SCIENTIFIC ABSTRACT ZUYEV, V.YE. - ZUYEV, YU.S.
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CIA-RDP86-00513R002065630001-8
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RIF
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S
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100
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September 1, 2001
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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L 44211-66
ACC NRt AP5021189
atmosphere. Analysis of the problem of light soatte-,,ring by the particles
nam.4
system Is also making progress from the poing ot view of electrody
Two new scientific and practical problems have begun to attract attention
!recent?,r: particular features of the propagation of laser radiation in
the atmosphere and interpretation of the optical and radiation data
of the earth's artifical satellites . Since the 'iprobIem~ of atmospheric
transparency has important practical-applications, Tnany researchers
have paid particular attention to the quantitative characteristic .s w1lichl
determine the general decrease in the intensitylof vadiation propagttd
in the atmosphere.
SUB CODE: 04, W SIMM DATE: l6jul65
2/2 J-5
C.,
. ............
L 09172-67 EWT(1)ACG_. ROP;~L___
'7ZC- NRI A16023407 SOURC E CODZ
AUVOR: ZUYev V. Ye.- Sokolov, V. V.; Tvoroaov, Be D*
ORG: Siberian Physicotechnical Institute im6 V, D. Kuznctiw (Sibirokly fitiko~
tekhnicheskiy ins itut)
TITLE: Aerosoll(icomponent of spectral transparency of atmo6 .pheric haze in the 0'0:5 14
Micron wavelength range
V
SOURCE: IVUZ. Fizika, no. 31 1966) 7-13
TOPIC TAGS: aerosol, atmospheric transparency., particle distributiono atmbipheric
optics; atmospheric water vapor
ABSTRACT: The author analyzes the behavior of the relativ6- aerosol attenuaiion~coef-
ficient as a function of the wavelengthp the meteorological.distance, the propagation
distance of the radiation, the particle-dimension distribution function, ahA the
minimum and maximum radii or the particles. Both horizontAl and oblique pr0pagation
of radiation in haze are considered. She various factors eIntering in the.ei'Tression
for the attenuation coefficient are gathered from the literaturep and tables of,the
attenuation coefficient and of its spectral components are 'lpres~nted. The dat& ob-
tained are sufficient to calculate the spectral tranaparency of,the aerosollcomponent'
of attenuation of radiation by atmospheric haze in the loWra, 5-1cm 3AYer of the ' atmo-
sphere for different relative placements of the receiver and of,the source.; Some
practical plats of the spectral transparency variations are pretented. Although the
Card 1/2
L 09372-67
_Adi~ -ki-Ar6623467-
calculations are made for homogeneous spherical droplets.,,I,'4e results are appliclable
to two-layer particles of irregular shape. It is pointed out in the conclu4ion:~that
a rigorlous theoretical solution of the problem of attenuation of particle4~0:f
regular form cannot be obtained at present because of lack~~,of dwta, an the ahape:and
chemical opposition of particles of the atmospheric aerosol. Qdg6 art. has:
formulasp and 2 tables.
figures., 3
SUB CODE: 20p 04/ SUBM DATE: 15ju164/ ORIG Fxrt 002/ OTH MW; '005 1
Card 2/2 .1r
L 04685-67 FSS-2/EWT(1)/FCC TTIGW
ACC NRt AP6001666- SOME CODE:.~ UR/0051/65/019/006/0994M91,
AUTHOR: ZuYev, V. Ye.; Tvororv ~SD
ORG: none-
TITLE: Conference on the spectral 4!R~herjq_tranppprency
SOURCE: Optika i Bpektroskopiya, v. 19, no. 6, 19651 994
TOPIC TAGS: atmospheric transparency,, IR spectroscopysilight scattering,
ABSTRACT: A scientific conference on spectral.transpar691cy ofl-the atmosphe.re in
the visible infrared range of spectrwn, organized by the~'schools-of highsi education,
was held from June 29 to July 1, 1965 in Tomsk. In this~qonference 127 representative.,
from 15 towns participated; 45 reports were presented anddiscussed. 11 of th .ese
reports were devoted to different aspects of the problem bf absorption function. T4e
discussions showed that at present two methods developed for calculating the absorptior
furiction: the utilization of a spectrum model and the approximation of tho experimentE
data determined by the standard'formulas, Also there are,two ways of approach to the
pr9blem. of absorption function in case of an inhomogeneous medium: the mehho&of
reduced mass and the method of weighted inean pressure. The problems of spectroscopy'
of the absorbing components of atmosphere (water vapor,.ciu-bon dioAide 0ZIone, oxygen)
were discussed on 8 conferences. The main attention was focusdd by the authors on
A
L 04685-67
A%.F- NKs Arowi-000
the obtaining of quantity data on the state., intensity a~d halfiridth of the aboorpqQr
line of atmospheric gases, and on the analysis of the aontour,of line in h strong
electromagnetic field. In 8 reports some theoretical problems associated'with the
light dispersion in atmosphere were investigated. Modern problems inclWod the J
attempt to interpret the transport equations from the point of view of electrodyruwd,cd
and the analysis of the transport equations for unresolved absorption bands.
10 reports were devoted to the discusion of results pf;axperiawrital study of the
light scattering by aerosols. 3 reports contained the d4ta ot tho transparency
of atmoophere in various sections of spectrum and for differont:meteorological
conditions. The description of the measuring instrumen~a was'given in 22.reparts.
A summary of the analysis of modern experimental and the-oretical material about
individual characteristics of t~B absorption lines of the main absorbing'components
of atmosphere was presented by PTI.JomBld _yq
,y (S K. Ya. Kondratl v,
I. Ya. Badinov, S.._D. Andreyev. D. V. Andreyev (Leningrad, -d about the
informe
basic results of the ground and high level investigar~ions of the transparency of
atmosphere. A. -- P. Ivanov Minsk), submi-tted for discussion~the ,
experimental material on the optical properties of dispersing model atmosphere
gathered by him. The conference showed that the foUo,,nng tmnds are 3uccesn..fully
developing: the theoretical and experinental, study of the absorption function for
various spectral ranges, the methods for solving the transport.equations in a
dispersing medium for different geometries and the estimation of the polarization
effects at dispersion; the analysis of the connection 'betweeri the optical and
microphysical characteristics of aerosoles, the inveBtigation or the instrummt
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'ACC NRI
coefficient of light attenuation in a dispersing mediumil the determinati(*i of, the
content of absorbing atmospheric components by'a spectroscopic methods the me,thods
for solving the inverse problems of scattering, the istiu~r of the propagation of
waves in a turbulent atmosphere. Recently are very inttlfnsiv!gy developing two
new important trends: the interpretation of the optical and"'radiation data of the
I artificial earth satellite and the investigation of the~~propajliEl-onof raiii-Faiafit-16-rl
in atmosph -*-TH-e -sec(;M' problem is especially closely linked with the problem of
atmospheric transparency. The features of laser emission reo'ire a wido application
of molecular spectroscopy, analysis of the problem of light dispersion by, a system
of particles from the point of view of electrodynamics'and~ a thorough study of the
fluctuations of local optical properties of atmosphere.
SUB CODE: 04, 20 SUBM DATE: none
fv
Card 3/3
ACC NR, A~(423419-- ___e0_1bCE CODFi
ZUeXj Koshelev. B. P.: Worogov, H. D.; rhmelvrpsov. S. S.
'ORG: Siberian Physicotechnical Institute im. Ve D. Kuznotscyv (Sibirskiy' Mlzik7o-
.LITLE: Spectral trapp. d microstructure of artificial! fogs. ConUarison.
pa
._rgn-cy an
lof calcu--lo6-t.e-d-an--d--e-xperimental data.
SOURCE: IVUZ. Fizikaj no- 3) 3.966) 121-125
TOPIC TAGS: atmospheric tranaparenwj., atmospheric water yaporj aerosol) tog) atmo-
spheric cloud, light absorption
ABSTRACT: In the first two parts (Izv. vuz1ov SSSR, Fizilop noi.,2 and 3.,~ :1969 the
authors determined the transparency and attenuation coefticients~of artificial and
natural fogs for a wide range of microstructure parameters. The presentArticle de-.
scribts the concluding investigations and presents a aumit~ry or -the results, which
cover more than 800 samples oontaining in all come 500,FOW cb..opst and more than 2000
spectral measurements. The theoretical values of the attenuation coefficient~of the
aerosol components of clouds and fogs, calculated by the zethoi Iproposedlin the earlier
papers, is compared with experimental results obtained Iii an artificial fog c4amber...-
The optical density of the investigated fogs ranged between oo06 and 2.Tjthe:&ttenU&-
tion coefficient at 0.42 IA wavelength was 0.02 - 01 tri.) 'and the ratio of the' attenus..
O*3T%o 1q4lj de-
tion coefficient at other wavelengths to that M OA2 V rangedtrom,
Card 1/2
L 093
-Add-~ 147-AF662-34 19 0
pending on the microatructure paramatern. Ilio wimirOPIO~tA w*rd WO atzo 1A r! 9 anVAQI
of wavelengths ft-om 1 to 14.0 p. The rma drop diamaterit rangod from 3.3 -to L)2. 5 1,.
The measured and calculated relative attenuation coefficients were in good Weement-
except for the wavelengths 6.o and 6-5 p. but the absolute attenuation coefficients
did not agree) the discrepancy being by as much as a factor of 8 in some cases. "Abe
only possible explanation for the discrepancy may be inaccurate determir~atvion 'of -the
'fog droplet concentration in the trap. Experiments aime(l at checking this accuracy
are now under way. Orig. art. has: 4 figuren', 4 formulaaO and 2 tables.
