SCIENTIFIC ABSTRACT SOLOVYEV, S.N. - SOLOVYEV, S.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652320007-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

WHITAKER, T.;._SOLOVIYIIV, S.N. [translator]; SORMR, V.I., doktor tekhaichs-
skikh nauk. r~daktoi-O-AMUGLOV. S.A.. redaktor; GIADKIKH. U.N.Otekhrodaktor
I
[Lightweight concrete in the United States. Translated from the
Naglishl Legkis batony Y 3ShAo Persvod a angl1iskogo 8.11.3olovieva,
pod red. V.I.Sorokerao Moskva* Goo* izd-vo lit-ry po stroit,
materialamo 1956. 147 p. (MLRA 10:3)
(United States-Lightweight concrete)

SOIA)VIYU1, S.H., inth.
Precast reinforced concrete In the Novosibirsk Economic Region.
Bitil. strol. tekh. 16 no#4:35-36 Ap 159. (MIRA 1216)
l.Mauchno-lealedovateltakiy'institut Stroyinformatoli Akademil,
stroitelletva I architaktW SSSR,
(Novosibirsk Provizee-P~recast concrete)

IYVIISAU, Alaknoy Grigorlyevich; Mli, N.J.; MEPM, Ye.M.; HYDIN, N.G.;
ROZEITMSSER, X.A.; SOLDV'X&Y,_,$_,LI,j_FILIYAX;OVp V.P.;
SWCYK0, V.V.; IMEZ-Abp V.G.,, retsenzent; 'USMIKO) L.A,)
tekhn. red.
(On the road of great initiative] Po puti velikogo pochina.
Y,oekva, Tranozheldorizdat, 1961. 75 p. 01IM 3-5:2)
1. Zarestitell nachallnika Glavnogo uprarleriya lokorotivnogo
khozyaystva Ministerstva putey soobshcheniya (for Merezhko).
Nailroads-&ployees-Labor productivity)

SOLOWIEV, '16YAULOI A.G.
ContX,einer for feeding electrode rods into the bunker of an
electrode-.coating press. Sbor.rats,predlovnedr.v proisv. no.5s4O
160. (MIM 14:8)
1. Zavod "Yrasnyy Profintern*.
(Feed mechanism)

SOLOVITEV, SIN,, inthener.
Working out speelfications for parts of centrifugal overhung-type
pumps on the basis of elements of the theory of dimension disgrasts.
Trudy TION no-13:62-87 151. (XLRA 100)
(Centrifugal pumps--Specifications)

UM/Mi a eel lane ous Industrial processes
Cold 1/1 Pub- 104 - 6/20
Authors s Solovyev, S. X.
Title 6 The accuracy balance of diametral dimensions of objects machined by
the fine grinding method '
Periodical i Stan. I instr. 26/3, 20-21, Mar 1955
Abstract I The error in cutting-tool adjustment is considered to be-the wain
factor cnuslnfi: errors in the Umensions of the 00jects machined
inmdiately after tool adjustZent. The most serious errors were
found to be caused by the displacements and deformations in the
machine-tool -object system occurring under the effect of the cutting
force8. Uther factors resultine in errors of objects machined on
grindinC lath&z are listed. Table; dravinCsj graphs.
Instituti-n ....... 00.
SubmLtted ..........

SOLOVITRY, SIX.
Using hard alloy drills. Itan. I Instr. 28 no.10t)8-39 0 157..
(Drilling and boring machinery) (KM 10111)

1-3
A"s Jour: 16, 25 AuS, 1.057, 69041
Author Solov-v S.N.
Inst
Title Liming of Acid Soils in Some Countries of the British
Empire.
Orig Pub: Udobrenle i urozilai, 1956, 5, 511-61.
Abatract: 'No abstract
Onrl 1/1 - 35

S01OVIM, S.N., kand.yurid.nauk
Capital investments in the chemical industry of the United States.
Op7t stroi. no.30:104-130 160. (HIRA 13:11)
(United States-Chemical industries)

I II --VI Q TI _.-L CIT all-~ OTL
'_INIDI cout-O.t-Lud in J9`;6. Anon Perechun nauchno-issledovatel-
s i ru s I~J
-abot I sborni4ob t dov 11 IDI zakonchennykh.v ~956 godu)
P;~iIIO ".-,rie.L-t-,Omasiiinost~roeriie", (Po~,.'or Machinei-j GonstMction
195'/t No. 32,
A WT i lu (,T Lolovlov, "".N. Investigations into the parameters of
JjuLe-ins-nr ~)ari-rzjin~j, peat and wood gonei-ator gaa Olo. 282).
An inv,_;stigation waz made into the influence of a numbex
of factors on the purification ancd coolinL; of the gas (the
type of nozzle, the density of sprin,::ling, the water
consuLiption, etc.) in application to a gas generator type
OG-16 workin6 on peat or wood.
Nosov, S.S. Invostigation of stresses in parts of the
crankshaft/connecting rod mechanism of heavily loaded engines.
(No. 293).
The work is devoted to the development and introduction of
a procedure for measurin,- stresses in parts of the crankshaft/
L;
connectin;- rod mechanism and results of measurements of
dynam-ic dresses in those parts are given.
Levin, LI.I. Investigition of a system of remote control
for the oi)eration of diesel installations (No. 239).
An investiCation vats made into systems based on available
eniuip-.i,-nt of Soviet =nufacture; spccial devices and systems
were developed and investigated Which can be used to solve
problems of rUL',Ote control in combination with other tasks
in.the automato -Jon of diesel en[;ines. Durin[; the course of the

