SCIENTIFIC ABSTRACT VASILYEV, V.P. - VASILYEV, V.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001858920010-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Conference Discussion on the Methods of SOV/153-58-3-30/30
Investigating the Complex Formation in Solutions
account the complex formation in solutions by means of the
potentiometric method were mentioned for systems with zinc,
oadmium and indium. In the evaluation of their results the
authors employed the method of the table difference. The
calculation of the consecutive constants was carried out
according to the interpolation formula by Newton. M. A.
Chepelevtskiy hold a lecture on "pH Measurement Method of
the Solutions in Combination With t~t System Analysis of the
Solubility Piagram, of the System Cu47-HC1 - H20 in Investiga-
ting Complex Copper Compounds in Saturated Solutions". It
was found that the substance at the bottom of the liquid is
more basic than the solutionj furthermore, the increased
acidity of the solution from the viewpoint of the formation
of hydroxy-ohloro, complexes in the solution was explained.
V. I. Kuznetsov opened the discussion with his lecture; he
pointed but the necessity of utilizing the concepts worked
out in the investigations of the polymerization in organic
chemistry in the chemistry of polynuclear complexes. A. A.
Card 5/16 Grinberg thinks that the new approach of the hydrolysis

Conference Discussion on the Methods of SOV/153-58-3-30/30
Investigating the Complex Formation in Solutions
investigation as developed by the Scandinavian school is of
high value. He also pointed to the necessity of studying
the kinetics of the polymerization process and a quantitative
determination of the strength of the polymers. I. K. Babko
pointed out that the study of the polymer structure was
necessary. X. P. Komar' mentioned in his lecture that the
rather widely spread polymerization type according to the
scheme "nucleus + chain members" is not obtained in all cases.
The following scientists took part in the discussions V. N.
Tolmachev, A. V. Ablov, I. S. Mustafin, I. V. Tananayev and
K. B. Yatsimirskiy. A. K. Babko then discussed in his lecture
"Methods of Determining the Dissociation Constant of the
Complex Groups in Solutions" the main principles of determining
the instability constants. N. P. Komar' discussed in his
lecture "Calculation Methods of the Instability Constants of
the Complex Compounds According to Experimental Data" the
possibilities of using the known calculation methods of the
instability constants for various cases of the complex forma-
tion in solution. If several mononuclear complexes are formed
Card 6/16 the displacement method by Abegg and Bodlender (completed by

Conferenca Discussion on the Methods of SOV/153-58-3-30/30
Investigating the (,omplex Formation in Solutions
A. K. Babko) cannot be recommended for the calculation of
the instability constant. The lecturer discussed the dia-
solution methods of the polynomials proposed by B'yerrum,
Leden, Rossoti, Sketchard, Edsolloy and other authors. The
constants calculated in this way are not very accurate. It
was proved that the method of successive approximations can
lead to wrong conclusions as to the chemical processes taking
place in the system investigated. The mcdt probable value
of the physical constants can be obtained by the method of
the least squares. B. V. Ptitsyn, Ye. N. Tekster and L. I.
Vinogradova described the determination methods of the
instability constants of the oxalate complexes of niobium,
uranium and iron which are based on the investigation of the
equilibrium displacement of the complex formation by silver
ions. N. K. Bol"shakova, I. V. Tananayev and G. S. Savchenko
held a lecture on "The Role of the Time Factor in the Investiga-
tion of the Complex Formation". In the discussion on the
lectures A. A. Grinberg mentioned that due to the slow
adjustment of the equilibria the methods discussed of
Card 7/16 determining the instability constants (palladium and cobalt

Conference Discussion on the Methods of SOY/153-58-3-30/30
Investigating the Complex Formation in Solutions
complexes) can often not be employed. A. V. Abloy pointed
out the necessity of devising direct methods of proving the
existence of intermediate forms in a step-wise complex forma-
tion. K. B. Yatsimirskiy mentioned that the instability
constants of slowly dissociating complexes can be calculated
from thermochemical data. L. P. Adamovich, A. M. Golub
among others took part in the discussion on the lectures.
A. K. Babko requested inclusion in the next conference on the
chemistry of complex compounds a lecture in which various
calculation methods of the instability constants should be
discussed by the example of actual cases. This should clarify
to which divergencies of the values of the constants dif-
ferent methods of evaluating the experimental data can lead.
N. P. Komar' stressed that in the determination of the
instability constants all chemical equilibria should be taken
into account that render complex the complex formation process
in the solution, especially the hydrolysis processes of the
central ion and the addendum. In the lecture delivered by
V. M. Peshkova and A. P. Zozulya "Application of the Distribu-
Card 8116 tion Method to the InveatigatiQn of the Stability Constants

Conference Discussion on the Methods of SOV/153-58-3-30/30
Investigating the Complex Formation in Solutions
of Some Thorium Complex Compounds" results obtained from the
experimental investigation of the distribution of thorium
compounds in the systemst acetylacetone benzene - water, and
2-oxy-1,4,-naphthoquinone -- chloroform water were given.
From these data the instability constants of the thorium.
complexes with acetyl-acetone and 2-ozy-1,4-naphthoquinone
were calculated. 1. V. Tananayev, G. S. Savchenko and Ye. V.
Concharov held a lecture on the application of the solubility
method in the determination of the stability of complex
compounds in solutions. In this lecture also other methods
of investigating complex formation processes in the solution
were discussed (pH measurement, measurement of the optical
density, as well as of the heat of mixing). B. D. Berezin.
held a lecture on the "Application of the Solubility Method
in Studying the Fhthalocyanine Complexes of Metals". He
used the determined quantitative characteristics of the
reaction of the transition of the phthalocyanides of cobalt,
nickel, copper and zinc, as well as of the free phthalo-
cyanine into the sulfuric acid solution for the theoretical
Card 9116 reasoning, and as an experimental proof of the existence of

Conference Discussion on the Methods of SOY/153-58-3-30/30
Investigating the Complex Formation in Solutions
jr-bonds in the complexes investigated. These characteristics
also served him as a proof of new electronic formulae of
phthalocyanine and its complex derivatives. In the lecture
delivered by I. L. Krupatkin on "The Method of the Two Solvents
as a Method of Investigating the Formation and Properties of
organic Complexes" it was proved that this method makes it
possible to determine the number of complexes formed in the
system, their composition and relative stability. V. I.
Xuznetsov, A. K. Babko, N. P. Komar', I. S. Mustafin and
Ya. 1. Tur'yan took part in this discussion. In the lecture
delivered by A. A. Grinberg and S. P. Kiseleva on the complex
palladium compounds (II) with a coordination number above
four it was proved that in the case of a farge chlorine and
bromine ion excess complexes with the coordination number 5
are formed. The instability constants of these complexes
were estimated. L. P. Adamovich mentioned a new manipulation
in the spectrophotometric investigation of the complex com-
pounds that can be used in systems with the formation (or
predomination) of one single complex. This method makes it
Card 10/16 possible to determine the composition and instability constant

Conference Discussion on tho Methods of SOV/153-58-3-30/30
Investigating the Complex Formation in Solutions
of the complex. In the lecture delivered by K. B. Yatsimirskiy
and V. D. Korableva the application of the theory of crystal-
line fields for the determination of the composition and
structure of the chloride complexes of cobalt, nickel and
copper according to the absorption spectra of these complexes
was discussed. It was proved that in a hydrochloric acid
concentration above,5 mole/liter in the solution there exists
an equilibrium between the tetrahedrio and octahedric form
of the cobalt chloro complexes. Yu. P. Nazarenko proved in
his lecture "The Application of Radioactive Isotopes in the
Inv.estigation of the Solvation Equilibrium in Solutions of
Complex Compounds" the possibility of using data on the
isotope exchange to clarify the structure of the complex and
mechanism of the hydration processes. V. Klimov mentioned
in his lecture the use of radioactive isotopes in the study
of tin and antimony complexes in non-aqueous solutions. A. V.
Ablov, V. N. Tolmachev, V. I. Kuzne-sov and A. M. Golub took
part in the discussion of the lectu;es. The usefulness Of
employing the theory of the crystalline fields in explaining
Card 11116 the results obtained from the absorption spectra of the com-

" p,, - ---- - - - f-l~
Conference Discussion on the Methods of SOY/153-58-3-30/30
Investigating the Complex Formation in Solutions
plex compounds was stressed. In the lecture delivered by
I. A. Shek on "The Investigation of the Complex Formation
by the Method of the Dielectric Permeability and the Polariza-
tion" the principles of the methods mentioned were presented.
This method was employed for investigating the compounds of
the type of the "affiliation" products. The lecture delivered
by I. A. Sbek and Ye. Ye. Kriss "Employing the Method of the
Dielectric Constant for Investigating Complex Compounds of
the Type of Crystal Solvates in Solutions" dealt with the
investigation of the solvates of lanthanum and cerium chlorides
with ketones, as well as with the study of the compounds
formed in heterogeneous systems with tributyl phosphate and
nitric acid. Y. F. Toropova gave in her lecture "The Polaro-
graphic Method of Investigating the Complex Formation in
Solutions" a survey of the applications of the polarographic
method in the study of the complex compounds, and illustrated
several fine characteristic features of this method. In the
lecture delivered by T. N. Sumarokova "The Cryoscopic Method
of Investigating the Complex Formation Reactions" a survey of
Card 12/16 the possibilities of the cryoscopic method was given, and its

Conference Discussion on the Methods of SOV11 53-58-3-30/30
Investigating the Complex Formation in Solutions
applicability in the study of several complex compounds of
stannic chloride with organic substances was proved. L. M.
Golub described the results of his investigations of thio-
oyanate complexes of several metals. I vivid discussion took
place on the lectures hold. Ya. A. Fialkov and Yu. Ya,
Fialkoy considered the cryosoopic method of investigating
complex compounds to be of considerable value. K. B.
Yatsimirskiy pointed out that the publication of the surveys
on individual methods of investigating the complex formation
reactions would be desiredi this concerns especially the
polarographic method. The cryoscopio method should be brought
to a level that makes the calculation of the equilibrium
constants of the processes to be investigated possible. The
problem of the method of evaluating the experimental results
becomes more and more important. Many scientists use the
instability constants without taking into account the way
in which they had been obtained. The calculation methods
employed by A. M. Golub are one step back, as compared to
those employed at, present. In his lecture N. P. Komar'
Card 13/16 pointed out the extremely great importance of the mathematical

