SCIENTIFIC ABSTRACT FR:MALAKHOVA, N.I. TO:MALAKHOV, V.V.

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CIA-RDP86-00513R001031700023-6
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1
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November 2, 2016
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23
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December 31, 1967
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SCIENTIFIC ABSTR
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APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 USSR/~Farri :Li~.:!ai-s ~ Honey Bees. labs Jour ',.;c~' ~~liu;' -Biol., Ito lu, ).i5u, ~i34G0 1luthor Ii1st Title Orin; Pu1~ ,Ustract Card 1~1 ilalalckiova L.i'..._. is i anciii,; of Vc~1;c?i a:ic ~~: _~ i ir:: ~tu�e s an ~'allo~~s . ,~ i~Ci''CIUVOL~.s'GVO~ 1g5~, 1'i~i :', ~~~~~~� r~ , 0:~ ~'~.olt'.s pls,ntec~ wi 4h vc uCi? ~..ic: oa~:s (cou-crol), c:cl c:~ .~ iac~r'c~.l l~la:itiii~;s on .1)JL!'v 2~ lla ac kolldlozes o.~ -clie 1,,~-~.., C,_i' :~~.;last' procluccc~. u .,,~ecii i:k'1ss crop of 92.3 cci:,,:~c._ s -yie~ iicc~~ar~; wlle:i bcai: secc~s sre~�e cidcled (4 1cU~ii ), ;,~-~= crop ~:iotuz~ec? to 101.11 c~::.,,~ic,�s;:.a; when only beua:~ -.ru_~c l~la:i~,cc'., t'ie crop equ^.l.:c ~`,'.~ ce~lt~lers ha. Ecs~.~-~'s, Y 'i~'cd �,ri ~:. rC ~.,~:' ~d;.~? ~,~t-~c Lo wl:icl,i l~cu:,~; tire.. c~ .: ~ i~.clc?:~ Lilo: ci.:cl, -~roc'uced 4 s,.t~-~ (i.~c cap) crop vi: 15 ltd l~cr ::a, ,r~.cl ~- ~~, ~~,:-� l.a was obtaii.cc:. 1~�o~.i .~:1t s as a ~:ectar crop of 25u _, .. ?1c:1-t~c' with bca11S o_;1; . T ~ :.~a 1 GCO!".ILl.Gl1~ ~C? -Lll~'~ : C ~ ^_: G_i.~ acan rii~:~vres b~: p1a:~~e~~ ,.. 1a11o~fr soils. APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 Subject USSR/Chemistry Card 1/1 Pub. 78 - 19/30 Authors Aleksandrov, S. H., Malakhova, a. P. and Shmulgakovskiy, Ya . ~~�'; ` � ~"" AID P - 1356 Title Spectral method of determination of sodium in aluminosilicates. Periodical ~Neft, khoz., v.32, #12, 6~+-67, D 195 Abstract : Spectral analysis on the basis of calibration against standard samples of low concentration Na20 is described. The analysis of specimens of larger sodium content is made with diluted solutions. Mean square errors of the determination of Na20 by this method are almost 10~. One table one chart and four Russian references off 7 (198-51~. Institution: None Submitted : No date APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 ' i a i phase of a reactor for 17+40 hr, except for Kh25T steel, were so�euhat higher (O1Ch2.NS'1' 0.07 mm/yr, 1Kh21N5T 0.08 mm/yr, Kh25~0.02ti m.~-/yr, OKh17T0.0',i8 mm/;y~r Yh18N10T 0.08 mm/yt)~ but alas corresponded to the e corrosion rates of stable materials too. Laboratory tests of ~.elded sp~,cimens showed that the carrosion of base and weld metal proceeded uniformly. Argon-arc welds of Kh25T and OKh17T steels made with filler of the we;Lded m~:tal under industrial conditions had na visible seams. Intensive corrosion of weld metal occurred; in specimens c>f Kh25T steel f welded with KB-;3M and E-3.B ~ electrodes and Kh25N13 