SCIENTIFIC ABSTRACT TRESHCHINSKIY, A. I. - TRESHCHOVA, YE. G.

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• Collection: Scientific Abstracts
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• Document Creation Date: November 2, 2016
• Document Release Date: March 20, 2001
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

TIMHCHIIMKIY, A.I.; CHOKIY, L.P.
Changes in the electric potentials of the skin in cerebral tumors. Vop.
neirokhir. 17 no.5:14-18 S-0 '53. MRA 6:n)
1. Institut neyrokhiru-rgii Ministerstva sdravookhranoniya VSSR.
(Skin) (Brain--Tumors) (Electrophysiolo&-)

TRESHCHINSKIf I A. 1.
ItNeuralgic *dromes Due
Degree of CAdidate for
Piroeov, (Odessa), 1955
to Affections of the Trafacial Nerve." (Dissertation Ibr
Medical Sc--iences.) Odessa State Medical Inst imeni 111. 1.
SO:* M-1036 28 Mar 56

DIWIJRG, A.D.:
Clinical aspects of lesions of the cervical intervertebral
disks. Zh:ur.nevr. i psikh. 55 no.10:721-727 '55 (MIRA 8:11)
1. Otdal klinicheskoy i eksperimentallnoy nerrologii (zav.
-orof. A.-F.Makarchenko) Inatitutafiziologii imeni A.A.Bogomoll-
tsa AN USSR j Institut ne7rokhirurgii Ministerstva zdravo-
okhrananiya USSR, Kiyev.
(INTERVERMRAL DISKS, diseases
causing nouralgias, cervica I disks)
(NLVRALGIA tiolner and pathogens
" toebral'-disk lesions, c rv
Interver
OW.RVES SPIXkL diseases
r;Aicular ;ynd.caused by cervical disk lesions)

TRESHcHiNsm, A.I. (Kiyev, ul. Otradnaya, d. 32); PATNZILIBIR, Ta.I.,
d.32)
Neuralgic syndromes caused by lesions of the otic ganglion. Nov.
khir.arkhe no~2:68-71 Mr-Ap 157. (MLRA 10:8)
1. Nouchno-issledovatel'skiy institut neyrokhirurgil Mintaterstva
zdravookhraneniya USSR
(NzuRATziA, ncIAL) (EAR--DISBASIS)

PEL'TS, B.A.; TRBaIGH
.. JALWw.-&&wuL~CKIYev)
New method for recording Babinski's syndrome And the Dlantar
reflex. Yrnch.delo sunplement 157:85-86 (MIRA 11:3)
1. Ukrninskiy nauchno-iseledovatel'skiy institut neyrokbirurgii
Ministeratva zdravookhraneniya USSR.
(REFLOXMS)

MOROZOVA, N.P., kand.med.nauk, roferent; -TRESHCHINSK-IT,-- A.I., referent;
GCRODINSKIT, D.N., dotsent, referent- -
Minutes of meetings of the Kiev and Kiev Province Surgical Societies.
Nov.khir.arkh. no 6:128-134 H-D 159. (MIRA 13:4)
(ICMV iVOVINCII--SURGICAL SOCIRPIN)

GORODINSKIT, D.M., dotsent; TRESHCHINSKIT, A.I*; BOYKO, V.I., dotsent
.,s of the Kiev and Kiev Province Surgical
Transactions of meeting
Society. Nov,.khir.arkh. n0-5:133-141 S-0 159. (MMA 130)
(XIMPROVINGD-SMICAL SOCININS)

AMOS.OV, N Mq LISSOV, I.L.; MOKIRIYUK, Yu.N.; SIDARWO, L.N.; TRESHCHINSKIY
-A:I,
Heart operations with the use of artificial bloqd ciraulatior4
Grud. Iddr. 2 no.6:18--JO-N-D 160. (MIRA 14:0
lo Iz kliniki torakalinoy khirurgii Ukrainskogo instituta tuberkuleza
(dir. - dotsent A.S. Mamolat) i kafedry torakallnoy khirurgii
Kiyevskogo instituta usove'rshenstvovaniya vrachey (dir. - dotsent
M-N.Umovist). A*es avtorov: Kiyevq 389 Baykovaya gora, Institut
tuberkuleza. ... I.
(BLOOD-GIRCULATION, ARTIFICIAL)
(HUM-ZURGERY)

TRESHCH AWL,
nIntervertebral diokon by A.D~D~naburg, A.F.Rubashova. Zhur. nevr.
i psikh. 60 no.10:2386-V88 16001 -~~= 14: 1)
(INTEnMTEBRA.L DISK) (DINABURG., A.D.)
(RUBASHOVA, A.E.)

AMOSOV, N.M*, prof.; LISSOV, I.L.; MOKM=, Yu.N.; SIDARENKO, L.N.;
TRF-SHCMSKlY, A.I.
Preliminary experience with the uBe of artificial circulatiun
in cardiac surgery, Vest.khir. 86 no,3:10-20 Mr 161. (MIRA 14%3)
1. Iz Ukrainskogo instituta tuberkuleza, (dir. - dotsent A.S.
Mamolat) i Kiyevskogo instituta, usavershenstvavaniya vrachey
(dir. - dotsent MoN. Umovist).,
(BLOOD-CIRCULATIONp ARTIFICIAL)

AMOSOVf Nikolay Mikhaylovich, prof.; L;SSOV, Igor' Leonidovich;
SIDARENKOP Lena flikolayevna: Prinimali uchastiye:MMUKg14SKIY
j_
MOKHNYUK., Yu.N.; mALAkHoVA, A.V.; BEREZOVSKIY, K.K., red.;
CLOAK, V.D., tekhn. red.
......'[Heart- surgery with artificial blood circulation] Operataii na
serdtse s iskusstvennym krovoobrashcheniem. Pod red. N.M.
Amosova. Kiev, Cos.med.izd-vo USSR, 1962. 245 p.
(MIRA 16:7)
1. Chlen-korrespondent AMN SSSR (for Amosov).
(HEARr--SURGERY) (PERFUSION PUMP (HEART))

TEMCHMSKly., A.I.; INIKOLAYEV, YuaA.; UMANSKIY, M.A.; EMM, S.N.;
I'd , A.S.; MALOVIUKO, A.Ya.1 FIVCHIKI DaT.
I f
]!~Ottqt of andaxin on healtby people. Vrachdslo to.1102+9-150
x 169. (MIRA 16s2)
1. Kafedra torakallnoy khirurgii i anes-tesiologii (zava - profo
N.M. Amosov) Kiyevskogo instituta usovershenstvovaniya vrachey,
(WROMIATS)

BRATUS' V.D., dots., otv. red.; pj4oSOV$ N.M., prof., red.;
K0jV4IycHENKO, M.I., prof., red.; FEDOROVSKIY, A.A.t
prof., red.; TUROVETS, I.G., prof.) red.; KLOCHKOV, I.Ye.,
LEVCHUKp G.A., dots., red TRESHCHINSKIY A.I.,
CHU~~-pL---
dots., red.; . 4
dots., red.; KOCHKOVI I.Ye.j red.;
[Problems of anesthesiology] VOPrOsY an6stez'ologii. sbornik
nauchnykh rabot, posviashchennyi 70-letiiu so claia rozhdeniia
chlena-korr. AN USSR, zasl. deiatelia nauki Prof. I.N.Ishchenko.
Kiev, Gosmedizdat USSR, 1963. 254 P. (MIRA 16:7)
1. Kiev. Medychnyi instytut.
'H
(ISHCHENKO, IVAN NIKOLAEVIC , 1891-) (ANESTHESIOLOGY)

URAVSKrL, M.A.; TRESHCHEISKIY, A.I.;LOBODYUKV M.S. (Kiyev).
Use of protamine sulfate in surgery with artifimil blood
circulation. Vrach. delo no.11:133 N'63 (MW 16t12)
1. Klinika torakallnoy khirurgii (zav.-chlen-korreopmdent
AMN-SSSR, prof. N.M.Amosov) Ukrainskogo a.stituta tuberku-
leza i grudnoy khirurgiio

'Muc, doktor xed.nauk; CHEPKIY, L.P., doktor med.nauk;
NIKOLAYEVr YU-A-,, kand.md.nauk
Book review# Ekisper. khi-r. i anest. 9 no.5.*95-96 S-0 164-
(MIRL 1811l)

TREJcHCHINSKIY9 A.I.; LYAVINETS, A.S.
I I;- --.- - . . -
Review of Jiri Pokorny's book "Controlled hypotension in anesthesio-
logy. Eksper. khiro i anest. 9 no.2:94-95 Mr-AP 164. (MIRA. 17-11)

Lid. M A- Ill":;
vp-r;tion of 1'6 f c j 1
lysi,, in -,urg(-,rY `di'~' L"'t
IE4.
93
i
n
c c)jj?ji3 c.,
It za

0, T.M., yr:~f. .),
DARBSITY,
UVAROV, B.S.)
fjjjji~=Lntalo aj,-d
Scuv.flli~d.
,Y

'Sn'CHUrNIK ,
- --- Tivn I- Ii.- - -
"Accountants of the Collective Farms Learn." p. 2?,
(GOOPERATIVU0 =,DELIE, Vol. 9, No. 10, 1954, Sofiya, Bulgaria)
(EE.T
SO: Monthly List of East European Accessions, "), LC, Vol. 4
No. 5, May 1955, Uncl.

