SCIENTIFIC ABSTRACT STEPANOV, A.V. - STEPANOV, B.A.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001653130007-5
Release Decision:
RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
August 26, 2000
Sequence Number:
7
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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CIA-RDP86-00513R001653130007-5.pdf | 2.43 MB |
Body:
ACC NR. AP6o23qjo
purities producing n- and p-type conductivity, p-n junctions of predetermined config-
uration can be obtained during the growth process. Orig. ar-t. has: I figure and I
formula.
SUB CODEs 20/ SUBM DATE-3 140ct65/ ORIG REFt 004/ OTH REFs 001
CCIII!Irt ct'Istals 'rom a Melt
Card 2/2
j
ACC NRi
Ap6o26704 SOURCE CODE U/08 f[66166816W[Mi12462
AUTHORS Tsivinskiyg S. V.; Koptevj Yu. I.; Stepanovp Ap Vo
OIRG: Physicotechnical Institute im. A. F. Ioffej_AN SSSR9 laningrad (Fiziko-tekhni-
cheskiy institut AN SSSR)
TITIZ: Growing of germanium tubes
S(XJRCE: Fizika tverdogo tela, V. 8, no. 8, 1966, 2460-2461
TOPIC TAGS; crystal growingp germanium single crystal
ABSTRAM The method used for growing thin-walled germanium tubes Is a modification
of one describ d lier b /Stepanov7Budushcheye metalloobrabotki. lanizdat,
a 12 nil AI1@.. -
1963). The seeK@(tungsten oi Abned into a tube and wetted by germanium) is im-
Morsed ir. molten germanlum, then gradually pulled out of it (at a pulling rate of 60
nm/hr). Thanks to surface tension forces, a thin-walled tube builds up behind the
seed. The temperature conditions are chosen such that the crystallization front is
located slightly (1 mm) above the upper end of the rod. Thus, during V(e pulling,
crystallization begins under conditions where thin-walled tubes about 11 an in diameti
can be grown onto the seed. In the cross section, one single-crystal ain frequent:
predominates over other single-crystal grains by displacing them during growth. In
good specimens, the thickness of the tubes was 0.20*6.3 mm. The length k90-100 mm)
was determined by the performance of the pulling mechanism. Orig. art. hass 2 figuri
0M
LCard-1/1
L 01814-67 EW'r(ni)/[-,W['( iL,11,(C)
At _R P6035633 WURCE CODE: Uit/0089/66/020/005/0429/0430
AUTHOR: Alekseyev, A. G.; Darkovskly, V. N-1- 11asarpin, Yu. G.; Vasillyev, V. No;
Litunovskiy, R. N.; Minypyev, 0. A.;_1.11_1@01,iyev, V. N.; S
ORGs none
TITIZi 68.5 cm sector-focused cyclotron jq
SOURCEs Atomnayn energlya, v. 20, no. 5, 1066, 429-430
TOPIC TAGS: cyclotron, deuteron, proton
ABSTRACT: A sector-focusing cyclotron that can dpliver protons of 7.5 to 100
14v and deuterons of 0.5'to 4.0 ',-.ev Is desc'ribcd, Ille acceleration of molecular
Hlions underscores the essential role of the procehs of proton'dissociation.
A
Unaer certain conditionsintrin5ic to the sector-focusing cyclotron where the ions
achieve several hundred revolutions, this process can Interfere with obtaining the
ln@ensity of the ign b9am ai finit enargles, if the'vacuum In the accelerator chamber
is ess than 1. 10- mni Ng cm- . OrIg. art. has: 3 f Igures. (NA/
S4 CODEs 20 SUBM DATEs 04 Sep 65 ORIG REF: 002 OTH REFs 001
card f v Ui)Ci 62t*384.011
ACC NRi AR60291193 SOURCE CODE: UR/0137/66/000/00G./DO32/DO32
ALT HOR: Stepanov, A. V.
!TITLE: Production of articles directly from the melt
;SOURCE: Ref. zh. Metallurgiya, Abs. 6D225
IREF SOURCE: Uch. zap. Leningr. gos. ped. in-ta im. A. 1. Gertsena, no. 265, 1965* 3-11
FOPIC TAGS: nonferrous metal, metallurgic process
I
;TRA1NSLATION: The substance of a method for producing art1cles directly from the melt
las proposed by the LSI@Ei@.@]@edagStgjSjal Institute in Gertsen and students of the auth-
or, is presented. This technique was tested under laboratory conditions on materials
,with different thermoi)hysical and mechanical propertieslyn the -solid and liquid state,
h'c*l-r -@'IYC@7S. -hers.
on Al, Cu and t i cast iron and ot. Acco Sing to the proposed technique
it is possible to organize the production of Al and Al alloy parts in the same distinct,
,steps. This technique necessitates extensive changes in the,5ptal processing plant.
iThus, for example, it is advisable to produce parts from Allan'd its alloys at a plant
Iwhich produces Al. It was noted that the above method for producing parts is still in
@the development stage. N. Yudina.
CODE: 11,13
UDC: 621.774.24:669.71
1
L o8342-67 EWT(m)/MVP(t)/ET1/EWP(k) IJP(c) JDIHWIJII
ACC NR' ARG033102 SOURCE CODE: UR/0137166/000/007/GO18/GO18
AUTHOR: Golldfarb, V. M.; Donskoy, A. V.; Stepanov, A. V.
TITLE: Producing thin-walled pipes of rectangular cross section directly from
the melt
SOURCE: Ref. zh. Metallurgiya, Abs. 7GI38
REF SOURCE: Uch. zap. Lenin r. goo. pad. in-ta im. A. 1. Gerteena, v. 265,
1965, 42-49
TOPIC TAGS: pipe, molten metal, aluminum, alloy microstructure, rectangular
pip e
ABSTRACT: Th xperimental results are described for producin@,q. 45-gage
thin-walled pipesEA@of rectangular cross section 32 x 52 mm from Al-@hd Al-Mg
(0. 8-16%) alloys directly from t d melt. The dependence of the pipe's wall
thickness on the mocil of drawing different profile and insert dimensions, and the
alloy tructu4 and mechanical properties has been studied in finished pipes.
_Lr @icros@@
Orig. art. has: 6 figures and 1 table. Bibliography of 6 titles. [Translation of
abstract]
SUB F.ODE: 11, 13/
UDC: 669.71.04
1 not
ACC
AR6034748 SOURCE CODE: UR/0276/66/000/007/GO45/GO45
AUT11OR: Golldfarb, V. M.; Golltsman, B. M,; Stepanov, A. V.
TITLE: Uniform cooling of thin-walled articles drawn from the melt
SOURCE': Ref. zh. Teldinologiya m ashinos troy enfya, Abs. 7G275
REF SOURCE,: Uch. zap. Leningr. gos. ped. in-ta im. A. L Gertsena, v. 265,
1965, 90-104
TOPIC TAGS: metallurgy, metal, metal cooling, cooling
ABSTRACT: A brief analysis is given of five methods of cooling parts drawn from
the melt: cooling in a slip mold, cooling in a movable-wall mold, convective coolin,
in liquid, cooling with a water spray or a water-air mixture, and blasting with air.
Computations are presented for estimating the heat regime in cooling drawn ingots.
The original article has 2 figures, 4 tables, and 13 bibliographic references.
[Translation of abstract] [SP)
SUB CODE: 11/
1/1 UDC: 621. 74.047. 2.06
@L ()9389-�1- LINP (k) /E'dr (M)/EWP(t) /L7TI IJP(c) JD/11W
=_9T-__A R 6 0 3 3 10 7 SOURCE CODE: UR/0137/66/000/007/DO43,/D*043
AUTHOR: Bogqjy!@bov, G. Goltdfarb. V. M.-, Donshoy, A. V#; Kqsty ov A. S.; J
Stepanov, A. V.
TITLE: Producing thin-walled flattened sheet pipe (radiator strip) directly from
the melt
SOURCE: Ref. zh. Metallurgiya, Abs. 7D316
REP SOURCE: Uch. zap. Leningr. gos. ped. in-ta im. A. 1. Gertsena, no.
1965, 75-89
N,
TOPIC TAGS: pipe, metal drawing, radiator pipe, fl
attened pipe
ABSTRACT: Metal drawing for radiator strip has been carried out on a laboratory
unit. The strip was drawn from A Mts alloy. The type of equipment and some
technological problems were de,@_el_opedj4d solved for producing 4-, 6- and 10-
channel strip with a 0. 3-1.'0-mm gage. The production technology for a 13
channel strip is described. An experimental batch (r---1300 m) of radiator strip for
two radiators of a tractor radiat6r was produced and analyzed. Semicontinuous
and continuous units were designed for producing thin-walled flattened sheet pipes
Card 1/2 UDC: 6 21. 774. 21
L 09389-67
Card 2/2
ACC NR, AP6023643 SOURCE CODE: UR/0149/66/000/002/0154/0161
AUTHOR: GoIldfarb, V. M.; Golltsman, B. M.; Donskoy, A. V.; Stepanovo A., V.
__7
ORG: Chair of General Physics, Leningrad State- Pedagogical Institute (Leningradekly
gosudarstvennyy pedagogicheskiy institut. Kafedra obshchey fiziki)
TITLE: Thermal conditions for producing thin-walled products from a malt
SOURCE: IVUZ. Tsvetnaya metallurgiyat no. 2, 1966. 154-161
TOPIC TAGS: metal casting, convective heat transfer, thermal analysis, temperature
distribution, optimization /<
/ABSTRACT: Thermal conditions and process parameters for the continuous casting of
thin-walled products from a melt are given. rour cooling methods are described: 1)
drawing from a melt with the crystal front sliding across water-cooled metal shoes;
:,J' convective cooling in a liquid; 3) convective cooling in a liquid without a buffer
zone; 4) by air-blast or water spraying. For method (1) so much friction results fro@
the ingot-wall interface that wall thicknesses must be maintained above 5 mm. Heat
conduction coefficients varied from 1000 kcal/m2-deg-hr for (1) to 2000-10,000 kcal/
/M2-deg-hr for (4). The temperature was--given as a function. of X--the Vertioal 00OZ-.
dinate, by the equation T= Texp .CPV
UDC: 669.017: 621.77
Card 1/2
C.rd 2/2
1 ACC NRs AP6034o97 SOURCE CODE-. uWoc)89/66/021/W4/0292/029
AUTHOR: Stepanov, A. V.
