SCIENTIFIC ABSTRACT TSEYTLIN, V.Z. - TSEYTLIN, YA.M.

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SOV/124-58-4-4875 Translation from: Refarativnyy zhurnal, Mckhanika, 1958, Nr4, p 166(USSR) AUTHORS- Tseyttin, V. Z. , Volkova, T. 1. TITLE: Investigation of Relaxation Process in Metals by the 1. A. Oding Method (IS51edovaniye protsessa relaksatsii napryazheniy v metallakh metodom 1. A. Odinga) PERIODICAL: V sb. : Prochnost' metallov. M05COW, AN SSSR, 1956, pp 41-49 ABSTRACT: Some laws governing stress relaxation and factors affecting the process are experimentally investigated by the method of relaxation with the aid of annular specimens as proposed and developed by I. A. Oding in 1944. Results of determination of quantitative characteristics of flexural stress relaxation are presented. The influence of numerous factors, both external (temperature, stress, time) and internal (chemical composi- tion and structural state of the material), affecting the process of relaxation have been studied. Recommendations are tendered as to the content of the alloying elements (Cr, Mo, V) that increase the resistance to relaxation of low-carbon steels for Card 1/2 various temperatures. The relationship between relaxation SOV/124-58-4-4875 Investigation of Relaxation Process in Metals (cont. ) stability and chemical composition of austenite steels was studied. Results of the experiments are compiled in tables and graphs. Yu. G. Maksimov 1. Metals--Mechanical properties 2. Metals--Chemical properties 3. Metals--Structural analysis 4. Metals--Mathematical analysis Gard 2/2 Translation from: Referativnyy zhurnal, Metallurgiya, 1957, Nr 12, p 351 f'USSR) AUTHORS: Tseytlin, V. Z., Volkova, T. 1. TITLE: Employment of 1. A. Oding' s Method in the Investigation of Stress Relaxation in Metals (Issledovaniye protsessa relaksatsii napryazheniy v metallakh metodom 1. A. Odinga) PERIODICAL: V sb. : Prochnost' metallov. Moscow, AN SSSR, 1956, pp 41-49 ABSTRACT: An analysis of advantages of the ring method of testing metals for relaxation, as proposed by 1. A. Oding E'Novvy metod ispytaniya na relaksatsiyu i polzuchest' " (A . Nev Testing Methcd for Relaxation and Creep), 1949, Book 23, MAShGIZ I , and an examination of certain laws governing the relaxation process when this method is employed.. It is pointed out that the proposed method deserves wide use and that it may be successfully applied to the development of a theory of stress relaxation in metals, and to an evaluation of the relaxation stability of materials. With this method it is possible to obtain directly quantitative values for re- laxation characteristics not only of parts subjected to bending, but also of parts operating under tension; such as bolts and dowels of Card 1/1 boilers and turbines. Z, F. 1. Metals-Stress analysis PiTi~P]A~~SKAYA. Z. N. kindidat'taihnichaskikh nauk; UTLIN, Va., Xandidat tekhnichaskikh nauk. In7eatigating the properties of 11723 (TsZh-4) steel. Metalloved. i obr. met. no.12:17-27 D 156. (MLRA 10:2) 1. TSentrallnyy nauchno-iseledovatelOskiy institut tyazhologo mashinostroyaniya. (Steel--Testing) -7~f ~11"Aj , V, Z. USISR/Solid State Physics - Mechanical Properties of Crystals E-10 and Polycrystalline Conwounds. Abs Jour : Referat Zhur - Fizika, No 5, 1957, 11908 Author : Tseytlin, V.Z. Inst ; Central Scientvific Research Institute for Technology and Machine biilding, USSR. Title : Third Period of Relexation of Streases in Metals. Orig Pub : Zavod. laboratoriva, 1950", P-2, No 7, 8k,5-849 Abstract - The author calls attention to the, incorrectness of making an analogy between the third period of creep with the third period of relaxation, as proposed by Gintsb'urg (2;aVod. lat- oratoriya, 1953, 19, 4). Analyzing the extensive exp'eri- mental material of the Scientific Research Institute for Technology and Machine Building on stress rela.1mtion ci:rve.