SCIENTIFIC ABSTRACT VAGRAMYAN, A.T. - VAGRAMYAN, A.T.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001858330009-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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trokhimlia 1 1, ~ --
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1. institut fizichesl::(,~ '.N 3311:11,

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L 2618-66 EVJT(m)/~Pi?(C)/E.WP(i)/gWP(t)/BV-T(b)
ACCESSION NR: AP5011366
JDIWB
UR/0365/65/001/002/0230/0232
620.199.621.351.7
AUTHOR: Baraboshkina. N. K.; V!VjManp A. T.; Titova, V, N.
TITEZ: On the possibility of photometric determination of adhesion of electro-
lytic plating to its bass
SOURCE: Zashchita metallov, v. 1, no. 2, 1965, 230-232
TOPIC TAGS: nickel plating, corrosion protection, electrolytic deposition ad-
hasion Y4, Tf,
ABSTRACT: The feasibility of continuous photometric characterization of the ad-
hesion of nickel-plating to a metal base during the electroplating process was
examined. After focusing a light beam an an electrode surfaco subjected to elec-
trolytic nickel-platl,,ig the intensity of the reflected light was measured photo-
metrically. The nickel plating reflectivity and polarization were measured in an
electrolyte containing# 300 g1l,Of Ni8O4*7H2O, 60 g/1 Of NIC12#6HZO, and 38 g/1
, and at 250C. The nickel,
Of H3BO3; at pH = 3, with a current density of 40 mA/cm2
platings ware deposited an passLvated (immersed for 20 sec in a chromic acid--
250 g/1) or activated (immereed in 5% H2SO4) nickel and steel electrodes. The
,-Card 1/3

L 2618-66
ACCESSION NR: APS011366
change in reflectivity and polarization during the process of nickel-plating of
steel samples is shown in fig. 1 of the Enclosure. The electrode surface activity
and the strength of adhesion of nickel plating is well characterized in terms of
reflectivity decline after the initial current switch-on. The strength of the
plating-base adhesion is determined by the photometric method more accurately than
by either mechanical or electrochemical methods. It is found that passivation
with chromic acid impairs the adhesion strength. Orig. art. has: 3 figures.
ASSOCIATION: Akademiya nauk SSSR, Institut fizicheskoy khimii qad of
Sciences SSSR, Institute of P~Xsical Chemistry)
SUBMITTED: 20Aug64 ENCL: 01 SUB CODE: MM
NO REr SOV: 003 OTHER: 001
Card 2/3

L 2618-66
ACCESSION NR: APS011366
ENCLOSURE: 01
rig. 1. a--passivated sample;
3 b--activated sample; 1--reflec-
tivit ; 2--polarization$AB and
y
A f;)
A1181--prior to current switch-

I C I') ' --during t
on-, BCD and B he

r 'A E electrolysis prfcess, DE and
DIE'--current-ovf-period; EF

r and E71--after the second on-
S -3 current period.

Card 37S

A('CFS-,S1f)N ';-R: kp-,,ioaAn- 1; rv,4" ~,5 onj no3 o.12! 0325
A Mi(IR: Tovhava, 1'. 1. A. 1
TITLE: Passivation,of the sur-face o1 _hqw,! FLad solid gailium in th.- course of
electrodepositi n(
SOURCE: Elektrekhimiya, v. 1, no. :,, I'JG7, 321-325
TnT11(- TA(-,,S-. Z-11jium m. -illiurr. pasl;tvatifyn, efectn-whernktrv.
7-,Xlp
Card 1, 2

L 413,,3-65
ACCESSION NR: AP5009303
changeq on-ly with the thermal frotinn of thi- particles, whereas on the surface of liquid
gallium the foreign particles are weakly a lsorb-(A because of the greater motAlity u'. the
liquid electrode. In all probabflfty, these 7haracterfatfcg of Hquid and golid gallium are
responsibi , for thp differpnc~, in thi rr-tar(lation in the (-ourg.- of r(,-
ductioa of gallium ions. Orig. art. has: figures.
A.';SOCIATION: Institut fi7AchPrkc%-,- khimi~ Ak-idernii nnuk SR9R (Institute of Phygical
A
~ ~ 1, 1 J 7,
.;U'BMITTF'): 20Apr64 FNCL: '.'~'XF- 1(-, MMI
NO REF SOV: 001 OTHER: 003
x-
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ACCESS .19.11 NP AP501774' 5/t 5 1
2 1 157.
AUTHOR: -Nikit ina - A. A. S oin i u i ki, ya Z. irry i n .A
TITLE Combined qleqtroLvlk Aqp,-qi~ion of Hienium and copper
3 ('V'~ :F 7 a
a Me t.1 V,
1/ 3

.AC,,&SSCON Rt AP5017741
71 Pb. T$,, f- r - f r - .
i rr t r c rl .-M 1 ..,3 i
r r-::
1 ixi -

r-* 6 3 ~, 82 -65)
A"CESSIOV NR: AP 5~~' 7 74 1
facilitated reduction rf metal inns b;: f ',rent iated from
'-heir fnn,,; crymvn-er4 v"~- r. r n
e~; ~.v
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AS 0(-- T AT T C-N Gt,,;,jd,1 r iv.--y .. ....
Cheakuy pr(=TUh!enncsci (State Scientific Reaearch
Rare Mptnla-
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SOLOVIYEVA, Z.A.; VAGRA14YAN, A.T.
Cathodic passivation in chromate electrolytes with the additions
of chloride ions. Elektrokhimiia I no.4:413-417 Ap 165.
(14IRA 18:6)
1. Inatitut fizicheskoy khimii AN SSSR.

i a i
Tr)PIC TAGS: gallium, electr-ide
U /P J /ffc) :4 f-) 4 R L;
APS7'!'ArT 7-he -,~Afinn-arv nntential --f a ncnvolar-ze~ do(q -,i-t alwav-
thus p, r, 3 7-e -i iL-
,Card 1/3

L
ACCE
T-t-or..t 41 wi,f.r, rhe me tal
Grnmis~crmi, Aca~iuury Oll
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KUPHYAVTSEY9 V.E.1 IIALAKIN, Yu.11.1 VAGRAMYAN, A.T.
flydrogen absorption by ntee-1 dur.ng cathodic ixlarizatirn In acid
solutionas Zashch, met, I U0,5t471-481 8-0 165. (KrRA 18:9)
1, lustitut fizitbeekoy khlmii AN SSSR,

~io I,i',,V 17,
hlfect ot, chlocir'a i--~nci on polar-iza'- -n
no. 5, 5151-:5-5c I.,v- 10,
i , f list i ~Vlt "~I ,~ I chr! hil! wd J AN

VAGRAMYANp A.T.; ZHAMAGORTSYAN, M.A.; UVAROV, L.A.
~~T
Effect of temperature on the kinetics of cobalt ion reduction. Xlektro-
khimiia 1 no.6t633-639 Je 165. (MIRA 18:7)
1. Inatitut, fizicheskoy khimii AN SSSR.

