SCIENTIFIC ABSTRACT TITSKIY, G.D. - TITUSHINA, V.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001755910015-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

l~- 16445~5
ACCESSION NR: AP4043839
ASSOCUTION: Kharlkovakiy gosudarstvenny*y univeraitet im. A. NL Gorlkogo
(Kharlkov Siate University)
SUBIETTEM. 04Apr64
SUB COIYE: GC
ENCL: 00
NO' REF SOV: 010
OTHER: 005
Card ---3/3

LITVINENKO, L.M.; ALE10ANDROVA, D.M.; TITSKIY G D
....... 1~11--?,~~!--~
Carboxylic acids as a medium for the preparative acylation
of aromatic amines. Ukr. khim. zhur. 28 no.1:77-80 162.
(MIRA 16:8)
1. Khartkovskiy gosuclarstvennyy universitet im. A.M. Gorlkogo.

LITVINENKO, L.M.; OLEYNIK, N.M.; TlTSKIY, G.D.
Search in a certain direction for new bifunctional catalysts.
Dokl. AN SSSR 157 no.5:1153-1155 Ag 164. (MIRA 17:9)
1. Kharlkovskiy gosudaratvennyy universitet. PredstavInno
akademikom M.I. Kabachnikovym.

ZUGLTT/I.P., kand.sellskokhozyaystvenn7kh nauk; TITSKIY, I.Ya.,
kand.selekokhozya.vstvennykh nauk.
Brower's yeast increases butterfat percentage in cows.'
Zhivotno,vodetvo 19 no.12:36-40 D 157- (MIRA 10:32)
l.Teruopollskaya oblastna.7a seliskokhoz7aystvennayn op7tnay~a
stantsiya.
(Cows--Feeding and feeding stuffs)
(Yeast)

KILWKIN, V,V.; TITSKIY, Lye.
Mixed silage for poultry. j?titsevodstvo 9 n0-8:7-11
Ag A 59- (MIRA 12:12)
1. UlcrainskiWa opytnayu ntantelya ptitaovodntva.
(Poultry-Fe"ding and foods) (Nnsilage)

CHEKINI, V -0 TITSM., 14,
,bibb
Semiautomatic line without converters for "N-sn"Irocessin of poultry.
Mas.ind. SSSR 33 no.3:6-7 t62. - fMIRA 15:7)
1. Poltavskiy mashinostroitell4k zavod myasnogo oborudovarxiya.
(Poultry plants-Equipment and supplies)
(Assembly-line methods)

MTSUL-Rikolay-Faylovich; ZAYTSEV, V.S., red.; PRESNOVA, V.A.,
tekhn. red.
[Green light for advanced practice] PerAdovomu - zelenuiu
ulitsu. Leningrad, Lenizdat, 1962. 58 p. (MIRA 16:10)
1. Sekretarl partiynogo.byuro motor-vagonnogo depo Leningrad-
Finlyandskiy (for Titskly).
(Leningrad-Railroade-Employees)

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1- k t i 1 9, t
AL
Degull'uristac ParvAn and thalt We under atmasPeric j
00 1. N. rift. Sv. Rrpl, 00
pressure'
VqIA,--b,,,,-^,I-S I% quantitatively removilt A~ lfg;
fil"ll Mg. :~ comrx1%. by patting thc pnxfnvI% over M- ;-0o
Pt-AW'. .1 vdil. WC A
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-Vj_ 1"Ift -!(1 - -I.-IM: 'to "IN '901 JIM' Aw>f""'
1 i4ad -11.~ -2-if 01% WJ."9 . "NJ*3 00
00. -csipiq v1qj pfcapaw 10 milin" Donruakip,Iqla(I
r It I ff I
f AfA 4

0 & 0~ -@I[*- It 0 IF 0 111 0 w w 'w w
C
a 111"0 0 G'Q 0 6~111 00 0 4 00000000 0
03 if 11 IJ w Is Is It 4 It a n a " a A V A A ';Pli 11 IA IS All 11 a 0 #1 61 Q Cl ad asto
A A i I Y I '_X' 1. 1 AA 14 CC Cc U 41 k
00 4.110.1
00
00 _100
00 ..64
0 o C, Froducits under attito Deautfurl"don -40
0 1, 4:ThtSrdkPOrOqTUurC
0 in presence .1f 2 ickel claWyso. 1. N, .40
I ils itail ):13. K. Ylw'ev. Sci. Reply. Moj.~"w St'll,
-'M 'w6wity C4 IT-hI% -40 0
00 1
11, TV W.
00 i catalysts falls during uw lo a collm. Valli,
116 able catalyst Climinates about half of the S Content
I )cc
00 pcuotetan products. The activity of catalysts coutit .00
I?li% Ni is less than 40%.Ni and equal to those cumg. kilt
00 x1f; I Ao
Ni. Evolution of HIS begins after a certain time, t; 0
of a length of witich is proportional to the N1 content of Or :00
00 Desuilutizadon of kerosmil fracdou In a 0
"dy&t;fp1y1r-oIjW&ps. LN.Tits,A.F.PlatcawlN.F.
00 Clushnev. Ibid. .365-74-Satisifactory retuaval of 8 zo
90 .00
is achit-ved by passing the petroleum fraction over 40%
N I catalyst in a stresan of pyrolysis gav from Which lifelines
have been removed. H. C. A.
t
09 zo 0
04
i Aa
00 1-
AS&ALA OfTALLUROCAL LPTINAT"t CLASSIFJCATICN
Elow $M#)Jr.
0 0 -A laic*) .1. ':.' Car U., Is.
U it AV PO it: lit of
7 '0 of a it It : It OF a or it PC ff it U K AID n t 14 Old
0 0 4111 0 0 A * * a 41 Q 0 0 0 6 0 0 0 * 0 0 0 0:0 0 0 0 0 4? 9 1111 6 0 4 00 0 0 6 411 1111
*
1*0111601000*10 0 0 0 0 0 0 0 0 0 0 9 0 94 0 * 4 0 4111 0 0 0 0 0 6 'Ji a 0 0 a a *A

hynthegis and fundamental constants of tnized sulfides
with Cii-Cm WbOn AtOMS. 1. N, Tit%-Skv,,rtsov.&. S. 1'a.
Levina. A. 1. Lerincivu. and T. A. RiniNva(M. 1'. l.mil"11-
Ov State Unly.. NICAMW). Nauk S.1;.A.R.
74, miits. of RS11, K011 or
NaOll, and RX in FtOlf lir *Aft-Oll arr alloncif m re-irt liv
droplivisr ndeln. tit RS11 I-) alkali in ROll at %ttmn 1,1111
le"11j., titter whicli 0.5 hr. at 0, -711' cimilikit-% f1tv f"rill.1-
tion of RS%'a (or RNK); It X 14 %imilmly iiiM.,I 1111.1 All 1
1.4-2.0 hrc tit W 7,11", the prtOuct i4 Wa4it-d %%illl 11j).
mid ifq Pt,O %nlri. wuqhrd Milt 19)r;, MOIL Comip,l,
Co./Ir.S1'k(84%1,b,17')
,1:1 ItAM); Ilk cyclapentyl jul 'Ade ii"
1.57-10, (11* UL571; cychthex.vt drcvl vil.fide m,--c- t b? 14 1
5', at- 1.4W). d.1- OJWO (best train C,,ll!jllr: the re%*4,t,,-
reaction tives only a 17% yield): tyclopentYl de,'Y1 iislfile
(72%). b7 158". xj.' 1.47M, fl,- UAS:13; 1-
p,rxlvl Smifidt (47%;, li, 9 V 1.511K.
I-Raph/hyl d4reyl Wfulo, (72%). J,, . 2*11 A'. tv I.Wl i,
I till.; I -maphlbyl eyy1ohoryl im/fide 1:11. F ; j, I.,
MIA r1" 1.141SI; 5.6.7,14 o I
m,tphlby
(Y(1OJwxY1 jultide (34.9%), prrjwl. at l2b)". bcst with HSNa,
1h lX7.11MA', I- L.V01, dl- 1 J,543~ C.. X1. K.

USSR/Chemist ry - Petroleum ' Iw"i
"Syn'thesis and Catalytic Conversion of Aliphatic Sul-
fur Compounds Through Their Contact With Alilmiaosili-
Cate Cajalyst," 1. W. Tits-Skv-orteova, S. Y&. LeVIMA,
A. 1. Leonova, Ye. A. Karaseva,'Lab Petroleum Chem,
M08cow State U
nZhUr Obshch Khim" Vol-=,.No 2, pp 242-250
Obtaired aliphatic sulfides and disulfides vith C9
apd CIO from corr bromides, and aliphatic mercaptan
of C10 from Clodisulfide. Concluded from passing
compd formed over aluminosilicate catalyst: (1) At
2500 mercaptans (decylmereaptan) form sulfides (di-
dec~lsulfide) and alkenes (decene-1), at 3000 only,
JM' i7fta.3
USSR/chemistry - Petroleum (Contd) Feb 51
alkenes. (2) At 3009 sulfides (dinonyisulfide)
form &.1kenes and mercaptans. (3) Disulf ides (di-
nony1disulf ide I f orm merc~ptans vhidh are p-artLV con-
verted into alkenes.
176T13
E-
~_i
E-#

USSR/Chemistry - Sulfur Compounds 21 Sep 51
"Transformation of Some Sulfur-Compounds of the
Aromatic Series (Dithioresorcinol, Thiocx4esol,
Ditolyld.isulfide and 2,6-Dimethylthianthrene)
Over an Aluminum Catalyst," I. N. Tits-Skvortskov,
A. N. Leonov, S. Ya. Levin, Moscow State U imeni
Lomonosov
"Dok Ak Nauk SSSR'I Vol IMM, No 3, PP 377-380
Thiophenol reacts with hydrogen in 2 ways to form:
(1) Benzene and H2S; (2) thianthrene. Dithiores-
orcinol reacts with hydrogen to form toluene and
kS. -Diphenyldisulfide, when hydrogenated, splits
21OT30
USSR/Chemistry - Sulfur Compounds 21 Sep 51
(Contd)
to form thiophenol. 2,6-Ditolydisulfide splits
to form thiocresol. 2,6-Dimethylthianthrene
splits to form 2 molecules of parathiocresol.
k4
210T'40,.
V:)
E-4

