SCIENTIFIC ABSTRACT STEPANOV, B.A. - STEPANOV, B.I.
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CIA-RDP86-00513R001653130008-4
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December 31, 1967
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SCIENTIFIC ABSTRACT
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Redox Potentials of Dithiophosphates SOV/"6-33-8-.27/39
pentasulphide (Ref 9). For the determination of the (HP) of
the dithiaphosphates (DP), two methods were used - a determina-
tion of the equilibrium constant of the oxidation reaction
of the (DF) with iodine, and a measurement of the (RP) by
the compensation method, The results furnished by the former
method for an initial concentration of the (DP) of
1.85-10"' 3 g.molll are given (Table 1); as well as those obtain-
ed by the potentiometrical measurements of various (DP)
(Table 2). In order to determine the accuracy of determination,
the standard potential was calculated by, means of an equation
(4) for dihaxyldithiophosp4ate and comparedL.vith the experimen-
tal data (Table 3). The reversibility of the oxidation process
of the (DP) with iodine was found@ and-the standard-(R?) of
alkyldithiophosphates was determined for systems in which
liquid disulphide was regarded as standard state. The effect
of the length of the hydrocarbon chain of the (DP) radicals
upon the magnitude of the (RP) was examined, and an appropriate
equation given for calculating the (RP) as a function of
the carbon number of the radicalu The influence of the iso-
structure of the apolar group of the (DPI upon the magnitude
Card 2/3 of the (RP) was also found. Furthermore, the solubility of
Redox Potentials of Dithiophosphates S.OV/76-33-4-27139
dimethyldithiophcaphate disulphide in water wap determined
at 250C and a formula for the calculation of the solubility
of dioulphides and other (DP) was suggested. The standard4n)'
of the homologous (DP) series for the standard state (di@
oulphide solution in water) was oalculated with an activity - 1_'
There are 1 figure, 3 tables, and.19 references, !6 of which
ax-e Soviet,
ASSOCIATION, Urallakiy politekhnicheskly institut im. S. M. Kirova
(Urals.Polytechnic Institute imeni S,, M, Kirov-)
SUBMITTED: February 11,, 1958
Card 3/3
AVSARAGOV, B.G.; NAGIMEAK, F.I.; SIFMOV,_-B.A.
Ways to increase the complete utilization of copper and copper-zinc
pyrites of the Southern Urals. TSvet. met. 34 no. 4:1-3 Ap 161.
(14MA 14:4)
(Ural Mountains-Pyrites)
KLEBANOV, O.B.; SKROBOVA, A.V.; MANOV, B-A-,
Using residues of electrolytic zinc plants for copper deposition
in the concentration of oxidized copper ores on a combined flow-
sheet. TSvet. met. 35 no.11:36--17 N 162. (MIRA 15:11)
(Copper-Electrometa3lurgy)
CHAKHOTIN, V.S.; UDALOV, L.K.; STEPANOV. B.A.
- --
Use of natural gas at the Almalyk copper melting plant. TSve*,.
met. 35 no-1149-51 N 162. (MIIU 15sll)
(AImaljvk--Copper-Jbtallurgy)
KLEBANOV, O.B.; NESTEROV, V.G.; STEPANOV, B.A.; KORFSHKOV, G.Z.
Using the original ore to reduce an excess of reagents in
flotation. Obog. rud. 8 no.2:5-6 163. (MIRA 17:2)
ZUBKOV, A,A.@ STEPANOV, B.A.1 CHERDYNTSEV, I.Ye.
Draining of copper cement concentrates. Izv. AN Uz. SSR. Ser.
tekh. nauk 8 no.505-77 164. (MIRA 18:2)
1. Sredneaziatskiv filial Gcsudarstvennogo nauchno-issledovatell-
skogo instituta tsvetnykh metallov.
tITZITMOVO V.0111 STNI'mov, @PiAlk
Thvestlanting the deewptlar, of butyl xwthato ft-M galmite
by mate minerals during flatatIcne IW* All Uss Me Bar.
taklu nauk 9 no* IsObW 965 (RIPA 1911)
1. SuInittod J%=h 25t i964o
STEPANOV, B.A.; IVANOV, V.I.; GOLOMZIK, A.I.; NAGIRNYAK, F.I.
Microbiological leaching of sulfide ores. Fiz.-tekh. probl.
razrab. pol. iskop. no-4:118-121 165. (MIRA 19:1)
1. Politekhnicheskiy institut, Tashkent. Submitted March 2, 1965.
STEPANOV, B.A.; FOMINYKH, B.A.; GAREYEV, V.N.
Series of metal stresses in the solutions of alcali sulfides.
1zv.AN Uz.SSR.Ser.tekh.nauk 9 no.5:75-77 165.
(MIRA 18:10)
1. Sredazniprotsvetmet.
STEPANOV, B.D.
Organizativakh Proizvodstva Na.
Nyasntkh Predprivatiyakh. Organization of production for the Meat gnterprise
Moskva, Pishcheprohitdats 190
158 p- illus., Graphs
STIPANOV. B.D.
[Organization and planning for enterprises of the meet Industry]
Organizataila I planirovants prodpriiatit miasnot promyshlonnosti.
Moskva, Fishchapromizdat. 1955. 330 P. NLRA 10:1)
(Meat Industry)
@*kTSPANOT, B. kandidat tekhnicheskikh nauk.
@- - -- ;@kt
A@W-- @* - " --.w
r, - .
1,
Planning of organizational and technical measures. Mias. ind.
SSSR no.2:35-36 '57. (MLRA 10:5)
(Heat industry)
STEPAITOV, B., inzh.
Administration of packing houses without sections. Mias. ind. SSSR
29 no.2:45-46 158. (MIRA 11:5)
(Packing houses)
STEPAINOV, B., doteent
"Science Day." Mias.ind.SSSR 30 no.6:22 '59. (WRA 13:4)
(Meat industry-)
STEPANOT, Boris Dmitriyevich; DONSKOY, Y.Ye., spats. red.; MOISEYHY.P.N.,
spots. red.; 1107MI11A,-V.A., red.; KISINA, Ye.I., tekbn. red.
[Production organization and planning in enterprises of the
meat industry] Organizataiia i planirovanie proizvodstva na
predpriiatiiakh misenoi promyshlennosti. Moak-va, Pishchepromizdat.
ig6o. 383 p. (MIRA 14:5)
(Meat industry)
SMKOV, V.D.; ST,31PANOV, B. D.
Strengthening the creative collaboration of science and industry.
Izvevys.uchebezav.;yishch.tokiL.no-5:175-176 160. (MIRA 13:12)
(Science) (Food industry)
STEPANOV, B.G.; ZAKRARCHNNKO, B.F.; BEZEL', V.S.
On rotating plasma. Zhur.ekap. i teor. fiz. 34 no.2:512-513 7 '58.
(MIRA 11:4)
1. Urnl'skiy politekhnicheakiy institut.
(Gages, Ionized) (MAgnetohydrodynamics)
011ectric discharges through gases)
AT6o36573
-Kalinina, A. U.; Stepano,@,_ B. G.; Shugam, Ye. 1.
_tj: none
Visual ition and visual determination of the degree of similarity
image recogn
botween image per presented at the Conference on Problems of Space Medicine held
sT
in Moacow from 21; to 27 May 1966)
SOURCE: Konferentslya po, problemam kosmicheskoy meditsiny, 1966. Noblemy
kosmicheskoy meditsiny. (Problem8 of space medicine); matorialy konferontaiip
Moscow, 1966, 188-189 1
TOPIC TAGS. vision, pattern recognition, space psychology, visual test
ABSTRACT: In previous experiments, one of the authors, using a special
Ielectronic assemblys observed an artificially retarded process of
pattern recognition. Based on this observation, a description of the
characteristic peculiarities of two approaches to recognition was
given:- The use of one yields a small number of errors but is charac-
terized by the retardation- of the rec6gnition process; the use of the
second is characterized by more rapid recognition but a higher number.
of errors. After analyzing the experimental data, it was proposed
that under certain reception conditions, the speed of recognition pre-
vailed with no substantial loss of accuracy.
The verification of this observation was one of the purposes of
jhe present investigations. Another aim was to reveal the nature of
L 10954-67
,kd_Wf _A_T
connection between recognitior@ and the similarity of certain patterns.
Simple, contour patterns were used. The contour was broken down
into portions of equal length. By erasing various portions, lined
patterns containing various amounts of information were derived. The
position of the lines was arranged using a table of random numbers.
The patterns were arranged in three groups according to the a-i-nount
of information. The pattern presentation proceeded from a to a
'large amount of information. The order of presentatidn - within groups
was random and uniform for all subjects.
Two series of experiments were conducted. First, tests for re-
cognition of graphic patterns were conducted. Here . the two methods
of recognition were revealed aInd it was demonstrated -that the second
method had the advantage of higher speed and quantity-of test objects
to be recognized for the majorityof patterns in a given class.
To solve the problem of the link between recogi)ition and
similarity, a second series of experiments was conducted in which the'
similarity, of a pattern to its standard was measured. It was -necessary
-to compose a series with progressive similarity, L e. , each subseqi@ent'i
NR: "AT6036573
t.'.orn had to be more similar than the preceding to its standard. A
1111.1115or was assigned to each pattern. The distribution of numbers
assigned to a given pattern by various subjects was constructed and the
mathematical prediction and dispersion of distributions was calculated.
Later, the mathematical prediction was used to evaluate the degree of
pattern similarity with its standard. After processing these results,
it was possible to isolate 9 of 20 patterns in each series which signifi-
cantly differed from tile standard.
Ex-perimental verification of these patterns according to the same
scheme used in a preceding test showed that of ten subjects, eight - -
assigned a given pattern the same number and that the distribution of
pattern numbers in the abridged and un.abridged,.series was identical!
