SCIENTIFIC ABSTRACT VASILYEV, A. - VASILYEV, G. V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R002203430006-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

USSR
A. VASIVILY, Director of the Siberian State Scl-Reo, Institue of
~Ierolcgy' movosibirsk
"hetrologists offer Their Services" (Letters to the,Editor)
Yoscow: Sotsialisticheshaya industriya,.,.20 If-r.73,'F 2
Abstract: At the AcaderT of Sciences Ukrainian, SSR Lnd at the Yain
GecT-Yjysical Laboratory in Ieningrad metering systems - have been set up
with 50 antonatic metsuring stations wldch~reveal the concentrition of
polluting gases, the effectiwness of air-filtcmng equilmort, and
Fredict the Farticulate content and polluticm of the air in rolztion- to
the natural atmosyliere. Ilans call for setting ul. thgise stat--ons in
sevcxal cities in the 1; rol-ean T,;art of the USS. and in EeiTkrovo in
19-73-74.
The alithor calls the 1-reservation of neture the most 4 im ortant social
yroblem of the centu-,y end yroj:oses that metrolcgical ser-vices share
the antij~o2.luticn task with the medical servi-ercs, and that a syster, of
rzeasurerent staticns, similar to seism.ic~staticns, be set uT throughout'
the USSR to monitor air ollution.
76

USSR LIDC: 621-375.826+532-783
VASILYEV, A. A., XOMPPITETS, 1. N. , NIKITTY, V. V.
'%hortening the Switching Time of an optical Transparency on a Liquid
Crystal"
Moscow, Kvant. elektronika (Quantum Electronics), Ito "Sov. radio", 1972,
pp,81-83 (from RM-Avtomatika, Telemekhanika i Vychislitellnaye Tekhnika,
No 1, Jan 73, abstract No iB438~by T. V'.)
Translation* A transparency on a liquid crystal controlled.by an electric
field is.used for data recording. Scattering of the light flux with tur-
bulent motion of the, domains of the liquid crystal by 4-ections of the
transparency to which the electric field-is applied leads to loss of co-
herence of the transmitted light and a shaxp attenuation of its intensity.
The pattern of electric,voltages recorded on the transparency is thus
transformed tc an optical Image which is,transferred asla hologram to a
photographic plate, using a laser, The frequency characteristics of dy-
'ion. As a result
namic scattering are studied for activation and deactivai.
of'studying the influence which an alternating electric field and short
field pulses have on scattering duration, an image recording cycle time of
less than 1.2 ms is achit-.!ved., Three illustrationsbibliog--aphy olf' six titles,
a/1

USSR UDC 620.17
AGARONIK, V. Ya., VASIL'YEV, A. A., DAYCHIK, M. L.
Study of Characteristics of High Temperature Tensoresistors"
Issled. Temperatur. Napryazheniy [Studies of Temperature Stresses Collec-
tioh of Works), Moscow, Nauka Press., 1972 pp 103-132, (Translated from
Referativnyy Zhurnal, Mekhanikaj No 11, 1972, Abstract No 11 V1347 by the
author's).
Translation: Methods and results are presented from studies of temperature
nichrome, k%20NSOYu and Kh20N8OYuD
and time.characteristics of constantan
chrome-nickel alloy, N~123L'iYu ni ckel-molybdenum ~ alloy. and QKh2lYuSENI,
OKh2lYu9 and OKh2IYu1O iron-chrome-aluminum, alloy wirvtr, upito 30 11 in dia-
meter, used inhigh t~-Imppraturc teiisore~istors. The studies are performed
at temperatures tip to 650*_ The basic dependences ofithe resistivity in-
crement of the wires Linder isothermal holding are established and critical
temperatures are determined for each alloy,above which stabilization of
the specific resistance and temperature factor of resistance of the tenso-
resistors is impossible. The jjoss~ibility.is demonstrated of.creating thermal
self~compensation of tonsoresistors in the interval up~.to 350' using chrome-
180YLt and Kh20N80',uD. The temperature and'time charac-
nickel alloys WON
1/2

