SCIENTIFIC ABSTRACT SLOBODIN, B.V. - SLOBIDIN, YA.M.
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CIA-RDP86-00513R001651330003-9
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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Body:
SWBODIN, B.V.; FOTITTr, A.A.
Phase diagr,-.,.i of the !!a 4C - V205 sys@em-
Zh
- u z,,- priki. kchim.
38 no.4:801-806 Ap 16.5. (EM4. 18:6)
1. Institut Uralskogo filialla AN SSSR.
SLJOBODIN.-J.- __ --
In the Department of Economic Research of the Urals Branch
of the AcadeaV of Sciences of the U.S.S.R. Top.ekon.
no.8:159-160 Ag 160. (MIRA 13:7)
1. Zaveduyushchiy otdelom ekonomicheskikh issledovaniV
Urallskogo filiala Akademii nauk SSSR.
(Ural mountain region--Collective f%rms--Income distribution)
(Ural Mountain region-Power resources)
SLOBODIT-4, V.G., inzh.
Semiautomatic machine for the circumferential hardening of the teeth
of the driven pinion of the TE3 diesel locomotive. 14ashinostroenie
no.3:55@-58 MY-Je 162. (MIRA 15:7)
1. Luganskiy zavod imeni, Oktyabrlakoy revolyutsii ,
(Steel--Hardening) (Diesel locomotive.)
TNBZNTIYEV, M.L.; OSAD'KO, M.P.; BRAGIRSKIY, B.I.; "04001016&-j Fisawl,
Z.A.; LEVIN, I.Ye.; TSYNKOV, M.Tu.; BAD1RYAN-.-G-.7.-, TTEITIN. V.A.;
ABR&MOV, V.A. ; BUM,S.V.; KOBCHIKOVA. I.A.; XARMUKHOYA. Te.I.;
OBOIXNSKIY, K.P., IL'IN.S.A.; GAVRIWV. V.I.; YUYDMAN, S.M.;
UJASHNIKOVA, V.S., redaktor; I&PIDUS. M.A.. redaktor; RAKITINA.
Ye.D., redaktor; FEDOTOVA, A.F., tekhnicheskiy redaktor
[manual for students of collective farm economy] V pomoshch'
izuehaiushchim skonomiku kolkhozov. Mosk-va, Goss izd-vo eelkhoz.
lit-17, 1956. 423 P. (KIRA 10:1)
(Collective farms)
AVERKIYEV, A.S., red.; AGEYEV, Ya.P., dots., otv, red.; AREFIYEV, V.A.,
dots., kand. ekon. nauk, red.; DEVIDOV, S.F., akademik, red.;
KARSHIN, V.Ye., dots., red.; KOGAN, #_,Ta., starshiy prepodav.,
red.; MIKHALOV, V.I., starshly prepod&vatel', red.; PITAYEVSKIY,
P.I., prof., red.; Sj@@ @rof., red.; SHOLOKHOV, Ye.I.,
red.
[Problems in the new system of agricultural planninglVoprosy no-
vogo poriadka planirovaniia sel'skogo, khoziaistva; trudy. Kyiby-
shev, Kuibyshevskii planovoi in-ti 1961. 419 P@. (MU 15:12)
1. MezhvU2ovskaya nauchnaya konferentsiya, Kuibyshev, 1960.
2. Zamestitell preds6datelya Kuybyshevnkoy obLIaetnoy komissii
(for Averkiyev). 3. Kuybyshevskiy planovyy institut (for Ageyev.,
Makhalov, Karshin). 4. Deystvitellnyy chlen Vsesoy!lznay akademii
sel'skokhozyaystvennykh nauk imeni V.I.Leuina i Moskovskaya or-
dena Lenina sellskokhozyaystvennaya akademiya imeni K.A.Timiryazev
(for Demidov). 5. Urallskiy filial Akademii nauk SSSR (for
Slobodin). 6. Zamestitell nachallnika otdela sel'skogo khozyaystva
i zagotovok Gosudarstvennogo planovogo komiteta Scveta Ministrov
RSFSR (for Sholokhov).