T-k
-j CY--
319
Y oC data
1 11; 10
liollulLin: ko, o. flD Pam
on Wiu, vA:ar of i:,lovint; par,,L; in diusol cn;_;1noo ty,)o,-
U10.5/13; D6; D,)0; Ch36/45; D and Dr30/5O and
8-DR43/61. (No. 249).
Nikitin, L.D. and Kalinovskiy, O.E. Investigation of wear
of piston rings and cylinder linings when running diesel
en-ines at hitfher -than normal speed and pressure (No. 24?).
The work demon S4- rates the possibility of using small
relative activIty in investigatin.6 wear of diesel parts by a
radio-active mQthod usinG a scintillation counter. A method
was developed for determining the wear of a diesel engine
cylinder liner by a method using radio-active isotopes. A
relationship is established between wear of the upper piston
rings and the cylinder liner and the r.D.m, and maximua
pressure of th,: cycle for a small four-stroke diesel engine.
"'Ymposium No. 29. "Internal Combustion Engines",
The E",jriposium contain-s articles describing investigations
into thu combustion chauber and pistons of engine lChlO.5/13;
results are r-iven of tests on an e3Terimental engine lChl3/16
with a chamber in the piston when viorkdnE; with supercharging.
Thu question of corrosion properties of oils with addities
is consideied t:,nd recommendations are made about oils to be
used in diesel en6ines with lead-bronze bearings.
Oymposium No. 30. "Internal Combustion Ut'ngines and Gas
Gene,iutor Installat ions".
The svayosium contains articles describing investigations

3-19
Ijist of L;ciozitL ic i -:4;earch workp, an siyi:~.Lo-id of r~s
of TsNI)I completed in 1956. Anon. (Cont.)
work a system of telemeasurements of the conditions of a
diesel installation suitable for operation over very E;reat
distances was made and investigated.
Volchok, L-Ya. Development of a procedure and apparatus
for measurinG the speed of pulsating flows of gas (No. 291).
A thermo-anemometer was developed for isometric flows
usinL-; a tunCsten wire 11 microns in diameter and experimental,
pick-ups were made. A special rig was designed and made for
calibrating the thermo-anemometer and investigatinC, the
thermal inertia of fine wires. An investigation was made of
the the:Lmal inertia of fine wires from 11 to 50 microns in
diameter with air flow speeds of 25 - 325 metres/second.
Frolov, F.A. Heat transfer and the hydraulic resistance
of oil coolers with wire type turbulators within the tubes
(No- 309).
An investigation was made of heat transfer in an oil cooler
working on a circuit with oil inside a pipe with a wire
turbulator and water outside the pipe. Formulae are given
for the rulationship between heat transfer and hydraulic
resistance in tiie oil section of the cooler. An outline is
given of the design of a new efficient and small oil cooler
and resultz are given of tests on a cooler connected to a J,la,
supercharged engine for purposes of comparison with desigm rm-

SOLMITEV, S..11.,, kand. tekhn.naukp dotsent
Using the rpecifications of -technological systems in
developing the processes of part manufactiwe. Vesto
mashinostr. 45 noolO:46-51 0 165.
(MIRA 18:11)

HAZHBZUK-HELIKOVA.Z., kandidat tekhnichaskikh nauk; SOWVIM,S.
Glass blocks--efficient material for use in window apertures.
Stroi.mat.. izdel. i konstr. 1 no.7:17-19 Jl'55. (MIRA 8:11)
1. Starshii nsuchnyy sotrudnik VNIIS (for Bashbouk-Kelikova)
2. Nauchnyy sotrudnik TSentrallnogo nsuchno-issledovatelOskogo
institute, promyshlennykh sooruzheniy (for SolovIyev)
(Glass construction)

SOIDVITIVI S., arkhItektor.
Using rippled glass for covering light openings In roofs*
Strol, mat. 2 no.11:24-25 N 156~ (MMA 10: 2)
(Glass) (FLoofing)

