SCIENTIFIC ABSTRACT KUKAROV, G.V. - KUKHAYEV, F.F.
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CIA-RDP86-00513R002201620013-4
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RIF
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S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
September 17, 2001
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13
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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Metrology, S urvey,'"C' ?I~Lim.
USSR
UBC 772.99.004~,778.142
ZHAMENSKIY, V. B., W~.QONI, G. V., STRUKOV, V. S.
"Study of Possibilities of Using Holograph), to Incroase the Information
Packing Density of Microfilm"
Moscow, Zhurnal Nauchnoy i Prikladnoy Fotografii i Kinemalografii, Vol 17,
No 6, Nov-Dec 72, pp 419-422.
Abstract: This work presents an experimental study, of tho naximLLI pracking
density of information of varying degrees of ccunplexity oTi microfilm
(letters and text). The method of' successive and slimiltancous superi?iy,osi-
tion of holograms and various methods of production of redticed-dimcns~on
holograms were used. The dependence of the maximum iiumber of hologran-, of
an individual letter and of a segment of text on letter halplit is dezenidlied:
the number of holograns decrease5 with decreasing letter hiiight. 1%b e n a
spherical converging signal wave is used, the readablAity of the restored
image of a microfilm text is good when the area acctipitad h1i the hololra:n is
1/16th the area of the initial microfilm. An aelditirwial holt)gram can be
superimposed over each. of these reduced-size holograms with only a slipht
reduction in text readability. The compacting of Inforriati.011 achieve'd cor-
responds to a 45-times reduction -in dimensions of the orill.1-nal text. letter
1/2
USSR UDC 772.99.004.77S.1,12
ZNAWNSKIY, V. B., KUK&ROV, G. v., sniumv, v. S., Iijuscow, Zhurnal Nauchlio-v
i Prikladnoy Fotografii i Kinematografli, Vol 17, No. 6, Nov-Dec 72,
pp 419-422.
height 1.7 nm, with satisfactory readability.
212
USSR UDC 66q.7v?zi.o48
REUTOVA, G. A., and KU 0, E. YEQ
"Composition and Properties of Salt Baths for Two-layer Processes of
Vacuum Distillation"
V. sb. Vakuumn, protesessy v tsvetn, metallurgil (Vacuum Procasees in Non-
ferrous Metallurgy -- Collection of Works), Alma-Atat "Nwuka, " 1971,
pp 144-149 (from Referativnyy Zhurnal -- kintallurgiya, 1k) 6, JLui 71, Abstz-act
No 6G158)
Translation of Abstracts According to results of tasts, ii.nd calculations,
optimum composition of a "hot" bath was selected and suc"ssfuLly operated for
a two-layer process of vacuum distillation for alloys on Al ard Me, iba~ses.
The composition of the fusion recommended was C&C12 with 15-2(Y,9 Ca:-" for allo3ts
on a Xg base and a mixture of HgF I CaF , and W In a Osl8i42 railio for
alloys on an Al base. (three 111iiatrationsl 3 b1k1ogmjih1c entrica)
1/1
USSR
SMIOROV, A. L., KUKAVADZE.G. M., RAZINKOVA, 1'. L. , %1ARON', B. V. ,
FEDORMENKO, V. A., BOHKOV, A. F. and KUZNETSOV, V. VA.
"Autoionic Microscopy of Uranium. Preliminary Resulti.11
Moscow, Atomnaya. Energiya, Vol 36, No 1, Jan 74, pp 1.4-18
Abstract: The primary factor inhibiting autoionic microscopic analvsis
for now (particularly fissionable) materials, apparently, is the lack
of any final theory of the fo-niiation of images in the. autnionic inicro-
scope, or of a complete understanding of the physical. prin6ples upon
which the field evaporation phenomenon is based. Tho firs-t stage of
the work reported is an explanation of the capabilitLes of the autoionic
microscopic method for studying uranium specimens, and a si!arch for r-lore
effective modes of analysis, as well as the developtigint of corta-In assio-
ciated methodological problems. It is found that uranium needles can
resist the mechanical stresses imposed in the autoi~.-wtic. microscope.
The best result is achieved using pure argon and a mixturc of lie - 0.51
112 as imaging gases. A computer is used to con~.trui.,t a model of the
autoionic image of ct-uranium and standard stereograpliii.- p~ro.jvction!~ f'or
a-uranium in the planes (010), (001) and (110.1, the crystallo-
graphic faces to be indicatcd on the photomicrographs prod-oci~d. Pre] im-
inary results presented indicate the pos,-sibility in fixinciple of autc-
ionic microscope analysis (in atomic details) Oi Uranitun spc,~.~imvns.
1/1 - 41 -
USSR UDC 669-172:541.12.037
SUVOROV, A. L., and KUKAVADZP, G. H.
