SCIENTIFIC ABSTRACT YELYUTIN, V.P. - YELYUTIN, V.P.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001962620007-8
Release Decision:
RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
March 15, 2001
Sequence Number:
7
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
File:
Attachment | Size |
---|---|
CIA-RDP86-00513R001962620007-8.pdf | 5.31 MB |
Body:
ACC NRs Ap6o36839
structure. The results Indicate that the observed.higb resistivity of the alloys is
connected with the structure of the metastable y' phase and depends on the nature of,
the alloying elements. The necessary condition for obtaining the y' phase is quenchin
from the unstable 0 phase which exists In such alloys, The resistivity decreased as
a rule with increasing atomic number of the additive, and increased very strongly with
increasing atomic percentage of the additive, This report van presented by Acadenicii
G. V. Kurdyumoy 4 February 1966. Orig. art. has 1 3 figures and 2 tables*
SUB CODEt 200 U/ MEN DAMR: O3Feb66/. ORIG R17: -OOT/ OTH RM 005
Ccwd 2/2
-- - Iz- I..Vt z r-- E- - I 1,1!r r -t- I -
tC Lf 2- , -
F- 4
0 * 4 0 0 0 0 0 0 0
0 0 0 00000 0006ONNON 0-
$I it " as is ita 2 a 4 is As it aa is UU w 0 - 1) - 0 aa it m of of aa r
C LAU I.. v- L I a r . a a a I v I 1.1fl. -J, I it AA a (X 0a 6ad 6 11 4 a4 4 1 ~Vqo
%- 'It
MUM Of (eftocmo(Ybdenufn by the Silicuthtrmal
without use of electric futuAte.
Trkhmiki 1938, No. 1. 24~-7.-Cak-incd mulyh.
cmts. MOOj KIN). So~ (1,94, SO* 8.7 end FvO
.*A)4'7o. was rrduml by Fc~Si in thr prewntv ut Fe In a
A;xvi41 florns". Ife-Nio tAilainni in fhe Lab. exp1q.
'""fairml Sto C 11.11-o.13 arki .14 0.24-
1) A. A. I'mitmov
Coo
o0j coo
Ioew
00.4
see
*09 COO
P Ot
met
--oO
It
no*
sotl
am I Asa3 0
0U is a. -0 a tv at it a at K a Or a PC aIt it I
f o 0 0 0 a
e.0 0 4_0 0 0 0 4 0 & 06 4
0
o
of 0 0 * 0
If W
11
2 a Al it 0
WON& a At ft Jit It Ad
-L lal a -a A-6--A -A
*0
soil Ple4esdats of WWWWWOM trems toli, V. liltu
so tin and R. Otillorash. Trady Moiborsbote Itia.smit tin.
f. V.Ndixe 1030, No. 12,24-W- Chm Zm& M9, 11,
,
So 4M
--A study is mported on (6,e ;;dzkm
.( sm
,
SOS
I .
.
.
alunsinum from ash such as Is oWairwd he large quatstit"
c'
I
098 ; , ft 1br bu tion nt mkkval ftft4g of high ash content
i h, =mg=k "0., Th. .1 "tob"4 C&O
l
*so A. Fr4
1,04. PrAh 11.10. AV1% 10.76. %Os NO ofmi C
oo* PUS70. lAb. tstitm. yiekk4 an millay contiming of .04
1
7
A
40 4
l 1*-32, C up to 0.6, 1
.
ebmt 0.2. and 8 less thall
IM11%. The *Wy woo produmd by a gog4rwv pr"ftst Aw
iahwh ortiod clsomal was Ifted to he the best tediocing
In this, sob also mis a# a re&4ring
ol nWWdn# owl to be sd&A was
"it
'doctory '-p- kv ct"71"S out
The process woo 1700-170. U. m4m*
0
9
ova.
saftoms -0 18108j .4r a- G-c 48W1
I if 5 1 1 "IF-1-
of it a' tt a MW
&-06896*60996600006000404
0 41 0 0 0 0
P 0 0 a
of at 41 mito
1-4 0
00
loo
-00
-00
loo
.00
ZOO
a 0
woo
woo
4`00
1400
woo
zoo
woo
too
000
000
its 0
*81AS1 dW 4.. its
a a
L 1 9 FM 0 it 9 1 As Of 2
0*000000004000M
didolo Sri
1*1 0u 0. 6 6 U 4 1 a Ad A' A' N_ a of 0 a Id so 14 It 11 0 At M".6- ii
f-A-4 "_44.m.cc I A,
114 4.0 `-7-0
440 f0f#Ij#4ft .1tv,
~ . 1--.11 ... . .1. -.1- -- 11-- - ~ ~ -- - --I
W1611100 of Istrolvecs"'? *I a (084"tross Into Iff4lbi'llf-11 M W141FAIMIr toy At an-I 1,1 11P411, 40,
00 .1 111 Istin-J'flody 110JAW 11off. %ji Ills, V.* an active heat I.I.Atlit, it obtaltird. Itipm hawc-4 the
oo .8 -%X" I I-No. 12.37-M, CAtirm.Ziglir, I . U. I,- W yk III in I hi# vot,e Io I., IKII-j- F.. I bi, 14'.1114 1 to" nf I
jj~ C. A. 31, 4(ko-ot.-Ciskn. 01 Its, hesj I it Its.ul W In the alloor '-~'75 its, wollmooi,. 11.~ 1.1 Its. fm- 7
00 Ir ?.,I* v*#. for Is silivotherntal reftl frilte. ilkvn. 02,1 its. Al. 0.31s) its, botar tt-aft, and 1141ft kg~
*0 9 Ub- CxPts- vtfiW this cakn. The trwilm twk p fluorile are requil elf. The C k1wil"It ;4 ON Mlay did not
,i- MY SJOWIN A Mae was formed whkh coo(Almd tm ext"d is.p% Thr irrri-iuuxtien wilr-"
SO mcftnic St. The reduction was likewise introol I Irnm slas Inclutit,114. 'the tomY444 reductiors pew-^
IIY & Milk-0013"Inal reduction of
0*8 Walfrismite with a
cientlor large &list. of heat bring %jjppt;rjI %n x1joy tit hilh.* thin (it the dc~llolieil under [All, o`tIft4h1bf1FV* if$
0 content 01M TJ m7p) WAI Pelklibeed. lout the W Yield WA, 141,11. ki1xv--hir p"Rholl."t i, Firlill-
:Ot, fordy M 6 Aj`~. IL'Ak-n. of the heat tilifillit-C in ttw Ittulptrit "it ill%, lw jorolturd Itmo - fori-lite toy the AN.
Oil- tb.,.l tviticlifm of wolfrantite XXVV a high ". voluf. MindAtIfflult! sfUt file 4`1111114% 111CF1111W jAI + fritmilwon)
IKII)ts, showed the forrytituntraters produeed promsvc Howell", I" the rvolut'lion 4 whechle the W
fly this proreto
to be (if .4titfu. tality and the W yield to be 92%. yield was h,%* thoin ivitirn vniffismitt, wAq u~tl. The W Ili
i:! For She forlidursk. WhCelitr W40 1110rr diffit-1111 III rr.IIUV IhAu III&I In *Chlffll~
'on, I is. of W In the *Iloy :1017 its.
ill wolirtmite and 014 Its. At are required. A difad"uttagr mit?, AmordinX to H.. the r"ulto of the l4b. ritlits. are
Sold , of this prrxv" 14 the Comparatively high Consumption cd uffirien, it ofIrr m kuyvey tolf the rificaror" tod the dil.
I At po!dcf. Throrelk-al cvkmv. showed turther thst in Irrmt praceg4cs and to-how thradvantAgr4of thruw4thr
00 flusnarr"s prorr" in the ptudliefilon oil Imottlicun falbef
(hall (tit u%rof the clec. Ifflellifix forwor, NJ I.. %C
AML!
FR,!
01741.1,L10CAL JiTIRAILONIF CLASSIFKAIKIII
I L*
114;vj ~Jf I*. aft @#,ill do a., &i6
3 1 v 1rx
Uso A* K3 A% 3v ~Ix An A a fW a x
0 410 0 00001 0 0 If it Co At X a It of tf It it Of 03 AI is* d"d
111111 0 0 0 0 0 0 0 0 o a 0 0 do 0 0 0 do Ca do 0 o do 0 0 0 0 0 do IS a do 0 * 0 0 0
0 0 Site 0 f 0 do 0 11111 0 00 0 * 0 11111_0~40 0-0 Roi-o-A-0-0 0 0_0 0 do do 0 0 o 0 do do 0 0
0
**0
-00
-00
v0d,
400
coo
coo
coo
r
tro 0
ties
Igoe
0 0 0-1111144A
0009&00090000000 we
a a
4 0
,A -9-4-1 -A-1. - 9, b~6r 3 I-M-1,
00 A
00 A Phyak"beWeal ptInciplee of allk4a rollactwo in the
odlictimoliffrosillcon. V.114
wyut W 8. K. [Avis
r%fiv"Ply itcri "U'd G.-IM ).-The point
I.
of dc rluft, Is thil In (he Itroduclion of 1109, q is pro-,
Of 3.47.4m a requit of reducing Si(h by villd C. Reduction
00 it hy CO is not likely, sim-c by the Nertut equation even at
99 MDWO011%oxidit"SA. Thr likely reaction tberefori is
Theequil.const
S
00 111 I.W this reaction 10 called. frivo X ~ (Pco9.AmMAv1-:
So &.J&o,). where /to 6 the partial pressure of CO and Am.
Ac. and A&AN are the corre-spotiding activity Indears.
0 0 Z; It ran be assumed that Amot - I and Ac - I and there.
00 j foir K - A&Xcol.' Fri"is free energy cakna. K is onn-
puted far temp%. between 22M stiff 2101)*K. At 1943*K.
0 O'K - 11.3 awl Pro - 3.41 atm. At this temp. (1(170';
00 '3 the reducilon of SIOS ;ill procred ralpidly. At 2IMPIC.
. 'fIW%K-MOan4 co-15.4atm. Undersuchcon-
Of u ditiot" the reaction will Proceed very rapidly. Further
0 0 14 riW In temp, Is U-Cless and will lead to km of Si Im.
03 a diagram of state It can be wen that of 27w-veraf
JLj_4rI"%-II4r Fe dlicidv% the tnot stable is FeSi. Thelatteris
ift formed In the presence of 11.3 wt. '!'car Matom %. The'
formation of FeSi prormis according to I%% + Fe +
C - FeS + 2C0. The thermal effect of this reaction
C
F
Saisoinclutics the beat of formation of FeS. Purtherther-
*I-
modynarnk- calcris. are made for the formation of 43 and.
73 wt of ferrosilicon. The former is f3rmed at INV)--
3
7
[20'Kt.- (_f.527-47') and the faller at 1804RI'K. (1567-
97~'). Iloth irmIn. are below rite temp. at which Si alone
4is"diseed. Thf-*calctm. are for pure subilsom. Ufidtf.__-_______1_-____
_W W'4"
ZN;6694
~' W tv ft " - . ft . 4. ~ .# . J~
t-- 11. 1,; 1 j040,
1~;Iuctlnn ermilitions. the prero4v of Al. Co. 161n. S.
a ~_
id ,
of P will tffrct a change fit the ditcuw*d picture.