SOWVIYEV, S.P. Cand ',,L'ech Sci -- (diss) "Tran3parent guards
made of hollow Flass blocks and corrugated glass". j%los,1957.
10 pp 22 cm. (Acau of Construction and Architecture USSR.
tA 141AV~f,', V,4,r I./
ici fies Iniit of Azchit*etwpe~l Physics and Saf-e-", Structures)
110 copies (KL, 9-57, 101)
C~
L

GUaV, H.K., doktor takhnichaskikh nauk, professor: SOLOVITIT, S.F., imndld&t
takhnichoskikh nauk. 0K.-
Using glass and reinforced concrete elements. Stroi, pros. 35 no,5:
27-32 My '57. (K= IOW
(Glass construction)

SKOBLOV, D.A., Inzh., red.; ANDRIYEVSKrY, V.G., kand. tekhn. nauk,
red.; SOLOVIYEV, S.P., kand. tekhn. nauk
(Construction specifications and regulations] Stroitelinye
nornW i pravila. Moskva, Gosstroilzdat. Pt.l. Sec.V. ch.20.
[Articles for filling openings and skylights) Izdelila dlia
zapolneniia proemov I fonarei (SIV I-V. 20-62). 1963. 6 p.
(MIRA 17: ))
1. Russia (1923- U.S.S.R.) Gosudarstvennyy koritet po delar.
atroltellstva. 2. Goastroy SSSH (for Skoblov). 3. Mezhvedom-
stvennaya kon,issiya po peresmotru Stroitelinykh nom i pravil
(for Andriyevskiy). 4. Tsentralinyy nauchno-issledovatellskiy
institut eksperimentallnogo proyektirovaniya zhilishcha Aka-
der.ii stroitelistva i arkhitektury SS&i (for Solov'yev).

SOLOVIYEVt S.P.p kand.tokhn.nauk; DUBOV, E.M.j, inzh.; KOIAMOVSKOY, A.A,, Inzhe
Hermetic industrial buildings with exterior valls of glass rein,,breed
concrete* Prom& stroie 41 no*20-12 F '64o (MIRA 1713)

?0-3-2-&jP
AVTHORS: Verbitskaya, T.N., Zhdanov, G.S., Venevtsev,
and ov'yev, S.P.
_Q0
TITLE: Electrical and X-ray Investigations of the System
BaTiO 3 -BaZ_-O3 (Elektricheskiye i rentgenograficheskiye
Issledovaniya sistemy BaTiO 3 - BaZrO3)
PERIODICAL: KristalloGrafiya, 1958, Vol. 3, Hr 2, pp 186 - 196
(USSR).
ABSTRACT: Various solid.solutions of BaTiO 3 - BaZrO3 were
prepared, having up to 30 mo1% of the latter, by heatigg 0
appropriate mixtures of BaCO 31 T102 and Zr02 at 1 400 + 10 C.
The resulting materials were examined by the Debye-Scherrer
method with a camera cf diameter 11.4 cm, and Cr or Cu radiation.
With Cr radiation the lines 310 and 222 occur at a sufficiently
h1gh angle to give accurate cell dimensions. (For Cu radiation
the appropriate lines are 501 and 431) The significance of
the splitting of the lines under the distortions observed is
explained. Dimensional measurements were made to + 0.001 A,
monoclinic angle to + 1.5', rhombohedral angle to 7 l' and
axial ratio to + 0.0?5b5.
Cardl/3 For the pure coEpounds the cell dimensions were found to be:-

70-3-2-9/26
Electrical and X-ray Investigations of the System BaTiO 3 - BaZrO 3
BaTiO 3 a= 3.990, c = 4.027, c/a = 1.0093, V - 64.12; and
BaZ_rO3 a = 4.186 and V = 73-35 . From 0 to 2 mol% of
zirconate the dimensions of the tetragonal phase approached each
cther slightly. From 2 to 6.5% the solid solution was pseudo-
mono,-lilo-ic with a c and the monoclinic angle decreasing
L 0
frcm 90 M5' to 90 04.01 From 6.5 to 20 mol%, the s8lution
was rhombohedral with the rhombohedral angle equal to 89 57'
and increasing from 4.01?? to 4.0440. Above 20% the solut4on
t
was cub.1c with an increasing from 4.044? to 4.0616 at 30%.
Over the whole range the -volUM3 of the unit cell increased
linearly from 64.12 to 6?.00 A with no breaks at the phase
transitions. In pure BaTiO 3 three phase transitions (all with
hysteresiag are sbserved on changing its temperatures They
are at 120 , 0-5 and -70 to -80 C. These transition points
were measured for a range of compositions. Below 10% zirconate
all four phases occur at appropriate temperatures, between 10
and 15% there is a confused region and above 15% only the cubic
and rhombohedral phases occur. Measurements were also made of
the dielectric constant of the material at various temperatures
Card 2/3

