SCIENTIFIC ABSTRACT SMOLYAN, G.L. - SMOLYANINOV, N.A.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Increase of capacity of driers for heavy ceramics, M. KiL. I Nr
LSR.-Z. A. SKOLVAKOVA, AND A. P. LAasKxav. Transtated Ili:
'SiljkaFk~c. 4T4TfaMj (1953): cf. Cer4m. -Absir., 1951, Now.,
p. 202h; Mot, April, p. 73d. MAA.

Z. A.
SNOLYAKOVA, Z. A. -- "The Selection of the Optknum System of Drying Ceramic
Parts in Terms of Their Structural-Mechanical Parameters." Min Cojistruc-
tion Materials Industry USSR. All-Union Sci Res Inst of Glass (VIIIIS).
Moscow, 1955. (Dissertation for the Degree of Candidate of Technical
Sciences.)
SO: Knizhnaya Letopis', No 5, Moscow, Feb 1956

FETISOV, A.!.; SMOLYAN, G.L., redaktr,%,,; AKHIAMOV, S.N., tekhruchask--27 rs-
dakto:v.
[Demonstration in geometry-] 0 dokazatellat7e v geometrii. Hoek-v-a,
Gos. izd-vo tekhniko-teoret.lit-ry, 1954. 57 P. (Populiarnye laktzii
po matematike no.14) (laRA 8:4)
(Geome try)

V. ; ARLAVJJ:IOV, 1,11.; AR.3KE, F. ; DAU11OV, S.; BELOUSOV, I.;
:~ILL1,11YE.', D.; VA'-ELI, T.; I'LIDINIHOV, L.; GUSHCH-111,
YELAGIII, V.; YEPESHKO, F.; ZHURBINA, S.; YAZAPdIG%-7SFXYA, G.;
B =jI T
KALINE., Yu.; KELEER, V.; KONOVALOV, DLIN, Yu.;
LEjED7ETI L.; PODGORODNIKOV, RABTT.O~ICH, I.; REFIN, L.;
~ZIOLYAN G T-ITA-.RFIIKO, V.; TOPILRIA, T.; FEDCHENKO, V.;
.AN) N.; E:.2.!E, A.; N-112%
'OV, F.; YAKOVLEV, N.;
VIKHAYLOV, K., nauchn. red,; LIVANOV, A., red.
[Little stories about the great cosmos] ',"'alenlkie rasskazy
bol'shom Kosmose. Izu.2., Moskva, Molodaia E-,vardiia, 1964.
368 p. (MIRA 18:4)

KARADZHAYEV, K.V.[translator]; MANIKO, V.L[translatorl; CHUKREYEV,
K.Ye.ftranslatorl; SMOLYAN, G.L., red.; VIASOVA, N.A.,
tekhn. red. ----
(Semiconductor radiation counters] Poluprovadnikovye schet-
chiki izluchenil; sbornik statei. Moskva, Gosmatomizdat,
1962. 311 P. (MIRA 16:5)
(Nuclear counters)
f. .

SMOLYAN, G.L.
Universal decimal classification of literature. Atom.energ. 13
no.6&620-623 D 162. (MIRA 15:12)
(Classification, Decimal)

NOVIKOV, Vasiliy Vasillyevich; ZUBOVSKIY, Leonid Isaakovich;
PRAMNEK, German Fritsevich; KOGAN, Valentina Solomonovna;
KLYKOV, Semen IvPnovich; NAUMOV, Pavel Alekseyevich;
YEMELIYANOV, Gennadiy Alekseyevich; VORONIN, Nik6lay
Isidorovich; SERGEYCHUK, K.Ya., red.; GRIGORIYEV, B.S., red.;
FORTUSHENKO, A.D., red.; NOVIKOV, V.V., otv. red.; SMOLYAN,
red.; MARKOCH, K.G., tekhn. red.
[Manual on electric communications; telegraphy) Inzhenerno-
tekhnicheskii spravochnik po elektrosviazi; telegrafiia.
[By] V.V.Novikov i dr. Moskva, Sviazlizdat, 1963. 654 P.
(MIRA 16:5)
(Telecommunication-Handbooks, manuals, etc.)
(Telegraph--Handbooks, manuals, etc.)

GORDEYEV, I.V.; KNOILSHEX, D.A.; tIAU,;ILEV, A,V.; SMOI-SAN, G.L.,
red . ; POPOV A, Yu , ',,- . , to, k I m. red .
[Constants in nuclear pIT.-dcs] IAderno-fizichesrkie konstnnty;
,;priwoc~milc. Moskva, Gosatomizdat, 1963. 507 p.
(MIDA 16:12)
(Nuclear physics)

iu-i-AYEVSKIY, N.A., red.; LF-i3EDINSKIY, A.V., red.; S,11OLYAN, G.L., red.
I.testorative processes in radiation lesions; collection of
articles] VosstanovitelInye protsessy pr-1 radiatsiomiykh po-
razheniiakh; sbornik statei. Moskva, Atoydzdat, 1964. 243 p.
(MIRA 17:5)
1. Deystvitellr*rye chleny AMN SSSR (for Krayevskiy, Lebedinskiy).

V-fr'SfW. Aleksarid- Dani-,i-chap L I-, l' te ]"1 -17.. - . '' 7'!"i , I- ,
:, E. rd . -,- - I r
(Thi-,nry of linear Teo---~.a 'ine-nykh usk,)-'-
~ -L I I
teiei. 'Poskliti) '~nmizdat 119651. 306 P. (1,11;tk m-1"
F I

USSR/ Organic Chemistry - Synthetic organic chemistry E-2
Abs Jour Referat Zhvr - Khimiya, No 4, 1957, 11632
Author
7-
Zil'berman Ye. N., Suvorova S.N., Rmol
Title On Preparation of Adipic Acid by Oxidation of Cyclochexanol with
Nitric Acid
Orig Pub Zh. prikl. khimii, 1956, 29, No 4, 621-627
Abstract Studied was the effect upon the reaction of oxidation of cyclohexanol
M, by the action of nitric acid., to adipic acid (II), of catalysts
(CT), duration of reaction, concentration of ENO and the presence
1
therein of organic acids. Maximum yield of 11 8
-83%; minimum yield
of by-products: glutaric (111) (5.6%), succinic (IV) (3.9%), oxalic
(v) (4.2%) acids, is obtained with HNO concentration of 40-50%.
With decreasing concentration of HD
103 4ield of II decreases and that
of III and IV increases; with 5-10% HNO the main reaction product is
3
III. In presence of CT (NH4VO
31 CUC03, Bi(NO3)3"'cj-'12 0 and NH4VO
3
CuC0 (1:3) yield of II increases and that of IV decreases.
3 M4V03
inhibites formation of V. In the presence of CuCO 3 formation of III
Card 1/2

- - .. , ., .: , -~a_-,~-,.~~ .". ;

SOV/81 ~59-8 ~284 30
Tr-anslation frcm? Referativxnyyy zhurmal, Khlmlya, 1959, Nr ~, P 406 (USSR)
AUTHORS Smolvan., :Z.S., Ku_-jn4mqya,__N1.:h,, Pyr~yaicwa., ~PS,.
TIME.- The Low-Temm9rature Chlorlra~ion of_jtthai~ejin the Presenoe of lhltlat.*crs
PERIODICAL- Tr. po khimli i kh1m. t8khnol.,, 1958, NT., 1, pp 187 - 189
ABSTRACT- It has been shown that- the chlor-Ination of ethane at temperatures Of
65 - 700C In a mediur. of C,-"Ih Cont;5.~-n-Lng about 1 mol. %-of din4.-.:1l_= vf
the azolsobutyric asid benzoy! -p=roxide (1-7. an dimethylpercar-bonate
C .1 ba a&
(III), leads to the formac.,0- if, C H 01 and -Lychlorosubstultu-,5d etian...
" _' - -~-'2_ J~
1, 11 and. III Play the role of rsac-t_~on initiatc7s formIng active radicals
in the temperature rapg,-~ !_ndl wh-', oh stax-, th-A devsIaDment of the Shain
process. The co-mrsrsian of _~thaxn,~ Ln the rf i-nitiallons a+~ a 1-atlo
of Cl2 C21'6 = I 2.-r about and at a ratloo of 1- g 1 ~7 It iz 6096,
I! Is an init-latlor, of, ac--tlon -p-r-c-luAng the. largest quan-1-
ty of C2F_5C1. 'Em diagra-m o'- , a laboratory ~-..!:-allalllon for shlorl-na:--lon is
presented,
Card 1/1 O~ Chernatzo-~r

20-119-1-27/52
The Physical and Chemical Investigation of Several Systems Containing Tri-
ethyl-Aluminum and Its Derivatives
complex Al(C 2H 5)2 H-.C9H7N ~nd the complex Al(C 2H5)2H .2C 2H7N
with considerable electric conducting power. Ethoxy-diethyl-
-aluminum does not form complexes with quinoline. In the course
of the investigation also the complex compound Al(C H I )2Br.C9H7N
not described as yet was eliminated. The potentiomeG C
titration confirmed the results obtained potentiometrically,
the sudden modification of the electromotive force in the
singular points being remarkably more distinctly marked here
than the peaks of the electric conductivity. Two diagrams
show the curves of the conductometric and potentiometric
titration of a mixture of Al(c 2H 5)3 , Al(c2H 5)2 Br, Al (C2H5)2 H
and Al(C H 5 )2 OC H The-course of these curves is briefly
explaineg. In Q*titration of the equimolecular mixture
Al(C2H ) Cl + AlC 2H Cl a conductometric investigation of
m;032
this mKiure was I sible. The W esent paper is also im-
portant from the point of view of an eventually possible
quick and reliable determination of the active triethyl-
-aluminum for the estimation of the relation between catalyst
Card 2/3 and the second catalyst in the production of the polyalkanes.

