SCIENTIFIC ABSTRACT STEPANOV, B.A. - STEPANOV, B.I.

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December 31, 1967
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SCIENTIFIC ABSTRACT
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Redox Potentials of Dithiophosphates SOV/"6-33-8-.27/39 pentasulphide (Ref 9). For the determination of the (HP) of the dithiaphosphates (DP), two methods were used - a determina- tion of the equilibrium constant of the oxidation reaction of the (DF) with iodine, and a measurement of the (RP) by the compensation method, The results furnished by the former method for an initial concentration of the (DP) of 1.85-10"' 3 g.molll are given (Table 1); as well as those obtain- ed by the potentiometrical measurements of various (DP) (Table 2). In order to determine the accuracy of determination, the standard potential was calculated by, means of an equation (4) for dihaxyldithiophosp4ate and comparedL.vith the experimen- tal data (Table 3). The reversibility of the oxidation process of the (DP) with iodine was found@ and-the standard-(R?) of alkyldithiophosphates was determined for systems in which liquid disulphide was regarded as standard state. The effect of the length of the hydrocarbon chain of the (DP) radicals upon the magnitude of the (RP) was examined, and an appropriate equation given for calculating the (RP) as a function of the carbon number of the radicalu The influence of the iso- structure of the apolar group of the (DPI upon the magnitude Card 2/3 of the (RP) was also found. Furthermore, the solubility of Redox Potentials of Dithiophosphates S.OV/76-33-4-27139 dimethyldithiophcaphate disulphide in water wap determined at 250C and a formula for the calculation of the solubility of dioulphides and other (DP) was suggested. The standard4n)' of the homologous (DP) series for the standard state (di@ oulphide solution in water) was oalculated with an activity - 1_' There are 1 figure, 3 tables, and.19 references, !6 of which ax-e Soviet, ASSOCIATION, Urallakiy politekhnicheskly institut im. S. M. Kirova (Urals.Polytechnic Institute imeni S,, M, Kirov-) SUBMITTED: February 11,, 1958 Card 3/3 AVSARAGOV, B.G.; NAGIMEAK, F.I.; SIFMOV,_-B.A. Ways to increase the complete utilization of copper and copper-zinc pyrites of the Southern Urals. TSvet. met. 34 no. 4:1-3 Ap 161. (14MA 14:4) (Ural Mountains-Pyrites) KLEBANOV, O.B.; SKROBOVA, A.V.; MANOV, B-A-, Using residues of electrolytic zinc plants for copper deposition in the concentration of oxidized copper ores on a combined flow- sheet. TSvet. met. 35 no.11:36--17 N 162. (MIRA 15:11) (Copper-Electrometa3lurgy) CHAKHOTIN, V.S.; UDALOV, L.K.; STEPANOV. B.A. - -- Use of natural gas at the Almalyk copper melting plant. TSve*,. met. 35 no-1149-51 N 162. (MIIU 15sll) (AImaljvk--Copper-Jbtallurgy) KLEBANOV, O.B.; NESTEROV, V.G.; STEPANOV, B.A.; KORFSHKOV, G.Z. Using the original ore to reduce an excess of reagents in flotation. Obog. rud. 8 no.2:5-6 163. (MIRA 17:2) ZUBKOV, A,A.@ STEPANOV, B.A.1 CHERDYNTSEV, I.Ye. Draining of copper cement concentrates. Izv. AN Uz. SSR. Ser. tekh. nauk 8 no.505-77 164. (MIRA 18:2) 1. Sredneaziatskiv filial Gcsudarstvennogo nauchno-issledovatell- skogo instituta tsvetnykh metallov. tITZITMOVO V.0111 STNI'mov, @PiAlk Thvestlanting the deewptlar, of butyl xwthato ft-M galmite by mate minerals during flatatIcne IW* All Uss Me Bar. taklu nauk 9 no* IsObW 965 (RIPA 1911) 1. SuInittod J%=h 25t i964o STEPANOV, B.A.; IVANOV, V.I.; GOLOMZIK, A.I.; NAGIRNYAK, F.I. Microbiological leaching of sulfide ores. Fiz.-tekh. probl. razrab. pol. iskop. no-4:118-121 165. (MIRA 19:1) 1. Politekhnicheskiy institut, Tashkent. Submitted March 2, 1965. STEPANOV, B.A.; FOMINYKH, B.A.; GAREYEV, V.N. Series of metal stresses in the solutions of alcali sulfides. 1zv.AN Uz.SSR.Ser.tekh.nauk 9 no.5:75-77 165. (MIRA 18:10) 1. Sredazniprotsvetmet. STEPANOV, B.D. Organizativakh Proizvodstva Na. Nyasntkh Predprivatiyakh. Organization of production for the Meat gnterprise Moskva, Pishcheprohitdats 190 158 p- illus., Graphs STIPANOV. B.D. [Organization and planning for enterprises of the meet Industry] Organizataila I planirovants prodpriiatit miasnot promyshlonnosti. Moskva, Fishchapromizdat. 1955. 330 P. NLRA 10:1) (Meat Industry) @*kTSPANOT, B. kandidat tekhnicheskikh nauk. @- - -- ;@kt A@W-- @* - " --.w r, - . 1, Planning of organizational and technical measures. Mias. ind. SSSR no.2:35-36 '57. (MLRA 10:5) (Heat industry) STEPAITOV, B., inzh. Administration of packing houses without sections. Mias. ind. SSSR 29 no.2:45-46 158. (MIRA 11:5) (Packing houses) STEPAINOV, B., doteent "Science Day." Mias.ind.SSSR 30 no.6:22 '59. (WRA 13:4) (Meat industry-) STEPANOT, Boris Dmitriyevich; DONSKOY, Y.Ye., spats. red.; MOISEYHY.P.N., spots. red.; 1107MI11A,-V.A., red.; KISINA, Ye.I., tekbn. red. [Production organization and planning in enterprises of the meat industry] Organizataiia i planirovanie proizvodstva na predpriiatiiakh misenoi promyshlennosti. Moak-va, Pishchepromizdat. ig6o. 383 p. (MIRA 14:5) (Meat industry) SMKOV, V.D.; ST,31PANOV, B. D. Strengthening the creative collaboration of science and industry. Izvevys.uchebezav.;yishch.tokiL.no-5:175-176 160. (MIRA 13:12) (Science) (Food industry) STEPANOV, B.G.; ZAKRARCHNNKO, B.F.; BEZEL', V.S. On rotating plasma. Zhur.ekap. i teor. fiz. 34 no.2:512-513 7 '58. (MIRA 11:4) 1. Urnl'skiy politekhnicheakiy institut. (Gages, Ionized) (MAgnetohydrodynamics) 011ectric discharges through gases) AT6o36573 -Kalinina, A. U.; Stepano,@,_ B. G.; Shugam, Ye. 1. _tj: none Visual ition and visual determination of the degree of similarity image recogn botween image per presented at the Conference on Problems of Space Medicine held sT in Moacow from 21; to 27 May 1966) SOURCE: Konferentslya po, problemam kosmicheskoy meditsiny, 1966. Noblemy kosmicheskoy meditsiny. (Problem8 of space medicine); matorialy konferontaiip Moscow, 1966, 188-189 1 TOPIC TAGS. vision, pattern recognition, space psychology, visual test ABSTRACT: In previous experiments, one of the authors, using a special Ielectronic assemblys observed an artificially retarded process of pattern recognition. Based on this observation, a description of the characteristic peculiarities of two approaches to recognition was given:- The use of one yields a small number of errors but is charac- terized by the retardation- of the rec6gnition process; the use of the second is characterized by more rapid recognition but a higher number. of errors. After analyzing the experimental data, it was proposed that under certain reception conditions, the speed of recognition pre- vailed with no substantial loss of accuracy. The verification of this observation was one of the purposes of jhe present investigations. Another aim was to reveal the nature of L 10954-67 ,kd_Wf _A_T connection between recognitior@ and the similarity of certain patterns. Simple, contour patterns were used. The contour was broken down into portions of equal length. By erasing various portions, lined patterns containing various amounts of information were derived. The position of the lines was arranged using a table of random numbers. The patterns were arranged in three groups according to the a-i-nount of information. The pattern presentation proceeded from a to a 'large amount of information. The order of presentatidn - within groups was random and uniform for all subjects. Two series of experiments were conducted. First, tests for re- cognition of graphic patterns were conducted. Here . the two methods of recognition were revealed aInd it was demonstrated -that the second method had the advantage of higher speed and quantity-of test objects to be recognized for the majorityof patterns in a given class. To solve the problem of the link between recogi)ition and similarity, a second series of experiments was conducted in which the' similarity, of a pattern to its standard was measured. It was -necessary -to compose a series with progressive similarity, L e. , each subseqi@ent'i NR: "AT6036573 t.'.orn had to be more similar than the preceding to its standard. A 1111.1115or was assigned to each pattern. The distribution of numbers assigned to a given pattern by various subjects was constructed and the mathematical prediction and dispersion of distributions was calculated. Later, the mathematical prediction was used to evaluate the degree of pattern similarity with its standard. After processing these results, it was possible to isolate 9 of 20 patterns in each series which signifi- cantly differed from tile standard. Ex-perimental verification of these patterns according to the same scheme used in a preceding test showed that of ten subjects, eight - - assigned a given pattern the same number and that the distribution of pattern numbers in the abridged and un.abridged,.series was identical! [W.A. No.'22; ATD Report 66-1161 SUB CODE: 06 /. SUBM DATE., OOMay66 Card I Ivanov, S. N.; S rtsova, N. Ye.; ORG: Insti-tute gr 1 radlotekhnW i elektroniki AN SSSR) 21, V TITLE: Investigation of GaAs p-n junctions operating as converters of ultrasonic oscillations into electric oscillatlo-ns SOURCE: Akusticheskiy zhurnal, v. 11; no- 3, 1965, 398-399 TOPIC TAGS: gallium arsenidep semiconductor diode, pn junction, acoustoelectric transducer, ultrasonics, frequency dependence ABSTRACT: The authors investigated the performance of GaAs diodes to determine the effect of the gegmetric dimensions of the base on the efficiency of such a diode as " lu'ttansducer. This influence can be investigated by vaxying In definite an ultrasoh c fashion the relation between the thickness of the base and the wavelength of the ap- plied ultrasonic oscillations, and observing the frequency dependence of the conver- sion efficiency. The measurements were made at frequencies for which the wavelength was approximately equal to the base thickness. The diodes were prepared by diffusion of zinc in n-type GaAs plates and tested by applying rectangular ultrasonic pulses to the investigated diode through an ultrasonic delay line (Fig. 1). The output-signal voltage was found to exhibit a definite dependence on the frequency of the ultrasonic oscillations. The transformed signal had a maximum when the thickness d of the diode L 12069-66 ACC NR, AP5021483 Fig. Diagram of test setup. q I I - Pulse generator, 2 - quartz plate, 3 - tested diode, 4 delaX_ line (10 microseconds), 5 -C oscilloscope base region was connected vith the vavelength X by the relation d i(2n + 1)/4 (n - 0, 1.9 2.