SCIENTIFIC ABSTRACT SMIRNOV, N.V. - SMIRNOV, O.K.

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SCIENTIFIC ABSTRACT
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Ol rr~m rerllfAc.-dil a z-asa.. m a t-eiii. ob.2 SO* ",:athematic-s in t,,e USjR, 1917-1947 edi.t--a Eurosh, A. G. , ilarlour'llevich, &. 1., Raz~aeevskiy, P. K. .7-aad, 1111,18) -14 . SMIRNOV, N. V. tIon the Estimation of the Maximum Term in a Series of Observations." Dokl. ANSSSR, 33, No-5, 194i-rr-3-4~- I Steklov Math. Inst., AS USSR .-Lu u Pribiizh~-,Aye zalkonov raspredielc!,iya s, vel~chi; :,o ennir'; che S,-, , dia!.~i~-,,.. "spe'-Iij 10 (1-4'-), SG: -Une 105R, jc~17-11~~,tr( edited by Yurosh, -A. G., I- A. I., RashevsIdy, P. K. I::osco-,,--ILe,--ingrad, Ic,43 1. SMIRNOV, N. V. 2. USSR (600) 4. Physics and Matheumtics 7. Application of Mathematical Statistics to Experimental Work, V. I. Romanovskiy. (Moscow, State Technical Press, 1947). Reviewed by N. V. Smirnov., Sov. Kniga, No. 5, 1948. 9. 4W Report u-3o8l, 16 jan. 1953, Unclassified. PA 174T31 USSR/Mathematics - Cbance Quantities n SOP 50 "Constructing the Confidence Region for a Density of Distribution of a Random Sample.." N. V. Sairnov "Dok Ak Nauk SSSR" Vol LXXIV, No 2, pp 189~-191 Considers n independent observations of chance quaittity X, distributed vith continuous density f (x). Ordinary method of approximating unknown f(x) according to given selection on Interval (a,, b) is to construct "histograze' of frequencies f,*(x). Submitted 14 Jul 50 by Acad A. N. KOIW- g0rov. USSR/Mathematics - Statistics Mathis- Jtll/Aug '51 matical "The Works of N. V. Smirnov on the Study of the Properties of Variational Series and on the Non- parametric Pr.oblems of Mathematical Statistics," A. N. Kolmogorov, A. Y. Xhinchin "Uspekh Matemat Nauk" Vol VI, No 4 (44), pp 190- 192 Until recently in math statistics one was limited almost exclusively io problems of detg the para- meters. For example, earlier it was assumed that the distribution function F(x) possesses the usual gaussian Zc m and'the usual parameters a 191T84 USSR/Mathematics Statistics, Mathe- Jul/Aug 51 matical (Contd) (shift) and sigma (spread) are evaluated from the observed quantities xl, x2, - _., xn. Often such an approach is artificial in problems. However, Smirnov considerpd all possible types of distri- bution functions and terms. 191T84 0 SMIRNOV,N.V. - Method for the construction of confidence regions for a normal distribution function from sampling data. Trudy Inst.mat.i mekh. AN Uz.SSR no.10 pt.1:122-130 '52. (KLRA 8:9) (Probabilities) xoyatudstel i, matemati& Mya stausulca. v tehiuke. : 0 IThe theou'd probability an mathe-w bg&ya Ust. _ matical statistiai-In-en OSU- jiii~iring,, Gen&al part.] G ' s 1955 cow, -556 darstv.-lidaJOin.-Tedr, Lit., Mo PR 25;85 rvbW,: This 6b a,9P ability. wid-:maithematical statisti bo* p cs T 'er _p _a fbr_engineex~ and engineedng~.students ~sw is e fore Pnly thog Wiv theorv:ared parts of probab 4PA for the exposition of the methods of- which aTe. nee matMmatical 5t0istics, and more complicated proofs are frequently ginitted.,Chapter -1 (pp. - I I ~- 15) gives - a briek:-! historical survey * which consists mostly of a listing of th names:dv4_d4 , of proininent scientists working in a , fi;-Id. The role of the Russian School is ffir?,Pgly, empha- sized but the work of western statisticians, is also:briefly- discussed. (of- conternporary scientists R. A. Fisher, J. ' ` ` :~- - authors A. Wald are menti6hid). ~the In Neyman. and opinion the results of English and American mathema statisticians, ~A;v applied to further reactionary- aims., Ho eve tip ew does not prevent the use an W T. ~i A d expo-. es -#OA o~ these ults in the book.* he student of th b r e 00 will a ~ good working -knowledge -of statisticid methods regardless of thek origin. aaP. 11 (pp. 16--50), "10as4c cdnc.epts of Probability theory", Ch. III (pp, 51-104),: "Random' variables and their characteristics", and Ch.'IV (pp.:105-177), "Some special distributions", . provide an -introduction into, probability theory which is Fdequate.for the put pose,of the book-,, Cha V (pp. 178-29 1) j "Sampling methods ' ' " f estimates 61, distribu discu sse and, statistica tiqns - ' - tro- givesi an in then briefly descriptive statistics and ductioninto the' matheinAical'methods of statistics.The topicsdismssed include., 6siraW Oro ties of estimatesi: per 'estimates in es methods to obtain point terval timationi, order statistics. Chap. "Testi . U ng o . ontaitis the.usual material but- statistical -hypotheses", c 1Y treats theanalysis of vuiahd Whly very biiefly..Tests 6 gooduss,of, fit (including K61-logorov ste6t) M Well, as_ tests for r t nality are di5- andomness and.Jests- ornorr , cussed. The concept, of tfi~ bower function is introduced - in the last paragraph. of this chapter. Chap,,.VII (pp- 364-430), 'Fundamentals of Correlation Theory", deals * , i not only with measures of`_. ation pro- assoc iatioh, estim blems.and testing of hypotheses concerning correlation - - t-squ-ares and, regression C~Pfficient� but-also''with leas ' itations of "Some appI VIII (pp. 431A90) th6ory Chap .. . statistical and: pro , babilistic methods in en neaing"i treats some specif icengineening a Ipplications, the precision , M V, ~_,.Oh thir stiMU6 firmation of to"H67 pro a ilities in ~Iaikov 'cham'. Vestruik . Len' ~gra& 10 (1 055),'no' I I ~ 47-48i. (Russia:n) niv, U - b h b~hiAi t f - .s c:. ma e a order s+ I wit rit q Let 11P(JI ap -be j) I the corre- strictly positive elenients,d let (P ~ sponding set of stationary -AbsoluWpiikabilfties, with PfPjj:~=PjPjj. Let "lij be the number, of transitions froin i ~ q to j in n trials. Then the probability of a -specified matiik 11injAl,is calculated. and this leads to a ~2 test with 0 +s ' degrees oi freedom that a vedfie stocliastic ~d matrix be the true one. J. L_Doob- (Urbana'111. 7 ------ 77 E91RNOV, N.Y., prof., otv.red.- [Tables of Stndent's distrib-ation functions and densities] Tablitay funktsii rsspredelenils i i3lotnostei raspredeleniia Stliudenta. Moskva. 1960. 121 p. (MIRA 13:11) 1. Akademiya nauk SSSR. Matematicheakiy institut. (Mathematical statifitics-Tables, etc.) SKIRITOV, N.Y., otv.red.; YOLKOVA, Y.Y., tekhn.red. [Tables of the distribution function, the probabilitY density function, and its normal derivatives] Tablitsy normalinogo integrals varoistnostei. normal'noi plotnosti i ee normiro- vannykh proizvodnykh. Moskva, 1960. 135 P. (mmA 14:4) 1. Akademiya nauk SSSR. Haternatichaskiy institut. 