SCIENTIFIC ABSTRACT TALALYEV, YE.V. - TALALAYEVA, T.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001754730001-3
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 1
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

G'~;nor_-.I and Zoology. Insocts. Insocts
and 1'_.raclinids. Biologic,-,tl ----thod of !-Jontrolling
ins,ets and Z,'~rach_nids.
.i-.bs lour: Rof Zhur-Biol., No 21, 1956, 96613.
.~4uthor Talalayov, YO. V4
Inst ildE_ -glvcn.
Titlo Reproduction of 3pizoctic Sopticcraia in Cator-
Dillars of the -Siborian 3ilkworm.
Orig Pub: Zntoinol. obozroniyo, 1957, 36, No 4, 845-859.
Abstraot: x". s,:;ction of young c-_~dar plantinSs was artifi-
cially infestod with spores of 3~icillus dendro-
limus. -1-Aborian silkworm cator-oill-.rs of the
IV-V g~,nor-itions wore rol,;ascd on th-1 section
in the sLL-.i-,-.i.Qr of 19'34, ~-,.nd cat,~r,_)illlrs of tho
V-VI T --.n,-) r--,. t ions wc;ro r~l&ascd in the spring of
1~55 flight y,:;ar) Th--so 3x-)oriiu~-nts domon-
Card 1/3

Ganoral nd Sp~~ci-f'l Z00109Y. Ins-cts. Ins,~~cts p
-1 '*~Ahod of Controlling
ind .;r-.chnids. Biological
Ins,-cts and z~r-chnids.
Abs Jour: Raf Zhur-Biol,,.Nd 21i 1958, 95613.
Abstract: of s,~;condary infostation of tho larvao. ThD
location of tho cocoons in th.- upp-r stratum
of th-~, crowns vias chifly rosponsible for th,-,t.
-- 3. 1,1'. Gorsh,~nzon.

TALAIAYEV, Ye. V. (Irkutsk)
Bacteriological method for controlling the tent caterpilla?*
Dendrolimus sibiricus. Zashc:h. rast. ot vred. i bol. 6 no.61
20-22 je 161. (MIRA 16:4)
1. Zaveduyushchiy kafedroy fiziologii i mikrobiologii Irkutskogo
universiteta.
(Tent caterpillars-Biological control)
(Bacillus Dendrolimus)

TAiAIAT-V. Y--,VL, kard.biolog,nnuk
Let's exterminaie t-e '. 'De~dro-7--as
~az,--n 5-PPI-15:" " -
Priroda 51 no.2.--79-83 F 162-. (.'--!I-iA 15:2 )
1. Irkutskiy gosudarstvennyy universite'u.
(Tent caterpillars)

LfAYEVA
"ReactLon of ~lhe Strama of Stomach and Duode=n in Ulcerous Diseases." Cand
'irs t" T 1 T T~ 0
-,,ed -ici2 r Moscoa Med-l-ca Inst, Moscow, 1953. (R-7h3liol) if 3, Oct 54)
Survey of Scientific and Tec~unical Dissertations Defended at USSR Hisher
Educational Institutions (10)
Sri: S,,im. No. 431, 5 `iay 55

~YCT__~RPTA Sec 16 Vol- 5/7 Cancor JulY 57
g I le*0111voola of th'. Stornach with 171:11-
2697.
trxt) Arkli. Patol. 19.57, 19/1 (78) 4
A 52-year-old man developed nausca, epigastric pain, weight l(rs and weaki-irss
9 yr. prior to death. Four years after tile onset of these symptoms a turnour in the
greater curvature of tile stomach was diagnosed roentgenologically and a gastric
resection was pt-rl'Ormed. At that time a metastatic nodule was found in the omen-
tuin. For several years the patient's condition remained satisfactory, but eventually
lie developed pro ~~ressive cachexia an.d jaundice, and finally he expired. Autopsy
revealed metastatic lciomyosarcoma in the liver, kidnevs, adrenals, lungs, heart,
retroperitoneal and omental lymph nodes, and in the sl~eletal systeni. The author
points out that Iciomyosarcoma of the stomach is a rare neoplasm constituting not

2 (5,iq /
ovcr 0.5-2% of all primary cancers of the stomach, Of 380 gastric sarcomas re-
ported in the world literature until 1936 only 9.5% had been diagnosed as Iciomyo-
sarcomas. Wilson - Dearborn, Mich.

BAYANDINA, S.A.; ISAYEVA, L.P-, TALALAnVA, A.V.-, R-AL1,U-CaE;A, Z..-.!
KONOPIEVA, A.V.
Clinicil picture and outceme of acute dissezinated !-UP--s erythenatesus.
Pediatriia 37 no.1.76-83 ja ~59- (MMA 12:1)
1. 1z kliniki detskikh bolezney (dir. - deystvitellnyl chlen Awl
SSSR prof. Yu.F. Domborvskaya) i kafedry patologicheskoy anatomii
(zav. - chlen-korrespondent At-III SSSR prof. A.I. Strukov) I Moskov-
skogo ordena Lenina meditsinskogo instituta.
(LUPUS ERYTHEMATOSUS, DISSEMINATED, in inf. & child
acute, clin. picture & outcome (Rus))

\1
GVEKINA, A,V.; TAIALA~EVA, _A,lV, -
Fluoreacence cytological method for detecting caijoer ca-Us in
the lymph nodes. Vo . onk. 6 no.1;74-79 Ap 160. NIA 140)
p A+
(LDTHATICS-GAINCER)

VASILENKO, N. V. , nauchnyy sotrud.; TALALAYEVA, A. V., ~-and. med. nauk
Gancer of the larynx in a D-yanr-old boy. VeBt. atorin. no.4:
93-95 161. (MIRA 15:2)
1. Iz otdeleniya bolezney ukha, gorla i nosa (?;ay. - Prof. D. I.
Zimont(deceasedl) patologoanatomicheakogo otdela (zav. - kandidat,
meditsinskikh nauk Z. V. Gollbert') Onkologicheskogo instituta
imeni P. A. Gertsena, (nauchnyy rukovoditell - deystvitellnyy
chlen 9fif SSSR prof. A. I. Savitskiy), Moskva.
(LARYNX-CPUNCER)

SILINAY I.G.; TALAUYEVA, A.V.
Pseudot-,=-or of the costal cartilage (Tietze s7n-4-cme). Vop.
onk. 7 no.2:,54-60 161. a-: JO
(RIBS-DISEASES)

ASNIN, D. I.; T.UALAYEVA, A. V. (Moskva)
Lysis of hyphae of Actinomyces in tissues of patien-Ls with
actinomycosis. Arkh. pat. no-9-47-50 161. (MIRA 15:6)
1. Iz otdola borlby a aktinomikozom Instituta meditsinskoy
parazitologii i tropicheskoy mediteirq imeni Ye. I. Hartsinovskogo
(dir. - daystvitellnyy chlen AMN -SSR prof. P. G. Sergiyev) i
patologoanatomicheskogo otdeleniya (zav. - kandidat meditsinskikh
nauk Z- U- Gollbert) Gosudarstvennogo onkologicheskogo instituta
imeni P, A. Gertsena (dir. - -orof. A. N. Novikov)
(ACTINNYCOSIS)

TALALAYEVA, A. V., kan& med. nailk; FIIATOV.A, A. M.
Sarcomas of the par-ametrium. Akush. i gin. 38 no.3:7M1
My-je 162. (MIR-A .15:6)
1. Iz ginekologicheakogo otdeleniya (zav. - Prof. L. A. Novikova)
i patologoanatomichaskogo otdeleni7a (zav,, - kandidat meditsinski)~
nauk Z. V. Gollbert) Gosudaristvannogo onkologichaskogo instituta
imeni P. A. Gerteena (dir. - Prof. A. N. Novikov)
(UTERUS-CARCER)

TAULLAYEVA, A.V. (Moskva); ASNIN, D.I. (Moskva)
Diagnosis of actinomycosis in "Issues. Arkh. pat. nc~.'It7-74
164. (MIRA 18~11)
1. Otdel bortby s aktinomikozom Instituta meditsinskoy para-
ziLologil i tropicheskoy meditsiny imeni Ye. 1. Martsinovskogo
(direktor - deystv-itellnyy chlen AMN SSSR prof. P.G. Sergiyev)
i patoloEo,natomicheskoye otdeleniye (zav. - kand. med. nauk ZIS,
Gollbert) Gosudarstvennogo onkologicheskogo instituta imeni P.-k-
Gertsena (Direktor - prof. k.N. Novikov).

TALALAY'E',,'Al A.V.; KAMIU]V) Fdi.
ChemiGdectorlas of the stc,,mach. Vop. onk. 11 nc,.~:3-0
1. lz ~atologoanatomicheskogo otdelerdya (zav. k-and,.med.n-wA Z.V.
Gcl'berf.) i I!I khirun:richeskogo otdeleniva (zav. - dok--or med.nauk
Gosudarstvennozo onkolocicheskoc-o instlvim 2--.eni
A.1 .2azlnenova)
Gerlsena (dir - prc-f. A.N.Ilovikov), ',SDs-kva.

e., jz- p
t LU, S TAL A',' YEN,', , A. V
---j7,-M2 --?-~e cez`~-- mane2~ a la~lfer o: ion exchan-
r"~!nn 1 th onn oompont---nt in thf! Trixt-ure. Plast.
J 1 (MIRA 173~

-.~ ~ " , "'~ - )I
- _ - j

L 28713-65 W(m)/M(m)/T/EWP(t)/EWP(b) -TJP(c) JDAwH-
ACCESSION NR- AT5004072 B/3127/63/000/05-/0058/0062
AUTHOR: Sinyakova, Se. I., DuAMeva,. A. G., Markova 1. V.,
TITLE: Determination of zinc, cadmium lead and copj~)r mpurities In JA41M. and Its
salts
.7
SOURCE: USSR. Gosudarstvennyykomitetpo-khim'ji.:M6todyanalizakhimicheskikh
reaktivov I preparatov, no. 5/(;, 1963. Polyarograficheskoye opredeleniye'ulltramikropri-
mesey s nakoplenlyem ihk na statsionamykh rtutnykh 111 tverdykh elektrodakh s posleduyush-:1
,chim rastvoreniyem (Polarographic determination of ultramicro-imparitle v4fli their
accumulation on stationary mercury or solid electrcFdes and subsequent disd6lutiori), 58-62
TOPIC TAGS: indium. analysis, indium. refining, zinc determination, cadmium determina-
tion, lead determination, copper determination, amalgam pojF22LaE~y, mercury cathode
the separation of indium. by oft 'ho
ABSTRACT: The method is based on ac . n with diisopro -
pyl ether from a solution of hydrobromic acid followed by a determination of the impurities
.by the amalgam polarographic technique with their electrolytic accumulation on a stationary
:mereuxy cathode. The apparatus, reagents,. and solutions employed are listed, and the
determination procedure Is described. The content of the Impurities present In iniffinn as
'determined by the method of additions Is calculated by means of the formula
Card 1/2

