 0 C aho~~ec~
Investigation of the adsorption isotherrz5 of w~`ilicaagel anclCal~mi*-um
(1 } Superiority of the zea:l.ites compared Myth, ~ b owing tp l,o+~er tempera
oxide, (a} owing to greater moisture capa.c~ity, ( }
liter iai.thout cooling;
tore cl.ependence. Ga.aes may therefore be dried by Zeo.~ ~ ~i9~ameter,
the a~,;sorber. ~xperimente with an adeorbE~r tube of 1 ~
ranuJ.ation of the ueolite$ 1-2 mm, depth of layer b'} cm, w's.re conducted
g dew o lnt of -1i0 tot-,65oC
with rs.ir of known dew paint. f1.$owlof.l .17}1 fcm2�m~.n~ and 0.4 1/cm �min in
vras r~:ached for a rate of gas
the ap~.aarption layer. (~} 'femperature in~ereaee from 30 to 8~D�C reduces
Card 1 ~2
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3ynthetia Zeolites a ~ Cont. } ~34V/62~+0
Kex' t8ev, N. V. , ~~. P. Qgloblina; and N. ~t. Tor~~eheahn:tkov.
8egeneration a~"~ed~li~t~s~~i a teas ~treaun 203
Vaynshteyn, g. M., Q~. V. Aataf'yev, Sle. Y~~. t~iye~nko, 1V.. Z.
I~ulova, and A. 7.`. 3lepneva. Methods o:P Plant and ~~~lity
Gontx~ol of Finished Px-oduots Daring Ma�ufactur. a of ;~eo~.it~e
q, ~yp~ Adsorbents 212
APPLICATI0~1 OF ZBOL:L'z'$S
Kiselev, A. V., Y'u. A. El'tekov, and V. N� Semenova. ~Ad-
sorptian of a Mixture of 1'hiophene~ and Heptane an
ZeolitE~ :~aA 218
Pavlova, J~. F. Adsorption From n-Hexane-l3en~enle ~olut.ions
Kith o33tnthetic; Zeolite CaA 225
Card. ~-~~/`
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i
i:,,~>
Synthetic Zeolitees (Cont.)
- ~-V/6246
`'~C~= 'The book Ss a collection of reports presented at tale First
' Conteren,ce on Zeolites, held in. Leni~igrad 16 through lg Na,z~ah 1961
at the' L~cn;tngx~d Technologioal Institute i~A3en1 ,~rfe0vet, aiad 1ss
purport~il{~ the first monograph on this sub,~eat. 'The reparts are
8r'auped ,k17~~G ~ eub,~ect aY'iaas ],} tl~earet~Loa1 prafbtesslo of adrrarFw
tion an ~~r ~~uua types tat eeolltos~ Intl ~+~th~ads~ tat tRselr it-veet~-
g~ttiap, ;;3~ th~l praduQtl,oro of ~eo~~,tt1er g11i! ~} tpplioatla
zeolites~, po personalities are mentioned. aeterenees toi],orfin-
divfdual ai`tiolee.
TABLg OF CO~tTL~lT3 s
Fore~vord
Dubinin, X. N. Introduotlon ~~
5
Card 2/fit yf

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- li4./-J ~~/7 1 -
w-+y
~V ~~~4.//"'~!� / '~...~.,I. A.:.. _ _.._.__.. .....-,.......,,.......__.._ ~...- - srwww+.w~rw.wwr,.wr.~.w+rOw~MAw
~^'
/ Ze9~
1'HASS I BOOK BXPIA]:TATIOIi SOV,/6246
' 3oveehchaniye &~o teeolltam. let, Leningrad, 1!61.
Sintetiaheakiyel teeolit:yf poluoheniye, leleledo~raniye i primenen:Lye
(Synthetic Z~eolitea: Produotian, Inv~,etiga,ion,and IIs�). Moe-
ooty, Izd-vo AN d89R, X962. 286 p. ~~-eriesE Stes Dok],ady)
I~rrata e11p inaertecll. 8500 copies prE,nted.