[W.A. No.'22; ATD Report 66-1161
SUB CODE: 06 /. SUBM DATE., OOMay66
Card I
Ivanov, S. N.; S rtsova, N. Ye.;
ORG: Insti-tute gr 1 radlotekhnW
i elektroniki AN SSSR)
21, V
TITLE: Investigation of GaAs p-n junctions operating as converters of ultrasonic
oscillations into electric oscillatlo-ns
SOURCE: Akusticheskiy zhurnal, v. 11; no- 3, 1965, 398-399
TOPIC TAGS: gallium arsenidep semiconductor diode, pn junction, acoustoelectric
transducer, ultrasonics, frequency dependence
ABSTRACT: The authors investigated the performance of GaAs diodes to determine the
effect of the gegmetric dimensions of the base on the efficiency of such a diode as
" lu'ttansducer. This influence can be investigated by vaxying In definite
an ultrasoh c
fashion the relation between the thickness of the base and the wavelength of the ap-
plied ultrasonic oscillations, and observing the frequency dependence of the conver-
sion efficiency. The measurements were made at frequencies for which the wavelength
was approximately equal to the base thickness. The diodes were prepared by diffusion
of zinc in n-type GaAs plates and tested by applying rectangular ultrasonic pulses to
the investigated diode through an ultrasonic delay line (Fig. 1). The output-signal
voltage was found to exhibit a definite dependence on the frequency of the ultrasonic
oscillations. The transformed signal had a maximum when the thickness d of the diode
L 12069-66
ACC NR, AP5021483
Fig. Diagram of test setup.
q I
I - Pulse generator, 2 - quartz
plate, 3 - tested diode, 4 delaX_
line (10 microseconds), 5 -C
oscilloscope
base region was connected vith the vavelength X by the relation d i(2n + 1)/4
(n - 0, 1.9 2.* ... ). In the experiments d was equal to 1.7 x 10-3' cm.- making it poa-
sible to observe in the 7-14 Mcs range up to six frequencies corresponding to the
maximum of the converted signal. This relation is similar to that of a compound
vibrator., and it is shovn on the basis of several other properties that the model of
the compound vibrator can be used for the analysis of the performance of an electro-
acoustic diode transducer. The conversion efficiency depends on the choice of the
geometrical dimensions of the diode. Orig. art. has: 2 figures and 5 formulas.
SUB CODE: 2o/ Sum DATE: o6jul6k/ oRiG REF: ooi/ o7H REF: oo6
ec"I
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9. Monthly List of Russian Accessions, Library of Congress, ju-rv. 195X, Uncl.
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STITIANOV, B.I., dotaent; BOKOV, V.N., dotsent. red.
(Lectures in the course of machine parts; brief information
on interchangeability, toleranceep and fit@) Lektaii po kursu.
detalei maahln- kratkie evedentis po vsaimosamniaemosti,
dopuRkam i posadkom. MoBkva, K-vo vysehago obrazovaniia SSSR.
Vses.saochnyi energ.in-t. 1959. 40 p. (MIRA 13:3)
(Mechanical engineering--Study and teaching)
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,eally any raw. It is finally shown that the nrvr%,icy 4of
taking into arcount a third intrriArling levtl greatly hain-
javrs the computation of lite const. of the 32; h-vel.
Frank Gonet
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the Triplet State at Sigma in the Molecule CO," Zhur. Fiz., Vol-2, No.3, p. 201, 1Q40,
Lab. of' Molecular and Atomic Spectroscopy, State Optical Inst., Leningrad.
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00 .
al. i
icva, of a
nt with ob-d perturbations in the $Mtrm Of @00
Call. N.. S,-d-,kN- G. NI. Murphy
so
so -00
00
so .00
00
00 =so
00 -00
so zoo
00 io 0
00 41
600 0
z;O 0
Sao
xoo
too
t!o 0
I L .1 t.LLLrGKAL
S We MATUME CLASSIFKATKh
too
ISI gas
U SS
LO
It ff it CC
0 oooo*:Ooooooooooooo: :::iooolooooo
: *ooeeoooo
:1
0000010000000000000 1099909000000006666
a 9 M 0 [A&'M-Ak M-"-M M's 0 a V V V W V IF V V V V - V - -
15 @jj j; if 1) 13 M is hS v M M 40 41 M A) as a VL_
50 "
p, "!r L
so
'06
Vo
too
-00
see
C
=00
Pnimbetions In molocular xpectra. a_L__Sgapa@- 17- A Ittt wk, -00
Hidl. "ad. jri. U. R. S. S., Sir. phys. 4. cf. coo
C. A. 34. W46I.--Several cams of perturbation in the spec-
tra of diammic mols. were investigated. For the caw of 'PI,
interaction between a given level anti the neighboring vi-jr
brational level% a method for the calen. of the rotational
j ronst. is developed. Thiq mcth(mi k applird to the njolt.
CO, flail and CaD. For CO mobt. the 1wrturbation't ,f
the vitirstionallevel-twcreititificil. Unk.-tilatiaGarnow
zoo
see
__oe
too
I L A of TALL.,'@,K" LITEROLAE CLASSIFiCATICh
Noe
_T -5 S a 1.d 0 4 4 1 ur 0 9 a a 3 1 T
$1 ts IT '0 it .10
0 it if tt a (I q a Pt 19 it at x n i ju
0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0 0 0!0 0 0 0 0 0 0 0 0 0 0 0 0 9
'0
-9000
T nin@7ad
Le
:,aboratcry of Ycl@@cul!ir inz@ @t:lfe,
"The Oscillatory S'pectra of Hydrocarbon Molecules." Part II. "The Frequencies
of Valpnce Oscill.-itions of a Carbon Chain of Molecules of the Paraffin Series."
Zhur. Piz. Khim., Vol. 14, No. 4, 1940.
3TT q @' M. T - ; -14 -TT T- - - . - - - - - - - - - 7 -
ti Ar Lk- - -z.- -- - - - -- ---- --- -- --- -
A
N M PD U
- - - - -- a
7-
A AL A-L-1 -L A
41 4 1t @I. k
-A-,I -L L it Is F 9
Resonance perturbAtions in the spectra Of dIAWIME
mOlecules IL I. Str;NIII- J Ph,, it' SS I? 1 4.
go -A 1 21( I'M 1: S, ifn,r fl,,ft-tf 45A, I
* "
'It 111, 111 \ '11, 111 X '11, 'It "f
go
of ... . ...
PhIlled. mu ".1111-ill-41 I., 'JI'm Ow 11111.1
1.-11.,11 .-1 14.1 l-1, 0 aliv 111,111114" it
00
00
00 see
of =0
0:
j
a
J:
00
too
A II aS I. A NETALLUOGIC41. LITIMATUSE CLOUPICATIO16
he
- ----- - - --------------
S.111.1 -41 a., it,
---- -- -0@Clw Ar &1 43
3 9
r' 1, 'Via sit Mgt K gilt Iraq-Lon
00 0 0 000 * 0 If 0 0 0 0 4110 0 0 0 llit
0000 0 0 so *of* 0 0 0 0 0 0 0 sees 0 0 0 0 0 1/
d do ke"S"m
it.
tie
iA@Ilrvstsch and 11, 1. Str Iaftj P S
I'll) , 1941, 5. 103 1,17) A 111khm 13 t.thu!.Iting
the VII)rA h'n @etjucnries of polyAt. I_, th.-
1-0-1 I.Itt'll'.1t If., '111', Coll. i% mutcr44111 I it
- - - - - - - - - -
I. is 16 F1 I-JM,T 77 71 ZY 0, a
so aIt P tt4 T t-
41114111 ---- ,I ,
00 J1
00
so
Vibistiom spetum of hydicicarbou molocultim. V CAI
culation of 11" ft"Meades of valence miscillfillous of carbon
00 0; rigg. J1. 1. Stepanov. J. Pbp
cbsiss of the GIA�k w
(,ktm. (1:. S. S. R.) 15 -797"M I)--- t 'ling 211
quation lirrivril fly El'ya'llevivit W. A. 35, 2117111
0 S. vale'. the o'cillation ItrqlIelivir, Of tile hirdr--ati,oll
@ Ismill. of I fir willpIr olefill, Is m 'llown thm tile Charm..
IM111C IrVjUVI1CY Of 113C d-Aable NIIIII il A 61111-16.11 111 OW =00
I tire and no. oft he nciShborinig bond, but i, isniqwod,ii I
the drSrec of 1wanthing I)( all furtht-r-frinoved part, of i;* 0
00 fhe inol. 71tv differrner Im-1wt-rn the obwrv"I and Oil
:-alcd. frrqtleeci@ I* alloof 13 1-11). 1 in tmixht@haio =00
00 Z40 0
ooijul% 4od tru-mi-i 1,# 12 cin for doublv braw-litA
.drfio, If Nallsolmoo
1000
Nee
@0, C301111
tie
-7-W7-
14 r Nee
4 j.,
a 'N LID It 8 1w 0 -01
0 0
goes 0 0 t
--G III Go agog CO 00090 9 4jPW owwwwwwww-w- -
Zi - ; I . I . I . . 1, 1,11 1- .11. 11 1. 1- IJUJUIS J417 Uncif
A,1 L L L I L, U 4-1- L 9 P I, I k i I k,4 i
-Oo
-00
00 lee
Oscillatino spectra of hydrocatbon molecules. Calcu- -00
tion of the potential-enere constants from the ouilts-
d
I
ion frequencies of methane and ethane molecules. R.
..
I -"It-pa1mv. J. Nvy. Chem. (11@ S. S. It.) Is. W", "I
041 11911); d , t'. .1. 3i, Kr,ultN of the valvii, aw see
J, 'howl III IIIC IkjIIIv-,.
zo 0
00 00
00 ;lee
Go .700
ze
00
lp
S I L I A L t AL I? 1 4 A fi,@ f rL LISIF 1CATfCk tre 0
i
l
2
0 It K R it it "T
W n
if 11 IF A
K a
0 *10 0 0000 41110141 066 0 0001000, a 0 0 0 00000 *Gee of 0 4
0 0 0 o 0;0 0 9000 * 0 e 000 0 0 o,,O.o 0 Ole 0 0 a 0 0 6000 0904
Oat I I I I 1 11 u tj 4 tb
K. r a A I I v
1316
of prepm 'd
bob- FLIANIMUM, AND S"PAP", it, Cft.
a V Anw. Jw. vm,
Wl.
fi*i=c(tm"wdmdhw
fftowndu of
'm 4a @--Nx
IW Cakablien
WAM wah (or nwham
and echww OW ttAir
am
rand w" a
1@
Vithm rqw*wft-ia%
00 Wor"at MW &As" "M VAVkl4d With Old ilki
"W knmm 90 Of (0" Cullstalits. Qmd Srvg@
00 fflem with oqmdmmw vgbm aaa Oks,,A kdwo
to a 4www jhWAMW Or frequw"imt,
00
4
A. 1. T.
o
V
l$ X
11:1" me,
AD
0 ell Is, It a
0 ro, no 0'
A41
46O994O49::::::ee
L j; L uId n IF 11 IF
l' I@ 11 " a 9!*
A 1 T -A, A-
AA M
of 4i I.E;I.l . : -00
00,
06 9
go'
I make of udep". 10L M
Efi&Khe%,dmdM.d Te
M
A
j
d b -00
Of do
1
1 .
.
m
W&
61 MM m
-.%-
-Fre-
14$==T38)
1943
17
Ch
R
3 1-
. S
i .
em.
oss..
.
.
tepanov U.
dt,
on the basis ofthose of CH
we cak
f C
H
H
.
m o
quenc
. an
,,
.
