SCIENTIFIC ABSTRACT TIPOGRAF, D.YA. - TIRAKYANTS, ZH.S

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Creation Date: November 2, 2016
• Document Release Date: July 16, 2001
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

'.1 .4 U. S T U I V--L A a I
)RD ..P
P11CPgOT'Is .04.
YCROWUMA Cam'd 049APYWRKX KnAttenot MXU
(A mpfd method ddiagnosing ring rot of potato
C.R. Pa*,%r. vi. Lenin Awd. agric. &i., Moscow. 19WI: 5. -00
pp. 35-M. 1 fig., 1941. 9
eel
*04 The author describes an amurste and quick method (requiring two
to three minutes) of diagnosing potato ring rot (Baderium wpdmicm)
008 [R-4M., xx, p. 4191. it canuffts in an agglutination test in which
10,08 plant juice from a diseased stem or tuber is mixed with (1) immune $00
eel germ obtained by injecting a pure culture suspetudon of Had. orpdoni-
3
mm into rabbits and (2) nortnal strum; in caw of a positive reaction
GOO the drop containing the immune serum becomes flocculent and lighter
in colour, while the dro ~ with the normal serum used as a control too
oev remains turbid. In p0let tests the results obtained by meum of the
Ticro-p- in most cum entirel coincided with the serological data.
00-a - y woo
as::
woo
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OCTALLUNCKAL UMATURI CLAMPKATION
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but sometimes remained somewhat indefinite. Intestsofthespecilicity-
of I lie inimune Peritin it was found t lint 59 out of 60 attains of bacteria
ifolM141 frons lHoAlIN-A Offi-OMI by tin# tof viphli,41 I'lf%tl,V firgalivo
'111414,41 Ali 11~4!111010 tval'1141fl, A1114i
tPAUltil I&IRI thr MWAIIIIIIg 0411111 Ilit
cation of the wrologival motbW in the fiAl ohowi%l that '12-1) Iter evot,
of apparently healthy, well-developed plants were infected, ntl it 4
conchided, iberefore, that appraisal of healthy plants by external
appearance only does not offer sufficient guarantee against the presence
of ring rot Stems containing Bad. sitpdovtiam, when dried at room
temperature, retained their capacity to agglutinate after 100 days of
storage; pure cultures of the organism retained theirs; after being dried
at 80' C. for AO minutes. This shown that the scrological method of
diagnosis can be made with both fresh and dried sterns of the potato.
- . .. T%.- 'T ^ . - -
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- F , , -
I i C_ ~v Ia.
"'Etiolo&v and Diagnosis of Poteto Ring Rotir Sub 4 MaY 51,
MoEcow Order of Lenin State U Iment M. V. Lomonosov.
Dissertatlons prpsente0 for science and engineering degrees In
Moscow during 1951.
SO: Sum. No. 480, 9 MAY 55

TIPOqRAP,*D. Ya.
"Etiolopy and Diagnostics of Ping Rot in Potatoes, (Zualifying Dissertation in Com-Getition
for the Degree of Candidate in Biological Sciences, Moscow, 1951.
141krobiologiya, Vol XX, No. 5, 1951
O-W-211635

VESE1.11OVY S.Yll.i TIPWRA!", P-Dt.p- i;,*: Tl i I A. T,A.
z.zl.- - il
IiBrRrgj-,---,ILS car.-a--~ a--- zrrx:llce~ C.L abcmasa,
- -
J
-L mtkrobiol. I mo.-'-.52-56 Ja-F 165. (MIRA 18;5)
3. T(Ahnologic-hookly irptItut, pishchri-,cy Mirkvn.

VESELOV, I.Ya.; TlPOGRAF,_-D,,,,,Ya.1 YURKOVA, A.I.
Formation of proteolytic ferments In deep grown bacterii. Izv.-
vys.ucheb.zav.; pishch.tekh. 2:24-29 162. (WRA 15:5)
1. Moskovskiy takhnologicheskiy institut pishchevoy promyshlennosti,
kafedra mikrobiologii.
(FERMNTATION)

TIPOGRAF, L.M... . - S. Avt.prom.
- -'. universal clamPs for fork li_ft ~%,ruck
162.
zavod avtopogruzchikriv. lift trucks)
1. L-vOvskiy (Fork
28 no 12-/.2 D
iMIRA 16:1)

TIPOGW, S. 0.
Remodeling, the ventilation system in the body repair shop of
a motor car plant. Prom.enorg. 15 no.2:19-20 P 160.
(MIRA 13:5)
(Ventilation) (Automobiles-Maintomnce and repair)

S&CHI, KDroy EMCHT, Naroly], Prof., doktor;__T_jpW,-'2,S.A.,Inzh.
Ltranslatorl; Y=ROT, K.Te., kand.takhn.nouk. nauchnyy red.;
EMU , B.A., red.izd-va; OSMO, L.M., tekhn.red.
LIrrors occurring in foundation engineering] Oshibki v soor-azhenii
fundamentov. Predial. M.I.aorbunava-Posedova. Koakva, Goo.izd-vo
lit-ry pa stroit.. arkhit. i stroit.materialem, 1960. 142 p.
NiRA 14:1)
(Foundations) (Soil mechanics)

MOKK, Laslo [Mokk, LAszlO'j; TIFOLIT, S.A., inzh. [translator]; SOROKER,
V.I., doktor tekhn.naa-,-r-e'd.';-":~H"ALIN, Tu.P., red.; GILENSON,
P.G., tekhn.red.
[Precast reinforced concrete construction elements; manufacture
and assemblage in constractior yards] Sbornye zhelezobetonnye
konstrukteii; izgotovlenie i montazh na stroitel'noi ploshchadke.
Pod red. V.I.Sorokera. Moskva, Goe.izd-vo lit-ry po stroit.,
arkhit. i stroit.materialam, 1959. 302 p. Translated from the
Hungarian. (MIRA 13:1)
(Precast concrete)

TIPOV, G.Ye., redaktor; FLAUM, M.Y.a., redaktor.
[Instructions for welding in marine ahip constriction and repairl
Pravila pr1menenila evarki Y morskom Budostroenii i audoremonte.
Moskva, Korskoi transport, 1953. 167 P. (MLRA 7:3)
(Welding) (Shipbuilding)

M&A

AUTHORS: Galley, Z.A.,-TiRt~a ~V-G.,and Peshkova, V.M. SOV/555-158-1-28/335
TITLE: The Application of the Ascorbic Acid in the Amperometric Titration.
Communication 2. Determination of Iodine, Hypochlorites and Iodates
(Primeneniye askorbirV 4VPY,kidloty v amperometricheskom titrovanii.
Soobshcheniye 2. Opreae-ileniye yoda, gipokhloritov i yodatov)
PERIODICALt Vestnik Moskovskogo universiteta, Seriya fiziko-matematicheskikh i
yestestvennykh nauk, 1958, Nr 1, pp 209-213 (USSR)
ABSTRACT: It was asserted that the ascorbic acid can be applied successfully
as a reagent mean in the analytic chemistry, e.g. for the
determination of copper and active chlorine in a iodometric manner,
or of hypo-chlorites by a direct titration with ascorbic acid. Lead
and silver can be shown by titration of the excess of the
potassium iodate.
There are 5 Soviet references.
ASSOCIATION:Kafedra analiticheskoy khimii (Chair of Analytic Chemistry)
SUBMITTED; September 20, 1956 Zh A Kh
July 11, 1957 VMU
Card 1/1

AUTHORS: Busev, A. I.,,,Tiptsova, V. G. sov/i56-58-3-20/52
TITLE: The Ionic Interaction of Trivalent Thallium and Iodide. The
Thallium Iodide Complexes (0 vzaimodeystvii ionov trekhvalent-
nogo talliya i iodide, i ob iodidnykh kompleksakh talliya)
PERIODICAL: Nauchnyye doklady vysshey shkoly, Khimiya i khimicheskaya
tekhnologiya, 1958, Nr 1, PP- 486 - 490 (USSR)
ABSTRACT: The reaction between the trivalent thallium ion and iodide ion
was investigated. On the addition of weakly acid solutions of
T12(so 4)3 to iodide solutions the following reactions occur:
T1 3+ + 2 J T1' + J 2
12 + J 13
Tl++ J- + j3 ~~Tl J
4
Thallium is determined titrimetrically according to the first
reaction. A selective titrimetric method for the determination
of small amounts of thallium (0,2 - 2,0 mg) with potassium
Card 1/2 iodide solution was worked out. The determination is not

The Ionic Interaction of Trivalent Thallium and Iodide. SOV/1-56 -58--j-2o/-:2
The Thallium Iodide Complexes
influenced by a great number of elements. The cadmium and
mercury ions influence the titration as they also form com-
plexes with iodine. The absorption spectrnm of the following
molar solutions was taken for the determination of the
thallium complexes with iodine: T1 : J = 1 : 2 and
T1 : J = 1 3. The maximum for the complex TlJ 4 is at
395 mg. The absorption maximum remains constant when more
iodide is added. There are 4 figures, 2 tables, and 5 refer-
ences, 1 of which is Soviet.
ASSOCIATIOU: Kafedxa analiticheskoy khimii Moskovskogo
gosudarstv~i.iiogo uni.,ersiteta im.M.V.Lomonosova (Chair of
Analytical Chemistry at Moscow State University imeni M.V.,
Lomonosov)
SUBMITTED: December 27, 1957
Card 2/2

11-2,4127
AU, 21101W': T
Stuu7i-._'3 of of (isoledovaniya
ol~ 1: -.,1 'Gi :L"1:1" i ti c:'- I o i c;il- ion
o i'h, t I I i )~'!i,`.oniyo I

E 1110, 1) 1 CL tic':C:1 '~j-/ ".!A~.di. 1Vol,. 1 3,:I-r 2 r)- -190-1115(Usft)
A133TRACT: A ',ru~it nuitber of tiu,'.hod~o c~,~n ~;c .'ound in ,,',u'blicutions foi- the

ar~ 11-ative rjetermin-~.tic.:: of tL.J-.i1Am j
~'i' l I i (Ref 3 1 , 2' ,~iiere i3,
q
ho-aever, u1, to now nG suffliciuntl.',' specific, qUiCk,. Und re
liable deteloination :lethod f(.-r th-Aliun in variaw-, industrial
and nat-.r,,_l si,,bL;tances~' In t1:C -..;Ilytical che'n'listry t. 110
formaticii af complex compoun,.;s of trivalent thalliurri i--- al-
mont not iz:z,-d at all. ExPeriTwnts that thero j.~l a
Eveat, nw.:l1.w..r o, ovich oon-'ourvill 'A)lcll aro, hovievor, ozil:! to
I 'I ), .1

(itur ~.'Vejl the reautiorl of
U QXtCrlt -
the -~rivalcnt th~,.liiiu;i .-ith c(-,rv~l_-:on III is not sufficic~IA-
ly investi,~",lted c,.nd is t'locrefor,-, prLLctically not uscd. T13+
for..is Iu stable complux vtilt'c.. t.,o.;lplexon III. _11C. ::10;11
Card 1/4 odo ro'- the 2o oil of "by -Lndircct; compl~.xci..