- . I , I. ., .
Dissertation- "Interaction of Uxea vith .1--mmorlitua Calki Cher; '-oscow
Acadpmy of J'*;-Iculiure irenl H. ;'--. TI:-Arya-zev, ~-'Oscow, 1953. --,efc-rul.ivr.T,' hllrnl-.l--
aimiya, i;-oscow, I*:o 7, -%.rr 54.
SO: 'Al-I 28/,, 26 Nov 195/,

RAOHIIISKIY. T.Y., doktor khIm.naukj 3AWOHOV, A.G.; K(WIMOT, I.Y.
(Handbook on the use of isotopes and radiation in agricultural
Praktikum po primeneniiu izotopov i izluchenii v sel'skom
khoziaistve. Pod obahchei red. T.Y.Rachinakogo. Moskva, Hook.
sellkhoz.akad. No.5. [Radiochomistryl Rediakhimiia. 1960.
98 p. (MIRA 14-.4)
(Radioisotopes) (Agricultural research)

LEvINA, R.Ya.; SKVARCHEMO. V.R.; KTJZIMIN, M.G.; EIZSHGHOVA, Ye.G.
Synthesis of hydrocarbons. Part 17: Partial reduation of hydrocarbon
dienes with conjugated double bond systems usiig sodium in liqui&
ammonia.-Shur. ob. khim. 26 no.8:2195-2199 Ag '56. (HLRA 10:11)
1. Mookovskiy gosudatetvennyy universitet.
(Olefins) (Hexadiene)

ISVIHA, R.Ya.; KIM DYAY GIR, SMIRNOU, E.N.; ORWVA, H.D.; TRESHCROVA,
Ye.G.
Synthesis of hydrocarbons. Part 59: (0,1,3)-bic7clohexanes with
two quaternar7 carbon atoms. Zhur.ob.ldiim. 27 no-7:1779-1783
Jl '57- (MIRA 10:10)
l.Moskovskiy gosudarstvennyy universitet.
(Bicyclohexane)

YUR!-Mr, Yjj.K.;.KVANTSOTA, N.N.; MELMIYEVA, T.A. TRESHCHOVA, Ye.G. ..
The chemistry of selenophene. -Part 7: Synthesis and acetvlation
of 3-arYloelenophenes and 2.3-benzoselenophone. Zhur. olb. kmm.
27 no.8:2260-2267 Ag '57. (MLRA 10-0)
1. Moskovskiy gosudarstvennyy universitat.
(Selenophene)

C4-', -Al
LEVINA, R.Ya.; SHABAROV, Yu.S.; DAUKSHAS, V.K.; TRZSHCHOVA, Ye.G.
2.4-Dimethyll-pentadlene-1,3 in the synthesis of alkanes with two
quaternary carbon atoms separated by a CH9-g-roup, (ditertiary
41kyljqethanes). Dokl. AN SSSR 113 no.6tl286-1289 Ap 157.
1. Predstavleno akademikom A.N. Nesmeyanovy-m.
(Paraffins) (Pentadiene) (Methane)

lz.:p

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Determination of mAccular composition and of druc-
tural elements of organic compounds by the method of
CADinbined ges"cring. E. C.. Trchchova, 11. A.
ALI-Jiln, and V. M. 3,

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ZMHCHGVAl Ye. G.. ,
Treshbhova, Ye. G. - 11 Combination scattering spectra of aromatic C8 hydrocarbons,"
Vestnik Mosk. un-ta, 1948, No. 11, p. 149-513
So: U-3566p 15 Marph 53, (Letopis 'Zhurnal Inykh Statey, No. 13, 1949)

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a
00
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-7 1 IdW
to
Combb" Diffadw NoWra at C Arsow4k H d
and 7,
carbeeks. (In Rusalan.) Z 0, TrwActwo M,
Tatevskil. Dokk4y Akodswii N"tk SSSR (Reports
of the Academy of Sciences of the USSR). v. $1,
Aug. 11, 1048, p. 941-844.
The above were studied for othylbensent and the
three Physlewhecalcal constants were do.
termill"n insthods of Invest1gation am de-
scribed. Data an tabulated and Xrophed.
400
'04
000
it
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# 14 .0

TRESHCHOTTA I Ye. G
FA iU/491"k,
USSR/Chemistry Organic Conpoundq Determination of SOP 48
Aromatic in Gasoline
Chemistry Analysis,, Spectrochemical
"Quantitative Determination& Aromatic Hydrocarbons C6-C8 in Cracking Gasoline by the Method
of Combined Dispersion of Light," It. D. Tilicheyevp P. A. Akishin, Ye. G. Treshchova, V. M.
Tatevskiy, Can Inat of Aviation Fuels and Lubricants and Moscow State U, 8~ pp
"Zavod Lab" Vol XIV, No 9
Measures frequency and intensities of lines in combination dispersion spectra of aromatics-
ethylbenzene, c-, m-, and p-xylenes. Demonstrates possibility of determing these aromatics in
cracking gasolines in the presence of alkenes by this method for 60 artifical mextuxes. Con-
centration of individual compounds varied 2 -40%.
16/49T26

USSR/Oba~nlatry - Hydrocarbons, Aromtio
Chemistry - Hydrocarbons, Faman Spectra
Aug 48
"Spectra of the Combined Dispersion of Aromatic C8
Hydrocarbons," Ye. G. Treshohova, V. M. Tatevskiy,
Moscow State U imeni, M. V. Lomonosor, 4 pp
"Dok Ak Nauk SSSR" Vol LXI, No 5
Ihmn spectre, of following hydrocarbons with the pu-
rity indicated are reported: ethylbenzene 99.4%,
o-xylene 98.4%) m-xylene (purity undetermined) and
p-xylene 97.2%.
-am . 24/49r17

TIU;SHOEOVA, Ye. G.
USSR/Chemistry - Synthesis
Chemistry - Bonds
Jan 49
"Synthesis of Aliphatic and Paraffin Hydrocarbons: VI, Diene 1~ydrocarbons in the
Synthesis of Olefin Hydrocarbons With the I)ouble Bond in the (~,nter, " R. Ya. Levina,
V. IL. Skvarchenko, Yu. B. Kagan, Ye. G. Treshchova, Lab of Org Chem imeni N. D. Zelinskiy,
Moscow State Ord of Lenin U, 6 1/2 pp
"Zhur Obshch Khir!" Vol XIX, 1b 1
In the reaction between allyl halides and organom-nesium compounds used for preparing
1-alkenes, the double bond causes an exchange of the halogen for a radical. In present
study, l,it-dichloro-2-butene and its bromine analogue, prepared by halogenation of
1,3-butadiene, reacted with methylmagnesium bromide or iodide. Both halogens of these
compounds were substituted by methyls theoretically forming 10% 3-hexane in the case of
dibromide and up to 40% in the caso of dichloride: 1,3-butadiene viis formed- as a by-
-!ppoduct, 'Die 1,2-dirhloride of butadiene undergoes an allyl rearrangement to a
1,4-compound, and subsequently forms an alkene with the double bond in central position.
Submitted 29 Oct 47.
58/49T42

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69840
Z713100 S/051/60/008/03/015/038
E201/E191
AUTHORS: Treshchova, Ye.G., Panchenko, Yu.N., Vasillyev, N.1.5
--h~m [nTG., Shabarov, Yu.S , and Levrn--a-
, R.Ya.
TITLE: Raman Spectra of Hydrocarbons of Various Classes. VI.
The Raman Spectra of Some Arylcyclobutanes I
PERIODICAL: Optika_i spektroskopiya, 1960, Vol 81 Nr 3,
pp 371 375 (USSR)
ABSTRACT: The authors investigated the Raman spectra of
phenylcyclobutane and of the following aryloyclobutanes:
m-toiyicyclobutan , n-tolyleyclobutane, o-anisylcyclobutane,
n-anisylcyclobutane; for the sake of comparison the Raman
spectra of pheny1cyclopropane and n-tolylcyclopropane were
also obtained. The apparatus, the experimental technique
and the methods of calculation were the same as in earlier
work (Ref 6). The results are given in Tables 2-4, and tha
properties (such as the melting pointg refractive index,
etc) of the four arylcyclobutanes and of phenyloyclobutane
are listed in Table 1. The Raman spectra of all four
Card arylcyclobutanes included frequencies characteristic of the
1/2 appropriate mono- and dialkylbenzenes and alkykcyclobutanes.
The intensity of the Raman lines characteristic of the

69840
S/o5l/6o/oO8/03/015/038
E201/E191
Raman Spectra of Hydrocarbons of Various Classes. VI, The Raman
Spectra of Some Arylcyclobutanes
four-member cycle and of the benzene ring (lines in the
region - 1000-1600 cm-1) is greater in the spect,-"a of
arylcyclobutanes than the intensities of the
corresponding lines in spectra of alkyleyclobutanes and
alkylbenzenes. This behaviour of the intensities was
Card not observed in the case of lines at - 600-800 cm-1)
2/2 which are characteristic of the benzene ring.
There are 1+ tables and 7 Soviet references.
SUBMITTED: July 3~ 1959

LEVINA, R. YA. ---- SHUSHMINA, N. P. - TRESHCHOVA, Y,;7. G.
Hydrocarbons
Synthesis of hydrocarbons, rart 16. Synthesis of 2, 3, 4-trimetbylhexane, an isononane.
Vest. Mcsk. un. 5, no. 9, 1950.
Montlily Ust 2f Russian Accessions, Library of Congress, October 1952. MiCLASSIFIED.