* ... ). In the experiments d was equal to 1.7 x 10-3' cm.- making it poa- sible to observe in the 7-14 Mcs range up to six frequencies corresponding to the maximum of the converted signal. This relation is similar to that of a compound vibrator., and it is shovn on the basis of several other properties that the model of the compound vibrator can be used for the analysis of the performance of an electro- acoustic diode transducer. The conversion efficiency depends on the choice of the geometrical dimensions of the diode. Orig. art. has: 2 figures and 5 formulas. SUB CODE: 2o/ Sum DATE: o6jul6k/ oRiG REF: ooi/ o7H REF: oo6 ec"I Card 2/2 n:- s:@:s lo,,,;i j -h., 12) r c 9. Monthly List of Russian Accessions, Library of Congress, ju-rv. 195X, Uncl. 2 STITIANOV, B.I., dotaent; BOKOV, V.N., dotsent. red. (Lectures in the course of machine parts; brief information on interchangeability, toleranceep and fit@) Lektaii po kursu. detalei maahln- kratkie evedentis po vsaimosamniaemosti, dopuRkam i posadkom. MoBkva, K-vo vysehago obrazovaniia SSSR. Vses.saochnyi energ.in-t. 1959. 40 p. (MIRA 13:3) (Mechanical engineering--Study and teaching) 11 U u u a bb 11 m 'my T I CT, :0 A M-911-OL" .- .- . . --.I- @ 1-1.1 1 -- --.1-11 - - - - - OWil it A-0 PROPtNTICS I-Ot- H 99%. itne StISCUMS 4j 60 MOOMU*140, IAVVOI tt NIU"@- 544POWN, r4v. zeim. it, SpiqiMmims 0, a. pp. w4m, IOU la Geff"Al.-A rftMd ot **IVA spcuW*phk obwYationa. This -6" found for the smagnitude 0( tbo 80"114 *1 the U@ IM-140A awl 1746-MA are 2-1*cm.-lwW 2-13cm.-I. Z p - --- ------ ts A@l #.,I LA, STALLUUICAL UTERATtAt CLAWMATIC16 U 0 p to to ap A[ It a R a It 11 0 41 0 0 4 0 4 0 0 *sisal OK O"T M 01 Igloo SO.)xrega a a a 9 0 0 0 0 0 0 0 0 0 0 0 00 -00 -00 .0* 600 400 809 too 000 see 400 SOO 00 noo - v W w W w w w v 0 v 6 w 0 w w 9 0 IV IF v I I & 1 8 1 1 9 v of 1; It #a is Id III I# x V U In 9 C A L I It A A IL L a A f Q III UVIS l1AA1dtL1vtt,fk 4 00 06 .00 041 dr 06 so -00 00 The low* pwWwo baM group of cubm fba"A" to 2Z Chulant-L, and ILA- V M dw kkiiiiiiiiiiiiiiii rvg" -00 . . . Satijelam" 10, '.'IVJ .3141 so A7h, Imml, 13,M). 13.7). Il.-S). %) 44 the loutill lft. CO IV."II, 11) 41114111 1 . ( 0 . have twrn antitlymi. The "atk9tal 0-101. tJ OW 1VVvl, . 4 do* XI-1 atul A111, which hawr been .1cid. by Kher authws. elp ha%v been ebtcked and improved. In &H cd the tmnilfw@ IS, 9 pcrturloacktas wert, c4swrvcd mW invetnigated. The Age as J:: nirth"I .# dets. the "Ali'dw "taits. 4 the perturl" triplet Scrin hum 1XVII i1nivowd "nrwhat@ Coulph-t, Ib".4 the baM6 at, sivr". Ge"hinowns 00 0 8*41 00 0. 1 L A s4IAI,Lw*GK,,L LiT14411AI CLAS&OKAIPOO, at t1s a I V!Z).--w-jjv ado v WINS12 a a 2 MA.1 n dft 0 0 0, J, 0 o o J q o go 0 0 go 6 o I " A 0 0 0 0 0 0 * 0 00 0 o go 09 *0 0 0 0 0 0 0 RE ARR - RR I A 6 1 A A A _PT LID - - - - - - A -_ PROCtittl AND PBOVIIIIII )MOIR 00 :@l 00 j 00 00 .00 oes D9 4d 11 1 11 am* m Webb. i .00 00 A @ '.see oe @; 9 awe A 00 ' aw for dUbmm% -400 000 way be fmnd in Th d l goo 00 e meammo . A w,vfiwatkmW k"b * Q9'j b w i n w gm.a m q spe NINE ma aminmr, bui is raw. A. J. A j voo =00 00 414TALLWIGICAL LITERATLOE CLASISRICATIMS 1900 goo S413410,; .10 4.v 40C laluilme; cm a.. 14, I I g IN REPERLIER EIR.- 0 9 dD 0 3 1 v III* MAINE 169181 tug 0 0 4600*00 00000000000000 0000000 00 000000*00000 1 4 :*oeoo@oedle 00 "'A'SIM-60009000090000: frv, 'j@, -@ .1 - iff _L, - m . a a I I tl if k a Is as Is i I I A C A_" Ix a s a ' A-A -1- 1. L AI-A 1. a it I 1 10 ists - ..0 A FF ..* *w, i.."fas oo I.- is., I luvemillsollon of The Interediou ut visfitsus (molAill.w. A level -I' With I#V*J 111. )A. I@NVPArOV. J, PAVL It . '1@ lorol 411 Ow -00 111;1trix cletrictst4 ut irtcraction N-twa-vii Ill air, I " lcv,-I, U emot sitable f,,r t wal invi-migatril arld (orltitsla,4 m -00 00 oil %pin 4 Ilw ? oul"T pler(tom 1.1 (If, Ill tit 4 1 1. M %of Ilw -00 1 " III .. I... ... 1,11"I ..It . , l 1 00 I ... 1.1i ... 1. .-1 Ih, I- I .. -- it It 'If J 1h, I %I o..4 . .1 -00 he 1'.4muld I", otAtit, rtilo,ol, 0.0o".1 I,% 11-I.. .-d , ' *00 . A. 3.1. 7.%2414 limo Ow .-oos-it,m thAt 0%, ..v .1", it K Iwin% tit the 'it I"el arc orictitaictl along flit axii ull stir 600 so i% tm-lirv"I to 1w wronx. It i% turthcr %hown by af. is. that flit- vii)% tire ool ori@sttvd iti Ow dirretion of 00 It,, K It 1. finj1h, H'Somr.1 Isms Ow see 00 "t .4 ca- oI cooploig 11,11.0o".1 J." 'If -.1 ',I appit".41d.. I. Ow 'If 1-.1 V G-1,1 UAt A 1 4 1 L A of TA LLWGACAL L 111414T Wif CLAIMPK&I so ad., 4-.1- w4.Lnv wool .0 on, OL'Aliptl I;_iiiii - u a AV do as 6 Q " a 0 00 4 0 V 0 0 0 0 a 0 0 W W V V V 9 V IF W -- Tattoo- - Ita sub xvrl@-;;M 12044*bv ON--. 14 a 16 It is ff a I... A -2 a AA N Q DO tt 0 I- is 60 4f 0410119t Shope callearturbotion curve& for The intergecUon of 041 le'vels 'I an aIf of the diatomic molecule. R. 1. Step- 00 ;'nov- J. Phys. (U. S. S. R.J 2, M 9-VI940)(in I-*jjx- li,fil-It is shown, with the Mturbation of the sitilph- 00 feed r 0 Allf of the CO mol. as an example, that lite -!ripruxtrtsation given lay Kovics anti fludo (cf. C. A. 32, a`U01) for the intersertion of the III anti 'Z: levels does jwt always hold, owing to the intersection %ilh the triplet Icvt 1 31-. At the jaoint of interseLtion of L levels the ths. torting effeet of a third one has to he cott,idcrvd. A method is also developed for all atilarox. -lotion of thv "Vellar delcrininant (,I the Ihird ordcr applit-able in prar- ,eally any raw. It is finally shown that the nrvr%,icy 4of taking into arcount a third intrriArling levtl greatly hain- javrs the computation of lite const. of the 32; h-vel. Frank Gonet oe at A S+it ephiA 65't., 1 L Jolt. lofft CLAWFICATON A I a L A SIETALLURGICAL LITIMA a J--r IA A T -- -otm 0 a, U S AT OCII dj; IT a It' o o o ft It Is go g e o 4 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 C 0 C 0 0 0 0 o M .00 .00 000 @06 .00 .410 see 0 200 0 a 0 0 0 0 0 0 0 ; . i$ I . . . . . i AA #4 @C -4 A 8 1. 1. 460 -00 Valculedoe of t."Istante of lhv levol 1111 In 111"Irtnip VO 00 1 it%1,2*1111Y. J. 1'4 'V.. tlt@ .1; S It ) J. It,; _11m Iin " Mj);' ri, C. . 34, M41P., GCr'i'* welluld l4w CSICAS. tile fulall,"Imil con't. h 62 nor mpplimble wbm the pertuitistiorm am clowly spaml, -A 06 muce-amratif imthod of ralcri. is given. Mir the vibm. 06 tio"al levels v - 0 and v - I of the It 1Z male of Ili, CO mol. the cimplit. were ralexi. anti funint lo be It. - LVOV% 00 0 06 21M, A. .rlle' I"C X.Aud @ air In N..Kl alit,vulvill a It It I It, i-11"Itiv 0 0 wherne of Chuianovskil (C. A. 33, Interaction =0 0 of the level bIX with the Wo vibrational level* of the 00 triplet elete a OZ in the molecule CO. It. 1. SI rJusnov. see 00 Aid. Wb 12-4,11V InIrmVilois 44 tile Is -XI 411.1 a '_' mal- a, limr.11itairst Ily mrsht.1 the vmliirv A It liq the Vibrallotal klatrit P - 31 anti v - J6 4 the lierlin Imix too level a Ir we: AWN - U.MV, DO - 0.711. The reason for the relatively great intensity of the a "."@ a $11 Imuck (lite to the U., and 1. level., i., to be finind in petwiluition. me IL Usithmanil * o see boo 40 -00 oo 2t It, I W 86 a a 3 1 L$ a It it tt it IM0 n 1 1. 0 0 0 0 0 0 0 0 0 0 0 * 0 9, .0 0600 0'0 0 0 0 000000000 40 0 000 0,0 0 0 &.0 000 0 0000000 so STF2ANOVY B. 1. "On the Intera5tion of the Level b:@ Sigma with the High Vibrational Levels of the Triplet State at Sigma in the Molecule CO," Zhur. Fiz., Vol-2, No.3, p. 201, 1Q40, Lab. of' Molecular and Atomic Spectroscopy, State Optical Inst., Leningrad. t Q -M A oo -00 The isteractim of the pateatlal coves of a diatondc molecide. 1!. 1. 51cpamv. J. Phys. (17. S. S. R.) 2, @@1940)(m English) -Theoretkal-math. The reso- 111teractitm of 1kitential curves in inw@igated. I'lic """ins -4 thi., inirra, oily, -tion and it@ rtmnrct@m with ce h@ wdiflarY r@uan "Urbaition oi rutarkmial tevrl, and with [he ..,-aWd vilwational prtturlwt@)n have been a@ruaincd. F. 11. R at a ago 00 =00, goo Zoo 00 010 see see Ze 6 goo I z T', GO IKE 7.71 r- AW L i 1 9 it C. ic K it w to n @ q 91@ 0000.0 0 009 0 r! 64 0 0 ooo *so 000 0 00 0 0 moo use lee i. it is I. x 12 ;041 oo des Curves for the interactlow of soweewd. If. 1. stpldnilw.