(Agricultural policy)
SLOBODRi, V.V..; IV.,U'YUI,. Yu.I.; ITZOVIEV, PX.; IIAGAIYEV, `u.!-.,LUPIJIE%rA,T.F.;
MESIICIW4INIT~',,-O-.I.;BP=,.~HOV,'~-'u.A.; KOffAKOV,P.O,j,
ved.; ZJII@OVP, E.N., i-ed.izd-va; TAM-OVA, --i,F.,, tekhn.red.
[Distribution and specialization of agriculture in Chelyabinsk
Province] Razmeshchenie i spetsializat-siia. sellskogo khoziaistva
Cheliabinskoi oblasti. Sverdlovsk, All SSSR, 1963. 204 p.
(MIRA 16:12)
1. Akadeniya nauk SSSR. Ural'skiy filial, Sverdlovsk. Otdel
ekonow,icheskikh issledovaniy.
(Chelyabinsk Province--Agriculture-Economic aspects)
ZAGORSKAYAJ, N.G..; YASHI.14A, Z.I.; SLOBODIN, T.Ya.; LEVIfa, F.M.;
BELFVICH, A.M.; URVANTSEV,-9.9., doktor geol.-mineral. nauk, red.
(Mrine Neogene(?)-Quaternary sediments in the lower Yenisey
Valley.] Morskie neogen (?)-chetvertichnye otlozheniia
nizhnego techeniia reki Eniseia. Moskva, Nedra, 1965. 90 p.
(Leningrad. Nauchno-issledovatellsldi instit-ut geologii
arktilcL. Trtidy, no. 141j.) (MIRA 18:9)
SLOBODIN, Ya.M.; MAYOROVA, V.Ye.; SMIRNOVA, A.M.
Thermal degradation of ethylene-propylene rubber. Part 1:
C C6 hydrocarbons in the products of thermal degradation
oi ethylene-propylene synthetic rubber. Vysokom. soed. 6
no.3:541-544 Mr164. (MIU 17:5)
1. Severo-zapadnyy zaochnyy politekhnicheskiy institut.
1
w
0 4 0 0 0 4 C 0 0 *
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1
i
1 4 4 it tt it W is k it Is tv a IQ 11 At It 14 a m p it of 41
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t
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t
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-
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0 0 fit @to 1-0 V!pm .1-
00 -00
00 lo
famerlsadon of hyifrocarboms of the diallyl series Under
th
W
ll
00 it e
i
uencia of mUkates. S. V. LclKilev aud Ya. M.
Sk4)Win. I. Grit. Chm. ( U. S. S. R.) 4. 2:1
'
cf--C
. A - 19, INV,; 24, 42;-,rp.-Bv thernial
diAllyl and dii4obutylene (1) with m-tivated fl.widin -1-re
obtained the same products of iumnerizatimi ai lie (lie
action of air. alkaffirs OlaviirAil. 1. Ruts. Phvs.-Chrm,
19. 414. AM(M47). 23. 2Xltl-%P.1l I). A vivid if
00 41.5,'j tliiw%wttvl resulted h%. 6 recirrulatimm ufJi;illvl at .00
00 and a VVIticit y (if 0.3-0 4 g. Swr tuit,. through it trav- Age*
J
-c
hamber 10 nim. in diarn- and 15cm. in length charged
li-
00 a ith
"idin activated at n%'. thitlersimilarcondititi-
*
'
'
Mi-- to
I passed once at
-
and a vel,%-ilv of 0.4 4) 4., g. per
coo
00 .3 min. gave 70% diiwrr,)Iyl. TUC Witticrit2tion i% ac- I
00
.3 couipanied by a pjrtial jxdymerization of the fornied
' coo
00 hydrocarbons with conjugat
l dmilile bon&q. I was COO
prepd. from 1,2.3-trihromoisobutenr (9) by the Grignard
reactiun (Erestinskil and Krivorot'ki). C. .4. 7. 31.44).