IORG: none
I
iTITLE: Stationary diffusion of thermal neutrons in media with random inhomogeneities
SOURCE: Atomnaya energiya, Y. 21, no. 4, l966, 292
TOPIC TAGS: thermal neutron, neutron diffusion, neutron absorption, neutron diatribu-
tion, relaxation process
ABSTRACT: 7his is a surmry of paper No. 105/3727, submitted to the editor and filed
but not published in full. The article deals with diffusion of thermal neutrons from
a stationary source in a medium in which the degree of absorption of neutrons varies
from point to point in accordance with a randoirk law., with a constant diffusion coeffi-
cient. An approxitrAtion using -the second moments of the distribution of the neutrons
i:@ employed. Cases of isotropic (on -the average) and strongly anisotropic media are
considered. An expression is obtained for the rela)-.ation constant of the neutron den-
sity in the medium, in which the homogeneity is violated by meana of localized inclu-
sions.
SUB CODE: 18/ sm DA-,E.. :L2YAV661 m REF: ool
UDC: 539-125.52
-;kCc NRT ,Mn0_34415 Mono"gxaph-
Stepanov, Aleksandr Vasillirevich Doe'r ep - 07, lflje0j@,? // e 4 1 .5 c ,- ove o,@s
'f@w Pt- ploy.,;
("P OF r- '@ 54 - - A I _) I :
Producing articles directly from melts @Polucheniye izdel-iy neposredstvenno iz
rasplava) Mdscoir, Izd-vo "Manlye", 1966. 48 p. illus. 46,700 copies printed.
Series note: Novoye v zhizni,,-nauke, tekhnike. Seriya IV: Tekhnika, 1966, no. 17
TOPIC TAGS: MQ_t0,j V%P-kt tvAe@axk%w @0_ 1@vocje'7-5 , VAQA01 @Ormk%
PURPOSE AND COVERAGE: This book is intended for engineers-metallurgists, engi-
neering personnel of metallurgical plants and for students specializing in metal-
lurgical processes. The book describes the process of obtaining articles dlrectl@
from the melt, stresses Its advantagesand outlines new machinery introduced to
carry out this process. Variously shaped articles produced by applying the de-
scribed method an Illustrated and the possibility of controlling the process is
shown.
TABLE OF CONTENTS:
Introduction -- 3
co,d 1/2 zi 0e 'V101OV06
ACC NP,, A,,.,, 6 o 5 14 15
Why is it desirable to produce articles directly from'the melt 6
Technological principles of shape forming -- 7
Methods of producing articles directly from the melt -- 12
Size and shape of articles produced from the melt -- 20
Materials from which articles can be produced 25
Possibility of controlling the process -- 25'
Process rapi.dity -- 26
Proces6 yiela -- 31
Properties of articles produced from the melt 36
Composition of material used to produce articles from the melt 39
New machinery for metal treatment -- 40
New engineering possibilities -- 45
Conclusion 48
References 48
SW COLT,-r,.- 1.3)11/ S I jur - i D -4'-, @ E -. 181wg,56/. ORIG REY: 003/
ACC NR: ARG035101 SOURCE CODE: UR/0137/66/000/008/GO16/CO16
AUTHOR: Golldfarb, V. M.; Golltsman, B. M.; Donskoy, A. V.;.Stepanov, A. V.
TIT LE: Thermal conditions for drawing parts from the melt with variuos methods
of cooling
SOURCE: Ref. zh. Metallurgiya, Abs. 8G160
REF SOURCE: Uch. zap. Leningr. gos. ped. in-ta im. A. L Gertsena, no. 265,
1965, 118-143
TOPIC TAGS: metal drawing, cooling 171047-le'.-U /77rr/g-,
ABSTRACT: Test data, diagrams and equations are presented for various condi-
tions of the process of drawing parts from molten aluminum (strips, pipes, and
intricate shapes). The prospects are worked out for various methods of cooling
while drawing. Orig. art. has: 18 figures and 5 tables. The bibliography contains.
22 titles. A. Tseydler. (Translation of abstract) [NT]
SUB CODE: 13
C.,d 1 / 1 UDC: 669.71.04
SHVEDOV, V.P.; STEPANOV, A.V.
Separation of rare earth elements by continuous electrophoresis.
Part 1: Separation by means of citric acid. Radiokhimiia 1 no.l:
112-115 '59. (MIRA 12:4)
(Rare earth metals--Analysis) (Blectrophoresis)
(Citric acid)
SMDOV, V.P.; STEPANOV, A.V,..-,
Electrical migration Tiethod for the deternination of the instabi-
lity constants of complex compounds of eln-ionto present in micro-
concentrations. Part 1: Determination of the instability constant
of complex compounds of sone lanthanides with the anion of ethylene-
diaminotstraacetic acid. Radiokbimila I no.2:162-167 '59.
(Rare earth compounds) (Acetic acid) (MIRk 12:7)
STEPANOV, A.V.; SHVEDOV, V.P.
Eloctromigration method of determining the instability con-
stanta of complex compounds of infinitely diluted elements.
Part 2: Determination of constants for complex formution be-
tween some lanthanides and citric acid. Radiokbimiia I
no.6:668-673 '59. (14IR& 13:4)
(Rare earth compounds) (Citric acid)
STEPANOV, A. V., Gand Chem Sci - (diss) "Study of the separation
of rare-earth elements by electrophoresis," Leningrad., 1960., 18 pp, 200 cop.
(Leningrad State U im Zhdanov) (KL, "-60, 128)
S/08 61/000/022/003/076
B1 02YB1 08
AUTHORS: Shvedov, V. P., Petrzhak, K. A., Sedletskiy, R. V.,
Stepanov,_ A. V___
TITLE: Extraction of the rare-earth group from U 238 photofission
fragments by continuous electrophoresis
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 22, 1961, 36, abstract
22B248 (Tr. Taahkentsk. konferentsii po mirn. ispollzovaniyu
atomn. energii. Tashkent, AN UzSSR, v. 2, 1960, 325-326)
TEXT: Electrophoretic separation of rare-earth fission products is
preceded by the extraction of their sum. Recipe: dissolve 1 g of
irradiated U3 08in 2 ml of concentrated HNO 30 add Pb(No 3)2 (20 mg with
respect to Pb) and Ce(NO 3)3 (15 mg with respect to Ce) as carriers to
15 ml HNO3 (spec. wt. 1-5), and twice precipitate Pb(NO 3)2 to remove the
Ba and Sr isotopes. Isolate the precipitates, boil down the solution to
2 ml, dilute with water to 15 ml and precipitate CeF after adding Zr
3 (N%
C a r d 1 / 3 al@_"
5/08Y61/000/022/003/076
Extraction of the rare-earth ... B102 B1 08
carrier (20 mg with respect to Zr) and a mixture of HF and NH 4F. The
precipitates are rinsed with water and dissolved in a mixture of H 3BO3 and
HNO 3* Then Ce 3+ is oxidized to Ce 4+ by bromate, 3 mg of Fe 3+ are
introduced into the solution, and Ce(IO 3)4 is precipitated by means of
15-17 ml of an 0.35N HIO3 solution. The solution containing Fe 3+' K,
103- BrO- and rare-earth elements (REE) is heated, and Fe(OH) is
3 7 39 3
precipitated by a solution of concentrated NH4OH. The Fe(OH) 3 precipitates
with the REE are rinsed with hot water and dissolved in 4 ml of
concentrated HC1. After cooling the obtained solution, Fe3+ is removed
by fourfold extraction with amyl acetate. The aqueous phase is evaporate4
the dry remainder is calcined and treated with HNO 3and 30@6 H202* After
having removed the acids have been extracted by heating, dissolve the
remainder in 0-7 ml of 0.01@6 Trilon B solution, Ce3+ (0.001 mg/ml) carrier
introduced, and subject the obtained solution to electrophoresis in an
0-01@6 Trilon B solution (pH 1.94) as an electrolytec Separation is to
take place at a potential gradient of A/10 v/cm. The flow rate into the
Card 2/3
S/08 61/000/022/003/076
Extraction of the rare-earth ... B102YB108
cell of the mixture to be separated is 1.5 ml1hr. By this method
La 141, 140, Pr145, Nd149, 147, PM140, 150 , and Y91, 93 have been
extracted. The separation time of the total of REE was @j2.5 hr, the
time of electrophoresis was 2 hr 26 min. EAbstracter's note: Complete
translation.j
Card 3/3
10 &1 1 12 2,19 111
s/i &1/-")ct/O02,/O01/ 010/022
A@0 9 7/A 129
AUTHORS: Shvedov, V.P.j Stepanov, A.V.
TITLE: Separation of rare earth elerrients by the rre@hcd of ccn-Linkicus e-,e---
trophoresis. II. Separation by means of ei~l:--~'leneJiaminetett,aacelic
acid
PERIODICAL; Radlokhimiya, v. 2, nc,. 1, 1960, 65 - 67
TEXT; Using trilon E (Na. salt c--'* ethy-Lered-.l.a-,riiii-t~r--traac-eti,2 aciri) az com-
plex-forming agent, a separation rm-@I@cd fov rare, earttLoz% (La, Cs, Fm,, E@.i and Y) by
continuous electrophoresis was deve-'--@ced. 1@hli i-s a of previcus @1-1:
vestigatlons concerning -lanthanids separat.,or, by rijpani@ cf ----mp1ex-fcrmi1ng ager...,
The principle of separat'lon la base-! @@n t)z-z diff-rc-n@, atab!-@Ilty of rare earth,
complexes. In the p-nevIous wcrk citri@ acid waz used as c-@mplex-fcyrming agent.