filler. P9etallo- � graphic examination showed that intergranular corrosian occured in the weld-adjacent z~~ne of OKh17T steel specimens welded with a VT-12-6 electrode and O1{h18N9 filler wire. Corrosion tests of lox-nickel and nickelfree steels in a reactor medium showed that OKh21P15T, 1-Kh21N5T, '~ Kh25T, and OKhI'TT steels are more corrosion resistant than Ki,xu~ilOT steel. Errosio~a tests, performed in a special installation far 20 hr in a 60~ 1VH4No3 solution with 10~ sand at 60C, showed that K1i2jT, OKh17T, a~1d OKh1z1N5T steels have higher erosion stability than Kh1oN10T steel. Bl~sed a~n the experiments, a pilot reactar was bS~i1t of OKh17T ~, sheet ete~sl, 5 ~~m thick ~ arc-welded with a TsL-ll elect~rvde and Kh~N10T ~ ' filler. lDuring a 1.5 year test, na dei"acts xere reveals:d by visual 1 inspectio~l. Or,Lg. art. has s 1 figure SUB CODE: 11'/ SUBM DATE: none i Card 2 /2 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 :f ..:'~ :+� ~gA }. ,~ .~ .; .. ,:~. � �rt- ~r. '~~ ~~? ,. i` i:; i i S ACC~NR: ApT00123.1 N~ SOURCE CODE: uRIo31~+/66looo~oi2%oo-2a/oo2y~' ,' ,A.UTHflR: Makaro~ra, A. V. {Engineer) ; tdalakhova, r.. K. (Engineer) ORG: none 'TITLE: Corrosion resistance of low-nickel and nickelfree steels used in the production of complex ferti.lixers and ammonium nitrate f SOURCE: Khimicheskaye i neftys.noye mashinostroyeniye, no. 12, 1966, 20-21 chemical. production, ammonium nitrate, chemical plant equipment TOPYC TAGS; fertilizer , ammonium nitrate, lo~a ,,nickel steel, chromium steel, corrosion r~:sistant steel/Kh1dN1flT steel, ,Kh25T steel, OKh17T steel, OKh21NST steel, 1Kh21NST steel. `ABSTRACT: Chronium steels Kh25T and 0 h17T and law-nickel steels ~O h21N5T and 1Kh21N5t have been anvest~igated as substitutes for Kh18N1flT steel usQd for equipment in ammonium-nitrate production. Tree corrosion rates for specimens tested in a mixture of nitric acid (4g0 g/l}, phos'pharous acid (300 gj1}, and hydrofluoric acid (l. cm~/C) at 64C for 100 hr xere practically the same {0.035 mm/yr for GKh211tS'~, 0.049 mtn/yr far 1Kh21N5T, 0.026 mm/yr far Kh25T, O.0~+ mm/yr f.or OKhI",T, and 0,035 mm/yx~ for Kh18NZOT} and corresponded to~the corrosion rates of stable materials. The corrosion rates of steels tested in the liquid Card 1/~ UDC: 66q.15'26-19.46.631.81 __ _. APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 Catalytic Decomposition of Di-n-butyl S/076 60/034/009/030/041XX Sulfide an of-Fel 8020 8056 sulfidized d,,-FED hydrogenizes sulfides more slowly at higher temperatures, which may be seien from the values of the activation energy. Fig. 2 shows the thermomagn~-togram of ~.