Ilasch
as( -
St P 9 a 4 .7 6 1
bN.AW 10, AS 0 W v a IV 0 It Or a Ill IS It a a
.00
00
.00
-00
$00
=00
coo
=00
4
too
coo
::0 0
me 0
0, 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 0 0 * 0 * 0 0 0
00000141 0000 00 411sib"al 0 o 6,4 0311W
0 0 0 0 0 0 0 0 0 0 0 0 0 0 W.*=611 014'-* 6TO!;
1 A 0 12 0 U 11 It It 4 it "Pill Dun AVISM X10 12 It so 4 u it a Iffill aft ooioc*
LI-L-1-1-Aill At. Q
AA U.1 C~ A", I a I
0 4 00
,,A
Grap" on4thod for cakulatinS a chugg for smolong -00
00 j f2frOGUO0. V: P.- FfyWirt &A Vu. A. Pavicoso (Jifoscusir
0o .4 Inst.sterl). -WSl 7. 124-009474).-Smutgritm are Sim
lot cakg. the charge in smelling FeSi. The nonwilranom
00 &it t+p(ted on the 1*4% of 3 cquatkms; for the quantity
.0
00 U( frolucing agent needed. qualitity Ot PC turnings, awl 0
wt. of the alluy. The quantity tof feducing agent (cake) .60
00 4
mleol is calcd. Irmi: y - a(SMWC) where (SiOO
Zi; o- the 'UOs ectittent in the quart tilt, (C) is Ole C costent -00
0
fit the MILICifft Itittfil, INS(h ill %, &H-1 4 14 4 Cneff, Flr .00
:o ff~ 46% FeN a - 44.8 xmJ I-mr M% VeN a - 42.9. ~ It It is woo
auututtl Out the PC tufflifigs emilmill IN1% t4 PC. tilt
quantity u( turnings nmW is -tvid. frous Z - 16(5i(h) - =00
NJ /0.90 where b is a coeff. equaling 041 and 0.14 for 43
and 75170 &1", frsp., and K is the quantity at Pe anif of coo
4-flict elements except Si entering the &Hoy (favu the quart. =*o
60.3 tile, For the 451,allar. lbequatt-
Ilty oil PC vs4moldisest Is colvispenmitil toy the Fe sletivr) COO
(.11 tAllct oomtcrs; Illus K m 0. For tile 7517C alloy, X a&0
004 ivc&kd.tabe2.8. The wt. of the alloy obtaltwi iscskd.
00
frcon equAlincis which in their simptifK4 horru becurnt M.
0.1114(51601) *IUl .11. 044(S%0h) fOr 45 SnLl 76 !1-00
%
9
alloys. relp. flaotch
-Ir t:**
1400
boo
boo
j: Aso.$ 0
Gi i i aw It
Some.) .41 v., o1vt
Ani sopwo "six
U marfailtv filpip Do* no fill Wact It 01 KW $1 1 Ilk
0110*0001000000000000004POO09 i*406000000006000000i
o o * 010 0 0 0 0 0 0 0 0 0 0 0 0 a 0 0 0 * Ole 0 0 0 0 0 0 0 0 0 a 0 * 0 * 0 0 * 01
1&0 AM* Of* tltflL_
90A IIIA tbWRWdYA4fUiC rOMMOft tosewnst im tha ptudoctias
of fenvaum aMora baft;
IN the dac. MW kw~dcn al tuvwUllk cw=pd& in the
NW.1 TM cqw. at jd~bm an " # istw-'.
depem&mt. Givendwe"U.Con"AwrtladvocWUL,
d the rmctbW substsum am rftMT C4W. For
Ow Only Fe Wad& walde at den"d tMps.. X - a"-
Is./arft wbers a is Av w d whi. of dansub wA
Mxpds. at fq". MA Us 19 %M MWAROOM Of 10" 00
canocents in the Karl! On the &WAM*dM 0 a" a
re 97 Md a 3%. and a wap. d Imal(K., In
to be 1400 and the diance. ang. a - US X 10'#.
Itus. tbw pr*waca ad Few Ow"Idy saw" tha Oak five-
tion of bw 81 In the mW phaia. AnAestawls, hr Fe". ago
the al=MWe 14 The odt. X - 0.9100 a w 0.9719. 6*0
eAls affwu dm i... i of 6" A saly OWII cassm be
TWO'd; . wikii~oiv dkw=.'COu4j. be dctd.. gl" jrqg
&W my be dlwvvwded In cakm. 1U ftka. d tands. own Is oes ukamm Mm thad dmxv Mv equtions.
of aW snoyWs diments Is Ukwated by OtsaidW wW thmaWyn4ade " kg tW r,4,1"i,, Th, doe
004 zk=Wa. Fat FtvTl. K Is e". to be JJ X 10-1. in- -skCwW laujou" rcwt6m at on
4 fkadog that u kkk UnMe. AftTi diacm ama*. data -be OdM- from evaWLbk pbys.. i Ng
data an The bests of kwasation of C=Pds. ad &WO4 ck- jAJI" goo
bWlkW goo
mats w" S &W Al kruc&M (be caW. of thn mm.
consts. is the soelt. AP far TiC. ZcC. and WA an jfawb 1900
aw"dies to Keky. The Mwft wicate that am cat-
Was am dabk ad that in 4.1 wC the MW pbm, It
*=W be Into soment . that pmast. =" al It
C
wM Cuabbe into C.UbidM The Ond- IW Uls skd P&M.
boo
Jkj4.ILA M x 0 V*q
1040 SIVISISIN
of"@* 04# as*
r I
NA
ff
go *,
0 10
-0 .6 WWO104 0 0-0 0 0 0 0 6A 0 1* 0 -16 0 0 0
LUIM IN,-VP.
"Investigating the Effect of Some Factors on the
Service of Electric Resistance Alloys." Theadi
for degree of Cand. Technical Sci., Sub 10 Fob 49,
Moscow Order of the Labor Red Banner Steel Instimeni I. V. Stalin.
Summary 82, 18 Doc 52, PlasertatiolIg Presemte4
-For Rgerees D_Sciepce and Enrizeering..in-Ho.sjow
ill 1949 From Vechernypya Moskva, Jan-Dec 1949
TA 4-
t."AtiedJ1, uf A
t,116
~ i~', .I
71
eII2,c lit.
jrn let
Vr; t3c
al v,
urts
It redaktor;
Bole, Yet
tekbniclieski3r redsktOrD
.1lrJOP3 'Proisv0dat" ferrosplo'vOT;
't.COM64, ,.hwtokhn. ,a-vo lit-ri PO
s1loy productiOD; e Goo* rig' - C)dcrof il"J
(IT is. 1409kva 1951- 496 1)- (MLRA 8:4)
ejektrom$t9,llurt9' gli. pt. 20
chernol j tove oj metsilur
(Nis t....tallurgy)
(Iron
P* winners
lilt Vo -ze
IELIXIT hnIcs; on the works of StB11n Pr5
ence and tOc
New achjev~ments in So~"t sc'i oj-=noe obshchestvO po rasprostraneniAu PO"t'
- y skva, znanies 1952o 30 P- (7ses ogramI7 lektsli Ser-11a 3. no. 11)
Broshiur
of 1951 -o znaii- Y~Osco"- y-sten
cheskikh I nauchnykh
DA
------------
USSR/Engineering Metallurgy
Card 1/1 ; Pub. 41-11/18
Author : Sokolov, L. N., Yelyutin, V. P., ard 7AIesakiy, V. 1.
Title : Investigation of the plastic properties of commercial titanium
Periodical : Izv. AV SSSR. Otd. tekh. nauk 3, 110-115, 1954
Abstract : Studies behavior of titanium specimens in upsetting test and in test-
ing for tension, torsion, and impact at various temperatures, from 20
to 1,OOOOC. Diagrams, tables, micrographs.
Institution
Submitted by Academician M. A. Pavlov, April 3, 1954
s. fyw 4
YELYUTIN,'V. P. (Prof.)(Ph. D.): PAVLOV, Y. A.; WRKULOV) R. F. (Eng.)
"Temperature Detex-minations at the Start of the Reaction in a Reduction of
Oxides by Carbon." In book: Application of Radioisotopes in Metallurgy, Syr-Tosiwm XVAIV;
Moscow; State Publishing House for Literature on Ferrous and Nonferrous Metallurgy, 1955.
T, 45-5'x-
Prof. B. P. 'YELYUTIN, Ph. D.; Y. A. PAVLOV, Assistant; R. F. MERKULOV, Engr/Chair of
Rate Metal Metallurgy, Moscow Inst. of Steel im I. V. Stalin.
YELYUTINJ V. p. (prof -) (Dr. Tech. Sci- ); MAURAU, M. A.; pAVLOV) Y. A. ;
------ S,-,el'L-led Titanium with Gx-aphiteI" in book The Applicaticn
"The Interaction of ;y,, symposium XXXIV ; Moscow; State publishing House for
of Radioisotopes in MetallurE ferrous Metallurgy) 1955-(ruy--1.1~
Literature on Ferrous and Non
V. p. yELyuTIN, Dr. Tech. Sci.; M- A. MAURAKH, Assistant; Y. A. PAVLOV, Assistant/
Prof. st.of Steel im I- V, Stalin,
Chair of Bare Metal MetallurgY.- Moscow In
YELYUTIN, V. P., Dr. Technical Sci.; HATIWISON, A. K.;
I "The Degree of Homogeneity of Mechanical Mixtures of Metallic Powders,," in book
The Application of Radioisotopes in Metallurgy, Symposium XXXIV; Mozcov; State Publishing
House for Literature on Ferrous and Nonferrous Metallurgy, 1955- p - 2,7~- 292-
V. P. YELYUTIN, Dr. Tech. Sci.; A. K. Nathanson, Assistant/Chair of Rare Metals Metal-
lurgy, Moscow Inst. of Steel im I. V. Stalin.
USSR/Engineering Metallurgy
Card 1/1 Pub 41 11/16
Author : Yelyutin, V. P., Maurakh, M. A., Pavlov, Yu. A., MGsccjw
Title : Penetration of liquid titanium into graphite.
Periodical : Izv- AN SSSR, Otd. Tekh. Nauk 5, 129-132, May 1955
Abstract : This investigation was made necessary because with the
present method of melting titanium in a graphite crucible
there was too much loss of the metal by its penetration
into the graphite and also its seepage completely through
the crucible and onto the heating elements. This caused
the breakdown of the heating furnaces. In conclusion the
author states that ordinary graphite crucibles are too
porous and cannot be used. It is recommended that graphite
crucibles with higher walls and smaller bases, made of the
lowest porosity graphite, be used in melting titanium and
that the metal be kept in the crucible, in its molten state,
for minimum periods of time and at'the lowest temperatures
possible, above melting point. Graphs, tables. one refer-
ence, USSR.
Institution
Submitted April 1, 1955
1.