2. Chlen- korrespondent AN SSSR (for Smirnov). (Distribution (Probability theory)) A'I "Ov /V pq ri I t li ~ i 61, 1 I ~nv E, Sri I'm iN I m 0 1 38 i I~vs a F N U It iL '43 a 8 'a A .11 gj 25608 8/517/60/059/000 --00:~/'006 BI 12/B202 ATITFOI;S- Bykhovskiy, E. B., Smirnovt N* Vo Orthoo-oxial decomposition of a apace of vector functiof s quadratically summable over a given domain and of o4)ei.-,Aura of the vector analysis PFR1ODICkL:,- Akademiya nauk SSSR. Matematicheskiy institut. Trudy, V- 59t 1960, 5-36 TEXT: 'The authors study Hilbert spaces L of vector functions V 'V IV ) whose domain of definitiort is a r ~a of '(x) (vi 2 3 egion the thraedim- ci,siorial Euclidean zpace E 3' The scAlar product in L 2 is: (U-'V) uj, d.. T;ie Luthors consider a decompcsitior',L of L 2e) into subspaces G, U and J3 onal to each other which have been introduced by H. Weyl ina fundamental P',Tar ',"!~qe method o--f" orthogonal projection in potential theory. Duke Math* C., z-'! 1/3 256o8 8/517/60/0"I./cro B1 12/B202 T'lic equiv-11011ce Of tho decurri-oo."ition of �1 to weylls IF, ted; in �ij the wuthoi:-s study the projoction Onto the Weyl tubap~~cco. nh, . t. :j 1 111. con!;,, ns Lhe stuclies of clatliter 11 extended to, limited, 1*,,:].,f cor~&Cted w~aces. The Inot uection p furl-her studies ivos aspects of 0. A. Lnd~-zhcnokrya, S. T). Sobolev, S. G. Kreyn IV. B'7~'-Iich ziro T"wrt-ioned. Th*rc ,ixe I figurc- and '16 referow:cs: 25 -n--I ron-Sovict-bloc. 25496 S/043/61/000/00'2/006/009 An analytical solution'of ~MOVD306 the order of changes on passing from the smooth to the disturbed 7. region, is small. With the above assumptions the'problem of flow is solved for one region by-the method of linear approximations and recurrence relations are then derived which make it possible to find A Jz in any region between the airfoils. 3-dimensio-':. y and nal equations*of flow are )0) 5X + (XY k + (I" 31 5) an -+o k I awl" jux awl Y 0, T -a7;- + -61 at a n + 0; kv - t (T' whpr6 Card 2/ 6' 25496 S/043/61/000/002/00~/009 An analytical solution of ... D207/D306 d(P2 I d(PI dJ2 I + all df, (31) 2ka da 41 df., df, d;- '10 do dF, 2k- d-: d- dF, dF3 I- - 2-. WT The.equation of shock waves is obtained on assumption that if the equation of the characteristic is a~ then the equation.of; the corresponding shock wave is + + where is small, and a and are constants. It is.. Card 4/6 TO -5- 15 AUTHOR TITLE PERI OD IC i d. S/104.3/61/000/003/007/008 0201/D305 AnalyLical sol-ution Vow Ue ~)rnl)lem of supersonic glas t1ow past a lattice u[: con-L.cal nirf(,ils. U. Le n k,.-ig r ad ,I-In i ve r s it c rIle sT,-i i k, Seriya matematiki, nieRhaniki i astronomi-j-, no, 3. 1961, 1-16-1.56 TEXT; The DrabLem was dealt with in the. LEirst approximation by the iiuthor in part: r r' -~'Liis artic-'.10 (Ref, 1~ i~naliticheskoye resheniye zadach.-il Ob (", t-ckatiii reshetki konicl-ieskil 1i lopatok sverkh.- z-vul"Civyn gaza, I- Vestnikc Leninnr,, an-t~a, 7, 105-116, 1961)~ Tbr- -'present deAs v.-I'tii tiie second approximation. The nota- tions- ccs?-ilt-s and asstirmption-, -)I: part I are jidely used in the YoLlciwin~,r. Ttie ~zeroclvn,a,.ii-c Oilrameters in L.-he cl-isturbed region are .0.) :,.2): z (2) X Y Y Z X2) C ard S/043 61/()0 tical solution... Oly 0-003/007/008 Analy D2 D305 through the point cm, in the first approximation; p is the of cm; g(2)(S) -L ordinate is a second-order. quantity. There is no tangential discontinuity in the first approximation. Equations -are set up which make it possible to determine 'the 3 arbitrary functions and, to find (to an accuracy of second-order quantities) the equations for shock waves and tangential discontinuities. Recurrent formulas are given for the solutions ~(2) (2) in the regiops 1 A A 1~0) 1 y 1%, z a nd 12 of Fig. 1. It is assumed that the solu-ftons are known in. the regions ml and m2; the solutions in m3 and m4 are obtained by continuation of the solutions in ml and m2. The equation for the line of tangential discorLtirr,!ity is found by a simple quadrature. The shock-wave equation reduces to the integration of a first-order differential equation. Me tav-ential-discontinu-ity line which divides m3 and m4 is determainad. It is concluded that in the secon(~ api)roximation, the continuatio--a of aerodynamic parameters from one region into the next -,-.iay lcac~- to a series of new tangential discontinuities; but only those neec, be determined which originate, - at t1ic points of intersectioa of Slaock waves; the others are direct- Card 3/4 S/043/61/000/003/007/008 Analytical solution... D201/D305 1y obtained from the continuation formulas. It is noted that the continuation process of %the second approximation gives an incomplete oicture of tangential discontinuities, w1hereas the first approxima- tion did not reveal them at all. In addition, in th~ second 'approx- imation the tangential discontinuities terminate upon Intersecting ~ a tangential discontinuity which originates from the point of inter- section of shocl_~ waves. There are 2 )Eigures and 2 Soviet-bloc ref- erences. Fig. 1. Legend: Diagroun of division of inter-airfoil space by discontinuities Puc. 1. Ka4ecTBetina cxcma Pa3d)IC11HR XCXG1ORaTOqHoro HPOCTpalICT82 P23PUSaMit. Card 4/4 31103 61/000/008/002/005 New fields of mathematical statistics B105%206 Akademiya nauk Litovskoy SSR (Academy of sciences Litovskaya SSR) and Vil',nyussk-iy universitet (Villnyus University), 26 of a total of 88 reports and communications dealt with problems connected with randem. processes of various types. This illustrates the great importance of thIs branch of science. In the period of 1930-1940 great progress was made by Soviet mathematicians in the field of nonparametri~ statistics. The theorem Dn = Sup IFn(Y-) -F(x)l by A~ N. Kolmogorov is pointed out-. This is an expression for the maximum deviation of the empirical function Fn(x) from the theoretical distribution function F(x), The latest studies by E~ L. Lehmann, Z. U. Birnbaum, N, V- Smirnov,. D. M. Chibisov, and others on nonparametric methods are mentioned. At present, nonparametric methods are being elaborated in detail, since a number of difficult new problems are to be settled by nonparametric statistics in connection with the theory of random processes. Many studies stimulated by the ever-increasing demands of physics and technology are conducted in this field. The possibility of applying statistical methods on an enlarged scientific basis is much promising, There are 5 references: 4 Soviet-bloc and 1 non- Soviet-bloc- The reference to the English-language publication reads as Card 213 3596FJ S/5 17/6 1/064/000/004/006 ]j299/D301 AUTI10-R: Smirnov, N. V. TITLE: Probabilities for large values of nonparametric one- sided fit-tests SOURCI.J: Akademiya nauk SSSR. Matematicheskiy institut. Trudy. v. 64, 19-01, 185-210 TEXT: Exact distribution laws are derived for the statistics D~, R+ and R ; this is done without having recourse to integration. n n n Correct estimates are obtained for the probability of large devi- ations of the empirical function from the continuous distri- Fn(x) bution-function F(x). First, 2 lemmas are proved. Lemma 1: The probability Qs of regular distribution (in the system of 3 points (s ~/2) is: Card 1/8 S/51 61/064/000/004/006 Probabilities for large ... D299YI)301 P (X. fn' c~_+ sd f C 1 R~ (4-8) Card 5/ 8 S/51 7/61/064/000/004/006 Probabilities for large ... D299/D301 Analogous results can be obtained for the statistics D~ and Dn. fo r n I or Reni~ statis'ics, the-qsymptotic distribution Z u z 0(1/n is expressed by: P(R+(Q, 1 zn Ir z n (8.6) where _VR (8.7) There are 10 references: 6 Soviet-bloc and 4 non-Soviet-bloc (in- cluding 1 translation). The references to the English-language publications read as follows: Goro Ishii. Kolmogorov-Smirnov test in life-test. Ann. Inst. Statist. Math., 10, n. 1, 37-46, 1958; Card 7/8 _�I,~OV~ NikQIU Vasil?yevic ~ 13OL'SHEV, Login Nikolayevich3 MEDM, V.1-1-,, red. izd-va; SD;T.JIIA, G.S., tekhn. red. [Tables for calculating the function of two-dir--nsional normal distributionlTablitsy dlia vychisleniia funktsii dvumernogo nor- mallnogo raspredeleniia, Moskvap Izd-yo Akad. nauk SSSR, 1962. 203 p. (MIRA 15:9) (Mathematical statistics) On supersonic conical flovis with S/043/62/007/002/005/007 D407/D301 as compared to the oncoming flow; the aerodynamic elements in the disturbed region differ little from the corresponding elements in "the oncoming flow. Linearization is effected and the first- and se- cond approximation of the solution are considered. In the first approximation, on fe obtains PlEel + P2 V2P P =2- -z (20) 2 v7 -2 E 2 2 UIn In- PP (21) IVY IV. IV V ;- - Yj X Formula (20) pan be used for determining the position of the shock. wave..In the second approximation, one obtains Pl (27) 2 2 2 24 3 T a 2a a, P1 a, PI. and a formula, analogous to Eq. (20). In view of the above resultat it can be assumed that the problem of flow past a lattice of coni- cal airfoils can be solved by the same method as for E 1 P Card 2/3 1 P SMIRNOV.. N.V.J. inzh. Evaluating the strength of concrete and reinforced concrete elements under compression. Transp.stroi. 14 no.12:44-45 D164. (MIRA 19:1) 11 .3141RNOV, Hkolay Vasillyevich; DUNE-1-BOKOVSKIT, llgo.rl Valerianovich; LAPKO, A.F., red. (Course in probability theory and mathematical statistics for technical appl-ications) Kurs teorii veroiatnostei i ma- tematicheskoi statistiki dlia tekhnicheskikh prilozhenii. Izd.2., ispr. i dop. Moskva, Nauka, 1965. 511 P. (MilLk 18- 5) P 0 Z D NY AK 0 V., ii r It s Pa v. 3c, v-~h K 0 1 E L 'N,i K () vA i V . FrA I . n a u,-, bu, setr. ~V_ f. re tsen.,zen- N.M.;, red. [Sampling methods in sp4zu-iing] Met.:wiy ~tbora prob v pria- deni-I. Moskva. Legkaia industr-ila, 19f~---5. 2_26 P. (MIRA 18t1G) 1. Matematioheskly inst-It-1-14, All SSSR (for Kotellnikova). ACC NR: Aiwo8gi.8 wore stored after a 4-daY preliminary set and held at a temperature of 14--160 under a water apray for a 28-day period. A scheme for providing step increases in stres3 for the test specimens is discussed. During the tests measurements were mado of the longitudinal deformations along the principal stress directions, and also of transvorso deformations in the unloaded direction. The test results wore contrastod with the hypothesis that the increase of strength observed in individual i tosts was due to the force of friction at the edge of the specimen. The stress - distribution from normal and tangential edge forces on an element of a test specimen is plotted. Ultrasonic stress measurements were employed in the tests, and the measuroments are tabulated. Data plots of transverse deformations are shown, as is a plot of the measured variation of the coefficient of transverse deformation for uniaxial and bia:dal compression.- Orig. art has: 6 figures and 2 tables., SUB CODE: II/ SUB14 DATS% none/ ORIG REFs 004/ OTH REFI 001 2/2 L 43141--66 AP66SM'- J CODE: UR[0020/66[16T/00611238/1241~----- ALC NR: SOURCE AUTHOR: Smirnov, N. V. (Corresponding member AN SSSR); Sarmanov, 0. V. --Vi K. Zakharov. ORG: Mathematics Institute im. V. A. Stekloy _Academy of Sciences,SSSR (Matematicheskiy institut Akademii nauk SSSR) TITLE: Local limit theorem for the number of transitions in a Markov chain and its application SOURCE: AN SSSR. Doklady, v. 167, no. 6, 1966, 1238-1241 TOPIC TAGS: Markov process, transition probpbility ABSTRACT: A simple homogeneous Markov chain with s + 1 states Ei, i - 1, 2, s + 1 and a positive matrix of transition probabilities {Pij 1, p, >0 i j - 1, 2# s + I is considered. It is assumed that the initial probaghit; o; Ei is PiW*" 0. A chain consisting of s states among whose elements must be distributed iii a definite way a series of states Es+l is treated. It is noted that the expres- sion for the number of different chains of length n consisting of s + I states reduced- earlier by the same author (Vestn. LGU, No. 11, 47, 1955) is in error. It is pointed out that the assumption that Pij be always positive is not necessary. Orig. art. has: 14 formulas. CODE: 14JUBM DATE: 08Dec65/ ORIG REF: 003/ OTH REF: 001 L 09094-6 7 ACC NRt AP7002335 .The use of an orderea sample for.the solution of various statistical problems should rest on an Investigation of the asymptotic behavior of the distr but ons of xkn I 9'v'en large n. The two parts to this problem were solved for the. maximum and minimum terms by B. V. GNEDENKO and were considered for "central", terms by the 4uthor-of..the present article In 1949. However, for a long time there was no consideration of the case of the so-called "Intermediate"'terms of series (1)**' k 00 (ft 00 (2) -1.0 or analogously n - k (n) co 'n-k(n) n In 1964 D. M. CHLBISOV found three possible types of limit distributions., Of'xkn for intermediate terms and established the regions of attraction of J each..'IjoWever, CHIBISOVI 9 investigations assign an.important'role to*an'assuM$Ya'--- tion defining the order'of Increase of k(n)q together with-n: viz., k(n) Cord 2/3 L 3179-66 ETC (m) WW I ACCESSION NA': AP5015k3 UR/029/65/666/dog/6698/6099 681.14. Krasikov Miroshnichenko. A. K. AUTHOR: ChehaiQN-~ - ftayan. 44. V. I'T P. - et'-4 bukho _i~.rnovK V Yq Vorontsov, A. Smirnov, N. Yer-',' Kheyfets A. Sffi A M.