75 IJ, ,//;)7
Studies of the Annlytical Chur.ii-L;tr.y of 12 iallitir. C n c o n ~),:s - 1 c x
metric Determination of
metric titration (Ref- A.,
are based upor, the lazt-inci-,tioned fact., are L.-,d
not specific. In the presont pl-.per tnetl,-iod is
f o r th o, comjloxome tric t c rmi r.'; J k) 0 i' '111 a I I j 117
L, I ~ - .~l, r
pu rpo so th o 1 ovie r 1 j. ~,i i t (j C t 1 ~e pll - v 1 u~. f t u ,t L,-, 1); 1. 1 %y
j,
the complex compound o2 th--Iliiin v;c.,3 (j. ti,rilincd t'! L 1,
diamine te'raLcetic Lacid .ne C'-'ric
by amperoi.iLtric titr~LtiOll 1.1~' ;1ec'nS OC
tinum-electrode, A merciiry electrode can:;ot b,2 ust-,d, -"2'.rC.C
mercury ig dissolved in ca:~o of a roduct-Ao;i
of the "'13-i-,-ion on the Y, ~, J R c! f B -, s c d U 1,) 0!, 1 IU r 2) t 3
of these inve6tigation t"'C- poss-ibilitzi of a
zaetric titration of the T13+.-ion at loa pl!-valiics u'ls !I.-
vestigat-A and a suitable indiC--tOr OOL11f1ht, Cr. tht-.
strength of these experi7.-.ents a dircot coraparatavely zclec-,,
ive mqthod was worked out for Uhc! =;r,lexometric titra".1cin
of 21-,+ in soveral tcchnioi,). -,iL Lv ria, Pi., It ,-(~m3
direct amperotactrIc titration cC triv~-L.L(-~nt thl-Alit-tw wit"11
complexon III is pos2ible in th'3 (-,~t3C- of absr.nce of .--reat
quantities of Cl and Br --ions at vulues ;,- 1 : 2 1-1(1 1 n.
Card 2/4 the ca;.,e of presence of coi,--iderabble quL-.ntitic:-, of C1 a

7C-17-2-4/2~
11 11 1/ 1
Litudies of the Analyticf.;l Chemisbr~f oL' '21iLllium. Cc-_-.-.unica--.ior 1. Complexo-
metric Determirabior of Thalliua
-.'ias found to
plH-values
oc. best ;-,ui'ucd ).3 in,~i(,%,!-ov for tlic 121)+-.ion. This azo dye
forms a rcd--violet colord ii; acid solutions_' with
T13+-jolis, witi-, Lt io', Irqclr coni-e.,itration or hijier,
_.~cruito Lhu visual titrat-Lon of Lhalliuui wiWi Qw.iplexon III
at pll,,j 2 ~tnd hi,-Iher. This determinaLion mathod is riot
disturbed by -reat quantitie3 of Zn, Cd and Pb and can
0 2+., 11i2+
,e analysis of technical material
be uscd for th S~ CU
PC 3+. and Bi 3-~ disturb the vi.,,uul titration bj formation of
colored coi.%--,1exes vlitlh the indicator (Ref 12), Gi- Br' and
J_ destroy thu coloration of thc complex of the TO+-ion
With 1-(2-pyridylazo )-2--naphthol and dioturb therefore.
Colored n-rions disturb, too. 3+
T"he wiperovietric titration of thallium is dioturbed by PC
3+ 2+, -3 by oxidizinrr iono which -enurate a
Bi and Cu. as well [?: U
reduction current at E = 0 v Cr 10 2-, 11 0 etc.).
I -ie f. ri C., iZn 'r~ao'aRvaritc~L;e3
In spite of thi3 the ariperoi, tit rri 0
Card 3/4 compared to the visual titration, since it. tl,e deter-

75 - 13 2 - .,/ 2 '1
Stud i o n o f th e fin alyt i cal Cho t,) i j t ry o i, Ij icc, t icr 1o1
metric Detcrminati(-)n of
mination i,. Presence of cn1crido ions -,I, I)II-v, hi ~0" 1!4-2i0
CS
and furthermore cL- be u!-icd in turbid and coluretl colutions.
The carryinr- oui, of the tao complexometric deturi:0rintion
methods (amperometric alld visul~.l) for tvchnical il,tterials
is described preciu--1.7. ThUTO are 2 fi~,ures, 6 Lable:l~ ---.:-,d
12 referencus, 2 of vihiell,, are :3oviot.
ASSOCIATION: ;,4ozikovolly univer3itet i!-. l.". V. LonC)no:)ov:l
(IMOSCOVI State Univerility ii~ioni 7. loiionosov)
SUBMITTEDt November 27, 1956
1. Thalliur.--Quarit-it,~t""~,,c-: Tha].! i liT,
--Determinat~'Ion 4.
Card 4/4

TIPTSOVA, V.G.
- "Methods of organic chemistry" [in German]. Reviewed b7
V.G. Tiptsova. ZhtLr. anal. khim. 13 no.3:376 ify-je '58.
(MIRA 12:3)
(Chemistry, Organic)

5(2) SOV/156-59-1-25/54
AUTHORS: Busev., A. I., Tiptijova, V. G.
TITLE: The Photometric Determination of Thallium With Tetratie.loyl-
diaminodiphe?iyl-.antipyryl carbinol (Fotometricheskoye
oprodeleniye talli a 8 pomoshcblyu tetramet-ildiaminodifenil-.
antipirilkarbinoia~
PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimiya i khimicheskaya
teklinologiya, 1959, 1Jr 1,. PP 105-107 (USSR)
ABSTRACT: The reactions of methyl violet, crystal violet, brilliant
green, rhodamine etc with certain heavy metals (Zn, Au, Sb,
T1 etc) are known. Difficultly soluble compounds are formed,
which can be extrac"Ied with benzene or benzene homologs
whereas the dyestuff itself is not extracted. These dyestuffs,
however, require a very high concentration of acid and ions
etc and are not selective enough. Tetramethyl-diaminodiphenyl-
antipyryl-carbir,ol ', which has been proposed by Zhivopist3ev
(Ref 12) for the qualitative determination of zinc in the
presence of rbodaniuni ions was investigated as a reagent for
TlCl4 ions. In the presence of chlorine- or bromine ions a
Card 1/3 bli)e-vioiet precipitate is formed, which can be extracted with

SOV/1 56-59-1-25J/54
The Photometric Determination of Thallium With Tetramethyldiaminodiphenyl-
antipyryl-carbinol
ether or benzene. The organic oolv-,nt assumes an emerald-
green color. The reagent itself is not soluble in ether or
benzene. Only in the presence of bromine ions does part of
the reagent enter into the organic solution as bromide. For
this reason a restriction was necessary to the extraction of
thallium in the presence of chlorine ions. For this purposed
a mixture of 2 parts by volume benzene with 3 parts by volume
carbon tetrachloride is recommended. The large surplus of
the reagent required has been investigated by experiments.
The light absorption curve has a maximum at 638 mg (Diagram,
Fig 1). The influenca of the acid concentration on the opti-
cal density is 'J'n9ignificant between 0.1-1 n HC1 (Diagram,
Fig 2). From 2 n 11C1 upward the optical density decreases to
be zero at 5 n HCI; which means that a colored compound is
not formed in strong hydrochloric acid. In this range the
optical density is proportional to the concentration (Diagram,
Fig 3Y. 1-20 1 tliallium in 10 mole solution can be detei-mined
by this -method. The molar extinction coefficient is 68000 at
2- form colored pre-
Card 2/3 638 mp. Whereas CdCl 4. BiCl 4~ MO 4,

0,011/1 rj6-c'5- , -2c /54
The Photometric Determination of Thallium With Tetramethyldiaminodiphenyl-
antipyryl.:.carbinol
cipitates with the
not be extracted.
like thallium. Fe3+
at a ratio of Tl :
expressed to V. P.
agent. There are 3
Soviet.
reacent, these precipitates, however, can-
Ifg, Sb, Sn react as complex chlorides
ard CU2+ flo not disturb themselves even
Fe (or Cu) = 1 : 100,000. Appreciation is
Zhivopist3ev for having provide the re-
figrures and 12 references, 10 of which are
AS90CIATIOTT: Kafedra analiticheskoy khimii I'Joskovskogo Gosudarst'vennogo
universiteta im. M.. V. Lomonosova
(Chair of Analytical Chemistry of Moscow State University
imeni IT. V. Lomonocoir)
SURIMITTED: September 8, 1956
Card 3/3

!2i T)t,.O
A'I
'Aud:~-
-
o 1) 1 a
.
,
v
1-joli 2.
mide Comple:-oc

I., c 11 1 1,; 1. C.'.' 71. J ("C.
-obc'
-
?
v o
t o i
i bi

u silz
`11-_ _-2cipitation
A'SThACT: Thc authorz of the rz%per
. C :
it" '~ra'."Olovc
.
reaction of thallium brou,irle complexes w
* -*
d
dorivatives and deterviinod the com-i-ositUcn c: or
-
1
nt the
compoundn an VC11 a:--, 1"'eir propcr-Liec. it ;:at;
-
- i
.
-j-' brouiine
.cc
i
riv .; in the prcij(
ion o4' 1, -lent thalliur. rcac~
antipyrin, dinntijyryl.
idon
,
ions -.Ath pyram
in
-
diantipyryl phenyl methane, ca=_
i i C"