---
NIKITINA, A.A.; SCLOVIYEVA, Z.A.; SOWNSKAYA, ZA; VAGRAMYAN, A.T.
Meohanism of rhenium electrodeposition. Elaktrokhiaiia 1 no.6t
748-751 Js 065. (MRA 180)
1. Inatitut fisicheakoy khimii AN SSSR,

TITOVA, V.N.; VAGRAMYAN, A.T.
Reflecting power and structure of electrolytic copper deposita.
Blektrokh3miia, 1 no.BtIOII-1015 Ag 165. (MIRA 1919)
1, Irotitut fizicheakoy lchimii AN SSSR,

L 7968-66 EW(m)/WP(i)/EWP(t)/WF1(b) IJP(c) JD
_----A-CCNR: AP5025079 SOURCE CODE: UR/0364/651001/ 010/1222/1217
AUTHOR: Vagramyar., A. T.; Titova. V. N
72
ORG: Institute of Physical Chemistry, AN SSSR (Institut fizicheskoy khimli,
AN SSSR) Vy'ri
TITLE: Study of conditions for obtaining bright copper deposits by anode treat-
WF,
ment
SOURCE: Elektrokhimiya, v. 1, no. 10, 1965, 1212-1217
TOPIC TAGS: electroplating, Sq2pper pulse generator, electrolytic cell, light
reflection
ABSTRACT: The article describes an attempt to produce bright copper deposits
by anode treatment with a current pulse in a pyrophosphoric acid electrolyte
used for electroplating. The reflecting power of the copper deposit was studied
in the electrolysis process with a photometer developed in the Institute of Physical
Chemistry of the AN SSSR. The photocurrent characterizing the magnitude of the
reflecting power, with the aid of a direct current amplifier, wad recorded on a
POB- 14 loop os iUograRh.\O Simultaneously, in the electrolytic process, measure-
ments were made of the electrode potential, measured with reference to a satur-
Card 112 UDC: 621. 357. 7

L ?968-&
ACC NR: AP5025079
ated calomel electrode. A pulse device was used to produce the current pulse;
this made it possible to vary the duration of the impulse over a wide time range.
The electroplating and the anode treatment of the coating were carried out in an
electrolyte of the following composition: CuSO 90 grams/liter; K4P207, 350
41
grams/liter; ammonium nitrate, 20 grams/liter; pH, 8. 1; temperature, 60 C. A
series of experiments was carried out at different current densities to determine
the conditions for anode treatment at which a noticeable increase in the reflecting
power starts. The observed increase in the reflecting power after treatment with
a current pulse beyond the critical point is in all probability connected Nvith the
fact that, at large current densities, a supersaturation of the solution occurs. In
anode dissolving of the metal there should also be observed a smoothing of the
surface of the electrode, i.f the removal of the metal takes place uniformly over
the whole surface of the electrode. It is evident that during the dissolving of
metals, a projection will be completely dissolved if the thickness of the dissolving
layer is commensurate with the thickness of the projections. Therefore, in this
case also, we can expect a smoothing effect. It is possible that both cases occur
during the treatment of copper with a current pulse. Orig. art. has: 7 figures
SUB CODE: GC, MM/ SUBM DATE: O8Feb65/ ORIG REF: 004/ OTH REF: 004
Card2/2-

VAGRAWIAN, A.T.; YASTREBOVAJI E.K.
Copper polarization in pyrophosphate electroly-tes. Zh..:r. flz.
(t"- F~A Ici: I I
khim. 39 no.4:865--869 Ap 165. - 1 11
1. Irstitut fizicheskoy khimil. AN SSSR. Submitted July 2.3, 1963.

LE'ZFAVA, T.I.; VAGRAIMYAN, Aj,
Passivation. of the Erarface of 'Liquid and sclid gallium. ~'n -.he
process of electrodeposition. Elektrckbimiia I no.3:321-325
mr 165. (MIRA 18:12)
1. Institut fizicheskoy khimii AU SSSR.

'T Tj2t-~ 1)
ZZ J_~_f,- I j
015291 ON) SOURCE CODE1 UR/0365/66/002/003/0349/0352
AUTHORI Nikitinap A. A.; Sominakaya, Z. M.; VagrnZan, A. T.
33
ORGs none
TITLE: Mechanism of electrodeposition e f rhentum-
I
SOURCE: Zoahchita metallov, v. 2, no. 3, 19669 349-352
TOPIC TAGS,* rhentums electrodeposition, passivation
ABSTRACTt The study was devoted to a verification of a proposed mechanism of rhentum
electrodeposition, and to the determination of the passivation rate of the electrode
'Surface. Electrolytes of the following composidons (in g/1) were employed$
(1) ammonium perrhenate 50, sulfuric acid 25; (2) ammonium perrhenate 50j sulfuric
acid 25, ammonium sulfate 40. The electrolysis was conducted at a current density of
1 A/cm2 and 700C for.15 min. In the electrodeposition of rhenium from solution (1)
with an Intermittent current, the minimum on the curve reprosenting the current effi-
ciency of the metal vs. the pause between the current pulsea was found to correspond
to a pause of 10-2 see. As the pause decreases, the current efficiency of the metal
Increases, Indicating that the renewed surface of the cathode does not manage to
become fully passivated. The curve shows that a pause of the order of 1o-3 sec Is
required for the electrode surface to regain Its original state. Thus, the experi-
mental results bear out the "activation" mechanism of rhenium electrodeposition and
I Card

ACC NR, AP600291
show that the current efficiency of the metal depends of the state of the electrode
surf&cep which In turn depends on the admixtures (such as ammonium sulfat,st which is
an activator of the electrode surface) present In the electrolyte. The experiment
shown that In many cases, electrolysis with a pulsating current makes It possible to
determine the passivation rate of an electrode surfoc*. Orig. art. h&&$ 3 figures.
SUB CODEt 11,07/SUEN DAM 210ct65/ ORIG RL71 003

JD/1fa/J'G
L 27381-66 EWT(m)/EWP(t) IJP(c)
ACC NR AP 6015013 SOURCE CODE: UR/0364/66/002/005/0551/0556
AUTHOR: Vagramyan, A. T. (Moscow); Ginberg. A. M. (Moscow); PedotQva. 11, Ya.
(Moscow)I-GinVeig, T. A.'(Hoscow)
I ORG: none
TITLE: Effect of ultrasound on the electrodepositlan of alloys
SOURCE: Elektrokhimiya, v. 2, no. 5, 1966, 551-5561%
TOPIC TAGS:' electrodeposition, alloy electrodeposition, nickel alloy, iron
containing alloy, molybdenum containing allcy, ultrasound effect
ABSTRACT:' The effect of ultrasound on the electrodeposition of Ni-Fe-Mo alloys from
a sulfate electrolyte containing 2.2-18.0 g/1 sodium molybdate has been investigated
The alloys deposited without ultrasound contained less than 1% molybdenum, regardless
of molybdate concentkation. At concentrations of molybdate higher than 12 g/1, the
deposits were dark and cracked owing to high internal stresses. Ultrasound with
an intensity of 0.9-1.04 W/cm2 and a frequency of 22-26 kc had a beneficial effect
on the electrodeposition process and quality of alloys. At a molybdate concentra-
tion of 8-10 g/1, the Mo content In tie'al]W was 4-5%, the internal stresses in
deposit decreased, and the deposits were dense and lustrous. The optimum pH of
the electrolyte was found to be 2.3-2.7 and the optimum current density, 40-60 a/a~
Card 1/2 UDC: 543.251:546.3-19

- - I

OSMAN-ZADE P Sh.D.; VAGRAIWANI A.T.
EquillbrIT-m potential of a electrcrde ft.
solutiona. Elektrokbimila 2 no.11:85-87 Ja 166.
(MIRA 19:j,)
1. Institut fizicheskoy khimii AN SSSR, Moskva. Submitted Februar~
25, 1965.