S~-OLYAV:, Z.S., Cand ',hem Sci -- (di,;~~) "InitiaLed cidorinaTion
andl dehydrochlorintAon as an indusurial re~nod for obtaini.,;g
--ono:.iers.l( Gorl?iy, .191A, lb pp ("in of :~' ' - lion USSR.
- - -L!~C:Icau
Gorlkiv St,3te Univ -im N.I. Lobacl~evskiy) 1,,0 cinn-es (~:,,L, 2t-59, 12Q
- 23 -

SOV/80 - 3 33/47
AUTHORS Berezin, I, V, Ve.T~ , Suv-Drova, -S,N Smolyan, Z.S. and
Emanuel 1 , N ~ 101, ----------------------
TITLE The Oxida7-"on of a MI-Ixturv Cyclohexane and Cyclohexanol tc,

Adipic A~,--,d 10kislen'ye ---mesi
tsiklogeksans i tsiklogeksanola v
adipi,nc-vuyu kislotu)
PERIODICAL~ Zhurnal prikladnoy khimii, 1959, Vol 32, Nr 4, pp 888-892 (USSR)
ABSTRACT- Production of monomers for plastics and synthetic fibers is one
of the import-an-~. "asks of modern chemistry. The utilization
o-f various waste materialz can contribute to the solution of this
task, One of --hese waste materials is the mixture of cyclohexane,
80 rflol,%, and cyclohexanol, 20 mol.%. The authors studied the
kinetics of the oxidation of this mixture, called "anol head",
w
'th an aifn of obtaining cyclohexane and adipic acid. The oxidation
was --arrLed cu~ in an autoclave at a pressure of 20 atm by mole-
-ular oxyCen a" temperatures of 130 and 1500C. Kinetic curves of
c--f the reaction nroducts were obtained and the
"bil'tv
nossL of nroducin- adi-~)ic acid by oxidiz-~ng the "ancl head"
was rroven. it was shown that some oeculiar-ities in the oxidation
Card 1/2 ne-izs were deTermine6 whoily by the concentration of cyciohezanol

SOVeo-32 -4-53/47
The Oxi~nticn of a Mixture c,,` and Cyclshexanoi -n-c A-414 A
in the "an-D~ heal", The orocess of oxidizin- "anol head" is tc
carr-,ed cut ;v--~h continuou-s r~~;Ticval of adipic ac-io obtained in
order -6o ~-,;q bu-,-n-.n-- intr. lower dicarboxyilc arids, and
h c 1) r r) c E,- r P hy -q .- q u i r,~ ~onrinious oharacter,
Therf~ are L;-~* g.--aph;5 an" 7 Soviet references,
SUBMITTED: Nc-Vem-cin-r 1;
Card 21*11,

C ( i
SOV/'130--.;-?- 4-35/47
AUTHCRS-, Freyd~~tn, L.-fL'h,, Sha-rf, V_Z_ and Smolyan, Z_S,
TITLE- On the C2mpo5it1-_.n of the Products of Dehydrogenation of Cyclo-
hexanol. on a Zinc Catalyst and on the Transformation of the
Obtained Vat Res~due Into Cyclohexanone (0 sostave produktov
deCidrirovaniya tsi-klo-eksanola na ts-Lnkovom katalizatore _J o
prevrashchenii poluchayushcheg-osya kubovogo ostatka v tsiklogek-
sanon)
PERIODICAL; Zhurnal nrikladnoy khimii, 1-959, Vol 32, Nr 4, Pp 901-905 (USSR)
ABSTRACT! The auth;)rs s+udied the composition of the products obtained in
the industrial process of dehydrogenation of cyclohexanol on a
zinc catalyst and found oat that the yield of the latter amounted
to 80 or 85-P, The amount of cyclohexanol which did not react
was 10 +0 15~'Q, In addition to these, in the products of the re-
action were discovered ~he following substances,. cyclohexene in
an amount of 0.3 to 0,5%, water - 0.1 to 0,2%, phenol - o.1 to
0.15%, cyclohexyl ether - 0,02 to 0.03%, and cyclohexylidencyclo-
hexanone-2 in an amount of 0.5 to 1%, The latter constitutes
Card 1/2 about 'V16 of the vat waste which can be transformed into

S/595/6o/ooo/ooo/ooi/ol4
E075/E435
AUTHORS: Topchiyev, A.V., Tolchinskiy, I.M., Krentsell, B.A,,
Smolyan, Z.S.
TITLE: Polymerization of olefins for the production of
intermediates for plastic masses and synthetic fibres
SOURCE: Vsesoyuznoye soveshchaniye po khimicheskoy
pererabotke neftyanykh uglevodorodov v poluprodukzy
dlya sinteza volokon i plasticheskikh mass. Baku, 1957.,
Baku, Izd-vo AN Azerb. SSR, 1960. 37-49
TEXT: A description is given of a method for the polymerization
of propylene using triethylaluminium in combination with titanium
tetrachloride as catalyst. Purified propylene was passed into a
0.5 litre glass reactor containing a solution of the catalyst in
pet.ether, b.pt. 85 to 1150C. The reactor was fitted with a
thermostatic jacket and a fast stirrer. Experiments under low
pressure (4 to 6 atm) were carried out in a stainless steel
reactor fitted with a paddle stirrer. The optimum temperature
for the polymerizations was found to be 50*C. Results of the
polymerization at atmospheric pressure are listed in Table 4.
Another catalyst - triisobutylaluminium - was also used
Card 1/4

S/595/60/000/000/001/014
Polymerization of olefins E075/E435
successfully. Triethylaluminium is synthetized from Al turnings
(99.5% purity) and ethylbromide with manganese chloride acting as
a flux. The active ethyl groups in the product are determined by
potentiometric titration with quinoline in dioxane solution
(A.I.Grayevskiy9s method). Quinoline forms a complex only with
the active constituents, i.e. Al(C2H5)3, Al(C2H5)2Br and
Al(C2H5)2H. This mixture can be used successfully as a catalyst,
Approximate composition of the product is: Al 17 to 20% wt.
Br 13 to 20'A wt, active ethyl groups 55 to 65% wt. TiC14 used
had a density of 1-70 to 1-72~ Dried pet.ether and "white spirit"
were used as catalyst solvents. The prepared polymer is washed
with absolute alcohol, 0.5% aqueous HN03 and then with 30% aqueous
alcohol solution. It is dried at 60 to 700C. The high molecular
weight components are separated by fractional precipitation
(acetone added to toluene solution). Experiments with diffe-rr=nt.
batches of catalysts and different molar ratios of catalyst and
cocatalyst have shown that the optimum ratio is of the order of
8 moles of Al(C2H 5)3 to 1 mole of TiC14- Analogous results are
obtdined for trilsobutylaluminium and lithium hydride,
Investigation of catalyst consumption in relatiOT) t0 ItS
Card 2/4

S/595/60/000/000/001/0i4
Polymerization of olefins E075/E435
concentration in the solvent during reaction showed that the b-ss'
concentration is approximately 4% wt. In conclusion, it is
mentioned that the process for the production of polypropylene --.~an
be considerably simplified by polymerizing pure condensed
propylene or the propane-propylene fraction of cracking gas,
A.A.Korotkov is mentioned in the article in connection with his
contibution in this field. There are 8 figures and 9 tables.
Card 3/4

Po-lyinerization of olefins
AI(C2f'5)3, moles
TiC14, moles
Conc, catalyst in sol, Yo wt.
Solvent
Gas passed... litxes
Unreacted propylene, litres
Conversion, %
Time of reaction, hours
Characteristic viscosity
S/595/60/000/000/001/014
E075/E435
Table 4,
Feedstock
Propylene
spirit
5
1
5
pet,.ether
70
55
21A
3~O
0.90
Tech-
Propylene
5
1
5
pet'eth'31-
68
54
20.5
3~O
o.86
Card 4/4

C!/-c 9O/GOA/OGz/02q/Oz6/XX
AUTHOR: Smclyan,, Z,- S~
TITLE. Studvirg '.h~ D-,oinposition Pro-ess of Di.chl-croethane in
the Pr~-ser.-.,7i -1 iri4.iatorz f~~r th~ F-,~rposi~ 2f Producin.-
V.in-il C.*-hl~'r-i-
PERIODICAL; tryssh-ikh -~ichebnykh zavedenly. Kh-,miya j
kh,m-,:,.hp-~kaya -khriol--i-ya. '.',0'0. Vol, 3 ~ No~ 3,
pp,,
TEXT: The au-.h~~r rc-v.~,.s ---n his study of the d;~comrlpositlcn of dicb,110ro-
ethane (DCE-) -..n ,'he ,~-osgr ~e. of -i -,. -11~iators (R - R) for the purpose of
producing vinyl -3h1r:,rid.c.: (VC), In the introduct;lcn he exrjlains the kine-
rules governi.ng the initi,ar.~-d d~,-hydr--)~;hIorinaEicn Of DCE on the basis
-moral tht~!c-rr-ms of the ,-hair, reaac~icir, the-ory. On the baiis of the
.jv 'Refs -ono the fellowing
papers by N N. Seiner, 4 1 ~i) the author ment-
s-,herBe of the Dro-es-z ment-.cnz~,j (S.
e a~ta-...hed s3hene). From th-~~ indiv-idu-
al- phases of this pri:-.ess he d~?rilres ~he kineti-c equation:
Card -,/,!