8po-~eoring Agenays Alca,demiya Weak $$SR. Otde:lgniq~ khimiaheek~ikh
Hank. Komie~iya po teeolitam.
Reap. Ede. s 1~. M. ~Duba,nin, Academioisn end V. V. Serpinskiy, >~oo~or
of Che~nioal-~SolenoeeE &1. c Ye. Q. Zhi~kovalu~yaE Tech. ~d. s ~B. '1P.
Cv:lub' .
P~RP0~3B: This book is intended for scieritiete ar~d eng~neere en,gag~~d
in the prodc-otion of. synthetio zeollte-e (mo:lecu].a:- sieves), and
/ Po;r ohemista~ in ge~~gral.
f
Card l~
tf
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The Ca.xbonatic,n Rin.eticy of the Ammonia Liquor SdV~'15>-~5g.:,2~17,13;;
y
mixing intensity. This coefficient remaj.ns con;~tant ~.~.~�ir:~; tree
entire carbonation prooess at eac.~ temperature :investigated and
in a constant hydrodynamic treatm~3nt. The coefficient mentioned
i~ more ~ary3ng with ~ modificatil~n of the mixture of the
solution than with temperature ah~~nges. Ttir~ mod:Gfi�d. bel o~loi ~ skit'
equation (2) can 'be applied ~.urini~ the ~�hole t~.~ne of carbonation
for any possible temperature and rust' of bydxod3~namic treatments
The hydrolysis oj' the ammonium ca:^bamate does not form the
limiting stage of the carban.~.tion process. The :rate of the
hydrolysis is dept;ndent upon th~a i,rystallizatio:z rate ~~f the
sodium bicarbonai;ea. There ar~3 3 f':gures, ~ tabl.fas, and 7
references, 5 of vrhich are Soviet�
AS50CTATION: Moskov,akiy khimiko-tekhnolog:iches~~iy inst~.tut in~eni De T.
~den.del~ayeva (i~oscc~w Institute, a:� (chemical Techr;rlo~y amen.
D, I. ]Vlende;le,yev) Kafedxa tekhni~lug3 i svy~�ann;,~;o azCti~ ~.
shohelochey (Chair of Teohno:log4t of found NitSa~cen andAlkFalies)
StTBMITTED: Septe~mlber q, 1957
Card 4,~4
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The C,~,rbonatian Kinetics of the Ammonia L:lquar SOY~~1!53-~5$-2-~'!? f 3~
being always determinable, find tll,a.t of the tot;~~l, chlorine will
be su:Fficient. `very indication :required for 7the c.alc~ulation
of Ka (constant of the abso.�ptao7l rate was ar~a:ilc~ble ~ The
results of this computation ara ;:resented in ta.blel 1 o Tt can boa
seen :`'rom it that Ka remain~~ suf':iciently conet;ant; at a given
temperature. TY}us, the modij'ied ]3~~lopol~ skiy 4ha.uat;on
sufficiently determines the GQ~~~ibsorption kine~tic;s i:n the
initi~~l stags of cari~ons.tioll of ?;h4~ ammonia l.iq,uaa~. `.Cl1e
dependence o.f Ka upon tGmpe_ratu.r4~ is rep~~esentc~d t>y the function
lag 7{~~ = f (-~~-~ as a straight line, The activa,fiian energy
calcj~~ated from thc~ equatio~i of this straight line ie
3~~q cal~mal. since the liquid px-ase pl.aye are l.w,porta~t r~a1.e
in t~143 G0~-a'bsarption by amnaon~.a I,iquar (stet` ~) 9 the ;c~Fxt4? ref
abea:~H~~tian wall be determined in f,hi$ case by t~hl~ dl.Y'a:'usiori
rate of free ammonia in the iiqui.d phase towards the area
sepa:;rttitl.ng the phases. Accoa~ding to the investigation of the
kine�t~.ca of the 2nd carbonal;ion F~tage (ir~closure Fig '! ~ floe
authl,~rs came to the canclus~.on tk:.at the values of the ab:~arptian
Gard p-/4 rate co4sffic~lent increase cansidcrably ~w~ th an increaf-i.ng
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The C,!~rbonatiot~ Ki n4, do s of the Ammoni~i L:lqul~x~ SUV f 1 !~ J-~g..~?-1'j j'~U
'k(~ ~ X k is tb.e raga ~.onsta~lt cf i,~-e d.irect
'.-., liqu.t G
Dkfqu,
reaot:ion, multiplied with thca Corr�sponding cancentrs.~iions of
oompo~unds reacting with the i~beorbsd sulastanc;e. i.~ the
u.