A yield of A)% pinr H was obtained frmn i4obutylene and
'
*
00 firs at 0
(Pugor4hirl'skil. J. Rurq. PkYj.-Ckem
. N.C. M,
008 t468M.94)). while at 10* resulted is mist. tit 59A% I and
41.4% N1r,,CBrCHHr. (M). and at 41P :N.6@@e I and
7.7.4%M. M gives diisocrot vi by the Grignard react igin.
Chat. Minc
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ASO-SLI SITALLOICKAL LITISITURt CLASSIOICATION
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A that aid pialyawaristation. The piroatas is evedirratly site.
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es Were
o
i"' -MrTq"Y
(u. S..S. R-) B. -
ng
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2W
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0
J 58.2g. AIA + Fetol 2105. C.0 + MCO 4-09, K + evidently i
be Nao 1.10 anti IflO 17.M8%. (4) -kil- from SwIlenva; beating. !
.
1 I I ll.'-Is' Fro OW,
,,mig Si(N 49 9- AY), 2:.-09, .112, CIAO Call chwo
es
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A%Ah
j W,
d 11,0 13.29%. The polymerimlion powrrs
fated with bobutyleft amd the *@kprk
*h gavolwe. kmam mw sea
abilily of The d6ratce is at w activs- "ZI me 0
MW an mettwatleft temp. belver
,
=00
mrOW'de Swc"wPolymmicalitm. The
I' t
c Nitical"
caw
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o upon inner 5tra"Ural ebang" Caused by =419
ics gel does not cause polymerization. Sw-
1
moo
rriuA by high pdymeidq POM bave Wan 1:
Ptionpowm. Thcadsorptompoirtrdonnot l Coo
-A upon the activation temp. WOMB the ramw
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to a a at
0* A
* 6 C
so I!
of Creft IV was cowArmed by otidimium to
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T
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of deabb bmda. Yx@ h J. Gra. (IAiltoWwaspro
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&Mytop
,
1219 :1406*11.- After pawins I-
6 The aborwe in the isomerimikin products of M of the
00
.
etbrayI41"ckheirtiv (1) over dmidin at 210-W. thea 14
expected imoterpimirm (I-mrth
cyckdWarm) (v) mud the high pr@tas. iw%) of PQIY-
00 el had inryta" and dw reaction products with, C-(NOa)G nieri" product is to be explained by The straft trudenry
l tied chmiged from yvilow in biond-red. The hent
of V
which was probaW the tied product of the isomeriza-
0 0 1 were examd. an the h"Isrsis that the 2 deshir Imeb ,
tion petwe". to polynievise. I isumerized with dwSr"by
00 j M 1 would trad to appnxbcb rach,wher to &@ a coa-
jugated Sirstrin, and the fnrination ni I-etbYlidrne-2- when pwmed through the 10 sam. diam. hord Kim tube
t 0
IS
3
f i1
idi
h
ft
i
00,3
cyckibeartse (0) was estabbsbed. It was dumn that I- was arres-
.
n. ower
clu. o
or
at
a
e, W t
C./M
sar- to pow it severid times, twh time removift by disfil.
00 rihesyl-2-cWkibrient, I-ribenyl-i-cyckshesew, I-etkyii-
th
w
d I
1
kA
di
r
d
3
M
l
3 the pro&,wt which b. above 110'. Two fractions. ow b.
-
-e
-cyc
e
ttir-
extric an
tza
e
m
"c
.
y 13D-4* NV IAMAI) wW &&Abrr b. l.U-?* (aT 1 .47107)
00 absent. but it serms fikely that mew prudwt imawdkic vat embixted and oxidized with KMnO, In Arlie to
0* betwere I and 11 %bould be formed. Vince a Mhomer iWW give I-a-bydrosyethyk7clukess -1.2,1-trid M), M.