,
ement with
A
l
ogues.
gre
and Q1. and their heavy ana
T I It
00 fr"luencies is satisfactory. zoo
ro
00 voe
A14,
1300
Ate ILI DITALLUCKAL L,Tf*ATL4[ CLAISIFICATION
111, 1, K) I
u
,
t Ru staft Itag
w W 0 1 W 9
114- a Aj IT T
mton 1
I it IF OF W
i
( :
4 0
r 0 0 0 Ole 0!
p
o 0 00000000000010 goes 606 go see go go 0 0;
7- -1 T 7, @ 7. @ @ - - - 17 j
AA r- 'ILC Ltal-hil .1?4 IQ$ iR4._1__L
00 d Debwai"M d POMM min
" Wmelawthau& 11. 1. Strpan,w (C
'
* 19,Ll. 49, 2.,U-2-d2)-TW
Weiieral
:
9 vibrational " of polpAt, mole. given
1. 193) has beca applied to the compl
00 13 bromo-methanes. A comparison of
00 0 1
00 'A
eadb ompt.
ete
i t
AS-tLA attALLURGKAL LTINATURIE CLASSIFICATIC06
(PAIIN sit 149 MOO Her
0000 0000000
6001118@ for UkM &dv-
reisd. Arid. Ses. (I.R.S.S.
wethod for the calculati@,n 4
by Eliashevitsch (cf. A.. 1142.
series of fluort), chloro, and got
the vAle. obtainni is attern
zoo
goo,
t!oe
200
Ez., tgoo
S 9 1w 0 1 1( &1 5
0 0 0 0 IS 0 0 s ee 00 00 a
--w -
00
jr
a.-
00
00 Ir
w 9 W 9 IF 9 OF 9 OF Is Is w a Is 0 w F01201, w lwlwlwl@w w1w1w w - w - w - w
L., JD 1 11 n a u is IA V a .4, x 11 V IS JA t 14 V It it 46 &1 Q AJ AS JC
et A S. I I k j 4 '! # P - it.- -.1,
A- -f@ -rm
-.00
1-06
Calculation of mkwwn vibration spectra of balwn- t
1@90
balitated methames. 11. L StelQUOV, L'OmPl- rf"d,
und. iri. U.R.S.S. 45, .54-7(1944). @-71trorctically ralvd.
vallue, are recorded for the vilxat ion of frequmiriti C I I i fir F.
ClIfirl", COllf.F. cc[,BrF. CCI[IrF,. ClArY. ClirF.,
Slid CCIF1. It A.
0
00 J
00 ze 0
00 a 00
go. coo
0011 goO,
.,see
!see
Zee
oil
t@oo
.(TACLU14KAL LINNArtm cLA wFic,itich Ur. we*
Si
._A:
a., Q., 41"11 ut 4ft. 411
IF-
(P It a, Or K ME If 09 n I ..a IN 'j
ef
di 000 0000 0000000
*&I I ; ; 4 1 4 7
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A
00
00 A j
00"
00
00
0
0
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00
00
00
0 0
M is Is V M " a nil
P -g- a 1-1 - 1111, 1 -14 11-134 1,., -.9 1, MI, 11 , I,
IT AkV IND CADIRS
Spectroftolsic method (or like determination at tho
hasil of the hydgfg@n haled. V. I. Malylhey. a, 14
16. U.N.S.S., SO. thyr. 9, &1,-
A-
IwArance of band spectra Is attributed to complei for III
(iun in akohols due to the "hydrogen band" In the Mf
radical. The beat of the bond is cakd. to 13.0 kii.-cal.
per tual. from intensity trwAsurentictib of the spectrum in
soins. of Clf,011 its CCI, at different terup. S. Pak%wer
Rated*" in the spectra of molecule& with hydrogen
bonds. H. 1. Stestanov. Ball. aead. sci. U.R.S.S.. Sir.
Pustulation cd hands
its liquids with linkages Oil.. .0 6 TIJIlAincil through di-
cussion of their potential-mergy curves. S.P.
j4'J' &IN-ILA WITALLURGICAL LITIR&Tt*t CLASUPKATICIN
It J,., 1.0A080 -A 11304k) 41F ONY 04E
I @rw
:AT Soo is
oo 0 0000000000000*0000000Ooooeoooo*eoo*Oo
00000010000000000000*ooooooooooooooooooooo,o::Il/
11 U is
Jill MIS 1917ARC Z; IP
L__ -. 1 -1 _!@
.-D 1 1.0111
,00
_60
.00
-Go
-00
.00
T
ro 0
00
900
400
800
gool
woo
ISO*
tlowl woo
4,11"at 419431 am a.- all
Lw Is 1 14 Ali A I a rhd 0 a WIN sfi-dw-d _too
-0 9 0-0 -0 0 0- 0 -0
. I . . . . . . .
Is j--A--L
:0
0 0
0
:0
0.
0
0 a fit M A #A 0 st W a
n I,- YT-M@@@ X V 17 IT
p-, r x AA
-00
ftediftacladoct 41 a system of discrete levels. It. 1.
NI 1 114 (USSR)
ys
wpli-on hamis it nuskO out fiv the
rhole seeks W ckmfly litinotell d6c"te levirls, and Ab.
winkon CurvTo -
of different
0
I no.
cjk@,.
00
rhe dependence of obwxplkwj an The magnitude of the 00
inatrix element and on theinteraction of,liwreteand -,,2.
finuous levels 13 considervol. JU nnIditions of con,plete roe
ififfij,ion of the vibrAtIonal structure of the tIK%-trwn ar,
Prutik 6,snet 00
CLASSIFKATION
&S-SLI .11A111111 Al I
V% A, of
V, IF Op be IN 41 111 9
0 00 1949,1010 of *4
: : a
so 0000 00 9
Zoo
ago
coo
i-go
7.-0*
tz
A
An I a
n
4w
0 0000600 0000 00000
: : 0 0090900
ST]EPANOV, B. I.
"The Theory of Vibrational Spectra of roiyatomic Molecules, II. Computation of the
Frequencies of Halide Derivatives," Zhur. Eksper. i Teor. Fiz., 15, No. 1-2, 1945.
Lab. of Spectral Analysis, State Optical Inst., Leningrad.
7
A A
got,
00-rA
9
fl
V lw IF - - . I
7 77-77777 T T 7till it 111v )I
6
C &.4-J _f. L 4 14, j v 1, 1. -A 1. 1 " K Q;
14 and lolpfPfflation
114111peulps 1 memylalrobol
S 14 N 41 11 K, WMI
ll..1swilvi., .4 ill'. HIIIIIIII) Wit, 4 00111.
mul
AS. IL tlAkLlf:GK.l IMOAlt"If CLOPFICAMP
It It Ct
I-A
X90
t-00
UZ tie*
M L Ni 6-
n I
W - 6 - # - q i 0 0 0 0 0 a G 0 0 a 9 * OWW-TE-W-w@-r 1- r! -
0 24 6 1i
It to 11 It 1, 14 " m @ )I a - RD
Y.a---A- J-L- AA ;P It
OG*
0:
The theo7of hydmvn bond. 1. Jjx*nAtjon of the
9 reg IlAritlea n the IpW,d ot tnoleculve forming hydrogen
:10 bonds, by Prordlowistiots liffects. It. 1. sIqLall'ov (stilte
iowual .1.
'0151: cf,
tog! .
Ll@ I'llif 14% lilt- ()-it link It III till-
st 0 0-11. Whom till, Hook It VIII'llooll, it I-millilIPM4 %to IIIj;j'I' 14
0 of 11111111114. 41111-1 14 joopmllllt@ loot III,. I
1 1 ;
4
Illitm- Italisilkloli frooll a ktubli. fit till till.
@tjfr are Itrobable which fralor tutaflected till, (I
0 see
V%P13in thv diffaiw haticit 0. on this toasi, it i, p0%,ij,1' voe
heir %hifl@ 41tic too %lob,titillilutictt7f 11)1 lomyrneill
Variations.
ZOO
!-00
i CIO*
I L A OfTALLVOICAL LITEMAtkP( CLASSIFICAYICW
(I., jooloo.,o;' _Lj
*0 tloo@*)A- - - - @ 11, 117,,:
La 'a .
-6 1 a
-or- It I
" it is mw Ill I 9A
W3 IS, It
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0 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 so Wo 0 0 0 0 0
ak Ask SooW** 0 a 0 00 $0000100 0 0.
_jwwwwwwww._Wwwww_w_ -
, I I I j a I a 0 6; 1 i U i j ii T5 U -" !; M. r T-ii I m U U x it m a a a At a a a GE40
A I @L 4, L_J A 11- 1 L L h f 9- A 1. 1 _1d 4 9 A I. d I I
00
00
00
00
0 .00
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meth
It
ane,
. Stclialuov. AIM PAV'If"(Awl. U'R.AN,
0
:
0
43 M(lillb)(Rholkh Millimary;_ N4,'111clir 1.*.. CI.,
00
Will 11FAUIA61111CA 111011alitli life. Al"'I. milli I"1111.1ft,l 1.. -00
00 Sevelity-flille f1equell. it, sue talKiLit"I.
00
The fOrm Of vibratimis all(I file 1%1%. .00
Of th-C CIIIIIJK14. ArC (164-IMAIL 500
0
=OO
00 COO
00 a coo
410@ roo
00 V.-O
12 SOO
n
yho
C@AZZ44
goo
0 SOO
goo
1-00
60 cloo
a of TALLUr&K AL LITIO47URIE CLAISIPICAUCII
Wo
. 2 ct
w:: I
0 Ili,.
-------
_
it
.'v C., 044
--
--
- c@; is I
ao@
a It
p t, T
r
j -
j
opm sit Isa Iftfic 110( 0 1
illo A
00000
0 0 0 eie 0 0 9 0 0
0 0 0 001 0* 00 00 00
0 0 0 0 0 Ole 0 0 0 q 0 0 0 0 0 0 0 0
00 0 0 0 *1/
61 11 a, IIJ -11 11-1-1-jL a m P a ai11 -1 ix @10
k' It
06 ir
M
0
:4
17K
0
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00.t
w-Al, 1" 1w
'k IK V V--
1-11, w-t
'
"Valence Force and Central Force Models for Molecular
0
pal,
Vibrations, Zhur. Fiz.) Vol. 10, NO-3, pp. 24.3-51, 1946.
A
00
oos I
oot I
ad a IA 41 2 2 9
07
to P It it at A17 tr 01 2
00*606906006060660004
0 0!006000000000000000
-00
.00
00
.69
*0
.00
400
800
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goo
9 goo
400
goo
'0
i@oo
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i U400
ta 7 r a ts ts, -. T V,, V. W., T Iff, W, IT, T181, 771-yr, 1 11 It U
A I C 1L. A., r . Q L- v AA 00 M it 4-, 1 1
The theory of hydrogen build. Explanstwit of the
refluittrities in the spectra of molecules fointing a hydrogen
i bond. by the predissodation effect. It. 1. v
Oplical just.. I.Clungrad). J. PAY). 0
0 U.S.S.R.) 20, 907-15094f;)(in Rll-ialf); a. Ll
0: :.!*;A01, b!0*0-The txplin4tion givvtt lavvil)(tsly 6 put
'
@
whrtwttinvr e(wation for tile
rue
tit, a quant. imsis.