70-3-2-9/26
Electrical and X-ray Investigations of the System BaTiO 3 -BaZrO3
and compositions.
The phase diagram constructed is like that found for BaTiO
BaSnO by Smolenskiy and Isupov (DAN, 1954, Vol 96, 53) and
not like that drawn up by Kell and Hellicar (Akustika, 1956,
Vol 6, Nr 2, p 232).
There are 8 figures, 2 tables and 26 references, 10 of which
are Soviet, 2 German and 14 English.
ASSOCIATION: Fiziko-khimicheskiy institut im. L.Ya. Karpova.
(Karpov Physico-chemical InStitute) and NII MRTP
SUBMITTED: July 183 1957
Card 3/3

SOV/70-3-4-11/26
A6THORS: ifenevtsev, Yu.ii-, Zhdanov, G.S., Solov'yeY, S.P. and
4ubov, Yu.A.
TITLE; The Internal Fields in Certain Fakro-electrice with
Structures of the Perovskite Type (Vnutrenniye polya v
nekotorykh segnetoelektrikakh so strukturoy tipa
perovskita)
PERIODICAL: Kristallografiya, 1958, Vol 3, or 4, pp 4?3-4?9 (USSR)
ABSTRACT: An analysis of the methods of calculating the internal
field in ferro-electrics of the perovskite type is made.
The internal fields and the spontaneous polarisation in
the tetragonal modifications of BaTiO 3 and PbTiO 3 are
calculated and the influence of certain cation parameters
on these quantities is estimated. The structure was
assumed, as a first approximation, to be built up of point
charges and point dipoles. Kozlovskiy's method kZh.Tekh.
iriz., 'rol 21, r 11, p 1388, 1951) where the five
differLnt ions'are attached to five separate sub-lattices
was used. In BaTiO 3 the Ba ion was taken as the origin
but in the PbTiO 3 the Ti in view of the reported displace-
cardl/3 yenta (Shirane, Pepinsky and Danner, Act&-Crystall, 1956,
;01 9, P 131). Published polarisabilities were used.

SOV/70-3-4-11/26
The Internal Fields in Certain Ferro-electrics with Structures of
the Perovskite Type
As the effective ionic charges were not known, a coefficient
of charging y(O
fore, be expected to show peculiarities where these two effects
interact. The variation in structure. dielectric and piezo-
e1c,cirl(; properties is not contintiolis from one end-member to
thin other. Experimentally. solid solutions with 7, 9, 11, 111
and 2`4 wt. I,;- PbTiO3 showed anomalies not explicable as due to
Jo_~..4 of PbO. NaNbO 3 undergoes several phase transitions in a
- -ic -v and optical observations
,;1 rt temperature inter al. Dielectric 0
give tranzAttions at 56o, 470, 520 and 640 C. X-ray data contra-
di,_r all but the first of these. Polycrystaltine material was
Catd 1/11

82509
5/070/60/005/004/009/012
E132/E36o
Crystal Chemical Investigations of Substances With the Perov-
-qkit-~ Type of Structure Which Ha_,, Special Dielectric
F t Ild L ed by X-ray atettiodr. up to ?000C and transitions at 360,
4W, 470~'520 and 640 C were found. Below 360 0C NaNbNO, is
0 1
rno nf~ C I 1 0 L,~ W.1 t~-l b and 0 900C. Above 360 C It is
Monoc I Inic Witt] a b and a > 90 0 C (true symmetry
ort ftorhcmbi:~ ). The tran.,;jtton from ortborhombic to tetragonal
is not at 360 blit at 430 0C. The X-ray method is no legs
Zensitive than (lie optical. and dielectric triethods.
From an examination of solid solutiong BaTiO 3 (Ca,Sr)(Zr,Sn)o.,,
ii, tq conc luded that . other things being equal the Curie
tt-mperaturr- of perovskite- type ferroelertrics Is higher, the
smallvr is th(! periou of the lattice and tile higher Is the
pciarisability of the artive cation.
L3 i T i G3With added Bi,,O,.Cr,,o3 and Bi2o 3 At2o 5 has been
~Ynthesi.,.,~d -ind pe,.impns r-li(K-d prnpc-rt-&v_z Itke those found in
B~,TiO C"t"tatiling, 81 Ti 0
2

19 2 5-09
S/0-flo/60/005/004/009/012
E
Crystal Chemi.cal Investigat ions OP949MOnces with the Perov-
skite Type of Structure Which Has Special Dielectric
properties
BiFeO and specimens in the system PbTiO--.BiFeO have been
3 3
synthesise-d. The former has a rhomboliedral distortion
(a .~ 3.g63 I , u = 890210) and a susceptibility about 80.
At 200 C the susceptibility has a maximum of about 1200. In
the solid solution up to 700P, by wt. of BiFeO3there is also
a tetragonal modif.ication. The Curie point of BiFeO3 appears
to be higher than that of PbTiO-.
Ueneral methods forcnIculating the Internal field have been
developed for structure5 of any dipole configurations. These
have been applied to the orthorhombic structure of CaTIO 3*
Ifere, the internal electric field is zero at the T1 si-tes.
There are 29 references. 2 Japanese (in English). d English.
2 international. I Swiss, I German and 15 Soviet.
C a r d -5 / ")