S/075/63/018/003/003/006
E071/E436
AUTHORS: Sinyakova, S.I., Dudareva, A.G., Markova, I.V.,
Talalayeva I.N.
TITLE: Determination of copperl lead, cadmium and zinc
impurities in particular pure indium and its salts
by the method of amalgam polarography with a stationary,
electrode
PERIODICAL: Zhurnal analiticheskoy khimii, v.18, no.3, 1963, 377-384
TEXT: A method of amalgam polarography with a stationary
electrode (mercury drop) was developed for the determination of
zinc, admium, lead and copper impurities at concentrations down
to in metallic indium and its salts. The method is based-on*
the extraction of ind:Lum (as bromide) with di-isopropyl ether from
5MHBr. After concentrating the impurities in the mercury drop by;
electrolysis at a controlled potential from potassium (sodium)
hydroxide and HCI solutions, they are determined from the curves of~
anodic dissolution of the metals from the amalgam at a continuously
changing potential. Since indium is not completely removed by the
extraction, the effect of additions of complexone III, sodium jI
CArd 1/2

S/075/63/018/003/003/006
Determination of copper ... E071/E436
acetate and sodium tartrate on the shift of the indium wave to morel
negative potentials was investigated by the method of oscillographic
polarography. The method was tested on a number of samples of
metallic indium and indium iodide with satisfactory results.
The maximum error does not exceed + 15%. There are 6 figures and
4 tables.
ASSOCIATIONS: Institut geokhimii i analiticheskoy khimii im.
V.I.Vernadskogo AN SSSR (Institute of Geochemistry
and Analytical Chemistry imeni *V. I.Vernadskiy AS USSR)
Moskovskiy institut tonkoy khimicheskoy tekhnologii
im. M.V.Lomonosova (Moscow Institute of Fine Chemical
Technology imeni M.V.Lomonosov)
SUBMI TTED: June 26, 1962
Card 2/2

24(3) S07/ LB-27-9-~ij'2r
AUTHO~iLi; Mi tsuk, V. Ye. , Koz I rainykh, M- 1) , T,-Llal ajeva 1 1. V -
TITLL: Measurement of an Electric Field in Plasma of UltrahiCh
Frequency
PEHIODICAL: Izvestiya Akademii nauk SSSH. Seriya fizicheskaya, 1959t
Vol 23, Nr 8, PP '1031-1035 (USSR)
AB3ThACT: In the introduction it is pointed out that the linear Stark
effect cannot be investigated in the space of the positive
column at' a plasma since then fields within the range of
103 v/cm -~,,ould be necessary for a noticeable effect. In the
1;lasma of microwaves, however, such electric fields occur, and
the amplitude of the electric field is reported to be
104 v/cm for a frequency of 1010 cycles. Conditions are de-
scribed for a Holzmark effect so small that the contours of The
Balmer lines represent the Stark effect. It is further shown
that measurement of the electric field in microwave plasna is
,possible by the quantum mechanic thecry of the Stark effect
d ~
introduced by D. I. Bloklhi:~tsev. In part I of this article the
Card 1/1, Stark contour in the _:lternzitin~ field i-z investigated, and

SOV1A6-2'z-8-21'25
t
Measurement of an Electric Field in Plasma of UltrahiErh Frequency
formula (1) by Epstein-Schwarzschild is given for line split-
ting. The line splitting in a static and alternating field is
discussed and exemplified in the diagrams of figure 1. The
theoretical structure of the alternating field is shown in the
diagram of firure 2, and it is indicated that the voltage
amplitude of the electric field may be determined by measuring
the half width. The methods of measurement are discussed in
part H. The results obtained by means of an arrangement, which
has already been discussed in a previous paper (Ref 3) where
the half width was found by photo-raplij, are compared to results
determined by means of a photoelectronic multiplier. The dia-
Cra.m cf figure 3 slio-vs the COMPUri3on. In part III of the pre-
sent p~,Lper the measurement of the electric field is described,
and the above methods of measurement and the block scheme of
the experimental arrangement are discussed, The measurement of
the half -width is ext,lained bi figure 5. The experimentally de-
termined. function of the electric field of high-frequency dis-
charge in deuterium is shovn in the diagram of figure 6. There
are 6 figures and 3 Soviet references.
Card 2/2

SOKOLOV, ,i.; ."'LAYEVA, M.; MITIN', P.; 1-11RUPOL'SKIY, I.; OCHKIIN, V.;
GCLIP~A!!. B.; STRUMQV, V.; E'C';-~ISOV' V.
change of pracL-ces. MJas. Ind. SSSR
"X
(MIRA 17:2)
1. Vsesoyuzny.,f nauchno-issledovatellskiy inst-itut myasnoy
promyshlennosti (for Sokolov, Talayeva, Ochkin). 2. Gomell-
skiy myasokomb-inat (for Mitin, Miropol'skiy). 3. Brestskiy
iVasotres'u (for Gol'i'man). 4. Kislovodskiy myasokombinat
(for Stromov). 5. Rizhski-y zavod "Kompressor" (for Borisov).

SO V / 137- 58 10
T ri n s I a t i c) ri fr o ri-i Refcrativnyy ZIMI-nal Metallurgiva, 19581 Nr 12. p 201 [USSR,
AUTHORS Kuznetsova Ye T , Taialayeva, 0. D , Tikhonov, A S
T!TLE Rapid Method for the Analysis of a Cadmium Alloy Usin 'a Sodium
Versenate (Uskorennyv metod analiza kadn-iivevogo splava s primenen: -
yern trilona BI
PER'OD;CAL Sb tr Voronezhsk otd Vses khim. o--,-a im D. I IvIendeleyeva,
1957 Nr I pp 151-1534
ABSTRACT The analysis of the Cd-Sn-Pb alloy is based on the initial separation of
Sn in tile form of metastannic acid from a nitric-acid solution followed
by the volumetric determination of Cd and Pb jointly and of Pb separately
in separate portions of the solution. 0.5 cy of the alloy are dissolved in
15 cc of HN03 (I : 1), Sn is filtered off., and the filtrate is diluted to 2;0
cc 10 cc of 10% KNa-tartarate solution and one drop of methyl red -are
added to 50 cc of the solution, whereupon it is neutralized with NH4014-
10 cc of an an-imoniacal buffer solution mixture of 350 cc of 25% NH40H
arid 54 g NH4CI in I liter of water), 10 cc of 10% NaGN, 5olid chron-iogen
black and 100 cc of water are added, and the whole is titrated with so
Card 1 12 dium versenate (1) The Pb content is calculated according to the

SOV/137-58-12-25510
Rapid Method for the Analysis of a Cadmium Alloy USing Sodium Versenate
formula O~,)Pb = 5 VJ~j 207 21 , 100/1000 D, where V is the volume of I used in
t lie t j? rat ion of Pb. N1 is the rnolarity of I, and D is the vveight of the specimen of
the allov To another 50 cc portion of the solution are added an excess of I solution
and one drop of methyl red; it is neutralized with NH40H, 10 cc of the ammoniacal
buffer and chromogen black are added, and the excess I is titrated with a solution of
MI-ISO-1 until the color changes from blue-green to blue In this way the suni total
136, and Cd is deterniined. Cd is calculated by the followino formula-
M
O",,C(I = 5 " (V lIvIl i -V)NI?)-VMI - 112. 41. iOO/10001~, where V1 is the volunie of
Taken in excess, M, is the molarity of 1, V), is the volume IF "molarity ' in Russ
Text; Trans] Note I of the MgS04 solut'o~ used for the back titration, and M2 15
rfle niolar-ity of Tvl,-SO4. Results are adduced for the analysis of the following alloys:
M
(i n "n ISri 46 5, Cd 17 3, and Pb 35. 5 with an error for Cd from -0. 29 to +0 3676
and for PI) from -0 49 to FO. 13%
Z. G~
Card 2

TIKHONOV, A.S., II.K.; TALALATWVA, C,,.-i;- `~VS7`0VA '.7-
Sturlyifir-l the formation reaction of hy-droxides of cerf-gin M-Stals
'--)y P'hysicochemicaal analysis. Zhur.neorg.khim. 2 no.9-?196-22ol
3 1 ~,-
(MIRA 10:12)
( Flyd ro xi de s )

0 0 0 0 0 0 *&P 0 0 0 0 0 0 a 0 0 0 q a 0
0 0 0 #10 0 4 0 0 0 0 0 #!4, 0 4 0 0 0 0 0 0 6
-A 0
00 L L' L 1
I
00 00
00 1 h, -tHwir ot -Waort phir.11IX.1I A
1 It. 1.4, 11'.1. al III,
00 tht, ul.t.l. .1 Igm.p. It, IV -.I III, so
00 i AA.Ai- Alld k It k-l-h
penodic systent. 1. It, I 00
,
- I I;- (hes 1 1. S. :1. 14 8. 1 ....... 11.
00 L
1!1.0~ .. Il,,th MiLs 4 1 wid MiNIgIlt 11 mwitf-, -00
00 -hrtivi: rvaclivily wilb ml-tal% #d Krinill, 11, IV allif
1 ith III,- metal, Mg. 11g. Sri. Pb, A, mutSh
00 N"NIK. 13.s`~ vivi'l; 1,11,11g. I-L.1-1 Phllgkl.
00 Vh.sn 111. 1,104. IV.
-00
V, -.h.
1*1,,:,I. Vi 00
40
it
SI ..... 1 11'.1 1... t .-1.,I
40
II

I It M
00

41111, ...... !141 It,, mill., it, .,I d" N. 1- .00
00 Ow re" I,A .4 11'. .0-- 1, f-d. I
A 1.11g, '-f 1.1 lia, fillwd .1,11 1,101 MM.
06 4r S.I. 11~. A'. Sl,. It. h, 1-i -1 .. .....1 .00
06 '1 .., ",-p '-I
,

00 I
V. Vt.'.
,
f 1.1, ..1 1"'.
,
00 3
00 -.00
Os -00
00 :0*
*0 t ~'o 0
00 s .00
00 1
14 0
i0 it A, I,
~* : : : : : 0
:D loo

0 Ill 0
0 0 0 0 0 0 0 0
I, L 1-.11~~I-t' I I V
60
00 A Orgamotin con d4 of the naphthalenit I
00 I'sLatui. 1'. V. =41 Alld K A~ K..
Gen. (At.- it.) a. IS1.1 9-111
AWN). I. *(.,.II,Nlglir,l Willi lit
giv- all pai.- vril". ill
04 furflict treattatt!l1i with It "it jill, At 1:
Ill,. -Alrd till.. IV
1 1, al- I-ml 41 )IV 1-1 ..1 1. 1 11
es 11, I-Allw C .11,11fkA V to; 1
00 X I )I I IV 114
VI
00
.81.1 Ilgcl, its Oil, giv-
00 ;h-vii.41.1till Ivf",.t..) ... I III
00
At- I,v ll-tmcm ,I VI %'rh
09
06 a pli,141 IV alld ',",It m
I.-I I to'. at I:.. m A -1.-d 1.0.- IV c-,