USSR/Chemistry - Organic Sulfur Compounds Jan 52
"Mixed Sulfides With a Number of Carbon Atoms From
C11 to C20 and Their Basic Constants," 1. N. Tits-
Skvortsova, S. Ya. Levina, A. 1. Leonova, T. A.
Danilova, Lab of Petroleum Chem, Moscow Order of
1&nin State U
"Zhur Obshch Khim" Vol XXII, No 1, PP 135-138
By interaction of metal derivs of aliphatic, aro-
matic, and naphthenic thioles with aliphatic and
naphthenic halogen derivs, following mixed sulfides
vere synthesized and described for the lst time.
USSR/Chemistry - Organic Sulfur Compounds Jan 52
(Contd)
pbenyl-, cyclohexyl-, cyclopentyl-, and q(-naphtbyl-
decylsulfides; phenyl- and cyclohexyl-cyclopentyl
sulfides; cK -naphthyl- and /'3-tetralyl-cyclohexyl-
sulfides. Yields were 62-84% except in cases with
cyclohexyl. halogenides, where they were 30-34% due
to side-reaction of cyclohexene formation.
ft 2o7T26-
E-
V)
to
E-

USSR/Chemistry - Sulfur Compounds, I Jun 52
Petroleum
"Transformation of Some Sulfur Compounds of the
Naphthene Series Over an Aluminosilica Catalyst,"
I. N. Tits -Skvortsova, A. I. Leonova, S. Ya. Le-
vina, Moscow State U imeai M. V. Lomonosova
C%j "Dok Ak Nauk SSSR" vol 84, No 4, PP 741-743
Cyclopentanethial and cycloheyrLnethiol do not
behave alike over an aluminosilica catalyst at
300P. Cyclopentanethiol, losing a mol of H2S)
becomes cyclopentane. The end product of
232T11
zYclOhOX&nethiol is mathylcyclopentane. Apparently,
the f*lloving process takes place: cyclohexane-
thiol, losing an ~2S mol, becomes cyclohexane;
cyclobexEtne isomerizes into methylcyclopentene which
hydrogenates to methyleyclopentane. Dicyclopentyl
sulfide becomes cyclopenteme over an aluminosilica
catalyst at 3000, the sulfur leaving the mol in
the form of H2S. Dicyclopentyldisulfide is reduced
ever an aluminosilica. catalyst at 3000 as a result
of detitructive hydrogenation into cyclopentane
thlol, part of which, losing a mol of K?S, turns
into cyclopentene.
232TIl
E-
E-
I.,.
E~

4
Catalytic trinivifornl4ti-nr ovel MII mosPica Ill ent'IL-St of
fliphintyl lfisulfid~, ruld
Nank 1, 511-7(1953).-Tim aro-
matic S dri liteii qlio% c. (in contact Ivith Aimmilicate
cnta;yst A 3110 the nimt charact"Li3tic rqq~tiolj of
etstrw-fi-, In. ziv,gi Thm. P-MeC,I Tj1):1 chinipt3 14
part tc, ~; not forillef.
P11-% yidd- PhSil. Che latter then b~!ing converted
to C'114 -III,! thj;In!hrenc. (p-,fcC.H,~-S,,- ht rjr-,t yiplds
A-- 'Celfisili- Wfklt then _is -cutiverti-dto MePh 2JI-
i~ IL
Dimethyfflifivithrene fis totally decompd., yielding lvjeC.-
it part raiwerted to C arid It. Reduction
T1'Sf1 arid beinj I
01F P-%1eCJfjSO-dI with,Zn dust In iced JGS04 at 0' gave
78.6% P-McCUL$11, in. 43'; a 23.81~,' yield was ablaincd
from p-MPCsIi.Nfgtr and S after 2 fir.q. mPuxing. alcing
witIl a low Ii"+! of (!-AfeC4114)%S2' bi 178-NI". in. 44.6-5
(frorn iNtc(M). jljj~,Fj, in. W)", %v.-v; ribtai,vl in Inior )-16.1d
fraut 1111NIgnr and SICN. in Rt.0' alanf V011 nitich Pill.
PhIS and IlhDr- (p-3TgCs1jjjSg. in. 47 , was obWlned III
30.4% yield from -jG g. p-MeC.I[,SOCI and 30 g. p-MeCt-
11,511 in FIV) In OTC prestnc'! of 311.3 g. polvd, KOH,
6~g 4(i P.. r-Nf~ ~"Jf'S!f '-ith 210 Ill, vOTICII. 14SO, inin
One ~ji 1,;, ;~tvc ju.2 x.
I, ji,ic
jlv~duct' in, 117, (from ULWO.

TITS-SKVORSP,'j';, , I. N. , ~ EGITOW., A. I. , LEVINA, -'. Ya. and M. A.
Catalyt--c Conversion Over Alumosi-,Acate Catalyst ,of p -Thiocresol, Diphenyi-
disulfidat ppl-Ditol,,-ldisul-fide and 2,6-Dimethyl fhianthrene, page 54:L, Sborn-Jk
statey pD obshchey khimii (Collect-Jon of Pauers on General Chemistry),, Vol I,
Moscow-Leangrad, 1953, page3 762-766.
Moscow State U, Chair of Petrolem Chemistry

in ~,rruadoqq of sulfur Om-
"I ~1.109 "I CO
"undd of til th huict W"
ta:x,~ n,
---------- 1~qvna 01. V. Sbomlk
.125 ml. MOU 3aid. with 11:3 with cooling and trented
at re~diax with 74.6 g. cycloptntyl bromide 4tl%Ln refluxed I
fir gaveij'1074 iyefalentarelAiof. b,. 129-31 ~nV IA,", "'IT3
0.65i. n4 5.9~yj' dieyckponlyl xulfide, b-i l33-4*.'vV
pent ylin,.igu eilam brofffld~ and S. The ptiir: JU0.1 )J!41
129,64TV. 1j'3 LV71. d. 0.0351; Ov! di!Ufld: ~j 1404-
I*, n"', d-4 1.lulo, larm~d In 5% yield from the
M-,~iartl ~:yntbe3i, 10 n i
C ', s. Cveloptntanedi I pasaM ever alit i -
at 300' give MAO/O cycloptutene, 16.15%
'11nVJ1AoRt!(f thi0f, O"J.150' 11-5, U fit-tie ('0', 4.65% Olefifti,
54~-V 0, xzd 15.31", 11; zhe rtzaciiup )yaj rian In N Nt'ream.
Reartiou ofcyclohQ!xy1ma_,ne%iuca laraju~ic with 8 -,tvc 007,
cyriolieranelHol, bp n" d,, 0.0449. along
with 3A g. r orz~51)-wk ding difidj7de, ba nj 1.5176,
di, 1,047& The tbol vn.5scd in N over 0113171ino3ifirate
t I t obtained In 49%
yichl) in- cth-yfc_)'6oP_en_t_an-
u,9.47
Ow -of, .,"I I;iui*
10; the kaltiian eill the. hydroearbon was pm-ceffed fly
treatment with 00% H-.SOi to remove unstild. ca4ppdi,
abl -tit
Pcl, 1,; cyrlob~, ue). ever th.
catalyst at Silk' gave no change, Cyc tene gave 27171.
znethylcyclop~!nw;L and small arnounti of methyleyelo-
pftiten--4, alo ", %vidn aroinatic !iubstanceq. Cyclopente-te
over th~ ahlinitiosUiezitee calalyst at 3W, gave no rtiactioll.

W~,

kc7sctfoil `c .1, c3,60-n;ity, broluide. %,Vith It's f4ltoll gav-e,
42A yl s:dlide, b.,, 13 4 1.5102, d. 0 ~97"26,
nlong Ivitli 6.01/7 cYcloptmtawl.hiol. The sulfide over
411millosilimte vatavst at -IDO' gave rutich H-S wid 00,9%
eYcloPcntl:nc, 1-11c cycloPentallf-thiol, and uimatd. ami
arom.,Auc compil,,. in low Add. Rc-action of cyclohcxvl~
mfqIqc!,4jnI blaillide with "i, fallowed by decompil. of tht:
7
intentl
itilte vnmplex -Nith ueidifil~d H:O flu be mme day
(tit-Illy lowers tit'! Yield drustically) rrar~ 4,5% did~Yclab=y,',
.rlltfide, b% 138-Vor. -j- '1-0 0.0714, along witli the
,
'
colm-4imudIng Viid,
I
tcacLioll of cyclollegyl bromide with
lit lint Tvft~Oll rave 8.0% cycle,-
Ltbivi- sulfide. bs ISC~S', nlo* 1.5140, d:4
UGF7. Attempizi tb prepare the sulfide froM cYOIQlIcx-A
hmiuidc and zwlid X invicaptide. NvItIl K's. or Wit", A3
failett, To cYclofieutallethiol in
equiv, ninuunt z,( -:~,5(/'o uq. KOH N%,%s ulded art equiv.
AInNIljIi0fiOdi--Ie', ihe-S~Pll- Oil VeIIS iU
witI7 tbiusuffau: nd lul~O N-1011. glVe 8151c d-i.VdjfVrjw
l
5
478, J.~ 1.06M ibii i~:Lssu
41i4ul'fide, b, ?!Q 1.1
'
gave ~01.4 ca-
c-talyst at jf)~,
-Lb-ZLI[e, ObLair:tj it, ~)o% yield) cycloficuteue, 20.71~o cydo-
peritiLTIV61i0l, ~-,ric! a little high builing inatedal -of
It 'LliliV.
allivo. Oxidation (if NvIth I C (If
" LI
Mire. in IKL611 gave 600,fe dicy.0phexyl dijiswe. b& IG2.0- 3
,
,u To sutd. ale. KOII at 00-w-go, was
ny, I.FrI59, d-
-
add(A eyelohQvyl merraptan, fOll0%Ved by ectuiv. '1111(jurit 'if
cyclopentyl larurnick; after 2 Ims, at. TO flit-rO UILS i~otatcd
67. V, 0 cyclols ex vI cycloPeutyl s idlide, b~ 119 -20 1 -5 114,
if,. 0.9692. Thit; p;mcd over
300' t,~~VC Much I-I.S, I.b% cyclap(,atenc, sairic S.S% Inixtil
Tie --nd niethyleyclopentaitc, 15-8r~li ~Iicyclc~-
'
, :i.3'~dititt-tliYI(IL;Ycloll~intYl; till thilA.; or
p;nzty!, and 6.65j
%Yue found. Thxi in I'll v-Wtion
there If, the forillatiun 01, cv-!Dpt~"Imlc and
tune, with Ilic pm(litrU, of adda. of frtt! -4:cz.'t! re-

s -0 i, 46,
j),jjj,-fro,tj t1i,, c1cav;,reof Cf. 17.A. 45. -L Z
Z
WOW.