L 08110-b7 EWP(e )I hWTtM)j Lwe~V )I k,,,vP k Z)/ 1!,'ri Id 1-~ I; ILj~ "r V I'l
ACC NRi
AP6033076 SOURCS' CODE': Uiz/0032/66/0.12/oio/12:-.j/1226,
I
:AU-MOR: VlgraVan, A. T.; Baraboshkinap N. K.; Batrukova, M. G.; Titova, V. N.
IORG: Institute of Fhysical Chemistry AN SSSR (Institut fizichaskoy khimii Al,,' SSSR)
TITLE; Fhotometric method for determining the roflectivity and the adhesion of a
Idopositod metal to the backing
Zavodskaya laboratoriya, v- 32, no. 10, 1966, 1223-1226
TOPIC TAGS: 'electrolytic doppsition light reflection coefficient, adhesive bonding
ABSTRACT: The article describes a method and apparatus for determining the adhesion of
an electrolytic coating to the base directly during the electrolysis process, and so
for evaluation of the reflectivity of the coating at the t e of its dojSq
im - _~Aion. -1 - -A
schematic diagram of the apparatus is shown in Fig. 1. 1ho eloctrolytic-cel-l.',pcnsists
of a removable cathode i and an anode 2, which are fixed to -o body of the instrument.,
The anode is so located with respect to the cathode that unifoim distribution of the
flow over the whole surface of the electrode is assured. 7he electrolyte under
investication is placed in a glass vessel 3, which is placed in a themostattod Jacket
4, connected to an ultrathermostat. The photooloctric unit consists of a light so-arco
6, a system of lenses, and the photoelement 7. The reflectivity and the polarization
of a nickel deposit woro studied in a solution of NiSO407HZO-300 grams/litor;
Card 1 /3 UDC.- 6?IJAI-.-139, --535.31

AP6033076
Fig. 1.
Schematic diagram of photoelectric instrumont
NiC12-6H20--60 grams/liter-t'H3BO3--38 grams/liter; pH = 4; Dk = 40 ma/cm2; t = 250C.
7he nickel was deposited on nickel and steel samples with different preliminary
treatments of the surface of the metal. The experimental results are shown in graphic
Card

- - ~ I
I ACC NRi
AP6033076
'formi. 'IhoImethod is said to be applicable for the determination of adhesion at ver-.(
high current densities, OriG. arts hast 4 figures.
.1
.70 OQ
SUB CODE? i' WSUM DATE I none
Card 3/-j 'e-

JA

L 5220-66- DIT(m)/EWP(w)/E7,4A(d)/Ttv-A(t)pdp(z)/-zlIP(b)/EWA,(c) MN/JD
ACCESSION NR: AP5022654 UR/0365/65/001/005/0477/0481
620.193.41 Z
669.788 ~:)?~
AU'rHOR: Kudryavtsev, V. N.; Baakin, Yu. P._; Vagramyan, As T.
Y1, 55
TITLE:__HYdrtqgen absoMtion in steels dmring cathodic polarization in acid solu-
tions. Is Effect of current densityliw
SOURCE: Zashchita metallov, v. 1, no. 5, 1965, 477-481
TOPIC TAGS- h drogenation, electrolysis, steel, low carbon steel., h
'-bri tlement 11, 6
qq,5,,
ABSTRACT: Cathodic polarization experiments were performed in 0.1 N H2SO4 sOlu-
tions, both with and without AS20 .ch was used as a stimulant./~Armco iron and
3 w I
3OKhGSA steel were used; 3OKhGSA s 1 had the following composition: C (0: %)9
Si (A), Mn (0.9%), P (0.03t), S ( .025%), Cr (0.9%), Ni (0.2%), and Cu (0.2%)..
The quantity of absorbed hydrogen was determined by vacuum extraction at 4000C,
while mechanical properties were measured on samples 3 mm diameter and 20 mm long,
at a strain rate of 8 mm/min. The criterion for determining the amount of hydrogen
embrittlement was the difference A* between the reduction In area for charged and
Card 1/3

~L 5220-66
ACCESSION NR: AP5022654
.uncharged samples. Results are given in terms of A*% as a function of i k (mif/CM2
the polarization current density; and hydrogen concentration as a function Of ik-
:The influence of cathodic polarization of steel on the loss in ductility is severe;
.the curves for A* and absorbed hydrogen content both.pass through a maximum at about
.25 ma/cm2. These same curves were given for cathodic polarization in 0,1 N H2SO4
.solution with 0.01 g/L addition of AS203. A difference is observed; with increase
in ik' the brittleness of the samples and the amount of absorbed hydrogen continu-
,ally increase. An explanation is offered based on reactions at the electrodq:
H + e = H (1) H H (3)
ads ads abs
Hads + Hids H2 (2a)
H + H + H2 (2b)
ads
Thus the concentration CHI ads depends on the speed of disintegration of hydrogen
ions, and on the rate of removal of atoms of hydrogen from the surface of the elec-
trode. The increase in the current density depends on the amount of absorbed hydro-
'gen on the surface of the electrodes, as well as on the speed of its removal; this
removal depends on the recombination mechanism (reaction 2a)-, whose speed is pro-
Card 2/3

L 522o-66
ACCESSION NR: AP5022654
.portional to the concentration of absorbed hydrogen squared--i = Kl([Hlz )2. The
ads
data are explained using the above considerations, the maxima being as sociated with
a limiting value of hydrogen concentration at the electrode due to the recombina-
tion mechanism. For the As203 additions, there is no maximum because the removal
of the absorbed hydrogen lessened by retarded recombination. Orig. art. has: 4
figures, 1 table.
ASSOCIATION: Akademiya nauk SSSR Institut fizicheskoy khimli (Academv of Sciences
,SSSR, Institute of Physical Chemistry)
SUBMITTED: 25May64 ENCI': 00 SUB CODEt GCLMU_
NO REF SOV: 014 OTHER#t 004
Card 3/3

Vagramian, 11. T. and Vagraunan, A. T., The influence of surface active substances on the
rate of growth-of the electrolytic mono-crystal of silver. P. 78.
The dependence of the degree of polarizatLon on the current density are studie'd w4i-__,
and without surface substances d~=ing. the growth of a mono-cr-jstal of sil-,cr. -LIo d if ferent
methods are applied to obtain the true current density. It Is proven that when the true
current, density is taken into account then the degree of polarization is practically the
sane in both cases.
Institute of Physical Chemistr-y
Aca, of Sci, USSR
Moscow
April 27, 1948
SO: Journal of Pbysical Chemistr-f (USSR) 23, uo. 1 (1949)

V, zkr~ ~ ~ A f.~V ~', N-,T , . rif, , IAT, - -
-_._-_-, - - _a_ - - ---
Dissertation: "r.'echanis-Tr. of Electrical Reduction in t~ie Ni tro-Fe n~.ene -Anil i ne
Series and the Nature oil Hydrogenating Arent."
23/6/50
Moscow Order of Lenin Che-ical-Technoloa,ical In6t imeni D. I. t'ettdeleyev
IC Vecheryaya Moskva
Sum 71

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1--fir (H). and 1111) in ale. '21 N lfw%04
-4)lns, on a Pt cuthowle vmq ~llldjftl at ~A -t 0,1' Its cw.f" to
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I,kel I. at s Pt rlectr-lv %III hirl H.U'Urt

S/080/60/033/'012/013/024
D209/D305
AUTHORS: Vagramyanp N.T., and Koboanidzep G.I.
TITLE0 Distribution of me-l'al on the surface of a cathode
during electrodeposition of nickel
PERIODICAL: Zhurnal prikladnoy khimii, v. 33, no. 12, 1960t
2731 - 2734
TEXT: In order to compare the throwing power of 7 electroplating
solutions (numbered 1, 2, 3 etc. ) used in practice, the distribu-
tion of the nickel deposit obtained from them was examined. Elec-
trolysis was carried out In a cylindrical electroplating tank with
cylindrical anode made from nickel sheet and cylindrical cathode
consisting of Lo metal rings, numbered 1, 29 3, etc., fitted tight-
ly and fixed on one bar. This cathode was placed in tne center of
the tank at an equal distance from the anode and from the bottom
and the surface of the electrolyte. ".3arts of the cathode above
ring No. I and below ring No. 10 were sealed with plexiglassp a
Card 1,11,1