0 # 0 9 0 0 0 0 q 0 0 0 0 0

so
ti
. I 1 00
e
1. -00
J~Njti. .00

nn .00
I_ I l_
oil It: 00
-00
-00

k-,If
.00
k

I it, I h, -00
1- 1~06
It

L JI-N.101,
k, Ill "ll, 11
00 bruled .1111 It"'; llcl Wtilt PhNfl:. till -1- .00
00 I.L- VII f-I.. dn, coml.l. VII
.1111 l(RO, ill A- ah.. g.- V. .II,v -AO
.,Ill 111IMS11t lit
A ','T 1,41si I ival, ZP 0
0 Z.0 -%
~1-11%1' OIC.
:0 ~41110
00 0
00
0 0 0 9 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6
0 0 0 0 0 0 0 0 0 0
0000 4 0

0
of
00
00

00
00

0

00
ll:
so 4*8
COM%l
a
00
in cow as

00
0
W
AIDW 4
SIMI tbm
thm a%
coa,. am
7-8
MOAC
.
(pptd. OM

wv-!
ract, b
moo". a
or
It to
U AV ;p0;_L_%*' F, k,
1 6 0 0
10000000:0060
:::::1000000
w- Iff-ler 1w
M 42
d'_j
';Y T-0 0
0
1-0
-00
-00

___ - 6 '
qSNOW 414" With
rrL km isoll gism.
. m
e..
SW. in C
im M xr, It=
meov-dVA-AVO. U
in
WA. In
I A W S.
. 0.4

goo
;1 ;11 ; 0 0 0

:18000
0
COO
moo
Soo
400
goo
000
goo
w0

0 0 0 0 0 0 0 a 0 0
06 4jr
*0
00
00 11
00 15
Cl
0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 a
11 v D 34 J3 x ID P Wl u m 11 m v 16 J9 .1 u a
R S 1 4 Y~ V__A __I I AA 0 4 A __L I-&
i
. i
0 6 0
h~'f 'Q
Synthesis 0 r_y
Is w !~&W* by.
~Iuwi WIN
k- ( . InO
TV K.' in. aji --wu-T-nr7-. T4t'k'fj'j--t,() _III .,I
tf,,ml 62,7 9, Hilir and 6_7 x 1,,, 1?---
11N)CC, E.1'o.ind
frc.,t,,l .1114 ice, y1d,11"K.
all't rValm. "I OW I-W). 101; 7'; PA,Nb, m. !,L" (Irmn
J-tl~ 01-il S-W."Iy. P-11FC.H.Afe Ica--- 11, A, ~ 1'. -P
t"1adnI*-'"V. 114. 127, (frulla MCOI I);J~p ' tirmn(Killiu'le
K."VC Al'; 1-P--,,y4amljm.my. tn. ISA (from CIICI,.
vtoll);
P-hr,sm--plicliettile gj- M.4';. Ira.p-pkejef 'W~
m. S.!*; p-bruntoliijilienyl gAve 57. ', tri
tiphenYl'O,inrj-,mv, tn, 176' (from CIICI. mol FA011i;
1~", t'..I-lpklhAiml~vi N. m. 21S 19:
p-BrC.Il.NMe. x~ve 7,.m.1,;. j,-ip.
Ill. 221), (from CIICI.-
Tbc U'r "I Licmrqxl~. wasmuch inw,
fid th."I lh.'t of the Mx Criwaards. G. Nt. K-4,j-)tT
A I A .(TAtLLoPGK.L LITI..TURE CLASSSFICATM* x
I J T An L I I rW 0 0 If 00 5 0 0 11 1 ---Val
;U 11 AT-93~ -1, it or 6( Is (I q( IF PC tf ff it n
"100,
.00
000 00 00000 : 0 : :
0 * 0 * 0 6 0 0 0 0

Now medwP& of popmadw of crystailiae Ifthisan-arpak
eq-towitle *( allphatic. ailtattyl, 4ad aromadc *@two.
T. V. Talalaeva and K. A. lCuchesibb". Daklady A"d.
Nask S.S.S.R. 77, 1121-4(1951).-Vew technNa" for the
pa. of RIA are described. Direct action of JA and RX
In oftable in casm in which 1AX is imol. in the dumirititl soi-
t. For a* pros. a# cry*. Btu. pingtow b MU& bMW
'in -w4 -1
d','1iy qtspiai= % bt*=1d1
=
Inpie obtained with aromatic Sb derivs. Cryst. FjLt h(
is treated with 0.33 M Ar.% at room temp. or witil.
ight beating. mW the pptil. AFLi filtered off, witaw with
pentane, and drIed. In this manner the following wirre
obtained in arialytieWly pure state M yield gi-n)-.
PhLi ,A) , p-M.C.H.Li fQ, o-ij~ 62, "ontir 48, p~
0C.H.Li 46. p-Br ast4lor 041, I-C.HrLi 56. AM can be
stored in N-filled tuba; all are oxidixed and decorapd. by
.air. (Phcffl).Sb give 56% PhICHOU, the product is
~ertsitive to heat anti cannot be stored for ever 1-2 da"
I ban C.11,1. I tie reacit'"I '.11.1 11 h III III I.* enwherinir iinti
gives a LiRr ppt. as a gray-violet wiliti. The mist. is treated
with C4tfo to take up the Etl.i anti the ext. is concd. anti
chilled; addii. of pentene plits. pure FJU. which after
drying. in. 95'. is spontaneously flammable in air. A single
errsin. froin hegane gives an analytically pure product in
XS% Tield; (lit yielid In original CJIa "n. rewbes 65c,*-
Only EtU iq recrystallizable among the aliphatic members.
.isolation of PhLi in the PhBr reaction with Ll is complicated
in HtyO %olits. by mriplexes of PhIA, LiBr, and Et*O. Hx-
rhange methods of prepirt. Innis other organometallic compils.
"gay employ deriv%. of Sh. Hi, Rr. iodine, Ph. and Sri.
Reaction with comptis. based on N. 0, S. F. CI. P. or As is
les,% qatisfactory but their is evidence that the LW 2 cle-
merits may be u~t. Fichanige of BtLi and DuU was
%tudied with aroutalic drrivs. tif Sb. Hi, Ur, and iodine; Pb
14jefivs. are Itixic anti &I derivit. arr Augglab. The Wurtz

TAL A L A YEVA,,, T.V

'T V
Y G V f-i
V
Chemical Abet@
Vol- 48 No. 6
Mar. 25, 1954
organic Chemistry
'Crystalline a0p~.gorn unds-, Compounds of
"::. Y _tL
serle r
aromatic a. 1'. Kocheslikov..
__U
Izvest. I Akad. 7 Maul SMR.-, idel. Mint. Avauk 1953~
126-U-m-Alt expts. were performed fit closcd.ntip. in an
:atm of pure N. Diagrams of several.plecesW app. are
-ahoW To UL-g. EtLI in 82 ml. C411s was added 3.9 g. -
O-MeCotfjsSh In 10 ml. hot Colit, and the mixt. stirred a
lirs.-at room temp. and M firs. at 30-5* and fittered under N
pressure, yleldint 72-82Z,,,rM,CaZi, InfuMble uystals, ".2
it,
-sparingly sot. In itts, reac ug most violently Willi Htoll tir
~HjO, but not Inflaming fit air. A, 60% jield 14 obtained -:t
-also
similarly In CgHs from EtLi and (p-ble J14)313i and
~obtalned from RtLi and J~-MeCABr iM C4H. after 24 lirs.'
Similarly 0.69 g. EtLi and 1.07 g. (o-1teCjHj)jSb In Cells In
.2 weeks gave',62% o-AleCtff4tLi, fine solid. a M.0% yield
results -in a few firs. with a-Afeaffj and HtLL . HtLi and S
.(M-MeCHJSb In 2 weeks gave 48% m-MeCaff.U. cryst;
solidi a 3001 vield results Im 2- davs front,ni-McC41M..
Readug 0.75 9. RtLf and 2M g. PI4Sb In (~jl:fj Vfffi~.-javc
50% AM; lnftWble needles, furning in airbut not inflaming,
reacting violently with HzO, sot. in abs. BtjO but only spar-
ingly in CgFu or petr. ether.. Similarly EtLi and Plil in
C.H. immediately gave 52.1% PhLi, mixed-with some LH.,
~PhBr gave 78% after 24 firs. but if the mixt. is allowed to
sLand I month, the PhLi ppt. is replaced by L that of U13r.
To 1.57 g. PhLi in 40 ml. dry M30 was added 2 g. SnBri in
C,H, with ecibling; after 2 his. the usual treatment gave.
i'CO gave,.-
7U% Ph.Sn; m. 224-5*, PhLi in Elio with P)
7070 PhjCOH. , EtL1 (0.79 g.) and 2.9 g. (p-BrCAFfjjSb In
warm C4H4 gave-in 12 firs. 100% p-BrQUoU. crystals
inflaming in air; RtLi with, p-CJJ4Br3 In 6 hrs. gave 76 1-0'
oU the same product. (jto-CICJQjSb gave 45.8c",
Llibi, which,49cs not inflame in air; RtLi and Z913,01
gave 88.8% same product in 24 firs. EtLi and I-C~eHr)3%'
gave 56.4% .1-Caff7U. while _P-PhCjUr gave 44.49c..
p-Ph C.9,Li. G. M. Kosolapoff a

TALALAYEVA. T.V.; KOCHESHKOV, K.A.
Crystalline organic lithium compounds. BeU2.Vllithium. Izv. AN SSSR. Otd.
kh1m.nauk. ao.2:290-293 Mr-Az. 153. (MA 6:5)
1. Fiziko-khimicheskiy Institut Imeni L.YaAarpova.
(Lithium organic compounds)
!3en-,,yjlithiLL,n as the simplest ar
yi-alk,
y1 Li comod differs from
both aromatic xid aliphatic Li compd5 by its greater reactipity, which is utilized
mostly for analytical purposes. Crystalline benzyllithi= was obtained by reacting
tribenzylanti,nony with ethyllithiurr, in a pentane-benzene soln. Its properties
were investigated. ~56-129

TA-LULIYEVii, T.V.; KOCH&SHKOV, K.A.
Crystalline organic lithium compounds. Fluorenyllithium. Lithium pheny-
lacetylide. Izv. AN SSSR. Otd.khim.nauk. no.2:392-393 Mr-4 '53.
(MLRA 6:5)
1. Fiziko-khimicheskiy inetitut imeni L.Ta.Karpova.
(Lithium organic compounds)
Using the exchanCe reaction H netal (Shoy-jgin's reaction),
fljorenyllithitua was prend by interacting fluomne vith ethyll-ithium.
Cr7Tstithiur. phenylacetylenide was s~rnthesized on the basis of the sarae reaction.
2250'n1

Z E H --Synthnsij and itud
-L,of
-Orgatioln b RU -Ar'
K" ITT2 fforn
'lad 4d g. Li ~'l LtIO tr~:at~'j with, ic'e coolitli; with 6.5 g.
'Ll~ifl'-A into ivc (to re'lawk! rcsi,111al Lil
~ibU_,,tirr,d I la
(1), la~ lvv: t
and rXid.
SimiLirlv *btaln-,-i~ 7i-sck" In. 72'~ long
with Ju- 137~ (iraju 111~ Illot"wr
:.md 77-5',0 -0 MI),
AL
tn. I W.f- 1A Nvrxid~ Ividt dN ci~ il-v~ Owd, 7"'arzfe (IV), in.
IS9.6". '1-41uihriy P-1ircillvt
dicfdv~.We (;71,, pr;-3d. as ts,uttl, m. 195'.
M, in. 1:56
I-C~"H;Nlglir j;ave wmiyz O~Ctulh)'Sli (VIO' ut,
Traum~sit of thc ArISMA~ with Itnt aq.;dc- KF iohl. gave
"!T~SLF, Ill . tiId , ,
75-o0' '-wal' ~%ere Uwailwd tilt- following
A,-'~,',S, (Ar and m.p. sivvn). PA-, 115';
C~ CV1., 115.5 ~.l L' V-arc~ 1`14; 149 -!u-5
h9br'r with ILS In Moll wl td. wi'll
-j'so*.