diffusi.an coefficient in the film of thE; :Liquid and she
xl~rgtt .
thickness of this film. If e.{peximental evidence on the alJSOrption
rate of: C02 by ammcnia liquo:c is available ~ ~ ca7~ be computed
aecord~:ng to the metrod of l~elopal~eki;~ (I~ef 1;-. The results
obtainE~d by the al~thors have proved that this v~~lue i,l close to
the number 2. Thus, the value the is l~xacticaLly equal to ~
and ~ c;s.n be put equal to ~ � T:~e modif:Led equation g~.ven by
Helopo]! ~ skiys NA m�K$(PA(~;y ~ ~'~" ~.(~,~j `2} ofi'ers n;:~ dii'i"ieulties
in its practical use, in order ~to check i l,s app:licabil.ity the
author~~ investigated the CQ~��absorption rate b;y the aaimon~.a li.quar
bath ~~.is th~a beg~.nni.ng o~ Uho aarbo~r~s,tiar~, viz, lac~t'a~~~; tl~~c;
cryst,~,].lization of the NaHC0,3, and in the fir..s..F. stage (at the same
tame y~j.th the crystallizatio~l mentioned;l. For the calculs.te of
Card 2,,/4 m (NFi,~QH-aoncentration}, the carbonatiai~ degree of they Fjalut:Lon.
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5. Z
d THCI~Ss ~hoki.n� I. N., Ogloblina~ T. F'. SGV~'ic~3-5C-2-.97~;(}
~'TTLE~~ The Cap�bonation Kinetics of i;rie A~~onia I,i:quor
(Kinet~.ka karboi~izatsii ammiFichno,go ras~io]la}
PERIO]}ICAI~: I~veytj.ya vysshikh uchebnykh za~.~eieniy. K'r~imiy~~ i khiaticheskay~ ~lc~~+~~ ~
c~~` kk~~~ 2~~c~ p~r~cnn k~~.+v~r~ ~ao~,~.n.. ,

~13~=~~~ 'I' "~s~~a~a~ ~~r~G~~~~r~~ ~~x~ua~ ~roc-d~~ axe ~c~n~�pc~~i~~c~xba~~'~i
~a:i,~~ of t)~~~ ~t~~~ ~hm11~ w:l~o~a~ u~ ~.~v ,an~:dldl~
e~~a~~~~� 4 ~.:~lms~~~, ~7~ut+~x ~ �i1E,bsim#, t T,a-~.~~ ~~,n ~~orna~r..
~~~~s~ ~7,~b��~;:~~.~.~~r~~a~ of ~ar~~;r~-t~.r~~l v~xt,~�~;~o~~ :f.~ ~~tt.~
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t?'
~,~',~;; j T'orestry. ~+'ci~.~~~?~
Reaction of Nit:r~osyl Chloride ~-ith Un.,f~turated Hydro-
car.'aons. V.Reac'kion of Rutenc-1 e.nd 2-r',ethj~]. Putenc~-3 With YTitrosyl ahlaxile
Q~~t~pri of Chloric Hcid Anhydxide
in the Presence of Hydre~gen Chlorxfle.
of the a-~Chloro Isov~.lero- and c~-C'.lloro Biztyra I3ycixoxamic ~icid
gel' 2 and butenE~-t (Ref 3 }
cY:-loride Frith 2-methyl tutene-3 ( }
nc- solid nitrosa chloride is foamed. The m~z.in prod,uct~; are
Moro .alk~.nes i,e. tkie initie.l:.y
tk~e rnzr+a:~pondin~, 1-~nitr4-2-c
forrnin~ ;manorrRer nitrc~ao rhlort.cia i�~ oxidized ley n'.txasfl
chloride to the chlora-~Yitxo camp}aund-c~kzionaoftn~ttro,syline
forming in connection rr:tth the decompo~it
chloride is added to th+3inydafctheonitroscr~chlori+iesoafdv.