1. IT. ; MOITCWA, A. 1. and T,'VVTIAt, Ya.
c C'
Synthesis and `tt-!"
on Contnct with aa Aluminum Silia~%te CatalYst, CrPe 1135, -3r,5- i~' '~'rL-,AYn
ObshchtV !:Ilimii (Collection of Paoers on Gone-al Chemintry), 1101 11, Foscou-
Lenin,grad, 1953, p-iges 1680-1686.
MOSCOW State U, Chair of the Chemintry of Patrolnum,

Abst.
a P, '10- 5
f,~
lo, 1954
Orr_-nnic GhOmistr'y
Catzilytic transio n1dons over SJUMOBIRCAN WAIVII Of,
no,
thio hen,l, r 01, thiantht 5 MMI
A. I I . Ya,
Sul I
Fai -
I it and U A - Knmzxa JAW=
I , 23. 4Lar wins
"Were passed over the Al,Os-SiO, catalyst In N at space
velocityO.25. lit all cases 11,,S evolution was noted. PhSH
was used at 200*, 300". and 5W*. In all cases the ca-
lalyzatewasamixt.of liquid and solid products distributed as
follows: at 2100* C,11, .19.5, thianthrene 11.1. and PhSH
7.7; at 300* 42.2. 15.9. and 6.0%. thesp.; at WO* 30-1,
10-12.7. 14.6-17.7%. resp. Possibly more PhSH is re-
11"incil by the catalyst at"the lower than at the higher temp.
(W). Pure thlanthrrne m. 155' (from EtOll). CISOJI
(1950 g.) heated with 195 g. C41-fi, 2 hrs. at 150--60'. cooled,
and poured into lee, yielded 70.8% n;-C#Hj(SOjCI)j (29-2%
putc), m. 61-1.5* (from petr. ether). This (75 g.) added to
180 g. Zn dust and 200 ml. HO at 50% then heated with 20
g. Zn 10 min. to 70', cooled, treated with dil.HCI (I kg.
coned. lICI and 500 tul. 11,0), then treated with 25 C. more
Zn dust, stirred 2 hrs. at 20', and the resulting plit. extd.
with Et30 gave 77.7c,", tYj-CsFI,(SII)j. rn. 2M.6% bi, 12,0,
.4.5*. Passage of this (29 g.) ever the catalyst at 300' gave
23.1% catalyzate contg. C%H4 23.8. MR 11.9, M3%
thianthrene, and 52.1% HrS, along with CO, 0.26, 0 1.8,
atidl-110.5%intheoff-gascs. Thianthrene passed over the
catalyst at 400* yielded 2270 catalyzate which gave 367o
Cqllq, sonic PhSll and -157ounchangedthlanthrene. Addn.
of 91 g. AlCIj to 177 g. C.Fl,, then 85 g. SjClj and 81 .5 g.
Citis at 10--13*, stirring I. hr. without cooling and 1.6 bri.
at 30-40% treatment with Ice, filtration of the &rg. layer,
cyalm., soln. in MeOll, and refiltration from S gave 70.6%.6'
Plt,S, bu, 162.5% n2D4 1.6312, d:* 1.1100. This passed over
the catalyst at 300' gave W,"o catalyzate contg. CH, 9.
thianthrene 13.7, and PbS &5.279; at 350* the yield was
with 29.6% C411a, 14.8% thianthrenc. and a trace of
Ph2,9, at 450% 457c with 35 17c C411i and 14 7vf thian-
threne; at &)0*, 55k With 4.5~, C.H. and I l*.3?, thinti-
threne. PhSH was detected by odor in all cases. -)W
.G.M.Kowlaporl_
/I-

S S
Catalyst of
5u
4.11
317
WO E -FA M 5 W &W i.-.

Synth esis a nd rataly tte ! rit rl i4orm a [ions, on alumlaosilicate
catalyst, of O-th;otctralol, fi-taralyl nonyl sulli6o, ii-tetralyl
cyclohexyl sulM and O-tetralyl
methyl sulticle. 1. N. Tics-
Skvorts,c-.,a and T. A. D~,milava (M. V. Lorriona-;-ov State
Univ., Zhar. 0`*S~~;'--'.Kh'*~:. 23, M~-92
cf. LW;en-ye Za e isk; Jt~;' 1 --71 G~':tuzfa -U. b" 1 51, -11MA 191,11
-. msait oi
-1 - ~l ) Over
tl;dlllillu~ilicate C:atalyst at ~00' ill N Fa~c t~"'70 -;Italyz~ltc
and 21.3% INS. Cor,;idvml& frt-c S wan tound ill Vie
%mvilyzate. alonj; %vith tc~tr ihydn-jimplithalene, 27.9%
C16114. aad t3s';7" starting Illatedal. Re-actioll of (1 71132,11
with 1, K halt (11), gav(!
nonyi zu1j.--de, U. 218.5-9.3'. nl~' 1.5~3370.
passed over the catalyst as above, gave 69.71,~ CaLalyzate
and 19.3% H.S. . Thc (-italyzate coutabicd 26.8% tetra-
hydronaphtlialene, 15.V"O 1-noneite, I" '-I '/'1' 1. 4.3% C;'fl'j'
and 3.8/j nonyl llle'rr.~Ptall. Thv~ b""', yiel'I (it
cyclahex)l -naph1hyi sidjfde! (111)" (1'~
187.6, 8.5', n" IZROO, (In 1.6513) wn; obtained fluln cyclo-
hexyl chloride and I Nc~ salt, on livaling 10 lirs. at 115-23%
cycMiukme w-s L, by-produet - Cyelal~cxyl bromide gave
lower yi(-Id (271/0) even -with 11. Tb-1- -ulfidle, pa---.~ed over
It Q
t
e catalyst Is above, gave 81.77o czltaly7ate and 27.95 j0
If,-S; the (-at:Llyzate Contained
Me, ts~'s(;; 1. methyleyclopentalle, 6.06u, cu,14.
and 1%'originai sultMe. Reaction of Mel with"il gave
74.r7% me1hyl z0fidt, h,~
155", n""' 1.5920, d-9 1.07,11. This, 1'~"icd over tile cata-
ly-st :Lq above, gave vatalyzate and 6.56% 1(,S with
M-360' McSff. The culaly-tte contairiLd 31.63% tetra.
'0
ImIrunaplithalent,-, 36.313% 2.,111, 15,M176 Me,S, an I
5,63% 1, pasred liver the cat.-
IY!,t .110111" gave 1.4~?/, Cloll.. 2.9%alkunes (mostly CHO wid
unchanged sta-dug mattrial: if tile. reaction k run in 11,S
stream Cw1l, ii ohlzdned. Ill is MICIlLtIged On
sage through an cynl)ty whe it 300'. M. Ko%olipoff

IZ~
At
P"i

TITrj--SKVORT5OVA, I.N.
Conversion of phenvl nonyl and 0~~-naphthyl nonyl ether by using
an aluminum silicate catalyzer. Vest.Mook.un. 9 no.6:81-89 Je 154.
(MLRA 7:8)
1. Kafedra khimii nefti.
(Catalysts)

DANILOVA,
g;
I
Synthesis and conversions of sulfur acyl- O(o -derivat~voo of
totralin on aluminosilicate catalysts. Vest. Moak. un. Sor. mat.,
mekh., astron., fiz. khim., 12 no.SZ05-214 157. (KIRA 11:9)
l.Kafedra khimii nefti Moskovskogo gosudarstvennogo universitata.
(Tetralin) (Catalysis)

50)
AUTHORSs Danilova,T.-I., Tits-Sk
Vortsova, !.-I
TITLE: Synthesis and Catalytic Convernion of Sulfurous ac-3
Derivatives of Tetralin With an Alumo - Silicate Catalyzer
(Sintez i kataliticheskiye prevrashcheniya na alyumosili-
katnom katalizatore sernistykh ac-3 - proizvodnykh tetralina)
PERIODICAL: Vestnik 19oskovskogo Universitete.Sori,a matematilri, mekhaniki,
astronom.ii, fiziki, khimii, .1950,!-.r 2,pp 159-16d (Uj3R)
ABSTRACTs The ac-B - tiotetralol decomposes into hydrogen sulphide,
tetralin and naphthalene when it comes in contact with an
alumo - silicate catalyzer. In the presence of an alumo -
silicate the 1,4 - dihydronaphthalene suffers a conversion
of the type of the irreversible catalysis of Zelinskiy.
The influence of the benzene ring of the tetralin on the
stability of the combination of sulphor with the hexa-
methylen ring is expressed by the fact that this combination
can be split more easily than the same combination in the
molecule of the cyclohexylcyclopentisulphide.
There are 32 references, 10 of which are Soviet,12 American,
6 German, 2 Japanese, and 2 Italian.

IANIIAWA, T.A.; TITS--:.' WORTSOVA, I.N.
Synthesis and catalytic conversions of sulfur ac-p-derivatives
of tetralin over aluminosilicate catalysts* Vest.Mookoun.Sor.
mat.,mekh.,astron.,fiz.,khim. 13 no.2:159-167 158.
(MIRA 12:2)
1. Kafedra. khimii nefti Hoskovskogo universiteta.
(Nephthalene) (Catalysts)

.P
S/081/61/000/022/021/076
B11O/B138
AUTHORS: Tits-Skvortsova, I. N~, Danilova, Tt A,
TITLE: Synthesis and conversion of sulfurous tetralin
derivatives on an aluminum silicate catalyst
PERIODICAL: Referativnyy zhurnal,, Khimiya, no, 22, 1961, 174, abstract
22Zh128 (Sb, "Khimiya seraorgan, soyedineniy,
soderzhashchikhsya v neftyakh i nefteproduktakh", M.,
AN SSSR, 1959, 174-182)
TEXT: The isomeric thiotetralenes 4-(Ia), 5-(IIa), 1-(IIIa) and
2-thiotetralenes (IVa) were synthesized, along with their sulfides
(Ib, c, IIb-g,IIIb, c, IVb-d). (Substitute b = nonyl, c = cyclahep-,yl,
d = phenyl, e = methyl, f = decyl, g = cyclohexyl). The catalytic
conversions occurring in conducting I to IV over the aluminum silicate
catalyst (AC) at 3000C ana a volume velocity of -,.)0.25 hr-1 were
examined. H 2S is always separated in the catalysis. The catalyzates arp
fractionally distilled. Ia and IIa form tetralin (V) which is converted
Card 1/2

S/081/61/000/022/021/076
Synthesis and conversion of... B110/B138
into naphthalene. IVa forms a mixture of 1,2-(VI) and 1,4-dihydro-
naphthalenes. IIa is thermally unstable and at 3000C forms VI in the
absence of AC, The substances Ib, c, IIb, c, e-g decompose, the sulfur
forming one of two bonds with the radicals. Ia or IIa and the
appropriate RSH are separated. The two bonds are almost equivalent, In
the case of Na, the bond between S and the radical of V is broken, and
thiophenol is separated. For IIIb, c and IVb-d, decomposition on the AC
was only found where S is bonded with the V radical, The schemes
proposed for I-IV decomposition are given., [Abstracter's note: Complete
translation.1
Card 2/2

