SCIENTIFIC ABSTRACT YANOVSKIY, K.A. - YANOVSKIY, N.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962110020-9
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I ) 104-3-32/45
Au,BIOR: Prokhoroval A.M., Engineer, Prokhorovt F.G. and
Yanovskiy, K.A., Candidates of Technical Sciences.
TITLE: Experience of using total chemical de-salting of water
on an industrial scale. (Opyt primeneniya polnogo khimich-
eskogo obessolivaniya vody na promyshlennykh ustanovkakh)
PERIODICAL: "Elektricheski-ve Staitsii" (Power Stations), 1957,
Vo--1.28. No-3. pp. 80 - 83 (U.S.S.R.)
ABSTRACT: The chemical method of water de-salting is to be widely
used during the sixth Five Year Plan. This note gives brief
information about this new method of purifying water as it
has been applied at a number of $oviet power stations. One
equipment with an output of 50 m/hour consists of eight ionite
filters. The circuit is given, it consists of first stage
H-cation exchange, first stage anion exchange, decarbonating
and second stages of cation and anion exchange. The processes
are described. Somewhat different circuits aie used in other
stations. If the process is coriectly operated very pure
water is pioduced. The total salt content not exceeding 0.02
Card 1/1 mg/l (without SiO'). It may be used for single-pass boilers
without evaporators as well as for drum type boilers. Full
scale tests axe to be carried out at power stations. There are
6 fJ 1 Slavic reference.
LABLS~garea and
AVAI Library of Congress

XXIA"C' V-~11,/VNI j
~7,--
LIVSHITS, I.; YANOVSKIT, L., aspirant.
Tetrahedrons in hydraulic engineering. Mor.flot 17 no-10:30-31
0 '57. (MIRA 10:12)
l.Glavn7y inzhener proyektn07 kontor7 tresta "Gidromekhanizateiva"
Ministerstva stroitelletva RSFSR (for Livehits)
(Hydraulic engineering)
M,
-N-

YMIOVSKIY, L.A6, kand.med.nauk; OSTAPKO, K.I., hand.med.nauk
. ..................
Epicritic sensitivity in the defects of extremities and its
importance in training for work and in prosthesis. Trudy Ukr.
nauch.-issl. inst. ortop. i travm. no.35:Z49-254 159
(MIRA 16:12)
14 Iz Ukrainskogo tsentrallnogo nauchno-iseledovatelliskogo
Instituta ekspertizy trudosposobnosti, I organizataii truda
invalidov (dlr. prof. A.P. Kritor).

Y~~VSKIT, L.A.
Medical testimony on neurogenic contractures following Canshot wounds
of the peripheral nerve trunks. Zhur.nev. i paikh. 59 no.6:735-741 159.
1. TSentrallnyy ukrainskiy inatitut ekspertizy trudosposobnosti i trudo-
ustrosystva Invalidov Wir. - prof. A.P. Kotov), Khar1kov.
(MMVES, PERIPHERAL, wds. & Inj.
gunshot wds. causing contracturee, work capacity
determ. (Ras))
(COYMCTURE, etiol. & pathogen.
peripheral nerve gunshot wds,, work capacity determ.
(RUBD
(WMK'
capacity determ. in contractures caused by peripheral
nerve gunshot wds. (Rua))

DERGACIIEV,' N.F., kand.takhn.nauk,, YANOVBKIY, LsPe, inzho
Scrubbing of the flue gaBes of the TP-40 steam boilers,
Toploonergetika 8 no.6:20-24 Je 161. (KMA 14:10)
1. Vsesoyuznyy teplotekhaicheskiy institut.
(Boilers) (Scrubber (Chemical technology))
7777M

- . , , - ~ ir
U V -.T-EN 'I-Tj 4"
- ~V'
GOWLERG, M.; YA-TIOVSKIY. 14,
Shipment of Goods
Standardize accounting of delivery of shipped goods. Dan. i kred. 11 no. 5. 1952.
Monthly LI-st 2f Russian Accewsions, Library of Congress, August 1952. Unclassified.

FUMY-
YANOVBKIY, M.A.; KRYLIN. G.S.; LOZOVSXIY, V.L.
Anticorrosive fluz for soldering with soft solders. K*d.pron. no.3:
38-39 JI-S '55- (KLRA 9:12)
1. Hadiko-instrumentall Wy ordena lenina zavod "Irrasnogyardaysts."
(APPARATUS AND INSTRUMENTS,
anti6orrosivo soldering)

UNOVSKIY, K.A.
Kschanization. of grinding; drum grinding under vater. Med.prom.
11 ho.1:19-25 Ja 157. (MMA 10: 2)
1. Mediko-instrumentallnyl ordena lanina zavod 01rasnogvardayet-aw
(GRINDING AND POLISHING)

T"OVSKIT, N.A.
----------------,U'eal removal of projections from Plastic parts. Wed.PrOlde
Mocha i (nu 13:6)
14 no.608-49 Je 160.
1, NedIilm-lustrumOutallnn zavod lUagnWardayeta"s
(PUSTICS--MDLDING)

ACC NRt -AT7005057. SOURCE CODE: UR12649A66100012321005010055
-1AUTHOR: Gordeyev, A. S. (Doctor of technical sciences, Professor); Klokov, V. G.
(Engineer); Yanovski ..M.,F.,.(Engineer')
,ORG: None,
-ITITLE: Effect of the shape-of blade profiling on the chara.cteristics of atype
TP-1000 hydraulic coupling
SOURCE: Moscow. Insti tut inzhenerov zheleznodorozhnogo transporta. Trudy, no. 232,
1966. Gidroperedachi teplovozov i gruzopod"yemnykh mashin (Hydraulic transmissions of
diesel locomotives and hoisting machines), 50-55
TOPIC TAGS: hydraulic engineering, hydraulic device, blade profile, sheet metal
ABSTRACT: The article is a report on experiments conducted in the Hydraulic Transmis-1
sion Laboratory of the Moscow Institute of Transportation Engineers in conjunction with
the Kaluga Machine Building Plant to determine the effect which the shape of blade pro-'
Ifiling in the pump runner and two reactor*wheels has an the characteristics of a type
ITP-1000 hydraulic coupling. Comparative tests of conventional bladea made according
-to plant drawings and blades of constant thickness notched on the input and output
ledges without mechanical finishing of the working surfaces, as well as experiments on
a hydraulic converter model with artificial distortion of the blade profiles showed
Card 1/2
0

ACC NR, AT7005057
,the possibilities for effective use of constant-thick-ness blades. The e;gerIL=f_ntZ-_I
I
.TP-1000 hydraulic converter in rude in two versions--one vith a standard blade system
Iand the other with blades in the form of arcs of constant thicknesu with notche3 on
,:the input and output edges-so that the two blade systems may be subjected to c=parr--
:tive tests while eliminating the effect of other factors on the hydraulic characteris-
I
,tics. Tests at pump speeds of 1000-4500 rpm using DT GOST 4749-49 diesel fuel as the
iworking fluid showed that the profiling of the blades in the pump runner and reactors
.has an insignificant effect on the external characteristics of the hydraulic coupling.
This conclusion is important from the standpoint of technological economy since con-
siderable savings can be realized by using blades pressed from sheet steel in bydrau-
ilic couplings of this type. Orig. art. has: 3 figures.
SUB.CODE: 13/ SUBM DATE: None/ ORIG REF: 03

KOGTRV, Petr Nikolayovich; MOVSKIX, H.I.j red.1 SEDOVA, Z.D.,,
red.izd-va; SHIEY.DVA_, R.Te., tekkn. rmL
(Financial plan of a woodworking enterprise]Finansovyi plan
derevoobrabatyvaiushebego predpriiatiia. Mosk7a,, Goslesbum-
izdat, 1962. 105 po' (MIERA 16:3)
(Woodworking industries-Finance)

YANOVSKIY, M. I.
"Experimental Investigation in the Field of Sorption Separation
of.Gas Mixtures." Sub 15 May 47,, Moscow Inst of Chemical Machine
Building . I
Dissertations presented for degrees in science and engineering
in Moscow in 1947*
I
SO:; 8=. No. 457s 18 Apr 55
4"YVI,

Chemical Abstracts Ii oll

room d! I
Vol. 48 No. 5
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Mar. 101 1954 a
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e C.A. 47,10310i.
General and Physical.Chemistry

