SCIENTIFIC ABSTRACT TITOV, A.G. - TITOV, A.I.

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SCIENTIFIC ABSTRACT
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A TITGV 5 r, . -1.11 . Tito-v --.i.. G. - YA region of colored stones," (The Illmen state forest imerd V. !. leninj -Georrafiya v 5:~!-cle, 19LI5, No. 2, - . 2-;-Y-F SO: U-453b, 2~ Oct 53, ~Letopis 'Zhurnal Inykh "tatey, No. 16, MS)). 17., -i nrf., n';'I -.1J, zrt-- gm, r, i r irT rlpnr fika iT,- all" , TITOW,--A.I. [T~tov, A.I.] prof. Ionocomplex mechanism of nitraticn of aroaat~- and unsaturated compounds. Wiad chem 15 no.12:741-811 D 161. 1. Panstwowy Instytit Naukowo-Badawczy Organicznych Polproduktow i Barwnikow w Moskwie. TITOV. A.I. Primary loss of weight and some features of water exchange in newborn infants. Vop.okh.mat. i det. 1 no-3:19-23 XY-Je 156. (MLRA 9:9) 1, Iz kafedr7 gospitallnoy pediatrii (zav. - daystvitollny7 chlen Akademil meditsinskikh nauk SSSR prof. A-F.Tur) Leningrad- skogo gosudarstvennogo pediatricheekogo meditsinskogo instituta. (INFARTS (NAMB11)) TITOV, A.I. Chronaxy during the first days of life in infants born prematurely and at term. Pediatriia 39 no-5:11-13 S-0 056. (MIRA 10:1) 1. Iz kafedry gospitallnoy pediatrit (zav. - daystvitelinyy chlen AMN SSSR zasluzhennyy dayatelf nauki prof. A.F.Tur) Iseningradekogo pediatricheskogo meditsinskogo institute kdir. - prof. H.T.Shutova) (NNRVOUS SYSTRU. physiology. chronazy in premature & normal newborn inf. (Rua)) (INFANT, NEWBCRN, physiology, chronaxy (Rua)) (INFANT, PRMATURX, physiology, same) FUn.TNTSOV, V.I., nolkovnik mad. sluzhby; BARONOV, V.A., -p-olkovuik mad. sluzhby; T)olkovnik mad. sluzhbv, dots. ; FIALKOVSKIT, Y.V., Polkovnik mad. sluzhby; SM.IRMOV, K.K., -)olL-ovnik mad. sluzhby, kand. med. nauk; DOVZlb4NKO, G.I., polkovaik mad. sluzhby; DIVN39W, P.G., polkovaik mad. sluzhby; GORYUSHIN. G.S.. T)odpolkovnik mad. nluzhby; SHC~EKOV, N.I. podnolk6ifiik mad. sluthby;,ZMK, Ye. G., r)odpolkovnik mad. E;Iuzhby; BUTOMO, N.V., maycrr 'Ged* sluzhby; P]BOBRAZNEBSKIY, P.V., mayor mad. slnzhby; TUMONOV, K.B., mayor mad. sluzhby Clinical manifestations in subjects exposed to prolonged ionizing ir- radiation. Voen. vied '. zhur. noi.2:40-43 F 157 (MIRA 12:7) (RADIATIO11S, effects, A clin. manifest. In subjects exposed to prolonged ionizing irradiation (Ras)) TUR, A.F., prof., zasluzhannvy deyatell nauki, otv.red.(Leningrad); VCLOTOV, A.H., dotBent, red. (Leningrad); EVASHATA, L.G. , dotsent red.; KOTIKOV, Tu.A., prof., red.; LIBOV, A.L., prof., red. (Leni~- grad); MALYSHEVA-H&SIKOKOVA, Te.S.. dotsent; red.: MIRONOVICH, V.K., dotsent, red. (Leningrad); TMUIOVSKIY, S.D., prof., red. (Moskva); TITOV, A.I., kand.med.nauk, red. (Leningrad); IIATAROVA, N.V., red.; LIVS11TS, D.A., tekhn.red. [Proceedings of the Seventh All-Union Congress of Pediatricians in Leningrad, 1957; abridged stenographic report] Tmdy VII Vsesoyuzno- go s"ezda detskikh vrachei; sokrashchennain stenogramma. Otv.red. A.F.Tur. Leningrad, Gos.izd-vo med.lit-ry, Loniiigr.otd-nie, 1959. 654 P. (MIRA 13:5) 1. Vsesoyuznyy suyozd detskikh vrachey, 7th, Leningrad, 1957. 2. Deystvitellnyy chlen Akademii meditainakikh nank SSSR (PGr Tur). 3. Chlen-korrespondent Akademii meditsinskikh nank (for Torno'7skiy). (PEDIATRIGS-COITGRESSES) TITGVj A.I.v kand.med.nauk- POTANIN, N.V.2 kand.med,nauk I Case Of erroneous diagnosis of --osinaphilic reactions in rhildren. Sov.med. 24 no.U:I-U-114 11 160. (MIRA .14:3) 1. 1z kafedxj gospitallnoy pediatrii (zav. - deystvitellnyy chlen A14N SSSR prof. A.Pi.Tur) Loningradskogo pediatriohookogo meditainskogo Instituta (dir. - prof. N.T.Shutova). (=INOPHILES) (LEUK124IA) TITOV, A.I. Erythrocytometric data in anemia in premature children. Vop. okhr. mat. i det. 6 no. 1:22-25 Ja '(A. (MIRA 14;,4) 1. 1z kafedry gospitallnoy pediatrii (zav. - de7*stvAel'v*y -. chlen AMN SSSR prof. A.F. Tur) Leningradskogo pediatrichookogo moditainskogo instituta. (dir. - kand.med.nauk Ye.P. Semenova). (INFANTS JfREMAVM)-DISEASES) (ANEMIA) (ERYTHROCYTES) DYMSHITS, L. A., prof.; DROZDOVAP M. V.P dotsent; BELEVSKIY, A. G., kand. med. nauk; TITOV, A. I. Lesion of the eyes in marble disease (Albers-Schonberg disease). Vest. oft. no.2:52-55 162. (MIRA 15:4) 1, Goopitaltnaya pediatricheakaya klinika (zav. - deystvitel'n7y chlen AMN SSSR prof. A. F. Tar) i kafedra glaznykh bolezney (zav. - prof. V. I. Grigorlyeva) Leningradskogo pediatricheskogo meditsinskogo instituta. (BONES--DISEASES) (E;YE--DISEASES AND DEFECTS) TITOV., A.I.; BARYSMIrKOVA, A.1-1. Chlorosulfichlorination and ---h! orosullfochJ orinat ion ,f ethylene. Conversion of -Ihlotoetharm3ulfinic acid 4o 'Itio ethe:?. Dokl. AN SSSRP, I. - 'j I 51 no.l.-139-1142 II (MIRA 17,8) 1. Predstwi-leno akadamikom M,M. Shem7akin-ym. AUTHOR: Gitell, P. Titov, A. 1.; Sizova, M. V. !TITLE: A method for p-r-)d,-lc!n- B-chl~)rallryl fal~-n-! -4-*~~il,.~r,-~~-"I-su,.h.Inq~,. 1 -1 S,~; N.D. ;SOURCE: Byulleten' iz,Dbreteniv i tovaniyL-h znako-.,, no. 1'~65, 20 TOPIC TAGS- aklyl phosphine, chlorinated organic compound 1ABSTRACT: This Author's Certificalle 4r- n-n SLPMITTED: 014E-=c62 OC GG Cart! SHILOV, P.M.$, doktor tekhn.nauk; KRIVOSHEYEV, A.Ye., doktor tekhn.zlauk; DEMIDOVICHI N.S., kand.tekhn.nauk; RUDNITSKIY, L.S., kand.tekhn.nauk; FLOROVI K.V., kand.tekhn.nau-k; SHAIPOVAL, I.M., kand.tekhn.nauk; OLEYITICHENKOI V.G.' inzh.,- ZAIKIN, N.A., inzh.;_TTTOY, A.I., irzh. Replacing alloyed steels by high-strength cast iron in manufacturing machine parts. Mashinostroenie no-4.,59-61 JI-Ag 165. (MIRA 18:8) L 5409-66 E~.'T(l),"E,,IT(m)/i/giP(t)/DIP(b)/DIA(c) IJF(c) JD ACC HR: AP5027386 SOURCE CODE: UR/0181/65)'007/011/315913162 AUTHOR, AbrLpyan, 1. A..; Lavrov V. P.; Titov 1. ORG: Leningrad Polytechnic Institgto (Leningradskiy politekhnicheskly Institut im. M. I. Kalinina) TT TITLE: Secondary emission of germanium bombarded along various cyrstallographic axes by potassium ions SOURCE: Fizika tverdogo tela, v. 7, no. 11, 1965, 3153-3162 TOPIC TAGS: semiconductor single crystal, single crystal, secondary emission, _germanium single crystal -~~ 71 ABSTRACT: The ion-electron emission of germanium sin le crystals is studied to determine the effect which the crystal