`%"'Dubro. G. B 'Alipov, A. Nq"' ITITLE: Electronic instrument for measuring velocity' distance traversed, and time ikClass 42, No. 170776 qrA ISOURCE: Byulleten' izobreteniy i tovarnykh znakov, no. 9, 1965, 98-99 TOPIC TAGS: tellurometer, radio rangefinder, geodetic instrument ABSTRACT: An Author Certificate, issued for a device which measures velocity, distance traversed, and time, combines a high-precision tellurometer, a phase i recorder equipped with a unit for converting sinusoidal signals to pulsed signalst.j... and a unit for measuring phase differences. Readings ipx~- made'V;isiiall~. Thia circuit cdnnecti6ns or the d~vic',,~consisiting 6 a s6 0 ries "t 6omput' ei-type- modules-',-, are described in detail. (SP] ASSOCIATION: none Card 1/2 ROZHKOVI, Mikhail Ivanovich, knudidat biologichaskikh nauk; SMIRNOV, N *ikita Yefimovich; PRITYKINA. L.A., redaktor; CHICBYSHEYA, Yel..' tekhni-- :-' cheakii,redaktor [Plants rich in vitamins] Vitaminnye rasteniia. Moskva. Pishche- promizdat, 1956. 196 p* (MIRA 9:10) (Vitamins) (Botany, Medical) "Clinical observations of the prog-ress of virulent proces5 in Paralytic myo-lo- ~-.-inuria in horses!, (,VS, DeTart:ient of Frat'-oio~~ and Thera-py of Internal lion-onta-Zious Diseases of Agricultural Animals). Collected -1d'orks No. 141, of Lenin,-ad Veterinary Institute U3SR Iinistry of A-ticulture, P 80,, 3ellkhozgiz, 1954. 0 Q Jour: Rof llur-rdol-, 1-1o 23, 1958, 92569. ut', c r O.K.. Tiors6 Drcedinr- Institute. Title : llorkinL; Qualities of Pribbskiy T7 rses mid T-lic-L. Crossbreeds. Ori~~ lVa :13yul. muchno-told'un. inform. Vses. n.-i. in-t-" kolie"rod- stva, 1957, I'lo 3, 44-47, tract: IlrinLskiy l.orses au,.C. t',-e-'Lr crosses wj.',,I-- trottcrs in Tllanty-I;T--,nshiys?iy 02u-uC showed excal- lent work capacity; t'l-,ey strode in 1 hour with an load uP to 7 !--a ana trotted tip to 21 lm:. The t2mtt-er Pri,ibsl-iy crosses of tile I to IV Genernations turred out fine results, althou[,)i t%ay were inferior to the C-C-rd 1/2 1~8 SMERNOV, 0. X., Candidate of Agric Sci (diss) -- "rhe Ob? horse and methods of imPrOvilIg it"- Leningrad -Fushkin, 1959. 17 pp (Min Agric USSR, Leningrad Agric Inst), 150 coPies (KL, No 20, 1959, 114) 1 P W IF-F, 7 I A4 "i:. 4 I mma~w -. 4 a, v I i7 j l BMIMOV~ y 957 . Vcb. 25, 1 bsiltuted cwhydAides 0' , Olkyl- d" Z&d by heating f acids vVith anhyd. LlqOiR)%., hl ic Ids" plaosp z - , ~,ftAAM"e14- tR~5~ t'~" '~4 -Y Z41i .SMRNOV2 O.K. A., AA.. ~f n, dA I APF~F ny+ uq 25 .1057. ny uc mc im ydrides am esteriflM w Ith -For the esterification is used a glycerol. inixt of polyine a of butylene and atuyleue gases, b.70-220* obtld in CM Ck ing and reforming petroleum. Phmn fg; Mizi AW i LIL-" sa t k 7c rl'. qnT k a. in; V.U.tL 105;727, -e 25, 1057 Watcr-5ol.' (hydroxym -fur ethyl)ificl amine ethers ofmono, or clibask Mrs. are incorporated into a pllotntensitlvj~ emitisiou: in order a~combinelh~ t:intijn g , atidpla. ticizing effixtq. Hoseh J7 Di str i 4E4j ~irface-active &ubstanc~s. 6_1- wov S. M. Levi. and-. 7 U.8,57. 10 Mr Ct. A. T. RYbWikdi~-if.. , ~ - -- i~i a. An ~kyl pfijnic w :id anhydri& (1). the al phw of which cont ains k 10- 12 C a totru is heatcd w ith the "M . . , of glycerol at 2:200* in th-o presetwe of ca(Alytie Anits. atilt. f KOIT i1 h d d f O I l r n o unt it'ni . atilt. o e pre a a d the t H s sp resulting acid esters arc - neutralized; - About 3"0 moles --of glycerqtis.uscd per mole of L-TWrj~action can becarried- out by use of 8 motes of glycerol Or inale of I hIL-0 phos- phinic add anhydride, anoth& *mole of I b8ng added to the resulting acid estArx,, and the whole "i heated for 1, lur. Ized. at 150 IV, after which-tbe resulting diethir is rte4ifal Ac Hosefi 0, J~l Distxr'~ Wd/hMd , z ; .4, teil TAct opidi hgoats E a 1 In cand a photo avhic emu It `ur_S 7_ff t 77 fr ~ ich.. - 1 a . . a PON Va Khiqi Nauk 3 M2 , JPriklad. Pol. i Khmmalografli I ,re~. Ifiess of varfous; types of wettirig agents'In elimim ti :" ' t during the process of coatint film base w t comets ' tes at td [ th l d de 1 1 d l o 7were - . - . - a r ra s CMU an so e , a 3 0n, 'R w d`777 # l d h l b l d l - ts vat e ts are ta ate an m lm esu u e gmp netted by 0.00 1 M conc ns. of Na butyluap hthaknes dfonette, -the Na vdt of the bbs(2--thythexyl) ester.of sullosuLeluk the K salts of the mort6glycerides of alkenylsucclate add selds where the alkenyl clWas coatained 8-16 C atains.'et; complex ester of the "Oetaglycerlde" of an alkenyisuecinid. acid mixt. (alkeny) contained 8-40 C atoms).'and the."octa-, glyceridn" of an alkeny1succinic acid (alkenyl contained 1 2-16 C Moms). Polyllycerides of alkenylsuccinic acids, f 0.001M) bavin the general (ormuli HOC112CH(OH)CH- f 1C1t,j.OXCHiCH(R)CO, fc%c if (Offy- OCITiC 14(01 l : CF1tOI.Ct4~C1((OH)ClLOH, where a Is 3, 7, It, 15,; or IQ ad R. Ij alk-enyl. eliminated comets when R j 0 contabled 1 _ 12 -10 C atoins but fiat when R contaimed only 8-10 C ~ b P . Lawt ergj slams. J. W fte 1 . . . . . . . . . . q pIRNov, O.K.; LEVI, S.M.; RYBNIKOVA, A.I. The action of moisteners against ncomets' in the coating of photographic emulsions. Part 1: The action of some derived alken7l succinic acids against "comets.9 Zh.ur.nauch. i prikl. fot. i kin. 3 no.1:34-38 Ja-Y 158. (MIDA 11:2) l.Nauchno- issledovatel'skiy institut organicheskikh poluproduktov i krasiteley im. K. Ye. Voroshilova i Vaesoyuzny7 nauchno-issledova- tallskiy kino-fotoinatitut. (Photographic emulsions) SOV/77-3-6-A/Ilq AUTHORS: Smirnov, G.X., Levi, S.""., Rybnikovn, A.I., Kochneva, S.N. TITLE: The Antistreak Effect of 'Wetting Agents in the Casting of Photographic Emulsions (Antikometnoye deystviye smachivateley pri polive fotograficheskikh emullsiy) II. The Antis'reak Effect of Certain Industrial Alkyl Phosphine Acids (Antikometnoye deystviye nekotorykb proizvodnykh alkil- f.osfinovykh kislot) PERIODICAL; 7hurnal nauchnoy i prikladnoy fotografii i kinematografii, 1958, Vol 3, Nr 6, PP 416-418 (USSR ) ABSTRACT: The authors continue their investigation of the mechanism of the antistreak effect of surface-active substances during the casting of a photographic emulsion. A relation between the structure of certain commercial alkenyl succinic acids and their antistreak effect was established. The Dresent article investigates dinatrium salts, mononatrium salts, mono- glycerides and DOlygglycerides of alkyl phosphine acids. Re- sults, with respect to the structure of the R radicals, anti- streak effect, surface pressure of a 3_' gelatin solution, and the critical speed of the wetting effect in cm/sec are dis- Card 112 cussed'and tabulated (Table 1). SOV/77-3-6-4/15 The Antistreak Effect of -,Vetting Agents in the Casting of.. Photographic Emulsions. II. The Antistreak Effect of Certain Industrial Alkyl Phosphine Acids. The anti-streak properties of