SCIENTIFIC ABSTRACT TOLSTOPYATOVA, A.A. - TOLSTOUSOVA, Z.A.

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• Collection: Scientific Abstracts
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• Original Classification: S
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• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

TOLSTO-PYATOVA,, A.A.j yUy TSI-TgyUANo [Yu Chli-chluan]; DULITSKAYA, K.A.
Catalytic propertieo of neodymium oxide in the reactions of
debydrogenation of-tetral-in. Izv. AN SSSR. Ser. khim. no.12:
2095-2100 D 163. (MIRA 17:1)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN
SSSR.

KONENKO, I.R.; TOLSTOPYATOVA, A.A.; BALANDIN, A.A.
Scandium oxide as a catalyst of dehydrogenation and dehydration.
Izv. All SSSR. Ser. khim. no.11:1899-1905 11 163. (MIRA 17:1)
1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR.

) A. A.; TOISTOPYATOVA, A. A.
"Selectivity of catalysis and bond energies."
report submitted to 3rd Intl Cong on Catalysis) Amsterdam.. 20-25 Jul 64-
Inst, or Organic Chemistry im Zelinskiy., AS USSR, Moscow.

- TOLSTOPYATOVA, A.A.,- BALANDIN, A.A.; YUY TSI-TSYUAN' [Y~ Chli-chl~an)
Kinetics of dehydrogenation and dehydration of isopropyl alcohol and of
the dehydrogenation of tetralin on lanthanum oxide. Zhur.fiz.khim. 37
no.lOt2220-2227 0 163. (MIRA 1722)
1. Institut organichaskoy khimii AN SSSR.

BALANDIN, A.A.; KONENKO, I.R.j_ TQ1SJ-QMTO~A,_A-.A.
Kinetics of dehydrogenation and dehydration of ethyl and isopropyl
alcohols on ytt4Lum oxide, Kin.i kat, 2 no,6:90Q-906 N-D 161.
- (MIRA 14:12)
1. Institut organicheskoy khimii imeni N.D. Zelinskogo AN SSSR.
(Ethyl alcohol) (Isopropyl alcohol)
~(Dehydrogenation) (Dehydration (Chemistry))

BAIANDIN, A*A*, akademik; TOLSTOPYATOVA. A NAUMV, V.A.
Bond energies of interaction between organogens and the surface
of oxide catalysts. Dokl.AN SSM 148 no.42825-828 F 163.
WMA 16:4)
1. Moskovskiy goErudarstvennyy universitet im. M.V.Lomonosova.
(Chemical bonAs) (Chemical elements) (Catalysts)

FERAPONTOV, V.A.; BAIANDINq A.A.; TOLSMPYATOVA, A.A.
Catalytic dehydrogenation of ethylbenzene th styrene on
cadmium oxide in the presence of water vapors. Izv.AN SSSR.Otd.
khim.nauk no.3s4l4-423 Mr 163. (KIRA 1634)
1. Institut organicheakoy khimii im. N.D.Zelinskogo AN SSSR.
(Benzene) (Styrene)

TOISTOPY a A ; BALANDIN, A.A.; NAUMOV, V.A.
Kinetic method used in the determination of bond energies of
the reacting atoms of organic molecules having a blue moIrWenum
oxide surface. Izv.AN SSSR.Otd.khim.nauk no.3&423-429 Hr I _1-_
(MIRA 16:4)
1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova.
(Chemical bonds) (Molybdenum oxides) (Organic compounds)

TOLSTOPYATOVA, A.A. BALANDIN., A.A.; FYN BI-SYAN [POOng Pi-4isiaag]
Kinteics of the dehydrogenation and dehydration of isopropyl, alcohol
and of the dehydrogenation of tetralin on thulium oxide. IZV.AN SSSR.
Otd.khIm.nauk no.9:1524-1533 S J62. (IffRA 15:10)
1. Moskovskiy crosudarstvennyy universitet im. M.V.Lomonosova.
(Isopropyl alcohol) (Dehydrogenation) (Dehydration (Chemistry))
(Naphthalene)

BALANDIN, A.A.; TOLSTOPYATOVA,_A.A.; PYN BI-SYAN (PIOng Pi-holang)
Catalytic properties of dysprosium oxide with respect to the
reaction of &hydrogenation and dehydration of alcohols and
debydrogenation of tetralin. Izv.AN SSSR.Otd.khim.nauk no.6:
974-980 '640 (KRA 15:'8)
l.. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova.
(Dysprosium oxide) (Catalysis) (Dehydrogenation)

TOLSTOPYATOVAJO A.A.; BALAVDIN, A.A. PYN BI-SYAN [P'8ng Pi-haiang]
Kinetics of dehydrogenation and dehydration of isopropyl alcohol
and dehydrogenation of tetralin of dysprosium oxide. Izv.AN SSSR~
Otd.khim.nauk no.7:1-154,-1163 J1 162. (MIRA 15-7)
1. Mbskovskiy gosudarstvennyy universitet im. 14.V.Lomonosova.
(Chemical reaction, Rate of) (Catalysis) (Dysprosium oxide)
. . . . . . . . ....
13W 531L P 1v

TOLSTOPYATOVA$ A.A.;_ PYN BU-SYkN [Ptgng Pi-hsiang]; BALAIMIN, A.A.
Kinetics of dehydrogenation and dehydration of isoprop,71
alcohol and of dehydrogenation of tetralin on ytterbium oxide.
Izv.AII SSSR.Otd.khim.nauk no.8:1322-1329 Ag 162. (MIRA 15:8)
1. 14ookovskiy gosudarstvennyy universitet im. M.V.Lomonosova.
(Isopropyl alcohol) (Naphthalene) (Dehydrogenation)

BATA INJI A.A.; TOLSTOPTATOVA. A.A.; NAUMV, V.A.
Determination of bond energies of the reacting atoms of organic
molecules with the MC~ catalyst surface using a kinetic method.
Izv,AII SSSR.Otd.khim,,.nauk no.70250-1154 Jl 162. (KRA 15:7)
1. Moskovskiy gosudarstvennyy universitet im. M.Moomonosova.
(Chemical bonds) (Mlybdenum oxide) (Chemical reaction., Rate of)

BALAMD1, A.A.; MI BI-SYAN [PIOng Pi-hsiang); TOLST-OPYATOVA, A.A.
Kinetics of dehydrogenation and dehydration of IsopropjvI alcohol
and of dehydrogenation of tetralin on gadolini= oxide. ImAll
SSSR.Otd.khim.nauk no.8.-1330-1336 Ag 162, (MIRA 15:8)
1. Mookovskiy gosudaretvennyy universitet im. M.Lomonosova.
(Isopropyl alcohol) (Hapththalens) (Dehydrogenation)

TOISTOPYATOVA, A.A.; ULAWIN, A.A.; MATYLIBBENKO, V.Kh.
Determination of bond energies of atoms of organic molecules
reacting with the a-prface of the YhO catalyst. Izv.AN &9SR Otd.
khim.nauk no.8d333-3.336 Ag 160. (MIRA 15:5)
1. Moskovskiy gosudarstyennn universitet In. MoVAomonosova i
Lwtitut organicheskoy kbildi im. N.D.Zelinskogo AN SSSR.
(Chemical bonds) (Chemical reaction, Rate of)

S/06 62/000/008/002/016
B1 01 YB1 80
AUTHORS: Tolstopyatova, A. A., Ping Pi-hsiang, and Balandin, A. A.
TITLE: Kinetics of the dehydrogenation and dehydration of
isopropanol and the dehydration of tetralin on ytterbium
oxide
PERIODICAL: Akademiya nauk SSSR. Izvestiya. -Otdeleniye khimicheskikh
nauk, no. 8., 1962, 1322-1329
Ta-T: Data was obtained on the catalytic dehydration of i-propanol and
the dehydrogenation of i-propanol and tetralin on Yb 203' using methods
described earlier (Dokl. AN SSSR, 138, 1365 (1961); Izv. ml SSSR, Otd.
khim. n., 1962, 974, 1154). The low specific surface area of the catalyst
(9.1 M2/g) precluded capillary condensation and complications due to
diffusion. 'When the catalyst was mixed with quartz powder in a 1:1 ratio,
the reaction took place isothermally. z, the relative adsorption coeffi-
cient of the reaction products (H 2 0, C3H31 acetone's H2, naphthalene), and
the thermodynamic functions AH (kcal/molo)p AP (kcal/mole), AS
Card 1/3

S/062/62/000/008/002/016
Kinetics of the dehydrogenation ... B1011BI80
(kcal/mole-deg) were calculated:
dehydration of i-propanol dehydrogen ation of i-propanol
0C z &H tLF AS 0C z AH AF AS
H2 0 aoet
325 7.23 -18.7 -2-39 -10-4 345 2-56 -21.9 -Ie13 -33-5
365 3-48 -1-57 -10-3 365 1-54 is -0-54
zC3H6 zR2
329 1.60 -23 .6 -0.69 -38-3 325 0-15 34.7 2.24 54-4
36o o.61 It 0-4b Is 345 0.40 of 1.13 54-5
dehydrogenation of tetralin
z napht' 21
R2
500 1-37 26-5 -0-49 34-9 500 1-40 -48-4 -0-49 -62.0
524-5 2.32 It -1-35 530 0-42 11 1-39 -62.1
The real and apparent activation energies and the energy of adsorption of
the C,11 and 0 atoms onto the sur faoe of the Yb 20 3were calculated from the
Card 2/3

S/06 62/000/008/002/016
Xinetics of the dehydrogenation B101 Y2180
above data (the first figure being the apparent value, the second the true
value, in kcal/mole): dehydration of i-propanol E H20 25-19 30.-6;
dehydrogenation of i-Propanol E 20.6, 22.9; dehydrogenation of tetralin
H2
6A2 34-7, 36.6; QC-cat 22.1, 19.4; QH-cat 53.5; 55.1; QO-cat-52-5, 49-7.
There are 3 figures and 13 tables.
ASSOCIATION: 'Moskovskiy gosudarstvennyy univeraitet im. M. V. LomonosovA
(Moscow State University imeni 11. V. Lomonosov)
SUBMITTED: February 13, 1962
Card 3/3