TALALAYEVA, T.V.: KOCEEKSHKOV, K.A.
Structure of some crystalline orgazolithium compounds. Dokl.AN SSSR
104 ae.2:260-263 S 155. (MLRA 9:2)
l.Chles-kerrespeadent kN SSSR (for Kochashkov). 2.Fizike-khimichookiy
institut Imaxi L.T&.T-arpeva.
(Lithium organic c*mD#uads)

TALAM.YRVA, T.V.; NADI, M.P.; KOCHBSHrOV, K.A.
Etherates and dioxanates of lithiumorganic compounds. Dokl. AN SSSR
109 no.1:101-104 Jl-Ag '56. (K[JU 9: 10)
1. Chlon-korrespondent Akndemii nauk SSSR (for Kocheahkov).
2. Fiziko-khimicht-skiy institut imeni L.Ya. Kar
.povn.
(Lithium organic compounds)

.." . .*,~ ~': ~ . * :.!l N , -
. . - ~- sssz~ , . ~! - . . , -, - : -- 1 --
I . - - ~~- ; - , ~cz C,

U T ". C 3 il C, d, r-, S 4- JL n D 17 a T 62-1-28129
T IT LF,
.1 toL
P-.~:ITC)Djll L: Iz vo o'iy -a -- Otdeleniye K!--J L~J chc-':i,~h 1356, "~r 1
u Ii. -A - - '. j -
1!20-120 'UjJR'
ADMRACT: On the ztrength of the research of "he infrarod i1jectra of the
R - Li and 0 - Li tl.r- unthors of thio lettt:r dis-
i_
covered the formation of an ~teriuolecular lithium binding
- I +
+
C -L L~, and 0 L 0 Li. A coL-T3a.-iso-n o'
the spectra of the varors, solvents, and po-aders in vaseline
c-41 as -.-i-ell- as an a-allysis of the "Cird of oscil llation of the
molecules --a,-;e -cossible V-.e precise dct-nrmination of tlle fre-
c:uency of the Talent oscillations of zhe grours C'--L-4 (of Ue
free and -,nose takii,6 i- tne -`or--~allion of the lit'-~iu-m
binding; see table), The int,--rmolecular lituhiumbind-in.-
4 +
-C ... L i - i s c on 2 t -a n t . 'W i t h t ! i e b a i n Un- -L-i...O- the latter
is, however, still more stable. Tile formation of especially
re6istenf inter::,clecular bindinSs has to be "raced
C a 1, d, 1 2 t o t *,io r,~l c---,--, i a--- -* -,y of :*.-e atoi-: cf, the !--I thium : Small

62-1-28/2Q
sma7l icn~:~at4o:-, _ote. 1, tte~
radil n~i a e
T,o:~ ~i: b _J 1 _J by of t i 11,., 1 nC t 1--e- -orl-t. ~11 this makes -.os:3ible
d i a r; :_,,oi,e and :bore activr- ta!_-inE of its electron
c I ti ,, 1 , 1 ,-, ri i i t:, a~- L i otliarl i 0t ". eCa3c wi th the
atom. Thc_~v,~ if3 1 ta~)le.
AS.~OCIATIOJ: imeni L. fa. Karpov
(Fiziko-
L. Ya. 1~ar-,cva)
SU31.:ITTED: 20, 195'7
ATL I L A 11 LE Li'01-ary of Conrress
1. Lithium-Tlolecular structure
3. Infrared spectra-Applications
2. Vaseline oil spectra-Analysis
Card 2/2

A _7
Taialayeva, T. 7. , Kocllaesh':ov, K. A.
T I'IL E Infi-red Absorl,~tion Snectra Of Or-anolithilum Cor--~cunds
(Inflrakrasnyye s,.'e"ltry porloshcher-iya litiyorLanlic~IeST 41.
s o Y e d i n e n i YI i i t e T m. o 1 (--- c ul a r L i t h i umn Bi n 3 1 np- (Y e z h m ol e -
arn,-!-a liti-fevaya svyazl
:'E- '-DC I--vesti7a Akademi' nauk SSS4. Seriya fizicheskaya,
Vol 22, 14'r 9, PP 1110 1113 (USSR)
A. ~S"i' R A CT In ti,.is a report is given On the "liz;Cove'ry :Ind
e . . ..tiOn Of t"1(-- interMole.CUlar lithium
-L,, i v es t !
-C - Li C - Li and -0 - Li ... 0 L i 4 C', ;Ve r e
based u,,)on t'-,e study of tale irlf-ared soectra of commounds of
t,
..e t.-j.-Pe a- Li and R - 0 - Li. The inter~~olecular
4
lit',lium bindini-
; -Li ... C - r.-,ust be gr!--nt-d special
-i:~,portance because i t can be for-~-~ed without coooeration
of t,,e ecceptor-doror interaction. T.-'.e re~-.uired co-,-,:)unds
Z,Mt'-etized --nd -ourified accordin,g t'ne
C.-I rj 14 by Kochleshkov e-u al. (Refs 9,10;". 7:-.e S,.-~-Ctr~

! n. f e d A.1i j n 3 c r .7 , n r) 11 t h -* Lim C om ou n 11 s . S D -i 2 - 2
T - ec
-ular L~ um B ind i r:,,-
i recorded o' va-,-.ors, solut-I ons and powder Jn vaseline
we
oil (F!-.,s 1,2,. A co:..f,ar--"son of t~-,e s'-ect-ra and t,~e
nn~:Iysis of t'-Ie nature of t,e oscill-tion of the moleculez
permJt to determine t-ie frequencies of tne valence
of free ~,nd of C-Li Croui~s tulrin- part i~,-,
L~.e i,or-lation DL, lit'hillul (T-A)le 2). T,i(!
-'r +1
i--- uermoleci,-Iar l--', thium b 4 n~~n~ -C ... Li - is s~-.u',Ie
12 notr;it'ncta-din,5 t"e -F-ct t'nat it is
2 r i, c e d -.,; i t-,, o u t c j --l o e ra t i o n o f t *,,. e a c c e t o r - r! on o r i L r -
action. Even more St.--Lble is t..e binding Li ... 0
4
S j
Ta -a e n t i o! ~ e d '--, e f o r e , t ', i e - L u- li."-7 d
b J n, - J- S
witl-.ou t t-,- coo--)ei-tion o-* t,-,e acce-,-tor-lonor i-te~
raction.
t is con: ection t~ e ;problem of t",.e na"--.:-e 0~ t--~ i s o n d
t 4
a rf ses. t -i S I n n z.,.at -,. e e r- t I, F, t a . - C n - _2 a
-S u n t C, e X -'.L a, i n c om:~ 1 e t e I y t',, e f a
il C D:n 3'-, d X L
molecit-
Card 2/4 T-)heno~enon car, i- th~e

fi-t- red A-1j.;,) i,) n t ra ~)f ~ r-,~ :: o I i th i
T~Ac-i,.%gIr-cular Lithium Bindin,
ii-~Aure of the lithium utoms. it' is po~-sible in t--,,e
r,ase u.,,,Jr2r review t~,e nature of the ljitnium bonrl,
:!,,,;,wi:-.,L.11,,, be I~y tho
of t`ie electron from the lithium atom, .,;h_icl:l is i, a
:)-S,ua'.e toet;,er -ait*,. t")e "free i)art of t'-e eleczron
jf t-'-Ie carbon atom u-nd partly a-lSO t'-Ie di-cole 4 r-
action. Tere are 2 fi~--ures, 2 tables, and 1,111 referencc--~?
11 oil whlic~-. are Sov-let.
ISCOCT~'. 10~T: Fiziko-khimicheskiy irstitut i,,-.I.L.Ya.K--r-pova (I-lsti~u~e
A
of Physical Chemistry imeni L.Ya.'Karpov)
C ad 3,

2
A T~ T -H, 0 R S: Rod ion ov 1 '7. 4

S r i ~'; ,~J. -)
S-,07/2o- 123-1 - 2o /56
.
,
-
-
T~1al~-Yev-,,
'. V. , K--,c' -',':ov, K A. CDr-
nesh Member
,
_
Academy of erces, USsj
TIT T In'rared Spectra of Or,-_anolJt-,.iu,-,, Compound's (Infrakrasnvye
S-,,,ektry llitiycrZanicheskil-h soyedi-.-eniy) Intermollecu,"ar
j
Lit'-.ium Bond (LTezlimole-Kulyarraya litiyevaya svyaz,)
0 A
FERIODICV"L: D~-'-_lady AL-~:Clemii SESi, 119,-
~-A_r 1
`;-Q, Voll 123
~
,
,
pp 117 _ 11' ~TTSSR)
AESTRAC7: The i-vesti~._rted absorAion spectra were taken from the
`
me,~tioned compour,~s of tyz:e Alk-Li and Ar-Li. In par-LJc-
-r
_
-
l
utyl
b
dodecyl-,
2 a s e s a - " '-,*,-j ~'-;
u- -F~-e z~-.~d'=d.
w~~rn Pr.- L~.red and iso'~znll acccr,-;n:-- to a ~,,-,_,,od pre-
viou~-ly deccri`ed (Refs 1,2). Tn
-.e s-
1 m 6 =i" fre-.1-,,~nc i es _~re rec ~~r:l eA
t'--ory of
of 7,olecu-!(,s. T-e ",:,:-.d 1052 cm-1
~,-rd 1/4 j- 4 on
is aSsi-t:ned to Vnle :.Scil, __GUZ~