structure of the target has on secondary emission. Germanium specimens were bombarded with potassium ions at energies up to 7 kev, and secondary emission. was measured as a function of the angle of inci- dence. It was found that the coefficient 60.1 (the ratio of the number of ions reflected from the target at energies greater than 0.1 kev to the total number of Card 1/2 L 5409-66 ACC MR: AP5027386 :primary particles incident on the target In the same time intervial) has a strong Airect relationship to the temperature of the target. At 7500 %diLth primary parti ,,cles in the 0.5-1.5 kev range, 60.1 = 6-7.5% at angles of incidence between -30 .and +240. The experimental data show that the angle of ion incidence affects se- .condary emission in the semiconductor single crystals In a mannej7 similar to that lobserved in the case of metals. It is suggested that aU single crystals regard- !less of conductivity type (insulators, semiconductors and conductors) or type of i - ~chemical bond should show a non-monotonic relationship between the angle of incl- t 'dent radiation and secondary emission. The authors are grateful to ff. A. Yeremeyevi6-.r and N. N. Petrrmwlov constant interest In the work and useful camultation. Orig. lart. has: 2 fig [SUB CODE, SS/ SUBM DATE: 23reb65/ ORIG IREr-. 006/ QrH REF: 003 VK !Card 2/2 L 18754-66 &C(l)/:-24T(M)/EWP(t) IJP(c) JD/JG/AT ;ACC NR: AP600377(0 SOURCE CODE: UR/0181/66/008/001/0111/0114 1AUTHORS.~ Abroyan, I. A.; Makarova T. N.; Pukshanskiy, A. L.; itov, A. JORG; Leningrad Polytechnic Institute Im. M. I. Kalinin (Lening.radskiy politekhnicheskiy institut) ITITLE: Excitation of electrons In aermaaiu by alkaline metal ions -f, V/I 15 ') ~- 7 -7 SOURCE: Fizika tverdogo tela, v. 8, no. 1, 1966, 111-114 TOPIC TAGS: germanium, single crystal, alkali metal, ion bombardment,' electric conductivity, pair production, electron interaction ABSTRACT: The authors investigated the increase in the conductivity of germanium single crystals upon-excitation 'of electron-hole pairs by lithium and sodium ions of energy up to 6 kev. The induced con- ~ductivit, was investigated by a pulse technique described in detail earlier 4TT v. 4.. 27191 1962), The target preparation orocedure is also described elsewhere. To compare the pair-production efficiencies:.,;,- of electron and ion bombardment, two guns, one emitting electrons and~'- Card L 18754-66 iACC NR: AP6003770 Ithe other ions, were Installed in the apparatus. The germanium used was n-type with resistivity -u38 ohm-cm. In all' cases when the Ion beam struck the surface of the germanium, its electric conductivity increased. The total number of electron-hole pairs excited by an ioni of given energy before It Is completely stopped In the target is e3- timated with the aid of Fermi-Dirac statistics at -500 pairs when lbombarded with 3-keV sodium Ions and v2000 pairs when bombarded with Mthium ions of the same energy. The number of pairs is-found to decrease with increasing atomic number of the bombarding ions and to increase monotonically with increase in the ion energy. The values l Iobtained experimentally agree with the theoretical estimate. Orig. ;art. hass,..3 figures and 2 formulas. jSUB CODE: 20/ -SUBM DATE: Oljul6.5/ ORIG REF: 004/ OTH REF: 001 2 2 TITOV inzho Y Compensation of capacitance of Vest. TSNII MPS try with the aid of 'he the 701tage diEBY=4,~~ - . the DPR (two additional wIreB-ra,,-I) .3ystem. 24 n0.6:40-43 165. (MIPLA 18-9) A S 1 C11 11 AP5021~',!' A U"11HOR -Gitel', P. 6. ; Titov, A. i.; Sizova, M. V. 4.1 TITLEE: A method for producing ~-chloralkyl ~--Ikenyl-') _d-irhIer,~.-ph-sph; nes SOURCE: Byulletenl izobreteniy i tovarnvkh 7,naYov, no. 13, 1965, 20 TOPIC TAGS: aklyl phosphine, chlorinated organic compound ~ABSTRACT: This Author's Certificate introduces a method for prod'icing 9-ch1or;31kv1 1(alkenyl) lic-h1orophosphines. ~'r--jsphor~is is w,,*k the !clefin r-r 11A n-lon I-,- P AScSOOTATION: on e ,NO REF SOV: 000 Card J/l L 56o4g-65 EWT(mVEP;(c)/-E'z--(jj )/T 17C-11 ACCMSION MR: AP5018360 AUTHOR: Titov.-A. I.; Sizova, M. V.; Gitel', P. 0. TITLE: Neu reaction for producing beta-chloroalk)rliichlorophos)ihineFli, according to an ionic mechan"sm P Y. UP,/OID20/64/159/002/(,38r,-/Y'C)3M i'-otr Olefinz SOURCE: M.' SSSR. Doklady, v. 159, no. 2, 1964, 385-388 TOPIC TAOS: chlorinated organic compound, organic phosphorus ccmpDund, ionization. readtion mecharnism ABSTRACT: B---ta-chlorGalkyldichlorophosphenes ,mre produced by additioin of PG1 6 olefins in tbA presence of aluminum cliloride, onalogotioly 11() the a r. hme o Ets e I e c t r o nn a Card 1/2 NP -. AP XESST011 PGi3 and olefbi were used to shfft the equiltbrip. Lr, thf~ ner-p-s9sry dfrectt(lmi. S p -:7 iF jr r v 7~ c t~ t9 Tic c, 1 s c ASSCCUTIGN. none SUBMITTED: 06May64 MICL: 00 SUB CODE: OC, Gr- UR REF SOV: 006 OTHER: 003 J PRS r-~, - Card 212 AC'a?~~ION NR: AP 5 0172 90 i,,p /rI nri-, I or)-, AUNIOR: Abroyan , I. A. ; T i tov A. I TI TLE: Induced conductivity in gemaniyn~jduring homt,ardmpnt by pntas;ium ionis in differi-pt crystallographic directions -k ,SOURCE: Fizika tverdogo tela, v. 7, no. 7, 1965, 2007-2012 JOPIC TAGS: anisotropy, electrical anisotropy, electric field, electric conductivity, semiconduct ermanium ~ -tor,A iABSTRACT: The induced conductivity in single crystals of gerranium was investigated as they were boml-,arded with potassium ions with energiGs up to 7 kev. The experi- menta! device consisted of a sphere with two mutually perpendicular -?Xtensions. One r)f these a sourt:~e of alkaline ions whi le L~e other contained the sinRle ryst;3' germin i,im. target The tar;7e' , wa cri e7 n wa,,, ~~,31 c-t I e r C ---I Ce ~'l iciv'~E~y oeelffl was varied by rotating the target. A flat ~5creen cr)ver--,! with "Wille-mite wa'; -~Ja -1 ir. fr.-3n+ of the target a:i,~' canzzroiledl by an ele,:tromagnet. Caj-d 1/2 R 74-65 4~110!1 RR: AP~0172' 0 A ,This made it possible to observe the ion L-oam. vici inrl p!rvc-ntt--I t~:r- tinitri)rtion of iho whor "hr- w;i,i lifted on1y whilt- thp ~-!irvont p~iise r. ~,I Mee d 5 A,~ 11 1 S 0 pr3ter:~e~! the S-'r-4-L-ce 7;F -ne fr% fr- _J cuiiductiviry corresponds to the direction of maximum crystal "transparency" to the ions. "The author-- ar-- grateflu, to M. A. Yeremnyev for Constant intems~ irl work and tt~7pf~il advice, and t--~ 'N'. D. f-r ir measline- me ri t S ,rrig. 3r,. has. 5 f-gureL. ,ASSOCIATION: Leningradskiy pcilitekhnicheskiy institut im. M. 1. Kalinina (Leningrad Pol-technic institute) ISUBMITrED. 