~t, K a
..Chemical Abst.
Vol. 48 No. 9
.May 10, 1954
General and Physical Chemistry
hromat ra h h t
. Y Y
IfT..'Y"d "PO 8 o "no 10), 70- 85:
(w , a-,e ,
cf. C-4. 47, 1031 I.-By an& gy 2t"h., .1,1 C, zl., -
d V. write 1. ec,
tion ou bornogtricous surfaces.R rn
surfacei (over a restricted
inMography on lietero eneou
tinge of conen. chanjef P(Q) - C v7jif h T, whrre p(Q) h
ithe d1stribution function for licit o whorption Q, C il
;concn. at the time vol. V has passed titrough a led of
length z contg, H jr. of packing per unit I~nsth-
it. 1. Kandincr
;2
DISKS
4~i 1W:. j A~~ -
IV t

in k9don of peas in dynamis soaditions. S. Z.
d and M-,I. Vangvskil (Acad. ".. U.S.S.R.,
R724. 137-43(likWI).-Jillsts.
Z&vr. 0; . n
-4 &If Willi C(h. Wiltylvae (1). to Illultene (11) wrtr pata"I
at 20' through 4 tubes Alk4 w tit activIttetl C 4INIk d.
0,47. pAilk-le the 1.4-173 mm.) until The outgoing pi
had the conen. of the Incoming tu (amm. OD12 mal,11.).
Then Ilun air was dowly (a rie cc./min.) forced through
ttw 4 tutwo atut 4 adtful. tubes, equally NW, all In secks,
and the ctwwvi, r 0 OW SM11111111. In the air wits dellf. aft"t
Vve. that postad throtloh,
The rate tot -h-plaernwat lortmilml from 11 to CO,.
r.j~, the cancu. after the 41h tube beconw OAM M4.A.
afirt V - 001), 0110, and I='. ". At a given (latirr)
1'. f lit"rawil firw4vally ftom she let to thir Offs IN 71h
futv awl then 1AP411Y gkffftwvl to -t0. IV Owfoorpthin
ttuiit inerviorif with 1'. The stimirptlovi isolherins of CIA.
Land lion C weretirtd.uplo(PAMISWA. Assurniftillial
the outgoing air was In "oil. with the sint. adsorbed. a
waot calc&, atut the oalca. ctitifirmird by detil. 4 In the It
1111W4 fly em"14vto Ilisplareme"S 44 The ipfmf%t. with N.
alm,w) -umil. rhr equation IltXAj - (4d1j.) I I - (tit.f 1,
wai, YAW; X Is the dIstArtry from the InW, At the al"t, fit
alf.0twilt jWg 4'1-t. 41( the cofuntat. oold to to the total roiWit.
.4 air still alimitt. OWMA"

/A.F, PFAW. Kkiss. 24. ddIAHM-li-Th..
C
i-shvitu, J(C) .1.
I"Sth of the adw"lan Mumn. x the r1humv from itq
orisin In The Mrvct;*n of the dow. v the vol. of ~Ivent
i. derived (runt the ettv" V(r.
by vullhk- Ittirmtkwiti, IwImn and Ismicirv -ire sirld. (tv"t
~ik-soldrsorNlunturvromidiffrrrntimin. Constfurfloni
Art jgivrn for the cow when the suars at the ad-orptlim
column is lem than The JI.v iwceww7 for complete sle%wp-
In". N. "on

"::z t 4 i ~? 4'. ~Ia -Ila ;171~R-!;- q, t, T~7-, 1 -!42 'C-' Y61 A;
~x ~V~~M ~,~4 -x ~~l
ROGINSKIT. S.Z.; YANOVSKIYP 1491-
The theory of chromatography on nonhowPnOOUB surfaces* I* NtsminatiOu of
the distribution function of portions of a solid surface over heats of ad-
eorption from the desorption curves. III. Dynamics of the adsorption of
mixtims on haterogenoons surfacese Bull, Acad, Sci. U.S.S.R., Div. Chan.
Sci. 152, 63-8, 69-79 Efte. translation).'
(CA 47 no.M10310 '53)
jj
A4,

U&SR/Chemistry - Adsorption Jan/Feb 52
"The Theory of Chromatography on Nonhomogenous
Surfaces. 1. Determination of the Distribution
Function of Portions of a Solid Surface by Heat
of Adsorption Taken From Desorption Curves,"
S, Z, Roginskiy, M. I. Yanovskiy, Inst of Phys
Chem, Acad Sci USSR
Iz Ak Nauk, Otdel Khim Nauk" No 1, PP 59-63
Studied the effect of energy nonhomogereities of
the surface on the character of dynamic desorption
~
icvrrea in chromatographic analysis. Found the
USSR/Chemistry - Adsorption
(Contd)
coxmection between the form of the desorption
cm-ves and the function of distribution of surface
portions at adsorption temp. Gives a method for
constructing this function. Obtained eqq of
desorption curves for general forms of distri-
bultion. Gives the limits and conditions under
VhIch this method can be used.
t4
R
0
20 8T4

YANOVSKIY, H.J.; KAPUSTIN, D.S.; NOGOTKOV-RYUTIN, V.A,
The method of rapid etermination of violar radloactirity during
chromatography of Gl labeled gases. Probl. kin. I kat. 9:391-398
157 (Radioactivity-Meaenroment) (MIRA 11:3)
(Games)
(Ghromatographic aTalysts)
A

GAZIYEV, G. A.) YAT-IOVSI-ay, M.
'A Radicmetric Cell for Measuring the Radioactivit.,
Chromatographic Separation of Mixtures," of Gases During the Volumetric-
AN S -~-713F14:7 1
Dt~

20-.1l8-4-28/6X
AUTHORSs Sinyak, Yu. Ye., Roginskiy,*S,
J1emb6r.qf_'the AS*jJ$SH, Tanovskiyt U. I.
TITLEt The Isotopic Exchange of Carbon Dioxide Chemically Adsorbed
on an Iron Catalyst in the Synthesis of Ammonia (Izotopnyy
obmen C02, khemosorbirovannoy na, zheleznom katalizatore
sintaza ammiaka)
PERIODICALt Doklady AN SSSR, 1950, Vol. 118, Nr 4, PP- 727-730 (USSR)
A.BSTRLCT.- The catalytic synthesis from nitrogen and hydrogen at an ison
catalyst with aluminum- and potassium additions has already
often been studied. The nature of the accelerating effect of
these additions has hitherto remained unexplained. The second
author emphasized in a previous work (reference 2) the exploi-
tation of the velocity measurements of the isotopic exchange
between the atoms of the surface and the gases. The kinetic
isotopic method has a number of advantages, campared to the
former methods (references 1,3-5) suggested for the study of
the heterogeneity. If it is used,,the probability of a re-
distribution of molecules decreases and all measurements are
Card 1/4 carried out with an unchanged filling of the surface, which

The Isotopic Exchange of Carbon Dioxide Chemically Adsorbed 20-118-4-28/61
on an Iron Catalyst in the Synthesis of Ammonia
is essential. The exchange velocity of chemically adsorbed
c4rbon monoxide at the same catalyst has already been studied
(reference 6). The velocity constant of the exchange decreased
gradually in these experiments which cannot be explained by
the influence of the interaction. The iron catalyst was double-
-activated, reduced, and passivated outside of the reaction
system. Active carbonic acid was produced from BaC1403 and
H2SO4 of 96~. The inactive carbonic acid was formed in a py-
rolytic decomposition of Na2CO3. Figure 1 gives a scheme of
the experimental plant. The lower curves of figure 2 show that
adsorbed C02 i*n atmosphere of CO ' H and Ar at a pressure
Of 500 mm torr. is not desorbed. in t9e, case of presence of
C02 iAthe plant a quick rise of the activity is observed in
the gas phase. After the equilibriuzi had been reached C02 was
freezed out in a calibrated container ( figure 1,4) which was
fitted out with an and-counter MST-17. Then the total acti-
vity (A IAust 0A Iobm ) of the CO2 was determined. It was found
that AIAust forms a quantity of approximativelY 40-50% of the
Card 2/4 total quantity of the ~&dsorbed C1402* Then an equal quantity