A, ~ *-~-, I - ". 1 1-
t I . I : '-. i_'-
.. 9
YT /- /yc, 7 //Y, ~/, ~ /
IN
WWWW1 yFl Y U T 11 V.
D-8
IjSSR / Liquid" jzik&) No 4, 1957) lio 9092
Abs 'Tor - Itef 2hur - Y A
X.., mautl~h) 14. N. cl.Commercisi Titanium
Author yelyalny- face Tension of Licill
1 Sur
Title *.'SensitlIan( . ota. tekhn. no~ 1956, go 4, 129-3-31
orig pub T ZV -AN SSSR, .9 of the measurements Of
I of a method and result 0.1~ Fe, leas
DeacrIPtiO' rof co=ercial tit&niwn (I n 000 mg) in
Abstract the surface tension an 0-1~ Ca) and less tha erature d^
tha,n 0.2$ Si, less tI the crystallization temp
the liquid siate. At
3.510 � 18 dyne/cm.
Card
. K'k-
d rest. Zdox-,,,"* 3 no.3-5-6 Vir 157
Hyglem of studant's work an (j4i 10:4)
'br,zovanira SSSR
1. 14inistr vY'Rsb o o
M
(sTUDIN 2s
7 6' h 4> 1'6/
PHASE I BOOK EXPLOITATION 230
Yelyutin, Vyacheslav Petrovich; Pavlov, Yuriy Aleksandrovich;
'-U-r-TH, ~-r ~se~ye ~0; Ubkseyev, Yevgeni7 Nikhaylovich.
Proizvodstvo ferrosplavov; elektrometallurgiya (Production of ferro-alloys;
Electrometallurgy) 2d ed., rev. and enl. Moscow, Mashgiz,
1957. 436 P. 7,500 copies printed.
Ed.; Alekseyev, Ye. M.; Ed. of Publishing House:
Rozentsveyg, Ya. D.; Tech., Ed.: Vaynshteyn, Ye. B.
PURPOSE: The book is intended as a textbook for students at
Institutions of higher learning. specializing in
metallurgy and may also serve as a manual for engineers
and scientific workers.
COVERAGE: Theoretical and practical data on production of ferro-
alloys are systematized and generalized in this book.
The theoretical foundations and technology of producing
various ferro-alloys are discussed, Some information
on physical chemistry is given in order to facilitate
Card 1/7 understancL4-ig of thermodynamic calculations.
-Production of Ferrb-alloys; Electr~metalliurgy._(Cont.) 230
Problems of economics and 6f safety engineering in the
production of ferrous alloys are elucidated. 'The present
edition of this book gives a more detailed description of
technology and progress in Soviet and non-Soviet ferro-alloy
industries than that given in the first edition. The
bibliography contains 93 references, 69 of which are Soviet,
15 in FxAlish, 6 in German and 3 miscellaneous.
TABU OF CONTENTS:
Foreword 6
Ch. I* Brief Notes on the Thermodynamics of Ferro-alloys 7
Ch. II. Silicon Alloys 27
1. Physicochemical properties of silicon and its compounds 27
2. Composition and use of silicon alloys 39
Raw materials for production of silicon alloys 42
Theoretical base for reduction of silica 46
Card 2/7
,Production of Ferro-alloys; Elpetr6niettalurgy (Cont.) 230
5. Production of high-grade ferrosillcon 55
6. Aluminum-silicon alloy 80
7. Calcium-silicon alloy 87
Ch. III. Manganese Alloys 97
1. Physicochemical properties of manganese 98
2. Manganese ores 105
3* Manganese alloys 109
4. Carbon ferromanganese 110
5. Production of manganese-silicon alloy 124
6. Production of medium-carbon and low-carbon ferromanganese :L28
7. Production of metallic manganese -133
Ch. IV. Ferrochromium 153
1. Physicochemical properties of chromium and its compounds 153
2. Grades of ferroc hromium 166
3- Chromium ores 168
4. Methods of obtaining ferrochromium 172
Card 3/7
Production of Ferro-allOYB; Blectrdmetialurgy (cont.) 230
Ch. V. Ferrotungsten 215
1. Physicochlmical properties of tungsten and its compounds 215
2* Tungsten.ores 1 220
3. Methods of obtaining ferrotungsten 222
4. Selection of production method 246
Ch. VI. Ferromolybdenum, 249
1. Physicochemical properties of molybdenum and its
compounds 250
2. Molybdenum ores 256
3. Methods of obtaining ferromolybdenum 258
Ch. VII. Ferrovanadium 28l
1. Physicochemical properties of vanadium and its compounds 282
2, Development of the production of ferrovanadium in the
Soviet Union 286
3. Vanadium ores 288
Card 4/7
Production of Ferro-alloys; Bleetro'meta2lurgy (Cont.) 230
4. Production of vanadium 290
5. Production of ferrovanadium. 297
Ch. VIII, Ferrotitanium 311
1. Physicochemical properties of titanium and its compounds 311
2. Titanium minerals and ores 320
3. Thermodynamic bases of the reduction of titanium oxides 321
4. Technology of production of ferrotitanium by the
aluminothermio process 324
5. Obtaining metallic titanium 332
Ch. IX. Zirconium Alloys 335
1. Physicochemical properties of zirconium and its compounds 336
2. Zirconium minerals and ores 342
3. Production of zirconium alloys 34J
4. Production of metallic zirconium 34
Ch. X. Ferroniobium 350
Card 5/7
e
230
j0..; Bloctr6mets1lurgy (Cont') ounds 350
FerrO-al to comp 353
Production of a, properties of nlo-blum and 353
rhysieochemi,o as rind ores
1. NiobiUm minev onjobiUm 358
2, on of ferr
3. product. Is 359
Ferroboron 363
Cho X1. sicochemical properties of boron and 'to compound 363
Phy
Boron ores ferroboron 369
tion, of
3. Froduc
XI-j. FerrOphosphorus osphorus and its 369
Ch Pbysicochemical properties Of Ph 371
Compounds f ferrophOsphoruO ces 375
production 0 Iron in Sl.otric Furna OIL
Ch. production Of Cast du0tiOn Of Ferro-alloys 39-
Problems in the Pro
Cho FConomle
Card 6/7
Production of Ferro-alloys; Electrometanurgy
1. Production planning
2. Production cost of ferro-alloys
3* Organization of production control.
Appendices
Bibliography
AVAIIABIZ: Library of Congress
Card 7/7
(Cont.) 230
394
401
412
416
434
rd,
24 x2i
-8-13 34
AUTHORS: Grigorlyev,G.A.~ Telyutin, V.P. and Maurakhj M.A.(Moscow).
TITLE: Viscosity of molten titanium. (Vyazkost' rasplaviennogo
titana).
,e Tekhnich
PERIODICAL: "Izvestiya Akademii Nauk, Otdeleniy eskikh Nauk"
(Bulletin of the Ac*Sc Technical Sciences Section),
1957t N0.8t pp. 95-101'ZU.S.S.R.)
ABSTRACT: The titanium was molten in graphite crucibles which were
sufficiently dense to hold the molten titanium for twenty-
five minutes without appreciable penetration of the metal
into the crucible walls. The authors used the method of
Meyer which was further developed by Shvidkovskiy, Ye.G.(2)
and was intended for measuring torsional oscillations of a
cylinder with a liquid suspended on an elastic thread and
then determining the viscosity from the logarithmic damping
decrement and the period of oscillation of the cylindrical
crucible suspended on the thread and filled with the molten
metal to be investigated, The authors used ahigh tempera-
ture viscosity meter embodying a vacuum resistance furnace
with a carbon-grap&te heater, the design of which was
described by Yelyutin et alii (3), a sketch.of which is
Cardl/2 shown in Fig.1, p.96. The estimated measuring error was
5 to 6% and the Ti used in the experiments was produced by
Viscosity of molten titanium. (Cont.) 24-8-13/34
the magnesium-thermal method and remolten in an are furnace;
it contained less than 1% admixtures, i.e. max 0.2% Fe,
max 0.2% Si, max 0.4% 0, max 0.1% N. The results obtained
in five series of measurements at temperatures between
1730 and 1920 C are entered in Table 21 p.100 and it can be
seen from the obtained data that the viscosity decreases
from 0.89 to 0.37 centistokes if the temperature increases
from 1730 to 1920 C. Calculated results show that the free
energy of the viscous flow is a linear function decreasing
with temperature. The heat of evaporation/energy of
activation of the viscous flow ratio equals 2.7.
There are 2 tables, 4 figures and 10 references, 5 of which
4we Slavic. I I
SUBMITTED: April 26, 1957.
AVATLA Library of Congmse
Card 2/2
y E'L Y 0 r/ Al~ V, P.
AUTHORs Yelyutin, V.P.y Xinister of Higher Education, USSR. 3-11-1/17
TITLEs 40 Years of Higher Schoola in USSR (Vysehaya shkola SSSR za
sorok let)
PERIODICAM Vestnik Vysshey shkoly, 1957, llv PP 3 - 10 (USSR)
ABSTRACT# The author gives a description of the educational conditions
in Russia before and after the Revolution. He states that the
development of higher education made enormous progress during
the post-revolution period. He indicates some figures relating
to this evolution. The number of students in 1940 amounted to
811,000; in 1950 to 1,247,000; in 1957 to 2,001,000. Compared
with 1919 the number of students increased by 16 times, especi-
ally in the fields of engineering, transport communication,
agriculture, forestry, and economy. The creation of vuzes in
remote areas was considertbly-activated. The organization of
new vuzes and the expansion of those already existing was car-
ried out in the Ural, western and eastern Siberia, in the Far
East and in Central Asian republics. The number of students
increased in 1956 by 1.6 times compared with the figure of 1950
and bY 3.2 times compared with 1940. In tha eastern areas
Card 1/2 there are 25 technical, 7 agricultural, 6 medical and a few
40 Years of Higher Schools in USSR 3-11-1/17
other higher educational Institutions. In the Soviet Union
there is no republio without a national university and other
higher educational institutions. In 1956 the Soviet higher
and secofidary special educational institutions released
770,000 specialists, and during the last 5 years - more than
2,700,000. The Soviet Union has now 38 universities, and the
number of students amounts to 200,000. A characteristic
feature of the higher schools is the uninterrupted endeavor'
to improve their education methods.
ASSOCIMON: Ministerstwo vysshego obrazov&WAya SSSR (USSR Xinistry of Higher
Education)
AVAnANX: Librax7 of Congress
Card 2/2
SOV/163-58-1-17/53
AUTHORF)s Yelyutin, V. P., Pavlov. Yu. A., Glukhovtsiuv, B. V.
. ..........
TITLE: The Interection Betwei~n Nickol-Vanadium Alloys and Refrac-
rories (Vzaimodeystviye nikeleyanadiyevykh splavov s
ogneuporsmi)
PER10DICALt Nauchnyye doklady vysshey shkoly. Metallurgiya. 1958. Nr 1,
PP 87-92 (USSR)
ABSTRACTt The present investigation was carried out to improve the tech-
nology of high-temperature alloys, especially in regard to the
removal of inclusions of rion-metals or gases in alloys.