TRESHCHOVA, E. G.
Levina, R. Ya., Skvarchenko, V. R., Treshchove, E. G., and Tatevskii, V. M. - "Synthesis
of hydrocarbcns. IX. Diene hydrocarbons in the synthesis of olefinic hydrocarbons
with a central double bond-." (P. 41P)
SC: Journal of General Chemistry, (Zhurnal Obshchei Khimii), 1950, Vol. 20, No. 3.

TRESHCHOVA, F, G.
4W.
!A
X. Partint rpilaction of maJuRated-
in it ind ammonia, I( IT 4;v na,
V. 11. Mv.1171INIKO, V. I'll In"!V9 JIM'. G- PrP41,11ova
ff. A., 19,50, 11, 175).-Tartial rellitclion'fif It%, Na in
liquM N11, afford:t a niNture of fliv. I -. 2- -.in([ I , 11-dilivilro-
and (Y.111U), 05--
Iftn,l ii thns miquitable for the prep, (if Ow latter
analysi.,i (detail-, given and disciism)) Imik-s-4 Mil, lir, it
cis. (30*1%) and Itans-formr, (70%). -,vrith. .-I,
for comp: rhon pitrpo3c.4, from I iml CAM; Isi.
I
mixture of rit- ('20%) and Impas-form-i
Slow additirin of (11; g.) is) I;t,() tv Na [ W; j,) it)
liquid Nil, at -50* to -~M', tirring 1,,r 5- 6 )or,, ;still I' -,piog
overnight afford a prothict. C,11, j;3':'), 1, Ii, 67-67-5, i7i;l min..
dil 0,INW-to".1 I-3062F(ri,il li,im Larfw,~
which ig analysed sprt:trograplii~ Alv ti,.mum-p, ti.fl hr. llm-
fats:,d), War tin n I-I f q, 1. 11 C I V 1: 1 V, . 1. i, 2 -
e n e 1). 1. S. 1-j 74.11 m ni., 1 0 - 9 2S2, ,;:, 1 .4. 1. 1, 1,, st I -
ene: b.11). fi.l*i7-18 mm., d,11 089,10, ni'l 1--tt"141 : 1-til i-mvl w(
with EV%1gl1r in 1--t20 in III,- ii,ital matmer oll't id,ofl,,a
produds., ViZ., In XeLl rii aml to ritc-hrx-2 eno k1s, 1.7 S 1.7 7
i
7,18.5 min., do' 0-6805, till;' I PHO. I

TRESHOROVA,,S. G.
Synthesis of hydrocarbona. XI. Partial reduction of conjugated-diene
hydrocarbons by sodium in liquid ammonia* Re Ya. Iffvina,, V. Re 5kvarchnrJ-.,),
E. A. Viktorovaj. V. Me Tatevsky* and E. 0. jreshcbov~ (J. gen. Chem USSR,
1950, 20, 690--696 (U A. transt., 727--732); cf. preceding abstract;.
Partial reduction of iCYA2:CR)2 by Na in liquid NH3 affords CHBu'tCH82 (73%)
and confirms that under these conditions 1 -. 2-addition of nascent H prefer-
entially occurs (and not 1 r. 4-addition as thought kItherto)e
Isomerisation Of Cb2'-CH6-(CH2)2-CI46:Ch2x bep, 3.13-114o/ 755 mm., d 2/40
0.7505,, n 2/dO 1.43o3 (from CH2:CFb CH2C1 and Mg) over Cr203-A1203at 2500
gives (CMe2tCH)2 (83%)s b.po 134--134-5'P/ 747 Imes elo 0-7636, 1-4760,, which
on addition to Na in liquid Wf3 at -- 500 to -- 600 (5 hr.),, and then at room
temp. (overnight) affords CHBuItC1462 (73%), b.p. 111 2 -- 111 5 /747 Mm., d2/40
0-7182, n 2/40 1-4120. The structure of this is proved by Ramanspectral
analysis and by ozonisation (with 6% 01; CHC12 solution) which gives acetone
peroxide, m.p. 130#5 -- 131#5 , and Bu C02H, bepe 1740 tphenylphenacyl ester,
mep, 77 a q Be S. Siren

TRESHCHOVA, Ye. G.
USSR/GhemiBtry - !~vdrocarbote
May/June 51
"Synthesis; of Hydrocarbons. Communication No 25: Synthesis of Alkenes With a
quaternary Carbon Atom by Pyrolysis of Acetates," -1. Ys. Levina, A. A. F-aynzill-ijerg,
T. I. Tantsyreva, Ye. G. Treshchova.
111z Ak 1'auk SSSR, Otdel Xhim Nauk-," No 3. PP 321-327
Describes application of method of acetate pyrolysis for synthesis of 4,
4-dimethylhexene-2, Established (with aid of spectra of combination light dispersion)
that pyrolysis of acetic acid ester of secondary alc of pinaeolinic typo
(4, 4-dimethylhexanol-3) leads principally (to extent of 96% of total) to
formation of trans-form of the alkene, I.e. substance that has same carbon
skeleton as initial alb.
183T13

TRESHCHOVA, Ye. G.
USSR/Chemistry - Petroleum Hydrocarbons
"Isomerization of Unsaturated Hydrocarbons Through Their Contact With Oxides of Kettals.
XII. Production of Methylpentadienes by Dehydration of Dimethallylcarbinol Over
Chromium Oxide on Aluminum Oxidej" P. Ya. Levina, A. A. Faynzillberg, V. M. Tatevskiy
Ye. G. Tre~shchovaj Lab Org Chem Imeni., Acad N. D. Zelinskiy, and Lab 1,11o1 Spectroscopy.,
Moscow State U
"Zhur Obahch Khim" Vol XXI, N 2x pp 233-239
Dehydrated dimethallylearbinol over nixed catalyst of Cr and Al oxides to yeild
2-methylpentacliene- 1,4 (1) and pair with close bp composed of 2-methylpentadiene-
2,4 (11) ard 2-methylalyst of Gr and Al oxides into mixt of II and III. Yield 59%
of theoretical. Compn checked by Spectrography. Mechanism proposed.
176TU

TRESHCHIEWA, Ye. G. Feb 51
USSF/Chemistry - Petroleum Hydrocarbons
"IBomerization of Polymethylene Hydrocarbons Under Influence of Alurdnam Chloride.
XVI. Isomerization of 1,-l-Dimethylcyclopentane,," N. B. Turova-Polyakj, V. A. Adamova,
Ye. G. Treshcheva, Lab Org Catalysis, Moscow State U
"Zhur Obsheh Khim" Vol XXI, No 2, pp 250-255
1.,l-Dimethylcyclopentane mixed with aluminum chloride., thourh unreactive at room temp,
was coverted into methylcyclohexane with yield of 92-97% after 10-15 hr heating at
100-1150. Presence of quaternary C atom in 1,1-dimethyleyelopentane did not impdde thi s
isomerization.
176T14

TFFZ-H,MGVr~) E. G.
"Isomerization of Polymethylere Hydrocarbr~ns under the Influence of _Alum-in=
Chloride. XVII. Isonerization of IMethyloyclohexare, 1, !-Dime thyl cj clohfxare ~
1,2-Dimethyleyclohexane and EtIvjlcyclohexare." by F. D. Zelllrs-y, le'. B.
Turova-Polyak, E. F. Tsvetko-va, and E. C. Treshchova. (p. 2156)
SO: Journal of General Chemistr -
y (Zhurnal Obshchei Khimii), 1951, Volume 21,
no. 12

TRESHCHOIVA, E. G.
"Some New Data on the Isome.rizaticn of Cyclohaxare by Alizninum Chloride."
by N. D. Zelinskyp M. B. Turova-Polyak, N. F. Tsv,-.tkova, and E. G. Treshchova.
(p. 2160)
SO: Journal of General Chemistrff (Zhurnal Obshchei Yhimii), 1951, Volume 21,
no. 12

UM/Chomistry - Axxtiknock Fuels Oct 51
"Spectra of Coubinstion Scattering of Certain
CB-Cll Isoalkanes With Tertiary-Clarbon Atoms,"
To. G. Treshchova, V. M. TatevskAy, T. I. Tant!
eneva, A. A. Fayuzillberg, R. Ta. Leirina, Mos-
cow State U imeni, M. V. Umonosov
"Zhur Piz Xhim" Vol XXV, No 10, Vp 1239-3247
FAmurements of mmber and intensity-of lines
in-spectra of combination scattering of 2, 4-
dimetbylhexane, heptane, oatazte, and nonsne, 2.,
4,, 5-trimethylhexme, 2, 4, 6-trimettylbeptane,
and 2, 4, 7-trimethyloctane, in agreemint, vith
154T18
VSSR/Chemistry- Antiknock Fuels (Contd) Odt 51
1
theoretical conclusions of B. I. Stepanov, showd
that different types of branchings of k1kene C
skeleton are represtn~ed by sp chaxacteristiefF Of
spectrum.