@ 00 Using Upfl. data of Jenkins, Rownthal. Rools, an,tAluill. best. tl@js niquPlettly the fvwwcc TIUrbation of tow 00 to Mit - It still A111,11P -it 110 Cv 111A. TIw ithapp of thr et1tvOll 1-6 In pollpvt avviltil *fill Krotillit's theory. ablepw W pe"Wiladon twes for W rosemasice Imiteracdon of the 'if and 0: levels of a dis- took 16d. 381- 5; cf. C. A. $4. 53411I.-Itt- Man'& aPProximaitloin (C. A. 26. 30. 27. 4734). in whi,:h aWy the mutual influence of two levels in mch of the four tmints of interwetion was con%ittert4l, tor the rr-nmicr twitlan of nug...uVil *-OW. liv.11i'le'. o It 4 11" 000 0 0 so 0 0 0 see 0 0 so 99 lee me 0 Ve 000 Ise lee I I too t9o too 'lee I 1A U I Y -1 9 AA L f, L- f 1. A. J L L A ft I Q It I T - U y - 'L-t- I @ I AA 0 CC W U Al 2 0 --A- go Perwisadma no" the adlesoclAtion Unit. It. I. -bo mj v 0 Las so w ;t,pawv , (U. R-) -I. - J. phyj q @@ nun),interaction between tliscrctc and conVA-110 C 00 wr is conSidcred. -rbe results are in nol di so 00 . al. i icva, of a nt with ob-d perturbations in the $Mtrm Of @00 Call. N.. S,-d-,kN- G. NI. Murphy so so -00 00 so .00 00 00 =so 00 -00 so zoo 00 io 0 00 41 600 0 z;O 0 Sao xoo too t!o 0 I L .1 t.LLLrGKAL S We MATUME CLASSIFKATKh too ISI gas U SS LO It ff it CC 0 oooo*:Ooooooooooooo: :::iooolooooo : *ooeeoooo :1 0000010000000000000 1099909000000006666 a 9 M 0 [A&'M-Ak M-"-M M's 0 a V V V W V IF V V V V - V - - 15 @jj j; if 1) 13 M is hS v M M 40 41 M A) as a VL_ 50 " p, "!r L so '06 Vo too -00 see C =00 Pnimbetions In molocular xpectra. a_L__Sgapa@- 17- A Ittt wk, -00 Hidl. "ad. jri. U. R. S. S., Sir. phys. 4. cf. coo C. A. 34. W46I.--Several cams of perturbation in the spec- tra of diammic mols. were investigated. For the caw of 'PI, interaction between a given level anti the neighboring vi-jr brational level% a method for the calen. of the rotational j ronst. is developed. Thiq mcth(mi k applird to the njolt. CO, flail and CaD. For CO mobt. the 1wrturbation't ,f the vitirstionallevel-twcreititificil. Unk.-tilatiaGarnow zoo see __oe too I L A of TALL.,'@,K" LITEROLAE CLASSIFiCATICh Noe _T -5 S a 1.d 0 4 4 1 ur 0 9 a a 3 1 T $1 ts IT '0 it .10 0 it if tt a (I q a Pt 19 it at x n i ju 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0 0 0!0 0 0 0 0 0 0 0 0 0 0 0 0 9 '0 -9000 T nin@7ad Le :,aboratcry of Ycl@@cul!ir inz@ @t:lfe, "The Oscillatory S'pectra of Hydrocarbon Molecules." Part II. "The Frequencies of Valpnce Oscill.-itions of a Carbon Chain of Molecules of the Paraffin Series." Zhur. Piz. Khim., Vol. 14, No. 4, 1940. 3TT q @' M. T - ; -14 -TT T- - - . - - - - - - - - - 7 - ti Ar Lk- - -z.- -- - - - -- ---- --- -- --- - A N M PD U - - - - -- a 7- A AL A-L-1 -L A 41 4 1t @I. k -A-,I -L L it Is F 9 Resonance perturbAtions in the spectra Of dIAWIME mOlecules IL I. Str;NIII- J Ph,, it' SS I? 1 4. go -A 1 21( I'M 1: S, ifn,r fl,,ft-tf 45A, I * " 'It 111, 111 \ '11, 111 X '11, 'It "f go of ... . ... PhIlled. mu ".1111-ill-41 I., 'JI'm Ow 11111.1 1.-11.,11 .-1 14.1 l-1, 0 aliv 111,111114" it 00 00 00 see of =0 0: j a J: 00 too A II aS I. A NETALLUOGIC41. LITIMATUSE CLOUPICATIO16 he - ----- - - -------------- S.111.1 -41 a., it, ---- -- -0@Clw Ar &1 43 3 9 r' 1, 'Via sit Mgt K gilt Iraq-Lon 00 0 0 000 * 0 If 0 0 0 0 4110 0 0 0 llit 0000 0 0 so *of* 0 0 0 0 0 0 0 sees 0 0 0 0 0 1/ d do ke"S"m it. tie iA@Ilrvstsch and 11, 1. Str Iaftj P S I'll) , 1941, 5. 103 1,17) A 111khm 13 t.thu!.Iting the VII)rA h'n @etjucnries of polyAt. I_, th.- 1-0-1 I.Itt'll'.1t If., '111', Coll. i% mutcr44111 I it - - - - - - - - - - I. is 16 F1 I-JM,T 77 71 ZY 0, a so aIt P tt4 T t- 41114111 ---- ,I , 00 J1 00 so Vibistiom spetum of hydicicarbou molocultim. V CAI culation of 11" ft"Meades of valence miscillfillous of carbon 00 0; rigg. J1. 1. Stepanov. J. Pbp cbsiss of the GIA�k w (,ktm. (1:. S. S. R.) 15 -797"M I)--- t 'ling 211 quation lirrivril fly El'ya'llevivit W. A. 35, 2117111 0 S. vale'. the o'cillation ItrqlIelivir, Of tile hirdr--ati,oll @ Ismill. of I fir willpIr olefill, Is m 'llown thm tile Charm.. IM111C IrVjUVI1CY Of 113C d-Aable NIIIII il A 61111-16.11 111 OW =00 I tire and no. oft he nciShborinig bond, but i, isniqwod,ii I the drSrec of 1wanthing I)( all furtht-r-frinoved part, of i;* 0 00 fhe inol. 71tv differrner Im-1wt-rn the obwrv"I and Oil :-alcd. frrqtleeci@ I* alloof 13 1-11). 1 in tmixht@haio =00 00 Z40 0 ooijul% 4od tru-mi-i 1,# 12 cin for doublv braw-litA .drfio, If Nallsolmoo 1000 Nee @0, C301111 tie -7-W7- 14 r Nee 4 j., a 'N LID It 8 1w 0 -01 0 0 goes 0 0 t --G III Go agog CO 00090 9 4jPW owwwwwwww-w- - Zi - ; I . I . I . . 1, 1,11 1- .11. 11 1. 1- IJUJUIS J417 Uncif A,1 L L L I L, U 4-1- L 9 P I, I k i I k,4 i -Oo -00 00 lee Oscillatino spectra of hydrocatbon molecules. Calcu- -00 tion of the potential-enere constants from the ouilts- d I ion frequencies of methane and ethane molecules. R. .. I -"It-pa1mv. J. Nvy. Chem. (11@ S. S. It.) Is. W", "I 041 11911); d , t'. .1. 3i, Kr,ultN of the valvii, aw see J, 'howl III IIIC IkjIIIv-,. zo 0 00 00 00 ;lee Go .700 ze 00 lp S I L I A L t AL I? 1 4 A fi,@ f rL LISIF 1CATfCk tre 0 i l 2 0 It K R it it "T W n if 11 IF A K a 0 *10 0 0000 41110141 066 0 0001000, a 0 0 0 00000 *Gee of 0 4 0 0 0 o 0;0 0 9000 * 0 e 000 0 0 o,,O.o 0 Ole 0 0 a 0 0 6000 0904 Oat I I I I 1 11 u tj 4 tb K. r a A I I v 1316 of prepm 'd bob- FLIANIMUM, AND S"PAP", it, Cft. a V Anw. Jw. vm, Wl. fi*i=c(tm"wdmdhw fftowndu of 'm 4a @--Nx IW Cakablien WAM wah (or nwham and echww OW ttAir am rand w" a 1@ Vithm rqw*wft-ia% 00 Wor"at MW &As" "M VAVkl4d With Old ilki "W knmm 90 Of (0" Cullstalits. Qmd Srvg@ 00 fflem with oqmdmmw vgbm aaa Oks,,A kdwo to a 4www jhWAMW Or frequw"imt, 00 4 A. 1. T. o V l$ X 11:1" me, AD 0 ell Is, It a 0 ro, no 0' A41 46O994O49::::::ee L j; L uId n IF 11 IF l' I@ 11 " a 9!* A 1 T -A, A- AA M of 4i I.E;I.l . : -00 00, 06 9 go' I make of udep". 10L M Efi&Khe%,dmdM.d Te M A j d b -00 Of do 1 1 . . m W& 61 MM m -.%- -Fre- 14$==T38) 1943 17 Ch R 3 1- . S i . em. oss.. . . tepanov U. dt, on the basis ofthose of CH we cak f C H H . m o quenc . an ,, . , ement with A l ogues. gre and Q1. and their heavy ana T I It 00 fr"luencies is satisfactory. zoo ro 00 voe A14, 1300 Ate ILI DITALLUCKAL L,Tf*ATL4[ CLAISIFICATION 111, 1, K) I u , t Ru staft Itag w W 0 1 W 9 114- a Aj IT T mton 1 I it IF OF W i ( : 4 0 r 0 0 0 Ole 0! p o 0 00000000000010 goes 606 go see go go 0 0; 7- -1 T 7, @ 7. @ @ - - - 17 j AA r- 'ILC Ltal-hil .1?4 IQ$ iR4._1__L 00 d Debwai"M d POMM min " Wmelawthau& 11. 1. Strpan,w (C ' * 19,Ll. 49, 2.,U-2-d2)-TW Weiieral : 9 vibrational " of polpAt, mole. given 1. 193) has beca applied to the compl 00 13 bromo-methanes. A comparison of 00 0 1 00 'A eadb ompt. ete i t AS-tLA attALLURGKAL LTINATURIE CLASSIFICATIC06 (PAIIN sit 149 MOO Her 0000 0000000 6001118@ for UkM &dv- reisd. Arid. Ses. (I.R.S.S. wethod for the calculati@,n 4 by Eliashevitsch (cf. A.. 1142. series of fluort), chloro, and got the vAle. obtainni is attern zoo goo, t!oe 200 Ez., tgoo S 9 1w 0 1 1( &1 5 0 0 0 0 IS 0 0 s ee 00 00 a --w - 00 jr a.- 00 00 Ir w 9 W 9 IF 9 OF 9 OF Is Is w a Is 0 w F01201, w lwlwlwl@w w1w1w w - w - w - w L., JD 1 11 n a u is IA V a .4, x 11 V IS JA t 14 V It it 46 &1 Q AJ AS JC et A S. I I k j 4 '! # P - it.- -.1, A- -f@ -rm -.00 1-06 Calculation of mkwwn vibration spectra of balwn- t 1@90 balitated methames. 11. L StelQUOV, L'OmPl- rf"d, und. iri. U.R.S.S. 45, .54-7(1944). @-71trorctically ralvd. vallue, are recorded for the vilxat ion of frequmiriti C I I i fir F. ClIfirl", COllf.F. cc[,BrF. CCI[IrF,. ClArY. ClirF., Slid CCIF1. It A. 0 00 J 00 ze 0 00 a 00 go. coo 0011 goO, .,see !see Zee oil t@oo .(TACLU14KAL LINNArtm cLA wFic,itich Ur. we* Si ._A: a., Q., 41"11 ut 4ft. 411 IF- (P It a, Or K ME If 09 n I ..a IN 'j ef di 000 0000 0000000 *&I I ; ; 4 1 4 7 *$A A 00 00 A j 00" 00 00 0 0 oo 00 00 00 0 0 M is Is V M " a nil P -g- a 1-1 - 1111, 1 -14 11-134 1,., -.9 1, MI, 11 , I, IT AkV IND CADIRS Spectroftolsic method (or like determination at tho hasil of the hydgfg@n haled. V. I. Malylhey. a, 14 16. U.N.S.S., SO. thyr. 9, &1,- A- IwArance of band spectra Is attributed to complei for III (iun in akohols due to the "hydrogen band" In the Mf radical. The beat of the bond is cakd. to 13.0 kii.-cal. per tual. from intensity trwAsurentictib of the spectrum in soins. of Clf,011 its CCI, at different terup. S. Pak%wer Rated*" in the spectra of molecule& with hydrogen bonds. H. 1. Stestanov. Ball. aead. sci. U.R.S.S.. Sir. Pustulation cd hands its liquids with linkages Oil.. .0 6 TIJIlAincil through di- cussion of their potential-mergy curves. S.P. j4'J' &IN-ILA WITALLURGICAL LITIR&Tt*t CLASUPKATICIN It J,., 1.0A080 -A 11304k) 41F ONY 04E I @rw :AT Soo is oo 0 0000000000000*0000000Ooooeoooo*eoo*Oo 00000010000000000000*ooooooooooooooooooooo,o::Il/ 11 U is Jill MIS 1917ARC Z; IP L__ -. 1 -1 _!@ .-D 1 1.0111 ,00 _60 .00 -Go -00 .00 T ro 0 00 900 400 800 gool woo ISO* tlowl woo 4,11"at 419431 am a.- all Lw Is 1 14 Ali A I a rhd 0 a WIN sfi-dw-d _too -0 9 0-0 -0 0 0- 0 -0 . I . . . . . . . Is j--A--L :0 0 0 0 :0 0. 0 0 a fit M A #A 0 st W a n I,- YT-M@@@ X V 17 IT p-, r x AA -00 ftediftacladoct 41 a system of discrete levels. It. 1. NI 1 114 (USSR) ys wpli-on hamis it nuskO out fiv the rhole seeks W ckmfly litinotell d6c"te levirls, and Ab. winkon CurvTo - of different 0 I no. cjk@,. 00 rhe dependence of obwxplkwj an The magnitude of the 00 inatrix element and on theinteraction of,liwreteand -,,2. finuous levels 13 considervol. JU nnIditions of con,plete roe ififfij,ion of the vibrAtIonal structure of the tIK%-trwn ar, Prutik 6,snet 00 CLASSIFKATION &S-SLI .11A111111 Al I V% A, of V, IF Op be IN 41 111 9 0 00 1949,1010 of *4 : : a so 0000 00 9 Zoo ago coo i-go 7.