USSR
UDC 532.593+662.215.1
ASILIL A. A., GAITRILFNKO, T..P.,'MITROP-ANOV, V. V., SUBBOTIN, V. A., and
TOP&ITH, ~M.Ye.
IrThe Position of the Point of Transition Through Sonic. Velocity Behind a
Detonation Front"
Novosibirsk, Fizika Coreniya i Vzryva, No 1,' 1972, pp 9 8- 10 4
Abstract: An attempt is made to deten.-.iine experimental ly the position of the
Chapman-Jouguet surface behind the front-of a detonation occurring in a Pipe.
pipes-filled with various gas mixtures, the interaction of a detonation
wave with a thin plate, situated along the pipe axis, iz studied at various
pressures to determine the position of the.Chapman-Jouguet point. 2 figures.
Itable. 9 references.
36

All tals
Si3X CrYS
USSR UDC 539-67
VASIL')%V-
ayid GRUZIN,F L
"Thteraction Between Point Defects an&Dislocations in M.-Iybdenum Single
crystals-,
Sb. "Vautrenneye treniye v metallicheskikh materialakh" (Tnternal Friction in
Metallic Materials), Moscow, Izd-vo "Nauka, 1970., PP 90-94
Abstract: The results of an investigation of the recovery of amplitude-
independent and amplitude-dependent internal friction:on deformed, amnealed
molybdenum sa=les am present4d. 'Am -recovery phases were, obseinred. The
first recovery phase tLs related to the w1gration of dislocated impurities
atoms; the second phase is divided into two stages. A redistribution of
impurity atoms takes place in the first-stage, with subsequent locking on dis-
locations; however, the locking ot.dislocations is weak, and with increasing
vibration amplitude the dislocations break away from locking points. The
formation of Cotterell atmospheres.occurs.in the second stage. Radiation by
electrons affects-only the first recovery phase- 3 figures, 4 references.

USSR UDC 534,222.2
VASIL'YEV. A. A., GAVRILFNKO, T. P., TO~CHIYAN, If. YE.
"Location of the Chapman-Jouguat Surface in Multifront Detonation in Gases"
V sb. 3-y Vses. aim Lum po gore (Third All-Union Symposium
nivu iy L_rL -u, 1971
2o
on Combustion and Explosion, 1971-collection of works), Chernogolovka, 1971,
pp 199-200 (from RM-11chhanika No;llj Nov. 71, Abstract 'Alo 11B135)
Translation: In the example of gaseous explosive mixtures, a study was made of
the transition of the steady-state detonation,wave frora a metai tube to a tube
of the same diameter made of cellophane film. At low initial pressures of the
gas mixture after the transfer of detonation to the cellophane tube, a detona-
tion rate drop was observed, sometimes reaching extinguishing of the detonation.
With an increase in pressure, beginning with some value, tile detonation rate
became identical in both tubes. lt.is proved that in the first case the detona-
tion rate drop is connected with the occurrence of an expansion wave occurring
as a result of expansion of the cellophane~tube into the vone In which tile gas
velocity relative to the front is less than the speed of cound, that is, into
the zone between the lead 'Lap, edge of the detonation and the Chapman-Jouguet
surface. The position of the C',hapman!-Jouguet surface with respect to the dis-
tance between the leading edge of thevave and the place.where noticeable
expansion of the tube begins as a result of spreading of the walls was estimated
1/2

USSR
VASIL'YEV, A. A., et al., 3-v VsPs, simp6zium 12o &,o_reniyvi i vzryvu, 1971, Cher-
nbgolovka, 1971, pp 199-200
by means of instantaneous photographs of the critical detonation in the cello-
phane tube . By using the analytical form,of the expansion trajectory of the
cellophane tube, a one-dimensional numerical calculation of the profiles of the
mean gas parameters behind the detonation wave:was,performed as a result of
which it was discovered that these parameters differ essentially from those ob-
tained by the one-dimensional Zeltdovich-Neuman theory.
30