UM CODE: 2o,, o4/ suBm DATE: 26oct&/ ORIG TW: :002/ OUI REF: 001
t 42072-66 ZiT (1) no/w
A ACC NR, AP6013466 SOURCt qOM I UR/6139/66/000/bm/M43/0150
AUTHOR: ZUev, V. Ye.; Tvorogovo So D.;
Siberian Phjsico~echnical V, Do Kuz rskiT,fizik
Inatj&jj&e im; tletso~ (Sibi o-
to'eElnicheslay institur, I I I
TITLE: The effect of microstructure parameters of water caloiaks%And fop, on t,heir
spectraltransmittance in the 0*5-14 micron region
SOURCE: IVUZ. Fizika, no# 2. 1966, 143-150
TOPIC TAGS: atmospheric cloudl fog,, cloud physical distribution functiono atmoapheric
refraction, optic tranemissionl optic spectrum
ABSTRACT: The averaged efficiencyJactor for radiatidh attonuation by water
clouds and fogs is analyzed by considering thpir true poly ilipersion and
their- complex refractive index. The aerosollycoefficidnts of water clouds
'&nd-fogs are also examined.
'rhc- averaged efficiency factor (F) for radiation attenutWOn by wakdr
,.clouds and fogs is defined aa the ratio of the attenuation coefficient of
Xne aerosol component of the atmosphere to the particle cross section
dn 2- unit volume. By considering some special proper'des Of the drop' ,
digtribution ftinction, which can be determined from logarithmically' I
Sz;orrnal- and. gamma-distribution, relations. several foi~jnulas are derf"d,
Card ---1117
L 42m---66
A=NR, APO 6
for,7 calculating F. These expressicna are then used to analysc~ qualltad~'
tively the dependence of F an the microstructure charieteristics of w ittr
clouds and fogs,
The-behavior of function F Is analyzed'for variou, 3 values'of
and p , 'where 0 is the phase angle and p is the parameter ' character-'
izing the distrilution half -width. It is found that with~ increamed S
'the maximum of F Is decreased. This maximum varies with decreased
p, but only for small values of 0. Thils, the maximum ofY appears
to be narrower the srnallev the distribution half -width. this Indicatel.
:that calculations of the spectral transmittance ofwatei Clouilo. and fog*;
made without considering their microstructure and compleic refractive
index will not yield rbliable results.
Bearing this fact in mind, the aerosol attenuation coefficients (tW
are also calculated and analyzed for various values ot)j and r, 'where r
is the most.probable particle distribution radius.
The results of the calculations are Illustrated In ~Fige.~' 1-6. The'
data presented in these figures cover practically all* Uxe~ different mir-'ro'-
istructure characteristics encountered in the atmospbore ofliquid clouds
and fogs.
Card 217
-h2072-66
ACC NRt AP6013466
Aj~A`anij~_sis of ihe results yields the foliow"Ingcondvisioinsf- 7
In the visible region of the spectrum a ( x) and, conse 'ientV,, the spec
CP
tral transmittance of clouds and'fogs are independent of wavelength.
In the 10.5 -12.2 micron region, cloud and fog transmittliance is always
higher than it is in the visible region. Depending on thip parame-ters
of the microstructure, the ratio' values
from 1 to 50 With increased distribution half-width (deereasesd'p) or
increased r, the transmittance maximum., shifts toward: the longer wave
region, but does not go beyond 10 12 microns.
In the 1-5 micron region,, cloud and fog transmittance for' an
micro-
structure characteristics. is lower than it is in the visible i~dgion. Th
ratio ct(A)/ a (0.5) reaches its maximum of 1,76 at x ~3.5 microns,
JA = 10, and e a 2 microns.
in the spectral regions of 5-10.5 and 12 -2-14 rnicrons~ trarismittance'
can either be higher or lower, depending on mtcrostruelturepararneteri,~
behavior of the aerosol attenuation coeffide
The speSt nts of clouds
Card 3/7
'42072
-66
L
ACC NR, AP601349-6
and fc.-s 'in tfii_~-4 -and 10-12 micron'regions Is deter
Mined chiefly by;
the compleX refractive - .;
index. In the entire range of wavelen~qhs in
iestigated, a( x) depends essentially on microstructure parameters 1A,
and r. The maximum difference in values of a (X) is observdd in the
case of small-drop clouds and fogs at IA a 10. In large~drop Clouds
with a large distributiod half-width (r - B-10 microns, i IA 1-2), the
-behavior-of .' the.aerosol attenuation coefficients is practically Independeilt
:.of wavelength.
The results obtained Illustrate the futility of num.Olous attempts to
establish by purely empirical means a correlation between the trans
mittance and one of the wavelengths in the infrared region or: in the
visible region. The results, however, can be used to detertulne this
correlation uniquelyo provided parametere r and u are.gilyen-'
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I Card- 617
1; 1072-66
'ACC NRs AP6013466
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Fig. 6,
Fig. 5.
Orig. art. hass 14 figures and 14 forimulas, [FSBI va~4, no;, 71
SuB CODE: 04t 02 SUBM DATEt 15JuI64 OHIO M73 014 07H MW I Oq4
I Ca-d 7/7 af
mifflifft'Iffili mii I SNOOK "11 illI1.i;:. -jr!
AUTHOR: Zuye-,r V. Z.
TITLE: A Dril2ing Machine for Mob'Lle Repa~t.J,1,1 Shopa
(Svez-1ilInyy stanok d1ya peredviz1-.-,~.,ykh r,e=ontnykh'raasterskikh)
PERIODICAL: Stanki i InstrumentV 1958', Nr (31~p 40, (USSR)
ABSTRACT: A drJ.*'jj## head mounted on a sleev4t sliding along the, drill
a 0 UM14-, 1the spindle and driving potor on opposite isid~s
of the column is described. The mind worktable j8;
arranged an a vice. The largest d-rill &tameter is.18 mm.
There are 3 figures.
Card 1/1.
MUCEIEVICH. Vadim Andreyevich. kand.geograf.nauks, KALTBHHT, Andr
Takoylevich, kand.geograf.neuk; ROGOMTO 318ofid Ternolayevich,
.kand.geograf.nauk; red.; YqRMEY, P.S., takhh.red.
[Cities and villages of the White Russian S.S.H.: histori Ical
and geographical outlines] Goroda i sela Beloruaskoi SSH;~
instoriko-geografichookis ocherki. Minsk, Gosouchebto-ped IAgog.
izd-vo, H-va proov. BSSR. 1959. 278 P.! 1~:8)1
(White Russia)
KOLOKOLOVI A.A.; SHCHETININp N.V.; MIRONOV, N.I., Insh.', reteenzent;
zu~Eu~ insh., retsenzent; KRAYNOV, B. P. in sh..,
retsenzent; BRAYLOVSKIY, N.G., insh.,, red.) VOWTHIKOVA,
L.V., tekhn. red.
(internal combustion engines for refrigek*tor r6lling stock)
Dvigateli vnutrennego agoraniia izotermlobeakogopodVi2hnop
sostava. Moskva, Transzheldorisdat, 19636.~ 219'p.
OuRA 16:7)
(Internal combution engines)
(Refrigerator cars)
ZUIEV YU (1,
tatent respiratory innufficiarlay in aurgjdaj~p&tjO,jtA, Vast. khir 91
na.90-32 Ag 164. 18~17)
1. Tz gospitaltnoy khirurgiohdakoy klitAki ("v. 4 jwdf .S.P.Yllabov)
I kafedry normallnoy fislologli (tav, - pror, O.A4VAslaygsr)~Orttiburg-
skogo maditainakogo instituts, (rehtor - prot, S.SAMaylov),"
0050
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10i)501
AX065315
AUTHORs -Ztwavp Yu. H.
0R0: none
TITLEt A Mriza electric driva* Class 219 No. 177503
SOURM rsobreteaiya, proaqshlawWye obtaztay# tovar)~Jjle zr401,, no. 4 50
TOPIC TAGS: electric propulsioa, martra angina, ship oompotiont
ABSTRACT t This Author Certificate explains an application ot a screw (Wive Alrect
current electric motor to a varine electric drive, TI-14) drivo has twin 0 ronous
YU10
generators which rotaite at a conatant speed. One of t1o gettirators is ulated
and Is serte&-aonnected in titase with tho other gonerator which is regeat . The
power supply of the ship system is delivered by the oiride unregulatad ganisrator.
The screw electric drive of the ship is provided Lry the two gemarators thraqpjn a
rectifier. Thie is done to inaresse the speed replation range of the drive motor.
SUB COEEs 21/ SUBM DM 1 3014ar64
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UDC, S
-621.316
RYZHKOV, O.A.; KHAIMVv R.N.; VITCHINKINI, M.M.; ZUfEV 07i, Tu. If
FaleozoA'c oil of Uzbekistan and adjacent territories. Soy.
geol. 7 no.8s95-107 Ag 164. (Kith 17310)
1, Institut geoloCil I razrabotki noftyan7khl gano'vykh
mestorozhdoniy AN ThbSSR.