Nickel-vanadium alloys were used as 161tial materials the neir
of which was produced at 1 800 - 1 900 . The melt of the
nickel-vanadiu,m alloys waE carried out in crucibles of Al? 01.
BeO, ZrO. with diffsrent duratJon of storing. The analysie
sho,ved that the alloy3 were rich in -gasca nuch an 0,072 -
0,0222~ 02 and 0,01 - 0,0951% N 2' It was found that the high gas
content of the alloys is caused by inclusion of the initial
Card 1/4 materials, especially the aluminum thermic vanadium.
SOV/16i-58-1-17/55
The Interaction Betneen Nickel-Vanadium Alloys and Refractories
To determine the suitable refractory for the nickel-vanadium
alloys the interaction between the alloys and the refractory
wan Investigated, Vanadium is a comparatively activP metal in
the melt and reacts energetically with the refractories of the
crucible, bringing impurities Into the metal melts. In the re-
actions mainly VO reacts. In the interaction between VO and
the oxides of refractories also V20 3 is formed. The lower sta-
bility of ZrO2 as compared to vanadium melts is probably a
consequence of the reaction 2ZrO + V ~FkZr 0 + VO.
2 . 2 3
By means of radioactive indioatorn the character of the ln'~er-
action bet-ieen the refractory and the liquid metal alloy with
a vanadium content of 30% was determined. ZrO . was used as r,~--
fractory to which the radioactive isotope Z ~5 'was added.
The investigations showed that non-metallic impurities can be
avoided only if the melt to not overheated and is left in the
state of melting for as short a period an possible.
The reaction products were Investigated also by means of' x-ray
Card 2/4 structural analysis to explain the charactez of the interac-
SOY/163-58-1-17/53
The Interaction Between ffickel-Vanadium Alloys and Refractorips
tion between the refractory and the liquid nickel-vanadium
alloys. This analysis showed that in the interaction betwp,~n
the alloys and the refractory ZrO2 is reduced to Zr-
The character of the interaction between the alloys and the
refractoriec of beryllium oxide was not explained by th.,?
Y-ray structural analysis. Probably only little vanadium
oxide is formed in the interactionj this vanodinm oxide dis-
solves in the melt. Beryllium vapor is formed whIch alao diti-
solves in the metal melt.
Experiments on the interaction of nickel-vanadium alloys and
Al 0 were also carried out.
2 3
The macro- and microscopic investigation of the surface off
zirconium bricks 3howed that in the melting in zirconium
crucibles in the case of a longer peri6d of storage the metal
melt penetrates the ZrO.. In melting beryllium and aluminum
oxide in crucibles the interaction between the liquic metal
and the refractory is much smaller.
Card 3/4 There are 1 figure and 1 referenceo
sov/163-'~6- 1 -17/5",
en Nickel-Vanadium Alloys and Refractor~J,~.,:
The interaction Betwe 1 Institute)
ASsoCIATION: MoskovskiY institut stali. (Moscow Stee
SUBMITTEDs October 1, 1957
. Card 4/4
AUTHORS: Yelyutin, V. P., Merkulova, R. F., SOY/163-58-7/-2/49
Pavl ov-1 _M
TITLE: Investigating the Reduction Reactions of Metal Oxides With
Carbon (Issledovaniye realttsiy vosstanovleniya okislov
metallov uglerodon)
PERIODICAL: Nauchnyye doklady vyashey shkoly. blettLIlurgiya, 195a,
11r 3, PP 10 - 14 (USSR)
ABSTRACT: The influence of the temperatures on the reaction velocity
of the reduction of metal oxides with carbon was in-
vestigated. Activated and non-activated charcoal were
used as reducing agent; it had been obtained by the inter-
action of the gas mixture CO 2+ 04o 2 with metallic
magnesium. The initial temperature of the interaction
between carbon and motal oxides, as for instance MoO 39
Fe OV V 0 11b'O and TiO was determined. The reduction
2 2 5' 2 5 2 0
of V 205 was investigated at 6oo, 700, 800, 900 and 1000 C,
41r44)-i the reduction of MoO 3 at 500, 590, 600, 650 and 700 0 C,
Investigating the Reduction Reactions of Metal Oxidea SO-1/163-58-3-2/49
With Carbon
the reduction of Fe 0 at 500, 600, 700, and 000 0 C, and
2 3 0
the reduction of WO3 at 900, 1000, 1100 and 1200 C.
The reduction processes take place at the same time
with the increase of the reaction velocity they reach
their maximum at the corresponding temperature and then
slowly decrease a0ain. The increase in temperature effects
an increase-of the rate of the reduction process. The
kinetic curves obtained show that the reduction processes
of the oxides have an autocatalytic mechanism.Vased on
the results obtained the apparent activation enerCj
of the reduction processes of the oxides with metals
was calculated. The following values were found for the
activation energy: kcal/1101: V20 5 -2,3)1'1003 - 14,3,
Fe 20 3 - 11,7 and WO 3 -18,0. The linear dependence between
the initial temperatures of the rednotion and the
activation energy of the corresponding processes was found.
-1A There are 4 figures, I table, and 9 references, 3 of which
are Soviet.
"3~~ I.,Lz
18(6)
'AUTHORSs Yu.A., soll/163-56-4-2/47
Glukhovtsev, B.V.
kTLE; Flu idity and Density of Nickel-Vanadium Alloys
(Zhidkotekuchest' i plotnost' splavov nikelya a vanadiyem)
PERIODICAL. Nauchnyye doklady vysshey shkoly. Metallurgiyat 1958, Nr 4,
pp 12 - 16 (USSR)
ABSTRACT: In order to determine the fluidity of nickel-vanadium alloys of a
content of 25, 30, and 35 % of vanadium, the method of pouring the
alloys into molds of the Ruff-type was chosen. By this method, the
tests can be carried out in vacuum or in a neutral atmosphere. The
metal was melted in crucibles of beryllium-oxide with argon in a
high-temperature resistance furnace with a graphitic carbon heater.
A special furnace structure as shown here allowed the metal to be
poured into crucibles without disturbing the tightness of the fur-
nace. The experimental method of Yelyutin and Maurakh (Ref 6) was
c=plofred to determine the specific gravity of the smelt. This for-
merly used method is rather simple but reliable.- By investigating
the fluidity of the nickel alloys of a vanadium content of 25, 30,
Card 1/2 and 35 % It was found that these alloys showed a rather good fluidi'W;
-Fluidity and Density of Nickel-Vanadium Alloys SOV/163-58-4-2/47
e.g., their fluidity surpasses that of stainless steel. T"he
fluidity of nickel-vanadium alloys of the investigated composition
increases with increasing concentration of vanadium. Measurings
of the density of molten nickel-vanadium alloys showed that it -.~a5
lower by 0.3 - 0.4 g/cm3 than the specific density of the solid
samples. TILere a.e 5 figures, 2 tables, and 6 references, 4 of which
are Soviet.
ASSOCIATIONt Moskovskiy inatitut stali (Moscow Steel Institute)
SUBMITTED: March 29, 1958
Card 212
. ..........
3-58-6-1/34
AUTHOR: Ye.lyulillk,__,~ Minister of USSR Higher Education
TITLEi The Higher School Is Confronted with Great, Responsible
Problema (Pered vy9ahey shkoloy atoyat boAhiye, otvetstvennyye
zadachi)
PERIODICAL: Vestnik Vysshey Shkoly, 1958, Nr 6, P 3-10 (USSR)
ABSTRACT. In recent years the training of specialists has been substantial-
ly improved, both theoretically and practically. The system
of obtaining an education without ceasing to work in one's
profession has been considerably expanded. Out of 2%lOO,OO0
higher school students, 880,000 are being trained by the
evening and correspondence system. In recent years higher
education has developed vigorously in the eastern provinces
of the Soviet Union. At present over 500,000 student a almost
25 % of the entire number, are being trained there. in 1950,
there will be established in the East the Khabarovskiy avto-
mobillno-dorozbnyy(Khabarovok Automobile-Roads Institute) and
the Akmolinskiy sell 8kokhozyaystvennyy institut (Akmolinak
Agricultural Institute). The Karagaddinakiy gornyy inatitut
Card 1/3 (Karaganda Yining Institute) is being reorganized into a
The Higher School Is Confronted with Great, Responsible Probleno 3-58-6-,W4
f
polytechnical institute with a branch for evening study in(
Temir-Tau. In the light of N.S. Khrushchev's speech at the
13th VLXSM Congress, the question of shop practice must play
not only an instructional, but also a great educational role.
It is considered expedient and necessary, beginning with the
1958/59 school year, to considerably increase the admission
to vuzes of persons with not less than 2 years experience in
industry, agriculture, and other branches of the national
economy and culture, who are recommended by the social
organizations of theenterprises where they are working. The
new,ruleo of enrollment into USSR higher schools this year
provide.for admissiont with work being discontinued, of persons
awarded a gold or silver medal on graduating from secondary
achools or of excellent pupils of secondary.special schools,
who are in the top 5 % of the graduating class. The encourage-
ment of youth with shop or personal experience does not pre-
vent capable young.people with secondary education from enter-
ing the vuzes, even though they have no shop practice. The
now rules of admission providelthat 20 % of,adminsions be
allotted for general competition in case applications of
persons having priority exceed 80 % of the vacancies. At
Card 2/3 present a 7 year plan of higher school development is being
3-58-6-1/34
The Higher School Is Confronted with Great, Responsible Problems
planned. The most 'important task of the 6igher school is to
supplement the cadres of Soviet intellectuals with young
specialists who-have not only acquired the highest professional
qualification,.but also have been educated in a spirit of un-
conditional loyalty to their country and to the cause of the
Party and Communism.
ASSOCIATION: Ministerstvo vyeshego obrazovaniya SM (USSR Ministry of
Higher Education)
Card 3/3
AUTHOR s Funke, V. F., Yely-utin, V. P. 78-3-4-6/38
TITLE. Some Data on Equilibriun Diagrams of Chromium-Niobium.
Systems( Nekotoryye dannyye x diagramme ravnovesiya sistemy
khrom-niobiy)
questions and Answers (Voprosy i otvety)
PERIODICALi Zhurnal Neorganicheskoy Khimii, 1958, Vol. 3, lir 4,
pp. 866-867 (USSR)
ABSTRACT: Question :In publications data exist on the fact that at
13000 the cubic face-centered 1TcCr (HgCu2 type) phase
changes to the hexagonal phase, which remains constant up
to 15goo. What is your opinion on this fact ?
Answer: That refers to the diagram: tantalum-niobium, where
the transition of one modification into the other is found.
In the niobium- chromium system this cannot be obser*ved, any
longer.
Question: What is the opinion on the accuracy of determining
the liquidus- and solidus points and on the analysis of alloys?