in-f-ri--ed S -.e c t r,~. :)f 02- 1 _i t .~. 1 11: --- r, er- SOV/20-123-1-70 "56
C C d
4~ f
C Li. T- e acc u-r-,- cy o--.- t`-Iis ass -L.7- -~en ' i s in ac c
witIl tne so,?ct-val mlalYslis of et~'--,Yl-, bu-11--l-, and
dodecyl T'ats, 'U-":-.c freQuenc. ,/I of the vallence
-1 1 s - ~ - -:)r L ne
,)scill.;tion, ~:--inj -J 1050 cc, c 4 fic
respcctive serli-es of c-ompaunds. ]:(-of of t,-,Js
";_c,' is ;'resenterl. T'.e vari.---.-tion of t,:e "e:-.t--Io!-ied fre-
4t4 'ro-.. t-e
quency of the C-Li t 0 on :1
on te ~ L -L -
v-1--,orous state to t,ie solid and to solutions is
ap--,are,,,tl,-,, rel-~ted to 'U*-,c. f.:Lct that the C-Li erou-.~,s in
cryctals ond soluti-ohs t5?~!:e cart in so~~e intermole-cular
re7-.ctio"s. Th-i's in ;~articul-r is s--ifti-j t`ie C-Li-band
in tl-k? dllllecltion of t;~e lon-- u r
slllovi defi,li t'~--t t~,~c -21-.1-S of '.'-e or --O~Iit~ .4,."
cc) :-.,,nund's in s -~nd tio~ s ed u, er
r r-, a s sc a t
ex f or,--tion in co:,:fc. r---i ~y tl~
T, j,j C-,.yS---7
StC,
e:- -_Ce 0~
poc c -r I -A u t i o n s w t r on- :: 02 --r .-e L t fo t io n
ible,
o f as s ric a t e er o- -o f t e z~ t i e
C -,4
on r, vo r

t I!,
of
a S W C 1 s y v a r t i or,
c~',-- ct---r :--,d -if ~-,
jl~
t 0 r
t4 t,.e
So I.T;C -4
or
o n und r -f,1 u f I i
t
e
of c ry C) R-2 C r e 3
C) t ~-' I ~'- 'l,
4.
and C I
c 01-exen e
C ":Or+ 1c:- Of
se mo c- s y 4 - ', -IC) _- .
-- . - -) il
S C a Cn i
L
a 2 ed "j'ez
0.-
r) f
-07.. t t in arcz:~tic 7~~ydlrocar--
T C C'~ r ~t f 0.'! Z
of + I, on. 'o ft z,--. E-Ilt and
v
u-or
0 t
t
tion
t d s e e
Cl- r -5 4 Of a Or-

S
SOV//2o- 12 3-1 - a !5
Lill
An excc_,,,.'i cr is
va-'i -tion :), t~,-_ C'~---_Cter n-nd de,--ree
jf
t',e R-T-1 mo7ecules -Ii~oie
to tl`.,~ Cho compound,
e r e a
, o ra c e n t ra t i o n and t'ie te-,.,ev,~ Ltw . it c n be assumed
ti Lt the dipole nompnt of Pt?tyl lit!-!W:! is the
d
-.. m,),7,,ent of a
j 4:
(aj by com-,lon
Vi-;_-'Ilyeva). T.-~-- i7 -t-.~_,s fou--.d
r
G t ~c -hors cc)n,:-T_-.dc-1
-A :tiit
c c'-:s of r ---,:0l an
in t 7-::01 1 1
a e f:
ca_:-es of j:_.~eraC140,_
-1 T -re ~-a
c
:.'_7'_7:: D J-1y
C,-_-L_-d .1r// 4

/ 7 ~ , ~: /~~ ~ - , -1 o !,:8
Sov !r
TJ T 7~1 f"; I , , " . , -
T _ I all v T . V Ka z_ e -- n i, a '7
Koc."eshkov,
TIT1 E: Fluori-a-cel 3tyren,es (Ftorirovann.-,,Ye stirol.v) 'loin runication
_`~,-I-D_iflimro St.-,,--one (Soob."ic''oni4ye 1. 2,4-Dift-or--tirol)
C.~, 1; lzvtestiya naizk 5-*,!.F. ':)tfiel-nniye 1-hiiniclt-ae~-Irii",h ri-iW~p
IT 1.

5
7") OTS110
S: CT
In t-e ~)respnt na;l
er t,,.o a!itho_~s 2,4-
d 4. f 1u 0 r o
styrene for the fi rst tirue. 2,4-difluoro-phenyl lithium
was also obtained f~,r the first time from 2,41-dibromo
benzene and n--buty l lithium :,.t low temperttures. The initial
ci-~iifluoro benzene .-.-a-s obtiincd from hydrochloric M-p'henyl
dia,-iine. TIP-1 ~~ynt*n e~--is wao ;serf -,.,-,,ral wavs
- o r:, e, d i n se - (Scho-2e).
Them followin- vari fints, :-,,roved to be .:,.ost f,-vor~.!~le:
a) m-,lifluoro ben:, a-~e (I) v.'s condensed -.Ath --cetyl c-1r)ride
in ti..-.? -rc,:7ent e of -,1_u--rinu.,;i cillo;4le in carbon disulf4de
at 350. The y`seld of 2t4-difluoro-aceto ohernone (IT)
a-mounted to ec-3n ' .(!I) was re-luced by ti,
.1 I'le effect of -Ddium
bor-on h -'r4'e
Y, - of 10-115p in -.quolus alcohol under
cnrd 1,1'3 vorY ::Oft r-).-~1itio n,, ..,t 500. T`., viold

:-amic _tion~ I.2,4-)Mu,)ro St.,;,:-ene SOV
of 2,4-`,;fl11Oro phenyl-methyl carbino! (TIT) amounted to
6 5, ', which .,,as dehydrogenated I.-y --uifuric acid pota_ssium
(Ref 11). The yield of 2,4-difluoro styrene (IV) amounted to
70;`.' in that cnce. The compou-,,! represents a mobile,
colorless and punjent li-uid. oilin-, POi!:t 50-51
i~ r 0(25 mm.).
b) 2,,I,-difluoro pho::.,-l-moth,-,-l carbinol (III) ras ~-vnt-esized
by way of lit:-,ixim and )rT-rio-,na:-nesium coMuounds; 2,4-di-
f,luoro-_-)hen-,l lithium (VI) obtained b.-, the P"!'ect of
ether solution of 2 fluoro-bromo be!. -ne on the ether
solution of n-butyl lithium at iv-7(00. A 1_ar_,e cuartity o-.:'
acetaldehyde was -.d!ed to the transi~arert 21J,-Jifluoro-
phen-.1 lithium -~2oluti_on at -65 - -700. The Yield of
2,Aj-difluoro pher..,,~l-meth,,~l c~rlrinol (IITI O.mounted to 07,
The authr-rs tri-~,1 to svnthesi ze `rectlY 2 , 4-di
I U a~ E~tyrene
the con-~ers-ition of vinyl bromi-de -.,.,-Lth 2,4-difluoro
he.-.yl ima,.:,nesiu- bro-_i4e in t*.--e pre:--erc of cobalt nhl~~ride
.f 17). T~-.- yi~l~ of sf-,-ene WaS -;7',11:
(in nitro,-en) (Iv~
-kJ 5 - 7 ,',(as 1J,-o-ni`_e). T----- :~trc 1 fi,~ure and 1,) re,er-
j -V4
cnces, I of j..
21

Fl u o r-i t .d
c 1c t
7 0 L V 0 v
SJUB;"' TTT--D:
c

S!"
17~
T a!

IPTTI,--,
,
~
,
(Ftnrirov
n-
~
,ti
,
l
:
ye :
,
,
roly) cr)-i un-icn-tjon
P-Dj-
fl
uoro St",rene (So0l.,z;i,-c'.-niye 2. 2,-'j-Diftor-P-ftrrvtirol i
vol
C., L izvesti-n
19 - ("
"I'
'J
1
- 7
P2 7
In tile -pn-per the ~-;tho s descri'Ded th
-
e S
mthesic of
-
'
styrenes which were fll-,I)rin-itQd b
th i
o
n the side
chain
~nd
,-
nucleus. 2,4-diflUro-'C-flu
~
oro :3
~Yrere and 2,4---lifluo,-O-
'
*
-
,
,
P , f !','Oro 3 t
yren e
;.
e
-
e synt
,,,~F~ i ~ ~d f,~ r t I-
.f-
r

ene wn
y
s obt~,ined on
In e
is of 2,4-c~ifluoro-w w ifluo
ro-aceto ,,,.-,enone (VI)
-
- a --
T h i sketo
e -~
t 1
j
j
1
1
,
I o
6
cj
u in7 --4.4fluoro
::cnz~~ne n-nd bem:cne as i-
iti-1
l
compounlds~
The c0nde-sation in r:ifluoro :lcotic acid vrith 2
,'
dif, l

car'd 11 -
9,
uoro-
l't"'iu:;, ( V
'
) -t" -700
~
l '
rovcf
1
:
0
-e th-~ fiivor,~hle.

U t - f n - - -
"07
-'r-2 -Di f1 -I '~~2- 50-
P-Di f 1 uo r!-, r, -
-.-Jifluoro-:_c,-.to -Ai--rione was tI.erein ob-
t~ired ir, a yii~jj
"0 3 i I I m Of e, P.T~f 7"" rnfhnc.~d
ron ',"Y-1 r i.Je in
c--u-binol (VTT) .e., L
- ; -1 ~ r. of
T Y T T
t o n - C T.
yield of Aipl
I 1 -1 ~ 1 " C 1' 0 T T
amoun t Ovp~ Tj n3 _. - ~
t i - ! ., ~
of zinc di~,F-L upon
(VIIT) n__,i-difluoro [)-fluoro ~t
yrene "IX) as
Synt!'Csi-~,_.d ir, acet!jmi`e in a yield of a~),,,. 1) k
0 r -I,- - , 4! -1 4_._rl-C Cro-
tilr-.1ifluoro otI.,ron'.2 (,(IITI
n
y . T 1
y""d to 4D,-j. The 2 ? 4,- if lu'aro-a ~e
P~!Ollone and ri_,~jfh!oro UL;-d in
61e, 1S
ohtairej to th'', do.,:cri'Ct3 in Co,:,,uni,
D~fiuoro acetic and' .jj~fl tioll
UOrO Chloro acetic acid
were -f*ro---,
salts
of eld
Pard 2,"z

Fluoriti CO-, u.:i": ' ioll IT - fl S -1 V,
--Difluoro-3, Q-Dif" r
3 C L'l 10 J I Fiziko-!~hi~7:icllleskiy instillut im. Ca. Karpov-a (.~h7Firo-
C~--c,,~,ical Institute i-rioni L. -Pov
D A,l,il Vil
Card