STAIUMINETAF I.S.; KIIAIMOVt RoN.; "UYEW, Yxt,N,; IJASIVINIMI, V.P0
Oil potentlal of the Malmazola depamita Of rmlArIal Asia,
Dbk1, MI 'Uv*.IMR 21 nos 1094640 #04 (mial Iron)
1, Tnatitut geologli I rmdrabotki nvfty0ykh i Igazovykh
no-4torozMenly Gonuitaratyannogo gotil.oll 1.0mok ago ~nm'Atetd
MR.-iPubmitted March 2Vp 1961,
z UYU. V I Yu. S.
Mbr., Sci. Res. Inst. Chem., Dept. Colloidal Chem. -191+21~; Mbrk,. Lab,
Colloidal Chemistry, Moscow Order Lenin State Univ. -194'1-,. M.IV, Lomonosov'
"On the Kinetics of Development of Individtal Grains of a Fhotc&Tdpbic Emulpion;,"
Acta. Phys., 16p Nos. 5-6., 191,2; I'Determinining the Adhesive Power of Particles+
in Suspension Sediments," Kolloid. Zhur, 10, No* 4, 1948i
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Chemistry Adli6elvenass
ONtermining the Adhesive Power of Pirtioles",
in Suspension Sediments," Ya. S. Zuyar,'14b of
Colloidal Chan, N11K,, Xosoov State U, 8 pp
01olloid Zhar* Vol X, No 4
Studies the sedimentation of a suspension of zinc
oxide In banione as wall as effect of addition of,
surface-active substances. Cites mothod of
estimating adhesive power of particle relative
to ~ x14p, which consists of datorminiz the
Uniting slip stress of the suspa=lon sodi=Ata~
sod is.apportIoned among contact points or aqw%"-
UM/Chemistry.- SusponsloAB(Contd) Jul/Aag
~:-~Geztimetor of slip, surface. 1"s of
power between partio lea of aus asion, -due-to
addition of surface-active -'substawas Is rolatlve'-'.~~
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13AM6
't 1856-66
ACCESSIdN MR4 AP102209i idl SM/6W 60 di*46
AMHOR I Z S.; V
TITLE*. effect Of antiozottante4an the 6zenizatiort bt ~Ivjbbdf4 at dif Or~'k tempers-
tures
SOURCE: Kauchuk t rezins, no_8, 1965i 12-46
TOPIC TAGSs vulcanizate, ozoalzs~ldq, lin'ti6sonant;., i, ur f-tubb4iri- 1101Vregle -rubber
---------- -
ABSTRACT., The effect of temperature oni the otoaizat"!t of, retbers in~Ohe ~iresence.
of antiozonants has been studied to'cla~rffy the,vie~hi ~il;a, It ~pacition 4 1datiozonants
and for technical purposes.- IUperinient6,:-wer~e conddciii4. at 6 to 46C *~th-#ressed
and unstressed unfilled LSO--
,/vulcanizates ofluatural (paU,erepe and no
prene (SKI-3) rubberg.P M-phenyl , i
(4010A) a6d
N,H'-d1pheny1*0henylened1ajdne (DPMA) ware used an Ilia an-1:0zondate. The ozone
concentration during the expertwnts wa* maintained at 1-1#5 x 10"3 vol%; %tressed
rubbers vere subjected to a deforution sppteachtag tho crtnical value of ZOZ. ;The
experiment consisted of the deteridmatidO Of OZ0ne-CdflWUwVtAaa =tJ crac~-Zrowth
kinetics. Trim"estigation of the respective kinetic comm Owed that t6e 40109A
antiozonant slows down atone crack grovth in naturdl athd toopveoa rubbot by,reactiva
Card 1/2
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L 1856-66
ACCESSION MR: APS022091
both with.ozone' and the polymerk them effect iveneis.. 6~ i 4 ~ioi ant iot M4 is
partly due to promotion of:the~ catelytU dficomposftlOil of oioitao Incrgosinig the
ozonization temperature of vulcaninates in the vicinU~ of 4xitical defOrvialAons
usually Increases the ozone consumption but slows doim the 4eattuction twd Increasoi
ithe life of vulcanizates. In the initial stages, the ozontoation procoos of un-
,stressed natural and isoprene rubbers does not differ from that of stressed rubbers
In respect to the values of the activation maergy, but bas a stuch slovet rate. In
the absence of antiozanantso ozonization of SKI-$ proc*eds domewhat faster than that
!
of natural rubber due to the presence of traces of S%I-J polyatstization catalysts.
This difference disappears in the presence of an =t2aw.0namt. nle results of the
study indicate that ozone cracking cammat be attributeii to dh4imical prot,466416 alorte~
band that the physical conditions of the procegs Oust, dild.0 NJ taketi into decount.
Orig. art. bast 4 figures.
ASSOCIATIONt Hauchno-inaladmtellakly inatitilt "it6h4q ~it%N20shletmotti tscientiar-
Research Institute of the tUther t0dustry)
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r was Ism to wwdtntq protisatito of AIA fthervom cook-
riptor peptitatiort kwt"d Pico morm MiAAmnhopmfit
,nm P to iota III tbp cagwits. tol OJ?J **I timr, "I.
,two# The pasho r6matalowil Alan 1% 10 If hmimw 411foolooff toft-
ruiWd p to 9. MW 0 it," koift" of
to irra: Its the ptemnxv tif 1% 1 the as:i. 13 at
IIA-U.
P-;IatO.4 ;IWOoslo-Of
lanodfirm In 1. A" pqxur In IM N At ~ NAP
AlCls. atul F%CL in oull" ixp*vft fiv 1111416641W
p-l"Ilm. The AlO,%wd emcialmaditilo CAO anti 40.39's;
Oro Shorwow, to If
V)i Its 1164114 11"lu"I fall(,$$ r
a. witmorroom win 0. 1 1 Cl.mms 9 -2. dowl at 0. 1 N
KIM 4
I JI 41 H
The POUND of blo.-Olawlik Wake
1h4lolify AUd. Xsok~S~SAA 13.
biwIre'a (C.A. 43,7771W; 44, $%Me I Model 611A t L", M-UIR!
0. - fook Rk'o(& + U. (*brm Illitial, #.",w rquit.
wttm, FA - C"mtWal Instantantalo, ""offulds. F.
lilmlitfut of cialikity) is twifirinvorl row 3 IlW4 of "llitwir.
toy the cammisrwy of W*,. In the reWivv ri-wifilo rAnite
e notural rutAwr
rul)ber 1.1121. Isiollrbloortifoortow I.W. The rmpirkod f4mistA
n( S46knlav and Kmona'(C.A. 35. rtlaillit the
hick-cla"tkily mralff 0 at the til"t I )o fill SIMI thr ArAin to
-olt 0. > it, S gives tnr the mrain ft dr*Iming
fluting The time (I - #01, ft ft. Thi-1volil ,l4nelf
"ith the ftlatioid + "I'll) vot%j A-C the
It, Model (F. - Mcb-duticity mil. tilofulas. 0 " In.6.f
'of elastic 61trTA"10" - "IF., Vlith it
A"i"ll vkaWtY), SIVI's 1h "' A4110/0- 11 will
(F. -'h V10.24)" - III and. (or (0/4), 1, 4"
I.t. 0 psims thrmish a win. &A (tAO" It I -
SL Mon
CA
M,CbAss th "w timis III medium itilitsilleat
hba V: for
S
J, 74,
,S
imilmidt 44 iotoplito - III) o thkA oil 4 C4 conig. 4. 111
IM ore chavicterlwil to
11,11, Ill The ftirlituditf
Of Our lgh t1holkily Fit, tht. Op 1, hljh~
elasticity niodahm A., the pittloill 0 timink-oftetai6in P. atil
the vbKolity of elastic afteraction, in, lowd cits IlMndci'~
-inadef (CA. 43, Tr7*,, 04. 6231k) ond deftell
4110101-11 and 0 - I 'FO/H.U1101,41. ~. 1y "T I "It
privreimilve. ~urr 10MAlian with Inm-a4ing! Longib ot
Crilsonitialisin
Prot. pfc4%lgl6mLilly to pg. sififth 111119nit" list
4 tho prcw*" of sit"Otutp flit"W04"; Thew. too-vit art
gnalkril only In V*ry IhN 6.11%, ther det'll-p-ir *4~11 hi'l-.1
In% thicluirss. atul ore unobservAoir with thirk billi, 4 04
onfa el 2 inim. Tb* ltrepence of an hildbiltv Jino MfUtO
(he ffficts' with 0-41-4079 no
Chan!; In the merb. privertki was obsinvvi eitr4 after 116
firs. nannizatkin, The astiCiijbil-it" f
an indicative 4 a chain nature cit the pwriIi. '.4f. Thim
Altstatten ot she mtthmiakAl peopectles of sofloot4utes-
clients rubber causedbylitiftf. Y"' Koo?'.,
nsinskif. Ke4ra. Zhup. Is. uw~-I~jRMO; e. C..4. 43,
ruNwr (1) filins. ahootllf.~)l
thicle, *we exteakiftl W londs *Ukh ditsirdwited *Wo 1hr
films dreethed 10 that thereat Or"t rMflabstrd 4.44184. 1..g
to - defortruthlett inerress"I Iffintfly'"llh ll)c I to 4 little)
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when this "tied from 21113 to 11M, 4,111, fluill"1411-Scild 1
I X jarpi Is J*Iural) sorwrMl In 11,M11 0
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It
Ior to 100 OR twile") alits the iloll it W111
el.x.e it- a%% ("fill of chwicig (81) team 10 ta:1.4 A esq.
cos.). Intercrprino cA 11C t shotter Than 211117 A, fry illgawsq
screell retard"I the* thilmr; r X.. In 0.111
ftattvirl r.".to3OXlOt. Adtls.s~l%
jIheIIYWMMph1hVIAoII*C MATAICII site C114till" III f0i'lietill.