r
CriZation CA HIMOMMO fM) XSVV hUHMONOW (1400b*
48' (from 91,0), in approx. 505'v
yirld. " bWkd with
O
00 (IV) - The o*wt of
i4amerinstionl7u,"i =11 rd takw with J(NOO. (In KjCrV% &Dd HjS04 fRw fi hrx. gave a-ketandipir acid sod
*
00
@-pticafiy inactive
and had a decrcw-xd
1 gaw yelk,w) a neutra! substance. m. 52-4
, diNA-Wtly sui. im 11.0, cold
*
,
,
b, p., a and d. Frwlkjoal distn. at 10 g. gave (A) 4.5 ak- mW KtO. The frartim b. 1&1-7
reected vigormAidy
w
th
t
b
th
i
h
ki
id
h
d
N
b. 1419 -,2'. 1 B) D-5 It.. b. IM 4'. (C) 5.0 a.. bry
i on
e
er
a
w
a
t
ma
c an
r
e.
o pme prod-
y
ucts were fimbited. but the scid obtained after treatment
askyth
de
A and D did not react with makic with Na.M and 1140, gavv s Ax uft with the coW. Ag
nor did they show an evaitatkin. A resembles The IV
19
R
P
CI
S
414
am costest. The frectim A from M witk KMnOq In AcIde
J uss.
AYS.-
MM.
m.
A Chussev U.
;
.
,
g&vratrtrW1VU),m.61-3*. VU with Cr% mist. save
23.2W3). It has d. OJMI. nj? IAGM. mW gave nocrya.
VM. M isomerizeJ much nKffr r adify thas 1. oWy I
nitrosochloricIr tw teirabromide. The structure of A passage over Goridin being necessary- IAwk W. Owu
I* it a
0 U U 'o
0 0 0 04
0 0 0 0 9 0:0
of TALLVOWCAL LITCRATUM! CLASWICATICO
W TP LT Ll Is K 9 41 It 0 09 ; M it It
so so 0 0 0 0 *1
6 e e
00 00 000066 so 0 00 0
Iaz
CW 0 a -1 Is a 9 M -0
0 06 0
66 0
-00
-00
-00
-00
-00
800
zoo
ZOO
WOO
coo
400
see
0
a 0 0
else
-4, 4,
! 'o 0
Ila Is
Y I "
L-A-A-A--f-A- A
1-11P
A %so goo 4 r. Coof a 1
-00
POOCISSIS Afto 090FIS1.1% -of.
I
A .i
?
twoodattim so slim hy&0orbM wifir 610011M. J6IftCWCHlJrCHMe,, th. 710 NJ'; this with I ttu4. Or,
W. Inaedn" d NOMM41bj%lko. YA.I.-M. _st 00' sives.10.3% Mr4C9rCHIkCIkUr,, bw 123 S';
Slow
cf.* C. A. 29, 4-sS-`o.--Ptue te
USIM"hyWkSt (I)AMOMO the kilter distd. with good. KOH at 115 40' and 10 mm.
gim 71 41 MesC-CHWOrMet, bea tal 7%
. preMMV
owr activated fiaridia, " demMoed brim FM=
toonlefults to 2,4-dismethyl-1.3-pastadieme M&. beaW in Z. dust. aim W2% 1.
- 0.7ARMS
-4% M
mJ7 1.440W. 13 is pr
from
b. 82 @Vd
ot
completely polymerim at the asomeat
d .
.
.
'
mewit
l 4)ai& b
au
tifi
tio
ol F
lm
ll
d .
-
The&mt.o(poIme.sfonwdio3")%, Puraff. a
th
s
i t
)14
diti
d i
0% 1
U n t
x
ca
ra
e
a
y a
rrS
y
(Poor. IV. Tbequeedemelimmowba-
d
e an
e con
twis.
,
o
s
w
-
. aw o "gumbo k am, "am aftme-d"ne. a".
Ist ilefialtely proven instowe
ot trenitim w a kd
s
stem to owe with adjmcmt Unsalm
Pal Imri! 4.-Rkbrr pure agnor (1). prnW. by tbr Proredure
f 1
b
6
A
6
(C
M
fl
k
a a**
.
y
in 114-7
a 'sm
ield
we almod exclusivel
b
0% o
v
.
4
.
e
, -
). or pure a
ne (
), prevd.
y
b
f h
b
t
fi
i
h
.