-2/3 036
UNCL4SS.1 FIE,D PiZifICESS ING DATE-04DE-r''10
CC --A-
,C ~tRC A lll~- --C P;G 7 0 9
Gp-o- ABSTRACT. 'TH r- S TANID R rl I z S R C f-I
'll00Ir-fCAFl`;q) IS
SATELLITE CREATE-D I N THE USSR i UNCLIUDING ITS SEVERAL
CHARACTERIZED BY !NfERCHANC-FASILI TY OF' 'ITS RASIC S-YSTE!iS A-ND PARTS. H E
D
"KOSMOS" S AT EL L I T~ES AU HAV E TH E -S AME 80 1 E 5, ANT E NINA S , S ME ON B0 D
'ND CO,'-TIPOINENTS OF TH EL It" ~Ql
E .1 SYS 4' E
CONTROL SYSTEMS, ELEMENTS ...CTR C L FO'
IT 4ENTATIGN "HE ""KCSI-MIS11 SUDY IS
BETTER PLACEMEN OF APPARATUS AND INISTIqUI
DIVIDED INTO SEVERAL C014PARTiMENTS. PROVISION 15 Al-0 MADE FOR PLAICEM~114T
JC SCIENTIFIC CGIMPW IT S ON -11 SURFACE~
.OF SOME SERVICIi , AtW 14. E N THE ROUTE.
DEPIENDING GtN, THE MISSIDINS 4 S S I GNIEG ON A, FLIGHT, PA-Al'lc'ULARLY FL[GHT
DURATION, THE EUECTAICITY 53i RCE IS CHEMICAL BATTER
IES, SOLAR CELLS, OR
SIMULTANEOUSLY. IF IT IS NECESSARY* FOIR THE SATCLLITE TO HAVE
PROTRUDIING PARTS, A-S 1WHEN S T ii Y I NIG S G -%I E P P. 0 P E A, T I E S OF T11-mE: 10,NOSPHERE,
THE "SOURCE G~: :ELEr-T:7Ir, ?~3WER 15 EXCLUSIVELY CHEMECAl. 6A."vERIE.S. N
c o ~-4, D uC T I ~,, G s c E ~,,, r I I,- I c p E,3 fE A ft HC. IRIE. Q ti f R I N R tj U R -N ~0 F I., (" 1) 1', P, p A I I J."; t4io
x p FRI 4 t.- u y A L A I I A L v (3 1- A p I j i T ii~ ~` E rif; I IN rl*,R $ H A Y f 11. F A T ED K 0 SM C'
U b -F 'UR "~LY
7'~ OUT WITH A OESl.-NT M-M)ULE4 NA 1 #4
This
PUTRODUCTION GF. A 8RAKING 1E.NGINE A 110 PARACHUTE SYSI'liM. THE SCIENTIFIC
-PENDENCE ON THE
INSTRUMENTATION ON THE- IIKUSI',150111 SATELLITES VARIES IN D
14 I'S S I ON, THE MAKEUP AND TYPEOF SERVICE SYSTEMS, REMAINS
VIRTUALLY CONSTANT. IF ANY CHANGES. ARE t4k)E THEY ARE INISIGNIFICANT.
THE SERVICE SYSTEMS ARE USUALLY It? PREFABRICATED ASSF118LIES. Til I S
MAKES POSSIBLE EFFICIENT USE OF THE' INTERNAL VOLUME OF THE SATELLire AND
SIMPLIFIES. ASSEMBLY AND ADJUSTMENT WORK, EVERY STANDARD11ED 11KOSMOSIN
SATELLITE HAS SEVERAL SERVICE SYSTEMS.~
UNCLASSIF IEG
V101 A 1