"Mobility of Displaced Atoms and Their Complexes in Cryt4tallina Lattice of
Tungat= Under the Influence of an Electric Field"
Monokristally Tugoplavkikh i Redkikh Metallov [Single Cv~4stals of Refractory
and Rare Metals -- Collection of Works], Nauka Press, ki'171, pp 108-111
Translation: A helium ion projector is used to study the dev~,Iopi,,ont oif
displaced atoms and small complexes in tungsten specin,20t; boiri")~Lrdcd With
deutrons with energies of 5 MeV. A method is described for ilc-!ntification
of individual atoms displaced into interstitial positioios and corl-
plexes of these atoms on ion images of speciniens stibjeclod to bonbzirdment.
It is demonstrated that the individual displaced atoais to the
surface under the influence of the electric field in thot! proj(~ctor at
78*K. The temperature threshold for immobility of the Misplaced atoms
with an electric field intensity of 450 Mv/cm is assiztedl to be 21'K. It
is demonstrated that the complexes of displaced atons observii(I on ion
Images of bombarded tungsten specimens, containing tip til) 20 individufl
atoms, are practically immobile in a strong electric fiq.,Id at MOK. 111is
allows their crystal lographic distribution to be deterin.-I-ned, :1 Fij.,,ure-s;
5 Biblio. Refs.
USSR
UDC fi,69-172;539.2
SUVOROV, A. L., and KUKAVADZE, G. M.
"Nature of Defects in Single Crystals of Tungsten as a Putictk,n of Fnergy of
Bombarding Deutrons and Method of Irradiation"
Monokristally Tugoplavkikh f RedkIkh Metallov [Sin~jlc! Crystals of Refractcir~
and- Rare Metals -- Collection of Works) , Nauka Preiis, 1-9 7:1, P11 3,03-107
Translation: Results are presented from an experirent studlyh1r, the Structure
Ji,s
of -tungsten single crystals subjected to 4ombardment with 6.utrons at enerp .
of 100 KeV, 4, 5, 8, 10, and 12 NO, performed in a low-tempexature- helit=i
ion,projector.
Significant difierences are established in the nature o1! defects formed
with the two methods of irradiation, differing in the miquenci, of preparfl-
tion and irradiation of specirians. The dependence of tho nature and con-
centration of defects (individual vacancies, vacmL-j climiters, individual
displaced atonis and Lheir cor-plexes and dislocaiatm) ob.iierv~id oil ion kna;,lt!F
of the irradiated specimens on energy of bod)n-Ming deut-mv; Jil !1(~Ildled.
3 -Figures; 6 Bibliogral)hIc Raferevire,-i.
USSR
UDC 669-172:611.3.032.26
KUKAVADZE, G. M., SMIOROV, A. L., and SHCHAROV, B. V.
"Study of Neutron-Bombarded Tungsten Single Crystals th5ing an Ion Projector"
Monokristally Tugoplavkikh i Redkikh Metallov [Single Crystalii of Refractor;
and Rare Metals -- Collection of Works], Nauka Press, :1.971, pp. 99-102
Translation: A low-temperature holiLU.1 ion projector B, used to sto(ly de,.
fects arising upon bomnardment of tungsten specimens with fist;ion-spectrU.111
neutrons (intergral flux 1.5-101`3 n/=2). The fomation, of hidividual.
vacancies is detected (concentration -10-"), a6, well a!i imlividmi) atom!;
displaced into interstitial positions, vacancy c1mit(mi "10 A in diameter
and larger, and dispersion clusters encompatosing multiatilmilic oroa3, in
which a significant nunber of atains of the lattice are li,,)eated. 3 Figurci;;
5 Biblio. Refs.
52 -
LNil^L S S I I IF C GATf--,*-WUL7
TJIL~--Aufc ILN III c~'Hcjs M fO~Gsll'.lq Ccy_-^.f'-LS rULIE T~
ALP~.~ 11.1sIICL-E E~ -1 -
ALTHL~--SUVCQCV A L KUKAVZC,~,"-a.V L'(76,KLIV r A #F
CCL;%TPY CF INFC-LSSR
SCURCE--ZFU~t%tL-ENSFERI',6EhT.8L4NCY I TECSET lCt-ES?,CY F 12 IK I10,7C, VCL 56
Nti It PP 6 cl- E 7
DATE FLFLlSFEE------7C
SLOJECT AREAS--Fl~YSICS
TCPIC TACS-SINGLE CRYSTAL STbLCTLRE-,'TLKGS7ENr P A F, I [ C L E 60E h I ,
ALFHA PARTICLE
FARKlKC--hC FESTRICTICN5
-OUVENT CLA5S--LhCltSSlFjEr
JRC A-CCESSICN NC--4FCC3EC31
UNCLASSIFIEC
Acc. Nr: 4POD3803I.- 'Ref. Code: UR 0056
PRIWZY SOURCE. Zhurnal Eksperiment:al'noy I -mlc,.)-reticlhes'M)~7
Fiziki, 1970, Vol 58, Nr II, P ~, IR6, 8 7
AUTO-TON MICROSCOPY OF 138FECTS IN TUNGSTRN St)GLP.