S,/080/60/033/012/013/024
Distribution of metal ... D209/D305
polymethacrylic resin. The distribution of the metal was examined
by determin e increase in weight of each ring after electroly-
SiB. The results are given in which the ratios
Igns increase in weight of given ring ~where 'go?
Ig01 means increase in weight
total increase in weight of cathode)
number of rings
are plotted against the corresponding number of rings. The increase
in weight of metal obtained from each of the 7 nickel electrolytes
is much greater at both ends (ring No. 1 and ring No. 10) than in
the central part (ring Ho. 5 and ring No . 6) of the cylindrical ca-
thode as is expected for electrolytes with poor throwing power. The
increase in weight of the metal on the bottom ring No. 10 obtained
from all the nickel ftlutions is greater than the increase in-,F~
weight of the top ring No. 1. This can be explained by the presence
of convection currents arising in electrolytes from the bottom up-
Card 21b c/,

S/080/60/033/012/013/024
Distribution of metal D209/D305
wards. The 7 nickel electrolytes used in practice could be set in
the following sequency according to the uniformity of nickel de-
posit: electrolyte No. 2, 6, 1, 3, 4, 5, 7. Although for different
nickel solutions many factors such as composition, concentration,
pH, temperature and current density vary considerably, the distri-
bution of metal is nearly the same. These factors have little in-
fluence on the thming power of solution and cannot be changed
without impairing the quality of deposit. The throwing power of
nickel solutions can be improved only by changing the 'geometric
-factors': dimensions form and relative positions of electrodea tak-
ing into account the convection currents in electrolytes as they
influence the throwing power. The table gives the composition of
the electrolytes and the operating conditions. There are 1 table,
2 figures and 11 references: 8 Soviet-bloc and 3 non-Soviet-bloc.
The references to the English-language publications read as follows:
R. Harr, Trans. Blectroch. Soo, 34, 698, 1938; G.E. Gardam, Trans.
Faraday Soc. 68, 4259 1936.
Card 310

S/080/60/033/012/013/024
Distribution of metal ... D209/D305
ASSOCIATION: Institut fizicheskoy khimii AN SSSR; sellskohkhozyays-
tve institut Armyansk3y SSR (Institute of Physical
Chemistry AS USSR; Agricultural Institute Armenian
SSR)
SUBMITTED: April 18, 1960
Table. Composition of electrolytes (in g/liter) and operating
conditions.
Legend: 1 - Components and operating conditions; 2 - electrolytes;
3 - 4ickel, sulphate MiSO 7H20; 4 sodium sulphate Na2SO4 -
1 OH20; 5 - magnesium sutphoate MgS04 7H20; 6 - nickel chloride
NiC12 - 6H20; 7 - potassium chloride; 8 - sodium chloride; 9 bo-
ric acid; 10 - ammonium sulphate; 11 - cobalt sulphate COS04 7H20
12 - potassium fluoride; 13 - sodium formate; 14 - 2.6 or 2.7-naph-
thalenedisulphonic acid- 15 - formaldehyde 40 %~ 16 - acidity (pH);
17 - temperature (in OC~; 18 - current density in amp/dm2); 19
current efficiency of metal (in
Card 4/p~k

VAGRAKWI, II.T.
-aw..".1 ..... obmft-
Metal distribution oti t--,~ dut-Ing d-ipositlon by
the reversing c-ta-rent. AN Ann. 11ILTI na-l;ki 16 no.6.-.
521-52 5 ' 63 ( m -, FA I?xP,)
1. Armytinskly ln~:tltut, kafadra nlx-ih,-h,!,y
khbali,

P.
MR/Chamistry - Electrodeposition of Oct 51
Metals
"Porosity of Electrol)tically Deposited Nickel,"
A. A. Sutyagida, P. P. Vagramyan
"Zhur Prik Khim" Vol XXIV, No 9, pp 945-950
Found that number of pores of electrodeposited Ni
decre"es with increasing thickness of coating to
certiLin point, then remains nearly const; that
curve for number of pores against cd passes through
min; and that some surface-active admixts increase,
some decrease number of pores in comparison to
electrolyte without admixts -
193T25

V.*,r,wrn~sp Zq It*
IL IA
!9--414 1,%4 . %
'hur. - (Mfl(A
1'7~8
It t I tu t. f i-m.-Z R .

VAGSEI1YE-I, ISTVV4
'777777':~~
A fuves vetesforvo szerke7etenek vizsgalata, fiv mm rs
yele rel annak magyaro zari
alkalmazasara. Fudapest, Yezokazdas,-i Kiado (1955) 67 P. (Pudapest, Magyar
Agrartudomanyi Egyetem. Avrako2kazdasgi Kar. ApTarko2jazdasat-I Kar kiadvanyai
1955. evi, I. sz.) (Analysis of the rotition of grassy crops with reference
to Its arplications in Hunvary. German and %-ssi-an summarips. illus., maps.,
bibl., tables.)
SO: Mohthly Index of East European Accessions (EEAI) M. Vol. 7, no.4,
April 1958

VAG3ELLYEI, I.
Investigation of the stricture of grass crop rot.-Ition with rejr--,r:! to its
in Hungary; a fragment of a candidate's thesis. P.
(MGYAFJ-U-:7,OGADA5AG. Vol. 9, no. 4, 1956. llun.gavj)
SO: Monthly List of East European Accessions (E7AL) LC, Vol. 6, no. 6. June 1957. Uncl.

VA('~iIIAL' D.S.
A
Practire in using gravity surveylng for exrc-aing trougla in
prospecting for sillcate-nickel delysits in the Centrai Ura-la.
Trudy Tnst.geoflz.UFt.N SSSR no.3:31-34 165. (MA 18:8)

VAGSMILI, I., inzh;; LAGUTIN. K., arkhitektor
Pay more attention to the construction of underground structures
in cities. Zhil.-kom. khoz. 10 Ao.8:10-11 160. (MIRA 13:9)
(Sewerage) (Water-supply engineering)

KAMATCHUK, K-I-, dots,; KAWDRYKDTA, L.D., biologLVIGSHULI, I.I.
Case of food poisoning of staphylococcal etiolog7. Gig. i san. 24
no.2:82-8~ 7 1~59- (KIFU :2:3)
1. Is kafedry mikrobiologii P~ratlgorakogo farmatsecticheakogo inati-
tuta i FYatlgorskoy sanitarno-spidemiologicheakoy stanteii.
(FOOD POISONING, stiol. & pathogen.
Hicrococcus pyogenes (Run))
(MICROCOCCAL 1URCTIONS, case reports
food pois. (Rue))

VAGU, P.. candidate in atiinte economics
V----------- --
Correlation between the inm-eased labor productivity and the autowtion
of production. Probleme soon 14 no.10:31+-47 '61.

VA00 P., candidat in atiinto economice
Aspects of the plundering of Rumania's bourgeoio-
landlord oil resources by the international monopolien.
Probleme econ 15 no.9:11+3-149 S 162.

VAGU, F., candidat in atiInte economice
Sit4fton of oil industry workers in Rumania during the 1929-1933 petiod.
Probleme econ 16 no.205-64 F 163.

VAGUJFALVI, Dezso; TYIHAK, Erno
Daily change in the prochamazuIene content of camomile (Hat-
ricaria chamomilla L.) Botan kozl 49 no.1/2:64-70 161.
1. OyogynoveAykutato Intezetq Budapest XII.q Daniel ut 40,

VAGUJFALVI,, Desso (Budapost,,XII.,Daniel ut 40)
The effect of gibberellic acid - ng on the amount of nutrients
in the plant, Botan kosl 49 1 221-232 162.