PHASE I HOOF F=L401TATION SOV/4941
Mozhwuzovskoye soveshchanlye po khimll nerti, moscow, 1956.
3boralk trudov )(tzhrizovskogo noveshchanlya po khlmil naftl
(Collection. or Transactions of the Inter-University Con-
forence on Petroleum Chemistry) (MoBcowl lzd.vo Mask.
unly., IQ60. 313 P. Errata slip Inserted. 1,600 copies
printed.
Organizing Cc~ ttee or the Conforencet Cha.1-man: B. A.
Kszanskly. A-cademictan; Vice-Chaiman. S. 1. Khroov,
Docent; 0. M. Panchen1cov, Professor; A. F. Plate, Pro-
fes3or; Searetary: re. S. ailenkova, Scientific Worker.
Witorial Board: Reap. Ed.: A. P. Plate; 1. V. Gostun-
skayal 1. X. Tlts_~Avortscva. L. A. Zrivans a.
PUIL-ME: This collection of articles In Intended for the
teaching atafr or universities and schools of hi&her ed-
ucation training upecial"t, f,, ~h.
a=-refining Industries.
CArd 1/7
CC-.--RACE: The collectlen Includes a-rtloles dealing With the
present state or tze p*troleuni industry. the scientific
research proble= in petroleum chemistry, the chemistry
cf petroleum, the ecoposition Or petroleum and petrole=
producta, the scientific principlea of refining patrols=
into motor fuels and lubricants, and bhe manufacture or
synthetic products from hydrocarbon gaM03 and petroleum.
One article dis-u3ses the effect of chemical composition
and additives on ruel =tustion In Jet engines. The ma,
terlal was presented at the Inter-Univer3ilty Conference
on Petroleum Chemlstr,7, held at the Moscow State Universi-
t7 imenI X. V. 1,omonoBoy November 26-2a, 1956. No par3on-
alltles are w~ntloned. References accompany most of the
artLclee.
TA= OF CCN=%=: None given
The authors and the titles of articles are an follova:
Introduction by B. A. Kazanskl7, Academician
Caurd 2/7

Collection of Tran_:iaction~j (Cont.) sov/4941
Obolentsev. R. D., Bashklrakiy filial IN SSSR (Bashkir
Branch of ihe Academy of Sc1ences USSR). Specific Prob-
lems In Refining Sulfur-Bearing Crudes 128
Aklohin., P. A.j N~ G. and
Yu. K. Yurlyev, Moscow State University imeni M. V.
Lomonosov. Study of tbe Raman Spectra of Certain Sulfur-
Containing Compounds 146
Dorogoehinakiy, A. Z., Groznenskiy neftyanoy nauchno-
issledovatellskiy Institut I Groznenskiy neftyanoy In-
stitut (Groznyy Petroleum Scientific Research Institute
and Groznyy Petroleum Institiate). Alkylation Reactions in
the industrial. Synthesio of Hydrocarbons and Some of Their
Derivatives 163
Oborin, V. 1., M. S. Ostrikov, I. V. Rostovtseva, and
0. L. Arut-yunova, Grozryy Petroleum Institute. Effect
of the Foro8ity of SIlica-Ba5e Catalysts on the Cracking
Cwd=:5/7LT-,

S/1 89/60/000/003/012/01 3/,U.
B003/B067
AUTHOM Tits-Skvortsova, I, N- Danilova. T. A., Kuvshinova, N- N.-
TITLEi On the Changes of the Individual Sulfur Compounds on the
Alumosilicate Catalyst at 300 and 4000C
PERIODICALi Vestnik Moskovskogo universiteta., Seriya 2, khim-~ya. 1960,
No. 3, pp, 61-65
TEXT: The authors studied the changes of various organic sulfur?compounds
caused by passing them above alumosilicate catalysts at 300 a 400"C '
Reference is made to earlier papers of the authors in which the behavior
of organic S-compounds at 3006C was studied with the same catalyst under
the same conditions, The author of this paper attempted to determine the
temperature effect on the catalytic reactions. The results are the
followingt At 3000C aliphatic S-compounds are divided into two parts each
at the S-bond (decyl mercaptan->decene + H 2S, dinonyl sulfide-4 nonyl
mercaptan + nonene, dinonyl disulfide--~>2 nonyl mercaptan), At 4000C
these compounds are cracked under the formation of gasoline (boiling
interval 35-1550C) with a 45-48,4% yield. The remaining part consists of
Card 114

On the Changes of the Individual Sulfur SlIB91601000100310121l-JI31XX
Compounds on the Alumosilicate Catalyst BOO3/BO67
at 300 and 400 oc
resinification products At 3000C S-compounds of the naphthene series
produ.ce hydrocarbons which can be identified (Refs. 3A) tinder cleavage
of 112S., Because of the almost quantitative reaction process (76-94%)
this class of substance3 was not studied at 400oCr From among the hydro-
aromates two isomeric P -thiotetraloles were studied with the SH group
(ar) "and/or in the alicyclic part (ac At 300'C the
(0011) icg") -
following was obtained from ari 22% S (as H2S), 7% initial substance.,
42% tetralin, 26% naphthalene. With ac ?,he following was obtained.~ 95%
S (as H S), 4% tetralin, 40% naphthalene With ar the following was
2
obtained at 4000C: 98% S, (as H2S), 24% tetralin, 48% naphthalene, From
ac 95% S (as H2S), 721% naphthalene were obtained,. The authors explain
these proursEe in the following way:
Card 2/4

On the Changes of the Individual Sulfur S/189/60/000/003/012/013/XX
Compounds an the Alumosilicate Cat!-.Iy,-t B003/B067
at 300 and 4000C
SR H S 2 H 2
Cc" ~ 2 -`->
(temperature increase to 4000C promotes dehydrogenation),
Is
SR- H, 00
-~H S. or H23; >-> 00 + X
00 2 cc, H Co
Aromatic S-compounds proved to be tIhe'most stable, T15~ essentially
zhanged only at 50000 (Ref. 7), 7) Thiophenol, benzene, diphenyl sulfide,
benzene, thianthrene, thiocresol, toluene, n,n-ditolyl dioulfide
n--thiocresol + toluene In general it may be said that a temperature
increase from 300 to 4000C (and/or 5000C) does not change the kind of the
final products but only the quantitativO. ratios, Zelinskly is mentioned,
There are I table and 9 Soviet references.
ASSOCIATION: Moskovskiy universitet, Kafedra khimii nefti (Moscow
University, Chair of Petroleum Chemistry)
Card !./4

TITS-S DANILOVA, T..A.; KUZNETSOV, B.V.
- ---- WQR
Reactions of an aqueouB solution of mercury-acetdte with sme
organic-sul-fides and thiols. Khim.aera-i azotorgesoodsoodev naftei
nefteprod. 3:75-80 160. (MIRA 14:6)
1. Moskovskiy gosudarstvennyy universitet imeni M.V.Lcmonosova.
Nercury acetate) (Sulfide) (Thiols)

5.3620
78292
SOV/79-70-5-406/6_9
AUTHORS: Danilova, T. A., Tits-Skvortsova, 1. N., N~,voqel'tsev, I. I.
TITLE: Synthen-13 and Cori ve vs I.onj of' ar.- 13 -and ac - 13- Tetralyl
Phenyl Sull'Ldes Over- ari Alumlna-Sill.ca Gatuly:,ft (3yinbo13
ur arid ac 2how that the are In the berizene,
or in Lhe hexarriethyLene i,lric, C11' tetr.'aLin)
PERIODICAL: Zhurnal obshchey khImil, 1960, Vol 50, 1Nr 3,
pp 96,2-966 (USSR)
ABSTRACT:' In connection with previous studies (I. N. Tits-
Skvortsova, S. Ya. Levina, A. I. Leonova, Ye. A.
Karaseva, Uch. Zap. MGU, 132, 254, 1950,and others),
two new sulfides of tetralin series were synthesized,
and their conversions over an alumina-silica catalyst
at 30001tiere studied. This work was undertaken in
order to prove the mutually weakenIng effect of one
tetralin ring on the sulfur bond in the second
tetralin ring.
Card 1/4

Synthesis and Con7ersio-'- 0- a,_
0~ an-,
ac- 13- Tetralyl Phcnyl Sulf'Ides 1, ",Irj
Alumina-Silica Cataly3t
SOV/ ci
S-C
G 6
C d
(a) ar- tetraly! phenyl sulfide; (b) ac-/3-tetralyl
phenyl sulfide; (c) diphenyl sulfide; (d) cyclohexyl
phenyl sulfide
,,ht-yellow
at-9 -Tetralyl phenyl sulfide (65%), 11F
0 20
liquid, bp 189-1900 (5 mm), n 1.6)581 d)I 1.111('(I
was obtained as follows: Add ar-l~ -thlot'etralol
to alcoholic KOH (at then add by small pol.-
tIons pheny1diazonluvi chloride solution; heat the
Card 2/4 mixture on a water bath until the evolution of N.

SynthesLs and Conversl.on.,3 of av-/3 - a i I d
ac-/3 -Tetralyl Phenyl SUlfidess Ove_- ai-i
Alumina-Silica Cataly;jt
ceases) extract with ether, and distill over, metallic
h 0.
Na under vacuum. ac- Tetralyl phenyl sulfide
13 -")o '_~ 0
bp 184.5-185-50 (- 4
5 mm) , nD 1 .6229, d. I . 12 (3 vi a s
obtained by the gener,al method fop mixed sulfides
(F . Kr6tev, J. Pv. Ch., (2), 111, ~206; 18'(6). Analysis
L)
of the pvodUCtS of catalytLc convev:~Ion of' at- /3-tetvalyi
JAI(Myl LMIPMe OVOr' U I LITU 11 1 ,;1 ly~.;t; "--.,t 2,000, c3ho".1
that the conversion proceeds accor~dinC, to the assumed
scheme:
/VV +
I ~1 _\ -sit
j
It was found that the conversion of ac -t-e-palyl
I. - Po -_ -
phenyl sulfide also pvoceeds according the assumed
scheme:
Card

Synthesis and Conversions of ar-P - and
- -Tetralyl Phenyl Su fi ea r ar,
ac 13 1 d
AlLimina-SLIlea Catalyst
1-8292
s
x
+ -S11 (2)
Thus, it was proved that the tetralin hexamethylene
ring has a weakening effect on the sulfur bond with
the aromatic ring. There are 2 tables; and 13 re-
ferences, 2 U.S., 1 U.K., 4 German, 6 Soviet. The
U.S. and U.K. references are: F. D. Rossini, Selected
Values of Physical and Thermodynamic Properties of
Hydrocarbons and Related Compounds (1953); H. I.
Waterman, 11. H. 0. Span, Rooy H., van Nesk, J. Inst.
Petrol., 36, Nr 317, 2B1 (1950); W. Karo, R. L.
McLau hlin, H. F. Nipsher, T. Am. Chem. Soc., 73,
5233 M53).
ASSOCIATION: Moscow State University (Moskovskly go8udavstvennyy
universitet)
SUBMITTED: March 30, 1959
Card 4/4

