SCIENTIFIC ABSTRACT DOVLATYAN, V.V. - DRAGAN, YA.P.

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CIA-RDP86-00513R002200710011-7
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December 31, 1967
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SCIENTIFIC ABSTRACT
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USSR UDC: 5L2.91 + 6-32.-1- V. V., and ELI-I'AZYA~;, K. A., A=enian llgricultu~,~LLI InsLi-,ute, Yerevan, fydnistry of Acrricu-Iture USS"'IR I - "Synthesis of Herbicides. Ethyl Esters of Acids" Yerevan, A::-~-,yanskiy KII cheskiy Zhiunal, Vol 23, 11--~o 4, 1970, mp 5-363' Abstract. Reaztion of sodiim 2(4)-hydroxylbenzoates wit-H yielded e-uhyi esters of 0-2(4)-hydrox-jbenzoylglycoli-- acids, w1hi"ch w-el,e "-~~O- genated and methylated to yield ethyl esters of glycolic acids. Among them the ethyl esters of 2-methaxy-3,5-dichloro- and 2- me't,hox-J-3,6-d:~chlorobenzoylglycolic acid exhibited hij~iest herbicidal activity against dicot, edons. Y1 - 60 - 1~ -1/3 015 UNCL ASS IF I i:Z) PROCESSING.- DATE-13NOV70 -TITLE--SY-4THESTS OF PESTICIDI:S. XXV[. SYNTHES!5 OF ALPHA CYAl!Gl-,L,~?L ARYLCAR3.414TES -U- AL)THUk-(02)-DJVLATYA,"J, V.V.s A-'!&ARTSUMYA,`4, YE.N. 1 -UUNTRY OF INFO--USSR SCURCE--A,--,,*4. KHIM. ZH. IWOv ?-3(1)p 49-53 -OATE PUBLISHEDI ------- 70 SUBJECT AREAS-310LOGICAL AND MEDICAL SCIENCES TOPIC TAGS-CHEMICAL SYNTHESIS# CARBAMATE, PESTICIDE, URFA DPmIVATIVE .CCNT'C'%GL MARKING-N3 VESTRicriu,,,is 00CUM"PIT CL,`%SS--fJ%CLA'JSIFfE0 PROXY REEL/FRA?4E--19q9/I893 STEP NO--(JR/0426/70/0?-'i/OOL/00tt9/~,'053 CIRC ACCESSION ;i0--AP01?3b9l . - I- . - It") k;.; " I -'. SI'* I ., -. .2/3 015 UNCLASSIFIED PROCESSING DATE--13NUV70 -CIRC ACCESSION !,43--AP0123681 ~A-5STRACT/EXTPACT-1U) GP-0- ABSTRACT. THE REACTION OF ARYL ISOCYANATES 0HYDRINS OF ALDEHYDES AND KETONES IN THE PRESE, , F PYRI E WITH CYAM NICE Q DIN (1) GIVES ALPHA CYANOALKYL ARYLCARBAMArEs. TO A STIRREJ mix-r. OF 21-38 G PHN'CG AND 1.25 G GLYCOLONiTRILE III)t 0.025 G I WAS 'ADDED TO GIVE 75PERCr'_NT PHNIHCO SUB2 CH SJ32 CN, M. iZ-30EGREES. SliMILARLY PREPO. WERE THE FOLLOYIING (PRGDOCT, PERCENT, YILLDp AND M.P. GIVEN): P-CLC SLJ36 H SUB4 J%HCQ SU:32 CH SLJ34" CN, 90.4, 93-IOOOEGREES (PHI-IE); P;iNrlCU SU112 CH(CNIMEv 99v 77-30fEGIREES (C SIJ63 H SUB18) ; -(;Lr. SU66 ti SU64 NHCO SU32 CHI C?J) 1-1 E t90.5, -Y2-4DEGkEES (C SUB6 H SUB18). A IMIXT. OF 2.38 G PHNCO, 1.9 (; ME S(Jf32 C (UH)CN ( I I I ) , AiNf) 90.025 G I WAS KEPT Al rrCjd;M TEMP. 3-4 DAYS TO GIVE 92PEFC-ENT PliblHCO SU82 C(CN)ME SU82, M. L36-70t-GREES (FKDM PHME) . SI,-'.ILAPLY PAEPO. v1AS 70.6PERCENr P-CLC SU66 H SU134 NHCO SU82 CKWME SUIJZP 1-1. 117-190E(;i~EES. A MIXT. OF 3 G M-CLC 5Uf36 H SUB-i NCO, 1-25 G 11, A:4Z) O.U5 G I 14AS LEFT UVER.NIGHT AT ROON, TEMP., 7-3 '4L C SUB6 H SUB6 WAS AODED, AND THE MIXT. HEATED TO ff0-900FGREES FL]k 3-4 HK TO GIVE 80.9PERCENT M-CLC SU~36 It SU34 NHCG SUB2 CH SU132 Ctli M. 112-13DEGREES. ThirE WORK OF 1. G. KHASKIN AND V. 1. KONDRATENK0 (1966) WAS REPEiiTED; AIND THF PRODuCTS ARE GAAZOLINE A,.IU OX-AZOLIOINE 0;-:kfVS. RATHER rHAN ALPH-: CYAN0Pil"JPYL ESTERS UF CHLUH~LJFOXMIC X40 ilHF14YLCA,BA"-ilC ACIDS. THUSt COCL SUB2 wITH III GAVE ZtCXCt4)CHLCRQf5t5tUl,METHYL,3iO-XAZOLINE (IV), M. 70-20EGREES, WHIrH ON HYDROLYSIS GAVE 2,4,DIOXC,5t5,Dlj'iETHYLOXAZOLIDI14E, M. 75-6DE~;REES. THE REACTION OF IV WITH PHNH SUB2 AFFORDED 2tUXOy4lAi'-IILINC,5J5,DIMETHYLt3rOXAZOLI~iE, M. 262-4DEGRIES. UNCLASS*1FIED 3/3 015 UNCL ASS IF I ED PrOCESSII,lr, DATE-13NOV70 ~C RC ACCESSI'),N NO-AP01236-31 ~ABSTRACTIEXTRACT--HE4TING ARYL ISCCYAuATES WITH CYAN(.`HYDRI-NS IN PHME AT 90DEGREES GIVES-MM-NLY 1qj;A',DIAKYLUKEAS ANO NOT ALPHA GYANUALKYL PHEMYLCARSAlATES AS STATitz-9 BY K. D. SHVFITSOVA=SHIL;)VSKAYA, INI. N. MELINIKOVi Z. 1. MAKSIMOVA, T. S. LAKHAROVA, AND L. P- f3GCH4-,0VA (1962). T14E IR SPECTRA WERE, DISCUSSED. FACILITY: ARM. SCL'SKUKHOZ. INST., EREVAN, USSR. USSR DOVLATYANI V. V.J. 19WHATRYATI, N. Xh., Armyanskiy Khimicheskiy Zhurnal, Vol XXTV, No 2. 1971, PP 3.67-173 (dialkyl) amino-symm-tria2ines are obtained. The experimntal procedures for obtaining the mentioned compounds.. their formulas, yields and -Physical and chemical properties are presented. 2/2 us s1z - UDC 547.495.1+6372.938 11DVLATYAN1- V. V., and MBARTSUIMYAN, E. N., Armenian Agricultural Institute, Yerevan, Ministry of Agriculture USSR "Synthesis of Pesticides. 'C,%VII. The Problem of Dehydrachlorina- tion of ,.~~,-Cyano(carl)ethoxy)-,',;~,,I~-trichloroethyl-rZ---ryL (benzoyl, methyl)carbamates" Yerevan, Armyanskiy Khimicheskiy Zhurnal, Vol 23, -N1o 3, 1.970, pp 295-296 A.bst I tract: The paper is a report on synthesis of (j-cyano(or A- carbethoxy)- 113,1'~-di(.,tilorovinyl-N-substituted carbamates with the general formula RNIICOOC-CCI, X -(-N, COOC,11,, R -C11,, Q1,CO, CIC,11,. -sis was achieved by interacting chloral cyin0hydi-it-, or :;~.hyl Synthe tH clil orol ;~( t:ate widi isocynnates Ln the pres(mice of (A' il*/!;l it- in nhown that of ~'k-cyzlno- witio agent!~ M-y L-If -im i Ito -5-dichlorome Lhylerioxazol idines. 1/2 USSR DOVLATYAN, V. V., et al. , Armynnsidy Khimi(-he.-I,:jy 2-1--urnal, Vol 23, No 3, 1970, pp 295-296 Potasli dcnydrochlorination of -cyano- -tricIiLorOet[-Iy*jI--N,I- methy1carbamate produces - -cyano- carbamate, while sodium C~anide as the dchydroclilorinat3ing agent givew 2-oxo-3-metliyl-4-imino-5-diethLoror;iethylenoxazolidine. Dissolution of 2-oxo-3-aryl(methyl)-4-imino-5-(Iictlorometilylenoxazo- lidine chlorohydrates in water produces the corresponding 2,4-dioxo-3-aryl(methyL)-5,5-dichlorometliylenoxazolidines. 2/2 USSR U DC 3? 12. C i51 o3~ 2, DOViATXN&-)L# V. V. and Z. N. A rmcni -= A gz -fcu rzt Inz; iz JVfr%,`an, Mlinistry of Agriculture USSIR "Pesticide Synthesis. Intral-nolecular CyCIi----zI-.--'O;- 0-17 N-arylcarbanates" Yerevan, Armyanskiy IC-iiinicheskiy Zhurnal, Vol 213, c) Abstrac-1: Heat,-ng-~,-CY4.;-noalkyl-N-arylt'or mc,-,:hylI~c;,rbama-L:os the presence of py3:id--;n,a or red mercury oxide, yie-!