VAGUJFALVI, Dezoo
Mineral nutrition of Datura innoxia. Pt.3, Botan koal
50 no.1:1,2-49 My 163.
1, Gyogynoveny Kutato Intezet., Budapestv XII., Daniel ut 40j
Magyar Biologiai Tarsasag, Botanikaj Szakoaztalya valaBztmanyi
tit)cara; *Botanikai Kozlemenyek" szorkeazto bizottsagi tagjvL.

VAGUJFALVI, Dezoo; TYMAK, --*:-ro
lizsential oil componEr-te as universal r.1--nt suh--t-mces. lio-rw.
kozl 51 no.3.t4l-49 ~64
1. Medicinal Flant Reseim:h bstitute, Budapest, M., %rdel
ut. 40.

U S S R
=4,vgy=~ Mattes to tits #Ad"'
~..Guorgnt=an d t2
J. VOSUIAMS (~Cmti
;cWture Expd. Sta. Pm, Latvia). L4f#&i-PSJtZsx&ja
Akcd. Vistis 1954, No. 12 (Whole No. fig), 55-oRusslan
summary 6&-O).-In growing grapes In the open, as well as
In gmenhouses, it was found that yield and sugar content In-
creased, while the acid conteirt decreased consistently vith
Increase In amt. of heat avallable during the vegetation.i
Heat was measured as sum of temp. over &tys wbzu temp. I
exceeded +10% and varied in tests between 18Wand 4100'.~
JmrAwtance of m1cro-climate in the eiract location of the
plants is stressed. Andrew Drayukks

-VAULIN, G., ekonomist (LaningriA)
This method will simplify measurivg the sarface of patterns.
From.koop. 14 no.8:11 Ag '60. (MIU 13:8)
(Cloting industry--Technological innovationo)

YUKAL. R., MUDr.; BRONEK, J.. MUDr.; VAGUNDA, S.. Mr.
Case of giant neurinnna. Cask. neur. 19 no.4:268-270 Nov 56.
1. Z neurolog. odd., chir. add. a prosektury KUNZ Gottwaldov
Prednostove: Prim. Dr. 1. Muller, prim. Dr. V. Loutocky, prim.
B. Vaneeek.
(NIIURILIDMXA. came reports,
sciatic nerve, giant case (Cs))
(MV11S. SCIATIC. neoplasus.
.. neurilemmoma, giant case (Cs))

VAGUNDA, Simon; REZAC, Milos; WEBER, Jaromir
Gastric cancer in a 12-year-old boy. Cesk.pediat.15 no.10:913-916
w6o.
1. Patologicko-anatomicke oddeleni, prednosta prim.dr. S.Vagunda
Centralni rtg oddeleni, prednosta prim.dr. E. Sanda. Chirargicke
oddeleni, rednosta prim.dr. Fr. Kudlac.
MOKAGH NEOPLASMS in inf & child)

AUTHORs
68021
SOV/155-58-6-22/36
Vagurtova, Y.11.
TITLE: A %--Tr ~o ~d-Surfaces Where the Curvature Lines of One of
Them Change to Asymji5it-ic tines of the Other
PERIODICAL: Nauchnyye doklady vyashey shkoly. Fiziko-inatematioheakiye naukiq
1958,Nr 6,pp 139-141 (USSR)
ABSTRACT3 The author shows that,83=g'vith the minimal surfaces which
are developed upon their conjugate surfaces, there are pairs
of surfaces with the property of being developable upon another,
whereby the lines of curvature of the one surface change over
into the asymptotic lines of the other surface. The solution
contains four arbitrary constants.
The author thanks Professor S. Finikoy for the guidance of the
paper. - There are 2 Soviet references.
A330CIATIONi Moskovskiy pedagogicheskiy institut imeni V.P. Potemkina
(Moscow Pedagogical Institute imeni V.P. Potemkin)
SUBMITTEDs October 20, 1958 V
Card 1/1

5(2) SOV/78-;4-10'-7/40
'AUTHORS; Breusov,,O.-N.,-Vagurtova, N. M., Novoselova, A. V.,
Sima*ov, Yu. P.
TITLE: On the Thermal Decomposition of Ammonium-fluoro-beryllate
(NE4)2BeY4
PERIODICAL: Zhurnai neorgani6heskay khimiii 1959-1 Vol 4; Nr 10,
pp 2213-2219 (USSR)
ABSTRACT: Since the reaction under review represents the principal method
for the production of 'crystalline beryllium fluoride, the
course of this process was investigated. The authors mention
in brief the publications available so far on this problem and
especially point out the paper by A. V. Novoselova and M.-Ya.
Averk9va (Ref 14) who first-obtained the ammonium-meta-fluoro-
beryllate NH BeF in addition to'the ammonium-ortho-fluoro-
- 4 . 3
beryllate (NE 4)2 BeF 4* The thermal decomposition of the ortho-
compound in the inert gas current gives only low yields, where-
fore this reaction'was-investigated under decreased pressure.
Figure 1 shows the decomposition curve at continuous increase
Card 1/2 in temperature where no breaks can be seen. On gradual heating

BOV/78-4-10-7/40
on the Thermal Decomposition of Ammonium-fluoro-bei-y'Llate (sH ) BeF
4 2 4
up'to 165, 180, 205, 220 and 2400 (Pigs 2 and 3) it becomes
evident that the decomposition takou place in three stages:
(NH 4)2 BeF4 &NH4BeF 3 __* NH4 B ej 2F5 -4- Be72 . Table 1 presents the
analysis of (NE 4)2BeF 4' table 2 that of NH4B62F5 . The lattice
constants of NH4Be 2F5were calculated on the basis of a radio-
gram obtained by means of the RKU-86 chamber and found to
belong to the hexagonal syngony (Table 3)- In the same way the
corresponding lattice constants were calculated from the radio-
grams of KBe F (Table 4) and a-CsBe F (Table 5). The radio-
2 5 2 .5
grams are shown in figure 4. Tabie 6 presents the data for the
compounds of the MaIBe 2F5 type, table 7 compares the lattice
co-,-.istants of NH'Be FKBe F and a-CaBe F There are
4 2 51 2 5 2 5*
4 figures, 7 tables, and 12 references, 8 of which are Soviet.
SUBMITTED: Julie 19, 1958
Card 2/2

KOCKITKOV, N.K.; SOKOIOT, S.D.; Vj~qURTOYA, N.M.; NIFANTIY]bN, I.Te.
Organomagnesium compounds of the Isomazole series. Doid.
AN SSSJI 133 no.3t598-601 Jl 060. (MIRA 1.3t7)
1. Kookovekly gosudarstyenrWy universitat imeni N.V.
Losionomova. Predstayleno akad. A.N.Seemayanovyu.
(Niagnesium organic compounds)
(Isoxasole)
-01

KOCMTKOV, N.K.; SOKOLOV, S.D.; VAGURTOVA N.M.
Isamwle seriea. Part 12: Iodination and bromination of
isoxazoles. Zhur.ob.khim. 31 no.7:2326-2333 Jl 161. (MIRA 14:7)
1. Moskovskiy gosudarstve-n-nvv universitet imen-i M.V. Loinonosova.
(Isoxazole5,

KOCHETKOV, N.K.; SOKOLOV, S.D.; XAGURTOVA, N.M.-
Radical halogenation of isoxazoles. Zhur. ob. khim. 32 n0-1:325-
326 Ja 162. (MM 15:2)
1. Moskovskiy gosudarstvennyy universitet imeni M.V.Lomonoaova.
(Isoxazole) (Halogenation)
(Radicials (Chemistry))

VAr,'VOL'-YT, J -
On the fauna of the springs of Hungary. I. Y-ts. Dunazug. Tn Fn7lish. p-1,77-
(Magyar Nemzeti Mu7eum Termezettudomanyi Muzeum -.,'Vkcnyve, Vol. 7, 1956,
Fudapest, Hungary)
SO: "flonthly List of East European Accessions MAL) LO. Vol. (, no. 0, ~*,ep!. 11~!57. Uncl.