Answer: Tbit can easily be observed in the iron-aluminium
Card 1/3 system where the great crystallization intervals permit
78-3-4-6/38
Some Data on Equilibrium Diagrams of Chromium-Niobium System
exactly to determine the temperature, to which the de-
termination of the liquidus point in the fusion method
corresponds. Ifere it can be determined that in the interval
of 3000 the lag of the temperature in liquidus
can amount 4~a 4o - 45 0. Tl,%ttyields lo - 15~ of the tempe-
rature interval of.crystallization of the alloy. For
measuring temperature the thermocouple element is used in
this case, which is connected with the molten part of the
sample. Besides, here the cooling-down curve (Thcrmal ana-
lysis) is recorded. In determining the fusion temperature
according to both methods a difference of lo - 2oO is found.
After this the accuracy in determining the temperature of
solidus in alloys, which must amount to + 15%,is classified.
.Question: How is it that you put in the (~hromium-niobium dia-
gram such a low melting temperature for niobium - 21000 1?
Answer; The melting temperature of niobium lies higher,
Card 2/3 however this problem was out of question, since in the ex-
41
78-3-4-6/38
Some iata on Equilibrium Diagrams of Chromium- Iffobium Systems
periment no pure niobium, but 99,54, niobium with 5%
tantalum content was used, because pure niobium was not
present. (See article publ. in Izv. Ali SSSRI OKhN, No- 3, 68 (1956))
Card 3/3
V . doktor tekhne u833kl R,Y., inzho; PAVIA)Vt
IzLTJTIN, _it,,-prof
ru..ket-dots*, knd. tekhn. uw1k. im by, solid carbon-
a at the start Or metal oxide reduct
Temperature stau no*'38:79-i7 158-
Sbor. I.ust-
talj.~,gl, redkIlikh mgtal,.Oy "o,kllkl* Institute,
-1. Wedra me
stali im. Stalina, The
(Cbddation_reduotjou roactiOn) ( rmowtry)
(Re,dioisotope jj~lnduetrlal applications)
SOV/137-59-1-575
Translation from: Refcrativnyy zhurnal. Metallurgiya, 1959, Nr 1, p 75 (USSR)
AUTHORS- Yelyutin, V. P., Mozzhukhin, Ye. I., Shulepov, V. I.
TITLE- Effect of Combined Chemical and Heat Treatment on Heat Resistance
of Alloys (Vliyaniye khimiko-terr.-ticheskoy obrabotki na zharoupornost!
splavov)
PERIODICAL- Sb. Mosk. in-t stali, 1958, Nr 38, pp 427-432
ABSTRACT: The authors investigated the effect of combined chemical and heat
treatment (CHT) of the surface of specimens of a TiC base (71.5%
TiC) alloy cemented with a NiAl compound containing 54 atom-1/6 Ni
and 60 atom-16 of metallic Nb, Zr, Cr, or Be on the resistance to
scale formation at 1150 - 12500C. The CHT consisted of annealing of
the specimens covered with a 50:50 mixture of ZrO2 and alloying
metal and 1% NH4CI in an H2 atmosphere at 15000. Saturation of the
surface with niobium. and zirconium does not improve the resistance
to scale formation of TiC - NiAl alloys - GHT with beryllium and
chromium increases the heat resistance by 19007o and 2001o, respec-
tively. The authors note that a change in the procedure of saturation
Card 1/2 of the alloy surface with chromium (for example at 11500 temperature
SOV/137-59-1-575
Effect of Combined Chemical and Heat Treatment on Heat Resistance of Alloys
in an atmosphere of air) has no effect on its resistance to scale formation. How-
ever, CHT conditions should remain constant (15000 temperature for 0.5 hour) for
Be, because any difference in the interaction between Be and TiC and NiAl re-
sults in a different concentration of Be in these phases. The authors submit that
during longer CHT Be reacts predominantly with the NiAl and that the TiC grains
become exposed, which lowers the resistance to scale formation of these alloys.
R. A.
Card Z/2
Lyt/-r /p1
MUT131 W,,
The technical cadras in the U=sand the U$ ."Przegl techn 79 no.2:
62-64- 158,
.(Rusvja-TscbnOI09Y)
(United StatOls-TschnOlogy)
Zan 114, Vvacheslav Petrovich
,Tj I vy Mosjrva3
~rysshaya Shkola StrarW sotsializra-
Sotsokgiz3 1959*
98p. Tables.
Bibliographical Footnotes*
614,V07-141 V'
Y
AYZMOLIB, F. [Bisonk-olb, Friedrich], prof., Dr.Ina.habil.;
MAURMI, M.A., kand.tekhn.nauk, prepodavatell (translator];
MOZZHOUN, Yo.I., )cnnd.tokhn.nauk, prepodavatell (translator];
NATANSON, A.K., kand.takhn.nauk, prepodavQtalt (translator];
LRYIN, B.Ye., kand.tekhn.nauk (tranalatorj;
prof., doktor, nauchnyy red.; RUMMY, V.S., red.; ELIKIND,
L.K., red.izd-va; ATTOPOVICH, M.K., tekhn.red.
(Powder metallurcyl Poroshkovaia metallurgiia. Pod nauchnoi
red.Y.F.Eliutina i A.K.Hatansona. Upskva, Goo.nauchno-tekhn.
izd-vo lit-ry po chernoi L tsvetnoi metallurgil, 1959 518 p.
Translated from the German. iKIRA 13:1)
1. Kafedra metallurgii redkikh metallov i poroshkovoy metallur-
gii Moskovskogo institute stali (for Kaurakh, Mozzhukhin, Natan-
son).
(Powder metallurgy)
18-3100
AUTHORS:
TITIE.-
PERIODICA14-.
77678
Sov/148-6o-i-1/34
_Le~~~ Pavlov, Yu. A., Lysov, B. S.
Free Energy of Formation of Vanadium-Oxygen Solutions
Izvestiya vysshikh uchebnykh zavedeniy. Chernaya
metallurgiya,-1960, Nr 1, PP 5-11 (USSR)
ABSTRACT: The authors iwvestigated the solubility of oxygen in
metal while treating vanadium with liquid calcium
within the temperature range of i,000-1,90CP C.
The,equilibrium of,the system V.- 0 was investigated
by heating (to a certain temperature) vanadium,
contaminated by oxygen, In the presence of molten
calcium or magnesium, with subsequent determination of
residual concentration of oxygen in metal. The ex-
perimental part was conducted in the laboratory of
rare metals of the Moscow Steel Institute (Moskov-
skly institut stali). Tne initial material con-
sisted ofi distilled calcium, containing 0,3-0.4% N 2;
Card 1/12
Free Energy of Formation of Vanadium- 77678
Oxygen Solutions SOV/1118-60-1-1/34
magnesium of MG-O type; and calcium-treated vanadium
containingabout 0.5% 02-f 0.2.d,,, N21 and 0.2% C.
Vanadium was crushed to the particle.size under 1.0
Rim. Tne experiments at 1,000 and 1,2000 C were
conducted in steel crucibles, and at 1,5000 C In
molybdenum crucibles. The crucibles contained 1-3
g of vanadium and 5-10 9 of reducing metal, Tne
diagram of changes of free energy in the system
vanadium-oxygen for 1,0000 C was plotted by 0.
Kubashevskiy and coworkers (N. P. Allen, 0. Kubas-
chewski,, 0. Goldbeck, J. of the Electroch~!m. Soc.,
98, 417, 195) (see Fig. 1) who determined the value of
free energy by the equilibrium content of oxygen'
in metal after its treatment by liquid calcium,
magnesium, alLd barium,
Card 2/ 12
Free Energy of Formation of Vanadiujn- 77678
oxygen Solutions sov/148-6o-1-1/34
VO
+ go VO It
Oard 3/~2
0 to ?0 .30 40
Fig. 1. Equilibrium diagram of a vanadium-oxygen
aystem.
Free Energy of Formation of ianadil-vn-
Oxygen Solutions 711484-60-1-1134
Table I gives the equilibrium content of oxyj.~-en in
vanadium and the corresponding values of partial
free ene .rgy of Bolid solutions z 02V.
Table 1. Eq~iillbrltim oxygen content in metal and
partial free energy.
0)(14CM CONrENT- PARrIAL r4ZEV
IN tiCtAL AFrr-R Eqrjt,&j
flEOLICEA TACAr"em r, -I. CAqMO"
Wivm 0 26; 0,34: 0,21 1899w
HA&M1C5JVtj. . 0 181; 0,163; 0.10 224000
C.Al,t f #j" - - 0.41
6.134. 0.18. 241000
Card 4/12
Free Energy of For-mation of 'Vanadiwl- 77678
Oxygen Solutions SOV/148-60-'1-1/34
The authors determined the equilibrium concentration
of oxygen In vanadium htits melting temperature, by
analyzing the metal obtained by the reduction of its
pentoxide by calcium in the presence of IodIne. Tne
equilibrium oxygen content was considered to be the
minimum oxygen content established by several
tests. The value proved to be 0.02%. These results
correspond to the results obtained by R. K. McKechnle,
A. U. Seabolt (J. of the Electrochem. Soc., 97, 311,
1950), who obtained the following content in various
samples of vanadium: 0.025, 0.031, 0.017, and 0.02c%.
The results of determination of equilibritLi, concentra-
tions of oxygen in vanadium, treated by liquid calcium,
at 1,000, 1,200, 1,500, and 1,9000 C are givenin
Table 2 and in Fig. 2(a).
Card 5/ 10-
Fre a Energy of Formation of Vanadium- 77678
Oxygen Solutions SOV/1118-60-1-1/34
Table 2. Equilibriijm concentrations of oxygen in
the vanadium-oxygen system at various temperatures
and reducers and corresponding free energy values.
TCHPIFIZArvRe 0,KY6Cm 4WEM MtrIJAL
KEDUCER E0
Y
tr4 tip-rAL F-9 V z r-Pi V_ 9 CN
4
OC
low 1273 0,13 241000 214100
CALCIUM 1200 1473 005 231500 193700
15W 1773 0:03 216300 167300
19W 2173 0.02 197 9W 133300
MA&MES10H 1000 1273 0,16 224000 107 2M
1200 1473 O,E,8 213940 178 9ca
Card 6/ 12
Free Erler,W of FOrInation of Vanadlull-
OyySen Solution:1
77678
Card 7/12
acentratiOns of oxy en in
Fig. EquIlib-rium COIIt vjith calcium: test
vanadi= after treatmer cording to thermodynamic
data. (b) calculated ac
data for oxides.
Free Energy of Formation of Vanadium-
oxygen Solutions
Card 8/12
77678
sov/148-6o-i-1/34
The authors' calculations were based on conditions
of reduction of vanadium (containing dissolved
oxygen) by calciumi
101V + Cal tr-- Ca0s; A Z;. M.!
This reaction-is characterized by the following
change of free energy:
A Z; A Z*co A Z(*Ojv. (2)
At the same timez
A Zz RT In K. (3)
'When activity of CaO and Ca is equal to 1, the
equilibrium constant can be expressed by:
77678
Free Energy or ForrnatiOll of Vanadium- sov/148-60-1-1/34
oxygen Solutions %he region
tlues of free energyjp characterizinz o
The VE urri-oxygen (in presence of
of so-Lid solutions vanadi
-1 be calculated by substituting
d calcium) caj ie equilibrium values of'
liqui equation ti and F19- 3).
into the above tions (see Table 2
oxygen concentra
Card 9/12
of Formation of vanadilun-
Free Energy
oxygen Solutions ova
T
Card 10/12
.80
tL 12
77678
SOV/1118-60-1-1/3'I
av,
Z 60 'M ff 1 -/6
Alf WNT
2 4 LOVO z
Is
0 0XV f TF
#00 1000 .