SOVTJ-30-3- .)Ilbg
v L
AUTHORS: Tits-Sk ortsovp.,..,11...N., Danilova, T. A., Markov, M. A.,
,M~6-~anova, I. I., Osipe*nko, Ts. D.
TITLE: Synthesis and Conversions of Sulfur Compounds of'
Naphthalene Serles Over aii Alutilliva-S111ca Catalyst
PERIODICAL: Zhurnal obshchey Ichimii, 1960, Vol 30, Nr 3, pp 985-
991 (USSR)
ABSTRACT: The following compounds were synthes1zed and their 0
conversions over an alumina-silica catalyst at 300
was studied. M - Thionaphthol (72%), bp 143-1440
(6 mm); e -thionaphthol (80%), mP 79-800; C(, -napthyl
decyl sulfide S72%); Cf--nap~ithy~ocyclopenty~osulfide
(45.6%), bp 16 -168-50 (2 mm), n D 1.6419, dil 1.1193;
9-naphthyl decyl sulfide (68%), bp 209-2190 (~.5 mm),
mp 34-35 0; jg-naphthyl cyclopentyl sulfide (65%),
Card 1/5 bp 187.5-1880 (4 mm), n20 1.6455, d20 1.1052. This
D 4

Synthesis and Conversions of Sulfur Compounds 7829F7
of Naphthalene Series Over an Alumina-Silica SOV/~9-30-3-51/69
Catalyst
study was undertaken to see whether the conversions
of the thionaphthols over the above catalyst* at 3000
proceed similarly to the conversions of arc)rriatic
thiols under the same conditions. Conversions of
aromatic thiols proceed as authors showed (DAN SSSR,
8o, 377, 1951; ZhOKh, 21, 212, (1951); and others),
according to the, following scherne:
/0J - I
It was found that both CC- and U1. lotiaphthols
undergo an identical convell'slon over this catalyst
at 3000, according to the following scheme:
SH
Card 2/5

Synth(:,lio and
of' Naphtlhalenc
Catalyst
Conversion-- of Sul fur C~_;mp~)und,;
Series Over ,.,n Alumina-SiI.I.Ca SO".I/ Yl-)-j(j-3-51/6~
Comparison of schemes I and 2
a,- andq -tillonaplit.1101.,; and
similar conversions ovev the
same temperature. CC-Naphthy!
over the catalyst at 0000 to
of weight of catalyst), decyl
(7.8%), and H2 S, according to
shows that the isomeric
aror~,iatl--, thlolo undergo
same cataiyot at the
decyl sulfide decomposes
form naphthalene (36%,
mercaptan (13.1%), decen
scheme:
(3)
jJ
Card 3/5
a--Naphthyl cyclopentyl sulfide decompoaes over the
catalyst to form naphthalene(~40% of weight of
catalyst), cyclopenianthiol .6%), dicyclopentyl
sulfide (2.2%) and H S. The reaction proceeds*also
analogously to schema 3. Catalytic decomposition of
naphthyl cyclopentyl oulfide under above con-
C
-ions results in the formation of 8 -thionaphthol
(15.6% of weight of catalyst,), cycIdpentene (10.2%),

Synthesis and Conversions of Sulfu~r Compoijndu 782W
of Haphthalene Series Over, an Alumina-Silica SOV/79-30-3-5i/69
Catalyst
naphthalene (43.5%) and H 2S, according to a different
scheme:
\/^\\/s TC S11
+ (4)
Card 4/5
Catalytic decomposition of 0-naphthyl decy!
under the same conditions results in the for-mal~icn 01":
-thionaphthol (1.1% of weight of catalyst), decyl
Percaptan (6%), naphthalene (30.5%), decene-decane
fraction (4.2%) and H2S, ac2ording to:
S
+- c1n,120
q,if."S11
+

Synthesis and Conversiom of Sulfur Compoi-Iii(IL; 7 P, 2 ~J'(
of Naphthalene Series Over ar, Alumlria-Sllica SOV/79-30-3-51/69
Catalyst
The comparative strength ot' the sulf'ur bond with
different radicals is shown in scheme 6:
1 ( I C' ; i-
C'I I,,,-S-~Cjf)I 121 .10161 -3- (~j I
call.,-S-IL Ci; I I I I (111121-ST 7-(:10117
(-'19112L-S I C.'11, CJ 11-S-L "' 17 (6)
There are 3 tables; and 14 references, 1 U.S., 1 Dutch,
4 German, 8 Soviet. The U.S. reference is: E. D.
Rossini and others, Selected Physical Values and
Thermodynamic Properties of Hydrocarbon6 and Related
Compounds (1953).
ASSOCIATION: Moscow State University (Moskovskiy gosudarstvennyy
universitet)
SUBMITTED: March 5, 1959
Card 5/5

84877
2A)
S/07 60/030/010/018/030
BOO1 A6 6
AUTHORS: Tits-Skvortsova,...I. N., Rybnikova.. A.-A.,.. and
Kuvshinova, N. N. q
TITLE: Synthesis and Catalytic Transformations of a.-Decyl
Thiophane.by Means of an Alumino-silicate Catalyst
PERIODICAL: Zhurnal o shchey khimiiq 1960, Vol. 30, No., 40,
pp. 3316 - 3319
TEXT: The authors synthesized the hitherto unknown a-decyl thiophane
(V) by applying the general method of synthesizing a-alkyl thiophanes
by R. D. Obolentsov and V. G. Bukharov (Ref.1). The present paper de-
scribes these data and contact transformations by means of an alumino-
silicate catalyst. The following intermediateB were obtained;
a-nonyl-furyl carbinol (I); ethyl eater of y-ketotetradecanoic acid (11)i
1,4-tetradecanediol (III); 1,4--dibromo-tetradecane (IV) (which have not
been described as yet). They were synthesized in the following way:
Compound (I) from furfurole according to Grignard, by the general method
of synthesizing alkyl-,furyl carbinols (Ref.2); compound (II) by boiling
Card 1/3

8h877
Synthesis and Catalytic Transformations of S/07 60/030/0.0/016/0-10
a-Decyl Thiophane by Means of an Alumino- BOO1 YB066
silicate Catalyst
a-nonyl.-furyl carbinol in anhydrous alcohol to which HC1 was added
(Refs. 2 and 3); compound (III) by reduction of the ethyl ester of
y-ketotetradecanoic acid with lithium-aluminum hydride; compound (IV)
by reaction of 1,4-tetradecanediol with dry HBr. a-decyl thlophane (V)
was obtained by reaction of 1.4--dibromo-.tetradecane with Na2S dissolved
in alcohol. This reaction offers a good yield and gives a pure end prod-,
uct. a-decyl thiophane decomposes on an alumino-silicate catalyst at
3000C to give hydrogen sulfide and tetradecene-1. Unchanged a-de,:~yl
thiophane was found in the catalyzate.. The cleavage of a.-decyl thio-
phane may be illustrated by the following Scheme:
Card 2/3

81j877
Synthesis and Catalytic Transfor=ations o-,"
a-Decyl Thiophane b'y Tilean.3 of an Alumiro- B001 3066
Silicate Catalyst
H 2C C112 112S +. ICH2~ CH - C11 - CH - C 10H2 1]
H2C CH - C10 H21
CH2 - CH - (CH2)IICH3'
The behavior of cyclic sulfides thus differs from that of aliphatic
sulfides, which form m _ne0and alkenes under the sam-. 7~onditions
tE21ptan~ I
of catalysis (Ref.4). There are 6 references: 5 Soviet,
ASSOCIATION: Moskovskiy gosudarstvennyy universitet (I.,loscow state
Universit,t)
SUBMITTED: October 26, 1/059
Card 313

Slo8lV621000100510401112
B151/B101
AUTHORS: Tit 1,11. , R ybnikova, A. A., Kuvshinova, N. 11.
TITLE: Transformation of- -decylthiophane in the presence of an
aluminosilicate catalyst.
PERIODICALt Relrerativnyy zhurnal. Khimiya, no- 5, 1962, 264, abstract
5Zh238 (Sb. -'Khimiya seraorgan. soyedineniy,
soderzhashchikhsya v neftyakh i nefteproduktakh. v- 4".
Y., Gostoptekhizdat, 1961, 136-140)
TEXT: The reaction between furfural and C 9 H19 ?AgBr is used to obtain
,- -nonylfurylearbinol W (here and later the oalculated yields in %, L,~l
b. n. in 0 C/mm Hg, m. p. in OC, n 20 D and d420 )s 76, 144-145/5, 3.9t
1.4665, 0.9326; by the action of HCl and C 2 a5OH I iu converted to the
ethyl eater of..--keto-tetradecanic acid (11), 35, 142-144/3, 17, 1.4508,
0.9227; by the reduction of 11 with LiAlH 4 tetradecandiol-1,4 (III) is
Card 1/2

S/081/62/000/00=/040/112
Transformation of---deoylthiophane ... B151/B101
obtainedt 73-98, 172-174/59 57.3, -, -; by the reauction with HBr gas III
is converted to 1,4-dibromo-tetradecane (IV), 709 182-184/9, -, 1.4857,
1.2174; by the reaction of IV with Na 2S(--decylthiophane (V) 13 obtainedt
75-80, 148-5-149/5-5, -, 1-4804t 0,8959, the complex with HgC1 2 has a
m. P. 47.5 0C. The contact conversion of V on an aluminosilicate catalyst
(ABC) is studied. V is passed with a volume rate of 0,3 hrs- 1 over ABC
(73-3~4 ASC on the 7it. of V) in a stream of N2at 300 0C. H 2S is obtained
in a yield of 53.7% (on the s content in V) and tetradecene-1, C 14H281
b. p. 80-82 0/8 mm Hg, n20 D 1-4383, d420 0-7841- [Abstracter's note:
ComDlete translation.-[
Card 2/2

3/031/62/000/000/0~2/075
..UTPC,:?J: Danilova, T. A. , 1.:ar'
1. 1., Osipcnko, To. D.
TITLZ. Conversion of or,-anosulfur compounds of theof,- and(%-na-)hthal-
ene seriez in the -,)resence of an aluminocilicate catalyst
ieforz,!-ivny,-,., zhurnal. Khi;,:iya, no. 11, 1062, 228, abstract
'~~Zh`180 (31b. 11.1'.'himiya scraor~an. so,7cdineni~-, sod erz1hkU_hchi't:hs.,
v neftya'Kh i -nefteproduktakh. V. 4", L., Gostoptekhizdat, !13,61,
141 - 14111
TEXT: Contact conversions of oreanosulfur compounds of naphthalene as
carried out at 300 0C on an aluminosilicate catalyst under conditions des-
cribed earlier (Zh. obshch. khimiya, v. 21, 1951, 242) are reexamined.
and ,,~'-thionaphthols (-~_ and,,-I) were synthesized for research,;,- and
~'-n'aphthyldecylsulfides (le.- and and,~ - and ~'j' -naphthyloyclopentyl-
sulfides (,~- and,;.~-I!I) synthesized for the first time. It was found thZ.Lt
under these conditions -;-I and ~I-I are converted to C10 if8and H2S situilarly
to the th-Aophenols studied earlier the respective yields being 52 and 42~-j
Card 1/2