TOLSTOPYATOVA, A.A.; KONENKO, I.R.; BALANDDI, A.A.
Bond energies of carbon, hydrogen, and oxygen atoris of organic
molecules with yttrium oxide. Kin.i kat. 3 no.1:103-106 '62.
(MIRA 15:3)
1. Institut organicheskoy khimii imeni N-D.Zelinskogo AN SSSR.
(Chemical bonds) (Yttrium oxede) (Catalysis) (Organic compounds)

IA
'13
A:-- ' OR
m a -MMY-05
+'03 'jjO --- 5"'
Ahad. Ndqh ;r9)
~dohcO
% C%j -3L-
~y zi-cito
41~11 '0 -348
ve catal lip t297
7vT 'ctivity of Z,Os
38 1 with theorye
Y. )".
itr.~~yd "S llar fur all It
, ti i -lu- ire 1%1'. nbladin -!rgd-~: "6 very
the =ti,, "I" -, " ,
I diffo, Z6fij~Aorably,', fr6,11 tjlc
but t1le '111'a j calc:ulatc talysts, %v Ul't ge cataly3t_o
with thc cataly5t' 1 14i ond CrOscLL it. TRusc .
cl", to thr"S'3 found I'll
is uch jo%ver.
:bond-Olergy

BALANDIN, A.A.; T~I~~TOYAJQ-VA-~,-A~.A.; DUD~IK, t.
Catalytic properties of thorium dioxide in the dehydrogenation
and dehydration of alobhols, and in the dehydrogenation of cyclic
hydrocarbons. Kin.i kat. 2 no.2:273-284 Mr-Ap 161.
RIA 14.6)
1. Moskovskiy gosudarstvennyy universitet, kafedra organicheskogo
kataliza.
(Thorium oxide)
(Dehydrogenation)
(Dehydration (Chemistry)

TOLSTOPYATOVA, AI~A.; BALANDIN, A.A., akademik
Regularities in the catalytic properties of rare earthae Dokl*PII
S,VR 138 no.6:1365--d368 Je 161- (MM 14:6)
I
1. Institut organicheskoy khi-ii im. N.D.Zelinskogo AN SSSR i
Moskovskiy gosudarstvemyy universitet im. M.V.Lomonosova.
(Rare earths) (Catalysis)

BALANDIN, A.A.; STSHIZHEVSKIY, V.; TOLSTOPYATOVAj, A.A.
Thermal effect of the reaction of alcohol dehydration affecting
the results of kinetic measurements. Vest.Mosk. un. Ser.2:lddm.
17 no.1:3'0-33 Ja-F '62. (MIRA 15:1)
1. Moskovskiy gosudarstvennyy univers~'Set, kafedra organicheskogo
kata.liza.
(Alcohols) (Heat of dener7ation) (Catal7sis)
�r
i Mil

BALANDIN) A.A.;,TOISTOPYATOVA, A.A.; DUDZIK, Z.
Catalytic properties of thorium dioxide in the dehydrogenations and
dehydration of aicbhols., and in the dehydrogenation of cyclic hy-
drocarbons. Kin.i kat. 2 no.2:273-284 Mr-Ap 161. (14-TRA 14:6)
1. Moskovskiy gosudartsvennyy universitet, kafedra organicheskogo
kataliza.
(Thorium oxide) (Dehydrogenation)
(Dehydration (Chemistry))

TOLSTOPYATOVA, A.~.) BALANDIN, A.A.; MATYUSHENKO, V.Kh.; PETROV, Yu.1
Kinetics of the dehydrogenation and dehydration of alcohols-, and of
the dehydrogenation of hydrocarbons over WS2 and MoS2 catalysts. Izv.
AN SSSR Otd.khim.nauk no-4.-583-590 AP 161. (MM 34:./+)
lo Inatitut organicheskoy kbimli im. N.D.Zeiinskogo AN SSSR.
(Dehydrogenation) (Dehydration (Chemistry))
(Molybdenum sulfide) (Tungsten sulfide)

TOLSTOPYATOVA A.A.; KONEK09 I.R.; BALANDINg A.A.
Catalytic properties of yttrium oxide.-Conversions of alcohols and
hydrocarbons. Kin. i kat. 2 no.1:131" 143 Ja-F 161. (Mmk 14:3)
1, Institut organichaskoy khimii imeni N.D. Zelinakogo AN SSSR.
(Yttrium oxide)
(Alcohols)
(Hydrocarbons)

BAJ~MII, A..A.-,--TOLSTOPYATOVA, A-A; KONMO, I-R.
Study of the catalytic converalons of isoprojq1 alcohol and cyclic
hydrocarbons on titanium dioxide (anstase) by means of a differential
thermocouple. Izv. AN SSSR.Otd. khim. nauk no.l2s2096-2102 D 160.
(MM 13:12)
1. Institut organicheskoy khImR Im.N.D.Zelinskogo AN MR.
Ueopropyl alcohol) (Eydrocarbons)
(Anataae)

TOLSTOFnYhT!0TV~Aj_~A.; KOMMKO, I.R.; BALAIMIN., A.A.
Kinet-ics of dehydrogenation and dehydration of isoprop
- I Y1
alcohol over titanium dio-dde (Anatase). izv. AIT SSSR.
Otd. khim. nauk no. 1:38-44 Ja t6l. (MRUt Ili: 2)
1. Institut organicheskoy khimii im. I.I.D. Zelinskogo AIT SS311.
(Anatase) (Isopropjl alcohol)

KOILE,110, I.*~.; TOLIjTCI"- R-W., A.!..
F,ffect of the proT.4rz..tior matl,r)d on the catc-lytic prol,,erties of
titan~lm dioxide in ri~:Lc-'Loiom, of ethyl ~;,nd --*sor;-.cpll alcohol
and &yplohe::ane. Izv. '2T, SSS-?.. Otd. Ichim. nauk no, 1:/+5-50
Ja 161. EUMi. 14 ; 2
1. Imtl"'.Ut or-i nichl-zlzoy Idiixdi 'elinslcogo A.". 6340'lc-
cj
(Titanim oxide) (ZthlAnol) (Isopropyl alcohols)
(Cyclohe;cane)
J

TOLSTOPYATOVAt A.A.; BALANDINp A.A.; KONMO, I.R.
Energies of the bonds between reacting organic compounds and the
cataly-tic active centers~of titanium'dioxide. Izy. AN SSSR. Otd.
khim. nauk no.2:214-.217 F 161. (MIRA 14:2)
1. Institut organicheskoy khimii im.N.D.Zelinskogo AN SSSR.
(Titanium oxide) (Chemical bonds)

S10621611000100110041016
B101/B220
AUTHORS: Tolstopyatova, A. A., Konenko, I. R., and Balandin, A. A.
\j
TITLE: Kinetics of dehydrogenation and dehydration of isopropyl
alcohol on titanium dioxide (anatase)
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
no. 1, 1961, 38-44
TEXT: By way of introduction the authors offer a s' urvey of reports
dealing with the catalytic efficacy of T102, and then report on the
dehydrogenation and dehydration of isopropyl alcohol on anatase. Regarding
the production of the catalyst they refer to another report published
by them. For the verification of the kinetics of monomolecular
hetero eneous-catalytio reactions they 3roceed from the equation
k - A 7z Z )lnA,/'Al 1)m (1 . A is the volume of alcohol
1 2- 3 % -M)-(Z2+Z3- I
converted per minute, which is introduced at the rate v; m is the volume of
are the relative
propylene (or hydrogen) formed per minute; Z2, Z3(
adeor.ption coefficients of the reaction products hydrogen and acetone
Card 1/3

B10621611000100110041016
Kinetics of dehydrogenation and dehydration... B101/B220
in the case of dehydrogenation; propylene and water in the case of
dehydration)l Z2 and Z3 were calculated from Z - (mo/m-l)/(100/p-1) (2),
where mo, m are the amounts of the reaction products resulting on the
passage of pure alcohol (m0) and on the passage of a p molar mixture with
the reaction product. Since Z is the equilibrium constant of the
displacement of the isopropyl alcohol from the catalytic centers by the
reaction products, it was possible to calculate also 6F of the free
energy, AS of entropy, and AR of the heat content. The adsorption
coefficient Zac of acetone was found to be highly dependent on temperature
and much less so on the degree to which the catalyst was covered with
carbon. The following is indicated for not carbonized T102: Zac = 2.4 at
282OC; 1.7 at 2940C; 1.2 at 3100C. For carbonized T102 these values
amounted to 2.7, 1.8 and 0.9. The adsorption coefficient ZH2 of the
hydrogen remains constantly 0.9 in the range of 276-3060C. Moreover, it
was found that ZH20 - 1.9 at 2820C, 1.4 at 2940C, and 0.9 at 3100C,
whereas Zpropylene remains a constant 0.2 in the temperature range of
300-3300C. A. M. Rubinshteyn and S. G. Kulikov are mentioned.
Card 2/3

S1062161100010011004-1016
Kinetics of dehydrogenation and dehydration ... B101/B220
There are 1 figure, 8 tables, and 24.references: 8 Soviet-bloc and 13
non-Soviet-bloo.
ASSOCIATION: Institut organicheskoy khimii. im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy, Academy of Sciences USSR)
SUBMITTED: June 29, 1959
~ I
Card 3/3

5106 61/000/001/005/016
B101XB220
AUTHORS: Balandin, A. A., Konenko, I. R., and _Tolstopyatova, A. A.
TITLE. Effect of the method of production on the catalytic proper-
ties of titanium dioxide in the reaction with ethyl alcohol,
isopropyl alcohol, and cyclohexane
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
no. 1, 1961, 45-50
TEXT: The authors were concerned with the investigation of the catalytic
properties of titanium dioxide. Here, they studied the dependence of
those properties on the method of TiO 2 synthesis. Four specimens were used.
Catalyst 1 (anatase), whose production is described in Ref. 1, a previous
report of the authors; catalyst 2, obtained by hydrolysis of TiCl 4 by means
of qmmonia solution in a weakly acid medium at room temperature; catalyst
3, obtained by precipitation of Ti(OH)3 from TiCl3 by means of ammonia
at room temperature and conversion to Ti(OH) 4 which occurred automatically
Urd 1/5

