SCIENTIFIC ABSTRACT TISHKOV, B.N. - TISHKOVA, V.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001755820005-8
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 5
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I 1:1 ~-I! .
TISMY, B*N*9 fol'daher (solo
Intravenous injections
no.6-51-53 Je 154.
(INJECTIONS
*Intravenous,
Malinovka, Stalingradskaya oblast')
with a detached needle. Felld. I almsh.
(MIaA 7:7)
with detached needle)

AUTHOR: Tishkov, I.A.,- Scien-c-ts
TITLEi More Initiative in the KAhodical hork of the Chairs of
.Social Sciences (Bol'she initslativy v metodicheskoy rabote
kafedr obshche6tyenrykh naiik-)
FERIODICALi Vestnik Vysshey Shkoly, lir 5~ PP 33 -- 37 (USSR)
ABSTRAM The developmenL of tha S,;-,jiet higher school during the last
years is characterised by a Loarked growth of the systems of
part-time tuitiong eapocially that of instruction by corres-
pondence. Therefore~ the que9tions of work method with cor-
respondenoe students is Inoraikaingly occupying the minds
of the vuz workers, in thitj article concentrating on the
social sciences: I.e. pria;arily of the Marx-Lenin ttieo~y,
the Communist Party history, ot~,, It is necoosary to im-
prove the present forms of r,,)rk in correspondence. The
Voeaoyuznyy zaochnyy ekortomlcheakiy inatitut (&11-Union
Economic CorrasporWertoo TriotLfuto ) and tho Savero,utpadilyy
politekhniohookiy inutltiit (North-West FolytechnIcal Cor-
respondence Instituto) nave intrcd~icod the cyclic i3yatela.
The Vaesoyuznyy zaochnyy mauhinostroitallnyy institut
Card 1/2 (All-Union Machine Conatruction Correspondence Institute)

7
blore Initiative in the Methodical 4ork of' the Chairs of Soci -:-1 _)~c i enc e s
and the V5esoyuznyy zaoch.,-,-yy inatitut sovetskoy t ~) r E~ .7~ %, I i
(All-Union Correspondence Institute of Soviet Tra(ie) are
mentioned as having obtained considerable experietice on
questions of method. The Chair of Marxism-Leninisw of the
Vaesoyuznyy zaochnyy institut inzhencrov zhe1ezs,(_,(Aorw~hnogo
transporta (All-Union Correspondence Inbtitute of Hailroad
Engineers) is severely criticized,
ASSOCIATION; Ministerstvo vysahego obrazovaniya 5SbR (USOR i4,iLkJ'i_Gt.j
of Higher Education)
AVLILABLEt Library of Congress
Card 212

AUTHOR: Tishkov, I.A., Candidate of Historical Sciences 3-B-3/34

TITLE: Instructive Results (Pouchitellnyye rezulltaty)
PERIODICAL: Vestnik Vynshey Shkoly, 1957, ~',' 8, PP 15-18 (USSR)
ABSTRACT: The author tells why the Chair for the History of the KPSS
and Dialectical and Historical Yaterialism, of the Voronezh
Agricultural Institute (Voronezhskiy sellskokhozyaystvennyy
institut) has been cited as an example for other chairs in
Social Science.
He mentions the names of the instructors M. K. Meshcherina,
P. T. Khudyakov, D. S. Novokshchenov, who have either already
obtained their degrees or prepared their theses. V.I.Smirnova
has prepared her thesis for obtaining a candidate's degree,
while P. Ye. Pavlenko, T.K. Teplyakov and A. V. Losev are
conducting the necessary degree research work. The in-
structors V. I.Chekalin, V.T.Ivankov and Yu.I.Padalkin are
also occuDied with such research. Dotsent M.K. Teplyakov,
in charge of the Chair, is an able leader.
The author also quotes a few deficiencies noted in the
delivery of lectures and in the seminar work on dialectical
Card 1/2 and historical materialism. The USSR Board of the Ministry

,Instructive Results
ASSOCIATION:
AVAILABLE:
of Higher Education has approved
3-8-3/34
the ChaiA activity.
Upravleniye prepodavaniya obahchestvennykh nauk
(Social Science Teacbing Administration)
Library of Congress
Card 2/2

'fIU-KOVGIAI-'7q Alo -h; SIROV, I.D., red.; ZAXHARIKOV, A.N.,
red.lzd-va; KMASHOVA, V.A., tekhn.red.
[Postwar struggle of tho Commnist PArty for the rostoration
and development of the oooiallat national economy, 1945-19531
Bor'ba rommunisticheskoi partil za voostanovlenis i razvitie
,;otsialisticheskogo uarodnogo khoziaistva v poslevoennyl
erlod, 1945~-1953 gody; materialy k lektailam po kureu, OIstoriia
KPSS.* Moskva, Gos.izd-vo mVyoehaia shkola,", 1960. 121 p.
(MIRA 14:12)
(Comumnist Party of the Soviet Union)
(Russia-laotomic conditions)

Ti~ mv, ~rhn~:alAmni
2573~,M-L'.E~-K,Ca~)J); Givca TicuaCL;
Cokintry. Bulgaria
Aca---=~c not indicated
Aff 111- r. ~k ion: Junior Scientific Collaborator, member of the staf~of
s,j Editor: Tyan]lco YORDA1,10V
Geoi-ra;~~ya
Orouarcc: Sofia, Geop
.,~jqfiyp,, No 1. 19612 pp 20-22 and p 24
1.1,ta: "The Present and Future of- Weather Forecasts." (pp 20-22)
I'Dimitur Y. Dimitrov's Book The Wea"her in Bulzaria,
by Science and Ar~-CTJaWc-a i IzI-ru~-fv-oY State
Publishers, Sofia, 1560., 152 Pages it (p 24)

TISHKOV -,,-Kharalampi So, no sutr.
Why the ice is formed in the Bratsa Ledenika Cave.
Priroda Bulg 12 no. 4: 87-90 Jl-Ag 163.
1. Geografski institut na Bulgarskata akademiia na naukite.

TISHKOV., Kh.
On certain peculiarities of the Mediterranean climatic irSluence
in the Strandzha, region. I7.v Geog inst BAN 6:133-156 162.
1

TISHKOV, Kh.
Formation and spreading of humid trOPid'Al veather in eastern
Bulgaria. Khidor i m0tdorolOg 13 no.6j22-32 164.

TISHKOV, Khar. S.J. n. sutr.
Thiny years of meteorologic obser-vaticns over *ie Musala
MassX. Priroda BuIg 11 no. 6:104-1(Y7, 112 N-D 163.
1. Geografski i-t pri Bulgarskata akademiia na naukite.

TISHKOV) Kh. S.
Cortaln n~sw moirifirm bi npidIvIng 141P v. Y. ri
I I an
L. A. Chubukov complex method. Khidro i m(--teorolog 13
no. 1:31-37 164.

TISHKOV, L.B.Y inzil.
Selecting the rated instances of the rollin'r down of --,,t3 on
classification humps. 'lest. TSNTJ MPS 25 no.1:46-49 166.
(MIRA 19:2)

SADIKOV, P.P.- AIM'YEVA, S.A.; LE3EDEVA, T.F.; SMIRITOV, Ye.K.: FRIGOROVSKIY,
V.F.,inzh.,red.; TISHKOV, 1rt14Tj-,'XATOLICHXUO,' V.A.;,P"IN; A.V.;
HOSKOV, Yu.A.; TJJUFOHOVA,,M.G.j-KI3TMEHOV, Ye.I.; BOBROVA, Te.m;,
takhn.red.
[Technical equipment for large general-purpose freight yards]
Tekhnicheskoe oanashchenie krupnvkh gruzovykh stantaii obahchego
polizovaniia. Moskva, Gos.tranap.zhel-dor izd-vo. 1958- 186 p.
(Moscow. Mookovskii institut inzhenerov zheleznodorozhnogo
tranBporta. Trudy, no.161) (MIRA 12:2)
(Railroads-Yards-Equipnent and supplies)

SADIKOV, F.P.; LEMIEVA T P KORSH, V.B.; BELENOV, V.K.; PE,rRUNENKOV, A-)[&.;
!SHi601 A.K., inzh.~ retsensent; PREDE, V.yu., -1
"VE.1 red.; VOROTNIKOVAI L.F,, tekhn.red.
[Technological eqitipment of railroad stations] Tekhnicheskoe
oanashch4nie stantaii. Moskva, Transzheidorizdat, 1963.
153 P. (MIRA 16:6)
(Railroads-Stations)
(Railroads-Equipment and supplios)
b-,

TISHKOV, L.B., inzh.
Speed of uncoupled cars at te
on the classification tracks
MPS 22 no.5-12-17 163.
MiilroRds-Hump
points of "aiming" tmd
of automated hump yards.
yards) (Automnilon)
"spacing"
Vest.Tsliii
(MIRA 16:8)

LEBEDEVA, T.P.; STRAKOVSHY, I.I.1 TISHKOVP L.B.; LOMAKINA, N.N.;
ZABELLO, M.L.; SADIKOV, P.'1'.'d-'FrTMJNENKOV, A.Ye.; BELENOV, V.K.;
ARUTYUNOV, V.A., inzh., retnenzenL; PETROVA, V.L., inzh., red.;
BOBROVAP Ye.N., tekhn.red.
[Basic requirements related to the technical equipment of
classification yards] Osnovnye trebovanlia k tekhnicheskomu
osnashcheniiu sort-4rovochnyk-h stantsii. Moskva, Transzheldorizdat,
1963. 218 p. (Its TRUDY, no.270). (MIRA 17:3)

au ~.ofn.