2gDec64 ENCL: 00 SU13 COVE: NP, EM NO REF SOV! 003 OTHER. 005 Card 2/y 1. Ti-rov, A.I. 2. USSR (600) 4. Agriculture 7- Production of butter of improved quality, Moskvp,. Pishcheproudzd!t,1952 9. Monthly List of Russian Accessions, Library of Congreso, March,1953.Unclassified. nt o0 -It'asllit~f C'.'. k~ ~dai ~U& 'Fli~O~'V:- 4. Tislidonitfl. MOO dy V .. Y 'V5 ,t ,To. 13, 3949; Rtferal. &ur., KhOn. 1954, No. 37129. '-Fresli butter, put to storage just after its prepa., preserves its arlzi:nal qualities for a long period of time when stnted at lemps. not higher than +I*. Melled butter is best stated at tempi. approx, -5'; at lower temps. the undesirable pistachio-jTeeu color cau be developed, at high temps. the '11qpidphasecuutbesevd. Milk fat Knd refined butter have to Lie titnrrd at temps. not lower thau -5*, and not higher 1han 8'; under these covd(t1=s the atorage can he as long u 2 years. Pasteurized butter can be stared for 3 yean at tctap3. not higher Unn 6'; when the butter is made from (at + millt it can bt btorcd for 2 years at minus temps. only. The product made from fat + -%alt water Ij st2ble also at 3 talopi. us) to a *; such 14 product Is umally net attacked m&4da, ry butter xt4nx%J lit hermetk-ally scaled can, t4 Dmierves its n4turl freshilem for 12 months avtu when ept at 19-20*; 'at lower temps. It I, Atable for 16 snant ". When butter contains yeasts It can be stored 14mnt cliatiges for Alp"t any awl 2 yemv.. 7_17-06 A),_2, 'AUTHORSs Titov, A.I.; Vlodavets, I.N.; Rebinder, P.A. 69-20-1-13/20 TITLEs The Processes of Structure Formation in Milk Fat andTheir Significance in the Manufacture of Butter (Protsessy strukturoobrazovaniya v molochnom zhire i ikh znacheniye dlya proizvodstva slivochnogo masla) PERIODICAL: Kolloidnyy Zhurnal, 1958, Vol XX, # 1, pp 92-101 (USSR) ABSTRACT: A study has been made of the strength characteristics of milk fat and butter. It was found that in order to satisfy the consistency of butter)the fat must form a mixed crystal- lization-coagulation type of structure with the coagulation structure predominating. The specificities of structure for- mation in the production of butter by churningjand by the con- tinuous chilling of high fat content creamjhave been examined. Two major ways have been indicated for improving the butter consistencys controlling the crystallization temperatur3 of the milk fat, which allows changes to be made in the total solid phase content of the system, and regulating the me- chanical treatment in the hardening process, which allows changes to be made in the character of the structure formed Card 1/2 so as to bring it closer to the crystallization or to the 1 69-20-1-13/20 The Processes of Structure Formation in Milk Fat and Their Sifnificance in the Manufacture of Butter coagulation type. There are 6 figures, and 15 references, 11 of which are Soviet, 3 English and 1 Dutch. A.SSOCIKTIONt Vsesoyuzayy nauchno-i5sledovatellakiy institut molochnoy promyshlennosti, Moskva (All-Union Scientific Research Insti- stute of the Milk Industry, Moscow) SUBMITTEDt July 19, 1957 AVAILABLEi Library of Congress Card 212 *4 66 9-0 6 0 0 0 0 0 0 9 0 0 0 0 0 0 0 0 6 0 1 4 1 0 1 0 0 Is It 13 li w it Id It w a It n A id a i'714,110" li Id is 4v u h A 61 #j #1 A A a a a ?-.Q A -)--I IV. a I , II Vt I 1, ~w .Zl rN.M 0 if tOnn&ld*hYJPOUIIOIYIAIO, V K %IAIVDICV Awl A V a Vh Ikm), %ldt 31, IIN1:1, 1.1 4,111i%t. clustAIIIIIIN 41--ill I III'd C11.0 and I m.4 .4 NA Our added AN'lit 1 1114.1 '1 zil tfLj*t And IlloU 'd 11,A), 00 #1, 00 * 0 .6's so 0 to J,o 0 .Ol & 5 0 - 5 L A.91AMIRrICAL &ITIMATOOf CLASSWKATION 9 1 14 ba 0,1 v u s IT VD at I ~at a 4 1 14 0 OAO 0 0 O'o 0 0 0 0 0 0 0 0 0 a 0 0 0:0 0 0 0 * 0 0 0 * 1: 00 0 a 0 0 0 0 0 0 0 0 * 0 0 0 0 jo 0 0 0 0 0 a * 0 0 0 0 0 0 0 00 7W 0 # *,; # # 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 0 ~o 0 0 0 0 0 1 0 0 0 off; 19 , " 0, " . x w " 4 1 I if if 14 10 , "1 l t ' 1 l I k 1 L a I i Af ii- I r0 1 T . - t , U_ Acatyllating aromatic amino suffoolc acids. A. 1. Tifov - A i-v. Rti- -w,*_lt-o, Njorcil nt 1juil i 4 4, " ,. owl th.-i. 'w' W.1 ht ih, 41. fitq: , -I..* ~ I. I ' "'' j a ~ ,,, fit, .'llhmu 0' W. 00 a 0 zoo 0 0 W L A MIIALkQ#GKAl LIIIIIAtfillf CLASSItKAItCh too u 4 W 10 1 I - 0: Offa lfx S li VU '6 ~hn I"I T .Vf( Kit ( %1 wt to (fit 0' 0 0 0 . . . it 0 C CFO -*-' *0 0 111 40-4111,111 0 0 0 0 0 0 41114 6 0 0 W-w-, U u it W It It It to 4 122 a )A A 24 1) 26 29 JU 11 1) M 38 is A, v x ILI 41 $7 A L_ L a 2 AA N (Z PC 11 00 Acylation *I amialsoultook acids. -N. N. VorO&haoOv gruttlia is Acc-talli"N 'he 'he"A". .AN- + RCtX)--N&* ri R(:O,N[I,Ar,* I - *0 and A- I ~ Titn%, j CAP- f 1* S.S. R ) 6. )'.*1 *-I.Rls - h%'* ef Lull- sind late of atrlylatkin and don, 'r, 14Y.. ('A#", 54. fil"(1140M. The ohilov (at V A 100 '1" I~y SgIgg 10 act pirleadjoly do the If -vI,*- I-, Nil _flIYMii0n Of 11) alCkIl UCFV %ZUI in She in"r2w III f1w x4y.. 'll.NAt- '0-11 fu). I.'-- am! anti I,-,- iMj'0"&.t factor "liva. W lI'N'C'IW "A).- F! 11.14WAh- + 11 + RCO,%'*) fliNC4114SINII tM atul l1wit wall. With AfOll and If- hr ,tv'stiOn Of I _It~ ill V llW_ 4:thN, with vlat 01th-ull the whism of N.41Ar aiml If. + N.' + UCtkll. ill I M 1110CWIMPSCINIS Jay tevetwd owilh 11W C0,N4. 41 111firallf latka aj,J lwdmb 64 lln)r I fie lfw- C I ant the slow raft of Acttyt4tl4,n ill thr vallit 4d 1 at'salt A1141 I hr lift Itilift. wnv treated with Ived water and JICI I the .19 the $"'way 0: uAthanord I seid,6 were thrated Wilb 0A N NaN(h. fit often o0cuffluir Inim-ilailily 14 ivnipleff* 6 cowl ni -Tn. Of fnv I UcLd. I don, Thisdiffcully in the artlylation 44 free IWO$ Will 0: own - and At her analysed t Wall dk-tved In dil. N&,C0, I heir AS Inch or United with tho, M'jlu 1; 00 so Vrodu" Of I'Mclitati- The liaboalated remit z 0 a show that it. of V valts. h.)Wrvrf, cars Influence the 1-f"Crev. rMlical diffirultiars In the wtlyf%gion of foal, I acid, can and the final ottate Of the fitudarriental re,action of Welyla 00 4P 0 be explained bY I Ile extrrmelY unall vorwrt. of satd. %Wns. all I acids In the nuboxyllar acials IV) at the It. p, of the don- 11,NAjS(hhl + RCOH = R0CNffArS(hM 00 latter. and the improtabuity ftm the t HO. At a ttom. of the casboxylate Ndt vxct-finat the hermod=mlc oraifonate -all (VII be- zoo virwtvinf o( Itair reaction., *JfiNArfi0j- + RC X - I M the coff"Ponding smin .