Effect of the method of production.... S/062/61/000/001/005/016
BIOI/B220
while washing the precipitate; catalyst 4, obtained by hAmlysis cf ethyl ortho-
titanate by means of distilled water at room temperature. The further
treatment of the hydroxides for the purpose of obtaining TiO2 was per-
formed according to Ref. 1. Ethanol reacted with these catal t accord-
ing to three reactions: a) dehydrogenation, b) dehydration, c~shydrogena-
tion of the resulting ethylene. Moreover, up to 2% ethyl acetate was
formed on all four catalysts. The reaction of isopropanol corresponded
to data mentioned in Ref. 1. Due to the growing accumulation of carbon
on the catalyst, the rate of dehydration increases, whereas that of de-
hydrogenation decfeases. Cyclohexane is dehydrogenated on all four
catalysts. The differences between the catalysts regarding the activation
energy E and the factor k0 of the Arrhenius equation are listed in Table 8.
The linear function log ko = a6 + b (a, b - constants) is conserved for
all reactions. A. M. Rubinshteyn and S. G. Kulikov are mentioned. There
are 2 figures, 8 tables, and 6 referencest 4 Soviet-bloc and 2 non-Soviet-
bloc.
Card 2/5

Effect of the method of~ product-i-on... 3/062/61/000/001/0~5/016
BIOI/B220
BallISHIle cnocoft OpIlrelosileiXX ZMAKMTOP& 7102 "a BM-IRXW OfftPrItA aJLTHUZINK
14
Ic tlajut wop
tit KQrAfilf-
2 3
.2
4. 0. jjlerHAporeH"3swiR qvzowm cnmpT& 22.8 20 4 0,4 12,4 t0$
t0 1,9-101 1,4
4. Q, JAMIAPMWIS sninosoro enmpts 250 25:4 0,0 12,5 :
1:5 tOf 5,6406 V
in. 0. UerHAPaT8WfO m3onponmowro cnifpTa 22 9 9,1 20,2 2
17 3 7,104 9.1-105 1,0
i it. o. forilAporettitnwin svifietfa 21 2 24,2 MO 10:8 1: 8 - 10') 1,0- tOl 1.3
4 q- 0- l0lerHAPOreHH30OR wtuore=H& 19:0 14,7 2i,G 15,0 8,7406 5,1.104 1,3
~ q. 0. (XAerllAporeHH3aLwsi smoripawowro
CnHpTa 9,1 10,4 1.01104 2,2.104
yq. 0. qaertIAPSTURR mapommowro cnupTa 24,4 15,3 4,5.109 6,9-t0$
H. o. flAerHAporemnatinn tisonponHao3oro
cnupu 1,9.101 -
11. 0~ tJlerHAporeHH38WIR ttworexcamt 25 2 4,9.101 - -
q.L 0.
Aerl]AporemHugusi nponmosoro cups
19:4
2 3.100
-
it q. 0. (yAentApATaww H.nponunowm cnHpTs 12,1 4 5. 1(~ -
Card 4/5.

COMSMIte
-101
-101
40111
-104
-
-
-
-
R

3 4
1,2-104
4,4404
2,8407
2,7406
i0# 3,5406

KHTO.AH3JTOP
Effect of the method of S/0621611000100110051016
4
2 3 B101/B220
.2,94 281 3,0t 3 05
2,73 2.90 2,70 2:70
.2 39 2 28 2,54 2 31
:0 3,01 3'
2:91 3 1 110
3,20 3,12 3.53 3,3,0
24 2,40 -
2:53 2,02 -
2,25
3,27
2 71
3:05 2,73 2,96 2,89
2,60
Legend to Table 8: Effect of tNe method of preparing the TO catalyst Oil
2
the amounts of activation energies. 1) Condition of catalyst surface;
2~ reaction; 3) catalyst; 4).partially carbonized; 5) completely carbonized;
6.1 not carbonized; 7) dehydrogenation of ethanol; 8) dehydrbLtion of ethanol;
9) dehydration of isopropanol; 10) hydrogenation of ethylene; 11) dehydro-1-
genation of cyclohexane; 12) dehydrogenation-of isopropanol; 13) dehydro-
genation of propanol; 14) dehydration of n-propanol.
Card 5/5

TOIZTOPYATOVA, A.A.
A.A.Ralandin's work in the field ef haterageneous catal7sis.
Vout.Kbak.un.Sor.=Lt,, makho, astron., fiz., kh1u. 14 no.):
159-169 '59. (mm 13:5)
(Catalysis) (Balandin, Alakeei Alakcandrovich, 1898)

81725
20
S/O 0 133/01/36/070
BO11 B003
AUTHORS: Tole ouatom A. A., Balandin, A. A.9 Academician,
Konenico, - . .- --
TITLE: Catalytic Transformations of Alcohols and Cyclic Hydro-
carbonslon Titanium Dioxide
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 133, No-19
pp. 130 - 133
TEXT: Although titanium dioxide is easily available, it belongs to the
little investigated catalyst lThe authors wanted to study its cata-
lytic properties with various modes of preparation, in reactions with
ethyl-9 isopropyl, and n-propyl alcohol as well as with cyclohexane,
cyclohexene, and 194-cyclohexadiene. Moreover, they wanted to investi-
gate the.kinetics of these reactions and the energies of the bonds of
C-,7 H-,, and O-atoms with the TiO2surface. The method of the differen-
tial thermocouple is used for the study of the catalytic reactions.
Fig. 1 shows the position of the catalyst in relation to the thermo-
couple. The electromotive force (emf) was uninterruptedly recorded on
Card 1/3

81725
Catalytic Transformations of Alcohols and S/02q&/133/01/36/070
Cyclic Hydrocarbons on Titanium Dioxide BOIV~003
a potentiometer of the typ! 0
_?2P-OL(EPP-09)- Apparatus and methods are
described in Ref, 4. By combining the above method with analytical meth-
ods the authors found that in isopropyl alco,hollthe surface of the cata-
lyst is coated by carbon-containing sediments. In this wayp the rela-
tion between dehydrogenation and dehydration of the alcohol is consider-
ably influenced. Within the first 2 - 5 min it is only dehydrogenated.
Subsequentlyq the two processes mentioned take place, and after
20-25 min there occurs dehydration only. Meanwhileg the total amount of
the gas liberated per unit of time remains unchanged. All this proves
that the centers that are active for dehydrogenation, are poisoned
after decarbonization with respect to this reaction, but at the same
time are capable of dehydrating the alcohol at the same rate (Table 1).
Also the regeneration conditions of the catalyst were determined with
the same apparatus: The carbon film was removed after each experiment
by means of a strong air ourreato with the catalyst being previously
brought to a temperature exceeding the one of the experiment by 40-50 C.
Regeneration usually took 20-30 min, The authors studied the influence
of the mode of preparation of T102 on the catalytic properties on four
samples: No. I - by precipitation of the hydroxide from TiCl 4 with
Card 2/3

81725
Catalytic Transformations of Alcohols and S102016011331011361070
Cyclic Hydrocarbons on Titanium Dioxide BOIIIB003
water, No. 2 - the same with ammonia. No. 3 by oxidation of freshly pre-
pared Ti(OH)3 (precipitated from T'Cl3 with ammonia) with air, and No. 4
by hydrolysis of orthoethyl titanate. it was established by X-ray strue-
taral analysis that anatase resulted in No. 1. Table 2 shows the reac-
tions studied in certain temperature ranges, the activation energies 'C
as well as Ko of the Arrhenius equationj furthermoreq the degree of de-
carbonization of each sample surface. It may be seen from these data and
Table 4 that the mode of preparation exerts a great influence on the
above-mentioned values and the binding energy. Table 3 shows the depen-
deRce of the adsorption coefficient z on AHO (heat content) the entro-
py ASoq and the change in free energyAFO. The binding ener6 values
were oaloulated for the first time (Table 4). There are I figure,
4 tableap and 11 references: 10 Soviet.
ASSOCIATION: Institut organicheakoy khimii im. N. D. Zelinskogo
Akademii nauk SSSR (institute of Organic Chemistry imeni
N. D. Zelinskiy of the Academy of Sciences,_USS
SUMTTED: April 29 1960
Card 3/3

UU-JUJ
S/195/60/001/004/008/015
.54--5oo B017/BO55
AUTHORS: Tolstopyatova, A. A., Balandin, A. A., Stshizhevskiy, V.
TITLE: The Kinetics of Alcohol Deh:.!dration on Tungsten Oxide and
the Energy of Carbon, Hydrogen, and Oxygen Bonds With
Catalysts
PERIODICAL: Kinetika i kataliz, 1960, Vol. 1, No'- 49 PP- 558-565
TEXT: The kinetics of the dehydration of ethyl, isopropylt n-butyl and
tart-butyl alcohol and cycloh6xanol on W 205 were investigated under
isothermal conditions. This catalyst was also used to study the de-
hydrogenation of methyl alcohol and 1,2,3,4-tetrahydro naphthalene.-The
catalyst was prepared by subjecting the yellow tungsten oxide WO 3 to heat
treatment in air at 350-4g0 0C for 5-6h, and subsequent treatment with
alcohol vapors at 200-390 C. Thermal effects in dehydration reactions of
n-butyl alcohol are shown in Table 1. Table 2 gives the apparent activa-
tion energies of alcohol dehydration on the tungsten-oxide catalyst. A
relation was found to exist between the apparent activation energy and
Card 1/4

88360
The Kinetics of Alcohol Dehydration on Tungsten S/195/60/001/004/008/015
Oxide and the Energy of Carbon, Hydrogen, and B017/BO55
Oxygen Bonds With Catalysts
the structure of the alcohol. For ethyl and n-butyl alcohd~ the apparent
activation energy of dehydration is 30 kcal/mole, for isopropyl alcohol,
24 kcal/mole and for tert-butyl alcohol, 18 kcal/mole. The true activation
energies of alcohol dehydration (isopropyl and butyl alcohols) were
determined at 26.1 kcal/mole for isopropyl alcohol and 33.4 kcal/mole for
n-butyl alcohol by means of the kinetic equation by Balandin (Ref. 20).
The relative adsorption coefficients of the dehydration products from
n;C,H6OH and iso-C,H OH as a function of temperature are given in
T b e 3. From this il may be seen that the relative adsorption coefficients
are independent of temperature. Results obtained in the kinetic
determination of the dehydration of n-butyl and isopropyl alcohol are
shown in Table 5. The true activation energy is 3 kcal/mole higher than the
apparent activation energy. The alcohols to be dehydrated are oriented
with their functional groups towards the surface of the catalyst:
C - C'~
H 0-
The kinetic method was used to determine the energies of the bonds of the
Card 2/4