Consequently no regrcu,p g
the mono-BUbstituted E-t'hylene into chlorooximes t.3kes
place as their oxidatj.a~n into the r,~itro ctatnpaunds proceeds
more rapidly, In order to be able t,o conta.nue the irives-
tigatior.-s of the influence of HCI upon the regrouping of
the chlc-ro-nitroso compound into cYilorooxa.me~ the react~an
of nitxt~syl chlorida with 2-methyl butene��3 (I) and
butane-"~ (II} waa carried cutchlor~tc ~cid~anhydrideckc-f~en
chlarid~~. The result rra.s 5~
o:-chloro isovalera hydraxamic acid and a-chloro tut;~Y'o
Card 2~3
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o~l~~bl~~z, Y sov/7J-~=~~1~~~6/'7~
~~ "tith Une~atTlrat~ad Hydre~carl5onf~
TIrnLI,: ~E.ss.z;tior~ of r~itrosyl Chlcxide~
{Vzc~imodeystviye khloristcl~o nitro~il.nx~rerr.;a.tet~.~ S~r~y~. ~~~~ y.~~ ~. r:h~:r~a ~ ,

~:5'~j~1~v~E
t'~ TY;2 C~'lY'Qllli~tC~;Tc'L~)~'1'i C ibllP~.~.,YC{:LF' llu'E'(~i h4~rE'. ~.ti1 CPa11T1i:;C,. ~;ei~ Y/1 �al C?'::Z`y1.C'Z'
'
. i~1vc:~tz~atian~ concE:~rnin~ the ahx�omatcrgraphi~~; sep~x~a~tia~~1 ofi
Xtl1?"()3 U'w t~th$x' ny~:S'Odp~'1t1~i,i;1.VE?�~ of th:' ~.r~vIll3."~:. J SeriE:C
71
l
.
.
(~~~~~ 1-~~) ~1n ~i~L`(:at1C JX],i~C C~ Et~,tlRis.ilutt1 `N x,t�": t3 :~f?CE'x' r~~tet~_'2".''i; C~
F .. '!~t~ L'1~S uN~~d f'aT' the �z'y[79,Tt3t~t,'n Q~4 ~'.h@ iA.~~'~1:1~C iil~lit~1C~:It?(~ ._Pl
'~~F} ~~t~�~ 31'id a~4~1'~'~Clt�; ~'IE?xE~ bF~i1.Z�I1~: c3nt'~ I7~.XttZ7'~"? ^i b2li?,'wl'1~'
Frith ethex ar~~. ;~c~:toPie ~~c~~~~r:~mc~t~te w,Lth, c,th.e^ ~r,i:r~:it~ tiitl I1 t3#
ld `~:lti.;'IL~C. ard' z'~=~ult~i r~.'~1�! :~YtV~":;'all~'i3wE?~~ ;A11~tU~ ~? ,`,Cikti;~,_2'1C~1
4f'1.~ ~.r ~' ~
w-( ~) ! ~:~ (.~I) ~ ~.!".~. Tl (III ~-�j11.tY'Ctir�'IXZ~'~.G 1~5". a. t.~?~ ! ~ttt-(~y~ ~i.lad
3 f ~'". (Q~ ..~j~ 11~.Lx'U~~'212!~].C &, C:~d{~~ I'he ~epi~rF3 ~'~.4I1 Pll.;t ~t1:~CC't~~3~'tl.~~ j`
c;~rried out in the daub:.e Ini.xtuz'e:~ (I)+(IIZ i ~ (IS)~~ III) ,
Ii +(IV), (SII)+(IV), (ItT~+~V) Fror~ the mf.;.t~.~re4 (I.);~(II) ar~d
~:IT~+(~1) alal.y (II) gas obt~.3znfld iIa pure firm l.t f ~ ~ se ~ ad-
Card ~,/2 sc~rbable then ~ I) and (V) ~. Trae adsc~rbabila.~ty ~~Z ttya ~,.nd.~ v~ dual