&,,be, with the free I acid: If,N- ROCNIMMAoll + 11.0. Th.. Xnn-u P;t " at times to Z; 0 0 + Na" (+ RC )') j-t ll,NM4~!~* (04n.) a- mily. ad I Acids In V evidently W elaporiv related it) list edit A,90. 4100 formation Iiietwern tbo Nil. and 01,11 vuul,4. it 6 WJid tall. The frauld"S decrease rd tIW Vs CIMCII. Ma" greater Inv MOM than for AcOll. Enfirrlir different calm a retardation of lht ,-action; ""' Can "0;U" IjL_ i : *00 relations exist In the psimorrarr ut the same adit2 of v in tho~ jeally strong to th-k the s"Cletating at-tinn of furtbri old .4 ooln~ At th# twilinj temp. of V the *Ievirolylic div*wn. dClu.. .1 V it* to spite of the Increasing I)WIDS lernp. Of in J Thar cu of the tvisclioca vidd o(thrir edim fit very t he r*Wkxl mixt. a -ansid"able. l4tv,* the maxi: Stroto- OA, "men. 4howa, that lin' Pr bwrrat-'%4n orith ah"Sillan"Ma tain. of thr2actitv Itlaticarl to No joe III finihi f.In. if 'qatjA-. 0- 0401 I Z" Z. =0 'a .11ALLLPGOCAL LITEROURt Ck"It"KAT10" ire 00 09 8 WXY1 40 "a- 11 L 43 is'; to W at a ft It So 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * 0 0;0 # 0 0 0 0 9 9 0 9 0 0 0 1* 0 0 0 Ogg 0000000 0 0 0 et~ a 9 0 0 0 0 0 0 1 0 0 0 0 00 00 00 *0 00 00 ifternizing Imp. $lolls ftyrictstro the a4titut, And Ow #9 00 Virld. after reaching & UIM., tW9i114 (41 hNIVOW, 1 411416 *0 00 in), giving va-". Piahs. gave no in*%. flocauocifthr 00 -411ins-4mt. effect of the cations o( V mits, the AcrtYLAti.141 p(mluct Is gradually ppid.: ROCNIfAr.SO,- + No. 10 00 f+RCOO-) rj ROCNUAt$O..';& rz mWid saft. Thiv 00 action esums a shift toward the Ak*AIAW " (d the r"W. ** tim: ffsNArSChN& + RCOvff r-f R(X:NHArl*'hN4 0* 41111111 (+ HWO) - Now mit. making It p-acticable to hwtr*w 0111 the yieW abov that possible by the co"ditionq o( the so il.luaborixigenousmedhim. Theamelersibigarlion 00 he catiom of V safts dwesses in the order tA K, No. m 00 The rate of acylallon 6 sornewhat influenced by the Za 00 t;!~tum of I acids, and Inctrava with the greater ccm%t%. 00 0 4111 of electrolytic dissorn. of I acids. Thme. smylalkm of U $9 (Ko - 6.2 X 10-1) Procerth at a stealer vvkwity thAll 0* tbat of M (Xgo . 1,96 X 10 -4). The resction of fonnyls. 00 so lion VNceedii at a greater mte than acetylation, bm-awir 00 of the greater shift of the equil, towwd the eight %Ide, 041 Tbe catam. of HiNArS(h Ion canw; attain the main. point 00 at which VI we solicit out by the carkmi of V Wis. The 00 PPM. of famylated products Prociettis as in the MW of the 00 afttylatim products. Chas. Blanc to 00 00 00 0 l 09 90 M 0 oi ~ 0 0 0 0 0 9 0 0 0 0 0 0 0 0 0 O's 0 0 0 0 I 0 o 0 0 6 fit 0 4 0111 0 0 0 0 0 0 0 0 04 Got 0 0 0 0 0 0 $0 6 0 0 0;0 II 1AAJ-- ALILLI-L Is'.. Alt As It 0 it a 1) 0 Pa Is is I 44 in rills, t",,, `41iW ail time of P1 IC, IV) I. nitr slightly m IU action of altrossite di on issinezent. toluene and chktob sa 1 Wi ati. ore to give W- coned- It and it h h I nrcessitall-, 10071 CICANo ( a I Y higher tem nitrated V 0 n ao. . tmilm with aftMen dioxide la the Ffeessucis Of gulfutic 9814 PholPhOrk ecide A 1 , p. at 0 D. Tol -1 will, . 4; Vill bm "9e of 34.4% 1 l4 of Mixed U C ;i; . , Tituv and A. N. Daryishnikovs. J. Gire. Cliesn. .(U. S, ) e a 4 JI.NO. Mlb- About 2j 2~" - oltro. ile S. R 6. 1 141JI-60"ll. (ill the A-umptitin that It NO,, formed toy rrdctk)a of N l) ill with H R) (111 i th w tie~A i. -di t V11 with I ,, , Ml-b 111tiord. 1ji"I""gell 11111,1 1 10111 I , i . s e % . e , intratinS fissent when aromatic hy0tocarbon% am nitrated 1"n CIIII), S,%'- 111-detilled IMMUcts, if Preliminary Cc Filov " mm I 0 with I let the pirvorner of 11. thir following equation. sop. - wited b est d daraj ff d l i . llif I K unication , 1 V, 41., 111 jljq~ AIA I'll, I do,. o V 4 "., W - oll . Aci ri r I y tuexp a p n thecourstrof the reaction: Hil INPO, + if liiO..m lft0 - RNO, J, reat " I Iva 1 watt, Ill Irlop. A ,. V, sold Vil ,, I.,0111 t IM, 1 huld,led 111t V IISNO, + In 1) 110).-tini + 1) UP. To attain o , ( A c".) bif 14 hr, llll%t' of V1 (f) -1K. 9.). Ill the nitr t h **a i :~umplrlr utilization (if I the ratio loward the rod of the l 't'on at favor sli Of Vil vo. '" n. Of 1, 114111.41 If low IlevalellI 0e a k trariloon wf,*trn free It will water, too -- 1); (m f- 1), rill lid illilloillalloll i 1" , ' I ftc ' the sid , i 0 0 ~1 tnual exceed a certain solo. valor characteristic for ruch ,onspil. The great tendency of H to transfer protons to , e-4 lolls ob.11101i't ' fill, Is riplaillea fly 111,11,1111Y .11, "J"llor"er's' No, 10 slid t f f : *0 i consipthi. which normally in sq. otedium are not proton l i o u double On the duration of the reaction and ,b"d- 1-scix-lidins "'11edwithl "* e on 0 z acrMtors exp a rcs its marked activating effect. Neither unhyd. H.PO. nor 12.0, appreciably wtivates the reaction. ', 1 cn. of 1, V11 ~ in iht-sdj,,n,vofill days gives 1-21~1 still fo, Pl3c"Yho tro h indicating that they do not react with I to form HNO~. 1 p rriethan, 4 74-- -Adinitrotrietit:m- B,,O (X). 11 IS% 11,11 H (Za) To - 9.2 g. C#Ha (M), vignrously stiffed, kq added at 4W ' liver a per iodof:blniin.asotn ofl3Ag lin 19 23 if . , and Vill. c%poloe HIM. to d, of (he re. -ii IrtVI illuininali . . . . ir. I .94%). Stirring is continued I hr. at 5W and the reac- vil ijollight or ,If un cvleral all o IN- f " iian mixt. worked up to yield an dist n- cul,, d as Ws and in the ull I -~ own VM to 4 UV` ' 1 I 111111"Inali 25-309 j- it nitrobeniterse (IV), In. V, and 16.6 S. M. The reaction d b h h . X 21c on the yi,1,14 S~ 70 X. .,i 107. X1 , VW 43 ' -!Pe 7 XU and XU , .1 procee s eat w en t e cown. of free U is 79 He -M%. - low this corica I does not com kiel t b hi . and aft ProWbly t eke . d ~ "ge Of LK and X by hysiml; . y rew s owe t , a p conim. side fractions sharply lower the yield of IV. fig tt, and oxidation of VU. 1. L A I A. I L A 111TALLUNUCAL LITIS IALLII GICAL T l A WE CLASSWICATIO l M ~ L CZ- fig t JQ.. #0.1~. Is It -A' of U"'. It a. n It if As Is UAT 10 It se In I so An 1 4 of 0 If a 0 a o o ; 0 0 sis 10 0 , , , 1111109S 0a 00 610 * 0 a 0 0 0 se to to ___e 0 0 0 0 00 .0* -00 -00 -04110 -0411111 see wee 0 15 aeo Ives t: 0 0 1900 --i-0 0-0 0 0 0 0 0 0 a 4 1 0 0 0 o0 0 0 is I a I 1 '6106 00' 'A 10 0 Pitt Fists I.n 0 Aol4** of ottiviall. 