~0)' 5k) :3ov/ 62 -
WTHORS: Jad' 1L. bi. ,'Talalay_~,~a, T. V. , Kazenrii;-~),,--, ~3- V.
Kocheshkov, R. A.
TITLE: Fluorin~Lted Styrenes (Ftorirovarinyye stiroly).Communication 3.
Side-Chain Fluorin,,Lted Styrenes (Soobahcheniye 3. StirolY,
ftorirovannyje v bokovoy tsepi)
PEAIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 2, pp 272-277 (USSR)
AB3TRACT: In the present paper the authors present data concerning the
synthesis of 0-fluoro styrene, 0,0-difluoro styrene, a,13-di-
fluoro styrene and a-fluoro-o-chloro styrene. P-fluoro styrene
and a-fluoro-orchloro styrene are described for the first time.
The synthesis methods of P,P-difluoro styrene and a, ' 5-difluoro
styrene devised by the authors deviz~te from the conventional
methods described in publications. For the synthesis of W,(,--di-
fluoro-acetophenone phenyl lithium was condensed with difluoro-
0. ;o -
acetic acid at -70 The yield was 70',. Besides dichloro-aceto
phenone was fluori.%~-ted i,-. dry Flycerin tind-ar the influence
of potassiun~ fluoride. Difluoro--,--ceto~henona was obtained in a
Card 1/5 yield of -,/350~~. This -aas reduced under the influ~~-nce of sodium

sov,16')-~-,~- *~ - 1 -1/40
Fluorinr~ted Dityrenes. Communication 5. Side-Chain Fluorinated Stiriur'E2
boron hydride to difluoromethyl-phenyl-carbinol (yield 95~2)-
Furthermore chlorine was substituted for the hydroxil group of
j
the carbinol by me ns of thionyi-chloride in pyridine
yielded a-chloro-P,P-di-f*luoroethylbenzene (73-,~',)- 3,- the action
of zinc in acetamide chlorine and fluorine atoms v.-_~re sebarated
from thi6 compound, with r--fluoro styrene being formed in a
60-65~,_/- yield. P,P-difluoro styrene was obtained in the following
way: difluoro-chloro-acetic acid was condensed with phenyl
lithium at -700. The w,u,ti-difluoro-chloro-acetophenorie was
formed (50'/~G'). This was reduced by means of sodium boron hydride
to difluoi-o-chloro-methyl-phenyl carbinol (yield .00-92 `0'). By
the action of thionyl chloride in pyridine the a,0-dichIoro-.3,'q-
difluoro ethyl benzene (78,-L) was obtained. By the ---ction of
zinc in acetamide 2 chlorine atoms were unlit off and
~j
fluoro styrene was formed in a 60-65% yieid. By the influence of
alcoholic KOH-solution hydrogen fluoride -xas split off and
a-chloro-p-fluoro styrene (60~;) with u small imiurity of
fluoro st.-rene was formed. a,P-difluoro styrene wa3 synthesiz~a
as follows: From difluoro ace-~ophencne a,a-dichloro-3,~-di-
Card 213 fluoro-ethyl benzene (85~,Q was obtained in the usual mariner. 3,y

.;1.1/62-59-2-14/40
~',~yrene5. "'o.-imunicition 5. Side-Chain FlioririLted St~,renes
fluorinrition with antimony trifluoride the a-chloro-a,~,13-tri-
fluoro benzene (30-40~fo) was obtained. By the action of zinc in
ac c tat, fter
Ade P-difluoro styrene (45-501,43) was formed at 125'
40 minutes. a-fluoro-p-chloro styrene: a,a, '8,0-tetrachloro-
ethyl benzene was obtained by means of phosphorus pentachlozide
from dichloro acetophenone (37-4&,'~D ) . This was fluorin~,te-J 7.ith
antimony trifluoride to a,a-difluoro-O,P-dichloro-ethyl benzene
(46-49%). 5,' r the action of zinc in acetymide a-fluoro-P-chloro
styrene was obtained in a yield of There are references.
~-:i~jOCIATION: Fiziko-khimicheskiy institut im. L. Ya. Karpova (Pllysico-
Chemical Institute imeni L. Ya. Karpov~
-:-"UBI,*JTTED-. April 19, 1957
1
11 Ur d 3/; 3

KOC HESHXDV-, K. A. ; KjUZGI 11, V.A. ; TALATAYEVA, T. V. ; SOGO IOVI., T. 1. ;
FAm,uv, 0. A.
MacromolRcular polymers of ethylene obtainnd from mixtures of
lithbim organic compounds with t itanium tetrachloride. VyBokom.
sond. I no-1:152-156 Ja '59. (MIRA 12:9)
1. Fi z lko-kh lint cheakly Inatitut im. L.Ta.Karpnva.
(Ethylolin) (Lithilim organic coripniinds) (Titplijur, chloride)

~7
S:1.
7,wo--; mm.-ml,
n,
1-4
-i Li r na
of e n
-t,:lms on the nucleus -.,ms
-.;2 t i o n
C rC - .---nt in the t- tic-
c. -a- ini tiril substance. This tms o h i: an n
!-jrochlori,J(~, of p--,,hnny1Fne diamine by
0
~n conceritrats-' nitrous acid, convern-;..-n in-.o
Y
f'l 4
ZO fill-' "n -,,C -,-.)n L
d~ at the sarae
r ~i n i t i ~- n la t -a r c-ompound. In co n r & I th e
r -:i
o o L 11,7, -~ithors f 2
this reaclici
tenp,!raturo
if Vie

iin of 4 i
z n s o r. 1 o 7L
c o n -i n r::i -I t,- i
c a.- i n IL w
f 1 c -
s e n r~ c f p, 4 b il s f oc c f
cyl..
1~71. 7
On f i"19 1,0 -In-1 -1
n-
C r4
11 e) r c, c t a(, 7 "!7 1:o r-, - cj
I L
y1!:. c, n a 5i s tl- ~,n.z. z
i i'lucr-;
n -1 c f .3 r ,n

i f 1~
0-"Iuo,
:.ca!

5(-2,4)\ SOV/20 '2r-3-27/63
AUTHORS: Rodionov,A. N,, Vasillyeva, V. N,, T-alalayeva, T V., Shigorin,
D. N., Gurlyanova, Ye. ff-, Kocheshk&-v, -K.A., C6-rr-esponding
Member, AS USSR
TITLE: Intermolecular Lithium Bond, Its Influence Upon the Vibration
Spectra of Molecules and Upon the Dipole Moments
(Mezhmolekulyarnaya litiyevaya svyazl, yeye vliyaniye na
kolebatellnyye spektry molekul i dipolnyye momenty)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 125, Ur 3, PP 562-565
(USS't1)
ABSTRACT: In an earlier paper (Ref 1) the authors proved the formation of
a bond referred to in the title -CH,)-Lj -CH L4 /I
az d
R-O-Li-O-Li (II). The lithium bond like the hydrogen bond is
a secondary chemical bond (Ref 2)' Type (f) was clos--ly i-n-
vestigated on the basis of infrared absorpticn spectra ir, the
work under review, infrared 5peztra of Alk-L-~ compolands with a
varying length of the radical chaJ.n were solved in hexane and
Card 1/3 investigated at various concertrations The aim was to clarify

SCT'20- I 2,z - 3 -27 15 3
In termolecular Lithium Bond, Its Influence Upon -~he Vribra-,i-cn_ Spec-ra Yole..
cules and Upon the Dipole Moments
the dependence of the intermo1ocular spacc, of the stability of
the lithium bond and also of the magnitude of the frequency
displacement of the groups C-L-i on the length and on. the struc-
ture of the carbon radical , Table I as well as figurect I and 2
illustrate the results obtained. As may be observed therefrom,
the value of the displacement of the said groups ac-tually de-
creases with increasing chain length. Thus also the stability of
the lithium bond in the complexes decreases. The investigation
of the solutions of ethyl, n-butyl.. and n-amyl llithiam in hexane
showed a linear course of the dependence of the dielectricity
constant on the concentraticn in the case of lower concentra-
tions. This course diverges from :he straight '---'ne on an in-
crease of concentration (0.4-3 0 m-ols '%'~. The diDole moment of
ethyl lithium in benzene remains constant between 0.08-0:43mols,,(,
and amounts to O.B7 D. The variation of the diDole moment in
the complex, connected with the formation of 11thium., goes
back on the whole to the action ef this bond upon the type of
orientation of the dipoles w1-:h respect to one another. There-
Card 2/3 fore, the formation of cyclic complexes a_nd espez-_all~ -~he type

'~(~V 20 12 2' i E
Intermolecular Lithium Bond, Its Irifluenr.;-:. Upon 'he f
cules and Upon the Dipole Moments
of the "quadrupoles" must decrease the dipole moment- 'rh:.s ap-
parently takes place in the ethyl lithium solutions in benzene,
It follows from the above that alkyl 11-thium molecules are as-
sociated both in benzene and in hexane solutione Thl" chara-.ter
of the associate depends both on the nature of the solvent and
on the radical composJtion. The ifth-Jum. bond considerably in-
fluences the frequency variations of the vibrations of the
C-Li groups and also the dipole momen-~,s of the complexes; these
variations here depend on the ra!Hcal length, on the _-oncentra-
tion of the solutions, and als~~ on the nature of the solvent.
There are 2 fi-gures, I table, and 3 referencea, 2 of which are
Soviet.
ASSOCIATION: Nauchno-issledovatellskly fiziko-khim-cheskly inslitut im~
L~ Ya, Karpova (Scientific Physico-chemical Research !rst_-.tuTe
imeni L. Ya. Karpov)
SUBMITTED: December 29, 1.958
Card 3/3

-,
1
~
j ~
5
1 - 1 7
N. , -'a' D T ,,
Ta- -yF,.'Ia4 1. 7.,
If
D Kocheshkov
A
in
St
.
.
I
,
,
o Y, t di
-es;,ov., 4 rig Member AS USSR
71111~ :nfrared Szectra ani Stru,:Lure of ArD--atic
in s

?E~~'IGDTC`-
128, Nr A; up '725
D~~klady Akademii naul, SSSR, 10/59', Vol I
(USSR))
A BST R.A.,", T There are verT 'Lew experimental data on the compounds mentioned
tie (Ref s 1 2). To clar-' 'y the structure of these s,,.~*b--
r. the t - 1.
3tances, the infrared absorption spectra of phenyl-, o- and
2-t~;Iyl -, mesityl-, p-dt-pheny~'--, p -chlorophenyl-, p-bromo--
phenyl--, n--'odcjuhenyl-, as well as a-- and P-naphthy! lithium
w~-r~- measured. These aromatic 3ompounds acre :,rystalline sub-
stan:~es, and not soluble either in hexane ~r benzene. Therefo-re;
-oowders were measured in vase14ne- and
,!-,e a-oe~,-tra of their
flucrated oil. Table 1 shows that in these spectra several new
a~- - which are In a zertain o-=.Iectior, with 'he C--Li
.,,ear
, - - -,- I well as --so. with spectra
lol"A, T', dl-IiLft -I tA,11-t~ a s a --~mp a:
a- ccm,,;c,,-~nds prev;ously 'y %hc-

~ard ~-,ad -,he conclus' on tha- tne ban,,-4 -n th-e range r.