Mt he Outne C.WIM alverferatm tbrill Ill filght > L ibi.if thil.
?I Ifer I ht. was 11A) X $0l 4,14 M x stir, S"p., All all
IfliV &M 41V!aT*'CIl 4nd then 11KIM'id (10dog
Illumination.
q
**,a of gi6m buck Am cbe scalm ad raw am nober.
val- S~Zmww.- D*Alay Abed. Vamk SASA U
93"
rate of Okmotwo of bum4k
b" at cow. temp. (25, vedirt ,
m waVA.
~. tell-
at -11 MIN Is imucaft vokmatma Musalusiko; mearv
lbe.iu~c;;;7k~ C black (1). With
OWN rM
1
ve of cl
4
10 diganoti= b
&w" the p4
or abwwe W NOt but with 1
Mmvimtim hicream tk rate Co
id
bl
~F Vb"d(Y 060
Pt"A 1 the
'
'
61 t1w
~ rubk
ns
era
y. .
w effect al
~lillvotfpsdfic: l%o(dwdy*3udanblmckjuB%t)4rvbb*r
"
T,
S
Y
'A a Jim) fklu 14h,
k' ~'h 4o **lk4Jt prod"
I Sad
kw
a
2% im polybuladimm rabber we am I imorike
them L
Tbm le w "pk relaiiam b"m
the seat. of I r"ONNI'T.; (In'lor 'm
1-b 1
y -tyk f0f
1
U14" llwalmak
~
" of
mporporated (03-23%) and tk
kierfaff of the Awoo". . ski Mo
n N" the -Tate 4 el
1
ll~
cvl, 1`11
4 01 7VP Xbmm 71)6
I. la.
".
lmA d". bidimew that tktk &"i*a is 0 w
On of klit and mot with a a
of OW
Me
b
ahwav.
l
M
.0 lm or tl* j"
. 2tat.
th"! rikosit by
N
.
N
y
~Ti& vkwp(Wnt Is borm cut by On obsevratimit
,twommis iflumi"Atka aaaw a INUOW solm. of I o
m
t
o,
lhat con.
r ad Mwk . Thou
ska. We" do" rather, thall somferafts tu ~a~dmm of
Aw ablim - The cgwt of am k6t is tbu dw to its
allaorp.
tim bY the I or tbe black dye is an mbbar. Th
PW sedy for Iftankeallm with mw ultraviolet
h kht Alte
d
h ra is uw
W Also i
re
t
romo a 0.1 N joW of FgC&. trum.
imildra wow kagdo over 4W A., ubkb an absorbed by I-
Ob Ight bee an aim only on mbbw Ahm positc. L 1;
demetrust to N I dome Awkg dm
-7 caromm to MoM is hwilecdve.
USSR/Chemical Technology. Chemical ?roducts~and 1-22
Their Applicatioil--Crude rubber, natural and
synthetic. Vulcanized rubber.
Alls Jour: Ref Zhur-Khimlya, 1,10 3, 1957, 9786:1~
Author ZuYev. Yu. S. and Kuzlminslciy, A.
Inst To Given
Title On the AGing of Vtilcanized Rubber,U!prler~Atmospheric
Conditions
Orig Pub: Sb.: Stareniye i utoml,eniye kauchukov i rezin i~
povyshenye ikh stoylcostl, LeningrAdi, OodIchIml zdat
1955~ 157-1-84
Abstract: See also RZhKhim, 1955, 35967
Card 1/1
---------------------- ------------------------------------------ --------------- .... . ....
Category: VOWIMMMistrY Of H1gh-YIO100U1*r;Su'#tAdCMs r
Abe JoUrl RifeliLt Maxi~ftUdji,~ N-6 ~911-119~ 5t, 161' k
902
Author Zuy" Yu, SO'-
last :'AagwUrTf-Mences USU
Title PhotovulcanizatIon, of
Rubber and
OrIt Pub: Dok!'.*AWSSSO,-~~�560 ~Ii6 16! i 1161 '64
I of fi~
Abstract; On Irradiatica Of,~UtA J~b ii
weight 49,0001 U41411ritl6a C06i1#09
!too
means of a MwT IMT) a, pyrox guso 1, ght rutez *Ud
distilled vater, there ~ I's ~observM f 9~ ''an:
row ex t ~Ii;~M
cl~~ in,o 8~,,Jltb durs"r
Of PhotO_WlCaniZ^tie
~n as Conce
tion. of illumination and dwage in tate of jphb vdization i
with concentration of S. Occurence Of an op
~tribUteA
to increasing intensity of destr~qtion ad's. or Ine"ased
liot absorptiou'and Idecreasing liten Iilty,of I i IrUCtii*bi0,n as
c
a result of decrease hi coheentraticni of free. ' 043 iizwuation~
e
of photovulmlzate,- e v with-if, -t hAered thru
UP- to th Otim I ~ I !~
Card 1/3 -13-
................... ....... ......
:116
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... . . . . . - - - - - - - -
Categor7: MR/chemistry or High-molecuiar Substancem
Abs Jour: Referat Zhur-Khimiya, No 9, 195T., 30902
rubber on an increase of concentration froiO-5 to 2,5% and
change in modulus at the optim=, depending~upon concentration
according to a curve showing a zoaximm.
-15-
Card 3/3
..................................................... ............ ------ ....................
ZUYEV,,-Yu.
USSAIChemistry - Rubber
"The Disintegration of Stretched Rubber Under the Influence oflozonevo Yu., So
Zuyev, 4.S. Kuzlminakiy, Sci-Res Inst of Rubber Industry,:
DAN SSSR, Vol 89., No 2,, PP 325-328
Investigated surface cracking of rubber when Stretched in an atm containing a'!
small amount of ozone. The rubbers investigated were SM (polybutadiene)l MLS-30
(Divinyletyrene), SKN-26 (divinylnitrilacrylic)p and NXII(natuial rubber)'.! The 3
conditions apparently necessary for cracks to appear on~rubber as a result of1the
action of ozone are: (1) presence of centers of reactivity it the rubbor~(doubie
bonds), (2) the presence of definite, directed stresses'jstretabing but no com-
pression), and (3) specific nature of the chemical reacLion bo,tween the rubbeT
and the ozonev leading to a rapture of hydrocarbon chalto with Cormation of an
inelastic surface film if solid ozonides are present &M chariteterized bythel
(over)
ZUIJ6VP IU* 00
USSR/ChMISUI - -Vulcanize~rs :2 ~3
"Some Ch4racteristids of ..the Light-Agini~of -Vaca'-i
.~ t_ 1
nizers,'~4'u. s. iuyev an6-_-4. S. Kuz'minSItIijj,:-:~,!A
Res Inst of the Rubber Industry
DAN SSSR, Vol,90, No 6, pp~ lo63.lo66
Studied the effect of phen~I-Pwnaphthyllaihine on
the light-aging of vulcanilzerb at differiti'mt tehrj~s I
different concs of (1~ and with the intr6ductibii of
light-filtering substancei. At 250 (1) 4~nsitii~es:
the vulcanizer to lIght, but at 800 senj$441za~W4;
by I decreases. Raising the concn qf 1,~ieesuliitd, in
,the sensitizing actior -pa Isuing' through'i a mix :
_i__L:26qa
Addition of a light-filtering substance,,ICGpeq,i& 9ity
~carbon blick, has a4trabi effobet 6a tbeil,OelOldki..~
heaj.117 . e:! i
ship between aging by light, and by Preol stod
-by Acad P-A-Rebinder.21-APr 53,
a cat .-tins"
Ii-el
m 096
Prot4dida mbber fm
Ik". 17'suk V.S,S~ 90" V.
to 'I of (1311k,
t1flat 11111111t Ito 4111110 1 Pro "il
froll, dusl6cilyd III)II Its I t. ft
t 41jewm'd
ut hat Old Oat tell I I III iih1wth it 11toilt kit (110
(lot !I
o
action of n, a 11111tv
a r r*
am pi, -ooll & 1244 OtAbulm
3,
rnttbbtr agulust 1 11. l, tnictioll, Ili doco t illf br hot
2 CS
tor It 0." 1' it atter
Chaill, teagellta
effect is tc;lnpnmrr and (114appim's !it -3 days (after'
difluslon of tho swoffillff agent Int~ the 1.114
esm A a
ru)IT I
ZUMT, YU, AIM RATNE R, S. B.
Application of Fechanical. Models for the Investigation Of C~Aqs,,eo in the
Structure of Rubbers and Resins
The authors enumerate the equilibrium and kinotio constants Ohich
make possible a description of the highly elastic propertie6~of high
polymers, They describe mechanical models used for vinal presentatim
of the deformation processes of high polymers. They give e."les of
the application of these models in the quantitative determLnAtion of the
above-mentioned constants for several different types or rubber. (RZh-
Nekh, No. 6. 1955) Tr- n-t- In-ta Razinm= Prrffn-StjI' No. It 1954, 32-524,
SO: Sum. 110. 744, 8 Dee 55 Supplementary Survey of Sovlet;&~iontific
Abstracts (17)
;- '? 1- 1 1 It -
U:35H/
Card 1/1 : Pub. 50-24/25
Author : Yu. S. ZuYev
Title A new rubber-3.ike polymer synthesized on the basis of polyethylene
(Review of foreign publications)
Periodical Xhim. prom., No 8, pp 503-6 (55-58), Dee 1954
Abstract Reviews foreign work on the preparation, pioperb,les, and uses ot the
1
elastomers obtained by treating polyethylelie with sulfur diaxidei. and
chlorine or with sulfuryl chloride. Twenty seven referenc4o, 2 of
them USSR (both since 1040).