KMOSOV,A. inzhanor; TISHKOV,P. inshener
Wider use of metallic supports. Hast. ugl. 4 no,1:15-16 Ja ''55.
(Mine timbering) OGRA 8:6)

KURROSOV,A., inzhener; TISHKOV,P., inzhener
SKR-11 conveyor intermediary tension roller. Mast.ugl.4 no.9:
14-15 S155. (KLRA9: 1)
(Conveying machinery)

KURNOSOV.A. inzhener; TISHKOV,P. inzhuner
An important condition for achieving the planned capacity of a
mine. Mast. ugl. 4 no.4:5-6 Ap '55. (MLRA 8 - 6)
(Zolotoye, Voroshilovgrad Province--Coal mines and mining)

TISHKOV.P.. inzhener
Footstep bearing for water discharge pipes installed in boreholes.
kast.ugl.4 no-7:18 J1'55- (MM 8:10)
(Mine drainage)

KHAVCMUFKO, V.I., kand.tekhn-nauk; TISHKOV, P.A., gornyy insho
Maintenance costs ard the distribution of lateral drifts. Ugol!
Ukro 4 no.12:33 D 160. (MIRA 13t12)
(Coal mines and mining--Costs)

TISHKOV. Petr AlekseYevich; XURNOSOV, Anatoliy Mikhaylovich; KIRIYFJffO,O.,
""~re ~or-,~E.M.. tekhnicheakiy redaktor
EuBe of new types of mine supports] Primenenie navy)di vidov krepi.
Kiev. Goo.izd-vo takhn. lit-ry USSR, 1955. 38 p. (MLRA 9:2)
(Mine timbering)
;4..

KURNOSOV, A.M.; TISHKOV, P.A.
'dater outbreak from sandstones occurring in the soil of coal
seams in the "Pervomaiskaia" mine. Ukol' 29 no.4:38-40 Ap 154.
(MLRA 7:2)
1. Institut gornogo dela Akademii nauk SSSR (for K-urnosov).
2. Treat Pervomayskugoll (for Tishkov).
(Voroshilovgrad--Coal mines and mining) (Coal mines and mining--
(Voroghilovgrad) (Wator, Underground)

AUTHOR TISHKOT P,Q. PA - 2992
TITLE _T99- ~Seoond Relaxation in a Spin System at Room Temperatures.
(Vtoraya relaksatsiya Y spin-systems pri komnataykh tomperaturakh,
Russian.)
PERIODICAL Zhurnal Eksperim. i Teoret. Fiziki 1957, Vol 32, Nr 3,
pp 620 - 621 (USSR).
Received: 6/1957 Reviewed: 6/1957
ABSTRACT The Investigation of paramagnetic aboorptio'n iz Cr(NO 3)3' 9H20
in parallel fields at 300 0 K by means of t'he method of the
lattice current led to the discovery of a phenomen on which is
unusual for room temperatures. The absorption curve X 11(H 11 )1
which is shown in a diagram for the frequency -r-- 160 mega-
cycles of the oscillating field, has a very ikarroto maximum. The
,right half width of the curve is of the order of 300 Orsted.
With increasing -T the maximum of absorption shifts towards the
direction of the greater field strength of the constant magnetic
field:
Y in magaayoles 46 93 131 16o
magnetic field strength (Orated) 250 290 330 360
in maximum
CARD l/ 3

PA - 2992
The Second Relaxation in a Spin System at Room Temperatures.
The intensity of the maximum absorption (in comparison to
the absorption at field strength H 0) decreases in the investiga-
ted interval of form 10 to 160 megacycles with increasing
frequency. At frequencies of the order of 600 megacycle@ the
shape of the curve of paramagnetic resonance differs only from
the ordinar ourve -X II(H 11 ), which is desoribed by the formula
X" a (I - F~2 ~.-v developed by SHAPOSHNIKOV.
The phenomenon discovered is apparently conneoted with a new
form of a spin-spin relaxation, which was discovered by GORTER
and DE VRIJER in chromium-potasmium quartzes at temperatures of
liquid hydrogen.
GORTER and his collaborators then discovered this relaxation also
in a number of other substances, but only, an was found in the
case of the first experiments, at very low temperatures. At room
temperature, as far as the author knows, this effect has up to
now not been observed.
CARD 2/3

PA - 2992
The Second Relaxation in a Spin System at Room Temperatures.
By means of the lattice current method the author is at present
carrying out analogou investiptions with other chromium salts
11 + ++
and also with the salts on MA , Cu and Fe++.
(No illustrations.)
ASSOCIATION: Physical-Technical Institute of the KAZAN' Branch of the Aaadeny
of Science of the USSR.
PRESENTED BY: -
SUMaTT&D: 11. 12. 1956.
AVAILABLE: Library of Congress.
CARD 3/3

24(3)
,WT110A: Tishkovi P. G. SOY,/56-36-5-1/76
TITLE: Measurement of the Spin-Lattice Relaxation Time
in Some Mn ++_ Salt Solutions (Izmereniye vremeni
spin-reshetochnoy relaksatsii v nekotorykh rastvorakh
soley Mn ++)
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki, 1959, Vol 36,
Nr 5, pp 1337-1341 (USSR)
.iBSTRACT; The author of the present paper gives a report on experimental
investigations he carried out of the spin-lattice relaxation
time ~L by means of measurements of the quality factor 0 of
the coil of a resonance vibration circuit. Determination was
carried out by measurement of the absorption coefficient X'
and using the formula AE - -41r^% X11EQ, where E denotes the
voltage generated on the resonance circuit. Determination
of relaxation time was carried out by means of the Q-meter
of the type KV-1. Two methods are, in principle, possible:
1) X"-measurement in the broad frequency range and
Card 1/4 construction of the X11(v)-curve; 2) All-measurement at 2

1' %ourecient of the Spirl-Lattice Relaxation Time LJOV/56-36-5-1/70'
in Some Yin Salt Solutions
frequencies and computation of ~,according to the
formula developed by Casimir and Du Pret ~" - ?(OF~, 0 +3'-)~
F - H 2/ (b/c + H2) i b/c is a constant characterizing the
internal magnetic field in the paramagnetics. Experiments
were carried out on b1n(NH 4)2(304)2 .6H20 at the frequencies
of 1; 1-5; 2 and 3 Megacycles, and on MnCl 214H2 0 at 3.5;
5.25; 7 and 10 Megacycles. In glycerin solutions of the
latter salt woric was carried out at 12, 21.5, 32 and 43
Megacycles at the molar concentrations of 3.9, 1.8, 0.9,
0.45 and 0.225 Mol/l. Results:
1200 1600 200 2400 2800 3200 3600 H [0~8
1.1 1.45 1.7 2.1 2.45 2.7 3.1 5L .10
1-4 1.7 1-95 2.3 2.7 2.9 3-15
1-4 1.65 1-85 2.15 2-5 2.75 3.05
Figure 1 shows the dependence of ~L- on field strength
Card 2/4 within the range of between 800 and 3200 oe at various

Leasurement of the Spin-Lattice Relaxation Time SOV/56-36-5-1/76
in Some Mn ++_ Salt Solutions
concentrations in form of a diagram. A family of nearly
monotonously rising curves is obtained, which are near
to one another especially within the range of low field
strengths, i. e. the concentration of the paramagnetic
salt exercises but little influence upon the spin-lattice
relaxation times. Results:
Curve Molar Concentration b/c
go p
6
1 3.9 2.5-10
0.68.10-
0-147
2 1.8 2.4-106 0.95-10-8 0-15
3 0.9 2.27.106 1-14-10-a 0-155
4 0.45 2.1.106 1.5-10-8 0.17
The following holds according to Drono - Van Vlooki
?. b/c + H2
Card 3/4 b/c + pH

,,easurement of the Spin-Lattice Relaxation Time SOV/56-36-5-1/76
in Some Mn ++_ Salt Solutions
Measuring results are in good agreement with this formula,
as well as the Casimir-du Pret theory, if the spin-spin
absorption is taken into account. The author finally thanks
D. M, Kozyrov for ouporviaing work and for hia help, and
he also thanks V. 1. Avvakumov for taking part in the
discussions. The applicability of the Q-meter for the
purpose of ouch investigations was first pointed out by
Yu. Ya. Shamonin. There are 1 figure, 1 table, arid 11
referencesq 8 of which are Soviet.
ASSOCIATIONt Fiziko-tekhnicheskiy institut Kazanskogo filiala Akademii
nauk (Physico-Techdical Institute of the Kazan' Branch of
the Academy of Sciences)
SUBMITTED: July 2, 1958
Card 4/4

N v
24.2110,24.2200,24-7900, 76969
16.8loo,5(4) sov/56-37-6-9/55
AUTHORS: Avvalcumov, V. I., Gariflyanov, N. S., Kazyrev, B. M.,
Tishkov., P. G.
TITLE,: Paramagnetic Resonance and Paramagnetic Relaxation in
Electi,olyte Solutions
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheskoy fiziki,
1959, Vol 37, Nr 6, PP 1564-1569 (usn)~
ABSTRACT: Measurements were made of the paramagnetic resonance
and paramagnetic relaxation in aqueous solutions of
MnO MnCl Cr(NO ) and Cu(NO )2. An analysis of the
3-t 2-1 3 3-9 3 2+y
experimental results showed that the complex Cu 6 has
a structure of bipyramid stretched in the direction of
one of the symmetry axes of the fourth order (cf.
V. I. Avvakumov, Zhur. eskp. i teoret. fiz., 37, 1017,
1959). This effect for the hexahydrate complex in liquid
solutions is dynamic in nature (cf. B. M. Kozyrev,
Card 1/4 Faraday Soc. Discussions, 19, 135, 1955). This means that