4#vdM.*ujf"*w &.44a 11 Malk.4 A .4 Imi-709M).. C(. kill (d IA-Ciislis(14110- 4'( / .5hilwitsewried "n in the tollossirs, tanner: the WW was dissolvcd in a hot 'he .('A -1d. mid. oWn 'sGAc in 98% AcOll and the Assin. was 411.swtqllo* I IiIiiiifly) let lite entlof lite rearthan Then, 41J.'ated I 1"i". 41 Allpf slow v, .11111, Iffe I'I'l. l'"Ittril sea. 1111tit.1 alt'l 11's- III,,Iliv 11111'" *an 41,1111 u-) III Ifir I.I.- A I"' is'".. "as Att . Itivilatt wills a lit.1% lkwiton 4 Air antim, &,,i,1 A 't aN&OAc. It I! ptiouble to vlfirlr~ ut about 10 upera- S-OA1. I. p before reaching the limit of acid ditu. The yield of W I in" he cytation P,.dt Ist. latj product increased with each operation (77=.0 o(theory), becauqeof the increawo(concti. 0: Sit (it the AcOll at the ctmt at I he N&OAr. i. ir.. I he acyla(i(m .3 00 sea carried exit. Pra,11-11r. of lite cost 4 the Nnf)Av. "I'd *11.1 fAlt,whad d4wtoll(tril IfIfIrt fro") the first III that the arrlylaiii"i Isoitiltict is wo,fint with dil. A,WI, ft'sm it), pr,xlwt of the Preceding "Iteration d1jillig .0 'C' its drying. The lormylatlem of the same cuttilid. by this -00 method vielded about 94% of the product. A. A. 11. =0 0 *sW.j atTALLURCINCAL LITIMAIVIC CLASSIFICATION :61 1 . slow siv,v 041 1-t4"0101 ~-e- to I-j 0 or III it a 3 2 1 AT so is 11110 U Its A 1 0 U iitt a, arowa got V oft a U It OW "M 0 00 0 9 0 0 0 0 0 : 0 0 0 * 11111,411 0 0 6 0 0 9 0 0 0 0 a EOP 0 0 0 0;e 0 1111, 0 0 1111, 0 411 0 0 a 0 0 0 04 0 0 0 0 0 0 0 0 0 0 q 0 0 111111 - - - - - - - Z Q, 4 4 0 0 0 0 0 0 -44-4414~; ; ; 0 0 0 0 0 0a 0 I g I Z 4 4a, 0 0 0 0 0 It 11 1, J! it 1! L, 11 2" .1 ;4 1' It 17 1 ?1 JUH11 11 14b 16 If 1. 1, i .1 4f0 . h R I T VY A T I &A 14 OL W I XLa L A a Ii j . - - - . 00 40 00 00 00 00 velocity of acetylation of aromatic aminosul- 00 phonic acids. A-L-T=V--And A. S. 11-kRI. -00 g0 SLUNIXOVA (J. Gen. Lhatu. Rum., 1937. 7, 357-- -00 a X 302).-The velocity of cotylstion of I and 1:7 R b. been detenninod under 'NH1'C1OH(SO3 k different ooimlitions. R. T. Use I I I A A(TALLURWAL LITERATURt CLAWFICATION tz* .0 We 1 -- - - - --Y-! ` 1 It 91 M K It It R U tt a of n N Nr AA N 0 I I ji ~ M I 00 00 00,009 00 00 00 0 0 0 6 10 0 00 oil o 0 60 03 v to it u It is M It it IV a " all J1JU Alls Its) sops 0 u .3 III, g A I L -IL- t-A-1-6 4-4 -,,-, a ' - &~ 41 00 tu, a the At field t2soct). whu itia high tit lfierlz v& of force has been attsawd. the furnset! ru '. we nvxe pd 09 v . or Itsis vienpletefy ppid. (c(. I-ROJ, ' 00 of pitrusta dl*sM* am bassaw. Wumm Wisild and Wertypircich. I . A. 23. 4--Rij. Ndo. ll i 111 00 Al and tbiwolsouxentis. Ill. Skmdou witis altMiluss aside nuoiliscril, wish into 4 Itake. 'd gradua y * -0 11 in this pieloesce ist Aluminum chlorldle. willsom pista- 941 ; 65 g. (0315 niol.) I bCI strul 10.72 C. 111.191 sikil, i AW4 * A Cl i -00 0 1 chloddit and rugmutry stitrate. A. 1. ri(uv~ J. Gfx- 1 0 ~ s was vorisp ctely di*wjivrd when 3.74 1. l 'N (U, S R 17 Wl 4 IM .W.) NO, a, ab,.ioff~l, i. r., voictly ~,isdinij -00 I to the (twulula. AC T). FuIthrT Ithuirvitoo of NO, fig 11 14 NUIAIIAlk' IMIFIWORIKI40% th Ne), III the pccvetu~ -d I ' Minvan6l tit v%M Orfili-lic- litieraii-io ,( beat. Afirt lots v, 10.5 st Nils (11 114 in.4 1 (RA% tit thr 4!- AIC4 pitw%vol, by the fiatuatkin of this, twispitit AlO..- - . . . , =)" the CUCIO-ItIlir was Irplarcil by a teduk COMWI-i Wilfs(N(N)ONd I IV. kill [a the friseviii; d hydrocutWo. g 0 #1 64 roni vounc rted with I0% XOII and a rurren d its deiinipo. toy The action tit 1W) Into MCI, MX4 0 n u i 4 x. , of try Cf), *#* Im"", ljormth the girlefit-like irrarlio.. d IINtV Iftipil, ditts -howed that AICL is A 6ftdvw l i I 16 by the Itictioil I-( The ants. u( NA). that wu&iW Its os l1 heated pt*dU&IIY it? 1xi he ikin. of IININ ji"K. H ITAilliltd IM the (ol"940till tit 1, with fUItIWf Adda. of And I in the '$J~nbcist slum"I a li-w tit 7.44 X, NOU 0 Nith the, grac "I livist-crito Ifluck k~ vis"grik-ally. RW 1 tT.44 g. rakd, aivotdinlUo lite fixtinsfit 11)). Ittv filtre WAID 0 the actitio tit Ie0 if #it" itsill-pru"Ishe to the fiRmalksti 1 tshfut gate S 2A it. of k- At -Wto thrict! in a vacuum 13 ~ 4 nitto I be truction pross-4119 toy beating Its ' drislivator at own Ictup. (14-46 C. by the fixtauts (I) I NO rhe fillrair contalrord 17 ll dsl%i of mitrif ClC 2 s the itbwnv (it 11.0 4o-or,fins to tlw h-tivida; 2AIC14 . t. . . o :11111 1 3NP. -- :IRNO, I, 3N(K:l 4 AWWOJI)t 11)~ the altraiiiso of C.11o love attakwiti, or-ulay. 001 * 4 It is 1%youlatt's that the coussir of The Itavilimi I* vlowly fig A his 14141 the Irso"I 11111"I ducling N004 At IlAN 40 9 votturctril with the vaFkAts phas" of coeltitinated valn. wivasird the yield of ullto prodift-le by xl%. Nistalk'" 10 A P1 11 0 d 0*9 Of AICI,, Anti that the nitivient of AICI, win 04 - toceirgioutis - asi # 4 wish N,0. its lir h, pmwncio(AICIs(aik-dtogi%lepte Fvsulis TheSchau: vilth the visit is( the travtkin: lilt 4 N.O. + 2AICIs - . . Whinidt netbod of nittatkin of PhMe wa o im d b o0 RN(N.AlCt. I AICI.iOIi).N0CI vt RNO#~AICI*(Oll) + s vr pf y g the Intritsectilorof thr-oln, If hientival the tevetris-41 order of adda. of AICII to the itsist. of Nits. with that ril a AWL. w,hi. in the pr~-A N4WI '11w In M!". Is. 2") 41" And 111INte. froollinf l Ni l following stitvs iof Ili* ivacliots am tvistril to At tial ivi ist MCI w Ih N.Ah , " The pree"Wir tit Mi. Natr C" of CIV 140 ,01 111 Il Nt i h , -; Ottkally pturvvdivs sa(u. of (tit At drid al' fotv, M cv, . ., , t , and h w 1 a NO, fit (1, Kave rapidly A Ila it 1 0 t and at I..". Mill"11. Iw rirfirrAtatril fir the whirtn"; RN(N-A" + AICI 0 Z Assive-like itailim. ;Ldox at bous. SIO a ;- Rif - AICltOIV.t2R.N0,)(NOCI); ~j O am altm ste"14117" ve beagavie. foluit" "d 144 . Wl + NA #- kit -* AICI Ohl urld.l. 1011) 400"11F O IFIC 0 T 11110 T IC -ciptnimb onts clikrobvilsainair. IW,IW17 72, -M~4 AL A S a . S 1, 4 O ALLM W Ww- a a W-twirviling subvilluml. XWO; " j0h " Okhyde %90 ~ Stroups. do " FrAWt with NgOi tvm am*f prefoute oil ' '1 uvat V K) I i I' n 4 w w 0 1 0 0 IT u - - a s- ; ~ 0 e 0 * 00 9 16 00 0 0 1111114 *0 0 0 ' 0 4 0 s q 0 o o 010 00 # 19 0 0 4 * 0 6 016 0 0 6 0 0 't 0 0 0 A L*- ~ ' * 4111 ,il III- slid Inaurn ctwnpdm~ Is Gwily rile,,1_1 wah.Np, is, ' 11i h f f i 11 80 f 00 t e presentee o um . nck. I ng , (c I. , 00 1141tritay.C.A.11,11XII). Ito the nutatl--n of Mollialk cowixfi. with NrO, In the pre-race of 5n% of 00 coast4ned N is convened into HNO, which is not tt.