'
go ,, courdinal- and the
vslcln oil ... o ii -solved tit jacoby
mstilt accounts for tile eflect of file 11 W2111 vill tile witith
and Ixttition of SIVCtruln lines at vart'j", ti,fults.
0 &1 1. ItLk,rulan
0
Y,
f
-0
Foe
ei A I a - S L A OETALLuRrKAL LITERATURE CLASSIVICADOW me&
-go*
L It Q.w v .3,11 -1sk
0 j V
U "Ilo fog taii list -"C An I S a Ad a - - I ar 61 '1 A3
it it it x Za 0 1 wit
0 0 64 q 0 ***sees* 00 00 0 00 *ie 0 * 0 0 a 0000 go * 0 00 0 a 0:
0
0 0 o o 0 0 go 00 go** 0 0009 00 0 0 00 of
7 7 T T 7 7 7 7 7 7 1 17 7 w 7 T 7 AwITT-F-I; r, IT A ,, - .. -
A It L.-I F P it 1- 1 . III T I I-j_ 1_1 a a Ik U i i
.-UM I
Chag"telr6till: firequendes in the spectim. Of complicated
britachad wafts. It, 1. SIVIL41mv (m.at'. (1101, .1 In't.,
.1. Phyl, It 1 :0. 9G -s
R11.1imal). I'll., 'It.
and l,xi
It"Im-liviv,, ill mantAl Iwallill, AT'. CoMI'lled .1111 111~
I"millk'A jmlafliqt@, Xl4mal I"lailm, ISAV,- Ill., Im".
I I Ill ( I)l awl [ilk) k 1). th,4-. ill tit, j.,Itctjtjj--, sitrA.111lit
Ih, -h-li0ty mt ail Airbiltarr 1-1,srallm@ Owl, f1w
list,-. 11111 11 11 Awl 11.0 1 11 IAtallm, 'll ilw Vok,11.1,
V1. hA%, likil"I'l Ill,
.,t tit, , Ill l4 A @ IlAll, A it, I
'At I tic dv(It. W ill, '1141, wt, A A WAmil"I 1,41.41 -
till is Ralluff 'twegillin I, 111ti,trale'l In w%vlal . I.
A 4
. .
.00
00
-o
roe
qoo
-90
:;*0
"'00,
1900
1_10 0
unutchl. Liltaillumit CkAtSIFKATFON,
77 XG0
ONE
Ji-ll aw Q.. ill
g."090 -1 - ; - -
. . q r I - I - P - I - a I V ill I a w 0 so 5 Aa a 3 4
U In 4w va As it It CD Ail 0 4ff N KW n
IU Thettry of Orews"Mitiambs. P. V. MI&LVAIt and H. 1.
Compt. rend. Acad. Sci. U.N.S.S., $4, 791-794, Dec., 1946. --TV Dfw.A@ J4
trierry nbwrbcd in the region of sensitization is much less than that Wedlo
bring in activated electron in the silver bromide lattice into the cLoMwnwAdwtdl
zow. It is suggested that the machanisin of sensi"tion can be cwhiod
supposing that the additional energy is furnislied by the thermal ei@w"Of
dye molecule. Analogous phcnoawns owurri*S in the case of fluoreseme, the
proposed hypothesis has a physical basis.
the lowerinf of the initial sensitivity by st"titi dyes and the nwhasism of
desensitization. 1111C. (based on S. et LP.).
-fi-A-A-L-L a.-It P 0 C V
it A 0 1.;, n-vias
A
:
!
A
00
00 1
o o x I:
6#71 Tho Tbrwy of the opdw somaidwim so nwo-
id
i
M
I
R
P
V
M
AA
i
) w%
.
.
e
uu
an.)
&r and
Mm
n
w& (
grop
1
i
0 eurfo
. Stepaw:v. Roprio */ the Ae4demy #1 Sc
of U-9.S.R.
v. 54
Dec. 21
799-M2
1946
p
,
.
,
,
,
,
(Sm abo AbIL NaL U1, IV)
S 1. A RIYALURWAL LITCOATURI rLASSWKATMOO
Ll S410" Ly 0@1 q&C sill 110" RMII 00 4PIV 119
u is AN PO wl- An
Sal ;a, 11111r@ I I I FM 0 0 4 1 w 41 9 a 4 3 4 1
0- - - - - i - 0 -!T9 # *
f-! ! A to 1 0, OK 1, 11 -1 if 1) 4 if t4 11 X I, -, ; ;; ;; -,, ;; i&II ti * 0 0 0 0 0 0 0 0 6 0 0 0-1w
ll 1.411 Jill MMW41 J.141.41CO
r, L II, r- IL L I, h r Q A Iv 1 1 AA Of Q W f _.I
-
-
-
-
,
-
-
-
-
-
-
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,
--
,-
--
-
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-
,
-
-
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-
-
-
"
ittgularifies In the spectra of MOIeCUIe% totinitig the in-
t
e
ru
i
ol
c
c
ul
&
r
h
b
i
o
oge
u
ond by the p
redisso
c
i
at
n
e
ffe
c
t
ydr
(SlAti, Oplival 111,1, Irililleva.1, %.I
'
00 f C, M I
my
'00
.00
10 .00
0: see
0 =0 04
0
0
00
-0
wee
ve*
lie ASO-SLA -ITALLtRGKAL LIt1QAI60E CLASSIMATIC"
wee
-,AA
0
@11 u Is AV K) 11: If 61 "0 n I
It ti IP
*10of COO 0 0 00 0 4096466411606064
0
0 4 1010*10 Gese **I,
0 0
009*0#00
"Approximate Method of Calculating the Fluctuation
Wequency of Complex Molecules," B. I. Stepanov, 6 pp
'lz.Ak,Nauk, Ser. Fiz!, Vol zi, No 4
On the basis of the method developed by Ellyashevich
and Stepanov for calculating the fluctuation frequency
of molecules, the author evolves a method of approxi-
mating the fluctuation frequency of complex molecules.
The basic inethod was developed.for molecules of the
first matrix. If this same method were applied to
molecules from a 50-stage compound, however, one would
at..
have to conduct socke 250,000- -operationa.-Submitted -
the-Stat 'got
e 1661"UitItite. 28T62
006cg$ff1 Ate pacrtmott '.v(s
..---
Tb4ory of tho op6w sedutt"b"
smalsims. 8 1 skepamv and Fl. V.
011tiCAl JUSt-, J. PAYS. CAtm. W.S.S.R.)
ji, if,24(1047)(in Rwmimn); cf. C.A. 41, W17C.-The -00
aeldnl. energy requircol to lift an electron (if AgOr into a
catul. band, when a Aglir mulsitnt it ilblinift4ted With 109
9 long-WAvc light, is suinwheil by the vibr4tinual em-rty
pf the mn%ithind ilyr. The miginal owle of thr dyr i.
*0 minwiliAtcly r"Itpred at the cxtwn%e of the heAt rurrgy W
file sy'Ittil; th - -AiNfity at nue uog.
i. i"xuunt@ for the pr
4 dyc vau%inx ftwntatiou of numy Aft aloem. From the
dejoemirnee of file Wiltilivily of the sen'@Wzrd rnluwtml
ms the wtive length, the no. W dcgrm of frectiont invi4ml =0
: i,& the tran4vt tJ energy to Aglir is cuW. to tK- about :141
0 f-W CrUift fly"- 711C theory expWins. 9 essenwi fra- IV
041
10
0 J. J. Dikerruan
0
oo
goo
@
00
00
11 AS-SLA .1TALLUPIGICaL L.171*47M CLAS$WKAYMN
"68, - I 1 1-- --@AL@@
.30" SIT,# -
%xja4j .1, 44t
u u AV 43 Ali; IV IF a x K a a a a x a is a
0 0 0 0 : : 0 0 e 0 0 0
0 0 0
.1@1 so-JAw
IX"Ani So rig 0 m v i v u o a a 3 s v
U0 I
:10 0 0 00000000
0 41 0 0 0 0 0 0 0 0 0
goo
too
set
!100
age
U00
too
STEPANOV, B. I.
USSR/Spectrum Analysis Feb 1947
Pentane
"A Theory of Vibrational Spectra of Polyatomic
Molecules, V," I Stepanov,-24 pp
"Acta Physicochimica" Vol XXII, No 2
Calculation and interpretation of the spectra of
normal hydrocarbons., the calculation of frequencies
of the normal pentane molecule possessing 450 free-
dom., the interpretation of spectra of all other
normal paraffin hydrocarbons, the treatment of the
rotational isomerism of molecules of that type, and
proof of the existence of a rotational isomer of
lower symmetry for normal butane.
9T25
b&Q - A 2, 3
STHIPANOV, B. 1.
Author: Vollkenstein, M. V., El'iFLshevick. M. A., Stepaaav, B,_I.
Title: The vibration of molecules. (Kolebaniia molekul. ) 440 p.
City: Moscow
Publisher: State Printing Houze of Technical and Theoretical Literature.
Date: 1949
Availsbie: Library of Congress
Source: Monthly List of Russian Accessions, Vol. 3, No. 3, Page 164
Call No: QC 173-V815
Subj)act: Molecular dynamics.
hdrartid spows of uranyl Wlis. A. N. Serchettko anti
If. I. SteRng A rrof.*. Fill. to, It 13 -' .11)
1. Y_'zkUv. EkIpah
Effhl. Of Absorption made On fine powders of
tYtNM_),.3Il,0 (1). XlT('h(S0o)r.211r0 (U). UcAlf4co),
(111.0 (111). still U(so(N(MIAHS0, hel't between floorit
plate% translAntent to oil) to 11 A. Or lActwern crysfY
transitarrtil up 143 15 M. in the t,tille (S-t2 $4. test it)
and Con"ItlJots. at vistriance '.ilh thow CAI Conts
and WU (C.A. 33, NMI). Pvrtincutr of the Sliscrvird
Atomption lvaks to tile ljo@ ion, not to the anion, was
."CertAillM l.v C ..... with all,orption slwctra I,(
ll,so#. KSA)s, and COSA)#. lit tile %Atne region. The
ol~fvrtl Irrilm-tivus son vin. 1) an,l noilsillnuirtits are:
I KM ("). 913 f"), fill) (b.'), 1130 JVA I vs). IL!Ivl
(thAt, ra + 2rd, MN (7v,, 1. + 3"), N7.3; 11 tit$.$ ("),
Kv (5,P), lixid (PA + 1,,), 1130 (P3 + Ali), 12114 (ti,#, P, +
2rl) ; Ul 9 18 (1,,), If 11)(1 (Soi). 1420 (7-1, P, + 3,:), 1515
4,v + 3PI). 877; IV 9633 jr:), IIM (Pj + ft), 13113
t., + 2.0. 1390 (7-t. va + 3-0. 1515 (P. + 3n). These
Irrquencim are cOnsistrait with the fundaincrital vibra-
tions All m MO. All - '21(0. P2 @ MM coo.-I. The %-try
interim frequi,sicy S', 3 in 1 (977 in JU) remains unamigns d,
atilt its Absence in It unexplaincd. Thc high intensity of
%o) tfwp j@ surprising fur so high a harnionic. The
-igntilents All ILN)I arid of MV. Are Ambiguous. oil the
basil Of the a,,siglournts given, the U0, , , anti I cannot
p(milily ha.w As, linear shape, oil account of the frequencics
?M, MU), amd 12MI. which are fmbidden in a li"ear
uuxlcl; cun@cqurntly. U0, - fit 1. anti also in 11. is bent.