Paramagnetic Resonance and Paramagnetic 76969
Relaxation in Electrolyte Solutions SOV/56-'37-6-9/5_1
Card 2/4
in a given positlon ol' the ligand along the axes in
a rectangular system of coordinates, the bipyram4dal
complex can be stretched in the direction o~ any
three coordinates of the axes. All states in this
case are energetically identical. In order to pass
from one state into another, the system must overcome
a potential barrier, which for the hexahydrate complex
^_'1000 cm- 1. It was calculated that the transfer
proceeds at a frequency of lollsec-1. At the
same frequency the returning of the electron density
of the magnetic ion also takes place. This leads to
an averaging of the g-factor. The electric field of
the violet modification of the salt [Cr(H )~6]3+ has
- 20
in the main a cubic symmetry which, because of the ef-
fect of the particles of the second coordinational
medium, contains an admixture of the fields of lower
symmetry. The fluctuation of the fields caused by
these particles is sufficiently slow. The existence
of such fields was confirmed by comparing the observed

Paramagnetic Resonance and Paramagnetic 76969
Relaxation in Electrolyte Solutions sov/56-37-6-9/55
width of lines in solutions with the period of the
spin-lattice relaxation for 0.1 M solutions of
Cd+(Z~H = 200 G, P IP%a 10-8sec). These fields are
weaker than the axial fields in solid chromium alum,
because the total spectral width in powdered alum is
considerably wider than the width of a single line
observed in solutions. In the green modification of
Cr3+ salts, the paramagnetic resonance line is still
wider because the complex Er(H,0)4XI+ is less
symmetrical. The magnetic complexes of Mn 2+ in diluted
solutions have nearly a pure cubic symmetry, whereas
In nonaqueous MnCl solutions there were observed very
wide resonance lines at a given relaxation period.
This was explained by the presence of a strong axial
component of the crystal field, which is caused by the
presence of ionic molecules of the type X- - Mn - X-.
The experimental values P, for a given magnitude of H 0
Card 3/4 in the case of Mn(NO3)2 gradually increased upon dilution:

Paramagnetic Resonance and Paramagnetic 76969
Relaxation in Electrolyte Solutions sov/56-37-6-9/55
ASSOCIATION:
SUBMITTED:
approximately 50-60% with a change in the concent~rau-ion
by several moles up to 0.25 M. The anion had'a small
effect; on the magnitude of' this phenomenon. These
data accord with the theory of S. A. AlItshuler and
K. A. Valiev (cf. Zhur. eksp. i teoret. fiz., 35~, 974,
1958). The text contains a diagram of the setup;
4 graphs; and 111 references, 10 Soviet, 1 Dutch,
1 U.K., 2 U.S. The U.K. and U.S. references are:
(1) U. Opik, M~-. H. L. Pryce, Proc. Roy. Soc., A238,
425, 1957; (2) B. R. McGarvey. J. Phys. Chem., 61,
1232, 1957; (3) H. J. Mc Connell. J. Chem. Phys., 25,
709, 1956.
Phys.-Tech. Inst. of the Kazan Branch of Acad.
Sciences USSR (Fizilco-teklinicheskiy institut kazanskogo
filiala Akademii nauk SSSR)
July 6, 1959
Card 4/4

82009.
3/056 60/038/02/04/061
B006YB01 1
AUTHORS: Tishkk P. ~G. Vishnevskaya, G. P.
TITLE: Paramagnetic Relaxation in Manganese Salt Solutions
PERIODICAL: Zhurnal eksperimentallnoy i teoreticheekoy fiziki, 1960,
Vol- 38, No. 2, PP- 335 - 340 '
TEXT: The authors measured the paramagnetic absorption in parallel and
perpendicular fields in aqueous manganese salt solutions at concentra-
tions of 0.25 mole/liter and more. In the paper under review, they re-
port on the method applied and results obtained. Measurements were made
with a Q-meter described in a previous paper XRef. 1). It had already
been shown there that the spin - lattice relaxation time h and the
constant b/c in liquid,,electrolyte solutions can be determined with a
Q-meter by measuring at two frequenciesp in which case it is neces-
sary to effect a correction for spin - spin absorption according to
1. G. Shaposhnikov (Ref- 3). For this purpose, the absorption in zero
fields is measured and compared with that in perpendicular fieldal it
Card 1/4 tqr

s/o 6/60)0200~02/04/061
Paramagnetic Relaxation in Manganese Salt 5 36
Solutions B006/B011
is furthermore assumed that the spin - spin absorption in fields
1,500 oe be negligibly small. Measurements were made at frequen-
cies of 12, 219 32, and 42 Me/see. All frequency combinations were used
for the determination Of fL , except 32 with 42 Ma/sec, as these are
much too similar. The calculated mean values of % for MnSO 4
(I mole/liter, 220C) are given in Table I (in the dimension 10 see)
for 7 field strength values between 1,200 and MOO oe. The values are
between 1,18 + 0-14 and 1-93 � 0-05. The deviation of the values from
the mean valu7e is �6%. The values of b/c for MnSO4 solution
(3.2 moles/liter, 22 00) are given in Table 2: b/c lies on an average at
(2-48 + 0-18)010-69 the deviation of the values from the mean value
amountis tg , + 10%. This is illustrated by Fig. 1 which shows the
curves 1,'(H) in MnSo4 (3.2 moles/literg 300OK) at all of the four fre-
quencies. The experimental TL values of aqueous solutions of Mn(NO 3)29
mnso 49 and MnCl. are with 10-asee of the same order as with solid
Card 2/4

8
Paramagnetic iialwcati(,xA i:, S'alt 5/056/60Y0'T&2/04/o61
Solutions B0061BOll
substances. The function YL (H) is well reproduce& by the formula by
BronB-Van Vleok, as is shown in Fig. 2 by a comparison between experi-
mental and theoretical curves for manganese nitrate, -sulfate, and
-ohloride solution (2 moles/liter). Fig- 3 illustrates the dependence
Of % on the type of anion and the concentration N, of Un ++ ions in
aqueous solutions of these salts. YL 'a found to grow with increasing
dilution, especially in manganese chloride solutions. Lt low conoentra-
tions the difference of the ?L values of the three solutions decreases.
The rules observed are explained by the theory formulated by
S. A. A12tshuler and K. A.. Valiyev (Ref. 7), in the same way as the
temperature dependence of fLP which was experimentally investigated in
manganese nitrate solution (2 moles/liter) at -2, +22, and +580C. More-
over, the dependence of the internal field constants b/o on the type of
anion and on H was also investigated. It was found (Fig. 4) that b/c
rises practically linearly with N9 the fastest in the case of chloride,
the slowest with nitrate. Fig- 4 illustrateag for VnCl 29 the concentra-
Card 3/4

8 0
Paramagnetic Relaxation in Manganese Salt 8/05 60 0 /02/04/061
solutions Boo6yw i
tion dependence of and ~, (spin-spin relaxation time). The
paramagnetic resonance absorption line width A H and the relaxation
times and are linked by the relation 6H -_illfs + 1/e . it fol-
L 3 )L
Iowa from the results obtained that the investigation Of YL in electro-
lyte solutions permits the determination of the BtrUOture of such solu-
tions. The authors finally thank B. M. Kozyrev for guidance and as-
sistance giveng as well as B. K. Silant9yeva for having taken part in
the experiments. A. I. Riftind is mentioned. There are 5 figures,
2 tables, and 12 references: 9 Sovietq I Americang 1 German, and
I French.
ASSOCIATION.
Fiziko-tekhnicheakiy institut Kazanskogo filiala kkademii
nauk SSSR (Institute of Physics and Technology of the
Kazang Branch of the Academy of Scienceaq USSR)
SUBMITTEX.- July 6. 1959
Card 4/4

TISHKOV, P, G. CAND PHYS-MATH SC,j "PARAMAGNETIC RE-
LAXATION IN LIQUID SOLUTIONS OF SALTS OF-!* IRON GROUP
ELEMENTS." [KAZAtill, 1961. kMIN OF HiGHER AND SEC SPEC
ED RSFSR. KAZAN' ORDER OF LABOR RED BANNER STATE UNIV
IMENI V. 1. ULIYAt4ov-LENIN). (KL-DVj 11-61, 209).
-23-
top=
g_r -., , z - -
4 KEN
N
1919 Mem; MON

VISHNEVSKM, G.F.i TISHKOVv P.G.
Paramagnetic relaxation in vanadyl sulfate and its solutions.
Dokl. AN SSSR 142 no.4-2841-843 F 262. (MMA 1582)
i. F#iko-tekhnicheskiy institut Kaza6kogo fi-liala. MI SSSR.
Predstawleno akademikom B.A.Arbuzovym.
_(Vanadimm sulfate-Magneti,-; properties)

_~ ~2665-66 LW(m)/EWP(J)/T RM
ACC NR&AFW150" (A) SOWN COM U1V61WW0"VT8V0789
AUTHORi Prokoplyw. V. P.; Tiabkov, P.G.1 M-ni~Etp A. I ; 10ardise A. F.
ORGI VoindErad Folitechnic Imthute 081909radskiY poUtekhnicheiddy
instituti-
TITLZs Investigatiou of methylmethacrylate In the presence of heleni~ro---
pe dealby the r-An-echo mthod
SOURCE: VysckomDlsku1yarnyye voyodinenlyaj, v. S. no. 5. 1966,, 787-789
TOPIC TAGSt metkWlmethaer7latep polymerization, percxId*# gel, proton interactionp
spin relaxation Rdm-w;bm==~6bad
ABSTRACTs Investigation of nothylwthaorylate poljmarization in the presence of
,4-phlororand-4-bromo-4),4-dinitrob~4tyi-pI peroxides was carried out at 50C and a
peroxide concentration of 3.7z10-2 mol/l. Halonitroperoxiden inl$tiata the
polymerizatiomi?of mGt!qlmth&cqrl&t4jw1thout a noticeable gel effect. The nature
of proton spin-laf-tice relaxation during polymrization with and without air was
shown. Orig. art. bast 2 figures. [Based on authors' abstract] CNT]
SUB CODEt 07) 13/ SUBM DATE: 25Feb6V ORIG HEY3 0021 OTH RErt 007
Card
UDCt 66.095.26 + 678;7"

VISHNEVSKAYA, G.P.; KOZYREV, B.M.; TISHKOV,"_~-,G-
Paramagnetic relaxation in concentrated aqueous solutions of
(VO)2~. Dokl. AN SSSR 152 no.3:6"-646 S 163. (MIRA 16:12)
1. Fiziko-tekhnicheskiy institut Kazanskogo filiala AN SSSR i
Kazanskiy khimiko-tekbnologicheskiy institut. Predstavleno akademikom
B.A.Arbuzovym.