Conference Discussion on the Methods of SOV/153-58-3-30/30
Investigating the Complex Formation in Solutions
evaluation of the results obtained, as well as of the plotting
of curves. A. K, Babko suggested selecting one or two systems
that are experimentally well investigated, and to evaluate
the results obtained according to different mathods so that
it is possible to check and evaluate them. Y6. I. Tur'yan
took part in the discussion. Ya. A. Fialkov discussed in
his lecture "The Effeot of the Solvent on the Complex Formation
Process as Vell as on the State of Equilibrium in the Solutions
of Complex Compounds" the influence exerted by the solvents
upon the molecular state, upon the solvation of the system
components, upon the stabilization of the complexes formed
in the system, upon the step-wise dissociation of the complexes
and upon a number of other processes. The influence exercised
by the dielectric constant upon the complex formation process
was discussed. It was concluded that a direct relation does
not exist, and that the chemical nature of the solvent must
be taken into account. A. V. Abloy and L. V. Nazarova held
a lecture on "The Spectroscopic Investigation of Nickel Cobalt
,Pyridinates' in Various Solvents". The instability constants
Card 14/16 of the complexes were determined and it was proved that the

Conference Discussion on the Methods of SOY/153-58-3-30/30
Investigating the Complex Formation in Solutions
stability of the 1pyridinates' is changed in dependence on
the solvent. Ya. 1. Tur*yan in his lecture "The Influence
of the Solvent Upon the Composition and Stability of Complex
Iona" discussed the polarographic investigation method of
the chloride and thiacyanate complexes of lead in aqueous
ethanol solutions at different content of the non-aqueous
solvent and at a constant ionic strength. k step-wise
character of the complex formation was found as well as the
instability constants of the complexes. The influence of
the dielectric constant of the solution on the stability of
the investifated complexes was proved. In the lecture by
V. F. Vasil yev on the "Investigation of Aquo Complexes in
Mixed Solvents" the main attention was devoted to the neces-
sity. of the qualitative recording of the dolvation effects
in the complex formation. The applicability of the polaro-
graphic method in the determination of the composition and
stability of the aquo complexes in mixed solvents was proved
and experimental material on the thermodynamics of the
dissociation of the cadmium-aquo complexes in aqueous ethanol
Card 15/16 solutions was mentioned. V. N. Tolmachey, V. I. Kuznetsov

Conference Discussion on the Methods of SOY/153-5a-3-30/30
Invesiigating the Complex Formation in Solutions
and I. V. Tananayev stressed in their lectures the necessity
of a more complete and general investigation of the eolvation
processes. A. K. Babko and A. M. Golub pointed out the
great importance of the investigations of the complex forma-
tion equilibria in non-squeoue solutions, and made several
critical comments on the lecture by Ya. I. Turlyan. The
following scientists took part in this disoussioni L. F.
Adamovioh, 0. 1. Khotayanovskiy, A. P. Moskvin and A. G.
Mustakhoy. It the final meeting of the conference A. A.
Grinberg, Corresponding Member, AS USSR, said in hie speech
that such a conference was very urgent. A detailed discus-
sion of the determination methods of the composition of the
complexes, as well as of the method used in the study of the
quantitative characteristics of the stepwise complex forma-
tion was extremely useful for all who attended this conference.
Card 16/16
uscow-Dc,0976

VASILITEV, V. K01URLEVA, V.D.; TATS114IRSKIY, K.B.
Discussion conference on nethods for study of complex formation
in solutions. Zhur. neorg. khim. 3 no.8:1891-1986 Ag 158.
(Complex compounds-Congresses) (KIRA 11:9)

SOV/78-3-8-46/48
AUTHORS: Vasilfyev, V. P., Korableva, V. D., Yatsimirskiy, K. 3.
TITLE: Cd~ference Discussionon the Methods of Investigating Complex
Formations in Solutions (Soveshchaniye-diskU3Siya PO Met0daM
izucheniya kompleksoobrazovaniya v rastvorakh)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1958, Vol- 3, Nr 8, ppe 1982-
1986 (USSR)
ABSTRACT: From February 18 - 212 1958 a conference with dis,::ussions took
place at Ivanovo, which dealt with the methods of investigating
the complex formations in Bolutione.,
At this conference the methods of determining the compositi(,n
of the complexes in solutions, the methods of calculating the
stability constants on the basis of experimental data, as well
as the influence exerted by the sol7vents on the process of com-
plex formation were discussed. Numerous experimental and theo-
retical papers were submitted to the conferencs, which dealt
with the process of complex formation in aqueous and non-aqueous
solutions. Especially methods concerning the composition of the
complexes as well as methods of investigating step-wise complex
formations were dealt with in detail.

VkSIL'YEV, V.p.; MUKHRIA, P.S.
-- Equilibria in aqueous solutionfl of thiocyanate co=lexes
of Iron. Zhuro neorge khim. 9 no.5%1134-1140 My 164.
1. Ivanovskiy khimiko-telechnologicheskiy Anstitut.

AEFtAMCrVA,--U.,A.,)rnauchn. sotmy iiELICIP-11KO, G.V.j knn(j. tokfin. nauk;
V.V., nauclun.--otr.; VASILIY4-V, V.P., kuni.kbin.
nauk; DGaCllilli', D.P., dok-,or kh,4-nn. na-ulk; IC=-, 33'.V., dc'kt.
khim,nauk; KAMINSKIY, Yu.L., nauchn.sotr.; FAPF07A, 1-7.)
kand. khini. nauk; KOFYLEV, B.A., doktor klibr., nauk;
LUTUGIPA, II.V., kand. khin. nauk; IAIAIEROVA, Ye.h., kand.
khim. ruiuk; VO.R.11CHEVSKIY, AI.G., kand. khIm. nauk;
YORACIIEVSKIY, An.G., kand. khirT-,. nauk; NIKEROV, A.E.0 kand.
khim. nauk; FALIM, V.A., kand. khim. nauk; RAJJIIIO~ICII, V.A.,
kand. khim. nauk; SOKOLOV, F.E., kand. khim. nauk;
FRIDiUKIiSbERG, D.A., kand. khir., nauk; TSYGIR, Ye.N., nauchn.
sotr.; 311AGITSULTANIOVA, G.A., kand. khim. nauk; SHKODII., A.M.,
doktor khim. nauk; YATSIMIiiSKIY, K.H.; GFUGOROV, 0.14., doktor khiff'.
nauk, red.; ZASLAVSKIY, A.I., kand. khim. nauk, red.; MORACHEVSKIY,
Yu.V., prof., red.; RACHII:SKIY, F.Yu.., kand. khim. nauk, red.;
POZIN, 1%.Ye., doktor tekhn. nauk, red.; PO'iAY-KOSPITS, B.A., doktor
khim. nauk, red.; PROITASOV, A.M., kand. fiz.-mat. nauk, red.;
ROMANKOV, F.G., red.
[Handbook for the chemist] Spravochnik khimika, 2 izd., perer. i
dop. Eoskva, Khirdia. Vol.3. 1964. 1004 p. 4URA 18:1)
1. Chlen-korrespondent AN SSSR (for Romankov). 2. Deystvitellnyy
chlen AN Ukr.3SR (for Yatsimirsk-iy).

AUTHOR:
TITLE: The Problem of the Ion Compound Solubility (K vopro3u 0
rastvorimosti ionnykh soyedinen-ly)
PERIODICAL: Zhurnal neorganicheskoy khimii, 1958, Vol 3, Nr 0, pp 20',3-20'0
(1jSSR)
ABSTRACT: In the present paper the solubility of ion compounds as de-
pendent on the radius of the ions was investigated. Mg 24- , Ca 2-F
Sr 2+ and Ba 2+ viere used as ion compounds. These c~.,mpounds in
aqueous solution are completely dissociated
I;A2+ 2-
xsolid + X
The heat of hydration of the ions is calculated by the equation
6a
-AH liqu. 662,0
2+ + 0, 62
Y
The lattice energy of thF~oe ion compounds is calculated
according to the equation Of KO-PU3tirskiy (7).
Card 1/4

SOV/78-3-9-9/38
The Problem of the !on Solubility
U - 287,2 ZnZ 14Zx --2,345 ) + B (7)
rIA + rx r. + rx
The dependence of the solubility of these salts on the cation
radius was investigated and the solubility prcduct SP wag
calculated according to the following e-~uation
al,-sp = 16s4,4 11~2,2 470d
arM (rM +rx)2 rM +ZI X)2 (r,,,+O, 62)2
The results show th~;', the solubility product increases as the
cation radius becomes lc~ncqr, and that the decrease of the
solubility product pas.3e3 a -minir-= value. From this for=,~la it
becomes evident that the solubility product of the sul-fates of
2+, 2+ -2+ 2+ to Baso
Mg Ca , S. and Ba decreases from MgSO 4 4' The
solubility products of the selenates, tungstates, molybdates,
and other bivalent anions show the same order. Also the catlo-,
radius can be calculated according to formula (15). For 'he
determination of the solubility product of the above mei.tioned
Card 2/0 cations with mono va len-'61 anions, that io with salts of the type

J
The'Problem of the Ion Compound Solubility
MX, where X denotes the mono7jalent anion, also equation
was applied. The solubility product of radium salts w3s d-:3-
cus3ed) and the solubility product of radium chromate SP RaCrO
with -10-! c;f radium fluoride SP RaY with -10-4 , anct of 4
-9 2
SP RaCO3with -2.10 was calculated by extrapolation.
There are 1 figure, 4 tabl~as, and 8 references, 6 of which ar~-
Soviet. .
ASSOCIATION: Ivanovskiy khimikr-t-3khric-heskiy inst-.tut (Ivanovo Chemical
and Technical Insti'~ute)
SUBMITTED: July 8, 1957
Card 3/4
3