Institution
Submitted
.90V/81-59-9-33456
Translation from: Referativnyy zhurnal. Xhimiya, 1959, Nr P 50 (USSR)
AUTHORS: Zuyev, Yu.S., Kuzlminskly, A.S.,'.Postovskaya,'.A.F.
TITLE: Some Peculiarities of the Light Ag:~j Of Rubbibrs~'and~VUaanizateil
PERIODICAL: Tr. N.-i. in-ta rezin. prom-sti,1956, Mr 3, pp 102 113
ABSTRACT: The action of light on rubber ditfers from thd~action of'a high
temperature. In the action of light on vulcaniZatesiVie role of~the:
optical properties of ingredients is obsential,'lit id necessary~theri-
fore to separate the optical and chemical actlo4 of the age reslitort
for establishing an interconnection between t141chemical structu-,~e of
these substances and their chemical light-prot 'eotive'aotion. Some
age resistors and dyestuffs cause a photosensitization in the
vuloanizates. The suppression of the SenSitizihg actica and the'
manifestation of the efficiency of the sensitivors can be obtained
using vigorously light-absorbing ingredients.
V. Glagolev
Card 1/1
Translation from: Referativnyy zhurnal. Xhimlyao 1959, Nr 9,IiP 563 (USSR)
AUTHORS: Zuyev, Yu.S., Pravednikova, S.I.:
TITLE: A Method for Objective Determining the Kinetics!; of QZ'M'2 ackiix~
of Rubbers
PERIODICAL: Tr. N.-i. in-ta resin, pr2q-_sti, 1956, Nr 3, PO~ 1,14 1.22
ABSTRACT: The degree of ozone cracking of rubbers In cliaritterizad by a decrease
in the nominal equilibrium tension in the ssnpi~4 duAng their oioniia-
tion, which is conneoted,with macroscopic chang ibs in~,a limited Z~ne 6f
the sample. The entire kineticsbf the processils deterrained an~onel
sample and the tension measurements are carriediout vithout takib
~g it
from the testing chamber. A device for determining the kinatical,of the
widening of the cracks has been described, Theil~design of the dey~lcei
permits the tension to be exactly measured on eirery oanple. Exorimental
data obtained on the device are cited. Using1he redults of theiperiodic
determination of the nominal tension, the averag~e effioient. depth of;the
cracks and their growth rate are calculated.
Card 1/1 V. Glagolev
947
.AUTHORS: Kuzfminskiy, A.S., Lezhnev, N.N., Zuyev Yu4S.
TITLE: Oxidation of Natural and VUlcanized Rubbers (Okisleniye
kauchukov I rezin)
PUB.DATA: GoBudarBtvennoye nauchno-tekhnichei3koye lzdatellstva
khimicheskoy literatury, Moscow, 1957, 319 pp.,
5,000 copies
ORIG.AGENCY: None given
EDITOR6: Babushkina, S.I.; Tech. Ed.1 LtWly~o M.S.~
PURPOSE; The monograph is intended for scientific and engineering
personnel of the rubber industry,.and for specialists
in allied fields of chemical techholog:~.
Card 1/20
Call Nr: AP 1154947
-Oxidation of Natural and Vulcanized Rubbers (Coht.)
COVERAGEz The book discusses aging or natural~6d vixIcanized tubbers
! h6ical
caused by oxygen, ozone., high temperdture; light, Mee
stress and catalysts. Methods of studying aging and pi~even-
tion of aging are reviewed. Personal~tiea mentioned include:
Angert, L.G., Belitakaya, R.M.,, Degte*va, T.G., Lyubdhan-
skaya, L.I., Mayzells, M.G., Peschans'kaya, R.Ya... ftpova, Ye.13.,
Postovskaya, A.F., Xhitrova, N.0t, Shomastina, Ye.Vij
Shokhin, N.A., Shanin, L.L.,, Kargin,' ~.A., Medvedev) S.S.J.
Dogadkin, B.A., Dblgoploskiy, B.A., Rabinder, P.A
SlonViskly, G.L., Bartenev, G.M., AbkLn, A.D., R:;4!--
linger, B.A. There are 42 references; 19 USSRs 20 gnglish,
2 Geman, 1 French. There is a biblIpgraphy at the;end
of each chapter.
Card 2/10
Call Nr: AF 1154947
Oxidation of Natural and Vulcanized Rubbors (Cont.)
TABLE OF CONTFMS
Preface 5
Introduction T
Bibliography
Ch. I Thermal Oxidation of Natural and Vulcanized
Rubbers 13
1. General considerations
13
2. Effect of high temperature on natural d
vulcanized rubbers 22
Card 3/10
Call Nr: AF 1154947
.Oxidation of Natural and Vulcanized Rubbers (Cont.)
3. Structure of'natural rubbers and their reactivity
to oxygen' 28
4. Free (autocatalytic) oxidatiolk Wi. &kCXt.%"1:CS1
iubber
35
5. Oxidation of natural rubber in soluti0l).3 53,
6. Oxidation of natural rubbem in the premence'of
antioxidants
55,
7. Oxidation of natural rubbers in the presence
of various Ingredients of vulcanized rubber
mixtures 76~
8. Oxidation of vulcanized rubbera 89,
9. Catalytio oxidation of natural rubberg under
the action of metals ofalternate valency 1001,
Card 4/10
C 11 11
:,t.i r AF 1151~947
Oxidation of Natural and Vulcanized Rubbers (Con
10. Action of various oxift-ers on natural rubber
Bibliography :113
Ch. II Aging of Natural and Vulcanized Rubbers by Air .118
(Aging by Light)
1. General considerations 118
2. Oxidation by light 125
3. Effect of light on various natural rUbbers 142
4. Role of rubber-mixture ingredients i~ the action
of light on natural and vulcanized rubbers 145
Card 5/10
roall on
Nr: AF 1154947
Oxidation of Natural and Vulcanized Rubbers (Cont.)
5- Protection of vulcanized rubbers from,the effect of
light 153
Bibliography 163
Ch. III A
ging of Natural and Vulcanized Rubbers by,
Air
(Effect of Ozone and Light and Ozone) 168
1. aeneral aDnaiderations J68
2. Effect of ozone on -undeformed natuft.1 and vulcanized
rubber ~171
3. Effect of ozone on deformed vulcanlzOd rub ber
4. Structure of natural rubber, its chemIcal resistance
to ozone and cracking ozone ~180
Card 6/ 10
W&
1 rj
Call Nr: AF 1154947
Oxidation of Natural and Vulcanized Rubbers (Cont.)
5. The role of some ingredients in craWdng of rubber
by ozone 183
6. Combined action of light and ozone on.vulcanized
rubber 186
7. 'Increase of vulcanized rubber resist ahae to cracking
by ozone 193
Bibliopranhv 200,
Call Nr: AP 11511947
Oxidation of Natural and Vulcanized Rubbers (Cont.)
Ch. V Oxidation of Natdral and VulcanIzed Rubber b3r
oxygen During Technological Treatment 219
1. The role of oxygen in the rolling of natural rubbers 219
2. Oxidizing processes in the vulcanizatIon ot natural
226
rubber
3. The role of oxygen in reclaiming rubbor 223
4. Effect of the chemical nature of solv4wts on the
oxidizing destruction of the swelled vulcanizates. 235
Bibliography 248
Card 8/10
,C,all:Nr#. AF 1154957
Oxidation of Natural and Wleanized Rubbers (Cont.)
Ch. VI Methods of Testing the Aging of Natural and
Vulcanized Rubbers 250~~
1. Chemical methods of testing 251i
2. Mechanical methods of testing 260,
3. Methods of accelerating aging of rubber t 27&
Bibliography 29k
Card 9/10
Call Nr: AF 115495T
Oxidation of Natural and Vulcanized Tubbers (CO;nt.)
Ch. VII Oxygen Diffusl~~.. 4"Id Solubility in Natural and
Vulcanized Rubbers !2981
1. Oxygen solubility in natural and vuld4aniz6d
rubbers
2.98
2. Oxygen diffusion in natural and vulcanized
rubbers
3. Solubility of ingredients in rubbera~ 310'
4. Oxygen diffusion and kinetics of rubber
oxidation 314:
Bibliography
AVAILABLE: Library of Congress
Card 10/10
ZUTWO Yu.S,-, BORSHCHITSKATA, A.Z.
(Methods for protecting rubber goods fromj.Q'HonCor&*kln9j X4*odlr
vashchity razinovkh Isdelti ot ozonuogo r~ptrejk~,vsnlisis Xpwkvitt 1957.