(.s tives which form by int:ramolocular cyclization. This reac-L'icn --,:1v G i. alo place Jn sor-ae cases on stand~-ng at roorl temperz,,,ture for 10-20 (,1- all cases whe--e the other solution Ls saturated wizh ciry The position of a substituent on the phenyl ring has -~ sUJ S1 z':-1. Ll "-L on the rate of cyclization. The hydrochlorides of thcso easily in water, yielding sence of an aryl group directly attached to nitrogo-1-1 %-.as I-Ound i~cc!ssai:y -~:Or cyclization, since '/0032/0035 CIRC ACCESSICN NG-AP0129271 UNCLASSIFIED 212 019 UNCLASSIFIED PROCESSING OAT=--30UCT-'O CLRC ACCESSION NO-AP0129271 ABSTRACT/EXTRACT-1U) GP-0- ABSTRACT. THE AUTHORS DETERMINED 31LIRUBIN IN THE BLOOD SERUM AFTER HIMANS VA14 DEN BERG IN 219 PATIENTS WITH CHRONIC LEUKEMIA AND ITS FRACTION, AFTER ESERLEIN IN 91 PATIE'NTS. QUANTITATIVE STUDY OF URINE UROBILIN WAS MADE IN 109 PERSONS AND CAPACITY OF THE LIVER TO EXCRETE ASORUBIN STAIN IN 107 PATIENTS. INCREASE OF FREE AND MUNUGLUCURGINID BILIRUBIN AND CHANGES OF DIGLUCURCNIDBILIRUBIN IN THE BLOOD SERUM WERE FOUND. THESE CHANGES WERE MAINLY ASSOCIATED WITH A DISORDER OF THE CONJUGATING FUNCTION OF THE LIVER DUE TO A REDUCTICIN OF GLUCURONIL, TRANSFERASE ACfIVITY OF MICROSOMES OF HEPATOCYTES. IN THE TERMINAL PERIOD THE BILIRUBIN EXCRETORY FUNCTIGNI OF THE LIVER WAS DISTURBED MOST OF ALL. UROBILINSOkBTIVE FUNCHON OF THE LIVER WAS CONSTANTLY DISTURBED AND EXCRETORY, REMAINED UNCHANGED. FACILITY: KAFEDRA GOSPITAL'NOY TERAPII VIT-EBSKOGO MED]r,TSINSKOGO INSTITUT. UNCLASSIFIED 1/2 013 UNCLASSIFIED PROCESSING DATE--27NOV70 TITLE--ON THE DISSOCIATION CROSS SECTION FOR SLOW COLLIDING EXCITED 1. MOLECULES -U- AUTHOR-(03)-DOZOROVy A.A.j KUDRINv L.P., NOVIKOV, V.M. COUNTRY OF INFO--USSR ..SOURCE--ZHURNAL EKSPER IMIENTAL 'NOY I TEORETICHESKOY FIZIKI, L970, VOL 58, NR 6, PP 1955-1958 DATE PUBLISHED ------- 70 SUBJECT AREAS--PHYSICS TOPIC TAGS--EXCITED ELECTRON STATE, MOLECULAR INTERAcTio,"j, EXCITATION CROSS SECTION CONTROL MARKING--NO RESTRICTIONS DOCUMENT CLASS--UNCLASSIF[tc-0 PROXY REEL/FRAME--2000/2243 STEP NO--UR/005b/1'0/053/006/1955/1~;53 CIRC ACCESSION' NO--AP0125821 F= 212 013 UNCLASSIFIED PROC C S S P1 G 0A T E-- -77, 7 01 ACCESSION N3---AP01251-21 ABSTRACT/EXTRACT-M) GP-()- ABSTRACT. THE CROSS SECTU-',,'4 F~~:, r.Hp- (AB) PLUS M YIELDS A PLUS 13 PLUS M 15 CALCULAUE0; viFRE (ABI il,"Jo m MOILECULES IN THE EXCITED ELECTPON STATE5, THIE C-~rjSS S-;:CTlz)",l CA"4 RE EXPRESSE-0 IiN TERMS nF WELL KiNOWN EFFECTIVF CROSS -*;Ecrft)!*,is ,coR -S " F HE MOLECULES', AT THERMAL ENE,'Gllc I PHOT001 SSOC [AT ION OF I IS L r- U R D;~ OF 10 PRVlE NEGATIVE14 CM PRIMEZ. U`4CLASSIFIE0 'USSR UDC 911.3.616.981.455(470.333) ADAMOVICH, V. L., STRUTINSKIY, V. M., and DOZORTSEVA A. A. "Elimination of Tularemia in the Desna Flood Plain in Relation to tile River Irrigation Project" V sb. Kompleksn. probl. Desny (Complex Problems of the Desna -- collection of works), Tula, 1970, pp 196-202 (from RZh-36. Med�tsinskaya geografiva, No 1, Jan 71, Abstract No 1.36.122 by V. Maslovskaya) Translation: From 1948 to 1963 there were 1,417 recorded cases of tularemia in Bryanskaya Oblast, and morbidity was gradually increasing. The high in- cidence in 1963 can be explained by the abrupt intensificacion of the epi- zootic process in tularemia foci and the absence of appropriate vaccination for the population. After 1963 the morbidity sharply decreased: in 1964 -- 7 cases (in the environs of Bransk) ; in 1965 -- 2; and in 1966 -- 12 cases (in the Desna flood plain). In the Desna flood plain there are two dan- gerous epidemiological areas: from the mouth of the Bolva river to PH'- shino village and front Itadutino to Belaya Berezka village. Tularemia study in Bryanskaya Oblast showed that elementary foci of itifect.ton are associated with the distribution of Ixodes apronophorus ticks and are found in alder 1/2 USSR ADAIDVICR, V. L. , et al, V sb. Kompleksn. probl. Desny (Complex Problems of the Desna - collection of Works), Tula, 1970, pp 196-202 (from RZh-36. Meditsinskaya geografiya, No 1, Jan 71, Abstract No 1.36.122 by V. I-faslov- skaya) groves. Cartographic data shows that tularemia foci in 1963 were associated with areas of land reclamation. These conditions are causing Ixodes ticks and rodents to inhabit the shores of drainage canals. Microfoci emerge, from vhich infection spreads into the flood plain with subsequent increased incidence of tularemia in the population. The morbidity probability has Increased for tularemia, hemorrhagic fever with a renal syndrome, Q fever, and other diseases. 2/2 1/2 020 UNCLASSIFIED PROCESSING DATE-30OCT70 TITLE-CHROMOSOME MUTATIONS INDUCED BY SPACE FLIGHT FACTORS IN BARLEY SEEDS DURING THE FLIGHT OF THE AUTOMATIC STATIONS ZOND-5 AND ZOND-6 AUTHOR-(05)-NUZHOIN, N.I., DOZOXTSEVAt R.L.r PASTUSHENKUSTRELETS, N.A., -SAMCKHVALOVA, N.S., CHUDIWMKAYA,, G.A. T-4 CGUNTRY OF INFO-USSR i ') woli SOURCE-ZH. ABSHCH. BIOL* 1970, 31(11, 72-83 DATE PUBLISHED----70 SUBJECT AREAS-BIOLOGICAL AND MEDICAL SCIENCES TOPIC TAGS-RADIATION INDUCED MUTATIONt AGRICULTURE CROP SEED/(U)ZONO 5 CIRCUMLUNAR PROBEt (UILOND 6 CIRCUMLUNAR PROBE UNTROL MARKING--NO RESTRICTIONS DOCUMENT CLASS-UNCLASSIFIED PROXY REEL/FRAME--1999/1962 STEP NO--UR/03ZI/70/031/001/0072/008-a CIRC ACCESSICN NO-AP0123743 i it"f- i A ,z 1-1 r F i r. a 2/2 020 UNCLASSIFIED PROCESSING DATE--30OCT70 CIRC ACCESSIGN NO--AP0123743 ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. SEEDS OF 2 VARIETIES OF BARLEY (RADICRESISTANT, AND RADIOSENSITIVE), IRRADIATED WITH 5 OR 10 KR AND PRIME137 CS GAYMA RAYSt OR NONIRRADIATED, DURING THEIR DORMANT AND RESTING STATE, WERE PLACED IN THE ZOND-5 AND ZOND-6 SPACESHIPSy WHICH FLEW AROUND ThE MOON. AFTER THE FLIGHT, THEY WERE THOROUGHLY ANALYZED. THE CYTOL. STUUIES SHOWED SIGNIFICANT DIFFERENCES BETWEEN THE EXPTL. AND CONTROL SERIES IN THE AMTS. OF ABERRANT CELLS DUE TO CHROMOSOMAL MUTATIONS CAUSED BY THE SPACE FLIGHT FACTOR (SFFI, SFF CAUSED CRRCMCSOMAL MUTATIONS IN THE SEEDS. THE GENETIC EFFECT OF THE COMBINED INFLUENCE OF SSF AND GAMMA IRRADN. DEPENDED ON THE PHYSIOL. STATE OF THE IRRADIATED SEEDS, AND ON THE DOSES OF IRRADN. DORMANT SEEDS WITH A HIGH RADIGRESISTANCEt AFTER IRRADNo WITH LOW GAMMA RAYS DUSESP WERE MORE AFFECTED BY THE COMBINED INFLUENCE OF SFF.AND GAMMA IRRADN. SEEDS IN THE RESTING STATE WITH HIGH RADIOSENSITIVITY SHOWED A SHARP INCREASE OF THE EFFECT OF SFF. THE ADUITIVE AND SENSITIZING EFFECTS OF GAMMA IRRADN. AND SFF WERE OBSO. IN THE SEEDS FROM THE SPACE SHIPS. FACILITY: lNST. BIOL. PHYS.9 MOSCOWP USSR. !;,:F i A t: i: TFl USSR UDC 632-95 TRUYdILIK, S., K9VACH, I., and GAGER, S. "Metathion -- New Low-Toxicity Organopliosphorus Insecticide" V sb. Khimi,,m i prineneniya fosforarran. sovedin. (Chemistry and Application of Organophosphorus Compounds -- Collection of Works), Moscow, "Nauka," 1972, Pp 477-483 (from RZh-Kiiniya, No 14, 25 Jul 72, Abstract No 14N440 by T. A. BELYAYEVA) Translation: 'rhe article presents physical and chemical properties and '11-.ethods of producinU. metathion (I), data on the hydrolysis of I in varioia; inedia, and toxicity of the preparation for warm-blooded animals. Compound i con- su=tion norms for various crops are indicated. Compound I can be used in fruit and vegetable growing and in vttictilture to control the of orna.- mental plants and a6ricultural. crops. 1/1 )J9 USSR UDC 621.396.674.3 PRA#KIN,_ A.