62509
S/070/60/005/004/009/012
E132/E36o
Crystal Chemical. Investigations of Substances with the Perov--
6kite Type of Strurture Whirh Has Special Die-lecArlc
Propet ( I e5
ASSOCIATION. Fizi.ko-khmi.cheolkiy Institut
Im. L. Ya. Karpova
(PlIvsico-Chemical Institute imeni
L.Ya. Karpov)
SUBMITTED February 23. 1960
Card 4/4

S/07060/005/005/oo6/oI7
E132/E36o
AUTHORS: Solovlyev,--S.P., Venevtsev, Yu.N. and
Midanov, G,S,
TITLE- On a Method of Calculating the Internal Fields in
Complex Dipole Structures
PERIODICAL: Kristallografiya, 1960, Vol. 5, No. 5,
Pp- 718 - 725
TEXT: A method is proposed for calculating the internal field
in complex dipole structure. In general, the problem comes down
to the solution of a system of linear equations with 3m
unknowns, where m is the number of atoms in the elementary
cell. If the symmetry of the structure is taken into account
the number can be decreased to 3n where n is the number of
complexes and where n is less than m . Ewald's method can be
successfully applied to calculating all the structure sums
necessary for estimating the fields. The method Is generally
applicable in all cases where the structure has been determined.
The calculation of the structure sums enables the idealisation
of the structure to be avoided as these sums can be calculated
in any case. Sometimes, however, in spite of the methods
Card 1/21

A-
S/070/60/005/005/006/017
E132/Z36o
On a Method of Calculating the Internal Fields in Complex
Dipole Structures
available for reducing the tediousness of the calculation of
the fields in real structures, the number of unknowns may be
too big to enable the system of equations obtained to be solved
by hand methods. This raises no difficulty as modern computing
machines can deal with such systems of equations with extreme
speed In fact, the systematic calculation of the fields in real
tiantiferroelectric crystals and in other structures is best done
by a machine appropriately progranuned.
There are 1 figure and 14 references; 5 Soviet. I Swiss,
5 English and 3 German.
ASSOCIATION:
Fiziko-kbimicheskiy institut imeni
L.Ya. Karpova (Physics-chemical Institute
imeni L. Ya. Karpov)
SUBMITTED- March i, ig6o
Card 2/2

e 84996
LA 7 P0 M V2 / 11 S/048/60/024/010/005/033
B013/BO63
AUTHORS: -splovIyev, S' P.. Venevtsev, Yu. 11 , Zhdanov, 0. S.# and
Ivanoval V.
TITLE: Method of Calculating Inner Electric Fields in Complicated
Dipole Structures and Their Application to.CaTiO ; ill
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya, 1960,
Vol. 24, No. 10, pp. 1191 - 1194
TEXT; A general method is suggested for calculating the inner ele--tric
fields in complicated structures, in which there may take place both
parallel and antiparallel ionic displacements in an arbitrary direction.
This method, wLich was applied to the calculation of fields in CaTiO
type crystals, constitutes a generalization of the methods that are
used for calculating the fields in Riezoelectric substance#Df an
ABO 3- type structure, and proceeds from the respective structure model
of the compound concerned. A total of six different cases were examined.
The calculation was made at the vjchislitellnyy teentr MGU (Computer
Card 114

84996
Method of Calculating Inner Electris Fiells in S/048/60/024/010/005/033
Complicated Dipole Structures and Their 30131B063
Application to CaTiO 3
Center of MGU) with the computer (Strela). The calculation of
the fields in CaTiO 3 shows that the distribution of fields in this com-
pound depends only little on the polarizability of Ca Ions. It is all
the more dependent, however, on the effective ion charge. up to the
change of the signs of the fields acting upon the oxygen ions, although
the qualitative picture remains unchanged. The fields acting upon Ca
ions are only little varied in this connection. In all of the six cases
examined the fields are considerably smaller than is the case with the
piezoelectric ABO 3 compounds. In this case, as may be seen from the
structure symmetry, the field acting upon the Ti ions is exactly vanish-
ing. In BaTiO 3 and PbTiO3 (Refs. 8 and 9), on the contrary, fields of
maximum strength act upon the Ti ions. The basic difference between the
fields in CaTiO 3 and in the piezoelectric ABO3 compounds related to it,
is connected with the fact that in the latter the octahedra are greatly
deformed, while they are nearly ideal In CaTiO 3* The relationship
Card 2/4