The Isotopic Exchange of Carbon Dioxide Chemically Adsorbed 20-118-4-28/61
on an Iron Catalyst in the Synthesis of Ammonia
of inactive C02 was introduced into the oatalyat. Tile activity
(A IIAust ) in the gas phase increased unimportantly. This ope-
ration was carried out a second time. No rise of the activity
(A,I Aust) was found in the gas phase. Then the reactor was
heated up to 4750C. Thus an activitj appears in the gas phase
which amounts to approximat_,ely 2o% of the total activity
which was absorbed by the contact. Only the introduction of
hydrogen at 4750C into the circulation makes possible the con-
sumption of the residual activity. Figure 3 shows the second
experimentla series. The trained catalyst had to absorb a cer-
tain quantity of inactive C02 and then a strictly dosed quan-
tity of active C140 2* Then the kinet .ic experiment was carried
out. In the second experiment an equal quantity of C140 2 was
absorbed by the catalyst immediately after the draining and
then the curve of the isotopic exchange was recorded (figure
3). Hence follows that the exchange percentage depends on the
Card 3/4 sequen ce of the absorption. If C14 0 2is absorbed first, the

The Isotopic Exchange of Carbon Dioxide Chemically Adsorbed 20-118-4-28/61
on an Iron Catalyst in the Synthesis of Ammonia
exchange portion is lower by 15-20% than in the case of a re-
verse sequence. Figure 4 shows the exchange velocity of C02 in
experiments in which first 2,85 om3 of inactive C02 and only
0-42 ml of active C1402 act on the catalyst. In this case the
exchange portion amounts to approximately 6o-65%. The given
data point to the existence of two sections which differ accor-
ding to their properties sharply:&Om one another and are cha-
raoteristic of the alkaline part of the surface of the catalyst.
'The exchange mechanism is apparently approximated to that of
carbonate-alkaline and alkaline-earth elements (reference 8
There are 4 figures, and 8 references, 5 of which are Soviele
SUBMITTED: July 25, 1957
AVAILABLEt Library of Congress
Card 4/4

OHM SOV 12 ci-,12 -:14 /67
T., Grziyev, G.
'na 1.
T ITLE: Application of .'rorzyitlA v~-in J.n Grt~eou:-,-Liquld 17hromato-
graphy of Radioactiv,~- Find Not-4ndioactive Gasps (Primeneniye
frontallnogo analiza v gazo-zhlikoctroy khromatojr-afii rpdio-
Pktivnykh i n,~,radtortktivrvlca g~,,zcv)
PER IODIUAI, Doklady Akademii nauk SSSH, 1958, Vol., 12o, Nr 4j PP. 612-814
(USISR)
ABSTRACT: The frontal gaseous-liquid analynis is not videspreqi in
practical analysis since with th4a r:ethod the dynnmiest of
adsorption in the layer of the ad3orbent are considerably
complicated by displacement processen. Those processes are
connected with the intleraction of the mixt,=-e comt)onents
during their adsorption on the surface (!leis 1-~). Therolorp
it 18impossible to determ.1ne the composition of tile mixture
fron the frontal diagram directly. Vxhaustive dsta on the
1pothermal linen of adDorution of the mixtures and the infii-
vidual componentn in the entire Investigat-rd fipld of concen-
trA,,-jon are required. for nomputationa. An insurficlontly work-
O)it ndsorption theory of mixturns i)nder ttatic and dynanic
Cal. d. 1 oondi"Inna 9nd the Insufficipncy of the Pxr.,~rimpntnl roz:71,1tz

SOV/ ?o-120-4-34,`67
Applic,ation -of Ana2yois in Gaevorf. -Liquid Chrommatri-rrayhy of ~?adio-
Pctivti Pnd Piol.-iridiount"ve Cases
in this field limit the application of the mentioned rinnlyoia
to a circle of 9yatems rhich obey the ndsorption equation.,
of the 1-angmulir type (7,engmyur, Refs 9, 3). Th- qtternvt wpo
made of using the frontal analysis In the nontioned chroirato-
gram. Its developirip., 'var4ant found a -videspread ftppiicati~)n
(after the publication of Rof 4). The experiment consisteA
in an uninterrupted passage of the mixture through t~e
column and a taking of it so-called frontal diagram. ft chitr-
acterizes the deWndence he"'ween the concentration of com-
pr,nents at leaving the column and the volurro of the mixtur'~
havAng pasned the column. "Figure I shoyip some frontO dia-
gram!i in a diatomite-,116tyl-phthalate column. Thny prove
triat in a first acproximrition the Interaction of the com-
ponents in the phase rithout mobility may be neglectpd.
Figure 2 shows the ;pof;gibIlity of the ana1yF!i!m of -n 8-com-
ponent mixture (di atomi te-ril troben zone). Firure 2 b cho-Arr it
gaspous-liquid develo-o,ing, chrOMAtogram of the ~~amc- mixture
ap figure 2a. Py comT:z -,,ring the fLmires it crn be eeen thrl.
Card 2/3 each step on -the front~J diagr,-m :orresponds to a dev,~loplng'
-A S

SOVI 2o-120-4-34/67
Application of Frontal Analysis in Gaseous-Liquid Chromatography of Radio-
active and Not-Radioactive Cases
maximum. The analysis mentioned in the title ray apart from
the radiachromatographioal developing variant (Ref 5) be
used for the determination of the specific radioactivity
of the components of a gas mixture, The methods are discribed.
Figure 3 shows a typical radiochromatogram of an air-propylene-
-divinyl-pentans mixture in hydrogen. There are 4 figures
and 6 references# 5 of which are Soviet.
PRESENTED: January 2, 1958, by S. 1. Vollfkovich, Member, Academy of
Sciences, USSR
SUBMITTED: December 31, 1957
1. Gases (Radioactive) -Chromatographia'analysis 2. Gases--Chrorat-
ographic analysis 3. Adsorbente--Chemical effects

5(4) BOV/2o-121-4-28/54
AUTHORS; Roginskiy, So Z, Corresponding Member, Academy of Sciences,
USSR, Yanovekiyq 11, Iqq Zhabrova, G. X., Vinogradova, 0. 11.,
Kadenifs-l,--B-.-Tro-,--gark-ova, Z* A.
TITLE:: A Catalytic Synthesis of Unsaturated Hydrocarbons of the Series
C4' Labelled by the Radioactive Carbon 04, With the Use of
Vapor Phase Distributive X-Ray Chromatography (Kataliticheakiy
sintez nopredellnykh uglevodorodov ryada C
f mechennykh
4
radiouglerodom 014, s ispoltzovaniyem paTofaznoy raspredelitelf-
noy radiokhromatografii)
M,RIODIOAL: Doklady Akademii. nauk SSSR, 1950, Vol 121, Nr 4, pp 674-677
(UWR)
ABSTRACT; This paper reports on the results of the production of labelled
unsaturated hydrocarbons on the basis of ethyl alcohol
labelled by 014t It is a peculiarity of this method that
all the labelled molecules are produced simultaneouslyby
the same catalytic process which develops under the influence
Card 1/4 of So V. Lebedev's catalyst for the synthesis of divinyl.

SOV/20-121-4--20/54
A Catalytic Synthesis of Unsaturated Hydrocarbons of the Series C V Labellod
C14,
by the Radioactive Carbon
With the Use of Vapor Phase Distributive
X-Ray Chromatography
This paper discusses a special case of the general principle
of the synthesis of labelled molecules. This principle con-
sists of the carrying out of a group synthesis (which gives
a nixture of some substancoa with an unusual isotopic compo-
nition) and of the subsequent application of phyaical-.,r!,IT,-.i-
cal separation methods. Especially interesting is the sepa..
ration of the labelled hydrocarbons of the C 4 series wit!',
various degrees of saturation and with various structural-
isomeric shapes. Such hydrocarbons are butadiene divinyl),
a-butylenef P-butylene (cis-variant)t 0-butylene ~trans-
variant). The catalytic synthesis was carried out by means
0
of S. V. Lebedev's catalyst at 390 . A labelled ethyl alco-
hol C14H3C14H20H with the specific radioactivity 02724 Curie/ml
was used for the synthesis. The chromatographic oeparation
of the marked gaspous labelled products is then discussed.
A figure shows a typical chromatogram of the mixture of the
Card 2/4 gaseous radioactive products of the synthesis of divinyl from
777777

SOV12o-12T-4.4-8151
A Catalytic Synthesis of Unsaturated Hydrocarbona of t&'e "-~es ' 7 a'- rf 7
14 4
.by th6 Radioactive Carbon C , With the Use of Vapor Phase Dintributivc,
X-Ray Chromatography
the labelled alcohol (C 1411 011). According to this chrcmqto
2 5
gram, the main gaseous product is divinyl (81,3 cd). The per-
centage of butylene is not higher than 4.7 The COMDOSition
of the products may be changed by a heat treatment of thp
catalyst. The specific activities of the hydrocarbons have
approximately the same values. In order to iden"'ify the ir.
dividual fractions, their infrared absorption spectra -more
taken; they are shown by a figure. The combination of chroma-
tography with rectification, extraction and with a counter--
flow distribution is very promiBine. These mothods are very
productive and may be used for the preliminary group separa-
tion of a mixture into some fractions with a subsequent ex.
traction of the individual components. The catalytic exper-
iment takes I hour and the chromatographic separation -
2 - 295 hours. There are 4 fiLzures and 9 referen-.e3. 7 Df
Card 3/4 which are Soviet.