'~
1
-1 "
vrith the folmulan, C (C
13 1 11 12 4

2C"C6L15"'i'q*"
T and (0, i I G..
Mli:
(
1

o ::e';Ul
-
C 1
;2 4' 4 0 11 2
23 24
Card 1 /3

A 3tudy of the Analytical Chcmistrir of :I'llalliuM. 5(jV/7`-1,`-1-:
Communication 2. Precipitation Reaction of Triv.,_,lont '~hallii)n ~-,'romide
Complexes ','Iith Some Ilyrazolcnp Derival.ivr_,~,
On investiCating the properties of the mentione(i camijounds, the
compounds C1,1! 11TIBr (c if ON I ;,. I j L11
170ii3' 41 11 12 2)2 L-4
C29112802N 4' IITlBr4wore found to be un-uitable lor tzc
determination of' thallium. 'ilho compound .-;ith pyraf;idon i~~;
considerably soluble ill VIELter, moreover L'o-d.litim i:: not
precipitated quantitatively. The cornpound ;-.ith anLipy-rin also
possesses considerable solubility. 'I"he com, -n,ound -:-i ti`~
diantipyryl phenyl methane finall,r, cz,~nnot b:~ for the
Gravimetric determination of thalliur. liccause t'i;- is
difficult to solve in v7atcr and the same for the
bromide of diantipyryl phenyl methane, co -.-ecipitatcc
along with the precipitation of the thalliu,:1 fho
compound with eiantipyryl methane C. if ..1- P !-.rrmits a
3
gravimetric as well as an amperometric deterinirw,%ion of
thallium. The respective determination rethods out
and are accurately described. Copper anC_ -ii;c rl,() not
the determination, Cadmium can be kept in tlic by
C-rd 2/3 choosing the bromide concentration.

of the :ji,.!.Iliu joV/7' 1 1 -
,or.~rilyiic~ tion 2 rc c i J. i o", ~-i 1 t
"ith
j. i
A (t o o
ti i
-c c. i lile
0 X 0 n
o v i (3 U
o
Lo-ononova
V. Lononosov)
Jilly 27, 1957
Card 30

TIPTSOVA, V. G. Cand Chem Sci -- (diss) "On certain complex compounds of
INIM trivalent thallium important in analytic chemistry." Moa, 1959. 16 pp
(Moo Order of Lenin and Order of Lnbor Red Banner State Univ im M. V. Lomonosov.
Chem Faculty), 110 copies (KL, 50-59. 124)
-7-

S/075/60/015/003/013/033/XX
B005/BO66
AUTHORS: Busev, A. I. and Tiptsova, V, G.
TITLEt Investigations in the Field of the Analytical Chemistry of
Thallium, Communication 4,, Diantipyryl Propyl Methane as
Reagent for the quantitative Thallium Determination
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, vol. 15, No~ 3,
pp. 291 - 294
TEXT: The authors of the present report studied the applicability of
aliphatically substituted diantipyryl methanes for the quantitative
precipitation of trivalent thallium in the presence of chloride and
bromide ions. By condensing antipyrine with acetaldehyde and butyraldehyde
in hydrochloric acid medium diantipyryl methyl methane and diantipyryl
propyl methane were synthesized. These two derivatives of diantipyryl
methane precipitate the bromide complexes of thallium quantitatively,
while the thallium chloride complexes are quantitatively precipitated only
by diantipyryl propyl methane. For this reason only diantipyryl propyl
methane was used for the further studies, the synthesis of which is
Card 1/4

InvestigiLtions in the Field of the Analytical S/075/60/015/003/013/033/XX
Chemistry of Thallium,. Communication 4, Di. B005/BO66
antipyryl Propyl Methane as Reagent for the Quantitative Thallium
Determination
described in an experimental part- After the above-mentioried acid condensa
tion the solution is neutralized by aqueous ammonia (10), In which
connection diantipyryl propyl methano precipitates which melts at
155-1560C after recrystallization from methanol. The yield of the synthesis
is practically quantitative,. For the gravimetric determination of thallium
a 1% solution of this reagent in acetic acid (I.-I) was used, 5-10 ml of
concentrated HCl (or HBr) and 6-B ml of the reagent solution were added to7_
a solution which contained 20-30 mg thallium in the sulfate form. The
resultant precipitate was filtered, washed several times with water and
then recrystallized from an acetone--alcohol mixture,. The chloride complex
(I) of thallium with the reagent is slightly yellow and melts at 56-57 0C.,
while the corresponding bromine compound (II) is green-yellow and melte
at 128-1290C. The solubilities of these two compounds in water are on the
average 5.7-10-5 moles/1 at 200C (compound (1)), and 6.7,10* 6 moles/1'
respecti-ely (compound (H)), The elementary analysis gave the formula
C26H 30 02N 4' HTlCl4for compound ~I), the formula C26H30 02N4 HTIBr. for
Card 2/4

Investigations in the Field of the Analytical S/075/60/0j5/oo-/oj1T/O-,3/Xx
Chemistry of Thallium., Communication 4, DL- B005/Bo66
antipyryl Propyl Methane as Reagent for the Quantitative Thallium
Determination
compound (II), Both compounds can be weighed out dirpetly. The authors
investigated the effects of the bromine ion concentration and of the
acidity of the solution on the determination of thallium as
C26H 30 02N 4' HTIBr 4* Changes of' the bromide concentration from 0,,1 M to I M
do not appreciably influence the results of the determination (Table 2).
Ata bromine ion concentration of 2 moles/l the reagent precipitates, so
that the results obtained are too high.. The acidity of the solution does
not influence the completeness of the precipitation in the range of 0.1 N
to 5 N H 2so4(Table 3),. In the determination of thallium as
C26 H30 02N 4" HT1Cl4neither the chlorine ion concentration (> 0,,1 M) nor
the acidity (I N - 6 N HCI) affect the completeness of the precipitation
(Table 4).- While in the determination of thallium in the form of the
bromide complex the same ions disturb as in the analogous precipitation
with diantipyryl-methane (Ref,l), the determination of thallium in the
form of the chloride complex may be carried out in the presence of zinc,
copper, cadmium, bismuth, indium, aluminum, magnesium, iron(III) and of
Card 3/4

Investigations in the Field of the Analytical S/075/60/015/003/013/033/XX
Chemistry of Thallium, Communication 4. Di- B005/BO66
antipyryl Propyl Methane as Reagent for the quantitative Thallium
Determination
the anions As03- and P03-' In this case the solution must contain at leastt//
4 4 IV 2+ 2-- - 2-
3 M HC1 when being precipitating, Ga, Sn , Hg , Cr207 i C104, and MoO 4
disturb the determination, The method described was applied to the
determination of thallium in cadmium. The proceeding is given. The method
has a much higher selectivity than the method, described in publications,
of precipitating thallium as 1(C6H5 )4As]TICI 4' There are 1 figure,
5 tables, and 5 references: 4 Soviet and I US-
ASSOCIATIONi Moskovskiy gosudarstvennyy universitet im, M~ V., Lomonosova
(Moscow State University imeni M,. V, Lomonosov)
SUBMITTED: June 12, 1959
Card 4/4

B002YB056
AUTHORS: Busev, A. I. and Tiptsova; V. G.
TITLE; Investigations in the Field of Analytical Chemistry of
.Thallium. Communication Investigation of the Complexo-
metric Indicators for Trivalent Thallium
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No. 5,
pp. 573 - 580
TEXT: It was the aim of the authors to find out to what extent three
new complexometric indicators for the determination of thallium may be
used at low pH-values. The following investigations were made;
1.-(2-pyridyl-azo)..2--naphthol, synthetized according to A. Ye. Chir~hi--
babin; 1-(2-pyridyl-azo)-.resorcinol, synthetized according to Chich-,
babin, and xylenol orange. For the purpose of measuring the absorption
spectra, a Q-4 ~SF-4) spectrophotometer was used. For the complex?)f
fhallium with I -(2-pyridyl--azo)-.2--napht)ioI the following wa;--~fo-n-*J.
absorption maximum 560 m j molar extinction coefficient 2.17-jr,t, nqui-
librium constant 1.93-10~, measured at pH 2..2. In this regio-.j. however.,
Card 1/3

Investigations in 'the Field of .4-rial.-tical 9/075 160/015/005/Gl,
Chemistry of Thallium. Communication 5. B002/BO56
Investigation of the Complexometric Indicators
for Trivalent Thallium
chlorine,-, a,id bromine ions considerably interfere with the measuremente.
The influence exerted by hall.de...ions becomes low only at PH 4--5, where,
however ` the selectivity of the indirator is also very low. Bes-ides,
the solubility of the complex in water is limited. The complex may there,
fore practically not be used for the photometrical determination of
thallium. For the complex of thallium wit-h 1:.(2-pyridyl azo)-.rosorcinol
the following was found: absorption maximum 520 m4,.. molar extinction
coefficient 1.805~'10 4, equilibrium constant 1,.70'10 4~ measured at
PH 2.2. For concentrations of betwer)n 1, and 10 pgr V por ml , Lhe Beer
law holds, Yor the complex of thallium with xylenol. orange the follow.,
ing was found: absorption maximum 580 mp, molar extinction coeffIcient
1,96*104, equilibrium constant 8~00-1047 measured at Pit !-4, For tho
t1itration of a 0.01 M thallium solution, the indicators may be used
from the following PH values upwards (in brackets ~he theoretical error
of titration): 1-(2--.pyridyl-azo),,2--naphtho1 from PH 1,88 (-.0.45~6),
Card 2/3

Investigations in the Field of S/07 60/015/005/014/026/X7
Chemistry of Thallium. Communication 5. B002YB056
Investigation of the Complexometric. Indicators
for Trivalen+ Thallium
I k
1--(2--pyridy1-azo)-resorc1nol from pil 1 .7 ' +-O,,6Vo) , xylenal orange from
pH 2.0 (+11.88%). N. P. Komar' and V. N. Tolmachev are mentioned. There
are 9 figuresp 3 tables, and 9 references; 6 Soviet-
ASSOCIATION-. Moskovskiy gosudaretvennyy universitet im,, M.V. Lomonosova
(Moe--ow State Unt.versity imeni M.V. Lomonosov)
SUBMITTED: Ju-ne 29, 1959
Ca-rd 3/3