S/081/62/000/009/0,'2/3-tS
Convoraion of orCanosulfur comi')oundon 8158/001
by weight of catalyst. As established previously (see UCh, zap. i.-.GU, v.11,0,
1953, 263), in the case of mixed sulfides of.the C 6H5SR type (R beinE an
alkyl or cycloalkyl), the bond between the sulfur and R is always ruptured.
In the case ol"A-II, it was found that C H and C H oil are formed viith
10 a 10 21
further conversion of the latter to G 10H20 and 1.1 26. --4 -111 also ducom~;ose:j
t
- aame way, forming C il and cyclopentanothiol with subsequent con-
iL . 10 a
vers-6on of the latter to dicyclopentylsulfide and H 2S. (~ -III under t:,.ese
-iondlil'In3 decom Dozes to ~,-I, cyciopent.-~ne, 0 H ard H,6. In the cas~~ of
10 8 e
ft-, 11 OH, a decene-decano fraction and H 3 -;.,ere detected. Con-
III -It 0 10 21L' 2
se-uently the bond betv;een the sulfur and the benzene rinE in :Axed Sul-
fide:; is iauch more stable and .vao, not rLiptured in any of the ca!ies examine'l.
The bond between the sulfur and the C 10 illa~Ln the.-i-position is far lcs:;
stabLe. The bond bet-ween the sulfur and the alkyl and naphthyl in the
-er
position is zore s-table than that betv. n the sulfur and naphthene ri-111L.6
lAbstracter's note: Com-,ilete translation.]
6ard 2/2 1

IV
S/081/62/000/010/045/0,35
B168/13180
AUTHORS: "it s-3kvorts
i..... _qya-, 1. N , Danilova, T. A., K'uvshinova, N.
Transformation of ortanosulfur compounds at 300 and 4000C
in the presence of an aluminosilicate catalyst
Referutivnyy zhurnal. Khimiya, no. 10, 1962, 169,
abstract 1OZhgg (Sb. "Khimiya seraorgan. 86yedineniy,
soderzhashchikhsya v neftyakh i nefteproduktakh.
v. 4"- G.ostoptekhizdat, 1961, 132-155)
r2S.','1T: The transformation of or"ano3ulfur comuounds of various classeo
t ) -
,.-,as studied on an aluminosilicate catalyst at a Ler'Petature of 400-500C.
In the case of C Tj SH, C H SC H and C If SSC 1111o crac%ing accompanied
9.10 9 19 9 19 9 19 9
by formation of the ganoline fraction is the principal reaction at 4000C.
7n the case of ar- and ac-p-thiotetralola on an aluminorlilicate catalyst
at 4000C no processee occur other than tho3e %hich take place at 3000C.
,,hen aromatic orGanosulfur conpounds are brought into contact with ;Ln
only ",-he
,,luminosilicate catalyst and the temperature raised to 5000C,
quantitative ratio of the reaction products varies, but not the direction
Card 1/2

s/oal/62/000/010/045,'085
Transformation of organosulfur ... B168/Bit3o
of the decomposition processes. -Abstracter's note: Complete
-translation.i
I
4
Card 2/2

Bl 17/B147
Tj IT" T C) R
Ryl~ni kova A t. s-Sk-vortsov., , T 'i~ , Norclov
17TTLE Hydrogenoiysis of sul furor-anic. compounis on aluminum- cclba I
f.~iolybdenum catalyst
P E R 10 D I C.A L Refcrativny,, zhurnall Khimiiya, no, 2 5 , 196 1 , 1')O - 1 1
1-,l;'t(-khimi-j-k, v. 1, IIWI.
TE~IXT For the first F.1.;lfi"leE.-., an! (itsu
ot, ~he -u)_-pnat'C und aromati,. nn an
(:;! t ", I.-T F I -,,-rc- n :) -:!:atic system fit hydr.- .:r~- r;
r fitl ['11, lin'd Ild 1 t ("I t* 7'a I. I !;I I hy d ol I!; om, 1, 1 ~ I,-! r,
~Q n - n o ny I mc, rca n n -,.- nd t h i o phe riul anid ( 1, .1
4e un~'
.,!.If, de~-~ (d i n-nonyl sull fid d inhenyl ~ul fide) are suggest-~?d , A~~ c o r,~
t 0 -, ~l ~- r,' I Tl ( a ) , t h e lpr-),.,~os I ~i kes p I ac- i n t wo d i rec t i on.~; :
p + H H, 3 1 Rif' ~t ri d 2 RS H --~> H S -t RS 11 Tt wrin round that Ql.F, hydrr-
2 P
f oi, tho 'tromatic -wrlco
r -i i -i -.r:i m-1 via:-. Ila t some oll I'l 7- compoll""d
r", r T .11 l d t'u r i --.:t I I on. c.,;, ANIC :LrIA
Card 1/~

H S/O~i 1/6 1/000/023/0 i 6//0(-') 1
.vdro,:Yprtoly-Qis of s u I u r o r ga c '9 1 17 /B 1217
ht.,Tdrocarhoris were the Cinal pro-Auct; slitfur was 'pren ip L ta t ed as
-,ulfjd,2~ The lulf 'tir compoiinL3 uso(l in tills -Iltudy V~Pre
Iflo d I c r ib t2 c! o t Iic~ i t, or, iL,-i r--

I

-'a r 1 4f, r
!7, n hF, -7, e

'U~
0 3 t ;I I ff;i I
i
iT frf A'.',c a r t-.- h -,;i td i n th i n'
t,v ~j r n r r;o a A"t, -)o I - -
r r 1) e d i n "i-l") [I I ~t Clli.1 -4 1;,- 'i'A "L; i~ I t A o n ;3ome etner i addej rc- tr; e
qu id
~s r
f f and tli~ ca"'al v za
r-I c. r-I a iI t n i~ u 1v Y, ~3
h arto ot;~ r y C. -i~r CIO Ino I e s o convertod su b s inr
r tl n n - n r ia r, I T

o e 7o ~i t
-
5 1 1) 52 1013
.
C) V)
r; n-itty; d -'1 .3 e

S/081/61/000/023/016/061
Hydrogenolysis of sulfurorganic ... B117/B147
100, 112S, (II), M, (111), 59.2, 33.9, 104.7, 10.0; diphenyl sulfide,
98.7, H2S, C6H6' (IV), M, 48.2, 13.7, 97.8, 11-5. 7 references.
IAbstracter's note: Complete translation.I
Card 3/3

DANILOVA, T.A.; TITS-MOICSOVA, I.N.; KUZMTSOV) B.V.; NASYROV, I.
111torttation of wreury acut4to aquooun 80lUtIon vith organic
sulfur compounds. Vest. Mosk.un.Ser.2: Khiz. 17 no.2:72-75
I.b:%-Ap 162. (MIRA. 15.4)
1. Kafedra khimii nefti Moskovskogo universiteta.
Norcury acetate) (Sulfides)

DANILOVA, T.A.; TITS-SKVORTSOVA, I.N.; NASYYROV, I.; KUMETSOV, B,V.
Reaction of an aqueous solution of mercury acetate with sulfzr
organic compounds. Vest. Mosk. un. Ser. 2: Khim. 20 no.2:79-90
mr-Ap 65. OAIRA 18j7)
1. Kafedra khimU nefti Moskovskogo universiteta.

Z/O1i/62/O1q/ooi/oi4/o17
E073/El36
AUTHORS. Rybnikova, A. A. 1 and Tits-Skvcrtsova, I. N.
-7:7~
TITLE., Hydrogenolysis of organic sulphur compounds on
aluminocobaltomolybdenum catalysts
PERIODICAL: Chemie a chemickA technologie. P~ehled technicke' a
hospodAr4ske' literatury, v.19, no.1, 1962, 35,
abstract Ch 62-483. (Neftekhimiya, v.1, no.1, 1961j
104).
TEXT. The conversion of mercaptans, sulphides and
disulphides of aliphatic and aromatic compounds under conditions
of partial hydrogenolysis is studied. For the aliphatic and
aromatic series, a similar conversion scheme applies. It is a
complicated process, during which the sulphur compounds become
mutually transformed and the final result is the formation of
hydrocarbons and of hydrogen sulphide.
3 tables, 7 references.
~Abstractor,s notes Complete translation.3
Card 1/1

A(-'(l-*w.Sz,()~; NP T:30,,

Acc,Essro.,N NR: AT3001315
ex,nerime.nts was satilsiqctory- '11-w efft~,ct (if viilriol)r-
14VTI Ullo
Card 2/5-

anch. A!~ Fs~~ P11 T-~
,h-,- lit -733 sh-~ r P?
RN-l 7TT D. 1:
Card

ACCESSION ~,I: AT"001315
ENCU~SURE- M
Fig. Effect of mAfides on Me corrosMty
of hydrorellned diesal Wel:
1 - dibenzy1waUlde; 2 - diheptylsulfide; 3 - dibanzy1suffide
(!r% an atmosphere of N2).
Ordlizate: corrosion In g,/m2; abscissa: collcentratxn
4/5 of mdfide S in %.
CV%;,,T'JeMCd Cf~pbl, Wit

f0
Fig. E" C-ct of me rcapbujs (-)rl
sl-~itv if ilvrfror,~-fine(f dies-I filf')
'l,3Cy1:-r)erc,4)tar : 2 p-thlocrf~,--()!
N~nzvlznorcaPian -1:
5/5

0 a 0 0 0 0
61966000600000404 0000
0. of 04 11901 0 0 Cr 0 0 0 0 0
14 a 16 u a 0A; &j Aj a a Ile
C 4L Aal
lot .--A --- L-A-
*0 PIOCIIIII AND petpilefill W011
0*4 1-S T/ T7-&-j
00
00
'Imaneffin Dow* km" tow pm.W" *00
,0.3itt.C.L la"yLa"i 46 "Lumoti LAPOk 1949. VOL -400
010 iti [In Hunprimaj. The prospeda of andini,
WO
00 bentonits in Hunpuy &M:
=00
Hungwimin ormim i. dmwn
tO thO fact that the tem'bentmlite'14 SW used in H. 0
for rvvtotin &Iuminium hydnwilicatm which do not iIixtw7tb~
00 .3 !:=~ming bentonits understmi in otim coo
;00
0
00
Ago
ZOO
too
toe
I
Ato-ILA SCIALLUKICAL LITINATLAC CLASUPICATPON 9 1
7L7 .94., 04.6n.
Irla" sivivill",-- WOO
t samari -1 1%slaIj lal) Qkv cat --illi J&&
U AV 6 0 It 0 Aa a 31 a IF
00 ~: I III I T
It 10 Atwa It a a tt at d""a
0 0 0 46 0 0 * 0 0 * 0 706 0 0 0 0 0 a 0 0 0 0 0 0 0 0 0 * 0 0 0
00
0 0 0* 0 00 0 So 0 0 0* 049 4 41 0 0 ** a 0 '. 0 0 0 0 0 0 0 0 0