, I/xx
5A2 fj/o
Study it: Qif, Dci-,c in i,~-n Pr ~:os--j of P lorj )0

EbI 6
3 0'8
D t e th an -, in the Freserlc~ 6f
p rf Chlcr~d-.~--
jr,.Atiators for tht~ urrp-
.12 K I E ~,he ra
w
K ~qu 1 b r -nstant,
e ac

y~ rL = the equi lb-.Ium
RII
Om 6 i
%h~? cnn--n,~ rat ion. of DCE :r,
or. s ta r. t i n r e. a ')r, [D[,, Ej - th a t 9 f --,F,
A E3 s ~Iml ~, F,
-a-~U- - , t -t E-~s
t t I all allth.
a c -- I
fo nir a r'n
h,~ b a s i s q, j a r.,
Ih
p F., y f ct-tj via
E E, 2 "i E

t, h
1 13 ':~ s
E.
r,-
ard Q 'r~h~
a c-u at~ rS ~r ~Ji~

h 1

.hIc-ni-, 3Lrd
-h it 'or, rua

:-Ey

ri ~ s n. 47 F r C-r-n

-hor --,~-rcludes that,
'c~ F. s ~ s n

4 0 c; C w a s 60CO
D-E
or
H
wh e
Card 2/1-1.

601'7-3/0171~/'2'n !c-76,/xx
57 ' *,.; ,, .1
sition _,rcceso O~
Stu'aYinu!- c 16 /-B 0 50
:D 4- C111 Oro e thanc 4 'Ile presence Of
't, I nr7 v nyl C'
.)vc Of p-
ur~,.r
-Ini t ilat ors -or e S
a 0 t i v 0 as initiator. The diithor
o-F ~he
,~i_,,jcticaily
ad'
3
C_
t 11,2 r fr QM "e 1 r
V
L 1)
I y
Of
13 (,,.L "w%rl -.511
0 r .1 a ro-fri
S:i ni.
cture
that the de-rce Of DCE conversion :s I;.)
s one. The L,_ u 'U, i (,) r r e c o m. La e1tri i Sp t e o r t In e ri a, va, I a
L;-Ias neCtu tl_.at at 4000C
CI;on vessels. T!,e author stater!
exper-impnite.-l re-a
'ec
the initi, _;0 w4 th in-
a-1- .11.,j..-,c-;,hat hl_61-ier,
d-ust-r-i ally ap" J C7.'Olc,- 'rate UG k"'I'l VC are uroduced -from
authc~r recorn::le~nd _- a coln-
u-m e Ih- 1) a s i S
':' 4 deC 4 S. j -;~e -for
t;~-,ct Durati on 0-f 20 see . rfhe e ~nitiai DC_ I
"0" -'at-- de-
6 e c o_ c t o n ra e 0 'L D, C -ces n the reac
c t, .2 a s e '511 11- 1 ce a: sn E t e m e i a t e e a u;-, at !C0 'Ic.1250C. The
reac 40
a-thor fJra",y ~)roved 'hat tne V, n -s sui-able
'or -he T.-Lanufacture cf poly~-,Jny` C'hlcr-*~C -:1i'llout additi onLl purii fi. ca-
t 4cn and fcr zu-bseouent oir' :)e--chlo ro vinyl- resin . This
S S -
A 1 1 c. - C

S~Udy4-~; the DecomposJ'On `~Ccess Of S/15-',/ C//c 00 3 1"0 2"C :56
the -Presence of'
Dich-loroethane in n 6/3('58
c or a
niziatoxvs for the Purpose of zrod-,l i .,'-n-,1 C1,1 i le
of Tnit-Jal Fmiucts --or the E,-nufac-'Llure of -~olvmorsll lield at
Yart)slavil from. Son'.'eriber 29 tc Cctob.Qr 2: D. 1. :,'i-I,'rIzy1o-,,sI-.iy
0.-,C C r 4 M,.~ 11 t S a
_ C_re r
pa.rtici.jatue(l in the e f J -, -,;z r e s ,I table, and
I 7'alisn, and 3 Germn.
15 refez'ences: 7 Soviet, 2 US, r 31 -,,, 4 t j
M+R-P,:--2P,. -,. M:, R-+C.H2CI-CH2CI-RH+CH2CI-~HCI;
CH2CI-CHCI - CH2=CHCI+Cl; CH2CI-CH2CI+CI-HCH.-
--!-CH2CI- ~HCI; CI+CI+M-CI,+jN,j; CH2CI-CHCI-.CI -
CH2CI-CHC12; 2CH20-d-ICI CH2CI--~CHCI-CHCI-CH2CI;
R.+Cl-" Al - RCI+AI; R.+CH2C]-tHCI - CH2CI-CHCIP,;
P,.+CHCI=CH, - RCYI,--tHCI; Cl-LCH2=CHCI -~H-CHC12,
Card "'/,I

,;~?04
S/ U81~611000/01 61102 1/027
B l o Z/-z l C) l
A~JTHORS: Smoly-an, -', S., Kurdyumova, N. A., Pyryalova, F. S~
Low-tem,~)erature chlorination of ethane in the presence of
"ITLE:
initiators
PEIRIODICAL: Referativnyy zhurnal. ir'.-himiya, no, 18. ic)611 340, abstract
18DO (Sb. nauchn. rabot In-t Fiz.-crgan. khimii AN, BSSR,
no. 8, 1,-',60, 119-125)
~I'EXT; The possibility of a low-temperature chlorination of ethane in
CIC14 in the Dresence of initiators was Pointed out. The reaction
products are halogen derivatives of ethane with different degrees of
substitution (27-35/'~ C2 H5Cl, 65-73',~') polychloro ethanes). Practical hints
for determining the parameters of the -.n~! its realization in an
apparatus are given, Abstracter's note: Complete translationli
Y
Card 1)

50)
AUTHORS: Smolyan, ZpSz, Pyryalova, Paq.-i S/074/60/029/01/002/005
Ku- r dYa_q-v`a-j__Y. A BOO8/BOO6
"1 17
TITLE: Progress in the Field of Chlorination of Saturated Hydrocarbons
PERIODICAL: Uspekhi khimii, 1960, Vol 29, Nr 1, pp 23-54 (USSR)
ABSTRACT: This is a survey of papers published in the USSR and in foreign
countries from 1947 to 1958 on the chlorination of saturated
hydrocarbons. A marked growth of the chemical industry of the
USSR is planned for the period between 1958 and 1965. The
necessity of utilizing natural and industrial petroleum gases
as raw materials is mentioned. At present, there is a noticeable
tendency to increase the production of chlorine-substituted
hydrocarbons. Chlorine derivatives of hydrocarbons can be V/
prepared in various ways: The methods mainly applied are
1) hydrochlorination and chlorination of unsaturated hydro-
carbons, and 2) chlorination of saturated hydrocarbons.
Valuable work was done in this field by Butlerov and V.V.
Markovnikov (Ref 6), D.V.Tishchenko (Ref 8), foreign (Refs 10-
13), and Soviet scientists (Refs 14-29). N.N.Semenov and his
Card 1/5 school (Refs 14,15,16,29) are particularly noteworthy for

Progress in the Field of Chlorination of S/074/60/029/01/002/005
Saturated Hydrocarbons B008/BO06
their theoretical and experimental investigations of the
mechanism of chain reactions. By reason of their arguments-
tion,.the chain mechanism of phatoohlorinationj may be regarded
as an established fact.. Further papers on this subject are
given in references 10, 29-4T- In indua try, th8rmal chlori-
nation of paraffins in carried out at 400 - 600 . These
temperatures ensure a considerable, reaction rate. Apart from
chain reactionsp homogeneous bimolsoular reactions evidently
take place In thermal chlorination. At sufficiently high
temperatures, thermal chlorination is to a greater or lose
extent accompanied by pyrolysis of'the initial and chlorinated
products* Also, a certain amount of isomerization of inter-
mediates occurs. Thusp polychlorides are formed not only by
chlorination of the monochlovide, but also by chlorination of
compounds formed by pyrolysis or isomorisation; Investigations
of the chlorination of saturated hydrocarbons is-mainly oon-
oontratod on the chlorination reactions of methane (Refs 10,
23933934948-71). The thermal chlorination of m*thanot which
has been realized on an industrial scale in the USOR, is do-
Card 2/5 scribed in detail in reference 72. The production of mothylene