~l 0 in the reaction. A compkie use of Nit), I, Ix-4ble in 00 thii 1&h. teats by the adda. .1 K.V). to the tea,two taixt. 00 V alter (he "Multiveloill oil file Ixf gfear a( (Ill. Irin-lian: 111119 RH 4. Me I 111A)s - 14NO* I IUSNO. 1 110); 09 "If + IIANO. I K"NO, - ItNO. I il.41. I "Al. I so 00 KJL4. flence, the without addial. so IIkLh or S". C.11.(N(h)t was obtained In 97,64% yield 00 fly valifing dtopwise. with slitting, 10.1 a. Nit). its V) a. -7' 45% fumin 11 RX t 122 PhNiLt I E Afi 09 00 o P a. . rt J , & g 00 -14rallng lot I hr.. the Irl"p. DI the rr;".14xtl tnill. **. Fill" to IM, 0 hr.), Own "U" 1.0 411' and 4111il. Willi 00 1 100 tv. 1111A). fly this nimil uxi. MirCJI.Nih save 9011,~ 00 I-ANWIIII&IT anti M M 61 1 C 2.4.0. MN)tCol I Me. And 1 11 N( V C ) i :'1 . i-m lit aildi . N ,( , 640 so ittle ivactitm ortup, 4"40 ) n howctl nortlcvt at the riatiar 00 00 And the y1clits of the Oration I'lool 111A K. , " 1141. 111 t. NtL% anti L I a. of 34% funiong 11"), at ;l 041 ormillef 0.6 a. of a alito ptoduci, solidifying at 46 4W. 7 - ' 3 i X 00 I) Treat . 7 a. (thl ittol.) p- IeCjIjN(h as vialt ng 1 0M l i 4 f M 0 N 12 fi 4. . P. jO- mo .) n it. a. o niang IIN), % 111441C o(:R) min luld then at file Mine frili 'Ailb 1:1 A ., 0. p. jUJIS inul and stittin for an ad l Ii .ull ) K ~Q t I of . . i . u t., m " . s lit 1". 11*6 2.4-iO#N),CJ1&%Ir. Fw4hlifying Imunt Os cll.~. Man, 'U. 00 V 00 00 so 00 a Ms- "Moo W# ANO 0200091,11 -0#0 00 68 0e A 00 L 19OW0819es 41 ZO A. I.- Own. R=I, - I9W- to"- it I - W mixt"MO(clipmN , r-- JqLA 0 sad JkOIL UW YW&%S Pdina =v9 vmvrww~ W aw4wsuc sea Saw* temp. obt9od Wkb PM& d mutim Wd W~Vd% R. T. dhosinviL I JUL 4 As"LA alt"LUt"AL UINNATtOt CLAUWKATWM too. 119,421va - 141461 -&b cow ant u " AV Q Ali; 10 D to to a of a 1 4 ; In 00000,00000000 ::.::logo 00:00 00 0 0 0 0 -0 #1- ~9910.i I Z- .104. Q.Ow -4141i1 -4tt , Wo as I IN tt a 00 1 0 000000006*0000 0000 -00 00 loo .00 '-See j 200 Ile* .-too ,too 1100 No 0 tie 0 ::0 ---------- 7 - Ktiff R R U.N-1111 Joe f 04 , S 0 0 * 0 I f - k. It it " I, " I it a a L U L r 6 it 4 L a k r 6 1 V A 14 h "a ff art 4-11 VI) 1.11 t," , I , ~. L AA 0 a W it, A Hydraly I of the amlno 910UPS in the nitro" and nitro 4orivativeo -of 2.6-diandnopyiidins and 2-amalno-fli-hy- V call lye otitaim-A fil "Al IRP ", Vivid fly immisK Ill and IV droxmilidine. A. 1. Titair. J. Grm. CAWm, (U - S. S. R.) Willi C.A.1 N ( M I'll 3 11,1V -I * at 1) 1 "II"I K,0 1. and 1" 14KI-JAIiin Fairtilb. cf. Zridr asid', 1-ili"it V oxi'lli'll Willi :10 , Ho, m Ill N!1~011 .4 1. t', A. 30. 11739'.- Alitmir addid. clipt Titov N44COT siv- 3--a- ~*.,-1,hJ--PY,14lq, M), I ~ml , l 11 1 1 silictl .4, the gtitit,111ir alul rurtsy -lationallilit AMM 11 ."1 lilt ,, I a. .4 64". -00 1 : d The Fraclim n( llydrEdyaq. I he IlCl 1411, A 1., j " IIN(h t- I x. R".. dl-~( o m l 1 81111 11 i Nil) and N a, at . (IICI Aw MOM fitact will, oil. it, jorl dr,irypyridim; (Vill), tr,4 41141 midalp"I N -490 . d , giv, U1.4it Ilit", wvf~ ol'idilml frmts I " JIT'hiticts. hkmieal pt' ! ! a 31. ill 1 mill IV fly midali'm Willi 110, In '111 '%1[.( M. I 1., - stud IV si%r tkl`~ W Id l 110 i .4 11 gav.. a 11-fly it It'd$ '10A .4 file .11 A, A Vill fla-l't --I N-,, 0 , . n %MW I'l 2. "lilt titl- il . lt i 1104111 At lb, fill IL days- lly'litAybi4 at virvacrit trittim lilt' Pf.1010'111 -1011' "1 Vill, 11. L411V 11" ' -Olill ' procced, very vapidly but give$ Misitirl"I'le i ill it" _ht I., 111 VII Alld Vill tilk" jlL1VV Willi lit 04 V call IK. jilcutly uk,taitted In INK10 field from I.Xillvis 1.111iliff. 110ifilIg %Hll 11,SA)j IM A fill, X4- trlke~i . I *nil It fly Ittating 2 a. amine in -ill UIL liso t-Jutg, it lilt- r of Nil, aud fill, pt,xim-1 0 Will, Ki ill ia j s. at t)- will& 4m.od lilt. cif 041 X NuN( h and lit'ilms Ga 2 Ili,. tile 'll-A, derm, .I Vil aml Vill 400 -d alh,wing the kra.lion mitil. I-, malld All, lra,ilv ImillAirt'd ill 11tyl, VI Ch~i.. lllmw 04111 far lu't.vs. V. a twatly _A~ltr~ -b.twav. jlVt73r,,1w~d .1111110 00 ludlis if I'll, Nil,, 134, No. K and kh', the int~r;-OY -1 -10 1111 file .14.w lmn"~ %, it It tile irmater t-ictt y of th~ makirm 00 .09 1.111N.TURF (1.111P.CAtiCk %u A, 0 0 0 0 0 4 0 0 0 a 00 00 C 66 to o 00 00 00 13 00 00 0 .4 00 so so 10000000000000 0 , M.L. if Of IVA _Ii 4 4 U LU Tog 00 The CA#MW Profwd" W scst'llitit- T%* "I"bWO ol Wd in &&qtj6 " in the fe-0941, Of filld(StOd. -0411 lljo-v.~' J. G". CA", (U, S. & It.) 9, 0.3"(1m) - k -studin an the effect of U acetate. Na Almlato -00 mid K acetate ork tbo mulY. of w1fardlic acid In AcOlf fe- .00 virmled that the say. was Inemwd couiddirtably. CkTtrudo &.rvend -L 111111TALLUAGIC&I. LITRI&IM CLAIVOKAIM 7- --:7 11119111#0 -- a; " Ilk vi I oill , - - ow d"I ilk 1-7410 U AT 00 V 1,1A 14 I I ff a L g I OW a N 0 0 0 0 0 0 o o o 0 010 0 0 * 0 # 0 0 ~ 0 0 0 0 0 0 0 0 0' 0 0 0 0 9 0 0 0 0 0 0 . 0 0 o o 0 o o 0 o 0 0 & 9 * 0 0 * o .00 A 0 too A 0 000 AO U00 wo~ 0 9 0 0 0 f, 16 0, 0 0 051?07101 f?119.90 loot. 1021, A. "1 11 is IT ZVY a loll U13 Ull 3611 xxv 41 043 hlan* no PIS s V 0 It T Z AA F- F- C N 1 9 L . u - . A - -L A -e PIC-COSIt A.0 PROER110 The inechanim of the Konovaloy reaction (nitration of Titov. saturated h!4Ttigbons). . 11. A. 1. J. Ceq. C1WM. (U . 