However, the instability constants cf t@he 41 zit-rate n@@mplexe-i cf rare
earths are less different than Uhcae -:@f EDYA cc:.'.np1i:-xeS (sec, Table). Tfrus
trilon B is more efficient in separation by The present experi-
ments were carried cut In an apparatuz@ fc-r c,@n'Anuous describe-d
In a previous paper [Ref. 1; Radickhamiya, 1, 1, 112 BesauSe of the low
Card 1/4
22459
Separation of rare earth elements by tht- mc-thod of.... A-05-1/AI29
solubility, 0.01% trilon B solutions were used. pH was mea-sured by a quinhydrone
electrode, the temperature was Rept at 200C, and the Ic-nic atreng-th of the solu-
tions at 0.017. Curve3 repregenting the i!,hifl, of equ.11-AbrIlum of t@.ie reversible
reaction H+ + [M enta]- = M3+ + Ii enta-3- (1) are given In Figure 1. The mobil-
ities of the Em ental- and M3+ jons of the Investigated rare earths are very sim-
ilar, therefore, the observed effect of zone separation of the rare earths can be
explained only by the difference in the instability constants oil each rare earth
element. Hence the norrela-.Ion between -,he zeparation -:-ffe_A and the In-stabil'X-ty V
constant is evident. The most efflcJerit separation is lJmIt-ed tc a narrl.w pH
range. From Figure 1 the optinrxii separation conditions for any ccmb-ination of the
cerium group of rare eart s can b determined. As a typical ex-;Lmple conditions
for the separation of NdlO .. FIrIt-I - EU152-154 with t@ie follcwirg specific data
are given; 0.01% trilon B, Ioni c strength 0.017, tempera,,,ure 200C, pil 1.8% po-
tential grad@ent 9.2 v/cm, &ate of supply into the @@ell 2.5 ml/h, separar'.1on time
86 min. Nd147 and Eu152-15 were not free of the narrier. Th-e authors remark
that with citric acid, even at oonsiderably higher p-Itential. gradients, this mIx-
ture of rare earths could not be separated. There are 2 figures, I "able fund
3 Soviet references.
SUBM=D: May 8, 1959
Card 2/4
22@159
S/186/60/002/001/010/022
Separation of rare earth elemerts by the method of.... A057/A---29
element KM Cit;- XM enta-
La ....... 3.6 10-10 1.0 10-18
Ce ....... 2.2 10-10 2.5 10-19
Nd ....... 2.6 10-10
PM ....... 1.8 '10-10 5-0 10-20
Eu ....... 1.6 10-10 1.6 10-20
Y ........ 8.0 10-21
Separation of rare earth elements by the method of....
-/0 -8
2 2159
S/186/66/002/001/010/022
A057/AJ.29
Figure 1: Change in the traveling rate of the zone
of La, Ce, Pm, Eu and Y in dependence on the acidi-
ty of 0.01% trilon B sblutiori. (D - to the @node;
c2)- to the cathode; (3 4 travelinF rate of the zone
in cm2/y sec 105.
Card 4/4
0 8 16 24 32
SHVEDOV, V.P.; STEPANOV, A.V.
More accurate values of the instability constants of certain complex
compounds formed between lanthanides and the ethylonediaminetetraacetato
ion. Radiokhimiia 2 no.6:261-262 160. (MIRA 14-4)
(Rare earth compounds)
(Acetic acid)
0 0
21,.089
s/i86/60Aa02/006/0I4/026
A0511AI29
AUTHROS: Shv-iov, V. P.; K. A., Sedjets@ciy, R. V., Stepa-nov,A.V.
for th,3 separa-
TITLE: TI-e appl'..:@s-.-fon
ti@Dr c-f '--la- @.vT@h grcou.p U2@8 fragm-mts
PERIODICAL.@ Rad.!oWtImlya, v. *2, nn. 6, 1960, 711 - 714
TEM Tnt% a7attors ll@re i-aveetAgated the possibility of applying the
elestrophoZe;rl.s rr@:-.h@.d aLrd subz-,-qu--7r.Lt, detarmination of the yieh-c
of +he rj236 tir-vlng Lissas in the region of ths rar@@ -earth
ele.mv@nnt-z. A 1!@ izl.v- of I;ti;: m.-:,@thol of tLe radiodklanLcal a-eparation
of a sum of rarl@; a, %arrier f-rom the prcdu,-@ts Of the photo-
separ-atic, . @ie -PZ -, - .. norasis 0 5.-7-Da
- n of J 1.:@ - P---! f r rat-
ing re-J"Loc-aemic-all. @ep3xazton of the sum of
the rare eartt Frc;-c waE @a4=:veloped for maazl@ring "he beta-acti-
vil i@zs of thc- .?vrpl- :f., a The Is as f llows.
About I gram. cf @-qde iz- dissolved in 2 m! of concen-
tratsd FRI703 t!-@l:,ng 2C @w Lf Pb2+ is added to the solution
8-irid 15 mg of Ce(III) in -@'- frlr of rlf.-at-@,,S. 5re is zloole4. Pb(NOI-,)2
Card 1/4
24089
s/i&6/6o/6o2/bo6/o14,/o26
The appli.3atto-n of A05I/A129
fSr*; B-a*) 1@ 1-y aza@_ig .15 rr-1 -of fuming HNO-, (93 %) while cooled on
ice fclr 15 5.rvI _mlylnza. Yrv@! Pb(NO,
,)2 silution is'diszo"ved in 1 irl of H20
and a ss_@ord pre.:@IpIna-Aon @:,f P:'w'0j_ @.z-performed. Th- ;@omblned solutions efin-
taining -ttct 3,.;.m of riz- -a?7rt.
_pAnt_z (Al, other srprzration fragmen-ts a-rid
Tjrj, )2 aLr_E@ L:, _tl. Afti@r- st'xing with wa.tsr up -to 15 mi, :20 Mg of
Zr-carrler are int-_. tn@' so__"u-,Aon and the plrr-@ipltation of CeF@3 JS
carried oull Wltt P_ -f qF--NHjF. A-ft=-r washing the flucrides with water
they ara d1ssolved in a 7:f. 1!.r M-e -7 6 Ini o f 2 gr of ro is added
4 3 3 a@'fII) @@C) CerT-V-7@'- 19 3
to the obtain,@d 3olunion. fo- a..Aj_lfying C@T 3 mg F';AIII -carrier is
added and preclpit56t.@_.,)n z, is ._--arried out with 15 - 17 ml of 0.35 r-
HI03, wtile !_='Iling ^,n -1.1-- and rr!)ring f3r 10 minutes. The sclution contalining
Fiz(III), the sum of the rare earth fragments, K+, IOS, BrO-:: Is heated and a care-
ful precipitation of Fe(ON )3 1- ceLrried out with conaenntra@ed NH40H. The Fe(OH )3
residue containing -;h5 rare eaz-th -zlemants is wash d t. lee with hot water and dis-
solved in 4 mi of concentrated HCI, after which FeMIT is removed with a four-
-fold extraction of the iron--alraorlde -nomplex in awjlacetate. The experimentally
Card 2/14)
s/i 86/I('j/'o'o'2/o ()6/o 14/0,26
The application of continuous ...... A051/A129
determined yield of the rare earth fragments was found to be 60 %. The time
required for the radiochemical separation of the rare earth fragments Athout
a carrier was 2.51 hours. The addition of Fe(III) before the precipitation of
Ce(103) reduced the losses. The possibility of using the extraction of iron
diethylcarbamate into ether from 0.1 n HC1 for removal of the iron in thelast
stages was investigated and vras found to be unsuitable, since products of the
thermal decomposition of diethy1dithiocarbamate remained behind. The electro-
phoretic separation of the rare earth sum fragments and the appa-];atus used for
the procedure shown in Figure 1 are described. The apparatus is being recon-
structed at present in order to decrease the time of the separation of the sum
of the rare earth fragments. The final yield of the rare earth fragments with-
out a carrier.in radiochemical and subsequent electrophoretic separation w K 4
determined by means of Y90 (T = 64.3 hours), pml47'(T= 2.65 years) and Eu15 15
(T - 16 years), and.was found to be about 45 - 50 %. There are 3 figures and
8 references: 7 Soviet-bloc and I non-Soviet-bloc. The reference to the English
language publication reads as follows: K. E. Ballou, Radiochemical Studies: The
Fission Product, 9, 3, 3o6, ig5i.
SUB14ITTED: july 6, is5g.
Card 3-/4
The application of continuous
Figure 1: Diagram of the apparatus for conducting
continuous electrophoresis. I - electrophoretJc
chamber, 2,- platinum electrodes, 3 semipbrme-
able membranes, 4 - electrolyte, 5 syringe, 6
device for pushing out the syringe, 7 - synchro-.
nous motors, 8 - RC-gencrator for feeding the
synchronous motor, 9 - pump of peristaltic action,
10 - polyethylene tubes, 11 - test tubes for
collecting the fractions.