CRYSTALS DUETO a-PATITICLE J;0M1ARRNfI:.?,NT
A. L Surrrav, 6. 3t. Kubivirlzr, A. P- !W%Iulu,
.-St' L a
Tungsten C)-N -11 1111 li()Zl,~ (lilt' tJ 1xill noll, v.
(from 12.7 le) 213.1 NitV) arc im"Lip,,iml, by U1430.1)'i of a lic"111jr.1 I'm
riting at 787' 11*1. Tha intoual irratlialitin di)~es variol irA par-
licles /cat2. Fuur main types ijf impeffecLian.4 wvre obsvivf,~4 iii lhq irrii~h;iteil
Angla vacancies, afoivs displacc(l W ititcrstiGicl jmsiutms~ v; ciricy clutvrs of 10 A
ifiameturantl sinall comph"w-i 0 ilisplaced nimix un 0ie surfitce,
RLEL/FR4ME:
J LITY 3 10 72 0e
L IN t'.- L A 5 5 1 F I F CPk(Cliss P.(; 114TE-03jull7c,
TI]LE-AUTC JCN ~MCSUPY CF CEI-ECTS I& ru f4 TeN OOL I-,
41K
ALT~;CF-SUVC409
..G -11
CELNTPY CF INFC-LSSR
.scuRcE--lf-Uf-hhL kg!FERINENTALINCY I TECgETICI-ESKCY FUlKl, Lq?Ct VCL 565,
NK It PP 65-F7
-DATE FLELIS~-EC--70
SLHJECT AREAS--FFYSICS
TCPIC TAGS-SINGLE CRY~TAL SfRLCTL.R&,' TUAGST'EN, PA~71CLE
ALFHA PARTICLE
CEhTFIL PARKIhC-NE ;ESTRICTIONS
OCC L N7 CLASS-OCLASSIFIEC
PACXY -PEEL/FRA"-,i--lS7_'l/lC72 SIEP
Cillc t,(--;,FCC3,prjl
L N C L h S S 11: 1 E C
.Acc. Nr: :1 W f Code UR 00-56
PRDURY SOURXE; Zhurnal Ekspcrirmer~tai'noy i Teaj:uticjjo-s,,Lcy
Fiziki, 1970; Vol 58, Nr 1, pp $16-617
AUTO-10.N -1110(C)SCOPY OF D'EFECTS IN TU"WiSTFIS SINGLI.,
CRYSTAB D(;Pi TO a-PARTICLE 130,Nj[I~,ikItDIIFN r
A. L. Surorov, Af. Kukarwl--,~,
-7
ai impk.,rfecTi,,ms
Tungsten crypt tj IpgIlkirdille fit:
01-0111 t-I.-, !,)
, -N!,V)
ra t, opo
ing it 7S.'K. Tim ifitegral irradialitirl dl,'-'ies uarie,l ~--vhvoi:-p 1-7-I'll", ard par.
liclas /cui2, Your main tvpc~ I
4.)j jj~11I.Cirl,* Ct,i(jn..j wer ol,S iii Cho t-i,des:
Single vacandes. alows disitlaced to NINIS1411111 WS11101PI. 'a(W.Y cb, (if 10 A
dimuetor and sm~dl comple--w-i lot dv5placed altorti, ~Ljn the surfacl?.
REEL/FUME
19731072
It
Mal /<
Ins-,tuze of
Rir r" ~N' o in~
Member, Academy of Sciencec Lacvia:i S~~,
"Virus inh-.-Lbitors"
Riga, Sovezskaya Tatviya, 11 Pe:3 70, p
.~-.bstract. in the discovevy of` Viras JA*.111kJ.::;-_,_-(:~.-;-q fic"
few yea-_-s is de s crib ed_ The discussion centorc; 12 L,.:) C.