VAGWIDY!, J.
Yalaco faunistic data. Tn 7n;rlish. r).!.c:l.
(Mag . T,~rmzettirlomanyi Muzeum FvIkonyve, Vol. 7, 1FI~6,
_yar Neynzeti Muzeum
BudapE,st, Hungary)
SO: Monthly List of East FuroDean Accessions (FEA1.) I.C. Vol. 6, no. 9, Sent. lqc~7. Uncl.

VACIVOIGY7, J.
Problems of relationships between the aaradla and Beke eaves frcv,, t he zoclogical
viewpoint. p.427- Vol 4, No.4. FOLDRAJZI MCESITO
Budapest, Hungary.
So: Eastern European Accession. Vol 5, No4, April 1956

V,*LGVI,)LGI'I, L.
After the conference held in Hek.
p. 2 (Allami Gazdasag) Vol.9, no. 10, Cct. 1957, Budapest, Hun.,,,ar-j
I
SO: MONMILY !ND-.'~X CF EAST EUICYZAN AC-Cf-SSICIIS (E',-:AI) LC, V-L. 7. Ir. 1. GTA~-I. jql~r

7AGV,"LGYI, T.
~j'enological exarination of th, r.ollusks of the Torek 77arsh. In En.-I i sh. p. 197
.1
Vol. 6, 1955 VAGYAR NEIZETI MUZZLIT! TE,!-Y-.SZF:TTM)'I-!A'1~i 11 LISFMI, VvKONIM".. A;7*,:AL77S
HISTORICO-NATMALES VASFI NATIONALIS HCGz'JzICI. Bu.-lanest, liunf~rxry.
Source: East European Acces3ion List. Library of Congress
Vol. 5, No. 8. August 1956

-V
0g aw Ewmapoduou d zgtds from CT"w
T. %I =Yan &ad N. X. Bakdava (rrudy
SovedicAan..., 1". MS. W7-242 In
_R= &P--k- of d- = 0
po t on the time of were obtained fin
CNII Au CX sobi. V. and IL con-
clu to t t4 that in so . of o3ankt" the electrode
is In an ketive coWition the met~4 Is deposited " a restdi
of the discharge of complex km adAotbed On the sQtfxm
This expWris the prodn. of fine-grained depodU from oy&W&
baths.-G. V. E. T.

n if,-
V
--7
-th to dcp~Afrf-~
.1 -A 14,q mV, at -~Nl
I- I ?Ikh sE 70 Q( the
j',u 1.
TrT.
P--da. '~9~111arkm. f 1- P-J. 'w-.njz
'i" Eml,f-atwo of V~ 13 .14,; tm~ lthe-rv ad
b'~ 1(i)(t Val %'~Irr iP-. ki,ef,,~A- S~. 1948, 94, FA)l
r"t
,e,
Pr G 9, R rn PtQ,
Usl".'R/Chenistry -- PhysicalTicmistry
ft-ld 1/2 Pub. 40 - 3/27
Authare s Pookov, A. P.,, and VagraWan, A. T.
Title I Electrode processes during depositicn and solution of Ag in cyanide
solutions
Fe riodleal I jzV. AN S1--JSR. Otd. khim. nauk 6, 966-971, Nov-Dee 1954
Abatraot i Certain processes occuring on a silver electrode during polarization
with alternating and pulse currents are discussed. A simple method was
developed for the study of nonstationary electrode processes which take
place within short time intervals. It is shown that the cathode and
anode polarizations during the deposition and solution of Ag in cyanide
solutions are basically concentrational.
Institution Acad. of Sc., USSR, Institute of Physical Chemistry
Sitbmitted April 3, 1954

966-971, 1954
J,V.
p rfri a 61

MRIWAflp A. T.
USSRI'Chamistry
Card 1/1
Authors Vagramyan, A. T., and Popkov, A. P.
Titlo The Theory of Electrolytic Rectifiers.
Periodical Zhur. Fiz. Khim. Vol. 28'. Ed. 49 752-756, Apr 1954
Abstract Studies of the speed of deposition of nickel in a nickel sulfate
during the alternate (cathode and anode) polarization of electrodes.
Also mentioned is the rectification of A. C. current during its flow
thi-ough a Ni/NiSO4/Ni system. Three references; table; graphs.
Institution In.stitute of Physical Chemistry of the AS of the USSR, Moscow.
Su6nAtted August 24, 1953

r
" I- ~'
Ms',
WSR1 Chemistry Physical chemistry
Cad
Autho" I Vagramyan., A. T., and -lolovyeva, Z. A.
Title S Method of studying the rate of electrcchemical reactions
Periodical i Zhur. fiz. khim. 28., Ed. 6, 3.153 - 1157, june 1954
Abstract t A method of studying the rate of electrochemical reactions, based on
complex investigation of relations betueen polarization and current
density, between polarization and time at constant current density and
between current intensity and time at constant cathode potentio1j, is
described. A more complete and accurate understanding of the processes
taking place on the electrode during electro-deposition of metals can
be obtained only through study of above mentioned relations. Four USSR
and 2 German references. Graphs, drawing.
Institution - Acad. of Sc. USSR, Institute of Physical Chemistry, Moscow
Submitt,ad December 27, 1953

MW Chemistry - Physical chemistry
W4 1/1 Pub. 22 - 25/49
I Vagramyan, A. T., and Usachev, D. N.
I Electrodeposition of chromium
Perladicel Dok. MIT SSSR 98/4, 605-6o?, oct. 1, 1954
Abstract The processes occurring during the reduction of chromc acid, widely
used for electrodeposition of Cr, are described. The problems of
current distribution between the various reduction processes, changes
in rate of reaction in its relation to the electrode potential and
nature of polarization, are discussed. The methods by which the rate
of cathode reaction was investigated are explained. The intensity of
electrolyte mixing and concentrated polarization and their effects on
the rate of reduction cf hexavalent Cr into tri-and divalent state
are analyzed. Thret- references: 2-U!;SR and 1-Ckerman (1893-1953).
Graphs.
enis
Institution Academy of Zciences, Tnr-~itute of 11bysical (,h try
Presented by Acad,-.-jrii clan A. 11, Fru~.,-ki-., A-VII 16, 1954

--VAG rV4 tv~ mot F% T.
Mwchemistry - Physical chemistry
Card 1/1 Pub. 22 - 29/47
Authors I Vagramyan, A. T.,, and Teareva, Yu. S.
Title : Internal stresses of electrolytic nickel depositions arA their porosity
Periodical : Dok. AN SSSR 98/5, 807-809, Oct 11, 1954
Abstract t The effect of surface-active substances and alternating current on the in-
ternal stresses and porosity of electrolytic coatings was investigated. The
effect of 2,6 - 2,7-naphthalindisulfonic acid and paracresol., on the porosity
of an electrolytic Ni-deposition, is explain6d. The extent to which the
value of internal -stresses is affected by the addition of the above mention-
ed substances is discussed. The parallelism "oetween the effect.of surface-
active substances and variable current on the internal stresses indicates
that the porosity of electrolytic depositions is due mostly to the stresses
in these depositions. Two USSR references (1951 and 1952). Graphs.
Institution :
Presented by : Academician A. N. Frumkin, May 21., 1954

VAGRANYAR, Ashot Tigranovich; ILOINA-KAKUYNVA, Tatlyana Borisovna;
SINaW-,T-.PF., re or; KAMA A,O.M., redaktor; ATTOPOVICH.
M.K., tekhnicheskiy redaktor
[Current distribution on surface electrodes during electro-
deposition of metals] Raspredelenie toka nn poverkhnosti
elektrodov pri elektrooeazhdenii metallov. Moskva, Gos.nauchno-
tekhn. 12d-vo lit-ry po chernoi i tevetnoi metallurgit. 1955.
66 p. (MLRA 90
(Bleotroplating)