SOV/2 0-121-,1.-2 a/54
A Catalytic Synthesis of Unsaturated HydrocaTbons of the Series C 4 Y Labelle,]
by the Radioactive Carbon C14, With the Use of Vapor Pbase DiDtributi7e
.X-Ray Chromatography
ASSOCIATION: Institute fizicheskoy khimii Akademii nauk SSSR
(Institute of Physical ChemistryAS ussn)
SUBMITTED: April 16, ig5a
Card 4/4

28(5)
AUTHCHS:
TITLE:
PERIODICALs
ABSTRAM
Card 3/2
0-"'raner, S. N., Gaziyev, G, A., E-M/;2-25-6-4e/53
Yano-iskly, M. I., Drnyakov, V. S.
147 for the Gas-chromatography
Ionization Datec;tor With Prometium-1 U
(1_-nizr,t5_1onny-j dotelktor a ipromatlyGin-W dly& gazovoy khromatogizfii)
Zwmdakaya Laboratoriya, 1959, 1101 25, Nr 6, pp 760-761 (USSR)
A gas naialyzer Is described with Fm147 as source of the icmizing
~radidlz6 i041z e;ect ro'ytically applied, in form of a thin oxide
layer (surface 2 om 1 and has a specific activity of 2-5 MC/cm
Me differential d6teator consists, of two chambers separated from
each cthbr with teflon. The :cure carrier gas flows continuously
throu&t one chamber, Whila the other one is connected with the
ahrematcgraphing column, receiving the components to be analyzed.
MeasuremaLts ara carried out by means of an amplifier EIAU-3 and
potentioiuiti~r EPP-091 instead of -the latter it is however also
possible to uno an automatto potentiometer EPPV-51. The mchematical
dranIng of the uonstruotion of one of the ionization chambers is
9~ven' (Pis 1). TLa desorited detootor was tested on a chromat%Mphio
d,wloj~- of the vau&l type (Ref 6). The chromatogram3 obtained were
comparad with thoae obtained under the name conditions by the

Ionization Detactor With, Frox,~t-iir.-1147 for the Gas-chromatography 30'7/32-25-6-48/53
thomooonduo'LomateLc gar, analyzar GEEUK-2i. The chromatogrAms of a
;ura of propylano, iso"cutyleze and pentano (Fig 2),' show that far
mixt
mc.r-.-, moxkpd mad prveirm diagrams were obtained by the ionization
det&,itor. It was found -that the ionization deteetor is practically
innenaltive with respect to variations in the velocity of flow and
temp,arature (21gs 3,4) and, therefore, well sUted for separating
uubstances with a hi&% boiling point as well as for determinationj
e. high tamperaturea. There are 4 figurgs and 6 references, 3 of
WhIeh are Soviet.
ASSOCIATIO); Institut fizichookoy khimi'A. Akademii nauk SSSR (Institute of
PbysiW Cbemlatry of the Acadenty of Sciences, USSR)
Card 2/2

ai, I
us 9 1 h U,
PSI
Vega
via a
I'di j"Cr
s z~
1 V d1j] a It
Z
&:gal
4 a .,
All
IPA I i J11.111
of p vg" .99 ;-.is 4:
a! 0. fill

B017/BO55
AUTHORS: Gaziyev, G. A., Yanovskiy, M. I., Brazhnikov, V. V.
TITLE: Simplified Chromatographic Method for the Determination of
Adsorbent and Catalyst Surfaces
PERIODICAL: Kinetika i kataliz, 1960# Vol. 1, No- 4P PP- 548-552
TEXT: A simple and rapid chromatographic method for the determination of
adsorbent and catalyst surfaces was developed. The surface area was found
by determining the vapor volume of reaction products adsorbed on
adaorbents and catalysts at fairly low concentrations. Fig. I gives a
scheme of the experimental arrangement. The surfaces of adsorbents and
catalysts were calculated by the equation Sg W A . V 9 (5), where S9 is
the specific surface and V 9 is the specific volume of adsorbed vapor. The
method was tested using various adsorbents and catalysts and the results
are listed in a table. The relation between the surface area of various
adsorbents and catalysts and the volume adsorbed, as determined for
Card 1/2
S/195/60/001/004/007/015

Simpli fied Chr m
ato rap hic Metho d for the S/195/60/001/004/007/015
Dete i atio of
rM n a c Adgso rbent an d Catalyst Surfaces B017/B055
n-heptane, is shown graphically in Fig. 3. Experimental and calculated
values are in good agreement. The dependence of V 9 on the amount of the
liquid sample introduced is shown graphically in Fig- 4- According to
Table 5, the experimental and calculated values at various carrier gas
velocities are in good agreement. H2 or Ar were used as carrier gas. A
linear relationship was found to exist between the adsorbed volume and the
specific surfaces of the adeorbents and catalysts. There are 5 figures,
1,table, and 10 references: 3 Soviet, 2 US, 1 British, and 3 German.
ASSOCIATION: Institut fizicheakoy khimil AN SSSR (Institute of Physical
Chemistry of the AS USSR)
SUBMITTED: April 28, 1960
Card 2/2
7

ROGINSK IY, S. Z. ALI TSIMER, 0. V. YANVISKIY, MsI.; MININA, Ye*Io;
HOHOKIIOVICTSt A. Ye.
Preparation of radioactive cesium concentrates by the use of
ion exchange glauconite columns. Radiokhimiia 2 no.4:431-437
l6o. (MIRA 13:9)
(Cesium--Isotopes) (Glauconite)

jit
agn;
-t 6ii
4651

A;

ROGINaIY, S-7- ; MALININA, Ye.V.; YAN()VSKIT,_M- I.-_ ALITSHULER- O.V.;
MORCiMbVETS, A.Ye.
Preparation of concentrates of radioactive cesium Isotopes on
heavy metal ferrocyanides precipitated 41rom solutions with a
high content of extraneous ealtse Radiokhimila 2 no.4:438-445
'6o. (MIRA 13:9)
(Cesium--Isotopes) Oerrocyanides)
IN -
0

ROGINSKIY2 S.Z.; SINYAK, Yu.Ye.; YAROVSKIYj_~j~,_
Investigation.of the surface of an alkali promoter of the a=.onia
catalyst by means of the isotopic method. Proble kin. i kat.
IN210-213 160o WIRA 140)
l.-Institut fizichesko~khimii All SSSR.
(Catalysts) (Alkali metal.- oxides) (Alkaline eELr*ths)

81147
S/030/60/000/05/05/056
.5 .5'0 0 B015/BOOS
AUTHORSs Yanovskin.34-J., Candidate of Chemical Sciences,
Famz*i.~yev,
TITLEz Gas .. Liquid Radiochromatograph
PERIODICALi Vestnik Akademii nauk sm, 196o, No. 5, pp. 27-31
TEM A few days are required for conducting a complete radiochemical
analysis of a complicated mixture by the present method. The Institut
fizichesk9y khimii Akademii nauk 83SR (Institute ofjhysical Chemistry
of the Academy of Sciences, USSR) succeeded in conducting such a radio-
chemical analysis in a time required for a chromatographic analysis
alone (15-30 minutes), by combining the methods of the chromatographic
analysis which takes 15-30 minutes with the measuring of the radio-
activity of materials in the flow. On the basis of this principle, some
types of radiochromatographe were worked out, built and tested at the
Institute, as can be seen from the paper by M. 1. Yanovskiy, D. S.
Kapustin, V. A. 'Rogotkov-Ryutin. The gas chromatographlby S.-IT.-Uz-1raner?
0. A. Gazivev. M. I. YanovskTy-and V. S. Kornya-k-ov, the scheme of which
Card 1/2