VISHNEVSKAYA, G.P.; TISHKOV, P.G.
Paramagnetic relaxation in vanadyl salt solutions. Dokl. Ail' SSSR
154 no.5:1149-1152 F164. (MIRA 17:2)
1. Fiziko-tekhnicheskiy institut Kazanskogo filiala AN SSSR i
Kazanskiy khimiko-tekhnologicheskiy Institut. Predstavleno
akademikom A.Ye. Arbuzovym.

ACCESSION XR: Ap4o16513 S/0020/64/154/005/1149/1152
allTHORS: Vishnevskaya, G.P.; Tishlacov,_P..G.
TITLB: Paramagnetic relaxation in vanadyl salt solutions
SOURCE:'AN SSSR. Doklady*, v. 154, no. 5, 1964, 1149-1152
TOPIC TAGS: relaxation parameter, spin lattice relaxation, spin spin
rn-laxation, vanadyl, vanadyl solution, acid medium, vanadium complex
glycerin, Ion concentration, aqueous solution, vanadyl sulphate,
solid sulfate, electron relaxation, exsiccator
ABSTRLCT: This investigation deals with the determination of the
spin-lattice and spin-spin relaxation time of vanadyl acqueous solu-.,
tions with various acid contents and glycerin additions. V001
soluti~ons with'concentrations of 3 and 4 mole/liter were seleNed
for measuring purposes, and measurements were also made in aqueous
and glycerin solution of vanadyl sulfate (VOS04- 3H2 0) with a con-
centration of about 1.5 mole/liter. Solutions with a maximum gly-
cerin content were measured in a temperature range of 295 to 368K.
It was found that the spin-latill-ice relaxation in aqueous-glycerin
Card ~1/3

ACCESSION NR: AP4016513
solutions undergoes a greater change than in aqueous solutions alonei
0
It is assumed that the rapid change of the spin-lattice relaxation
,in aqueous-glycerin solutions vrith temperature is due to the fact
that glycerin viscosity changes rapidly with temperature in relation
.to water viscosity. A careful Investigation has been made of solid
vanadyl sulfate as well as VOC12*5H20 powder. The solid vanadyl
chloride was.prepared by drying a 6.5 mole/liter aqueous solution
.in an exsiccator with sulfuric acid. The temperature measurements
..made in VOS04-3H 0 powder revealed that the spin-lattice relaxation
time within the temperature range of 293 to 268K is not affected by
the temperature, but there is a definite relationship with the
temperature in a solution with the highest possible concentration
("3 mole/liter). "In conclusion, we take the opportunity to express
our sincere gratitudd,- to B.M. Kozyrev.for his supervision and con-
tinuous assistance in the project.' Orig, art. has: 1 figure and 1
table.
Cord 2/3

ACCFZSION NR: AP4016513
ASSOCIATION: Fiziko-tekhnicheskiy institut Kazanskogo filiala, Akademii pauk SSSR.
(Physicotachrdeal InBtitute of the Kazan Branch, Academy of Sciences# SSSR)j
Kazanskiy khimiko-tekhnologiches4~,institut (Kazan Chemicaltechnical
Institute)
SU&%aTTMt '08oct63 DATE ACQ: Mar64 ENCLt 00
SUB CODE CH NO REF SOV: 009 OTIERs 003
Card 3/3

- TImmQT'_2argQ_v Ivanovich ETSishkou, S.1; RABINOVICH, A., red.:
TA CHjTSTG. rK-alechyta, H.3, tekhn.red.
[Growing corn in White Russia] Tyroshchvenne kukuruzy u BSSR.
Minsk, Dziarzh.vyd-va BSSR. Red.sellskshaspaderchai lit-ry.
1959. 101 p. (MIRA 14:4)
1. Chlen-korrespondent Almdemii sellskokhozyaystvennykh nai*
BWR.
(White Russia--Corn (Maize))

TISHKOv.,.-VJL.p--- in zh.
'What experience teaches. Vest. elektroprom. 34 no.31:56 Mr 151~3*
(YMA 16:8)
1. Glavnyy energetik tresta "Vorkutdorstroy."
(Electric motors)

FTETRAKOVSKIY, A.P., inzh.; TISHKOV Yu.Y-a inzh.; TISHCHIETKO, C.I., -'nzl,.;
_'? I
SOLODOVITIK6V, V.V.,_ir`n~~.
Use of compressed air in intensifying open-hearth smelting with furnace
oporation by the ,virup proomijR. St.n'll 23 no.12:1,070-1082 D 163.
(MIRA 17:2)
1. Matoustovskiy mpt-dlurgicheskiy zavod.

TISHCHENKO., 0.1.; OMIMOVICH, B.P.;,TISHKQV,.Yu.Ya.; K7JLAKOV,, I.I.;
KHRUSTAMOV, L.A.; VASILEVSKIY, P.A.; PASYUK, K.I.
New method of buil4ing arc furnace hearths. Metallurg 8
no.2:15-17 F 163. (MIRA 16:2)
1. Zlatoui3tovskiy metallurgicheskiy zavod i Chelyabinskiy
Institut ogneuporov.
(Electric furnaces-Design and construction)

LEVENETS., N.P.; Sj"IN, A.M.; SEMIKIN, I.D.; KAZAKOV, V.E.; BEMBINEK, Ye.l.;
PANYUKHNO, L.G.; SVIXOLOBOV, N.P.; AVERIN, S.I.; SMIRNOV, V.M.;
ZELENSM., V.D.; LAYKO, B.G.; TISHGHENKO, 0.1.; OKHRIMOVICH, B.P.;
DANILOV, A.M.; TISHKOV, Yu.Ya.; PAtIOV, M.A.; MARKELOV, A.I.;
PETROV, A.K.; VASILkVSKIY, .... :~.A-.; PASYUK, K.I.; NESTEROV, V.I.;
KHRUSTALIKOV, L.A.; GLAZKOV, V.S.; MAKAGON, V.G.; FOMIN, G.G.;
7RISHCHEYK0. V.D.,- KORZH, V.P.; SUYAROV, D.I.; ARSEYEV, A.V.;
P
PAVLYUCHENKOJ, A.A.; ZHADAYEV, V.G.-, KONDORSKIY, R.I.; MOROZOVA,
I.A.; KOCHETOVp V.V.; PRUZIIINER,-V.L.; MALEVICH9 I.Aq
MALIOVANOV, D.I.; ZAKOVRYASHIN, I.I.; NOVSKIY, I.S.; NOVIKOVA,
V.P.; GRISHIN, K.N.; MOSKOVSKAYA, M.L.; KORf4EYEV, B.M.
Inventions. Met. i gornorud. prom. no.3:75-76 My-Je 164.
(MIRA 171l0)
I

"0
OT
VVIO 0.
V's e
1:0
Ile ;I C
0l, 86
r O.L
LJO tot. -,0).
f&N15 '. %)o I 6-a-rc- '106 05-
Fj _0.66 1 "v a. -r 0-?
-n" 0-1&3 - -~T~ r-
V j-'I"OL -0. . -'I.~e
0
to 01. ; ,
,e tNje
C' 'Y'L
:ce J'%13-
0
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%) I* ~ e~' ' '~ ~ cv, Ir I S. t 0 tll
as 'pl: e lo.'Jc f'6' Vo ~' ~.v'
o To'~' , t1'. e& ted. 6.-V'J)
C6 O'P- t"16-1 C 5 'f~
A of, ~OT~ * G io\)
o ti
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es' tee' 'Oo ty,
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.,SC
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0 j. a
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t e 3-al -as .Clot 5
. r,.r, e -ic , '~"o t
e
-FoT

New method for hearths ...
s /1 2 /` r 2 ' r.4
;V IGO
B105j -.1
4. C,
mol tc or ~ the --rialls and vaults. To increase the of hearths
of s- 1. furnaces especially wh(!n meltin;~ ldja-qualit~ steels, the former
U U
are :Iuced by rumming dry nagnesite powder with a content of
Wil !~LJ. The -reatest. density of "he -uorkin,- layer of l.earths in obtained
U
bl, uc-'a,- ma-nesitc. powders ,--4'h a 65-75P content of 'he -1-0.1 min fraction,
j . 'I u
1 111. ir.-ludin, 25-15';j 'he
3c)-25 of a fraction < 0.1 < 0.06 -n . To improve 1,
hearth density without a consiaerable reduction in refractorine3s, up to
clrl' of titanomagnetite concentrate is added. Ramming and repairinL; hearths
.-*th dry maSnesite powder increases their durability considerably and
reduces the tirie of waitin- and the consumption of ma;nesite powder and
fuels. To promote the application of the new technique, the production of
ma-nasite powder of the required 6~rain composition will have to be applied,
in the 1111.1an-nezit" plant. There are 3 tables and 3 Soviet references.
U
ASSOCIATION: Zlatoustovskiy metallurgicheakiy zavod (Zlatoust Foundry)
(O"hVinioviall, 1j. P., Tialikov, Yu. Ya.)l Inatitut
o.a;ieuporov v. E. Satke (Institute of Refractories' in Sat~a)
(Vasilevskiy, P. A., Pasyuk, K. I.)
Card 2/2