wetting agents of derivatives of alkyl phosphine acids confirm the conclusions drawn with respect to experimental results with derivatives of alkenyl succinic acids. The antistreak properties of the wetting agents are determined by their structure. A systematic interrelation between antistreak properties, surface pressure and kinetic wetting could not be established. There is 1 table and 9 references, 7 of which are Soviet, 1 American and 1 German, ASSOCIATION: Vsesoyuznyy nauchno-iseledovatellskiy kinofotoinstitut (The All-Union Scientific Research Institute for Motion Pictures and Photography) SUBMITTED: November 10, 1956 Card 212 AUTHORSs Levi, S.M., Smirnov 0 K. 69-58-2 -9/2A TITLEs The Effect of the Structure of Some Surface Active Substances on the Poaming Capacity of Aqueous Gelatine Solutions (Vliyaniye stroyeniya nekotorykh poverkhnostno-aktivnykh veshchestv na penoobrazovaniye vodnykh rastvorov zhelatiny) PERIODICALs Kolloidnyy zhurnal, 1958, Vol XX, Nr 2j PP 179-183 (USSR) ABSTRACT: The formation of resistant foams and emulsions takes place in the presence of surface active substances which are ad- sorbed on the interface of the phases. The principal sta- bilizing factor which ensures the resistance of the foams is the optimum of the structural-mechanical properties oi' the surface layers in the disperse medium. Some of the derivatives of the alkylphosphinic and alkenylsuccinic acids were taken in order to investigate the dependence of the. foaming capacity on the structure of these surface active substances in aqueous gelatine solutions. It has been shown, that the salts of the two acids, as well as monoglyceridea, increase the foaming capacity if the length of their hydro- phobic part is increased. If the length of the radical is less than C , foams are destroyed by these substances. Tht~ same propergy is present in acid esters of the alkylphos- Card 112 phinic acids and in monoatomic alcohols. The foliowing 69-58-2 -0112_~ The Effect of the Structure of Some Surface Active Substances on the Fcam- ing C&pacity of Aqueous Gelatine Solutions range has been established: acid esters of monoatomic al- cohols (do not give foams)--+disodium salts (do rot give foams when R4 Ca 4. CIO)--p acid esters of glycerine (dc nozk~ give foams when R,!~ C 8 and m = l)-+polyglycerides (foama'.nl- agents). R being the'hydrocarbon radical and m the numbe-- of moles of glycerine. There are 6 tables and 16 references, 11 of which are Soviet, 3 German, 1 French, and 1 English. ASSOCIATION: Nauchno-issledovatellskiy institut organicheskikh poir, produktov i krasiteley, Moskva (Scientific Resear~-_h tute of Organic Intermediate Products and Dyes, Moscow) SUBMITTED: January 15, 1957 1. Gelatine--Solutions--Surface structure--Analysis 2. Gelatine --Solutions--Foaming--Effectiveness Card 2/2 DIMYAGIN, Boris Vladimirovich; DWI, Sergey Maksimovich. Prinimali uchastiye: SHOR. M.I., glavnyy inzh.. BANKVITSYAR, A.L., red. izd-va; GUSEVA, I.I., tokhn.red. [Physical chemistry of the deposition of thin layers on a moving base] Fiziko-khimiia naneseniia tonkikh Bloev na dvizhushchn- iusia podlozhku. Moskva, Izd-vo Akad.nouk SSSR, 1959. 207 p. (MIRA 12:9) 1. Chlen-korrespondent AN SSSR (for Deryagin). 2. Fabrika foto- bumag No.4 (for Shor). (Photographic emulsions) (Films (Chemistry)) 5(4) SOV/69-21-3-13/25 AUTHORS: Levi, S.M. and Smirnov O.K.-, TITLE: The Relation Between the Structure of Surface Active Substances and Their Adsorption Properties PMMODICAL: Kolloid-nyy zhurnal, 1959, Vol XXI, Nr 3, Pp 315-321 (USSR) ABSTRACT: This is a study of the relations between the structure of surface active a-ents and its effect on 1) the re- duction of the surface energy of aqueous and gelatin solutions, 2) the kinetic vietting capacity of the sur- face active agents, 3) their emulsifying capacities, and 4) the foaming of gelating solutions. The experi- ments have shovin that the maximum emulsifying and foam formin effect in gelatin solutions can be obtained with 1~ alkenylsuccinic acid derivatives vrith an al- kenyl chain length of 12 to 16 carbon atoms, provided there are ionoCenic groups, and 2) polyglycerides of al'k-jlphosphinic acids -with a chain length of more Card 1/3 than 20 glycerine molecules. The critical velocity SOV/69-21-3-13/25 U f Sur_TU~ce Active Substances The Relation Bet%,,een the S~ruc-k,-ure o U and Their Adsorption Properties of kinetic vietting (see specification on page 315 and diagrams 1 and 2) increases with the gro,;,.,-th of the molecu- lar wei6ht of the com--ound to a certain maximum value, -.-ihich remains %,iithin the limits of one homologous series., The highest maximum value could be observed vrith poly- glycerides. The authors further stated that linear gro~.'.,ing of the alkyl radical chain of surface active compounds, which are c3mronent-s of aqueous and gela- tin solutions, involves reduction of the surface ten- sion. The authors exT'ress their gratitude for the aid of the Soviet scientists: CbrresjpndIngMember of the AS USSR B.V. Deryagin, Academician P.A. Rebinder and Pro'Lessor A.D. Taubman. There are 2 diagrams, 1 6raph, 5 tables and 21 references, 16 of -urhich are Soviet, Card 2/3 3 English, 1 French and 1 German. SOV/69-21-3-13/25 The Relation Between the Structure of Surface Active Substances and Their Adsorption Properties ASSOCIATION: Nauchno-issledovatel'skiy kinofotoinstitut, Moskva (Cinema Photograph Scientific Research Institute, Moscow) SUBMITTED: 30 December, 1957 Card 3/3 SMIRNOV, O.K.; LEVI, S.D.; RYBNI]KOYAt A.I.; Prinimali uchastiye: GRINEVA, N.I.; STEMOVA, T.K.; KOCHNEVA, S.N. Investigati'on' of the 4etting properties of some derivatives of alkenyl succinic acids. Org. poluprod. i kras. no.2:168-178 161. (MIRA 14:11) 1. Gosudarstvennyy nauchno-issledovatellskiy institut organi- cheskikh poluproduktov i krasiteley (for Grineva). 2. Vaesayuznyy nauchno-issledovatel'skiy kinofotoins",tut (for Stepanova, Kocheva). (Succinic acid) (Wetting agenta) Imi-O -S.M. J~ A' IWV-,--O-~-- Anticomet-effeo~ andlj'struAure of wetting agents. Part 4: Mechanism of the anticomet effect of surface active agents-diaring the cok~ing by pouring of photographic emulsioxisi Zhur. nauch. i prikl. ?otA kin. 6 no.1:34-38 Ja-F 161. 1; Vsesoyuznyy nauchno-issledovatelf4iy Wmo-fotoinstiltut kNIKYl). (Surface active agents) (Photographic eurulsions) r-0 ~ K-1 KALINEINA (friu), MMTSEVA, V. A., SNIRNOV;-and UVAROVA, V. M. "Improvement of the properties of nuclear track emulsions through introducing surface active substances of the homologous series of sodium salts of the sulpho-succinic acid(.