- D. "Elementary Radiators in a Conducting Medium" Moscow, Radiotekhnika i elektronika, Vol XVII, ho 2, 1972, pp 264-267 Abstract: A study was made of the problera of transmitting electromagnetic energy by elementary radiators -- electric and magnetic -- in a semiconducting medium. Simple formulas were obtained for the active resistance of such radi- ators. Near the dipoles, on going away from the radiation sources, the power leaving the electric dipole decreases appreciably faster than In the case of the magnetic dipole. The conducting medium around the loop antenna has a significant effect on the active component of its input impedance. This ef- fect on the reactive component of the input impedance is appreciably less and it can be approximately determincd by means of the known expressions for the meditua without losses. The method of induced emf's and the concept of a complex dielectric constant of the medium was used to obtain the expression for the power supplied to the insulated loop (without considering losses in the loop conductor). USSR DROKIN, A. L. and STETSDIFE.0, V. A. UDC 621-371 "Electromagnetic Energy Distribution of the Simplest Ra(liators in a Semiconducting I-ledium" Y-oscoi-.,, V sb. X Vses. konf. no rasprostr. radjovoln. Tezisv doir-1. Sehts. 6 (Tenth All-Union Conference on the -'Propagation of Radio Waves; Report Theses; Section- 6--collection of "Nauka," 1972 PP 45-49 (frora M-11 Lad io tek-hnika, 1.1o 10, 1972, Abstract 1,'o 101.389) Translation: The change in energy of an elect-roiaaCnetic -,.a%,e c'].ose to the radiator (a short electrical vibrator or frame) disp-aced in a uniform limitless semiconducting medium (S' is investir~atcd. 11 Two possibilities are considered: 1) the radiator is placed lirect ly in the 2) the radiator is surrounded by a dielect.-ic Sphe~frc T beyond -the limits of which is a uniform isotropic It is shown thmat, for frame radiators, the power a to nttenuates the ~-iotanlce at a lower rat L 11 -e than 4"or eloctrical vibntorn; the pre-ence of the dielectric shell a-Iffucto them to a lenser cxtwit. Tl;o il-iU."tra- tions, biblio-raphy off one. 21. S. 56 - 1/2 010 UNCLASSIFIED PROCESSING DATE--L8SEP70 ,TITLE--WORK QUALITY AND BONUSES -U- AUTHOR-DRABKINt G.M. COUNTRY OF INFO--USSR SOURCE-STANDARTY I KACHESTVO, 19701 NR 21 PP 7L-74 DATE PUBLISHEP -------- 70 ,SUBJECT AREAS--BEHAVIORAL AND SOCIAL TOPIC TAGS--BONUS, QUALITY CONTROL, SCIENCES INDUSTRIAL MANAGEMENT CONITROL MARKING--r-40 RESTRICTIONS DOCUME14T CLASS--UNCLASSIFIED PROXY REEL/FRAME--1964/2025 STEP NO--UR/0422/'10/000/002/0071/0014 CIRC ACCESSION NO--AP0100590 UNCLASSIFIED 2/2 OLO UNCLASSIFIED CIRC ACCESSION NO--ArOI00590 NBSTRACT/EXTRACT--(U) GP-0- A3STRACT. THE AN ENTERPRISE IN IMPROVING THE QUALITY OF SOURCES ARE RECOMMENDED FOR THE BONUSES TO HIGH QUALIY OF THE ITEMS PRODUCED, BUT ALSO THE EMPLOYEESo UNCLASSIFIED PROCESSING DATE-13SEP70 ARTICLE DESCRIBES THE WORK OF THEIR PRODUCTS. CERTAIN BE AWARDED NOT ONLY FOR THE FOR THE HIGH QUALITY WORK OF 89 USS.111 uDc: 621.315-592 'nPA'ZV-iN T L . and I.El,'SON, I - V- , Semiconductor Institute, Acad. Sci-US-511 Leningrad "Infrared Absorption by p-Type Pb I-x SnxTe Alloys" leningrad, Fizil-a i tekhnika poluprovodni-Icov, vol 6, 11o 6, 1972, pp 1046-1049 Abstract: The results of experimental investiC-otions into the i-n- frared absorption characteristics of n-type and p-typ_e Pbl--,Sn,.Te solid solutions, where x = 0.02, 0.05, 0.1, and 0.2, are ~-Lven. in this paper. Specimens for the experiments were prepared fron, al- loys of the original components i;i evacuated ampoid-es, the coml,o- nents being heated by pressing and consequent homoCenization by annealing. X-ray and metallographic analysis used to verify that the snecimen was single-phased. The absorption measurements were made -vith the IKS-21 infrared spectrometer, the tem_per,-_,,t-U_re tests of the sDectra being made in a special vessel to pernit di- rect measurem-ent c~' `he c~bsorDtion in a micro-att-.aclu-,ent, tly~e PMO-21.1, in the 110-3000 K int;rval. The authors 'Lind that zhr-ir 4 results agree closely with V-he data obtained by other researchers. 1 112 024 UNCLASSIFIED PROCESSING DATE--IHSEP70 TITLE--INCREASE IN THE PHOTOELECTRIC SENSITIVITY OF POLYMERS WITH A CONJUGATION SYSTEM. 1. PHOTOSENSITIVITY OF A POLYMERLOW MOLECULAR AUTHOR-(05)-DRABKINt F.A.i.TSARYUKp V.I., CHERKASHIN, M.I., CHAUSER, 4.G., KISILITSA, COUNTRY OF INFO--USSR :SOURCE--ELEKTRDKH[MIYA 197o, 6(l), 65-9 DATE PUBLISHED ------- 70 SUBJECT AREAS--CHE-41STRY, PHYSICS TOPIC TAGS-CONJUGATED POLYMER, MOLECULAR WEIGHT, PLASTIC FILM, PHOTOSENSITIVITY, BENZENE DERIVATIVE, ACerYLENE, IODINATED ORGANIC C nim Powi o tCHLORINATED ORGANIC compnUNDo ORGANIC AjfNE COMPOUND, PROTON 'I~PKIN~--lln, RESTRICTIONS DOCUMENT CLASS--UINCLASSIFIF0 PROXY REEL/FRAME--1984/1814 STEP NO--t]R/0364/70/0,')(j/001/,JO65/')069 CIRC ACCESSInN NO--AP0100188 IjV' jCLASSIFIE-D CiTJ I SS V I )viln 'AIIH911S S?9WAlOd 9HI 40 'ONOD N18VO 3HI SgSV3W3Nl OSIV S-dOld3D3V 3141 90 *NGOV 3HI *3DV383INT W3hAlOd )jOld3DDV 3HI AD 3dAl 3H1 Sl VW91S 9Nlc,)NVH0 NI ~WIDVJ INVIbOdW] ISDW 3H1 *bOld93)V 3HI =10 SS3NNDI)ql 'd3AVI G9SV3dDNl HIlM ION Ing 'SS3NNDIHI WlJJ 89WAIDd 3HJL HIIM VW91-S AD 3SV3~-13NI NV Sl Bb3HI 'S3WlI S3WJ'dd0loiivm,3'H0NVHISS31 Sd3WAlCd BHI :40 ( VW9 I S ) 'ONO:) 01014d 3H I USV3EMI (AN I 7VA10d ~10 ' (9N3IN-3d0-l3,k:)0bO-lui:) 1),kl0d '(3NAl0VlA9lAN3Hdl0)Al9d '(3N31AI.~3VIAN3HdOGOI V13U)AIDd 4(3N9lAl33VlAN3.HdlA10d) si~3wA-llGd ogivonrNOO 01 (30lbOAHNV DIIVHIHd \,qO 'EOM IDIV '9N~1714300NVADV~!i3l '9N31AH130NVA0Vbi3i I NVHJ DW 1400NInbONVADV~1131 IIINV801140 l-llNvW0b9) S*bOie3:):)V N01011d 'IM- '10W P101 AD 'N0JUV -lHI *IDVelSflV -0-dO (n)--iov~iix:-uiov~usov VU~0010dV--CN NOISS333V :)dl-, 0Ld3S9l--9IV0 DNISSADO'~d 031=1]S'JVI)Nn ~zo 212 USSR UDC: 621-315-592 VINOGRADOVA, M. N., DRkBKIN, I. A., YELISEYEVA, Yu. Ya., and NELISON, I. V. "Optical Characteristics of p-Type Pbj_x1,-1nxT-- Solid Solutions" Leningrad, Fizika i tekhnika poluDrovodnikov, No 8, 1972, pp, 1478- 1482 Abstract: The work described by this paper is the investigation of �nfrared reflection and absorption spectra in solid solutions of Pbl-xl,lnxTe, with the purpose of explaining the energy structure of these alloys. The reflection spectra were measured with specimens having various carrier concentrations and with an Kn concentration of up to 95-' at 3000 K, and such spectra are plotted for alloys in which x =- 0.03, 0.06, 0.09 with identical Hall concentrations. The absorption spectra were obtained for polycrystalline specimens of Pbo.95Mno Te and Pb lin jTe and are reproduced as well. It is founcL thal'Zhe introduo~?ion' of Yin into Pbj-xMnxTe alloys leads to a change in the respective positions of light and heavy hole zones, and that the structure of the alloyol valent zones differs substantially from those of FbTe. 1/1 USSR TJD(: 621-315-592 DRABKIN, I. A., MCRGOVSKIY, L. Ya., NELISON, 1. V., and RAVICH, 1U-._'T_._ ;~e_miconductor Institute, Leningrad "Characteristic Light Absorption in Nonparabolic Regions of PbTe and Solid PbTe-SnTe Solutions" Leningrad, Fizika i tekhnika Doluprovodnikov., No 7, 1972, pp 1323-1326 Abstract: A comparison is made between the experimental data for the absorption coefficient of PbTe and compounds of similar zoiial structure on the one hand, and the theoretical expressions derived on the basis of the two-zone model on the other. ComDutation of the characteristic abBorption coefficient is ninde in the frame- work of the two-zone model by computing the matrix elements of the dipole