-0* tz A An I a n 4w 0 0000600 0000 00000 : : 0 0090900 ST]EPANOV, B. I. "The Theory of Vibrational Spectra of roiyatomic Molecules, II. Computation of the Frequencies of Halide Derivatives," Zhur. Eksper. i Teor. Fiz., 15, No. 1-2, 1945. Lab. of Spectral Analysis, State Optical Inst., Leningrad. 7 A A got, 00-rA 9 fl V lw IF - - . I 7 77-77777 T T 7till it 111v )I 6 C &.4-J _f. L 4 14, j v 1, 1. -A 1. 1 " K Q; 14 and lolpfPfflation 114111peulps 1 memylalrobol S 14 N 41 11 K, WMI ll..1swilvi., .4 ill'. HIIIIIIII) Wit, 4 00111. mul AS. IL tlAkLlf:GK.l IMOAlt"If CLOPFICAMP It It Ct I-A X90 t-00 UZ tie* M L Ni 6- n I W - 6 - # - q i 0 0 0 0 0 a G 0 0 a 9 * OWW-TE-W-w@-r 1- r! - 0 24 6 1i It to 11 It 1, 14 " m @ )I a - RD Y.a---A- J-L- AA ;P It OG* 0: The theo7of hydmvn bond. 1. Jjx*nAtjon of the 9 reg IlAritlea n the IpW,d ot tnoleculve forming hydrogen :10 bonds, by Prordlowistiots liffects. It. 1. sIqLall'ov (stilte iowual .1. '0151: cf, tog! . Ll@ I'llif 14% lilt- ()-it link It III till- st 0 0-11. Whom till, Hook It VIII'llooll, it I-millilIPM4 %to IIIj;j'I' 14 0 of 11111111114. 41111-1 14 joopmllllt@ loot III,. I 1 1 ; 4 Illitm- Italisilkloli frooll a ktubli. fit till till. @tjfr are Itrobable which fralor tutaflected till, (I 0 see V%P13in thv diffaiw haticit 0. on this toasi, it i, p0%,ij,1' voe heir %hifl@ 41tic too %lob,titillilutictt7f 11)1 lomyrneill Variations. ZOO !-00 i CIO* I L A OfTALLVOICAL LITEMAtkP( CLASSIFICAYICW (I., jooloo.,o;' _Lj *0 tloo@*)A- - - - @ 11, 117,,: La 'a . -6 1 a -or- It I " it is mw Ill I 9A W3 IS, It " a it 10 OF of 0 0906 0 *****a 0 0 * 0 0 0 0 0 0 0 0 0 0 0 0 0 0 so Wo 0 0 0 0 0 ak Ask SooW** 0 a 0 00 $0000100 0 0. _jwwwwwwww._Wwwww_w_ - , I I I j a I a 0 6; 1 i U i j ii T5 U -" !; M. r T-ii I m U U x it m a a a At a a a GE40 A I @L 4, L_J A 11- 1 L L h f 9- A 1. 1 _1d 4 9 A I. d I I 00 00 00 00 0 .00 :0 '-AICW&tWO Of the IM41116MC1011 Of halogen -substituted meth It ane, . Stclialuov. AIM PAV'If"(Awl. U'R.AN, 0 : 0 43 M(lillb)(Rholkh Millimary;_ N4,'111clir 1.*.. CI., 00 Will 11FAUIA61111CA 111011alitli life. Al"'I. milli I"1111.1ft,l 1.. -00 00 Sevelity-flille f1equell. it, sue talKiLit"I. 00 The fOrm Of vibratimis all(I file 1%1%. .00 Of th-C CIIIIIJK14. ArC (164-IMAIL 500 0 =OO 00 COO 00 a coo 410@ roo 00 V.-O 12 SOO n yho C@AZZ44 goo 0 SOO goo 1-00 60 cloo a of TALLUr&K AL LITIO47URIE CLAISIPICAUCII Wo . 2 ct w:: I 0 Ili,. ------- _ it .'v C., 044 -- -- - c@; is I ao@ a It p t, T r j - j opm sit Isa Iftfic 110( 0 1 illo A 00000 0 0 0 eie 0 0 9 0 0 0 0 0 001 0* 00 00 00 0 0 0 0 0 Ole 0 0 0 q 0 0 0 0 0 0 0 0 00 0 0 0 *1/ 61 11 a, IIJ -11 11-1-1-jL a m P a ai11 -1 ix @10 k' It 06 ir M 0 :4 17K 0 0 00.t w-Al, 1" 1w 'k IK V V-- 1-11, w-t ' "Valence Force and Central Force Models for Molecular 0 pal, Vibrations, Zhur. Fiz.) Vol. 10, NO-3, pp. 24.3-51, 1946. A 00 oos I oot I ad a IA 41 2 2 9 07 to P It it at A17 tr 01 2 00*606906006060660004 0 0!006000000000000000 -00 .00 00 .69 *0 .00 400 800 too goo 9 goo 400 goo '0 i@oo '00 PI i U400 ta 7 r a ts ts, -. T V,, V. W., T Iff, W, IT, T181, 771-yr, 1 11 It U A I C 1L. A., r . Q L- v AA 00 M it 4-, 1 1 The theory of hydrogen build. Explanstwit of the refluittrities in the spectra of molecules fointing a hydrogen i bond. by the predissodation effect. It. 1. v Oplical just.. I.Clungrad). J. PAY). 0 0 U.S.S.R.) 20, 907-15094f;)(in Rll-ialf); a. Ll 0: :.!*;A01, b!0*0-The txplin4tion givvtt lavvil)(tsly 6 put ' @ whrtwttinvr e(wation for tile rue tit, a quant. imsis. ' go ,, courdinal- and the vslcln oil ... o ii -solved tit jacoby mstilt accounts for tile eflect of file 11 W2111 vill tile witith and Ixttition of SIVCtruln lines at vart'j", ti,fults. 0 &1 1. ItLk,rulan 0 Y, f -0 Foe ei A I a - S L A OETALLuRrKAL LITERATURE CLASSIVICADOW me& -go* L It Q.w v .3,11 -1sk 0 j V U "Ilo fog taii list -"C An I S a Ad a - - I ar 61 '1 A3 it it it x Za 0 1 wit 0 0 64 q 0 ***sees* 00 00 0 00 *ie 0 * 0 0 a 0000 go * 0 00 0 a 0: 0 0 0 o o 0 0 go 00 go** 0 0009 00 0 0 00 of 7 7 T T 7 7 7 7 7 7 1 17 7 w 7 T 7 AwITT-F-I; r, IT A ,, - .. - A It L.-I F P it 1- 1 . III T I I-j_ 1_1 a a Ik U i i .-UM I Chag"telr6till: firequendes in the spectim. Of complicated britachad wafts. It, 1. SIVIL41mv (m.at'. (1101, .1 In't., .1. Phyl, It 1 :0. 9G -s R11.1imal). I'll., 'It. and l,xi It"Im-liviv,, ill mantAl Iwallill, AT'. CoMI'lled .1111 111~ I"millk'A jmlafliqt@, Xl4mal I"lailm, ISAV,- Ill., Im". I I Ill ( I)l awl [ilk) k 1). th,4-. ill tit, j.,Itctjtjj--, sitrA.111lit Ih, -h-li0ty mt ail Airbiltarr 1-1,srallm@ Owl, f1w list,-. 11111 11 11 Awl 11.0 1 11 IAtallm, 'll ilw Vok,11.1, V1. hA%, likil"I'l Ill, .,t tit, , Ill l4 A @ IlAll, A it, I 'At I tic dv(It. W ill, '1141, wt, A A WAmil"I 1,41.41 - till is Ralluff 'twegillin I, 111ti,trale'l In w%vlal . I. A 4 . . .00 00 -o roe qoo -90 :;*0 "'00, 1900 1_10 0 unutchl. Liltaillumit CkAtSIFKATFON, 77 XG0 ONE Ji-ll aw Q.. ill g."090 -1 - ; - - . . q r I - I - P - I - a I V ill I a w 0 so 5 Aa a 3 4 U In 4w va As it It CD Ail 0 4ff N KW n IU Thettry of Orews"Mitiambs. P. V. MI&LVAIt and H. 1. Compt. rend. Acad. Sci. U.N.S.S., $4, 791-794, Dec., 1946. --TV Dfw.A@ J4 trierry nbwrbcd in the region of sensitization is much less than that Wedlo bring in activated electron in the silver bromide lattice into the cLoMwnwAdwtdl zow. It is suggested that the machanisin of sensi"tion can be cwhiod supposing that the additional energy is furnislied by the thermal ei@w"Of dye molecule. Analogous phcnoawns owurri*S in the case of fluoreseme, the proposed hypothesis has a physical basis. the lowerinf of the initial sensitivity by st"titi dyes and the nwhasism of desensitization. 1111C. (based on S. et LP.). -fi-A-A-L-L a.-It P 0 C V it A 0 1.;, n-vias A : ! A 00 00 1 o o x I: 6#71 Tho Tbrwy of the opdw somaidwim so nwo- id i M I R P V M AA i ) w% . . e uu an.) &r and Mm n w& ( grop 1 i 0 eurfo . Stepaw:v. Roprio */ the Ae4demy #1 Sc of U-9.S.R. v. 54 Dec. 21 799-M2 1946 p , . , , , , (Sm abo AbIL NaL U1, IV) S 1. A RIYALURWAL LITCOATURI rLASSWKATMOO Ll S410" Ly 0@1 q&C sill 110" RMII 00 4PIV 119 u is AN PO wl- An Sal ;a, 11111r@ I I I FM 0 0 4 1 w 41 9 a 4 3 4 1 0- - - - - i - 0 -!T9 # * f-! ! A to 1 0, OK 1, 11 -1 if 1) 4 if t4 11 X I, -, ; ;; ;; -,, ;; i&II ti * 0 0 0 0 0 0 0 0 6 0 0 0-1w ll 1.411 Jill MMW41 J.141.41CO r, L II, r- IL L I, h r Q A Iv 1 1 AA Of Q W f _.I - - - - , - - - - - - " , -- ,- -- - " - , - - - ' - - - " ittgularifies In the spectra of MOIeCUIe% totinitig the in- t e ru i ol c c ul & r h b i o oge u ond by the p redisso c i at n e ffe c t ydr (SlAti, Oplival 111,1, Irililleva.1, %.I ' 00 f C, M I my '00 .00 10 .00 0: see 0 =0 04 0 0 00 -0 wee ve* lie ASO-SLA -ITALLtRGKAL LIt1QAI60E CLASSIMATIC" wee -,AA 0 @11 u Is AV K) 11: If 61 "0 n I It ti IP *10of COO 0 0 00 0 4096466411606064 0 0 4 1010*10 Gese **I, 0 0 009*0#00 "Approximate Method of Calculating the Fluctuation Wequency of Complex Molecules," B. I. Stepanov, 6 pp 'lz.Ak,Nauk, Ser. Fiz!, Vol zi, No 4 On the basis of the method developed by Ellyashevich and Stepanov for calculating the fluctuation frequency of molecules, the author evolves a method of approxi- mating the fluctuation frequency of complex molecules. The basic inethod was developed.for molecules of the first matrix. If this same method were applied to molecules from a 50-stage compound, however, one would at.. have to conduct socke 250,000- -operationa.-Submitted - the-Stat 'got e 1661"UitItite. 28T62 006cg$ff1 Ate pacrtmott '.v(s ..--- Tb4ory of tho op6w sedutt"b" smalsims. 8 1 skepamv and Fl. V. 011tiCAl JUSt-, J. PAYS. CAtm. W.S.S.R.) ji, if,24(1047)(in Rwmimn); cf. C.A. 41, W17C.-The -00 aeldnl. energy requircol to lift an electron (if AgOr into a catul. band, when a Aglir mulsitnt it ilblinift4ted With 109 9 long-WAvc light, is suinwheil by the vibr4tinual em-rty pf the mn%ithind ilyr. The miginal owle of thr dyr i. *0 minwiliAtcly r"Itpred at the cxtwn%e of the heAt rurrgy W file sy'Ittil; th - -AiNfity at nue uog. i. i"xuunt@ for the pr 4 dyc vau%inx ftwntatiou of numy Aft aloem. From the dejoemirnee of file Wiltilivily of the sen'@Wzrd rnluwtml ms the wtive length, the no. W dcgrm of frectiont invi4ml =0 : i,& the tran4vt tJ energy to Aglir is cuW. to tK- about :141 0 f-W CrUift fly"- 711C theory expWins. 9 essenwi fra- IV 041 10 0 J. J. Dikerruan 0 oo goo @ 00 00 11 AS-SLA .1TALLUPIGICaL L.171*47M CLAS$WKAYMN "68, - I 1 1-- --@AL@@ .30" SIT,# - %xja4j .1, 44t u u AV 43 Ali; IV IF a x K a a a a x a is a 0 0 0 0 : : 0 0 e 0 0 0 0 0 0 .1@1 so-JAw IX"Ani So rig 0 m v i v u o a a 3 s v U0 I :10 0 0 00000000 0 41 0 0 0 0 0 0 0 0 0 goo too set !100 age U00 too STEPANOV, B. I. USSR/Spectrum Analysis Feb 1947 Pentane "A Theory of Vibrational Spectra of Polyatomic Molecules, V," I Stepanov,-24 pp "Acta Physicochimica" Vol XXII, No 2 Calculation and interpretation of the spectra of normal hydrocarbons., the calculation of frequencies of the normal pentane molecule possessing 450 free- dom., the interpretation of spectra of all other normal paraffin hydrocarbons, the treatment of the rotational isomerism of molecules of that type, and proof of the existence of a rotational isomer of lower symmetry for normal butane. 