016 014CLA~S I k~0'~ PROCESSING OATE-04~DEC70
NO--APO!39709
:C-IRC ACCESSION
..ABSTRACT/EXTRACT--ONE, THE HEAT REGULATING SYSTEM, MAINTAINS THE NECESSAkY.
HEAT REGIME DESPITE VERY STRONG EXTERNAL ANO INTERNAL HEAT SOURCES. TH F
EXTERNAL SOURCES INCLUDE EXPOSURE TO THE~SUNIS RAY.S ANO RADIATION
REFLECTED BY THE FEART.H. INTERNAL HEAT, f5 CREATED i3Y OPERATING
I74STf-Lj-.4=_-'llT,c -ND ASSEMBLIES* HEATING OF. THE- 11KOSM0511 SATELLITES 15 VERY
INONIUNI FORM AND IS DEPENDENT ON MANY FACTORSo ~WITHOUT HEAT REGULATION
00ME INSTRUMIENTS WOULD BURtl UP ANDIOTHER WOUL19 FREIlE. THE RADIO
TELEMETRIC SYSTEM IS VIRTUALLY ALVAYS OPEN, THE SERVICE SYSTEM INCLUDES
I STRUMENTATION FOR A
IN CHECKING ON THE ORBITAL PARAMETERS AND SPECIAL
COMMAND RADIO LINK. THE TYPE OF ORIENTATION SYSTEA USED 15 DEPENDENT Q;%
WHETHER A PARTICULAR AXIS MUST BE ORIENTED ON THE SUN OR THE EARTH. A
'COMBINED SYSTEM IS SOMETIMES USED. THE, WORXING ORGANS ARE GAS JET
MICROENGINES ~ND FLYWHEELS ROTATING WITHIN THE:SATELLITr-. 1FOR-ROTATING
THE SATELLITE -ABOUT ITS C!~NTER_,`OF !MASS."NOTHER CASESITHESE SATELLITE"
f HAVE- AN A4ERODYNAMIC STABILIZATION.,SYSTEM. IN COjvlBINA;T.ION* WITH A SPECIAL
p,
OAMPING SYSTEK,~
UNICLASS~1!" LED

77
AA00445-75-.
Acci`Kr.:
Ref Code: :12jeoVoy
A
A
-
Training 'of Personnel in 'gachine_* Coastruction (Podgotovka kadrov v mashino-
-stro
yenii) Moscow., Hashinostroyaniyej, 1970,: 236 pp (SL:1944)
~TLBLE OF CONTENTS:
Introcbiction 3
Chapter I A Brief Raview of the Development of the Training 4stenj in
the Country 9
II Forms of i-abor Division and Tileir Relationship With
Trainip; of Personnel
Iii Irprovement of flon-Professional Training of Young, People 105
IV. Improvement of Trainijig and,SkiUs of Pei~fomel at Enter-
prises 165
B
iblio raphy
238

USSR UDC 539.3-.551.243
VASIL'YEV. A. A., and GRUZIN, P. L.
"Interaction of Point Defects With'Dislocations in Molybdenum Mono-Crystals"
V sb. Irnutr. treniye 7 metallich. materialakh (Internal Frictions in
Metallic 141aterials - collection of works), 'Moscow, Ncauka Pub. House, 1970,
pp 90-94 (from RZh-21,1ekhanika, No 12, Dec :70, Abstract*'No 12V507, Author's
Abstract)
Translation: Results are presented froma study of the rerovery of amplitude-
-independent and amp A tude-d6pendent internal friction in the follmling classes
of monocrystalline molybdenum specimens:. ~deformed, annealed at different
temperatures, and bombarded witb electrons. Two recovery stages were found.
The first recovery stage is associated with the migration of dislocational
impurity atoms; the second stage is divided into two further substages.
Redistribution of the interstitial atoms occurs in the first stage, fol-
lowed by their im-nob-i'Lzation at dislocations,-, however, dislocational im-
mobilization is weak and when there is a rise in the amplitude of vibrations,
dislocations part from their Immobilization sites. The formation of Cottrell
atmospheres occurs in the secondstage'~ Electron bombardment affects onlv
the first recovery stage. Bibliography: ~,4 encries.
36