junctions through the use of wave functions found by the R-F Eiethod. Such calculations show that ~he absorption coefficient in the nonparabolic zone increases because of the faster growth of the density of the compounds as a function of the energy. Experi- ments to determine the absorption of epitaxial films of PbTe, Pbo.qSno.lTe and Pbo.83no.2% are described. The results of these 1/2 U19SR DRABXIN, I. A., et al, Fizika i tek-hni'Ka mluprovodnikov. Lio 7, 1972, pp 1323-1326 experiments are given in the form of curves showing the absorption coefficient and the coefficient squared as functions of the light energy. For the sake of comparison, the theoretical and experi- mental results are plotted on the same axes. 2/2 TJSSR 1JDC: 620.179-152.5 GRUZIN, P.L., DRABKINI, L.A. and KOSAREV, L.I. "Scattering of X -Radiation by Cs137 Steel Cylindrical Barrier" Sb. Radioizotop. sredstva Kontrolya i automatiz. teklinol. protsessov v prom-sti (Symposium on Radioisotope as Means of Control and Automation of Manufacturing Processes in Industry) Moscow, Aton-lizdat Publishing House, 1972, pp 523-527 (from Referativnyy Zhurnal- Metrologiya i IzmeritEl'naya Tekhnika, No 8, 1972, Abstract No S. 32. 255) Translation: Angular spectrum of once scattered radiation is obtained for the case of narrow beam of X -ray falling on Cs137 steel cylindrical barriers of various thickness and curvature. It is shown that data on scattering of K -quanturns in parallel plane barriers with scattering angle of 300 can be used in this case with sufficient accuracy. The effect of cylindrical barrier thickness on the scattered rZdiation flux was investigated. The obtained relations have maxirnums. With the wall thickness greater than the one corresponding to the rna%imurn flux the relation between flux and thickness is linear (3 illustrations, I reference). Vi 117 USSR UDO 621.~97 SOLOVEYCHIK, I.YE., DRAEK14., YARNIMIN, K.K., IMSSKAYA, G.V., __ _J.1. P SHARGORODSKAYA, F.M., KOHNITEMO, G.G., 75EDIK, A.S. lElectronic Device For Information Display" BlektroavyazI, No 1, Jan 1972, pp .59-6~ Abstract: The paper describes an information display device of the desk typo, intended for operation with an electronic computer through a telegraph communi- cation channel. A block. diagram of the device and the basic parameters of the unit are presented. The authors report that a now information display device was developed on the basis of the unit described, but few details are given. (An-exterior view of the device is shown on the journal cover.) In the new de- vice it is possible to n5produce 512 symbols (16 lines, 52 symbols to the line) of an ELT23LKgB screen. The set of reproducible symbols includes the Russian alphabet, figures, and special symbols--altogether 64 symbols. With an indi- vidual keyboard which has 47 figure-letter keys and 21 functional, it is possible to feed information into an electronic com mter and to accomolich complete editing of the text with the aid of an electronic carriage (=rkor). The device contains a special exchange unit which makes it poseible to operate with an electronic computer in GOST 10859-64 code and in code 14TV.-2. In addition, this unit provides coupling with the OMinsk-32" computer for the slow channel. 5 fig. I tab. 1/1 USSR UDC 547-397+595.7 DJATIVT~"-&-, YEFIMDVA, 0. V., TSIZIN, Yu. S., GAIMER, N. M., and PRIDANTSEVA, Ye. A., I-nstitute of Chemical Parasitology and Tropical Medicine imeni Ye. I. Martsinovskiy; All-Union Institute of Plant Protection "Compounds Which Simulate the Effect of the Juvenile Insect Hormone. III. Synthesis of 3,11-Dimet:hyl-11-chlorodecen-2-oic Acid Ethyl Ester" Leningrad, Zhurnal Obsbehey Khimii, Vol 42(103, No 2, Feb 72, pp 1457-1459 Abstract: 3-11-Dimethyl-11-chlorododecen-2-oic acid ethyl ester (11) was synthesized for biological tests. Compound (II) shows the groups typical of the active analogs of insect Juvenile hormone of (1). 1/3 - 53 - USSR DRABKINA, A. A., et al., Zhurnal Obshchey Khimii, Vol 42(103), No 2, Feb 72, pp 457-459 COOCK, n'COOC CN COOCLH5 IX IV Ch '~~CN NO) 1 0 V V1 VII COOC'Hs CDOCat,5 CL Vill 11 2/3 USSR DRABKINA, A. A., et al., Zhurnal Obshchey Khimii, Vol 42(103), No 2, Feb 72 pp 457-459 The synthesis is based on methylB-cyanooctanoate (III). It was assumed at first that ester (III) could be converted to hydroxy ketone (IV) with excess metbylmagnesium iodide. However, even a reagent ratio of 1:10 failed to give the desired result. Careful selection of reaction conditions showed that ester (III) reacts with three moles of methylmagnesium iodide to form hydroxy nitrile (V) which is converted to unsaturated nitrile (W) after dehydration without filtering. Reaction of (VI) with four moles of methylmagnesium iodide yields ketone (VII) which is converted to the diene ester (VIII) by the Whittig reaction. Compound (II) is obtained by bubbling hydrogen chloride through an alcohol soluzion of diene ester (VIII). Tests on mosquito larvae showed that (II) is as active physiologically as compound (IX), which is called "synthetic Juvenile hormone." 3/3 - 54 Entomology D USSR UDC 591.147:r95.7 isim", Yu. S., -RA- A. A., Institute of the Chemistry of Natural Compounds, 'oscow. Aca emy of Sciences M d "Juvenile Hormone of Insects and Its Analogs" Moscow, Uspekhi Khimii, Vol 19, No 6, 1970, PP 1074-11Z9 Abstract: The survey covers the chemistry of the juvenile hormone of insects and its analogs. Literature data are cited on the isolation. structure determination, and synthesis of the juvenile hormone and natural compounds mimicking its action. Synthetic compounds showing hormonal activity are described and the relationship between their structure and physiological activity is discussed. USSR UDC 547.963.3 DRABKINA, L. Ye. and ADSEVITISM, M. I., Physico-Technical Institute imeni of Sciences USSR, Leningrad 'Influence of Metabolic Toxins on the Formation of the Helical Ring Form of Lambda Phage DNA" Moscow, Molekulyarnaya Biologiya, Vol 4, No 4, Jul/Aug 70. PP 590-597 Abstract: A study was made of the effect of metabolic toxIns on the formation of the helical ring form of DNA (obtained from a lambda phage) under conditions of superinfection. It was determined that chlorazophanicol (100/ig/ml), as well as act1nomycin 0 and proflavin (in doses up to 5 #g1ml), did not have any real effect on the formation of helical molsoulias of lambda-DNA. However, in much larger doses (up to 10-15 PS/ml), both actinomycin D and proflavin almost com- pletely inhibited formation of helical lambda-ONA. 1/1 - 13 ctroscopy USSR AKHMANOV, S. A., BOLISHOV, M. A., DRABOVICH, K. it., SUKHORUKOV, A, P., Physics Faculty of MoscmT State Universj,~Lv ~Trjen~j- . V. Lo-monosov "Suppression of Induced Raman Scattering in Dispersive Media With a Nonlinear Refractive index" Moscow, Pis1ma v Zhurnal Eksperimental'noy i Teoreticheskoy Fiziki, No. 11, 5 Dec 70, pp 5117-551 Abstract: A theoretical and experimental study of indliced Raman scattering of in- tense