3 ~d 11/12 for caption.
See Ca
Free Energy of Formation of Vanadium-
Oxygen, Solutions
Caption to
Fig. 3. A
vanadium-oKygen
("reatment
'treatment
2Mg + 0 -
2
M.
77678
sov/148-6o-i-i/34
Fig. 3,
nomogram of free energy of formation of
solutions. M 2V + 02 = 2 Z-01v
by calcium); (2) 2V + 0 21= 2 ZO_7V
by magnesium); (3) 2ca + 0 = 2CaO; (4)
2
2mg0j. (1j) 21C -1 0.1 u 2CO; (6) 2V + 0
2
Tne established relationship of chancre of free energy
of formation of' vanadium-oxygen solutions gives
means to peilform the thermodynamic calculations
involving other reducers. The described methods can
be used for a more general problemi the thermo-
dynamic analysis of solutions of metals with oxygen
in the presence of third component. There are 3
figures; 3 tables; and 5 references, 2 Soviet,
3 U.S. The U.S. references are: N. P. Allen, 0.
Card 11/12 KubaschewzkI, 0. Goldbeck, J. of the Electrochem.
Free Energy of Formation of Vanadium- 77678
Oxygen Solutions sov/.148-6o-l-1/34'
soc., 98, 417, 1951; W. C. Lilliendahl, E. D. Gregory,
J. of the Electrochem. Soc., 99, Nr 5, 1952; R. K.
McKechnie, A. U.-Seubolt, J. of the Electrochem. Soc.,
97, 311, 1950.
ASSOCIATION: Moscow Steel Institute (Moskovskiy ins,titut stali)
WnMITTED:~ January 26, 1959
Card 12/12
~ ", ." "' 3
/4P. 9.200
3/148/60/000/002/007/008
ATJMORS% Mozzhukhin,-Ye.I., Yelyutin, V.P., Umanskly, Ya.S.
TITLEi The Effect of Sinter,4Conditions on the Strength of Carbide
Base Alloys CiFUU'r =ze by a NiAl Compound
V1
PERIODICAL: Izvest-tya vyashikh uchebnykh zavedenly, Charnaya ~atallurglya,
1960, Nr 2, pp 142 - 147
TEM To determine optimup sintering conditions ensuring the pre-
paration of h1jxh-,_qjrenRjh_AUqys.0 the authors studied the of feet of various
sintering conditions on the properties of Ti-earblde'bnd Ti-W-cax-bid0base
alloys carburized by a Ni-Al compound. The effect of sintering conditions
on th~ strength of alloys during be .nding tests at room and elevated tempera-
tures-was mainly studied, Students of the Moskovskiy institut stale (Moscow
Steel Institute), Ye.A.~ Bvchkova, JL,V. Maksimova and Ye.I. Oginskaya took an
active part.in tke studies. The carburizlng alloys contained -54-- 60% (at)
Ni. The given theoretical compositions of-the investigated alloys are con-
tained in Table 1. The specific weight of Ti-W-carbides was calculated from 3
the weight and volume of the carbide component in hard alloys. It was 11.4 g/em
q1
Card 1/ 4
S/148/60/000/002/007/008
The~Effeot of Sintering Conditions on the Strength of Carbide Base Alloys
Carburized by a NiAl Compound
for TL3 carbide, 6.16 &/cm3 for Ti6O carbide. The alloys were prepared of Ti-
carbide powder and complex Ti-W-carbides. Powders of the initial material
were mixed in alcohol for 48 hours, dried in air, pressed into briquets and
dri,4d In a vacuum cabinet. Sintering was carried out in argon and hydrogen
atmosphere, in a laboratory vacuum furnace with a graphite shaft and In a
TVV-2 furnace. Optimum sintering conditions were determined from the results
of measuring the strength, hardness, speciflo weight, and changes in the com-
position of the alloys. Greatest changes in the composition were otserved in
sintering Ti-carbide-base alloys In a vacuum. Loss of individuall ccmponents
through sintering was oaloulated after ainterirA in a vacuum, hydrogen and
argon for 1 hour at 1,7000C. The loss amounted to 15% TI, 67% Al and 13% C
of the total amount of the component in the alloy prior to BinterIng.
Minimum loss was observed in sintering in pure argon. Table 2 contains the
composition of the T100B (15) alloy prior to and after sint-ering under
different conditions. The strength of alloys during bending was investigated
with the aid of a special device on a two-ton testing machine at high temperatures
card 2/ 4 q/
8/148/60/000/002/007/008
The Effect of Sintering,Conditions on~the Strength of Carblde Dane Alloys
Carburized by a NIAI Compound
without shielding atmosphere. Figures 1 - 5 show the effect of the sintering
temperature on the alloy strength during bending. Highest strength of Ti-
carbide'base alloys was obtained by sintering for I hour at 1,9000C. A raise
of the sintering temperature up to 2,1000C did not affect the strength (Figure
1), although shrinkage and density of the alloys increased. Extended holding
up to four hours entailed decrease in strengthl holding time reduced down to
0.5 hra entailed a decrease in density. The authors oontradict the statement
made in [Ref 41 that the optimum temperature of sintering for a TIC-NiAl alloy
was 1,6500C. They proved experimentally that alloys of highest strength and
density.were obtained at 1,9000C and above. It was-establiahed that optimun
mechanical properties of the alloys depended on the optinram amount of the
licraid phahe during sintering. To obtain this, alloys with a lesser content
of'binder should be sintered at higher tempgratures which ~ralse the amount
of the liquid phase due to the dissolving of the carbide component.
Card 3/4
q/148/60/000/002/007/008
The Effect of Sintering Conditions on the Strength of Carbide Base Alloys
Carburized by a NiAl Compound
There aret 2 tables, 5 graphs and 7 references, 6 of which are English and
1 Soviet.
ASSOCIATION.- Moskovskiy inatitut stali (Moscow Steel Institute)
SUBMITTED-, May 25, 1959
Card 4/4
q-410o 1451
858211
S/148/60/OW/003/015/018
A i
AUMORS: ~bzzhukh1n,_Ye.I,; YFlyutin, V.P.; Umanskly, Ya.S.
1)
Strength of Carbide Alloys emented illAl and'CoAl Compounds
TITLE: bV
PERIODICAL: Izvestlya vysshikh tichebnykh zavedeniy. Chernaya rje*,allurgi,,ra,
1960, No. 3, PP. 131 - 135
.11 -_1 61
TEXT: An Investigation was carried out with titanium and titanium-tungsten
carbide powder bound with NiAl and CoAl compounds. The effeit of the composition
and of different quantities of the binders was determined. The results are illus-
trated by curves. In case of titanium carbide with 15 volume % NiAl the binder
composition bad no effect on the alloy strength at room temperature, but a pro-
nounced effect was observed at 1,0000C. Alloys bound with binders of stoichiome-
tric composition proved strongest, and alloys bound with NIA1 with 60 atomic %
Ni weakest. Alloys with over 025 -vol=e % NiAl have the maximum strength. The
strength of TiC-NiAl at 1,000 C was in all cases higher than at room temperature,
which not fully corresponds to statements made in a previous investigation (Ref.3).
Me alloy with high NiAl content had a considerably higher heat resistance than
with low NiAl content. Titanium- tungsten carbide T-15 (T-15) and T -60 (-1-60) were
bound with CoAl with 60 atomic 56 Co, with 10 and 15 volume % CoAl, respectively.
Card 1/2
S/148/60/WO/003/01,=/018
Strength of Carbide Alloys (bmented by NIA! andCoAl Can - A16l/AO29
pounds
A higher strength was observed in alloys with 15 and 20 volume % of NiAl at 9000C
than in cold which is explained bv higher plastioity of NiAl at c)OOOC. At. higher
temperature the alloy strength dropped. The high strength of TIC-NIAl alloys in
hot state Is apparantly also due to the plasticity of NIA1 and stress redastribu-
tion. This phenomenon had been observed by G.S. Kreymer, O.S. Safonova and A.I.
Baranov (Ref. 4) in WC-Co alloys (maximum strength at 2000C due to softened coball-)
The following conclusions were dravni: 1~' Titanium carbide alloys bound with NiAl
j -
have higher bending strength at 1,0000C than at room temperatire. 2) Titaniim-
-tungsten carbide alloys with 16% titanium carbide bound by NiAl retain their
strength up to 900-1,OWOC, 3) Titaniiur-tungsTen carbide bound with CoAl has a
higher strength than analogous alloys bound with NiAl. 4) At room temperature
the strength of titanium carbide alloys doeq, not depend on the composition of NIA1,
but at 1,OOOOC It does. At 1,OOOOC alloys bound with NiAl of stoichiometric com-
position have maximum strength. 5) The carbide base composition is Important for
alloys bound with NiAl. and CoAl. Alloys with pure titanium carbide and titanium-
tungsten alloys with high titanium content (64% T-10 have low strength at room
temperature, bulk, they retain their strength or even Increase it at 1,000 - 1,1000C.
There are 4 figures and 5 references: 3 So7i,~t, 2 EnglIsb.
Card 2/2
81002J601000100810021002
0111/0222
AUTHOR: YeIntin, V.P., Minister of the Advanced and Intermediary
SpOUM BdUCAM5 of the USSR
TITLEt On the Condition and Problems of the Preparation of Specialists
in the Domain of Meohanisation and Automatization of the
Engineering-Technical and Administrative-Managing Work in th* USSR
PERIODICALt Veetnik statistikif 1960, No.8p pp. 29-32.