81147
Gas Liquid Radiochromatograph S103016010001051051056
B015/B008
can be seen in Fig. 1, and which is described in detail, proved to be
the best. One of the chambers of the ionization dotector is shown in
Fig. 2 and a proportional counter in Fig- 3- In contrast with the
detector with an Sr go source, described in publications, the radiation
of the PmI147 is used as ionizing radiation in the paper under review.
A typical Miochromatogram of a mixture of radioactive and nonradio-
active gases and vapors is shown in Fig- 4- A number of investigations
were conducted at the Institute of PhyBioal Chemistry, at the laboratoriya
3, Ze Roginskogo (Laboratory of S. Z. Roginskiy) by means of this radio-
chromatograph, which showed good prospects for the application of radio-
chromatography and chromatography for the solution of various problems
of kinetics and catalysis. The formation of butylenes according to S. V,
Lebedev could be clarified by means of radiochromatographic methods. It
is assumed that the radiochromatographic method will allow the
determination of the relative adsorption coefficients of individual
products in the course of the catalytic reaction. There are 4 figures
and 2 non-Soviet references.

Y4NOVMIT H.I. OZIRANIIR, S.N., LU PET-CHZH" [Lu Plei-chang]
Qz:=::=
Xechanism of chromatographic separation of pses in thermal
displacement analysis. Zhur.prikl.khim- 33 no-5:1084-1091 My
16o. (MIRA 13:7)
(Gas chromatography)
0"
f-2
i Diu
ag, Ar,
n
TF:,

S102016011331()0410401040XY
B004/BO67
AUTHORS: Roginskiy, S. Z., Corresponding Member of the AS USSR,
Yanovskiy, M. I.. Lu Pey-chzhan, Gaziyev, G. A., Zhabrova,
G. M., Kadenatsi, B. M.p and Brazhnikov, V. V.
TITLE: Rapid Chromatographic Method of Measuring the Adsorption
Isotherms of Gases and Vapors
PERIODICAL:, Doklady kkademii nauk SSSR, 1960, Vol. 133, No. 4,
pp. 878-881
TEXT: Since in heterogeneous catalysis the dimensions of the specific
surface are of great importance, the authors attempted to develop a rapid
method of determining the specific surface. Their studies were based on a
paper by J. N. Wilson (Ref. 1) where the relation between the chromato-
graphic curve and the form of the isotherm is theoretically studied. The
results were compared with those of the ordinary vacuum technique. Fig. I
shows,the scheme of the experimental apparatus. The gas analyzer was an
ionization detector on the basis of Pm 7 (Ref. 5). The adsorption of
heptane was measured. Nitrogen and sometimes argon were used as carriers.
Card 1/4
W
W
F.
j

Rapid Chromatographic Method of Measuring the S102 6011331004104010407X
Adsorption Isotherms of Gases and Vapors B004YB067
The height of the steps recorded corresponds to the initial concentration
Co of the adsorbate. The desorption curves recorded on blowing the pure
carrier gas through the column permit the calculation of the isothermal
line of adsorption. In a variation of this method, the column is not
saturated, but the sample is periodically injected into the column through
which the carrier gas flows. The experiment then lasts only 10-15 min. On
the assumption of an immediately established equilibrium and the absence
of longitudinal diffusion,the adsorption was calculated from the following,
equations: f(C) -tOkSi/ug (2), where f(c) is the amount of the substance
adsorbed by 1 g of adsorbent (mmole/g) in which C is the ejuilibrium
concentration; k is the constant of the detector (mmole/cm cm); u is the
speed of the recorder tape; g is the weight of the adsorbent (g); and Si
is the area below the desorption curve. The following adsorbents were used:
refractory diatomite bricks, silica gel of the type E (Ye), nickel-
hydroxide gel, nickel catalyst, MgO produced from Mg(NO 3)2' ZnO+14-5 ZnSO V
and carbon black. The values for MgO, silica gel Ye, nickel hydroxide, and
diatomite were in good agreement with those obtained by the vacuum
technique. For adsorbents with a large number of very narrow pores (active
Card 2/4

Rapid'Chromatographic Method.of Measuring the. B/02o/60/133/004/040/04OXX
Adsorption Isotherms of Gases and Vapors B004/BO67
Coal).the,resultq were unsatisfactory. The range of application of the
chromatographic methdd must be further otuditd. The-authors thank
I. Ye. Neymark and M. A. Piontrovskiy for preparing the coarse-pored
silioa.,.gel Ye and-nickel-'hydroxide 'samples. There are 4 figures, 1-table,
and 5 references: 2 Sovieti 1.US, 1 British, 1 Dutch, and 1 HunaArian.
ASSOCIATION: Institut fizicheskoy khimii Akademii nauk SSSR (Institute
Physical, Chemistry of the Academy of Sciences USSR)
..SUBMI.TTED: January 28, 1960
Legend to Fig.* 1:'1: cylinder with carri3r gas; 3: bubbler with adsorbate;
3: chromatographic column; 4: gas analyzer; 5: recording potentiometer;
6-10: fine-regulating valves; 11.' four-way cock; 12-15: rheometers.
-,card .3/h
20-
7

u

C ard

wov 1\
PME I BM MWITATION 80715W
Vseooyuznoye GoTeahchenlye po linedrenlyu radloaLktivnykh izotopor j y.&rnykh
lzlucbeniy Y narodnoyo khozycletTo SSM. Riga, 1960.
RaUoakUTnyYe Izotopy I .1mornyye Uluchenl7a Y narodrbom khozymyotre SM;
trudy soveshchaniya Y 4 tomakh. t. 1: Obahchlye voymay primneni7a
lzotopoy, pribory s Istochnikami radioaktivnykh izlucboniy, ra&istsionnaya
khimiyapkbi-Acheskaya i neftepererabatywayushchAya promyshler='Sto (Radio-
active Xaotopes and Nuclear Radiations in the National Economy of the USSRI
Trannactions of the Sympoeium in 4 Mamas. Y. It General Problems in tba
UtiUzation or icotopos; Inatrumanto With Sources of Radioactive Radiation;
Radiation Chetd try; the Chentical and Petrolem-Slatining Indantry) Moscov,
GostoptAkbAzdat: 1961. 340 V. 4,140 copies printed.
Sponnoring Agency: Goandarstvannyy nauchno-tekitnicheskI7 komitat Ba"ta Kinistroy
SSM, and Go=darotve=yy komitet Boveta Ulnistroy OUR po ispol. Izovenlyu
ato=oy enorgii.
Ed. (Title pav)a N.A. Petrov, LA. Petranko and P.O. Switaklyl Ids. of tb1s Vol.o
L.I. Petrenko, P.S. Swritskiy, V.I. Sinitain, Ya. H. Kolotyrkln, I.P. 83rrkus
and R.F. Romm; Executive Zds.t Ye. S. TAYIna and B. F. Titskaya; Tech.*Ed.:
E A. MukUna.