-esters" Fourth International Colloquium on Photography (Corpuscular) - Munich, West Germany, 3-8 Bep 62 LEVI, S.M.; SMIRNOV, O.K. Investigation in the field of the application of wetting agents i-n the coating of films with photographic emulsions. Trudy NIKFI no.51:20-38 162. Hardening properties of compounds containing methylol (N-hydroxymethyl) groups. Ibid.-.80-91, (MIRA 16:12) LLVI S;M.;,; SILIRNtj,V.,.P.~~4.~_~VANCHIKOVA, A.F.; KOCHNEVA, S.N. I ". -1- Comet preventing action of wetting agents in the coating of photographic emulsions. Part 5. Comet preventing action of acid esters of the sul- foauccinic acid and their effect on the kinetic wetting. Zhur.r-uch. i prikl. fot. i kin. 8 no.2:87-91 Mr-Ap 163. (MIRL 16:3) 1. Nauchnyy institut organicheskikh poluproduktov i krasiteley (NIOPiK) i Vsesoyuznyy nauchno-issledovatellskiy kinofotoinstitut (NIKFI). (Photographic emulsions) (Wettifig agents) (Succinic acid) SMIRNOV, O.K.; LEVI, S.M.; DRUNA, S.G~; KOCHNEVA, S.N. Some surface-active derivatives of loohexadecenylauceinic acids. Zhur. nauch. i ~rikl. fot. i kin. 8 no.3:165-166 MY-J9 163. (Y-M l6t6) 1. Nauchno-isaledovatel.1skil institut organicheskikh polupro- duktor I krasiteley (NIOPIW i Vsesoy-uzW nauchno-issledo- vatellskiy kinofotoinstitut (NIKFI). Succinic acid) ~Photograpbic emulsions) SI'MUIIUVJ O.K.; LEVI, S.M.; AVERBAKHjj K.O.; KOGM-IEVA, S.N. Anticomet effect of the wetting agents produced daring the coating of photographic emulsiors.Report No,4: Anticoidet feet of the esters of -sulfopropionic acid and their eff"t on the kinetic wetting ~~hurnauch. i prikl.fot. i ICUO 8 no* 5:321-326 S-0 163. (KMA 16-:9) 1. Nauchno-issledovatellskiy institut organicheskikh poid~ko- duktov i krasiteley (NIOPiK) i Vsesoyuznyy nauchno-issledov&-~ tellskiy kinofotoinst-;tut (ITIKFI). -,1l Of IRL C 9.1i A Iduktr,*4 ppul~i 7,,. L 08458-67 EWT(ni)/LMP(j) Rx, 1 ACC-kF~- 036-9-6i-C ",~--SOWRCE COM-S-UR[0-~~80 &6-/039/008/1837/1844 AUTHORI Zolin. V. M. Rozental'p L. V ; Smirnovp 0. K. LA~ ORGS none TITIZi Plasticization of cellulose triacetate films\ by substituted asters of orthost licic acid SOURCEj Zhurnal prikladnoy khimlio v- 39, no. 8, 1966, 1837-1844 TOPIC TAGSs plasticizer, cellulose plastic, organosilicon compound ABSMACT9 The purposo of the study was to find siibstituted esters of orthosilic acid (GSA) having both a high resistance to hydrolysis and a satisf&ctory compatibility with cellulose triacetate, In order to obtain plasticizers for cellulose triacdtate films. Monosubstituted asters of OSA containing various groupsibrming the borm as well as alkoxyl groups of various lengths and structures of hydrocarbon radicals were synthesized. The main factor determining the hydrolytic stability of the esters was -found to be the size' and structure of the hydrocarbon radical of the alkoxyl group. The compatibility of the substituted asters with partially saponified cellu- lose triacetate depends on both the length and structure of the alkoxyl radicals and on the structure of the radicals linked directly to the silicon atom. Some of the synthesized substituted'eaters of 03A effectively lower the brittleness of film fron Cord 1/2 uDct 66.o63.72 7711j- ..7. Arid - t t- j,! -nyev~ -) s! h 0- 1-61 and D-yes, "is 0-~r Tnttn~lUatt s L ca x -,icth-od. l- -a 4- n s ci v a as rtciu.! PA Tj~ 7 - - - - --l'Lnv(--rAi;;aUon irt iel,l of 5-etl,,jl Nonane Devivatives." Cand Chem Sci, -Arlirnov, L, All-~.'P-ion Sci -es Inst. of Synthetic and NaWral L,ssent,ial Oilt, vlo!icow 1953. (~iLEJ~'i.RJWIVNYY ZHU~C1.~AL-:,L'U.Tf -IJ* No I., Jan 54.) Source: s,'l-I 168, 22 J,-'ly 10"54 S?4IRNOV,O.K.; BWUT SAVA, V. M. Determination of the,iodine (Vijs) number In mixtures of 9&tu- rated and unsaturated mines produced from ste&rIc acid. Zav. lab. 21 no.4:414 '55 (MLRA 8:6) 1. GosudarstyenW nauchno-Iseledov 'Mel'skly Institut organichookikh poluprodukt.ov I kmattelsys (Stearic acid)(Amines) Z~ '7' D rbi IS its derivativeC Some relctions of e bu rolactane. and I and lreli Inj� Rt ~= zhur. ups"Res AISSOL ;dy.'-IU4Z-4jIMV)' X IF A~151,7344a.--7-To 2.3 g. Ka suspwded id C4Ha W added at once 12.8 g.~ Ac6li.mi'.61'.0. 0 and .10 drops MeOll and the mixt. shaken 4 hrs.~ warml-Auntil all Na 11~ -1, and-re4wed 3 hrs~ yield- - - discisolml, treated with',17 g Ne -ax b n tcr~a ttuat 750 AcHet tm cliag / t - q.. .. g 0 125-6% itis 114-4 ny 1.4561, * ba" SeNtOr na, tn. JOW.; The oxo lactone relluxed.0.5, fir. with 5%:HCI, cooledi and satd. with KjCO~ - give - 081/0i -AcCHAIeCHXHgGII,: be .-89* d,,0.0811,W,-1.4405. TheNadexiv.prepdasabove, '- - from 0 g. Na and,32 g. acetobutyrolactone was refined 15 firs, With UuMCII .CfI,.CH~.O.-L,-J55-6* n"'I 737, exl bA 1) .4 which treat with MeONa. iu McOll-WI, g~vc ace-tobutyrolactone an d 88% BURLOICOiNte. Tre~itrucnt of 70 g. aectobu 03 g. p-ONCGIICOCI in aq. lactone m Melco uith addn. of 20 g. 9~01:f at 10--;15o. ai t pH " followed by Sepn. -ind of,the pp'-,-washing it %ith MeOll~, - adding -100 mi... 4 15% N1,1,011 and stkifiij:12 firs. jave wn bran -ge.,Ppt. which- was washed with MeOll a~d.stirmd with 1,1. H-0 at 0. and treated with 100'ml.'25% NaOH -yieldinga residue of: 36 g. p4).NCsHCONH.-,. while the filtjute on acidification gave 12% yellow. p-OjIVCHjCOCff.CHj.CHj.O.CO, m.- 119-20% The Na deriv. from 25.6 X. acetabutyrolactobe and 4.6 'g. NIa in C%Hj'iv" treated with 36 g. BrCHr ' : CH2CHCOCI, refluxed I hr.,:treatE-(t w ith HIO,the sepd. org. Layer freed of volatile~ materials in vacuo, refluxed 2 g. Na in 50. ml. MeOff, and treated with 420 gave 161Y0 bui-cm-0-COA bcm.cm.-CH, :m. W7' bail 120-309 Id. Fittig, et al., Ann. 257,192, 200(1892)): . MARTYNOVj~, 0.1.; SAI-IDYWV, Yu.F.; SIURIIOV, O.K.; CILMOVSK&YA, S.D. Dissociation of calcium chloride in the process of generation of water vapor at high temperature and pressure. Zhur.noorg. khim. 5 no.1:16-22 A 160. OAIRk 13:5) (Calcium chloride) (Water vapor) SMIFTOV) O.K.; G`UIXA, N.I. Conjugated oyd-da.ion of -phosphorus trichloride and mixtures of aliphatic hydroparbone. 