I
The Kinetti--s of _lcohol Dehydration on Tungsten S/195/'0/001/004/008/015
Oxide and the Energy of Carbon, Hydrogen, and B017/BO55
Oxygen Bonds With Catalysts
carbon, hydrogen, and oxygen atoms with the active centers of the W 205
surface. The bond energies were found to be a function of the structure
of the alcohol. The energies of the bonds of reacting atoms and molecules
with the surface of the W 205 catalyst are given in Table 6.
Table 6 Activation Bond Energies
Alcohol Energy of '~H-Cat qc-cat %-Cat
Dehydration
n-Butyl 29.9 56.7 24.1 39.4
Ethyl 29.4 56.4 24.5 39.7
Isopropy! 23.7 52.6 27.6 43.5
Cyclohexanol 21.9 51-5 29.5 44.6
Tert-butyl 17.8 48.7 32~2 47.5
I. Ye. Adadurov and P. Ya. Krayniy are mentioned. There are 6 tables and
25 references: 24 Soviet and 1 German.
Card 3/4

83360
The Kinetics of Alcohol Dehydration on Tungsten S/195/. 60/001/004/008/015
Oxide and the Energy of Carbon, Hydrogen, and B017/ 055
Oxygen Bonds With Catalysts
ASSOCIATION: Moskovskiy gosudaretvennyy univerait~.-.t (Moscow state
University)
SUBMITTED: May 13, 1960
Card 4/4

TOLSTOPYATOVA, A.A.; BAIANDIN,A.A. ; STSHIZHEVSKIY, V.
Kinetics of dehydration of alcohols on tungsten oxide, and
energies of the bonds between the catalyst and carbon,
b~*&rogea, and oxygen. Kin. I kat. 1 no. 4:55B-565 N-D 160.
kMIRA 13:12)
1. Mookovskiy goeudaretvannyy universitet
(Dehydration (Chemistry)) (tungsten oxide)
(Chemical bonds)
---- ----------

s/o62/6o/ooo/oo8/1o14/f03,3/XX
B013/BO55
AUTHORS: _T Balandin, A. A., and Matyushenko,
_qjg~tq,Uatova, A. A.,
V. Kh.
TITLE: Determination of the Bonding Energies of the Atoms of
Organic Molecules Reacting With the MnO Catalyst Surface
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960,,No. 8, pp. 1333-1336
TEXT: The present paper is a continuation of the investigation into the
transformation of alcohols on manganous oxide begun in Refs. 1 and 2. The
experimental methods and catalyst 1)roparation have been deaoribed previous-
0 0
ly (Ref. 2). Dehydration was carried out between 330 and 380 C. The gaseous
products consisted of unsaturated hydrocarbons only. The first series of
experiments was performed to determine the apparent activation energy
(Table 1, Fig. 1). The siativatton ontirgy calculated by manna of tho
Arrhenius equation from the relation log ni - f(I/T) was 24.1 kcal/mol.
Relative adsorption coefficients of isobutylene (Table 2) and'water (Table
3) were determined. The determination of the relative adsorption coeffi-
Card 1/3

Determination of the Bonding Energies of the S106216010001008101410331XX
Atoms of Organic Molecules Reacting With the B013/BO55
MnO Catalyst Surface
cients and their temperature dependence permitted calculation by the
method described in Ref. 5 of the changes in free energy, enthalpy and
entropy produced by displacement of trimethylcarbinol from the active
cent'ers of the cs,talyst by isobutylene and water (Table 4). The true
activation energy for the dehydration of trimethylearbinol, calculated
fr~om the relation log k = f(11T) (F_ = 31.0 kcal/mol) was found to be
kcal higher than the apparent activation energy ~E' = 24.1 kcal/mol).
the strength o~ this investigation, the authors were able to determine
6.9
On
the
bonding energies of the atoms reacting with the catalyst surface according
to the well-known method (Ref. 6). These reactions are:
C-C C-0 C_f
I I I I I
H H 11 11 0
(I) debydrogenation of hydrocarbons; (II) dehydrogenation of alcohols; (III)
dehydration of alcohols. The following bonding energies were found:
~H-k - 50-75, QC-k = 26-7 and QO-k = 36.8. V. N. Kondratlyev is mentioned.
Card 2/3

Determination of the B,,,ndirjq Enert,n;ius cf tiie S/o62/60/000/008/014/033/XX
Atoms of Organic Molecules Reacting With the B013/BO55
MnO Catalyst Surface
There are 1 figure, 4 tables, and 8 Soviet references.
ASSOCIATION: Moskovokiy gooudlarstvennyy universitet im. M. V. Lomonosova
(Moscow State Univergity.imeni M. V.. Lom.o.nosov).
Insti-t~v,o-rgalliclle-s,k-o-y--khimii im. N. D. Zelinskogo Akademii
nauk SSSR 'Inatitute of Drt~anic Chemistry imeni N. D.
Zelinskly of the Academy of Sciences USbR)
SUBMITTED: January 14, 1959
Card 3/3

s/o8i/60/0Q0/621/Oo5/bl8
AOO5/AOO1
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 21, P. 50, # 83983
AUTHORS: Tolstopyatova, A_A . Balandin, A. A.
TITLE: The Determination of the'Energy of Banding-With Oxide Catalysts by
the Kinetic Method for Developing a Theory of Catalyst Selection
PERIODICAL: Probl.-kinetiki i-kataliza,,1960;'Vol.- 10, pp. 351-355
TEXT: The authors determined by the kinetic method the bonding energies of
hydrogen, carbon,,and oxygen w1th various oxides and'showthat, In riccordanco with
the theory, the molecular structure, the catalyst's nature, and the mode of the
catalyst's preparation affect the values mentioned.
Summary of the authors
Translator's note: This is the full translation of the original Russian abotract.
Card 1/1

S/062 60/000/010/019/031/XX
B002/~060
AUTHORS: Balandin, A. A., Ferapontov, V. A., and Tolstopyat-ova, A.A.
TITLE: Ability of Cadmium Oxide to Dehydrogenate Hydrocarbons by
Catalysis
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 10, PP- 1751-1758
TEXT: The authors based on experimental work made on the dehydrogenation
and dehydration of alcohols by means of oxides to make a theoretical study
of the ability of beryllium oxide, magnesium oxide, zinc oxide, and cadmium
oxide to dehydrogenate hydrocarbons. For this purpose, the activation
energy was calculated on the basis of the multiplet theory (Table 1). The
average value found for the adsorption potential of hydrocarbon dehydroge-
nation was 51.3 for beryllium oxide, 70.7 for magnesium oxide, 116.2 for
zinc oxide, and 132.3 kcal/male for cadmium oxide. The catalytic properties
of cadmium oxide were studied experimentally. Cadmium oxide was synthesized
by precipitating a cadmium nitrate solution with ammonia, and causing
hydroxide to glow at 5000C in air free from CO and was examined by X-rays,
21 0 0
Dehydrogenation of cyclohexane was studied between 458 and 540 C (Table ~4.
Card 1/2

Ability of Cadmium Oxide to Dehydrogenate S/062/60/000/010/019/031/XX
Hydrocarbons by Catalysis B002/BO60
The reaction starts at 487 0C; at 5220C the catalyst is completely reduced,
and dehydrogenation stops Dehydrogenation of cyclohexene to benzene takes
place between 470 0 and 52~ 0C (Table 3 B). No cyclohexadiene is formed in
this connection. Conversion of butylene to butadiene in nitrogen atmosphere
takds place between 575 0 and 6050C (Table 4). The degree of conversion
was 5 *6% at most. Conversion of piperidine to pyridine was examined between
4650 and 5200C (Table 5), and is believed to take 0place over piperideine.
Metharie does not reduce cadmium oxide between 500 and 5950C. It wasconclud-
ed from results that two different types of reactions take place:
1) a) C4H8 ), C4H6+ H 2
b) CdO + H 2 b Cd + H20
II) CdO + C 4H8 --4 Cd + H 20*+ C4H6
0. V. Krylov, S. Z. Roginskiy, and Ye. A. Pokina are mentioned. There are
1 figure, 5 tables, and 26 references.: 24 Soviet, 1 US, and 1 British.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR (Institute of Organic Chemistry imeni N. D.
Zelinskiy of the Academy of Sciences USSR)
SUBMITTED: June 15, 1959
Card 2/2

S/062'/60/000/D 11 2,/-D02,~020
B013?BO55
AUTHORS:
TITLE:
Balandin, A. A., Jols~ppyptova A. A., Konenko, I. R.
I---- -)-s--, -- -
Investigation of Catalytic Transformations of Isopropyl
Alcohol and Cyclic Hydrocarbons on Titanium Dioxide (Anatase)
Using a Differential Thermocouple
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 12, pp. 2o96-2102
TEXT.: Zhe authors of the present paper investigated the dehydrogenation and
dehydration of isopropyl alcohol (Tables 1-4) and the dehydrogenation and
irreversible catalysis of hydrocarbons, cyclohexane (Table 5), cyclohexene
(Tables 6 and 7) and 1,4-cyclohexadiene (Table 8) - on a modification of
titanium dioxide (anatase) using a differential thermocouple (Chromel - cupr
nickel). The latter had 10 junctions each at both sides of the mica sheet
to which it was attached. All the 20 junctions were on the one half of the
sheet. The distribution of the catalyst in the quartz tube containing the
thermocouple is shown in Fig. 1. A continuous reaction vessel was used for
the kinetic experiments (Refs- 4 and 5). The temperature was maintained with
Card 1/3

Investigation of Catalytic Transformations of S/o6 6o/ooo/o12/002/020
Isopropyl Alcohol and Cyclic Hydrocarbons B013Y-11055
on Titanium Dioxide (Anatase) Using a
Differential Thermocouple
an accuracy of +50. The evolution rate and quantity of gaseous products were
measured and recorded by a rr-n-lo (GSP-10) gas meter (Fig. 2). X-ray analy-
sis of the catalyst prepared from titanium tetrachloride showed it to be
anatase. The transformation of isopropyl alcohol on TiO 2 was accompanied by
a marked change in thermal effect during the first 15-20 min(Table 1, Fig.3a).
The analysis of the gaseous products formed in the reaction showed that
the alcohol is practically only dehydrogenated during the first 7-8 min:
After this period dehydrogenation and dehydration take place simultaneously
and after 15-20 min dehydration occurs alone. From a comparison of the
thermocouple data with the analytical data of the reaction products and t;:e
degree of carbon deposition on the catalyst surface it can be seen that
the rates of dehydrogenation and dehydration, and the carbon content of the
surface run parallel. The change in selectivity at otherwise unchanged general
activity of TO 2 is probably due to the acouinulation of carbon on the aiir-
face. Deposition of carbon on the surface of Cr2 03 (Fig. 3b), however, was
found to have no effeot on its activity and selectivity. Summarily, the
Card 2/3