Card 4/4
24089
s/186/6o/0o2/oo6/014/026
A051/AI29
mp@
5-5700 77741
SOV/75-15-1-3/29
AUTHORS: Shvedov, v. P., Ten Ten, Stepan'ov,._A,._.,.v.-_
TITLE: Separation of Some Isotopes by Focusing
Ion-Exchange
L.,
PERIODICAL: Zhurnal analiticheskoy khimli, 1960, V01 15,
Nr 1, pp 16-19 (USSR)
ABSTRACT: Application of focusing Ion-exchatige method to the
Separation of fission products, such as Sr 90-1 90;
Sr 90-Y @@"O_Ce 14 4; Ce 1421 _La 14o, without carrJers
as
,
well as of the mixture Ce-Pr, was studied. Description
of the method is given In a series of articles
published previously (Kolin, A., Proc. Nat. Acad.
Scl. USA, 41, 101, 1955, and others). A diagram
of the installation is shown in Fig. 3. A few drops
of the radioactive solution containing the isotopes
to be separated are placed cn a strip of filter
paper (with pencil lines 2-3 mm apart); the ends
Card 1/1"T of the strip are dipped into the electrode vessels
Separatlon ot' Some I@ofope.,-- by FOcusillg 77741
Ion -E.'-.-chanre SOV/75-15-1-3/29
Fig. 3. Scheme of
separating installations:
@a@ line, (b) rectifier,
c Lalectronic stabilizer,
d carbon electrode, (e)
ion separation zone,
f@ anodic solution (lici),
g cathodic solution
complex forming compound),
h) paper strip.
1
Card 211,11
Seoaration of Some Isotopes by Focusing 77741
Ion-Exchange SOV/75-1.5-1-3/29
and the centval part of the paper is immersed into
CC14 In the central container. Now the current
(26o-28o v (20-30 v/cm) is switched on. After
2-5 aiinute3 the concentvation gradient is established,
and aftev 2-3 minutes the elements are separated and
concentrated. Position of the zones Is found by
direct measurement of radioactivity of the paper
strip or by autoradiographic method (autoradiographs
are given). Identification of the elements is done
by measuring the maximum R -radiation or according
to the half life periods . Conditions of the experi
ments and the results are shown in Tables 1 and 2.
The following conclusions were made: MiXtUVeS
Sr 90 + Ygo ; Sr go + Y90 + Ce 1411 ; and Ce 144 + La 14o
can be separated by the above inethodusing
complexon III or citric acid, in 5 minutes. The
complete separation of a mixture of Ce and Pr
In concentrations up to 0.5 mg/ml cannot be
reached when complexon III is used. Better results
Card 3/7 are obtained by the use of a mixture of
SeDaration of Some Isotopes by Focusing, 77741
Ion-Exclcon.ire SOV/75-15-1-3/29
ASSOCIATION:
SUBMITTED:
complexon III and citric acid. There are 2
tables; 7 figures; and 9 references, 5 U.S.,
3 Swiss, 1 Soviet. The 5 U '*S. references are:
Sato, T. R., Diamond, H., Norris, W. P., J. Am.
Chem. Soc., 74, 6154 (1952); Sato, T. R., Norris.,
W. P., Strain, H. H., Analyt. Chem., 26, 267 (1954);
Sato, T. R., Norris, W. P., Strain, H. H., Analyt.
Chem., 27 521 (1955); Kolin, A., Proc. Nat. Acad.
Sci. USA 41, 101 (1955); Hoch, H, Barr, G. H.,
Science, 122, 243 (1955).
Lensovet Institute of Technology, Leningrad
(Leningradskiy tekhnologicheskiy institut imeni
Lensoveta)
July 29, 1958
Card 11/7
Separation of Some Isotopes by Focusing 77741
Ion-Exchange SOV/75-15-1-3/29
Table 1.
(1) Experiment nr; (2) cathodic
solution; (3) anodic solution
(HC1); (4) complex forming com-
(5) concentration of
pound; oL) PH (6)
.
complex forming compound, M; (6)
concentration, M; (7) complexon III; la (7) O,t it 0,5
1b (9) 0,01 it 0,5
(8) the same; (9) citric acid. 2a
2b O'l
1
0 It 0,5
ge ,
0, 1 0,1
0.02,
31
O'l 0,5
3b 0. 1 7 0,5.
30, 0, 1 4 0,5
4a O'l 7 05
4 b 0,03 12 0:5
Card 5/7
Sepavation of Some Isotopeo by Vocuoing
Ion-Exchange
Table 2.
(1) Cathodic solution; (2)
anodic solution;S@3) distance
between the zone mm);'@4@ com-
plex forming compound; 5 con-
centration of the complex form-
ing compound, mole; (6) concen-
tration of NaOff (mole); (7) con-
centration of HCI (mole); (8)
citric acid; (9) the same; (10)
complexon 111; (11) the same;
infocusable; (**) inseparable;
@*.k*) NI-iOH concentration constant.
7774 1
SOV/75-15.-I-3/29
(See Card 7/7)
Card 6/7
Separation of Some Isotopes by Focusinz
Jon-Exchange
Table
Card 7/(
al
1 )
77741,
SOV/75-15-1-3/29
O'ot 12 0.5 30 45
0.03 12 0,5 15 27
0.05 Q 0,5 8 20
0,1 12 0,5 6 to
0.5 12 0,5 0 4
0,10 0 - 0 5 - -
0. t 0. t - 0:5 is 25
0.1 0.3 - 0.5 to 20
0,1 0,5 - 0,5 to 15
0.1
0,8
-
0,5 6 10
o,t-O 1,0 - 0.5 0 0
0.1 12 0.1 8 30
0. t 12 0,3 8 16
0, t 12 0.5 6 10
0.1 9 o.03 12 4
0.04 9 0,0 ! 5 A
q.- o,o3 30 6
SHVEDOV, V.P. (Jeningrad); STEPANOV, A.V. (Leningrad)
Instrument for continuous electrophoresis. Zhur. fiz. khim. 35
no.1:217-219 Ja 161. @ (KrU 14:2)
(Electrophoresis)
@TEPAINOV, A.V.; SEVEROV, E.A.
Gagarinite, a new rare earth mineral. Dokl. AN SSSR JJ*l no-4:
954-957 D 161. (MIRA 14: 1.1)
1. Kazak:hskiy nauchno-issledovatel'skiy institut minerallnogo
syrIya i Institut mineralogiij, geokhimii i kristallokhimii
redkildi elementov AN SSSR. Predstavleno akademikom D.I.
Slicherbalcovym. (Rare earth fluorides)
(Minerals)
STEPANOV, A. V.; KLYAVIN, 0. V.
"14echanical.properties of crystalline bodies at liquid helium temTeratures."
paper submitted for Intl Conf on Fracture, Sendai, Japan, 13-16 Sep 65.
Leningrad Physico-Tech Inst.
STEPfMV, A. V.; 0. V.
"Mechanical ProDerties of crystalline bodies at liquid helium temperatures.
report submitted for Intl Conf on fracture, Sendai, Japan, 12-17 Sep 065.
Phys-Tech Inst, AS USSR
STEPANOV@ A.V.. SHVEDOV, V-P-.
Flectromigration method for studying hydrolysis of cerium (III)
in nitric acid solutions. Zhur.neorg.khim. 10 no.4:1000-1002
Ap 165. (MJRA l8t6)
SMEDOV, V,,!',,; :)'@E,PANCT, 4,V,; GORSKIY, N.I.
Study ot' rhe separation of' strontium -rom the prevhiling
smounts of calcium by tho rpathod of continuous
plectrophoreqis. RadiokIliuLtia 5 no,, r6i690-694 163.
411RA 17:7 )
-T
STEPPIIOV9 A. J.; STFPAJ',O'dA, A.A.
1-@Y dipgram of the pyroly,-:Is of etl:Ame and propane n-!, i tudkh,
.L 41IRA 17 9-11)
Wpl. i masEl 9 no.0'910-14- Je'64
I.. Iii,.@tltut jspolvzovanl7a gaza AN MaM.
S/775/62/002/000/001/01i
AUTHOR: Stepanov, A. V.
TITLE: Novel method for the making of parts (sheets, rods, tubes of various
profiles) directly from a melt.
SOURCE: Avtomatizatsiya protessov mashinostroyeniya. t. 2: Goryachaya
obrabotka metallov. Moscow, Izd-vo AN SSSR, 1962, 26-29.
TEXT: The paper provides details on a fundamentally novel method for the
making of parts out of metals, alloys, intermetallic compounds, semiconductors,
salts, organic compounds, plastics, etc., which the author and his associates had
initiated in 1938 and first disclosed in ZhTF, v. 229, 1959, 381 and 394; Vestnik
mashinostroyeniya, no. 11, 1959; and Akad. n. SSSR, Izv., Otd. tekhn. nauk. Metallur-
giya i toplivo, no. 5, 1959. The participation of V. N. Dyn'kov, A. L. Shakh-Bydagov,
B. M. Golltsman, and A. V. Donskoy, in various stages of this work is. acknowledged.
The novel principle of shaping material consists in establishing the required form,
or its basic element, in the liquid state by capillary, kinetic, or other effects.
"Freezing" of the shape thus established creates the desired solid object in speci-
fied conditions of crystallization. The shaping device consists of a "float" that is
set up on the horizontal surface of the molten metal. The float is a horizontal plate
-oninteracting material with a suitably shaped vertical slot, surmounted by a
Novel method for the making of parts ... S/775/62/002/000/001/011
cooling installation. A "primer" or "catcher" is lowered through the slot into the
liquid metal and is then lifted, drawing liquid metal with it through capillary and
me tallos tatic -pre s sure action. The metal reaches a zone of low temperatures and
congeals into the given shape (sheet, rod, tube) establisheo by the shape of the slot,
the rate of pulling, the cooling history, etc. Thicknesses from tenths of mm to tens
of cm can be drawn, with preference for thinner shapes; thicker shapes require
lower pulling rates. NOTE: The slot shape alone does not determine the final
dimensions of the shape of the product; the slot is not a die I The crystallization
takes place at the top of a shallow liquid column that is held together by capillary
forces and, hence, is thinner than the slot. Parts with a*longitudinally varying
section and curvilinear parts can be made. The crystalline structure is controllable.