S / 0 7 4/ 6 0/0 2 910 0 B/ 0 04/ 0 G 5/J-
B023/BO70
AUTHORS. Busev, A. I. and Tiptsova, V, G.
TITLE! Analytical Chemistry -- of Thalliuml-1
PERIODICAL: Uspekhi khimii, 1960. Vol., 29, No. 8, pp~ 1011 - 1028
TEXT: The present paper systematizes the data on analytical reactions of
mono- and trivalent thallium published in the last few years. The contents
are as follows: 1. Classification of methods for estimation of thallium,
The most reliable methods are considered to be the gravitational methods
which depend on the precipitation of thallium as chromate, iodide,
thionalidate, mercaptobenzothiazolate, oxyquinolate, hexamine cobaltihexa-
chloro thallate, tetraphenyl. arsonium tetrachloro thallate, or diantipyryl
methane tetrabromo thallate, Titrimetric methods are of much more practical
importance, Other methods in use are: electrochemical, coulometric, polaro-
graphic, spectral photometric ., and spectral methods.. Trares of thallium
are determined by activation methods, Methods of separating thallium from
the accompanying elements and methods of concentration are dealt with in
Refs.. 29-40a. 2- Analytical reactions of monovalent thallium, Those ions
Card 1/3

Analytical Chemistry of Thalliuz
1. /' /' , 10."/ C' r" " ", '- ::,IX'K
- / Q 7 14 i a -3," G 20
BO_;~`/BOTO
and molecules which tend to form a covalent binding may serve as reagents
of Tl.+, as, for examples mercaptobenzothiazole, thionalide, dithizone,
thiourea, and Reinecke's salt., A, Reaction of precipitation of monovalent
thallium ion. Precipitation in the form of chromate, bichromate, iodide,
reineckate, iodate, cobalt nitrate, and ferrocyanides. The last topic was
treated by I~ V, Tananayev and M. N, Glushkova (Ref.. 79). Precipitation
as sulfide.. Precipitation with inorganic ions.. Precipitation of thallium
by organic reagents. B., Reaction of the oxidation of monovalent thallium
(Refs. 110-137),, C. Reactions of reduction of monovalent thallium to
metal. Reduction on dropping mercury electrode (polarographic methods)
Reduction on other cathodes (electrolytic methods). D. Reactions of
formation of complexes by monovalent thallium (Refs., 157-178), 3.Analytical
reactions of trivalent thallium ion (Ref., 179), A. Reactions of formation
of complexes of trivalent thallium, Hydrocomplexes, nitrate complexes,
eulfate, cyanide-, halide-, acetate-, tartrate complexes; complexes with
some amines; complex with ethylene diamine tetraacetic acid; complex
compounds with 8-oxyquinoline and its derivatives; complex compounds with
various dithiocarbamates; and some other complexes of thh1lium with
organic reagents, B. Reaction of reduction of trivalent thallium
Card 2/3

Analytical Chemistry of Thlaili~;-~ S / 07 4/6 0/02 9100 8/OC-,' /CC,
B023/BO70
(Refs. 270-280). It is recommended that n,-,tv methoda of t1i I
application of thallium. be developed for the complex compounds'"of tri-
valent thallium.. These must be simple, rapid, and accurrate, aann must
eliminate the shortcomings of the methods available at present.
K. B., Yatsimirskiy and N, 1,, Bashilova (Refs. 56; 57) are mentioned,. There
are 280 references: 96 Soviet..
ASSOCIATIONs Khimicheskiy fakulltet, Moskov3kiy gosudarstvennyy universitet
im. M. V. Lomcnosova (Department of Chemistry, Moscow State
University imeni M. V. Lomonosov)
Card

BUSEV, A.I.; TIPSOVA, V.G.
Determination of thallium in its antimon7, arsenic, and phosphorus
allo7s. Izv.vys.ucheb.zav.; khim.i khim tekh. 3 no.1:69-71 160.
(MIRA 13:6)
1. Kafedra analitichaskoy khimii Moskovskogo gosudaretvannogo
universiteta imeni M.V.Lomonosova.
(Thallium alloyp)
(Thallium-Analysis)

BUSEV, A,L; TIPTSOVA, T.G.; SOKOLOVA, T.A.
- --------
Reactioa of trivalent thallium with disodium e thylenediami ne tetra-
acetate.. Zhur. neorg. khim. 5 no. 12:2749-2758 D 160.
(MIRA 13:12)
1. 14ookovokiy oeudarstvennyy univeraltet imoni M.V. Lomonosova.
Mallium compounds) (Acetic acid)

BUSEV, A.I.;-TIPTSOVA, V.G.; 'T.A.
Stability consta.-its of chloridc- ~~.,.,d I-rcmide complexes of trivalent
thalliuri. Von-U. 1,oLk. ur. Ser. 2:1,2-11-5 1:-D 160s (I"I'A 14:2)
i
1. I(afedra analiticheskoy !:1,' L,'J i "Icalcovskogo universiteta.
(T.,.aaIiw-.i

1 EXPLOITATION vo
7/5777
A. P., Acadcaajc~arj, and D. 1. Ryabchikov, Doctor or
L;ulcneea, llvofe3~;ui~ Reap. Us.
1-2-Lody opred-~lcnlya 1 analiza redkilldi clementov (Methoda for the
D~;-ot,-Uon and Analynis oC Rare Eleracnts) ;,',aBcow, Izd-vo All SSSR,
11,1'vrata alip in3erted. 6000 copies printed.
Aj~ezicy: Akadenlya nauk SSSR, Inatitut gcolchimii I
anallticheolcoy ichimil im. V. I. Vcrnadslcogo.
of PublizhinS House: M. P. Volyncts; Tech. Ed.: 0. Gus,kova.
L. U;~; OS-`7: ThI3 book is Intended for analytical chemists and for
ztudentG of analytical che.-idstry.
COVE~-%GE: T'hc handbook ;,= published in accordance with a decision
,~!* ti-,c Vz;tsoyu-noye soveshchaniye po analizu redkilch eleraentov
(Ail'-Union, ConKrence an the Analysis of Rare Elements) called

IY
Methodf! 'at, the Di~tection (Cont. SOV/5777
to~etber by the Goz:udoL_-,-,tvenn- nauchno-tc!-:hniche:;*ciy vcnitc-'.
jy
Soveta !Unl3trov S"SR (State Scicntific and Technical Committee
of the Council of 1111113tevo of the U~,'-' ) and the Aca"emy of
Sciences USS11 in'D:!ceT,-,bor, 1959. The, aterial io avrangod In
accordance with the group position of elements in the periodic
qyste,m, and each section 13 prefaced by an article dlacuooing
the analytical methods most used in the Soviet and non-Soviet
countries. Each section deals with the physical, phy3icochcmical,
and chemical methods for the analysis of raw materials, seni-
products, and pure m,~taia, and is aaccompanied by an eyton*ive
bibliography listing Works publiched in the field In recent years.
The following are mentioned for thair help in preparinG the book
for publication: I. P. Alimarin, G. 11. Bilimovich, A. I. Bu-.Ov,
E. Ye. Vayn3hteyn, 1-1. P. Volynctz, V. G. Goryushina, A. M. Dymov,
S. V. Yellnoon, 0. Ye. Zvyagintsev, G. M. Kolosova, Ye. K.
Korchemnaya, V. I. Lebadev, G. A. 11-lalofcyeva, B. 11. Valentlyev,
V. A. Nazzarenko, 1. 1. Nazarenko, T. V. Petrova, N. S. Pojuekto'V,
A. I. Ponomarev, V. A. RyabukhIn, N. S. Stroganova, and Yu. A.
Chernikbov.
Card 2/5

Vathods for the Detection (cont. SOV/5777
Analytical Chezilst ry of the Rare Earth Elements, Scandlura and
Yttrium 128,
Buoev, A. I., and V. 0. aptaova. Present State of the Analytical
Chemistry of ThallT'u6jmT-_ 182
Bu3evp A. I., and L. M. Skreblcova. Present State of the Analyti-
cal Chemistry of Gallium 201
Melent '~-,v, B. N., and A. I. Ponomarov. Present State of the An-
alytical Chemistry of Titani= 238
Yelinzon, S. V. Present State of the Analytical Chemistry of
Zirconium and ITafnium 303
Ryabehikov, D. I,, and D. 1. Korchemnaya. Present State of the
Analytical Chemistry of Thorium. 374
Card 4/5

6,.,~t..Od3 fOr the Datection (Cont. SOV/5777
V. 11. Pre--ant Stattc of t~,.o 1.~%lytical Ch-- . y of
C --~ r,7,n-" U Lin; 1100
Zolotavin, V. L. Present State of the Analytical Chomi.3try of
Vana~Uun 462
Altr;larin, 1. P., P ;nd 0. 11. D111j.-wich. Pronent State of the
Pnalytical Chemistry of Tantaluia and 1,11obitmi 467
Du-;ev, A. 1. Preoent Statoof the Analytical Chemistry of
1"OlybdIenum 537
Troltskaya, 14. 1. Preucnt State of the Analytical Chemistry of
Selenium and Tellurium 580
Ryabchlkov, D. I., and Yu. B. Gerlit. Present State of the
Analytical Chemistry of Rhanium 628
AVAILABLE: Library of Congrosa
JA/raeec
Card 5/5 12-1- 1
-- -------- -----

S/07 5/61/016/00 5/002/007
B106/B208
AUTHORS: Busev, A. I., and Tiptsova, V. G.
TITLEt Studies in the field of analytical chemistry of thallium.
Report no. 6. New complexometric methods of thallium deter-
mination
PERIODICAL: Zhurnal analiticheskoy khimii, v. 16, no. 3, 1961, 275-278
TEXT: The authors devised a method of indirect complexometric determination
of trivalent thallium, in which the complexon III excess is back-titrated
with a standard solution of Mohr's salt at 40-600C in the presence of
sulfosalicylic acid as indicator at pH 2. The color changes from yellow-
green to orange-red. This method permits the determination of Tl 3+ in the
2+ 2+ 2+
presence of Cd , Zn , Pb , and 4. O.1MC1 and thus offers more advantage---
than a direct complexometric titration at pH 2. Br- ions interfere with the
determination, as well as Bi, In, Fe, and Cu. Table 1 presents the results
obtained by this method. For a separate determination of trivalent iron
and thallium the fact may be used that at pH 2 trivalent thallium forms a
Card 1/8