Progress in ths.Field of Chlorination of 3/074/60/029/01/002/005
Saturated Hydrocarbons. BOOS/B006
chloride in England and Eastern Germany is treated in references
73 and 74 respectively. Further chlorination methods applied
in Germany are described in references 75-78. The usual pre-
paration of carbon tetrachloride by reacting elemental chlorine
with carbondioulfide (Rafe 78-79) is replaced by the thermal
or photochemical chlorination of methane (Rof 00). A now method
developed in Romania is mentioned ). The chlorination
reactions of-the other gaseous p&r&('f;fin's'j(o*jep ethanol-propansp
butane) are lose.thoroughly investigated. The thermal chlorina-
tion of ethane is described in references 59, 8246o and the
thermal chlorination of propane and other hydrocarbon* in
references 6, 19g23p.2703#59997-104. Comparatively little has
boon published on catalytic and photochemical chlorination
process*&* Of those, the reactions of methane and ethane were
mainly Investigated. A.V.Topohiyov and V*PoAlaniya (Rof 1,05)
showed that the application of homogeneous catalysts in radical
reactions yields very interesting results. It may be soon from
publications (Refs 106.-011) that various metal chloride@ an
well an adsorbing materials mixed with crushed calcium oxide
Card 3/5 have been used an catalysts. In paraffin chlorination, the

Progress in the Field of Chlorination of
Saturated Hydrocarbons
S/074/60/029/01/002/005
BOOe/Boo6
conditions required to obtain a certain reaction product depend
not only on the type of catalyst but also on the initial
paraffin. In photochlorination of paraffins, the substitution
rate of primary and secondary hydrogen atoms is hardly
influenced by the use of catalysts such as the chlorides of
antimony, lead, aluminum, titanium, bismuth, or by iodine or
sulfur. The catalytic chlorination of methane is discussed in
references 24,25,48,109,112-138, and that of ethane and other
saturated hydrocarbons in references 11, 21, 105, 109-111, 113,
139-147. The photochlorination reaction, which involves the
splitting of a molecule into two atoms or radicals by a photon,
is of great significance for the investigation of the theory
of chain reactions. Both gaseous and liquid hydrocarbons can be
chlorinated by the photochemical method (Refs 148-174). At
present, great interest is taken in initiated chlorination.
The introduction of materials into the reaction zone,-which
are able to form a great number of radicals, facilitates the
dissociation of chlorine molecules into atoms, thus enabling
chlorination at lower temperatures. In references 7,10,106,
Card 4/5 107,110,176-18o low-temperature chlorination and the applica-

Progress in the Field of Chlorination of S/074/60/029/01/002/005
Saturated Hydrocarbons B008/BO06
tion of various types of initiators are described. The follow-
ing Soviet scientists are mentioned: B.A.Krentsell, A.V.
Topchiyev, D.Ye.Illina, V.A.NekraBova, N.I.Shuykin, Ya.P.
Choporov, O.A.Tishchenko, V.T.Vdovichenko, I.P.Galenko, I.G.
Sarashvili, R.S.Galanina, A.S.Nekrasov, A.Trifonov, A.I.
Kipriyanov, T.P.Kussner, N.A.Pokatilo, L.N.Andreyev, S.S.
Nametkin, A.G.Serebrennikova, A. Dobryanskiy, Ye.Gurevich,
A.Lemke, D.V.Tishchenko, N.I.Kursanov, R.S.Galanina, Yu.G.
Mamadaliyev, M.Efendieyevat M.M.Ketslakh, D.M.Rudkovskiy,
I.F.Suknevich, L.N. Terenin, and Y.N.Kondratfyev. There are
13 figures, 5 tables, and 180 references, 53 of which are
Soviet.
Card 5/5

S/1 90/61 /003/00 1 /0 It 1 /02C
B1 19/;B21 6
AUTHOaS: ZaQlyg,~~ Grayevsk-iy, A. 1. , Dewin, 0. 1. , Fukin, V. K. ,
lt.',atveyeva, G. 11.
TITLE: Certain rule3 ot-, oul~mi~r-ization of ethylene on heterogeneous
catalysts
PERIODICAL: Vysokontolel::~lyarnyye soyedineniya, v. 3, no. '), 1961, 81-83
TEXT: The autnor:- point out ttie fact that the catalysts of the -L.,vpe
TiCl4 plus or.-unometa-llic al~,ylatinE aSent used for the preparation of low-
pressure polyethylene rapidly lose their high activity in the course of the
ne sixth of the initial activity -within 0 min.
reaction, droppin- to o-, 30 to 4
The present 1rork attei.-lpts to find the causes for this drop in activity.
Experiments vrere carried out on polymerization of polyethYlerie on ca-Lalysts
of the systems '-'iCl + ,,, 1.-~' ( r~ 1 ( "' ~' 11 23'r, ClI-L1(.- H5)2 0C H
-1 3 - 5)2 5 2' 2 2 51
Al(C H AIC,-H and other comucunds). Pol.,--ierization v;as per-
2 5 3) e - -
0-
formed in an autocla-,re at 6-j 1. ani a -,)reas=!,e of I atm.. abs. individ-aal
Card 1/3

311901611003/00110 11/020
Certain rules on polymerization of ... 3119/;B216
catalysts .,;er(, prepared b, mL.,:iw. tlic co,-.q)uner't:_,, !incter arc,-on in i~: 2pecial
thermostat and kept therc t*or 1.9e. Cutalyst "Lctivi~',- froiyi
the initial polYmerizatic-n rate and, ;fith the jaiiic frolil tLe
polyethylene yie1j. It was found that the activit'- of all the catalyi3ts is
low at the very outset bu~.- increases to a maximum ,,.,ithin 4 to 5 i.-ALn and
then drops to practicallv zero within another 20 to 30 rain. The same effect
was observed on cLLtal,.:st.- re:!,,oved fro.-ii the argon atmosphere and placed in
P Y ri
the reaction vessel in the u'sen,.e of ethylenie for o1. i, eriza tion. The
authors found that the activity of a catalTst of -6ne ty-pe under st'udy da-
J
3~
pends on the concentration rat 0 of Ti and Ti+ (low initial activi'u-y
due to the sole presence of Ti maximum activity on reaching the optimum
0
Ti3+ : Ti4+ ratio, follo-,,ied by decrease with increasinc, Ti3+ content).
Purther experiments showed that the optimum Ti34 : Ti4T ratio and thus also
the maximum activity may be maintained constant by careful addition of a
corresponding quantity of- oki i izing a-ent (to reoxidj7e excess Ti3+).
Air and 0 , respectivel,-,,, were used a2 oxidizing ai~,ents. There are
2
figures and ~4 non-Soviet-blec references.
0 11
Card 2/3

8 0~ D
3
S/064/62/000/001/001/008
B110/B138
AUTHORS: Kotlyar, I. B., Matveyeva, G. N., Smolyan, Z. S., Fogel',
Ts. I., Gulyakov, V. M., Kudryavtsev, Ye. N.
TITLE: Continuous method of producing cyclohexanone oximes
PERIODICAL: Khimicheskaya promyshlennost', no. 1, 1962, 16 - 19
TEXT: A two-stage, continuous method of oxime production has been
developed. Not only could it be automated, it also produces better
quality oximes, and reduces losses of hydroxylamine hydrosulfate (A);
Cyclohexanone Solution of oxime in Solution of A
I I cyclohexanone
1 Stage IJ< ::2~Stage III
(NH 4)2S04 Solution of (NH 4)2S04 Oxime I
solution and A 7
Reaction I is conducted with an excess of cyclohexane, and II with an excess
of A., The formation of cyclohexanone oximes follows the reaction
Card 1/V

33h38
S/06410621000100110011008
Continuous method of producing... B11O/B138
2 0- 0 + (tm2OH) 2'H2so4 2 a NOH + H2so4 + a20, with H2so4 being
neui-~-alized by NHY Thus, the acidity indicates the stage of oxime X
formation. Preliminary experiments were carried out to determine-C, the
contact period which must elap3e before the acidity of the reacting mass
becomes constant, and the percentage extraction of A as dependent on its
concentration in the initial sulfate solution. Results:-e = 15 - 20 min;
optimum A concentration.~20 g/liter. B and the stage II sulfate solution
containing 20 - 25 g/liter of A pass continuously into oximator 1 (Fig. 1)
of stage I. The resulting mixture is passed into 2, where it is
neutralized with gaseous NH 3' The bottom layer in separator 3, spent
sulfate solution, is passed into an evaporator, the upper one (oxime
solution and B) into collector 4, and thence into stage II oximator 5,
where it is mixed with a new A solution. 11TH3 is used in the stage II
neutralizer 6. The upper oxime layer in separator 7 passes to the next
stage, and the sulfate solution passes via collector 8 into oximator 1.
A stoichiometric ratio must be preserved between the fresh amounts of B and
A fed into I and 5, There are 1 figure and 2 tables.
Card 2/$ '_1