(9 tile ftequencies ot,wvr,i in fill ,nly 1515 is forbidden
for lite filleAr Ittalm; tile rvinaliling aII,
allowed. anti frAltinctivici oft,,erved lit I anti Ill whit-h Are
forbidden fur tile lilw4f III.Adel.arr wholly ahl,ent' coo,t-
quetilly, in Ill. the U(N * ' full muilt lit nearly lincar.
Ilossibly, tile amigninent of 1615 to P. + 3ol is wroux And
should lie replaced fly P, 1- 3"' with tile deviation fruill
tile Colcal. valor title either IV Frrild frMillance Willi 70,
I* to) fly au'lloplon'4 cull'i'Irfation,%,
V(h ' ' in IV apiwar, lo Ile nearly 1111C.Ar. I of
I by heating it hirs. at ;441, 'hw, Ilk't Lite I lite t
"'AC'Uttli It,
of the altllorption maxinia. bill it d4xA after . At hCir
relative Illork4lver. xives ri'C l" a lim fir.
Ifnelley m JIM41 vln@ I J" f- ") Ili,.h j, t"M"I"ll, t'M@Ilt
ill 110tated It -Old IV SylilliviiiLd antiv.1. 1'6,@A). I,_
A spectillol V.1y Ann, 11.1ilkirill festal 6.01
11 411.1 it practically Undefituor, III) vilange Ill I %tilt
norAmally humid air. The uiujl bAnd' At 10J, N.2. Atilt
7.0 ". ("' tall, Atilt 14N CIII._') Are either absent or
very weak; if the Litter two are interpreted as hjrinwiks
(62 and 7.., rather titan as combiliAlions rt + ;.1PI ;tilt]
P. 4@ 3", this may me-An that high harnionics are linked
Willi the Prr,,cnA:v of CryAlls. 116,0. Of that 11,0
tightly lostand with the Uok- jug, incrrale it.4
moint,111 for h4rinooic% of PA. The @pectrunj of inhysi.
XIIOAI@ AIMY the 110) (P, + It) in 1.
The clOstrite- of tile 1-111d IWIlwovil 140 atid the Ut I,, -
iwt 6 further indicalctl by the almence. in 1. A)( the A; A,
Abs"Ptionfiandotil'o. That IIAIIII Malqe..S ill illit"lly
anhyd. VOtSO. after it has been exposed to usoiture.and
belongs, evidently, to hygroscopically condensed llso-
Its @ntvA.@t to U0vS0,. the spectrum of dehydrated IV
chAsige., with the duration III exi"ine to) mosiNt air. Svn-
the-iml U(N(NOO. with 0, 1, 2. 3. and 611.0. "hilviN file
@alllr fiv%plestries, fail 13913 i. at-I ill tile prt-Im
with P@ 1, Awl 'Aist). 6 strall in tile @dt itith 3144 1. A-1
lauly h-1011W isilly ill IV (voWl 011,0), Till" -v-
filill, fll.tt Cryltu. IllO l*CihtAtC1i the A111WAMAICt 1-1 high
hanitusises. Ott the Other hAnd. the thalle of tile I'll lis ' '
istli i!l little affected by tile Cryan. Iflo, i.e. by tile vrv@tal
lattice, Which afforctis istily the rditivo, intVIINItirs. Ill
voutrouit to dw infrotted isilectrum, the flilitic.'rme .$it.,-.
truill 4d UOM " milis it Olts"sAly sit-lovillient till tile ezvoll.
11,0 content, which affect* tout ottly tile relative Ijjtvjj,itj,-,
lout alai the vibrational strtwtuxv. i.e. the vibratitai.tl
firques vivs. This C0111fAdil-tiOll call 0111Y 1W 14krll I-)
14
i'sibeate tholit the ount. of t-ty-itti. 140 Alid file 1.0mv
@"-wtum. while it dw* 11"t 'idilifintrilly Affect tile v-da...
timis At%ml. with the lvwer oolectrosiic lrvrL dtw@ have
a det@isi%c Cifeet lot the vibratitulal 31ruk tuft .1 Ill, r
vimtronie levd. N. 1,11"n
r
V. and I-bL'YAS*.iE
STEPANOV B. I-j, VOLKEIISHTE'-ql ,-
2a@@@ t, 1049.
les MOSCOW-Lerdngrad 5 Itc. Tech. Press
.,s@jll@atuons of !;Olec"
i rn, 195o
skiY, Sov. irniga, 1-10.1
by V. Chulanov
USSR/Physics - Nev Techniques Oct'510
Light
"Determining the Duration. of the Excited, Oscil-
latory State With the Aid of M. L. Veyngerov's
Spectrophope," B.-T. Stepanov, o. P. Girin.
"Zhur Eksper i Teoret Fiz" Vol XX, No 10,
PP 947-955
Investigates procesies occurring in the chamber
of Veyngerov's spectrophone. Determines lav
governing time variation of temperature during
pulsating illumination. Obtain mathematical
169T98
USM/Physics - Now Techniques Oct 50
(Coutd)
expression connecting quantities measured experi-
mentally vith duration of excited oscillatory state
of molecule. Submitted 9 Mar 50.
169T98
P4
r.
W 0 - 0 - as W W Ml' w - ;rL - W- -- - - t W
I It I a t to It 1) )1 It Is It It Is" V k ]Ed
It 1 1 1 AA IL-'j -t
-A A @L' A -"--b -1-AL N r-A k-LriM 40 Apt, It. -of.
40 lit AND RD 0111)[1111
A
40 PROCISSIS A.0 FROVILIT191. INDEI
4729
0 0 RFPZCT Of WATZR OF CRYSTALUZATIO14 ON THZ
FLUOREWSPICE BPECTIttO OF URANTL 1111TRATIC.
00 PART 13. A. W. SMbwko gall S. 1. Steputtim. Zhur.
go shalow. I To". M. 31. 313-10fWFyi-&-ami -RUS.1aw
Part I of (Me vwk appeared In Zimir. SbWl'. I Tooret.
Fig. 21 2"1951). Changes In the buinber of molecules of
water ad crystaUlzatiom in uraskyl nitrates are accompanied
by consider" cb&Ws In the frolquimcy both of the sym-
oo metrical valwy 00C1114110as at (he UO;* Ion in the lattice
and of the electronic transitions. The fine structure of the
oo
spectrum, " observed at low temperature, to determined
essentially by transitions bet a Is energy levels of the
crystal lattice. ugly a tow lines being due to transitions
between tilsdromic-ascillatim levels of the uranyl ion.
I L A 011ALLURGICAL LITERATURE CLAIISIFICATICIS
7- 7
0.1 eat
U % -0 a Q-V ji it 1i It it it it
0 0 0 e 0:6 9 0 0 0 * 0 0 0 0 0 0 * 0 0
a 0 0 e *to ego 0 0 000 0 * 0000
-a got
zoo
'06
cog
via.,
ltittilo-cl An I S a ad 0 alizill OK d-v Lit -j
" a I It a
K no n I
0 JIM
'L. 9 a 6 0 0 0 4 0
49000000 -4 4 00 -of 0 oil:
CP
"Aftore of the elementary precool" of 4
%"One"* *4 wanyl coaopawaft@ It. wranaw
E Eftwes. PIS. It. JIM-4001S.- NO-A
Ikilp. j;VA: (AITM, a
m4d* ve the rotitrudict4m hirforen the order od nuti-
rillude C4 thr life of all V%Cifc.l state of an eloc. dipole, 10 "
Ver., Arl'I the rajol. or,ler -4 ritagnitiAr. 111-1 me.. of the cit-
eijr,I stair in (34 %iRt, The jwinuv@l tmAuthill cA (his
. ovalirt 1. hap-e-I (01 tile it IM11.01111 thAl, i114111MICII &V CIVC-
lF.j.jjC VXM460t! k1t ('()' Ili A @110`ltdl tAttil-C IS tltVr*"CiIY
by a ChIllifir of file j."itions ol thestorns within
the km. it cittem al- proftlev a flelannatiort of the surround-
ing 1.1tire, Tile ffA ~itation rtirrsy ir thus composed
,J the etrilaii-i --sy pr,,i,, f obe elertnwi cloud in the
I'# I- - I ... 1 -4 the en,ricr -4 -1-4mrnation -4 the lattice. The.
1.9" .'t the tAtter 144(t I,, bff@frtll VO, Oftlis appears
ill, Laa #if 1*4sm4l,w (C.A. 43, 4IM61). acewding to
(III. electtorlic excilatimi energy varics betweett
.1iff.-resit _11@ by At much as ils@f rin@ -1. Tile sanfle assump-
Il'of 1, It'liber "WFtAKWAted by Sanxillfw's (hAr. cit.) dils
'howills '114et"W,s It the vibiIiijon fretitwilciri; in different
i*s), Ill, '@rv,brjiW on.1 Siq--'. (CA. 44. 47)424)
Pt'lolif flint the very Iczt@ -I the U(n' mar he different
itivot -w twill) fit diftclictit -sit*, a"d S. and S. (C.A. 46,
4t""' W.- ""I I'm* 4 rhalips 4 She Ilwarvislo as allairtrunt
drIM11,11119 -.11 Ilse "I,, It.() -4 eve%ta, The, Infill'oro
Ill the *11frf"tilding medillill Inanitesin limit Itatis" III the
clWWArt.h1v broadening of the emission Ulurs of U,%Mtt- in
0*411, will ill 16%nes. The life V all the exclicif stair is in-
Vrt%elY ll"%WtkM&I to flit pCOIlifibilitY P Of the ekVtfililsk
fian@ili,ml, which. for dipole ernluion. clin be written p -
pliffinfid,11. where pe Is the ttanaltioa probothilit in the
21,wnre of lattice deformation, and the intelfrial T.Lk.
the Initial and final-date wave functions of the lattice:
firoin the expil. facts it must be Mnch3drd that the value 0
this Iniefiral is of the order of 10-1 me. The Imig-lived
rnilwiim of Uth sells. detected by Nve"llaw and Sevelionko
(C.A. 4S. 407d) taust he attistmit"t to ut)l -. whir%, .@ cit-
citatiot. comes, 0 particularly strong defoevastion of the &at.
tice and Flar which the value of the integral in of the order of
10-4, beam p of the coder of unhir. A I o6jiscom
apinsit this awroption Is the fact that no indication of a
Ot"
Imillor lnt~km with the lattice Is lounil In solid amIts
-4hrr then of umnyl. N. Theft
Wideb of speakot Half* of Ofamayl Saft M4 he i
81*1milov. Atr. Fhq4l. 7=V.