N.P.; TRISHCHOTA, A.G.
...- 1. ..
Synthesis of hydrocarbons. IXX. Synthesis of 3.5-dimethylhaptane.
Testuik Moskov. Univ. 7, NO.2, Ser. Fis. Mat. i Zatootven. N&uk
No.1, 105-8 152. KRA 5.,7)
(CA 47 no.13:6333 153)
1. Moskovskiy universitet.

TRESHCHOVA, Ye. G.
USSR/Chemistry-Hydrocarbons
Feb 52
"Synthesis of Hydrocarbons. XVII. Homomesitones in the Synthesis of Isoparaffinic
Hydrocarbons," R. Ya. Levina, N. P. Shusherina, Ye. G. Treshchova, V. M. Tatevskiy,
Lab of Orp Chem imeni Acad N. D. Zelinskiy, ~bscow State U
"Zhur Obshch Khim"Vol. XXII, No 2, pp 199-208
Developed method to synthesize difficulty obtainable isoparaffind 3, 5-direthylheptane
(1) 3-methyl-5-ethylheptane (II), 3-methyl-5-ethyloctane (III), 3-methyl-5-ethyl-mnane
(IV% 2,, 3, 1+-trimethylhexane M., 3, 4, 5-trime thylheptane (VI), none described in the
literature. Synthesized I-IV by reaction of mixt of "hommesit6nes" 3-methylheptene-
3-one-5 and 3-methylheptene-2-one-5 (products of condensation of methylethelketone with
CaC 2) with org Mg comrds, then dehydration of products (unsatd tert alcs) and catalytic
hydrogenation of resuiting diene hydrocarbons. V and VI were synthesized in same way
with exception that "hommesitones" in this case were 3, 4-dimethylhexene-3-one 5, and
3, 4-,dimethylhexene-2-on6-5 (products of condensation of methylethylketone with 11CD.
209T14

5(3) SOV/70/-29-7-24/83
AUTHORS: Radzhabli-Seidova, 2.1. A., Khromov, S. I., Gitina, R. E.,
Balenkova, Ye. S., Treshchova, Ya. G., Kazanskiy, B. A.
TITLE: Contact Transformations of 191-Dimethyl Cyclohexane and
I-ethyl Cyclohexane in the Presence of an Aluminosilicate
Catalyst (Kontaktnyye prevrashch(?niya 1,1-diretiltsiklo&eksana
i 1-metil-i-etil-tsiklogeksana v prisutstvii alyumosil-4katnoGo
katalizatora)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 7, PP 2.212-2218 (USSal)
ABSTRACT: The numerous Russian petroleum types contain among other
cycloparaffin hydrocarbons 1,1-dimethyl cyclohexane and
100-trimethyl cyclohexane (Ref 1). According to reference 2
also the transformations of 1,1-dimethyl cyclohexane at 5400
over an aluminosilidate catalyst are described. For the
authors it was of interest to investiGate the behavior of the
most simple mixed methyl alkyl cyclohoxanps in the oatalytic
cracking process over an alum-Inosilicate catalyst. For this
purpose the behavior of 1,1-dimethyl cyclohexane and I-methyl-
1-ethyl cyclohexane over the above catalyst i,.rero inveotigated
at 500 0. In this connection gaseous product-, a liquid
Card 1/3 condensate, and coke which separated on the catalys" were

Contact Transformations of I,I-Dimethyl Cyclohexane SOV/79-29-7-2A '183
j
and I-I'lethyl-I-ethyl Cyclohexane in the Precence of an AlurtAnos'llicate
Catalyst
obtained. The gaseous products were first fractionated at low
temperatures and then determined. The liquid condenuate
subjected to an accurate rectificationp chromato-raphic
U
adsorption on silica gel as well as to optical and chemical
investigations. The following per cent composition of the
reaction products of 1,1-dimethyl cyclohexane were found:
hydrocarbon 21-4%s liquid paraffin hydrocarbons 2.6%,naphthene hy-
drocarbons 844, aromatic hydrocarbons 45.2%, coke 22.4%. Por 1-methyl-l-othyl
cyclohexane (in wt--I,,): 10.8% gaseous hydrocarbons, 23-OFi,3' mixture
of paraffin naphthene hydrocarbons, 40.5% aromatic hydrocarbons,
25.7% coke. Under the chosen conditions of catalysis the
separation of the alkyl groups which are in the quaternary
cyclic carbon atom, hydrocracking process, methylation,
aromatization as -tell as the isomerization of the six-membered
cycles into five-membered ones take place. The main products
are aromatic hydrocarbons and in small quantities paraf"fin and
Card 2/3

Contact Tranaformationo of 1,1-Dimothyl Cyclohexane S0V/7q-2r"-7-'24/,U
and I-Mothyl-l-ethyl Cyclohexane in the ProBence of an Aluninosilicate
Catalyst
naphthene-hydrocarbons. The direction of the contact trans-
formations of the mixed dialkyl cyclohexanes are illustrated
by the scheme in the experimental part. There are 6 tables
and 11 references, 6 of which are Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet State University)
SUBMITTED: June 3, 1958
Card 3/3

5(3) S -_ -) n _ ~? _ ~' 7 11
, -, 1 6,
AUTHORS: liadzhabli-Se'idova, 11. A., Yhromov, S. I., Dorzhin, C'%. ,
Balenkova, Ye. S., Treshchova, Ye. G., Kazanskiy, B. P,.
TITLE: Contact Transformailo-ff-e-Cf-l--Ire-Wy-r~.1-propylcyclohexano and
1-Methyl-l-butyloyclohexane on an Aluminum Silicate Catalyst
(Kontaktnyye prevrashcheniya i
1-metil-l-butiltaiklogeksana na alyumosilikatnorn 11-a-talizatorc)
PERIODICAL: Zhurnal obahchey khimii, 1959, Vol 29, Ur 7, pp 221~'---72211 (USSI")
ABSTRACT: The authors continued their investigations (Ref 1) a-e'
synthesized 1-methyl-l-propyloyclohexane and 1-methyl-1-butyl-
cyqlohexane over an aluminum silicate.catalyst at 5~00; under
the earlier conditions also in this case gaseous hydroca.-bons,
a liquid condensate, and coke separated on the cr~taly:-,t viere
obtained. The gaseous products were fractionated at low
temperature by means of the apparatus ',"sIATI,?,',-rl-U and the
composition of the separated fractionn was determined by means
of the apparatus VTI. In order to determine the composition
of the condensatep rectification, chromatographic adsorption on
silica gel as well as optical and chemical methods were applied
Card 1/2 of investigation. The following wt% were obtained for the

Contact Transformations of 1-Yethyl-1-propylcyclohexane SOY/7/)--9'0-7-25/83
and I-Ilethyl-l-butyloyclohexane on an Aluminum Silicate Catalyst
transformation products of 1-methyl-l-propyl cyclohexane:
gaseous hydrocarbons 23.0'p"', liquid paraffins,5.9'pf,
naphthenes 20.5cpf, aromatic hydrocarbons 33-3/co, coke 16.5,Tf-
The following resulted from 1-methyl-l-butylc,Tclohe--cane:
gaseous hydrocarbons 30.6114c, liquid paraf-fins 4-8,0-~, naphthenes
17-0A", aromatic hydrocarbons 41-8ifa, coke 5.8%. The results
obtained*confirm the rules set up already earlier (Ref 1) for
the catalytic transformation of 1,1-dimethyl cyclohe;.anc and
1-methyl-1-ethyl cyclohexane. Also in this case the main
products were aromatic hydrocarbons. In the gaseous products
saturated hydrocarbons predominate (propane and butane). With
increasing number of the carbon atoms in the alkyl group of the
above compounds also the intensity of catalytic transformation
increases. There are 6 tables and 6 references, 4 of which are
Soviet.
ASSOCIATION: Moskovskiy Gosudarstvennyy univeraitet (Moncow State Uziivoruity)
SUBMITTED: June 9, 1958
Card 2/2

5 (3)
AUTHORS: Levina, R. Ya., Kaykaris, P. A. SOV/79-29--1-28/817
Baukh, I., Treshchova, Ye. G.
TITLE: Synthesis of Hydrocarbons (Sintez uUlevodorodov). LYIX. A New
General Method of the Synthesis of Di.neoalkyls (C., OLT22 - 01 2H26)
Dineopentyl and Its Homoloas (LXIX. !To,;-yy obshchiy put' sinteza
dineoalkilov (C1,H22_C12H26)-aineopenti1a i yeCo -omologov)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 7, pp 2236 - 2240
(USSR)
ABSTRACT. One of the ethylene hydrocarbons with a quaternary carbor-
(Refs 1,2), 2,2,5-trimethyl hexene-4 (II) synthesized by the
authors already earlier, was obtained by the reaction of pri-
mary isoprene hydrobromide with tertiary butyl magnesium
chloride (according to Grignard-ftertz). ThIs compound (II)
was used for the synthesis of the di;ficulti-y acccss*ible
paraffins which have two quaternary carbons separated by two
CH i.e. of dineopentyl and its homologs 'of the di-
2 grouPs' %
neoalkyls). Compound (II) was transformed by hydrogen chloride
Card 113 into the saturated tertiary chloride (III), which ~Was caused