The rate of pulling is essentially a function of the heat-transfer process. Equip-
ment required: (1) Continuous smelting furnace; (2) continuous drawing mechanism;
(3) shaping equipment, consisting of float, cooler, and moving equipment;
(4) product- removing mechanism; and (5) inspection and control instruments. The
last-cited reference describes the author's and B. M. Golltsman's lab setup (at the
Leningrad State Pedagogic Institute - LGPI) for the making of "endless" strip of Al
and Al alloys, up to 120 mm wide and 0.5 to 3 mm thick. The pulling rate with air
cooling attained 25 m1sec. The strip has a high-grade surface, and its-mechanical
properties are equivalent to those of rolled and annealed Al strip. A cross-section
shows the graphite -crucible smelting furnace, the slotted "float" plate, and the
Card 2/3
MOGILINYY, V.I.; STEFANOVy A.V.
Investigation of a diethylene glycol-gasoline emulsionp
and methods for designing horizontal flow separators of
emulsions. Trudy Inst.isp.gaza AN USSR 9:90-96 161.
(MIRA 15:9)
(Gasoline) (Diethylene glycol) (Separators (Machine4 )
KLIMENKO, A.P.; STEPANCYV, A.V.; VEKSHTEYN, L.M.
Using the pressure drop of natural gas. Trudy Inst-isp.gaza
All USSR 9:97-102 161. (steam turbin (MRA 15:9)
(Gas, Natural) es)
STEMOV.? A@V@
Means of controlling an asynchronous drive with a phase-wound
rotor on a pendulum-type cableway. Trudy InBt.gor.dela IN Gruz..
SSR 2�165-1.72 760. (Mm 1-4: 1-0)
(Cableways-Electric driving) (Automatic control)
BARAIAIDZE, G.K., prof., doktor tekhn. nauk, red.; ASATIANII L.R.Y red.;
*
KAIAI,TDADZE, V.A., red.; PESVIANIDZE A.V.I red.- STEPMIOVI A.V..?
red.; SUIJJMIDZE, Sh. d.izd-va; DZOTM-IIDZE. ' te , rea.
., re I
[Ropeways] Kanatnye dorogi; sbornik statei. Tbilisi, Gos.izd-vo
"Sabchota Sakartvelo.," 1961. 286 p. (MIRA 15;6)
(Cableways)
STEPANOV, A.V., arkhitaktor.
- 1.
i "'Us
wwws' iw; silicon organic compounds in waterproofinc roofing materials.
Gor. khoz. Mosk. 32 no.11:20-22 N 158. (Mra 11: 11)
(Silica) (Waterproofing) (Roofing, Concrete)
STEPANOV, A.V.,inzh.
Device for removing a cone from the shaft of the RP-75 preliminary
screw press. Mael.-zhir.prom. 24 no-5:34-35 '58.
(MIRA 12:1)
1. Bayram-Aliyskiy maslozhirovoy kombinat.
(Oil industries-Rquipment and supplies)
4 iV
SIMIROV. F. I., inzh STAPANOV, A.V., Inzh.
Automatizing the control mechanism for lifting the thickener rake
with central drive. Sbor. inform. po obog. i brik. ugl, no.l.*64-
69 157. (NM lit4)
(Coal preparation-2quipment, and suppliem)
(Automatic controlY
I
STFP@FCW, MMIPYI VASH 1,11TEIVICH.
STEPANOV. APPPEY VASIL'YEITICH.
OPYT YALTINSKIKH PORTOITIKOV (EXPEPInICE OF YALTA HAPMR) YOSn.,A, YORSYOY TRANSPORT,
1952. 76 P. ILLUS., DIAGRS.
N15
756-53
.s8
TEPLOV, Georgiy Vasillyevich, doktor ekon. nauk, prof.;
EYDELIMAY, B.I.., red.
[Planning in an industrial enterprise; theory and
practicel Planirovanie na promyshlennom Dredpriiatii;
teoriia i praktika. Moskva, Ekonomika, 1964. 478 p.
(MIRA 17:12)
STETANOV, ii.Ytt. ; SOKOLOV, A.A., redaktor.
[Finanicul planning in a machine-building plant) Planirovauie finansor
manhinostroitellnogo zaroda. Pod red. A.A.Sokolova. Moskva, Goa, nauchno-
tekhn. izd-vo mashinostroit. lit-ry. 1953. 175 P. (MLEUL 6:8)
(Machinery industry)
MITICLIMAN, Ye.L.; SOLODOVNIKOV, V.Ya.; STEPANOV A Ya., retsenzent;
BROUN, MA., retsenzent; ETCHIN, re tor; VATYMVA, Ye.N.,
tekhnicheskiy redaktor; TIKHONOV, A.Ya., tekhnicheakly redaktor.
CFinancial operations in machine construction plants] Finanso-
vaia deiatellnost' mashinostroitellnogo zavoda. Moskva, Goo. nauch-
no-tekhn. izd-vo mashinostroit. i sudoetroit. lit-ry, 1954. 219 p.
[Microfilm] (MM 8:1)
(Machinery industry--Finance)
SOKOWV, Aleksandr Aleksandrovich, (1885-) ; STEPANOV,-A-t-yao-
[Finance and credit of the machinery industry] Finansovanie i
kreditovanie mashinostroitellnoi promyshlennosti. Moskva,
Mashgiz, 1960. 247 P. (MUU 14:12)
(Machinery industry-Finance)
THYLOV, G.V., prof., doktor skon.naukiJ.Prinimal uchastiye SMANOT. A.Ta..
PANTIR, B.Ta., 1n*h.,.rstseu;ent;.@OGINSKIT,
red.; SnYANSKIT, A.A., red.isd-va,- ELIKIND, V.D., tekhn.red.
[Planning at machinery plants] Planirovanie na mashinostroitell-
nykh zavodakh. Izd-3. parer. Moskva, Goo.nauchno-takhn.izd-vo
mashinostroit.lit-ry, 1960. 480 p. (MIRA 13:4)
(Machinery industry)
;Z*:,d) L.Yz,., ,tokLor elkon. nauk, prof.;
B.I., kzlr,--',. ekon. naulk, dots.;
ekon. nauh; CRIGOHI-YEV, A.Ye., doktoz- ekon. nauk, prof.;
ITIDY L.I., @oktor ekon. nauk, prof..,- LOKSHIII, E.Yu.' dol-tor
ekon. nauk-, prof.; MI'MUTSER, S.Ye.., doktor ekon, nauk,, profb;
OBLONSTM, Ya.A., kand,, ekon, nauk-, dots.; SOKOLOV,
dok-tor ehon.naW-., prof.; SHASS, N.Ye., doktor ekon.nauk;
STIEFAI-MV, A.Yi-; ULITSILTY, L.I., dolctor ekon, muk, prof.;
FODGCRIII0VA, V., red.; TIMANOVSKAYA, N., tekhn. red.
[Econonics of socialist industry; tectbook]Ekonomika sotsiali-
sticheskoi pror-yshlennosti; uchebnik. Pod red. L.I.Itina,
E.S.Gerashchenko. 2., dop. i perer. izd. Moskva, Gospolitiz-
dr.t, 1961. 775 P. (MMA 15:10)
1. Noscow. GosudarstmiTkyN, ekonoLAcheskiy inAitut. 2. Zavedu-
yushchiy kafedrov ekonoi,-Liki oro oh1cmosti Moskovshco gosU-
dartAvemnogo ekonomicheslrogo instituta (for Itin).
kimssia-Inclustries)
BERRI, L.Ya-, doktor ekon. nauk, prof.; MAKSIYOV, I.S.; BRAGINSKIY,
B.I... doktor ekon. nauk; GRIGORIYEV, A.Ye., doktor ekon.
nauk, prof.; ITIN, L.I., doktor ekon. nauk, prof.;
LOKSHIN, E.Yu., prof.; KAMENITSER, S.Ye., doktor ekon. nauk,
prof.; CBLOMSKIY, Ta.A., kand. ekon. nauk, dots.; SHASS, M.Ye.,
doktor ekon.nauk, prof.; STEPANOV IA Ya.- ULITSKIYI L.I., prof.,
doktor ekon. nauk; FODG0"uVA-,-T-., red.; TROTANOVSKAYA, N.,
tekhn. red.
[Economics of socialist industry] Ekonomika sotsialisticheakoi
promyshlennosti; uchobnik. 3., dop. i perer. izd. Pod red.L.I.
Itina. Moskva, Gospolitizdat, 1963. 646 p. (MRA 16:8)
1. Moscow. Gosudarstvennyy ekonomicheskiy inatitut. 2. Zavedu-
yushchiy kafedroy ekonomiki promyshlennosti Moskovskogo instituta
narodnogo khozyaystva im.G.V.Plekhanova (for Itin).
(Russia--Industry)
STEPANOV, A.Ya.
Atmospheric circulation over Ukrainian Transcarpathia in the
contemporary development of nature. Uch. zap. Fed. inst. Gerts.
244:39-70 163. WIRA 18:3)
BORISOV, A.A.; STEPAUNOV, A.Ya.
Aleksandr Mikhailovich k-khangellskii; an his 60th birthday.