AUTHOR:
TITLE:
PERIODICAL:
ABSTRACT:
Card 11A
2__
Vasi 11
QN/7 P- - 3 -C
The Stability of the Complexes of Magnesium, Calcium, Stronti-~-_,,
and Barium in Aqueous Solution (Ustoychi-,rostf kompleksov ma-gniyaj
kalitsiya, strontsiya i bariya v vodnom rastvorel/
Zhurnal neorganicheskoy khimii, 1958, Vol 3, Vr 9, pp 2060-2066
(USSR)
In the present paper the quantitative dependence between the
stability of the complexes and the radii of the ions of magnesium,
calcium, strontium and barium was investiCated. It was ascertain-
ed that according to the length of the radius of the addenda
the stability of the ccmplexes in magnegium, calcium, strontium
and barium decreases, increases, or reaches a maximum in con-
nection with an increasing length of the ra-dius of the central
ions. If the charge of the addandlL is inc~rea3ed, the stability
maximum of 'the complexpa can be determined more dir3tinctly. In
the complex compounds with monovalent anion the stability maxi-
mum of calcium changes to 11,3, that of magnesium to 5,1, and
that of strontium with bivalent anion from 14,7 to 6,3. The
stability maximum of calcium is more distinctly marked than that
of strontium. The dependenc-~ of the stability of the complexes

SO V/78 -.3 -9- 1 0/3E
The Stability of the Complexes of Ma.Enesiu=, Calciu=, Strontiu=, and 3a='1%= in
Aqueous Solution
with mono-, bi- and trivalent addenda on the radius Of the
central ion was invectigated. The following facts were co---
cluded from the results: If the radius of the monovalent
addendum is smaller than 1,9 X, the stability of the complex
decreases as the radius of the central ion becomes lonCer. In
numerous complexes with pcl~,valent addenda the stability shows
a maximum which especially in the case of tri- and tetravalent
anions is distinctly marked. The process of complex formation
in aqueous solution can be considered a peculiar competition
between the water molecules and the ions of the adderida or the
molecules of the adderide, respectively for the central ion. If
the radius of the addendum becomes longer, the energy of the
interaction ion-ion is lowered. There are 4 figures, 3 tables,
and 13 references, 10 of which are Soviet.
ASSOCIATION: Ivanovskiy khimiko-tekhnicheskiy institut (Ivanovo Chemical
and Technical Institute)
SUBMITTED: July 8, 1957
Card 2/4
I-

VASICYEV V,P 11
50) PHASE I BOOK EXPLOITATION SOV12032
-Yatsimirskiy, Konstantin Borisovich,~and Vladimir Pavlovich
Vasillyev
Konstanty nestoykosti kompleksnykh soyedineniy (Instability
Constants of Complex Compounds) Moscow, Izd-vo AN SSSR,
1959. 205 p. 4,500 copies printed. Errata slip inserted.
Sponsoring Agency: Akademiya nauk SSSR. Institut obshchey i
neorganicheskoy khimii.
Reap* Ed*t I.I. Chernyayev, Academician; Ed. of Publishing
House: D.N. Trifonov; Tech. Ed.: S.Ge Markovich,
PURPOSE: The book is intended for chemists, engineerq~and
technicians concerned with analytical chemistry, electro-
chemistry, technology of nonferrous and rare metals, and
related fields.
C"d=~

Instability Constants (Cont.) SOV/2032
COVERAGEt The authors claim that this book is the first
attempt to make a complete compilation of the instability
constants of complex compounds. Instability constants of
),,,381 oomplex compounds are given. Methods of oalculating
instability constants are described in an introductory
chapter. The book was compiled chiefly on the basis of
literature published up to 1954. No personalities are
mentioned. There are 79 referencespof which 35 are
Soviet, 28 English, 6 German, 4 French, and 6 Swedish.
TABLE OF CONTENTS:
Foreword 3
THEORETICAL PART
Ch. 1. Some Functions Characterizing the Stepwise Complex
Formation in Solution 7
Bibliography 15
Ca-rd=2fi&

Ak&dNLI._va nauk SSSR. Otdelenlye knlmicneaA,~h nauk

TormodInamika I stroyarLiye rastvorov; trU4Y 30veahchanlya...
(Therm>dynamlos and Structure of Solutions. Transactions of the
conference Hold January 27-30, 195a) M3cow, lmd-vo AN SSSR,
1959 . 295 p. 3.000 copies priPted.
Zd. I M. 1. 3hakhparonov, Doctor of Chemical 3cloncomi Ed. or Publishing
Bottoms N. 0. Yogorov; Tpch. Ed.: T. V. Polyakova.
PMUMUs This book is intended for physicists, thmalsts, vA
chemical engineers.
COVWtAGZt Thim collection of papers was originally presented at the
COMferonco an Thermodynamics AM Structure of solution& sponsored
by the section of ChemaLcal sciences or the AcadoKy of sciences I
U33Rv and the Department of Chemistry of Moscow State University.
and bald in Moscow an January 27-30, 1958. officers of the
*q::prMqj_mr* listed oremord. A list of other r*porca
- -
'
_
Li
he ooeoren" but not includi4
a., rou AE
t
am given. Among the probi;;B treatOd in this wori,
electrolitio solutions, ultrasonic measurement, dielectric
and tharmodynantLe properties of various mixtures, spectro-
scopic azxlt!~i~ etc Reforencoa accompany Individual articles.
CG_o TE.-
-..~d
namic
FRO
o
r
-
T
Inka=01. of 36onelectralyted 36
ZkzI=X__Y_jL. nuctuation or Snargy In solutions and Their
t1on to deat Capacity 43
nahor I Z and V. 1. Dislatich. Molecular Theory of
48
soluilfni
1
1
"
1_1L, and 11 Y Critical Phenomena
'
_9l
2
1T
&
B
r
ftqu1d Systems 49
y
study of the Critical States of Inlividual
Their Mixtures With the Aid of I'-_v3cnXc
Nothods 56
_ABjjajiaX._9_J6 ~ and A. A. Phase Transitions in
I
a
MIhr-ft
..Iflaatlon 45T
31"lo Systems and
Use of 'Mtromosdo Measurements 1A the
StuiVaf solutions 72
and Jr- r. Zamborak. Transformation or
Binary ROt*r0UOOtrop;s Xnt_0_53ic"*o ropis and Boamozootropos T9
_jjarnn1d.m_AJ.. and A. 0. Morajqtn!XjY_ Applicability or
-
Kanowalov'4 and Vr*vsRry-r1-ZWw
s to Ternary solutions 87
RmI&tIon of Thermo-
)C S1n=nnkLn__L_X., and R. M._2huLMa.
-
-
W
tnrated and early saturated Ternary
dynamLL0 ftvportla. of
la
Solutions to Their Composition 93
RUhabom"r-X-P. Thermodynaimlo Properties of Water in
'Nolut.lons of 1IactrvIjt*s 9T
O"clation. or gloctrolytas in Xonaquoous
_42
105
Al*kVjmndrox__T__V_, and rvahova Th:rmodyn-lo Propor-
-
-
Z

~-N
GT;
01rt a
vcr Nonacu*ous solutions L ;
--L lis
1=&Ylcvo S. A. p V A Kramer L. X. KUtay". and Yo. V.Titov. _
3t%47 Of the Kffeci ci 3olvenCe on the Strength or Acid@ by -
Neana of Optical Methods L22
-ALkellskis-1-2- Dissociation of Acids and Complex Compounds
wal Methods of studying it L26
TataimIrsidy, Change In Thermodynamic Functions in
a aoc~.Atlou of Ions In Solutions 133
!S1a-V-iLz4M4rmod7n&ma1s4 of *Aquacomploams. 140
study of Partial ir~&surs Of solvent In
Avocus Solutions of alwatrolytos 144
no Interactions or Proton With Molecules (Water,
~
~m
~
.
lhyl
1
IthYl And n-Propyl Alcohols) 152

5W
AUTHOR: Vasillyev, V. P. SOV/153-2-2-30/31
TITLE: On the Dissociation of the Aquo-complexes and on the Study
of the Ions in Mixed Solvents (0 dissotaiatsii akvokomplek-
sov i izuchenii ionov * smeshannykh rastvoritelyakh)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Xhimiya i khimiches-
kaya tekhnologiya, 1959, Vol 2, Nr 2, Pp 301-303 (USSR)
ABSTRACT: The publication of the discussion-paper by Ya. 1. Turlyan
proves once more the great interest taken in the problem
in question. In this connection it is necessary to explain
the fundamental theorems by Turlyan and to discuss his
remarks. The author is against neglecting the three factors
which influence the displacement of the half-wave potential,
except the change of the dielectric constant of the solvent,
as is the case with Turlyan (Ref 1). Turlyan's statement
that the influence of the persolvation-proce 'ases on the
aforesaid potential-displacement is irrelevant, remains un-
proved. The data submitted on the solvation-heat of some
alkali-halidee prove with complete certainty that the
solvation-heat of the salts in methanol and ethanol is
Card 1/4 definitely greater than in water. There is no reason for

On the Dissociation of the Aquo-complexes and on the SOV/153-2-2-30/31
Study of the Ions in Mixed Solvents
the statement that the heat or the free solvation-energies
of the cadmium- or zinc-ions are the same in water and in
alcohol. Consequently, the effect of the dehydration- and
persolvation-processes must not be neglected as "insignif-
icant". Furthermore, Turlyan attributes to the authfDr
first of all the neglect of the dielectricity-constant and
then proves, that one must not do this. If one argues the
way Turlyan does, then obviously one ought to revise all
equilibrium-calculations in solutions, under consideration
of the influence of this constant. According to Turlyan,
the instability-constants of the complexes in aqueous aolu-
tions would only have to decrease with the increase of
temperature. Of course, the instability constants can in
reality increase as well as decrease with increasing
temperature, that is in accordance with the sign of the heat-
effect of the reaction. The author maintains he has not
neglected the dielectricity-constant. There would be no
need to argue this any more, but for the fact +Jiat Turlyan
stubbornly underlines the extremely important role.of the
Card 2/4 dielectricity-constant and sets it against other 3 factors.