11. 114% 4U(ItjM).- Ale$ wrvn the fartup. a-( liattild flar and
totlUt tCUTP., three hl It XCAdUAI broadcolitit of the emillmallom;
lim- of VOt ealts. cutting in comphate "Plararmalft of 0
firiv orurfure. )IT, the pFkh*le of Incliftermilmawy, I"
-idth AF.d a Irvt and the life r of the @tat* am rollated by
A X', - I /r. The abclarplicam set a" be follatifird by 6 tyM
.4 tranottionv: (1) emism6im of light a r*d by
trainitilitm of be 1,10: 6 to flail, th"colde
fir
F=
a
am
"t
to
C
conversion of be elertronk- enersy, of the fort to imatmotical. or
Lattice vilmartku; energy. (3) Conversion of istemmool. to
laffiev vitairatiou energy. (4) triffirfribution of iWoud.
valmatiott onarrity liver tire whole lattior, (5) Imada ad the
lfthorftmlm@
five probabilities of thrir by a with the
-w-ampoinfingotaborripts.tile width cal the given frouslationary
Slatre a' 'he Cry%#" 6 -.It - (Or + at + 08 + 04 + OB)IC-
Front r2pl 1, data. I lie vattle of a" 6 known to be of the order
ol 10# if that Proval "me were derail. for the widtb
(h* level, an, Amtikl have AF - lit-11 com.-I. CONSIP.
'Juartatir. the efflissiou Ullar width cannot fail darid. by proclaim
M. Fron; data oil trints. quenching tat the flularmVem us
U01 malts. the C&C-1 14 process (2) calls be at Inctill of the
order
AN m 10" c-ni.-I. 'I'liat the lanallability of prax"vmm (3) is
lamittilibletila, higher flail" the part4mbilitles of the lot 412
Peale,"". friams front Ike ltwnwndoom 0, 111110 op"i'll"afR
OW quarmtom yki.1 tA the twor"Mam 4d 0A "0 of
the cracking radisatim. which UuMm" QMW
MW 5=
I Ivcm only a" or. at NO-
ismal conseqaaarattv. a farm arattelit of Vbndm
into vibration of 01111, laido. Fir
that , width the fears, ad 4=14. 2!! be oW. ft
-lo-11 w.-l; a fmA hwv" of that
Ituip. is plattoitak. but is 111%auffick"t
biroadmingal the lot stroulatal NO"- FJW (4)
in a =tigm to the rentutbatim wWb is do
1 .1 on, L-CO. . tWw4*W tillt b"k* Vkh *0
velocity of mound. m-sulto In a ravelled of dw Withal PH 1WIl
t ioak Over 100 at. di*tAWA'. Al per tSC.; Lll@ dW Ift Of 0
pe"tarbation feat thatordew oll 110-11amr-arms - 11810M.-I.
anti that ecrilitimpostifing Aj: W XAO Calmodarmal WM me
c%ptl. armisokin band wkith of 110o mks at V~ tsuiP@ Tbb
l4tit-rato Is about at lower toppe. an awguft Of 1111111
-of the amplitillies. 'no exideme at Plot"*
citel by the tlepolatitation of tk #Mb*A Of
at advamiced stages of the allivay (SewbftkD,
Ifowevir. the effect of that tollim" ad OW ex.
citatim rilem from one U01 * to aftelthelf. - the a- WWth-
is lamilit"ificant, The decivivis larloo 4, hr the
I
!bar"Wirttlas of the Owthiplim limaim, of U01 limmar is this red,*-
,tributinn of the lattkv vitirralliam " - harm @ limbral
i with art isoloted UO: , are lnC2J;m,&W CT;"mi" Ior that
Ahroadvalag. N. Than
iO J
USSR/Nuclear Physics - Crystallography Oct 51
"Width of Spectral Lines of Uranyl Salts and Its
Dependence on Temperature," B. I. Stepanov
"Zhur Eksper i Teoret Fiz" Vol XXI, No 10, pp
1158-1163
Studies effect of various transition processes and
energy propagation in uranyl salts on width Of
spectral lines. Shows that most important is ef-
fect of distribution of oscillatory energy, in
cryst lattice. Hence spectrum t*ype is connected
with change in cryst lattice. Stepanov acknowl-
edges A. N. Sevchenkols advice (cf. Sevchenko and
Stepanov, ibid. 21, 12, 1953X Subuitted 29 Dec 50.
Tic 19=00
'YibratioJE!_e1Le and
tcomplex mD!e
U3 @- @ , : -
43.
1951 of a
Collipiex firg. 'tf the CiFivieller and tile
tim:16-m "i v:11rat.1,311 (nwtv", ;m'i odwr
fealtir"S of I!:(. or;r. 111"I. al,_- -Most of Itit.- ivrtrk
tic ml fillt'lUic0liCe ill arc.
diflicul, ti) 'nake at c'Illij, fill' ill'VCitiVA-
01f, fill, of val'or- l1w.t. do not
doll of
.
fircollip. oll 1:v3pil., pvc.-S tilt! ;Io.4-@ihiliLv t1f Stll,!Villi; 1.1.Ally
aspf@as to olitidn in C,jitijtlv.% nioli. are
mols. in whi: t'je c6f t@nerqy r@_,,lklrihuticill is
grc.ltier 0'w the v@Czprl_-,d, 4 tilt! lifetimc! of tli@ excUcA
@tatu. I'll(! ipeetra are li:ic slxcma in simple mok., diflused
@Iqll: 0". -alit I-Mqr;!Il loll'i ;1, Complex mols. E Irlis-
sio:1 and zlb@rrptiori spectrri 1:-v-c@ mirror svinmeEry. Tlm
n output is lar,
quantun - go'r ill suill@ thall ill %-aperi@. Tile life-,
ti'lle of tile vxmterl state und the quenching by other gases
are tltscril)ed as wAl as flic ill,,ma@c in filuortscence by
fOrCigil 9USQ'S .111d tile (if fluorc:cence by collf-
I)Y tritu@ftr of tile vil@ratio,i energy, characterized byaji
@@acc")mvnodatioll c'j-21T." (cf. C.A. 4S, .555118A)@ 11. B. 1.
-
:
t,pa;iov. Ibid. 402-25-1 thcory of ioealiz.-ition oryri
c
;@=Dlarion cnergy on certain degrees of frecdoin is developed.
'0%vizig to a coutinumvi Omnge in localization -and a redistri-,
bntinli Of %libratitill i!jlL:r,,,y (if the mol. on diffurent degrees uf
frt@vdrljn, contintious spvctra tirv- fnrinzil. Thus classical
st:itistios can b-L! appliud to suci! wolL;. wbic'?i -m have thei,
Mvil specific ti-rip. " :101 "Ile
alld tile dkirihilti,in fulluli, It of :t("! - t:it@zl ;k-" olci-kc.1,
and HIC dvv;tv Hult, uf "'m 1), C@klci. flot'll fm
valiots and for soins. The kl;z@;nluat outpur, ;m(l ffic temp.
(Iticuching of 11timesvilce are also Jet ivut! frvrn tile distcibu-
tifill fulletioll (cf. 4tl. 1
STEPANOVt B. 1.
USSR/Physics - Oscillatory Spectra 1 Feb 52
"Distribution of Intensity in the Oscillatory Spectra of Linear Chains,"
L. 1. Vidro, B. I. Stepanov
"DoktAk Nexk SSSR" Vol LKXXII, No 4y PP 557-560,
Calculates the intensities of infrared and combinational lines for 2 simplest
models - linear chains, using the valent-optical scheme of M. V. Vollkenshteyn
and M. A. Yellyaskevich. Considers a simple linear chain consisting of 2n-rl
identigal bonds: o-o-...-o-o. Acknowledges the helPful assistance of Prof M. V.
Vollkenshteyn. Submitted by Acad A. N. Terenin 4 Dec 51.
PA 213T112
1'.., c v1.
lpu,@ I- a Z-ic-l
Sevchcmho) A.IQ "Inv@,stication of the Lirunescence Academy of Scimces Belorus@
Stepancv, E.I. ) of Ur'anyl GcrapoundsU sian SSR
n's law.
a law.
o
S S. effect j-
whe, formulation of Kirch
resence of rog d nwo
ol -ta. t-
the radiation and 4. sub-
Vcquk
stance being Irradiated Is dirived. TheactualexpresslonoU
Kirchhoff's law is (W,1IVt)j(a,1IVI - 1) - Ir. --@ (8r-'
hrl)l I".- I /(eMr " 1) instead of the conventional formula I
Wrlav @ M, W, ;w@ M.(Srh&J)IV' I. and av - Mrs#11:,
resp., where IV. - potency of an isotopic substance to emit.
radiation. ;K - potency of the forced radlation..d.
ability of the substance to absorb radiation, U, - d. of the!
radiation energy, h - Planck's const., V, - velocity of the*,
radiation distribution in a given medium, Y - frequency oli
the radiation. k Boltzmann const., and I' - abs. temp.
AOL
USSR/ Physical Chemistry Molecule,,. -Chemical bond'
Abs Jour : Referat Zhur Khimiya, No 4, 1957, lo847
Author : Stepanov B.I.
'A--
Inst cade-w--U-Tciences Belorussian SSR
Title : Probability of Electronic-Oscillation Transitiohe ar4d Lava of
Fluorescence Atten-dation of Complex Molecules
Orig Pub : Vestai AN BSSR, 1954, No 5, 6o-69 (Belorussran); Izv. AN BSSR, 1954,
No 5, 65-74
Abstract :
Uara 1/2
B-4
Specific features of emission-And absorption of light by co*lex.nolecules
are connected with the occurence Of redistribution of os6illatioin'enqiij@r bet-
ween different degrees of freedom. Optical'pr6perties of molecules are-
strongly affected by energy exchaige'vith surroxmiding'xiediua. 'U this Paw
are investigated characteristics of probabilit.* of traiwitions with -adoision
of light in cozple@x molecules. It is shovin that this to *ener& exchanti'vith
surrounding medium,,probability values of all optical transitions are avera-
ged over all oscill tion levels of initial electronic state. This ex@lains
the rigorously exponential law of fluorescence attenuatioji of solutions of
complex molecules. This law is found to be the as for all frequencies
G O.P.; ZHIDKOVA, Z.V.; S7X V IVAIIGV, A.P.; TOPORETS, A.S.