S/07 5/61/016/00 3/002/007
Studies in the field B106/B208
stabler complex with Br than with complexon III. Thallium can thua be
masked with bromide ions. Fe 3+ ions quantitatively react with complexon III
under these conditions. 5-10 ml of 2 M KBr solution and so much alcohol
as to attain pH 2 are added to the acid solution containing Fe7/+ and T13+;
trivalent iron is then titrated with complexon III against sulfosalicylic
acid as indicator at 40-600C until the red-brown color disappears. The
solution is then adjusted to pH 4-5 by adding ammonium acetate, and some
drops of a 0.1% solution of pyridylazo-resorcinol or 1-(2-pyridylazo)-2-
naphthol are added as indicator until a distinct red color appears. The
trivalent thallium is now titrated with a complexon III solution until the
color changes to orange-yellow. A distinct change can only be seen if the
iron contents are not too high. This method gives good results (Table 2).
The separate determination of Cu 2+ or B13+ and T13+ is not possible by this
method. For the separate determination of B13+ and T13+' the sum Bi3+ and
T13+ is first determined complexometrically at pH 4-5 (adjusted with ammo-
rJum acetate) against a 0.1% methanolic solution of 1-(2-pyridylazo)-2-
17+
naphthol as indicator, the color changing from red to yellow. T '~ is then
Card 2/8

S/075/61/016/003/002/007
Studies in the field ... B106/B208
reduced to Tl+ by Na 2SO 3* A certain amount of complexon III is thus set
free which is back-titrated with a standard solution of Cu(NO 02 (color
change from yellow to red-violet). This method gives very good results,
especially in the case of high thallium contents (Table 3). To determine
the end point of the direct complexometric thallium titration, the reaction
of the iodide complexes of trivalent thallium with complexon III may be
used, which proceeds quantitatively at pH 6-8. Starch may be used as indi-
cator; as long as thallium ions are present in the solution, which are not
bound in the form of the complexonate, i.e., as long as TlI 4 ions exist in
the presence of I also the ion I is present which colors the starch blue.
3
In the end point of the direct thallipm titration the blue color disappears.
Some ml of 1 M tartaric acid solution and so much NH 40R are added to the
solution to be analyzed (3-50 ml in 80-100 ml) that the color of added
tropaeolin 000 changes from yellow-orange to pinks 1 M tartaric acid solu-
tion is then added until the yellow-orange color appears again. 1 ml of a
1% KI solution is now addedg forming a yellow precipitate. If the precipi-
Card 3/8

3/07 5/61/016/0r) Y,/002/007
Studies in the field ... B106/B208
tate is pink, some further KI has to be added, but not too much, as other-
wise TlI may precipitate. The solution is then titrated with complexon III
until the color changes from an intense yellow to pale-yellow. t%t that
time, some ml of 1% starch solution are added, and titration is continued
until the blue color disappears. Accuracy and reproducibility of this
method are satisfactory (Table 4). At pi[ -;~-,B too low results are obtained,
at pH - 6 too high ones. The method is not selective since many elements
are interfering. There are 4 tables and 9 referencest 3 Soviet-bloc and
6 non-Soviet-bloc. The three references to English-language publications
read as follows: Kinnunen J., Wennerstrand B., Chemyst-Analyst. 46, 92
(1957); Foley W. T., Pottie R. F., Anal. Chem ?.8, 1101 (1956); Reilley C.N.,
Schmidt R. W., Anal. Chem. JO, 947, 953 (1956~-.
ASSOCIATIONt Moskovskiy gosudarstvennyy universitet im. M. V. Lomoriosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED: January 29, 1959
Card 4/8

BUSEV., A. I.,- TIPTOVE, V. G.(Tiptsova, V. G.)
"
Analytic chemistry of thallium. Analele chimie 16 no.1:50-71
Ja-Mr 161. (ERAI 10:9)
(Tha-Ilium)

TIPTSOVA, V.G,
"Methods of organic chemistry- bY Houben-Weyl.
V* G* Tiptsola.
Zhur. anal.khi,,. 16 no. Ple"16wed by
3:379 lify-elle 161.
(Ghemistryp Organic) (MIRA 14:6)
(Houben-Weyl)

S/137/62/O0q/oo4/2oO/2o1
A154/Atoi
AUTHORS: Busev, A. I. Tiptsova, V. 0.
TITLE: The analytical chemistry of thallium to-day
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 4, 1962, 13, abstract 4K81
("Metody opredeleniya i analiza redk. elementov", Moscow, AN SSSR,
1961, 182 - 200)
TEKT: This is a review. A classification of analytical methods of deter-
mining TI is given. Analytical reactions of an ion of univalent Tl and an ion of
trivalent Tl are given. There are 280 references.
I. Golubeva
[Abstracter's note: Complete translation]
Card 1/1

BUSEV, A.I.; U_~TSOVA,-1-G-;, SORDKINA, L.M.
Composition and stability constants of trivalent thallium tartrate
complexes. Zhur,.neorg.khim. 7 no.9:2122-2126 S 162.
(MIRA lll~:q)
1. Moskovskiy gofjudaratvennyy universitet iinoni Lomonosova,
Oliallium compounds) (Tartrates)

BUSEV, A.I.; IVANOV, VJI.; .,TIPTS()VAj__Y.G, -___
Iodate-complexometric method for determining thoriu--. 28
no.7:799-800 162. bUfU 15:6)
1. Moskovskiy gosudarstvermyy universitet im. M.V, Lomonosovae
(Thorium-Analysis)

871-36
1?__73/ )L21~2 9/075/60/015/006/009/01e
C) B020/BO66
AUTHORS: Busev, A. I. and Tiptsova, V. G~
TITLE: Separation and Determination of Gallium by Means of Di-
antipyril-propyl Methane
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No. 6,
pp. 698-700
TEXT: The objective of the present paper was a systematic investigation
of the applicability of gallium precipitation with diantipyril-propyl
methane for separation and quantitative determination. The reagent men-
tioned was earlier (Ref. 2) used for the gravimetric determination of
thallium in the presence of Zn, Cd, Cu, In, Al, and others, in which con-
nection the presence of gallium did not disturb. The precipitation of Ga
with diantipyril-propyl methane starts from a solution in 3 M HC1, and i 'ts
quantitative precipitation takes place from 5.5 - 6 M HC1. Diantipyril
methane and diantipyril-methyl methane do not precipitate Ga quantitative-
ly from hydrochloric acid solutions. The gallium complex of diantipyril-
propyl methane has the composition C 26 H3002N4' HGaC1 4* The accuracy of
analytical results is fully satisfactory (Table 1); besides, the method
Card 1/2

87'. 12,~
Separation and Determination of Gallium S/075/60/O15/oo6/ooq/o1a
by Means of Diantipyril-propyl Methane B020/BO66
is 8imple and does not take much time, since the precipitate is easily
filtrable. The method is highly selective, since the gallium daterminatioc;
is not disturbed by many element fsuch as Zn, Cd, Cu, Al, Ni. Mn, Mg, In
Co, Bi, and others (Table 2). Tl~ and Fe3+ do interfere. The method can
be used for separating gallium from its accompanying elements. FO'~ must
be reduced to Fe2+. After separating gallium by complexing with dianti-
pyril-propyl methane, the determination can be carried out by the complexo-
metric method: the precipitate is filtered, re-washed, and then rinsed
from the filter with water. A few ml of a 5% solution of tartaric acid and
ammonium acetate are added to the solution up to a pH of about 5. After
heating up to 70-800C in the presence of 1-(2-pyridilazo)-2-naphthol, it
is titrated until the color changes from pink to yellow. The results were
completely satisfactory (Table 3). There are 3 tables and 2 referencez;
1 Soviet and I German.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Moscow State University imeni M. V. Lomonosov)
SUBMITTED: August 20, 1959
Card 2/2

TIPTSOVA, V.G.
Conference on the chemistry of rare elements. Zhur.anal.khim. 17
no.1:3 of oover Ja_F '62. (MIRA 15:2)
(Metals, Rare and minor--congresses)

GOLOVINA, A.P.; TIPTSOVAJ V.G.
Photometric determination of thallium with quercetin. Zhur.-
anal.khim. 17 no-4:524-525 Jl 162. (MIRA 15:8)
1. M.V.Lmonosov Moscow State University.
(Thallium--Analysis) (Quereetin)

TIPTSOVA V.G.
"Methods of organic chemistry,* by Haiben-Weyl. Reviewed by
V.G.Tiptsova. Zhur.anal.khim. 17 no.5:647 Ag 162. (MIRA 16:3)
(Chemistry, Organic) (Houben-~eyl)

A. I.;_Tj?!~SOVA V G - HMSTOVA, A. D.
BUSEVY J_ 1_10~ * .9
Present state of the analytical chemistry of tungsten,(Burvey)o
Zav. lab. 28 no.12:1414-3A24 262. (MM 16:1)
(Tungsten-Analysis)

I
.L 00039-66 DIT(m)MC/EW(m)/Z7t.T(.t-)/EwT(b)/M(h) IJP(c) RUdIJD'
ACCESSION NR: APS023711 UR/0075/65/020/008/0812/0814
543.43 s 543.70
AUTHOR: Busev, A. I.; Tiptsova, V. G.; Bogdanova, Ye. S.; And
TITLE: Photometric determination of antimony impurities in tellurium
SOURCE: Zhurnal analiticheskoy khImii, v. 20V.71no. 8. 1965t 812-814
TOPIC TAGSs antimony, tellurium, photometric analysis, dye chemical antimony
compound
ABSTRACT: The antipyrine dye 4,4t-bis(R-methyl-H-benzy1auLnophenyl)autLpyryl-
carbinol
OH
-NI H'
CoHg-H \'CH -C'"6
LC-CHs'
J A-CHO
Curd 1/2