.
y
.
w
y
11 U
1:184W
d
IS
1
74W
dW
U
I o
y trom
owa
rawo"y
rm w
t
&hr. KOH. sr@rll
moo
-M
.4
n=
M
, or
a*
.
,
.
1
4 11
6 di
f M
kil (C
1
hk
A
o
1 Over br&" fintlAin. ww"Norm part"d Im"MM124-
i
h
d
f i
i
a mers o
eres
ovs
.
. N
,
4
t
e
mmwrizat
on. t
epee o
on waryins abnost finrMy go*
,
),
(Amos. claims. jsky$. 171. 24. 4
j 1
)
)
' orkh the temp, is both comm. The ame rquil. conspe..
s
nwthW kw the
ptrpn. of I is deirribed. I4ft(iw-fiIm)-
h
P
7 01.5% U mad 38A% 1. is chtmined ot.T:15% ee
eated with (CWI)s at J30-
COH
sivro W
0%
t 10'
43
M
hi
i
i
CHCHM
h A
4%
C of whir Sm is taken as Uw vtartiik@ material. At temp%.
*
b 400
s w
:
a
m
.
e.: t
t
i
a
ft *
ow Ub
palymarrisatium rtectims prodamimate. At
a temp. wumd =6* the allaimmeat of equill. is proc
ll
i
fee
t
ca
y kithreodent 01 the rate of MW pomp (up. to 40
l
d
h
h
/
J goo
ra
.
n
e.).
n "Wa
o woe
see
60
I a - I L A MITALL~AL Lnl9AVM CLAUWXXIOM Igoe
Isom 11..8111.
woe
.1 $*"o, go M. am 8311al aw on. to. 0
11 T I I a, @
U a AT in a 19 a
0 - a 1 0 a a
i
@
0060000000600000400*46 00
r0oooo
o 0 19
:o:::oooo#oo
000000000000000000000 0000000040 6 0009000
:
-00 06 0 0 0 00 0 0 04 ale 0 o * 6--o 'e-44-4-0-4474-0 *4 0004 o a 0 a 0 0 0 W W
_
_
___
-_
-
,
:
a 0 0 0 0 0 0 0 0 0 0 00 0 0 o G o 0 6 1_*
0 0
a 0
e, G
#
6
0
*W*j
0 a 0 o 0 o 0 0
oa 21 21 n A a 29 A) 11 11 13 U 15 At 11 a FT A, Q At AS 4S C 40
a P a
o A r A AI 01 RO r, Mj"j;WrIz. A
7drocir"'a'of the bit Ely fe in
fro
!
00 C lot .
IcAbols. V. 11. Krauir usad Va. %I. SloI.MJ4I. f. lp-
-- -
1 ?. , . -
i
N
I c"
(I @
S
s
R
n Wri
) 9
( 00
- ,
00 "
.
.
.
.
.
i
I:," Ili
A
n
.
?193(1).- The lichaviur of Lebedev ratalvu'%icf4'jC. .1 . 25, -00
115) im4l in the conversimi of MrOll. 1,rolf. i!wii.pro". 00
00 jer-BuOll. as well as mixts. of EtOH and McOlf, Moll
00 and PrOff,andiso-NOlland FtOlf,carri"Imit by PAV4119 _41119
tile ale. vapors through a Xla.@s ttjlw chuged with the
00 alkwe calaly%B &fill heated tip to 4.71'. was studied. It
b
00
041 %a%
outid that McOlf is kkI% rwiverttil into MrIO in
v the pre-lencrof themixedcatal"t enutit.75%44 adchy Irti-
. I
1-00
00 gillA1111K Component. while 11010 ii Gwitted inmall Amt.,.