9T25 b&Q - A 2, 3 STHIPANOV, B. 1. Author: Vollkenstein, M. V., El'iFLshevick. M. A., Stepaaav, B,_I. Title: The vibration of molecules. (Kolebaniia molekul. ) 440 p. City: Moscow Publisher: State Printing Houze of Technical and Theoretical Literature. Date: 1949 Availsbie: Library of Congress Source: Monthly List of Russian Accessions, Vol. 3, No. 3, Page 164 Call No: QC 173-V815 Subj)act: Molecular dynamics. hdrartid spows of uranyl Wlis. A. N. Serchettko anti If. I. SteRng A rrof.*. Fill. to, It 13 -' .11) 1. Y_'zkUv. EkIpah Effhl. Of Absorption made On fine powders of tYtNM_),.3Il,0 (1). XlT('h(S0o)r.211r0 (U). UcAlf4co), (111.0 (111). still U(so(N(MIAHS0, hel't between floorit plate% translAntent to oil) to 11 A. Or lActwern crysfY transitarrtil up 143 15 M. in the t,tille (S-t2 $4. test it) and Con"ItlJots. at vistriance '.ilh thow CAI Conts and WU (C.A. 33, NMI). Pvrtincutr of the Sliscrvird Atomption lvaks to tile ljo@ ion, not to the anion, was ."CertAillM l.v C ..... with all,orption slwctra I,( ll,so#. KSA)s, and COSA)#. lit tile %Atne region. The ol~fvrtl Irrilm-tivus son vin. 1) an,l noilsillnuirtits are: I KM ("). 913 f"), fill) (b.'), 1130 JVA I vs). IL!Ivl (thAt, ra + 2rd, MN (7v,, 1. + 3"), N7.3; 11 tit$.$ ("), Kv (5,P), lixid (PA + 1,,), 1130 (P3 + Ali), 12114 (ti,#, P, + 2rl) ; Ul 9 18 (1,,), If 11)(1 (Soi). 1420 (7-1, P, + 3,:), 1515 4,v + 3PI). 877; IV 9633 jr:), IIM (Pj + ft), 13113 t., + 2.0. 1390 (7-t. va + 3-0. 1515 (P. + 3n). These Irrquencim are cOnsistrait with the fundaincrital vibra- tions All m MO. All - '21(0. P2 @ MM coo.-I. The %-try interim frequi,sicy S', 3 in 1 (977 in JU) remains unamigns d, atilt its Absence in It unexplaincd. Thc high intensity of %o) tfwp j@ surprising fur so high a harnionic. The -igntilents All ILN)I arid of MV. Are Ambiguous. oil the basil Of the a,,siglournts given, the U0, , , anti I cannot p(milily ha.w As, linear shape, oil account of the frequencics ?M, MU), amd 12MI. which are fmbidden in a li"ear uuxlcl; cun@cqurntly. U0, - fit 1. anti also in 11. is bent. (9 tile ftequencies ot,wvr,i in fill ,nly 1515 is forbidden for lite filleAr Ittalm; tile rvinaliling aII, allowed. anti frAltinctivici oft,,erved lit I anti Ill whit-h Are forbidden fur tile lilw4f III.Adel.arr wholly ahl,ent' coo,t- quetilly, in Ill. the U(N * ' full muilt lit nearly lincar. Ilossibly, tile amigninent of 1615 to P. + 3ol is wroux And should lie replaced fly P, 1- 3"' with tile deviation fruill tile Colcal. valor title either IV Frrild frMillance Willi 70, I* to) fly au'lloplon'4 cull'i'Irfation,%, V(h ' ' in IV apiwar, lo Ile nearly 1111C.Ar. I of I by heating it hirs. at ;441, 'hw, Ilk't Lite I lite t "'AC'Uttli It, of the altllorption maxinia. bill it d4xA after . At hCir relative Illork4lver. xives ri'C l" a lim fir. Ifnelley m JIM41 vln@ I J" f- ") Ili,.h j, t"M"I"ll, t'M@Ilt ill 110tated It -Old IV SylilliviiiLd antiv.1. 1'6,@A). I,_ A spectillol V.1y Ann, 11.1ilkirill festal 6.01 11 411.1 it practically Undefituor, III) vilange Ill I %tilt norAmally humid air. The uiujl bAnd' At 10J, N.2. Atilt 7.0 ". ("' tall, Atilt 14N CIII._') Are either absent or very weak; if the Litter two are interpreted as hjrinwiks (62 and 7.., rather titan as combiliAlions rt + ;.1PI ;tilt] P. 4@ 3", this may me-An that high harnionics are linked Willi the Prr,,cnA:v of CryAlls. 116,0. Of that 11,0 tightly lostand with the Uok- jug, incrrale it.4 moint,111 for h4rinooic% of PA. The @pectrunj of inhysi. XIIOAI@ AIMY the 110) (P, + It) in 1. The clOstrite- of tile 1-111d IWIlwovil 140 atid the Ut I,, - iwt 6 further indicalctl by the almence. in 1. A)( the A; A, Abs"Ptionfiandotil'o. That IIAIIII Malqe..S ill illit"lly anhyd. VOtSO. after it has been exposed to usoiture.and belongs, evidently, to hygroscopically condensed llso- Its @ntvA.@t to U0vS0,. the spectrum of dehydrated IV chAsige., with the duration III exi"ine to) mosiNt air. Svn- the-iml U(N(NOO. with 0, 1, 2. 3. and 611.0. "hilviN file @alllr fiv%plestries, fail 13913 i. at-I ill tile prt-Im with P@ 1, Awl 'Aist). 6 strall in tile @dt itith 3144 1. A-1 lauly h-1011W isilly ill IV (voWl 011,0), Till" -v- filill, fll.tt Cryltu. IllO l*CihtAtC1i the A111WAMAICt 1-1 high hanitusises. Ott the Other hAnd. the thalle of tile I'll lis ' ' istli i!l little affected by tile Cryan. Iflo, i.e. by tile vrv@tal lattice, Which afforctis istily the rditivo, intVIINItirs. Ill voutrouit to dw infrotted isilectrum, the flilitic.'rme .$it.,-. truill 4d UOM " milis it Olts"sAly sit-lovillient till tile ezvoll. 11,0 content, which affect* tout ottly tile relative Ijjtvjj,itj,-, lout alai the vibrational strtwtuxv. i.e. the vibratitai.tl firques vivs. This C0111fAdil-tiOll call 0111Y 1W 14krll I-) 14 i'sibeate tholit the ount. of t-ty-itti. 140 Alid file 1.0mv @"-wtum. while it dw* 11"t 'idilifintrilly Affect tile v-da... timis At%ml. with the lvwer oolectrosiic lrvrL dtw@ have a det@isi%c Cifeet lot the vibratitulal 31ruk tuft .1 Ill, r vimtronie levd. N. 1,11"n r V. and I-bL'YAS*.iE STEPANOV B. I-j, VOLKEIISHTE'-ql ,- 2a@@@ t, 1049. les MOSCOW-Lerdngrad 5 Itc. Tech. Press .,s@jll@atuons of !;Olec" i rn, 195o skiY, Sov. irniga, 1-10.1 by V. Chulanov USSR/Physics - Nev Techniques Oct'510 Light "Determining the Duration. of the Excited, Oscil- latory State With the Aid of M. L. Veyngerov's Spectrophope," B.-T. Stepanov, o. P. Girin. "Zhur Eksper i Teoret Fiz" Vol XX, No 10, PP 947-955 Investigates procesies occurring in the chamber of Veyngerov's spectrophone. Determines lav governing time variation of temperature during pulsating illumination. Obtain mathematical 169T98 USM/Physics - Now Techniques Oct 50 (Coutd) expression connecting quantities measured experi- mentally vith duration of excited oscillatory state of molecule. Submitted 9 Mar 50. 169T98 P4 r. W 0 - 0 - as W W Ml' w - ;rL - W- -- - - t W I It I a t to It 1) )1 It Is It It Is" V k ]Ed It 1 1 1 AA IL-'j -t -A A @L' A -"--b -1-AL N r-A k-LriM 40 Apt, It. -of. 40 lit AND RD 0111)[1111 A 40 PROCISSIS A.0 FROVILIT191. INDEI 4729 0 0 RFPZCT Of WATZR OF CRYSTALUZATIO14 ON THZ FLUOREWSPICE BPECTIttO OF URANTL 1111TRATIC. 00 PART 13. A. W. SMbwko gall S. 1. Steputtim. Zhur. go shalow. I To". M. 31. 313-10fWFyi-&-ami -RUS.1aw Part I of (Me vwk appeared In Zimir. SbWl'. I Tooret. Fig. 21 2"1951). Changes In the buinber of molecules of water ad crystaUlzatiom in uraskyl nitrates are accompanied by consider" cb&Ws In the frolquimcy both of the sym- oo metrical valwy 00C1114110as at (he UO;* Ion in the lattice and of the electronic transitions. The fine structure of the oo spectrum, " observed at low temperature, to determined essentially by transitions bet a Is energy levels of the crystal lattice. ugly a tow lines being due to transitions between tilsdromic-ascillatim levels of the uranyl ion. I L A 011ALLURGICAL LITERATURE CLAIISIFICATICIS 7- 7 0.1 eat U % -0 a Q-V ji it 1i It it it it 0 0 0 e 0:6 9 0 0 0 * 0 0 0 0 0 0 * 0 0 a 0 0 e *to ego 0 0 000 0 * 0000 -a got zoo '06 cog via., ltittilo-cl An I S a ad 0 alizill OK d-v Lit -j " a I It a K no n I 0 JIM 'L. 9 a 6 0 0 0 4 0 49000000 -4 4 00 -of 0 oil: CP "Aftore of the elementary precool" of 4 %"One"* *4 wanyl coaopawaft@ It. wranaw E Eftwes. PIS. It. JIM-4001S.- NO-A Ikilp. j;VA: (AITM, a m4d* ve the rotitrudict4m hirforen the order od nuti- rillude C4 thr life of all V%Cifc.l state of an eloc. dipole, 10 " Ver., Arl'I the rajol. or,ler -4 ritagnitiAr. 111-1 me.. of the cit- eijr,I stair in (34 %iRt, The jwinuv@l tmAuthill cA (his . ovalirt 1. hap-e-I (01 tile it IM11.01111 thAl, i114111MICII &V CIVC- lF.j.jjC VXM460t! k1t ('()' Ili A @110`ltdl tAttil-C IS tltVr*"CiIY by a ChIllifir of file j."itions ol thestorns within the km. it cittem al- proftlev a flelannatiort of the surround- ing 1.1tire, Tile ffA ~itation rtirrsy ir thus composed ,J the etrilaii-i --sy pr,,i,, f obe elertnwi cloud in the I'# I- - I ... 1 -4 the en,ricr -4 -1-4mrnation -4 the lattice. The. 1.9" .'t the tAtter 144(t I,, bff@frtll VO, Oftlis appears ill, Laa #if 1*4sm4l,w (C.A. 43, 4IM61). acewding to (III. electtorlic excilatimi energy varics betweett .1iff.-resit _11@ by At much as ils@f rin@ -1. Tile sanfle assump- Il'of 1, It'liber "WFtAKWAted by Sanxillfw's (hAr. cit.) dils 'howills '114et"W,s It the vibiIiijon fretitwilciri; in different i*s), Ill, '@rv,brjiW on.1 Siq--'. (CA. 44. 47)424) Pt'lolif flint the very Iczt@ -I the U(n' mar he different itivot -w twill) fit diftclictit -sit*, a"d S. and S. (C.A. 46, 4t""' W.- ""I I'm* 4 rhalips 4 She Ilwarvislo as allairtrunt drIM11,11119 -.11 Ilse "I,, It.() -4 eve%ta, The, Infill'oro Ill the *11frf"tilding medillill Inanitesin limit Itatis" III the clWWArt.h1v broadening of the emission Ulurs of U,%Mtt- in 0*411, will ill 16%nes. The life V all the exclicif stair is in- Vrt%elY ll"%WtkM&I to flit pCOIlifibilitY P Of the ekVtfililsk fian@ili,ml, which. for dipole ernluion. clin be written p - pliffinfid,11. where pe Is the ttanaltioa probothilit in the 21,wnre of lattice deformation, and the intelfrial T.Lk. the Initial and final-date wave functions of the lattice: firoin the expil. facts it must be Mnch3drd that the value 0 this Iniefiral is of the order of 10-1 me. The Imig-lived rnilwiim of Uth sells. detected by Nve"llaw and Sevelionko (C.A. 4S. 407d) taust he attistmit"t to ut)l -. whir%, .