L 00039-~6
ACCESSION HR:" AP5023711
reacts,with SbC16- ions to form a complex which can be completely extracted with
benzen 'e or toleune and has an absorption maximum at 585-590 mp. This reagent was
used to-determine microgram quantities of antimony in tellurium. Prior to the
analysis, the two metals must be separated; the separation is based on the dif-
ference in the redox potentials Sb(III)SbO and Te (IV)TeO, which permits the se-
~lective 'and quantitative reduction of Te(IV) with a mixture of sulffte and hydro-
zine to the elemental state, while Sb(III) remains in solution. If the antimony
content is less than 5X IC4% Sb, the weight of the sample must be Increased to
I g, but bince the precipitation of tellurium would trap some of the antimony, it
is necessary to concentrat%the letter prior to the analysis. Te this end, use
was made of coprecipitatio~ of antimony with telluric acid. The absolute sensi-
tivity of the method is 0.2 pg Sb in 5 ml of benzene, which for a 1 g sample
amount.s to 2 x 16-4. Orig. art. has: 2 tables.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. H. V. Lomonosova (Hoscou
State UnIv6rsity); Moskovskiy institut stali. I splavov oscow Institute c;~- Steel
SUBMITTED: 09Feb65 ENCL: 00 SUR CODE:' GC
NO REF SOV: 003 OTHEM 000

1, 23363-66 raq.,(m) /Frc (f Var-W I ao W IJFW RrV/JD/JG
/0075/65 011/1200,11203
AP6008696 SOURCE CODE: UR
AUTHOR: Tiptsova, V. G. Andreych A. M.; Bazhanova, L. A.
ORG: Moscow Institute of Steel and Alloys (Moskovski institut stali i splavo,,r)
os
TITLE: Spectropbotometric determination of merEury in _~~Ic~niwn by neans of
-naphthyl)thiocarbazone
SOURCE: Zhurnal analiticheskoy khimii, v. 20, no. 11, 1965, 1200-1203
TOPIC TAGS: mercury, selenium, trace analysis, spectrophotometric analysis
ABSTRACT: A simple and highly sensitive method of determining mercury traces in
selenium was developed in connection with the effect exerted on the semiconductinF prd-
perties of selenium by mercurnj in-amounts as low as 10-7_10-9% The complexing apent-1-
2+ 1 1
1,5-bis(B-naphthyl)thiocarbazone--forms a red complex with Hg ions which is extrac- I
table with chloroform. The molar extinction coefficient at 620 mv is (9-03 1 0.27)
104. Mercury can be separated from practically all elements by introducing a masking
agent (complexon III); it can then be determined with a sensitivity of 0.2 Vg/5 ml,
which corresponds to 4-10-6% for a 5 g sample of selenium. The sensitivity of the
determination can be raised to 1-10 6% by using a 1 ml volume of the 1---agent solution
in the final extraction. Orig. art. has: 2 figures, 1 table.
SUB CODE: 07,11/
Cord
SUBM DATE: 12Jun64/
ORIG REF: 008/ OTH REF: 004
UM 543.43 1 543,70

L 1~62 5-66 EWT(d)/EWT(m)/EWP(v)/E*rlP(j)/T/F,'.-[P(k)/F,-~,P(h)/FWP(1)/ETC(in) WW/RiAll
ACC NRs AP60()1002 SOURCE CODE: Ufi/028()/05/000/022/0~)7()/(io7O
AUTHORS% Bogdanov, A. M.; K
ulin, F. I.; Molontlyev, P, M.
T'iranov, V. Go
ORG: none
TITLE: Device for mechanical testing of materials. Class L2, No. 176bbB
SOURCE: Byulletent izobreteniy i tovarnykh znakov, no. 22, 1965, 70
TOPIC TAGS: tensile test, polymer rhoology
ABSTRACT*. This Author CerV .. presents a device for mechanical testing of
c
materials, eog,,, polymei oll extensibility. The device cotitains a system of two
clamps for fastening the material sample. One clamp is fixed and is mechanically
coupled to the force-measuring instrument. The other clamp is movable in the
vertical direction, applies the load to the stretching sample, and is connected to
a device for measuring the sample deformation. To automate t1he process of deformation
measurement, the movable clamp is provided with a contact device and a support for
free placing of the load on the stretching sample. The contact device in the form of
a nut on the screw axle of an electric motor closes the motor circuit when the nut
touches the load descending as a result of the sample stretching, The force-mea3uring
element of the device, in the form of an elastic beam., bendsunder the action of the
OC: 620.72

NRo AP6001002
0
force applied to the upper clamp of the device. A switch on the free end of the
beam closes with a contact fastened to a nut placed on the screw axle of an
electric motor. When the circuit is closed, motion of the nut mounted on the motor
axle continues until the contact is broken$
-:-50 CODE: II/ SUBM DATE t O(Apr64
W
2~2

ACCESSTON MR: APS013500
AUTHOR:
TITLE:
U-.-?,/0075/65/020/005/DS85/0590
543.70
Busev, A. I.; Bogdanova, Ye. S.; Tiptsova, V. G.
Antipyrine dyes as reagents for phototwtric determination of antimony
SOURCE: Zhurnal analiticheskoy khimii, v. 20, no. 5, 1965, 565-590
TOPIC TAGS: antimony, photometry, organic dye, chemical analysis
ABSTRACT: The purpose of this work was to investigate the reactions of pentavaleni.
antimony chloride complexes with the following antipyrine dyes: dimethylamino-
diphen,ila.ritipyryl(~ay-t)inol,
~j-j ;1n
Aii of t-ne
above n~agents r~~-*artp(i -aith SbCl~, icn, prDdl-icing ~av- Ili- pr-cipitates whEn anti-
1n_rkLe_px"__rqrjr_u of ra qu=ti.ti- of
n i`m_on_y__- an6 oU the -solUtion -was - notod,. upon
t
a
-tEe_-ad b oVe-r--aI -_ 64.-h- talned-~Cbftounds aated_vit"U~
gent -T e ~ob___ wo-re-extr
C*ard 1/2

-L 55083-65
ACCESSION NR: APS013500
zene, toluene, and chloroform. The completeness of the extraction of the produced
!compounds depends on the amount of excess re-agent and the acidity cf the solution.
IThe maxiniuin extractior was observed in all cases in 0.5-1 1.1 HCI. By means of isc-
molar series it was established that ShCIG forms complexes with antipyrine dyes in
a 1:1 molar ratio. The complex may be represented by the formula R-HSbCI6, where R
!is a molecule of organic reagent. All of the above reagents are highly sensitive
and sufficiently select-ive for the ~eterminati~,P. of ant -;m!-,ny. The me"hod -leveLoped
for the d -eterminat-'on of Sb was used f.--r 'he of Sb in two samples of
electrolytic copper containing 0.0020 and 0.00080% Sb respectively. Orig. art.
has: 4 tables and 4 figures.
JASSOCIATION- Piaskovskiy gosudarstvennyy universitet im. M. V. Lomonosove (Moscow
IState University); Orenburgskiy sellskakhozyaystvennyy institut (Orenburg Agri-
!cultural Institute)
!SUBMITTED: 12Nov64 ENCL: 00 SUB CODE: GC
NO REr SOV: 010 OTHER: 002
Card 2/2

IJUSEV, A.I.; TIPTSOVAJ,,V.G.; SOKOLOVA, T.A.
Reaction of reduced forms of turgsten with complexon III.
Zhur.neorg.khim. 10 no.8:1857-1861 Ag 165. (MIHA
1. Submitted July 16, 1964.

ALL NK: '0 (Al
AP60129 SOURCE CODE: UR/0075/66/O21/oo4/o459/o462
AUTHOR: Tiptsova, V. G.; Malkina, E. I.; Anisimova, Z. A.
ORG: Moscow I.nstitute of Steels and Alloys (Moskovskiy institute Itali i splavov)
TITLE: Chemical spectrum determination of impurities in mexcuzj
SOURCE: Zhurnal analiticheskoy khimii, v. 21, no. 4, 1966, 459-462
TOPIC TAGS: mercury, fatty alcohol, spectrum determination
ABSTRACT: A study has been made of the use of fatty solvent extraction of mercurjI
from hydrochloric solutions. It was found that isoamyl alcohol is the best ex-
tractant for separating mercury from impurities in 2--3 M HC1. A method for
determining the chemical spectrum was developed for Mg, Mn, Ag, Al Pb Ni Cu,
Ca, Cd, and Zn in mercury with an average sensitivity of 10-6-10-3% for each element]
Orig. art. has: 1 figure and 3 tables. [Based on authors' conclusions.] INT
SUB CODE: 11, 07/ SUBM DATE: 18Dec6h/ ORIG REF: 005/ OTH REF: 003
card 1/1 AL UDC: 543.42

TIRUGIN, V.N.;.VEYTSELI, V.A.; VMIISIIEV, Yu.Kh., kand. tekhn. nauk,,
red.; LYUBIMOVA, T.M., red.; SVESMIIKOV, A.A., tekhn. red.
[Radio control] 11adioupravlenie. Moskva, Izd-vo "Sovetakoe
radio," 1962. 7/+9 p. (MIRA 15:2)
(Guided miBsiles-Radio control)
N

TIFUKHIN, V. 1-1. (Candida:-e of Philosophical Sciences)
ItCybernetics and Labor.1t
Filosofskiye voprosy kibernetiki (Philosophical Problems of Cybernetics),
Publishing House of Socio-Monomic iterature, M03COW, 1961 392 p.