~ obtained with a large number of types of steell Card 1/2 137-58-2-4078 Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 2, p 259 (USSR) AUTHORS: Lashko, N.F., Tseytlin, V.Z. TITLE: Certain Peculiarities of Medium-carbon Chrome -molybdenum Pearlitic Steel (Nekotoryye osobennosti sredneuglerodistoy khromornolibdenovoy perlitnoy stali) PERIODICAL: V sb. -. Fiz. -khim. issled. austenitn. splavov. Moscow, Mashgiz, 1957, pp 167-171 ABSTRACT: A study was made of two types of chrome -molybdenum steel containing 2 percent Cr and 0.9 percent Mo, one with an 0.5 percent V content and one with no V content. The steel was fused in a high-frec~lency furnace with a capacity of 12 kg. The ingots were forged into rods which were normalized at 10000 C and tempered for 6- 10 hours at 650-7400 and for 100 hours at 6501 The phase cornpo'sition of the steel was investigated by means of a comprehensiveiphysicochemical analysis which involved sepa- rating out the su4plus phases by chemical means, a chemical analysis of the residue, and a differential X-ray and chemical study of the residue phases. After normalization and tempering Card I /Z at 6500 for 10 hjurs the steel with no V in it was found to 137-58-2-4078 Certain Peculiarities of Medium-carbon Chrome -molybdenum Pearlitic Steel possess three phases of varying composition- (Fe, Cr, Mo) 3C, (Mo, Cr.)2C, and (Fe, Cr, Mo) 23 C6 ; the steel with the 0.5 percent V content was found to have two phases (Cr, Fe, Mo, V) 7C 3 and (V, Mo, Cr)C. In the steel with no V the (Fe, Cr, Mo) 3C phase was not in evidence after a 100-hour tempering at 6500 , which suggests that this phase is metastable. The corn- position of a stable phase in the steel with no V was not ascertained. In the V-based MeC phase of a V-containing carbon steel the Fe was practically insoluble, the Cr was not very soluble, but a relatively large quantity of Mo could be dissolved therein. A small quantity of V ( -.10.5 percent) , which was almost wholly combined with the vanadium carbide, exhibited great influence on the phase composition of the steel. Because a significant quantity of the Mo combined with the vanadi-,irn carbide, the possibility of formation of Mo 2C was excluded. The remaining C combined in the phase Me 7C3' T.F. 1. Steel-Phase stadies Card 2/2 AUTHOR: Tseytlin, V. Z. 126-1-6/40 TITIB: Ferromagnetic phase in austenitic hibr~h temperature steels of the type 14-14. (Ferromagnitnaya faza v austenitnykh zharoprochnykh stalyakh tipa 14-14). PERIODICAL: Fizika Metallov i Metallovedeniye, 1957, Vol.5, No.1, PP. 37-43 (USSR) ABSTRACT: The results are described of detection of the ferro- magnetic phase in high temperature austenitic type 14-14 steels (approximately 14% Ni and 14% Cr). It -vias established that the hi,-- temperature strength ofthe ,h steel decreases considerably with the appearance of a ferromagnetic phase. The speed of appearance and of cessation of the ferromagnetic phase increases with increasing -temperature. The formation of -the ferro- magnetic phase is associated with concentration changes in the solid solution during carbide formation ~airl its cessation is associated with diffusion processes which lead to equalisation of the concentration. The structure of stainless and high temperature austenitic steels with 18 to 19016 Or and 8 to c)0,66 Ni may contain the ferromagnetic a-phase even directly after hardening in a quantity Card 1/6 which depends on the Ni and Or contents and also on 126-1-6/40 Ferromagnetic phase in austenitic hii~;h teraperature stee-15 of the type 14-14. the contents of those carbide forming elements which bring about anSM;3faction Of the y-zone. After tempering and also during operation, the quantity of the ferro- magnetic phase increases and may degenerate into the a-phasel bho oxistence of which Is highly undesirable. The presence of two solid solutions has Lua unfavourable influence on the properties of steels intended for long duration operation at elevated temperatures. Therefore, for steels intended for steam piping, the nickel content is frequently increased for -the purpose of improvint~ the uniformity of the solid solution. Type JL~-14 austenitic steels have a more uniform structure of the solid solution and it was assumed for a long time that the solid solution of such steels consists solely of alloyed austenite whatever the state of the steel (hardened, tempered, after operation over long periods). Now methodo of analysis, particularly the method of magneto-metallographic investigations developed by N. I. Yeremin (Ref.1) showed that under certain conditions a ferromagne-tic phase also forms in 14-14 steels but this phase is unstable and its quantity can be controlled by heat