On the Diisociation of the Aquo-complexes and on the SOV1153-2-2-30131
Study of the Ions in Mixed Solvents
As may be seen from the examples quoted by the author that
the consideration of this characteristic of the solvent alone
may lead to the most improbable results. In the case of
Turlyan it is not clear what he aotually understands by the
conception of the effective ion-radiua. It follows from all
this that the method of determining the ion-4adii from
polarographic knowledge, is too crude and'dode not even
allow estimating one tenth of an Angstr6m unit. Consequently,
the conclusion by Turlyan concernimg the con~tanoy of the
radii of aquo-ions, the immutability of their composition
and nature of the transition from water to the mixed solvent,
is proved neither theoretically nor experimentally. The
measurements of the dilution-heat ofthe alcoholic-aqueous
solutions of Cd(NO3)2, which were carried out by the
author, obviously show that the composition.0-f the aquo-com-
plexes in a mixed water-ethanol-Bolvent undiaigoes consider-
able changes, compared with the composition in water. The
polarogrEphing of solutions with a very high content of
Card 3/4 non-aqueous solvents, proposed by Turlyant is apgarently

On the Dissociation of the Aquo-complexes and on the SOV/153-2-2-30/31
Study of the Ions in Mixed Solvents
impracticable, as the potential jump at the phase-transition
cannot be comprehended with sufficient accuracy. In con-
clusion, the suitable methods are discussed. There are 9
references, 7 of which are Soviet.
ASSOCIATION: Ivanovskiy khimiko-tekhnologicheakiy institut; Kafedra ana-
liticheskoy khimii (Ivanovo Chemical-technological Institute;
Chair of Analytical Chemistry)
SUBMITTED: January 16, 1959
Gard 4/4

AUTBORS: Vasilly Vasillyeva, V. N. .9 0711' 15 3 - 2 -4 - 12
_Zt~~~
TITLEt On the Variation of Entropy in the Dissolution of Salts
PERIODICAL: Izvestiya vysshikh uchebny1ch zavedeniy. Khimiya i khimichf~slkaya
tekhnologiya, 1959, Vol 2, Nr 4, PP 522 - 527 (USSR)
ABSTRACT: The possibility of determining certain dependences in 'the
entropy variation in the dissolution of salts is very teMDting.
Thus it would be possible to determine the entropy variation
even of empirical or seini-empirical dependences if no experi-
mental value is known. The entropy variation upon transition of
a solid salt into aqueous solution under general standard
conditions is understood by the variation (dissolution entropy)
mentioned in the title. If the well-known thermodynamic inter-
relation is applied to this process, the equation
nRTln a .,&, _ TA,3 (1)is obtained which connects the ionic a:~ti-
vity in a saturated salt solution (a), the solution heat (,Nrl)
and -entropy (W). The dissolation entropy can be computed by
means of equation (1) using data from reference works regarding
solubility and dissolution heats. At present, the entropies
Card 1/ 4 of many solid salts, and salts in solution, are more or les3

On 'the Variation of Entropy in the Dissolution of Salts SOV/157/-2-,:--o,/12
well-known (Refs 1-3). This opens a new way of computing the
dissolution entropy. If the salt in aqueous solution is pract'-
cally entirely dissociated, its entropy in this solution can be
equated to the sum of entropies of the constituent, ions, i.e.
Saq = nSM+PSX (3), SM and S X being the entropies of the salt
cation and salt anion, respectively, and n and p the stoichio-
metric coefficients in the formula for the salt. It was inter-
esting t 'o determine the dependence of the dissolution entropy
on any function. This dependence was
supposed to include salts of various types, i.e. it should be
usable for ions of varying charge. From this point of view, the
hydration heat of the ion was very interesting since the disso-
lution process of the salt is extensively related to the hydra-
tion effect of the ions upon transition from crystal into solu-
tion. The paper under discussion aims at explaining the relation
between dissolution entropy and hydration hea 't of the cation for
a greater number of salts. In this case, only salts formed by
the cations of the most important subgroups of the I and II
groups of the periodic system are concerned. A quantitative ex-
Card 2/4 pression of the dependence in question ,-an be deterinined from

On the Variation of Entropy in the Dissolution of Salts SOV/153-2-4-lo/"2
the diagram: hydration heat - entropy variation- Figure 1 3how3
the values discussed of the salts of alkali metals with mono-
valent anions. The entropy variation was computed according
to equation (2) considering equation (3). As can be seen from
figure 1, the entropy variation depends linearly on the hydra-
tion heat of the cation. Table 1 shows that the constant of
the eqdation; &S - 0.306 H hydr +const (5) remains satisfactorily
stable. Thus it can be maintained that equation (5) expresses
the relation of the dissolution entropy of salts of type (4-1)
with the hydration heat of the cation in a rather satisfactory
way. Figure 2 shows the relationship between the entropy varia-
tion in the dissolution of salts of alkali netals of type M ?X
and the hydration heat of the cation. Here, too, a distinc,
linear Upendonce can -be seen. Thun , the entropy varia t ion
mentioned will be expressed by the equation & S-0.60all hydr f '_'onat
(6). Table 2 shows the above constant for salts of alkali me-
tals with 2-charge ions. The constant remains practically stable
(with the exception of rubidium carbonate), Figure 3 shows the
diagram: entropy variation - hydration heat of the cation for
Card 3/4 the salt sequence; magnesium, calcium, strontium, and barium.

On the Variation of Entropy in the Dissolution of Salts SUV/153-2-4-1o/32
Equation (7) holds in this case. All three e-`-s
and (7), are special cases of a more General equation:
,&S= 0.30 ' AH + const (8); z = the charge of the salt
z hydr
cation. The equation also expresses a linear de7,endence, and
renders possible the estimation of the entropy o.~ oolid salts
(Table 4). Professor K. B. Yataimirskiy participated ir^i thp
discussion. There are 3 figures, 4 tables, and 8 references,
7 of which are Soviet.
ASSOCIATIONt Ivanovskiy khimiko-tekhnologicheskiy institut) Kafedra analiti-
cheskoy i fizicheskoy khimii (Ivanovo Institute of Chemical
Technology) Chair of Analytical and Physical Chemistry)
SUBMITTED: January 28, 1958
Card 4/4

5(4) SOV/76-33-2-14/'45
AUTHORS: Vasillyev, V. P., Zolotarev, Ye. K., Yatsimirskiy, K. B.
TITLE: The Entropy of Gaseous flonatomic Ions Entropii gazo-
o',)raznykh odnoatomnykh ionov)
PERIO!..ICAL: Zhurnal fiziche-koy 1--hiriii, 1959, Vol 33, Irr 2,
PP 328 - 330 (ITSSR)
ABSTRACT: Values of the entropy of ~;aseous ions are often needed
for calculating the entropy of hydration of ions for the
quantitative calculation of a series of cycles in which
,~~aseovs ions appear in intermediate stages. The calculation
of the entropy of gaseous monatomic particles- is carried
out using a well-known equation of statistical therriody-
namics (1) (Ref 2) in 7hich the entropy of the rotation of
the monatomic ga-ses is neglected. In chernical equilibrium
at medium. and hi,-,h tenperatures the entropy of tl-le nuclear
spin can also be neglected (Ref 1). Thus in the calculation
of the entropy of a monatomic ion at standard conditions
only the atomic weight of tho particle and the statistical
,,.reight of the cloctronic ground level must be known. A
Card 1'2 table is given (Table 1) shoaing entropy values for 66

The Entropy of Ganf~ouo ronrttoliC Ions ',OV//7i)-33-2- 1 -1/45
Zaseous monatomic ions at standard conditions. Tne 7-~Jori'y
of the data on the electronic configuration and the terms
of the rround ntnte %-iere tz,.Iken from the publications
(Refs 3,5). In the canen where no data were given in the
publications the most Probable electronic ntrlicture was
assigned and the ter.1.1s viere derived accordina to GreCory
(Grej~ori) (Ref 4). There are 1 table and 5 references, 2
of which are Soviet.
A'1*0CL~-.TION: Ivanovskiy kliimiko-tel:hnologicheskiy institut (Ivanovo
Chemicnl Technological In.-Aitute)
July 5, 1957
Card 2/2

;..b. Ya
Va i 1. in "nw lorr~L~,-r:n
21" ta-,.Ics.
iJI17 j
1959.

VASILIYHY..,j~p.; VASILSYRVA. V.N.
Ratropy of solution and heats of hydration of ions. Izv-
vys. ucheb. zav; khim. i khim. tekh. 3 no. 5:826-828 t60.
kMIRA 13:12)
1. Ivanovakiy khimiko-tekhaologicheakiy inatitut. Xafedra
analiticheskoy i tafedrs, fizicheskoy kbimii.
(Ions) ('Batropy) (Heat of hydration)

S/153/60/'003/006/009/GO9
B103/B2o6
AUTHORSs Vasillyev Korableva, V. D., Yatsimirskiy, X. B.
TITLEs Conference on kinetic analysis methods
PERIODICALt Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i
khimicheskaya tekhnologiya, v. 3, no. 6, 1960, 1113-1116
TEXTs In the introduction the authors state that coordination and discus-
sion of kinetic analysis methods have been deficient thus far, although
they are successfully studied in the USSR and abroad. They are of special
importance for the determination of minute amounts of admixtures and con-
centrations of elements. In this 'connection the Ministerstvo vysshego i
srednego spetsiallnogo obrazovaniya SSSR (Ministry of Higher and Inter-
mediate Special Educations, USSR) convened a Conference on Kinetic Analysis
Methods, which was held at the Ivanovskiy khimiko tekhnologicheskiy institut
(Ivanovo Institute of Chemical Technology) from June 14 to 16, 1960. 16
lectures werodelivered by collaborators of the Institut geokhimii i
analiticheskoy khimii AN SSSR (Institute of Geochemistry and Analytical
Card 1/4