DEVYA7YKH, G.G.; ZORIN, A.D.; DUDOROV, V.Ya.; YEZHELEVA, A.Ye.; SMOLYAN,-Z.S.
Separation of bivinyl from the butane-butylene fraction by
extractive rectification. Zhur.prikl.khim. 35 no.7tl597-1601
Jl 162. (KRA 15:8)
(Butadiene) (Butane) (Extraction (Chemistry))

- 0 - ~ , ... .
,~C, '~ :"!" . . . - . ; ~ , - . - k :-. :
J, i 'I -.--.---I.;
-1 1, . .1
R
ll,(~ r,' 7L !~rl-.-nt in t~e r-actions of h~ Lcgs~,n~t.,.-')n -;;' oleflnc-i
writh a quriternai~v carbon atom at a double bon-1. Zhur. cb. kMirr.
15 nn.5:9-,l My 165. (MTRA 1,9:6)

ago=
L 41395,66
ACC NR: SOURCE COLE: Tj-i/0274/65/0Oo/bl2/AollAOll
AUT
HOR: Smolyanets, I. F.
TITLE: A simple method for suppressing the carrier
SOURCE: Hof. zh. Radiotekhnika i elektrosvyazl, Abs. 12A84
P,:.'v SOURCE: Tr. Uchebn. in-tov svyazi, vyp. 25, 1965, 33-42
TOPIC TAGS: carrier frequency, signal distortion
ABSTRUCT: A method is given for suppressing the carrier frequency, in which the
properties of the third current harmonic are used. it is shown that in the diode
circuit with a constant amplitude of driving voltage the amplitude of the third har-
monic is proportional to some coefficient 0 3(9) which depends only on the cutoff
in3(Q).coso.
angle and is equal to )63(g) = 2/37ts
The third harmonic varies monotonically with some distortions in the interval
cosQ < + 0.5 and is equal to zero for cosQ = 0. A simpler circuit selecting the
third harmonic of the AN oscillations can then be used instead of balanced modula-
tors. '" block diagram of the device is presented, the output signal spectrum is
analyzed, and the nonlinear distortions for various modulation indices are dotermined~_
The results of the exporimental verification are given. 3 illustrations, 1 table.,
bibliography of 1, citations. L. S. ZTranslation of abstrac2t
S-uB CODE: 17, 09

.9 naucbnyy rukovodi' 11 ;
BERLOV G. A. ve
PALICHEVSKIY., Ye. I., prof., nauchft7y rukovodit~ll
Changes in-tbe perivasculj~r connective tissue of the hypertrophied
heart, Arkh. pat. no.7:41-46 161.,. (MIRA l;:4)
(HEART-DISEASES)

terial"'; i 1~?6"

.2?,! -, I --,-A!-;- , "'i . . V.
' ~ ~E , i L 1 , I'l,
"'!c I u
, Insuffir-"ency at a Y.-.-,ung Age".
Medi ts inskliy Zh-l-irnal , No. 4, 1:-.,W--2

RARANITIKOV, .4., uchastkovyy mekhanik; SIUL'YAITIMV, A.
Device for the T-41 hoist to be used for feeding materials through
windows. Na stroi. Moak. 2 no.9:26 S 159. (NM 13:2)
l.Glavny7 mekhanik stroitellnogo uchastka No.60 tresta "Stroitel",
(f.or Smol'yaninov).'Z.Stroitel'nY7 uchastok No.60 tresta "Stroitell"
(for Barannikov).
(Hoisting machinery--Equipment and supplies)

SMOL'YAIIINOV,,A.A., kand. tekhn. n2uk; MOMMS, Yu. N., kand. takhn. nauk;
. ~- I - I ANTONOV. Ye. A., inzh.
Centrifuged orestressed contact system poles reinforced by hardened
steel. Traw. stroi. 8 no. 5:16-i9 Mir 158. (HIP-A 11:7)
. (Electric lines-Poles)
(?restrassed concrete construction)

ALEKSEYEV, Aleksey Pavlovich, kand. tekhr. nauk; DISSON, Pavel
Solomonovich, inzh.; SESSA.REVSKIY, Aleksandr Hikolayevich,
inzh.; S-:OL'YA11INOV, Aleksandr Andreyevichm, kand. tekhn.
Paulk; SHUiffGUT, Vladinir Pavlovich, kand. tekhn. nauk;
SHADRIN, N.A., prof., retsenzent; GOLtSHUKH, V.V., inzh.;
ABRAGAM, S.R., inzh., red.; BOBROVA, Ye.N., tekhn. red.
[construction operations in railroad electrification]Stroitell-
nye ra-boty pri elektrifikatsii zheleznykh dorog. [By] A.P.
Alekseev i dr. Moskva, Transzheldorizdat, 1962. 287 p.
(MIRA 15:12)
(Railroads--Electrification)
Nailroads--Buildings and structures)

SMOLIYANIN*., A.-A., kand.tekhn.nauk; KMKOV, Ye.P.J. kand.tekhn.nauk;
OREL, A.A., inzh.
Prefabricated 9
14ements of the reinforced concrete foundatiom
of stationary 6ontact-.bstwork poles wilf flexible cross pieces.
Ti-udy TSNIIS no./+7:83-104 163. WIRA 16:5)
(Precast concrete construction) (Electric lines-Poles and touers)

IVANOVI P.m., kand.tekhn.riauk; SM1O-L'YA.N.111.OV,_A.A.) kand.tekh.nauk; SOLN-
TSEVA .7 V.L., kand.teIdm.nauk
Waterproofing the foundation of poles of contact networks. Transp.
stroi. 13 no.9:51-54 S 163o (HIRA 16:12)

O.YA.? ciok'Lor tekhn.nauk, prof.; FISAINKC, G.N., kand.te',rhn.nauk;
A.A., karid.feklin.naulr; SHCHERBAKOV, Ye.N., inzh.
uauses of the fonnat-lon of lor,-Itud'-nai cracks in centriftaed
supports of overhead contact systems. Transp.stroi. 15 no.10:42-
46 0 1 0,r;. (lMIPA a8.-12) ,

, - I Y.", - 7 -.,- , ~ .-: - -.)" i -~ ", - -~: ~, -, ~ ~ Z, i ~ :-~ D f *. " ;~
0-* L;C4 -- (
S - - i, - ~ 1. - 19~I .: . , ~, L - -- . - -L,
pro-cass of I-Rollint- In Rollers viith interclian6eable ihadii,"
--inepropatrovsk, 16 pp (Dnepropetrovsk etuallurSJcal InEtlzute
e D - i~. L u
im Stalin) (KL, ;e-bli, lj-,L+)

CHEKMAqEV, A.P., akademik; SPOLIYANINOV A.F., inzh.; KLIMEITKO, r.L., inzh.
Investigating pressure during rolling with variable radius rolls.
Izv. vys. ucheb. zav.; chern. met. 2 no.4:65-72 Ap '59.
(MIRA 12:8)
l.Dnepropetrovskiy metalliurgicheaki7 institut. 2.AN USSR
kfor Uhekmarev).
k1lolling Metalwork)) (Deformations (Mechanics))

S/148/60/O0O/0o6/oo,,/o1o
AUTHORS: Chekmarev, A. P., Smoltyaninov, A. F.
TITLE: The Angle of Neutral Section in Rolling With Variable Roller Radius
PERIODICAL-. Isvestiya vysshikh uchebnykh zavedeniy, Chernaya metallurgla, 1960,
No. 6, pp. 77-87
TEXT: The authors investigated two cases of rolling, i. e., rolling with
increasing and decreasing of the radius roller. The intermediate section of the
roller is described by the equation of a logarithmic spiral. An analysizr of
equations derived is presented and the value of the maximum grip angle depending
on the angle of roller tapering is given for rolling with increasing and de-
creasing roller radius. An analysis of equations is presented for the angles
of neutral section in rolling with variable radius, depending on changes in. the
friction angle when-y (tapering angle) is constant. The possible range of
application of these equations is determined. The mean value of the coefficient
of external friction can be experimentally determined by the method of inter-
mediate sections in rolling with rollers of variable radius. There are 8 sells of
graphs and 3 Soviet references.
ASSOCIATION: Dnepropetrovskiy metallurgicheskiy institut (Dnepropetrovsk Metal-
SUBMITTED: June 25, 1959. lurgical Institute)
Card 1/1