'Nefiekhimiia 2 no.2-:237-241- '.Ir-Ap 162. (MIRA 15~6) 1. Nauchno-issledovatel'skiy institut orgard.chesklikh poluproduktov i krasiteley. (Hydrocarbons) (Oxidation) (Phosphorus chlorides) �ffLUDI, 0 - RYBNIKOVA, A.I. Alkylation of maleic anhydride by a mixture of butylene trimers and tetramers. Neftekhimiia 2 no-3:342-347 My-Je 162. (HIRA 15:8) 1. Nauchno-issledovatellskiy institut organicheskikh poluproduktov i krasiteley-. (Maleic anhydride) (Butene) AUTHORS: Rozentall, L.V., Zhurnina, TITLE: The plasticizing effect of vents for cellulose triacetate PERIODICAL: Zhurnal prikladnoy.khimii, 2512 - 2520 S/080/62/035/011/007/011 D287/D307 P.G., and Smirnoy, compounds which act as sol- V. 35, no. 11p 19629 TEXT: The solvent action of phenylethyl phenols and of some of their derivatives (esters of fatty acids and fatty alcohols) was studied. Films of partially saponified cellulose triacetatet con- taining approximateiy 60 % bound acetic acid and having an ave rage degree of polymerization of 350 were used during the experiments. The phenylethyl phenols were prepared by condensing phenol and sty- rene in the presence or absence of H So in toluene. A mixture of 2 4 o-and p-isomers as well as the di-dubstituted compound 2,4 - di (a- 5henylFthyl phenol) were obtained during both methods of synthesis. The isomers were beparated by repeated rectification and crystalli- zation of the p-isomer. It was found that compounds containing an Card 112 S/080/62/035/011/007/011 The plasticizing effect of ... D287/D307 unsubstituted hyd.-oxy group in the phenyl nucleus acted as solvents for cellulose triacetate. The plasticizing effect of compounds which have a low degree of compatibility is greater than that of plasticizers soluble in ceilulose triacetate; this is improved by reduced brittleness of the film, especially at low temperatures (at -600C). The authors suggest that plasticizing compounds with different degrees of compatibility with cellulose triacetate as viell as discrepancies between the specific weight of the films account for the above phenomenon. The slight effect of plasticizers (which are comnletely compatible with cellulose triacetate) at low temperatures is also due to the strong interactions between the hy- droxyl groups of the partly saponified cellulose triacetate and the polar groups of the plasticizer, i.e. the hydroxy groups of the phenylethyl phenols. There are 6 tables. SUBMITTED: June 2, 1961 Card 212 SMIRNOVY O.K.; LEVI, S.M.; RYBNIKOVAy A.I.; KORNEVA, E.D.; POPGVA, O.V. Hardening and plasticizing effect of water-soluble ethers of hexamethylol melamine and some mono-, di- and triatomic alcohols and polyglycerins. Part 1: Ethers of hexamethylol- melamine and of mono-, di-I and triatomic alcohols and poly~- glycerins. Zhur. nauch. i prikl. fot. i kin. 8 no.6:401-404 N-D 163. (14IRA 17: 1) 1. Vsesoyuznyy nauchno-issledovatellskiy kinofotoinstitut (NIKFI) i Nauchno-issiedovatellskii i titut organicheskikh poluproduktov i krasiteley (NIOPiKI. ns J~, . MALYSHEVJI A.I.; SMIRNOV O.K. Analysis of the surface-active derivatives of Alkeny-1succinic acid by titration in a nonaqueous medium. Zav. labs 29,n6.10: 1173-1174 163. (MIRA 16:12) 1. Gosudarstvennyy nauchno-isaledovatellskiy institut organicheskikh poluproduktov i krasiteley. ACCESSICH NR: AM26854 8/0O65/64/0O0/(X*/0O66/6* In AMOR: Averbakhj, K.O.; Shor,, G. S.; Smirnovq O.'K.; Golld , 0. S. TITLE: Methods of preventing the formation of Ice crystals In fuels SOURCE: Xhimiya i tekhnologiya topliv I masel, no.Ai, l9a, 66-0 TOPIC TAGS: Fuel, hydrocarbon fuel, ice formation, Ice crystal formatlon,*preven- tion, mechanical water removal, additive, ice prevention additive, surface active -agents, reviev, Hterature survey. ABSTRACT: This is a literature survey relating to the behavior of water In hydro-'.. carbon fuels at low temperatures and to methods of preventing crystalization in ahem. The 'solubility of water in the hydrocarbon fuels at different temperatureep' the transfer of water molecules between the fuel and air, formation of micro- droplets' of water on cooling,, and conditions for the-formation of ice crystals ars' included. Various physical and mechanical means of preventing or remoftng Ice have not proven too successful. Two types of additives have helped solve the problem. The addition of 0.1-3$ of materials which dissolve water and vhIch are dissolved In hydrocarbons at low temperstureej, e.g., certain t1cobols, glycols or.~ cAhers, increases the solubility of water In the bydrocarbon fwl. The V" of STYRIKOVICII, M.A., SEROV, Ye.P.,- SMITIOV, O.K. PULELA Kk[ESTARA SAMA. Use of the "salt method" in studying the characteristics of - ? 64 ma2a and heat reansfer. Dokl. All SSSR 157 no.1-91-94 Jl (MIM 17 -.8) 1. Chien-karrespondent All SSML (for Styrikovich). --s va. 0, K J S, -Z~,! I'-) ~,,, i Y 0 . F . " I r- . ~:, ~l -fer in 1;~eam zenel'atirig ld-lv. AN SSSR. Enou'u. S:2-0 r64. (MIRA 1'-,1:12) jj~- -~t4TRNCV CI F coin'-! n a uk; disser an, Exneri men t istudy of tho:~ boundary of the stability of a flcv in a U PRralle! ccnne:~ted steam c-enerating p-.Fes with nonuniform heating r - cf the surface. Teploencrge~-ika II no.lC;7C1-'[2 0 164. (MIRA 18:3) Moskovs'Kiy energetichesk-'y institut. NRt AP6037029 SOURCE CODE: UR/0069/66/028/006/0777/0780',--- AUTHOR: Averbakh, K. 0. (Moscow); GoIldin, C. S. (Moscow); Deryrgin, B. V. (Moscow); Smirnov, 0. K.~J?bscow) ORG: none TITLE: Formation of hydrosol in hydrocarbon media at low temperatures SOURCE: Kdlloidnyy zhurnal,*v. 28, no. 6, 1966, 777-780 TOPIC TAGS: hydrosol particle, hydrosol in toluene, hydrosol formation 16,venv, ABSTRACT: A study has been made of the formation kinetics of hydrosol particles in- toluene by ultramicroscopy. The equipment and procedure are described in the text. The effects of the time of the appearance of hydrosol nuclei, and of the water c ntent and temperature of toluene on the formation of the aqueous phase were investigated. The experiments were conducted with toluene containing 0.014-0.024% witer. It was shown that at -5 to -8C the particle concentration first increases rapidly with time, and then more slowly as the water content of the toluene drops; the rate of fomition of hydrosol particles increases with the water content of the toluene. Experiments conducted in a wide teTmerature range indicated that the rate of formation of hydrosol particles increases with dropping temperatures. Orig. art has: 4 figures. SUB CODE; 21/ SUBM DAT-Et 1114ay66/. ORIG REF6. Oll/ OTH REF: 002/ ATD PRESS. 