S/153/60/003/006/009/009
Conference on kinetic analysis... B103/B206
Chemistry AS USSR), Institut obshchey i neorganicheskoy khimii AN USSR
(Institute of General and Inorganic Chemistry AS UkrSSR), the Universities
of Moscow, Kiyev and Dnepropetrovsk, the IvanavoInstitute of Chemical
Technology and IREA (Institut khimicheskikh reaktivov, Institute of Chemical
Reagents). The conference was also attended by representatives of several
colleges, scientific research institutes and works laboratories as well as
chemists from Ivanovo. The following subjects were dealt with in the
lectures: I. P. Alimarin and Yu. V. Yakovlev; "The possibilities of modern
determination methods of 11ultrasmall" admixtures in "superpure" substances";
K. B. Yatsimirskiy, "The present state and development prospects of kinetic
analysis methods".. A. K. Babko, B. Ye. Reznik, V. I. Kuznetsov and
I. G. Shafran.participated in the discussion. Further lectures dealt with
the following subjects: A. K. Babko and L. V. Markova; "The photometric
determination of microamounts of sulfides and sulfur in metals on the basis
of the catalytic effect on the iodine-azide reaction"; B. Ye. Reznik and
N. V. Pchelkina, "The photometric determination of copper and molybdenum
on the basis of their catalytic effect"; B. Ye. Reznik, G. M. Ganzburg and
N. A. Bednyak, "Study of the catalytic effect of some transition elements
Card 2/4

3/153/60/003/006/009/009
Conference on kinetic analysis... B103/B206
on molybdenum reduction by means of thiocyanatell; R. P. Pantaler, "A new
kinetic determination method of tungsten- and molybdenum traces".
L. T. Bugayenko reported on the use of kinetic analysis methods in radia-
tion-chemical studies. S. I. Sinyakova gave a review on the use of kinetic
catalytic currents in polarography for the determination of verj small
concentrations of several elements. K. B. Yatsimirskiy and L. I. Budarin,
"Determination of the equilibrium constants in systems with complex forma-
tion on the basis of the study of catalytic polarographic currents";
V. I. Kuznetsov and Ye. S. Ullyanova, "Radiation-kinetic determination of
polonium". L. I. Budarin and K. Ye. Prik showed and discussed new types
of instruments for the kinetic analysis. Lt. N. Orlova reported on "Kinetic
determination methods of silver in solutions". Apart from those already
mentioned, G. A. Pevtsov participated in the discussion. Further lecturess
A. K. Babko and N. M. Lukovskaya, "The effect of complex-forming substances
on the catalysis of the chemiluminescence reactions". L. P. Rayzman
reported on the results of the study of complex formation of zirconium with
anions of organic acids by the kinetic method. K. Ye. Prik,"Application
of the kinetic method for studying the complex formation of tungsten (VI)
Card 3/4

3/15 60/003/006/009/009
Conference on kinetic analysis... B103YB206
in solutions"I M. 13. Shustova, "Unadium, determination in metallic titanium".
M. L. Chepelevetskiy pointed out the necessity of studying the kinetics of
heterogeneous prooesses, eBpecially the formation of crystalline precipi-
tates, for the purpose of using these data in the analysis. V. M. Peshkova
pointed out the possibilities of combining the kinetic methods with extrac-
tion methods for the determination of several elements. Some results of
the conference were summarized in the closing address by K. B. Yatsimirskly
and A. K. Babko. The authors are of the opinion that the conference was
useful and showed that the kinetic analysis methods are being successfully
developed in Moscow, Kiyev, Ivanovo, Dnepropetrovsk, KharIkov and Odessa.
The delegates had the opportunity of informing one another on the results
and of indicating future research trends. The authors propose to elaborate
concrete methods for practical use in the analysis of industrial objects.
New types of instruments are to be elaborated and manufactured in series.
Standards with fixed content of microadmixtures should be prepared and
corresponding data should be published.
Card 4/4

-VASIL, YNTIARF-a-
Some comments on the article by IA.1. Turlian, PInstability,
constants of complex ions as a function of the L..iectric
constant of the solvent.* Zhur. necrg. ichim. 5 no. 12:2851-
2852 D 160. (MIRA 13:12)
1. Ivanovskiy khimiko-tekhaologichook-iy iastitut.
(Complex ions) (Turlian. 1A.1.)

'31/076/60/034/008/023/059/ZZ
B015/BO65
AUTHORSt Vanillygy, Y. P., Z lotarev, Ye. X., Kapustinskiy, A. F.,
M:~khphonl~~,_K. _E.., Podrorn ypL. '~et_ and Yatsizirskiy,X.B.
TITLE-. The Most Probable Values of Chemical Heats, IlEnergies, and
Entropies of the Hydration of Various Ions at Infinite
Dilution an 0
PERIODICALs Zhurnal fizicheskoy khimii, 1960, Vol. ~4, No. 8,
pp. 1763 - 1767
TEXTs In the last 11 years three of the present authors have published
values of the chemical heats -.Hi and energies Z i of hydration and of the
h h
entropy S 0 of various ions in aqueous solutions (Ref3.1-3). As these
i
values disagree and since many topochemical characteristics have been
improved during the last few years, the most probable values of the above-
mentioned quantities have been thoroughly checked. Results are given in a
table; two methods were used to caiculate the values for t.H as from the
Card 1

The Most Probable Values of Chemical Heats,
Energies, and Entropies of the Hydration 0of
Various Ions at Infinite Dilution and 25 C
S/076/60/034/008/023/039/XX
B015/BO63
i i i
equation LH h -'H aq + -H gas -102.5-n) kcal/g.ion (1) (-H aq and L'K gas
0 standard variations of the enthalpy of the ion during its formation in
solution or gaseous state; - 102-5 kcal/g-ion - standard variation of
enthalpy during th~ production of a hydrated proton in an aqueous solution
of infinite dilution; n - ion charge). b) The table also contains the
average values of the simultaneous calculation of 'R i from the total
~ h
chemical heat of hydration r'H~ of the electrolyte at infinite dilutiont
h
from the energy '~H lat 0 f the crystal latzice, from the integral heat of
solution i%H 0y and from the values of the thermochemical cycle. The
initial values for the calculation of S' are given in coluains 3 and 4i
h
0
5aq . standard entropy of water ions referred to the entropy of the
0
proton in the aqueous solution go, - 01 Sa standard entropy of
i H as
gaseous ional LS h . chemical entropy of ion hydrationj and
Card 2/3

The Most Probable Values of Chemical lients, S/076/60/03A/008/02-3/039/,X;(
Energ~es, and Entrop'ies of the Hydration of B015/B063
Various Ions at Infinite Dilution and 25 0C
AS i (So - So + 6-35),'e.u. (5). There are 1 fable and 19 references:
h aq gas
13 SoViet and 6 US.
SUBMITTEDt November 15, 1958
Text to the tables The Most Probable Values of Chemical Heats, Entropies,'
and Energies of Hydration of Various Ions at Infinite Dilution and 25 oc-
0
Column 1i ion; 2: - AH , kcal/g,ion; 3: .... e.u.-; 4: S e.u.;
h gas
5t e-u-; 6t .... kcal/g-i9n.
Card.3/3

VASIL I YZV,-V.F--
The=,ochemistry of alcohol and alcohol-water solutions of
cadmium nitrate. Izv.vyo.uchob.vav; khim.i khim.tekh. 1j, no,5:
743-746 161. (MIU 14: 11)
1. Ivanovskiy khimiko-tekhnologicheakiy inLtitut, kafedra
analiticheakoy khimii.
(Cadmium nitrate) (Heat of solution)

VAS IL I YEV 11 V. P.
State of cadmium nitrate in aqueous solution. Izv.V7B.ucheb.zav~;
khim.i khim,tekh. 4 no.6.936-940 161. OUU 150)
19 Ivanovskiy khimik-o-tekhnologicheskiy institut, kafedra
analiticheskoy kbimil.
(Cadmium nitrate)

V_A~ILIYEV Vep.
- t~
Heats of dilution in mixed solvents. Zhur. neorg. khim. 6
no-3:664-673 Mr 161. (MIRA 14:3)
1. Ivanovskiy khimiko-tekhnologicheakiy institut.
(Heat dilution)

VASIL'YEVO-V,pep KORABLEVAI V.D.; YATSIMIRSKIYy K.B.
Conference on kinetic methods of analysis. Zhur. anal. khim.
16 no. 1:118 Ja-F 161o (MM 14:2)
(Chemical reaction, Rate of) (Chemistry, Analytical-Congresses)

VASILIYLV,, V.P.; VASIL'YEVA, V.N.
Change of solubility in the series of alkali metal salts. Izv.
vys.ucheb.zav.; khim.i khim.tekh. 5 no.1:12-16 162. (MIRA 15:4)
1. Ivanovskiy khimiko-tekhnologicheakiy institut,, kafedry
analiticheskoy i fizicheskoy khirnii.
(Alkali metal salts) (Solubility)

VASILIYEV, V.P.; VASILIYEVA, V.N.
Entropy of the crystal lattice of salts with monoatomic ions.
Izv.vys.uchob.zav.;khim.1 kbim.tekb. 5 no.2:243-248 162.
(MIRA 15:8)
1. Ivanovskiy khimiko-tekhnologichoskiy institut, kafedra
analiticheskoy i fizicheskoy khimii.
(Crystal lattices) (Salta) (Entropy)

VASILIYEV, VO PO
Heats of solutiofi In mixed solventa. Izv. vyB. ucheb. zav.;
kbim. i khim. tekh. 5 no.5.'731-733 162.
(KIRA 16:1)
1. Ivanovskiy kbimiko-tekhnologicbeskiy institut, kafedra
anallticheakcT khimii.
(Heat of solvation)

VASILIYEV. V.P.
Thermochemical. characteristics of cadmium nitrate complexes in
aqueous solution. Zhur.neorg.khim. 7 no*3055-561 Mr 162.
(MIRA 150)
1. Ivanovskiy kbimi tekhnologicheakiy institut.
(Cadmium nitrate) (Heat of solution)

VASILITEVII VIP,
Hffect of the Ionic force on the Instability constants of
complex oompounds. Zhur. neorg. khim. 7 no.8:1788-1794
Ag 962a (MIRA 16:6)
L Ivanovskiy khimiko-tekbnologicheakiy institut.
(complex compounds) (Ionization)

ACd NR'. AP60Z3881 SOURCE; CODE. UR/0109/66/011/007/1331/1332
AUTHOR: Vasil'yev, V. P.; Tartakovskiy, V. M.
ORG- Tashkent State University im. V. I. Lenin (Tashkentskiy gosudarstyeanyy
universitet)'
TITLE: Problem of determining excess barium in "doubled" oxide-coated
cathodes
SOURCE: Radiotekhnika i elektronika. v. 11, no. 7, 1966, 1331-1332
TOPIC TAGS: ele-ctronic tube cathode, oxide coated cathode
ABSTRACT: The results are reported of an experimental study of excess Ba in a
pair of oxide -coated* 5 -mm, diameter 70-80-14 thick cathodes firmly pressed
together; the cathode base was made from 100-14 thick Ni. Ba content was deter-
mined by the radioactive -iodine tracer method; error, 1016 or less; 8 specimens
:Card J/Z uDc: 6zi.385.7.011.2