'V'~ - In 1, ru r'-1 S ru 'ind S r,-, i A :':)::~a 1, 3 "D v 6 - 2
an lam c..:. an
0 4 1') 6 C -.~ m zi a a r ~ ri c n n e v d vi a fl t- ? C - - 1-i bnd c r
~L z) w tl, p) o r'L y pa rt i n :~a t I n th as S a t: on Th;i
w(ir frequencies (910, M ' ' ', I I
d h
e C---'i bon ds -o art i .ii oat I ne ir. 'he a ss a I, ion Thqse f~
-,7!: e s r. ar-a r 13 t o f -, h b r r 5 h a C L I' C 7 u 7:'
as as ""_eJr in fa,;
.
--ia a 7a c' T, -~he sa-'a 7:,~na n
. - - - - C las S
1: z' c
r -C .Ls Theref3rq, a5s-~-anrtlr- an :oni-
t'-e C-.L,4 bond in a.rcmati;- _)r&an-lithlum --omp,~~unis
41ound -in is The auhcrs investigate
depen.-ien--p- on aromatio ccmpounds resprnsible for thz
fl~rviatiorl of aliphatic. (;ompounds of this type (furmation -,f an
inte--mmlecular lithlur. bond and divole Interaction). in th.z_
1::esent uapev, they study not e~nlv the effe.,,-' of the pu_rely
factcr -,)n the s+rer_~zh of* --he lithium '----t also t a t
of the change in th~ genera-1 polarity of molecules. For this
parpose, they introd-a.--e other pola_r i7,roups oT a-.oais n
to the
rest Gf '~he molecule, On crjmparJsor of the spe..tra
phenyl-, c:-- and p--4.olYl- and m,-,si-Tyl 11thium., i

It n *,- r- ~i r e d Sar- d 32 t rj -f kr oma t 1. c S C V 1'2 6 - A - 2 6 '6 5
UI a r"(~ I it i IC nd S
,i.,
that tl-e degree and type of association of these sub--
51~a,nces a.-e differenL. The C11 -group in orthopositicn has little
efkfect on the degree and cnaracter of aseociation. The same
in pa-a-position (p-tolyl lithium), however, --hanges the
spectrum, considerably ~Fig 1). A complication of the nonpoiar
substituent in paraposition equals ar. exten S4 on of the carbon
res'. This redu,~es the df)sree of association. The screening ef-.-
becomes most distinet in the srectru%i of mesilty! lithium.
The symmetrically arranged CH 3-groups render the. association
rather di'-'Lf.-.-,ult. Therefore, only iha- band of the free C--Li
-4
gr--up at about 101~2 cm ' is more or less distinctuly visible.
Figure 2 shows the spectra of p-chloro--, D-bromo--; ard p-ioeo--
phenyl lith"urr.. 2 dipolas each - C-Li and C-Hal -- are present
in every case. They increase the general polarity of the moie-
cule. This brings abc,,.:-1 an intensification of the dipole inter-
action between -.he molecules. The p--chloro-phanyl lithium is
n,ost J--Lensely and completely associated. Tht:! spectra of a- and
3--nap'i -.,',lyl l' th-um are di 'f erent from a!7 c-~her szer-tra dis-

3+,U.,ture or kl.~!B,
The Infrared Spec~~ra azi, - -
- i f, 7
O_rgano- 11 .,~ c m..1 1-e little-
--3sp T e band 13
'd . t'- p s e
7y-i.
a, iol~o Cum
-,~e bands are pre3e oniated state-
Lntens i ,a,-nl y ass
au-,stances are tpt,.ejjtjy in a L f whi a-e
and 5 reference-33
2 figures)
t
ins,-:
'_~kiy
ASS I)C I AT L ON Res -aur
,,. y.. j,,,arpova
imen~L L. YFL. Karpclv)
S u 3:

6C,4F- 7
S-7,3200 rg) SOV/20-1 29-1- 33/61
AUTHORS: Rodionov, A. N., Kazennikova; G. V, Talalayeva, T. V.,
Shigorin. D~ N., Kocbeshkov, K. A., C6rresponding-Ye-m-Uer AS USZ-q
TITLE: The Infra-red Spectra and Structure of Acetylenides of Lithium
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 129, Nr 1, pp 121-124
(USSR)
ABSTRACT: Acetylene and its derivatives can form complexes with each other
and with several solvents by means of the hydrogen bond as well as
interaction of j'r-electrons of the groups - C =- C - (Ref 2)~
It could be assumed that the substitution of one hydrogen atom
by one lithium atom in acetylene and acetylene derivatives with
the aid of electrons of the C-Li bond and the 5'r-electrons of the
C7-Z-- C group will increase the complex~-forming capacity of these
compounds, In order to explain the structure of this group of
compoixnds the authors investigated the 3pectra of lithium
acetylenide, lithium methylacetylenide, lithium ethylacetylenide,
lithium tertiary butylacetylenide, and lithium phenylacetylenide.
Spectra of acetylenides and phenylacetylenides of potassium and
sodium etc. were plotted in comparison. The results are summarized
Card 1/2 in figures 1 and 2 and table 1. The paper under review proved that

~, ~, ~, 8 -1
The Infra-red Spectra and Structure of Acetylenides SOV/20-129=1-33/64
of Lithium
the molecules of lithium acetylerlides in crystals form stable
complexes (ammonia) with each other as well as with other
compounds, The recorded bands about !060 and 1080 cm-1 may be
assigned to the valence vibrations of the group9=------ C - Li...
in the complexes. The frequency of the valence vibration of the
free groups :;-=-C-Li seems to be 1200 cm-1, as was observed in
the case of lithium phenylacetylenide. Thus the authors'
assumption (Ref 6) that lithium aoetylenides show a stronger
tendency towards complex formation than acetylene itself has been
proved. This may be explained by increased polarity of the
C - L bond (compared vii th ==C - H) as well as by a more
probable cooperation of one valence electron of the lithium atom
using the p-orbit~ There are 2 figures, I table, and
6 references. 4 of which are Soviet,
ASSOCIATION: Nauchno-issledovatellskiy fizlko-khimicheakiy institut im,
L.Ya. Karpova (Scientific Physico-chemical Research Institute
imeni L~ Ya~ Karpov)
SUBMITTEM: July 6, 1959
Card 2/2

87118
I ko U 'Yej," TIT
ATJ T B IK
L:
npole
TITLE:
r j,3
PER pp, 1519-
r, a 1-1 A C) I
d ~.I~a
th~ batzii~ lith- a s a n
.T r - t b, y I
EXT 0 n c1 - -. 1 - 4 ~ , h
't;he dojecyl wh~ - h
measured r, d v, -
U,
.,Yl
lil-hium, ent rat; C~r-
Z_ t
8L
. 'd cut a t ~`, I C(-,Il-e' , .., ti va
were carr, aricl thes e ar-~
4c .0 -a s ani
s O;~ Cr'.-Scor-
r,~+Gn ~ ~ go n
by C! f t -e rut in "'Te
the;, S-rt~ _Z t, .1
extremely unst,,ble, , 1.- .1 , Were c rj ed lu-,ioas ano, th e
t',C- Clipole r t re SO
_Elt ion
rements Of 0
meqsu - 0 r describe t r.-I t ip~ n The
e . The auto ::;clans
atmos-jher
determinni'l.-.-
C.,3.rd I/ I

67118
3 1 e ,'o m 4~, n t Z'
moments -;;ere measured at 25 ':'C i t
T d 2
concentration of the solut;ons wa,
the results. TaIrl, 3 :3 11D i~? .-J 7~ M.~-de at
7 C,- t h s -,,I b -:3 -:1C
PCO P;.-~T
f') r e t hy 1 1 i "I i :L Lim 3onc ~n i, :,,t L nz; 02 0 7:cle5"'. f-
bu tyl 1 i t ~d Lim (-,)nc en tra. t i onS -3 C) r my! 1 1
d -
concen trEi tions o ~ 0 ~-O ~ 66 mol Pro m h~-- I i n,~ r e n I
dielectric con.,-.tant of the 3olution on ---on,>-nt-af-ion (Tabie and lie
con,-Jiincy of tiio --lipole moment valut.- of all three! :omLounds-, it -~s :,on
cluded th~.,t ir~ this ran-e of concent r:i Lion inclecules are ccn-
cerne(l, and tl--t -he value of the momen, for the Comipounds m-~n-
tioned referf~ t,- the moment of the morcmer. A devir-ticn from the l1rear
4 7- ~'
dependerce i s, found when measu ri ng the d : e t ric - on-z tan' o f alk I u
solutilon~-: in hexan~e at higher temperatures Th,, ;-r~%:Ltost (4ev'-atic-n I S
observe,! in the rano-e of concentr-~tion of f z' c) m 0) 2 t G 2" mo7 ~z7' Tr
Jevi~i~ion an" i~ r c. c o r C~ 'r. -"M.L nt -

D c I e e - t s o f 0 r jz a r, o 1 i th il u m. Com o u ~ d s o fS1062 1901OCC, /000
"he Aliphatic Series B023/30C,4
complexes. This is in agreement with the published dattla
If the chair. of the ali-,)hatic radical is extended from ethyl to t1ce
degree of association of the alkyl lithium compounds decreases. This
dependence will be subject of further invest.46-ations. The behavicr of the
alk-yl lithium compounds in benzere solutions differs flrom the hehwuior of
these compounds in hexane. The authors measured the dipole moment of
ethyl lithium in benzene at 250C and obtained 0.87 D in the corcentration
range of from 0-094-0-49 mole". Apparentl-, lithium -forr.-.s stable com-olexes
in benzene solutions also in the case of comparatively lo-,,., concent.-ations.
There are 3 tables ard 6 references: 3 Soviet,*2 US, and 1 German.
AS30CIATI07i: Fiziko-khimicheskiy institut im. L. Ya. Karpova (Physico-
che,mical institute imeni L. Ya. Karpov)
SUFMITTED: Yarch 7, '059
1,
Legend to Tables 1 and 3: c - concentration of the dissolved substance in
moles,; L - dielectric constant of the solution; d - density of the solution.
1) determination in hexa-e at 250C, 2) ethyl lithium, 3) ---n-'Yl iu
Card 3/5

81733
An Investigation of the Uature of Secondary S/020/60/133/01/49/070
Chemical Bonds B004/BO07
compounds in hexane gave the electric moment of 1,,1 - 1.2 D for C-Li. The
existence of oscillation frequencies and the low dipole moment indicate
the covalence-charactAr of the C--Li bond. In benzene- and hexane solutions
of lithium-organic compounds as well as on their crystalsq additional
bonds were foundg which lack in the vapor speatra, and which are due to
complex formation. Like the compounds of Be. B~ and Al, also the lithium-
organic compounds form complexes by way of a secondary Li-bond. This is
explained by means of the properties which these elements have in common%
free energetically low p-orbits; the possibility of changing the energy
state of the valence electrons in the direction s---.), p with only little
energy, In this way, polycentric molecular electron orbits can be formed.
These elements form chemical bonds not only by means of their valence
electrons, but also by ceding free orits to electrons which participate
in the primary bond of other molecules. In the dimeric complex of lithium-
organic compounds every C-atom of the carbon bridge with 2 Li-atoffle is
able to form a tricentral orbit (two electrons in the field of three
n~,clei). This orbit is more stable than the usual C-Li bond. For the
initiation of the polymerization of ethylene and its derivatives under
pa--tj-cipation of R-Li or AID) the formation of a complexl(i) is
V(
Card 2/4