treatment. Investi- Card 2/6 gations made on the steel 90-434, which contains 126-1-6/40 Ferromagnetic phase in austenitic high teiaperanture steels of t1-he type 14-14. approximately 14% each of Cr and Ni and 100/6' Co, yielded t8e followinG results: after hardening in oil from 1260 C no signs of a ferromagnetic phase wSre detected. However, cubsequent tempering at 760 C for 20 hours brought about appreciable separations of this phase in the form of a dense network alon6 the grain boundaries and around individual carbides (FiS.1a); if the tempering duration at the same temperature was increased to 50 hours, the network of the ferrowagnetic phase was thinner and discontinuous in some spots (Fig.lb) and,after tempering for a total of 100 hours, the network became even mor 8 discontinuous and fainter (Fig.lB). Tempering at 800 C for 20 hours produced a discontinuous fine network of the ferromagnetic phase (Figl~), whilst after tempering for an equal duration at 8 0 C, no ferromagnetic phase at all could be detected. These result-Is show that in this steel the ferromagnetic phase is not stable, forms only under certain conditions and decreases with time. By means of magneto- metallographic analysis of the microstructure (carried Card 3/6 out by N. I. Lebedyanska) the processes of grovith and 126-1-6/40 Ferromaf,znetic phase in austenitic IdLj-h tempera-11-ure steels of the type 14-14. reduction of the ferromagnetic phase in the steel. V-~34 at 650, 750, 800 and 850 C (after hardening from 1250 C) were watched and the results of these observations are entered in a table, P.38. It can be seen that at each of these temperatures the speed of formatioi-i -and disappearance of the ferromagnetic phase is different. The graph, Fig.2, shows diagrammatically the increase and the cessation of the ferromae;netic phase; with increasing temperature the maximum of the ferromagnetic phase shifts towards the left, i.e. towards shorter tempering times. A. -P. Shishkova (Ref.2) obtained analoSous results wh n studying the fatigue limit of austenitic steels Msimilar type. In Fig.L~ the change Of the relaxation strength (r8sidual stress after 4000 ohours of loading) at 650 C after hardening froin 1200 C and an initial stress of 12 kg/mm is Lrraphed. The author arrived at the followinG conclusions. The ferromagnetic (x-phase may exist not only in the structure of the austenitic steel 19-9 but even in the structure of the more stable 14-14 type steel; in such steel the Card 416 ferroma.-netic phase appears not only durin- a-eing but L, 0 Lj 126-1-6/40 Ferroma gnetic phase in austenitic hibh temperatui~e steels of the type 14-14. also as a result of tempering after hardeninS and ceases under certain conditions. This phase is detected along the grain boundaries and surrounding individual carbides. Appearance of -the a-phase in austenitic steels is linked with diffusion processes of carbide formation and with local concentration changes of the solid solutions in zones directly adjacent to the separating out carbide particles which bring about y to a transformation. Cessation of the cc-phase is due to diffusion processes which equalise the concentration of the solid solution. Appearance of a ferromagnetic a-phase brings about a considerable reduction of the heat resistance in static and cyclic loading. Therefore, it is necessary during heat treatment to select such a tempering temperature and a duration of the tempering at which the a-phase is suppressed completely or at least to a 8 onsiderable extent; in the case of tempering at 860 C, the a-phase was completely eliminated after 20 hours. The problem of formation of the ferromagnetic phase in an austenitic steel as a result of plastic deformation when non- Card 5/6 diffusional y to a transformation takes place has not 126-1-6/40 Ferromagnetic phase in austenitic high temperature steels of the type 14-14. been considered in this paper. There are 4 figures, 1 table and 4 references, all of which are Slavic. SUBMITTED: August 29, 1956 (Initially), November 15, 1956 (after revision) ASSOCIATION: TsNIIT11ASh. AVAILABLE: Library of Congress. Card 6/6 T-,F_Yru,~, v. _" . AUTHOR: TseytLin,V.Z. 32--7-27/49 TITLEt On the Early Period of Relaxation Stress in Metale (0 rannem pe- riode relaksatsii napryazheniy v metallakh) PERIODICAL: Zavodskaya Laboratoriya, 1957, Vol. 23, Nr 7,pp. 846-849 (USSR) ABSTRACTi Relaxation stress is considered to be the result of two processes: the intergranular and the internal granular process. At present the intergranular processes predominate, the effect of which is decrea- sed by degrees, while the part played by the internal granular pro- cesses at the same time gains in importance. For tests carried out according to the method of relaxation investigation annular samples were used, which were subjected to stress by a wedge being pressed into the interior of the ring. An analysis of relaxation curves ga- Ye the following results: 1) With a rising temperature in heating the samples of up to 6ooO the relaxation process takes an active course. 2) The higher temperature rises in the initial period, the more active does relaxation stress become. Relaxation velocity thus in- creases proportionally to the rise in temperature. 3) The decrease of stress increases proportionally to the increase of initial stress. The method of annular samples was repeated in connection with heating in a hot lead though. The following results were obtained by the investigations Stress relaxation in the early Card 1/2 period is explained by the viscous sliding of the grains along their On the Early Period of Relaxation Stress in Metals 32-7-27/49 boundaries, so that it appears to be suitable to decrease the num- ber of grains along the boundaries with an increase of the volume of the grains, which can be brought about by thermal treatment of the steel. (It is known that coarse-grained steel shows greater re- sistance against relaxation than fine-grained steel). . Easily meltable (and disturbing) admixtures of lead, antimony, ar- senic, and bismuth should be removed because in this way hardness is increased. By thermal treatment such a structure should be produced as con- sists of a small number of the grains of different phases, with, however, the geometrically correct round shape. There are 5 figures. ASSOCIATION: Central Scientific Research Institute for Technology and-Machine Construction (Tsentrallnyy nauchno-issledovatellskiy institut te- khnologii i mashinostroyeniya) AVAILABLE: Library of Congress. Card 2/2 TSBYTLIH, V.Z., kandidat tekhnichookikh nauk. Iffect of molybdenum on rela3ation resistance of low-t:arbon pearlite steel for steam pipes. [Trttdv] "THITUSH no.79:31- 86 157. (WLRA 10:6) (Molybdenum) all. ..Xn' ual lograpby) , __~_ I I- -, I U, ' ~ ~ T I /- I f Ff Y v - - " I 1 0 / I LASHE, N.F., kand.takhn.nauk; TSEYTLIN, V.Z., kand.tekhn.neuk Characteristics of medium carbon chromium-molybdenum steel. [Trudy] TSNIITMASH 84:167T171 '57. (MIRA 10:11) (Steel alloys-Metallography) Y7_ L IN 129-1-7/14 AUTITOR; Taeytlin, V.Z., Candidate of Technical Sciencesi and z5va, . ., Engineer. TITLE: Change in the Properties of the Nickel-chromium Alloy )W65 for Stationary and Mobile Turbines in the Process of Long Duration (Up to 10 000 Hours) Isothermal Heating (Izmeneniya svoystv nikellkhromovogo splava EI 765 dlya statsionarn,ykh i transportnykh turbin v protsesse dlitell nogo (do 10 000 chas.) izotermicheskogo nagreva) PERIODICAL: Metallovedeniye i Obrabotka Metallov, 1958, NO.17 pp. 30 - 35 (USSR). ABSTRACT: A considerable number of published papers are devoted to nickel-base, particularly nickel-chromium,alloys. In most cases, the experiments were carried out predominantly for short time durations (amounting to a few hundred hours). In this paper, the results are described of observation of the long duration isothermal heati~g,,of up to 10 000 hours.,on the properties of the nickel-chromium base a;loy ;~A?65 which has a high relaxation strength at 700 - 750 C. The heat treatment of the alloy consisted og hardening after heading for three hours at 1 150 or 1 200 C, tempering at 800 C for 20 hours or at 760 00 for 25 hours. The lo~g-duration isothermal Oardl/5 heating was effected at ?00 - ?50 C and the change with time 129-1.-?