picosecond and nanosecond light pulses in self-focusing lio-oids is presente-~~. The anomalous broadening of the pulse spectra caused bv the nonlinearitv of: the refractive index is accompanied by a considerable decrease in the intensav of the induced Raman scattering and,in many cases.,to its complete suppression. It -was established that this effect is caused by the simultaneous action of fast phase modulation of the pumping ariosing due to tionlinearity of th,--- medium and ,r- di_,-q,,,,- sion of the medium. A generalizaticn of the nonstatlon_:Iry theory of induced Raman scattering yielded quantitative relationships for this niode which had not been 1/2 USSR AKHMANOV, S. A., et al, Pisma v Zhurnal eksperimental'noy i teoreticheskoy fiziki, No. 11, 5 Dec 70, nT) 547-551 investigated previously. The experiments on induced Raman scattering in sel-IF-focus- ing media were made with the second harmonic of a necdvrnium laser -'-'n single-mode and synchronlzatlon mode ODeration. Anomalous broadening of the spectrum reaching 1000 cm I in nanosecond pulses and more than 1000 cm-1 in picosecond pulses were observed in carbon bisul-fide in a collimated beam. it is shown that the broadening of the spectrum of picosecond pulses in these experiment-s was directly associated with phase self-modulation of the pulse in a nonlinear medium. 2/2 92 112 046 UNCLASSIFIED PROCESSING DATE--230CT70 TITLE--THEORY OF GENERATION OF GIANT PULSES OF SrOKES RADIATION DURING .:STIMULATED COMBINATION SCATTERING -U- AUTHOR--DRABOVICH9 KoN* COUNTRY OF INFO--USSR SOURCE--ZHURNAL PRIKLADNOI SPEKTROSKOPlIt VOLo 12, MAR. 1970, P. 411-418 DATE PUBLISHED ------- 70 SUBJECT AREAS--PHYSICS TOPIC TAGS-LASER PUMPINGt LASER PULSE, PULSE SHAPE, COMBINATION SCATTERING, IR EMISSION CONTROL MARKING--NO RESTRICTIONS DOCUMENT CLASS--UNCLASSIFIED PROXY REEL/FRAME--1989/1026 STEP NO--UR/0368/70/012/000/0411/0418 CIRC ACCESSION t'40--AP0107540 UNCLASS I F IED 2/2 046 UNCLASSIFIED PROCESSING DATE--230CT70 CIRC ACCESSION NO--AP0107540 ABSTRACTIEXTRACT--(U) GP-0- ABSTRACT, ANALYSIS OF THE PROCESS OF GENERATION OF GIANT STOKES PULSES DURING STIMULATED COMBINATION SCATTERING ON THE BASIS OF THE EQUATIONS FOR THE DENSITY MATRIX AND SLOWLY VARYING FIELD AMPLITUDES. PARTICULAR ATTENTION IS DEVOTED TO PULSES TRAVELING COUNTER TO THE PUMPING WAVE. THE CHARACTERIsric SPATIAL SCALES OF THE FORMATION OF STOKES PULSES ARE DETERMINED FROM THE SOLUTION TO THE VELOCITY EQUATIONS. IT IS SHOWN THAT AT-FAIRLY LARGE WAVELENGTHS A STOKES PULSE ACQUIRES A STEADY SHAPE, AND ITS PARAMETERS (DURATION, POWER-, AND ENERGY) ATTAIN LIMITING VALUES. FROM THE RESPECTIVE FORMULAS IT FOLLOWS THAT THE PULSE DURATION IN THE PRESENCE. OF LARGE AMPLIFICATIONS MAY BE CONSIDERABLY LESS THAN THE TRANSVERSE RELAXATION TIMEo IT 15 ALSO SHOWN THATt GIVEN A HIGH PUMPING RADIATION POWER AND A LOW SCATTERING PARTICLE DENSITY, AN INVERSE STOKES PULSE BSCOMES A PI PULSE. THE POSSIBILITY OF THEN OBSERVING TWO PHOTON ANtl STOKES STIMULATED COMBINATION SCATTERING AND STIMULATED INFRARED RADIATION IS INDICATED. UNCLASSIFIED mm USSR UDC 621.375.82 AMIMOV, S. A., DRkBOVICH, K. N., SUKFORLIKOV, A. P., SHCHEDNOVA, A. K. "Combined Effects of Molecular Relaxation and Dispersion of the Medium in the Case of Induced Scattering of Supershort Light Pulses" V sb. Nelineyn. protsessy v optike. (Nonlinear Processes in Optics--collection of works), Vyp. 2, Novosibirsk, 1972, pp 3-16 (from lah-Fizika, No 12, Dec 72, Abstract No 12D865) Translation: A theoretical analysis was made of the effect of the local non- stationarity and dispersion of a medium on the development of the pulse of the first Stokes component of induced Raman emission excited by picosecond pulses of laser radiation as a function of the relation between their dura- tion and the longitudinal and transverse relaxation times of the medium. It is demonstrated that under conditions of group synchrony the pulse build- up coefficient of the first Stakes component can be reduced by comparison with the stationary value; in the case of strong nonstationarity, broadening of the spectrum is possible, and the ohase modulation of the pu-.lping radiation has no effect on the amplification. In media with anomalous dispersion in the case of inverse induced Raman emission the amplification saturation always takes place on a quasistationary length. The phase modulation of the pumping radiaLlon in Lho dispersing medium can have a significant effect on the ,1/2 USSR AKHMMOV, S. A ., et al., Neline%rn. protsessy v optike. (Nonlinear Processes in Optics--collection of works), Vyp. 2, Novosibirsk, 1972, pp 3-16 amplification of the first Stokes component. In the absence of group synchrony and in the presence of inverse induced Raiiiian emission, the formation of gigantic first Stokes component pulses is possible with a power exceeding its pumping power and a duration T. = 2T2/VO6-1 - 1, where T2 is the transverse relaxation time, Vo'is the stationary ampli- fication coefficient, 6 is the linear loss coefficient. The shift of the level populations in the medium was analyzed. Prospective problems were indicated for further study: in particular, consideraLlon of non- uniform broadening of the levels, analysis of resonance induced Raman emission in equilibrium and excited media, and so on. The bibliography has 34 entries. 2/2 USSR T A., D-Z1jnC)I.ITCJI"K. 11. 5UkaIORUr,9-15 A. and .1377C~ Moscow State Uni-j7r-sity imeni M. V. Lomonosov "Cof,,:bined Effects of Molecular Rela~ation and Disp----rsion o.f ?,.ed-iLun in Incluced Pamn Emission of 111trashort Light Pulses" Moscow, Lhurnal E11--sperim-entallnoy i Teoretiche!-,Iroy Fiziki, Vol 62, Eo 2, -Teb 72., PP 525-540 Abstract: The article d1--vcloT)s a consistent nonotationar-, theory for im-laced R-Yrym emisslan (IPE) which s:bnultaneously conside-rs t"Ne offect Of rcla>mtion and dispemion of the Broad -viti; respect to pua!ipin~, (a witho-ut pl-,ase mud.ilation, Continuous experiencirj;, rapia. rodulation). Dil"ferent rc:1-ationf; t~.c velocities of intcractfn;, waves arc! considered UIr- of nomal -an-,-' i,e- S,alt Of the is tI-.--- fact that, unric co-`~L-L of molecular vibx-atilonr, and dim)--trsion of the -LiVe-ly qualita 3 arif;e. The most impoitant of of a mode! of erp~~-nerit- -jal. rv!;plificatioa of Stoke-- radiation ty JP USSR AKD:ANDV. S. A., et a!.:, TI-Itrnal Eksperimental'no.,i, i Teore-ticheskoy Fiz-1-1; Vol 62, IR) 2, Feb "721 pl-'* '5~-15-540 - '~43 4 T at z < L acco=anied by stabili,-Ltion of Pulses with a duL-at.ior of 1 2 Y'. - the Stokes --ulse shai)e arv! width. Another imnortcnt effect is. t-ne sum,)ression of IIIS as a of ra-~)id -phase nodulation (at v- 0 ph--se modul-a-tion. has practical],y no or, Storkes ar.,Tplification). 71here, is' cormetition between the effect of st!