ACC NR: AP6023881
were tested. It was found that: (1) The evaporation of excess Ba from "doubled"
cathodes is'more difficult than that from single conventional cathodes; the
"doubled" set may sometimes contain much more excess Ba; hence, the results
of electric -conductance and heat -conductance measurements in a "doubled"
cathode cannot be directly applied to real cathodes; (2) The rate of exce6s-Ba
formation increases when a current is passed through the coating. "V. N.
Chernenko, a 5th-year student of Physics School, Tashkent University, took part
in the work. Orig. art. has: 1 table.
SUB CODE: 09 SUBM DATE: 13Sept65 ORIG REF: 005 OTH REF: 001
I dard_2,/Z

LOBANOV., G:*A.,; -WSIL'IEV,. IMi.
LcwerJ.ng t". rasmi7em,5nt li-mits of automati- e'lect.rcnic
potentiomete-n-4. 'Yhur. f!z. kh1m,, 39 nc.9:231-7-~3-18 3 165.
(milip is-.10)
I. Ivaw7ski7 khimiko-takh-nologichaakiy Irvititut.

VASILfYEV, V.P.; VASILIYEVA, V.N.; IVANOVA, F.I.; MOROZOVA, 0.14.
*~i ~~- -,
Configuration equilibrium in solutions of chloride and thiocyanate
complexes of cobalt. Izv.vys.ucheb.zav.;khim.i khim.tekh. 6
no.5-.712-716 163. (14IRA 16.-12)
1. Ivanovskiy khimiko-tekhnologicheskiy institut, kafedra anali-
ticheskoy i fizicheskoy khimii.

PW,MOV, V.P.; VASILZJHV~ V.P.
Determination of a fras alkaline earth metall in oxide cathodes
vith the aid of radioactive iodine. Izv. AN SSSR. gar. fiz,.
28 no.8tl354-1359 Ag 164 (MIRA 17:8)

ABBASOV, A.B.; HIKOLISKALA, A.V.; GERASIMOV, Ya.I.; VASIL'I"EV, V.P.
I .-I.,,---.-.-,-
Thermodynamic properties of galiiuri antimonide studied by
the electromotive force method. Dokl. All SSSH 156 no.6:1399-
1401 Je 164. (XII RA 1'1: 8)
1. Moskovskiy gosudarstvennyy univeraitet imeni Lomonosova. 2.
Chlen-korrespondent AN SSSR (for Gerasimov).

VASILIYEV, Vadim Petrovich (Vasylliev, V.P.1, prof.; BELOUSOVA,
M-
G
.
(Chemical control of peat-d Xhimichni zasoby borot1by z
shkidnykanW. KyivtDerzhsIlhorpvydnv URSR 1964. 38 P.
IMIRA 17:4)

VASILIYEV, V.P.; VASILIYEVA, V.N.
"-' '71~- _
Isobaric potential of the lattice of compounds formed by monoatamic
ions with an octaelectronic outer shell. Zhur.fiz.khim. 36 no.10:
2238-2241 0 162. (MIRA 17W
1. Ivanovskiy khimiko-tekhnologicheskiy institut.

VASILIYEV, V.P.
Thermochemical study of the nitrate complexes of strontium
and barium in an aqueous solution. Zhur. neorg. khim. 9
no.3:641-646 Mr 164. WRA 17:3)
1. Ivanovskiy khimiko-tekhnologicheakiy institut.

VASILIYF,V, V.P.; VASILIYEVA, V.N.
Stability in certain halides in the gaseous phase. IEv.vys.ucheb.z&v.;
khim.i khim.tekh. 6 no.4:693-695 163. (NIRA 17-2)
" I
1. Ivanovskiy khimiko-tekhnoLngidheskiy institut.',Katedra analiticheakoy
i fizicheskoy khimii.

ABBASOV, A. S.; RIKOLISKAYA, A. V.; GERASIMOV, Ya. I.; VASILOYEV, V. P.
lbermodynamic pron-ties of indium arsenide studied by the elect-
romotive force method. Dokl. AN SSSR 156 no. 1:118-120 My 164.
(MIRA 17:5)
1. Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova.
2. Chlen-korrespondent AN SSSR (for Gerasimov).

"successes of the chemical ,:ieth.-.d c;f cc.-i`-,at.tin pest-= and th- .,-,r~snectc r thle
introduction of cl-enical mearis ot' ,IaA ~rctectic.u -Int.. a-i-Joulfin-1
F4port t;resented at the 2-A 1.11-Unirn Scierti -fic -,o; fererwe ,.!i tl,,e
By-jene and '~oyicolo- of 1'esticides, ~-;inistry cf ilealtJ) Co.-,,-~Jttee
E~ -Y
o,i the Study and Ee..ulallion of 'lev .--'o--*,srn(,Lls (,hendca-Is of thn ;ai.-,, -n
Sanitar.., Irspecti-n LISSR anO Kiev institute "T at or a:A cccup,-
tional Diseast-s., Kiev 17-19 6ct 1962.
(.-Iit-:~.vena i Sanitariya, "G. 3, 1963 P. 1:--.,h-1o5-)
Kiev D-Istitute of 1,21-or H.'Ciene and ~.~ccupaticnal D;.sce~nec.

.-VASIL'YEV, V.P.; VASWYEVA, VJI.; KLINDUKHOVA, N.A.; PARFENOVA, A.U.
EquIlibria in aqivous solutions of calcium, strontium, and barium
nitrates. Izv.vys.ucheb.zav.;kUm. i khim.t,-kh. 6 no.2:33)-341
163. (14IRA 16:9)
1. Ivanovskiy khimiko-tekhnologicheskiy institut, kafedra
analiticheskoy i fizicheskoy khimii.
(Alkaline earth nitrates) (Complex compounds)

VASILIYEV,, V.P.; MUKHINA, P&S.
1-
.......................
Making all4q, ce fcrr- tbt- salt eff eat in the reactions of a complex
formation. Zhur. neorg. khim. 8 no.8tl8~j-1899 Ag 163-
(KM& 160)
1. Ivanovskiy khimiko-tekhnologicheskiy institut.

V.P., stDrs)iiy riaucirn.-ty totrudlnilr.,
"resent state of mticsl rauge-finling tr~chnll-,LeE 3'jr-,al. IZV.
VY8. licheb. zav . ; geod. i lerof . no . 2 :7'3-11. 157. (14 IRA 11 -7)
( RD rw,, e I' I n d i ng, ~

AUTHOR: Vasillye v, V. P. 115-5-5/44
TITLE: Device for Checking the Pitch of Bushing-Roller Chains (Pribor
dlya kontrolya shalga. vtulochno-rolikovykh tsepey)
PERIODICAL: "Izmeriteltnaya Tekhnika", No 5. Sep-Oct 19579 PP 14-15 (USSR)
ABSTRACT: The article proposes design of a device for measuring the
pitch of bushing roller chains under varying loads. Practical
experience shows, that chains do not break because they lose
strength, but because they reach prematurely the maximum
allowable pitch limit. Further it is said that chains are
being delivered by factories with "worn" pitch, which is
caused by ungrounded tolerance specifications and inaccurate
pitch measurements. The proposed design of the measuring in-
strument is claimed to be simple and convenient, and applic-
able for automatic inspection of chain links.
The article contains 1 drawing.
AVAILABLE: Library of Congress
Card 1/1

VA,SILtyV~ V.P. Col. yed. Service
"The Responsible Task of the Mfilitar7 Medical Service,u Voyenno-medits. zhur...
No.2,, pp 16-19, 1955
Translation D 311966, 16 *tug 65

VASILIYEV V.P. doktor biolog.nauk; KITITSYN, Ye.N., kand.seliskokhoz.
nauk
Effectiveness of phosphamide in the poisoning of plants. Zashch.
raot.ot vred.i bol. 7 no.5:34,35 My 162. (KMk 15:11)
(Insectioides)
V
J
Rw Mm7r

NAZARYAN, Ye.A.; LOBANOV, G.A.; TRUSEVICH, G.V.; STEPANOV, S.N.; DUWMINA,
K.K.; RYBAKOV, A.A.; KARANW, P.G.; ULlYANI&qCH3VA. A.M.; TTrH OY,
U.N.; KAZIZADR, F.H.; SIIZRMO, I.I.; SKMOV, Y.F.; SHIDn'KO,
I.Kh.;--VASZIIZV, V. P.; &ISUOYA, X.I.; SKRGSYBV. V.1., red.;
GORIKOVA, Z.D., i-ean-.-io-d.
[Grushn] Pear. Moskva, Goo.izd-vo sallkhoz.lit-ry. 1960. 534 p.
(MIRA 13:12)
(Pear)

VASILIYJ�V, V.R.
Idquid fuel heater for warming up bitumastica. Na Btrol. Moak. '-I
no-3:22 Mr 158. IkKW. IL:;,~)
(Bitumen)

VASILINV. V.S.
Analysis of alveolar air from patients with bronchiectasia (with
summary in Angliabl. Rksper.khir. 3 no-1:12--14 J8-F '58.
(HM 11:2)
1. Iz kafedry obahchey khirurgii (zav. - prof. V.I. Struchkov)
lechabnogo fakullteta I Moskovskogo ordens lenina meditsinakogo
Instituta Imeni I.H.Sechenova.
(BROUGHINCTASIS, physiol.
alveolar air sampling, preop. & postop. (Rus))
(nSPIRATION, funct. tests
alveolar air sampling in bronchiectesis, preop.
& postop. (RUB))

VAS14v, Vosili-i-Silant'evich, 1896-
Instructions on the field analysis of water. Saratov. Tip. 14. V. Krai.poligrafErests.
1930- 33 p-