5107 SOV/96-59-2-9/18 LUTHORS: Samoylov, Yu.F., Candidate of Sciences ~mirpD_v__O_Z-, Engineer TITLE: The Behaviour of Calcium !Vdroxide and Calcium Chloride in the Circuit of a Once-12hrough Boiler (Povedeniye gidrookisi _J 1chlarida kal'itsiya v trakte pi-yamotochnogo k-o t 1 a) PERIODICAL:Teploenergetika, 1959, Nr 2, Pp 53-57 (USSR) A11.9TRACT: A special test rig was set up to study the solubility of calcium compounds in steam and their behaviour during sueam raisingin conditions of once-through boilers. The test rig is illustrated diagrammatically in- Fig 1 and described.; the most important art of it is a steam- raising tube of 10/15 mm diameter M10 mm In the superheali- zone) that imitates the operation of a coil in a once-through boiler. Feed water is pumped into one end of the tube and the steam coming out of the other is condensed. The heating arrangements, the measuring instruments and the test procedure are described. After operation the rig was cleaned out., one zone at a time, Card 1/5 using pure distillate or in some cases acid. The tests SOV/96-59-2-9/18 The Behaviour of Calcium 1-g-d-roxi-de and Calcium- Chl'oride in the Circuit of a Once-Through Boiler discussed. A curve of the calri=i ion content in the steam as a function of temperature i~jben the rig is fed with a solution of calcium chloride at a pressure of 150 atm is given in Pig 3. It- is suggested that at the lower temperatures the calcium chloride is decomposed to form calcium hydroxide and at the hie;her temperatures above 4900C calcium oxide is formed., In order to evaluate the a~~clj_racy of the results table 2 gives values of possible errors in determination of the concentration of calcium ions in samples of condensate. In the tes-Us when the rig wa-9 fed with calcium chloride solution- the steam condensate was always acidic which potats to tiie presen,3e of free hydro3hloric acid, whilst the deposits were alkaline and so contained some form of calcium oxides At high temperature, calcium chloride is slightly hydrolised even in aqueous solutions but the process is much more int-ense whan boiling occurs and the volatile hydrochlorio acid is reMO-Ted with the steam. Card 3/5 The rat-lo between ooncentrations of calcium and chloride SOV/96--59-2-9/18 The Behaviour of Calcium f~ydroxide and Calcium Chloride in the Circuit of a Once-Throug~a Boiler ions in the deposits in the tube was variable and depended on the concentration of calcium chloride in the feed water. Graphs of the contents of calcium and chloride ions in the steam as a function of temperature are given in Fig L~ and 5 respectively. Within the limits of experijwntal error the carry over of calcium ions in the superheated steam does not depend on the concentration of calcium chloride in the feed water but the concentration of chlorine ions in the steam does depend on this concentration and this confirms the author's ideas about hydrolysis. Previously published data about the solubility of calcium chloride obtained by the radio-active isotope method in an autoclave are given in Fig 4. Comparison of these results with those obtained in the rig of the Moscow Power Institute shows that carry-over of calcium ions is governed by the solubility of calcium chloride and possibly also by the soiubility of the hydrolysis products of calcium chloride at temperatures up to 470'C. At hi&er Card 4/5 SOV/96-5 9-2-9/18 'The Behaviour of Calcium Hydroxide and Calcium Chloride in the Circuit of a Once-Through Boiler temperatures the carry-over is considerably less than the solubility determined in the autoclave and this is probably because of different hydrolysis c!_"ditions in the autoclave and test rig. There are 5 figures, 2 tables and 5 references of which 3 are Soviet and 2 German. ASSOC IATI Oil :Llo sko vskiy Energeticheskiy, Institut (11doscow Power Institute) Card 5/5 SOV/96-.59,.-.8--10/27 AUTHORS: Styrikovich M.A. Corresponding Member Academy of S3-Jeanei; USSR, Serov,, Y.6.P. Candidate of Te-.hnical Sciences, Smirnov, O.K., Engineer TITLE: The Influen3e of Displacing the Transition Zone in On-,e- Through Boilers for Supei-Critical Pressu-re PERIODICAL: Te-oloenergetika 1959, Nr 8., pp 33-37 (USSR) ABSTRACT: Displa3ement. of the transition zone into the convective part of the furnae~e in order to inarease the period between boiler washing was first tried on the fourth onc:e-U--criq~., boiler type 24-.SP-200/140 to be installed. In the three preceding types of boiler the transition zone was not dis- placed. It has been observed that displacement is ac-lom.- panied by more intense scaling at the end of -the evaporation zone and in the first stages of super-heat. It should 'be noted that the experimental data that served as a basis for displacement of the transit-ion zone were obtained on an experimental once-through boiler fed with water having a relatively high concentration of non-volatile contaminants. Card 1/5 Then the results of displaoinS the zone were mainly checked sov/96-59-8-10/2'.7 The Influence of Displacing the Transition Zone in Once-Through Boilers for Super-Critical Pressure. on industrial medium-pressure boilers fed with water of a quality that would now be considered poor. Displacement can only be effective if scaling is concentrated in a particular part of the boiler; and if the scaling is distributed over a considerable range of increase in en- thalpy of the steam, a transition zone entirely in the convective part of the furnace is scarcely feasible. This is particularly the case in unit-type set's whose feed- water temperature is redu3ed at partial load so that the boundary between evaporation and super-heating surfaces is displaced. The presence of various impurities in the feed water, and their solubility under different conditions, are then considered. A typical curve of the solubility of cal- cium sulphate in superbeated steam as a function of temperature at constant pressure is given ir. Fig 1. Most substan,,,es hehave in this way under super-critical con- ditions. that is, there is a temperature region of minimum solubi].Aity. In "alculating the density of scaling by a Card 2/5 substance from solution, it suffices to kn= the functional SOV/96-59-8-10/27 The Influence of Displacing the Transition Zone In Once-Through Boilers for Super-Critioal Pressure,. relationship 'between the solubility of the substance In steam and the temDerature, thou,gh unfortunately adequate information abcu,t this subject is not always available. The different substan,,es that oesur in feed water are then con- sidered in turn, in,Auding variOU;3 sodium. calcium and magnesium compounds and si-lica. The zones of maximum de- posit-'on of -%a,!.r;ium and sodium sulrihates in a onse-through boiler at pressures of 240 and 300 arms have been 3ad,,ulated frcm data about the solubility of these substances as a function of super--heat-ed steam temperature: the. results are given in Table 2. It will be seen that the tempera'~ure range of scaling is only 3800, but that it corresponds to the considerable increase in steam enthalpy of 19-0 kcal/kg. The temperature range of maximum deposition of sodium and calc.j.um sulphates is 630C with an enthalpy increase of 231 kcal/kg. The region of extensive deposition is broadened if -L*.he quality of feed water is impaired, as will. be seen from the results plott-ed in Figs 2 and 3. The Card 3/5 influence of mass exchange on the rate of deposition of