39 P, (Mascow, Nauohno-isaledovatellskil inatitut resinoTot
promy,shlennosti. Obzory, no 1) 157o OURL 11:7)
(Rubber goods)
ZUYICT, YU*S#
Modernizing the apparatus for light and ozone''aging:of rubbers
Kauch. i rez. 16 no*6:34-36 Js 157, (MIR& 10:10)
I.Nauchno-issledovatellskiy inatitut resinovb.V promVehlennosti.,
(Rubber) (Ozone) (Photochemistry)
--7777TI17-77~jj-j
'77-1 - -11 -V 77. T
66A&A "I"HA 14 11111P1111 11111,111AIIIII'll W! I'llil! 1: Ailhf fP: il: 0 1 1 1:01
AVMRS
TITLE:
PERIODICAL:
ABSTRACTt
Gard 1/2
ZUYevP YU.S., Pravednikova, 8.1. 76-11-33/35
On the Article by N.H. Znamenskil, "On the Kinetics of the lvkter-~
aotion Between Ozone and Rubbee (Po povodt't a tat' i X.N.Uamenskogo
"K voprosu o kinetike visalm eystviya osoul a resinoy")
Zhurnal Pixicheskoy Khimii, 1957, VOL 31 Nr i i pp. 2586-2588
(USSR)
The artiole is critioised, and faults are Pointod.out one by one
and dealt with in fom of a su=ary,-: it is cont#nbed that
Znamenskiy's method for an accurate investigation of the kinetics
of bursting under the influence of ozone is noV to be used in
practice, that it is too oomplicated for man a -experiments, and
that it is not provided with the neoessary.equipment and device 'a.
For these purposes it is necessary to employ methods in which,
during the test, the deformation, the aver Yalue of tension,
sm4 other faotorn remain constant [Ref., V . There are 3 fig-
ures and 14 references, 1i of whioh are 3174-iop.
76-1i-33/35
On the Artiole by N.N.Znamenskiy "On the Kinetic* of the Interaction Between'
Ozone and Rubber
ASSOOIATIM Mosoow Institute for the Rubber Industry (Institut resinovoy
prmyahlennonti, Moskya)
StOlaTTEDs November 3. 1956
AMIABLE: Library of Congress
Card 2/2
&)
AUTHORS: Zuyevp- Yu, got Pravednlkovap S. Io
TITLE; Influence of the Degree of Defor"tion on the For~mation
of Cracks in Rubber Caused by Ozone,I(Myliviye steperii
deformataii na osonnoys rastres%iviOye V.40in).
PMODICAL: Doklady AN SSSRg 19571 Vol- 116, It 5# pP. e13-a16:(vssi)
ABSTRACT: At first several previous works ammentioned. The.authoirs
investigated in detail the influonte mentioned in the title
of this work and calculated the vel6 city,'of growth of the
cracks by means of an objective method (reference 0) from
the effective depth of the cracks. The kinds of rubber
investigated are mentioned, This in~ostigation showed the
following:
1.) With all coutchoues a qualitatively equal de9endende
of the time passing till the fo~aation of craok~ on the
intensity of deformation is obdoryad'-With grcwing~
:
deformation this time gradually deerleases.to zero.,
2#) The velocity of growth found for the steady range of
the kinetic curve~initially iriOeasea with grolling,~
deformation, passes a maximum -within the rangelof small
Card 1/3 deformations 6nd then decreases again. With all couitchoucs,
Influence of the Degree of Deformation on the Pormation 20.,5-26/48
of Cracks in Rubber Caused by Ozone,
and independent from their characteristio$.the period passing
till the crack occurs pasees a minim~tm within the range of
critical deformation and a maximum withiwthe range of great
deformations if there i's a change of the deformation within
the range of critical deformation. The re6ults obtained
show the following:
1.) The strength of the rubbers in-the cane of multiple
regularities obeys to the same regularity as with the
formation of cracks by ozone. With all rubbers we observe
a minimum of strength too. The destruction (formation
of cracks) of deformed rubber b$means.of chemical
interaction with ozone develops analogously with tht
procese of static fatigue altho4h the velocities ot
these processes differ by many:o,rders..From this
follows the principal possibility of the accelerated
investigation of the static fatigue of rubber,
especially within the range of4mall deformations, by
means of the formation of cracks depi6ndent on ozone*
2.) Very small nominal deformations~lof the order of 10'%)
change the degree of orientati64 of otructural units
Card 2/3 at the end of the cracks. A cenflAtive Indicator'of
Influence of the Degree of Deformation on the 20-5-26/48
Formation of Cracks in Rubber Caused by Ozone*
these changes is the resistance of rubberlagainst destruction
in ozone. This phenomenon can prinoipally'Ae used as basic
for the investigation of the orientation of rubber. There
are 4 figureev I table, and 11 references, 5 of which area
Slavio.
ASSOCIATION: Scientific Rosearch Institute of Rubber iftaustry (Nauohno-v
isoledovatellskiy institut rezinovoy prom:rohlelinosti).
PRESENTED: June 6, 19579 by P. A* Rebinder. Academician
SUBMITTED: November 229 1957.
AVAILABLE: Library of Congress
Card 3/3
Ve,
AUTHORS: Malofopvskaya, V. F. It Zuyev, Yu, 04 62B-2-a/3
TITIM Elastomor Kel-F and Soi~e~~h~Ffho4pror :us-Contajning~
Polymers.' (Elastomer Xel-P i nekofo:L77e, drugi-ye
ftorsoderzhashohiye pollmery),
PERIODICAL: Kauchuk i RezinA 1958 11r. 2. pp. 55 :40. (USSR)
A
ABSTRACT:' This literature review article coVers th~ prepardtions
vulcanisation and properties as well as uses of~lel-P
and other phosbhorus-containing polymets. Thereiare-
24 Referencesp 113 English, 1 GerataA and 10 Russian.
AVAILABLE-. Library of Congress.
Card 1/1 1. Elastomers-Prepaxation. 2. Elastomars4roOrties 3. Blast~wrz-
Test results 4. Polymers-Preparation :6. Polymers-Propertiin
6. Polymers-Test results 7. vulcaniz&tion So Phosphoirous-~
Applications
USCOkSt-DC-54712
.8.ov/138-58-9 "/ll
AUTHORS: Zuyev, Yu. 8; Parshina, Ye. A; Gridunoli, 1. 'Fv
TITLLP-. Vleth-o-d-o-f-A'ecelerated Ageing' of Filbbei-4Ioated M4Iterials
(Metodika uskorennoeo s areniya prl'orezinennykh mtxtedy)
PERIODICAL: Kauchuk i Rezina 1958 Nr 9
pp 27 - $2 (TJSSR)
.
ABSTRACT Under atmospheric condNions, agettid o:t rubber arti6les
is due to ozone and light. It cano tharefore, be assumod
that aeeinp~ of rubber coated fabrics and fibres Would lie
caused by the same factors. Few results. of t e s: t a
on the effect of ozone on rubber coated fibres h4ve;ibep-o
i
published so far, and the authors Inveatleal-,ed the 6f:fL
bg On t",.-e
of ozone and light and the character of L-ensionl
,
ageir of these materials& They also :found a method of
i
tative evaluation of the eMciewy of rubber,
quant
coated materials,
The efficiency.was evaltiated by e6tima1;i1n_r the ViAter-per-
meability. The tested materirAls'differed accorAnc~to
the types of rubbers employed (la 14nd 12,B), and aiso-accv--
ding- to the composition of the eadeous la7er (la,2a ~M,
2aA, 2aDE). The action of ozone ahd t1le siinultsthec6s
interaotion of ozone and libht on litateftal la, oubjdoteel
card 1/4 to stretching along the vrarp, (100 lce/m) and aloTit,, tl-iq
Method of Accele Mted Ageing of Rubber-Coated 1haterials.
Card 2/4
weft (50 Ice/m) Is shown in Table.l. The gas-pertneability
of the rubber-coated material 2a durInM ageing under the
influence of various tensioning under atmospheric con-
ditions Is given in a graph (Fig-la). ~These results indi-
cate that an increase in the two-dimentional tenaiohing.
causes a decrease in the ageing atability of" th6~rubber-
coated materials. Fig.2-. chanpes In the gas-permeability
of material la during ageing under. atmospheric conditions
when 1- and 2-dimensional tensioning is applied'. It can
be observed that under the action of two-dimensional ten-
sioning the material ages much faiter than when one-
dimensional tensioning is applied.' The effect of tension-
Ing on the rate of agelnLj of mrAtarlials:la and 2a;under
accelerated lie-ht-ozoneoCeing, Whan concentration
of ozone equals 1 x lo-*-'P for material!la and 1 X 1 -2cf
0
for material 2a, is given in Figf. '3. The rate of ageinC
depends to a considerable Iextent jh the intensity of
sunlight radiation. The unit of lpquilralent summer',days
(ELS) was adopted. The coefficients depending on the
magnitude of sunlight radiation were d6fined by experi-
ments (Fiss. 4 and 5). The concentrati.on of the,,atmos-
pheric ozone is considerably lower In the inner layer
Method of Accelerated Ageing of Rubber-Coated Vate,~ials
of the rubber than in the surround#ig atmosphere4 This
Is to be taken into account when evaluqtinuq the efflo-
Lency of the rubber-coated materials (216,,s. 6 -8).~
The aCeing stability of rubber-coated materials,to aGe-
ing under atmospheric conditions,' was quantitatively
estimated at 5000, and the Intensity of -the light Yras
approximately twice that of sunlight. 1he testsAiere
carried out at room temperature (F~rjs. 9 and 10)., The
requL ed concentration of ozone Wa
10_7,,~rf g found to be 3.7 x
or material la and 1 x 10- fot lpaterlal~,2a.~
Comparative~results of accelerated and:natural aceing
of various rubber-coated materials~ are tabulated! (Table
Card 3/4 2). This method can also be used in industryo There
Method of Accelerated AgelvZ of 1kibber-Coated1laterials
are 2 Tables, 10 Figuro.3 and 8 Retelreno~a', 1Enclish,
and 5 Soviet.