.VAGRAXTAN L", A.T.; SOLOVIYNVA, Z.A.; ALEXSNY3V, V.As, redaktor; BREVORENKO,
u.n.".*%khnicheskly redaktor
[Research methods in the processes of electrolytic precipitation
of metals] Ketody iosledovaniin Protnessov elaktroosnzhdonita
metallov. Moskva. Izd-vo Akad. nauk SSSR, 1955. 250 P. (MLRA 817)
(Zlectroplating)

OV';
U81-R/Chemistry - Electrolysis
Card 1/2 Pub. 147 - 20/2-6
Authors I Tsarevaj Yu. S.; Solokhina, V. G.; Kudrvvts()tr, N. T.; and Vagramyan" A. T.
Title I Effect of surface active substances on the mechanical properties of
electrolytic Cu-depositions
Periodical t Zhur. fiz. khim. 29/1, 166-173, Jan 1955
Abstract I It was established experimentally that surface active substances added
some times to an acid copper sulfate solution for copper plating
produce different effects on the mechanical properties of the deposit.
It was found that surface active substances can cause internal con-
traction and expansion stresses depending upon the nature and concen-
tration of the substance and the current density.
Institution Academy of Sciences USSR, Institute of Physical Chemistry, Moscow
Submitted June 9. 1954

Periodical t Zhur. fiz. khim. 29/1, 116-173, Jan 1955
Card 2/2 Pub. 147 - 20/26
Abstract IIt was ebtablished that copper deponitsobtained from electrolytes
containing thiourea and naphthalindisulfonic acid possess sufficient
plasticity, high micro-hardness and small internal stresses. An
instrument is described which records automatically any changes in
internal stresses of electrolytic deposit in electrolysis processes.
Nine USM references (1935-1951). Table; graphs; drawing.

09 M
USSR/Chemistry - Electrolysis
Card 1/2 Pub. 147 - n/26
Authors I VagraWan, A. T., and Teareva, Yu. S.
Title Internal stresses of electrolytic metal deposit
Periodical t Zhur. fiz khim. 29/1, 185-193v Jan 1955
Abstract I The basic factors resulting in Internal stresses in electrolytic
metal deposit were found to be: changes in lattice parameters, changes
in the distances between the deposition crystals, amalgamation or
enlargemont of deposition drystals and the formation of chemical
compounds between the metal and the admixtures included in it. A
thorough study of the internal stresses of electrolytic metal de-
positions showed a parallelism between the internal stresses origin-
ating in the deposition ard ovarstarain.
Institution Academy of Sciences USSR, Institute of Physical Chemi3try, Moscow
Sutmitted June 9, 1954

I -- - -
Periodical : Zhur. fiz. khim. 29A, 185-193, Jan 1955
Card 2/2 Pub. 147 - 22/26
Abstract The electrolysis conditions and the composition of the electroly-te
were found to have a definite effect on the internal stresses.
Eleven references: 6 USSR; 3 Grerwan and 2 USA (1922-1954). Tables;
graphs.

USSR/ Chamistry-Physical Chemistry
Pard 2/1 Pub. 22- 28/59
Authors S -Vapanqanj A. T., and Popkovp A. P.
Title I Electropolishing of silver
Dok. AN SSSR 102/2, 297-3000 1:4ay 11, 3.955
Abstract I A nev' method allowing similtameous registration of changes in tha electrode
polarization and luster uccurring directly in the process of electro-
Polishing of metals.. is described. The mechwiism of sroothing during
electrolytic polishine:of silver is explainal. The change in luster of the
electrode surface was found t,~, be closely connected with the speed and
nature of the individual electropolishing processes. The basic facter
aiding the smoothing and consequently increasing the luster of the polished
surface is the formation and solution of Ag,)O which is realized through
brief connection and lisconncation of the cu"rrent. Graphs; diagram.
Institution : Acad. of Sc.p USSR, Inst. of Phys. Chem.
Presented by : Acadcmician P. A. Rebinder, December 3,, 1954

Category USSR/Solid State Physics - Phase transformation of solid bodies E-5
Abs Jour Ref Zhur - FizJka, No 1, 1957,No 1171
Author :_Vagr nyan,&J,) Popkov, A.P.
Title : On the Mechanism of Klectric Polishing of Zinc
Orig Pub : Dokl. AN SSSH, 1955, 102) No 3,.547-549
Abstract : Simultaneoup recording to the variation in the polarization in the brightness
of the electrode directly in the electric polishing process was uaed,to study
the mrhanift of electric polishing of zinc by pulse cFrent kcurrent *enslty
la/cm .polarization time 12 seconds, time of exposure'vithout current 2.3
seconds) in'.1n. ZnS,34, 7HpO. The surface of the zinc is -smoothed by the
formation of more satArated solution in the cavitipe of Its surface, thus
causing preferred solution of the projecting sections. Comparlson of the
el*ctric polishing mechanism of zinc and that of silver shown that in the case
of,*electric polishing the decisive reactions take place on the anode.
Card 1/1

VAGRAMYAN, A.T., professor.
Conference on electrochemistry at the Polish Academy of Sciences.
Izv.AH SSSR.O+,d.khtm.nauk no*2:260-262 7 156. WaA 9-7)
(Warsaw-Blectrochemistry)

VAGRAKYAN, A.T., profeunor, otvutstvonnyy rodaktor; KUDItYAVTSNV, N.T..profeaeor.
'-- ""b!t%i6t6tvonnyy redaktor: SHLUGNR, M.A., ~Mil4idat tekhnichookikh nauk.
otvetBtvennyy redaktor; YXGOROV, N.G., redaktor izdatellstva;
PAVIA)VSKIY, A.A., tekhnicheakiy redaktor
[Theory and practice of electrolytic chromium plating] Teoriia i
praktika elektrolitichookogo khromirovaniia. Moskva, 1957. 231 P.
(MLRA 10:9)
1. Akademiya nauk SSSR. Institut fizicheskoy khimit
(Chromium plating)

137-58-6-12951
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 6, p 252 (USSR)
AUTHORS: Vagramy Usachev, D.N., Chervova, G.I.
TITLE: Polarization of the Cathode During the Electrolytic Deposition
of Chromium (Polyarizatsiya katoda pri clektroosazhdenii
khroma',
PERIODlCAL V sb.: Teoriya i praktika elektrolit. khromirovaniya. M09-
cow, AN SSSR, 1957, pp 8-26
ABSTRACT: The polarization of the cathode during electrolytic precipi-
tation was studied, and a quantitative study of the different re-
actions taking place on the electrode was made. Data in the
literature concerning the dependence of cathode. polarization on
the cathode cd are contradictory. It is shown"Viat during reduc-
tion of Cr03 reproducible results may be obtaxnkd only with a
constant current intensity I in the circuit or with strictly con-
stant electrode potential F_ , 1) when I = const, the polariza-
tion curve consists of two stable segments wherein the ascend-
ing and descending branches do not coincide; there is a sharply
defined hysteresis loop; 2) when E = const, the polarization
Card 1/2 curve has an anomalous shape; viz., if the polarization of the