KODYK, G.T~; TIR, D.E.
Joining conveyer belts with steel clamps. Hauch. tnidy
XNIUI no. 11019-331 162. (MA 1727)

BEIENIKIY, D,M.J. kand.tekhn.nauk;.,,TI-R) D. E.
Research on the steel tract-4on ropes of rope conveyers. Vop.
rud. transp. no.3:129-132 1959. (MIRA 14-:4)
1. Karagandinskiy nauchno-iseledovatellskiy ugoltnyy institut.
(Conv'eying machinery)

BELF,NIKIY.,,,. D.M., kand.tekhn.nauk;ITIR, D.E.
Research on the sag of the*conveyer belt of a raps conveyer.
Vop. rud. transp. no.3:3,33-138 1959. (MIRA 14W
1. Karagandinakiy nauchno-isaledovateliskiy ugoltnyy institut.
(Conveying machinery)

TIR, K. V.
K. V. Tir, "Complete Calculations of Cam klechanisms.if
P6PW PM404Ud at the 2nd All-Union CW. on pundarantal problacm in the
TMI Ory of VAChIfts and ~b~anisw, n"cov, LIMP 24-28 mmruh iM,

124-58-9-9531
Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 9, p 11 (USSR)
AUT14OR: Tir, K. V.
TITLE: Comparative Analysis of the Qualitative Characteristics of the
Fundamental Laws of Periodic Motion (Sravnitel'nyy analiz
kachestvennykh kharakteristik iskhodnykh zakonov periodiche-
skogo dvizheniya)
PERIODICAL: Nauchn. zap. In-ta mashinoved. i avtomatiki AN UkrSSR,
1955, Vol. 4. Ser. mashinoved. , Nr 3, pp 72-99
ABSTRACT: Bibliographic entry
1. Motion--Analysis 2. Mechanics--Theory
Card 1/1

124-58-6-6341
Translation from: Referativnyy zhurnal, Mekhanika, 1958, Nr 6, p 8 (USSR)
AUTHOR: T i r, K. V.
TITLE: A Synthesis and-Qualitative Evaluation of the Combined Laws of
Periodic Motion (Sintez i kachestvennaya otsenka kombinirovan-
nylch zakonov periodicheskogo dvizheniya)
PERIODICAL: Nauchn. zap. In-ta mashinoved. i avtomatiki AN UkrSSR,
1956, Vol 5, pp 126-140
ABSTRACT: Bibliographic entry
1. Dynamics
Card 1/1

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I )-I - ~ A - 9 - ()r) i0
Translation from: Referat~tnyy zhu!-nal, Mckhanika, 1958, Nr 9, p 11 (USSR)
AUTHOR: Tir, K V
TITLE: A Clatsification Chart of the Laws of Periodic Motion According
to Peak Veloc ties and Accelerations (eI.3--eI3 tw) [ Karta
klas~ifikatsii zakonov periodicheskogo dvizhenlya po pikarn. skoro--
stey i uskoreniy (e 13--13 Sw) I
PERIODICAL: Nauchn, zap, In-ta mashinoved. i avtomatiki. AN UkrSSR.
1957, Vol 6: pp 152- 167
ABSTR ACT: Every periodic motion under examination can be represented
on the xy plane at a point the coordinates of which are
x = ST' 2/wm and y = ST_ 1 /v, , where S is the given finite
displacement, T is the duration of the cycle of a distinct
displacement: and v and w are the respective maximal
values of the velocity and the acceleration. Motions having
different characteristics are collected into grOLIP5 which can
be represented by lines on diagrams. Inasmuch as the
characterization of periodic motions by means of points is
exceedingly schematic, it is recommended that a more pro-
found classification of such motions be obtained by recourse
Card 1/1 to additional criteria. S. G. Kislitsyn
1. Mechanics--Theory 2. Motion--Mathematical analysis
3. Mathematics--Applications

T K F T T I I I T.-.
t
11 1 F 1; ~; t: IA L 1: 1 E
1: C I ! IN A Y A N", I' V A jA NUAW(-Ejt~ r

- TIR, K.V.
Nato"
Comparative sinalysis of qualitative characteristics of initial
laws for periodic motion. Nauch.Zap.INA AN UMM Ser.mashinoved. 4
no.3:72-99 '55. OaA 9:8)
(Kinematics)

TIR, Konstentin Vadimovich; VIKSKAH, Yefim Samoylovich; NEZNAMOVA,
Ye.H., red.; ITANOTA, L.A., tekha.red.
[Organizing the maintenance of printing equipment] Organizateiia
tekhnichaskoi ekBpluatetaii pollgrafichaskogo oboradovaniia.
Koskva, Gos.izd-vo "Iskusstvo." 1959. 377 p. (MIRA 13:6)
(Printing machinery and supplies--Kaintenance and repair)

TIR.K.V.
Qualitative evaluation criteria and classification of the laws of
periodic motions. Nsuch.zap. IMA LIviv fil. AN URSR- Ser.mash-3
no.2:80-99 '54. (MLRA 8:11)
(Kinematics)

T j R I rt, V_
TIR. X.Y.; RABINOVICH, M.B.; ZHOVDAK, A.V.
(Time norms for repair work on stop-cylinder and platen presses].
Normy vremeni na. remont plookikh mashin s ostanaylivaiushchimmis
pechatnym toilindrom i tigellnykh mashin. Moskva, Iskusetvo, 1953.
176 p. (MLRA 7:6)
(Printing press)

L tL,106, -i 5 ZWT1 ( M ',"-;'WP k +4F!- b JD
_7_ . :_ - ..- _1
PTESSTMI NP: AP 50 2 1
AUTHOR:
N, 1 7R F,2
TITIE : An elertri c f lirn;icp f T.--'! t inp, pljr- -1 1 q.
SOULICE : 13yulleten' izobreteniy i t~_-,arnykh zrinakt-v, n,,
TOPIC TAGS: metal melting, metal purification, induction melting, metallurgic fur-
nace
ABSTRACT: This Author's Certificate introduces an electric furnace for melting
pure metals. The unit contains a crucibl,~- which is transDarent to magnetic fields.
Provision is made for kt-eT;n,7 the m-i] 1,.- w,31~~ ~-F th- cruciMe qc
tnat the metal will Tic, be _-f~,,nfam~na-" I, The c~rucil~le ;,s
surrounded by an inductj~.,n ccdl wlith in ;:.n n: r vn i n. f7. -~c ve s cre-n. wh 1:-h dc~-s
not conta'_-t the Mel~ and ln~~f i-. -I, I'_
ASSOCIATION: Vsesnvuznvv nauchnn- i -,~. Ir- i" iT-,'; i I'lt e !~,ktrot,-rmi i r-heskogo
obnrudovaniva
Card

L 65io6-65
i ACCESSION NR: AP5021977 ~D
SUBMITTED: 27D-ec62 ENCL- 00 SUB CODE' IE, MM
146 REr SOV: 000 OTHER* 000
.I
Card 212 .

TIR, L.L.0 kand.tekhn.nauk; SHEPELYAKOVSKIY, K.Z., kand.tekhn.nauk
New trandformeris for high-frequency hardening equipment. Trudy
Sek.metalloved.i terr..obr.met.?1TO mash.prom. no.2:220-228 160.
(Induction hardening) (Electric tranaformers) OfEu 14:4)

GUMat~Wj KqDo j inzh, j, red*; BORUNOV, N.J.,
4-7~w tekhn,red,
[Transformers for highfrequency induction beating systems]
Transformatory dlia ustanovok induktsionnogo nagreva povyshennoi
chastoty. Moskva, Gosenergizd-voq 1961. 238 P.
(Electric transformers) (MIRA W6)
(Induction heating)

PHASE I BOOK EXPLOITATION 30"457
NaUChno-takhniche5koye obshchestvo mas.Unoatroitallnoy promyshlen-
coati. Saktaiya mateLljovedenlya I termIcheskoy obrabotki metal-
lov.
Metallovedeniye I termicheakaya obrabotka metallov; trudy Sektall
matallovedenlya I term1cheskoy obrabotkI metallov (Physical
Metallurgy and Heat Treatment of Metals; Transactions or the
Section of Physical Metallurgy and Heat Traat:ment of Metals)
no. 2.Moscow, Mashgiz, 1960. 242 p. 6,000 "ple3 printed.
Sponsoring Agency: Nauohno-takhnichaskaye obahabextvo
anshinostroltallnoy pronyahlennosti. T,3entrallnoys pravlenlye.
Editorial Boardt 0. 1. Pagodin-Alekseyev, Yj. A. Geller, A. 0.
Rakhahtadt. and 0. K. Shreyber; Ed. of Publishing Housaz 1. 1.
lAcnichanko; Tech. Ed.: , B. 1. Model,; Manaang Ed. for Litera-
ture on Metalworking and Machine-Tool Making: V. 1. Mitin.
rMOSE: This colleation of articles Is Intended for metallurgists,
mechanical engineers, and scientific research workers.
COV]UUGE: The collection contains articles describing results
or research conducted by members of NTO (Scientific Technical
Society) of the machIne-building Inlustry In -he field of
physical metallurgy, and in the heat treatment of steel. cast
Iron,and nonferrous metals and alloys. No personalities a.-*
mentioned. Most of articles are aczc=panlad by Soviet and non-
Soviet references and contain con-l'zolons drawn frem InVe3ti-
gatlons.
TABLE OF CONTENTS:
Elanter, K. Ye., Doctor of Technical Sciences, Professor, and
L. 1. MA=etaov and L. A. Metashop, Engineers. softening and
Raer7stalllzation Promesaes In Iran and Nickel Alloys 3
Trunin, 1. 1., Engineer. F-Ifect of Cold-Working Conditions on
the JDndurance of Steel 12
I
bsrnzh~~e. M. L.. Candidate of Tec~nical Sciences, and L. V.
Polyann!kaya, Engineer. Effect of Cold Isiork-Ing cn the Structure
and Properties of the V112 Titaniun Alloy - is
X1d1n__j. N., Doctor of Technical Scieice3, Professor. On the
Reasons for the Improvement of Iron-kl_105~ P=par-.Ies Af'ter High-
Frequency Qjench Hardening 25
Zakh-~va 1!. 1- Doctor of Physics and Mathematics. Professor.
Conditions for the 3iVz&-Ph&Be Formation In Alloys 39
Zakharova, M. 1. Structural Transformations in Highly Coarclit
Alloys 52
Pogod1.n-Alekseye_vQ_I., Doctor of TachnicAl Science etas 310 r..nd
Candidate of Technical Sciences jA.Prcf:d
i??.ot r the Microstracture on the Development of Reversible
Temper-BrIttlenes3 In rAw-Carbon Manganese Steel 59
Pogr~Lj&-Alekseyeva? K. M., Candidate or Techn.4oaX Sciences. Docent.
-Eff,ji6t~-cif-Somi Katalluigical Factors on Strain Aging of Conatrua-
tional Carbon Steel 6T
B M P., Doctor of Technical Sciences. Proresacr# and E. 1.
Engineer. In-waing tne Preheating Temperaturle In Forging