137
Radioactive Isotopes (Cont.)
PURPOSE: The book Is intended for technical personnel concerned vith problems
of application of radioactive Isotopes and nuclear radiation in all branches
of tbe Soviet economy.
COVERAGEs An All-Union Conference on problew In the introduction of radioactive
icotopes and nuclear radiation into the national economy of the Soviet Union
took place in Riga on 12-16 April 1960. The Conference van sponsored by:
the Gosudaretvannyy nouchno-tokhnicheekiy komit4t Soveta Kinistroy SSSR (State
Scientific and Technical Comittee of the Council of Ministers, USSH); Glavwye
upraylenlye W lopollzovaniyu atominoy energii pri Govete Kinietroy SM (Main
Administration for the Utilization of Atomic Energy of the Council of HLnisters,
U3M)j Academy of Sciences, USSR; Gooplan USSR; Gosudaretvonnyy komitat BoTota
Miniatror SSSR po avtomitizatail, I mahinostroyenlyu (State Committee of the
Council of Ministe", USSR, for Automation and Machine Wilding) and the Council
of 24inisters of the Latvian SM. The transactions of this Conference are
published in four volumes. Volume I contains articles on the following oubjectst
the general -problems of the Conference topics; the state and prospects of
development of radiation chemistry; and results and prospects of applying radio-
active isotopes and nuclear radiation in the petroleum refining and chemical
industries. . Problems of designing and manufacturing inatruments vhich contain
soarces of radioactive radiation and are used for checking and automation of
technological processes am examined along with problros of accident prevention
use. No personalities am' mentinDed. References accompany some of the
4c,91r.
Card-P4-le
FP
F7

Radioactive Isotopes (Cont.)
Ozirm-Ar. S.N., G.A. Gaziyev, M.I. Yanovokiy; V.S. Kornyakov and
Yu. I. Kapshaninov. Uti3.izati-o-E-&-Pr-o-m-eTh-ium-14T in a Highly
Sensitive Ionization Gas Analyzer ~78
Manoylov.. V. Ye.j, Yu. Ya. Loznovskiy., N.I. Osipdv., Ye. Kh.
Gellgren,, and SF, Denisov. Installation for Automatic Checking
of the Thickness of Polyethylene Film 283
Votlokhin, B.Z.y A.Z. Dorogochinsk:Ly., and N,P, Mellnikova.
Implementation of.a Radiometric Method for Checking Successive
Pumping of Petroleum and Petroleum Products in Main Pipelines 288
Alimarin, I.P., Yu. V. Yakovlev,, M.N1. Shulepnikov,, and G.P.
Perezhogin. Determiriation of S-11 Quantities of Admixtures in
Thallium,, Gallium,. Phosphorus., and Antimony., Using the Method of
Radioactivdting Analysis 293-
Gorahteyn.. G,I. Application of Radioactive Isotopes for Checking
the Fractionation of Microimpurities in Developing Methods for
Obtaining High-Purity Inorganic Substances 298
Card_3XAL2__

TANOVSM2 M4
~ftrauolatorlj ANVAYER, B.L(tranolatorl; TURKELITAUB, N.M.,,
r~d-.; YANOVSKIY, 14.1., red.; MENK01 Ye.F., red.; YEIIISIERILVA.,
O.M., vedushchly red.; FMIUA, E.A.., tekhn. red.
[Progress and achievements of gas chromatograplWj collected reports
and articles] Uspekbi i dostizheniia. gazovoi khromatografli; obornik
dokladoy i atatei Pod red. H.H.Turkelltsubal M.I,IAnovskogo I E,P.
Fesenko. Moskva, Goo. nauchno-tokhn. i2d-vo toft. i gorno-toplivnoi
lit-x7j 1961. 280 p. Translated from the English. (MIM .14: 10)
(Gas chromatograpby)

YMN, Yu.A.j YAIIOV,,KIY# M.I.
Microionization- detector for capillary gas-liquid chromatography
on prometbium-347 without the use of additional gas admission.
Kin. i kat. 2 no.2t292-294 Mr-Ap 161. (MMA 14:6)
1. Institut, fizicheskoy khimij AN SSSR.
(Chromatogra hic analysis)
(Promethium5

S/195/61/002/005/025/027
E194/E412
AUTHORS: Aleksandrov, A.Yu., in~
TITLE-. A flow proportional counter for capillary radio-
chromatography
PERIODICALi Kinetika i kataliz, v.2, no.5, 1961, 794-8oo
TEXT: In the recently developed capillary gas-liquid
chromatography a tube of 0.25 to 0,35 mm diameter and 50 to 200 m
long is wetted on the inside with a thin film of low volatile fluid.
The amount of mixture necessary for effective separation on the
capillary column is 5 to 10 micrograms and high sensitivity
detectors (lo-11 to io-13 moles) of very low volume (lo to 50 mm3)
have been developed to determine these small quantities, generally
using flame ionization and P-ionization detectors. It would be
very convenient to develop a capillary radio-chromatograph which
could quickly analyze the complicated mixture such an is formed in
a catalytic vacuum equipment of 2 litres volume at pressures of
1o-5 to 10-7 mm Hg. This article gives a brief review of
published work on detectors and the results of experimental work
undertaken to investigate the possibility of developing a
capillar radio-chromatograph. The relative merits of
Card J/
eF

S/195/61/002/005/025/027
A flow proportional counter ... E194/E412
ionization chambers, geiger-muller counters, scintillation
counters and proportional counters for recording ionizing
radiation of gaseous radioactive substances are compared. It is
concluded that the proportional counter is the most suitable; it
is not very sensitive to chemical contamination of the working
medium and can record comparatively active samples and operate
stably at temperatures up to 125'C~ However, the electronic
measuring equipment required with proportional counters in more
complicated than with geiger-muller counters. The present work
was carried out with proportional counters of the kind illustrated
in Fig.1 but of various sizes, In this diagram the gas enters at
the lower left tube an& leaves at the upper right, the notation is
as follow3i I - spring, 2 - frame, 3 - teflon gland, 4 - anode,
5 - plug connection, 6 - nut,, Counter diameters ranged from 2 to
20 mm and lengths from 10 to 50 mm, Since argon was used as the
-~arrler gas, the calibration was also made on argon using methane
as a damper,, Preliminary tests showed that the results were
little influenced by the degree of purity of the methane. As the
isiethane content is increased, it is necessary to Increase the
working voltage but if the internal diameter 3f the sathode is
Card 2/0 q-

S/195/61/002/005/025/027
N flow proportional counter E194/E412
above 10 mm, this has little influence on the operation of the
counters which have a fully acceptable plateau up to 400 V even
when pure methane is passedo Moreover, the beat operating
zonditions are obtained when the argon and methane are in the
ratio of 1e1. The counter characteristics do not alter much in
the range 20 to 120*C. StabI6 conditions could not be obtained
above this temperature with mixtures of argon and'methane using
teflon glands. The mean relative errors in measuring radio-
activity of acetone, ethanol and benzene are 1.36, 3.34 and 5.6%
respectively. The accuracy of measurement falls as the quantity
of radioactive substance in reduced. The use of large volume
zounters Increases the sensitivity and'accuracy of measurement
but reduces the effectiveness of the capillary column.
A calibration curve was plotted to determine the sensitivity of
the counter and it is found that the detector reading is a linear
function of the concentration gIvIng a-potent:Lometer_ eading of
approximately 150 mm for a sample quantity of 7 x 10 go Then
radioactive acetone with a specific radioactivity of x 1o-3
micro curies/g was passed through the equipment and a radio-
chromatogram was obtained. The sensitivity of the equipment
Card'3/0 ,

s/195/61/002/005/025/027
A flow proportional counter E194/E412
was 4.5 x 10-10 curle/mm.ml. Reckoning the threshold of
sensitivity as the value of activity which exceeds fluctuation of
the ba6eline by a factor of 3 to 5, the threshold of sensitivity
for the instrument in 1.35 x 10-9 to 2.25 x 10-9 curies. There
are 4 figures, 3 tables and'12 references: 8 Soviet-bloc and
4 non-Soviet-bloc. The references to English language
publications read as followst
Ref.2: MoI.E.Golay, Nature, Lond., V.182, 11469 1958;
Ref-3: J.G.MeWilliam, R.A.Dewar, Nature, Londo, V.182, 1664, 19581
Ref.9: R. Wolfgang, Nucleonics, v.16, no.lo, 69, 1958;
Ref.10; RoWolfgang, An. Chem., v.30, 903, 1958.
ASSOCIATION: Inatitut khimicheskoy fiziki AN SSSR
(Institute of Chemical Physics AS USSR)
Card
gfM
'.Z
4
7

GAZIYEV,, G.A.; OZIRANER, S,,N.j TAXOVSMO M.I.-, KORRYAKOV, V.S.
Effect of some parwr-qt*)ra on the functioning of an ionization
deUctor for pml47. Zhur. fiz. kbim. 35 no.5o.1150-1152 My 161.
(MIRA 16:7)
1. Institut fizicheskoy khimil AN SSSR.
(promethium-Isotopes) (Ionization)

GAZIM, G.A.; KRYLOV, ON.; ROGINSKIY, F,.Z.; SAMSO-*Illc)Vl -G.V.; -FOKINA-, -Ye.A-
YANOVSKIY, M.I.
Dehydrogenation of -.yclolexane on certain carbides, borides, ar'd
A
silicides. Bokl. All SSSII 140 no.4:863-866 0 961, U---ill 14:9)
1. Chlen-korrespondent AN SSSR (for Roginskiy)
(Cyclohexane). (Dehydrogenat'ion) (6atalysts)
R,
g

ROGINSKIY, S.Z.; YANOVSKIY, 14.1.; GAZIIXV# G.A.
Chemical reactions under c;hromatography conditione. Dokl,
AN SSSR 3.40 no.5.-1125-1127 0 161. (MIRA 15:2)
1. Inititut khimicheskoy fiziki AN SSSR. 2. Chlen-korrespondent
AN SS-R (for Roginskiy).