Izv. Vaes. geog. ob-va 96 rio.3t255-256 164 (MIRA 17:8)
ALPATIYEV, Anatolly r-likhaylovichp prof.; ARKIWIGELISKIY, Aleksandr IN
Mikhaylovich, prof.; PODOPIELOV, Nikolay YakovIevich, dots.; 'k,
STEPANOV, Anatoliy Y,-kovlevich, dots.; SHAGIROVA, I.M., red.
q
(Physical geography of the U.S.S.R.] Fizicheskaia geografiia
DOOn. LDYJ A.M.Alpatlev i dr. Moskva, Vysshaia shkola. lk@"
Pt.2. 1965. 557 p. (MIRA 18:6)
-1 - - @ - - IT - . w , - @ - - - - - - 7' @r ;r T
gat ,I I 1 4 i 7 ka TY U IT U Ty a , W - - - . ;7 Z@ i; Fr W4 it L 1, 1. If M a W v 11 ry 4,
-
-
-
f
T
- A-
A I A. v
A
11- it u v
it
A -:-th1fd for this 4tStOJ4,*,jn it oldal-oLotic 1
j 1-00
004
Lab. Proki, W. S. S. R.i
premure. A. E. $(
-
L
I
H
id
i-so
S..VQ.5,2I-d(fW -.
al.~mmlicprrwurei%iietlI
o
,
.
from the sun; of the ;c&!;W9 (in mm.) of the nuaovmet@r
And the brixht of the liquid in the capillary. Correction
00 -A for the capillarity is made by immersing the capillary
-9
vertically in the liquid and measuring the height of th -
c 1
0
liquid. The value (usually approx. 16--18 mm.) Ii dr 90
ducted front the previout sum. In the absence of sharp -
00 changes of the truip, no special thermoregulatiou (tit room 00
irinp.) is required. The "I tosidle front a solo. of coLlo- -00
908 (lion inuit be Impermissible to proteins and not too dense.
00 The d. of the shell is checked with a nomial blood serum .00
(coutg. 7.5-8% of proteins). Such a serum produces a See
0 0 Z coltoidal-ossinotic pressure of approx. 360-M mm. of IfrO.
00,3 A low colloidal-ounotic prifraffurv of blood serum (below
150 mm. of IlrO) &W of ascitic fluid (below W turn. of HrOo
000 %ignify a marked hypoproteinemia; a nonnal colloidal.
06.3 osmotic restore of blood serum (approx. 350 mni. of H&O) zoo
all Pf
and a It gh pressure of tratutudiste (approx. IM inin. of
00. IWI slitrilly is stalptuint dMI.Y. slid a hioderate drelva",
0*4 I life colloidal-onnotic pressure of blood (approx, 250 firm.
:
f 11411), a comparatively high pressure of the transudatc
1
1 (approx. 100 min. of HrO) and the presence of other phe-
-
2 nomena which point to an affection of the capillaries (pro-
teins in urine, etc.) signify a capillary or nephritic 41ropsy. zoo
Measurements of the colloidid-osmotic prcmurc in thr
differentiation of the inflammatory exudate ftont th,- see
I anaurcal fluid showed that a high pressure (approx. W, bee
firm. of 1110) of the punctate significs either an inflaturnst -
t tory exudate or a stagnant itaciles. Thecitudateproduce-
i
b
hi
h i
f f
di
f
l h zoo
r
a segm. o
i
n (on stan
or severa
irs.) w
c
s not
ng
ol"trved In the cam of a transudatc. The dein. of thr
colloidal-ostriotic premure is a necessary method for the
L
TI
A S a S L A DETALLURCKA I
L
d of water-salt ntetabali-sm. Three references.
_@tu y
wee
S via", 11"'aill. W. R. Henn "a" so"n'
-
-
E
E rin (P. Ist
0@1 (INC ul
-LI
US AV NO 1%
1; ; ; ; ", I - I I 1111A AR A I a fW 0 a a I N is 9 a a
a is it a I W Is a a at n , , I V
o o o 0 o 0 & 0 0 0 40 0 0 0 0 o 0 0 0 a 0 0 a 0 0 0 0 0 0 0 0
E
: :: : : : P__P..o 0 0 Go**** 0000 o//
1 0 o 0 0 0 00 00 0 4 .0 ; _
( 1@.72'00 SOV/21-59-10-7/26
A ITTHOR: Stepanov, A.Ye.
T UN', E: Calculation of Uncut Beams at the Elastic-Plastic
Stae-,c by -the Method of Consecutive Approximations
PERIODICAL: Dopovidi Akademiyi nauk Ukrayinslkoyi RSR, 1959,
Nr 102 PP 1077-1082 (USSR)
'IMTI-LIXT: In this article, the author discusses the calculation
of uncut beams in an elastic-plastic stage with a
constant load. The aim of the calculation is the ob-
taining of an elastic-plastic epure of the bending
moments. The solution is obtained by the method of
consecutive approximation with the aid of the grapho-
analytic method Z"-Ref. 1_7 by which the compiling and
the solution of the system of equations becomes super-
fluous. It is to be noted, that the solution of this
problem according to a method of strain equalization
leads to cumbrous transcendental equations. The de-
Card 1/2 termination of the criterion of correctness of th
SOV/21-59-10-7/26
Calculation of Uncut Beams at the Elastic-Plastic Stage by the
Method of Consecutive Approximations
elastic-plastic epure permits control of the degree
of approximation, as well as the use of various methods
of speeding up the convergence and the intuition of
the calculator. The presented formulae make the pro-
cess of integration during the computation unnecessary
in all possible instances. The method described may be
extended to the calculation of uncut beams in the case
of material with reinforcement as well as in the case
of a movable loading. There are 4 diagrams (epures),
and 3 Soviet references.
ASSCCIATION: Kyjivslkyy inzheneimo-budivellnyy instytut (Kiyev
Construction Engineering Institute).
C@
PRESENTED: By F.P. Byelyankin, Member of the AS UkrSSR.
SUBI'V'ITTTED: Mar@@h 6, 1959 VK
Card 2/2
10@ 00
AUTHOR: Stepanov, A.Ye.
- --V@ 04APW@# -,&_47-M&WA*1
TITLE: On the Calculation of High Beams
PERIODICAL: Dopovidi Akademlyi nauk Ukrayins'koyi
Respubliky, 1960, No. 2, pp. 168 - 172
S10211 &DI X010021001-5/0 10
A158/AO29
Radyans'koyi Sotsialistych-xv__
TEXT: In this purely mathematical work the author gives approximate for-
mulas, arrived at by using the variation method, for the calculation of high
beams on a normal load distributed alcng the upper and lower edges with the lat-
eral edges being free from load. These formulas (1, 2, 3) are said to be ade-
quate for calculating isotropic high beams having a rectangular cross section.
They do not allow for volumetric forces. They are based an equations of the t1L_
ory of elasticity for plane problems. Coefficients are calculated by formulas
(4, 5, 6, 7). Two examples of how to use the formulas are given. T'he solutions
satisfy the equations of equilibrium and the boundary exactly, and the condition
of conjointness of strains approximately. The solution indicates the relative
minimum of the potential energy of the beam's deformation. The formulas aresaid
to be convenient for practical application, and the solutions obtainedwithtkEdr
Card 1/2
S/021/60/000/002/005@.plo
On the Calculation of High Beams A158/AO29
help are very close to those obtained by other means (Table 1). There are 4fig- /Co.
ures, 1 table and 2 Soviet references.
ASSOCIATION. Kyyivs'kyy inzhenerno-bud:Lvellnyy instytut (Kiyev Institute ofccn-
- struct-ion Engineering)
PRESENTED. by F.P. Byelyankin, Academician, AS UkrSSR
SUBMITTED-. April 24, 1959
Card 2/2
STEPANOV, A.Ye. [Stepanov, A.IE.]
Afir-M Solution of a plane problem in the theory of elasticity by the
use of electric model stu&ies. Dop. AN URSR no.12:1575-1578 161.
(NIRA 16:11)
1. Vychislitellnyy tsentr AN UkrSSR. Predstavleno akademikom
AN UkrSSR F.P. Belyankinym [Bieliankin, F.P.I.
S/144/62/000/003/002/002
D234/D303
AUT119R: Stepanov A.Ye Chief Engineer
T ITLE: Electric simulation of the biharmonic equation
PER1001 CkL: Izvestiya vysshikh uchebnykh zavedeniy. Elektromekhanika,
no. 3, 1902, 262-268
TEXT: To solve the equation, a quadratic lattice is drawn in the domain
to which the equation refers, and alrrebraic equations (equivalent to the
biharmonic equation written in finite differences) are formulated for all
internal knots of the lattice. These equations are transformed and simu-
lated by lattices of active resistances, for every knot. Investigations
are stated to show that the process will be convergent for any number of
knots. Method of simulating boundtry conditions is described. The si-
mulating lattice has been tested at the Computer Center of AS UkrSSR.
It is stiated to possess the following advantages in comparison with those
previOLISly known: Absence of error due to the simulation method, easy
Setting Of bOUndary.conditions, simplicity of choice of controlled poten-
tials. There are 9 figures and 10 Soviet-bloc references.
Card 1/2
. s/144/62/000/003/002/002
Electric simulation of the ... v234/D3O3
ASSOCIATION; Vychislitellnyy tsentr An USSR (Computer Center AS Ukr6SIZ) I -
SUBMITTED: October 27, 1961 a. ,
Card 2/2
PUK11OV, Georgiy Yevgf.-rilyevich; VASIL'YHV, Vsevolod Viktorovich;
q@.EFfi1-1OV,Arkadiy Yevgcnlyevich; TOKAREVA, 011ga Nikolayevna;
D,IAS, ii.L., red.izd-va; RAKHLINA, N.P., tekhn. red.; REKES,
M.A., tekhn. red.
[Electric modeling of problems in structural mechanics] Elek-
tricheskoe modelirovanie zadach stroitellnoi mekhaniki. [By]
G.E.Pukhov i dr. Kiev, Izd-vo All USSR, 1963. 295 p.
(MIRA 17:3)
(for Pukhov).