VASILITEV, V.S.
Agricultural accidents in Ust'-Pristan' District (Altai Territor7)
Sov.med.19 no.8:62-64 Ag '55. (MIRA 8:10)
1. Khirurg Uat'-Pristansko7 rayonnoy bollnitsy.
(OCCUPATIONAL DISEASES
in Russia, agricultural traumatism in Altai region)
(WOUNM AND INJURIES,
agricultural traumatism ih Altai region in Russia)

VASLL'YX7, V.S.; FRIMAN, M.I.
In the AVineering Center. Avtom., telem. L ffriazi ro.4:45-47
Alp 157* (MIRA 144)
l.' Nachallnik otdala massovykh mropriyatiy tokhnicheakoy pro-
pagandy TSentrallnogo doma takhniki (for Tasillyev). 2. Starshiy
redaktor metodicheskogo otdela, TSentrallnogo dom tekhniki (for
Priaman).
(Railroads-liquipment and impplies-Exhibitione)

-*7-0.
WO 0 0 0 06 0 0 *0 0 00 0 0 00 000*04%, 0 os ooGoqoo#q*O*;;;O-G
"I
0 1 6 8 9 at 11 it #I w I] to 11 if rf a n17 n x a is I? A)q la 11 Ll umisuslum&v u 41 Od ds f:
A A- A-M P~ 9 A I I -V I - I I Ah W M W It 1,
A
00
M. &jj
a,, V. VOMxv. JI'm
00
00
Vtws j4kpb. mis"al. Gow. 1931, 1. 240
F.SC"AJXXR
An as. lysis d batite Is give"
of
coo
00 j Go
90 go*
a-$ L AxftALLtjCfK&L UffROLff CLASSWICATIC. c I
..... Q1. 71.
~U 10 1.1'; -a- .;- j---r- Al I s -a ow.0 1-jj a .3
u n t sit
Al It C, 11 It 31 14 St t S,
'a 'a0
. F'.6

0 0 0 0 0 fo 9 41 0 0 4 0 0 0 0 0 0004
t it to to to 1, is to 10 a n m is A to to to IV I IV it it a it I, a c to of it 0
&a %A, UP Is
1110
00
0 0

00 C
00 or
minermlistillod 0t walef ill the R hoikilloi basin Poodal
00 a f schev province, Lower Volga regiun, It .00
00 10. N'- 3. ;9 1 Ult l%kft-Avmttfw%l
It t A

j zo 0

00 .00
so woo
00 x
.00
00 1**
Go Go
00 -
I

Of
040

to of
ot 1 1 4
0 0 0 0 0 0 0 0 0 0 0 & 0 0 a 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 i0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 so 0

- F.
;o 0 0 0 0 0 6 0 0 10 0 9 0 0 9 0 0 9 0
O'D OUVAW'Ji
W* -0
4 11 1? is a I u is )a I$ A
_JIL _J -A L, A 14 P 9 A I 1L__A .1 1 All 0 to u 6
.00 A
Ittr poticiend wkp of tow poor resister region.
to"Yor Z.P'.k# G-J~f'j. I'Kfr--.r - 0 0
_i_
St it
15, Nsp~ I 111MVII&OW"US). Itc. zt
0 wmi. he well m4irn cj( aw rpi-ri-rititAry
44 tilt- ChAP"v rrgioo wr munlAr lit Itow oi the rivrr-
00 simmutinst Ismixom urw the tU*4uyA Sakma Rawrl A1111 10
IN-31 the Itfuundsonstelsof the Tran%VlAsta rrows. Thi,
0 md) awl-'ri Irml the Aid hwitim, the KlivAls-cs Omits-,
008 moi ll,,.SsrtA dAys spent she
008 7: m -I Iwo I . VI
-43:~.-. 11CI It L'41,3:1 Ati,l IM, C," I.-Al. IW,
00 *11.1 Ntc' ' (17-S. 01 fi slut 1118A. Ulw Atcl aud
khtqti, is I"lliAt"I wrif wairvi miti, the Hol'shavit Kit*1stim4
604 Will ,"Ilmsin In Ing in f I Vl- 1111, PA), - loll lit', Is .1; 1
00.) Va' Hit 1 A"ll M 40A. The Ifiltirmhou'l wrills:
war flu, 1114,%havot I's.'.1111111A frilil"I Ift"o-witl a -I", Itil
00,2 Illout. f"f fill% frown I", I114-it o"ItIns. still Otte loftillioof~n.
11 .11 mnutr- lit then IISILI& "Alt Coultent "nit Ili the I"r-
:
14onmiAntv Ill clshicides juml HIS the 3,prangs are sitntLu it)
31 The wAtet3i a( pecrulcurn-beariag cirgiona. AltImah the
Krwixv 44 bulistes in muntit. Ill 45M nig.j. its unu-Awl Gw
the gumAl"lity -( Ilk
Invlo ImA 44 jW1144spluls 10 IIIA tvail"I 1% Own raclu'lel I Its-
.1,119to divi. 1-1 the X416114111111 .411 oltall., ..1 it*
IN-NAlsolsh IwIl.pleullf write slut cat Ifir (ko'kayis Nivirs lint
In 111008 14111 ZXI, 41A) &&lit 1401; C,
IF1.1111is MAN', 135,11011 VAI.- ' Vo I fAll 11;tIPI
A lit if [.oil Its, *nil 1411 VS, I ON) x1p 01 1, 1!91 ;411,1
"'Rap. Atjl, ' IN) fill?. 2-sollp XMI JOIN?; X, Jimf .1111.
I UNI. 11-Mrit Ill.- t"Oll."W111.1 On, ~Imilsjg. air al.,
rich in INS. As a reift .1 the itivroigatitut, it I, Its,
%Lumed that deposits of petrulcuut in the Chapary wcomi
1 a I L a 817ALLUAGICAL L1714 afir Eizht tvfrivtK-". W. tt. Ilenn
is
I Z",
. . Q .- I . - - 11W
i-
Tom;- 14
It rq P vr ~71 n I % 4 1
&v 013 It 0$t it It It n it a mo I Ilk
0 00 0 0 0 0 Le
00
o o
Q a e
Are 0
a
it
is

W.I.; -T
Saratov Univ(.I--rs!Lt.-;,", s,-
S-): U-'~,~-61, 10 April r-1, (LetwA3 'Zi,,urnal Inyk"..

no c - P":,
.. .........

VASILSTEV, V.S.
The mineralogical characteristics of authigenic silica In
11 edimentary rock13 of the Mesozoic and Paleogene in the lower
regions of the Volga. Vop.min.osad.obr. 3/4:292-298 156.
(KL'RA 9: 11)
1. Gosuniversitet iment, X.G.Chernyehovskogo, ~aratov.
(Volga Valley--Silica)

. ., I ~ w , ; -17r-~,,~3~ I 1, 11

VASILIYIEV~ V-S.: Z,ffli;[,Ilj, si'l
KI r; P,, ra I c om:,,~,o Q
Sit n t -.*ill MDT? 4 fir, r ir,
kM.~! A ';7-'G)
1. qaratovskiy gf.;sudar-st,,rennyy 'Ail 7C- 1'3 t.- Li1n.
tAv
a kadenakom U.M. S lur, nc v.,!T,..

3/191/63/000/003/W~/
,?q -
BIOI/B106
AUTHORSs Soroking M. F. I Lyalyushko, K. A. , Duciakova. R. A. . Vim ~1" e-!s"*
V,--a". Shuvalova, A. N.
TITLE: Copolymers,,pf1,V,nqatura,ted, glycidorl eaters. ,Copolymerization of
glycidyl methacrylate -with meth.)/1 m,-!tbacrylate in solvents
PERIODICALs Plasticheakiye massy, n6. 3, 1,)63, 3 7
TEXTs The copolymerization of-glycidyl mothacrylate,(GMA) with methyl mstha~-.
crylate (MMA) was conducted in a solution of toluenej dioxane, or cyclo-
hexanone under an atmosphere of nitrogen. wi, tb 0. 1 mol4 benzoyl peroxide as
initiatorg the purpose of this study being to produce polymers containing
epoxy groupsa GMA waa synthesized from epichlorohydr ine and oodium metha
crylate. Optimum reaction was reached at 90 0C and 30% conc.entration Of
components. At higher concentrations, Ahe reaction went too fast and the
mass became too viscous, making it very difficult to take samples. Lower
c.oncentration decelerated the reaction considerably. Copolymerization did
not occur at 60 0C and 30% concentration. At 50% it was too slow but could
be accelerated by increasing the benzoyl, peroxide addition to 1%. The re-
Card 1/2

5/191/63/000/003/002/022
Copolymers of.unsat.uraied-.... BIOI/B186
action was slowest in toluene yielding 77-89%1 in dioxane snd cyclohexanone
it was equally slow yielding 63 - 96~r. Reduced viscosity in dioxane was
3.55 - 3.79, in toluene 2.48 - 2.64. The ratio GMA i MMA was varied between
1 t 4 and 4 : 1. The resulting copolymers were white, solid substance3
soluble in acetone, acetAtes, dioxane, dichloro ethane, and'cyclohexarone.
The polydispersion of the copolymers was determined by turbidimetric titra-
tion. Pure pplyglycidyl' methacrylate had the lowest polydiepersion, whereas
pure polymethyl methacrylate hid the highest. The'values for the copolymere'l
ranged in between, depending on the wolar ratio of*components and on the
amount of initiator added. Fractionate precipitation showed'all fractions
to contain equal nmounts of glycide groupsz approximately 23;o at a ratio
MIA i IZMA ~ 1 1 19 18% at I 1 2, -11%4-at 1 1 4, *290A at ? t 1, and ---3.7?.:*.
-it A : 1. The copolymers were somewhat enriched with GMA and their fractio-
nal composition differed'from that of a mechanical mixture of components.
Th-c copolymerization constants were determined by M. Fineman's and 3. D.
Ross' method (J. Polymer Sc-i.,.5# 259 (1950))t rGUA 0-941 rMMA 0.0-.75-
There are 6 figures ancl 3 tables.
Cara- 2/2
~T;

KLEINE21TOV, A.V.f dotsent,
Elimination of lower porgnathism combined with a nonequalized
bite by means of Kostecka's operation. Stomatologiia 43 no.l:
91-93 Ja-F164 (MIRA 17:4)
1. Kafedra chelyustno-litsevoy khirurgii i stomatologii (na-
challnik - prof. V.K. Mukhin) Voyenno-meditsinskoy ordena
Lenina akademii imeni S.N. Kirova.