AUTHORSt
81
S 02o 611140100610151030
B103 B.,01
Alitshuler, 0. V., Vinogradova; 0. M.) Roginskiy? S. Z.,
Corresponding Member AS USSR, and Yanovskiyj M. 1.
TITLEs 'Preparation of high-purity hydrocarbons by the method of
thermo-desorption chromatography
FERIODICALt Akademiya nauk SSSR. Doklady, v. 140) no. 69 1961, 1307-1309
TEXT: The applicability of thermo-desorption chromatography to preparative
uses was studied. Isolation and purification of Tropylene was selected as
example. The methods were studied by M. I. Yanovskiy, S. N. Oziranerj and
Lu Plei - chang (ZhPXh, 31, 1084 (1960)). The laboratory apparatus used
consisted of adsorption columns connected in series, which were filled
with the same or different sorbents. After a certain section of the
adsorption layer had been saturated by the mixture of the gases to be
separated, the columns were immersed gradually into an oven heated to
200-220 OC. It was not possible to obtain complete desorption of propylene
Card Iwo

Preparation of high-purity ...
29818
S/020 61/140/006/015/030
B103YB101
at temperatures below 2000C. At higher temperatures, secondary reactions
may occur in the heated zone. Gas samples were taken at the column outlet
and their composition was determined chromatographically. Helium was used
as inert carrier gas. A katharometer or an ionization detector with a
Pm source were used to detect the components of the mixture, Coarse and
close-grained silica gels and alumo gels of various types as well as
active carbon were used as adsorbents. 10 - 20 liters of the mixture could
be separated with a sorbent volume of I liter and a temperature of -20 to
-300C of the cold section of the column. The content of propylene in the
initial mixtures was varied from 25 to 58%. Moreover, they contained
different volumes of ethane7 propane, ethylene, acetylene, and hydrocarbons
boiling higher than propylene, as well as H20 and sulfur-containin&
compounds. First, the partition capacity of the sorbents for the mixture
of propylene and one of these components was determined. It was
characterized by the ratio VRcomp /V R C3H6* Based on these values (V R rel)
suitable sorbents and their sequence for isolating the propylene from the
mixture were selected. The effect of the sorbents is shown in Table It
Card 2/0 -9

SJ020 140/006/015/030
Preparation of high-purity B103 B101
Sorbent admixture to be removed
active carbon heavy hydrocarbons (boiling point> 500C),
CS 2' mercaptans2 acetylene, ethylene, ethane,
H 2S
silica gel, propane) carbon sulfochloride, ethane,
ethylene, CS2
alumo gel ditto + CH2 and H 20
It has been established that the less sorbable components, such as air,
ethane, ethylene, and propane, concentrate in the first fractions; thereafter,
only propylene is found at the column outlet. In the ultimate gas samples
desorbed by heating the column end, admixtures were found which were more
intensively sorbed than propylene. The use of the highly sensiti-e detector
revealed that the admixture of propane, the separation of which from
propylone is most difficult, can be reduced to traces. Thus, it is possible
to obtain pure propylene even from initial mixtures poor in propylene.
Card 3

29818
S/020/61/140/006/015/030
Preparation of high-purity ... B103/B101
The purification coefficients do not become worsen ihen passing to the
range of propylene with very low admixture concentrations. This is an
advantage of the present alternative as compared with the rectification,
since it ensures a very high degree of purification. Unlike in development
chromatography, the components are isolated undilute in thermo-desorption
chromatography. Moreover, this method can be applied to obtain further
components of the mixture in pure state (e. g.2 benzene) cyclohexane). The
paper by Ye. V. Vagin, Gazovaya khromatografiya) Tr. I Vsescyuzn. konfer.,
Izd. AN BSSR, 1960j p. 110, is mentioned. There are 4 figures and 3 Soviet
references.
ASSOCIATIONt Institut khimicheskoy fiziki Akademii nauk SSSR
(Institute of Chemical Physics of the Academy of Sciences
USSR) .
SUBMITTEDi June 23, 1961
Card 4/4
4~

:/EDS PC-4/1r-:4 f1d"'W"dal, Ad
ACCESSION NR: AP3005449 3/0204/63/003/004/0523/C531)
AUTHORS: Krivoruchko. 0. P.; ;!~du~a, A. L.; Samoylenko, Ye. A.
Yanovski M. T. 0(0
TITLE: Production of acetylanic concentratea from the gaseous
products obtained from 61actrooraoking of liquid bydrocarbons by
thermal displacement
1963__:_-523-;-530
~FTOPIC TAGS: acetylenic concentrate-, liquid hydrocarbon electro-
eking, He, teflon, helium, adipic acid
craelking, electrocra
~ABSTRACT: The gaseous products formed during alectrocracking of
liquid hydrocarbons contain products which are both heavier and
lighter than aeotyleno. Based on this fact, it was assumed that it
would be possible to obtain acetyleno~?f higher purity by using the
method of thermal displacomen-T-.- An ap aratus was constructed for
this purpose which permits the study of the mechanism of the
Iseparation process of gaseous hydrocarbons by the stated
adsorption
ard,1/2
Val,, I
R
V., 0a
z RN,
_M~

L 1548-"-63
ACCESSION NR: AP3005449
method. The apparatus consiats of a stainless stoal column with 15
sections. Each section is 120 mm long and 15 mm inside diameter.
ThoGe sections are eonneoted by teflon fittings. The optimum
conditions for the thermal displacement separation were obtained
with a model mixture of C3H8 + C3H6. The carrier gas in this a tudy
was heliun, with a flow rate of 15 to 30 ml/min. The analygis of
propane-propylene mixture was perforipod either by silicagel adsorp-
tion or by gas-liquid chromatography on an 8-mater column rilled with
1ITZ60D stationary phase and 20~6 by wt. of adipic, acid dinitrile
liquid phase. 7,,As study shows the possibility of obtaining acety-
lene concentrate3 from gaseous products from elootrocracking of
liquid hydrocarbons. Orig. art. has: 2 tables, and 7 figures.
AS50CIATI011: Yloskovsk
in3titute tonkoy khImIchaskoy takhno
cow institute of fine chemical 'L-.ecb
zin
3
im. 11. V. Lomonosova
Institut khirnichoskoy
physicss AN 84SSR)
SUBMITTED: 16Jan63
SUB CODE; CH, PH
DATE Acq: o6Sep63 ENCL: 00
NO REF SOV: 008 Qt~LER: 000
-,Card 212

GAZIYEVI G.A.; FILINOVSKIyo V-Yu-; YANOVSKIY, M.I.
Kinetics of heterogeneous cataly+,ic reactions carried out wider
pulse-chromatographic operating conditions of ideal linear RA 16:12)
4 no.53688-697 S-0 163~ (MI
chromatography Kin.i kat.
1. Institut khimicheskoy fizik:L AN SSSR.
g
~X& gl,~-S

ROGINSKIY, S.Z.; SEMNENKO, E.I.; Y t z-q -II-Y L M .I -
Possibility of carrying out the catalytic dehydrogenation under
chromatographic conditions. Dokl. AN SSSR 153 no.21383-385 N
16 3 0 (MIRA 16:12)
1. Institut khimichoskoy fiziki AN SSSR. '2. Chlen-korrespondent
AN SSSR (for Roginskiy),
T
77,'

ZHUKHOVITSKIYj A.A., otv. red.; VAGIN, Ye.V., red.; GOLIBERT$
K.A.J. red.Ldeceased]; KISELEV, A.V., red.;UrMITAUB,
red.
N.M., red.; FESERKO, Ye.P.., red.; LANOVS~~
[Gas chromatography; transactions] Gazovaia khromatografiia;
trudy. Moskva) Naukap 1964. 1.83 p. (MIRA 17:12)
1. Vsesoyuznaya naucbno-tekhaicheskaya konferentsiya po
gazovoy khromatogrnfil. 2d, Moncowl 1962.
-V g'
Ng
-Z

IV7
si,
"Ot"

C., Ti't, IJW A t'
gi

SEMONKOP &.I.; ROOINSMIYO S-9 Z, M
Combined radloohromatography tachrAque for StOying the z9ohanimm Ot
hateroganaots catalytia roactions. Kin. i kat, 6 no.2020-328 Mr-Ap
'K (KRA 1817)
Inatitut khimicheakol Miki AN 999R.