Investigation of Catalytic Transformations of S/0062/60/000/012/0,02/10,20
Isopropyl Alcohol and Cyclic Hydrocarbons B013/BO55
on Titanium Dioxide (Anatase) Using a
Differential Thermocouple
authors conclude that a gradual accumulation of carbon on the anatase sur-
face almost entirely suppresses the dehydrogenation cif the alcohol -and
promotes its dehydration, but does not affect the total activity of the
catalyst. The catalyzed irreversible transformation of cyclohexene and
cyclohexadiene is suppressed by the accumulation of carbon on TiO 2Y whereas
the dehydrogenation of cyclohexene, cyclohexane, and cyclohexadiene is pro-
moted by this process. There are 3 figures, 7 tables, and 12 Soviet
references.
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinsko,go Akademi-i
nauk SSSR
(Institute of Organic Chemistry imeni N. D, Zelinskiy of the
Academy of Sciences USSR)
SUBMITTED: June 26, 1959
Card 3/3

B102016011341003103010331XX
B004/Bo64
AUTHORS: Balandin, A. A-2 Academician, Tolstopyatova, A. A. and
Stshizhevskiy~ V.
TITLE: The Catalytic Activitylof Tungsten Pentoxide
PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 134, No. 3,
pp. 625 - 628
TEXT: The authors investigated the dehydration of ethanoll isopropanoli
t-butanol, cyclohexanolg methanoll, and Tetralin7with -WO under iso-
11 1 2 5
thermal conditions. Blue W 205 was obtained from tungstic acid at
350 - 4000C in an air current. First, WO 3 was formed and then reduced to
W205 during the reaction with the alcohols at 200 - 300 0C. The reaction
apparatus operated continuouslyj and the liquid substances were auto-
matically added. The gaseous products were collected in an automatic
Patrikeyev gasometer, and analyzed with a BTM (VTI) apparatus or chroma-
tographically, In the liquid product of catalysis, the amount of
Card 1A

The Catalytic Activity of Tungsten _c/020/60/I34/C03/C3O/C-
.4 ~ VXX
Pentoxide B004/BO64
unsaturated hydrocarbons was determined by the method of Kaufman-Gall-.
pern. Since the endothermic effect of reaction affected the results of
measurement, the catalyst was diluted in a ratio of 2 : 3 with quartz
of the same grain size, the alcohol with water or with the corresponding
unsaturated hydrocarbon. Under these conditions, the process was iso-
thermal. By determining the apparent activation energy (Table 1) it was
found that the primary alcohols were dehydrated with the same energies
(approximately 30 kcal/mole), that the activation energy of the second-
ary alcohols was about 6 kcal/mole lower than that of the primary ones,
and that the activation energy of the tertiary alcohol was approximately
6 kcal/mole lower than 'that of the secondary ones. The reaction constant
and the relative adsorption coefficients z2 and z3 of water and the un-
saturated hydrocarbon were computed (Table 2) by Balandin's method
(Ref. 3) with reference to the adsorption coefficient of alcohol. Check-
ing by introduction of the experimental data into Balandin's equation
confirmed the validity of this equation (Table 3), Table 4 gives the
actual activation coefficients for isopropanol and n-butanol,, which are
approximately 3 kcal/mole higher than the apparent ones. For the binding
Card 2/4

The Catalytic Activity
Pentoxide
energies QHC, QCC, QOC
face of W 205g the follDwing
tion: Table 5:
of Turgstrin S102q6011 34/003/C 30/C33'/jrX
B004/BO64
of the H, C, and 0 atoms reacting with the sur-
was computed from Balandin's kinetic equa-
Alcohol Activation energy B i n d i n g e n e r g y
of dehydration QHC QCC QOC

- - - --- - - I~kcal/mol~j
- - - - - - - - -
- -- - - - -
_ - - -
- - - - - -
n-butanol 29.9 56.7 15-9 39-2
ethanol 29-4 56-4 16.3 39.5
iso-propanol .23-7 52.3 19.4 43.3
cyclohexanol 21.9 51.5 21.3 44.4
t-butanol 17.8 48.7 24.0 47.3
Although the hydrogen atoms and the radicals substituting them do not
directly take part in the reaction;
Card 3/4

The Catalytic Activity of Tungsten 3/02o/6o/i 54/003/C3,O/C33/;rX
Pentoxide B004/Bo64
H
C-C (CH3)they affect the binding energy between the C; H, and 0
H I I H(CH3) 'atoms and the catalyst. The authors mention a paper by
HffH
H
R 0 H 1. Ye. Adadurov and P. Ya. Krayniy._There are 5 tables
and 8 Soviet ref-erences.
ASSOCIATION: Moskovskiy gosudaretyennyy universitet im. M.V. Lomonosova
(Moscow State University imeni M.V. Lomonoa-Qv)
SUBMITTED: May 17, 1960
Card 4/4

TOLSTOPYATOVA, A.A.; BAIANDTH, A.A., alcademik; KONENKO, I.R.
Catalytic conversions of alcohols and c7clic Yordrocarbone on
titanium dioxide. Dokl.AN SSSR 133 no-1:130-133 J1 16o.
WIRA. 13:7)
1. Institut orgunioheakoy khimii imeni N.D.Zelinakogo Akademii
nauk SSSR.
(Alcohols) (11ydrocarbons) (Titanium oxide)

TOLSTUPYATOVA, A.A.; B&LUMN, A.A.; HATrUSHMO, V.Kh.
Dehydrogenation of alcohols and cyclohezene on XnO, Izv.AX
SSSR Otd.khim.nauk no-5'-787-793 MY '60- (MM 13:6)
1. Moskovskiy gosudaretvennyy universitet imeni M.Y.,Lomonosova i
Inatitut organicheakoy khimii imeni N.D.Zolinakogo Akademii
nauk SSSR.
(Oyclohexene) (Oyclohexanol) (Isopropyl alcohol)

VARI
as
2t :1
u't
-08

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All
It
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poll: V, d"'g i'll ;4
1 9'V4
p IRV
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tag
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Af

TOLSTOFUTOVA, N.S._Jjeningrad, P-49, ul. Lizy Ghaykinoy, d.18,, kv.1)
Occupational epicondylitis of the arm. Vest. rent. i rad. 36 no-5:
46-51 S-0 161. -r- -- 0'1IRA 15:1)
1. 1z rentgenologicheskogo otdeleniya (rukovoditell - prof. A.V.
Grinberg) Leningradskogo nauchno-issledovateltakoCo instituta
gigiyeny tcuda i professionallnykh zabolevaniy (dir. - prof.
Z.E.Grigorlyev).
(ELBOW-DISEASES) (OCCUPATIONAL DISEASES)

TOLSTOPYITOVA, R. V,
Work experience with parafin in the preparation of orthopedic
apparatus. Mad. sestra, Mosk7a no. 9:29-30 1951 (CUL 21:1)
1
1. Author is'a plaster-of-paris cast technician belonging to
the Bone Division (Head -- A.P. Sokol'skaya) of Ivanovo Oblast
Tuberculosis Sanatorium No 2 (Head Physician -- Honored
Physician RSFSR A. L. Gallperin).

157 j-~ 00 6 6 0
BOV/20-129-4-22/68
AUTHORS: Balandin, A,A,, Academioianp Karpeyskaya, Ye.Iop Tolstopyatova,
'j
A. A*
TITLE: On the Irreversible Catalysis in the Presence of Metallic Rheniu~_l
PERIODICAL: Doklady Akademii nauk SSSR9 1959, Vol 129, Nr 4, PP 795-798
(USSR)
ABSTRACT: Metallic rhenium, applied to active carbon dehydrogenates the
cyclic 6-membered hydrocarbons. On an ammonium perrhenate (Re-1)
Catalyst1small quantities of cyclohexene and-also benzene are
produced from cyclohexane (Ref 3). This is not the case on a
catalyst of a dioxane complex of rhenium-acid-anhydride (Re-2).
The authors investigated the transformation of cyclohexeneqon Re-1
and Re-2 to find the reasons for cyclohexene lormation on Re-1.
Moreover, the capability of rhenium to bring about irreversible
Catalysis (expression by N.D* Zelinskiy) was to be investigated.
The gaseous reaction products were collected in the gasometer by
V.V. Patrikeyev They consisted of hydrogen with 6-8% methane. The
experiments were made between 215*and 4650C.Por both catalysts a
temperature range was distinotly observable in which no gas is
formed and the process takes place according to equation
Card 1/3 3C6910 ~ C6H6 +2C6H12 . At higher temperatures hydrogen is separated,

67260
On the Irreversible Catalysis in the Presence of SOV/20-129-4-22/68
Metallic Rhenium
Catalyeates of several experiments with Re-1 and Re-2 were poured
together. After the removal of the incompletely reacted oyclo-
hexene benzene was chromatographically separated from cyclohexane.
Figures I and 2 show the results of various experiments which were
well reproducible. It may be seen from a comparison of the kinetic
data on dehydrogenationlof oyclohexene and the disproportionation
of hydrogen on Re-1 and Re-2 that the activation energies of the
processes aro in agreement on both catalys"U-s. Apparently both
processes stop at the same stage of reaction. Table 3 shows that
on Re-2 benzene is formed from cyclohexene twice as rapidly as from
cyclohexane. According to M. Yao Kagan and IN. A. Shcheglova (Ref 6)
cyclohexane is dehydrogenated on Pt by 4500 times more slowly than
is the transformation rate of cyclohexene. On the basis of these
data and according to bl. Ya. Kagan and R. Y. Flid (Ref 7) the
mentioned researchers draw the conclusion that the dehydrogenation
of the cyclic hydrocarbons takes place step-wise (see Scheme).
The results obtained by the authors are in contradiction with this
conclusion: cyclohexane is deby'drogonated on rhenium not according
to a step-mechanism but according to a sextet mechanism. Benzene
Card 2/3 was formed on Re-1 from cyclohexene about twice as rapidly (Table