Physical Metallurgy and Heat Treatment (Cont. SOV/5457 17
Cpnetructional Alloy Steals 84
Lakhtin, Yu. 4., Doctor of Technical Sciences, Professor, and
X7_A_._P_QN_81)_Cinb, Engineer. Gas Baronizzing of Steel 92
XInkovigh, A~B.s Candidate of Technical Sciences, and A. W.
XQE-O-IEngineer. Thermochemical Tr-aatmant of copper and M~aza
&;-In'.rea3ing Thair Surface Haminess and scale Resistance 106
Makhimoy, D. M., Candidate of Technical Scl4nces. The Forma-
tT*_n__o_r-C_r_&cVa_ During the Quench Hardd.-.'Ing of Steel and Their
Prevention Lis
t, A. G., Candidate of Technical Sciences, Docent, and
.Vaht=aa t~iFEv_
Engineer. Transformation, Properties, and
T16eM`md_nt_-5.7-A'Iloys of the Cu-NI-Mn System Used fat- Springs I"
KallnUina. Yo. I., Candidate or Tochninal Sciences. Determl-
MAtIon 70f Cyr. tIonal Properties of Tool Steels and Alloys 260
Culyayev A P., Doctor of Technical Sciences, Profeasor. S. L
Ru3t;W.~ ~an_ate of Technical Sciences, Docent G_K. Orekhov,
St.. I -_ ____bf
ahd iP. Al.kayela, Engineers. He. Is for Die Vorgins
279
Geller, Yu. A., Doctor of Technical Sciences. Professor, Te. M.
IWIMRI'n ~.d V. H. Lomakin, Engineer, Hardenability of Alloyc4
19T
L. Candidate or Technical Sciences, and K. Z. Shep2lyakov_
.1 Transformare for Hish-Prequency
INZI-1-MLIfons 220
Pogodin-AlekBeysv, G. I., and V, V. Zabolayev-Zqtov. Effect or
Ultrasonics on the Struature-Fdt-m-NtTo-n-Pr-oceiiin in-Metal Alloys 229
AVAXLI=: Library bf Congre so TN6 72. N3 4)

-01-k-
TIR, L. L. Cand Tech Sci -- "Development and study of ~ method of 'dispersal'
of V& ~mateirial _indiffjfor the reduction of energy losses in stepped-up-
frequency transformers hardening plants." Mos, 1961 (Min of Higher and
Seepndary Speoialized Education RSFSR. Mos Order of Lenin Power Engineering
Inst). (KL, 4-61, 201)

_IR ~_, k.
T I
TIR, L.L,, inzh.
VWAW4~111 zt,-"Op" V-~~
quency
Voltage transformation in high-fre
installations. Vest.elektroprom. 28 no.8:40-43 Ag '57. (MIRA 10:10)
metal hardening
1.0soboye konstruktorskoye byuro tresta "Elektrpechl."
(Metal--Hardening)

TIRj Yeon L _J.Ch. nzh.
_ AMray __I_
Study of losses and current distribution in alternating disc
windings of transformers at increased freauencies. Izv. VY9.
ucheb. zav.; elektromkh. 3 no.7:22-15 160. (MIRA 11:9)
1. 11achallnik nauchno-Ims1ndovatallskogo sektora otdela
indvdctaionnogo nagreva osobopo konstruktorskogo byuro 'BlektroDech'."
(Electric traneformers--Windings)

L 32160-66 EWT(m)/HWP-(t)ZET1_-IJ-P~c.) __-JD-,.
ACC NR~ AP6011522 SOURCE CODE: UR/0382/66/000/001/0137/0141
AUTHOR: Dragunkina, N. I.; Tir, L. L. ;L
iORG: none
1TITLE: Experimental investigation of the conditions of similarity of the melt flow
~in an induction furnace,(),
SOURCE: 'eiagnitnaya gidrodinamika, no. 1, 1966, 137-141
TOPIC TAGS: induction furnace, induction melting r4oc.0
J
ABSTRACT; Experimental measurements describing the behavibr of aluminIzAn induction
furnaces are used to clarify the significance of the various criteria, especially the
relative frequency and gravitation, needed in establishing similarity conditions. The
range of data is sufficiently broad for use in the design of steel furnaces. It has
been found that in a range of frequencies from 50 to 2500 Hz the effects of viscosity
can be neglected provided the Reynolds number of the flow exceeds 20,~", which is the
case in many aluminum, steel and lead furnaces. The effect of gravitation was found t
be small except in cases where a large meniscus occurs. Dependence of the flow veloci
ty on the meniscus height was measured and shown to reach a maximum of 15% reduction o
the flow computed without taking gravitation into account. It is shown that flow velo
city is not strongly dependent on the amount of heaT circulation. Somewhat different
UDC: 621.365.5:538.4
Card 1/2

L 32160-66
ACC NR: A
effects were found in models of inductors with parallel sections. Engineer L. K.
Chentsova also took part in the work. Orig. art. has: 4 figures.
SUB CODE: 20,11/ SUBM DATE: 25May65/ ORIG REr: 002

for k" WbMe predDIWIln, S, Tira
(Ric. ppt". of l1beqww"O'e-
licl at'20, o=uffed at pH 0.5 In PbCJ, ackition suid at pH 0.03 itL
Ph acitite solution, Fricke and garnmet's method (Z amil. Ckem..
1943. IN. 13) -as used to ~timate the i-jCl, remaining ir. colution.
- --- -- - - -~ADMAMa

MOROV, Yu.M.; PANGHWOV, G.M.; ZROTSER, S~P.j TTRUITAN, Ya.A.
Ylivelopment of the mt,hematinal desoription of platforming for
optimir,ation of a process. Part ls, Kin. i kate 6 no. 6:1092-
1097 N-D 165 (m:ru. 19 ti)
Is MoakovoMy Inatitut neftekhimithookoy I gazovoy y---omysblen-
nostl imani ChibUna. Subnitted June 2% 196A.

'034-66 EWT~m)/EWP(j)/T WE/RM
2~
-
ACC NRs AP6012991 SOURCE CODE., UR/0065/65/000/0a/0012/oolq
AUTHOR: Zh'orov, Yu. M.; Pan henkov Yu. A.
~~~~G. M..- Zelltser, S. P.; Tiraklyan
ORG: 110MI i GP
'
TITLE, Heat of reaction in catalytic reformin
of gasoline fractions
SOURCE; Khiniya i tekhnologiya topliv i uirisel' no. 1, 1965, 12-16
;roPIC TAGS: heat of reaction, heptane, aromat-ic hydrocarbon, napthalene, crude
petroleum
AB3TRACT: In previous studies an cripirical equation has been sug-
gested for the determtnation of the heat of reaction of hydroform-
Ing:
q 298 = (4-5 al + 5-36aa + 5.45b) - ~c
q298 = heat of reaction at 2980C, kcal/ke;, a I a2, c. b
yields of armatic hydrocarbons from naphthenes a~~ paraffins, gas
and coke respectively (in pr cent weight of crude material); '~ =
coefficient, depending on gas composition and varying from 2.5 to
3.2. The heat of reaction of hydrocraoking of heptanelealculated
from this equation and the actual value are 32 aEd75F?_1kcal/kg, re-
spectively. Thus calculation by this equation Is substantially
in*error. In addition, this equation cannot be used in determin-
Card 1/2 UDC: _66.092 665.521.2
Z
T
60.

L 22084-66
ACC NR. AP6012991
0
ing the heat of reaction of the process under industrial conditions,
that Is, In 5000C. The empirical derivation of this equation casts
doubt on Its possible use In qualitative description of the plat-
.forming process. Accordingly, the authors developed an analytical
[method of determining heat of the reaction in catalytic reforming
,based on a kinetic scheme of the process, affording determination
tof heat of reaction with considerably greater accuracy than other
,methods. The crude material usually contains a slight amount of
!olefins, which upon further analysis is united with the paraffins.
.The possibility of calculatIng the heat of reaction of the complex
,technical mixture of hydrocarbons with different molecular weights
''and boilin %,
g points according to the scheme preseiitc~ft in the article
-is accounted for by the fact that the molar heat of reaction of any
i
:of the reactions examined depends 9. little on the molecular weight*',
of -the crude material. In hydroreforming of heptane, the heat of
reaction is +10.5 kcal/kg, In platforming of hep~ane with near
,conversion-- + 231 kcal/kg. The h t of reaction of hydroforming
fu:a
of different technical forms of depending on naphthene content
in crude according to data given can vary from 40 to 160 koal/kgl
and the values for platforming - trom ~6 to 200 kcal/kg. Orig. art. has:
16 formulas and 3 tables. [JFRS]
SUB OODE: .3-1, 07. SUMI DATE: none ORIG WF: 010 on IMF 1 001
Card 2/2 OL&

DELYATITSKAYA, R.Ya.
CHERNOBAY, A.V.; DMITIMMSKAYA, L.I.; TIRA~~'Y
Stri.icture and reacti-v-1ty of monomers of the 4-vlnyllblph~enyl earies
in the initiation of polymerization. Vysokom.sood. 7 no.7:1221-1227
il 165. (MIRA 18:8)
1. Nauchno-issledovatellskiy institut monokristallov.

OUR CODE*i---UR-/019-07667008/006-/Ug
AF0019536 S CE
AUTHORS: Chernobay A V.; Tiraklyants, Zh. S.; Delyatitskaya, R. a.
ORG: All-Union Scientific Research Institute of Single Crystals
(Vsesoyuznyy nauchno -is s 17ed6vat 61' skiy Axis fituf fiionokristaildv)'_~."
TITLE: Structure and reactivity of some vinyl aromatic monomers in
initiated polymerizationj
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no,6, 1966, 997-1002
TOPIC TAGS: monomer, polymerization initiator, polysterene, copoly-
merization, homopolymerization
ABSTRACT: The relation between structure and reactivity of some vinyl
aromatic monomers in initiated polymerization has been investigated.
The monomers are arranged by their activeness in homopolymerization as
follows: 9-vipy1bnthrac-entej-C acenaDhth4ene'l < vinylnaphthalene , styrene <
N < _1rjnY_1d .I The copoly-
2-,vinylnaphthalene 2-v ifluorenel < 4-_~ iphenyl
merization constants of styrenewith 9- vinylanthracene have been deter-
mined to be rl a 0,3 and"r2 - 2.2., Q = 2.0 and 0' = -0.16 It has been
1/2
UDC: 66.095.26 + 678-746