10. IS78'SI(I!Wi; c[. C. A. 31, 85161-NO, acts an McPh at 10)* to give chiedy I'll- a Cff,NO, (1) and. by oxidation, litif and WOII. Sam, PhCI1(NO,)j (H) and nitfritolucurs are also fortned, but Wh has a very slight nitrating action oil the tiog, Con versely, HNO, acLs only to nitrate the ting when it i- pure, but if it contains some NO, NO, is jortned anti the side chain is also nitrated. rhu., it ureA is added to JINO, to remove all NO before nitrating, 2,6-dinitio-p- see =00 96 cresol is the chief product, anti the %ide chain is neithrr nitrated nor oxidirM, although the latter reartions prr- 00 Zee NO. dominate when NO is left in the acid. Ncillicr If. nor NO, converts I into It. It ii prolluced when the MCII, radical, fornieJ bv rmetwo 4 PhMe and NO.. reacts with NO to form i1tCIIINO which i,;ouierixc% m Q;0 0 PhCff NOH and then reacts with N(h to form 11. 00 It. M. 1xic"ter 1000 We 0 i'troo PTEMITURE CLAS111"CATION Ito 0 .11 CIl "1 0 Aii - 0 U AT PO It K ts rt It 09 n 1 14 An I 1 4 ftd 0 1 lc 14 1 it 4 3 1 #10 0 00 000 49 46 0 0 0i0 0 6 0 0 a 0 0 0 0 0 0 * 0 0 0 0 a 010 0 0 0 * 0 0 0 0 0 a 0 0 0 0 0 61'e- 0 a as Gig a 0 o 0 a & 0 0 a 0 0 0 0 0 * 0 4111-0 a * 0 * 0 0 IM R 021 . . 0 0 0 0 0 # 0 0 0 0 0 00 06 6 31 33 13 10 1 0 1, 00 0 11 .01 '0'. 44 01,0 000 00 00 # 0 00 19 0o " 00 W 00 L C-4 I a _j -&-t- J~ T7-60 Thari a l of Ia. favestiption of the d I Z l /0 !-Go . . 2 l ,. h dine and 3,6- droxy- y Y "Mahy ~ a ~'00 dine. A. 1. Tit ov nh. B. Levin. Chrm. - mr. S. S. continuation of previout 00 1 ock (C. A. 30, (17MV) tin vomptis. rontif all attliflovinyl 00 grouping. the vote of hydrolysio of if) was studied. On the banis of resonant situcint" the 0 relative case of hydrolysis of thin compd. to 2,6-,unino. -00 h* yridine is explained, as well as the comparative 1 "I tit further hydrolysis to the 2.6-dihydioxyt,vri. rhr tote of hydnily-it, hy 4111, lt,~k 1. wo- oudio,d n't front, 11o'c data obtained ok-t of In rative Conditoinq / 041 .00 fqW 11 will deld, as follows; lip g. I And 0" K. IIA"', 1 It-4 1, T are heated at 155' for 4.6 ht%., difd. with Mire. Hot), let Itand at 7-10" and the anhyd. sulfate of It is filterrd off in 4.6-g. yield. On diln. (it the mother liquor A further *0 ~1.6 g. Ito obtained, giving a total yield tit W%. Toobtain ~06 he free Ww. the sulfate UN g.) in '.'tp tv. tioilins wain it ;1roted slowly with NuOAe or NOIS(h unill twitteal top Congo red, boiled for several mIns.. filletcd and cooled. 00 The ppid. product is the hydrate of It (50.5% yield), m. ` .~W.5-204 . By treatment with Acj0 it iscuriverted into theOll-dia"fate no (39"(froonlitO). Prolonged hydroly. is,Wl in `70% UpRi. at 175" yiehli more Nil, than the 00 hrowellcol dint. fitim hydrolyWoo of the Nflo group,o. in- t 06 tilt-at Ing hydrolysis of the pyridine ring. Astuall(InAntily 1`00 of an acid was isolated frout this hydrolysis tuixt., but could not be identified positively. G. ht. K. =41110111111 Ald-SLA ARTALLURGiCAL 1.111101JR9 CLASSWKAMW MA.&SICNI *pilot a" a... all to to I IA KWI 1 -0 is AV No ISIS,, I $A I I V PM 0 M 0 1 it k 9 A a I U to Cr to 00 69 K 4 It N it cc if it 00 0 0 io 06 00 04 0* 00 004 00 - 09 -r 004 00 ,, it 00 of "-w-W-W-4v4v-4v,w v W- IV w W-W-W -W 0 x wl m u a 10 a 41 a a a t A-li-i 4 '1 4 0.. " 0 a 00 13 C- '00 SL A OCIALLUROKAL UIRRATLO11 CLASUPICATIC* t-It, , - u a AV go Ls ;o *00*0000000000:0:0:001 .T.'s 1 000 :0*!0o00o0,oGo:*Q****.c I la-I **-In. in a I #A L S I 000000000000000000000 o0 1700 0: 000000*000000000**Ooo 100 so 0 GOO 200 %0 Coo o Wo 0 VO 0 %0 goo 104 bo 0 too goo *$A 00 4 0 9 00 13 00 43 *OV Inductive, Mea6mlifle. And little Ofticts In Unuttirlited sad aromatic scids. A. 1. Tiloy.(Lilo, Orl. chem., K. H. vorashilov Milit. Acall., *161micow). . . Gels. Chem. (V.S.S,R.) 10, Iffil-MI94d)(in Rus.-lan).-The fact that a,$-unsaid. acids are weaker th;tri the cormsponifing 0,-l-unWd. widis (e.g.. Cif,C11,01:01CM11, loex - 1,11: CII,CII:lCIfCII.COOII. VIX - 3.41) 1- iotermted fly the sullcrIKKillms of a tx)G. lvt~wiorric (-# At) rffcvt on, the ties. Induclivt (-I) effect. rVitilling ill all Increo-W of the tit charte an the earboxyl And a Irsstning of the entirticy to ;onistation. The -#-.V effeel v.%plains also the; increased It: -ijj.c-ptopcrjk~ of IlliNth a4 minpuriA with. !IM-SLA 49TALLMICAL LfftNATURN CLAUWKATON b U AV 0 0 0 0 0 0 04,0120 0 me I wait Oz/ hlv.Nii,. whrle.44 Ito- det-Fritse of the I%LOC prol.flits in PIINII. U, cooil..Lml *tilt MeXII, i~ lur to the -M effret. The %troog bicteww of acidity from CII&CII: ClIC0011 to CII,C!CC(X)II I IOK - 250 as arunit 2-1) is und,r~iari(Liblv from lite fact thAt lite two r-booth of C: C Itc tit tti&mtit pLutt., only tow of which .u% he the scat ,(,in Af~&vt, Ijrtr;&, ill 11tv other in.joetivv alliav. gioll of "I'virotil t"n.on, oliv-411no,tted. I'lic loArge4l ck-cl I uph 111,111 Ill Ow e.kiltolivI C. ilue it) the At anti thel 0-trotorTic rAvvis, del.. l1w much lo%%vr r,ilmo( qno~vifi-l cation of acidb in comparison with tW corr"potuling !640. avioN, whereas the somewlLit greatcri rate in #.-f-uo"td.avid, 6vilplAinedbythe e 0,vurrence of the I-effect. Ina,inuch as full realizat"ion of the M-1 effect of r-bonds dvpvtjds on location of the cormpouding atou" in one plitne, sub~titucuts that disrupt the plarve structure an bteric Uoundi will hinder resonance and re-1 suit In higher a61 di,-4vu.; [cr atefic reAsm%. the cis, fornis of Cl[sClf:CIICoOll and of I,hCll:CIICOOII art.1 littongtr acid, than lite tr4m forms; the lauic stcric fmior! also umictlics the ffirtt-wse of iixiAlity from PhCOOH to o- NICCJJ,COOII to ~.1,1141eCJIXOOIJ wi contmited with the "ity-decreaillit +1-cffert of introduction of Me Xfoupa ill P" anti P IN)%itioni. Thecotntsinrdxrtionoftbt~ teric and the +I cilt-vt I, drid. for the stAbditr tit the I 2.11111-Africil 11CO I Varbunittill ion in U411. In &Vrx= 2-- 134. VOWAng --Ijiisl GK GOT Its i i a im o a v -i ir v 9 a a .00 goo 86 ~41111111111 coo Ire 0 t600 we* goo 1100~ Ze see see age it** WOO 0 0 0 0 0 -0 0 0 0 0 4 46 0 00 goo 0 o'W f 10 11 4 U M " M V 1 0 us :16sr alto A11 go 40411~0 I L A, 41- c 0 004 iiOry Of nitration Of saturated bydrocittlions and their d#riVs!jVQ' 1 G J l d 00 - , CuNrA Conc - usions on the primary ' Wertion of th i ! 