USSR UDC:
VASIL'YEV A. A., GRUZTN, P. L
of Point Defects With'Dislocations in Molybdenum Mono-
....... ... .
:Cry
Vnutr. Treniye v Metallich. ?4ater.ialakb [Internal Friction in Metallic
Materials -- Collection.of Works]., Moscox,:Nauka Press,1970, pp. 90-
94.:(Translated from Referativnyy.Zhurnal Fizika, No. 11:1 1970, Abstract
No. 11 Ye 1364 by the Authors)
Abstract: Results are presented from thelstudy of the recovery of
amplitude-dependent and amplitude-indepen.dent internal friction in defor-
mations annealed at various temperatures and bombarded by electrons in
monocrystalline No specimens. Two~stages:of -recovery are detected. The
farst stage of recovery is relatedto migration of dislocated impurity
atoms; the second stage.is divided into tWo parts. Dwring the first part,
-redistribution of Interstitial atoms occurs with subseqt'ient a-ttachment of
1/2

Aerospace.Medicine
USSR yX 616.1;359.6
VABIL'YEV, A. B.3 First Lieutenant, Medical Corps, KOL'1W.11, A. I., Major,
MM, =edr--]~g-,-and TUANOV1. N. I.,, Candidate of Medical Sciences, Lieutenant
Colonel M ledical Corps
"The Punctional State of the Cardiovascular System in Xaval Aviation Crews
Awing S=mmer"
Moscow, Voyenno-Meditsinskiy Zhurnal No 4, 19731 pp, 68-69
Abstract: The state of the cardiovascularsystem iiaa eyaluatmd in the case of
26 Haval pilotr, find navlgatoro during and~aftar a prolorged cruize. The studies
showed that changes in the cardiovascular system were to a large eytent dependent
on the duration of the cruise. At the end of the cruise the average decrease in
pulse rate was 4/min (P-e- 0.05); in comparison with the :vesting pulse ratle, at
the beginning of the cruise static muscular effort elicited a 30-40:r~, increase
in the pulse rate, in th~! middle of the cruise the averaf~e increace was 58%,
and at the end of the cnxisc the jrean increase was 65%. Arterial blood pressure
decreased by 11% in the middle. of the ci-uise forthe enti-re crew, but in 8
individuals the decre-ase mnged from,15-24. EKG studies~conchjcted at the
'ddle of the cruise the
neginning of the cruise showed no changes. In the mi
1/2

USSR
VASIL'YEV, A. B., et al., Voyenno-Medit'si:askiy Zhurnal., No h, 1973, p1., 65-69
electric systole was found to be prolonged, the amplitude of the P wave
decreased by 34%, and changes in the R and Twaves indicated decreased tonus of
the sympathetic innen,ation and increased tonus of the.parasnrpathetic innerva-
tion- In 7 subjects the T wave was flattened on pbysical exertion (1-5 to 2-
fold), and in 3 indiv-1duals physical exertion caused th'e QM complex to be pro-
longed. 'The EKG changas were morepronounced at the end of the C3:'UiSe. It was
al'so observed that after a 2 hr flight blood pressure and pulse rate were within
-the nom for t3ost pilots and navigators. After tWo 1-5-2 hr flights at
intervals of 15-20 nin the systolic and diastolic presstAre. was increased by rrore
than 10 nm HF, in the majority of the subjects,, -and the p%tlse rate i-nerensed by
10-15 beato/min. Me reactions in the navigators were less pronounced than in
the pilots, as a rule. After a 3 hr flight at the beginning of the cruise there
vas an increase in the isystolic and the diastolic pressures, without a change
,in the pulse pressure - A similar, flight in the. middle or the cruise caused an
increase in the diastolic pressure while the systolic pressure remained
unchanged or decreased; the pulse pressure fell by 15-20 m:13 Hgj on the average.
The data shov that long-term summer cruises elicit definite changes in the
cardiovascular system,, whdch become apparent at the end a' the first month,
Consequently, during nP.- cruises there should be periodic evaluation of the
-0
c4rdiovascular systen.
2/2