F7 f/ r
B"6mits as a o"andary m&WW In foundrin. 04skit
-SIUel--Bdjvydis. Kvh&s. LaM 61,
-Vor the evaluation of Hunj&rlan bentonlies as wconilwy
materials in foundries, the amt. of water sbmid be deld.
which is required to obtain sofidification in 24 hirs. Reu-
tonites of first quality talm up 154imes their own VoL,
water absorption in the 2nd group is 10-times. in the 3rd
group 7-time4 as much as the Vol. of the sample. Thitto.
tmpy and film formatictu on drying are 2 characteristic
properties of bentunites suitable for application In foundries.
1. Finily

III I Ile t' I if N Na Ill I iii,taIll
fill /11 -Ijo
1;11)N
V.1; 1 4 ir
tic I ..... .. IIll,. 1n".11 ~,1111041
:! i ra f .... I. 1 1, 1, 1 - I I I I t I . , ~ 'I I I .... per
Thu oll offill'! I'm III I I I I , . to I 1 .1.1, 110111 (If 4 f-liel"V Ili vxl-
Jillf, lIlM:-1I:IfImI I'll, I" , 1. 11 1, N, pow,,w ( wledij-, Inr 'Tie Imrl"-
If fft-If r fit Ill IT! I lo, m I If I It 1, if I nd,-: :'* Ali i-x a 1uple (I 1 0, 1
I f,1 I Il I t Itit, I - of v1 , I re "fit I 1:y I I I
:1 111 V1 IC t t C11111.111%,

TITTL74BRLJ-N. Boguslaw, doc. inz.;N01WAKOWSKI , homuald, mgr inz.
Utilization of large electrothermal receivers for power
load control. Energetyka Pol 17 no. 7:202-207 Jl 163-

TITTIEIMRLF~"., B.
TIM-1113RUTI, B. The conception of turbine units in analyzing the work of an
electric-power ph nt. p. 297.
Vol. gs No. 0', Nov./Dec. 1955
EITIERGETYKA
TE07HIPIOLOGGY
I
Warszawa, Poland
So: East Europeon Ilecession, ~01- 5, No. 5, May 1956

TITITEITERU11, B.
TIT-Fr,IFRIIrI'$ F. The need of drying transformers. P. 131
Vol. 10, no. 3, May/June 1957
ENTEVETYKk
FOi ITICAL SCIENCE
Varszawa, Toland
So: East Eurorean accession Vol. 4, No. #- 3, 'Yarch 3957

0, L
14M. Moisture In transformerq arLd its '117yal. B.
Lnet~e`c~lyka[Kufoii ice] 4, No. '-17-
'I') T034-y In Pchih~
Phy5ical lays goveming n)oistoye r1iigration in
transformer oil and insul-Ition are stated. Mcftds
of detumining wliether moisture in transformer
imidation approachei clangcrous level. ure di&cusscd
tcgether with niethucL- of moistw-e nmo~al. Cover-
ing vf, transfornicis during ovuhatils, Nvhcn.-vcr
possibf,-, to prevent contact with large quantitici of
moi-outrc-ladcq air is recommend-d. J. 1XK1',--ZEV,,C7

,',.UTIIOII,S:
39664
5/056/62/043/001/014/05'
B125/B102
Titts, T.,-Boychek, L.
'i'ITI F
1, formula for calculatinr phase shifts in the case of
Thomas-Fermi and Hartree potentials
PERIODICA.L. Zhurnal ekaperimentallnoy i teoreticheskoy fizik-i, v. 43,
no. 1(7), 1962, 87-88
TEXT. In the case*:of Thomas-Permi and Hattree-poteniials, the formula
r. 12 V (bIllip ~-,S S sin" q, + 2 ',~f2- ein fp
at C1 (21 + 1) (p I n dy. (7)
OT Y(bjj~L)' + 8E Si n2 q) y 0111A),+ 8E air,2 9 - 2 YTE Sinq
for small phase shifts 6(,,,) + 6 (2) + can be uzed to calculate the
I I
correction 6 (2) to the Born shif .t This formula is convenient for
practical calculations. The relation
+ b1 (6)
Card 1/2

S/056/62/043/001/014/05506
A formula for calculating phase ... B,25/B102
describes the Born shift, and Q1 are Legendre polynomials of the second
kind. The subscript i in (6) and (7) varies between 1 and 3, dependin- on
the value of the atomic number. its exact value can be found i~:
W. T. Byatt. Phys. Rev., 104, 1298, 1956. After the determination of a
from (7) 61 can be calculated from
2 (1) P
- at ; (5)
CIP
and (06). 2-c- (7) is much better suited for 1 1, 2 than the phase
15(1) derived by Born's method. There are 2 tables.,
ASSOCIATION: Institut tleoreticheskoy fiziki pri universitete v Lodzi,
Pollsha (Institute of.Theoretical Physics at thehod~
University, Poland)
SUBI,-'ITTEO: November 8,,1961
Card 2/2

4 7 EWT "' 1) A_)( a ),-5/ A
ACr-'ESSION MR: AP5000540
S/0051/64/C17/006/0805/0808
AUPHOR: Titta, T.
TIME: Analytic Tnethod for an appr:)ximate deterTniration of the
t~igenfunctions anud energies of elec~_rons 14-1 atoms
SOURCE: Optika i spektroakopiya, v. 17, no. 6, 1964, 805-808
TOPIC TAGS: Schrodinger equation, alectron energy, eigenvalue,
x ray line
ABSTRACT: The author solves the siagle-electron Schrodinger equa-
tion by using exact numerical valuea of the Thomas-Fermi function
for a free neutral atom. The method of F. Rasetti (Rend. Lincei,
v. 7, 915, 1928- Za. Phys. v- 49, 546, 1928) is used to determine
he -_~'Jenfunct' Ple-trons ir the atoms,
- - By
f Yhomas-Ft-rmi
M

ACCESSION NR: AP5000540
past) it- become2 possible to calculate analytical ly the
-'-e energ.,es of the eiec,~ror,.s -r,. t'ne deeper, I p - d. an d f
t S
energy 2tates. T-1he x-ray terms obtained in this manner agree with
thcse obtained experimentally as well as with those calculated by
the Hartree method- Orig. art. has: 13 formulas and 2 tables.
ASSOCIWPION: Lodz Universit , Poland
SUHMJTTHD- 29JunC-2 ENCL 1 00
SUB CODE: OP, GP NR RFF 30*,/,. 000 OTHERt 005
nff
M

.24 (5)
AUTHOR: Titts, T SOY/56-37-1-44/64
TITLE: On the Methods of Born and Pais for the Detection of Phase
Shifts (0 metodakh Borna i Paysa dlya nakhozhdeniya fazovykh
sdvigov)
PERIODICAL: Zhurnal ekaperimentallno i teoreticheskoy fiziki, 1959, Vol 372
Nr 19 PP 294 - 295 (USSR~
ABSTRACT: It is a known fact that, in cases when Bornfe approximation is
found to be useless for the detection of phase shifts, a more
exact methodo such as that of Faiso is used. The author of the
present "Letter to the Editor" gives a short description of
the two approximation methods with respect to the plane shifts;
Born's and Pais' approximation formula for them are written
down. In the following, the exactness of each of the two methodB
is compared for a concrete case, viz. for (11,p)-scattering at
,:00 Mev. V0 0 45 Mev and a 2 0.266.io 26 om- 2, Rosulta:
Pais' appreoximation 1 - 0-534 2 - 0.221
born's approximation I - 0.487 2 - 0-197
Card 1/2 Second Born's approximation 1 = 0-552 2 - 0.231

On the Methods of Born and Pais for the Detection SOV/56-37-1-44/64
of Phase Shifts
Pais' approximation thus gives much better results than the
first of Born. There are 4 references, I of which is Soviet.
ASSOCIATION: Universitet g. Lodz', Pol'sha (University of the City of L~d~,,
Poland)
SUBMITTED -. rebruary 2, 1959
Card 2/2

86907
S/056/60/039/005/024/051
*Coo B006/BO77
AUTHOR:
TITLE- Scattering of Electrons in the Thomas-Fermi Model
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki, 1960,
Vol- 39, No. 501), PP. 1347-1348
TEXT: The author offers a calculation of the differential elastic
scattering cross section of electrons using the statistical atom potentials
as proposed by Latter (Ref. 1)
V(r) = -(Ze2/r) J(x), Zl~(x)~ 1 in Thomas-Fermi approximation.
e2 /r, 7, �(x)< 1
X) is the Thomas-Fermi function for the neutral atom). This ansatz for
th13 potential yields more accurate energy values for the atom than the
Hartred method. The author obtains for the differential cross section
38/3 h4 Z 2/3 1it(x)sinPx dx + cos Pxo 2, wherel,91is the
234/3,r 4/3e4m2 1k2 0 ZP
Card 1/3

6
Scattering of Electrons in the Thomas-Fermi jo~~6~60/039/005/024/051
Model B006/BO77
2/3 .Z13 2
scattering angle, Z Nx 19 P = 3 hv sin(1%) 3 . 11 siO/2)
0 27/3 Tr 1/3e2Z1 327/3 Tr 1/3e2mZl//3'
v - electron velocity, ~- the corresponding wavelength). Using equation
5) for I(A) the cross sections are calculated for Ne, Si and S. In the
~
table the values are compared with the results obtai4ed by employing the
Hartree method in first Born approx.imation. A more'exact study showed that
the,Tesults of both methods agree quite well for large Z but exhibit a
large deviation for small values of Z. The author thanks Professor
P. Gombash for his interest and Ya. Vatso for aid in the computations.
There are 1 table and 4 references: 2 Soviet, 1 US, and I Japanese.
ASSOCIATION: Lodzinskiy universitet Pol'sha (Lodz University, Poland)
SUBMITTED: June 4, 1960
Card 2/3

Car,113/3
4
to- 31,
2
O'l
0,2
013
0,4
0,5
O'B
0,7
0,8
0,9
1,0
I'l
86907
S/056/60 /039/005/024/051
B006/BO77
1(0). cxs'
Ne St s
no

PTP no (5)
C
a .11 0

no (6)
lx.npTp.l no

, ,
X PTP
4900 26708 70000 38346 57600 44555
3900 6315 13200 11053 17400 13707
2180 2936 4150 5189 6130 6428
1220 1465 1830 24j68 2600 3021
700 716 WOO t2M 1340 1487
420 375 610 660 770 832
256 221 400 4 12 480 527
156 M 275 275 394 350
106 101 188 185 H2 233
72 70 130 1 160 141
49 41). - 94 116 97