On the lrraveroihie Catalysis in the Prooence of
Metallic Rhenium.
6 72 U_ 0
SOV/20-129-4-22/68
It may hardly be assumed that the dehydrogenation of cyclohexane
on two catalysts of the same chemical properties and on the same
carrier should proceed according to two different mechanisms.
Cyclohexene is no intermediate (in contradiction to the scheme of
references 6P 7) since it was not obtained in the reaction on
Re-2. Cyolohexene thus results from a side-reaction which takes
place to a small degree besides the sextet dehydrogenation. There
are 2 figures, 4 tables, and 8 referencest 7 of which are Soviet,
ASSOCIAT.'ON: Institut organicheskoy khimii im, N. D. Zelinskogo Akademii nauk
SSSR (Institute of Organic Chemistry imeni N.D. Zelinskiy of th
Academy of Sciences, US
SUBMITTEDs July 24, 1959
Card 3/3

VIKSNE, A.; VIL%WE, J.; DEVISOVA, U. (translator]; KASPARSONA, G.
[translator] LEGZDINA Zh. [L-erzdina, Z.) [translator);
POISHA, Ya. tpoisa., J.j (tranala'tor]; TOLSTOPYgO-Y".-
[translatori; ALKEKE, B.,, red.; BERZ3NA, K., red.; SILDIS,V.j,
tekhn. red.
[Riga Zoological Garden] Rizhskii zoologicheskii sad. Riga,
Latvijas Valets izdevnieciba, 1957. 1 v. (chiefly illus).
(MIRA 14:12)
(Itiga-Zoological gardens)

TOLSTOSHRY. A.V., student V kursa OMF
Methods of testing central photographic shutters. Trud7 141IGAIX
no.36:117-122 '59- (MIRA. 13:4
1. Studencbeskove naucbnoye obsbebestvo Mookovskogo instituta
inzhenerov gaodezii, aerofo oa".vemki i kartografil.
(Shutter, Photographic--Testing)

TOLSTOSHEYY A,N., assistenl~
Analytical method 1~ . i,~,,,Ixmining the basic norms for swit'Obing
operations. Mauch.tru-jy KHIIT no.55:39-50 62.
Device for recording the parameters of the movement of switcher
locomotives (electric switcher recorder). 81-87 (MIRA 16:10)

KONIKOVY P.S.P ~ kand. tekhn.nauk, dote.; DONTSOV, A.Ya., inzh.;
YURCHENKO, I.F., 1nzh.;-ANGELSYY.0, V.I., retsenzent;
BABENKO, V.I., retsenzent; ZAPREVSKIY, G.S., retsenzent;
KRDINUS, G.Kh., retsenzent; MANIN,-I.I., retsenzent;
NAUMOV, G.K., retsennent; TOLSTOSHEY IA.N., retsenzent;
TUCHKEVICH, T.M., retsenzent; FEDUMTS, Y.M., retsenzent;
FELIDMAN, M.F., retsenzent; FRANKOV, N.Ya., retsenzent;
USENKOI L.A., tekhn. red.
(Establishing work norms in railroad transportation] Tekh-
nicheskoe normirovanie truda na zheleznodorezhnom transporte.
Moskva, Transsheldorizdat, 1963. 366 p. (MIRA 16:9)
(Railroads-Production standards)

LF,BEDEVA, A.P.; TOLSTOSHEI.- O.N-
on of soil with hexachloran from its use in agriculture.
Contaminati 04IRA 1/,:11)
Gigj i san. 26 no.3-1:15-18 N 161.
1z Ukrainskogo nauchno-issledovatellskogo instituts. komunal'nOY
gigiyeny. (CYCLOEMYXE) (SOIL POLLUrION)

TOLSTOSHEr. 0.H.
Enlarged conference on sanitary protection of the sea near the
shoreline. (;Ig. I san. 24 no,1:88-89 Ja '59. (MIRA 12--2)
(SBA WATER-POLWTIOII)

BARAN, N.A.; TOLSTOSERY, O.N.
Hygienic problems of sewage and waste disposal in towns of the
Donets Basin [with summary in ftlish], Gig. i sane 24 noo2:22-26
7 159. (MIRA 12:3)
1. Iz Ukrainskogo, nauchno-iouledovatellskogo instituta kommunallnoy
gigiyany.
(SANITATION
hyg. problems of sewage & waste disposal of towns
of Donbas (Rue))

TOISTOSHEY, O.N.
'-'4,vgienic featuret3 of garbage disposal in Kiev. Grig. i sart. 23 no.12:60-
62 D 158. WRA 12: 1 )
I Iz Ukrainskogo nauchno-isaledovatellskogo instituta komimmallnoy
gigiyeny.
(SAMITATIOt-
garbage disposal in Russia (Rus))

. TOLSTOSHRY. O.N. Wyev)
Significance of a regular trash pick-up ser7ice for the public
health in cities* Vrach.delo no.6*621-624 Je '58 "'PIRA 11:71
1; UkrainsKy institut kmmmumnllnoY gigiYeavo
AUD MITUSE DISPOSAL)

TITLE, 54tenttric-tuchnt~.1 C-f4r'Au' of t-le I X In
1959 (N.-b-%.khnICh..k.Sa UITU 1 9 M9
PUZOUXULl Ixv**ti,a wyoohLkh uchabn.Ykh Z%Vwdtr.11. ro'o04oxIXA I aor.f.t..-- C>
yeake, 1959, Xr 3. pp 144 - 146 (034)

LUTRACT. Th. periodic dal.Atifia-t.ohni.al 0.0f.r..O. Of the
laotit.t insh.n.rov 1.0d.ZLL, I kortografli
(VQ0QOw Institute of Geodetic. Aerial Survey and Cartoljmphic
So4inoors) was held of. April 22-24, 1759. with the partialps-
$ion of 500 persons. 31 lecture. *or* delivered. Th. I.tr.-
ductory speech was hold by Proro.oor a. A. liatov. Canditsta
of Philosophical Sciences A._L._,LYJjX2' lactir.4 on -The Out. C_
Standing Work Of Materialistic Ph1l..;pbi*i Candidate of T..A-
steel act*".. I. T. lonarombkov on -4 G--
4" C4 didt. OrT.Mrc-l a G~~ 1. Ragrotimi On
"Aa4uracy of the Solution of the laver.# position Computation
th Coordinates of Different Geodetic Sy.S.Ra-I Condidato, of
W
,no Joel Sciences P. Y. 3hQkJA reported am ~Qravlmwtr7 in
!.
card Today-* U.S. of D~vilijmo.t-j Can4ldst. of Technical Sol*-..
-
malm~
af the Rules 06vernIng
1"Q1!Ah1"_'i6 *1nvsCt19At1cR
Uatrib.t-ta. of Irrare Than C*a.r&ljzjag %he golLsf in phat,
grOphyal ro-t-grad"to Student to. 1. Mokb.. on ?be Jorl *-.
_
of the Rounding Zrt`or on the APiio~~j
~CiZTttonm of U.-
Zq%AtiOA SYG%4"". p*%t-6rLdUat* Student 1,k~ PI:9,4* "period
.on
llh
aSolatIcA of Sys$." 1, be Co.po"Ation of Co.-
i
dot.is'- Docent 1, X, KoUlfv"ov, dealt with -The Uporl~nce,
;
'
is the JLppI1OLt1%Q at pmr%llsQtJQ r;
jygamaoatry With Short
3400
Od
Cozst '- Doctor Of Physical and hath.-
at Vertical Basis
:'~
a
mail a I no A. V. Fayasillb.rg lectured an 'Son. Integral.
:
Froo, the Theory Lppltzation to the Me.
ohonla. of Artificial Earth S.t.llltoa~l Candidate of Tochal"I
S11Gn4*4 A- S. VAIR" on -The Itoreocomparator With Correctors-.
A-G1_Gts--Q9_-_r-.-Nr., Wt. on -7hatosr-ma-t-la U-thoa of us-
UrRIA104 9E_eTTUVuu4o8 or Luminous Claude-. Candidate of Tech.
n1c6l U16MG49 on -The Contrail---
tJQ1 Of the FOrm-la* far th. 11.
Sarvol 4ut& %he &1t&
..a rl '. C.
1"I A Sure."d f Sol.."$ 4,-JL-
ol 4 d C--didt- Of T.chnl..& Sales... N. P. Z;Ak.j...
lo
i
Cazd 2/5 r.p.
1', 1. Send Tjrp- L.rL.1 _iz~ - R_
:
_SiJel =_
Sciences B. N. Rodlonav spoke an the
63trabo
oplo Collimator I~J-IAXXha3 rt;orlod
OR &~Catit& Geer for the Antomatic "%ry of the Airplane
:;,
to tb* Aerial Photography Path-. Post-graduate Student ~~ ~i.
luen.t.a.
"OpiloAtIon of the Inotanta...- Photo-
th
I
n
:
=* o
gr%phy for& 11.1"r. 2 it.&,.
e
spoke an the -Computation Of the Aerial Co.* I an. ~N
Chief T.chul.1.6 or the Cootkhboator%
*-
ClcGP3m-- TdM GO'So.. and Teel. &stated to Phot at"
dOl1t4 342's-ying Operstionawl Doctor of 2achalcoa SOL*..
:
OTh
Problem Cono.rALU the Content* of the
lo
3o.1 or 0 000*, D-*., .1 1.ab.,c.1
:
th
2 2, 11
_1,-Exg W an *vLawral Deposit- In the 0552
S.Iona..-A, br,~
1
and Th* ir Ropro4uctton an Economic tUpo-; Assistant 0.
_x2JA_. the method of Geographic Ino..i1gti.. on th
During the Preparatory Editorial Work am the Cart
"
phhe
.
Object (prom the Working Zzy.rionco Acquired by tT.
r.-
key. (NaLloborrlay% Empeditsom, of the MIX" 1 1 1955)-. '
ifit at AM -olt with ~rb. Problem r Y,
_
*
`
A
'
2
'
'K
I
o
d