TSAREGORODTSEV, P.P.; IZOTOV~ N.P.; TISHKOv,
yu.ya.
-
Reduction of idle periods in Q'm;lr,~i~~ce of hearths. Metallurg
9 no.11:15 N 164. (MIRA 18:2)

-TISHX0V,'Tu.Ya.,- KRESTIYAMOV,, V.F.; VASILEVSKIYs, P.A.
Pi=ed kmarth of a 190-ton furnace. l4etallurg 8 n0-52-13-15
My, 163- (MIRA 16-.7)
(Open-hearth furnaces-Maintenance and repair)

0.4164 so 0 o a 4 4 0 41 0 0 0 0
11 It 1) 4. 11 14 IP 18 1, toIn0 M M 14 17 111 ?1 N 11 UMbly nova, 1, 41.: a V. 41
R A I
0 A CA DSTMINATION' Or THE SFZCJ7IG GRAVITY 07 OILS BY THE AMOD OF 22
4 A ISUSPEDED MOPI. P.3. Panyutin and B.N. Tishkova. Neftyano* Mxos. -*o
1936, so. s, 55-6.- Ale.- B20 pobu. of various-Un-dtfs-'s-a"re prapd., and -00
o: a drop of oil under onvestigation Is placed on each of the ale. solne. until 1*0
the drop of oil stays on the surface of one and sinks slightly on the other
so1z6 Then to the light#r soln. to much of the heavier ale. soln. is added
that the drop of oil remains on suspension. The expts. are carried out at
00 200, The op. gr. of the final ale. solne. and therefore of the oil is detL x6*
0 J: from ic--(&b+cd. 100)/(ac+cg), where a is the amt. of the first mixt. used on =00
the fitration. b the amt of the second, Is the sp. gr. of the first and g that. 400
a a of the second mixt. A conversion homogram is given. A.A. Boebtlingk
coo
.60
0 0 -4r coo
00 R
06
go V
~
401 age*
~~. I
SIC X00
T
use
A$4.SLA MITALL(ORWAL MUNATURt CLAS11FICATION
41kili'4W C~v Isk
a AV bo is' ; a " * I
't 7 AA
It K I IM
*10 0
*;T44
-814

ILIINA, N.V.; SOKHATSKAYA, G.A.; SJIADRINA, M.N.; TISHKOVA, K.S.
Durabilit7 of lining of rotary kilns in 1962. Tsemailt 29
no.5g9-11 S-0 163, (MIRA 16tll)
1. Gosudarst7ennyy voesoyuznyy institut po proyaktirovaniyu
i nauchnc-iseledovatel'skim rabotam tsementnoy promyshlen-
nosti i Vsesoyuzrqy gosudarstvennyy nauchno-iseledovatell-
skiy institut tsementnoy proiayshlennosti.

ILIINAI N.V.; SOKHATSKAYA, G.A.; SHADRINA, MN.~-~KO~VA, K.S...
Analysis of the stabilit7 of linings of rotary kilu.- TSement 28 no.6:
16-17 1~-D 16Z
1. Gosudarstvennyy institut po ptoyektirovaniyu predpr~yatiy i
nauchno-isaledovateltakim rabotam. tsementnoy promyahle=6 .sti'
i Gosudarstvennyy vaesoyuznyy nauchno-issledovatellskiy institut
tsementnoy prom~shlennosti.
(Kilns, Rotary) (Refractory materials)

-TISHKOVA I.,,D -..
Effsot of pentox7l on the heallng of penetrating l4near wounds
of the cornea; an experimental study, Shor. nauch. trud,, SCGMI
no.14glO8-113 163. (MIRA 18:9)
1. lz kafedry glaznykb bolezney (IspoInyay-ushchiy obyazannosti
zavedu~-ushchego - dotient D.I. Zatsepin) A iz kafedry gistologii
I embriologil (zav.- dotsent med. nauk A A, Kolosova) Rostovskogo
meditsinskogo instibita.

TISHKOVA, L.D., ordinator.
among agricultural machinery operatorii in the Rostov
Province. Oft. zhur. 13 no.6:348-351 '58. (MIRA 12:1)
1. Iz glaznoy klinlki imeni K. Kh. OrlovEL (zav. - zasluzhennyy dayatell
nauld prof. P.F. Arkhangellskiy) Rostovskogo meditainskogo instituta.
(]CYR--WOMTW AND NJIMIM)
(ROSTOV PRO711103-AGRICULTURAL LKBORERS-DISMSES AND HYGIM)

0000 0 0 * a 0 * *1=110 0- 1- IF-v--w W~ ____ -
0 0 0 0 0 0 0 0 0 of 0 a 0 0 0 0 1 0 a 0 0 0 0 0 * 0 0 0 0
a MA16VAJI1111V u 14 4 111 v It x a 1; 41 a .1:0
L 10 1 AA " CC PC U
00 -90
00
00 Determination of ash in lubmicating oils P
00 Tt,lik-.t. Nell-wx' A h.,; 1916. N.
Ihi IV re, 44 the mt I, It-It 'ItAtrtf, ("..,I b-,
00 ,,~h. mfltli%l.~ And put m .; IWAINJ It'll, It/ 11".1, 1 h,
00 04A 6 Ilwo vtvigbol .611; Ibu mt .11.1 I'mil'i [,,,1 .111, '. -
loam "Jildrel-t Inm"I"I "all .11 4,141itill AO " A 'Alld
1111141111,A tile 'yPtrall i, oqmc,tvil I., A %A, %Still% Imittli I I,,- I'm 00
00 a 1-041K ffAlli-I 11 -11110 -t I ', *, - mAd -.11 'li
'Illwildillittill LIM, klliklo(olti of tit, .1i'llikic
tit III,. atialitm. Hit io, n,t it, t... 0
00 ti.t~ I I Ow 14A 1, it r littivi 1441111. 4 ff~ I h v fit flig. g
It,, f-Wilt. k 11411,1VII'VI U, 's 1.4'.Iaill JtAl
00 13 *'.', 4".). wlrd allil *.isIltd Ailli III,- ds-h I )it

0 11 111,11 11411illUt.1 ill, tilt' 11111A1 MAltill" .11111 tilt 0 0
..ell J -ti I, , .1-1, I-m j,h - I ,,, .,I I I IN k. . 11,
0 Ow at. of flic 401 fit K 111.1 ,( tit.. -f It,. ae 0
00 '411,14 Allil d 111.411 -( Ov 'r-I I.. flu
I_*I lilt, in thc 114.1, I,dI-A%vd fit .11. ""d
00 2i
IIAIj1ICtffII t1i fill- Jkli.t-Ijill 111,11 1111-t).41k J-.1,11141 14#111
00 5~.(. PM14"11. tit L.11.1, lilt- willms, A lilt- '11,1) 0
Out evapil'. igni4d. writclud 'ill.1 tit, Ix 1, vilt.,xv ,f A'll
00 il IIIt(I. A-11 b 11 th, .1 lilt
f* --pi- A A 400
00

00
00 a I I L t;A1LLt,rGKAL Lflt$kludt CLAWFICAM-

00 k" 'I.. .
ANt
In L I a 0 4
F r? it m It it (I a of ft a It OF WIj n 14 a 3
0

0
4 I
0 a 0 0 0 0 0 (a 0 0 0 0 0 0 0
0 0 0 0 0

0 0 * 0 0 0 0 0 0 0 0 111, 0 0 0 0 0 0 0 9 0 0 0 0 0 0 0

0

9 0 0 0 0

91 0. "PlOO 1-11" ~x
'A A 9 j a L
-A---t. C, A~-
if lot, A~v
0 11116COM AMO 010PIN119$ MC41
4W. DEMM1NATION OF THE LOW TWERATURE VISCOSITY UF
LUBRICANS FOR W&GUN AXLES. Blidehanko, If, and Tishkovs, -' VN
(bymp. Vi 0. Li uids and Colloids, toad. Sai. U S.S.R. 19"11"
1 2v 167-1721 j- Inst. Petro!. 1945, 311 327A) ~arlousylubricating
mixtures, either wholly distillates or else distillataAesidue
bland#, and all having a viscosity of 2'- 0.2 E., at ~O
were examin9d with respect to their v scosities at 50 Uv as
i!i the low viscosity components there wer* used gas oils.-With
0 z 3!i
:0 1H visooties of 1.24-1.4"Z. at 50 %,. Viscoties vw* measured in
a noWAM Ubbelobdo-Holde tuvej all oils were Frob"ted at
5Q*(;. for 10 &in. Results t 50 (i. for viscosities in the
00 Ij a
A.g~.!! range 800-8000 poiBes show a repeatability of about 2A. CTudes
from various fields were used.to provide the components. It
is concluded that the *oat favourable viscisity teapersture
relatiooshi~ is given by a blend of a.light Bibi Sibat gas
oil with a low viscosity (10"I. at 50 ".) residual fuel.
I
9( to ')twh blends, and those incorporating bitumens, hove viscosities
-50 Go of 900-16000 poison# as a-mpared to values of 2400
a it
-00
800
=00
coo
=09
r0 0
9
0
ZOO
Noe
ASA.SLA 17TALLURGICAL LITERATUOt CLASWICAT1011 94.1714-r.'=-."
Isom. 40.111~
woso -A .1. Q.V oat 611111 am QMV
U S Al jr3 Ls a 1 41 V I 1A MI L 1 9 FW i it I I Iff IN a 0-1 1-1 -.2
I xM
19
Wee
0 0 0 0 0 0 0
00. :10 0 o o 0 00 0 100 0,00 00 : V: : V: Isa-09- AOL 0 0 0 0 0 0 0 0 0 0 0 0 0 0