Synthesis of Hydrocarbons. LXIY. A Nev Genmr-1 M_-t:io,,_, SOV/70-2'3-7-2~C/83
of the Synthesis of Dineoalkyls (c, H - C H
10 22 12 26)v
Dineopentyl and Its Homologs
to react with alkyl magnesium bromides in the vresence of
HgC1 2 (Grignard-Wuertz reaction) and led to co-mpound (IV)
(Scheme 1). In the reaction of tertiary claloride (III) with
alkyl magnesium bromides also side-reactions 4,*,oolk place: the
separation of HC1 from the tertiary chloride (re-formation
of the initial-2,2,5-trimethyl hexene-4(5CF/M, which was then
reduced into the 2,2,5-trimathyl hexane (Scheme 2). This mix-
ture of dineoalkyl and the lower boiling trimethyl hexenc and
trimethyl hexane which is obtained in any case was separated
by fractional distillation. The dineoalkyls purif4ed by a
further distillation and by methods of chromatography on
silica gel resulted in yields of 10-16~;4, computed for the
tertiary chloride (III) used for the reaction. The Raman spec-
tra confirm the presence of quaternary carbon atoms in them.
By the method of the "Grignard-Wuertz reaction carried out
two times" the authors synthesized the difficultly accessible
dineo entyl (2,2,5,5-tetramethyl hexane) and its hoinolo-s
Card 2/3 p t~

Synthesis of Hydrocarbons. IaIX - A ITev Cencral Method SOV/79-29-7-2rj/83
of the Synthesis of Dineoalkyls (C 10H 22 - C12 11 26)1
Dineopentyl and Its Homologs
0
C11H 24 and C12H26, 2,2,5,5-tetramethyl heptane, 2,2,5,5-tetra-
methyl octane, and 2,2,5,5,6-pentametliyl heptane which have
hitherto not been described. There are 1 table and 12 refer-
ences, 3 of which are Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet (moscow state University)
SUBMITTED: June 27, 1958
Card 3/3

Chemical Abst.
Vol- 48 No- 5
Men 10, 1954
Organic CheMiStZ-y
-The- 16ydrobtomide
S-putadiene an
a 3 peutsdWo In the thesis of hydroearb
is. abucture. . Y&. A. -A. FaInzil g,'
B~."'vvktl MYT."WI J5 um I GFUN) "Min g IN -'ufl-u- n' A a t I o W
2P . ~ %
See C.A. 47, Si. . Synthows of Gagues "d
_Wbou atom. R. Ya. Lei
-alkuex. With. a qyflomary
Tanta a "an'd V A.
oscow). Md. 635-9.-See -MT.- IT
267 den of dieve hydrocarbons In
267
the syntheals a ole Ic and paraffinic hydrocarbons with!
IC
:4 quaternuffy carbon atom. R. Ys. Levine, and X. P.,
S1 usherina.v Ibid. 641-O.-Sce CA. 47, 2Mh. 'XW.,
or- *- diene hydrocarbons into cyclopropanl>
- Ya. Levlaa and B. M . Gladshtcln.,
'hy4f- ' a
Aid. ~~ ~5 -~- q
Y 2 ~q -,L
ICY

Classes. 111. Cffhf1bWr'j'r*S~V1A Spe-tra of kwyerill
"~ it 10rulg
alkadlenes with a system of isolated or conjup4ted double
bondg. Ir-. G. TreAschoya,'V. M. Tatcv5kij,"A, Ya.
1'gyina C Ianti -r__ A. Vik-tor va
Univ.,
12136-71(1952); cf. C.A. 43, 7_TWn(l9t9).-IZam;m spectra
have been 5tu(Rd of (1), 2.
methyl-2.4-pentalliene (11).
rl ji2,1 "tadicne (IV), 2,4-octadiune (V), avd 2,4.
R, b.p., P81,4" and (1.1* ill that order Luc
.f.' 50.5', 1.400, 0.6932; It. 70.3', 1.1520. 0.7101;
ill, 68.6% 1.4390, 0.7262; IV, 105'. 1.4-177, 0.73-23; V,
132'. 1.4W. 0.7439. Wave nos. and corresponding in-
tensitics for I-V are tabulated between 240 and 3131 cm. -1
The characteristic lines of 11 and Ill are 1630 and 1645-1
qn.-1, resp., with intensities of 678 Ond 1061) units, resp.
IV has 2 characteristic lines at 165ri and 1653 cut.-' with
#intensities of 1200 and 1050 units, rt~sp. It is concluded
that in the 16W-1680-cm.-I region alkaditates with i5olated
-double bonds have either 2 lines or a single line, the total
intensity being about twice that of the corresponding al-
acteristic lines in the 1600-1680-cm.-t
keite line. The char.
region of alkadicues with coujugattd double boads are
stronger :iarl those of n1kenes. IV, V, and VI have spectra/
Valmost identical ill %Yave ;,.is- and rather sitniLr in rda-
tive line hitersities. J. W. L., Jr.

LEVINA. R. Ya.; TANTSYREVA, T.I.; VINGGRADOVA. V.N.; TRESHCHOVA, E.G.
Cyclopentadiene and cvclohexadione in the Bynthesis of bicyclic
compounds. Doklady Akad. Hauk S.S.S.R. 85. 107-10 152. (MLRA 5:8)
(CA 47 no.15:7448 153)

Synthesis of hydrocartwnq. XLIjT. Patle! re-d-tion
(f diene hvdrocarb-oiis with -onjt:Cztr-d cf
~Ond.i bv v dium Li lipud xr-m~nia
if
.,W ,f H
4-f
id
t IF~,nuc of 'l- '-tHllliqr;1 i~ tb,
17 hich zL- f-t;--i

USSR
qpmyu&'= of the darivati-Ifis of Cictfritme an 91=L80-
Puma estalpt. K. V. Topchieva, . . RosoinvskmA, E.
0. Treshchava, S. S. Ncrikov, aM S. 1. Khmmo, - VirilQ
M01*40. Un~r. 8, NO. t2, F&.-M41. i atCnWP- NCO NO. 1%
iwprwylC7C!Gpeutane (IV).
1mtYtCyclGp!= V) uMerito thermM decompri. on tech.
At-silks catelyst (4) at NO A: 10. 1 and 11 uuderto rAt-
lipliechanges. EEI yields a. tow-ne, kepetnae'lasmw
tiokaowa hydrma~-bom. IV gave detivs. o( cydoh"s=
(~S%Nt. V gave a inixt. of monc~ and trisubstittsted derim
cif C4H* (60%), and afso dexive. of cyclulientane. For each
expt. 04 ml. of VI was used, and the hydrocasbons wem Im-
troduced into the quartz tube at a vc4. velocity of 0.5. VI
6 emfed in air at WO', and it3 activity standaftlizedl
(Cminik Moskov. Univ. J. No, 11, 1-Ti(IfI48)). M. R_- -

TR E S HC H 0 V0% G.
Synths;.; of XYXIX. 'rite '11'.00 ~fr. d
kc-alioll of tile dratOr-l"Id.
A olld
i ZI
c.J . 4 5, -18. 3."_!A~
d~,s lint affecl tiv. Nirld of tll,., jm.ftj~ t; vi Ii.,rioAin!:ilIt3;
bent ruji at -75* ill -11"i. 1?1~1) lollif ill.- I ill
wt. was renchul, and mt of Ow :riIvvt,i rave 321.",
dithfaride (11). bi, Ful -I". Ill. amf :11q, .1
fraction and mwItim*,d I To fromllf2li R.
IlA. T',W) V-v; ;Iddcd -t ith , ot'li'll: AO P,, I'lld
tilt: Illixt. allowed to (,,,I mgIll. (!ht,. ;It rooill
ternp, aisd tcfltj%t-,l 2 lu,-, du-mvit. with It)"," Ac( Af g.%%,-
101,1, 1 asid 23c1', 111.5" b"..,
'p, 't-o'
colitailled (Im follmi,iol- fill,-.: , :'-'I), 31;~,11),
t21(0.5, 4Ar4O.S), i )1 2)
7-11;(0), 7110i 0 5), S-Wi L.5). 907(0),
012(1)), %48(3.5). KOO), P9S( lills( 1) 5).
li(ho II'l 1( 1). 1 5), 1 11W( C"'.),
IZ37( 120 2 , I I l9f M),
1610(0.5) and The Will Nuc imli,.m.z .111 im-
purity of at! -etlivI,nic h%,fr--;Mu)tj. Pt%IrlIr (from
123 9. PrFir) with 4i.5 L. It --im'Hark. gavv ,, ie 1, 171",
Ilexane, and 11% b:,, -11.1 1.2
it',' IAMO. (1-1 fl.77S-2. Pain:111 (I-m. I) 276(l),
TWO.5), .1 W( 1), 191( 1), 5'-''( 1 r~~Ji(
013 0,5), 69r4l.5), 7.'i1-(C.;,), IVNI(l), 792(l),
821(2 r-1, R7.'(J_), SO~Ol, 1), 9F,rl( 1), 999( 1),
10r,(X 11, Ill 1~~ 11 , IIN511), 1102(.0. 1133(0 .), 117f)(0 5),
119,14 1 _r, ,I. 1~ II(D. 1,290(1,5), M01(2..5), 1329(f~5). MS2(3i,
14(11~f I i, III lot. Ili,] 1611.-,1, 10 .
Tltr -,ITI-~ i IW~10 admixt. If tilt -etlIvIi,nic
17,11- ll,A i,,131 ba,t, f.rowd by idlyli, Olift of t1w
io I - I!: d-i,. duri,,g th~
to (ClIXIl'), ill that Illcir