TITTS . T.
Electronic polarizability and diamagnetic susceptibility of
neutral atoms in the Thomas-Fermi model. Zhur eksp. i teor.
fiz. 40 no.6:1699-1704 Je 161. ?MIRA 14:8)
1. Wzinski-y universitetp Pol'skava narodnaya respublika.
(Atoms)
(Diamagnetism)

TITTS) T,
Scattering of electrons in the 1homas-Fermi model. Zhur.eksD.i
teor.fiz. 39 no.5:1347-1348 H 160. 0~& 14:4)
1. Lodzinskiy universitet, Pol'sha.
(Electrona-8cattering)

USTI NOV, V.S. ~- AR' I rYTTI-101:7. E A. I. P. ; 'TO'FLUYKO, I M.
KULIKOV T PXXW
TIT,'TKHI',-%'r'%, L 4 '1'
-'-Increrisirig mn~ne:ziuui reuovt;ry ciu.,--,rig the rerrielt-Ing of a
condensaLe. of riiagnes-i-wr metal and magnesium chloride.
TSvet. met. 37 no.ll-.75-73 N (YIRA 1-3:11,)

L 45675-66 EWT (m) /T DJ
[6~/666/&_4/0019/0021
ACC 111R, a6023623 SOURCF, CODE-. 8
AUTHORt Rogachevaq L. M.; Kazanskiy, V. L.; Titurenko, S. G.; Beschastnov, M.-V.
ORG: Kuybyshev Scientific Research Institute of Petroleum Refining,,(Kuybyshevskiy~6
nauch.no-issledovatellskiy insEit-uT po pe~;raboEke nofti)
TITLEt Production of the antiseize additivAi(alkylbenzyl) disulfide in an experi- I
mental industrial unit
SOURCE: Neftepererabotka t neftekhimiya, no. 4, 1966, 19-21
TOPIC TAGS1 antiseize additiveg sulfurizationp chloromethylation, saf4A650~ile
ABSTRACTS In order to determine the exact technological conditions of the process for
the industrial production of the antiseize additive di(alkylbenzyl) disulfide(ABS-2)11
and to prepare an experimental batch of oil with the additive for extended perT-ormaike
tests, an experimental run was conducted on an experimental industrial unit. Tho syn-
thosis usually consists of three stepsl (1) chloromethylation of a mixture of aromatic
hydrocarbons with Formalin and I[Cl; (2) reaction of the chloromethyl derivatives thus
obtained with aqueous sodium sulfide to form di(alkylbenzyl) disulfide; (3) purifica-
tion of the latter to remove active sUfur compounds. The results of the experimental
industrial run indicate that the technological process of production of ABS-2 does not
require any complex ap aratus and can be carried wit on typical chemical plant equip-
ment in two stagest M chloromethylation producing alkylbenzyl chloride and (2) sui-
1/2 uDct 665.4%66.o22

L 1156.75~66
ACC NIL AP6023623
furization of the latter. 'Ihe efficiency of the chloromethylatIon uf arorilatic hydlu-
carbons obtained from the heavy component of hydroforr-ang is largely determined by thL)
rate of stirring of their mixture with Formalin and concentrated HC1. In quality, the'
ABS-2 obtained with the experimental industrial unit in identical to the additive pro-!
duced under laboratory conditional howeverl its viscosity and density are higher.
Orig. art. hast I figurei
SUB CODEt 1i
Card 2/2fv

FRAVDINA, K,I.;__TIUNOT, L.A,
Iffect of r rays on the zanthine ox1dase and aldebyde dehydrogen"-O'
activity in the livers of white rate. Ked.rad. 4 no.12:81-82 D-159.
(MIRA 13:5)
(LIVER radiation off.)
(MMS313 metab. )
(MEMROOMSES metab)

TIUNOV,.K.V,
Upper Cretaceous sediments of the Greater Balkhan Range.
Izv. AN Turk. SSR. Ser. fJ-z.-tekh. khim. i geol. nauk
no.3;49-56 165. (MIRA 18:12)
1. Kugitangskaya geologo-razvedochnaya ekspeditsiya GPGK
Turkmenskoy SSR. Submitted Sept. 29, 1964.

?ALIYE?IKOP E*T*;,T3PjOv#:'r.*V#.
Goomorpholof;ical structure and hii3tor7 or tho de-vololmnt
of tho rollef of the Creator BmlkJ= Range, Izv, VI Turk,
SSR.Ser,fi,s.-tOkh,# k1dru i goal. nauk no.5s44-" 165.
opaniiesn)

MUMMA, R.Vj; RODIONOVA, N.A.; TIUN,OVA,,-N.A.; UlYZLO, J.V.; SAFONOV, V.I.
Study of celluloty-tic enzymes of ~lyrot~ecjum verruclril. DolcI. AN
sssR 162 no.34.702-704 Fq 165. WIFLA 18.5)
1. Institut biokhimii im. A.N.Bakha AN SSSR. Submitted August 17P 1964.

-T.[T'YUNIK, G.N.; SHAPIRO, V.YK.
- n r,~. 1 a - 4 ~:" ~ re
blechanical properties ce ai-a=in-jm, alloy plpe
1.4 1
the degree of deformation during drawing. TSvet. met. 36 no.5:
76-78 My 165. (,Hl RA 18:6)

, prof.(iS94-19CO'~ TITUNIN, A.Yu..
1.11MI-T, Yurly Sergeyevl,71.
red.
[Irl, ini ature electrical nachines of autov-atic sysrem;31
Zlektriehp---kie mlkromashiiV
Izc.1.2., ispr. Moskva, Energilti, 1964- 1~23 1,.
(%., [ ic't -,F, - 1 ~?

SHAKHNO, I.V.; FLYUSTICHEII, V.Ye.; TITUNINA, Ye.M.; SAMUSEVA, R.G.
Solubility in the system ffa2CrO4 - C82CrO4 - H20 at 25 and
500C. Zhur. neorg. khim. 8 no.6:1466-1469 Je 163.
(MIRA 16:6)
(Alkali metal chromates)
(Solubility)

TIUNCV, L.A.; VASILITEV, G.A.
Effect of cytochro.Tc on the radioprotective action of carbon
monoxide. Radiobiologiia 3 no.5:766-769 '63. (MIRA 17:4)

SVWIA)V, Mao, kand.tekhn.uauk; SOLNTSEVA, R.N., inzh.; TITUSHIKA, M.I.,
inzh.
Granular explosives for charging flooded boreholes in opencut
workings. Vzryv.dolo no.44/1:40-57 160. (MIRA 13-7)
(Explosives)
(Strip mining)

SOV/'5l-5-1--_'/'1q
AU MORS Titushina, V.P. and Fabrikant, V.A.
TITLEs InvestigLt ion of the Radiation Flux Divergence of the 2537 X Line
in a 1dercu Discharge (Issledovaniya divergentsii potoka izllacheniya
linii 25371 v rtutnom razryade)
PERIODICAL, Optika. i Spektroskopiya, 1958, Vol 5, Nr 1, pp 3-9 (USSR)
ABSTFACT: Under steady-state conditions the divergence of radiation at a given
point is given by the difference in the number of collisions per
unit time uhich excite atoms and the number of collisions which
do-excite these atoms. If the excited atoms are not affected by
secondary processes, such as collisions of the second kind or
cumulative excitation, the radiation divergence (div G) should be
proportional to the electron denaity (no). In this case the curves
of distribution of div G and no across the discharge tube should be
similar. If the secondary processes are important then the curves of
distribution of div G and no across the tube should be different.
The authors investigated the 2537 R lino in a positive colutiin of an
are discharge in low-pressure mercury vapours. Coris tru ati oil of the
Card 1/3 discharge tube rjas similar to that described by Klyarfolld (Ref 4).

6 OV/51-5-1-1/19
Investigation of the Radiation Flux Divergence of the 2537.& Line in a Eercury
Discharge
The discharge tube diameter was from 32-38 mm, the length of the
positive column was 450-500 mm. Measurements were made at various
pressures of mercury from 2 x 10-4 to 1.5 x 10-2 mm HS and currents
from 0.2 to 2.5 amares d.c. A, vibrating luminescent probe was
used vith its surface parallel to the discharge-tube axis. The
vibrating probe method vas described in detail by Titushina (Ref 6).
Div G -was calculated from the brightness of the probe emission,which
was measured. Simultaneously with optical measurunents the authors
found tho electron temperature and density using Langmuir and Mott-Smith
probes. Fig 1 shows the distribution across the tube of the
radiation diverGence (black dots) and electron density (open circles)
Both these quantities are given in the form of ratios of the value at
a particular point to the value at the discharge-tube axis. At law
pressures (5 x 10-4: m. Hg) and div G/(d1v G), curve (subscript 0 denotes the
value at the discharge-tube axis) falls faster at the tube walls than
the ne/neo' At pressurOB of the ordor of 6 x 10-1~= Hg the two curves
coincide, but at higher pressures (1.5 x 10-2iin Hg) the div G/(div G)o
curve fallis more slorwly than the electron density. The differences -4
Card 2/3 between the two oirves indicate that in the pressure regions around 10

~;OVI~-)l -5 -1 -1/19
Investi~ation of' tKa tiadiation Flux Div5r-~,cnce of ~;he 2537 X Line in EL ;,.arcury
Discharge
and 10-2 Rm HG i3ocondary procaBsou are important In the mochanism
of
axcitaliorl of atoms to the OP1 level. At pressures vi me order
,L
-
10 min HS and discharge currents of 0.5 A the secondary processes
intensified amisaion of radiation. At pressures nea.- 1.5 x 10-2 mm Hg
and disc~urge currants of 0.5 and 1 A different secondary processes are
active and they quench resonance radiation. Fig 2 ahoi~s the dependence
of the ratio div G/ne at the discharGe-tube axis on the current. Fie; 3
shows the discharge current dependence of div G/n. at a distazice of
Figr. 2 and
3
0.8 R (R is the tube radius) from the axis. In
,,
_
numbers 1, 2, 3, 4 refer to pressures of 5 x 10 4, 3 x 10-0, 6.5 x 10-3
and 1.5 x 10-2 mm, H& respectively. A short theoretical lureatment of
the observed effects is given. It relates the radiation diver~~ence to
the probability of primary excitation processes and the probabilit;7 of
secondary processes (intensification or quenching of amission) as well
as to -the electron density. It is concluded that the m6chanism of
excitation to the 63Fl level is complex and it is determined by difflasioL
of radiation and the electron density. There are 3 firures and 6 Soviet
Card
3/13 references.
=0CUTION: Moskovskiy ener&etiches1ciy institut (hioscow Power Institute) 1, Radiation

SUBMITTED: --'I'heory 2. Discharge tubes--Properties 3 Atoms--Excitation
4
Jul
1957
:,
y
4. Secondary emission 5. Mere ury--Applications