000000 *0009604600060*00 Gooto
0
00
00 poises, as compared to values of 24M poises for the 1u bricants
010 in current use. The satisfactory performance of sugh lubricants
of was verified in a friction s4obi operating at -50 G. and by
00 actual trials In winter (-53 C.) conditions.
00
00
00,
:00
0
000**00000000000000000000oooooooooooe
"00-010-40, 0 0 0 0 0 Is 0 0 0 0 0 0 0 0 * * 0 * o 0 0 o o 0 0 0 * 0 o o * 0 0 *
L
00
00
00
so
0:
0
00
00
00
60
0
:0,
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:0
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000

1
1
p
li
L 1"4 ;j 11 Al ;I n D14 6 N77 A h 1, 2, V is it It M 11 a mA. to
1
.
i
1
L 14 1 L AA KV~ 'IV It -I if I.jI A a '-f

LI
4 eterminationoflow-teimperstureiticosityofgtiii-egror-
1 irdaway-carades. I.F.Illid,henkolaridV.S.Ti kwa -00
jrk4d, Nauk SS.S.R.. Otdfl. Tkh. VW. "it -

Itatkimovoliod,w, SwrfAckaovic I'ysrk,uts 1hsdk,jj14,I I 1111 0
malrowin, (Cmif Imp Vicoity 14 H11,1141. And 04 - -411111111
00
06 I
l
1
II

00 lor
1111111 1.1. -111,
041 ;IINNI, 3111111 MKII
N, 0.
I
."V 110-IA0,301) -11011, IM-Nmilitill .1. ~I- , 11'.
-09
.1 lite al,illury'Ll.3, 4 mm.. orv.p~ Alh,if, %l,i, In, vi.m0%
It. 41"1 W 'At' I.,I lip 11011 1.1 wq 1., 1-111.01 1.11 Ollhl.w
4fid -I'll Aml .-f 14t .11"I whi

0 IIIA.le
hichi -)Iar di,fillatm tof l(4L%s 1,tialfin-fi..
1
1
I,w the vvwms "xt,"moeist m-,nlt .4 1---- 111.
-
urr lit-cfer"41. Sklell 1101:14. %li(#W al -- Ircifil ,%17 144 zte o
111W IxAws sold Irmic at almmit A lit, mutalmlitv 4
fliew lubork-wilb was rtwifirrowd in xpi- #,I a lrivii-.
mAchim- avul lit worvict- nit Siburiatt tailroud, N. I lum CID 0

-.00
0
U110111-1 L11I-tk.IoC-

S -1~ 13- -U It'
t~ w
op -1 3 -1 It w 0 4 a I v N
It (rip M69 Nit MCK
to
0
~ 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 40 0 o ;l 0 0 a 0 o lop 0 0 0 0 a 0 0 9 a
1 0 % 0 ej
00 000 Wo
to 0 0 0 * 0 0 0 0 0 0 0 so
0 0 Wo * pip 0o 0 0 0 a o 0 0 pill o0 o 0 o 0i

ILIINAJI N.V., kand.takhn.nauk; SOKHATSKAYAY G.A., kand.takhn.nauk; SHADRIINAY
M.N., inzh.; TISHKO' . K S., inzh,
I ~~A
, _~t
Durability of brick linings -in rotary kilns. TSement 30 no.6--9-11
I
N-D '64, kMIRA 18d)

19591
IX0~ teA ~355'~"
0 oi~
I&OS
'S Ot
e-~'e'406OTOV'4 'Vly~e-re
ov~ j oj'~'s 9 Sotse is *0's
0 0 I-Ij
ty'z-
ro' '1-~ A-
'00
yere S.
0
,.dgs, Ar
-f eO, gr T~
V WjW _ &~ _~N S
01 "' ,- , -txe oy~ '~"O"
Ot q 2 r, A ( 'ja
)6 t to
of~ v~l O'cv,
te-ck- t 07C 0COT d'js~is Ot
9.0t OF X~e-re or
-te"C 1k
e~~ -Ce a. Tyco& e& 0.0 erev 31 'Ir ~Nvss 51(16
6-
r5r'~ 0e te~0'9 -re 21
7a~e 010L Ot
eve & '08,
'Ve 252 ~.Oft t ~:a 'Dote Ot
'1aA-e I Ar I t
~:Vss ~Nvs) ~~e to'coo. _-1t1j0 -tile t'.U00
r
00 t,:,.e q ',,,te OICV 40SOV
A. jr 5,toofv Oft
elld'5 Ot "s
dLeV 01 66eaL, V106
% 50Aej
je la 5 's
0 Solo, ,TO
,,,Ojee- je je ot t-)'OLI
0., 'Mo
To V%O Tea-0
J) .0
ier
toe
The Synthesis S0VM?-59-7-233Jf3
Ma CO 3# th Of 'Ome Derivatives Of AkYlated Phenols
C ' 0 solvent is di
06, Yield 97%. stilled
SL;l off in the vacuum,
2, and 11 a is
43 g I In an analogous way from 41.2 g Ib :in 62 ml C H
gradually 13 1 b is obtained. T extracted by
above 36 g Ii 5 g s - 30 g of I a 11, 150 ml
2CI 18 added and by a method analogous6 and 10
I a is s2
and 0.1 Mole s C, eparated. C 146 atl~g - 450C 3 g
2~, 2 111 b ,In the 8=e WV from 0 2 describod
99% by intera,' 97% to thnt
on . Mole Ib 1r, 62 ml C H
22 Of obtained. TV a Is obtained with a Yield
,5 g I a In 112 0.15 Mole I a in 112 ml C
mass) was obtaine .5 ml C6H6 and 13.5 g s C, H With 0.1 Mole SCI 6
V b. d. 30.9 1 b In 47 m12 2 29.9 - From
From 37 5 g I a in Ig 2
50 ml C C H g V a (solid tr
ansParent
A and W9 and 13.5 g s
_C4HAHA2_4-C4~9902011 (VI a) was 2C12 Produce, 36 g
9 SCI 42 9 2 6 (3-AIS-2-OH-5-
'morphous Powder is obtained 2
obtained- when VI a I'
ml CeIL' 0 * I Mole sCl - To 0.15 "JOle n' s rubbed an
he su was a( -HOC H C(
YfIte of V.1 Ided and after Process.ing
IS) 6 If
Arl 2 - OH 1 2,9 -(Ar C
- 5 - c (C6H5) 4 ON)e(CrR ) 2 (V") In 50
freezing fru Zetion Mi ture
C6H31 IC6~t)(T3VC6H20H was SeParrIted [where
to a hard mass at %JR n t e
F2 form Of a very VISCOU, x
l1quId
Card 2/2
M

ISAGULYAWS, V.-J.-; TJ.S11KUVA, V.N.; FAVORSKATA, N.A.; OGANNSYAN, R.O.
Substituted hindered Dhenols and their use as antioxidants for
petroleum product3. Trudy MNI no.2):42-61 '58. (MIRA 12:1)
(Phonols) (Alkylation) (Petroleum products-Additivies)

ISAGUL-MYES, V.I.; TISHKOVA. V.11.; PAPOK, K-K-; ZMVA, B.S.
Research in the field of the synthaBis of additivea for
petrolewa products. Report No.l: Synthesis of phenolates of
sulfides and disulfides of substituted Dhenols. Trudy KNI
no.23:31-41 '58. Wa 12: 1)
(Phonoxi(lea) (Petroleum products-Additives)

ISAGULYMITS, V.I.;,TISITKOVA, V.N.; PAPOK, K-K-: ZUSNVA, B.S.
S)rnthesis o-f phenolates of sulfides and dilsolfides of substituted
phanols. Izv.vys.ucheb.zav.; neft' i gaz I no.11:97-103 158.
(MIRk 12:5)
1. Mookovskly institut neftelchimicheakoy I gazovoy promyshlennosti
im. alcad. I.M.Gubkina.
(Phenoxides)

SOV/81-59-16-58532
Translation frorn: Referativn,,pj zhurnal. nilmlya, 1.959, Nr 16, p ItIl (0'13k)
AMORS: Isagulyants, V.I., Tishkova, ~r,N., Papok, Zuzeva, V.0.
TITLE: Investigation in the Field of -the Synthe5is of AdmIxt-ures -t.o Petroleum
Products. Communication T, The 3ynflie.-A3 of Menolatos of 'Julfides iind
Disulfides of Sijbst.ltuf,ed Phenols
PERIODICAL: Tr, Vses. n.-i. po perc-rabo~lke nofkl I gaza 1. pDluchenlpu lslvisstv.
zhidk. topliva, 1958, Nr 7~ PP 378-389
ABSTRACT: With the aim of s';udy1ng fhe !Fynthesis of pheriolates of sulfides and di-
sulfides of var1ID,,).,3 phenols, and the offec'.. of 1.he compot1tion
and the stmictlAre on th~~Ar- properties as admlxt.uves tr~ Qlt~
aut.hors ayn~hesi.zed and lnveotlgated severaL a*1ky.Lj)hen-j1af..es confainlr4r
varimis (ju_-LntitJes of S) in f;~ie Tnolecule, various alkyl radicals and var-
ious metals. It has teeri found that, the solubili-ry of wie phenolates de-
pends on the iLarure of '.he radical ard in-.reases with an in-
crease in tht~ 1,,,.niz~,h of Hjz~ ~lde chain in the r1rig. Phenolaues
Card 1/2 with a long chain of C11 c.-,r r.-cwo,aLnIn~, :in aralk-y, ridi-i-I do noL di:jziolve

SOV/81-59-16-58532
Investigation In the Field of the Synthesis of Admixtures to Petroleum Products. Com-
munication I. The Synthesis of Phenolates of Sulfides and Disulfides of Substit7ited
Phenols
in mineral oil. The most efficient admixtures are phenolates of alkali or aLkal.1 earth
metals. An increase in the amount of S up to 13 - 15% improves the antioxidation pro--
perties of the phenolates. Me most active admixtures are phenolates containing a
tertiary alkyl radical with 8 - 10 carbon atoms. The initial substituted phenolates
for the preparation of efficient admixtures should be substituted phenols obtained in
the alkylation of phenol by Isooleflnes, but not by chlorinated paraffln.
S. Rozenfelld.
Card 2/2