Ptcv1V1 Sh
~
iA11
4
- h
tLon of a list '-b1t..
f
-
v4
Pr
Xm
it.ry

t
he Upodr.phic Key On the Scale of I - 10000'. C..dldt*
T
ochnic.l 3cion.., poke " _MPV QC C-Iti~.twd
~~
Lr..a In the CROPrah.R
of the Candidate
of Technical Sciences _L -1. Men txhtka, dosal oLth 'A. 3. Popov
-
_
5_im-f_(0_Q_tb- 1001b Birthday a
t
. I ... agar. 7-
do LoDtl:
"i-
o
1. 0.p,)". Scalar I.Outror x 1-.t.r.d a.
'

"Mirror 1,eas Objectives with
- Prof ... or
11
'
1
Sfirlf of C"pecoatin,
l the Tarta-
o:
::
n
;o
;
and
.
.
,
A
racy 1. the Of ph,.
f T.ch.lo.1 Sets.... T. AL .
C.:did.t.
_ArA=_
'
r_
';
aaL!ZAL dealt it; 'M thuds Measuring J.v "tlaA
t or. Can-
corn Ing Optical Main Charoct.ri.tI.s of Aerial Comers ObjeotIvem
uth Dropping Atmospheric Prosoure and Towporstar*-. Xndlneor
loc~ur*d on -Vertical A 11. 3y.t.- of 914h-rr..
oisl-n Optical Theodolites-. A,wl.t..1
spoke On
*
I h.
.1
5 A-4 by the Lid of Telescopes With Z.A. pl.t..-. past_
4
- -1
1
A.Iza
, ?. P!
Z4Xh,r,1 dealt 111
l
gr :-I t
* of
Card 4/~ _
:
::
.
:
!
o: art a ?air of Stereoscopic P.r ALt hary
~
b
h-14 an April 24 the Chief or the Cl-.y. up,
'1
*
"
'
t
Ikartograrit XYD SSSR (Chief Ad~laixtratw. N
1
.
'~
deep and C. rtography of the Ministry of I.t.r.al Affairs of
th: U53")-A,11~Urmrov lectured On *?he Swvsn-y,ar Plan &cd
th D ... -bt of Topoir pL1c_S,,odqt1c ead Cartographic %.rk..

3(2).3(4)
AVMM1 so" Gi~vwu SOT/6-59-6-21/22

VITUS chronicle (Khrovik.)
PZXXODICLL, Goodastys. I ka~~ogrsfjs. 1959. Nr 6, Vp 74-75 (USSR)

ANSTRAC?$ At the Koskovskly inatitut Inshenerow goodoxii, aorofotonoyeaki
I kartogragIl (Moscow Institute of Geodetic, Aerial Survey and
Ce.rtographia Inenears)o the Ordinary Scientific Conference
took place an April 22-24-- A. 1. Docent, Candidate of
Philosophic Sciences, spoke cn "The. Outstanding Work of
latarlali.tlo Philosaphy% A. N. BarecOv. Chief of the Glavuays
upravlanlye good*xii I kartografli (VAin Admilvalstration of
Geodesy and Cartography) spoke "On the Satvo~yesr Plan for the
.11 -lopment of Top graptic.good.tic and Cartographic Work* *Tb*
1.1lowIng rsports :or. delivered in the geodetic sections
A. X. Payvallfbar. Profeasor,"Soms integral. of the Surface
Th. reas &ad Their Application to the Mechanics Of Ax-tiflals.1
3=11itas of the Urth-.- A. T. Kondrm.hk.,v, Docent, *BAdjo.
electronics and Osadoay-.- G TV. B-a-to-L, Docent, "Accuracy
the Solution of Inverse ;;.Ittau Computal-c" by the f
Different Goodqtlo SZoteasQ.- tt
?-P kin a C
_2,
_
-Grmvi-tr7 in the Pro.*.' ~ts. of D.T.1o;.*SSt-.-Y
Assistant, "ported OIL the infliewi of rounding error& on the
socar cy of solution of linaLr,aluati- ayst2ma.-T, Djal'sh
C--41::ta of Technical Satenoom, spQko on the oravestigation
the Roa a of Distribution of Errore in Gonaralistag tho 12611st
LAS VrUdo~ P)4t-g-.dUit. Std.ot, reported an I

81
I tion of *-Locar ysta.. far the adjustment of p.datio
u
:0
1.
1k
s.
7. X. do .... t-t.d an Apparatus
;;7
do signed him far POVL114".1- trs7sraLng elth a short on "Lane
vertical bas!&.- The fol?av-na r,;iorts ware d.1--vored in the
40-pbotog.od.-Io oootio., A,_%_yAj4a~ax, Docent. "ported on
& parallactic roductr, an ad&-Itlaral lariao to the stereo.
acispax.tor.- ~ D~'ant. eyoko an the possibility
Of 96"MILS,149 the formulas for the air suroeY of Outlines and
wT--oA I P Zskazn~v, Docents, "ported
B. 1. R.dI
--
an & %id-hap. Sihutt.r-Tc-r-&-~-. =aossiora., R-
Radio=, an SS at"Soo-pia eight, 3. S. Radio-- anA
-
-2SjM
L. Yorkhov on the .*home o; a computing device for
ar X,
_
the automatic ntr7 of the airplane, -Into the rants tar air
survoya
11. P. hanLy pr*sauted pass Simplifications for the
_Are
Card 2/4 j
compute tar. of c3nat "-Ts of sarlov!
................
it..:~sdoats Student, spoke an the use of rapid filo'recarung
for *be IcwS&t-.Sstjou of -rjal-oamora shuttors-r-T -G-1.bL1vlj
c. 3p,.= RSYSR. spoke ICA sones
r of the coo takhkontom
M41m
t
Masult and Tasks In the rtvl~ Ica Of LLrg-----l- Photo'
:
thoodol4to SurS,.ys'.- Th. fall--ind ro;orts -.ra dftli-rOd 1%
tha asriagraphlo saiat.'an, T. 1. Skhay spoke an the
-
FY,%5,000- Professor
I
content of the ne. may a..!. of
nskiy spoke on 'Iduartl R-scw--- Of the VSU
aS;h
r*c
b
r

intitt'a a Z~'=.!l M-ps'.-
I,- rpr. - d'k2-
,;
:
!L
VE:
X
vothad of gooera;hio field researth
on th.
Assistant, reported
during -he p_p_&t r7 .11 1., e.,k at ho object of
,
c
asritcgrvphy~ Assistant, reported a- tL.
l
~~
l
,.Ntinz of wooded flat country on
t
f
I.Yr.vezont oAk
the topographic map .0 . so.,-* of I , 10,000.- Tn. 3. Bill.h.
A.&I t, "ported on are of pertzoat
t
rof %he Oblast'- In the section of building of
&%U%
syparatue, 1. 1. X~!a,V-L~a- D-ont, o2ok. or. the life Of
reported an rafl#otlug
a '. accuracy im
as tb. lu~
CrZI as r M. SS.-q, on -rtical
"W systems for highly 'pt th.. d~ -1 1 t", T, S. a",

C
ard 1/4 plat
Assistant. a- ightj1g ith with Sao*
- P. P. Zakh.ra,, Assl.tan', ~. th, of
"r. O.PI-.

TOLSTOUIWOV, A.S.
Practice of jonducting P,
vestigatior4s. Geod. i - Ii2llna~ topo~phic and 98~~ic ir
. Kart- BO,2:49-53., 1639
(Topographic mapj- (MIRA 16-3)

AUTHOR: Tolstoukhov. A. S.- Graduate Student S ro~,, / I
TITLE: Some Peculiarities in Representing the Relief of Plains on
Topographic Maps on a Scale of 1 : 10 000 - Shown in thle Case
of the Terek Delta (ITekotoryye osobennosti izobi-azheniya
ravninnogo rellyefa na topograficheskikh kartakh z:.~asshtaba
1 : 10 000 - na primere dellty reki Tereka)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Geodpzi,~,-a J. aerr-
fotos"yemka, 1958. 1Tr 1, pp 123-131 (USSR)
ABSTRACT: Topographic maps are used to a large extent in studying the
characteristics of various geographical areas in the USSR.
This is true especially of maps on a scale of I : 10 000.
These maps in use today do,horiever, no longer meet all re-.
quirements. Above all, the representation of the relief with
the micro-forms in the plains on topographic maps (large
scale has not yet been SUff~C4 ently developed. 'he au-chor
and his collaboratoistherefore selected the delta of the
Terek River for their investigations. One of the -oacuifari-
ties amongst others of the delta is the elevated position
of the central river bed in the delta (up to four meters).
Card 1/3 On both sides of ',-his river bed the terrain gradually fails.

SOV/1 54-56 16/22
Some Peculiarities in Pepresenting the -Relief of Plains or,
S - -e Terek Da'
;T.aps on a Scale of 1 : 10 000 houn in the Case of th Ira
The numerous other branches of the Terek therefore are situaT-
ed lover than the central river bed. innumerable small eleva-,
tions, dome-shaped and overgrown, are characterlcti3 of -11-nis
delta region, as well as the amorphous salt soil. The author
discusses in detail the methodsof relief representati(;n de.-
veloped by him. The combination of the micro rel--ef (the
Uound with small dome-shaped elevations), of the flora on
the one hand and of the semi-arid area on the oth,~r hand,
requires a comprehensive and uniform representaz~ion. ~?he
author proposes new topographic sy-pbols as i3arks of the small.
dome-shaped elevations. With respect to the flora the auther
sugggests the method already developed by K. A. Borodira.
The elevation marks and fig-ores should be printed on topo.
graphic maps in a way that they fbIlow the turns of the con-
tours. The present density of topographic marks within one
square decimeter has been insufficient and shoald therefore
be increased considerably. There are II-I fi,-,ures and 5 ret'--
Card 2/3 erences, 5 of which are Soviet.