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501~~?y-29~~12~~'IB/q i
R,~a,tfy.~~ ~;f fla~~x:~:.;~1 ~:h:s ~?r:ide ~i~..il Ua.satlzxai:ed ~TydrocartlonsnIVa~teactior. ti'Iii~}1
Z)~.7 y~.i~!1!11....'~
;~xdi:~es ;n;.tc~ n~.*r:~{~:i~;. t,h~.~a~^~.~~e tc the ~a~r~itr~o-~-~.,lalax^o i~utc~eN
The ~:~~~; r.;, ync~ farmed i.n ~~he d4Yromposition of the rlitrosyl, ch7.oriue
~ie`',d,3 w~ trx hydr{,rack ~n the c~~ chloride (.icheme 1'~ a The Etbserice cif'
the. *,;:~i,~,y ~�f `~. t~hlc,~~~ but,yxi.~� acid alde~h~Tde in the xeat;i;ion pz~n~~ac,ts
:~.ndac:,~te~~ a i.,r,~ �ael~c:~.t~ of :regr.0ugin~ oj' tha ni. troso cc>mpcund., a3
~~c~nnared h,i, that u't" the oxj,dl~tior pxccescsa The x~rssence of the acid
c,hlc{ra.de ~;~: r~:_~,hl~}e~~--ht~tyxcl~.';~ydroxamic ~.~~id :lr~ 1,1.1e reaa~Gi~on ~,xo~3uc~ts
.nclx~~atre:~ +,he 1'u~:matioxl. of r~hlarine axi.misp This acid chloride ~Ip--
~s:,reA~~,l.y is 1'�~z~rned ~n tt,e Etch on of chle:rine and nitros;yl chloxide
rn the ~?xamc~ Ref 31 (Scheme ?.), The structure 0f 1-nit:ra~2~-chloro
~ai~'ane rve~ r~rc:~red ry its tl^ansf>:rrmation int{~ �.-c;hloro blztyric aci3
on b.eatt..g it: in a sea~.ed ~~:npoule at 140-1450 (RP,f 1) (Scheme 3) o-
T~~=ire s~r~~ ~ re.fe.rencey~ _>. of which are ~ova.pt~
assac,:.~�rTc.~r~.. XbL~r,c.ti~~w:is~y ~-~~=~t~i.Gt:~ 3~er.zai~radskogo ~,osudaxstvenno~o tcniv�rsiteta
(Ghen~:~c~~ J:n;~titut,e cif the Leningrad State Univ$rsity)
St1~~?T.TEU. Ida-~a:cti~er 2~~, 195?
Card ~i
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TI~hE; Rpact:i.on of Nitrosy:l Chlarid+: ~'~ith Unsaturated ~lydracarbor~s
ystviye khlaristo~o nitxozila s nenasyshchennyrri of;le-
( Vzai~rod�
,
vvd4x~~darn~. ~
IV~ R~sacti#.oz~ ~',ith :k~~rtene..1 (:LV iZeaktsiy~~ s butenom-'~
FER1O~Ji.CAL: Zhurnal ~bshchey khimii, 1)5~3s Yal Zg, F;P 3245-3'4$ (US;iR)
ABSTRAC'T': ~arli.er (Ref 1} the author had found that in the reacti~~n of
r-it1'~~cyy1 ~~~t~lt~.ride with ~-rr'~E~tkiyl butane-~ the q-~riitro-3-~~hloro-~-
..:r~ethy? b~.t~l,~.,~ ar~zi 3s4~dictiloro-~~~-methyl butane are i'or;ued as
main ,~rodu~.t3.; Ta prt~r�e thE. direction typi::al of this reaction
al;ro wi.tY~, other morir-:~ubsti~l