TEXTo' The specialists in the domain of the mechanization and auto-
matization of the engineering-toohnical and administrative work need a
good finishing education in mathematics, electrotechniquep electronics
and computers. Therefore there exists the special branch "mechanization
of accounting and calculating problems" at suveral high schools. In
1959/1960, 1489 students learned in this special branch. From 1950 to
1959, 1322 students finished this special education, among them 700
oompletecitheir studies at the Moskovaiiy ekonomiko-statisticheskiy
inatitut (Moscow Economical-Statistioal InatLtute) and 3Q0 at the
Moskovskiy aviatsionnyy inatitu-t(Moscow Aviation Institute). Furthermore
the specialists in question were prepared in the mathematical faculties
in the Moscow and Leningrad universities. In spite of this the specialists
Card 1/3
SIOO
JY601000100810021002
C11 C222
On the Condition and Problems of the Preparation of Specialists in the
Domain of Mechanization and Automatization of the Engineering-Technioal
and Administrative-Managing W6rk in the USSR
in question are not sufficient. Therefore it is considered to educate
the specialists also in the Khar1kov Engineering-Economic Institute$ in
the Moscow Mechanical Engineering Evening Institute, in the Moscow Poly-
graphical Institute, in the Moscow Historical Archives Institute and in
the Moscow Engineering-Ea 'onomic Institute. Since 196011961 the education
in the special directions "mechanization of the accounting and the
calculating problems" and "programming on quickly working mathematical
machines" is given in secondary schools. At the same time an advance of
the quality of the preparation ahall be reached, theoretical and
practical educations shall go hand in hand. The establishment of books
is essential. A strengthened mathematical preparation of the students is
aspired. A research on the domain of mechanization on a broad bass is
essential. This research is performed already successfully at the
Moskovskiy gosudarstvannyy universitet (Moscow State University) at the
Loningradakiy institut tochnoy mekhaniki i optiki (Leningrad Institute
of Fine Mechanics and OptiGe), Moskovskiy energetichaskly institut,
Card 2/3
S10021601000100alOO21002
0111/0222
On the Condition and Problems of the Preparation of Specialists in the
Domain of Vechanization~ and Automatization of the Engineerlng-Techn.'Lcal
and Administrative-Managing Work in the USSR
(Moscow Power EnginesTing Institute), Moskovskiy inabonerno-okonomicheekly
institut (Moscow Engineering Economical Institute) and the Moskovskly
ekonomiko-statiaticheakiy inatitut Q!opcow Boonomical-Statiatical
Institute). There are still too little disse'rtafi-o"n's -6-ii -theiies of this
special branch. A better notice of foreign experiences idnecessary.
Card 3/3
YZIZUTIN, V.P.; EITAYGORDDSKIT, I. I.; JUSPE N, TO.I.; R&EKIN, T.B.
CowpooltIon of microlite and of the metallic comvund JIIAI.
Zhur.prild.khim, 33 w-3:559-563 Mr 160. (KIRA 13s6)
1. Moskovskly inatitut stali i Moskovskiy khimiko-takhnologi-
cheskiy Institut.
(Nickel compounds) (Aluainum compounds)
AUTHORSt Yelzutin, V. P., Natanson, 5/032/60/036/03/036/064
shulapoy., V.-J., rUdkovskly- 8- T BbIO/BI17
TITLEs A Device Used to Mew=9 the Electric Resistance of Alloys at High
Temperatures
PERIODICALt Zavodakays laborstoriya, 1960, Vol 36, N'r 3t PP 344-346 (USSR)
TEXTs A special device has been designed (Fig 1) for measuring the electric
resistance of samples I x G x 20 up to 10 x 15 9 40 am in size and used in powder
metallurgy, at 2000 to 25000, with a standard furnace of the type TVV-4 used to
heat the samples. The sample is attached to molybdenum- or tantalum electrodes
by spot welding. The electric resistance is measured by the compensation method
(Fig 2, circuit diagram), and calibrated resistqrs are used which were
V
calculated by the following equations R. W R V (Rxand RE- electric
resistances of the sample and the calibration sample, V. W voltage drop in the
samplev VE- voltage drop in the calibration sample). Phase transfoxmations
occurring in Ni-Al-Be alloys were investigated, and it was found that the
electric resistance ranging between 0.1 and 0-5 ohm has to be measured at
Card 1/2
A Device Used to Measure the Electric Resistance B1032160103610310361064
of Alloys at High Temperatures 3010/3117
0-01 to 0-05 a at most since otherwise the sample heats up excessively. The
sharp change of the electric resistance and the temperature coefficient of the
electric resistance as a function of temperature which has been observed in the
alloy consisting of 55.5 atom % Ni, 37 atom % Al, and 7-5 atom % Be at 14000
in attributed to a transition of the alloy from the two-phase to the one-phase
state. There are.3 figures.
ASSOCIATIONs Moskovskiy institut stali im. I. V. Stalins, (Moscow Institute of
Steel ineni I. V. Stalin)
Card 2/2
M65
s/148/61/000/007/001/012
E073/E335
AUTHORS: _yelyutin, V.p., pavlov, Yu..A., Surovoy, Yu.N. and
Shulenov, V.I.
TITLE. Electric Conductivity-and Thermal Expansion of
Vanadium, Molybdenum and Tungsten Oxides
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy, Chernaya
metallurgiya, 1961, No. 7, pp. 12 - 17
TEXT: The oxides V20 51 moo 3 and WO3 are n-type semi-
conductors. The electric conductivity of V 205 was investigated
by several authors within a very wide range of temperatures
(-200 to + 1 200 OC). One of these authoradid not study the temp-
erature range of interest to the authors of this paper, whilst
the results of the others might have been influenced by the
interaction of the V 205 with crucible material. As far as the
authors are aware, data on the electric conductivity of MoO 3
and WO3 are available only for temperatures below 200 0c, in
Card 1/9
2,5065
s/148/61/000/007/001/012
Electric Conductivity .... E073/E335
this paper, specimens for tests were produced from oxides of
high purity by pressing and sintering in an oxygen stream.
2
The applied pressure was 1 5 t/cm The specimens were sintered
at 600 oc (V205), at 700 '~ (m003 and at 1 000 OC (WO3). The
tests have shown that to obtain a stable density and electric
conductivity the specimens have to be held at these temperatures
for about 6 hours. The electric resistance of these specimens
was measured on a potentiometric instrument convisting of a
potentiometer, a mirror galvanometer and a DC source. The
measurements were made at elevated temperatures by means of
apparatus, a sketch of which is shown in Fig. 1 0 - test
specimen, 2 thermocouple; 3 - heater; 1* - stainless-steel.
tontainer; 5 lid-, 6 - stress-bearing current leads;
7 - clamping arrangement; 8 - pressure-current leads). The
results have shown that the plots - reciprocal of the temperature
ver-sus logarithm of the specific conductivity -- have a pronounced
bend located somewhat lower than the observed temperatures of the
beginning of reduction of these oxides with carbon.
Card 2/9
28065
S/148/61/000/007/001/012
Electric Conductivity .... E073/E335
Figs. 2, 3a and 3ra show the dependence of thn electric,
conductivity on the temperature and the reciprocal of the
temperature, 1.04/T . for V2051 M003 and W03 , respectively;
In Fl.g. 3 Curves 1 apply to the heating and Curves 2 to the
cooling process. The bSnds were observed at about 380 OC 0
for V20 57 at about 460 C for MoO3 and at about 700 - 725 C
for, WO 3' The temperatures of tho beginning of interaction
of these oxides with carbon are, respectively, 438, 475 and
782 OC. Thus, at temperatures at which the reduction with
carbon begins, a physical transformation occurs. which is
accompanied by a slowing-down in the increase of the electric
conductivity with temperature. From the point of view of the
Semiconductor properties, this corresponds probably to a
transition from i.mpurity- to intrinsic -conductivity of the oxides.
Card 3/9
28065~/i48/61/000/007/001/01 2
Electric Conductivity .... E073/E335
In a special series of experiments with specimens consisting
of V205 and finely-ground graphite, pressed and sintered for
6 hours at n50 0C, it was found that the electric resistance
increased monotonously at all temperatures with increasing
holding time. On the other hand,, the electric resistance of 0
pre,.4sed graphtte powder was found to drop on heatAng to 300 C
and remained constant on further heating~ This behaviour
of oxide-plus-graphite specimens is attributed to Interaction
between them, accompanied by the formation of CO + CO
the carbon consumption of the reduct:ion react.2on leads tc a
de,-,rea~ze in the elertric conductivity of the specimen sinc e
the ranductivity is basically determined by the electric con-
dut.t.ivity of the graphite. It follows therefrom that the speed
of change of the electric resi.stance at various temperatures
clan serve as a characreristic. of the speed of the process
-if reduction of the oxide by the carbon. Fig- 5 shows the
dependence of th speed of change with time of' the e1er-cric:
r#_=-~istan,-~.e (.6-PA ', r,.,0- /min) as a function of the temperature
OC) Zf the V 0 plu-i C specimenA~ a sharp increase was
ard .79 2 5
~
Electric Conductivity ....
2 80 65
s/148/61/000/007/001/012
E073/F.335
0
observed at about 380 C. The conclusion drawn is that the
beginning of appreciable reduction of the oxides coincides
with the transition from impurity- to intrinsic-type conductivity.
The results of dilatometric measurements on V 2 051 MOO3and WO3
specimens, for heating and cooling rates of 150, 200 and
250 OC/h, respectively, are plotted in Fig.6 E V2051 MOO3 (Fig.6a),
0
VO3 (Fig. 66 )],(change in length, p versus temperature, C).
The temperature was measured with an accuracy of + 10 OC and
the length with an accuracy of 0-5 Ii. Thermal expansion occurs
up to 350, 440 and 680 0C, respectively. From these temperatures
upwards, which correspond approximately to the bends in the
temperature-electric conductivity curves, contraction of the
specimens was observed. This contraction is attributed to
polymorphous transformation or to plastic deformation caused
by the measuring equipment as a result of the sharp drop in
strength of the oxide at this temperature. It is concluded that
at the temperature of the beginning of the reduction process, a
change is observed in the physical properties, which is accompanied
Card 5/9
2 8 0 6,5
5/111 8'/6i7OOO/OO7/00i/Ol 2
Electric Conductivity ... E073/E335
by a sharp decrease in the strength of the sintered specimens
and by a slowing-down of the drop in the electrical resistance
during heating. The beginning of the intensive chemical
interaction corresponds with the transition frow impurity- to
intrinsic-type conductivity.
There are 6 figures and 9 references. 8 Soviet and 1 non-
Soviet.
ASSOCIATION: Moskovskiy institut stali (Moscow Steel
Institute)
SUBMITTED- January 25, 1961
Card 6/9
35217
S /I /t 8/6'Vouc/col loollol 5
E039/E435
.Xuti V P. Pavlov, Yu.A. , 7's lao Fu-I.- lang
AUT11ORS: ill
TITLE: The connoction beti-;-eon t,
.)e 1)0-1.-Inin- or red-,Ic,,ion and
the semiconductor properties of oxides
PERIODICAL: Izvestiya vysshikh uchobny1ch zaveden-Jy.
Chernaya -metallurCziya, no.1, 1962, 111-19
TENT: Th emecbanism of reduction of metallic oxidles is
insufficiently understood, particularly fox- tenperatures below
7000C at which the speed of re,(.;encration of the oxides of carbon
is insignificant, hence new ;-.iethods of investigation are needed.
In this work the change in electrical resistance of the hiZhor
oxides of vanadium, molybdenum and tungsten was investigated at
-the temperature of their initial interaction with carbon.
Samples of cornets (2 x 6 x Ito mni) were prepared by pressing the
powdered oxides at 1.5 tons/CM2 and sintering in an atmosphere of
oxygen for 6 hours at 6oo"c (VP-05); 7000C (1)'1003) and SOG"C OWO~).
The electrical resistance of the samples was measured by a
compensating method using a high temperature four-point probe in an
atmosphere of argon at temperatures of 200 to 5800C (V205);
Card 1/2 Y,
S/148/62/000/001/001/01=
The connection between E039/E435
320 to 6oo0c (moo3) and 500 to 8500C W03). The results show
that the resistance of t1te samples has a typical semiconductor
character. A discontinuity occurs in the curves relating
electrical conductivity ,-Ind temperature and it is :010'.-In that the
temperature at wbich tiiis discontinuity occurs is approximately the
same as the temperature at which reduction of the oxides be-ins.