CHEKMARE-V., A. P., akademik; WLIYANIN-OV, A. F., kand. tekhn. nauk;
KLIYt&',TY,,O., P. L., kand. tekhn. nauk; ka)rt, Yu. G., inzh.
Pressure in rolling between rolls with a variable radius.
Nauch. trudy DMI no-48:167-173 162. (MIRA 15:1())
1. Akademiya nauk Ukrainskoy SSR (for Chekmarev).
(Rolling(Metalwork))

s/148/63/000/001/007/019
E193/E383
AUTHORS: Chekmarev, A.P., S!!i~~nov, A. , Klimenko, P.L.
and Lebedik, G.L.
TITLE: Roll-pressure during rolling in rolls with varying
radius
PERIODICAL: Izvestiya vysshikh uchebny1di zavedeniy, Chernaya
metallurgiyaAno. 1, 1963, 78 - 88
TEXT: The investigation reported in the present paper was
carried out on stand 330, equipped with rolls whose design is shown
in Fig. 1 (roll with varying radius). A roll of this type comprised
4 segments with constant radii (R max ~ 199-5 mm and R mi.Ln=
= 184.75 nim), joined by 4 intermediate segments with varying radii,
the tangent of the taper angle (tanq)) characterizing these segments
being 0.1, 0.2, 0.3 and 0.11. The wcperiments were conducted on
lead and steel specimens measuring, respectively, 43 x 40 and
45 x 40 mm. The roll-pressure was measured with the aid of
dynamometers mounted in the rolls and measuring the forces normal
to the roll surface. 3 dynamometers were mounted in each inter-
eAa segment in sectiorsI, II and III with one dynamometer
e
ar 175

S/148/63/000/001/007/019
Roll-pressure during rolling .... E193/S383
mounted in the neighbouring segments with constant radii (sections
IV and V); the positioning of sections I-V in and near the
segment with tan 1~ = 0.1 and 0.2 is sho'tv-n in Fig. 2; the
positioning of dynamometers in the other two segments was similar.
Setting of the rolls was such that the reduction given to the
rolled specimen in passing between sections of rolls with constant
radii (R . and R ) remained constant in each series of
min max
experiments, the reduction in the segments with R being 5 mm,
min
for the lead and 6 mm, for steel specimens. For comparison, the
roll pressure was also determined during rolling on three stands
with rolls of constant radii equal to the radii of the experimental
rolls at points at which the dynamometers were mounted in segments
with varying radii. -Experiments on lead were conducted at room
temperature and steel specimens were rolled at 1 050 0C. The
results (all of which are reproduced graphically in the form of
curves showing the distribution of roll-pressure in various
segments of the rolls) can be summarIzed as follows: 1) in
rolling under conditions of increasing reduction the roll pressure
-Cavd 2/5

S/140'/63/000/001/007/019
Roll-pressure during rolling .... P-193/E383
P increases on passing from section I to section III in each of
the intermediate segments. In the case of lead,the maximum roll
pressure for sect ons I and II , t h e s egm ent wit h tan Y = 0. 1, i s
4-5 and 7.8 icg/mm respectively, the correspondi2g figures for the
segment with tan = 0.2 being 3.8 and 7.2 kg/mm . This effect is
caused by the fact that on passing froin section I to section II, the
absolute reductin in thicImess increases (from 10-29 nim, in thecase
of lead) and so does the deformation rate; 2) the roll pressure
in section I is practically the same for all values of tan Y ;
the value of P in section II of the segment with tanY = 0.1 is
higher than in the three remainIng segments. P in section III
decreases with increasing tan 3) the conditions during rolling
of lead in segments with tan 0.3 and 0.4 are such that the
contact angle is smaller than the friction angle. The effect of
tan 4) on P during rolling of steel is less pronounced than in
the case of lead because the condition in the former cas'e are such
that tkie contact angle is practically equal to the friction anglei
4) the effect of tan Y on P is also less pronounced iduring
rolling under conditions of decreasing reduction. In this case,
Card 3/5

s/148/63/000/001/007/019
Roll-pressure during rolling .... E193/E383
the pressure exerted on t~e rolls by lead in section I is the same
for segments 'with tan q = 0.1 and 0.2; in segments with
tan W = 0.3 and 0.4 slipping takes place in section I because the
contact angle is then considerably larger than the friction angle.
P in sections II and III decreases with increasing tan I-V ;
5) owing to the geometry of the intermediate segments P the
repelling forces during rolling under conditions of decreasing red-
uction increase with increasing tan q); since the tensile stresses
also increase due to the fact that the contact angle exceeds the
friction angle, the roll pressure under these conditions should
decrease with increasing tan L~. There are 6 figures.
ASSOCIATION: Dnepropetrovskly metallurgicheskiy institut
(Dnepropetrovsk Metallurgical Institute)
SUBMITTED: August io, 1961
Card 4/5

Roll-pressure during rolling ....
fig. 1: OV-174,
s/148/63/000/001/007/019
L'193/E383
igg-al
Card 5/5

I ~1-!V't 11'. P ~ , SMOL' ~ANPII~J%r , A.. F~ I LE I i 11:1)LK , t 'I ~ L -
rAstribition of the increase in width and length during longitudinal
periodic rolling. Izv, vy3, tif-heb. zav.; chern. met. 6 no.5M3-117
F63. (RIRA 16:7)
1. Dnepropetr-ov3kiy metallurgicheskiy institut.
(Rolling (Metalwork))

E)rp(; rn.,-
VS K I Y 'n

i r, 'Erl ED 1 K, C, . L
'Orwa-d slip -ar.,-i the
t a', a v f-1,; L ha r a i s r o 111 ng w 5 t h
ohern.mei. 8 no.6:97-
(MIRA 18:8)
inst-it

88721
U
s/i,37,6o/looo/b 11/027/04,3
A006/A001
Translation from: Referativnyy zhurnal, Metallurgiya, 1960, No. 11, pp. 199-200,
# 26863
AUTHOR: Smolyaninov, A.I.
TITLE: The Structure and Properties of Copper-Lead Antifriction Pseudo-
Alloys
PERIODICAL: Tr. Rostovsk.-n./I). in-ta s.-kh. mashinostr., 1959, No. 12,
pp. 52 - 57
MCI': The structure of the Cu-Pb pseudo-alloy, applied to a surface by
electric metallizing,_represents a conglomerate of Cu and Pb particles separated
by oxides and pores. CU20 is observed in fine-dispersed diffusion-dissipated
state and in the form of eutectic formations as well; PbO is absent. Tke pores
are bordered with oxide films and are, as a rule, located along the particle
boundaries. Porosity decreases with a higher Pb content. The nature of the inter-
particle bond, the structure and the phase composition, predetermine the possibili-
ty of chemico-thermal treatment. Annealing for sintering is made in a 10%
Card 1/2

88721
S/137/160/000/011/027/043
A006/AO01
The Structure and Properties of Copper-Lead Antifriction Pseudo-Alloys
mixture of charcoal and A1203 in closed steel containers at 900 - 9_300C for 3
hours. A gray substance is not formed after annealing. Annealing improves the
physico-mechanical properties of Cu-Pb pseudo-alloys and increases the adhesion
strength with steel when using a Cu-underlayer. Wear resistance and fatigue
strength of annealed Cu-Pb pseudo-alloy with 30% Pb exceed those of 6 8_3 (B83)
babbitt and approach those of 6 pC30 (BrS30) Pb-bronze. Therefore it can be
employed for heavy loaded bearings operating under impact load.
I.A.
Translator's note: This is the full translation of the original Russian abstract.
Card 2/2

ift
5/136/60/000/009/006/oo6/xx
E071/E433
AUTHOR- Smolyaninov, AcI~
TITLE~ On ~~. _3tr_U_Ci_ii_r_6_of Lead Coatings Obtained by Spraying
PERIODICAL~ Tsvetnyye nietally 1960 No.9, pp,46-48
TEXT,-. Some results of an investigation of the structure and
propertie5 of sprayed lead are reported.. X-ray analysis (Fig,l)
of the sprayed lead coating did not show the presence of lead
oxide (PbO), the latter was determined by the acetate method
(Ref,3) and was found to be 1.47% corresponding to 0.1lI'D of
oxygen, The saturation of lead by oxygen apparently takes place
by the formation of lead oxide film on the surface of lead
particles, suspended in the air stream whi.ch prevent further
pact of particles with the base, the oxi-de f ilm
oxidation On im,
-is bi--)',en and its splinters are mixed with the liquid mass on
crystallization of which they remain inside the particles in the
form of fine yellow inclusions (Fig,2). This was shown by
heating sprayed lead at 350 to 370*.C for 60 minutes in nitroSen
whereupon ox.Lde particles floated on to the surfa..~e- forming on
SOlIdIfICEIL1.011 a powdery bright yellow film, X-ray analysis
Card 1/2