@ cit- citatiot. comes, 0 particularly strong defoevastion of the &at. tice and Flar which the value of the integral in of the order of 10-4, beam p of the coder of unhir. A I o6jiscom apinsit this awroption Is the fact that no indication of a Ot" Imillor lnt~km with the lattice Is lounil In solid amIts -4hrr then of umnyl. N. Theft Wideb of speakot Half* of Ofamayl Saft M4 he i 81*1milov. Atr. Fhq4l. 7=V. 11. 114% 4U(ItjM).- Ale$ wrvn the fartup. a-( liattild flar and totlUt tCUTP., three hl It XCAdUAI broadcolitit of the emillmallom; lim- of VOt ealts. cutting in comphate "Plararmalft of 0 firiv orurfure. )IT, the pFkh*le of Incliftermilmawy, I" -idth AF.d a Irvt and the life r of the @tat* am rollated by A X', - I /r. The abclarplicam set a" be follatifird by 6 tyM .4 tranottionv: (1) emism6im of light a r*d by trainitilitm of be 1,10: 6 to flail, th"colde fir F= a am "t to C conversion of be elertronk- enersy, of the fort to imatmotical. or Lattice vilmartku; energy. (3) Conversion of istemmool. to laffiev vitairatiou energy. (4) triffirfribution of iWoud. valmatiott onarrity liver tire whole lattior, (5) Imada ad the lfthorftmlm@ five probabilities of thrir by a with the -w-ampoinfingotaborripts.tile width cal the given frouslationary Slatre a' 'he Cry%#" 6 -.It - (Or + at + 08 + 04 + OB)IC- Front r2pl 1, data. I lie vattle of a" 6 known to be of the order ol 10# if that Proval "me were derail. for the widtb (h* level, an, Amtikl have AF - lit-11 com.-I. CONSIP. 'Juartatir. the efflissiou Ullar width cannot fail darid. by proclaim M. Fron; data oil trints. quenching tat the flularmVem us U01 malts. the C&C-1 14 process (2) calls be at Inctill of the order AN m 10" c-ni.-I. 'I'liat the lanallability of prax"vmm (3) is lamittilibletila, higher flail" the part4mbilitles of the lot 412 Peale,"". friams front Ike ltwnwndoom 0, 111110 op"i'll"afR OW quarmtom yki.1 tA the twor"Mam 4d 0A "0 of the cracking radisatim. which UuMm" QMW MW 5= I Ivcm only a" or. at NO- ismal conseqaaarattv. a farm arattelit of Vbndm into vibration of 01111, laido. Fir that , width the fears, ad 4=14. 2!! be oW. ft -lo-11 w.-l; a fmA hwv" of that Ituip. is plattoitak. but is 111%auffick"t biroadmingal the lot stroulatal NO"- FJW (4) in a =tigm to the rentutbatim wWb is do 1 .1 on, L-CO. . tWw4*W tillt b"k* Vkh *0 velocity of mound. m-sulto In a ravelled of dw Withal PH 1WIl t ioak Over 100 at. di*tAWA'. Al per tSC.; Lll@ dW Ift Of 0 pe"tarbation feat thatordew oll 110-11amr-arms - 11810M.-I. anti that ecrilitimpostifing Aj: W XAO Calmodarmal WM me c%ptl. armisokin band wkith of 110o mks at V~ tsuiP@ Tbb l4tit-rato Is about at lower toppe. an awguft Of 1111111 -of the amplitillies. 'no exideme at Plot"* citel by the tlepolatitation of tk #Mb*A Of at advamiced stages of the allivay (SewbftkD, Ifowevir. the effect of that tollim" ad OW ex. citatim rilem from one U01 * to aftelthelf. - the a- WWth- is lamilit"ificant, The decivivis larloo 4, hr the I !bar"Wirttlas of the Owthiplim limaim, of U01 limmar is this red,*- ,tributinn of the lattkv vitirralliam " - harm @ limbral i with art isoloted UO: , are lnC2J;m,&W CT;"mi" Ior that Ahroadvalag. N. Than iO J USSR/Nuclear Physics - Crystallography Oct 51 "Width of Spectral Lines of Uranyl Salts and Its Dependence on Temperature," B. I. Stepanov "Zhur Eksper i Teoret Fiz" Vol XXI, No 10, pp 1158-1163 Studies effect of various transition processes and energy propagation in uranyl salts on width Of spectral lines. Shows that most important is ef- fect of distribution of oscillatory energy, in cryst lattice. Hence spectrum t*ype is connected with change in cryst lattice. Stepanov acknowl- edges A. N. Sevchenkols advice (cf. Sevchenko and Stepanov, ibid. 21, 12, 1953X Subuitted 29 Dec 50. Tic 19=00 'YibratioJE!_e1Le and tcomplex mD!e U3 @- @ , : - 43. 1951 of a Collipiex firg. 'tf the CiFivieller and tile tim:16-m "i v:11rat.1,311 (nwtv", ;m'i odwr fealtir"S of I!:(. or;r. 111"I. al,_- -Most of Itit.- ivrtrk tic ml fillt'lUic0liCe ill arc. diflicul, ti) 'nake at c'Illij, fill' ill'VCitiVA- 01f, fill, of val'or- l1w.t. do not doll of . fircollip. oll 1:v3pil., pvc.-S tilt! ;Io.4-@ihiliLv t1f Stll,!Villi; 1.1.Ally aspf@as to olitidn in C,jitijtlv.% nioli. are mols. in whi: t'je c6f t@nerqy r@_,,lklrihuticill is grc.ltier 0'w the v@Czprl_-,d, 4 tilt! lifetimc! of tli@ excUcA @tatu. I'll(! ipeetra are li:ic slxcma in simple mok., diflused @Iqll: 0". -alit I-Mqr;!Il loll'i ;1, Complex mols. E Irlis- sio:1 and zlb@rrptiori spectrri 1:-v-c@ mirror svinmeEry. Tlm n output is lar, quantun - go'r ill suill@ thall ill %-aperi@. Tile life-, ti'lle of tile vxmterl state und the quenching by other gases are tltscril)ed as wAl as flic ill,,ma@c in filuortscence by fOrCigil 9USQ'S .111d tile (if fluorc:cence by collf- I)Y tritu@ftr of tile vil@ratio,i energy, characterized byaji @@acc")mvnodatioll c'j-21T." (cf. C.A. 4S, .555118A)@ 11. B. 1. - : t,pa;iov. Ibid. 402-25-1 thcory of ioealiz.-ition oryri c ;@=Dlarion cnergy on certain degrees of frecdoin is developed. '0%vizig to a coutinumvi Omnge in localization -and a redistri-, bntinli Of %libratitill i!jlL:r,,,y (if the mol. on diffurent degrees uf frt@vdrljn, contintious spvctra tirv- fnrinzil. Thus classical st:itistios can b-L! appliud to suci! wolL;. wbic'?i -m have thei, Mvil specific ti-rip. " :101 "Ile alld tile dkirihilti,in fulluli, It of :t("! - t:it@zl ;k-" olci-kc.1, and HIC dvv;tv Hult, uf "'m 1), C@klci. flot'll fm valiots and for soins. The kl;z@;nluat outpur, ;m(l ffic temp. (Iticuching of 11timesvilce are also Jet ivut! frvrn tile distcibu- tifill fulletioll (cf. 4tl. 1 STEPANOVt B. 1. USSR/Physics - Oscillatory Spectra 1 Feb 52 "Distribution of Intensity in the Oscillatory Spectra of Linear Chains," L. 1. Vidro, B. I. Stepanov "DoktAk Nexk SSSR" Vol LKXXII, No 4y PP 557-560, Calculates the intensities of infrared and combinational lines for 2 simplest models - linear chains, using the valent-optical scheme of M. V. Vollkenshteyn and M. A. Yellyaskevich. Considers a simple linear chain consisting of 2n-rl identigal bonds: o-o-...-o-o. Acknowledges the helPful assistance of Prof M. V. Vollkenshteyn. Submitted by Acad A. N. Terenin 4 Dec 51. PA 213T112 1'.., c v1. lpu,@ I- a Z-ic-l Sevchcmho) A.IQ "Inv@,stication of the Lirunescence Academy of Scimces Belorus@ Stepancv, E.I. ) of Ur'anyl GcrapoundsU sian SSR n's law. a law. o S S. effect j- whe, formulation of Kirch resence of rog d nwo ol -ta. t- the radiation and 4. sub- Vcquk stance being Irradiated Is dirived. TheactualexpresslonoU Kirchhoff's law is (W,1IVt)j(a,1IVI - 1) - Ir. --@ (8r-' hrl)l I".- I /(eMr " 1) instead of the conventional formula I Wrlav @ M, W, ;w@ M.(Srh&J)IV' I. and av - Mrs#11:, resp., where IV. - potency of an isotopic substance to emit. radiation. ;K - potency of the forced radlation..d. ability of the substance to absorb radiation, U, - d. of the! radiation energy, h - Planck's const., V, - velocity of the*, radiation distribution in a given medium, Y - frequency oli the radiation. k Boltzmann const., and I' - abs. temp. AOL USSR/ Physical Chemistry Molecule,,. -Chemical bond' Abs Jour : Referat Zhur Khimiya, No 4, 1957, lo847 Author : Stepanov B.I. 'A-- Inst cade-w--U-Tciences Belorussian SSR Title : Probability of Electronic-Oscillation Transitiohe ar4d Lava of Fluorescence Atten-dation of Complex Molecules Orig Pub : Vestai AN BSSR, 1954, No 5, 6o-69 (Belorussran); Izv. AN BSSR, 1954, No 5, 65-74 Abstract : Uara 1/2 B-4 Specific features of emission-And absorption of light by co*lex.nolecules are connected with the occurence Of redistribution of os6illatioin'enqiij@r bet- ween different degrees of freedom. Optical'pr6perties of molecules are- strongly affected by energy exchaige'vith surroxmiding'xiediua. 'U this Paw are investigated characteristics of probabilit.* of traiwitions with -adoision of light in cozple@x molecules. It is shovin that this to *ener& exchanti'vith surrounding medium,,probability values of all optical transitions are avera- ged over all oscill tion levels of initial electronic state. This ex@lains the rigorously exponential law of fluorescence attenuatioji of solutions of complex molecules. This law is found to be the as for all frequencies G O.P.; ZHIDKOVA, Z.V.; S7X V IVAIIGV, A.P.; TOPORETS, A.S. Determination of the true absorption spectra of scattering colored objects by their diffuse reflection spectra. Izv. AN SSSR Ser.tz. 18 no.6:728-729 11-D '54. (MLRA 8:3) (Absorption spectra) (Lighlu-Scattering) Wblt/ Physics - L@uantum mecrani.cs Card 1/1 Pub. 22 - 23/63 Authors s Stepanov, B.I:, active member of the Acad. of Scs..of the YSSR Title I On the quantum output of fluorescence Periodical i Dok. AN SSSR 99/6., 971-974, Doc 21, 1954 Abstract t A more precise formula for camputation of So._Called "quantum output of fluorescence" (the term id defined) is presented. The formlAa enables the quantum output of fluorescence to be computed by takinke into account the dependence of tha light on the thermal effect; the formula is ex- 110,vis. pressed as fo - A V/1C r 10 (1 - e- A vlk r) 4- and the symbols are explained. The quantum output is always less than unit, it equals 1 only when S r-O or de 1. Two USSR references (1951). Diagram Institution: Physico-technical Institute of the Acad. of Scs. of the USSR SubmItted! ...... SNVCHINKO, A.N., redaktor; ALWANDROVICH. Kh., takhnichaskiy reaak"t or [Luminescence of complex molecules] Liuminesteentsiia slozhnvkh molekal. Minsk, Izd-vo Akademil nauk BSSR. Pt.l. 1955. 