Method of Calculating Inner Electric Fields in 0/048/60/024/010/005/033,1~~
Complicited Dipole Structures and Their BOWN63
Applica ion.to CaTi
03
betweewthe anomaly of dielectric proportion and the deformation of
edra can be also observed in the case of such ABO compounds
B06 cot 3
as are, e.g.j PbZrO PPbHfO,, r*&NbO ~t can be stated that the presence
3 3-
0f a deFormation of B - 0 is an indispensable prerequisite for an anti-'
aj
piezoelectric phase transition. The authors thank N. Pq Trifanoyl coil
borator1of the computer center of MOU for his assistance in the comput&_~,
ta-
tions. ~he present paper was read at the Third Conference on Plesbal
t-ricityL which took place in Moscow from January 25 f0- 30t 1960. Ther's
are I f Cure and 12 references: 4 Soviets'
ASSOCIA~ION: Piziko-khimicheskiy inst~tut ins, L, Yaa~ Krpova~~
a
(Physicochemical InstituNe imeni Li7ya* Karpoy
t
77-
Card 3/
0,~
3

(22 0 3
., P VV)
141., 13.15; //.3 6)
5/070/6l/Oo6/(jol/002/011
E032/E314
AUTHORS~, Solovlyev, S.P., Venevtsev, Yu.N., Zhdanov, G.S.
and Ivanova, V.Y.
TITLEj Calculation of Internal Electric Fields in
Perovskite Crystals (CaTiO 3)
PERIODICALi Kristallografiya, 1961, Vol. 6, No. 1,
pp- 78 - 85
TEXT. In a previous paper (Ref. 13) the present authors
gave an account of a general method for the calculation of
internal fields in structures having an arbitrary dispostion
of dipoles, The aim of the present paper is to apply this
method to the calculation of fields in the antiferro-electric
dipole structure of CaTiO 39 using a model based on the real
structure reported by Kay and Baily in Ref. 14. In the
method described by the present authors in Ref. 13, it is
assumed that the polarizabilities and effective ion charges
are known, The polarizabilities of Ca and 0 ion:_Igre,taken
from the book by Kittell (Ref. 15) (%Ca ' 1.10 1
Card 1/5

20024
S/070/61/006/001/002/011
E032/E314
Calculation of Internal Electric Fields
Q0 = 2.4 x 10"' 24 CM3) ~ It is further assumed that the
effective charges of the ions in BaTiO3 are approximately
equal to one-half of the total ion charges. In order to
estimate the effect of the assumed magnitude of the charges
and polarisabilities on the field distribution jix different
variants of the calculation were tarried out, in which the
charges and polarizabilities were varied within reasonable
limits. The results obtained are summarized in Table 3,
which gives the internal fields in CaTiOY The first five
Variants are based on the real structure of CaTiO 31 shown in
Fig. 2. For comparison, variant 6 is based on values of the
f and h sums calculated for undispersed positions of the
ions, All the calculations were carried out on the electronic
computer "Strela" at the Computation Centre of MGU.
Card 2/5

-';/()7(;/6 1/00()/OUI/O();!/Ol I
Calculation of Internal Electric Fields ....
Acknowledgments are expressed to N. 1-. Trifonov and
A. Telljiova of the Computation Ceritre of ~;GU, who carried
out LIw nim"et-Ical calculation on t`w "Strela" computer.
Tiiere are 1: figures, 3 tables and '17 reforencesl 7 Soviet
and 10 non-Sovict.
A5~;UClATIUN: Fiziko-khijiticheskiy institut im. L.Ya.l.arpova
(Physicochemical Instittite im. L.Ya. Karpov)
61JUNITTED i March 11 1960
Card 3/5

20024
s/v7o/6l/oo6/ool/0U2/0l1
KU32/E314
Calculation o f* Internal Electri c ....
Table 32 1 - Var iants; 2 E- 10- V/cm; 3 Projection Axis;

CGSE esu

Or, b
pop-
'It mev a.

4C3;
a 1 00
0 MCS;

s
*CA

2 #CA W 110 #C& 1
: ~'
1 9.3
:5 C.4;
o
-
- - -
- ST,
. 1 2
1 T
40 1.0 0 Was;
00 --1.0 60-1.0 to-1.0
- -
2.0 CGSK; to
X -0.M108 -0. UM -0.0972 --o, (r, 2o -o.osm '-:.0.0072'
/,"CA 0 0
1
1 0
1 0 0 0

z
0.494
0,751 1
0.51,
601
0 . 0,537 0,422

X 0 0 4) 0 0 0
0 0
I
T 0 0 0 0
z 0 0 0 0 0

E X 0, 767' 0,876* 2,053-. -0,477 0,79r O.BW*
01 y 0 0
1
1 0
1 0 0 0
y 0.0215 O.Y)2 -0 ,499* U.680 O,OwG -0.0714-

Card 4/5 X 0 4706 9) 511G0 0.91294
*
0,0578 0.49q- 0,544-
y 0.873 0,892 -1,887
1 0.134* -0880 -0 942
z -0.("6 -0,()85 -0,5-,0 0,519 0:0= --0:520