SOV/154-513- 1 -16/22
Some Peculiarities in Repres'enting t~ic~ Relief of Plains on
Mlaps on a Scale of I : 10 000 - Shown in the Case of the Terek Delta
I e k . I
ASSOCIATION: Iloskovskiy institut inzhenerov Geodezii, aerofot086 y M,4
,kartografii
(roscow L-ngineering Institute of Geodesy, Aeroplictogiaphy,
and Cartography)
Card 3/3

"Maoxg Sollaftko.. V. D.. Canclid.t. of Technical Set .... 4
TITLAa Saleatific sad T"hntc&l Conference of the MI!GA 1 9 (M..chno-
takhatobaskaya konforentalys NIIG4 I K) It
FERIODICAL& Isweettya y..jktkn uch.boyich zxvdaniy~ Q.odvz1YL I
aa,rofotc.1y*m". 1958, Ir 2. Vp (U9.ig)
A05TR4Cr. 0, A. Gtn1b-,, DQG..z. Candl4ato or Technical Scivaces. spews
an Th: 9.1allood, Between Distortion* in Cartographic Prnjec-
L
L Badc. C n4joate or Technical ftclett-~sm. re-
tl.
A
'

port;i *T pagrapht D
v bft-%v4 From to# Airplane and
; alp

ILeapter at Aerial Phatographe In Cartographing Inaccessible
4
:
1
, 'a-*' * -1 Ilto4khll, 0.1i.r
Reprod o"Krvi,c.
I 1 10 000 000).~ 0. D. likhtar. Professor, Doctor of C.ograph.
troct%r. of
lost Oal
a"* Isalt
ith
th* ba&L
hic a
geo
gra
::
o:4
u
h
u
...... 91 and he cq on, .., .11 1. 1 pea liarition or
p
:g
the real on.
Ledia..r To. U. Toklistay reported on the conforrucs held to the
UTICA IIt (Moscow, toaln..ring r C.co..y, k.--
Card 115 photography. asut Cartography) fros, Way 6 to 10. The part%cl.
pan& discussed various qaeatio" In relation with the damiga
L
at a
detical a" cartogrophical tastrustenta. Kore than 3C0
fram away universLtit. " scientific XnotltaLLone.
401:6ates
s
" it . 02 repreavatatives or different agoncleA to
Lenin rad S
ardLovalL, and other wti-ip-tat in
' ILLS
'
a :Dnf
:
::
blo orefto Th D4pugy Uesd of the COCK# W. D. Koo-mhlu.

"ci.n1ific Raw
V-4 a pap ws,rmn 1. A.ri.1 Cast-
:r ..
3. T *, -se Coosa, , "'0 "" .. " present "1.%. of Pro-
.
d409. or Irueents. and Development of New, To-
eats.. Dr-by now, Profeamor. gave a Itcture *a taw

t
rids I instrument. In tn. U. IR .04
on
dew,
ts
-
4
0
n
1
*
, 4
1
0
t
t
c
1
r
1
"
p
q
lh "'
121 l
11"
!Q
r
,I.= r
t
la
t
rb
. 1
mt
:i 1.
L
*
t
.
.
4
nd
phot
M
r I "
a
D%
1
I
a
g
.
,am "s am mail &A t"
LMmv4zs for aerial phoLogmpny were
trux:
,,,
:
4 -0- *at f- 1. Y I.-Ye, and E.Sln,.r .., T. Z4.bnzk.e
-:

report a ang I-
4 a 0e04 1 1.,..~rur I=C trusents. gn4in- ~. V,
Resbc Ith the new Zrw1I1wyd
1-1~6
r
b::7
C dat es. .4
Ma.r. Technical 1.1
;
;.
range finders of greater precision. V. a. Vatichko. CA"%4a--
of ?.Chat CI Saiwaicos, an optical range finders of mo4zua
.c-
Card ?I, ~:
M. cy. KndI:_r I- I. A.drl&no,a sod To. P. F.ptv. C-'dd. aI
pOk. .0 madal.t.r. of optical
ftyst"l-Hathaftet.a.l. so t*UOA.
;.:
range finders. X^S I .. r L. V. zzo,ich spoke an the us. Or
Itot alloys in tn* manatecture of geodetical Instruments.
lkoe-at S. U. Mira4aw and Zadinewt, T. K. Sy..ka rapt,%.d
yr.ductLas, Of geodetical instruument..
mem, developments to th
:,
C-Ip ..It 'it' he opt "st"t" to
loa
l
Prof , I
I
ngirtear b. A.
L
am*dot a truseen .. ... r 1. I.
r.9o
.t T. A. Krt,mwli., r;*.wswz 1. X. Firson. ad Eruqx....
Sh Alin, Dcc
p- rticipoints on the results Of Ch.
Vshk , Info-od th
A.
:
SOL tific sad Techni 041nf.r.-. held 1. Kly., (Planning and
L
;o
production or 0"44tical
Card 5/5

TOI~QTOUKILIOIFI A. S., Ass't.
"On the Representation of Re-liefs of Plane Areas on Topographic Maps"
report presented at a Scientific-Technical Conference at Moscow Inst. of Geodesy,
Aerial Photography and Cartography Engineers, 24-26 April 1958.
(Geodeziya i kartografiya, no. 6, PP. 79-80, 1958)

op irs nt
Certain peculiarities in representing lowland relief on topographic
maps as exemplified by the Terek Delta. Izv. vys. ucheb. zav.;
geod. i aorof. no. 1:123-131 158. (MERA 11:7)
1. Moskovakiy institut inzhenerov geodezii, aerofotoa*yemki i
kartograf ii.
(Terek Valley--Topogreihical surveying)

TOLSTOUKIIOVA., L.I.; BYKIIQVSKAYA, A.M.
1-131 treatment of pootoperative rocurrencoo of thyrotaxi-
coois. Viod.rad. 7 no,11.5-9 14162. (14IRA 16:9)
1. Iz kafedry reptgenologii i radiologii (zav# - profo Ye.L.
Kevesh) Kuybyshevskogo meditsinskogo instituta.
(HYPERTHYROIDISM)
(IODBfL ISOTOM-TIIERAPEUrIC USE)

UZRANSKIY. Ys.G., prof.. XACHANOVA. S.0., dote., T0LSTOUKKOVA,.LI*.dots.
,
Fifth conference of the Ural branch of the All-Union Society of
Pathaphysiologists, Pat.fiziol. i ekspeterap 2 noJt&J-62
MY-Jf- 158 (MIRA 11M
(PHYSTOLOGY, PATHOLOGICAL)

UZHANSKIY, Ta.G., Drofesnor, iDredeedatell pravleniyL4 TOLSTOUKHOVA, L.I., dotsent.
sekretart.
At the Ural branch of the All-Union Society of Pathophysiologists; on the
organization and the first conference of the Ural branch of the All-Union
Society of Patheiphysiologists. Arkh.pat. 15 no.2:90-92 Mr-Ap '53.
(MI-RA 6:5
1. Ural.!,Bkiy filial Vaesoyuznogo obshchestva patofiziologav.
(U]~al Mountain Region--Physiology, Pathological) (Medical societies)

BYKHOVSKAYA, A.M.;_TqIZTOUKHOVAl L.I.
Treatment of tbyrotaxicosis with radioactive iodine. Med. red.
8 no.12:9-13 D 163. (MIRA 17:8)
1. Iz kafedry rentgenologii i radiologii (zav. - prof. Ye.L.
Kevesh) Kuybyghevskogo maditsinskogo instituta.

UZHANSKIY, Ya.G., professor, predsedatell; TOISTOUKHOTA, L.I., doteent. sekratar'.
Second conference of the Ural Branch of the All-Union SOciet7 Of Pathophysiol
gists. Arkh.pat. 15 n0-3:88-90 My-Je 153. (MLRA 6:11)
1. Pravleniye Urallskogo filiala. Vaesoyuznogo obahchestva patofiziologov.
(Ural Mountain region-Patholov-Societies) (Sooieties--Pathology-
Ural Mountain region) (Ural Mountain region--Physiology--Societies)
(Societies--Physiology--Ural Mountain region)

TOTSTOLIEHOVI A. S.: m)Aer Tech Sci (diss) -- '~RepreBentation of relief of a
lawland plain on topographic mapfj on a acale of 1:10,000 (on the c)xnrrtp'.L,.) of
the &elta of the river Terek)". Moscaw, 1958. 15 pp (Min Fip er Educ USSR,
:h
Moscow Tnut of Engimorfi of (Iloodaily, Anrial, Phol-,o(traphy, nnd Clart,()P-rnphy),
150 coPieB (KL, jqo 2, 19r
.)q, 123)

TOLSTOUKHOV, A.S.
...j .......................-
Editing tasks in the representation of flatland reliefs on
1:10,000 scale topographic maps. Geod.i kart. no.9:61-67 S '57.
(MIRA 10:11)
(Relief maps) (Topogrn-ohical drawing)

- - .. - . I --
. 11 ~ . - ~ . -

T-OLSTOUSOV, V. F., Cand Agric Sci (diss) -- "Ibe Soils of the YeLan,-Kolemovskiy
.1 - - ___ -
sugar-beet sovkhoz, Voronezh Oblast: their genesis, properties, and ways of
inereasir4q, their fertility". 'Voronezh, 19160. 22 pp (Min k-ric RSFSR, Voronezh
Agric Inst), 150 copies (K.L, No 11, 10,60, 136)

TOLSTOUSOV, V.P.
Ways of increasing the fertility of brown Solonetz-type spots
of the Chernozem complex. Fochvovedenie no.10:102-107 160.
(MIRA 13:10)
1. Voronezhakly vellskokhozyaystvenrWy institut.
(Solonets soils) (Soil fertility)

USSR/Soil Science - Genesis and Ge-,Lwaphy of Soils.
Abs Tour Ref Zhur Diol., No 22, 1958, 99985
Auth-or Talstousov, V.P.
Inst : VDronezh ALTicultural Institute
Title : Characteristics of the Soil Cover -of Yelant-Kolanov
Su.~pr Deet State Faru :)ftthe Vorone7liskayn Oblast' in
Conjaection wi',-h To_7,oLxaphy of the Area.
Ori_r Pub : Zap. Voronezlisk. s.-kh. in-ta, 1957, 27, No 2, 339-342
Abstract : Yelan'-KDlinov SuCar Deet State Farm is situated in the
eastern part of the Voronezhskaya Oblast'. Here soil-
forLntion rocks exhibit a considerable influence on the
character of soil formatim . VionE; the fomer predor.-Li-
nate the parti-colored soft rocks, usually the salt-
coutainin- sea de--
L, posits of the Tertiary AL:e. The sAl
cover of the described territory, a plateau with a
Card 1/2
- 16 -

TOLSTOLSOVA, Z. A.
A. A. KOF-tV, MSR 69,941, Dec. 31, 1947

TOLSTOUSOVA, Z. A.
23348 Tsellyuloznyy liesmyvayemyy Appret L i Ego Primeneniye. Tekstil, Prom-St',
1949, No. 6, o. 23-25.