S/136/60/000/009/006/oo6/xx
E071/E433
On the Structure of Lead Coatings Obtained by Spraying
indiz-.ated that the oxide is present in the rhombie modxfication,
A rharacteristic feature of the structure of mEtall.ized lead is
its porosity, The volume of communicating pores was determined
by the oil absorption method and was found to be 6.5% of the volume
of the specimen, The degree of adhesion of the coating was
determined by measuring the strength of the sprayed layer in the
direction perpendicular to the plane of fall of lead par--.Lcles.
Specimens were prepared by continuous and intermittent spraying. V/
In the latter case, the sprayed surface was treated either with -
ethyl al.--ohol or ifith 1% suspension of spindle oil in alcohol and
dried in a stream of air before resuming spraying
The strength of -.continuously sprayed coatings was 42 to 52 k~/--IM2'
with an intermediate alcohol treatment 8 to 12 kg/cm2 and with
oi.1 treatment 6 to 9 kg/cm2_ The other ropertie.5 determined were-:
modulus of normal elasTi-city - 1000 kg/mm~ and heat
conductivity -- 0.06 cal/r-m degree sec- The ratio Of Lhese two
properties of --ast and spray,~d lecid are 1.6 and 1.53 respectively,
In comparison with other metals these ratios for lead are Small,
There are 2 figures and 3 Soviet referen-es,
Card 2/2

SMOLYANINOV, A. I., Cand Tech Sci -- "Structure and properties
L
o'L copper-lead pseudoalloyst/ obtained by means of electro-
metallization." Novocherkassk, 1961. (Min of Higher and
Sec Spec Ed RSFSR. Novocherkassk Order of Labor Red Banner
Polytech Inst im S. Ordzhonikidze) (KL, 8-61, 249)
- 312 -

RUSIN, P.I.; GOFMAN, L.A.; SMOLYANINOV, A.I.; SHAPKIN, V.M.
Device for the control of the hardness of malleable cast iron
parts. Lit. vroizv. no.8:38-39 Ag 162. (MIRA 15:11)
(C,qst iron--Testing) (Hardness-Testin.-)

SMOL'YANINOV, A.S.
Sarcoma of the appendix of the testicle. Ehirurglia no.9:67-68 3 '53.
(MLRA 6:11)
1. Iz TSentralluoy poliklimiki No.l. (Testiole--%more)

USSR/Human and Animal Fhysiology - Excretion. v-6
Abs Jour Ref Zhur - Biol., No 2Y 1.958, 8736
Author A.S. Smol'yaninov
Inst
Title The State of the White Blood Cells during Renal Colic
Orig Pub Sovetskaya Meditsina, 1957, No 3, 61-63
Abstract A study was made of the state of the white blood cells in
50 patients with renal colic without injection of the uri-
nary tracts. Leukocytosis was within norml limits in
only 6 patients. Among the remaining patients leukocyto-
sis increased in varying degrees including hyperleukocyto-
sis. After the remission of the attack Of pain leukocyto-
sis decreased rapidly. Tn the presence of renal colic
leukocytosis can result from a pain factor as well as from
renal pelvic reflex with the entry of urinary substances
into the blood. Leukocytosis cannot serve as a criterion
in the differential diagnosis of appendicitis and renal
colic.
Card 1/1

SMOL'YANINOV, A.Ys.
t- I,r',,,--.,-.~~...,.--,-~-.;.--~- -
The TF-7 passenger diesel locomotive. Zhel.dor.tranap-39 no.1:15-19
Ja '57. (XLRA 10:2)
1.ZamestitelO glarnogo konstruktora, Khar3kovskogo 98woda transport-
nogo mashinostroyeniya.
(Diesel locomotives)

KIRNARSKIY, A.!~. ; ..I-YA211 I..NIO-V _-A.Ye.
New TE10 freigobt diesel locomotive. Zhel.dor.tranap. 41 no.3:50-54
Mr '59. (14111r. 12:6)
1. Glavnyv konstruktor Khartkovskogo zavoda transportnogn manhinostro-
yoniya (for Kirnarskiy). 01. Zariestital, gla-vnr)l-, I-onstruktore Khar'kov-
sk-ogn zavocla transportnogo mashinostroyeniyR (for Smollyaninov).
Oiesel locomotives)

-UTIZAt'OV, Ye.A., 'inh.; DOPd-l~ijU., Yu.1., inzh.; ',7.,SLAVS1,IY, Ye.G.,
inzh.; KUSHNER,, B.I., inzh.; PLUTS11EH-SAR1,110, YuX.. inzh.;
SMOL'YININOV, _A.YSt-x 1UNGE
--inzh.; SPIVAK, Ya.L., inzh.; STI
-tPSHT-EYN, A.S., inzh.; SAW-MV, A.G., inzh.,
red.; USENKO, L.A., tekhn. red.
[The TE10 diesel freight locomotive] Gnizovoi teplovoz TE10.
Voskva, Tra-nszheldorizdat., 1962. 171 p. (MJRA 15: 10)
(Diesel locomotives)

Si,:(',L ~.'WIIVTOVp:I,Y&,-- -
T*,.r, Tr,12 fre4ght locomoti-ve. Biull Ahi , --ekon.- I r-f crm,
162~ -15
L
(Diesel locomotives)

SMOLIYANINOV I I _ starshiv nauchnyy sotrudnik, kand.sellskokhoz.nauk
__Q
Characteristics of the influence of the Siberian pine on the
principal propertieW-vf taiga soils (Western Sayan Mountains).
Trudy VSNIPILesdrev 'no.5262-70 162. (MIRA 16:5)
1. Institut lesa i drevesiny Sibirskogo otdoleniya AN SqSR.
(Sayan Mountains-Forest influences)
(Sayan Mountains-Pine)

SMOL'YANIN-TI., I.!.
Ri--ti,ablic.-wide semiriar of the Ukraiatan Scientific 4search
institute of Forestr,
.r, Lumbering, and Land Improvement through
Affortstation. Pochvovedenie no.1.1110 Ja 164.
(MIR-A 17-3)

i van I vano vich; I V A , 'L VOG
doll(tor sellkhc,--. nauk, nau~--hri. red.
t --ricultural che::.i*ozrv or. -ua--,i for rokh-'
in~Lia na strazhe liloskva, lzd--lo "Znariie,"
196/,. 39 1). (T%ovoe v zhimi, natike, tehhrl.41ke. V Seriia:
3ellskoe khoziaistvo, no.18) ll;iA 17:10)

f
d L:
j
geo ~r
17

AUTHORS~
S/020/60/133/04/28/031
Boo4/'BO56
Khitrov,, V- A- Shatalova~ V, I., smol7yaninov, I~ S.,
Sadovskaya'. YU. I.
TITLE,, The Problem of the Influence of Temperature on the Rate of
Corrosion of Metals in Acid Media
PERIODICAL,- Doklady Akademii nauk SSSR, 1960~ Vol~ 133, No. 4,
pp., 886 - 888
TEXT- The authors investigated the influence exerted by temperature on
the rate of corrosion of Armco lron,~'~nickei,--,~zinc, and --cladmium in
1 N H 2 so4and I N HC1, and found a linear cou~7e-ior the function
log K .-. f(1/T` according to the Arrhenius equation (Fig. 1). For the
~L 11
corrosion of alumlinum in -1 N HC1, this function is, however, no longer
linear; corrosion increases with rising temperature more quickly than
would zorrespond to the Arrhenius equation (Fig. 2)~ This is explained by
the destructxon of the oxide layer of Al. In the Qase of commercial
aluminum of the type Al 2, it was observed in 35 N H 2so4 that the
Card 1/2

The Pro';Iem of tne Influence of Temperature S/02o/60/133/04/28/031
on the Rate of Corrosion of Metals in Acid B004/BO56
Media
corrosion rate obeys the Arrhenius equation up to 50 - 600C, attains
a maximum value at 700C, after which it decreases (Fig. 3). This is
explained by increasing passivation of the Al. A similar behavior is
shown by copper in 1 N HC! and 1 N H2so4 (Fig. 3). Slight deviations from
linearity are found in zinc and lead in both acids (Fig,, 4). ~hls is
assumed to be caused by the fact that the rate of the diffusion processes
increases more slowly with rising temperature than the rate of chemical
processes. The authors mention a paper by N. D. Tomashov and T. V~
Matveyeva (Ref, 7), There are 4 figures and 8 references -~ 7 Soviet and
1 British.
ASSOCIATION, Voronezhskiy gosudarstvennyy pedagogicheskiy institut
(Voronezh State Pedagogical Institute)
PRESENTED1 Mar~.h 10, 1960 by V~ II Spitsyn, Academician
SUBMITTEDj March 9, 1960
Card 212

SMOLIYANINOV, I PUTROV, V.A.
Effect of the temlerature on
electrode potentials of metals
Lead in a hydrochloric acid
i khim.tekh. 5 no.3:413-417
the corrosion resistance and
in acidic media. Part 7:
solution. Izv.vys.ucheb.zav.;khim.
162. (KMA 15:7)
1. Voronezhskiy gosudarstvennyy pedagogicheskiy institut,
kafedra khimii.
(Lead-Corrosion) (Electromotive force)

KHITROV, V.A.; SMOL'YANINOV, I.S.; SHATALOVA, V.I.; SADOVSKAYA, YU.I.
Effect of temperature on the corrosion resistance of some metals
in sulfuric and hydrochloric acid solutions of varions concen-
trations. Zhur.fiz.khim. 36 no.5:1058-1060 My 162.
NIRA 15;8)
1. Voronezhskiy gosudarstvennyy pedagogicheskiy institut.
(Metals--Corrosion)

SMO.LIYANINOI/I I.S.., KIIITROV, V.A.
Effect of temperature on the corrosion resistance and on the
electrode potentials of metals in acid media. Part 4: Copper
in sulfuric acid solutions. Izv.vys.ucheb.zav.fkhJ-m.i khim.tekh.
6 no.1:63-67 163. (KIRA 16:6)
1. Voronezhskiy pedagogicheskiy institut, kafedra khimii.
(Copper--Corrosion) (Electromotive force)

KIIITROV, V.A.; SMOLIYANINOV, I.S.
Effect of temperature on the arlr: elec~r.-A*6
potentials oC mftals in acid rried--ia, Part 3% Z~i,.ir. 'fiz. khirp.
37 no,11.2301-2390' 1-1 163. (KIRA 17:2)
1, ".Iar~~nezhskiy peringogicheski.-

c:' te-mu~-rature cn tl~e corrrc~sicn res-'s-ance an,--
potential's -:)f m;-rais acid media. ParL 5: Copper hydro-
ch~oric acid sohitiono. Jvv.vys.ucheb.zav,;khim. 1 kh-im. tekh.
7 no. 1-51-55 (MIRA 17: 5)
I
A.. Vor,-,n(jzhski,,r ~nstUut kifedlra Khim~i.