/14 Change in the Properties of the nickel-chromium Alloy 3~A?65 for Stationary and Mobile Turbines in the Process of lionE Duration (up to 10 000 Hours) Isothermal Heating. was studied of the hardness, impact strength, micro-structure, lattice parameter, phase composition, electric and magnetic properties and the resistance to corrosion in air. The heat resistance was determined predominantly on the basis of the relaxation strength. In Fig.1, the change in hardness, impact strength, specific electric resistance and magnetic suscepti- bility are graphed for isothermal heating at ?50 C for durations of 10 000 hours. Fig.2 shows the change in the contents of nickel, aluminium, titanium, molybdenum and tung- sten in 'the separated-out phases as a function of the iso- . thermal annealing time. Fig-3 shows the change in the residual stress after 10 000 hours as a function of the test tempera- ture for an initial stress of 25 kg/mm . Fig.4 shows the change of the residual stress after 10 000 hours as g function of the initial stress for a test temperature of 700 C. Fig.5 shows the change of the residual stress as a function of the number of loadings whereby the test duration between the repeated loadings was 1 500 hours. Fig. 6 shows the Card2/5 relaxation curves for repeated loadings. It was found that 129-l-'//14 Change in the Properties of the Nickel-chromium Alloy ~A?65 for Stationary and Mobile Turbines in the Process of Long Dufation (up to 10 000 Hours) Isothermal Heating. each repeated loading to the initial stress increases the relaxation strength; after 6 loadings fo~ 1 500 hours each, the strer can be increased from 14 kg/mm (first cycle) to 23 kg/mgi (sixth cycle). The speed of gas-corrosion in air at 700 C, determined by L.P. Kestell is very low, amounting to about 0.0011 mm/year. Observations relating to the change in the properties of nickel-chromium alloys alloyed with molybdenum and tungsten, carried out for isothermal hardening at 700 and 750 0 for durations of 10 000 hours (which is equal to the maximum duration of overhaul periods of power plants),permit the following conclusions: alloys of this type have a high stability of their properties for long service lives at 700 to 750 C. Particularly, the relaxation curves show that the relaxation strength is maintained for periods exceeding the test durations and this also applies, to some extent, to hardness and impact strength. Physico-chem~cal processes proceed in the temperature range 700 to 750 C very slowly for the alloys under consideration, the_ ix'---jp1-ha:ee.-4T-V",this Card3/5 temperature range is stable and combination of this phase'into 129-1-?/14 Chanoe in the Properties of the Nickel-chromium Alloy BM765 for Stationary and Mobile Turbines in the Process of Long Duration (up to 10 000 Hours) Isothermal Heating. Ni3Ti was not observed even after isothermal annealing for 10 000 hours at 750 OC. Some change in the properties of the alloy detected in the interval of 1 000 to 3 000 hours is attributed to dissociation of binary carbides and possibly to changes in the composition of the carbide Me 23C6, as a result of which an impoverishment takes place of the separated-out phases in molybdenum and tungsten and an enrichment of these with a solid solution and it is also ktj;ributed to proc8sses of coagulation of the al-phase 0which/tL$,tivated at ?00 C after 1 000 hours of heatiagsnd'~st 750 C somewhat earlier; however, these changes in the properties of the alloy are insignificant and do not affect the relaxation strength of the alloy. The fact that the physico-chemical processes in the studied alloys are slow can be explained by the complicatbd compbsitiori and by the increase in the number of separated-out phases (presence of carbide phases) and also by a complication in the composition and the structure of interacting phas which, Ca.rd4/5 according to the views expressed by A.A. Bochvar rRef. 52, 129-1--//14 Change in the Properties of the Nickel-ch-romium Alloy 3W%$ for Stationary and Mobile Turbines in the Process of Isong Duration (up to 10 000 Hours) Isothermal Heating. bring about a braking of diffusion exchange processes at the boundaries of division of these phases. M.F. Lesnykh parti- cipated in the experimental part of this work. N.F. Karpenko measured the lattice period and took the X-rays of the precipi- tates and L.A. Nude carried out the chemical analysis of the phases of the precipitates. There are 6 figures and 5 references, 3 of which are Slavic. ASSOCIATION: TsNI1TMASh. AVAILABIE: Library of Congress. Card 5/5 MINE= f, -,rQ 1 -:4, -41r 7~ J-Z- v*! 4. 