325 p. (Luminescence) (Molecules) (MIRA 9:9) Piiysics- C@ I'd 1'@l Pub i46-24/25 7C' Author Alentsev, M. N.; .4ntcnoi--Forancvskiy, V. T.; -1itle : Yield of resonance fluorescence of atoms R-@ricdical : Zhur. eksp. i teor. fiz. 28, 253-254, February lP55 jkbrstract : B. I. Stepanov (D.W SSSR, c;q, OTI, 1954) thC -,t- C' of radiation and system consisting of atomf-- posses@,!.n- enerD- an@ showed that the radiation output varies in @ne-e up-,)n the -'-v,--Jty of the exciting radiation (thiS CODCIUSiOll 11-0f-Y'S tL- the toti4-1 n). The authors apply the proposed method to the calcul-tion of the otitout of a similar system, e.g. the resonance fluo-.-escence of atc:,:.;. obtain an expression for the quantum output of -fluorescence. Institution: Physics Institute im. P. N. Lebedev, Acaderrj of Sc:iences USSR, Physics Institute, Academy of Sciences Belorussian zSS'R. Subr:dtteid : November 25, 1954 535. 345 : 635.231.4 4327 ! ABSORPTIOIJ AND EMISSION OF LIGHT BY A GREY @SUBSTANCE. B I StUanoy'. Zh. iksper. td-dF @To M, No. 6, 559-66 (1955). 1, Russian. English translation In Soviet Physics JETP (New York), Vol. 1, No. 3, 446-51 (Nov., im). A substance Is defined as grey If Its "absorption capacity" (ratio of energy absorbed to radiation density) is the same for all frequencies, and If Its emissivIty Is proportional to that of a black body. The thermodynamical propi-rdes of such a sub- stance are discussed. It ia claimed that the results obtained are rele4ant to absorption and emission of light by complex molecules. L.Pincherle USSR/Optics Miyzical Optics, K-5 Abs Jour Referat Zhur - Fizika, No 3, -1957, 7748 Author Antonov - Romanovs-kiy. V.V., St nov, B.I., Fok, M.V., Khamlyulk, A.P. Inst Physics Institute, Academy of Sciences, USSR., Physico- Technical Institute of the Academy of Sciences of the Byelorussian. Title : Luminescence Yield From a System with Three Energy Levels Orig Pub : Dokl- AN SSSR, 1955, 105, No 1, 50-53 Abstract : The luminescence yield of a system with three energy levels is calculated and it permits resolving the fun- damental problem of whether the value of the ene 'rgy yield 9 can.exceedup-ity. Attempts found in the literature of a thermodynamic proof of the impossibility of i are not satisfactory. The energy yield of luminescence of a system with three levels (Pringsheim. mcdel) (Pring- sheim, P., Journal of Physics, 1949, lo, 495) is calcula- ted Card 1/2 - 43 - 15 / /91 -1-. -USS/ Physical Chemistry Molecule. Chemical bond B-4 Abs Jour : Referat Zhur Khimiya, No 4, 1957, 10846 Author : Stepanov B.I. Sanson A.X, Inst Academy of Sciences Belorussian SSR Title Dependence of Probability of Optical Transitions on Transition P@requency and Oscillation Energy Supply of Complex molecule Orig Pub Vestsi AN BSSR Ser. fiz. -tekhn. n., Izv. AN BSSR., Ser. fiz. -tekhn. n., 1956, Nol, 5-14 (Belorussian; Russian summary) Abstract On the basis of the model of unidimen ional, classical harmonic oscillator for a complex molecule of group 1, an expression has been derived for the probability of transitions from different oscillation levels of lower islec- tronic state to different oscillation levels of upper electronic state. In the derivation there is taken into account the change in coordinate and impulse in the process of electronic oscillation transition. Investilption of the derived formula in the case of invariable impase is effected by nu- merical integration. It is shown that probability of the transitions de- pend on transition frequency and also on oscillation energy supply of the initial level. Elucidated are the reasons of slight dependence of absorp- Card 1/2 e USSR Physical Chemistry. Molecule. Chemical Bond. Abs Jour Author Inst. Title Orif; Pub Abstract Ref Zhur - Khimiya, No 8, 1957, 25747 B.I . Steipanov Academy of S,iences of White Russian SSR. i Speebroscopy in Science and Engineering 2 IV, AITISSR, Ser. fiz.-tokhn. n., 1956, No 2, 5-14 Report to the yearly meeting of the Academy of Sqiences of VJFhite Russian SSR in 1956. B-4 Card 1A - 8 - RUMANIA/Optics - Luminescence Abs Jour Ref Zhur - Fizika, No 2, 1958, No 4524 Author Stepanovp Bol. Inst Not Given Title The Vavilov Lav Orig Pub An. Rom.-Sov. Ser. mat.-fiz., 1956, 10, No 4, 47-74 Abstract See Referat, Zhur nzika, 1957, No 11, 29099 K-6 Card 1/1 /'V V USSR Physical Chemistry. Molecule. Chemical Bond. B-4 Abs Jour Ref Zhur - Khimiya, No 8, 1957, 25773 Author B.I. Stepanov. Inst : Academy of Sciences of USSR Title : Contour of Absorption and Radiation Bands of Complexhiole- cules. Orig Pub Izv. AN SSSR, ser. fiz., 1956, 20, No 4, 456-463 Abstract The computation of the shape of absorption and light radia- tion bands of complex molecules, and -the alteration of these bands with the temperature and parameters characterizing the molecule kodel is carried out; the model of the monomeric classical harmonic vibrator -was selected as such molecule mo- del, and it was assumed that the model preserved the quantum properties completely from the point of view of electron ener- gy. Taking into consideration the change of nucleus co-or- dinates at the transition of the molecule from one state into Card 1/2 - 25 - dr WSR / Optics K Abs Jour: Referat Zhur-Fizika, 1957, 1957; No 4, 10404 Author R_T_ Inst Not Given Title Quantum Yield of Luminescence of Complex Molecules. Orig Pub: Izv. AN SSSR, ser. fiz., 1956, 2o, No 4. 493-501 Abstract: Paper delivered at the Fourth Conference on Luminescence. The survey touches on the following problems. account. of the background of thermal radiation in the calculation of the quan- tum yields of luminescence and emission, effective vibrational energy on the luminescence of complicated molecules in solutions and vapors, quenching of luminescence of the first and second kind, possibility of realizing a quantum yield greater than unity, existence of negative lumin scence, and reduction in quantum yield of luminescence in the anti-Stokes excitation. A new ex- pression is obtained for the dependence of the quantum yield on Cara 1/2 USSR / Optics Abs Jour: Referat Zhur-Fizika, 1957, No 4, 10404 K the frequency of the exciting light at excitation frequency less than electron frequency. As a result of calculations, based on the step by step account of the exciting absorption, it is established that the dependence of the quantum yield on the excitation frequency is the same as the dependence of the coefficient of absorption on the absorption frequency. Card - 2/2 j USSR/ Physics Luminescence phenomenon Card 1/2 Pub. 118 1/7 Authors i Stepanov, B. I. Title i Vavilov's law FeriddiCa, I Usp. Fiz. nauk, 58/1, 3-36, Jan 1956 Abstraot I In connection with the 5-th anniversary of the death of Mr. Vavilov, physicist and academician, his work on the luminescence phenomenon is discussed. His definition of luminescence is considered as the most correct. His law dealing with the quantum output of luminescence is also considered as correct (experimentally proved) and important in the theory of.lumineseence, This law is stated as follows: the quantum output of luminescence (fluorescence) does not depend on the frequency of the exciting light, while they (the frequencies of exciting light or radiation) are within the range of Stocke's spectral band, but it Institution ...... Submitted ...... Card 2/2 Pub. 118 - 1/7 Periodical usn. nz. nauk, 58/1, 3-36, Jan 1956 Abstract (the quantum output) falls rapidly as soon as the frequencies of exciting light or radiation reach the maximum luminescence band. However, there is an indication that the mentioned law can be applied only to condensed systems. Fort.y@-seven references: I USA, I Swiss, 3 Germ., 42 USSR (1888- -As' diagrams; photograph. 1955). Grap /V d 16(1); 24(4p5) MASE I BW MIMMMON SOV/1899 Akademiya nauk Relorusekoy SM. Institat fiziki I =tsgm%jX Trady., vyp. 2. (Transactions of the Ustitute of Physics and WatbmtIcs Belorussian SSSR Academy of SciencesNr 2) Ninskj, 1957. 283 p. irratp& sUp inserted. 750 copies printed. Ed.: 3. 1. Stepanovp Academician, ESSR Academy of Sciences; Ed. of Publishing House: L. Narike; Tech. Ed.: 1. Volokhanovich. PURPOSE- This book is Intended for matbamaticlansp physicistep and graftate students In mathematics and p"ies. COVERAW: This book contains a series of articles on recent contrIbutims by menbers of the Institat fizikii Mtematiki (Institate of "Los wA Mathematics) of the Academy of Sciences, BW, in the fields of radiation., lmdussaencep olytics, and spectroscopy and on the applications to physics of analysis, tensor analysis, linear groupop theory of adjustments, and differential equations. The Card 1/5 Trans0tions of the X:nxtit&%e'(Con+'.) SOV/1899 first article conUins a brief account of the vork of the Institute, including names of scientists and mathematicians connected vith ity facilities, scien- tific accoul4isbmentsIand fields of interest. TAFU OF C011TENS: The Institute of Physics and Mathemtias at the T1w of the 40th AnnivOrwarY of the Great,October Sddiallst Revolution 1 Gurinovich, G. P.,, and A. N. Sevchenko,, Determination of the Nature of an Elementary E*it+.er for the Case When the Directions of Absorption and Radiation Oscillators Do Not Coincide 3, Stepanov, B. I. and Yu. I. ChekAlinskaya,, Lmdneocence of Scattering Media 1. 