Of HIM iS V0"VVFIC.I untler the shove condithm, nillittiv him .00
H(Altl, whilf ptopylent is Obtained it lite valitly-st coul. 6 0
00
j a hydrucartFort Cjf IF having a conjugated double bond wa-t
21@O olj-..erved to some extent. lso-PrOlf Ili the prescruc
"
" 0
@,f the
normal
catalyst (contg. M-25% of the dehydrat-
00 ing and 7S-M%of the dehydrogenatinjicatalytt) forms pfi-
@
matily propylene. although on is=raxing the temp. to
'
zoo
I
00 NMI
a tichydrotteriatiou and a dehydration take place ._
00 a with the formation of acetone. In the prmnce of 95%
A (he dehydrogenating and 5% of the dehydrating com-
00 pottent in the catalyst the formation of diene hydrocarbons
with conjugated double boods istin observed. In lite
"
"
decompit. tit BuOlf in the prrqem-e of the
nontial
%;AtL�IY'4t l".WUd0btItyICnV Illikinly is filtIllVd. NICCOE'l i%
I,,ttuv,I only in the presence of a 9517p dehydrotiestatimi
and 5% dehydrating cataly I. The yield of diene hydro-
.3
carlkms is in this raw still lower Ili-tit from WWII. In
tile caw td a rnixt. 4 ales. with differrut bwatiou of the
III
(
Krutill.ruch ale. fracts Ales.irithilic
7
-ine lovaiiat of the oil grotil. jVtMi and NOH) hicut
Nviny]. bipropeityl and piperyl.ne. The yields of dicut,
s L A of TALL UP(KAL LITER uhydrukarbtms in this ca!w amount it): bivinyl 26.2% of
iheamt.ofEtOH, bipropenyl 2.(197vof PrOlf and pipery- oJ-t-
so 2: -i7,-Ajvo -,-T
AT D LS!
0 0 0 0 0 111114
4 &;vue Its.7%uftheUtoll
I
throulgh the cattil
is IT tv
IF or At it 19 it
0 0 o 0 0 a 0 0 0 and 11.17c,iftheuint.oiC.HOlfsli~'.f - it, 00
". t. "A. A. ltmhtlinxk w la 2 Aj io
o 0 o 0 0 0 0 4 C 0 0 0 0 0 3 0
4 o o 060,6 0000 0 04 asill 666. 64 0.4 o sages 0 64 000000000-
a e 6 0 6 a a 0 a i's 6 f 4
*
h 0 9 0 0 0
00 o o o 0 e 0 0 f e 0 4 0 0 0 a 0-0 0 9 -.0 * 4 0 : : 4 0 o, a & 0
0 : ::0
I ; ; a I t 4 _., I 11: 11" 11 1* t? tj tv a. 1 11 .1 IjA1% 's @? :b N 1, L 11 m C I; m r. k I i, . -*
A C V L f 11 j L L a ftf 9 P I f V y j I I I AA 0 S L
so -00
00 -
9
06 :
0
00 -the L"mrimakm of alias* hydrowboon With &Ukal 00
40 V. Tk* Isocioditsdom al Agri-butyWass. Va.
00 C". 0% S. S- W) 7. 1614-7(1037.1;
31. 12414"1. wit"I t.
;W.Win t tL-ki Ih, 1.1 J@Q,wg 1. 2.41Ai ... 1.00
I twill. firlic, but thi, 1-111m.M4. ......
[,
;
tAw"lo 00
_eo
1
0 00
__00,
zoo
00
400
-40
_96
06 0
A i L A f1Aij!.,6PL4L L111441kOt @t'%SlftATIC@
is m VA 11 1 .4
0
4
70 J14
4*
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
sw w w 0
000 vo,c.
0.0 ;
0 0 0
0
0
I, it '1 4
0
tO A
o tjo
p It
iol
t
v
l
go
00 A !
0
The I- satiow ad aUsus bydrocarbo.-s b
00 V1.
M. .5lobo". J. Gem. CAm. (U. S. S. R.)
-
-cf. C. A. 31, MrAll-When FtC-CH
(t9n7j
ized iI;@ floridin at 275* the Ist step is the rev
06 alt ination of MeClf:C:CH.. Part of th. re
"
at
00 tobivinylanii no McCiCMc is formed.