an anzivlrus prozein which a nor,,i,1.,aL ceJ.L forims
its vi-I.al act-;*vity in response to irtroduct-ion of v:ixt.,.s L.-~Zc
Cell. I i', roil itaolf liar, a limited e` lect:, bul_- J~- tz- r I,*
indticers iij pro"lijirrv". ~,Uboriucleiic,
tiC, IMd 1,-.1,%CVOA101(!CL111_1r PoL."aniom; o C Iv':
imi-vr Dure 'nterfer-c-n C,11,11 katitrat
:iCrc;lAx! C,
L
succe.,,-zi. wC the Inst-L tiLe -'f
of the Nolecal,117
iand, oth,~rs arc E;ttldyin~-, ztle C~-
toka haz3 studied, the capacity of variouz I I', t Q 17-
feron. It has been dlemonatra~ad. that the
interfc:ron is closely connected wLth other rC,.,3Ct1_On_3
1/2
K'U.K_A.Y'N' 11'. Ct a' a,
of the or-an;_~-m. It recen'.".1v ",eq!n
-tip, al-'6
suppresses MU, Lic~k':-Lon Of bat"', infect"
)'-CC:eSS OL, A
viruses. It c;-n ia:iibit tile
cell , ever, he- i,-,troducud af ter t'ae Of, a
Virolo-ists ~,ad spccialflslco in
reagents ar-a called on to investi'.,'ate tile
of nucleic acid-- and expand research on synthc:.A;.~l 0~:
hiah-m,olecular-wei,-ht substances. which can be ~goad ;-il"ti-
virus protein in the organism.
2/2
4/2 027 UNCLASSIFIElY PRbCES$ING DATE-16OCliu
TITLE---STERILIZATION OF TIPS ANU DENTAL DRILLS 8Y NE:ANS OF ULTRAVIOLET
IRRADIATION -U-
AUTHUR-:~~~~..
COUNTRY OF INFO--USSR
S(JURCE--STGMATULOGIYA, 1970t VOL 49, NR 3, PP 64-65:
DATE PUBLISHED ------- 70
SUBJECT AREAS--BIOLOGICAL AND MEDICAL SCIENCES
TOPIC TAGS--DENTAL EQUIPMENT, MEDICAL SUPPLY STERIL.11ATIGNi UV lAkAWATION
CONTROL MARKING)--NO RESTRICTIONS
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/f-RAME--1998/0076 STEP NU--LJR/0511./7011)q.9/OJ3/0064/0065
CIRC ACCESSION i'40--AP0120776
UNCLASSIFIED
2/2 027 UNCLASSI FIED PMCMING DATE-16OCT70
CIRC ACCESSION NO-AP0120776
ABSTkACT/EXT.RA'k".T--(U) GP-0- ABSTRACT. SUMMARY. TIKE AUTHGA PROPOSES A
DEVICE IN WHICH STERILIZATION IS UfEc'rn BY MEANS (if: ULIKAVIOLET
IRRAUIATION. BACTERIOLOGICAL CONTROL (2a6 INVES114ATICINS) DEMUNSTRAILO
THE HIGH EFFECTIVENESS OF THE ABUVE MENTIONED METHUi. FACILITY:
ONEPROPETROVSKAYA GPROOSKAYA UOLINITS,A NO 11 AM) t~AM",KA
TERAPEVTICHESKOY STEMATOLOGII KIEVSKOGO J4E0I'TSJN$KLG0 1145fll-Ulh EM. A.
A. BOGOMOLITSA.
UNC L Al-, S I F I F D
USSR
IJDG 547,412
Y,UXWIj V. P., KASHEVAl T. N., wA XIEISANOVl A. V.
"Beaction of Trichlorophosphazoperthloro Maxie with Aryl Amines and TheIr
Hydrochlorides"
Laningradg Zhurnal Obahchey Xhimil, Vol XLIn (CV), No Ij 1973f pp 22-23
Abstracts Hydrochloride salts of annatio aalnes and flne aXonatic &minus
with PXa < 2 react with trichlorophosphazo perxibloro othamij on the
0(-dichloromothylone group with the forAation of trLctl:Lorol)h,oisz)hazo-~i-axyI
iminotrichlaro acetyls, On interaction of trichlorophama parckdom etl=e
with aryl aisinas In a Is4 ratio# tria(arylaaino)plioupfui)ut)-li-o4r:ylimino U-1-
chloroacetyls are formed. Bona of tho physical proportleist tho yields end
formulas of these compounds axe tabul.&W# and tho oxpoirlmnW lxroced=os
for obtaining five of them are outlined,
IF USSR UDC 5".1.03
ZHMMYA# 1. Not KUXW't Vs Psi TUM's 4, Ass ZOIMALWYAo L. A.