20024
Calculation of Internal Electric Fields .....
2:
z
y ~04
CA
Pxc. 2. Osemenapnam wiefixa CMOs.
Ci%rd 5/5

"OLOVIYEVI.~,P.l V21IRMP'.1", .1 ZHDAJOV, G.S.
X-ray diffraction study of phase transitions in NaNbO3. kr13-
tallografiia 6 no.2:218-224 Mr-Ap t61. (Mliu lo: 9)
1. Fiziko-khimiche3kiy institut im* L*Yaoharpovao
(Sodium niobate) (X rays--Diffraction)

VE,,,zVTSzv~, Yu,.N.j SOLOVIYFW, S.P.; ZHDANOVp G.S.
Methods for the X-ray diffraction study of &mall deformations
of cubic primary calls. Zav.lab. 27 no.9:1112-1115 161.
(MIRA 34:9)
1. flauchno-io:31odovateliskiy fiziko-khimichaskiy institut
imoni L.Ya. Karpova.
(Electric batteries) U Iray-Diffraction)

5/181/62/004/012/027/052
BI 2 5/B1 02
AUTHORS: Lyubimov, V, N., Venevtsevg Yu, N.1 Solo s-'EtJ
Zhdanov, G. S.,and Bakushinakiyt A. 0
TITLE: The dipole structure and the Internal electric fields in
PbZrO3
PERIODICAL: Fizika, tverdogo tela, v. 41 no. 12, 1962g 3543-3550
TEXT: The most probable values of the internal electric fields and field-
induced electron dipoles are calculated for a PbZrO3 crystal on the basis
of the model of point dipole structure. Using the method developed by
S. P. Solov'yev, Yu. N. Venevtsev, G. S. Zhdanov (KristallografiYa 3, 473,
1958), the determination of the 28 different projections of the electron
dipole moments was reduced to the solution of a system of 26 linear
algebraic equations for 28 unknowns. The structural sums which are
necessary for the eet-up of these equations describe the fields of the
infinite sublattices of the unit charges and unit dipoles# the number of
which exceeds by far 1000. Both the structural sums and the system of
Card 113

S/181/62/004/012/027/052
The dipole structure and the ... B125/B102
equations itself were calculated in various modifications using the
electronic computer "Strela". The effect of all structure sublattices on
each of the 40 atoms incorporated in the elementary cell was taken into
account. The variant P 5 was determined by extrapolation for the
parameters e Pb ' 1.270 eZr ' 1-73t e 0 - -it aPb w 4-32-10- 24 CM5
-24 3 24 3
aZr " 0.00-10 cm t a0 - 2.26-10- Cm . 0 1 denotes the effective
charges and ai denotes the electron polarizabilities of the ions. The
mall value of PS within a certain temperature interval makes it possible
:
0 establish a correlation between the data obtained from structure and
those from dielectric studies. At room temperature, the ion polarization
for the above-mentioned values of the parameters is compensated by electron
polarization, Hence, the PbZrO 3 crystal in antipolarized and very similar
to an anti-electret. Results, similar in principle, are obtain:d for any
of the ten crystallographic polar classes of pyroolectrics (ole trots).
It is assumed that at least the direction of most of the projections of
the electron dipole moments and of the internal fields corresponds to the
Card 2/3

S/181/62/004/012/027/052
The dipole structure and the B125/B102
real structures of PbZrO 3 at room temperature. The displacement of the
atoms may be attributed to nonelectrostatic forces. The highest field
11 tren6th acts on the Zr ion. In general the internal field strength
increases with decreasing ion polarizability. The rules found for PbZrO 3
resemble those governing the ferroelectric crystals BaTiO and PbTiO
It would be useful to investigate PbZrO 3under pressure# 3There.are 39
7 tables.
ASSOCIATION: Fiziko-khimicheakiy institut in. L. Ya. Karpova, Uoskvs,
(Physicochemical Institute inani it Yao Karpov# Moscow)
SUBMITTED: July 99 1962
Card 3/3

SOLOVYEVj S. 11,; UfUBIMDV, V. N.; VROMEII., Yu, N.; aiDILNOV, G. S.
"The calculations of the internal electric fields and electric-field gradients
in the perovskite-type compounds with special dielectric properties."
report submitted for 6th Gen Assembly, Intl Union of Crystallography) Rome,
9 Sep 63-
Karpov Inst of Physical Chemistry, Moscow.