)LANP.VSK1X,-M.1..; GAZIYEVI G.A.;IIIKIFOROV, V.P.j MAKARENKO, V.G.; ZIMIN,
R.A.; 14ARININ, P.T.; FRPITK, Yu.A.
Gas chromatograph with automatic pickup of Bamples from a flow.
Zav. lab. 31 no. 12t1526-1528 165 (MIRA 19t1)
1. Institut, khimicheakoy fiziki A14 SSSR.
~J IF

S "
ROGINSK12, ~. .1 ZIMINt R.A.- YANOVSKIY M.I.
4,
Selective oxidizing deri)rd ogenation studied by pulse chromato-
r
S 165.
graphic nethod. Dokl. AN SSSR 164 no.ltl44-146 (MIRA 18-.9)
1. Institut J~himicheskoy fizlki AN SSSR. 2. Ghlen-korrespondent
AN SSSR (for Roginskiy).

USM/Chemistry - Adsorption Jau#eb 52
eory of Chromatography on Nonhomogenous
Zurerze 111. The Dynamics of Adsorption of
141xture:lon Inhomogenoms Surfaces," S. Z. Roginakiy.
14. N. Yanovskiy, Inst of 7%ys Chem, Acad Sci USSR
"Iz Ak Nauk, Otdel Khi= Rauk" No 1, pp 64-73
On the basis of the statistical theory, the follow-
ina results were obtained. The effect of the
Inhomogeneity of an absorbent on the dynamics of
adsorption of a mixt of 2 substances was Investi-
f9sted. Crit data were established, which show that
208T5-
LISSR/Chemistry - Adsorption Jan/Feb 52
(Contd)
one dynamic adsorptiou regime can change to'another.
The conditions for the complete sepn of a binary
mixt were established. Conclusions drawn from this
are of particular interest for the dynamics of
adsorption in the field of low degs of filling,
where the effect of inhomogeneities is generally
very pronounced.

27,591
B/108/61/016/010/004/006
-3 0 e) D209/D306
AUTHORSt Yanovskiyt MOS. and Knyazlkovg B.N.t Members of the
-SoWN61-y-. _1
TITLE: A polarization-type wave guide modulator
PERIODICAL: Radiotekhnikap v. 169 no. 10, 1961p 26 - 27
TEXT: This is an abstract prepared by the author of his own article.
In solving many problems the need arises to transform the SHF osci-
llations of-frequency w into the oscillations having two frequencies,
differing from each other by a certain small magnitude. Such a trans-
formation can be achieved by using a waveguide modulator belonging
to the instruments of polarization type. The principle of operation
of such a modulator is as follows: Two rectangular-to-circular wave-
guide transition sections I and IVp each having an absorption vane
parallel to the wide walls of the wave guide, placed at both ends of
the modulator transform the H10 wave into Hil or'xQWrversa9 the
transformat�on being accompanied by the absor tion of the tangential
Card 1/5

27591
S/10 61/016/010/004/006
A polarization-type wave oet D209YD306
component of the field* Between the two transition-sectioner, e
placed 2 sections II and Mof a circular waveguidee Section II has
in its axial plane a sheet of dielectric and introduces thus bet-
ween the two field components, the one polarized in the plane of
the sheet and the other perpendicular to it, a differential phase
shift by 1800 (the A 1800 section). The second section III intro-
ducee between the two field components a differential phase shift
of 900 ( 6 900 section) the & 1800 section II is rotated with a
velocity -a rev/see. The position angle of the A 900 section with
respect to the fixed section (angle q>+ 450) is adjustable. The li-
nearly polarized wave Esin wt at the input of the 6 1800 section
may be represented as a superimposition of two oircularig polarized
oscillations. After passing through the revolving 6 180 section
the angular velocit f one of the oacillations increases by +2fl
and the other by -2YY The A 900 section transforms these two in-
to linearly polarized oscillationeq at 900 with respect to each
other and at 450 to the plane of the sheet of the a 900 section.
The position angle of the A 900 section relative to transition de-
termines the amplitudes of these oscillations at the outputt
Card 2/5

27591
S/108/61/016/010/004/006
A polarization-type wave D209/D306
e+ -V2=
e- -LEcosysln(w -2Q)t
The power averaged over one period at the output is independent of
anglecf, It c8natitutes one half of the input power which may be
easily seen from Eq. (1). If the differential chase shift in see-
tione II and III differs from 1800 and 900 by -2 and -,,' 3 respective-
lyp the spectrum at the output will have the component of frequency
w and changed amplitudes,of side band frequency.components
.___ I
e,=-FEs1nL' j/3-cas4T(1+s1n8a)-s1n&3s1ntu1
2
O+_ 1 EsintpeosL" I - C03 2y cos 51 Sin (w + 29)11 (2)
VY' 2 V I - Cos 27
e-= I EC03?COS.L' I +COS2?COS8 sin(w-22)1
Y-2 2 I+cos2T
Card 3/5
Ov Rt

27591
S11081611016101010041P06
A polarization-type wave D209/D306
Another type of modulator is also possible which produces at the
output two frequencies, one equal to the input frequency w and one
other differing from it either by +2d_1 or -21"~.v depending on the
direction of rotation of the waveguide phasing section. This modu-
lator differs from the previous one In that a fixed A 900 phasing
section is placed after the first trannition section; the dielectric Ale\
sheet is placed at an wngle of 450 to the vane in the transition
section and instead of a 6 1800 section the 900 section III is
rotated. The relationship between the amplitudes of frequencies W
and w + 2fL or w - 2 fl depends exactly in the same manner on the po-
sitioning of the last :! 900 sect 'ion IV with respect to the transi-
tion section V and can be, as in'the previous case, regulated. It
can be shown that with the signal propagating through the modula-
tor in the opposite direction with the same direction of revolution
of the phasing section, an inverse relationship exists between the
oscillations amplitudo at the output, as if the direction of rota-
tion was changed without the change in the direction of propagation.
It ie stated in conclusion that instead of a rotating 1800 or
Card 4/5

27591
8/108/61/016/010/004/006
A polarization-type wave D209/D306
,A 900 phasing sections with dielectriot a ferrite phasing section,
controlled by a transverse rotating fieldq could be substituted.
There are 2 figures, and 2 referencesi 1 Soviet-bloc and 1 non-
Soviet-bloc. The reference to the English-language publicatim
reads as followst A.G. Foxg PIRE9 vo 35# no.12, 1947.
ASSOOIATIONt Nauchno-tekhnicheekoye obahchestvo radiotekhniki i
elektrosvyazi im. A.S. Popova (Scientific and TechnJ-
cal Society of Radio Enaineering and Comm-
im. A."'. i-vuov LAbi,~,dutoi-a ii~,Lts: ]Name oi
Akmucia'Liva luaker,. !row first page of journal]
SUBMITTEDt pril Up 1961
M#orls abstract June 129 19611
Card 5/5
1~
t

.414;,Q
5/142/62/005/00/k/007/010
E192/E-382
AUTHORS: Yanovslciy, M.S. and Sharifarov, Ya*L*
0 TITLE: amic method of measuring the quality'factor'of
resonators by using synchronous detection
PERIODICAL: Izvestiya vysshilth uchebnykh zavedeniy,
Radioteld-inika, v. 5, no. 11, 1962., 515 - 518
TMM The method is based on the
dynamic plotting of the
frequency characteristic of the imaginary and the real components
of the reflection coefficient of a resonator. It has the
advantage of being based on measuring the spacing between
clearly defined points (minima or zerosY. 'Tho.reflection
coefficient for a resonator as a function of frequency(for
frequency-devlat-t6ns &w/wo,