"Mutual Effect of SubGtitutions In Triphartylphosphazo Datizents!,
Leningrad# Zhurnal Obshchey Kkdmiit Vol =1I (CV), No 'to M3, PP 82-66
Abstract# A study was made of the mutual effect of au1js:tjtuitjav3 in tri-
phonylphosphazo bcnzenes. The basicity constant of thij 'trir*4ony1PhcUFh4LLo
benzenes (G61i 5)3P - "C6 Hj~ and wuLlines X%Hj~HH2 twe correlivWd identicAaly
satisfactorily with &0 0 & and d - by the constipats of the subatitu-
tions X. In contrast to the dienthylaAino " the amixio groulLso the tzriptwnyl-
phosphato group has a positive induction affect, The :Voll(niing tale3 of
values are presenteds 1) the parameters of the comllLtion equations pK -
the constants CO 0, & and d - for Uiphenylphosphtuo banzer-as (C-H ~~P
6 5 3
NC6Y calculated by the data of V, P, Kukhar's et al,.o Pwicho uo W,
j, the more exactly defined psmsters of thm co=,elation equatiow
1696, 197r
pKa - constants Ce 0 and the paxameters eX the correlation
It
1/2
37 -
USSR
ZHMUROVAt 1. N.g et al., Zhurnal Obahchoy Xhimiip Val 11,11I (CY)t 110 1.
19730 pp 82-86
equations P11a - constants d 0 p dand d- for triphonylphosphaza berivyIA-
denanillnes nj nl-(C6H ) - NC, VCA~ in nitromathanop the ramwatexe
5 3P 0114CH -
of the correlation equations P11a - constants d 0. d and for viaii-asa
the reaction constants of the -t-riphenylphoaphfizo M)up In aacohol
"H296YP
and nitromothane by the equations of M. 1. Xabatachmlk frhonsThoruaj, No I p
117# 197gt the Hammett constants and the components the constanto
d n Of
of tho groups (C6H5)3P-rl (CH 3)ZU"t the 'basicity cowtants af the triphenyl-
phoaphazo-a-binyl benzonas (C611 3)3N1'C61'4C1'"CXY in jUtwitatliallo (95% (acolvdl)
andd subatitution consUnts in nitrojoVato (9.% aU*hol) Colculated by
pK of triphanylphosphazo benzenes (C6H ) PWNVI,~,
a 3 3
2/2
USSR
UDC 547.419.1
ZMVROVA, 1. H.., YUMMITKOO R. 1. MRMRI v-,,,P., ZOLOMI&EVA, L. A., and
0 1'... .111-1-.1 It - - .1
KIRSMOV,, A. V., Institute of Organic Cheridstry., Academy of Sciences, UkrLinian
SSR
"Protonation of Triphenylphosphazoazobenzeness 11. Effect at' .1-l'ubstituents on
the Position of Tautoireric Equilibrium"
Leningrad, Zhurnal. Obshchey Khimii, Vol 41,) (1011), No 9p '~ep 72, pp 1-954-1-359
Abstract: Thutownric equilibriwa in the solutions of
benzene calts depends an the concentration of acid as wull au an the Clectrartic
nature of the substituento at 41-ponitiono Die di-Mrevwen in nbsorption, raxira
in neutral and acid media and the basicity constants of
benzenes can be correlated with the a-conatants of 41-substltuenta.
USSR
UDC 546.135:541.651.2
ZIMUROVA, I. N., YURCHENKO, V. G., KMAR', V. P., and ZOLOTAMM, L. A.,
Institute of Organic Chemistry, AcSc"re-ciV'6'f-"'*'S"'c"f'ences, Ukraiwtan SSR
"The Effect of the Substituents at the Phosphorus Atom on the Reactivity
and Electron Donor Properties of the Phosphazo Group"
Leningrad, Zhurnal Obshchey Khimii, Vol 42 (104), No 121:, Dec 72, pp 2656-
2660
Abstract: In an attempt to compare the effects of substittients an the
basicity constants and electron spectra of phosphazubtinzenes, pKa values
of a series of triazy1phosphazabenzenes wera determin(M. Thc basicrty
constants vary considerably with the electron nature of aD;yl -.4ubstituanCs
up to 6-7 pKa units. The substituents at the pbosphor,%is itain have a lesier
influence on the electron donor properties of the ph olt lilt aitl 1group in ene
excited state than on the reactivity of the P:N.
i/I
1/2 012 UNCLASSIFIEd P40CESSING DATE--230CTIO
TITLE--REACTION OF TRICHLOROPHUSPHAZOPERCHLOROE-THANE WIT14
ARENESULFONAMIDES -U-
AUTHOR-(03)-KU5.H.LR,l V.-P., SEMENlYv V.YAot PISANENKOw N.P.