-Fe, upon which Di-n-butyl sulfide was decom-~ posed at 300 - 4000, whereas Fig. 3 show~~ the change in magnetization with the temperature; for a catalyst, which had been poisoned with mercaptan at 2700 and did not decompose the sulfide. When this catalyst 'was brought into contaot with Dl-n-butyl sulfide at 430 - 4800, a further accumulation of sulfur ~~as found to occur (Fig. 4, curve 1), where a maximum occuxs at 2000, anal at 2Ei0� magnetization vanishes. When cooling the specimen, a sharp rise of magnetization is found (Fig. 4, curve 2}. Table 4 shows the results obtain~sd by X-ray structural analysis. By the catalytic decomposi- tion of the sulfide and mercaptan, also compounds FeS1+x are formed, where x { 1. The effel~t produced by these compounds upon the desulfurization is investigated o~1 d~-Fe by means of carbidization and sulf~idization tests, where tY-e appa:cent activation energy of the sulfidized catalyst equal El 19.7 kcal mole. On the basis of the multiplet theory, schemes (index @;roupa) for the deeomp~~sition of sulfur-organic compounds and hydrogenolysis were suggested, which are confirmed by data from publications and the results obtained here. D~ention is made of I. N. Tits, F. P. Ivanovskiy, and Card 3/~~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 Catalytic Deco~lposition of Di-n-butyl 5~076~60~03~~00;?~OO~Og1}~{ Sulfide on d-Fey 80208056 tian rate per minute with a Jura +,i on of t;he experiments of 15 to ;i0 minutes was taken for the calculations. For the purpose of displacing the initial matorial and the decomposition products from the reaction. zone, nitrogen was blown through, and the catalyst was z'egener~jted with hycirogen at a temperature that was 50oC above the expea�imental, temper.atur~., with the result that H2~> was evolved. The compooition of the gaseous rlecompa:~itian ~" products is gisren in Table 1, from which it ma;,t be seen that unsaturated and saturated hydrocarbons (up to 17 j~~ as well as ~?2 were :liberated. H2S is formed aftea� a longer time of contact, if the activity o:f trie catalyst is highly, and the decomposition of the .sulfide is little reduced. Other sulfur-organic compounds are not formed. Fig. 1 shows a-og ~ as a :function of 1~T:10 , from ~rhich the apparent activation energy t is oalculatcd as amounting to 1~?.7 kcal mole. The results of the hydrogenation of Di.-n-butyl sulfide on of-Fe are given in Table 2, anti the composition of the gases, determined by 'the low-temperature rectifying apparatus uNAT~1M -51 (TsIATIhf-51) a.re given in form of a summary. The results obtained by means of a catalyst 'poisoned with sulfur at a hydro~;enolysis of the Di-n-butyl sulfide at q30 - d,80� are given in Table 3, wr,~rc: it was found that Card 2~[~ APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 S/076/50/o3q/0O9/~~3O/0~~ ~~ 802O/B056 AUTHORS: 13a1andin, A. A., Kukina, A. I., and Malakhova, E,. A. TITLE: Catalytic Decomposition of Di-n-butyl Sulfide on OC-:Fe PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vo1.34, No. ~, app. 2030 - 204.0 TEXT: 7:t was the purpose of the present work to carry out a multi-purpose investi~~ation of the pracoss of decomposition by mean; of kinetic, the;rmo- magneto~rraphic, radiographical and chemical analyses for the purpose of explain:tng the mechanism of the desL~lfurization on contacts containin�; reduced iron by the �xample of the catalytic model reacti.on.. The cstal.ytic and thexmal conversion of Di-n-butyl. sulfide and n-butyl mercaptan wf~~.