All
IAV'Iiil.,It: fx,lfilnF4 rIlliTF.IA AIKIIj
AP.11.0.10-1 "MIX III-IlrA;j R 4j,jjj:p%.jjjfljw
UArAAM it RIYT,,riiuo"
IL IL N...
Tlxl
a-ti 11" CbMI so
1. OU7
vo F-im.
"Doom
au.tv..U at rgpwu osbw"

ISAGULIANTS, V.I. (Leningrad); TISHKOVA, V.N
,(Leningrad); FAVORSKAIA, N.A.
(Leningrad); OGMSIAN, A-.O. (to-ningrad) -
Substituted shaded phenols and their use as antioxidant additives
of mineral oil products. Tr. from the Tuscian. Kam.tud.kozl.MTA 12
no.4s.-363-381 159. (UAI 9:4)
1. Leningradi Tudomanyogyetem.
(Phenols) (Kineral oils)

jj650
3/081/61/000/020/085/089
r? 6, 3 B110/B147
AUTHORS: Isagulyants, V. I., Tishkova, V. N., FavorBkaya, N. A.
TITLE: Synthesis of mineral-oil and motor-fuel additives on the
basis of substituted phenols
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 20, 1961, 410-411,
abstract 20M160 ([Tr.] Groznensk. neft. in-t, ab. 23,
ig6o, 132-136)
TEXT: Schemes for the synthesis of multifunctional additives of the
following types are given: metallic salts of sulfides and disulfides of
alkyl phenols; metallic salts of diether dithiophosphoric acids, whose
ether groups were obtained from disulfides of alkyl phenols; dialkyl
amino salts of diether dithiophosphoric acids, whose ether groups were
obtained from disulfides of alkyl phenols; Ca and Ba phenolates obtained
by chloromethylation of the condensation products of alkyl phenols with X/
CH20, by reaction of the chloromethylated products with metallic salts of
diether dithiophosphoric acids, and by subsequent treatment with Ca(OH) 2
Card 1/2

30650
3/081/61/000/020/085/089
Synthesis of mineral-oil and... BIIO/BI47
or Ba(OH) 2* A new method was worked out for synthesizing the oxidation-
inhibiting additive 2,6-di-tert-butyl-4-meth 1 phenol (I) by alkylation of
dieresol (mixture of p-cresols and m-cresols~ with the butane-butylene
fraction in the presence of H 2s0 4* By treatment with aqueous alkali in
the presence of a solvent, the alkylate is separated into a solution of I
in the solvent and into an aqueous alkaline solution which contains other
alkylation products of dicresol. The periods for which ethylated
gasoline with an addition of I and some of its synthesized homologs
remain stable are indicated. LAbstracter's nDte: Complete translation.]
Card 2/2

j
s/oai/6i/000/020/075/065
B106/B147
AUTHORS: Isagulyants, V. I. , !~i~Lhkov~e Ivanov, S. K.
,,,.-V
TITLE: Ionites and their use in catalytic synthesis
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 20, 1961, 321, abstract
20L45 ((Tr.] Groznensk. neft. in-t, ab. 23, ig6o, 137-145)
TEXT. The alkylation reaction of phenol with a fraction of polymer
gasoline in the presence of cationite K$-2 (KU-2) was investigated under
static conditions and according to a continuous system. The dependence of
the phenol conversion rate on the temperature and reaction time was
determined. [Abstracter,s note: Complete translation-3
Card 1/1

S/081J62/000/006/086/117
B167/B101
i
AUTHORS: Tish!:ova,_._V.__N. , IgagulyantB, V. I., Chang 11aiu-cheng,
TEEifill-yeva, N. M.
TITLE: Synthesis of diether dithiophosphoric acids and their
derivatives on the basis of substituted phenols. Use of
these materials as additives to petroleum products
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 6, 1962, 541, abstract
6ML259 (Sb. "Prisadki k maslan, i toplivam". M.,
Gostoptekhizdat, 1961, 34-48)
TEXT: Starting with diether dithiophosphoric acids (I), prepared from
P2S5 and alkyl phenols in toluene solution, 35 compounds have been
synthesized and studied as possible anti-oxidant and wetting additives to
motor oils. Their anti-oxidant action was studied in a solution of
mineral oil rIF-16 (aV-16) by the thermal oxidi~tion stability
f(M' 4953-49 (GOST 4953-49) and vaporizability rocr 5737-53 (GOST 5737-53)
methods; their wetting power was measured on a IT38(11ZV) apparatus. The
Ca salts of I, the I of which was prepared by the reaction of P 2S 5with
Card 1/3

s/oal/62/000/006/086/117
Syntheois of diether dithiophosphoric ... B167/B101
mono-alkyl phenol disulfides or with mono-alkyl phenols (alkyls;
tert-C H97 tert-C n and tert-C H ), had both anti-oxidant and wetting
4 5 111 a 17
properties, but the basic Ca salts had a stronger wetting action and a
weaker anti-oxidant action that the neutral Ca salta, which were powerful
anti-oxidant but indifferent wetting agents. The most attractive additive
is the basic Ca salt of I prepared from t~vdisulfide of tert-octyl phenol
(the multifunctional additive 1IF-22x (IP-22k)) and also the neutral Ca salt
of the same I (the anti-oxidant additive All-22x (AN-22k)). The Ba salts
differed little in activity from the Ca saltsp but the Zn salts had a
high anti-oxidant and a poor wetting action. The strongest anti-oxidant
effect was observed with the Zn salt of I prepared from tert-octyl phenol,
bis-tert-octyl phenol with a methylene bridge, or bis-tert-octyl phenol
with a disulfide bridge. By neutralizing I with organic bases (cc-methyl
stearylamine, octadeaylamine, guanidine, and the diamide of sebacio acid)
ash-free additives viere prepared. The neutralization was carried out in
a benzene medium at 400C (amines) or 160 0C (diamide). These ashless
additives had no wetting action, but were good anti-oxidants, especially
the guanidine salt of I prepared from octyl phenol disulfide. The eaters
of 1, prepared from I mole of I and 1 mole of propylene oxide, also had
Card 273

. SIOBI1621000100610861117
Synthesis of d;,iether dithiophosphoric ... B167/13101
no wetting action but were good anti-oxidants, and were furthermore
e1ofective stabilizers for oil solutions of other additives. A group of
compounds of the type 2,2-methylene-bio(methyl-4-tert-octyI phenol
6-dialkyl dithiophosphate) phenolate was prepared by condensing a
chloromethylated alkyl phenol or its disulfide with the sodium salt of I
(1-5-3 hours' heating at 70-800 in ethanol solution, followed by neutraliza-
tion of the condensation product with Ba(OH 2)) . Ethers of
diamidodithiophosphates were prepared by the reaction of P S with
2-5
OP(NH2)2 (in kerosene solution, 2 hours at 179-1850); neutralization
4-RC6H
4
Oryi~P_'(S)(SH)NH.
Compounds of the last two
with Ba (0H)2 affords 4-RC6H4
g
groups were similar in properties to the Ca and Ba salts of I.
Abstracter's note: Complete translation.
Card 3/3

82959
s/o65/60/000/004/003/017
0 E071/E435
AUTHORSs Isagulyants, V.I., Tishkovaq V.N. and Grushevenko, I.A.
TITLE*. Production of Synthetic Lubricating Oils of the Type of
p,olyglycol Esters 7 1\
PERIODICALs Khj-miya i tekhnologiya topliv i masel, 196o,,,~No.4,
PP-8-13
TEXTs A systematic investigation of condensation reaction of
propylene oxideTwith phenols,7substituted phenols (butyl and
actylphenols) and alcofi-oT-s-lpropyl, isopropyl, isoamyl, heptyl,
octyl and 2-ethylhexanol) was carried out in order to produce
synthetic lubricating oils (polyglycol esters) and to test their
low temperature properties. Altogether 39 spectmens of synthetl,:;
oils were prepared. The physico-chemical properties of polyglycol
esters based on propylene and phenols are given in Table 1, of
those based on propylene and alcohols produced at atmospheric
pressure are given in Table 2 and of those produced in an autoslave
are given in Table 3- The experimental procedure is described -4n
some detail. In respect of polyglycol esters based on phenols,
the following relationships were foundg
1. With increasing number of propylene groups in the molecule the
Card 1/3

82959
s/o65/60/000/004/003/017
E071/E435
Production of Synthetic Lubricating Oils of the Type of Polyglycol
Esters
viscosity of polyglycol ester increasesand its solidification
temperature decreases.
2. With increasing molecular weight of the starting substituted
phenol. the viscosity of the oil produced increases but its
te.mperature!.-viscosity properties somewhat deteriorate.
3. Condensation of propylene oxide with phenol takes place
easier than with a substituted phenol.
In respect of esters based on alcohols the following
relationships were found3
1. The viscosity of a polyglycol ester increases with increasing
amount of propylene oxide added to the alcohol.
2. With increasing viscosity of polyglycol esters, their
solidification temperature also increases as well as the ratio of
-q 5 0/ '1) 100 -
3. With increasing number of carbon atoms in the molecule of
alcohol, the absolute value of the viscosity and solidification
temperature of the polyglycol ester increases, The value of the
ratio of '150/'4100 remains practically unchanged.
Card 2/3