1. Chlen-korrespondent AN Ukr.SSR
L -16358-65 EiIT(d)/EWT(m)/F.WP(w)/E~IA(d)/FWP(v~/i-!,WP(
k)/EV1A(h)- Pf-4/Ppb
_AMM-2 ZM
ACCESSION NR: AT4045645 S/2943/64/000/002/0140/0150
Al
AUTHOR: Stepanov, A. Ye.
D,
TITLE: On electromodeling of slanting shells and plates
SOURCE: Seminar po metodam matematicheskogo modelirovaniya, i teorii elek-
tricheskikh tsepey. Matematicheskoye modelirovaniye i elektricheskiye tsepi
(Mathematical modeling and electrical circuits); trudy* seminara, no. 2 Kiev,
Izd-vo Naukova dumka 1964, 140-150
TOPIC TAGS: electromodeling, slanting --shell, plate, deformation, finite
differences approximation, interlacing net method, co - uter, cybernetics
MP
ABSTRACT: V. Z. Vlasov (Obshchaya teorya obdiochek-general theor of shells-
Y
GITTL- Moscow- Leningrad, 1949) described the stress deformed slanting shells
'hi, n ci,atdn@ nf rliffim-ronfinl ominfinne vnInfinfy tho riianlnnnv"n@+@
Card 1/ 2
L 1635@8-65
ACCESSION NR: AT4045645
differences approX4mation. By expressing the partial differential equations
through the values of the functions at the points of the net region, one obtains
for the three unknown components of the displacements a system of 3n equations
for npet points. The author shows that it is possible to construct the finite
difference equations in such a way that the system of 3n simultaneous equations
resolves into independent systems with smaller number of unknowns in each.
10 figures and 30 equations
ASSOCIATION: None
SUBMITTED: 22Feb63
SUB CODE: 'AS9 DP, MA
Card 2/2
j
[,9ork,,vs'kyi, B.A.]; ST@P-UIOV,
-"e. [Stapp-,no-,r, A. IE.
!,;e'uhod of coritimious operator modelim'. Dop. Ali' U.@iSR no-3:325-331
1"J. 17:10)
1. ln.Aitute Ail 2. Ghlei-lxorre37;cndeiA A:' UkrSS",
(for vukhov);
L 23616-65 EWTkm)/EWkt)/MFkb) JD/MU/IRM
ACCESSION NR: AT5002499 5/0000/64/000/000/0122/0127
AUTHOR: Stepanov, A. Ye.
'tIT7.E: Modelling a plane problem In the theory of elasticity on a quasi-analog grid
SO URCE: Analogovyye metodyi sredstva- resheniva krayevykh zadach and
m eans of solving boundary value problems); trudy Vaesoyuznogo soveshchanLya,
tvioskva, IUFJZ g KIUV7 MIM, 1OW, T22MIZI
TOPIC TAGS: elasticity theory, plane stress. electromodel, analog.computer, simulationt
finite difference, quastanalog grid, Hooke law, boundary value problem
ABSTRACT: The author proposes. the use of -grid electrointegrators for the solution Of
plane problems In the theory of elasticity. The fundemental equations of the theory of
Plantialtv consist of the saullibrium-
A +
Cord IV) +
t'R.
L 23616-0
ACC=ON NR.- AT5002499
au a
ax- +
lay)
The author breaks the plane region under consideration In the theory of elasticity down
into small squares, and writes the fundemental equations In finite difference form. He
then shows how to construct an electromodel for the solution of these equations. 7hese,
OW
el @ecf romodels permit the solution of problems Involving the determination of forces
-Aor-%omnnnnn fnr n1stna-atrAaaed atatan and for nlane daformationg for-shwlv-and
SEMENYUTA, N. (g. 1,7j,;.),. 11covo, Ybskovskoy obl.); STEPANOV, B.
Simple generators for istudying the MDrae code. Radio no.6:21
Je 161. (MIRA 14:10)
(Oacillators, Electric) (MDrse code)
-"I.
(On our tc the atorr)
U@mta, 1951, 16) 1).
list of* BAST ETTROPEAY ACCESSIONS (E:.AI),
LC, Vol. 8, 210, 7, julY 19,591, UPclas-
STNPAIUV, B.
1, @
Age of the atomic engineering. Znan. sila 31 no.8:6-12
Ag 56. (MLRA 9:10)
(Nuclear engineering)
d J,Pj@.s
uIr' IlarLloIcca-tion," (Qsnov@yr RudiolckArii.) published in the '.Lr
FIeet Herald (Vestnik llo--@dushnogo Flota), NO. 11, Nov. 52.
Smrzry 14 Dec 54
STEPANOV, B.. inzhener,
Airplane turbine-propeller engines. Kryl. rod. 8 no.5:17-19 NY 157.
(Airplanes--Turbine-propeller engines) (KLIU 10:6)
c
85-58-3-15/26
ATUTHOR: Bogdanov, V. and Stepanov, B.
TITLE: Tu-114 (Tu-114)
PERIODICAL: Kryl'ya rodiny, 1958, Nr 3, pp 16-17 (USSR)
ABSTRACT: The authors describe in detail the new Tu-114 four-
turboprop passenger monoplane constructed under the supervision
of Academician Andrey Nikolayevich Tupolev. The Tu-114 represents
the result of a prolonged effort to design and construct a plane
capable of carrying 170-180 passengers almost as economically as
a railroad train. A mock-up was discussed and revised by
specialists from many fields,in--luding doctors. Each of the 4
turboprop engine 's has almost twice the power of any non-Soviet
turboprop engine. They were built b7 a group led by N.D. Kuznetsov,
Hero of Socialist Labor. The Tu-114 is manned by a crew of five.
The test flight was made by Aleksey Petrovich Yakimov, his
assistant Yuriy Timofeyevich Alasheydv; flight engineer Leonid
Alekseyevich Zaboluyev, air navigator Konstantin Ivanovich
Malkhasyan, and Nikolay Fedorovilch Mayorov. There are 21
photographs on an insert between pp. 16 and 17, showing the
Card 1/2
Tu-114
85-58-3-15/26
Tu-114, its Interior, and its designers. On page following p. 16,
upper photo from left to right, D.S. Markov, Hero of Socialist
Labor; A.M. Cheremukhin; A.N. Tupolev, twice Hero of Socialist
Labor; A.A. Arkhangellskiy, Hero of Socialist Labor; and S.M. Yeger,
all Lenin laureates. Center photo shows: B.M. Kondorskiy, Lenin
laureate; I.B. Babin, engineer designer; and V.V Yeremin, shop
foreman. Three photographs on page preceding pagd 17, show - top:
Captain A.P. Yakimov, test pilot lst class, at the controls; center:
navigator lst class K.I. Malkhasyan. seated at the navigator's
pantely bottom - stewardess at the lighting panel. Photographs by
M. Red.9kin, V. Yegorov (TASS) and N. Men'shov.
AVAILABLE: Library of Congress
Card 2/2
S/025/60/000/07/05/008
AUTHOR: Stepanov, B., Engineer
TITLE. On the "Border" ot the Atmospheric Ocean
PERIODICALg Nauka i zhiznl, ig6o, No 7, pp 68 - 69
TEXT-t,Y The fluctuations observed in the braking of the Soviet satel-
lite by the upper layers of the earth's atmosphere have led scientists to
conclude that this braking depends directly on thdilgolar activity. The
F-y and month to
density of the atmosphere was found to vary from day to a
month by 1.5 times at a height of 200-250 km and by 3 times at 700 km. In
addition to these irregularities, the atmosphere undergoes a periodic change
in atmospheric density (28-day cycle). This is attributed to a solar ori-
gin, since the sun rotates roughly every 28 days. Streams of charged par-
ticles issue from the sun, and the earth passes through these at intervals
of 27-28 days. Collision with the corpuscles affects the thermodynamic
parameters ef the earth's atmospheric envelope. V111,
Card VI
PEASE I BOOK ZXPL0171TION SOV/4946
MIkhaylov, A. A., ed.
3tantsil v koamons; abornik statoy (Space Stations; Collection or
Articles) Moscow, lzd-vo AN SSSR, 1960. 444 p. 25,000 copies
printed. (Series: Akadomiya nauk SSSR. Nauchno-populyarnaya
Sorlya)
Reap. Z4.t A. A. Rlkhaylov; Compiler; V. V. Fedorov; Ed, or
Publishing Hous*z To. M. Klyaus; Tech. Zd.z 1. D. Movichkova.
MPOSEs This book In Intended both for the space specialist and
the average reader Interested In space problems.
COVrRACM:. The book contains 73 short articles by various Soviet
authors on problems connected with space travel and the launch-
Ing of artificial earth satellites and apace rocket3. Some pos-
sibilitlos of future developments are also discussed. The ar-
ticles wore published In the period of 1957-1960. No person-
alitles a" mentioned, Ther a are no rerarencen.
V. WU=M= PUT (W SaWW SCrEHCz
11
1
1
1 A. ACorresponding Member or the Academy
4"'
I i"Vis
or , 033i
Soviet Space Rocket Approaches the
.
1
.
.
Perihelion jOctober 18, 19591 340
Ahfghakoy, VCandldate of ?edagogic Sciences. The
Par Side or the Moon L October 8, 1959) 344
0
rov. V. 1. Corresponding Member of the Aced r
S"O
039
ncen U.53 . Outer Space Ph 0
3c r. tography (October 2
1959)
, 348
DRkrqnz&xax__X_7___Doctor of Phyalcal and Mathematical
--Sciences. Automatic Scout of Outer Space [October 28,
19591 351
BqXx]p&Ahav_X_ P. - Ac tl ve Member Of the Academy Of
Silonces tTkrSSR. Our 1ADorstory In Outer Space
lRovember 3, 19591 355
Ratilla-Z-1,L Candidate of Technical Sciences. In-
vestigations Bros don1nig Our Knowledge of the Universe
358
Ton Thousand Revolutions Around the Olobs llzventiYa.