ASSOCIATIOII%Nauchno-issledovatel'skiy instittik rezinWrov
shlennosti (scientific' Rese'arch Ing~tituteiof them 'Rubber
Industry)
Card 4/4
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AUTHORS: Zuyevp Yu. 1~ravednlkovri, *MN/76-52-7-3/45
TITLE r.-.c'&ing of
A Kinatia Study of LI!16 OL'Une 1,
Rubber (Iaz1c,iu.-un1jQ Vln~,~tiki ozoano o rozin)
PERIODICAL: Zhurnal fizicheukoy.k)imiit 19501~ Vol 32, qr 7, Tr.- 1457-1465
(Usca)
ABSTRACT; Rubber beingin the state Of tenulon in the presui. ce of ozone
is subjected to cracking. A syat~!nnt1c'.ihvesti6ation of the
kinetics of. this process does not 1,exist .il th the ~ exception
of a few papers denline w ith this~
subjett,,anongthem'those
l
of Buckley and Robison (Ref 7), 01 aell~aa I.I.Y."11nanionaiiy (Ref 8).
The present investigations were c0rledlout according',to a
now method, which is chnracterized~by a:rc-duction. of the
stress which causes the conrAunt d~pformaition of the sample
at the occurrence of cracka and their inlcrcase."The ki~~et-ics
of the increasing of*the cracking' lajer:,car. be. calaulated ac-
cording to this decre4se, as can the proportional Value of
the mean effective depth of the ctb~ck. in'the inved tigi~'tionn
the authors used an apparatua which'~ made' it possible to carry
Ivith 10 zam,)Iee during
out periodical stress meaeurerrents
Card 1/4 ozonization without chanaing the extent;of deformation and
!107/76-32'-7-3/45
A Ydnatic Study of the Ozone Crackine of Mbber
the concentration of ozone. The kinetic curves of i6e increase
of the cracks according to the cro's'M' section of the;sam IPle
may be divided into 4 sections: The~~indudtlon period within
which no visible decrastse of the utileo:7 tates placs4~ Thu sec-
tion in which the valo6ity of thf.- growthpf cracks increases
continuously. The stea4y section whiiPh in'aharacte~ized~by
a constant velocity of the increase-of the cracks, "d final-
ly the rapid rupture of the eamplc.~ Tt was observed that the
stages of the second and third secti6t% last. lonecvt,,,', and. that
of the last shortest. i comiari:Bon Pf tho e ;tp4primen.~ ill 411tik
for the purpose of tnvv41t19t,-t1ntr 041';O~ouk~~,Tm 3hot~,A that' also
In nahbor whiolt containi no oton%) PrAoct iog, rubs tane,e a,re-
tardation, as in polymethyl methucryli.Aez in found 'An the
case of ozone cracking. The obvervLti6tn =,de in the oxp6ri-
mento on the influence exerted by the ~thicknese of the sample
on the kinetics of the reaction are explai~ett by tha~tacV
that the process of ozone cracking ttkes plade gradually fn
the surface layer atid the openings oCIhe craicks. In,the 41x-
planations of the resulto obtained Vie"authors mention, that.
Card 2/4 the presence of the second,-Unateady.siction of the reaction
SOV/76-6~0'-7-3/45
r of the Ozone Cracking of Rubber
kinetics with a superstreso and its inc~easo in the, opvninga
of the cracks may be explained ac~4,r~iinj-to the ex'tent~~of
their depthl this is alao'explained~by the.different charac-
tV of the function of time taken uiltil ~' the occuiren~e
of cracks and the tlms~until the.cr6laking,- versus the de-
formation* The strong increaue of thq,vel6city of the process
after the third stage is explained b~ the'fAct thatAn the
undestroyed part of the,eample an acdumul~tion of inner de-
fects by the static fatigue proceed6,'~and that in th'Q~,Pen~a-
tration, of the crack to this part it t 'noreases r&pidly.
There are 5 figurest 3 tables, and 28 referencest 12 of which
are Soviet.
ASSOCIATION:
SUBMITTED:
Card 3/4
Inetitut rezinovoy
('14oscow Institute
January 121 1957
5W
AUTHOR:
SOV/76-32-10 13/39
TITLE: On the Separation of the Photochemical and Light Filtering'.
Effects, and on Latent Photosensitizati',on (0 razdelenii foto-
khimicheskogo i svetofilltruyushchego daystviya i o sktytox
fotosensibilizatsii)
PERIODICAL: Zhurnal fizicheskoy khimii, 1958, Vol 3 2, N~I10i pp 23d$-2314
(USSR)
ABSTRACT: The measurements were carried out by X,~ F. Shokhina. Investi-
gations of the type mentioned in the tittle had already~rbeen
carried out by B. A. Dogadkin (Ref 1) and Bo:ftdi (Ref 2). Of
late, detailed investigations have been carriad out by,'Yu.;S.
Zuyev and A. S. Kuzimiriskiy Nor 3) in ;,connection W ith:the;
characteristic feature of the light protecti'ne; effect~dlf di-
butyl and diethyl dithiocarbamates of nickel. The effoot or
these substances on the aging due to light action of the
vulcanizate M and of butyl rubber were inveatigated4;To de-
termine the intensity of the aging process t'hej kirietio4 of: the
change of the static modulus in the illumination of thin sample
Card 1/3 films was measured. The illumination was arranged by an; Hg:
sov,/76-32-10-13/39
On the Separation of the Photochemical and Light Filtering Bffects, and on
Latent Photosensitization
quartzlamp FM-2 through~a polyisobuty,lene -film. Twoiparallel
experiments were carried out: on the one hand the rubber film
with the substance to be investigated'(aaeo:~bent) was Irradiated
through a pure film of the light filter and on the other hand
a film of the pure rubber was irradiate~dl thr Iough a film of:the
light filter containing the substance,to belinveatigatod. The
measurements were carried'out taking inlto account certain 'Con-
ditions a little different from those,in the previous~paper
(Ref 3). According to the equations for the calculations mention-
ed it was found that an exact separation of -the light filtpring
and chemical effect can be obtained only with monochromatib
light. The observation made in an earlier p4por (Ref 4) th!at the
increase in concentration of.ZnO in the vulcanisate Sj:~ hainpers
a change in the static modulus of SKB in the case of ating~by
light is explained by a latent sensitization. Since alquanti-
tative separation of the light filterii~~g and chemical 6ffe6ts
has to be obtained for a direct deterininatidn of the liLten:t
sensitization the appropriate experimetits were carried.;out'. The
followine substances were introduced into s4~d_ium butadiene' rubber,
Card 2/3 and then were investigated: Nickel dibutyl dithiocarbartatel
SOV/76-3 2-10-~l 3/39:
On the*Separation of-the Photochemical and Light Filtering; Effectsp'find'on
Latent Photosensitization
-phe~yl-p-naphthylaminej and copper phthaloc atiate. Th3:illumi-
nation was carried out with monochromahic light of the:wave
lengths 365 and 578 mu. In illuminatinq the iSIEB and copper
phthalocyanate with a light of A - 365,4 it vas found that.cop-
per phthalocyanate exe~rted a latent seilaitization. There are
6 figures, 1 table, and 9 references, 8 of which are Soviet.
ASSOCIATION: Institut rezin Iovoy pkolnyshlennobt~,, Mos,kya (Institute of Rubber
Industry, Moscow)
SUBMITTED: ~MaY 4, -1957
SOV/138--~59-3-6/1r;)
AUTHOR: zuyevt Yu
of
TITM of Accelerated Lirht (Atmosphlo1105,460ing
High polymers K voprosu o metodaldi uskoxennogo
svetovogo (atmosfeniogo).stpenkya ~-yeokopolimero'7)'
FLRIODIGAL: Kauchuk i rezine., 195 Nr 31 pp 23 26
ABSTRACT: Ac. ce le rat, ed a6eing tests for polymergi aro in trio qa.tes~-
ories: either the daily or annual cyoles of conditions,
are. simulated, or one or several pait'icul4r factord:causine;
ageing are simulated in an intensive Ifomi. The relation-
ships found between time of a,&;eiag al~d intensity of a :1
given factor enable extrapolation t6i;be made to the value
of maxiTmim intensity of the agein(; f.~Ctor in natui~al !
conditions and at the most unfavouxable t-,biie of the ye,lar.
The "weatherometer" is an apparatut-~Avidely used for
artificial exposure testing. Samplefl; aro.(nTosed'to the
light of carbon are lampd at elevatea teRperatures . and
Card 1/4 are sprayed periodically with vrater.~ Also mercury.,-quartz
43 OV/1 ~8-59-:,5-6/~16
Yethods of Accelerated Idght (Atmospheric) Agol!,Lng #.High PIDIYM6rS
lamps are 0used, when the tempo rature can ;be varied7from
200 to SO 0 and the relative humidity from' 65~~ to, 100c,fl,
Different values are accepted fpr tho; enerl,:Zr fluxi of
natural sunlight varyinS from 43 to 49,2 Cal/cm'- or hou-ro
U!he amount of sunlight varies according to locali?y, and
for any given amount of sunlight ageing will vary~acc6rd-
ing to the as-z-ociated humidity and ul-Lra-violet content.