~'Uionar'V modo fommattion and IME su-.)pression. Oaie to Phase modulatuicn. shov that these effects play an -111.1-porLctnt rolf, in the 11RE of --4cost-cond in liuaid's and crystals. and in self -foci,~sod beams. Tliay i-.a- Iso v y a ' pp~--ar in other types. oll" stimulflte,i 3~zatterin:- Tne theoyy (~~eveloncd ci-m be used to ar-al-yze c1haracteristics of Stok,es and in nonstatio-nar~y scatterir,:- An quejClion J-1- non~:tationar-.- nca-tterin--_-, by poLaritons. 'Eie use of tho; calcl-,Iatior! rr;ethod c~na'~)Iu~d A. G. GOU.;Eli to establi'~'h t".'ut the line. wi.~-'.th of infi-ared vibr~-,tions under nonstaattionary conditiors la!,.- tn,--, ard#~,r of line vidILh, rp-~;arc';.less of the of thr,- 212 USSR UDC 547.78 + 547.241 DRACH._B. S., and SVIRIDOV, E. P., Institute of Organic Chemistry, Academy of Sciences, Ukrainian SSR "Reaction of Diethylamine With the Diethyl Ester of 1-Benzamido-2,2-dichlo- rovinylphosphonic Acid" Leningrad, Zhurnal Obshchey Khimii, Vol 43 (105), No 7, Jul 73, pp 1648-1649 Abstract: Heating triethyl phosphite with N-1,2,2,3-tetrachloroethyl- benzamide yields the normal Arbuzov rearrangement product which in the presence of triethylamine is convereted to the diethyl ester of 1-benz- amido-2,2-dichlorovinylphosphonic acids. The latter reacts easily with primary and secondarv amines; so that in case of dimethylamine, for example, a good yield of 2-phenyl-4-diethoxyphosphonyl-5-dimethylaminooxazole is obtained. 1/1 LES R LLDC 547-288 + 547.495 DRACH, B,,.,a,, and SVIRIDOV, E. P., Institute of Organic Chemisti- b-k3:;35R v y , Academy "Reaction of the Condensation Product of Broz&l and hathylurethane ~dth Phosphorus Pentachloride" laningrad, Zhurnal Organicheskoy Xhimil, Vol 9, No 5, May 73, PP 1074-1075 Abstracti The condensation product of bromal with mathylurethano -- the methyl ester of N-1-kydxoxy-2,2,2-tribrowthylearbamic acid (1) reacts easily with phosphorus pentachloride yielding with the 1:1 ratio of the reagents the methyl ester of N-1-chloro-2,202-tribromeethylcaxbanic acid (!I). With a liZ ratiot ths product is 1-chlox-o-2,212-trila-omethylisocyanate (III). Treatment of (II) with triethyl&nine yields N-carbomethoxybromalimine (IV). Both (111) and (IV) react exothermally with methanol yielding the same product - U-1-methoV-2,2,2-tribromethylcarbamic acid. 1/1 - 53 USSR SIBINAj A. D. j and DRACH. B. S. UDC 547.288 "Interaction of H-dialkoxy Phosphonyl Chloroalimines with Trialkyl Phsophites" loningrad, Zhurnal Obshchay Khimiig Vol XLIII (CV)O No 1, 9173, pp 211-212 Abstracti The N-dialkoxy phosphonyl chloralimines react easily irith trialkyl phosphites and give with high yields tatraalkyl eaters of H- -dichloro- vinylimido diphosphoric acid (11 11). CC13C11~NP(O)(OR),,,+(R'O).jP --> RCI+CCI.,=CII.NfP(O)(Oll'):,.]['(0)(011)1, (1) R=R'=C,1(..; (11) 1t=Cj1,, R'=C~11, If-benzoyl chloralimine interacts with trimethyl phosphite differentlys phosphorylation proceeds not with respect to the nitrogen atom but with res- pect to the carbon atoja fK. Burgarv et al. p Angew, Chem., No 84, 258 197_2 7. An experimental procedure is presonted for obtaining comppund (1) with a yield of 82% and compound (II) with a yield of 88%. Compound (II) uas obtained by two procedures - under the effect of the tripropyl phosphite on the H-cUethoxy phosphonyl chloralimine and also under the effect of triethyl phosphite on H-dipropoxy pho-sphonyl chlorallaine. 3 2 USSR UDC 547-241 DRACH,-,B,. S., SVIRIDOV, E. P., and 1,~OV, A. V., Institute of Organic Chemistry., _Wad~qr_ of Sciences, Ukraine SSR "Reaction of the N-chloromethylamides of Acids With Triphenylphosphines" Leningrad, Zhurnal Obshchey Khirqii, Vol 42(104), vyp 4, 1972, PP 953-954 Abstract: N-chloromethylamides reacts with triphenylphosphines according to the following reactiom R = CF,. Cc]-. qu.. If the phosphonium salt from the above reaction is treated with triethylamine in a dioxane solution, the hydrochloride but not the phosphinomethylene is formed. If the phosphonium salt has no H on the N, i.e., a tertiary N, the following reaction occurs: co I-C tI'\& ()/ cd V The bromine salt reacts in an analogous manner. i/2 016 UNCL ASS IF I ED PROCESSING ZDATE-27NOV70 TITLE-CORRELATION BETWEEN THE STRUCTURE AND THE ACT[VfTY OF NtACYLCHLORALIMINES -U- AUTHOR-(03)-DRACHi 3.5.f SINITSAt A.D.# KIRSANOV, A.V. COUNTRY OF l,',IFO--USSR SO.URCE--ZH* 03SHCH. KHIM, 1970t 40(4)t 934-5 0ATE PUBLISHED ------- 70 SUBJECT AREAS--CHEMISTRY TOPIC TAGS--MOLECULAR STRUCTUREt ACYL RADICAL, CHLORINATED ORGANIC COMPOUND, IMINE, MERCAPTANt ORGANIC PHOSPHORUS CW-11POUNQ9 CHEMICAL -REACTION CONTROL MARKING--NO RESTRICTIONS DOCUMENT CLASS--UNCLASSIFIED PROXY REEL/FRAME--3006/1515 STEP NO--UR/0079/70/040/00ti/0934/0935 CIRC ACCESSION NO--AP0135176 UNCLASSIFIED Z/2 016 UNCLASSIFIED PROCESSING DATE--27NOV70 CIRC ACCESSIOt4 NIO--AP0135176 'ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT- ETSH REACTS WITH CCL SUR3 Cli:NA IN 0IOXANE IN A 2NO ORDER REACTION THAT MAY BE FOLLOWED IODOMETRICALLY; THE FOLLOWING RATE CONSTS. AT 20DEGREES WERE DETD. (K IN L,-MOLE HR) FOR INDICATED A GROUPS: PHCH SUB2 CO, 1226; ETCO, 77; ETO SUB2 C, 14.6; AND (E-TO) SUB2 POt 4.7. THE REACTION RATE DECLINES WITH REDN. OF ELECTRONEGATIVITY OF THE ACYL GROUP* IF THE REACTION SOLN. IS LEFT I DAYP EVAPN. GAVE CCL SUB3 CH(SET)NHR:PHCH SUB2 CO, M. 137-BDEGREES; ~~-'ETCOI M. 103-4DEGREES; AND.ETO SUB2 Cv M. 78-9DEGREES. FACILITY: INST. ORG. KHIM-, KIEV? USSR. UNCLASSIFIED USSR UDC 615.372,576.851.553 DAAJA"NNIKOV, V. 1. . GOLSM11D, V. K. , REZEPOV, F. P., and CHENTSOVA, 0. 1. , 9tate Control-Iristitute imeni Tarasevicb and Moscow Institute of Vaccines and Sera imeni Mechnikov "Immunochemical and Biological Characteristics of Botulinus Type A Toxoids. IIII Moscow, Zhurnal Mikrobiologii, Epidemiologii i Immunobiologii, No 10, 1971, pp 12-18 Abstract: DEJE-cellulose chromato.graphy revealed that the specific antigen of botulinus type A toxoids is heterogeneous in physicachemical properties. Separation of the toxoids on DEAE-cellulose yielded a fraction containing over 50 percent of the total antigenic activity and free from nucleic acids and pigments. Its specific activity was almost double that of the original preparation. No relationship was found between the charge of the specific molecules of the toxoids and their molecular weight. Purification of the toxoids on DEAL-cellulose resulted in removal of the ballast subgtancas with no impairment of the immunogenic properties of the active fraction. ill USSR UDC 621-355-8 :QRA=. G, C., MATVEYEVA, M. I., and TOMASHEVSKIY, F. F. "Cobalt as a Trace Element in the Anode Part of Alkali Batteries" Sb. rabot no khim. istachnikam. toka. Vses. n.