diChloridtH Yield Ou by-prodimtj with jtj%jgx
MA. 46, 3941i). XL. Reaction of the dichloTide o!
cy;topentadiene with UgaaamAguenjuja-compound'. R.
Yd. and F- G. I'mbdinya.
Aid. 729-'45.:'-T~ 2-j." (1) in I Vol
EtIO was ad0d with eAA~i7 3.5.4 Z~ Cl; distn.
g-ave dichloride, C,J1,Cjj (Immimably the 3,5-Cl-
comiul. although dw might 6i pmwnt), h, 3.1',
b,, 50 " n, I' 1-219", 'Imkca, inairamil-Vell ill N'
MIMI high-buitiltp" l1lattvr wa~ al'st forim-A. To 'At,'AgRr
(from KNJ g. M03r) vfltl~ icv-NAA voolitig 120 g.
of the dichlori&' th! alt%(. ~tivuil !" hm. at rwin
tetnp- ant: 4 lirs. ;It rf'tjljX~ Ovecalipri. with (lit. At:011
all([ distu. over Na gave. 20e~fc, C11111, compossed uf some
CO-70% j,5- and which
r"llited (14)[11 allyli~: Mlift Ituriog thq rk7artjntt~ 'I'lle mixt,
coald 1, 1 Ix'Icild, in to Cam PrIlleff (,,I Ild the Whote
(1-,) 0.7614, The pmune,, of Ov, Raman litm
at 1613 cm." indir!ated tile evc1opr1itcIle structure witil
Thamixt.hydrogenaml
over M-AIA at 150' i mixed 1,2- and I .3,linrethyl-
cychypentaper, b,,, 111, 1.4113, (1,, 0.7-1.57;
the compiv of the mixt. tvai de,hictnt from known consts. of
tile ingreditits (BazImlin, c1 at., C.A. 42, 0238i: Kazamikil,
cl al., C.A. 42, -1535b). Similarly 1-.*tNlgBr gave 12%
tnixrd 3,1 and b;,I 140.3', n2l,'
1.4390, d, 0,7922 lit i:, miyp:Acd that 'Im suppmedly purc
3,54-rt"d1criv, cited 1) 'v 13:0wr mid Fjiglkh. C.A. 46,
440g, i,; altu a similar mixt.l. and 6% 3-c1hyleyclaprnicne,
1110 117', 1.4311), d~ 0.792-4 ( C.A. 47, 3248c). PrMgBr
gave apparently only .7-propy1cych)P~aIrpte (although some
4-11T analug might have buun pic~cnl), b,, t25 , n',* 1.4VO
"
-
701S
i
7
0
idd
1
s
l
ll
,
.
lw
.
c froll
,
l a pt-~Ilwt C
'Ill ;IT6 Il
,
% y
fi,rimition brmllidn;' whil-b
'
I
lyidl 11,0 yi~+i t6 t
tb'lV. (". M - - --

1EVINA, R.Ya.: TANTSYREVA, T.I.: TRESHCHOVA, Ye.G.
Synthesis of hydrocarbons. Part 40. Reaction of cyclopentadiene dichlo-
ride with organomagnesium conmounds. ZnLr.ob.khim. 23 no.5:729-735 my
153. (MMU 6:5)
1. Moskovskiy Gosudarstvenniy universitat. Laboratoriya organicheskoy
khimii imeni N.D. Zelinskogo. (Organomugnesium compounds)
(Cyclopentadiene)

TUROVA-POIPYAK, H.B.; SOGNINA, I.Ye.; TMHGHOVA, Ye.G.
a W"~- -
Inomerization of polvmetbylene hydrocarbons under the influence of alumi=mr.
Part 18. Inomerization of diayalopentyl. Zhur.ob.khim. 23 no-7:1111-1116
JI '53. (KLuA 6:7)
L.Kafedra organichaskogo kataliza Moskovskogo GoFmAarstvennogo universiteta.
(Isomerism) (Cyclopentyl)

Rio 1.44.110, A~0.7;i2 (R mi in fn~qnmcy 16V C;n 'I., lit 5-)
b", it 1~ 1. QOM d.. U.6135 (iUmsus
f,-.u,n~v ! 641 cm. -1). Cf. ~mold ind bowd;dl, (C A 42,
A 1, 'j, "I. X LII IA. ;Iew reactwa of t~~;mb-jdroph4halic
,,ahydridns (products at d;enL synthesis) witb phosphorus
S -it henko N. S.
Pentorific, R. Ya L~,ma, "k,
7
cf CA . 4 9,
99AW. 49, ~29,-The rtacti-wi of %,;irious sub'lltuml
1~trahydrophrh,dlc anhydride< ivith Ij,Oj d.~3 wit go tnmigh
oe Nmlalioa of a kcterm. and the decarboaylation step is
siiriultan~oug Tvith dehydration, in wimb (he -If at'.)mS
rarticipau. H~itfiig 20 g. 2,1-limethyl-I J-hufadl!mc
veith 31 g. omtmiit: ~nhydrjd-! in C41i. U fit., gave ::,3,(, 1.-
3.1hy-arr th- 75--
I. H~2 T~7is ~19 I g.) tr-,,1td 'will, 14 .1
,nd he:ittd g,-_~rttly. cntoz,,i a v,garou5 ru.,ptiun
(tetup. row to 2'Yj*); the mixt. %"s then h-ated ~:(,
a:I't finally t" 350" ywhiiog a di~tililite of 13.51~o PurL 1'_'j-
i.-, nethy!6ew-ne bh, TO, I ~vY.M. d~, O~S770~ the
P~_tvnw' also agTeed with Lit-it of tile purv Suit-
~ww~e. Na indicationi of ir,~sity!crv; or 1,2,3-trin-thyl-
!~nzen'.~ '-ere fottrid, If the re-amion wtnt through the ke-
3FIZI.. the Preievre of J1 ammi in tile I :md 2 p"'ition,

TRESECHOVA, Ye. G,
USSR/Chemistry - Hydrocarbons Oct 53
"Raman Spectra of Hydrocarbons of Different Types.! IV.
Raman Spectra of Some Branched Alkanes Containing
Tertiary Carbon Atoms,"~Ye. G. Treshchova; V. M.
Tatayevskiy, A. A. Faynzillberg,~'N. P. Shusherina,
R. fa. Levina' Moscow State U im M. V. Lcmonosov
Zhur Fiz Khim, Vol 27, No 10, PP 1564-71.
Detd the Raman spectra of 2,3-dimethylhexane, 2,3-
dimethylheptane, 2,3-dimethyloctame, 2,3,6-trimethyl-
heptane, 3,5-dimethylheptane, 3-methyl-5-ethylactane,
3,5-dimethylheptane, and 5-methyl-5-ethyloctane. From
272T15
the data obtained, drew conclusions on the frequencies
which correspond to definite types of branching.

~4 tqJE
'MR/Chemistry - Catalytic conversion
Pub. 40 1
.1/2 7/27
Authors I
Minachev, Kh. It.; Shuylkin, N. I.; Feofanoval L. M.; Treshchova, E. G. and
-Yudkina,- T*P.-
Title 1 Conversiona of n-heptane in -gresence- of metals -of- the Pd group at high
temperatures and hydrogen pressures
Periodical i Izv. All 35SR. Otd. khim. nauk 6, 1067-1074, Nov-Dee 1954
Abstraot The conversions of n-heptane over Ru) Rh, Pd and Pt contacts deposited on
silica gel was investigated at hydrogen pressures of 20 at, and temp-
eratures of 4600. It was found that the n-heptane, subjected to above
described conditions, experiences several deep conversions with a part of
it undergoing complete dehydrocyclization.
Institution Acad. of Sc.; USSR, The N. D. Zelinskiy Institute of Org. Chemistry
Submitted Februar-j 17, 1954

1-
T

ca. b.D
Xl'e 1

-VI

'Al C
WSR/Chemistry - Catalytic conversion
1/1 Pub. 151 - 14/42
Authors I Turova-Polyak, M. G.; Danilava,11. V.; and Treshchova, E. G.
TAU* I Catalytic alkylation of benzene with butyl alcohol
Perlodleal Zhur. ob. khim. 24/9, 1558-1562,, Sep 1954
Abatract The reaction of benzene alkylation with butyl alcohol was realized for
the first time in a flowing system at atmospheric'pressurs. 'The chemi-
cal properties of the reaction products obtained are described. A
temperature of 3000, molar ratio of benzene : n-butyl alcohol of 4 : 1
and a volumetric rate of feedi4c., the reaction mixture of 0.66 - 2.4
are considered the optimum conditions favorable for the derivation of
butyl benzenes. The percentage yield of butyl benzene was calculated.
Fifteen references: 9-USA; I-German and 5-USSR (1929-1953). Tables;
graphs.
Institution : State University, Moscow
Submitted : April 19, 1954
1 4,-
MR
~NW 2 WN - 00 am mtl
DN_. M Z;~r
Not.