~ studied w~.trr the help of a f].ow.a.ng-through method in a device usr~d in the authorH' 1r~barr~tory. Zt wary found. tt~ittt thb rrul~fl.c~~; dc~aom~~oc.~j:~ f,h~~rmr.~l.l.y at templuratures of more than 400oC. The kinetics of the catalytic decom- position of the sulfide was studied at 300 - 40OoC, where EI ml reduced d-iron 'in a 6.5 cm thick layer was used at a feed rate oi'~the substance ,. of 0.18 nl~min.. The experiments took 45 - 50 minutes. The mean g~:.s e~�olu- Card 1/4 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 c Electr.:icaa Conductivity of the Rec:ipracal S/078/60/OO5/010/029/030/XX Thxee_com~~onent System Form?d From the B017/B067 Nit.ratee and Nitxites of PotaesiTam and. Barium as we11 as the (KNOB) 2 ~~ 8a{N03) 2 and fo.r the syetem Ba(NO2) ~ �~~ (KNOB) 2y electrical conductivities of the melts at d.:i.f~p-rez~t~ ~~emperat~:irAg� F~~'g� shoved Yrhe pro,~oc~t-i.an of the i sathexm.al ~.:in.es of the specs #�i c: rondue;t:i.v:i ~`:y of the th:ree~aatt~ponent sy:atem s k 320nG. Tho expeay:i,mer~.t~ta,1 .r.-~:~.ru1 ti ~ i.ricl i.cs t ~; that the ele~;t:r3.ca1 conductiv3.ty of +,hA me~:1+ coana:~.i~t:~.ng of a1~. Z M M r a h lY ~ a r !i p iA y . 1~� w w O' rj N r O cr w G c: w r 1 to G y w O N �4 d `~ ~ 4~ rt !- ~y p fl O t* It p V N O 1~ 1+ (4 ~� !G d H O Sa N '1 �S d+ N m 'ti T .H '.Y h w r � O a ~~ H O r p~ M r'1) � r Pn ~c:n ~~ a ~ n- rL�rhy9p ~ a driowGO,r w � rr74A a~pNa~oNO< ~11~ ~ ao+~ . .; :b 1. ~ m n J1 n G >t y W a rr i n ~O 1� y Pl I. 1+. p IL 19 N ~1 A H S+ W 6 F+ r N i+U4+i�rt 1^rIMH tL ~ P'yy SI�JA dOP~ � i� Rf 0 OMtt rt - SO ry w (G I� �{ O tt N ',1 to wQ7 ( ^ y ry h '.7 (r r 'J h ~ , { N H A aq~ [t r l tt t+tJ Wi, C N. ? WU iy~ f: (F�S li rn~ ~lb .r-S. /i6 ~_J W~4 ~c~t 11 PS0�., /+ St '] x ywm !`r i~ rGi y~ ~ 7 i 4' G W U l lP� :J W W ~ w rl d 7 N a ~ ~ tt N tf t~ K ~ pprr ~ O ^ O ~ O' F� d + 'l O a ~) py N UI ii N ,9 W cr .try V + w r Ji ~ c ry ~l �r R c9 O ti /a h ~� p !+ U M r 4r A a a G w 11 tD 7 01a ,. 1p C H 9 it ~~tlt N a 0.'f f I W ~~y t~f N Y t. 1 ~(4n " F: tY U b p p o t a A 1.+ h rr CI n i';latiroo'�y3 ~0 yF+ aNtry+~ ~ w6 A~ QASn~~p(~ern p ~ 0 ~jb ~6P~~Oa n~u o c4+~ ~+T a tt GI 7 f1 1 4+ r M ~ ~ ({ b 4 r 7b' 11 11 w+ "~S,' ~ M { ~ ~ ~ ~ O ~ "t' I~ 0 M H 4 ~ 1+~yi � h/O ~t ; w 't ^ h a a ~ ~ ~ A ~~ p ` ~' r ~r_ ~ { � ~~j 'p! a a ^ r ^ ^ aye A 0 yA O N Q NQ M O O Ut ^ d 0 �b ~W �~Opp yro H H N O :C p a 01 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 ~~~-CC~ NR~~ ..AP''TOO4399 ~ .._....~.,..~,,._.~...,.~.~..,.~._- ..__~...._. that an Increase in the number of valence: eleE;irons, increases the energy stability; of the stable d-coY~figurations. The dependen~;es examined confirm the role of stable electronic configurations in the formatiion cif the physical pr, operties of ' elements a;nd compounds. The authors' thank G. V. Sarrasonov, Corresponding ' Member, ANN Ukr~-SR, for his valuable rE~commendations and advice. C>;rig. art. i has; 5 figures and 1 table. [Authors' abstract) [~Tl SUB CODE;; 11 jStTBM DATE: OIAug66 /t3RIG RED'; 018 /4TH RE:F; 001 / . 