00 In e react on. A.'I llov JIAIJ. L)r1j. %j -so got (wxow). J. J6 , 144-lig)(10916)(iii Riji. 004 -The incftectivellm, of purc I I.N(3, lot the "it'ati." .00 (Al 114r4fli-, lkiraffink- Adc ch.diii. and c)cIoWjffjnj, Was d ell"WrIliti Ill AWAY r%Pt4 at f': lit t - It elfin, * " " 2 T"F 7-Ahoethyloctati l l l o 7 . o r, cyc le' i, d ] h . " it IINO' l (I. 1.40-1,.L ; risults werc al- Sitg. with Cillo and cyclo. ' h e"'lle '&' IfX) , 1() lit", Nitration Proceeds not job see JA.No, Wt with So, which focill-i to mile xtent above 04 301% 5 - if) "d. cyviahriiane nitratetl with HNO. (d. 1.4) tit ' ;1* % V 40 - r4vc only 0-H of. proiluct while the same amt. re. - god acting with 12 9. N'(h gave 7.5 g. nitrated products. goo Furtfirr proof is dirrived front expose. an the nitration of 04 fill, J-11", Meic, Phcll,. Phricif, Phic. M-NIc viiih NA with czct%% of citht-r NO of 0~. in he -00 ow 38 kcal.) suit firm raw flu to 1, Ell 2.0, 3.0, 4.0. 3.5, 4.7, 3.1. 15, 26. r 'u wril disnell., X'06 - NO, + NO. dro- ondin h f th C rr ti it ti i l f E too 1 on o o ues or 1e n ra e esp 1e va f y g very Mix I.; in the presence of 0. due to the - 1 00 carbons, Rif. 11tat nitration 13Y Not is of the rAdwal olil,Lition of NO to NO,. nitration I!, significant. only as* rm-tioll type is furthri, corrot.,galel by uch (Ac-U aii its he "n"'?rMer X()~ is effective, NO, Is not. The '-Y Pful 0 t. locolzation in the hydrocarbon Oa-, abcnce Of An I rrac too isamumed tobe Rif + No,- R + HNO~Igiviflg ti -di f i t h i t. PreselKle e un on: ant o t ty ti ri- to free radicals R; by Its eltictrophilk nature, Nos .fluence of the liolar C i T " d T CL h h At Id . c -u w s s no strong , -,I,wus to at. h4loprill, being enrrgvtk-4Uy C1010t 10 Ac e" : - 1l i'While atwn. valu" of tile ene"" 0( stabilizatioci inechankin. Rif + NO, - R + JUNO!. is furtV" %up. hat 14 ra,lical, R arx- drrivrd flout the ditTerellcot of ki. 1"Itil by can4defutioris of energetic anti ii "ic imptub- ncti, cncrsjr4 of activation E d hydrOL-4i'llotis Rif and bility of other niechanisuis, such as )tit + NO, RNO, o( CIN. 4"uming the difference to be aptWo EA; for -+IlcwC--Crupturc. l * tile tytw RXOOII 6 improbabic oil ottic riound~ will on the nitrali"ll of elf H 43 to a is - ., all ht n ties of 66-1 (or a no. of rn,lk-aj% R (for ce of Cifi-trAUS ConWiNitkil UIMII'f 0W.W111011 Of Nos. A -.1 at'c I"#.' R Ft, f1r, 1300 - k SLA ACTALL411141KAL UTIRATU19 CLAIMPICATION ASO- I 11041 3*4W IlWas " - views 60,01MV - - - - - - MO - =4 S 4 4 9 I 183060 Nip OftV cat Call"C"Cl 1311111 Out 0-T ill U 0 AV 10 At I . , , . I M I I a w 0 8 1 Is so $10 ; it & a W 1, is 41 Or it i A T Us : 2 1 * 0 0 0 0 0 0 0 0 9 0 * 0 0 * 0 9 0 * 0 * 00 0 0 0 * 0000 0 0 0 0 0 6 0 *--W g'-* 0-0 * 0- 0 0 go 0000 * V W O s a I I I I 1 10 Is 12 13 u is 16 if Is AD v u III k a M jY Al 0 6 41 a it a d to -,A F J_ 11- 11. A Is IK _11~ 11_11_1 t' lit"11, - A *00 The 114itilkance of ateric fact orlt In 61kyuboa Aqu. Q!1.1 'zUJ,.Lf 06 &C I tilans A ~ 1, Titity'i K 1, jo. th- 2 r,-Ivms ' /0 -00 . VI)r,Atii',,v Mda. Ara.l.. J. r,,-- , CUM _ jt4Ijm t,y I .:..I ~.lkvwiitu by 11, pr,~I with Apw- 6, ;h1l 1 -IM(II1111)(ill Hu i4n); c( C A 41 S Amin is -0 thesunryaA-ity. rhel-tccicv. oi-acrst, the , . . , ' .1 fe.ielions Ythba type are detd. 1- *0 , : Undoubtedly greater in the nitrate that in the nitrite. but 04 ii not Ossify by the Poe. ekc. charge im the correspoudin I I 9 ter %jesic acceviibility the latter N exhibit' owing to Sm ~ so a electrophilic centers but also to a large extent b the its elccuophilic nAture m4we readily, forruing the intermr- " . o y 'k-o)"finafive isimitn." 4A thinse centers, expressing the diAte cunsiplex O=N -OCII,Ph. Likewisse, phrooli react d of their steric acemsibility and their capacity of ' = ut'N 4( f a consixts. with jk higher c~v&dis%Atiosa no. without o so substantially altering the elec. niturr of the rest of the readily with nittiles (in netstr;al or 'li4htly alk. inedi sur" , th RCIIO t i NO FAXI h C : forming nitrow coinpils.. hist are inert to alkyl nit ' mis u n %, .; , itsidSistoms ,, s. t e N. , o t i : 6 di li l td l d f di i (3) Further examp1m 0( t1w effect -)f sirric unsatri. me the ; to : are ca r na w y un%s . an teat y to orm nterme ate c m o0 .3 1 o te itho b t t tW i i Th alkyLatint action of alkyl indfAtri and the,wylating activn xe w c u 2u % ;4ti sixt vat mp on. ts- e nucle I 1 11' atoru A (charge -e) in the mol sc M-A-N will re ct ol most carboxylic acid riters. The enhancement bi the S . a . 00 a 1 J: F er With either the elewtiophitic ectiter % or with that alkyLifing Ability of sulfurtim acid esters by addris. 0(- 00 a i at tit (charg" +es anti +4, steric resistances, R, and NO) trong inorg. acith may he due to the form ition of interme- =0 0 it, the mol. (0)(T)(X) Bi-Ill (Y)(7).d 00 c ding on the r if 0 sign of the difreterwe tit the driving forces of the two fe- e* Sctions, itppcox. equal to the diffetence oll the two rate diatecompleiLm it _0 _S O-R] I 000 consts. ~: Ak ,, f, - ft -, Pe(ej - ei) - (RI - R,) where oo z J) a* o P 6 ~1 (unetion. of the I16tatim (3) These cimWitcrations are applied tit the reictious of MINH with the nitrite Ily w.sy of acylati-in of Priln-Y IliPhAtic al,7011011 H Pheu,N(h (t) and with the tiltmte PhCllsNO, (It):. V I i i h duc to a Iargr "tent to the greater steric acc"iihifity- see rcactun t A X. w 0) g. MINH under cooling. giving, ' Olf 300 after 2 da" standing and twice tepeater! distu., 94 20 ' to f th II C HIC-all" rif with o a ultrosuditnethyWnine. Ut.N.N0. Is. 17" , anti BN% o m I e a M c r mp 0 PhCllrOff; nil alkylA-tion took plam. On the other hand. 6.8 S. 11 maeted with 10 g. Rt'VIl with to 0 atom temp. ti%c to 65% solu. in 30 nil. HCI (L:2), the reaction proctrding over the In- oo with edier, WItAlinization. exits. with estber, and distia. of the ext. gave Nu% (PhCfl,dEtsX. b. 209-13% identical tI* a k Yw,-, with the product synthesized by bolling an a water hath - oo 40 -3 bra. 12.5 g. PlICIGO, 25 jc'co.' Cato. - 1 t its" "it I a ' *)&III ant ai. ~ Lis a ~ U 11 4' '0 "'i A 19 St K a tt It at K ; W ft An I t v 1W a 0 0 1 N as 5 a a 3 1 1, dara~ 0 0 0 0 0 0 0 0 0 0 T10 a * so 0 0 * 0 0 0 S'o 0 9 0 * : 0 o 0 0 0 0 * I 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e 0 * 0 e 7 0 0 a 0 0 0 9 * * 0 0 0 0 0 i i 00 00 00 00 00 so 00 0 00 00 00 00 0 so 0 * 00 00 so * 0 0 off of the alkyl. f