USSR
KULIKOVAj L. V.* TROPINO V. P., at al
"1R 14ethod for the Analysis of'a 45-% Watting Powder ~CG and DDr"
V s.b.,Khim. sredstva zaabehity rasi. (Chemical Plant Protective Agents),
Moscow#, Vyp 3, 19?3, PP 128-132 (from Wi-Xbimiyas No 20, Oct 73, Abstract
No 2ON470
Translations An IR method has been proposed for the analysis of a 45-%
matting powder FCC (po'.'.Ychlorocamphene) and DDT. ;It has been established
that presence of fillersp FAV and adhesion additive In the powder does not
interfere with the analysis of PCC and DDT. Prior to the analysis the PCC
and DDT solutions were filtered to removeithe fillers Analytical bands used
axe 1310-cArl for FCC and 1100 cm--t for ~DDI~*
31

USSR UDC 547-555+547497
SVIRSICAYA P. I., STIZESBULAYEVA, A., NEGREBETSKIY, V. V.,
~.~~~~rASIL I yEV -nnd BASK-NICOV, Yu.,A... All-
Union Scientific IR'esearch* Tnstitut& of lChemical Agents for Pla-It
Protection
"Hydroxylamine Derivatives With Her6icidal ActivitY, 42. Reactions
Of ~~Derivatives of ~.1-Carbanioyl-N-arylhydroxylamines with Halidos of
..Halo alkylc arboxyl ic Acids"
Leningrad, Zhurnal Organichosk.0y Khimii, Vol 9, No 6, Jun 73,
TP 1.163-1171,
Abstract: ' 4-Carbairoyl.-N-aryllivd,-oxylamine derivatives, on react-
ing. with halides of alplia- and be t a-halo pro pion ic acids, formed
_.N-subsbitutcd 0-alpha- or 0-beta-lialopropionyl derivatives of
carbanoyl_'T-arylliydroxyla;mijies. - Unden the action of bases, O-bcta-
~7 -11
chloropropiony1hydroxylamines were hyd~olyzcd to, the Aniti,
hydroxylamines. Dopending on the ~ conditions of. thr-- reaction and
the nature or thC:sLI1jst;!,tUCn.ts) the NT--~zubsti tutc d; 0 -a! pha -ha lo pro-
Tionyl dorivativas oC c~arbar--oy.L-~%-arylfiydroxylainiries, on beitar
'
ubjected to-the actioc. o~ 1)
s ascs~ either split off jhydra-rcr alide
with tht~ formation of 0--acryloyl derivatives or underw-nt cycliza-
t.~011 with the formation of 2-,irY:L-4-(al-lcyl)aryl-5,-Iilet)lyl-1,2.,4-

USSR UDC 541.127
SHEREMET, N. G., VASIVYEV, A F KHASKIN,.B. A
and MEL'NIKOV, N. N.
"Kinetics of the Reaction of 4,4'.Dipyridyl With Trimethyl Phosphate"
Leningrad, Zhurnal ObsLchey Xhimii, Vol 43 (105), No 12, Dec 73, pp 2735-2738
Abstract: It was shown that the rate ofithe reaction of 4,41-dipyridyl
with trimethyl phosphate in presence of water can be.described by the
kinetic equation for a sequential-parallel two stage raiction. The
reaction rate constant depends:on the amouat of water in the reaction
mixture.
39
------------
WI
i~'7

USSR UDC 632-95
SURZIaRMA, L. V. , awd VASIVYEV~ A F
P I patzine in a Conraercial
I'Quantitative JI-nalysis of Atrat ino~ Simazine and, Pro,
Product ard Vettable Fovderz from Infraxed Absorption Sleatza"
for PLmt Protection
V sb. LTAm. sreedstva zashchity rast. (Chenicad .Plant
collection of works), iup.l, 4,',ozc6w, 19'10i pp 2210-216 (froji ~Ah-Kbirniy--,
No 11, Jun '12, Abstract No 1IN-456)L
Translattioni The specimen is formed into pellets ulth Dr, an(I transmission
Is measured at abs0--PtiDII MaXIMI-I Of Sele ed analytical bamds, relative to
at
tablets of -DVx-- B13r. I'm "DifferencrA" method io used to (Ioteivine oDtica-l
densities, Th4A t eoretical errors-of analysis aro cal
th calatedj and the
results are statistical1y emalyzedvl