April 3. 19601 369
The Third Sputnik Ran Ceased to ZXl5t [lzv*BtIY&,
April, 9, 1111,01 375
Candidate of Technical Science$.
Liroless cosmonaut (April 14, 19601 3T6
V. SPACS SHIPS
TABS Information (May 16, 19601 381
motion or a Space Ship (Pravda. May 16, 19601 383
B-- CarLoldato of Technical Science*. On the
go the Stars IMay 17, 1960) 384
Pedotov
5 ' Tu.. Candidate of M
d
o leal Science~, Before the
Jum I
t
S
n
o
pace [may 18, 19
6
o 389
Xuleb Academician. Automaton In Outer
601 394
TA33 1nrOrs4tIOn On the Notion or the Sp4cs-Sh1p
Satellite Ifty 21, 29
601 397
'
TABS Inrormation 399
3*cond Soviet Specs Ship tPravda. September 4-6, 19601 400
Gr$*tlnal From the Central Committee of the CPSU and the
Council or Ministers or the USSR I Pravda, August 23, 1960) 441
S/085/60/000/009/002/003
A15a/AO29
AUTHOR- Stepanov,..B,, Engineer
TITLE: A Turbo-Ventilator Engine
PERIODICAL: Kryllya rodiny, 1960, No. 9, P. 17
TEXT: This is a reply to a reader on the difference between a turboventi-
lyatornyy dvigatell (turboprop engine), such as used on Ty -114 (Tu-114), WA -18
(il-i8), AH -io (An-10) airplanes and the Mvi -6 (Mi-6) helicopter. The turbo-
ventilator engine is a turbo-air feed jet engine, also often referred to as a
dvukhkonturnyy dvigatel' (double-contour engine). Thus far, it has not been pos-
sible to design an air-screw of normal type whose efficiency would not drop at
flight speeds of 800 km/h and more, because of the appearance of the wave drag
on the air-screw tips. Conversely, it was found that an engine incorporating a
gas turbine, a compressor and a small multiblade air-screw (called ventilator)
encased in a jacket, is much more efficient at the above-mentioned speeds. The
ventilator is driven by a part of the turbine power, compresses the air within
a sealed jacket around the engine and throws it out through an annular gap beet.-
ween the nozzle and the jacket, thus producing a forward thrust. This engine is
Card 1/2
Z/006/60/000/024/001/004
DO05/Dl02
AUTHOR: St6panov, B.
TITLE@ On the way to the stars
PERIODICAL., Technick6 noviny, no. 24, 1960, 2
TEXT., The article deals with engineering, biological and psycholo-
gical problems which must be solved to secure safety in manned space
flights. First of all, scientists will have to create conditions
during the launching of a space vehicle which would keep the g-load
and its duration within tolerable limits. It has been experimentally
proved that man can best withstand g-loads when placed flat (face
upward or downward) and perpendicularly to the g-forces in order to
effect the least strain on the entire circulatory.system. When the
required velocity is attained, the effect of the g-forces is dis-
continued and replaced by complete weightlessness. The astronaut
can easily learn to move inside the cabin by using grips fitted to
the cabin walls or other devices. Also.) artificial gravity can be
Card 1/3
Z/006/60/000/024/001/004
On the way to the stars DOO5/DlO2
produced by using boots with magnetic soles, or by rotating the
cabin or the entire vehicle around its longitudinal axis. The
composition of the atmosphere inside the cabin can be maintained
constant by highly active chemical compounds releasing oxygen and
absorbing carbon dioxide and excess vapors. An effective protection
of the astronaut against cosmic radiation is one of the most impor-
tant problems to be solved. While this radiation can be avoided on
comparatively short space flights, such as to the moon, it will
inevitably be encountered during journeys to other planets. Another
complicated and not yet satisfactorily solved problem is that of
reent-ry. The task is to gradually decelerate the space vehicle by
retroengines, or a series of short "dips" into the atmosphere, or
by -some other methods. Prolonged weightlessness,*unusual environs
without the accustomed night-and-day cycle, increase not only the
physical but also the psychological strain on man. The opinion was
voiced abroad that man may lose his mind under such conditions.
However, the example of four Soviet soldiers who spent 49 days on
the Pacific ocean under extreme nervous strain without any con-
Card, 213
Z/006/60/000/024/001/004
On the way to the stars D005/DlO2
sequences to their mental condition shows that there are many
individuals in the USSR who will qualify for space travel. A pros-
pective astronaut must be an energetic individual with well-develop-
ed physical and mental capabilities, able to operate the complex
board controls and instruments, and capable of quick reactions even
in the most unexpected situations which may occur during space
travel. There is 1 figure.
Card 3/3
STEPANOV, B., lnzh.
Ramjet engine. Kryl-rod. 12 no.6:30-31 Je 161. (KRA 14:6)
(Airplane,s--Ramjet engines)
STEPANOV, B. I inzh.
Limit of flying ranges. Grazhd.av. 18 no.7:30 Jl 161.(MIRA 14:8)
(Airplanes-Handling characteristics)
KAZZANSKIY. 1. WA3FT); 37-'-'PU,'OV, B. (U'y3AX)
Rad'o amateurs cort@:-%u= the--*z- conversation. Radlo no-4-14-15
Ap 164. ("MRA 17:9)
1 ogc soveta z
@. CUeny obshchestvenn hurnala "Hadioll po radiosportu.
LAPITSKIY. A.V.; SHISUINA, L.N.; PCE3LKINk, M.A.; STIPABOV, B.A.
Tracer study of the solubility of anhydrous metanlobates of
alkali metals. Zhur. ob. khim. 25 no.10:1862-1866 8 155.
(KIRA 9:2)
lAoskovskly gosudarstyennyy universitet,
(Solubility) (Alkali metal metaniobstes) (Radioactive tracers)
STAPANOV, B.A.
Desorption of some split radioistopes from bottom sediments. Gig.
i san. ?2 no.11:3-7 N 157. (MIRA 11:1)
(ISOTOPIS
desorption from bottom sediments of water, value in
assessment of secondary pollution of water (Rua))
(WATIR POLLUT ION,
secondary pollution of surface water by isotopes from
bottom sediments (Rua))
C;,21 @p Z8 PP)g 2 a p @8 t@ s s
3-1
V.
r3
jr -o
f
s t
d d
wn@ @g!a@edsq@;
I @ A -J., V, 3 -" Iz :.:
Ali
2 V
1! v,
A
r 'I Ul
SASH 3 S 3
50), 5W SOV/156-59-2-14/48
AUTHORS: Ste Kakovskiy, I. A., Serebryakova, N. V.
ov,
TITLE: The Redox Potentials of Xanthogenates (Okislitellno-vosetano-
vitellnyye potentdaly ksantogenatov)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Khimiya i khimicheskaya
tekhnologiya, 1959, Ur 2, PP 277-279 (USSR)
ABSTRACT: In the present investigation the same method was used that
the authors employed for determining the redox potentials
of dithiopho3phates (Ref 1). The calculation of the potentials
of the reaction (1) 2 ROCSS' - 2e = (ROCSS)2 was carried out
According to the graphical method described in reference 1.
The redox potentials of methyl-, ethyl-, n-propyl-, n-butyl-,
n-amyl-, n-hexyl-, n--heptyl-., n-octyl--, n-nonyl- and n-decyl
xanthogenate are shown by figure 1 and listed in table 1.
The potential increases as a result of -the decreasing solu-
bility of dixanthogenide with growing carbon chain. The sec-
ond author found in an earlier investigation (Ref 10) that
the solubility of the members of a homologous chain is reduced
by 1/4.25 in the case of an elongation of the chain by a
Card 1/2 CH 2-member. This corresponds to 1/(4.25)2 = 1/18 in the case
The Redox Potentials of Xanthogenates SOV/156-59-2-14/48
of the disulphide with 2 radicals. This is in agreement with
the increase of the potentials for the higher xanthogenates
(over C.), while in the case of the low ones the values of
measurement are too low by 5 -- 15 mv as compared to calculation.
This may be explained by the partial irreversibility of the
reaction (1) with low xanthogenates on the platinum electrode.
The reversibility of reaction (1) is to be investigated in
a later paper. There are 1 figure, 1 table, and 10 references,
5 of which are Soviet, and 1 Rumanian.
PRESENTED Byl Kafedra metallurgii blagorodnykh metallov Urallskogo poli-
tekhnicheskogo instituta
(Chair of Metallurgy of Pxreciaus Lletals@ Ural Polytechnic
Institute)
SUBMITTED: December 15, 1958
Card 2/2
5W S OV/76-7 3-8-2 7/39
. -1
AUTHORS: Kakovskiy, I. A.. Step&no;r.,_._B. Ryazaniseva, 0. F_
Serebryakova,, N., V.
TITLE: Redox Potentials of Dithiophosphates
PERIODICAL: Zhurnal fizicheskoy khimli, 1959@ Vol 33@ Nr 8, PP 1830-1839
(USSR)
ABSTRACT: Organic sulph.-hydryl reagents@ such as xanihogenates, di-
thiophosphates, mercaptanes, dithiocarbamatbsq etc., are used
to an ever-increasing extent in industry for flotations,
in hydrometallurgy, in analytical chemistry, etc@ For thermo--
dynamic balance calculations in connection with ihe above
reagents, it is necessary to know tha redox potsntial (RP)
of these compcunds@ but ihe publications hardly contain any
of the desired data. The present paper is; for this reason
devoted to the study of the (RP) of the ions of dialkyldi-
thiophosphates. The firmness of the chemical bond between the
two disulphide molecules is determined by the density of
the electron cloud between themv i.e. the character of the
central core of the group and the struotUre of the apolar
part. The synthesis of dithiophosphoric acids was carried
Card 1/3 out by means of the reaction of alcohols with phosphorus