COUNTRY OF INFO--USSR
SOURCE--ZH. OBSCH. KHIM. 19701 40(3)t 557-61
DATE PUBLISHED ------- 70
SUBJECT AREAS--CHEMISTRY
TOPIC TAGS--CHLOROETHANE, URGAN!C PHOSPHORUS COMPOUNO, SULFONAMIDE
CONTROL MlkRKING--NO RESTRICTIO04S
DOCUMENT CLASS--UNCLASSIFIED
PROXY REEL/FRAME--2000/0670 STEP ~i()--UR/00*11)/'fl~)/!)~,#,J/,)kf,.~/O~15'1/t)-161
CIRC ACCESS;ON N0-00124533
UNCLASSiFIC-0
2/2 012 UNCL ASS IF I EO j,A(:ICES.~j!JG CIATF-210,CTIO
:IPC ACCESSION NO-AP0124533
48STJRACT/EXTP.ACT--(U) GP-0- ABSTRACT. RIEFLUXING AN 1---QUE~~JLAR MIXT. OF
ARSO 503 NH 5U32 AND CCL SU63 CCL SUB~ N*.PCL SUB3 IN il)ICL 13-10 Ilk GAVE
100PERCENT HCL AND, AFTER PROLUNGED EVACUATIJ14 AT '10005-GPEESP CCL SU63
C(;NSO SUB2 ARIN:PCL SU63 ( AR SHOWN) PHv OILP G ;'51,14160105 L6J-21)E~REESt
0 PRIME20 1.6292; PPCLC SUBO H SUB4, 14. 102-4j)EGRUES; flobliC SU66 It SU34,
M. 109-11DEGREES; PrMEC SUB6 H S064v M. 104-60EGqUS; M#O SUB2 NC SW36 H
SUR4, M. 76-80UEGRESS*. P,U SU132 14C SUB6 H SUBsir .11. 184-150EGREES; 3 r 4 v 0
SU82 NICUC SUd6 H SU63 M. 97-80EGREES; 2vC. SUB10 +4 Still'il. 01L. THE SAME
WERE PREPU. FROM EQUIMOLAR MIXTS% OF PCL SUB5 ANri CCL $kIB3 C(;tq$O SUa2
AR)NHP0CL SUfiZ ( I) IN REFLUXING C SU86 14 SUB64 TAE Pik-ODUCTS TRCATED
WITH I MOLE ACOH IN C SU86 H SU06 GAVev APTER 10 PIR AT ROOM TE'10.v I IN
46-90PERCENT YIELDS (AR GIVEN): PIMEC SUB6 fl SUIPi 4. 1,40-20EGRUS;
GvCLC SUR6 H SU04, Me 153-40EGREI:S; PICLC SU66 H 51)840 H. 120-30EGkEES;
Pj8RC SU36 H SUB4, M. 150-IDEGREES; MvO SUS2 NC SDB6 H SUilltv M.
168-70DEGREES; P,O SU82 NC SUR6 H SU64o N. 164-6UEGREES; 3#410 SU82
N(CL)C SUB6 H SU33 M. 173-40EGREES; 2o4, SU310 H SU1.179 M, 179-800EGREES.
SIMILAR REACTION WITH H SU62 0 OF EITHER I OR THE.PHOLPHA70ACYLS GAVE
80-90PEkCENT CL SUb3 CCONHSO SU82 AR (AR GIVEN): PHt 4. 156-3DE~;R'EES;
P,MEC SU86 H SU64 M. 140-2DEGREES; PvCLC SU86 H. SU64 ?4. 169-71UEGKEES;
P98RvC SU86 H SU84, (14. 163-60EGREES); M*O SUB2 INIC. SU116 H SIJB~v- 414.
167-RDEGREeSI; P,O SUB2 NC SUbb H SU84, AM. 21.0-I.I.DEGReEE); 3v~,O SUB2
N(CLIC SU86 H SU133 (Me 149-50DECREES); Z#C S~JI310 Ii SU117 (Me
138-90EGREES). HOT H SU82 U GAVE ARSO WO? NH .11462o
UNCLASSIFIED
u S TRI UDC 54~-412 74 -t- 547-464-17
Y,UKHAR, V,_P-~I, an "KOVAL', A. A*, Institute of Oraania Chemistryt ruev
At-a-demy of Sciences Ukrainian SSR
";nteraction of (X,CXI-Bistrichlorophosphazo-C(tol,,4,,13,0~,,CLI, 6vo-
of-octachloroalkanes With Alcohols"
Leningrad, Zhurnal Obshchey Khimii, Vol 40, No 4, Ppr 71), pp 776-791
Abstract: 0( C-X'-Bistrichlorophosphazo-a,a,rl,,(Jco4t,(~41,,61,41-
octachloroalkanes react with prim"ry alcohols at a molar ratio of
1 : 8 to give dialkyl esters of
o(I-tetrachloro-O(,O(I-biaiminoearboxylic acids The latter react
with alcohols in the presence of hydrogen chloridfl at-, $00 to cave di-
esters of 0( , OG 0( 1, OL I -tetrachloro - o(, , I -tetra chloro- ifX, QL I --dicarboxylic
acids. Dialkyl esters (1) are hydrolyzed with witter al~ 20-250 to give
diamides of N,Nt-biadialkoxyphoaphonyl-o(,ot,,al~i,A1C13>1?eC13>SnC14>TiCI4. In 010 Case " tolt"!"e, t-110 reacti"
proceeds somewhat more readily in the presence of BblUr), whilil! chlorobelizene
reacts less readily than benzene with this catalyta. Pits-- reat--tion of LrJ-
chlorophospliazoperchloroctliane with other arpnic 1101114!rjt~l Ill tile
of Lewis acids Inads to renin formation slid difficulty ta isei3ating the.