Whe
rotrjpd. is isomerized, it goes directly to 1-.tC:C
t r
In er
modiste alkne formation. These "
19 ,
lu'ZiGhly general for such hvdrcArbnnx. It
06
:0Z
N
0 li U its 10
1
_
I
0 I
.11111014 1
:
09
-00
:g
silkates. ,
Ya. .00
', X170-80
.00
isisomer.
nible for- 600
t9 further
=00
thelattCr
If without 00
Lions are
00
M. L.
2 SOO
so
896
'00
;,qq
00 1
00.
.
00
S aI L AMETALLURGICAL LITIENATUSUE CLASSIFICATION
00 H@ .3", 00
go k; i-ILL-il avc-aw Lit
U 15 AV 10 All F All I 1 4 Od 0 0 4 1 Is 02 A 4 1 1 9
;6 0, a it it a No IS1 11104;
OTI;400 0 000:00 0 00 0 0 00000 0 6660990009006060046
M JA
CIP 4
ip * * * * * *-. * W-* 0 w w
09
Sa u X a 9 40 of a 0
-jL It I I , b _,_
ps Mt APP P*GPISTIIS MCIN
d 4110110. J.
VMA#MIlW a adt" Obtalyso of
iw - - - - - then k bubba (A., left. It. =00
R. T.
Igoe
MOO
of CLAUIPWATME
-14--sow ttat 904
in.
b u a Aw BAK
Am a a ad 0 a a I w 5 A a 3
d"
w w
0
I
i
0 0
F 0
0 0 0
*4 1 1 1 11611110 fill to W 1) 's it q
n
A m 14 H
A A V
A A L A A-ALA-1 L a if P-0 It I.A. A f I-", L,j _AA 14 CC W U
00 Ar
The dehydration of #&jkyj&jiyj garbinols. 1,A %I
(;r.. R I A 1, in
,
-
h-fiSIi
,ft
-_,&I)(Itu4). When 00
dehydrated by heating with lfcith or (C(hli): or by aildn. -00
0 and reirmoval of 110. it fortim CJijs, which he-% twen con-
I
-
to
m 2-toothyl-1.4-rlentadiene. Ozollation shows 00
1:
0 that onlY a mimalf amt. of thk compd. is pmwnt, and Inmt
f th
i -00
96 o
r react
m Iliroduct is
'
Onal
ic
h
i
d
l
d
i
d
-00
64 v
an
r
t
it a
l
n. couilm
y
.. tit. 132-4
). In a
%indar way. 10,C(OlOCII.ClUCH, gives chit-fly 1,1-
"
dir
hyl-I.A-buladhor (malcic anhydride addn. comtxI.,
4*
72
d
li
-
m.
a
), an
ttle 4-eth.YI-1,4-he%&diene; and Pr,-
0 a COHCHsClf;CH# Vvr% mainly 1,1-dipro
pyl-1.3-hutu-
.
dienc (fnalric anhydrkk adtin, "ilupd. is of high mol. wt.),
00 0 1 and sonic 4-propyl-1.4-hrpladirtir. However. im-Nt- ce 0
69 001I)CHiCILCH, gives a inixf. contg. 10% .5-inethyl-
0 4-isnlropyl-1.4-hriadirne and 207a 1,1-cifinopropyl-11"i-
butadimm (makic anh
dride addn
d
21V
zoo
0: . muip
y
.. m.