4-
--- - ------
.-Trandormation Of "Clohe"Al", in contuct with
of the valladia. MY.I. in A it.. system At elevated
ture aud pressure or byarogen.
1. Xf
-A R. A
A VtidkinQ, aild. p,,y
QZ-9-1 4VAd, %V,- U-4- q--TD,
NaVA!, Y.13"..Y.K., Wei. %A( 1 .H 501-11; Bull.
e
Acad. &i. U.S.S.R.. Div. - em.. &-i. LOSS, 441-9 (E-191,
translation).- The passage of niethylcyclobexane at *W
and 20, 35, and 50 atin. H over dispersed Pt, Pd, Ith, and
RuonAhC~aadSiOjwasstudicd- M20atm. the main r-
action Is the formation of McPh; withuRbSiO2 cat:alyst thr
highest content of CFft (32%) was attahzed. AI&ng with
dehydrogenation, there occur isomerization reactious whicli
Ylela isnmeric as well as (kine(hylu-
,I.. reactions. Usually tile i!vnnerizution react;lons with
rWa COnt-raCtiOn are favured hy I lighvr ope-ating presiums.
MethylcyclDhexane is catalytically 'Unwrted to dimethyl-
cyclo
,d.,,,rAt,,uics by wittact with A),.O, ,r SiO,, Pt-Al-Q, and
yield prillcip.01v
Ith,M%O~ aud f(u-Al:a, ywid in midn appreciable amousit,
of cir- a114 I ling I- I hq,walles. S1:6111 allit'.
of cyclohexane are alsl) formed. G.- N1. Ks-1;,,Iapo11

LEVINA, R.Ta.; MEUNTSOVA, N.N.; TRESHCHOVA, Ta.G.
Synthosis of hydrocarbons; synthesis of hem-dimath7leyclop'antans
from cyclopentadiene.Dokl.AN SSSR 104 no.4:549-551 0 155.
(ML'RA 9:2)
1.Moskovskly gosudaretvanVy universitat imeni M.V.Lomonosova.
Fredstav.le.zo akadamikom A.N.Reemayanovy-m.
(Cyclopentane)

ductloo of alls Iz
ll
lc
V~c
o"
I
,
,
la
u
l
~
U. A. D-4va -o
nL I:
;
ME %fkrwow+-. AtGj Nawk,
R,
5-5..S. 1?, 105, 48& so,
ti.n of 3,4-dimethyl-3,4-ixexELtcdiol with li;['(),Ac,O gave
3-tuetiiyl-2-ctliyi-1,3-p,entadiertt, b-~ 135.3', 0,1 1.4760,
titi O~7019. This (31.2 ~.) was reduced wigh Ca heriam-
jllulljm~ (fro", 40 4. (:.) y1chling 28 5 j foltrd Pri4jurts
Mrntificd a-i .1,4,finkcthyl-2-
hex.ne. and 3.4-dirnethyi-3-hexcue (13%. 52"1". 11%, resp.).
Reductii,n of 65.11 g~ 2-mcthyl-2,4-hexjd:vn, with Ca f,!,.a-
witnioniate (from 92 g Ca) gave M 7 g~ produt t, compcr-sed
of 31~70 lrans-2-melhyl-~i-hexcnc. 20% Ira ns-4-meth y 1-2-
hexene and 49% 2-methyl-2-itexene, idimtificd by Raman
spectra. The Raman spectrum of 2-inethyl-2-hexene is
270(10), 32.X3,5), 37S:&5), 421-34(4.15),
4(~3(6.6), 512(6.3), 647(0), 587(0), -Zd(4.0), 703(6.5),
780(8), 832(d), 869(21), 897(2), OSt(O), 1040(14), 1072(--~.
1"Q 20), 1117(0). 1170(12), 11KII). 1240(g),
INN, IOMO), 1320(14), 1330(20.5), 1353(12). 13 M) 51),
1137(6:'~), 1468(71), 1674(126). G. M. KOSOlapoff

LEVINA. R.Ya.; KIM CHAE-GIl.; TRESHCHOVA, Ye.G.
,~~ ~ - ~ I ~.-.
Synthesis of hydrocarbons. Part 54. Conversion of h7drocarbons of
the cyclohexadiene series into bicyclic hydrocarbons containing a
three-membered ring ; (0.1.3)-bicyclohexanes. Zhur.ob.khim. 26
no.3:920;-926 Kr 156. (M12A 9:8)
1. Koskovskiy gosudarstvennyy universitet.
(Bicyclohexane) (Cyclohexadiene)

-77
MOM

,~ .; - I I... - - I
S~= -mk 9=~
.; -. , ,
~s 6 , - . ,
-,, -,-. - , ,- :-. - I i ~ ~-;~ I-_ I- I - " i~ I- Z---
. , . L i ' - -Fl,:~,17~11A~ 74 an

-T 1.7~ C
20 -6 "A
JOTHOR: LEVINA, R. Ya. , SHABAROV, Yu. S. , WKS A&S, Y. X. anc ZE i; 3V i, Y~.
TITLE: 2,4-Dimethylpentadien-1,3 in the Synthesis of Alkarie6 i*th 7'wc
Quaternary Carbon Atoms Separated by a CH 2-Group (Ditertiary
Alkylmethanes).
2,4-dimetilpentadien-1,3 v sinteze alkanov a dvumya chetvertich-
nymi atanami ugleroda, razdelennymi CH 2-gruppoy (ditretichnoalkil-
metanov. Russian).
PERIODICALt Doklady Akademii Nauk SSSR, 1957, Vol 113o Nr 6, pp 1286 - 1289
(U.S.S.R.)
ABSTRACT: In earlier reports the authors described the method of synthesis
of ethylene-hydrocarbons with a quaternary carbon atom. It oon-
sibts of a reaction between alkylmagnesiumbromides and unsaturated
tertiar bromides of the allyle-typel the latter are easily pro-
duced by means of hydrobromization of dien-hydrooarbons of a rami-
tied structure with a conjugated system of double bindings. E.g.
hydrobromide of 2,4-dimethylpentadien-10 served as initial sub-
stance for the synthesis of 2,4-trimethylalkenes. In this paper the
authors worked out a new and easy synthe for the production of the
rather hard obtainable paraffinhydrocarbons with four quarternary
carbon atcms which are separated by aCH 2- group, that is of the di-
tertiary alkylmethanes. Here the came initial substance was used.
CrArd 113 The reaction mentioned is the first stage of this synthesis, where

20-6-28/59
2,4-Dimethylpentadien-1,3 in the
Quaternary Carbon Atoms Separated
methanes).
Synthesis of A"*- ~n,:.~o -,,'i',h Two
by a CH 2- Group (Diter1iary Alk,-l-
the yield could be increased from 30 to 45 %. Furthermore, the al-
kenes which had already a quaternary carbon atom were transformed
by the action of hydrochloric acid into saturated tertiary chloride
2-chlorine-2,4-trimethylalkanes (yield 90%). The latter were then
introduced into the reaction with magnesiumoreanic compounds with
sublimate as a catalyzer; the products of thin last stage of the
synthesis were alkanes with two quaternary carbon atoms separated
by a CH -group. In the case of an interaction with magnesiumorganic
compoungs the saturated tertiary alkaneB split off also hydrochlo-
rio acid and, with a yield of 50% form the initial alkanes. The
latter were used for alkane-synthesis. The Ocanes and alkanes were
easily separated by destillation. The alkane yield amounted to from
15 - 25 % calculated according to the tertiary chloride introduced
into the reaction, and to from 3o - 50 % according to that not uti-
lized. Reactions with yields, methoda,-and spectroscopic constants
are described. (3 tables, 6 Slavic references).
Card 2/3

2o-6-28/59
ASSOCIATION:
PRESENTID BY:
SUB1,1ITTER:
AVAILABLE:
2,4-Dimethylpentadien-1,3 in the Synthesis of Alkanes with Two
Quaternary Carbon Atoms Separated by a CH -Group (Ditertiary Al-
kylmethanes.)
Not given
HISMEYANOVI A.H. , Member of the Aoademy.
15 Deoember 1956
Library of Congress
Card 3/3

0
KSSIZR, Kh;P3NTJIT, Yu.A.;TRESHOROVA, Ye.-G.;TATIVSKIY, V.M.
Investigation of liquid and solid phase infrared absorption spectra
of hydrocarbons at various temperatures..Opt..i spektr..7 no.3:301-
310 S '59 jHydrocarbons-Spectra) (MIPA 13:3)

KHROMOV, B.I.;RAI&KOU, Ys.S.;'TIWHCHOVA, Ye.G.
e -
17~'~~ 1.1.4'ZicOm
Synthesis and contact traasfor=ations of cyclopenty1c7cloheptane in
the presence of p;;tinized carbon. Vest Mosk. un. Ser. mat.-, mekh.,
astron., fiz., khim. 14 no.2:143-148 159 (HIBA 13:3)
1. Kafedra khimii nefti Moskovskogo gosuniversiteta.
(Cycloheptane) (Carbon) (Platinum)

SHUSHERINA, N.P.; GLADYSHEVA, T.Kh.; TRESHCHOVA, Ye.G.; LEVINA, R.Ya.
S -Lactones and S-lactams. Part 44: Behavior of 2.2,5,6-
tetrasubstituted 3,4-dihydropyrans during their hydrolysis-
transformation to cyclohexadieneB. Zhur. org. khim. 1 no.4:
673-678 Ap 165. (MIRA 18:11)
1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova.