3'-f- '7~~ 4; R grA, A "M --IN, -P DRAM pgk,;- Ix it7 Ld 4:41, H"a F I VEF F.,11F I.. - - -- - - -Iz~: .."- -- , -. ~ -, - 7z ~-, -, 4 ~ ~, - 71-~ -- -Z-. ~ ~~. w~ -:,- =- - - = S I t Z-- 18(2),7(0) AUTHOR; Tseytlin, V. Z. SOV/32-25-1-33/51 TITLE: On the Determination of the Pl,~sticilty of Fleat-Resisting Alloys inDestruction flOb otsenke plastichnosti zharoprochnykh splavov pri razryve) PERIODICAL: Zavodskaya Laborntoriyn, 1959, Vol 25, Nr 1, PP 87-90 (USSR) ABSTRACT: The present determinntion of the plasticity of hent-resisting alloys, which is judgod from the extent of relative (con- ditional) extension, is inaccurate in the case of less elastic alloys where each per cent of residual deformation is important The plasticity of the E1765 alloy (chrome-nickel bsse) at 565-6500, for instance, can be wrongly determined (Table) in this way. Maximum deformation is determined more precisely according to the sample contraction since the latter charac- terizes the degree of deformation of the most strongly deformed part of the sample. Thus the maximum plasticity can be expressed by the dquation F0 - F K Card 1/2 F 0 On the Determinntion of the Plasticity of Heat- SOV/32-25-1-33/51 Resisting Alloys in Destruction where P. denotes the initial and FK the finel cross-sectional surface of the sample contraction. The absolute qunntity of extension, which is determined by means of the extensometer, permits the plotting of the creep cur;e in the coordinates "relative contraction - time" ('+ - t) (Fig 1). As this characteristic of plasticity is not commonly known yet the author recommends to apply I. A. Oding's suGgestion (Ref 3). lbroad, the plasticity of cast iron is alrepdy being deter- mined according to the relative contraction + , which in- dicates the necessity of introducing this term. There are 2 figures and 4 Soviet references. ASSOCIATION- Tsentrallnyy naunhno-issledovatellskiy institut t:?khnolopii j MqShinostroyeniya (Central scientific Research Institute of Technology and Machine-Building) Card 2/2 A 18(3) PHASE I MK EMDITATION SOV12103 Tsentrallnyy nailchno-issledovatellskiy institut tekhnologii i mashinostroyeniya Struktura i svoystva zharoprochnykh materialov; [sbornik] (Structure and Prop- erties of Heat-resisting Materials; Collection of Articles) Moscow, Mashgiz, 15L59. (Series: Its: (Trudy] kn. 93) Errata slip inserted. 4,000 copies printed. Additional Sponsoring Agencies: USSR. Gosudarstvennaya, planovays, komissiya and Glavnoye upravleniye nauchno-issledovatellskikh i proyektnykh organizatsiy. Ed.: Z.N. Petropavlovskaya, Candidate of Technical Sciences; Ed. of Publishing House: N.A. Ivanova; TL~ch. Ed.: A. F. Uvarova; Managing Ed. for Literature on Metal Working and Thol Making: R. D. Beyzellman. FUYIPOSE: This book is intended for workers of scientific research institutes and for engineering staffs of plant laboratories of the boiler and turbine industries and power stations. It may also be useful to staff members of higher educational institutions studying problems of physical metallurgy. Card 1/9 Structure and Properties of Heat-resisting Materials (Cont.) SOV/2103 COVERAGE: This collection of articles describes results of work done at TsNIITMASh on the strength of materials used constantly at high temperatures in power plants. The articles deal with groblems of heat resistance, al- loying, and the production and heat treatment of heat-rusistant steels. The evaluation of properties of industrial materials used under high and ultra-high pressures is given, and modern testing methods are discussed. No personalities are mentioned. References follow several of the articles. TABLE OF CONTENTS: Foreword SECTION I. THEORETICAL PROBIEMS 3 Osipov, K.A. [Doctor of Tachnical Sciences). Melting and Blip at Grain Boundaries in Metals 5 Klo Ving-sa Is formula for the velocity of slip and N.F. Mott's hypothesis on the direct connection between the phenomena of melting and -viscous slip at grain boundaries are discussed. Card 2/ 9 I Structure and Properties of Seat-resisting Materials (Con-11.) SCJV/2103 Ti!~ ~Ln ~Y.4. (Candidate of Technical Scienceslyand S. A. Yug94ovajC&ndj- Aatee Physical and Mathematical Sciences]. The Role of the4d4!-p)iase in the Resist- ance to Relaxation'of Ni-Ck-Aliti Alloys 10 The *conditions for formation and existence of the C