Determination of the true absorption spectra of scattering colored
objects by their diffuse reflection spectra. Izv. AN SSSR Ser.tz.
18 no.6:728-729 11-D '54. (MLRA 8:3)
(Absorption spectra) (Lighlu-Scattering)
Wblt/ Physics - L@uantum mecrani.cs
Card 1/1 Pub. 22 - 23/63
Authors s Stepanov, B.I:, active member of the Acad. of Scs..of the YSSR
Title I On the quantum output of fluorescence
Periodical i Dok. AN SSSR 99/6., 971-974, Doc 21, 1954
Abstract t A more precise formula for camputation of So._Called "quantum output of
fluorescence" (the term id defined) is presented. The formlAa enables
the quantum output of fluorescence to be computed by takinke into account
the dependence of tha light on the thermal effect; the formula is ex-
110,vis.
pressed as fo - A V/1C r
10 (1 - e-
A vlk r)
4-
and the symbols are explained. The quantum output is always less than
unit, it equals 1 only when S r-O or de 1. Two USSR references
(1951). Diagram
Institution: Physico-technical Institute of the Acad. of Scs. of the USSR
SubmItted! ......
SNVCHINKO, A.N., redaktor; ALWANDROVICH. Kh., takhnichaskiy
reaak"t or
[Luminescence of complex molecules] Liuminesteentsiia slozhnvkh
molekal. Minsk, Izd-vo Akademil nauk BSSR. Pt.l. 1955. 325 p.
(Luminescence) (Molecules) (MIRA 9:9)
Piiysics-
C@ I'd 1'@l Pub i46-24/25
7C'
Author Alentsev, M. N.; .4ntcnoi--Forancvskiy, V. T.;
-1itle : Yield of resonance fluorescence of atoms
R-@ricdical : Zhur. eksp. i teor. fiz. 28, 253-254, February lP55
jkbrstract : B. I. Stepanov (D.W SSSR, c;q, OTI, 1954) thC -,t- C'
of radiation and system consisting of atomf-- posses@,!.n- enerD-
an@ showed that the radiation output varies in @ne-e up-,)n the -'-v,--Jty
of the exciting radiation (thiS CODCIUSiOll 11-0f-Y'S tL- the toti4-1 n).
The authors apply the proposed method to the calcul-tion of the
otitout of a similar system, e.g. the resonance fluo-.-escence of atc:,:.;.
obtain an expression for the quantum output of -fluorescence.
Institution: Physics Institute im. P. N. Lebedev, Acaderrj of Sc:iences USSR,
Physics Institute, Academy of Sciences Belorussian zSS'R.
Subr:dtteid : November 25, 1954
535. 345 : 635.231.4
4327 ! ABSORPTIOIJ AND EMISSION OF LIGHT BY A GREY
@SUBSTANCE. B I StUanoy'.
Zh. iksper. td-dF @To M, No. 6, 559-66 (1955). 1,
Russian. English translation In Soviet Physics JETP (New
York), Vol. 1, No. 3, 446-51 (Nov., im).
A substance Is defined as grey If Its "absorption capacity"
(ratio of energy absorbed to radiation density) is the same for
all frequencies, and If Its emissivIty Is proportional to that of
a black body. The thermodynamical propi-rdes of such a sub-
stance are discussed. It ia claimed that the results obtained
are rele4ant to absorption and emission of light by complex
molecules. L.Pincherle
USSR/Optics Miyzical Optics, K-5
Abs Jour Referat Zhur - Fizika, No 3, -1957, 7748
Author Antonov - Romanovs-kiy. V.V., St nov, B.I., Fok, M.V.,
Khamlyulk, A.P.
Inst Physics Institute, Academy of Sciences, USSR., Physico-
Technical Institute of the Academy of Sciences of the
Byelorussian.
Title : Luminescence Yield From a System with Three Energy Levels
Orig Pub : Dokl- AN SSSR, 1955, 105, No 1, 50-53
Abstract : The luminescence yield of a system with three energy
levels is calculated and it permits resolving the fun-
damental problem of whether the value of the ene 'rgy yield
9 can.exceedup-ity. Attempts found in the literature
of a thermodynamic proof of the impossibility of i
are not satisfactory. The energy yield of luminescence
of a system with three levels (Pringsheim. mcdel) (Pring-
sheim, P., Journal of Physics, 1949, lo, 495) is calcula-
ted
Card 1/2 - 43 -
15 / /91 -1-.
-USS/ Physical Chemistry Molecule. Chemical bond B-4
Abs Jour : Referat Zhur Khimiya, No 4, 1957, 10846
Author : Stepanov B.I. Sanson A.X,
Inst Academy of Sciences Belorussian SSR
Title Dependence of Probability of Optical Transitions on Transition
P@requency and Oscillation Energy Supply of Complex molecule
Orig Pub Vestsi AN BSSR Ser. fiz. -tekhn. n., Izv. AN BSSR., Ser. fiz. -tekhn. n.,
1956, Nol, 5-14 (Belorussian; Russian summary)
Abstract On the basis of the model of unidimen ional, classical harmonic oscillator
for a complex molecule of group 1, an expression has been derived for the
probability of transitions from different oscillation levels of lower islec-
tronic state to different oscillation levels of upper electronic state.
In the derivation there is taken into account the change in coordinate and
impulse in the process of electronic oscillation transition. Investilption
of the derived formula in the case of invariable impase is effected by nu-
merical integration. It is shown that probability of the transitions de-
pend on transition frequency and also on oscillation energy supply of the
initial level. Elucidated are the reasons of slight dependence of absorp-
Card 1/2
e
USSR Physical Chemistry. Molecule. Chemical Bond.
Abs Jour
Author
Inst.
Title
Orif; Pub
Abstract
Ref Zhur - Khimiya, No 8, 1957, 25747
B.I . Steipanov
Academy of S,iences of White Russian SSR.
i Speebroscopy in Science and Engineering
2 IV, AITISSR, Ser. fiz.-tokhn. n., 1956, No 2, 5-14
Report to the yearly meeting of the Academy of Sqiences of
VJFhite Russian SSR in 1956.
B-4
Card 1A - 8 -
RUMANIA/Optics - Luminescence
Abs Jour Ref Zhur - Fizika, No 2, 1958, No 4524
Author Stepanovp Bol.
Inst Not Given
Title The Vavilov Lav
Orig Pub An. Rom.-Sov. Ser. mat.-fiz., 1956, 10, No 4, 47-74
Abstract See Referat, Zhur nzika, 1957, No 11, 29099
K-6
Card 1/1
/'V V
USSR Physical Chemistry. Molecule. Chemical Bond. B-4
Abs Jour Ref Zhur - Khimiya, No 8, 1957, 25773
Author B.I. Stepanov.
Inst : Academy of Sciences of USSR
Title : Contour of Absorption and Radiation Bands of Complexhiole-
cules.
Orig Pub Izv. AN SSSR, ser. fiz., 1956, 20, No 4, 456-463
Abstract The computation of the shape of absorption and light radia-
tion bands of complex molecules, and -the alteration of these
bands with the temperature and parameters characterizing the
molecule kodel is carried out; the model of the monomeric
classical harmonic vibrator -was selected as such molecule mo-
del, and it was assumed that the model preserved the quantum
properties completely from the point of view of electron ener-
gy. Taking into consideration the change of nucleus co-or-
dinates at the transition of the molecule from one state into
Card 1/2 - 25 -
dr
WSR / Optics K
Abs Jour: Referat Zhur-Fizika, 1957, 1957; No 4, 10404
Author R_T_
Inst Not Given
Title Quantum Yield of Luminescence of Complex Molecules.
Orig Pub: Izv. AN SSSR, ser. fiz., 1956, 2o, No 4. 493-501
Abstract: Paper delivered at the Fourth Conference on Luminescence.
The survey touches on the following problems. account. of the
background of thermal radiation in the calculation of the quan-
tum yields of luminescence and emission, effective vibrational
energy on the luminescence of complicated molecules in solutions
and vapors, quenching of luminescence of the first and second
kind, possibility of realizing a quantum yield greater than unity,
existence of negative lumin scence, and reduction in quantum
yield of luminescence in the anti-Stokes excitation. A new ex-
pression is obtained for the dependence of the quantum yield on
Cara 1/2
USSR / Optics
Abs Jour: Referat Zhur-Fizika, 1957, No 4, 10404
K
the frequency of the exciting light at excitation frequency
less than electron frequency. As a result of calculations,
based on the step by step account of the exciting absorption,
it is established that the dependence of the quantum yield on
the excitation frequency is the same as the dependence of the
coefficient of absorption on the absorption frequency.
Card - 2/2
j
USSR/ Physics Luminescence phenomenon
Card 1/2 Pub. 118 1/7
Authors i Stepanov, B. I.
Title i Vavilov's law
FeriddiCa, I Usp. Fiz. nauk, 58/1, 3-36, Jan 1956
Abstraot I In connection with the 5-th anniversary of the death of Mr. Vavilov,
physicist and academician, his work on the luminescence phenomenon is
discussed. His definition of luminescence is considered as the most
correct. His law dealing with the quantum output of luminescence is
also considered as correct (experimentally proved) and important in the
theory of.lumineseence, This law is stated as follows: the quantum
output of luminescence (fluorescence) does not depend on the frequency
of the exciting light, while they (the frequencies of exciting light or
radiation) are within the range of Stocke's spectral band, but it
Institution ......
Submitted ......
Card 2/2 Pub. 118 - 1/7
Periodical usn. nz. nauk, 58/1, 3-36, Jan 1956
Abstract (the quantum output) falls rapidly as soon as the frequencies of exciting
light or radiation reach the maximum luminescence band. However, there
is an indication that the mentioned law can be applied only to condensed
systems. Fort.y@-seven references: I USA, I Swiss, 3 Germ., 42 USSR (1888-
-As' diagrams; photograph.
1955). Grap
/V d
16(1); 24(4p5) MASE I BW MIMMMON SOV/1899
Akademiya nauk Relorusekoy SM. Institat fiziki I =tsgm%jX
Trady., vyp. 2. (Transactions of the Ustitute of Physics and WatbmtIcs
Belorussian SSSR Academy of SciencesNr 2) Ninskj, 1957. 283 p. irratp& sUp
inserted. 750 copies printed.
Ed.: 3. 1. Stepanovp Academician, ESSR Academy of Sciences; Ed. of Publishing
House: L. Narike; Tech. Ed.: 1. Volokhanovich.
PURPOSE- This book is Intended for matbamaticlansp physicistep and graftate
students In mathematics and p"ies.