Fhu%, dOwdralmn xlw@' ',m,hns t., tit,
%%.gut-r-zaIl-v radt-, ami tim exl@tijlg d(nable Nuld tit
-
i ire*
t
ll
11101. 411MI-94 tht rrilt-IiUtl tMAUrd till' fill'111:464-n fif .1 zoo
vonjuKaled vsfrm
11 10 r';-trt
see
z*e
No*
t:Go
F
AID-I,LA 41TALLURGK
_!7N AL LITINAT"I CLAISI
ICATION
too
0
-1-1 -- -, -.a., .1. c- 1
0
u 2 AV PO 15 i . I I
0 3 IIIAMIX 'dodo PI-IM815 3 @I I T
W" a
0 0 0 0 0 0 0 0 0 0 9 :;* 0 0 0 0 0 0 0 a 0 0 0 0 o o 0 0 e M
00 @ 00
*TOO:::: :N 00 0 0 00 00 0 00 0
0 1111 0 o 0 o 0 a 0 o o o 0 * 0 o & o 0
A is 11 1) 1) to b 16 31 is it a 17
11. F Q R.- 1-L -M-1. A (A M
A Ist A@o INV 004tal
Vilf-Ill)II AND POOPI 0 1 '11 a-b$ I
R
M(AAW-The im
And cryst. Nn,.S in IN,
no 46!ro1AiPpke!e (1) bit( gave bivin
U
0 ) resvm
p@cr!frd clastic product (
1, art I ni'li
- y. in mg. solveut,a, %ktw s
te l. The reaction in 7W7, alc. pr,@Nft
o: @o%illej atilts. A)f biyitivl atilt If. anti cat
1,4yulefirmat4lo IToduct iml@ In 50!",
metion product vm M, 1117, 1 and nt
00 (it is an extremely fetid substance and is
4 anti higher tx
- xtd. froin the dimit. midue with r1,O
,11,til. over %a. H. 1). tl:@
V M. R. 2A.0d (caled. It give-:% 11
00 11 9@! 4', and it Niel coinjul., in. IZ:.' 3*.
*0
L A METALLUSIGICAL LITIFO&TWE CLASUPKAVOW
jo 0 0 0 0 0 0 0 W-"- w W-,-
JN@Ioji 121) MIS I&V Mkim At 410 44GEO
if 4-t, It
00
01
J. 6er. I*Awaaw@ .00
craction td 1.4-
,,r; zlic. IWtoed
I alld a high1v -0
lux vulc-Anit"I
00
Ohng in Call,, .
clil tvaces of 1. .00
%Metuhle liquitl MOO
file. tile chief
larvinyt laml
11.
-0
.
robably a nuxt.
'
If was
rmem ;00
nd purified Ilv -00
14SM,
00
Clv in. .
CIIAS@ Maw
o* 0
2 goill
11410,
f
'
i
@
An I S 4 04 OMNIMBASAIIC3
up @ .1, %14
0 0 0 0 0;0 0 0 0 0 0 0 o 0 0 o 0 0 : : : 0 0 0 0 0 0 0 & 0 0 0 0
* o 0 0 010 * 0 a a 0 0 o * 0 0 0 0 Oil: a 0 0 0 0 0 0 0 4 0 6 0 0
0 0 0 * 0 0 0 0 0 0-0-0--o
0
o4 10 a 11 22 P N 1$ it v x M, x 11
t w 11 1) q 14 it it it 11 D MIS kPA144 s@ Gio
1-4 f. - A, j A , L 4 1 a a
t.k.1 0,
0
00
00
-00
00 Dehydropmadw of I-vW44idekssene. @a. R. -00
'I'W' N noba J (;Col. C". (V. S. .-No
00 xC
,?RP?l; d73"(i=).= I-'lri-yI-4;lYcM'v lie
04, 1 at the rate of 0.2 X./min. over Ni deposited an AIO@
00 at 300-20* produced up to 84% PhEt and traLes of sty-
rene. The gaseous reaction products contained no C11, -4L
00 and other hydrocarbons. 1. b. 129-30% nW 1.4631.1, wa.,
00 prcpd. by polymerizatim of 1.3-butadiene (LOwdev and
Skavronslimiya, C. A.#,&3.5). The presence of styrene i
the catalysate suggests that PbEt 6 focincd by hydrt4crtan
tion no the intennediste styrene and not by pfebminary
Lsom rization of I toethylcyclobesadienc and dehyd"e3m-
tion of the Wter to PhEt. Chas. 141jue -00
00
00
00
00 all ZOO
60 so*
-00.
b
moo
Ito I
A S a . I L A -ETALLUPWAL LITINAlbRE CLsSSfFKATPCw t.
F woo
T,
U is A. .0 is An S a Od a I Ar of 5 A 0 3 9