,- ,~:, . ~!, -- ~ 't ( , 1 - -. ~ i - - - ~ ;~.. ,-,1. .1!.
L A
Trs.irnfonriatlc~n of
2:Khim. 20 r~~ 5:19-22
tjoror. flxoride.
S-0 165. A TFL,% 18 :12
.1
Kafedra fizift-..eskcy kh~*mii
uni v e rs i t. a ta . S u bn I t t ed D a c . 1 6 L~

LUKIYAINETS, Ye.A.; SHUSHERINA, N.P.; TRESHCHOVA, Ye.G.1 YJ.7,ITSINA, L.A.;
LEVINA, R.Ya.
S -Lactones and S-lactams. Part 47. Spectroscopic s-t~,idy of
3 -enallactones with a semicyclic and endocyclic double bond.
~,.iur. org. khim. I no.7,,1194-11,99 J1 t65.
(MIRA 18: 11)
1. Moskovskiy gosudarstvennyy universitet imeni M.V.Lomonosova.

LEVINA R.Ya.-, KN&-M, I;A.~ GALIPJ-,RNi.'-,l,
TRES14GHOVA, Ye.(!
S~mthesls of hydrocarwns. Part 81? '-:1cpropanes
,iarbon atoms in the ring and in a sldp chain. Zhur. ob. Yh.!m. 35
no.5t785-788 My 165. (MIRA 18:6)
1. Moskovskly gosudarstiennyy universit-et Imeni Loricnosova.

TFUESHCHOV1. Ya.,G.; -,.XKH.ARDT, ".; YUn'Y]V, 'fu.K-
Corralatims in the Gf foran,
,u
derivatives. 7-huz,. fiz. ~Idm. 38 w,.2z29r-*~03 F 164.
(MIRA 1-7. 8)
1. Moskov:3kty gcs-dar.3tvennyy unIveraltef,

SHABAROV, Yu.S.; FOTAFOV)j:V.K.; LEVINA, R.Ya.; TRESHCHOVA, Ye.G.
Cyclopropanes and cyclobutane'9. Part 26.- Stereoisomeric
1,2- and 1,3-mothylphenyleyclobutanes. Vest.Nosk.un. Ser.2;Khim.
18 no.lt6l-65 Ja-F '63. (MIRA 16:5)
1. Kafedra organicheskoy khimli Moskovgkogo universiteta.
(Cyclobutane) (Isomers)
1.~~ -

IAEVINAI R.Ya.; GEMBITSKIY, P.A.; XOSTIN, V.N.; TRESHCHOVA, Ye.G.
Cyclopropanes and cyclobutapes. Part 27: Cyclopropy-lallcylbenzenes.
Zhur.ob.khim. 33 no.2059-365 ~ 163. (MMA I b; a)-
1. MOSIcovskiy gosudarstvennyy-un-l-vernitet imeni M.V.Lomonosova.
(Benzene) (Cyclopropyl group)

LEVINAj R.Ya.; GEMBITSKlY, P.A.; -TRWHCIIOVA, Ye.G.
Cyclopropanes and cyclobatanes. Part 29.- Bromination of
aryleyelopropanes. Zhur.ob.khim. 33 no.2:371-376 F 163.
(MIRA 16s2)
1. Moskovskiy gosudarstvennyy universitet imeni M.V.Lomonosova.
(Cyclopropane) (Bromination)

LEVINZ, R.Ya.; SHLNAZAROVr K.S.; TBESHCHOVA, Ye.G.
Synthesis of 1.1.2-trimethyl-4-alkylcyclopentanes. Neftekhimiia
3 no.1:3-9 Ja-F 163. (MIRA 16:2)
1. Moskovskiy goeudaretvennyy univeraitet imeni, Lomonosova.
(Cyclopentane)

LEVINA, R.Ya.; SHANAZAROV, K.S.; KOSTIN, V.N.; TRESH',HOVA, Ye.G.
Synthesis of hydrocarbons, Part 78: New syntheria of 1,1,,3..3,4-
pentamethyleyelopentane. Zhur.ob.khim. 32 no.8:2637-2640 Ag
162o (MIRA 15:9)
1. Moskovskiy gosudarstvennyy universitet imieni M.V. Lomonosovao
(cyclopentane)

S/169/63/000/001/008/008
D204/D307
3habarov, Yu. S., Potapov, V. K., Levina, R. Ya. and
Treshchova Ye G.
Cyclopropanes and cyclobutanen. XXVI
Moscow. Universitet. Veotnik. Seriya II. Khimiya,
no. 1, 1963, 61-65
TEXT: StereoiBomeric 1-methyl-2 phenylcyclobutanes and 1-methyl-3-';
phenylcyclobutanes were studied spectroscopically and an attempt
was made to determine the ciQ- and trans-configu-rations. Raman
-1
bands at -1200 cm of all isomers were slightly higher than the
corresponding lines for alkylbenzones. Cis- and trans-l-methyl-2
phenylcyclobutanes could not be distinguished in tre taman Spec-
tra. In the case of 1-methyl-3-phenylcyclobutanes, the higher boil-
ing isomer A exhibited a broad, fairly'intense band at 872 am-1,
whilat the lower-boiling isomer B showed a corresponding band at
854 am-1. The,.,.,1200 cm-1 and 1600 cm-1 intensities were also'higher
Card 1 2

Cyclopropazies and cyclobutanea
3/189/63/000/001/008/008
D204/D307
in B, a property characteristic of trana-forms. Uv spectra of 1-
methyl-2-phenylcyclobutanes in iso-octane ohowed that isomer A,
distinguished by-higher physical constants, absorbed more strongly
in the 225 - 250 mp region than the-other isomer, B. The same was
true of the A-forid of 1-methyl-3-phenyleyclobu-tane, though to a
lesser extent. Control tests with 1,2-diphenyleyclopropanes, whose
configurations were established chemically, showed that trans-
forms absorbed more strongly in the uv. Configurations of 1-methyl-;
2-phenyloyclobutanes may thus be assigned only from uv absorption
obu-
spectra, whilst the configurationa of 1-methyl-3-phenYl-cycl
tanes remain unresolved, since Raman and uv spectra gave contra-
dictory indications. L. A. Kazitayna measured the uv absorption.
There are 3 figures and 1 table. A
ASSOCIATIONs Kafedra organichookoy Ichimii (Department of Organia
Chemistry)
SUBMITTBD: June 26, 1961
tGard 2/2,

IEVINA, R.Yaj; KOSTIN, V.N.; GEMBITSKIYt P.A.; SHOSTAKOVSKIY, S.M.;
TRESHCHOVA, Ye.G.
O.volopropanes and oyclobutanoo. Part 241 CyclopropylmeBitylene.
Zhur.ob.khim. 32 no.5tI377-1382 My 162. (MIRA 150)
1. Moslcovskiy gosudarstvannyy universitet.
(YAsitylone)

5/189/62/000/005/006/006
D204/D307
AUTHORS: Treshchova Ye* G., Skvarchenko,, V. R., and
M_~ R, T_ j Y a
TITLE: Raman spectra of variouB.classes of hydro-
carbons. Communication VIII. The spectra of
polyalkylbenzenes
PERIODICAL: Moscow. Universitet. Vestnik. Seriya II,
Khimiya, no. 5v 1962, 66-70
TEXT: 'The spectra of (a) 1,2-dimethyl-4--~ethyl, (b) 1-t2-
dimethyl-4-butyl, (c) 1,4-dimethyl-2,3-diethyl,*(d) 1,2,5-
trimethyl-3,4-diethyl, and (e) 1,2,3,4-tetramethyl-5,6-diethyl
benzenes were studied in the region of 150 - 1700 cm- 1, using a
triprismatic glass vicn -s i (ISP-51 ) spectrograph and a (D3Y - 17
photomultiplier by a method described earlier. All
compounds showed lines in the regions of 224 - 257, 547 - 556,
Card 112