-LV, V. N. , SOWWIV, S. P., Vis ov, U. zi.
Yu. N., LYU31. v k AJS Id
"Calculation of Internal Electric Fields and Field Gradients in Perovskito
Conpounds -with Special Dielectric Properties."
renort presentod at the SyVosium on Forroelectricity and Ferromagnetism,
Leningrad, 30 May - 5 June 1963-

-OLOVYrV1 S. P.
"The calculations of the internal electric fields and electric-field
f-radients In the perovskite-type compounds with special dielectric proper-ties."
report prerented at the Symposium on Phase Transitions in Solids, 6th General
ASsembly, Intl. Union of Crystallography, Rome, Italy, 16-18 Sept 1963.
(Karpov Institute of Physical Chemistry, Moscow, USSR)

ACCESSION NM AP403OG34
5/0048/64/028/004/0630/0635
AUMIOR: Venovtsov,Yu.N.; Lyubimov,V.N.; Solov'yevjS.P.; Zhdanov,0.8.
TITLE: Calculation of the internal electric fields and their gradients in p*rov
skito compounds with distinctive dielectric properties 11sport, symposium on Fer;o.
magnetism and Forrooloctricity hold in Leningrad 30 May to 5 June 19627
SOURCE, AN SSSR. Izv.Ser.liz., v.28, no.4, 1964, 630-635
TOPIC TAGS: Internal field , crystal Internal field , porovskito structure, forro-
electricity, ionic forroolectricity model, ferroslectric compound
ABSTRACT! For a number of years the outhors have been engaged In calculatfog the
internal electric fields in compounds having the perovskito structure and peculiar
dielectric properties. The methods of calculation And the results have been reported
in a series of papers appearing in Kristallografty (CrystAllography) and Fiziks
tvardogo tola (Solid State Physics) from 1958 to 19G2. The results of those calculs.-
tions are discussed in the present paper. The calculations were based on the Ionic
model of a crystal with known or assumed structure. The charges and polarizabilWas
of the point ions were treated as given quantities, but the induced dipole moments
Card 1/3

ACCESSION NT.: AP4030634
wore calculated. Calculations were performed for several values of the chan-,o, pola-
rizability, and radius of the ions; reasonable variations of those pararw-ters (I'd
not alter the qualitative picture of the fields in the six compounds Investigated
(lead, barium, calcium and cadmium titanates, sodium tantalato, and lead zire
Good agreement was obtained between obnorved and calculated values of the spontall-
cous polarization with the value 0.5 for the ionic charge factor. The results of
the calculations indicate that XaTaO3 and CdTiO.3 are forrielectric materials and
that PbZrO3 is a forrielectric material with nearly antiferroolectric properties.
The internal field at the position of the Ti Ion was found to vanish in CaTLO3 but
to be large in DaTiO3 and PbTiO3. This difference in the fields accounts for the
different dielectric behavior of these materials. Doczuse of the strong field at the
T1 Ion, the conclusion of H.D.Regaw (Acta crystallogr.,5,739,1952; lbid.,7,187.1954)
that the principal factor In forroolectric transitions of AD03 type materials must
be a sharp increase In the covalent character of the D-0 bond is regarded as inado-
quately grounded. It is concluded that further theoretical " experimental investi-
gation of the possibilities of the ionic model is desirable, and Improved calcula-
tions of field gradients are promised for the near future. OrIg#&rt.hast I table.
C,rj 2/3

KAJPY3!EV, A.G., ',;,EM*,:'.,E";, SCLOPYEV, 3.1'.; GCRBATINC~V, L.A.;
"J.3.
X-ray ctamibers for high-tAmperaturo stadies. Zav. lab. 3C no.lf)z
1274-1276 fi~4. (KIRA 1314)
1. fiziko-khimic~eskly Institut Imen!
Karpova.

SOI.OV'YFVI J01.IVO-I),OBROVOL'SXIY, V.V.
haport on the activity of the Mineralogical society or the
U.S.S.R. for 1964, Zap. Vses. min. ob-va. 94 no.0486-495 '65,
(MIRA 18: 9)
1. Vltse-prezident Vaesoyuznogo mineralogicheakogo ob3htheatva
(for lojolovlyev). 2. Uchenyy sekreterl Vsesoyuznogo wineralogi-
cheskogo obshchestva (for Dolivo-Dobrovollekly).

i ~q We k~.,i"- 1 ch K-j tskii., I WM-I-i 5
V3es,
Of'R.I 2~
y3- 1. 1
vi t---] Iiyye chfl!:ll
f.bah,,hostva.

~; 11) LCO? I y ~741,.P., prof.
Main &Pm1cal characterlstles of basJc Igneous rocks in
the U.S.S.F. Zap. Vaes. min. ob-va 91, nn.6:625-641 165.
OURA l9sl2)
1. boystvitellrVy chlen Vses~)yuznogo mirin-ralogicheskogo,
,)bahchestva.

!-A.; 1Ei1,'-7FYKV, N.A.; MIKHAYD71. b.A., SOLOVOYEV, S.P'
VFLIKWJJ~A'1111N~~XITP
Vlad,m!rov!ch Cbruchev, 1891-1965; o~.!t-aary. Zap.
if
fses. min. ob-va 94 nn.64735-716 165, (MIRA 18112)

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