2/2 I APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 .ACC ~~ NR~ __~. --_.r......__,._...,_.~,:.- " ...~... .._.., .__..~~.,_~_... ~_._._ ._ ~...,__._~... _ __ _._... _ - AP~oo~~99 SOURCE Cor>~, 1JR/oaz6/67/000/00l/0o~sloos9~ AUTHOR; Malak}~~ov, Ya. S. ; Tkachenko, ;[. ,~. ORG; Zhdanov In;~titute of Metallurgy (Zhdun+avskiy metallurgicheskiy institut) TITLE: Properties of transition metals from the .viewpoint of the concept of stable electronic ~configu:rations SOURCE: Porosh;kovaya metallurgiya, no. 1, 196'7, 5$-69 TOPIC TAGS; transition metal, heat of atomization, resistivity, hardness, tryst lattice, electronic configuration ABSTRACT: Stab;te electronic configurations in t}ae d-shell of transition metals are correlated with their heat of atomization, interatomic distance, thermal coefficient of lines~r expansion, and resistivit~~ and hardness. It is asswmed that the physicochemical properties of transition metals are conditioned by the appearance of d-shell configurations in the crystal lattice, the statistical weight, and degree of energy stability, It is shown that the d~-configuration has the highest energy stability among the stable d~-, d5~, and dlC-confi;~urations and 1/2 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 ~~~~~~, . ACG NR~ APb0;1~'~21~ D~. t dium b droxide which separates Quit ig~ filterQd any mealsurin~~th ~a4t .Ch a in y grater; the filtrate conta.inin~ ~adueuixtithE~ofiltrate is disaiolved in Uot :flask. The indiu~ hydroaid� re i ric acid and the filtrate is collecte~3 in a mesineidncanlbek. ~aydrochlo ~Jetermination of ca.laium and indium etiveeiaeanusquar�oerror of the done by any desired method. b~ie�r rt. bas,, none. determination is about 1~. ~ SUB CODE : 0 ~'/ SUF1M DATE none ORIi~ R~~': 003 APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6 AP6o15724 SOURCE Ct)DE: UR/0032/66/032/f)05/0528/0529 ,~tJTHOR: Trukha, V. q. ; Malekhov, V. `~. I~RG: Institute of ;Tnor araic ~Ch~emisrtr Sitlerian Branoh AN SSSR f~Institu~"neo:rg`"`~c~; es y kT~~mi~^~~~~;SR .-----_ i ' ~ 7PITLE: Analysis of indium�~containin sodium chlo ~ a g __ ..._._ ~._. ride rystals LSOURCE: Zavadskaya laboratoriya, v. 32, no~. 5, 1966, 528-529 TOPIC TAGS: ~~uanti~tative analysis, indium, sodium chloride ~-BSTRACT: Experiments have shown that with melting of sodium chloride C~rysta.ls with soda sand with additions of In203 no loss of indium j:s observed. As a. result of analysis, more than 99~ of the amount oi' ~,ndium introdtaced i:~ detected4 For the analysis, Oo5 grams of a ~-ulverized sample of sodium chloride crystals is placed in a platinum a~rucible, mixed witky 3 grams of anhydrous soda, and melted i:n a mLtffle furnace at 1200�C for 30 minutes, frith addition of an additional Q.5 grams of sodau The melt is dissolved in hydrochloric acid and the silicic acid i:s sepEtrated out; analysis for silicon is compll9ted by weighing. After eeF-aration of tho silicon, an ammonia solution is added to the hydrochloric acid filtrate, up to th~9 point of a sligl~t odor. ~~ard 1/2 t APPROVED FOR RELEASE. 06/23/11 CIA-RDP86-005138001031700023-6