;xCESSION NH: AP40j4716 5/0064/64/000/004/0307/0310
AUMOR: MAtrov, V. A.; Zadorozhny*y, V. Po; Smollyaainovp I* So; Zhukova# Go Po;
Dugin, No A.; Konyayev,, B. Ya.
TITLE: Use of bottoms from SK production as acid corrosion inhibitors.
SOURCE: Khimicheskaya promy*shlennost', no. 4, 1964, 307-310
C TAGS: corrosion inhibitor, rubber production byproduct, still bottom# SK
TOPI
rubber production., saturikted alcoholp unsaturated alcohol, saturated hydrocarbon,
unsaturated hydrocarbon, xztpolymerisable hydrocarbon, acid corrosion inhibitor,
inhibition mechanism, chemosorption
ABSTRACT: The effectiveness of various cuts of still bottoms from rubber produc-
tion as acid corrosion inhibitors for steels and copper was investigated. Three
mixtures were examined: (1) foam reagents (PR) obtained from still bottoms
remaining after distillation of technical butanol and comprising 25-35% saturated
and unsaturated C6 and C8 alcohols, 3-5% butanol, 25-30% hydrocarbons, 30-35% heavy
ends and traces of phenols and aldehydes; (2) still bottoms (KO) comprising low
boiling saturated and unsaturated hydrocarbons separated from divinyl (35-45C
Card
1/3

AC.CESSION NR: AP4034716
' SUB CODE: MT
P OC
110 FW sav: 008 OMR: 000
I
Card 3/3 -

SMOL'YANINOV, I.S.
Corrosive and electrochemical behavior of copper in acid
media. Izv.Vor.gos.ped.inst. 47:18-40 164.
Kinetics of copper corrosion in sulfuric and hydrochloric
--cid solutions. Ibid.:41-45
Corrosion behavior of lead in sulfuric acid solutions at
tenipera~ures of 0 - 800 C. Ibid-:91-9/5
(MIRA 18:11)

KRWROVI, V.A.; SMMIYAJPINOV?- LS-I-m,
Effect of tonpomture m the carrosion reDirtance an,.'
eloatrodo potentials of -atals In acid codias Phrt 91
Cact~dua. Izv.Vorgos.pod.iwt. 47076-66 964o (mim 2,8:n)

KHITROV, V.A.; ZADOR(rLMYY, V.P.; SMOL'YANINOV, I.S.; SHATALOVA, V.I.-.
DUGIN, N.A.
Activation energy and temperature dependence of the rate of
the corrosion of metals dissolving in noncyidizing acids.
Izv.Vor.gos.ped.inst. 47:78-90 164.
(MlRA 18,11)

I.S., KIRTFOV, V.A.; KONYAYEV, B.Ya.
I s~&s t'rom the c, etic rubber as retarders
Nla t - -L III
*trc acid. lzv.Vor,gos,-,,e'.ins*
of copper corrosion in r L - . a
47:14~ 147 164. (MIRA 18:11)

3ec 6 Vol 13/1 Internal Yed. Jan 59
-13i. I PE W111TE. BLOOD PICH It E IN I(ENAL COLIC
a n i n o v K. S. %joscow - SOVETSK. MED. 19-57. 3 N I.F,3)
-picturp vias studied in 50 patients: with renal volic, -lue in 3d ca
1 he Ses tO
r-r-, -impacted Calculi. in I I to excretion of salts, and in one tr, a runal tumour.
normal ill 1. illode rat 6.v inc rvusod (8, 5 kit) -I U. 000 pv r '.11. 111:11.
in 11, more markedly increased (10,100-11,800) in 11, ind greatly invreasvd
(12,000-19,800) in 19 patients. An increase inWI1C with segmentelf and Stafffluclei,
the appearance (,f toxic granulations in the neutrophils, lymphopunia, and some-
titne-s -~ornplete disappearance of ensinophils were observed at the sanic, tim(% No
import,mvp is attached to levencytosis in the differential diagnosis ht,tw,vn avitte
nppi,ndivitim nnd rennl colic. Leueocytosis in renal colic if; ba.~ed on 2 favtm*.~ -
pain and the development of a urethrnl-renal reflex.
Aprosina- Nlosc,iw (S)
7-

SIML I ... A.
"Metho,ls of Traprovint.; Lhe Astralchan-S.Lviental Cattle of Vorone3hskaya Oblast."
Dr A,-,r Sci, Noscow Vcterinarr Acadev~v, !-1in UZ;her EkItication, Voronezh, 1955. (KL, No 16,
Apr 5.-,)
SO: Sum. No. 704, 1 Nov 55 - Survey of Scienti-fic and TecMical Dissertations Defended
at USSR Higher -Educational Institutions (16).

I
FINOGENOV, V.N.;'iPODSHIBYAKIN, YU.V.; SHOLIYANINOV, M.K.
i
Fluoroplast bushin%s. Mashinostroitell no.3:35 Mr 163. -4)
()CM 16. .
(Fluoroplast)

., riau,:-hr... :oir,
BELOUS, i.,Kh, st
K UY
NAitOVSKIlf, lllh~'D A EVAY I.V-l
U
!X,',OVILf)V, V i
, i 4 1 KOV A GOiC, U KI I'll. , Y;~ '; a ~~AGOI -.3 K ly , I.I.
A A~
P I VE I f bAl',XT(JV, G. Ye. GEBLE', , I SVC) LYAN PNOV
-:0LYNNINOVA, I : YUSHIP, V~!., LOY
~,-EZAFOV, 1,114. V-A L 1617%. ~ T , A.'.:, S111:01M,
A F.~ CAIQ.-ASH, A,A,; Ui"KGIT POPODII,', L,V,; -,"ClIKOV,
L, MICIIIII 1,. 3]~AKHCIV F ~-ed. SET AKOVSKAYA,
T
ZI-.elezorud-
i r --n ircit -'e. ba~-'
3--LjirskiD~?2 otd-
-L';,A 1-7 ~ 12)
SSR
In::titu-t geo-
S
-.'Jibirsko-o
UT.
f' r Ka--ay-.-k~ ;.',a vi Klya c v y
Sen-'erzon), InoL-Atut
go_-rnD,7,, ~-dela Akaye,:) Fc-,; t-- 3 a b I gec. c~eskoye
z~ FA
woravleirLye El~e, logii i ck' rany nedr SSE~~ (fa-r
,,bin 3erdr-l",r-, G-~rTlkhir,, I.I.-gor-akiy. Fiven
CTI riex-~ f---=-Cl)

v
s-, c, I y an nov Srcl,
ne ral
i.,:h i n
n:;:-
(for
J;
Gai rM~-- -7. J'n
aykov,, 'v
r r s ge,
Shakhov) -

S
S VE SRUMB
&HYAKOV, Ivan Haksimovich; Prinimali uchastiye: BEDAREV, G.; T , N.;
DOBROVOLISKIT, V.; K-AFLaN, S.; KOMZA, G.; KORCLEV, L.; KUZGINOV, K.-,
PETROV, V.; SUMAKOV, M.; SHOLYANINOV, N.; USHAKOV, I.; USHMOV, G.j
2AYCHIK, M.I., prof., dokt'&i~'te~i~.'nauk, nauchnyy red.; KOLOMIYTSNVA,
0.1., red.; ROZEN, E.A., tekhn.red.
[The story of the tractor] Povest' o traktore. Moskva, Izd-vo
*;Sovetakaia Rosaiia.1 1960. 318 P. (MIRA 13:12)
(Tractors)

SMOLIYAMINOV, N.A.
Belijkha and Eukuka denosits in Transbaikalia; mineral and chemical
characteristics. Trud MGRI 37:20-31 '61~ (MIR'. 15-1)
y
(Transbaikalia--Wolframite)