The effect of adding SiOq to V205 i-,ras also investigated. The
transition temperatures are: V-005, 373 to 430OC;
V205 + 0.08" SiO,-), 381*C; V205 + 0.17',o
/0 SiO2, 416*C;
V905 + 0-35% Si02, 11330C; 1,1003, 1115 to 11800C; wo3, 675 to 695DC.
Ii is also shown that the temperature for the initial reductIon
of the oxides depends on the width of the forbidden zone .'-Eo.
The larger /"Eo the highcr the transition temperature. The
addition of SiO2 raises the transition temperature of V`05 and
simultaneously lowers its chemical activity. There arz
3 figures and 2 tables.
ASSOCIATION: Moskovskiy institut stali (Moscow Steel Institute)
SUBMITTED: June 17, 1961
Card 2/2
35224
s/148/62/000/001/009/015
E073/E535
AUTHORS: Voleynik, V.V., 11fin Lysov, B.S. and
Mauralch, M.A.
TITLE: Electric conductivity of solid and liquid titanium
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy, Chernaya
metallurgiya, no.1, 1962, 137-140
TEXT: Although data on the electric conductivity of
titanium up to temperatures of 13000C have been published, similar
data relating t.o near-fusion temperature and to the liquid state
have not been published. An electrod6less method was applied for
measuring the resistivity of titanium. This is based on measuring
the stationary torsion angle of a sj~ecimen suspended on an elastic
thread in a rotating magnetic field. The stator coil winding of
the measuring instrument was provided with a high temperature
insulation and the coils were placed inside a water-cooled steel
housing. Graphite heater elements *ore used which permitted
obtaining temperatures tip to 25000C. The method of measurement of
the resistivity is similar.to that applied by other authors for
measuring the resistivity of molten metals. The temperature
Card 1/3
Electric conductivity of solid ... S/148/62/000/001/009/015
E073/E535
dependence of the resistivity of titanium e , mohm-cm is plotted
in a graph. Curve 1 represents the values obtained by the author
of this paper, curves 2 and 3 are published values. For the liquid
metal t-i values were obtained: A - for melts produced in ThO 2 or
BeO crucibles, B - for melts produced in graphite crucibles. The
author points out that the data for liquid titanium at 18000C
(points A and B) are not entirely reliable and should be verified
with a crucible material less active towards liquid titanium than
the graphite, thorium dioxide, and beryllium'oxide used in these
experiments. From the test results the temperature coefficients of
a- and P-titanium wero detorminod. Th'e specific resistance of
a-titanium in the temperature range 20 to 4500C can be expressed
by 61.5 [ 10-3
1 + 2.48. (t - 20
and for,P-titanium, in the temperature range 880 to 17000C, can be
expressed by -4
ep = 143 1 1 + 2.13-10 (t - 8801
There are 1 figure and 11 referencesi 5 Soviet-bloc and 6 non-
Soviet-bloc. The four latest English-language ref ces read
s Ref.2; McQuillan A.D. J. Inst. Met ., 78r,20qg, 1950-51;
ar~oi~Sws:
e
I.fl.ectric conductivity of solid ... s/i48/62/000/001/009/015
n073/13135
Itcf-3: T.L.Iiyrtt.,rrans.Amer.Inst.min.(metal) 1,',zigrs-197,903,1953!
Ile f. It :W.C.14fichels, S.-i-alford. 1]'IIYB.Rev. 76,1711,19119, 11cf-10:
13.Weber, M.Thompson. J.Amer.Cernmesoc- 40(11), 363, 1957.
ASSOCIATION: Moskovskiy institut stali (Moscow Steel Instittite)
SUBMITTED: April 6, 1961 p. rnohm-icm
J00
/.V
Figure
Card 3/3
T" C
GORELIK, S.S.; YELYUTIN V .; MOZ$UKHINL Ye.I.1 URAZALIMV# U.S.; FUNKE, V.F.
X-ray investigation of rearystallization processes of titanium.,
zirconiumt.and molybdenum boridem, and titanium and tungsten
carbides. Izv. vys. ucheb. zav.; tavet. met. 5 no.41143-148
#62. (MIRA 16:5)
1. Moskovskiy institut stali, kafedry redkikh metallov.. fiziki
metallov i rentgenografii.
(Boridea) (Carbides) (Crystallization)
a/126/62/014/003/Oi4/022
B193/9383
AUTHORS: 1 tin, V.P., Momzhukhin, YeeX., Panov, A.V. and
1 "1 V*P*'
K~ ~ha I ~il t n ~k.
.TITLE: Study of internal friction of copper on specimens
prepared by powder-metallurgy techniques
PERIODXCAL: Fizika metallov i metallovedeniye,~v. 14# no* 3.
1962, 443 - 451
TOM The object of the present investigation was to
study the effect of various factors (compacting pressure,
sintering conditions) on the internal -friction of green and
sintered copper-powder specimens. The test pieces
(70 x 5 x 0.5 - 1.5 mm) were prepared trom electrolytic copper
powder (20 - 30 It particle size), 99-915% purity, whAch had been
given a preliminary reducing anneal (2 hours at 400, C) in
hydrogen. The internal friction was determined by measuring
the amplitude of forced oscillations of thl'specimen near its
resonance frequency on an apparatus designed by one or the
present authors (a dekeription is given of both the equipment
.,.and experimental procedure)* Typical resuits are reproduced
Card,.I/
S/l26/62/ol4/oO3/Oi4/022
Study of iiternal friction E193/E383
in Figs. 3'and 5. InFig- 3, the internal :friction (~an 6 X 10
of green ompaets,prepa~red under a pressur4tof 4 t/cM , Is
plotted against temper:Aure (00, curve 1 representing the
results obtained on h64ting a freshly pirepgred compact, curve 2
showing th6 results olAained on subsequentt~6o4ing. Fig. 5
shows the temperature dependence of tan 6 X"10 of compacts
sintered at 900 OC in ~L'vacuum (curve 1)'anct'hydrogen (curve 2).
Several co'i~clusions we*i"e reached; 1) Temperature-dependence
of internal'friction of green copper-powder compacts have
two peaks: a low-temperature peak associated with the grain-
boundary effect and a high-temperature peak associated with the
presence of oxygen; thp internal friction of green compacts
decreases with increasing compacting pressure. 2) The internal
friction of green compacts, measurle d during the first heating.
~cycle, in lower than thAt observed during subsequent cooling;
this can be attributed'to sintering taking place during the
first heating cycle and'during the first intbrnal-friction
measurements, 3) The high-temperature peak disappegra if
isintering is carried out in hydrogen at 900'- 1 000 C&
Card W'd
S/126/62/014/003/014/022
Study of internal friction .... E193/E383
0
4) On increasing the sintering temperature from 600 - 900 C
the height of the low-temperature peak increases and the peak'
is shifted toward s higher temperatures; further increase in
the sintering temperature brings,about &.decrease in the height
of this peak. These effects indicate chat on raising the
sintering temperature from 600to goo C the contact ar.ea
increases at a rate faster than the rate of the grain orowth;
on raising the sintering t emperatur e 'from... 900 to 1 000 C the
rate of grain growth becomes faster.., There are 7 figures.
ASSOCIATION:. Moskovskiy institut-stali *(Moscow Institute
of Steel)
SUBMITTED: Februark 5j 1962
Card 39 5
AUTHORSi
T-TLEs
5/032j62/028/009/007/009
B104/BI02
Yelyutin, V. P.,, Panov, A. V., Natanson., A. K.,. Shulepov,
*7. ~-., ~a~V~asiilyev, 0. A.
A device for measuring the internal friction and shear
modulus at high temperatures
PERIODICALi Zavodskaya laboratooftya, v. 28, no. 9, 1962, 1123 - 1126
UXTj This device can be used to determine the internal friction and
shear modulus from the damping of torsional vibrations in wire samples
(0.2 - 1 mm diameter) at temperatures up to 25000C. The sample is
suspended vertically inside a tubular tungsten beater and has's zone
100mm long wherein the heat increases uniformly. Bits temperature is
Measured by a thermocouple whose hot junction is situated half way u;ong
it. The sample is fixed-at its upper end whilat'the lower end is twisted
by a vibrating mass. The latter has two long arms which carry permalloy
magnetic cores to excite torsional vibrations in the sample, which are
visible and are recorded magnetoelectrically. At temperatures below
10000C the number of vibrations is counted up to a certain value after
Gard'1/2
S/032/62/028/003/007/009
A device for measuring the... B100102
which their amplitude decreases. Above 10000C the amplitude of each
individual vibration is measured. The measuring error is only %Q Und
increases only slightly at very high temperatures. There are 4 figuren.
ASSOCIATIONj Monkovskiy institut stali i splavov (Moscow Institute of
Steel and Alloys)
Card 2/2
3/076 62/036/007/007/010
BIOI B130
iXTHORS: ,'f-elyutin, V. P. Pavlov, Yu. A., Shuiepov, V. I., and 14yaki-
3he~a,
TITL',--,: Electrical resistivity of V20 5' 1400,1 and WO 3 when heated in.'
hydrogen atmosphere
K-IRIODICAL: Zhurnal fizicheskoy khimii, v. 36, no. -7v 1962, 1.524 1527
TEXt: The initial stage ofthe reaction of V 0 moo and 710 with H
2 51 .31 3 2
vias studied by meazuring the electrical resistivity (apparatus see Izv.
vyssh. uchebn.* zavedeniy, Chernaya metallurgiya,-no. 7, 1961). Oxides
sintered in an 02 flow for 6 hr were used. At all temperatures applied
(200 - 7000C), resistivity was und'to diminishoin the course 0
f8 C 8*heating.
JR/RAZ-for V 0 was 0.002 at 250 C, 0.004 at 300 , 0.007 at 350 C,-O.016
at '7750C, an3 8.027 at 3800C (start of reaotion with H ). For moo- and
2 3
710 AIVR47"rose slowly at low temperatures, and'rapidly n4ar the beginn-
3'
Card
S/076/62/036/007/007/010.
Electrical 'resistivity ... 11101/D136
ing of reaction with 112(4300C for MoOV 6300C for WO3 The slow rise
corresponds to the extrinsic conductivity of the oxides with chemisorbed
H2 reacting as donor with the oxide, while the steep rise of the curve is
due to the changeover to intrinsic conductivity. Here, an-intense reac-
tion with F.2starts in the gaseous phase owing to sublimation (diesocia-~
tion) of the oxide. There are 4 figures and 1 table.
ASSUCIATION.., t:oskovskiy institut stali (Moscow Steel Institute)
ITTED: Ularch 1
1960
ja/ja RU PMN.Vp 51)(c) XULl
ACCESSION NR: AT4048120 8/0000/63/000/000/0065/0%4
crmorea in rn reniamu eiont7nuan azter rrarm w-Rta Trnm zp-rn in tt,- rir2t in* to imyn in t"
C-3111