137-58-6-12951
Polarization of the Cathode (cont.)
electrode is raised, beginning at a certain value, the intensity of the cur-
rent falls sharply; the ascending and the descending branches then coincide.
It is shown that the reduction of Cr6+ to Cr3+ corresponds to the first seg-
ment of the curve. The rate of this reaction is dependent upon the diffusion
of Cr6+ toward the cathode. On the last segment three reactions take place
simultaneously: separation of 1-42, reduction of Cr 6~ to Cr3+ and reduction
to metallic Cr. Polarization curves for a constant E value in the presence
and in the absence of HZS04 differ sharply from one another. The presence
of HZS04 favors the reduction of Cr6+ to Cr3+ on the first segment of the
curve and shart)ly inhibits the reduction on the second segment. It is shown
that upon an increase of concentration of Fl?SO., the rate of reduction of H
decreases, whereas the rate of reduction of H2CrO4 to Cr increases sharply,
and the rate of incomplete reduction increases steadily. Upon studying the
changes in I with E = const per unit of time it was established that a film
forms on the cathode during electrolysis, which film is destroyed so soon
as the current is switched on.
1. Chrom1um--Ele(!tx-odepos L t ion 2. (:athole,; (Ele(.-trolytic cell) L.A.
--Polarization
Card 2/2

137-58-6-12946
Translation from: Referatimvy zhurnal, Metallurgiva, 1958, Nr ~, p 252 iUSSR)
AUTHORS- :Vagrarn~ya D.N.
TITLE: Investigation of the Mechanism of Electrolytic Deposition of
Chromium by the Method of Tagged Atoms (Issledovaniye
mekhanizrr.a elektroosazhdeniya khroma metodom mechenykh
atomov)
PERIODICAL: V sb.: Teoriya i praktika elektrolit. khromirovaniya. Mos-
cow, AN SSSR, 1957, pp 27-30
ABSTRACT: An investi-ation was carried out with the object of verifying
0
the mechanism of Lhe discharge of the Cr6+ ion duri,jj its re-
tom of
duction to metallic Cr. Use of the tagged aCr af-
forded a means for the determination that the reduction of
chromic acid to Cr takes place directly without formation of an
intermediate Cr-3 (sic!) ion.
L. A.
1. Chromiwn--Electrodeposition 2. Chromium ions--Properties
3. Chromium isot-,pes (Ra(lic~ucti-.ie)--Appl..'Leations
Card 1/1

137-38-6-12945
Translation from- Referat.%rnyy zhurnal. Metallurgiya, 195.;' P 25: ('~'Ssp'j
AUTHORS: Chervova, G.I., Vakrainyan, A.T.
TITLE: Distribution of Metal on the Electrode During the Electrolytic
Deposition of Chromium (Raspredeleniye metalla na clektrode
pri clektroosazlidenii khroma)
PERIODICAL: V sb.: Teoriva i praktika clektrolit. khromirovaniya. Mos-
cow, AN SSSR, 1957, pp 208-Z14
ABSTRACT: Work on the determination of the relative character of the
distribution of the metal on the cathode in existing Cr batlis is
described. The distribution of the metal was determined by
weighing a cylindrical cathode assembled from 10 metal disks.
It is shown that during electrolytic depositions of Cr a change
in the content of electrolyte does not have any substantial effect
on the uniformity of the distribution of metal on the cathode sur-
face. The best results were obtained in a bath of the following
composition (in g/liter) Cr03 250, HZS04 1.2, H?SiF6 12-
Contrary to the statement of Farber and Blyum it was shown
Card 1/2 that as,,cathode cd was increased from 10 to 50 amp/dm? in an

137-58-6-12945
Distribution of Metal jcont.)
electrolyte containing 250 g/liter of C"03 and Z.5 g/liter of H2SO,j at 500C
the uniformity of the coating decreases. A certain improvement of distribu-
tion appears at small cathode cd but it is not significant.
P.S.
1. Chromi urn--Elec trod epos it ion 2. Cathodes (Electrolytic cell)--'roperties
3. Cathodes (Electrolytic cell)--Tes'u results
Card 2/2

VAGRAWAN, A. T. and PETROVA., YU. a.
"Untersuchung der physikalisch-mechanischen Eigenschaften galvanischer
'Uberzugs."
paper submitted for the Congress on Corroaion, Budapest, 24-30 Sept 1958.
Phys:Umlisch-/Chemischee Inatitut der Akademie der Wissenschaften der UDSSSR,
Mowcow.

SOV/12 2-58-?-3/31
AUTHOR: Vagramyan, A.S., Cand1date zef Technical
TITLE: A--Yevi _hleth~_d of Measuring Temperature at the Friction
Surface of Dissimilar Metals (Novyy metod izmereniya
temperatury na. Doverkhnosti tren-.ya raznorodnykh metallov)
PERIODICAL; Vestnik Mashinostroyen-iya, 1958. Nr ?, pp .13 - 15 (USSR)
L
ABSTRACT: The theoretical and exDerimental research into the tempera-
ture field adjoining fric-tion surfaces is said to be still
in a state of uncertainty due to the absence of a reliable
method to measure local temperatures. A variant of the
natural thermocouple method introduced in 1936 by Bowden
and Ridler (Proc. Roy. Scc. A, 1936. Vol 154, D 640) is
proposed. It consists of arranging a steel disc to rotate
whil,zt two specimens, one above the other, are pressed
agai!LSt the cylindzical surface of the disc. The thermo-
electric e.m.f. between the two specimens depends only on
the temperature at the friction surface and the materials
of the two specimens, wh1list -"-h.e d:~ac. acts only as a con-
ductor. In a friction test a variable speed drive
rotates a on a ,.-ertioal shaft pointing downwards.
A steel diss at the end of a .3hark is alamped in the chuck
and rotate;3 with i'5. The dis,~t -4s immersed in an oil bath
Cardl/3

SOV/122-518-~--3/31
A New Method of Measuring Tem--eratire at the Fr-42tion S---r-fane of
Dissimilar Metals
which can be raised o:! lowered. The friction specimens
are mcunted in a block at the end of a swingin.,. arm and
are pressed by a weight, exerting a torque on ~,he axle of
the swinging arm, against the rotating disc. The specimens
are eas-41-y interchangeable, being mounted by clamping in
spe,~Lmen ho--ders inserted in the block. Each specimen
holder fin--,shes with a plunger which compresses a liquid
in a bore into which the plunger fits. The other end
cf the bore is plugEed but the bores of both specimen
holders -ommunii~ata with ea,~h other and a pressure gauge.
Thus the two pressures are equali-sed and measured. The
specimens are -,alibrated against ea~;h other statically.
To obtain the e.m.f. aga.-*Lrst temperature, combinations of
carbon stee-',, bronze, babbit. cast iror, and aluminium were
tested. Figure 4 shows the relation between th'e temperature
and the presstre foi- vari-ous pairs at a sliaing speed of
3.6 mlse,~. An empirical formuIa for eaoh pair relates the
I'emperat-..~~e and the speed.
Card2/3

SOV/122-58-7-3/31
A New Method of Measuring Temperature at the Frict'Lon Suzface Df
Dissimilar Metals
There are 4 figures and 8 references, 7 of which
are Soviet and I English.
Card 3/3

5W
WTHORS: Popkov, Gevorkyar"
Vagramyan, A.T.
TITLE:
PERIODICAL.
Overvoltage During Electrodeposition of Antimony
(Perenapryazheniye pri elektroosazhdenii surlmy)
Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1958,.Nr 11, PP 1310 - 1314 (USSR)
ABSTRACT: In the present paper the authors investigated polarization
during the electrodeposition of antimony by means of a rapid
method. This made it possible to consider the displacement of
the equilibrium potential and to estimate more precisely the
quantity of the overvoltage. Preliminary results have ohown
that in antimony tartaric acid solutions fine crystalline de-
posits with a current yield of practically 100 % can be obtained.
In figure la a photo of an oscillogram with polarization curves
can be seen which have been plotted by means of the rapid methcj.
The more slowly the curve is plotted the more the equilibriu=
potential of the electrode is displaced in the pojitive directicn.
This is apparently in connection with the fact that a low curzent
density as well as with values i k = 0 an oxidation of the anti-
Card 113 mony surface takes place. Apparently the overvoltage q,-aantity Oru')