-n akkumulyator. in-t (Collec- tion of Works on the Chemical Source of Current. All-Union Scientific Study Institute for Storage Batteries) VYP ?, 1972, PP lt8-123 (fron Referativnyy Zhurnal -- nimiya, No 8(11), 1973, Abstract No 8L240 by V. S. Levinson) Translations The influence was determined of traces of cobalt In the form of a metallic powder and as different compounds in the positive working terminal on the capacity of alkaline batteries of the type TZHM-300. The greatest effect was shown by the compound CoSO in the form of a saturated solution# approximately 3%. Under these condizhns, the capacity of the batteries increased approximately 020% with a concommitant improvement In its power at higher temperatures (40 C) for conditions of a small reduction in the d-is- charge current. The actual specific energy of batteries having cobalt addi- tions with unlaminated negative and laminated positive electrodes was 73-5 watt hoursA and 34 watt hours/kg. Such batteries are recommended for appli- cation for loading zachines. 1/1 USSR UDC 681.327.67'12 BRODOLIN, L. I., VAYNSHTMiT, V. D., D.P.4CHEV, L.,A., KAN, A. Z., KUZNETSOV, B. A., MININ, Yu. P., and PETRUNICHEV, V. N. "Long-Term Photoscopic Memory" USSR Author's Certificate No 260926, filed 7 Oct 68, published 10 Jun 70 (from RZh-Avtomatika, Telemekhanika i Vychislitel'naya Tekhnika, No 6, Jun 71, Abstract No 6 B325 P) Translation: A long-term photoscopic memory designed for storing, retrieving, and selecting a symbol image is proposed. The memory contains a light spot commutator -- for example, a cathode ray tube -- a projection objective with telecentric behavior of the beams in the image space, a lense raster infor- mation unit, a fast collective, a transmitting cathode ray tube with storage -- for example, the superorthicon type and digital and analog tracking systems for setting the spot on a given address. The memory is distinguished by the fact that to prevent charging the target when retriev- ing the required microframe, the device contains an electronic image modu- lator in the transfer section of the transmitting TV-tube. In order to insure a broad range of variation of the capacity of the TV frame and the selection rate, the target of the transmitting TV tube is executed in the form of a metal fiber disc with a coefficient of secondary emission 1/2 USSR BRODOLIN, L. I., et al., USSR Author's Certificate No -16091-6, filed 7 Oct 68, published 10 Jun 70 (from RZh-Avtomatika, Telemekhanika i Vychislitel'nava Tekhnika , No 6, Jun 71, Abstract No 6 B325 P) of the side turned toward the photocathode equal to one. In order to simplify the design and insure the possibility of recording the service information used during operation of the tracking systems in the microframe, the device contains a fiber, vacuum-tight coherent light guide with a cross section equal to the size of the symbol in the focal plane of the collective. The photocathode of the transmitting TV tube is applied to the output end of the light guide, and the input ends of the light guides connected with the photomultipliers of the tracking addres s system are arranged around the perimeter of the input end. In order to insure the required levels of light flux from the standing light spot, the light spot commutator executed in the form of a cathode ray tube contains a built-in screen which vibrates in its own plane. There is I illustration. 2/2 - 73 - 1/2 OZ3 UNCLASSIFIED PROCESSING DATE--18SEP70 TITLE--MACROKINETICS OF THE: FLUIDIZED BED LEACHING OF ZINC CINDERS -U- AUTHOR-102)-BUROVOYr I.A., DRACHEVAr T.V. ft4% COUNTRY OF INFO--USSR SOURCE--TSVET. METAL. 1970t 43(l), 26-30 DATE PUBLISHED ------- 70 'SUBJECT AREAS--MATERIALS TOPIC TAGS--FLUIDlZr-D 8ED, EXTRACHVr METALLURGY, ZINC COMPOUND, REACTION -'Kl,NcTICSj MATHEMATIC MODEL, THERMODYNAMIC ANALYSIS CONT40L MARKING-N-0 RESTR. ICI_ IONS' _00CUMENT CLASS--UNCLASSIFIED PROXY REEL/FRA-HE--1986/075-1 STEP NO--UP/0136/70/043/001/0026/0030 CIRC ACCESSION NO--AP0102722 UNCLASSIFIED 2/2 023 UNCLASSIFIED PROCESSING DATE-18SEP70 CIRC ACCESSION NO-AP0102722 ABSTRACT/EXTRACT--(U) GP-0- ABSTRACT. THE EXPTL. RESULTS ARE PRESENTED ON-THE TITLE SUBJECT9 AND A MODEL IS PROPOSED FOR THEIR MATH. TREATMENT. THE EXPTS. WERE PERFOkMED UNDER SO CALLED GRADIENTLESS ISOTHERMAL CONDITIONS, UNDER WHICH THE DROP IN THE CONGNS. OF THE LIG. REAGENT AT THE ENTRANCE AND AT THE EXIT TEND TOWARD ZERO, WHICH SIGNIFICANTLY FACILITATES THE SUBSEQUENT TREATMENT OF THE EXPTL. DATA. THE MATH. MODELING METHOD FOR THE TREATMENT OF THE EXPTL. DATA WAS NECESSARY BECAUSE DURING THE GXPT. -ONE CANNOT BRING ABOUT CONDITIONS UNDER WHICH ONLY ONE OF THE GIVEN PARAMETERS WOULD VARY AND WHERE THE OTHERS WOULD REAMIN CONST. THE MACROKINETIC CONSTS. WERE DETD, BY VARYING THE COEFFS. OF THE 4ATH. MODEL WITH A GIVEN STRUCTURE UNDER THE CONDITION OF THE-MIN-* OF THE MEAN SOUARE ERROR. MOST OF THE EXPTS. WERE PERFORMED AT THE RATE OF 59 CM-MIN. AT C PRIMEO H SU82 SO SUB4 EQUALS 100 G-L-i THE DAMPING COEFF. OF THE LEACHING RATE BY REACTION PRODUCTS IS 1-10, 1-20 THAT FOR LEACHING FROM BRIQUETTES. -1/2 020 UNCLASSIFIED PROCESSING DATE--30OCT70 TITLE--THE AGING TRAITS OF CEREBRAL STROKES --U- AUTHOR-1033-DRACHEVA, Z.N.r PENEK, N.V., SHEHURINOK, L.A. CCUNTRY OF INFO--USSR SOURCE-ZHURNAL NEVROPATOLOk /I PSIKHIATRII 114ENI S. S. KORSAKOVA, 1970, .VOL 70, NR t, PP 312-815 DATE PUBLISHED- -70 SUBJECT AREA5-BIOLCGICAL AND MEDICAL SCIENCES TOPIC TAGS-CEREBRUM, HE14ORRHAGEr BIOLOGIC AGING, CLAGNOSTIC MEDICINE C0141TROL MARKING--NO RESTRICTIONS DOCUMENT CLASS--UNCLASSIFIE0 PROXY REELIFRAME--3001/0921 STEP NO--UR/0246/701070/006/0812/0815 CIRC ACCESSICN NU-00126580 UNCLASSIFIED 2/z ozo UNCLASSIFIED PROCESSING DATE--30OCT70 CIRC. ACCESSION NO-APOIZ6580 ABSTRACT/EXTRACT-(U) GP-0-- ABSTRACT. THE PAPER CCNCERNS A COMPARATIVE STUDY OF CLINICAL TRAITS IN HEMORRHAGIC STROKES OF THE YOUNG AND OLD AGE. ThE ALTHORS STUDIEJ 17 PATIENTS IN THE ACE GROUP OF 30-45 AND 25 PATIENTS FRCM 60-75 YEARS OF AGE WITH CEREBRAL HEMOkRHAGES. IN ALL THE CASES THE DIAGNOSIS WAS VERIFIED IN POST MORTE14 EXAMINATIONS. THE PATIENTS OF THE YOUNGER GROUP WERE CHARACTERIZED BY MORE EXPRESSED GENERAL BRAIN SYMPTOMS, A RAPID DEVELOpijEt%r CF COMATOSE STATES, AUTOMATIZED JESTURES, HOAMETONfA, OCULOMOTOR DISORDERS, DISTURBANCES OF RESPIRATION AND CARDIAC ACTIVITY. THE OLDER PATIENTS DID NOT EXPRESS SO STRIKINGLY THE GENERAL BRAIN SYMPTOMS, hHICH DEVELOPEO MORE GRADUALLY. THIS MAY BE RELATED TO A MOkE COMPENSATED BRAIN EDEMA, SivELLING# BECAUSE OF THE CEREBRAL AND BRA114 TISSUE ATROPHY, AS WELL AS A DECREASE OF THE REACTIVITY ON bhHALF OF mE NERVOUS SYSTEM. FACILITY; KIYEVSKGGO MEDITSINSKOGO INSTITUTA* FACILITY: KAFEDRA NERVNYKH BOLEZNEY. UNCLASSIFIED USSR UDC 669.295.476 R-11K.-, ABIAZIOVA, N. G., LUKINA, A. G. "Production of Titanium from Anhydrous Media on a Mercury Cathode" Nauch. tr. Kazakhsk. Politekhn. In-t [Scientific Works of Kazakh Polytechni- cal Institute], Alma-Atz., 1971, pp 548-550, (Translated from Referativnyy Zhurnal, Metallurgiya, No 5, 1972, Abstract No 5 G263 by G. Svodtseva). Translation: A 10% solution of TiCl 4 in isobutyl alcohol, with 1 volume of ethylene glycol added to 2 volumes of the solution, was electrolyzed. Each g was poured onto the bottom of the clectrolyzer, acting as the cathode, while the anode was a I't plate. The current density of the cathode was about 440 a/1112. Electrolysis time 1 hour. Metallic Ti was separated as a finely dispersed black sediment on the surface of the 1-1g. Following electrolysis, the sediment was washed and filtered by decantation in isobutyl alcohol. Only about 2% of the metal Ti was extracted from the initial solution. 