COVERAW: This book contains a series of articles on recent contrIbutims by
menbers of the Institat fizikii Mtematiki (Institate of "Los wA Mathematics)
of the Academy of Sciences, BW, in the fields of radiation., lmdussaencep
olytics, and spectroscopy and on the applications to physics of analysis, tensor
analysis, linear groupop theory of adjustments, and differential equations. The
Card 1/5
Trans0tions of the X:nxtit&%e'(Con+'.) SOV/1899
first article conUins a brief account of the vork of the Institute, including
names of scientists and mathematicians connected vith ity facilities, scien-
tific accoul4isbmentsIand fields of interest.
TAFU OF C011TENS:
The Institute of Physics and Mathemtias at the T1w of the 40th AnnivOrwarY
of the Great,October Sddiallst Revolution 1
Gurinovich, G. P.,, and A. N. Sevchenko,, Determination of the Nature of an
Elementary E*it+.er for the Case When the Directions of Absorption and
Radiation Oscillators Do Not Coincide 3,
Stepanov, B. I. and Yu. I. ChekAlinskaya,, Lmdneocence of Scattering Media 1. 19
Chekslinskays., Yu. 1. Uninescence of Scattering Media 11 38
Apanasevich, P. A. Transformation of Light, by an Atom 55
Card 2/5
Transactions of the Institute (Cont.) SOV/1899
..Godnev, T.N., R. V. Yefremova, and L. A. Krawtsov. on the Spectral Pro-
perties of Chlorophyll and Chlorophyll1de Ctaiplexes With Protein and
Certain Other Compounds 85
Krir.okiy, A. N. Spectroscopic Interaction of Sulp1mr and Tron in Sources
of Light for Spectral Analyvis 93
Yankovskiy.. A. A. On the Role of Electric Parameters of a Discharge Contour
With an Excitation of the Spectrum by a Law-voltage IxWuse Discharge no
Prima., A. M. Calculating the Oscillating Spectra of Silicates 124
Vo1od'ko, L. V. Electronic Spectra of Solutions of Uranium Salts 174
Stepanov, P.I., and A. P. Prisbivalko. On Us Theory of Dispersion Light
Filters 189
Prishivalko,, A. P. The Filtration of Light by Layers of Absorbent DuAt 206
Card 3/5
Transactions of the Institute (Cout.) SOV/1899
Borisevich., N. A.., U.S. Xhvashehevskaya.9and I.F. I&ptsevich. Digarsion
Filters for the Infrared Region of the Spectrum 214
Bokutv., B. V. Surface Energy of a System in the Neigbborhood of an
Ideal Wall 224
Fedorov, F. I. On Certain Dladic Representations for Three-dimensional
Tensors 230
Yerugin, N. P. Analytic Theory of Nonlinear Systems of Ordinary
Differential Equations 235
Krylov, V. I. On the Proof of the Impossibility of Constructing a
QuiLdrature Formula With Equal Coefficients and Number of Nodes
Greater Than Nine 2,110
Suprunenko, D. A. Two Theorems on Reducible Nilpotent Linear Groups 255
Pbpov, V. V. (Deceased) Determination of the Weight of a Function of
Adjusted Values Using Polygonal Adjustment Method 26o
card 4/5
AUTHORS: Kazachenko, L.P. and Stepanov, B. 1. 51-3-9/24
TITLE: Mirror symmetry and the shape of absorption and luminescent
bands of complex molecules. (Zerkallnaya simmetriya i
konturl@olos pogloshcheniya i ispuskaniya slozhnykh
moleku .
PERIODICAL 10ptika i Spektroskop-lya". (Optics and Spectroscopy),
19 7, Vol.2, No-3, 339-349 (U.S.S.R.)
pp.
ABSTRACT: V. L. Levshin (Zh. Fiz. Khimii, Vol.2, p.641, 1931)
discovered mirror symmetry between the absorption and
luminescence bands of complex molecules. Study of this
symmetry yields information on the vibrational excited and
ground levels as well as on the electronic transitions.
D. I. Blokhintsev (Zh. EkBper. Teor. Fiz., Vol.9, p.459,1939)
showed that this symmetry can be studied correctly only when
X/Va (X = the absorption coef f icient , -4 = -the absorption
freqaency),.and Wtl-4i (W = the luminescgnt radiated power,
Jt = the luminescence Trequency) are plotted as ordinates
against frequency. The authors apply Blokhintsev's analysis
to a series of phthalimide vapours and solutions. They show,
Card 1/1? inter alia, that B.S. Ne orent et al. (Dokledy Akad. Nauk
SSSR, Vol.92, p.927, 19M and V.P. Klochkov (Zhurn. Fiz.
Khimii, Vol-39, p.1432, 1955) are wrong in assigning mirror
Mirror symmetry and the shape of absorption and luminescent
bands of complex molecules. (Cont.) 51-3-9/24
symmetry on the frequency,scale to the absorption and
luminescent bands of 3-aminophthalimide and 3-methylamino-
phthalimide which do not possess such symmetry. These and
other errors of Neporent and Klochkov are due to the use of 4
X and Wt /-Jj as ordinates instead of %/Ia and W04
as suggested by Blokhintsev. The authors show that the
division of molecules into two groups(as suggested by various
workers), one with mirror symmetry on the frequency scale and
the other with mirror symmetry on the wavelength scale, is
quite unnecessary and unsupported by experimental data.
The authors also derive relationships between the absorption
and luminescent spectra in a form of a ratio WLIX , and
between the luminescent and thermal radiated povMrs. These
relationships are valid for condensed systems only.
Card 2/2 There are 5 figures, 2 tables and 14 references, 13 of which
are Slavic).
3b-B1,,-1ITTED: June 4, 1956.
ASSOCIATION: Byelorussian State Unive-sity. (Belorusskiy Gos.
Universitet).
AVAILABLE:
51-1-4/18
AUTHOR: Stepanov, B. 1.
TITLE: Effect of the Thermal Radiation Background on
Spectroscopic Processes. (Vliyaniye fona, teplovogo
izlucheni-ya na spektroakopichoskiye protseasy.)
PERIODICAL: Optlka i Spektroskoplya, 1957, Vol.III, Nr.1, pp.1-8.
(USSR)
ABSTRACT: The usual apparatus for the study of absorption and
luminescence (Fig.1) consists of a source of light
a, sample holder b and receivers of radiation v
and g. If the source temperature T. is higher than
@the sample temperature Tbj, then the energy in the
positive direction (from the source to the sample)
Wab exceeds the energy flowing in the opposite direction.
Wba' The difference W = Wab - Wba is called the
incident radiation power. It is often assumed that
Wba is negligible: this is not always true. The
Card 1/3 author discusses in general terms the effect of thermal
51-1-1/18
Effect of the Thermal Radiation Background on Spectroscopic Processes,
radiation from the source, the receiver and the sample
holder on results of spectrophotometric measurements.
The author deals In detail with the particular case when
the source temperature Ta is smaller than the sample
temperature Tb, i.e. the case of "negative excitation".'
Negative luminescence, negative Rayleigh scattering and
negative Ranan scattering are discussed. The essential
difference between positive and negat:Lvo excitations, 114a
in the fact that the positive radiationoinay be arbitraqvily
intense. The negative radiation has a maximum value equal
to Uoc/4 r, where Uo = equilibrium radiation density.
Negative excitation Is sometimes more useful than a
positive one. This is so when, e.g., the sample Is at
a temperature of 60000GY since there are no sources of
light powerful enough to achieve positive excitation.
From studies using negative excitation one can obtain
the usual,results: distribution of bands or lines in a
spectrum, relative intensities, polarization, excited-
Card 2/3 state 11fetime, quantum yields, ate. There are
AUTHOR.' Stepanov, B. 1. 48-11-1/13
TITLE: Introduction (Vstupitellnoye slovo).
PERIODICAL: Izvestiya AN SSSR Seriya Fizicheskaya, 1957, Vol. 21, Nr 11,
Pp. 1471-1,472 (USSR).
ABSTRACT; This issue is devoted to the l7t conference on theispectroscopy
of light-dispersing media which was convened in Yoscowton March
29-3o, 1956, on the initiative of the Commission for Spectroscopy
of AN USSR. This conference was attended by representatives of a
series of scientific organisations from Moscow., Minsk, and Lenin-
grad. The introduction gives a summarizing survey on the problems
of the spectroscopy of dispersing media, which is a newly disco-
vered line of spectroscopy. In most cases they just collect and
systematize the experimental material. for the time being. One of
the fundamental problems of this branchof spectroscopy is the
determination of the spectral relations and of the numerical values
of absorption-coefficients and indice of refraction of dispersed
s-ubstances. In dispersed media the variation of the spectrum can
be correlated with a change of the rules of light-diffuaion. Both
the reflection- and transparency spectra of the dispersed objects.
Card 1/2 depend not or-ly on the optic constants of the element, but also on
Introduction.
AVAILABLE:
48-1-1-1/1-3
the size of the light-dispersing particles, of the index of refraca
tion of the connecting medium, the relative content of absorbed
substance and connecting medium, as well as of the thickness of
the layer. By-varying one of these parameters, or all of them to=
gether, the spectra and the absolute values of the coefficients
of reflection and transparency can be substantially varied and the
dye of the substance can be changed, Many important problems ar, -se
with the study of the luminescence of the powdery materia1z.. No'..
only the re-absorption, but also the secundary luminescence should
be taken into account in this cases The elaboration of these pro-
blems is only in the beginning. The phenomena occuring during the
work with dispersion-light-filters are also within the field of
this branch of spectroscopy. Their theory is almost not elaborated
at present.
Library of Congress.
Card 2/2
51--& PA A C
AUTHOR: Stepanov, B. 1. 48-11-3/13
TITLE: The Fundamental Problems of the Spectroscopy of Dispersing Media
(Osnovnyye problemy spektroskopi.-i rasseivayushchikh sred).
PERIODICAL: Izvestiya AN SSSR Seriya Fizicheskaya, 1957, Vol. 21, Nr 11,
PP. 1485-1-493 (USSR).
ABSTRACT: First are shown the fundamental tasks of the spectroscopy of dis=
persing objects. 1) Determination of the inner properties of the
substance according to the transparency- and reflection spectra,
J. e. determination of the coefficient of absorption of the same
substance in none dispersed state. The refraction-index must be
determined parallel with this. The true spectrum. of luminescence
must be determined with luminescating objects. 2) Calculation
of the coefficients of both transparency and reflection, as well
as of the intensity of luminescence of the whole layer for various
wave lengths if the coefficients of absorption and the index of
refraction of the element and of the connecting medium, the degree
of dispersion, the thickness of the layer and the fundamental
characteristics of luminescence are known. 3) Determination of
the optic properties of the layer of the dispersed substance of
Card 1/2 optional. thickness. - Subsequently a survey is given of the