USSR UDC 630:54t541.571.9:547.871
TIBANOV, P. V. BASKAKOV, Yu. A., LEVINSM, B. N., and
MEL'NIKOVA 1. A., All-'Union.Scientific-Research Institute of Chemical
Agents for Plant Protection
"Herbicidal Derk-ratives; of Hydroxylamine. XL. Energy of the Intramolecular
Hydrogen Bond, and the,Structure of Associiates of, 0-Methy1hydroxylamine
iazines"
Derivatives of sya-Tr
Riga, Khimiya Caterotsiklicheskikh Soyedinen1y, No 1, Jan 1972, pp 124-127
Abstract: Experimental data have already suggested that simplification of
X -ntramolecular
methods and calculati=; for finding both the energy of the i
bond, and the dimer-monomer entropy difference, will not substantially affect
the accuracy of the results. Using the temperature rel4tionship of the
equilibrium constants, as determined by the ebullioscopic and cryoscopic
methods, the authors determined both of the constants in question for seven
compounds of the symtriazine group. Also ~obtained were the infrared spectrum
for a solution of 2-chlor-4-di-propylamino~6-metlioxyamin'o-svni-ti-iazine in
hexachlorobutadiene, and the relationship between (1) the association factor
(f = MA!, where M is the measured molecular, weigh t , and ff is the moleculnr
weight of the rionovier, diA (2) the.moldr coacentration. Figuras for the
1/2
jp~jj~-'J' 1- ~W' I
IF', M, "'R~
MR,

USSR
BASKAKOV - Yu. A. , VOLOVNIK, L. L. IVASU KINA, N. L. ,
TIBANOV, P. ~ V. , and NEGREBETSKIY,, V,
tiHerbicidal Derivativas.oU.Hydr. laminii. MV. The Reaction of Halides
~y
-of,Haloacetic Acids with Hydroxylamine Derivatives 6f.Thiourea"
Khimi~a Geterotsikl. Soyedin. [Chemistry of Che Heterocyclir Compounds --
Collection of Works],No 3,.Riga,-Zinatne. Press,J971,,p_p 104-107. (Trans-
lated from Referativnyr Zhurnal Khimiya,'~. No. 5i Moscow,11972~ Abstract No
5N676 by the authors)
Translation-. The reaction of ClCH2COCl with N-me thylthiocart, amoyi-O-Me thyl-
hydroxylamine (1) without any HCl acceptor produces 2-methoryimino-3-methyl-
4-oxo-1, 3-thiazolidinittm (II), which is,conv'erted by beating in MeOH to 2-
uethoxyimino-3-methyl-1, 3-thiazolidin-4-one (III). T1,76 point. two (2.2) g
ClCH2COCl is added to a solution,of 2.4 &;1 in 100 ml ether at -20*, mixed
for 2 hours (after which the temperature,of the mixtutelis about 20') and
3.6 g II are separated, yield, 94 M1P,160* (in a sealed,capillary). A
solution of Il in MeOH isi heated 1-2 hr m a water bath, ',the MzOH is dis-
tilled under vacuum, producing III,.yield Aout.100 %V zap 88*.:. For a
previous report see RZHKHim, 1969', _01038.
69

USSR uDc: 6~2-95
BASKAKOV., YU A., SVIII M-KAYA, P. I., SHMMLE&M, G. S
VSEVOL.OZRSKAYA, N. B., TIBAINOV, P. V. andWSIL'YEV, A. F.
"Herbicidal Derivatives of Hydroxyl LTdne. XVII. Synthaz5.is of III-Al'