1/1 1 USSR_ UDC 669.2851295 1296;764.018,44j620.186 GRISHOVI V. L., DRACFJ13KIY A S .h,, KAV~RINA, S. N., PISARENSKO, V. A., and TWIWVI- X. e Physics of lietals, Academy of Sciences Ukrainian SSR "Cbange in the Structure and Properties of Molybdenum After ?eating in the Hi&-Temperature Range" M6tallffizika. Resp. mezhved. sb. (The Physics of Metals. Republic Inter- d6partmental. Collection of I-Iorks), 1970, vyp. 30, pp 42-49 (from RZh-hetallur- giya,.Blo 3, Har 71, Abstract No 31732 by Authors) Ti-anslationi The following two types of heat treatment ifere used to obtain different structural stati,-s of No alloy with 0-35%,' Ti, 0.1%.1 Z'r, and 0.007% CI annealing in a TIN-4 furnace in a vacuum of 5-10-4 M ~ Ifg with four-hour holding and a cooling rate, of - I deg/sec; heating by passino, alternatina current through a specimen at a heatinGr rate of,- 150 deg/sec and a coolinC rate of.200 deg/see. Specimens annealed at different temperatures under these conditions underwent mrachanical tensile tests and nicrohardness measurements. The-influence of structure on the strength characteristics of the alloy was studied. A significant increase was found 0in the strength and ductility values of-.*specimens electric-hea.t-treated to 2000 as compared with annealing heat- 1/2- USSR. CRISHOV, V. L., et al., Retallofizika. Resp. mezhved. sb., 1970, vYP- 30, pp:-42-49 treated specinens. Agln'- processes were observed in the E0 --Uoy in so,~,,e cases after heat treatment. Eleven illustrations. BiblioGmphy with four titles- 2/2 - 14 - USSR b0c 547-75 ZHUNGIYETU; G. I J_)~GAII LIAL G. A., and DOROFEYENKO, G. N., Chemistry Institute of the Academy of Sciences of the Moldavian SSR, Kishinev "Reaction of Oxindoles with 9 -Diketones" Riga, Khimiya Geterotsiklicheskikh Soyedineniy, No 9, Sep 73, pp 1271-1272 Abstracti In the reacticn with acetylacetone in presence of hydrogen chloride, oxindole and 1-acetyloxindole form a mixture of approximately equal quantities of 3-isopropylideneoxindole, I-oxonia-2t4-dimethylcarbazole chloride and methyl ester of o-aminophenylacetic acid hydrochloride. In case of other 1- and 5-substituted oxindoles it was possible to isolate 3-isopropylidene darivatives. 1/1 USSR UDC 547.759.1'753'756 ZHUNGIYETU1, G. I., DRAGALTINA G. A., and DOROFFYENKO, G. N., Chemistry Institute, Academy ~f Sciencel-s of Moldavian SSR, Kishinev "Reactions of Indoles and Hydroxyindoles With Some Aldehydes" Riga, Khimiya Geterotsiklicheskikh Soyedineniy, No 1, Jan 73, pp 40-44 Abstract: 3,5-Di-tert-butyl-4-hydro.%cybenzaldehyde (I) reacts with indole and 2-methylindole yielding derivatives of di(indolvl-3)metliane; with hydroxyin- dole and 1-methylo%yindole (I) yields derivatives of 3-arylideneoxyindole. With salicylaldehyde hydroxyindoles form 3-(O-hydroc~(benzylidene)liydroxy- indoles. In reactions ,with arylglyoxals; hydro)Windoles yield (hydroxy- indolyl-3)aroy1carbinols which under the influence of acetic acid dehydrate to 3-plienacylidLiieliydro:~,yindoles. But the starting carbinols and thel.r products in reactions with hydrazine form 3'-arylspiro(iiydroxyindol-3,5')- A2-pyrazolines. 21 - 6 -' 3 USSR U--C: 02-372.o6i "A oiethlc-d Of P'LlIse -Reactions of Commu-n-'e-zions V sb . 'lor1r. ele tros,F,, a z-- (Pro blems of --' lecT ri, c a I Commu:-, 41 ca-tions-cc-L.Le clc:Lon = II - w 0 ilz`. si: i e v 1-48 (from o" "Tek~nnila l970, Pp 42 Nov 7C JVbstract No 92) irl ordQr to solve a number of r,-obleirz associ ated -,rj t"i develo,')m~ezit of correcti.,-ig devices 11"or higi-speed tralisrussion of, discretL~ information, it is nece:3sai-,r to know the relationships between tiie- reference value:s of the -nulse reanion in the uncol-rected channel. This proble", ca:i riot be solved by dilrect measurements at the present t;ime. ~n this connection the auzhom a of determining the reference rjl' reaction i.n chtuinf--l from reading.,; of its ar'(. -freq,uenc~-, characteristics. Formulas aro derived which ctui be u~;eu Lo de- the unknown, auwitities from readings of the ~-ransmission factor of' the channel. Apm-lication of these formulas is illustrutted by calculation of Dract-Ical. correcting devices. Two tables, bibliogruphy ol' ve titles. S. USSR UDC: 51:621-391 ILRAGAN_, Ya. P- "On Data Compression in Representation of a Random Process" Otbor i peredacha inform. ResD~ mezhved. sb. (Data Collection and Trans- mission. ReDublic InterdeDartm.ental Collection), 1972, vj-p. 34, pp 3-12 (from RZh-Kibernetika, No 5, May 73, abstract No 5V582 by Yu. Lin'kov) Translation: Let Z+ be a space of seq!aences a= (a,, a2,-) such that 2,V ~~ 0 for all k and jjajj~,Y~ ak H" where 0 is an orthonorma1ized Lo6ve-Karhunen basis. Extension to the case of multidimensional random processes is considered. 2/2 USSR DP,AG.kN, Ya. P. "Biperiodically Correlated Random Processes" Otbor i Peredaclia Inform. Resp. Mezilved. S1). [Collection and Transm, i ssi oil of Information. Republix Interdelmrtniental Collection], 1972, No 34. pp 12-14 (Translated froi.-i Refer~itivnyy Zhumal Kibernotika, No 4, 1973, Ab,;Lract No 4V148, by the authoi-). Translation: Ilic concept of hiperiodi call), correlated random processes is introduced, used to describe biwjry rhythir's ill Imtural phonomcna, Z!Ild the properties of 1hese processes are svudied. USSR UDC 519.2 P. "Types of Canonical Expansions of Random Processes" Otbor i peredacha inform. ResR. mezhved. sb. (Data Sampling and Transmission. Republic Interdepartmental Collection), 1972, vyp. 31, pp 12-21 (from RZh- Kibernetika, No 9, Sep 72, Abstract No 9V82) Translation: Two types of canonical expansions of the random process given in a segment are isolated. Using the concept of the Riesz basis, a description of all possible expansions of both types is presented for the given process. The relation to the Karunen-Loewe expansion, the problem of finding a shaping fil- ter, the Rice expansion and the reckoning theoren is established. 1/1 USSR UDC: 519.21 DRAM Ya. P., Physicomechanical Institute, Academy of Sciences, UkrSSIT? "On the Spectral Properties of Periodically Correlated Random Processes" Kiev, Otbor i Peredacha Informatsii, Resp. Mezhved. Sb. , No 30, 1971, pp 16-24 Abstract: The spectral properties of periodically correlated random pro- cesses are investigated by elaborating the ideas proposed by the author in 1969 (Ya. P. Dragan, Otbor i Peredacha Informatsii, No 22, 1969). Periodic correlation is understood to mean periodic nonstationarity of second order. The covariation function of the periodically correlated random process is represented as U) etax dF()., the time dependence of the spectral function being periodic, and the func- tion itself having the expansion 0. 23 F E F, Q.) e k--CO 112