corresponding trichloromethylketones. !V'-Dichloroplioqpti,,unylinil~4110tric-lioro-
acetyl chloride reacts much more slowly with benzene in the presence of
antimony pentachloride than does trichlorophosphazoperchloroel:hane with
a much lower yield of trichloroacetophenope.
1/1
USSR
K2=6016'". SEMEMY, V. YA. , KIRSANDY, A. V.
"Complexes of Trichlorophosphazopolychloralkaneswith Luwis Acids"
UDC 546.135
Leningrad, Zhurnal Obshchey Khimii, Vol XLII (CIV), Nu, 1, 1972. pp 93-102
Abstract: Trichlorophosphazotetrachloralkanes react casily ttith Lewis acids
to form crystalline salt-like complexes (I) which wero isolated In the individ-
ual state:
RCC1 CCI N-PCI + Mci (RCCl CCI-11-DCI I+11cl-
2 2 3 n 2 3 n+l*
I
The yields, formulas and some physical characteristics of the compounds
are presented. In the infrared spectra of the W, complexei; there is.,.an in-
tense abanrption band in the 1630-1700 cel rango. belongring to the C-I'4'- bond
vibrations [Z. Arnold, No V, 24187, J9621, The
(1) complexes are strong electrophilic agents. and their rea4:t easily with
various organic compounds - hydrocarbons, aldehydes, JLcronas, simple and coT-
plex eaters, nitriles, nitroalkanes, and so on. Structures a;re proposed to
explain the chemical and spectral properties of these -complaxes.
USSR
LTDC 546. 185
GUSAR', N. I., IVANOVA, Zh M. V and MRSADIOV, A. V.,
: E71-CAagReBM-;YA"07A?wceences Mraintan SSR
Institute of Organic Chemistry
"N,N-Dialkyl-N'-Dialkoxyphosplionylformamidines"
Leningrad, Zhurnal Obshchey Kh1mil, Sep 71, Vol 41, Ito 9, pp 2107-2108
Abstract: N,N-Dialkyl-N'-dialkoxypliosphanylforinamidEnes axe readily
obtained by treating N-dialk-oxypliosplionyliminofoiiiLic acid esters Witil
secondary amines at 0-5*C without a solvent
+ + WON
N-dialkoxyphosphonyli,minoformic acid methyl ester (II, R',-('H:3) was obtaincd
in low yield from the 1,1-dichloromethyl ester and dialky.himidophosphate,
in the presence of triethylamine in benzene
(110):P(Ot Nit. C-j~;CJ10Cjj,
58
USSR
UDC 547,553.1+546.185
ZWUROVA, 1. N. , YURCHENKO, R. I., P. , PE'rRkS11FKXO, A. A. , and
KIRSANOV, A. V., Institute of OrgaUrFLnUMI.Stry, Acad. Sc., Ukrainian SSR
"Protonation of Triphenylphosphazoazobens:enes"
Leningrad, Zhurnal Organichaskoy Khimii, Vol 7, No 5, May 71,, pp 1027-1031
Abstract: 4-Triphenylphospliazoazobenzenes (1) are protonated In alcoholic
solution of LN 11C1 principally at the triphenylphospioj2o group. Wlien the
strength of hydrochloric acid is increa6ed to the lev-0. of 3-6 N, the
tautomeric equilibrium is shifted slightly towards thol! azo group salts.
The differences in absorption maxima of (I) spectra token In neutral and
.acid media ON 11Cl) correlate with the a- constants Of the. V-position
substituents. In comparison to 4-amino- and 4 -dine
the 4-triphenylphosphazoazobetizenes are more basic by about 5-6 pKa vn;iL!;.
Although accurate comparisons were not pofisible, the basicittr canstanLli Of
(I) type c compounds correlate with tile aO and c- comotant.tj of tile subliti-
tuents on the 4-position.