Among the exi_,~ing sources of light Only thEl krypte,)n-
xenon lamps give a radiation spectruk that is close tO
that of natural sunliGht, but these are dangerous: and'
difficult to use and have low power., ~ consequently, 6arbon
are and mercury tungsten lam s with 4orrecting light
filters are normally emplOY2 for we4therometers. Ageing
effects depend both upon the light so'urce and the optical
properties of the exposed material. 'The 'offect of'a dark
pigment may be completely reversed in' a weatherometer itest
under high intensity as compared with nat~u~ai e)TOSUMI
The heating effect throuSh absorptioU.by dark material
may cause rapid ageing under artificial conditions, whereas
the dark pigment would give protection from penetration
Gaid 2/4 of ultra-violet under natural conditions& As a general
M'7138_59_3~6/16
Methods cf Accelerated Light (AtmoBpberia) AE~Ing!of High Pdlyr4ers
rule a photochemical reaction -oroceeas at: aa rate proport-
ional to the square root of th7e light inbensity, and
usually reaches a maximum which doedi not 'olieng b .i fu
lotoj~sirther
increase of intensity, Photo-oxidatIon and P' V
may proceed simultaneously causing.ps e-Tolution and deg-
radation of the structure6 and increazed~light int6nsity
accelerates photolysis. sually Intbrrupted exposure
produces greater ageing effect than pquivalent coB~,iviou8
exposure o Increasing temperature inI the ranse 25 to! 80 C
produces disproportionately hiGher ;i~slit:agping ef:feet' in
rubbers than at temperatures of 100 and:morea Filevated
temperatures may produce lower lightt ageing effects oil
account of -decreased photosensitizatioa due to thel presenese
of anti-oxidants in rubbars. lftcrea~sing~hwaidity frotl 30
to 1001% R.H. is knoval to accelerate disc6louration of! dyes
ceverely and the effect of humidit on light ageing of
(;ard 3/4 rubbers Is probably bound up with Ne inTluonoe o;n th~4
SOV/1;O-59-3-6/16i
Methods of Accelerated Light (Atmospheric) Aj,~,,:--ing of ifigh,Polymers
photo-sensitivity of any colourint'jmattpt present. A
f annual lis 6s
table is,,Given for values o *it intensiti
(k-cal/cm" per year), relative humid.ity and avemge air
temperature for temperate, sub-trop'ical and tropical
climatps from which appropriate Darameters for a6~,eing
tests can be establi-s-hed. It is :Pound that there is
practically no light agein,,i; ef fect under Arctic ~ condit-
ions. The article conclud6s wlth:ilemarks on methods of
measuring changes in the propertioiDi of 1 r n a,ge ing,
includin, a change in reflqctivity~~n.nd ~osysmeofstdranspar-
ency at different wavelengths of light ;and a change in
physical and mechanical propertiez~ particularly ~st#ie
elastic modulus, which need not b6ila de,structivel,test,
It is suUgested thLt weathering toets shcjudl be ~xun 'at
constant lioit intenbity and that' -4 e mpe'rature, and humidity
factors should be varied. From th6':~ curves so obtained extr~L-
polation should be possible to any,~Eivea natural,condition.
Card 4/4 There is 1 table and 40 references 'of which 21 are Soviet
and 19 English.
ASSOCIATION: Nauchno-issledovatellsidy institut 3~ezinovoy:prom sh-
lennosti (Scientific Rase arch Institute f or the Rubber IndustM
5(4)p 15(9) SOV12 -124-3-34/671!
AUTHORS: Zuyev, Yu. 3.p Borshchevskaya, A.A.
TITLE: 09-fh-e Static Fatig" of Some Defoknied MAtarials inliuorrosive
Cracking (0 diitallnoy.prochnonti n(j'kotoiykh deform'irov~nnykh
materialov pri ikh korrozionnom rah~raskivanii)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, V61124, Rr 3, W] 13416 (USSR
ABSTRACT: Reference is made to earlier papersi'd Iealing with this sulb-
discloes fiew camp!$ of the
ject. The present paper intends to.
'
xniine the~influ'ence
corrosive cracking of rubbers and to date
exercised by the chemical aotivity.o,t the:aggressivd agdint
upon this process. Analysis of experimental resultd~Ahois
that cracking of the various typso o~ rubber occure.whenever
distinctly marked destructive proc6elttles o~ the spade lattice
elements develop in connection with interaction with th4 ag-
gressive agent. Several photographo,113how Ahe outer~appearance
of rubbers after corrosive cracking in various media
(nitrogen-oxide, HC1, JINO NaOll, 0
1, CH 000H). First, the
'
,
3
3
influence exercised by deformation &lid by~the concentration
of the aggresgive agent upon phonomeza occurring before
i
Card 1/3 ssen'~of rubber tinder
ing in dealt with. The cracking proce
SOV/1110-124-3-314/67
On the Static Fatigue of Some Deformed Materials in Corrosive Cral-Aing
the influence of various aggTognive pedia~a:re almilai to
one another. Experimental results alolo inilicate common ~:
regularities in corrosive cracking aid in:the statio.fatigue
of rubbers, metalat and other substatoes.iThe next p6rt'of
the paper deals with the disooaiatiort constant of acids:
The reduction of time elapsing untU~Idracking of the~isamples
occurs Is undoubted4--a sign that the~,rateiof corrosive crack-
ing increases with an increase of the concentration of the
acids. For the purpose of explaining the part played;by
adsorption, corrosive cracking was investigatod also in
aqueous solutions of inorganic aoida~~(iicl~' an ), in.aqueoua
and alcoholic solutions of fatty acids of the Aomogeaeous
serieeg as well as in vapors of acidi. Acceleration of the
cracking process can be'oxplained only by.lucreased idsorp-
tion of acids on the rubber and by the hereby caused decrease
of strength. In conclusion, the relative influence exercised
by the concentration of the acids anA their adsorption
capacity (wetting capacity) is discuised.Vhe rate of corrosive
cracking of rubbers depends on the tension and concentration
of the aggressive mediumt and2 besidesp on ~he actiyi,ty 'and
Card 2/3 the adsorption capacity of the aggre~aor. There arei3 fi8'Ue1j1
bOV/2o;-,l 24-3-34/10
On the Static Fatigue of Some Deformed Materials in Corriosive Crackin~
8
1 table, and 20 references, 17 of vhib~h are Soviet
ASSOCIATION: Nauchno-isoledovatellskiy institut rez.inovby promyshlennbsti
(scientific Research Institute of tbe'Rubb6r Industry)
PRESENTED: September 26, 1958, by P. A. Rebinder"o Acaaemician
SUBMITTED: September 4p 1958
Card 313
0/08IJ61/000/01~/021/028
B117/B203I
AUTHORSs Zuyev, Yu. S., Pravednikova,
S. 1.
TITLEt Effect of ozone concentration on crackineiso of
iubbers
PERIODICALt R ferativnyy zhurnal. Xhimiya, no. 13j ip6i, 652, ab tract
1;9330 (Tr. N.-i. in-ta rezin. prom-atip ob, 6, 196o,63.15)
TM t The authors studied the crackiness of rubber from NC-30 (SKS-30)
and nairit as dependent on the ozone concentration ovii a wIde range of
deformations.. They determined the time bafori-orackinvroo!the growth
rate of craoks.on a steady section V, and the time of full destruction,of
the specimen 'r . The dependence of T- and V on'the coilcentration* of
1 0
0 (a) has the form log V. log K - n log a, where K and n are coefficients
3
dependent on the deformition Wi n-I with exception of cracking of nairit
rubber at +60C and -80C. Under these oonditioneg n gr .ova 4 to 2-5!and
5-8. 'This is connected with the change in kinetics ofthe chemical
reaotion of 0 with the polymer at low temperature if :each process of
Card 1/2!
26881
S/081/61/00'0/01~/021/028
Effect of ozone concentration on ... B117/B203
destruction comprises a great numbor of Orooeeaes of:ih~teraction of0
with the polymer double bond. The dependence ofTo rC~, &n& V on 6 retains
the same character with a change of a between 0415 and.
iar~also independent of c. It is convenient to determine tha~relativi'
stability of various rubbers to cracking dependent on the ozone concentra-
tion for different F_ (if possible, for E(orit)), and to characterize it
by the values of c at which equal'r are attained for all rubbers,
rA-~straoterls notet Complete translation.7
LJLO
j:
card 2/2
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B117/B203
AUTHORt ZuY*vj Yu. S.
TIhEi Light-protooting aotion of some $aIts of aialkyl dithio
oarbamic,acids in rubbers
PERIODICALs Referativnyy zhurnal. Xhimiya, no 1961t 653 ab a t r acil
131033 (Tro N.-i. in-ta, rezin. proti, 6p:14o, 16-26)
TEM - The qging due to light of vulcanizates of CKS(srb) , CKC-30 (SKS! 30A),
HK(NK)j and butyl rubber containing dlethyl dithio carblimatoi(T) and di -
butyl dithio carbamate of Ni (11) was characterized by ~he rOlative change
of the conventional modulus (hardness coefficient). Th4 lig4tprotecting
action of antioxidants was determined by their cho.mioal'activity, their'
light-filtering capacity, and their solubility in rubbers. 1hen separating
the optical affect of antioxidants from the chemical ono, the author found
a strong chemical activity of dibutyl dithio carbamate 6f Znj lie comparid
with (II), and equal light-filtering capacity of (1)s (tt), and dimethyl
dithio carbamate of Ni (M)~. The decrease in light-protecting action in
the order (III)