82959
s/o65/6o/ooo/004/003/017
E071/E435
Production of Synthetic Lubricating Oils of the Type of Polyglycol
Esters
4. Polyglycolic esters produced from normal alcohols possess a
higher solidification temperature than those produced from
corresponding iso alcohols.
Polyglycolic ester from experiment 13 was submitted to oxidation by
air according to the VTI methodq whereupon its resistance to
oxidation was established. It was found that polyglycol esters
based on propylene oxide and alcohols possess better low temperature
properties than those based on phenols. By varying the ratio of
starting components (propylene oxide and alcohol) polyglycol esters
of various viscosity'Und good low temperature propertie ~'lkcan be
obtained. It was also shown that alcohols produced at present on
an industrial scale (isopropyl) can be utilized for the purpose.
There are 3 figures, 3 tables and 9 referencem3 3 Soviet and
6 English.
ASSOCIATIM MINKh i GP im. Gubkina
(MINKh and GP-imeni Gubkin)
Card 3/3

V-W
;j
tlf-
V Bill
-10
'IC
cor"20 v 0,
P-S
'Llse JIS
,"flu 5.
., j ", (~-, i Ll 121) the ts
?I 37C jec"I 'aa ter'JL
t 0 v
os 0 O(JO t G,
'o
oil (VP .)LI
of
- GOTI v-
is " ncC
e -a- ro~ B6
-sbe3: 01 e tp
vi ~ " t,, e
enoIS C) j 10
V. al, ; ~- I a -,Ollol- 1 01
"I C -
O-C p &0 170 (L 0 o,
tjorl O-JO, -,eve c kx lite
I elle 0 -
.r.L, f tj )~ &. P,
in 11, e 0 120
-t. -10 e 120,
I j f 1, 1 vJD, L
ne OL 6
r L oc 11
s in
.0 -110 b
.13'a 0 0
s0--
11 1 e
2-et
^
v

The SyntiheSiU Und properLies ...
IS/061 /62/000/008/044/057
-~I 56/Bi 01
viscosities at different tem-pei-atures arz~ I-ivc.n for Uie ! produced.
increasitir- the number of !I 1J.-i -,.he 1 increases tile viscosity of
tile I. The i oroduced on an alcoho' base 'el points between -52 and
-600C) had luetti~.r lo-,,i-teiiiperature prop(:rtieo th;jx, the phenol -base I (gel
oints between -26 and
p -430C'. '11he authorv coiifjid,-,,l- thut it vIL11 be
effective to add cortaia of the I to tih,~ compoaitiona of additives for
1 L
,ybrivat-ing oils to improve, their dispersing and cleansing properties.
LA batracterls note: Complete tranulation.]
Card 2/2

ISAGULYAXTS, V.I.; FAVORSKAYA, N.A.; TISHKOVA, V.N.
Synthesis of 2; 6-di-tert-butyl-4~-methylphenol, Zlrir,prikl,khim-
34 no.3:693-694 Mr 161. (Cresol) (KM 14:5)

TOPIC TAGS: dihydrorcybenzene, divalent phenol, reqorcinol, phcnol alkylation,
ca t i Oil excha fige re n i 1, excha t12 r -rl L a t
&BSTRACT. The authors used the catton-exchari2e resin. K11-2~jq-lz F-r t~!e
'lc -E r::
their mtxt'~.rf: are f-mpul. delpndin~~

t C D u t v r1
e
71 71

TISIIKOVAJ, V.N.; ISAGULYANTS, V.I.; PAVOKI, i~.K~; 71-11F IVA, B.S,
- iti7e to lubr4ca-n:~- ---~
-r.tioxjiiz'ng add- '--
Synthesizing a n=w a 1 .1 -
L ~ 3 .
for forced working enginei. Trudy !-YINKHiGP no.4.4.105-109 'C"
( 141 PJi 18: 5)

lary ty I :,.Ti
~o r~: irl(A -
f b',ItYlr~
alia t~!T' LJ "Y
Synthesis 0
~e-tiarY ol-~ 3
catecholy 0.12:, '73
1 1. ihira. 37 n
Zhur. prik

ISAGULYANTS, VOI.; TISHKOVA, V.N.; CHZHAN SYU-CHZHEN [Chang Hsiu-cheng)
- - ___. .-- mltif-uncuional additives on a base of text-
Synthesis of ne,.4 :116-125 162. (miRA 17:3)
amylphenol. Trudy MINKIliGP no.37

ISZAGUL,JANC,v.~j. (Isagulyants, V.I.); TISKOVA, V.N. (Tishkova, V,11-j
GRUSEMENKO, I.A. [Grushevenko, I.A.1; F-ME'R, Domoakosnee [Translator]
Preparing polyglycolether-type synthetic lubricants.
Kam tud kozl WA 20 no.1:33-39 63.
1. Leningradi Tudomanyegyetem (for Tishkova, Grushevenko).
2. Ormeny Tanaeskoztareasag Tudomanyos Akademiajanak rendes
tagia (for IszagulJanc.).

.0
ISAGULYANTS, V.I.; TISHKOVA, V.N.; AMAR, Sh.; BYL11;HINSKAYA, M.
Production of synthetic lubricating oils of the type of monc- and
dicarboxylic acid esters. Khim.i tekh.topl.i masel 8 no.2:15-20
F 163. (MA 16:10)
1. Moskovskiy inatitTitneftekhimicheskoy i gazovoy promyshlennosti
akademika Gubkina.
1.

ACCESSION NR: AT4008702 S/2982/63/000/044/0105/0109
AUTHOR: Tishkova, V. N.; Isagulyants, V. I.; Papok, K. K.; Zuseva, B. S.
TITLE: Synthesis of a new antioxidative fuel oil additive for engines operating
under a loading
SOURCE: Moscow. Institut neftekhimicheskoy I gazovoy promy-shlennosti. Trudy*,
no. 44, 1963. Neftekhimiya, pererabotka nefti i gaza, 105-109
TOPIC TAGS: lubricating oil, EP, extreme pressure, extreme pressure lubricant,
antioxidant, lube oil additive, detergent additive, phosphorodithloic acid.
diester-. calcium salt, dithiophosphoric acid.diester-.calcium salt, AN-22K
additive, phosphorodithioic acid.octylphenol diester, octyiphenal, SB-3 detergent
additive, detergent oil, detergent lubricating oil, lubricating oil detergent
ABSTRACT: The authors synthesized lube oil additive AN-22K, a neutral calcium
salt of the dioctylphenyl ester of dithiophosphoric acid, in four stages: 1)
kylation of phenol with diisobutylene in the presence of the cationic reagent
KU-2; 2) preparation of octylphenol disulfide by reaction of octylphenol with
sulfur monochloride; 3) preparation of the diester of dithiophosphoric acid by
reaction of the octylphenol disulfide with phosphorus pentasulfide; 4) neutra-
lization of the acid obtained by calcium hydroxide. The additive is a solid of
~Card 1/2
_--------------------- --------
al-

ACCESSION NR: AT4008702
cinnamon coloration, becoming yellow when powdered, and has a mol. weight of
1200. It was tested with lube oil MT-16. it produced the best results when used
as a composition additive in a 1:2 mixture with the sulfonate additive SB-3 and
exceeded the performance characteristics of the phosphorus-containing additives
MN I-IP-22k and vniinp-360. Orig. art. has: 2 tables and I illustration.
ASSOCIATION; Institut neftekhimicheskoy I gazovoy prom *shlennosti, Moscow
(institute for petroleum chemistry and the gas industry~
SUBMITTED: 00 DATE ACQ: 16jan64 ENCL: 00
SUB CODEs FL NO REFF SOVt .004 OTHER: 001
Card 2/2

s/C65/63/000/002/001/008
E075/E436
AUTHORS: Isagulyants, V.I., Tishkova, 1.1L., Amarl Sh.,
Byllehinskaya, M.
TITLE: Preparation of synthetic lubricating oils of the type
of complex esters of mono- and dicarboxylic acids
PERIODICAL; Khimiya i tekhnologiya topliv i masel, no.2, 1963,
15-20
TEXT: Adipic and sebacic acids were esterified at 120 to 1400C
with isoamyl-n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl,
and n-decyl alcohols, using cation exchanger K*Y-2 (KU-2) as
catalyst (16% wt of the acids). Anion-exchanger AB-17 (AV-17)
was used after the esterification to remove residual acids from
the esters. To minimize the formation of acid esters (half
esters) an excess of the alcohols (25 to 56 theoretical) was
used. An ester of technical C? -C6 fatty acids with pentaerythrit-
ol was also prepared. The yie ds for all the esters ranged from
92.5 to 99.3%. Di-2-ethylhcxylsebacate, di-2-ethylliexyladipate
and diisoamyladipate had setting points of less than -600C and may
be suitable as components of synthetic lubricating oils.
Di-2-ethylhexylsebacate and the pentaerythritol ester are the most
Card 1/2

S/065/63/000/GO2/001/008
Preparation of synthetic ... E075/E436
promising esters for practical applications (viscosity at 1000C:
3.20 and 4.32 cst respectively; setting points: -60 and -650C
respectively; viscosity indices: 155 and 138 respectively). The
use of ion exchangers as csterification catalysts presents many
advantages over catalysts such as ZnO and H2SO4. The advantages
are: relatively low esterification temperature, high yields,
possibility of using continuous esterification processes, ease of
separation of the catalyst from the products. The catalyst can
be used several times and can be regenerated easily.
There are 3 tables.
ASSOCIATIONS; MINKh and GP imeni Gubkin
Card 2/2

I,k L I inzh.; TI:-" KOV GURVICII, II.L.
Kathods for oil conte-.-it of cc-.~,-~-nol
baull. Mas-I.-zhir. -c.'1:3/,-36 JI 10A.
14:?)
I# TientralInaya L' x-vIonl-ir~-
prota,yahlennost' Yxisnc)d:LrB,:oF,,o 3crnai-::'.oza (for Aleshina).
;1),:! tit
, (t.
2o
(for Gurvich),
(I~saoncac --nd essential olls)
(Basii(Botmay)