19 Chekslinskays., Yu. 1. Uninescence of Scattering Media 11 38 Apanasevich, P. A. Transformation of Light, by an Atom 55 Card 2/5 Transactions of the Institute (Cont.) SOV/1899 ..Godnev, T.N., R. V. Yefremova, and L. A. Krawtsov. on the Spectral Pro- perties of Chlorophyll and Chlorophyll1de Ctaiplexes With Protein and Certain Other Compounds 85 Krir.okiy, A. N. Spectroscopic Interaction of Sulp1mr and Tron in Sources of Light for Spectral Analyvis 93 Yankovskiy.. A. A. On the Role of Electric Parameters of a Discharge Contour With an Excitation of the Spectrum by a Law-voltage IxWuse Discharge no Prima., A. M. Calculating the Oscillating Spectra of Silicates 124 Vo1od'ko, L. V. Electronic Spectra of Solutions of Uranium Salts 174 Stepanov, P.I., and A. P. Prisbivalko. On Us Theory of Dispersion Light Filters 189 Prishivalko,, A. P. The Filtration of Light by Layers of Absorbent DuAt 206 Card 3/5 Transactions of the Institute (Cout.) SOV/1899 Borisevich., N. A.., U.S. Xhvashehevskaya.9and I.F. I&ptsevich. Digarsion Filters for the Infrared Region of the Spectrum 214 Bokutv., B. V. Surface Energy of a System in the Neigbborhood of an Ideal Wall 224 Fedorov, F. I. On Certain Dladic Representations for Three-dimensional Tensors 230 Yerugin, N. P. Analytic Theory of Nonlinear Systems of Ordinary Differential Equations 235 Krylov, V. I. On the Proof of the Impossibility of Constructing a QuiLdrature Formula With Equal Coefficients and Number of Nodes Greater Than Nine 2,110 Suprunenko, D. A. Two Theorems on Reducible Nilpotent Linear Groups 255 Pbpov, V. V. (Deceased) Determination of the Weight of a Function of Adjusted Values Using Polygonal Adjustment Method 26o card 4/5 AUTHORS: Kazachenko, L.P. and Stepanov, B. 1. 51-3-9/24 TITLE: Mirror symmetry and the shape of absorption and luminescent bands of complex molecules. (Zerkallnaya simmetriya i konturl@olos pogloshcheniya i ispuskaniya slozhnykh moleku . PERIODICAL 10ptika i Spektroskop-lya". (Optics and Spectroscopy), 19 7, Vol.2, No-3, 339-349 (U.S.S.R.) pp. ABSTRACT: V. L. Levshin (Zh. Fiz. Khimii, Vol.2, p.641, 1931) discovered mirror symmetry between the absorption and luminescence bands of complex molecules. Study of this symmetry yields information on the vibrational excited and ground levels as well as on the electronic transitions. D. I. Blokhintsev (Zh. EkBper. Teor. Fiz., Vol.9, p.459,1939) showed that this symmetry can be studied correctly only when X/Va (X = the absorption coef f icient , -4 = -the absorption freqaency),.and Wtl-4i (W = the luminescgnt radiated power, Jt = the luminescence Trequency) are plotted as ordinates against frequency. The authors apply Blokhintsev's analysis to a series of phthalimide vapours and solutions. They show, Card 1/1? inter alia, that B.S. Ne orent et al. (Dokledy Akad. Nauk SSSR, Vol.92, p.927, 19M and V.P. Klochkov (Zhurn. Fiz. Khimii, Vol-39, p.1432, 1955) are wrong in assigning mirror Mirror symmetry and the shape of absorption and luminescent bands of complex molecules. (Cont.) 51-3-9/24 symmetry on the frequency,scale to the absorption and luminescent bands of 3-aminophthalimide and 3-methylamino- phthalimide which do not possess such symmetry. These and other errors of Neporent and Klochkov are due to the use of 4 X and Wt /-Jj as ordinates instead of %/Ia and W04 as suggested by Blokhintsev. The authors show that the division of molecules into two groups(as suggested by various workers), one with mirror symmetry on the frequency scale and the other with mirror symmetry on the wavelength scale, is quite unnecessary and unsupported by experimental data. The authors also derive relationships between the absorption and luminescent spectra in a form of a ratio WLIX , and between the luminescent and thermal radiated povMrs. These relationships are valid for condensed systems only. Card 2/2 There are 5 figures, 2 tables and 14 references, 13 of which are Slavic). 3b-B1,,-1ITTED: June 4, 1956. ASSOCIATION: Byelorussian State Unive-sity. (Belorusskiy Gos. Universitet). AVAILABLE: 51-1-4/18 AUTHOR: Stepanov, B. 1. TITLE: Effect of the Thermal Radiation Background on Spectroscopic Processes. (Vliyaniye fona, teplovogo izlucheni-ya na spektroakopichoskiye protseasy.) PERIODICAL: Optlka i Spektroskoplya, 1957, Vol.III, Nr.1, pp.1-8. (USSR) ABSTRACT: The usual apparatus for the study of absorption and luminescence (Fig.1) consists of a source of light a, sample holder b and receivers of radiation v and g. If the source temperature T. is higher than @the sample temperature Tbj, then the energy in the positive direction (from the source to the sample) Wab exceeds the energy flowing in the opposite direction. Wba' The difference W = Wab - Wba is called the incident radiation power. It is often assumed that Wba is negligible: this is not always true. The Card 1/3 author discusses in general terms the effect of thermal 51-1-1/18 Effect of the Thermal Radiation Background on Spectroscopic Processes, radiation from the source, the receiver and the sample holder on results of spectrophotometric measurements. The author deals In detail with the particular case when the source temperature Ta is smaller than the sample temperature Tb, i.e. the case of "negative excitation".' Negative luminescence, negative Rayleigh scattering and negative Ranan scattering are discussed. The essential difference between positive and negat:Lvo excitations, 114a in the fact that the positive radiationoinay be arbitraqvily intense. The negative radiation has a maximum value equal to Uoc/4 r, where Uo = equilibrium radiation density. Negative excitation Is sometimes more useful than a positive one. This is so when, e.g., the sample Is at a temperature of 60000GY since there are no sources of light powerful enough to achieve positive excitation. From studies using negative excitation one can obtain the usual,results: distribution of bands or lines in a spectrum, relative intensities, polarization, excited- Card 2/3 state 11fetime, quantum yields, ate. There are AUTHOR.' Stepanov, B. 1. 48-11-1/13 TITLE: Introduction (Vstupitellnoye slovo). PERIODICAL: Izvestiya AN SSSR Seriya Fizicheskaya, 1957, Vol. 21, Nr 11, Pp. 1471-1,472 (USSR). ABSTRACT; This issue is devoted to the l7t conference on theispectroscopy of light-dispersing media which was convened in Yoscowton March 29-3o, 1956, on the initiative of the Commission for Spectroscopy of AN USSR. This conference was attended by representatives of a series of scientific organisations from Moscow., Minsk, and Lenin- grad. The introduction gives a summarizing survey on the problems of the spectroscopy of dispersing media, which is a newly disco- vered line of spectroscopy. In most cases they just collect and systematize the experimental material. for the time being. One of the fundamental problems of this branchof spectroscopy is the determination of the spectral relations and of the numerical values of absorption-coefficients and indice of refraction of dispersed s-ubstances. In dispersed media the variation of the spectrum can be correlated with a change of the rules of light-diffuaion. Both the reflection- and transparency spectra of the dispersed objects. Card 1/2 depend not or-ly on the optic constants of the element, but also on Introduction. AVAILABLE: 48-1-1-1/1-3 the size of the light-dispersing particles, of the index of refraca tion of the connecting medium, the relative content of absorbed substance and connecting medium, as well as of the thickness of the layer. By-varying one of these parameters, or all of them to= gether, the spectra and the absolute values of the coefficients of reflection and transparency can be substantially varied and the dye of the substance can be changed, Many important problems ar, -se with the study of the luminescence of the powdery materia1z.. No'.. only the re-absorption, but also the secundary luminescence should be taken into account in this cases The elaboration of these pro- blems is only in the beginning. The phenomena occuring during the work with dispersion-light-filters are also within the field of this branch of spectroscopy. Their theory is almost not elaborated at present. Library of Congress. Card 2/2 51--& PA A C AUTHOR: Stepanov, B. 1. 48-11-3/13 TITLE: The Fundamental Problems of the Spectroscopy of Dispersing Media (Osnovnyye problemy spektroskopi.-i rasseivayushchikh sred). PERIODICAL: Izvestiya AN SSSR Seriya Fizicheskaya, 1957, Vol. 21, Nr 11, PP. 1485-1-493 (USSR). ABSTRACT: First are shown the fundamental tasks of the spectroscopy of dis= persing objects. 1) Determination of the inner properties of the substance according to the transparency- and reflection spectra, J. e. determination of the coefficient of absorption of the same substance in none dispersed state. The refraction-index must be determined parallel with this. The true spectrum. of luminescence must be determined with luminescating objects. 2) Calculation of the coefficients of both transparency and reflection, as well as of the intensity of luminescence of the whole layer for various wave lengths if the coefficients of absorption and the index of refraction of the element and of the connecting medium, the degree of dispersion, the thickness of the layer and the fundamental characteristics of luminescence are known. 3) Determination of the optic properties of the layer of the dispersed substance of Card 1/2 optional. thickness. - Subsequently a survey is given of the