USSR uDc 547,1119-1+546:181
WMAICHMP N. D.) M1rEN1Y, V. Ya., WMAR, V. P. and UMANDIt, A. V., rastitute
of Organic Chemistry, tTkxalnian Acadftl~brtdj6iice SSR
"Phenyldichloronhosphazopolychloroalkanes"
Leningrad, Zhurnal Obshchey Xhimii, Vol 41, No 5, MRY 191,11, pp ~.64-938
Abstract: Pheny1dichlorophosphine was treated with alipl~ntic n1triler, mrd
chlorinated to saturation, to -ivri
alkanes. These reactions proceed airt-jitane(waly and Ute prol-.icts rer-dily
hydrolyze, react with amines, alcohols, and phenols. In n. further reactinr.
sequence, the Dhenyldichlorophosphu.,~opolychloroalkanea viu-e treated witb
arenuoulfaudde. ,% 8 1) --. A r
PCCj2N=PC1jX J. JjjXS02Ar 211CI +
X =Cf. MI.
This reaction proceeds slovly in the temperature range of 110-.1300. 7he proJuct
is easily hydrol)-Led, reatts with alcohols,, amines and 'rhit=ls to form prhenyl-
dichlorophosphazo-ii-arylesul-foiwliidnopolycliloro acyl camounic.
1/1
USSR UDC :M.491.8
KUKHARI, V. F., BUKOVSKII, M. I.. KASHEVA, T. N., FALK31CHUK, V. S.,
A. A., SOLODUSHENOV, S. N., Institute of Orgaac ChamistrY,
Academy of Sciences Ukrainian SSR
OPhosphazo-1.3.5-triazines. IV"
Leningrad. Zhurnal Obshchei Khimii, Vol 4-0. No 6. Jun 90, 1226-1229
Abstract: 2-Azido-4,6-dir-etho>:~,(plieno.V)-l.3.,~-ti-ii-~7kni3:i easiily react with
tertiary, phosphines and trialkyl phosphites to form. ,(),V
(phenoV)-1.3,5-triazines. The reaction is axothorni* and it. completed Within
10-15 min. lariphenyl phosphite reacts leas rapid"'.y. 2virtiary phosphiraza
react easily with azides of diaminotriazines to Dorn
-10.5-triazines. !he phosphazo compounds are cokorlm:= cryi;tals which
readily dissolve in alcohol, acetone, methanol, but wh4ch arqj insoluble in
water and hexane. They are hydrolyzed :bw boiling watow or in L, hydrocnioric
acid. The basicities of the compounds were determin&4 ;Ui n~l,roxc"ano ani
recalculated to the corresponding values in water. All theso t=pounA3 'were
found to be weak bases. Presence of amino or alk7lamino gruvps in the mole-
cule raises the basicity by 3-4 units.
1/1
USSR UDC 546.185:541.6,,51,2
EE2W I , -Vr PEETRASUNHO, A. A. , ZINUROVA, 1. 14. , TIJ OAR A. A,
5DW-DUS IKO S. N., Institute of Or~;anlo CbemiiiLry, Kieirj,
Academy of Soicnaen Ukrainian SSR
"Basicity of Phosphazo Compounds. I"
Leningrad, Zhurnal Obshchey Khimii, Vol 1~0, Vo, a;, Auq- '70,
pp 1696-1641
Abstract: m-Triphonyl!)Iio-.~!phazobanzoii%. acid and Its Titathyl ester,
melting at 199-201(' and 126-12"ec, reapectivoily, were s,7-nthesiz(3d
by adding triphenylphosphine to a hot nolution oX tho parent acid
or aster in bonzono and collecting, tho produrt p;vev1.ji-j,tnt1A fro-M
the cooled mixturo. 'Ibo wit.-)
obtained analogotisly with veveraod addition ol
product melted at 21~1-21~30C. To obtain
trifluoromethylaulforiylbenzori4i, hi.p. triphony iphasp.111 lie
was added to the benzene 3olution of
benzene. A solution of p-trifluoramothy'laulfony~lani.l.incj In diluto
hydrochloric acid was diazatizedp and a 001%LtiOn, Of sodiLua azide
112
'USSR
KUKHAR t , V. P. , et al, Zhurnal Obghchey Miimiii, 'Crol 140 t NO 8.
Aug 70, pp 1696-1699
was addod graduallyo yielding p-tr:Lfliioromet,,hylslitlfol,,f'laz.l.ciobolii.-')ne,
m-P. 53-550, Other compounda wore obtained by Wiown mothods.
Their pK values for basic and acidic ionization wore determinod.
It was found that the substituents on the phenyl 3%inl-, ;.,jbo,,r prin-
cipally an inductive effect on the reactive contor of the tri-
phanylphosphazoarenes. Me m-triphanylphosphazo ~.:,-romp is a groater
electron donor than the m-dimethylanino groupp and tile p-triphonyl-
phosphazo group is a slightly loaner electron dowr tbiim the
p-dimethylamino group. In 95% aloohol the z~- and p-triphenyl.
phosphazobenzoio acida exist to a aonsi4ormblo dj%rem as internal
malts.
2/2
USSR
UDC 546-185
SHEVCHEW I V. IL. I LnOvCh&IC.