81733
A,n Investigation of the Nature of Secondary 3/02o/6o/133/01/49/070
Chemical Bonds B004/BO07
assumed on the basis of these conceptions. Together with V. I. Smirnova,
the authors proved the formation of radicals in the reaction of TiCl 4
with R-Li by means of elootron paramagnetic resonance,, The formation of
complex (I) is proved by the colored complexes of ethyl lithium with
styrene; a- and fl-methyl styrene and other unsaturated oompoundsq which
are characterized by an intense absorption band of the C=C bond. The
authors discuss the formation of secondary bonds under participation of
undivided electron pairs in the complexes R-Li ... X (X - 0~-~' N!::~' etc.)
-Cr
the 1,n-conjunction Li- C-CjC- in the compounds of benzyl lithium and
fluoy-enyl lithium as well as the participation of the O-Li group, O-Al
group etc. in secondary bonds in acetyl acetonates under formation of
ouasiaromatic rings with participation of n-electrons.lAccordingly, there
exist various types of secondary chemioal bonds,-w-Fl'ch manifests itself
in the physical properties and in the reactivity of the compounds. There
are 13 referenres. 10 Soviet, I British, and 2 German.
Card '1/4

81733
An Investigation of the Nature of Secondary S/020/60/133/01/49/070
Chemical Bonds B000007
ASSOCIATION.~ Fiziko-khimicheskiy institut im. L. Ya. Karpova (Physico-
,:,hemical Institute imeni L. Ya. Karpoy)
SUBMITTED: March 25, 1960
Card --;'4

KAZENNIKOVA, G.V.5 TALAWLYEVA, T.V.; ZIMIN, A.V.; SEVIONOV, A.P.; KOCHESHKGV, N.A.
Synthesis of side chain fluorinated vinylnaphthalenes. Izv.AN SSSR.
Otd.khim.nauk no.5:835-838 14Y 161. (MIRA 14:5)
1. Fiziko.-khimicheskiy institut im. L.Ya.Karpova.
(Naphthalene)

f 1

l
L
Ll t

25041
S//0,' 2,,"C" /Or-~0/0061`00 ~/O 11 C,
Fluorinatel styrenes. ~l e f
c o m -`,ours s o r ed re t -..'rcn Tl~e styr~-~nes -wore L;nialyzed Ly the TE~thod of
A. V. -.~irnln e~. i I I I S S R 7 8 4 Tnere Fre I -.1-1e -.tad
6j r, e, r t n,,, e 3: v I e t!d 'D rl C, 11 - Z; 0 V I
I ;i n,--,) i pol, 1 1 ul!~3 I f~ a d f i., I I P T~i r ra t L A, i- n ~- r
ilmc.,r, Criern USA
r I (-..V .1 Po ].,i;!1 t, r. :~f, 1 G B; 10
T a P i. o
Fizi o k i i in c ie s'- y L r: t i t u T. a P,;
1 1 1 U T i f:.,- r L a r r, v
A r,ri I
,,-rd ",~i

fj* T" n
a c
t Lc7i r d 1 -3 t 1~:i I a T. i j
I L. 7,
w
- L
a I e to c n o n f~ s f t e d emi e r tu s t:- v, e r. a n d 2.) e r
ll~-3uitini3 1r. -, ,art -Lar; -ar, an j C
I V 4 1. -1 r - Cl n.

v e 3 t
b c,

25042
S/062 61 1000 '006/00,1/010
Fluorinated styrenes. Report-, B 11 8/B220
-English-language nubUcations read as follows% 1) P. Tarrant, R. Taylor,
0 -
j. Organ. Chem. 2,1j, 2138(1958). 2) K. T. Dishard, R.Levine, J. Amer. Chem.
Soc. 78, 226S(1056); 77, 3r~5c`(1955); I. D. Park, R. E. Noble, I. R. Lacher,
Oraan. C heir, . 2 T). A . Rausch )Y. Lovelac e, L. E. Coleman,
A. Y. Lovelace , T
Amer. Chem. Soc. 79, 4;753(19t--77); J. Organ. Chem. 21, 1326
(1956). T. Mc.Groth, R. Levine, J. Amer. Chem- Soc. 77, 3656(10155)-
ASS'Q'IATIONI: Fiziko-khimicheskiy institut im. L. Ya- Karpova (Physico-
chemical Institute imeni L. Ya. Karpov)
SUBMITTED: June 1, 1960
C
"ard 3/3

- I , , . .--- - .. I I - ~ - I, - . - 'L - :,~ -, ~, L f , ~ ~
- I - . - - ;-~ :- , .1 :. I. -~ ~ . *~ ~ 7 -. - - 1 -.. I~... I - , - I

TADUAYLIIA, T.V."IQDIONDV, A.N.; KOCIIESHEOV, K.A.
Solu'-i,)ns of' aromatic organolithium compounds in ethers. Izv..-d;
SSSR.Otd.h-.him.nauk no.11:190,0-1996 N 161. (MIRA 14:11)
1. Fiziko-khimicheskiy institut im. L.Ya.Karpova.
(Lithium organic compounds)

S/020/61/136/002/024/034
B0161k6o
_T,a1a_1ayqva, T. V., Shigoring D. N., and
AUTHORS: Rodionov, A. N.,
Kocheshkov, K. A... CorresponcTi-Mg-M-emb*-r AS USSR
TITLEt Study of the Structure of Complexes of Organolithium.
Compounds With Ethers by Infrared Spectra
PERIODICAL: Doklady Akademi4i nauk SSSR,. 1961, Vol. 136, No. 2,
pp. 369-372
TEXT: The authors wanted to clarify the effect of ethers upon the
structure and the character of complexes of organolithium con-pounds with
the ethers. For this purpose 'they took infrared absorption spectra in the
two-beam spectrometer type H -800 (N-800) featuring a NaCl prism. The
follo,~ing compounds were examined.- methyl-, ethyl-, n-butyl, phenyl-,
o-, m-, and p-tolyl, p-Cl- and p-Br-phenyl-, mesityl-, and fluorenyl
lithium as well as the etherst (C 2H020' (n-C3H7)20' ('so-C3 H7)20'
(n-C4H9)20, and (iso-C 5H1020 . Table 1 gives the vibration frequencies
Card 1/3

Study of the Structure of Complexes of S/02 61/136/002/024/034
Organolithium Compounds With Ethers by B016~Bo6o
Infrared Spectra
(cm-1) of the C-Li bond in fresh solutions of the mentioned organolithium
compounds in the five ethers. Some of the former were synthesized directly
in the respective ethers. The authors compared the spectra with the data
obtained from their previous studies (Ref. 1) and in this manner assigned
the absorption bands to the vibrations of the C-Li...O groups. The con-
clusion is drawn from an analysis of the data in Table I that almost all
of the fresh solutions of the 11 substances mentioned display a similar
spectrum in the same ether. The replacement of one ether by another has a
remarkable effect upon the position of the C-Li ... 0 group bands (Fig. 1 B).
The analysis of the spectra proves that the more complicated the radicals
used in the ethers, the farther, the C-Li ... 0 bands will be shifted in the
region of shorter waves. It is inferred from results obtained that during
the dissolution of organolithium compounds in ethers the primary com-
plexes are deformed and decompose due to an acceptor-donor interaction
and a dipole interaction with the ether. Subsequently, new complexes
according to the acceptor-donor type
Card 2/3

Study of the Structure of Complexes of 5/020/61/1~16/002/024'034
Organolithium Compounds With Ethers by B0161BO60
Infrared Spectra
Li R\Li + 0 R Li/ R Li 00 R1 ->R-Li ... 0'/R1+ R-Li.
R R1 R Ri R 1
are formed (depending on the structure of the radicals of the two com-
ponents) between the molecules of the ether and the organolithium. com-
pound. In this connection, the polarity of the C Li bond is increased with
increasing stability of the new complexes. In the authors' opinion, this
is bound to express itself in a change both of the reactivity of the
organolithium compound and its stability in the solution. This circumstance
is believed to be the cause of the high activity of ethyl lithium in many
reactions in the ethereal medium as well as of the poor stability of this
substance in 'the same medium. There are 2 figures, I table, and 8 ref-
erences: 4 Soviet, 3 German, and 1 British.
ASSOCIATION: Fiziko-khimicheskiy institut im. L. Ya. Karpova (Physico-
chemical Institute imeni L. Ya. Karpov)
SUBMITTEDj September 14, 1960
Card 3/3

S/020/61/136/003/018/027
BO!6/BO52
AUTHORS: Simonov, A. P., Shigorin, D. N.~ Talalayeva,__T. V., and
Kocheshkcv, K. A., Corresponding Member AS U35H
TITLE: Examination of the Structure of Lithium Alcoholates by
the Method of Infrared Absorption Spectra. O-Li...O Bond
PERIODICAL: Doklady Akademii nauk SSSR, 1961, Vol. !36, No. 3,
pp. 634-637
TEXT: The authors examined the structure of R-O-Li bonds:
tert.-C 4H9OLi, CH3OLi, C2H5OLi, n-C 3H7OLi, and n-C4H 9OLi. By measuring
various properties of tert.-C4HqOLi (under the collaboration of V. N.
Vasillyeva.. V. A. Dubovitskiy, and 0. V. Nogina) the authors found that
the O--Li bond of ter~.-C4H901,i is of a co-valent character, and the latter
associates already in weak solutions. This was proven by infrared spectra
in crystallized state and in solutions (Table 10. in hexane, CC14,
cyclohexane, dioxan, di-, and triethyl amine, these spectra hardly differed
from those of the crystallized sample, Therefrom, and from 'the
Card 1/3

Examanation of the Structure of Lithium 3/020/61/136/0031/018/027
Alcoholates by the Method of Infrared B016/BO52
Absorption Spectra~ O-Li...O Bond
indifference of tert.--C,..HaOLi toward active solvenss and temperatures
betweerl, - 70 and -800C the authors conclude that it5 complexes are very
constant, They attempted to ex-plain the existence of such solid complexes
as follows: ?.-three-center intermolecular electron orbits are formed due
zo the fact that the Li atom of a molecule gives the free D-orbit to those
electrons which take part in the O_Ti 0-bond cf another molecule.
Consequently, one pair cf valence electrons takes part in the formation of
two 0.--Li...O bonds (see scheme Ia); 2. an acceptor - doncr interaction
sets in during which the unshared pair of p-electrcns of the oxygen atom
uses the free p-orbit of lithium ir, another molecule and thus additionally
intensifies the intermolecular bond (I b), From the luminescence spectra
Cf tert-04H90LI (crystals and solutions in hexane), the authors conclude
'hat either one electron changes over from the multi-center molecular
orbit of the ground state into the excited multi-center orbitg or that the
system is excited by the passage of one electron of the unshared pair of
the oxygen atom into the multi-center orbit. The four other alcoholates
studied, were spectroscopically examined in crystallized state (paste in
Card 2/3