VASILIYEV, V.S.
Method of conversion of the mineralogical composition of friable
sedimentary rocks. Uch.zap.SGU 65slO7-114 159. OURA 16:1)
(Rocks., Sedimentary)

PRAZZ I DOOK LXPEA)ITIT.10.4 3OV/5291
Soveshchanlye PC ko=pleksnoy mexharazatait I aVt0=atI_-at3!1 takhrio-
loelche3kikh protscz3ov v ma3hlnoat~.yenli. 24, Moscow. 1956
kvtomatizat3lya ra5hinostroltel'nykh prot5smaov. t. 11T: Obrabotka
rezartlyem I ob*hchlyc voprosy avto=1_!%atsII (Auto:;Atlon or Ra-
ch.lno-Buildin& Pri~ceoaes. v- 3: Xetal Cutting and General Auto-
mation Problem3) Moscow, Izd-vo M SS.51R, 1960. 296 p. (S*riosz
Its; Trudy, t. 3) 4,700 copies printed.
Sponsoring A&ency: Akademiya nauk S&SR. 1=tItut vashinovedonlya.
Kom'solya po tekhnolor;il mazh.1nostro7enlye.
Reap. Ed.* V. 1. DIku5h1n, Academician; Ed. or Publit,hing House:
V. A. Kotov; Tech. Ed.: 1. F. KutImIn.
PURPOSE: This collection of articles is Intended for technical
personnel concerned with the automation of the machine Industry.
COVERAGE: This is Volume In or the trwasactiona of the Second
Conference on the Full Recharilzation and Automation of ranurac-
turlAg Processes In the 14.2chlne Industry. hold September 25-29,
1956. The tra=actlona have been Published in three voluman.
Volume I deals with the hot presswo-Ving of metals. and volume
11, With.the actuation &ro control o: xachlnco. The present
volume deals with the automation of tatal machining and work-
har,denln&, and with general problezz encountered In &UtOau%-
tIon. The transactions on the auto=tion a f rietal-machaninZ
processes were published under the supe rv later% or F. S. Domt.
YanOk and A. M. Karatygirt, and those On the automation of work
hardening processes, under the supervIslon of E. A. Satoll and
X. 0. Yakobson. No personalities are mentioned. There ara no
references.
EM."er, Yu. B. on the operation of t" Tools In Automatic
Ti-oduction Lines 32
Lyu4mirikly D. 0. Experience of the -MB-6 ESpeclal Deelen
Office Vo. 11 In DezigninZ and Masterl-na AutonLitic Produc-
tion-LIne Operat-o." 43
Yeeorov, B. V. Automation of Univer.al Metal-Cutting VachA1106
for Mass Production 53
Neklyudov, 0. 1. Automatic MachlninZ of Parts Used in
Watch=klrZ 62
Automation or Yacht ne-fruildini,~ Proce:aez (Cont.)
Takobnon. M. 0. Autorated Production of Gears and Splin"
Shafta 66
X03hk1n. L. R. Auton-Lation of Manufacturing Proceosca Ws&4
an Kotry TramaCer Machines 82
kWk1n, 0. M. Ketal-Cuttine Tools for Autom.,%ted Productlon 93
Derblaher, A. V. Auto,~attcn of K3ru:'zcturJnZ ProcovcC3 at
the I 01'Z Elst State FcarlrW, Plant) III
Sokolov. Ye, F. Experience In the C-perAtIon of Semlauto-
WAtic Hydraulic Ccpy1n;; Ra,,hines 124
Auto-=~tlc VL-ilanctrz Machines 129
Kurlt3yna, A. D. Now Advanced rracessto for the Mae Prm-
ductlon or 51-,!%nr t~arlnZs 141
Card 4/ 7

V)SIL'YEV, V. S. Doe Tech Sci -- (dies) *Study of the measuring de-Tices of
modern balance machine tools and instruments." Moe, 1959. 20 pp (Min of
Higher Education USSR. Mos Machine Tool and Instrument Inst im L V. Stalin),
160 copies (KL, 48-69, 114)
-21-

25(2) PHASE I BOOK EIPLOITATION SOV/3092
Vasillyev, Vladimir Sergivevich abd Petr Stanislavovich Kutko
Stanki i pribory dlLya dinamickeskoy balansirovki Nachines and Instruments for
Dynamic Balazicing) Moscow, Mobgiz, 1959- 166 p. Errata slip inserted.
5,500 copies printed
Reviewer; B.L. Boguslavskly, Professor; Ed.: Sh. Ya. Livshits, Engineer;
Ed. of Publishing House: N.A. Ivanova; Tech. Ed.: V.D. ElIkind;
Managing Ed. for Literature on Metalworking and Instrument Making (Mashgiz):
R.D. Eeyzellmsin, Ezigineer.
PURPOSE: This book is 1htended for operators of balancing machines and designers.
covxmm The *ok eteals; with the construction, operating principles and sequence
of operations of modern balancing machines and instruments. The ieleign of the
more important elements of balancing equipment is discussed. No personalities
are mentioned. There are 16 referencesp all Soviet.
card 115

Machines and Instruments for Dynamic Balancing POV/3092
TABLE OF CONTEIRTS:
Foreword 3
Ch. I. Unbalance of Rotating Parts 5
1. Static and dynamic unbalance 5
2. Toleranceifor unbalance of machine parts 7
3. Effect of the precision of manufacture and assembly on the
unbalance of machine parts 11
4. Basic characteristic features of modern balancing
machines 12
Equations for'the motion of a rotor on suspended
supports 15
Ch. II. Constructions and Fundmentals of the Design of
Balancing Machines 20
1. Arrangement of balancing machines 20
2. Constructions of supports 21
Determining suspension rigidity in the horizontal
plane 27
C ard 2/5

Machines and Instrosents for Dynamic Balancing SOV/3092
4. Dampers and theire.onstruction 28
5- Bearing chocks 29
6. Direct rotor drive-by belt 32
7. Drive shaft vith elastic couplings 33
8. Shaft with double universal Joints 36
9. Effect of friction In double universal Joints on the
sensitivity of the'wxhine 38
10. Reduced sass of the shaft 42
11. CoupUng having a s.There for the ellipsoid df inertia 43
12. Flexible-shaft drive 46
13. Use of 1UAtened shafts 4T
'14. Headstacks, of bklwding machines 48
Requirements for drives of balancing machines 51
16. Induction-motor drive 52
17. Drive by an induction motor vith a centrifugal
clutch 54
18. Drives for heavy'-schines 58
Ch. III. Measuring Devices of Balancing Machines 59
Card 3/5

Machines and Instruments for Dynamic Balancing
1. Structure of measuring devices
2. Types of transducers.
3- Induction transducers
4. Device for measuring soplitude and phase
5. Resolving devices
6. Filtering circuits
Electric calibrating
z
: Schematic disgrems of standard universal machines
9. Setting up a mdversal machine for balancing
a given piece
10. Measuring devices for automatic balancing machines
SOV/W
Ch. IV. Balancing Machines. Balancing of Machine Parts
1. Balancing machines
2. Provisions made during construction and manufacture
to facilitate the balancing of rotating parts
3- Joining the coupling with the rotor shaft
4. Balancing of the coupling
5- Effects of the heating of bushings on the sensitivity
of the balancing machime
59
60
62
70
88
98
107
110
116
120
128
128
138
141
143
147
Card 4/5

Machines and Instruments for Dynamic Balancing SOV/3092
Ch. V. Instruments for Dynamic Balancing of Parts 149
1. Field of application 149
2. L~dsting methods of balancing 150
3- Proposed methods of balancing 154
4. Types of balancing instruments 156
Bibliography
AVAILABLE: Library of Congress
Card 5/5
165
vKlipp
2-24-60

VASILIM, Vladimir.Sergeye'vich; KUTKO, Petr Stanislavovich;
BOGUSLAVSKIY. B.L.. prof.'~-Iretsenzent; LIVSHITS, Sh.Ya.,
inzh., red.: IVANOVA, N.A.. red.izd-va; RLIKIND, T.D.,
tekhn.red.
(Machines and instraments for dynamic balancing] Stanki i
pribory dlia dinamichaskoi balansirovki. Moskva, Goo.
na-achno-tekhn.izd-vo mashinoatroit.lit-ry, 1959. 166 p.
(MIRA 12:8)
(Balancing of machinery)

V V;
EXCERP T k YEDI'A See 9 Vol 13/6 Surgery June 59
3203. ALVEOLAR Alit SA%Illl,l%,(; 1% itRONCIIIEC'i ATIC IMSEA-SE (Husslan
tl'xt)'- V LK1,11P.H. Kit Ill, 1958, 1 (12-14)
The for t.&Ing samples of alvecdar air ronsiaos of a 4-way
stopcock, a ruh1wr bag of 800-1000ml., 2 rubber bags of 75-100ml. for alveolar
air sampling and a respiration tube with a mouthpiece.' During expiration, after the
largv hag had been filled with the exhaled air, the small bags were filled
with the last portions of the expired air by manipulating the stopcock accord-
ingly. The air samples in the small rubber bags are then analysed in the Douglas-
liald.kne apparatus. Twenty-five patients suffering from varying degrees of
br(inchiectasis and 22 casets after radical operations for these conditions (lobectomy
8 cases, pulmonectomy 14 cases) were studled with the aid of this apparatus.
Analysim of data obtained shows that in advanced caties of bronchiectaxin increased
pulmonary ventilation it; unable to prevvnt alveolar hypuxin which, other factors
contributing, leads to arterial hypoxnetnia. After radical surgery the composition
of alveolar air returns to normal.

USILIYMV, V.S.
Concentration and specialization of local and cooperative induatry.
Sbor. at. CHPI no.3.5:28-34 158. (MIRA 12:3)
(Industrial management)

-VASILIM. V.S.
Development of certain branches of local and cooperative induttries.
Sbor. 9t. GUI no.15:42-47 158. (MIRA 12:3)
(Industrial management)
1.
f
I.II*
I